id	sid	tid	token	lemma	pos
5t34sj15655	1	1	the	the	DET
5t34sj15655	1	2	focus	focus	NOUN
5t34sj15655	1	3	for	for	ADP
5t34sj15655	1	4	this	this	DET
5t34sj15655	1	5	dissertation	dissertation	NOUN
5t34sj15655	1	6	involved	involve	VERB
5t34sj15655	1	7	the	the	DET
5t34sj15655	1	8	development	development	NOUN
5t34sj15655	1	9	of	of	ADP
5t34sj15655	1	10	new	new	ADJ
5t34sj15655	1	11	synthetic	synthetic	ADJ
5t34sj15655	1	12	applications	application	NOUN
5t34sj15655	1	13	of	of	ADP
5t34sj15655	1	14	nitroso	nitroso	NOUN
5t34sj15655	1	15	diels	diel	NOUN
5t34sj15655	1	16	-	-	PUNCT
5t34sj15655	1	17	alder	alder	NOUN
5t34sj15655	1	18	(	(	PUNCT
5t34sj15655	1	19	nda	nda	PROPN
5t34sj15655	1	20	)	)	PUNCT
5t34sj15655	1	21	reactions	reaction	NOUN
5t34sj15655	1	22	and	and	CCONJ
5t34sj15655	1	23	nitroso	nitroso	NOUN
5t34sj15655	1	24	ene	ene	NOUN
5t34sj15655	1	25	reactions	reaction	NOUN
5t34sj15655	1	26	.	.	PUNCT
5t34sj15655	2	1	three	three	NUM
5t34sj15655	2	2	projects	project	NOUN
5t34sj15655	2	3	have	have	AUX
5t34sj15655	2	4	evolved	evolve	VERB
5t34sj15655	2	5	from	from	ADP
5t34sj15655	2	6	this	this	DET
5t34sj15655	2	7	main	main	ADJ
5t34sj15655	2	8	research	research	NOUN
5t34sj15655	2	9	theme	theme	NOUN
5t34sj15655	2	10	.	.	PUNCT
5t34sj15655	3	1	in	in	ADP
5t34sj15655	3	2	chapter	chapter	NOUN
5t34sj15655	3	3	3	3	NUM
5t34sj15655	3	4	,	,	PUNCT
5t34sj15655	3	5	the	the	DET
5t34sj15655	3	6	stabilized	stabilize	VERB
5t34sj15655	3	7	iminonitroso	iminonitroso	NOUN
5t34sj15655	3	8	diels	diel	NOUN
5t34sj15655	3	9	-	-	PUNCT
5t34sj15655	3	10	alder	alder	NOUN
5t34sj15655	3	11	reaction	reaction	NOUN
5t34sj15655	3	12	,	,	PUNCT
5t34sj15655	3	13	particularly	particularly	ADV
5t34sj15655	3	14	the	the	DET
5t34sj15655	3	15	pyridinylnitroso	pyridinylnitroso	ADJ
5t34sj15655	3	16	diels	diel	NOUN
5t34sj15655	3	17	-	-	PUNCT
5t34sj15655	3	18	alder	alder	NOUN
5t34sj15655	3	19	reaction	reaction	NOUN
5t34sj15655	3	20	,	,	PUNCT
5t34sj15655	3	21	is	be	AUX
5t34sj15655	3	22	demonstrated	demonstrate	VERB
5t34sj15655	3	23	to	to	PART
5t34sj15655	3	24	be	be	AUX
5t34sj15655	3	25	a	a	DET
5t34sj15655	3	26	remarkably	remarkably	ADV
5t34sj15655	3	27	efficient	efficient	ADJ
5t34sj15655	3	28	method	method	NOUN
5t34sj15655	3	29	for	for	ADP
5t34sj15655	3	30	derivatization	derivatization	NOUN
5t34sj15655	3	31	and	and	CCONJ
5t34sj15655	3	32	functionalization	functionalization	NOUN
5t34sj15655	3	33	of	of	ADP
5t34sj15655	3	34	diene	diene	NOUN
5t34sj15655	3	35	-	-	PUNCT
5t34sj15655	3	36	containing	contain	VERB
5t34sj15655	3	37	natural	natural	ADJ
5t34sj15655	3	38	products	product	NOUN
5t34sj15655	3	39	.	.	PUNCT
5t34sj15655	4	1	three	three	NUM
5t34sj15655	4	2	structurally	structurally	ADV
5t34sj15655	4	3	and	and	CCONJ
5t34sj15655	4	4	biologically	biologically	ADV
5t34sj15655	4	5	unique	unique	ADJ
