id	sid	tid	token	lemma	pos
2z10wq00378	1	1	the	the	DET
2z10wq00378	1	2	enolization	enolization	NOUN
2z10wq00378	1	3	of	of	ADP
2z10wq00378	1	4	ketonic	ketonic	ADJ
2z10wq00378	1	5	substrates	substrate	NOUN
2z10wq00378	1	6	is	be	AUX
2z10wq00378	1	7	a	a	DET
2z10wq00378	1	8	cornerstone	cornerstone	NOUN
2z10wq00378	1	9	reaction	reaction	NOUN
2z10wq00378	1	10	in	in	ADP
2z10wq00378	1	11	modern	modern	ADJ
2z10wq00378	1	12	organic	organic	ADJ
2z10wq00378	1	13	synthesis	synthesis	NOUN
2z10wq00378	1	14	.	.	PUNCT
2z10wq00378	2	1	the	the	DET
2z10wq00378	2	2	research	research	NOUN
2z10wq00378	2	3	in	in	ADP
2z10wq00378	2	4	this	this	DET
2z10wq00378	2	5	dissertation	dissertation	NOUN
2z10wq00378	2	6	is	be	AUX
2z10wq00378	2	7	split	split	VERB
2z10wq00378	2	8	into	into	ADP
2z10wq00378	2	9	three	three	NUM
2z10wq00378	2	10	main	main	ADJ
2z10wq00378	2	11	sections	section	NOUN
2z10wq00378	2	12	,	,	PUNCT
2z10wq00378	2	13	with	with	ADP
2z10wq00378	2	14	the	the	DET
2z10wq00378	2	15	investigation	investigation	NOUN
2z10wq00378	2	16	of	of	ADP
2z10wq00378	2	17	s	s	NOUN
2z10wq00378	2	18	-	-	PUNCT
2z10wq00378	2	19	block	block	NOUN
2z10wq00378	2	20	metal	metal	NOUN
2z10wq00378	2	21	enolate	enolate	NOUN
2z10wq00378	2	22	chemistry	chemistry	NOUN
2z10wq00378	2	23	being	be	AUX
2z10wq00378	2	24	the	the	DET
2z10wq00378	2	25	underlying	underlying	ADJ
2z10wq00378	2	26	theme	theme	NOUN
2z10wq00378	2	27	.	.	PUNCT
2z10wq00378	3	1	the	the	DET
2z10wq00378	3	2	first	first	ADJ
2z10wq00378	3	3	section	section	NOUN
2z10wq00378	3	4	focuses	focus	VERB
2z10wq00378	3	5	on	on	ADP
2z10wq00378	3	6	the	the	DET
2z10wq00378	3	7	synthesis	synthesis	NOUN
2z10wq00378	3	8	and	and	CCONJ
2z10wq00378	3	9	characterization	characterization	NOUN
2z10wq00378	3	10	of	of	ADP
2z10wq00378	3	11	a	a	DET
2z10wq00378	3	12	series	series	NOUN
2z10wq00378	3	13	of	of	ADP
2z10wq00378	3	14	homoand	homoand	PROPN
2z10wq00378	3	15	heterobimetallic	heterobimetallic	PROPN
2z10wq00378	3	16	potassium	potassium	NOUN
2z10wq00378	3	17	and	and	CCONJ
2z10wq00378	3	18	calcium	calcium	NOUN
2z10wq00378	3	19	enolates	enolate	NOUN
2z10wq00378	3	20	.	.	PUNCT
2z10wq00378	4	1	this	this	DET
2z10wq00378	4	2	set	set	NOUN
2z10wq00378	4	3	of	of	ADP
2z10wq00378	4	4	compounds	compound	NOUN
2z10wq00378	4	5	was	be	AUX
2z10wq00378	4	6	generated	generate	VERB
2z10wq00378	4	7	from	from	ADP
2z10wq00378	4	8	the	the	DET
2z10wq00378	4	9	enolization	enolization	NOUN
2z10wq00378	4	10	of	of	ADP
2z10wq00378	4	11	2	2	NUM
2z10wq00378	4	12	'	'	NOUN
2z10wq00378	4	13	,	,	PUNCT
2z10wq00378	4	14	4	4	NUM
2z10wq00378	4	15	'	'	NOUN
2z10wq00378	4	16	,	,	PUNCT
