key: cord-353087-nxjfbo0h
authors: Kumar, Amit; Mishra, Saurabh; Taxak, A.K.; Pandey, Rajiv; Yu, Zhi-Guo
title: Nature rejuvenation: Long-term (1989–2016) vs short-term memory approach based appraisal of water quality of the upper part of Ganga River, India
date: 2020-09-16
journal: Environ Technol Innov
DOI: 10.1016/j.eti.2020.101164
sha: 
doc_id: 353087
cord_uid: nxjfbo0h

The deteriorating water quality (WQ) of the sacred north-flowing perennial Indian River, Ganga was a serious concern in recent decades for population adjoining to the river and policy planners. The present evaluation attempts to assess the long-term (1989–2016) physiochemical characteristics of WQ of river Ganga at five upstream locations (Uttarkashi, Tehri, Rudraprayag, Devprayag, and Rishikesh) of Uttarakhand, India using comprehensive pollution index (CPI) and environmetrics (PCA and CA). These methods were used to categorize, summarize expensive datasets, and grouping the similar polluted areas along the river stretches. The WQ of river at all the locations were within the good category and most of the physiochemical parameters were well within their acceptable limit for drinking WQ. Considerably, CPI demonstrated the river WQ was in slight pollution range (CPI: 0.40–1.00) in the year 2007 and 2015 at all the five locations. The positive correlation coefficient (R(2) > 0.50) among NO(2) [Formula: see text] NO(3), Ca, Na, B, and K indicates the significant contribution of organic and inorganic salts through runoffs from catchments due to weathering of rocks. PCA confirmed the input source of nutrients in the river from both natural and anthropogenic sources. Moreover, the upstream WQ assessed was found to be good as compared to the severely polluted downstream region. Due to COVID-19 and shutdown in the country, reduction of pollution load in the river was observed due to the rejuvenation capability of river Ganga. This information can assist the environmentalist, policymaker, and water resources planners & managers to prepare strategic planning in advance to maintain the aesthetic and cultural value of Ganga river in future.

Water resources and quality of freshwater are the foremost basic need of flourishing ecological diversity and sustainable development. The rapid growth of human population, urbanization, and industrialization have stimulated the over-extraction of water from the freshwater sources (e.g., river, lakes) for various purposes of the daily demands of a comprehensive study of WQ assessment using long term data of physiochemical and biological parameters has not been reported in the upstream of the river Ganga. The lack of long term evaluation restricts the visualization of changing WQ at one side and reduces opportunities to facilitate enabling conditions for management of water crisis (Tripathi and Singal, 2019) . Considering the lack of information about temporal changes in the WQ and thereby refraining for developing the suitable policies, the present study is focused to analyse the long-term variation in WQ of river Ganga at the site of culturally important upstream regions (i.e., Uttarkashi, Tehri, Rudraprayag, Devprayag and Rishikesh) of Uttarakhand, India. Attainment of this purpose is formulated on the premise to classify the overall WQ of the river with respect to the suitability of water for human consumption purposes and to identify the major contaminants that imbalance the WQ of river Ganga. The data sets for physiochemical and biological parameters were collected on monthly basis during the years 1989-2016 for achieving the objective. Primarily, the comparative analysis of individual parameters to the standards prescribed at the regional and international scale is performed to identify the WQ for anthropogenic purposes. Moreover, the available datasets are used to evaluate water quality indices (WQI) as comprehensive pollution index (CPI) to classify the overall water pollution in the form of single numeric value. Several WQI is available to classify the overall water quality of a freshwater body for anthropogenic uses (Kumar et al., 2017a,b; Khan et al., 2019; Panwar et al., 2020) , however, CPI a comprehensive numeric evaluation method for evaluation of surface water pollution was preferred for being a concise aggregation of various WQ parameters. Furthermore, the application of environmetrics like Principal component analysis (PCA), and hierarchical cluster analysis (HCA) was applied to identify the loading source of pollutants and similarity of pollution among the sampling locations. The government of India has formed an administrative body called as National Mission for Clean Ganga (NMCG) under the Ministry of Jal Shakti to look after the planning and implementation of projects related to rejuvenation of river Ganga that involves national and international organizations. The result of the present study would provide information to NMCG, environmentalists, policy-makers, water resource planners, and managers to understand the sources of pollution, pollutions sites, and making strategic mitigation plan to maintain the aesthetic values of the river.

