id	author	title	date	pages	extension	mime	words	sentence	flesch	summary	cache	txt
mp48sb41q6c	Julie A. Kessler	The Exploration of Metal Ligand Cooperation and Bond Activations by Late Transition Metal Complexes Containing the PNpyrP Ligand	1904		.txt	text/plain	315	9	28	Overall, the ability of late transition metal complexes containing the (PNpyrP) ligand to undergo reversible structural changes was investigated as a means to leverage metal-ligand cooperation for the activation of small molecules and typically inert bonds. This dissertation describes the synthesis of late transition metal complexes containing a new PNP ligand comprised of a central pyrrole unit and di-iso-propylphosphine donors, bis[(dimethylamino)methyl]pyrrole, ((PNpyrP)H), 1.With this ligand, multiple transmetallation reagents including [(PNpyrP)Li]2 (7), (PNpyrP)Tl (8), and [(PNpyrP)Ag]2 (12) were synthesized in order to afford group 10 metal complexes of the form (PNpyrP)MCl (M = Ni (2), Pd (3), Pt (4)) as well as (PNpyrP)Ir(COD) (6) and (PNpyrP)Ru(PPh3)Cl (12).	cache/mp48sb41q6c.txt	txt/mp48sb41q6c.txt