2z10wq00378	4	17	6'-trimethylacetophenone	6'-trimethylacetophenone	NUM
2z10wq00378	4	18	using	use	VERB
2z10wq00378	4	19	potassium	potassium	NOUN
2z10wq00378	4	20	hexamethyldisilazide	hexamethyldisilazide	NOUN
2z10wq00378	4	21	(	(	PUNCT
2z10wq00378	4	22	khmds	khmds	NOUN
2z10wq00378	4	23	)	)	PUNCT
2z10wq00378	4	24	and	and	CCONJ
2z10wq00378	4	25	calcium	calcium	NOUN
2z10wq00378	4	26	bis(hexamethyldisilazide	bis(hexamethyldisilazide	ADV
2z10wq00378	4	27	)	)	PUNCT
2z10wq00378	4	28	(	(	PUNCT
2z10wq00378	4	29	ca(hmds)2	ca(hmds)2	SPACE
2z10wq00378	4	30	)	)	PUNCT
2z10wq00378	4	31	.	.	PUNCT
2z10wq00378	5	1	the	the	DET
2z10wq00378	5	2	section	section	NOUN
2z10wq00378	5	3	details	detail	VERB
2z10wq00378	5	4	the	the	DET
2z10wq00378	5	5	crystallographic	crystallographic	ADJ
2z10wq00378	5	6	characterization	characterization	NOUN
2z10wq00378	5	7	of	of	ADP
2z10wq00378	5	8	a	a	DET
2z10wq00378	5	9	tetrameric	tetrameric	NOUN
2z10wq00378	5	10	potassium	potassium	NOUN
2z10wq00378	5	11	enolate	enolate	NOUN
2z10wq00378	5	12	,	,	PUNCT
2z10wq00378	5	13	a	a	DET
2z10wq00378	5	14	dimeric	dimeric	ADJ
2z10wq00378	5	15	amidocalcium	amidocalcium	NOUN
2z10wq00378	5	16	enolate	enolate	NOUN
2z10wq00378	5	17	,	,	PUNCT
2z10wq00378	5	18	a	a	DET
2z10wq00378	5	19	mixed	mixed	ADJ
2z10wq00378	5	20	-	-	PUNCT
2z10wq00378	5	21	metal	metal	NOUN
2z10wq00378	5	22	k	k	NOUN
2z10wq00378	5	23	/	/	SYM
2z10wq00378	5	24	ca	ca	PROPN
2z10wq00378	5	25	amide	amide	PROPN
2z10wq00378	5	26	,	,	PUNCT
2z10wq00378	5	27	a	a	DET
2z10wq00378	5	28	solvent	solvent	NOUN
2z10wq00378	5	29	-	-	PUNCT
2z10wq00378	5	30	separated	separate	VERB
2z10wq00378	5	31	k	k	PROPN
2z10wq00378	5	32	/	/	SYM
2z10wq00378	5	33	ca	can	AUX
2z10wq00378	5	34	complex	complex	VERB
2z10wq00378	5	35	with	with	ADP
2z10wq00378	5	36	a	a	DET
2z10wq00378	5	37	[	[	X
2z10wq00378	5	38	ca(hmds)3]ìâåø	ca(hmds)3]ìâåø	X
2z10wq00378	5	39	anion	anion	NOUN
2z10wq00378	5	40	,	,	PUNCT
2z10wq00378	5	41	and	and	CCONJ
2z10wq00378	5	42	three	three	NUM
2z10wq00378	5	43	mixed	mixed	ADJ
2z10wq00378	5	44	-	-	PUNCT
2z10wq00378	5	45	metal	metal	NOUN
2z10wq00378	5	46	enolate	enolate	NOUN
2z10wq00378	5	47	complexes	complex	NOUN
2z10wq00378	5	48	containing	contain	VERB
2z10wq00378	5	49	1:1	1:1	NUM
2z10wq00378	5	50	,	,	PUNCT
2z10wq00378	5	51	2:1	2:1	NUM
2z10wq00378	5	52	and	and	CCONJ
2z10wq00378	5	53	2:2	2:2	NUM
2z10wq00378	5	54	stoichiometries	stoichiometry	NOUN
2z10wq00378	5	55	of	of	ADP
2z10wq00378	5	56	k	k	PROPN
2z10wq00378	5	57	and	and	CCONJ
2z10wq00378	5	58	ca	ca	PROPN
2z10wq00378	5	59	.	.	PUNCT
2z10wq00378	6	1	this	this	DET
2z10wq00378	6	2	set	set	NOUN