River Ganga is one of the sacred freshwater bodies of India, flows in northern part of the country. Two Himalayan rivers are known as Bhagirathi and Alaknanda covers 200 km and confluence at Devprayag in Uttarakhand and carries the name called ''river Ganga'' in its flow pathway after this confluence. Bhagirathi originates from Himalayan Gangotri glacier located at an elevation of 7138 m amsl, in Uttarkashi district, while Alaknanda originates near the holy shrine of Badrinath, located at an elevation of 3300 m in Chamoli district of Uttarakhand, India. Since Devprayag, river Ganga flows downstream through the mountainous region for about 220 km before entering in the plain at Haridwar district of Uttarakhand. Further, river Ganga covers about 2290 km of downstream flow stretch across the states of Uttar Pradesh, Bihar, and West Bengal of India and finally merges into the Bay of Bengal (Kumar et al., 2017a,b) . In addition to a strong cultural presence among the residents of India specially the Hindus, the river has diverse ecological relevance and contributes huge support to the Indian economy. Each city and ghats located along the stretch of river Ganga have religious significance, as being either as a spot for temples or for cremation place, thereby attracting the pilgrims from all over the country and globe (Pandey and Yadav, 2017) . The river receives a huge amount of partially/untreated wastewater from domestic, industrial, and agriculture sectors along the stretch from its origin at Gomukh (Tripathi and Singal, 2019; Mishra and Maiti, 2019; . Considering the importance of river, entrance of wastewater, and land-use patterns, surface water monitoring, and assessment were carried out in the upstream region of river Ganga and its main tributaries.

The variation in temperature of the study areas remains in the range from 0 to 46 • C. In pre-monsoon (summer) and monsoon season, average temperature at upstream, midstream, and downstream was found to be 20-25 • C, 25-27 • C and 27 to >30 • C, respectively, while during post-monsoon season (winter), the average temperature at upstream, midstream and downstream was 13-15 • C, 15-18 • C and 18 to >20 • C, respectively (CWC, 2012).

The water quality data (Jan 1989 to Jan 2016) were collected from the five major locations, as Uttarkashi, Tehri, Rudraprayag, Devprayag, and Rishikesh. These locations were part of the Himalayan mountain region. The details of the data collection sites are reported in Table 1 with their respective locations in Fig. 1 . In this study, the sub-surface water samples were collected from the selected sampling locations during the day time between 10:00-11:00 am, on the first day of every month from January 1989 to January 2016 for evaluations of the physicochemical parameters like pH, dissolved oxygen (DO), electrical conductivity (EC), and surface water temperature (WT) using portable analytical instruments. The details are provided in supplementary table S1. The composite water samples were filled in three acidrinsed airtight plastic containers of 500 mL volume at each location, which were further stored at 4 • C temperature without freezing to avoid unpredictable changes in quality before analysis. Among three contained samples, one sample was fixed in biochemical oxygen demand (BOD) bottle for the analysis of BOD, while other two contained samples (kept unfixed) were used for the analysis of other water quality parameters. The contained samples were transported to the laboratory within 24 h for experimental analysis. The experimental analysis of water quality parameters was performed in triplicate as per the procedure reported in APHA (2011) and the mean value of observations was estimated. The experimental procedure followed for analysis of physicochemical parameters with their abbreviation, measurement unit, and the numeric value of standard acceptable limit in drinking water, prescribed by BIS 2012 and WHO 2017, is provided in supplement table S1. The water quality data obtained during laboratory analysis were provided by Central Water Commission (CWC; http://india-wris.nrsc.gov.in), a body of Ministry of Jal Shakti under Government of India to carry out river water pollution assessment in this study. Real-time data of water quality in the river Ganga at downstream regions during April 2020 has been taken from CPCB (2020) and used to see the effect of water quality during country lockdown (COVID-19) at downstream locations.

In order to identify the variable parameters that affect the river WQ, the data obtained during laboratory analysis of water samples were compared with respect to their respective standard acceptable limit (SAL) value. Based on that, the collected WQ data were used to evaluate the CPI to classify the overall WQ status of river Ganga in single numeric terms at a particular sampling location in the respective month. The CPI is evaluated based on those parameters whose SAL has been prescribed as per BIS (2012) and WHO (2017) . Parameters like DO, pH, BOD, EC, COD, alkalinity, total dissolved solids (TDS), total hardness (TH), and chloride were used to evaluate the index value. The mathematical equations (Eqs. (1) and (2)) of CPI are expressed below:

where PI represents sub-pollution index of ith parameter of water quality, C i represents concentration value of ith parameter obtained during laboratory analysis of collected water samples, S i represents SAL of ith parameter for drinkable water, and n is the total number of WQ parameters. The WQ status classified by CPI value and ranges from 0 to 2.0 and divided into five classes for indicating respective WQ status as 0-0.20 (excellent quality); 0.21-0.4 (good quality); 0.41-1.00 (slightly polluted quality); 1.01-2.00 (moderately polluted quality); ≥ 2.01 (severely polluted quality).