5t34sj15655	4	6	diene	diene	NOUN
5t34sj15655	4	7	-	-	PUNCT
5t34sj15655	4	8	containing	contain	VERB
5t34sj15655	4	9	natural	natural	ADJ
5t34sj15655	4	10	products	product	NOUN
5t34sj15655	4	11	,	,	PUNCT
5t34sj15655	4	12	including	include	VERB
5t34sj15655	4	13	ergosterol	ergosterol	NOUN
5t34sj15655	4	14	,	,	PUNCT
5t34sj15655	4	15	leucomycin	leucomycin	PROPN
5t34sj15655	4	16	a7	a7	PROPN
5t34sj15655	4	17	,	,	PUNCT
5t34sj15655	4	18	and	and	CCONJ
5t34sj15655	4	19	colchicine	colchicine	NOUN
5t34sj15655	4	20	were	be	AUX
5t34sj15655	4	21	found	find	VERB
5t34sj15655	4	22	to	to	PART
5t34sj15655	4	23	react	react	VERB
5t34sj15655	4	24	with	with	ADP
5t34sj15655	4	25	pyridinylnitroso	pyridinylnitroso	ADJ
5t34sj15655	4	26	agents	agent	NOUN
5t34sj15655	4	27	in	in	ADP
5t34sj15655	4	28	a	a	DET
5t34sj15655	4	29	highly	highly	ADV
5t34sj15655	4	30	efficient	efficient	ADJ
5t34sj15655	4	31	,	,	PUNCT
5t34sj15655	4	32	and	and	CCONJ
5t34sj15655	4	33	regioand	regioand	PROPN
5t34sj15655	4	34	stereo	stereo	ADJ
5t34sj15655	4	35	-	-	PUNCT
5t34sj15655	4	36	selective	selective	ADJ
5t34sj15655	4	37	fashion	fashion	NOUN
5t34sj15655	4	38	.	.	PUNCT
5t34sj15655	5	1	further	further	ADJ
5t34sj15655	5	2	chemical	chemical	NOUN
5t34sj15655	5	3	derivatizations	derivatization	NOUN
5t34sj15655	5	4	of	of	ADP
5t34sj15655	5	5	the	the	DET
5t34sj15655	5	6	nitroso	nitroso	NOUN
5t34sj15655	5	7	cycloadducts	cycloadduct	NOUN
5t34sj15655	5	8	were	be	AUX
5t34sj15655	5	9	investigated	investigate	VERB
5t34sj15655	5	10	.	.	PUNCT
5t34sj15655	6	1	broad	broad	ADJ
5t34sj15655	6	2	biological	biological	ADJ
5t34sj15655	6	3	evaluations	evaluation	NOUN
5t34sj15655	6	4	of	of	ADP
5t34sj15655	6	5	novel	novel	ADJ
5t34sj15655	6	6	analogs	analog	NOUN
5t34sj15655	6	7	were	be	AUX
5t34sj15655	6	8	also	also	ADV
5t34sj15655	6	9	performed	perform	VERB
5t34sj15655	6	10	,	,	PUNCT
5t34sj15655	6	11	suggesting	suggest	VERB
5t34sj15655	6	12	that	that	SCONJ
5t34sj15655	6	13	the	the	DET
5t34sj15655	6	14	nitroso	nitroso	NOUN
5t34sj15655	6	15	heterocycles	heterocycle	NOUN
5t34sj15655	6	16	changed	change	VERB
5t34sj15655	6	17	the	the	DET
5t34sj15655	6	18	biological	biological	ADJ
5t34sj15655	6	19	activity	activity	NOUN
5t34sj15655	6	20	profile	profile	NOUN
5t34sj15655	6	21	of	of	ADP
5t34sj15655	6	22	the	the	DET
5t34sj15655	6	23	parent	parent	NOUN
5t34sj15655	6	24	natural	natural	ADJ
5t34sj15655	6	25	products	product	NOUN
5t34sj15655	6	26	.	.	PUNCT
5t34sj15655	7	1	the	the	DET
5t34sj15655	7	2	syntheses	synthesis	NOUN
5t34sj15655	7	3	of	of	ADP
5t34sj15655	7	4	streptazolin	streptazolin	PROPN
5t34sj15655	7	5	analogs	analogs	PROPN
5t34sj15655	7	6	as	as	ADP
5t34sj15655	7	7	lipophilic	lipophilic	ADJ
5t34sj15655	7	8	antibiotics	antibiotic	NOUN
5t34sj15655	7	9	,	,	PUNCT
5t34sj15655	7	10	were	be	AUX