2z10wq00378	6	3	of	of	ADP
2z10wq00378	6	4	complexes	complex	NOUN
2z10wq00378	6	5	has	have	AUX
2z10wq00378	6	6	allowed	allow	VERB
2z10wq00378	6	7	a	a	DET
2z10wq00378	6	8	comparison	comparison	NOUN
2z10wq00378	6	9	of	of	ADP
2z10wq00378	6	10	the	the	DET
2z10wq00378	6	11	bonding	bonding	NOUN
2z10wq00378	6	12	between	between	ADP
2z10wq00378	6	13	the	the	DET
2z10wq00378	6	14	two	two	NUM
2z10wq00378	6	15	periodic	periodic	ADJ
2z10wq00378	6	16	neighbors	neighbor	NOUN
2z10wq00378	6	17	within	within	ADP
2z10wq00378	6	18	single	single	ADJ
2z10wq00378	6	19	complexes	complex	NOUN
2z10wq00378	6	20	.	.	PUNCT
2z10wq00378	7	1	the	the	DET
2z10wq00378	7	2	reactivities	reactivity	NOUN
2z10wq00378	7	3	of	of	ADP
2z10wq00378	7	4	magnesium	magnesium	NOUN
2z10wq00378	7	5	bis(hexamethyldisilazide	bis(hexamethyldisilazide	ADV
2z10wq00378	7	6	)	)	PUNCT
2z10wq00378	7	7	mg(hmds)2	mg(hmds)2	PROPN
2z10wq00378	7	8	,	,	PUNCT
2z10wq00378	7	9	khmds	khmds	PROPN
2z10wq00378	7	10	,	,	PUNCT
2z10wq00378	7	11	ca(hmds)2	ca(hmds)2	SPACE
2z10wq00378	7	12	,	,	PUNCT
2z10wq00378	7	13	several	several	ADJ
2z10wq00378	7	14	mixed	mixed	ADJ
2z10wq00378	7	15	-	-	PUNCT
2z10wq00378	7	16	metal	metal	NOUN
2z10wq00378	7	17	k	k	NOUN
2z10wq00378	7	18	/	/	SYM
2z10wq00378	7	19	ca	ca	PROPN
2z10wq00378	7	20	amide	amide	PROPN
2z10wq00378	7	21	combinations	combination	NOUN
2z10wq00378	7	22	in	in	ADP
2z10wq00378	7	23	enolization	enolization	NOUN
2z10wq00378	7	24	reactions	reaction	NOUN
2z10wq00378	7	25	are	be	AUX
2z10wq00378	7	26	reported	report	VERB
2z10wq00378	7	27	.	.	PUNCT
2z10wq00378	8	1	the	the	DET
2z10wq00378	8	2	second	second	ADJ
2z10wq00378	8	3	section	section	NOUN
2z10wq00378	8	4	concentrates	concentrate	VERB
2z10wq00378	8	5	on	on	ADP
2z10wq00378	8	6	an	an	DET
2z10wq00378	8	7	investigation	investigation	NOUN
2z10wq00378	8	8	into	into	ADP
2z10wq00378	8	9	the	the	DET
2z10wq00378	8	10	utility	utility	NOUN
2z10wq00378	8	11	of	of	ADP
2z10wq00378	8	12	ca(hmds)2	ca(hmds)2	NUM
2z10wq00378	8	13	to	to	PART
2z10wq00378	8	14	mediate	mediate	VERB
2z10wq00378	8	15	the	the	DET
2z10wq00378	8	16	enolization	enolization	NOUN
2z10wq00378	8	17	of	of	ADP
2z10wq00378	8	18	ketonic	ketonic	ADJ
2z10wq00378	8	19	substrates	substrate	NOUN
2z10wq00378	8	20	.	.	PUNCT
2z10wq00378	9	1	these	these	DET
2z10wq00378	9	2	studies	study	NOUN
2z10wq00378	9	3	demonstrate	demonstrate	VERB
2z10wq00378	9	4	that	that	SCONJ
2z10wq00378	9	5	ca(hmds)2	ca(hmds)2	NUM
2z10wq00378	9	6	clearly	clearly	ADV
2z10wq00378	9	7	deprotonates	deprotonate	VERB
2z10wq00378	9	8	a	a	DET
2z10wq00378	9	9	variety	variety	NOUN
2z10wq00378	9	10	of	of	ADP