In order to standardize the large dataset of WQ parameters, the mean, median, kurtosis, skewness, population standard deviation, and Z-test values were calculated, which were further used to assess the comparative responses of different sampling locations on a common scale. As the focus of the study is on overall response across the sampling locations, the Z test value is used to centre all year's (January 1989 to January 2016) monthly data on their mean value to reduce the influence of any individual year data, which might have high average raw values of a particular parameter that unduly affect statistical analysis (Spears et al., 2015) . The datasets were used to perform the statistical analysis to identify the root causes of WQ deterioration of river Ganga.

The statistical analysis of WQ parameters was performed through the HCA and PCA using SPSS, version 16.0 software. For HCA, a mean value of all year's monthly data of each parameter was evaluated and used to construct cluster of sampling locations that depicts the similarity in pollution load among the sampling locations. Further, PCA was performed using raw data of WQ parameters for each sampling location to identify the most influential parameter of water quality deterioration and to predict the sources of pollution in the river (Tripathi and Singal, 2019) .

The physicochemical characteristics of water in river Ganga were assessed at five upstream locations on the first day of each month from January 1989 to January 2016. The descriptive statistics of parameters (like DO, pH, EC, BOD, TA, F, B, Ca, Mg, Cl, SO 4 , Na, K, NO 2 +NO 3 , and WT) obtained from the analysis of water samples were represented as Box-Whisker plots (Figs. 2 and 3). The mean of individual parameter was estimated based on all sampling months along with median, kurtosis, skewness, and Z-test values ( Table 2) .

The onsite measurement of pH value falling in the range of 6.4-9.0, 7.0-8.9, 6.3-8.8, 6.3-9.9, and 7.0-10.2 at locations S1, S2, S3, S4, and S5, respectively, with overall mean value of ∼8.0 and median value of ∼8.00-8.08 at all sampling locations. The maximum value of pH (>8.5) was obtained in January 2010 at all locations, while it remained stable within the SAL (pH 6.5-8.5) in other months. The WQ parameters WT and EC were within the SAL at all locations in sampling period, with maximum values ranging from 18 to 27 • C, and 266 to 491 µS/cm, respectively. The minimum concentration of DO was 5.8, 6.1, 5.73, 5.69, and 3.85 mg/L, while the maximum BOD concentration was 2.49, 4.06, 2.88, 3.54, and 50.10 mg/L at S1, S2, S3, S4, and S5 locations, respectively. The lower concentration of DO < SAL (5 mg/L) and higher concentration of BOD > SAL (5 mg/L) at location S5 were obtained in summer and monsoon months. The location S5 is an important tourist destination and attracts huge tourists resulting in the excessive anthropogenic hindrance in terms of bathing, river rafting, and other recreational activities in monsoon months. Notably, the overall median concentration of DO and BOD were obtained as ∼8 mg/L and ∼1.2 mg/L at all sampling locations. In addition, input of agricultural and forest runoff from the catchment in monsoon month were the major causes of decline in DO with increase in BOD concentration in the river at location S5. According to CPCB (2020), if the pH and EC of surface water lie within 6 ≤ pH ≥ 8.5, BOD ≤ 3 mg/L, DO ≥5 mg/L and EC <2000 µS/cm, the water could be considered suitable for bathing, and irrigation purposes, but require conventional treatment for using for drinking ((Kumar and Gupta, 2020) . The concentration of TA, Cl, Mg, and SO 4 was observed within their SAL at all sampling locations at each month. Until February 1991, the concentration of fluoride in the river was estimated above the SAL value of 1 mg/L, while it became within SAL from March 1991 to January 2016 at all sampling locations. The improvement in WQ was due to decline in F concentration indicating the reduction of fluoride contaminated wastewater directly discharged into the river. The reduction is attributed to the impacts of GAP-II (Tripathi and Singal, 2019) . Mean and median concentration of B was obtained within the SAL value of 0.50 mg/L during the sampling period. However, during the monsoon season in year 2011, the maximum B concentration of 1 ± 0.10, 1.1 ± 0.10, 0.44 ± 0.2, 0.60 ± 0.1, and 0.40 ± 0.2 mg/L were observed at sampling locations S1, S2, S3, S4, and S5, respectively. The mean and maximum value of Ca concentration were within the SAL value of 75 mg/L at locations S1, S2, and S3 during the sampling period. Although, the mean value of Ca concentration at location S4 and S5 were obtained as 19.65 and 24.02 mg/L during the sampling period, but the maximum Ca concentration was above the SAL during monsoon months in the year 2006 for both locations. The concentration of NO 3 +NO 2 in river water was found in the range of 0.2-7.0 mg/L, and was lower than the SAL (NO 3 :45 mg/L). The comparative analysis of WQ datasets with their corresponding SAL values reveals that the WQ of river Ganga was suitable for human use after conventional treatment. Our results were within the SAL and supported by Kumar et al. (2010) based on physiochemical characteristics (i.e., DO, BOD, COD, and TA) of WQ in river Ganga at Devprayag and Rudraprayag. Similar to the present estimate, the physiochemical and heavy metal (Pb, Cu, Zn, and Ni) concentration was found to be either absent or within the SAL with alkalinity (Na+ K) type at Rishikesh (Haritash et al., 2016) . In order to ensure the variability and statistical significance of data, the raw water quality data was used to evaluate kurtosis, skewness, and z-test values of individual parameters. At location S1, the kurtosis of parameters pH, BOD, F, B, SO 4 , Na, K, and NO 2 +NO 3 were found to be >3, meaning heavier tails than a normal distribution. The kurtosis of parameters TA, Ca, and WT were evaluated as −0.11, −0.14, and 0.41, respectively indicating the flatter peaks and lighter tails than the normal distribution. The negative skewness of −1.81, −0.39, 0.10, −0.42, and −0.29 were obtained for parameters pH, TA, Ca, Mg, and WT, respectively, indicating the tail of the left side of the distribution is fatter or longer than the tail on the right side. The z-value was zero for parameters EC, Ca, and Mg and positive for parameters BOD, B, Na, NO 2 +NO 3 , and WT, while negative z-value for others that signifies the raw score below the mean average. Similarly, the kurtosis, skewness, and z-value of parameter datasets were also evaluated at locations S2, S3, S4, and S5. Comparatively, a wide variation in kurtosis value of parameters BOD, B, Cl, Na, K, and NO 2 +NO 3 was obtained at all locations indicating variable input of nutrients through wastewater or surface runoff discharge at different locations. Moreover, it is required to draw meaningful information, and classify the overall water pollution status at respective sampling locations in the river.