5t34sj15655	7	11	also	also	ADV
5t34sj15655	7	12	attempted	attempt	VERB
5t34sj15655	7	13	.	.	PUNCT
5t34sj15655	8	1	in	in	ADP
5t34sj15655	8	2	chapter	chapter	NOUN
5t34sj15655	8	3	4	4	NUM
5t34sj15655	8	4	,	,	PUNCT
5t34sj15655	8	5	lewis	lewis	PROPN
5t34sj15655	8	6	acid	acid	NOUN
5t34sj15655	8	7	-	-	PUNCT
5t34sj15655	8	8	mediated	mediate	VERB
5t34sj15655	8	9	ring	ring	NOUN
5t34sj15655	8	10	-	-	PUNCT
5t34sj15655	8	11	opening	open	VERB
5t34sj15655	8	12	reactions	reaction	NOUN
5t34sj15655	8	13	of	of	ADP
5t34sj15655	8	14	nitroso	nitroso	NOUN
5t34sj15655	8	15	cycloadducts	cycloadduct	NOUN
5t34sj15655	8	16	are	be	AUX
5t34sj15655	8	17	described	describe	VERB
5t34sj15655	8	18	.	.	PUNCT
5t34sj15655	9	1	indium	indium	NOUN
5t34sj15655	9	2	triflate	triflate	VERB
5t34sj15655	9	3	was	be	AUX
5t34sj15655	9	4	demonstrated	demonstrate	VERB
5t34sj15655	9	5	to	to	PART
5t34sj15655	9	6	be	be	AUX
5t34sj15655	9	7	an	an	DET
5t34sj15655	9	8	efficient	efficient	ADJ
5t34sj15655	9	9	lewis	lewis	PROPN
5t34sj15655	9	10	acid	acid	NOUN
5t34sj15655	9	11	in	in	ADP
5t34sj15655	9	12	promoting	promote	VERB
5t34sj15655	9	13	ring	ring	NOUN
5t34sj15655	9	14	-	-	PUNCT
5t34sj15655	9	15	opening	open	VERB
5t34sj15655	9	16	reactions	reaction	NOUN
5t34sj15655	9	17	of	of	ADP
5t34sj15655	9	18	various	various	ADJ
5t34sj15655	9	19	nitroso	nitroso	NOUN
5t34sj15655	9	20	cycloadducts	cycloadduct	NOUN
5t34sj15655	9	21	.	.	PUNCT
5t34sj15655	10	1	hydroxylamine	hydroxylamine	NOUN
5t34sj15655	10	2	containing	contain	VERB
5t34sj15655	10	3	cycloalkenes	cycloalkene	NOUN
5t34sj15655	10	4	were	be	AUX
5t34sj15655	10	5	selectively	selectively	ADV
5t34sj15655	10	6	generated	generate	VERB
5t34sj15655	10	7	through	through	ADP
5t34sj15655	10	8	the	the	DET
5t34sj15655	10	9	c	c	NOUN
5t34sj15655	10	10	-	-	PUNCT
5t34sj15655	10	11	o	o	NOUN
5t34sj15655	10	12	bond	bond	NOUN
5t34sj15655	10	13	cleavage	cleavage	NOUN
5t34sj15655	10	14	when	when	SCONJ
5t34sj15655	10	15	iminonitroso	iminonitroso	NOUN
5t34sj15655	10	16	or	or	CCONJ
5t34sj15655	10	17	acylnitroso	acylnitroso	NOUN
5t34sj15655	10	18	cycloadducts	cycloadduct	NOUN
5t34sj15655	10	19	were	be	AUX
5t34sj15655	10	20	treated	treat	VERB
5t34sj15655	10	21	with	with	ADP
5t34sj15655	10	22	indium	indium	NOUN
5t34sj15655	10	23	triflate	triflate	VERB
5t34sj15655	10	24	in	in	ADP
5t34sj15655	10	25	the	the	DET
5t34sj15655	10	26	presence	presence	NOUN
5t34sj15655	10	27	of	of	ADP
5t34sj15655	10	28	alcohols	alcohol	NOUN
5t34sj15655	10	29	.	.	PUNCT
5t34sj15655	11	1	in	in	ADP
5t34sj15655	11	2	direct	direct	ADJ
5t34sj15655	11	3	contrast	contrast	NOUN
5t34sj15655	11	4	,	,	PUNCT
5t34sj15655	11	5	indium	indium	NOUN
5t34sj15655	11	6	triflate	triflate	VERB
5t34sj15655	11	7	-	-	PUNCT
5t34sj15655	11	8	mediated	mediate	VERB
5t34sj15655	11	9	ring	ring	NOUN
5t34sj15655	11	10	-	-	PUNCT