2z10wq00378	9	11	ketones	ketone	NOUN
2z10wq00378	9	12	in	in	ADP
2z10wq00378	9	13	good	good	ADJ
2z10wq00378	9	14	to	to	ADP
2z10wq00378	9	15	quantitative	quantitative	ADJ
2z10wq00378	9	16	yields	yield	NOUN
2z10wq00378	9	17	under	under	ADP
2z10wq00378	9	18	mild	mild	ADJ
2z10wq00378	9	19	conditions	condition	NOUN
2z10wq00378	9	20	.	.	PUNCT
2z10wq00378	10	1	furthermore	furthermore	ADV
2z10wq00378	10	2	,	,	PUNCT
2z10wq00378	10	3	this	this	DET
2z10wq00378	10	4	reagent	reagent	NOUN
2z10wq00378	10	5	is	be	AUX
2z10wq00378	10	6	significantly	significantly	ADV
2z10wq00378	10	7	more	more	ADV
2z10wq00378	10	8	reactive	reactive	ADJ
2z10wq00378	10	9	than	than	ADP
2z10wq00378	10	10	its	its	PRON
2z10wq00378	10	11	magnesium	magnesium	NOUN
2z10wq00378	10	12	analogue	analogue	NOUN
2z10wq00378	10	13	,	,	PUNCT
2z10wq00378	10	14	which	which	PRON
2z10wq00378	10	15	is	be	AUX
2z10wq00378	10	16	a	a	DET
2z10wq00378	10	17	practical	practical	ADJ
2z10wq00378	10	18	advantage	advantage	NOUN
2z10wq00378	10	19	.	.	PUNCT
2z10wq00378	11	1	the	the	DET
2z10wq00378	11	2	regioselectivity	regioselectivity	NOUN
2z10wq00378	11	3	of	of	ADP
2z10wq00378	11	4	this	this	DET
2z10wq00378	11	5	calcium	calcium	NOUN
2z10wq00378	11	6	bisamide	bisamide	NOUN
2z10wq00378	11	7	has	have	AUX
2z10wq00378	11	8	been	be	AUX
2z10wq00378	11	9	tested	test	VERB
2z10wq00378	11	10	by	by	ADP
2z10wq00378	11	11	reaction	reaction	NOUN
2z10wq00378	11	12	with	with	ADP
2z10wq00378	11	13	a	a	DET
2z10wq00378	11	14	series	series	NOUN
2z10wq00378	11	15	of	of	ADP
2z10wq00378	11	16	unsymmetrical	unsymmetrical	ADJ
2z10wq00378	11	17	ketones	ketone	NOUN
2z10wq00378	11	18	.	.	PUNCT
2z10wq00378	12	1	these	these	DET
2z10wq00378	12	2	studies	study	NOUN
2z10wq00378	12	3	show	show	VERB
2z10wq00378	12	4	that	that	SCONJ
2z10wq00378	12	5	ca(hmds)2	ca(hmds)2	NUM
2z10wq00378	12	6	is	be	AUX
2z10wq00378	12	7	a	a	DET
2z10wq00378	12	8	highly	highly	ADV
2z10wq00378	12	9	kinetically	kinetically	ADV
2z10wq00378	12	10	selective	selective	ADJ
2z10wq00378	12	11	base	base	NOUN
2z10wq00378	12	12	.	.	PUNCT
2z10wq00378	13	1	the	the	DET
2z10wq00378	13	2	stereoselectivity	stereoselectivity	NOUN
2z10wq00378	13	3	of	of	ADP
2z10wq00378	13	4	the	the	DET
2z10wq00378	13	5	base	base	NOUN
2z10wq00378	13	6	was	be	AUX
2z10wq00378	13	7	also	also	ADV
2z10wq00378	13	8	investigated	investigate	VERB
2z10wq00378	13	9	and	and	CCONJ
2z10wq00378	13	10	found	find	VERB
2z10wq00378	13	11	to	to	PART
2z10wq00378	13	12	be	be	AUX
2z10wq00378	13	13	strongly	strongly	ADV
2z10wq00378	13	14	solvent	solvent	ADJ
2z10wq00378	13	15	-	-	PUNCT
2z10wq00378	13	16	dependent	dependent	ADJ