CPI was estimated to classify the water pollution status at upstream region of river Ganga from 1989 to 2016. In order to present the seasonal water quality status, mean CPI value was evaluated using monthly CPI data for pre-monsoon, monsoon, and post-monsoon seasons and reported in Table 3 . The range of the CPI were from 0.41-1.0, meaning the slightly polluted WQ during the pre-monsoon at location S1 (1991, 2001-02, 2005, 2006-07, 2011, and 2015) , at location S2 (1991, 2002, 2005-09, and 2015) , at location S3 and S4 (1989, 1991, 2002-08, and 2015) , at location S5 (1989-94, 2002, 2007-08, and 2013-15) ; monsoon season at location S1 (1990, 2001, 2006-08, 2011, and 2015) , at location S2 (1989-90, -04, 2006-09, 2011 and 2015) , at location S3 (1989-90, 2007, 2014, 2015) , at location S4 (1989-91, 2006-07, 2015) , and at location S5 (1989-91, 2005-09, 2015) ; and post-monsoon at location S1 (1990, 2000-03, 2005-08, 2014-15) , location S2 (1990, 2001, 2006-07, 2015) , location S3 (1990, 1992, 2006-07, 2014-15) , location S4 (1990, 2006-07, 2015) , location S5 (1989, 2006-07, 2013, 2015) . Considerably, the good quality of water was observed in other sampling periods at all locations.

The comparative analysis of the CPI reveals that all sampling locations were slightly polluted during the pre-monsoon season in year 1991, 2002, 2007, and 2015 and in the year 1990, 2007 , and 2015 during the monsoon season, and in the year 2006-07, and 2015 during the post-monsoon season. In general, CPI results reveal that the WQ in river has been slightly polluted during all the sampling months in year 2007, and 2015 at all the locations. Thus, the assumptions revealed from the comparative analysis of WQ parameters with their SAL value are found to be viable based on CPI results. In this study, CPI results revealed that the conventionally treated river water could be used for drinking purposes. The early evaluation of the WQ based on the nine locations of river Ganga between Haridwar city to Garhmukteshwar during the year 2014-2015 using CPI method reported 2.71 and 2.82 for pre-and post-monsoon seasons, respectively, signify severely polluted water unsuitable for human use (Chaudhary et al., 2017) . Contrary to this, WQ of the river Ganga at Allahabad (Prayagraj) based on CPI was poor quality (Sharma et al., 2014) . Moreover, in order to identify the similarity and dissimilarity of WQ among the sampling locations, statistical cluster analysis was performed using the hierarchical cluster analysis (HCA).

