id	author	title	date	pages	extension	mime	words	sentences	flesch	summary	cache	txt
work_nf5r437zefg45hytqvl6e5cl4m	Gerhard Grüber	The Beauty of a Visualized Peroxo-diiron(III) Intermediate	2015	2	.pdf	application/pdf	1430	139	67	The Beauty of a Visualized Peroxo-diiron(III) eIF-5A and a peroxo intermediate state. dioxygen to yield a peroxo-diiron(III) species named P. For the structure of the peroxodiiron(III) intermediate P, which precedes Q, various configurations Importantly, there is a human nonheme diiron oxygenase called deoxyhypusine hydroxylase (hDOHH) in which the peroxo-diiron(III) intermediate is stable. two crystal structures of hDOHH, one of the peroxo-diiron(III) intermediates, and native peroxo intermediate of a nonheme diiron enzyme. The 1.7 Å structure reveals a cis-m-1,2 arrangement that the peroxo intermediate may unusual stability of the peroxo intermediate of hDOHH: in contrast to all diiron enzymes, hDOHH features a Peroxo-diiron(III) Core (A) Possible geometries for the peroxo-diiron(III) core of diiron-containing oxygenases; (B) Fo-Fc difference density (contoured at 4.7s) for the non-protein ligands of the diiron core of hDOHH. n(III) intermediate P of sMMOH is by itself The Beauty of a Visualized Peroxo-diiron(III) Intermediate The Beauty of a Visualized Peroxo-diiron(III) Intermediate	./cache/work_nf5r437zefg45hytqvl6e5cl4m.pdf	./txt/work_nf5r437zefg45hytqvl6e5cl4m.txt