2z10wq00378	13	17	.	.	PUNCT
2z10wq00378	14	1	e	e	X
2z10wq00378	14	2	-	-	NOUN
2z10wq00378	14	3	enolates	enolate	NOUN
2z10wq00378	14	4	are	be	AUX
2z10wq00378	14	5	the	the	DET
2z10wq00378	14	6	major	major	ADJ
2z10wq00378	14	7	products	product	NOUN
2z10wq00378	14	8	in	in	ADP
2z10wq00378	14	9	weakly	weakly	ADJ
2z10wq00378	14	10	polar	polar	ADJ
2z10wq00378	14	11	solvents	solvent	NOUN
2z10wq00378	14	12	like	like	ADP
2z10wq00378	14	13	toluene	toluene	NOUN
2z10wq00378	14	14	,	,	PUNCT
2z10wq00378	14	15	while	while	SCONJ
2z10wq00378	14	16	z	z	PROPN
2z10wq00378	14	17	-	-	NOUN
2z10wq00378	14	18	enolates	enolate	NOUN
2z10wq00378	14	19	are	be	AUX
2z10wq00378	14	20	the	the	DET
2z10wq00378	14	21	major	major	ADJ
2z10wq00378	14	22	products	product	NOUN
2z10wq00378	14	23	in	in	ADP
2z10wq00378	14	24	donor	donor	NOUN
2z10wq00378	14	25	solvents	solvent	NOUN
2z10wq00378	14	26	such	such	ADJ
2z10wq00378	14	27	as	as	ADP
2z10wq00378	14	28	thf	thf	NOUN
2z10wq00378	14	29	or	or	CCONJ
2z10wq00378	14	30	pyridine	pyridine	NOUN
2z10wq00378	14	31	.	.	PUNCT
2z10wq00378	15	1	a	a	DET
2z10wq00378	15	2	group	group	NOUN
2z10wq00378	15	3	of	of	ADP
2z10wq00378	15	4	amidocalcium	amidocalcium	NOUN
2z10wq00378	15	5	enolates	enolate	NOUN
2z10wq00378	15	6	derived	derive	VERB
2z10wq00378	15	7	from	from	ADP
2z10wq00378	15	8	a	a	DET
2z10wq00378	15	9	subset	subset	NOUN
2z10wq00378	15	10	of	of	ADP
2z10wq00378	15	11	the	the	DET
2z10wq00378	15	12	ketones	ketone	NOUN
2z10wq00378	15	13	used	use	VERB
2z10wq00378	15	14	in	in	ADP
2z10wq00378	15	15	the	the	DET
2z10wq00378	15	16	selectivity	selectivity	ADJ
2z10wq00378	15	17	studies	study	NOUN
2z10wq00378	15	18	were	be	AUX
2z10wq00378	15	19	isolated	isolate	VERB
2z10wq00378	15	20	from	from	ADP
2z10wq00378	15	21	various	various	ADJ
2z10wq00378	15	22	solvent	solvent	NOUN
2z10wq00378	15	23	mixtures	mixture	NOUN
2z10wq00378	15	24	,	,	PUNCT
2z10wq00378	15	25	and	and	CCONJ
2z10wq00378	15	26	characterized	characterize	VERB
2z10wq00378	15	27	in	in	ADP
2z10wq00378	15	28	the	the	DET
2z10wq00378	15	29	solid	solid	ADJ
2z10wq00378	15	30	state	state	NOUN
2z10wq00378	15	31	.	.	PUNCT
2z10wq00378	16	1	crystallographic	crystallographic	ADJ
2z10wq00378	16	2	analyses	analysis	NOUN
2z10wq00378	16	3	revealed	reveal	VERB
2z10wq00378	16	4	the	the	DET
2z10wq00378	16	5	formation	formation	NOUN
2z10wq00378	16	6	for	for	ADP
2z10wq00378	16	7	monomers	monomer	NOUN
2z10wq00378	16	8	,	,	PUNCT
2z10wq00378	16	9	dimers	dimer	NOUN
2z10wq00378	16	10	,	,	PUNCT
2z10wq00378	16	11	and	and	CCONJ
2z10wq00378	16	12	charge	charge	NOUN
2z10wq00378	16	13	-	-	PUNCT