The overall mean datasets of WQ parameters were used for cluster analysis using the HCA through Ward method. The agglomeration resulted into two clusters in HCA and represented by the dendrogram plot (Fig. 4) .

In cluster one, the sampling locations S1 and S2 were grouped, and cluster two contains S2, S3, S4, and S5. Considerably, location S2 was found in both the clusters, which might be due to the impact of their geomorphologic position and wastewater discharge from both the point and non-point sources. The first cluster signifies input of wastewater into the river and can be mainly from the natural sources; however, the second cluster contained the impact of both anthropogenic and natural hindrances in the river. Most of the sampling locations of downstream regions were grouped in the second cluster confirming the input of wastewater through runoffs from the catchment (forest cover and agricultural area). The changing trends in aquatic environment of river Ganga at locations Uttarkashi and Tehri Zero point were investigated through evaluating the correlation between WQ datasets and the discharge and found good category of water (Kumar et al., 2017a,b) . Therefore, the results indicate the dilution effect of surface runoffs in the catchment area due to the base flow. Further, a Pearson correlation coefficient and PCA were performed to identify the source of nutrients in the river Ganga so that mitigation strategies could be suggested in advance to maintain the safeguard of WQ for human consumptive use.

The inter-relationship of parameters indicates the input sources or pathways of nutrient-loaded wastewater, thereby alters the water characteristics in a water body (Ray et al., 2018) . The Pearson correlation coefficient of WQ parameters was estimated to understand the pathway and input source of nutrients in the river using raw WQ datasets for each sampling location (see supplement Table S2-S6) . At location S1, the positive correlation coefficient was estimated between K-SO 4 (0.86), K-Na ( During the comparative analysis, negative correlation between DO-WT, and pH-BOD at all the sampling locations were found which signifies that the river water tends to be slightly polluted, loaded with organic nutrients. Negative correlation between DO-TA signifies that increased concentration of inorganic salts (in form carbonate and bicarbonate ions with the SO 4 , Cl, and NO 2 +NO 3 anions), resulting into interference with the solubility of oxygen (Sharma et al., 2014) . The positive correlation among NO 2 +NO 3 , Ca, Na, B, and K signify the significant contribution of organic and inorganic salts through runoffs from the surrounding natural weathering in mountainous resulting the river water alkaline (Mahmoodabadi and Arshad, 2018) . The positive correlation coefficients among the WQ datasets indicate their significant mutual dependency, actual nutrients characteristics, and common input sources (Singh et al., 2020c) .

PCA was performed through varimax normalized rotation method using WQ datasets to validate the relationship between parameters and to further identify the input source of nutrients for WQ. The rotation of the PCs was performed to elucidate an easy and relevant portrayal of the loading factors by adjusting the significant contributor . Primarily, scree plot of WQ datasets was constructed to estimate the number of components obtained during the PCA (Fig. 5) . For location S1, the scree plot indicates the major break after second component, which reveals that the first two components could produce more meaningful information about the loading of nutrients in the river water (Supplementary figure S1(a) ). The component eigen-values curve in scree plot has dropped after the fourth component which indicates that four components might be useful for better interpretation of nutrient loading. Similarly, scree plots curves indicating component eigen-values obtained from the datasets at locations S2, S3, S4, and S5 have resulted into 4, 6, 5, and 5 PCs, respectively for these locations (Supplementary figure S1(b-e) ).

All the PCs have eigen-value >1 with a cumulative variance of 63.39%, 75.35%, 80.64, 74.53%, and 77.74% for datasets of location S1-S5, respectively. Moreover, the Kaiser-Meyer-Olkin (KMO) and Bartlett's test of sphericity of datasets were estimated before performing the component analysis. The KMO values of 0.69, 0.69, 0.70, 0.66, and 0.65 with Bartlett's test of sphericity (degree of freedom: 105; and zero significance), the Chi-square values of approximately 815.12, 1009.81, 865.04, 1211.26, and 691 .14 were estimated for WQ datasets of all five locations S1-S5, respectively, which signify the suitability of datasets for PCA. The PCA component's value and commonalities of datasets are reported in Table 4 . All the PCs have high loading of different parameters (Fig. 5) leading to better insight into the hydrochemical and biological interpretation.