5t34sj15655	11	11	opening	open	VERB
5t34sj15655	11	12	reactions	reaction	NOUN
5t34sj15655	11	13	of	of	ADP
5t34sj15655	11	14	nitrosobenzene	nitrosobenzene	NOUN
5t34sj15655	11	15	-	-	PUNCT
5t34sj15655	11	16	derived	derive	VERB
5t34sj15655	11	17	cycloadducts	cycloadduct	NOUN
5t34sj15655	11	18	gave	give	VERB
5t34sj15655	11	19	exclusive	exclusive	ADJ
5t34sj15655	11	20	aromatic	aromatic	ADJ
5t34sj15655	11	21	alkoxylated	alkoxylate	VERB
5t34sj15655	11	22	syn-1,4	syn-1,4	ADJ
5t34sj15655	11	23	aminocycloalkenol	aminocycloalkenol	NOUN
5t34sj15655	11	24	products	product	NOUN
5t34sj15655	11	25	through	through	ADP
5t34sj15655	11	26	a	a	DET
5t34sj15655	11	27	nucleophilic	nucleophilic	ADJ
5t34sj15655	11	28	aromatic	aromatic	ADJ
5t34sj15655	11	29	substitution	substitution	NOUN
5t34sj15655	11	30	pathway	pathway	NOUN
5t34sj15655	11	31	.	.	PUNCT
5t34sj15655	12	1	in	in	ADP
5t34sj15655	12	2	chapter	chapter	NOUN
5t34sj15655	12	3	5	5	NUM
5t34sj15655	12	4	,	,	PUNCT
5t34sj15655	12	5	an	an	DET
5t34sj15655	12	6	unprecedented	unprecedented	ADJ
5t34sj15655	12	7	ene	ene	NOUN
5t34sj15655	12	8	reaction	reaction	NOUN
5t34sj15655	12	9	using	use	VERB
5t34sj15655	12	10	iminonitroso	iminonitroso	NOUN
5t34sj15655	12	11	agents	agent	NOUN
5t34sj15655	12	12	is	be	AUX
5t34sj15655	12	13	presented	present	VERB
5t34sj15655	12	14	.	.	PUNCT
5t34sj15655	13	1	the	the	DET
5t34sj15655	13	2	allyl	allyl	NOUN
5t34sj15655	13	3	hydroxylamine	hydroxylamine	PROPN
5t34sj15655	13	4	ene	ene	PROPN
5t34sj15655	13	5	products	product	NOUN
5t34sj15655	13	6	were	be	AUX
5t34sj15655	13	7	obtained	obtain	VERB
5t34sj15655	13	8	in	in	ADP
5t34sj15655	13	9	various	various	ADJ
5t34sj15655	13	10	yields	yield	NOUN
5t34sj15655	13	11	and	and	CCONJ
5t34sj15655	13	12	with	with	ADP
5t34sj15655	13	13	high	high	ADJ
5t34sj15655	13	14	regioselectivity	regioselectivity	NOUN
5t34sj15655	13	15	.	.	PUNCT
5t34sj15655	14	1	a	a	DET
5t34sj15655	14	2	solid	solid	ADJ
5t34sj15655	14	3	phase	phase	NOUN
5t34sj15655	14	4	supported	support	VERB
5t34sj15655	14	5	iminonitroso	iminonitroso	NOUN
5t34sj15655	14	6	ene	ene	PROPN
5t34sj15655	14	7	reaction	reaction	NOUN
5t34sj15655	14	8	as	as	ADV
5t34sj15655	14	9	well	well	ADV
5t34sj15655	14	10	as	as	ADP
5t34sj15655	14	11	asymmetric	asymmetric	ADJ
5t34sj15655	14	12	nitroso	nitroso	NOUN
5t34sj15655	14	13	ene	ene	NOUN
5t34sj15655	14	14	reactions	reaction	NOUN
5t34sj15655	14	15	were	be	AUX
5t34sj15655	14	16	also	also	ADV
5t34sj15655	14	17	investigated	investigate	VERB
5t34sj15655	14	18	.	.	PUNCT
5t34sj15655	15	1	three	three	NUM
5t34sj15655	15	2	amino	amino	NOUN
5t34sj15655	15	3	acid	acid	NOUN
5t34sj15655	15	4	-	-	PUNCT
5t34sj15655	15	5	derived	derive	VERB
5t34sj15655	15	6	hydroxamic	hydroxamic	ADJ
5t34sj15655	15	7	acids	acid	NOUN
5t34sj15655	15	8	were	be	AUX