2z10wq00378	16	14	separated	separate	VERB
2z10wq00378	16	15	complexes	complex	NOUN
2z10wq00378	16	16	.	.	PUNCT
2z10wq00378	17	1	nmr	nmr	NOUN
2z10wq00378	17	2	spectroscopic	spectroscopic	ADJ
2z10wq00378	17	3	studies	study	NOUN
2z10wq00378	17	4	in	in	ADP
2z10wq00378	17	5	pyridine	pyridine	NOUN
2z10wq00378	17	6	solution	solution	NOUN
2z10wq00378	17	7	indicate	indicate	VERB
2z10wq00378	17	8	the	the	DET
2z10wq00378	17	9	establishment	establishment	NOUN
2z10wq00378	17	10	of	of	ADP
2z10wq00378	17	11	complex	complex	ADJ
2z10wq00378	17	12	equilibria	equilibria	NOUN
2z10wq00378	17	13	between	between	ADP
2z10wq00378	17	14	amidocalcium	amidocalcium	NOUN
2z10wq00378	17	15	enolate	enolate	NOUN
2z10wq00378	17	16	,	,	PUNCT
2z10wq00378	17	17	charge	charge	NOUN
2z10wq00378	17	18	-	-	PUNCT
2z10wq00378	17	19	separated	separate	VERB
2z10wq00378	17	20	species	specie	NOUN
2z10wq00378	17	21	,	,	PUNCT
2z10wq00378	17	22	bisenolate	bisenolate	PROPN
2z10wq00378	17	23	and	and	CCONJ
2z10wq00378	17	24	bisamide	bisamide	NOUN
2z10wq00378	17	25	.	.	PUNCT
2z10wq00378	18	1	the	the	DET
2z10wq00378	18	2	final	final	ADJ
2z10wq00378	18	3	section	section	NOUN
2z10wq00378	18	4	outlines	outline	VERB
2z10wq00378	18	5	a	a	DET
2z10wq00378	18	6	detailed	detailed	ADJ
2z10wq00378	18	7	mechanistic	mechanistic	ADJ
2z10wq00378	18	8	study	study	NOUN
2z10wq00378	18	9	for	for	ADP
2z10wq00378	18	10	the	the	DET
2z10wq00378	18	11	enolization	enolization	NOUN
2z10wq00378	18	12	of	of	ADP
2z10wq00378	18	13	propiophenone	propiophenone	NOUN
2z10wq00378	18	14	mediated	mediate	VERB
2z10wq00378	18	15	by	by	ADP
2z10wq00378	18	16	mg(hmds)2	mg(hmds)2	NUM
2z10wq00378	18	17	in	in	ADP
2z10wq00378	18	18	toluene	toluene	NOUN
2z10wq00378	18	19	.	.	PUNCT
2z10wq00378	19	1	a	a	DET
2z10wq00378	19	2	combination	combination	NOUN
2z10wq00378	19	3	of	of	ADP
2z10wq00378	19	4	nmr	nmr	NOUN
2z10wq00378	19	5	spectroscopy	spectroscopy	NOUN
2z10wq00378	19	6	,	,	PUNCT
2z10wq00378	19	7	kinetic	kinetic	ADJ
2z10wq00378	19	8	studies	study	NOUN
2z10wq00378	19	9	,	,	PUNCT
2z10wq00378	19	10	crystallographic	crystallographic	ADJ
2z10wq00378	19	11	analyses	analysis	NOUN
2z10wq00378	19	12	and	and	CCONJ
2z10wq00378	19	13	theoretical	theoretical	ADJ
2z10wq00378	19	14	investigations	investigation	NOUN
2z10wq00378	19	15	has	have	AUX
2z10wq00378	19	16	been	be	AUX
2z10wq00378	19	17	used	use	VERB
2z10wq00378	19	18	to	to	PART
2z10wq00378	19	19	elucidate	elucidate	VERB
2z10wq00378	19	20	the	the	DET
2z10wq00378	19	21	mechanism	mechanism	NOUN
2z10wq00378	19	22	for	for	ADP
2z10wq00378	19	23	ketone	ketone	NOUN
2z10wq00378	19	24	enolization	enolization	NOUN