PCA for location S1 was resulted into four PCs with PC1 having 26.49% variance explained with higher positive loading for K, SO 4 , Na, Cl, DO, and BOD. PC2 has positive loading of all parameters except F and WT. The positive PC value of 0.62 for F was obtained in PC3, while WT was positively loaded in PC3 (PC value of 0.25), and PC4 (with highest PC value of 0.65). In PC2, Ca, TA, Mg, Cl, NO 2 +NO 3 , and pH exhibit their highest positive loading. The highest positive loading of Cl (0.59) was obtained in PC3, while loading of BOD (0.47) and EC (0.24) were obtained in PC4. PCs for location S2 resulted into four PCs, where PC1 with variance of 37.97% exhibits the highest positive loading of Na, TA, K, Ca, SO 4 , Cl, WT, and B, which indicates that the river receives a huge amount of runoffs water from agriculture and forest cover areas. The highest positive loading of parameters BOD and EC was obtained in PC2, while the highest positive loading of parameters Mg, NO 2 +NO 3 , and pH was found in PC3. Considerably, the parameters DO and F exhibits the highest positive loading in PC4. PCs for location S3 was defined by six PCs, with the highest positive loading of parameters Na, K, SO 4 , Cl, Ca, and B were found in PC1 with the variance 29.72%, while the highest positive loading of parameters Mg, NO 2 +NO 3 , DO, TA and EC, parameter WT, parameter pH, and parameter BOD were obtained in PC2, PC3, PC4, PC5, and PC6, respectively. PCs for location S4 resulted into five PCs, where the parameters Na, K, SO 4 , BOD, Cl, Ca, and B exhibits highest positive loading in PC1 with the variance 28.16%, while the highest positive loading of the parameters Mg, TA, NO 2 +NO 3 , and EC, F and WT, pH, and DO were obtained in PC2, PC3, PC4, and PC5, respectively. PCA for location S5 was based on five PCs, where the parameters Na, K, SO 4 , BOD, Cl, Ca, B, and TA exhibits the highest positive loading in PC1 with variance 29.85%, while the highest positive loading of the parameters Mg, NO 2 +NO 3 , and EC, WT, DO and pH were obtained in PC2, PC3, PC4, and PC5, respectively. The parameters loading in PC1 governed the nutrient input source from natural sources, while positive loading of parameters in PC2 defined the nutrient input through direct discharge of partially or untreated treated domestic or industrial wastewater into the river Kumar et al., 2018) . During the comparative analysis of parameters loading in PCs at all locations, it was noted that the parameter K, SO 4 , Na, and Cl were positively loaded in PC1, which signified the input of their salts from both natural source through runoff or landslides and anthropogenic agricultural activities (where use of chemical herbicides, fertilizers, pesticides, and mining operations occurs) (Dalakoti et al., 2018) . In this study, the trend of parameters loading in different PCs was found to be almost similar at all locations. Loading of parameters in PC2 was due to the input of nutrients specifically from the anthropogenic activities including agriculture, while parameters loading in the PC3, PC4, PC5, and PC6 were defined based on the input from the natural sources (Rajkumar et al., 2018) . The upstream Ganga river basin's catchment area (lies in active Himalayan Mountain) is mainly covered by forest and agriculture land with scarce industrial setup compared to the downstream plain areas with dense industrial setup. Therefore, the surface runoff and landslide due to weathering of parent materials often occur in the area, which might be the major input source of nutrients in the river Ganga. Researchers across the domain have investigated the water characteristics of river Ganga all along the stretch ( Table 5) .

The river water quality in the upstream region (from Uttarkashi and Tehri Zero Point Bridge via Devprayag to Rishikesh) has been reported to be good and safe for human consumption. The observations and findings in this study also supported the similar water characteristics at these locations. Compared to the upstream region, the downstream region (plain area from Haridwar to Kolkata) of river Ganga is found to be highly polluted due to excessive anthropogenic hindrance, large input of domestic and industrial wastewater into the river (Kumar et al., , 2019a .

In order to control infectious spread of pandemic flue disease caused by the pandemic Coronavirus , the government of India implemented the lockdown of country since 24th March 2020. During the lockdown period, human life comes to a standstill and all the major industrial activities (except medical and food industries) were shutdown (Yunus et al., 2020) . For decades, water pollution along the stretch of river Ganga has been a prime concern and a matter of research that is reported by numerous researchers in the literature (Table 5 ). Based on the literature available, the major cause of water pollution has been identified as direct discharge of partial or untreated wastewater from industries located in the basin of river Ganga and its tributaries. During the lockdown, since all the anthropogenic activities were prohibited and closed down for weeks, it was expected that pollution load could decrease in the environment (Yunus et al., 2020) . According to CPCB (2020) real-time WQ analysis of river Ganga, it is observed that the WQ is improvised and found suitable for life-supporting purposes in the studied stretch (CPCB, 2020).

Previously, the river Ganga water at sampling locations like Haridwar city, Kanpur city, Varanasi city, Prayagraj, and others were found to be severely polluted (DO <3 mg/L, unsuitable biotic environment) in every month and seasons as well, reported by Mishra et al. (2009 ), Chaudhary et al. (2017 and others. Considerably, the WQ at these locations becomes suitable for human use as the parameters like BOD, DO, EC, pH, WT, Cl, COD, F, NO 3 , and K are found within their permissible limit during the lockdown period in April 2020 (Table 6) . Moreover, river Ganga has self-assimilative or purification capability, which seems to be enhanced during the recent lockdown period (Dwivedi et al., 2020) . The results of WQ in preceding years were compared and it is observed that the aim of rejuvenation of river Ganga could not be achieved with GAP-I and GAP-II, however, during lockdown, the WQ was improved significantly and become suitable for human consumptive use. Therefore, it can be inferred that if the discharge of industrial effluent and wastewater in river Ganga would be checked, the river would rejuvenate herself. Moreover, this study draws further attention to the WQ of the river after the upliftment of the lockdown once the industrial activities will be resumed and the pollutants along with the wastewater will eventually be discharged into the river. Therefore, it is suggested that appropriate and stipulated actions should be implemented immediately to reduce the risk of environmental damage to the sacred river Ganga ecosystem with maintaining ecological health. Present study will act as a reference to the water planners & managers, governors, environmentalists, and policy-makers to take strategic mitigation plan to maintain the aesthetic and cultural value of the river.

The long-term study estimates the WQ of river Ganga based on the physiochemical parameters at the five upstream locations of Uttarakhand, India using CPI, PCA, and HCA to categorize the WQ into different classes for understanding the hydrochemistry and cluster of similar water quality status. The values of physiochemical parameters were within the acceptable limits signified good WQ of the Ganga river and suitable for life-supporting purposes after conventional treatment. PCA revealed the enrichment of K, SO 4 , Na, and Cl in the river through the runoffs and discharge from natural sources (i.e., surface runoff from catchment, weathering of rocks, and landslides). Comparative analysis of upstream WQ with the downstream locations revealed that downstream river water is severely polluted. The prime sources of river WQ deterioration were discharge of domestic, industrial, and agricultural wastes at the downstream of River Ganga and contamination from local villages into the river water. During the country lockdown due to pandemic Coronavirus disease , the WQ at downstream region was improved and became suitable for life support purposes. It is found that the self-cleansing property of river was enhanced and rejuvenated during lockdown period, which has been troublesome tasks to achieve in decades.

This study yields the valuable information of different indices and multivariate statistical techniques in the investigation and explanation of the compound datasets in recognizing contaminant sources, and in understanding dissimilarities in water quality for better designing of action plans for river rejuvenation. The rejuvenation should be achieved by reducing livestock activities and domestic discharge around the river, discharge of wastewater otherwise; over pollution have the potential effect on the human population leading to socio-economic disaster. These determinations should be considered for future planning and management of the river for realizing the potential ecosystem services to the inhibiting population along the river.

Amit Kumar: Conceptualisation, Data analysis, Preparation of the first draft, Proofread the final version of manuscript and agreed for publication. Saurabh Mishra: Conceptualisation, Data analysis, Preparation of the first draft, Proofread the final version of manuscript and agreed for publication. A.K. Taxak: Data collection, Extraction, Formal analysis, Proofread the final version of manuscript and agreed for publication. Rajiv Pandey: Proofread the manuscript and agreed for publication. Zhi-Guo Yu: Proofread the manuscript and agreed for publication.

The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.

The data that support the findings of this study are available from the corresponding author upon reasonable request.

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AWWA and WPCF Standard Methods for the Examination of Waters and Waste Waters

Assessment of Ganga river ecosystem at Haridwar, Uttarakhand, India with reference to water quality indices

Estimating the value of improved wastewater treatment: The case of River Ganga

Human health risk assessment due to agricultural activities and crop consumption in the surroundings of an industrial area

An inter-disciplinary approach to evaluate human health risks due to long-term exposure to contaminated groundwater near a chemical complex

Evaluating the performance of polystyrene sulfonate coupling with non-ionic Triton-X114 surfactant as draw solution in forward osmosis and membrane distillation systems

Estimation of water pollution and probability of health risk due to imbalanced nutrients in River Ganga

Managing the socio-ecology of very large rivers: Collective choice rules in IWRM narratives

The Ganga River is dying under the weight of modern India

Pollution Assessment: River Ganga. Central Pollution Control Board

Restoration of polluted river stretches. Central Pollution Control Board, Government of India