2z10wq00378	19	25	.	.	PUNCT
2z10wq00378	20	1	this	this	DET
2z10wq00378	20	2	investigation	investigation	NOUN
2z10wq00378	20	3	indicates	indicate	VERB
2z10wq00378	20	4	that	that	SCONJ
2z10wq00378	20	5	a	a	DET
2z10wq00378	20	6	key	key	ADJ
2z10wq00378	20	7	intermediate	intermediate	NOUN
2z10wq00378	20	8	prior	prior	ADV
2z10wq00378	20	9	to	to	ADP
2z10wq00378	20	10	the	the	DET
2z10wq00378	20	11	enolization	enolization	NOUN
2z10wq00378	20	12	is	be	AUX
2z10wq00378	20	13	a	a	DET
2z10wq00378	20	14	three	three	NUM
2z10wq00378	20	15	-	-	PUNCT
2z10wq00378	20	16	coordinated	coordinate	VERB
2z10wq00378	20	17	precomplex	precomplex	NOUN
2z10wq00378	20	18	formed	form	VERB
2z10wq00378	20	19	between	between	ADP
2z10wq00378	20	20	the	the	DET
2z10wq00378	20	21	amide	amide	NOUN
2z10wq00378	20	22	and	and	CCONJ
2z10wq00378	20	23	the	the	DET
2z10wq00378	20	24	ketone	ketone	NOUN
2z10wq00378	20	25	.	.	PUNCT
2z10wq00378	21	1	a	a	DET
2z10wq00378	21	2	large	large	ADJ
2z10wq00378	21	3	primary	primary	ADJ
2z10wq00378	21	4	isotope	isotope	NOUN
2z10wq00378	21	5	effect	effect	NOUN
2z10wq00378	21	6	indicates	indicate	VERB
2z10wq00378	21	7	that	that	SCONJ
2z10wq00378	21	8	deprotonation	deprotonation	NOUN
2z10wq00378	21	9	is	be	AUX
2z10wq00378	21	10	the	the	DET
2z10wq00378	21	11	rate	rate	NOUN
2z10wq00378	21	12	-	-	PUNCT
2z10wq00378	21	13	determining	determine	VERB
2z10wq00378	21	14	step	step	NOUN
2z10wq00378	21	15	,	,	PUNCT
2z10wq00378	21	16	and	and	CCONJ
2z10wq00378	21	17	that	that	SCONJ
2z10wq00378	21	18	a	a	DET
2z10wq00378	21	19	tunneling	tunneling	NOUN
2z10wq00378	21	20	effect	effect	NOUN
2z10wq00378	21	21	may	may	AUX
2z10wq00378	21	22	be	be	AUX
2z10wq00378	21	23	in	in	ADP
2z10wq00378	21	24	operation	operation	NOUN
2z10wq00378	21	25	.	.	PUNCT
2z10wq00378	22	1	from	from	ADP
2z10wq00378	22	2	these	these	DET
2z10wq00378	22	3	data	datum	NOUN
2z10wq00378	22	4	,	,	PUNCT
2z10wq00378	22	5	a	a	DET
2z10wq00378	22	6	six	six	NUM
2z10wq00378	22	7	-	-	PUNCT
2z10wq00378	22	8	membered	membered	ADJ
2z10wq00378	22	9	transition	transition	NOUN
2z10wq00378	22	10	state	state	NOUN
2z10wq00378	22	11	has	have	AUX
2z10wq00378	22	12	been	be	AUX
2z10wq00378	22	13	proposed	propose	VERB
2z10wq00378	22	14	that	that	SCONJ
2z10wq00378	22	15	aids	aid	VERB
2z10wq00378	22	16	in	in	ADP
2z10wq00378	22	17	rationalizing	rationalize	VERB
2z10wq00378	22	18	the	the	DET
2z10wq00378	22	19	observed	observed	ADJ
2z10wq00378	22	20	selectivity	selectivity	NOUN
2z10wq00378	22	21	of	of	ADP
2z10wq00378	22	22	the	the	DET
2z10wq00378	22	23	enolization	enolization	NOUN
2z10wq00378	22	24	.	.	PUNCT