CPCB, 2020. Real time water quality monitoring of river Ganga

Environmental evaluation study of ramganga major irrigation project. Central

Appraisal of water quality in the Lakes of Nainital District through numerical indices and multivariate statistics

The ganga and the GAP: An assessment of efforts to clean a sacred river

Use of water quality index and multivariate statistical techniques for the assessment of spatial variations in water quality of a small river

Self-cleansing properties of ganga during mass ritualistic bathing on Maha-Kumbh

The role of water use patterns and sewage pollution in incidence of water-borne/enteric diseases along the Ganges River in Varanasi

Assessment of water quality and suitability analysis of River Ganga in Rishikesh

River Development & Ganga Rejuvenation Report (39) of 2017 (Performance Audit), Ministry of Water Resources; Indian Audit and Account Department (IAAD), Government of India

Impact of climate change on the hydrological dynamics of River Ganga, india

Water quality assessment using overall index of pollution in riverbed-mining area of Ganga-River Haridwar

Artificial neural network simulation for prediction of suspended sediment concentration in the River Ramganga

Physical, chemical and bacteriological study of water from rivers of Uttarakhand

Activated carbon from sawdust for naphthalene removal from contaminated water

Biomonitoring of heavy metals in river ganga water, sediments, plant, and fishes of different trophic levels

Visible-light-driven N-TiO 2 @ SiO 2 @ Fe 3 O 4 magnetic nanophotocatalysts: Synthesis, characterization, and photocatalytic degradation of PPCPs

Hydrogeo-morphological influences for arsenic release and fate in the central Gangetic Basin

A novel approach for river health assessment of Chambal using fuzzy modeling

Analysis of water environment changing trend in bhagirathi tributary of Ganges in India

Long-term evaluation of water quality parameters of the Karoun River using a regression approach and the adaptive neuro-fuzzy inference system

Studies on the water quality of river Ganga at fatehgarh and kannauj, u.p. India

Assessment of river water quality for agricultural irrigation

Introducing a water quality index for assessing water for irrigation purposes: A case study of the ghezelozan river

Estimation of physicochemical characteristics and associated metal contamination risk in river Narmada

Study of simultaneous bioremediation of mixed reactive dyes and Cr(VI) containing wastewater through designed experiments

Seasonal and temporal variations in physico-chemical and bacteriological characteristics of river Ganga in Varanasi

Bacteria-mediated bio-degradation of reactive azo dyes coupled with bio-energy generation from model wastewater

Ecological health assessment of Surha Lake

Evolving human dimensions and the need for continuous health assessment of Indian rivers

Alternative alert system for ganga river eutrophication using alkaline phosphatase as a level determinant

Environmental magnetic characterization of the Alaknanda and Ramganga river sediments, Ganga basin

Heavy metal and microbial pollution of the river Ganga: A case study of water quality at Varanasi

Studies of selected water quality parameters of river Ganges at Patna

Evaluation of heavy metal contamination in soil using geochemical indexing approaches and chemometric techniques

Developments in forward osmosis and membrane distillation for desalination of waters

Spatial distribution of meso and microplastics in the sediments of river Ganga at eastern India

Changes in water quality index of Ganges river at different locations in Allahabad

Heavy metal pollution of river Ganga in Mirzapur

Spatial variations in water quality of river Ganga with respect to land uses in varanasi

Performance evaluation of conservation plan for freshwater lakes in India through a scoring methodology

Monitoring and assessment of pollution load in surface water of river Ganga around Kanpur, India: A study for suitability of this water for different uses

Assessment of spatial and temporal variations in water quality by the application of multivariate statistical methods in the Kali River

Bio-assessment of river Ujh using benthic macro-invertebrates as bioindicators

A meta-analysis of water quality and aquatic macrophyte responses in 18 lakes treated with lanthanum modified bentonite (phoslock R ⃝ )

Suggestions for a modified approach towards implementation and assessment of Ganga action plan and other similar river action plans in India

Use of principal component analysis for parameter selection for development of a novel water quality index: A case study of river Ganga India

Effective data convergence, mapping, and pollution categorization of ghats at Ganga river front in Varanasi

Update and SDG Baselines. World Health Organization (WHO) and the United Nations Children's Fund (UNICEF)

COVID-19 and surface water quality: Improved lake water quality during the lockdown

Authors are thankful to Central Water Commission and Central Pollution Control Board of Government of India, for providing the physiochemical water quality data of river Ganga to carry out this study. Authors are highly thankful to all three reviewers and editors for their constructive comments to improve the quality of the paper. All authors proofread the final version of manuscript and agreed for publication.

Supplementary material related to this article can be found online at https://doi.org/10.1016/j.eti.2020.101164.