5t34sj15655	15	9	synthesized	synthesize	VERB
5t34sj15655	15	10	,	,	PUNCT
5t34sj15655	15	11	and	and	CCONJ
5t34sj15655	15	12	their	their	PRON
5t34sj15655	15	13	use	use	NOUN
5t34sj15655	15	14	in	in	ADP
5t34sj15655	15	15	diastereoselective	diastereoselective	ADJ
5t34sj15655	15	16	acylnitroso	acylnitroso	NOUN
5t34sj15655	15	17	ene	ene	NOUN
5t34sj15655	15	18	reactions	reaction	NOUN
5t34sj15655	15	19	was	be	AUX
5t34sj15655	15	20	also	also	ADV
5t34sj15655	15	21	investigated	investigate	VERB
5t34sj15655	15	22	.	.	PUNCT
5t34sj15655	16	1	in	in	ADP
5t34sj15655	16	2	chapter	chapter	NOUN
5t34sj15655	16	3	6	6	NUM
5t34sj15655	16	4	,	,	PUNCT
5t34sj15655	16	5	2-(n	2-(n	NUM
5t34sj15655	16	6	-	-	ADJ
5t34sj15655	16	7	hydroxy	hydroxy	PROPN
5t34sj15655	16	8	amino)-pyridine	amino)-pyridine	PROPN
5t34sj15655	16	9	containing	contain	VERB
5t34sj15655	16	10	compounds	compound	NOUN
5t34sj15655	16	11	,	,	PUNCT
5t34sj15655	16	12	obtained	obtain	VERB
5t34sj15655	16	13	from	from	ADP
5t34sj15655	16	14	nucleophilic	nucleophilic	ADJ
5t34sj15655	16	15	ring	ring	NOUN
5t34sj15655	16	16	-	-	PUNCT
5t34sj15655	16	17	opening	open	VERB
5t34sj15655	16	18	reactions	reaction	NOUN
5t34sj15655	16	19	of	of	ADP
5t34sj15655	16	20	nitroso	nitroso	NOUN
5t34sj15655	16	21	cycloadducts	cycloadduct	NOUN
5t34sj15655	16	22	as	as	ADV
5t34sj15655	16	23	well	well	ADV
5t34sj15655	16	24	as	as	ADP
5t34sj15655	16	25	iminonitroso	iminonitroso	NOUN
5t34sj15655	16	26	ene	ene	NOUN
5t34sj15655	16	27	reactions	reaction	NOUN
5t34sj15655	16	28	,	,	PUNCT
5t34sj15655	16	29	are	be	AUX
5t34sj15655	16	30	shown	show	VERB
5t34sj15655	16	31	to	to	PART
5t34sj15655	16	32	be	be	AUX
5t34sj15655	16	33	a	a	DET
5t34sj15655	16	34	novel	novel	ADJ
5t34sj15655	16	35	chemical	chemical	NOUN
5t34sj15655	16	36	scaffold	scaffold	NOUN
5t34sj15655	16	37	,	,	PUNCT
5t34sj15655	16	38	selectively	selectively	ADV
5t34sj15655	16	39	active	active	ADJ
5t34sj15655	16	40	against	against	ADP
5t34sj15655	16	41	gram	gram	ADJ
5t34sj15655	16	42	-	-	PUNCT
5t34sj15655	16	43	positive	positive	ADJ
5t34sj15655	16	44	micrococcus	micrococcus	PROPN
5t34sj15655	16	45	luteus	luteus	NOUN
5t34sj15655	16	46	.	.	PUNCT
5t34sj15655	17	1	preliminary	preliminary	ADJ
5t34sj15655	17	2	structure	structure	NOUN
5t34sj15655	17	3	-	-	PUNCT
5t34sj15655	17	4	activity	activity	NOUN
5t34sj15655	17	5	relationship	relationship	NOUN
5t34sj15655	17	6	studies	study	NOUN
5t34sj15655	17	7	were	be	AUX
5t34sj15655	17	8	also	also	ADV
5t34sj15655	17	9	conducted	conduct	VERB
5t34sj15655	17	10	.	.	PUNCT
5t34sj15655	18	1	several	several	ADJ
5t34sj15655	18	2	lead	lead	NOUN
5t34sj15655	18	3	compounds	compound	NOUN
5t34sj15655	18	4	with	with	ADP
5t34sj15655	18	5	low	low	ADJ
5t34sj15655	18	6	micromolar	micromolar	ADJ
5t34sj15655	18	7	levels	level	NOUN
5t34sj15655	18	8	of	of	ADP
5t34sj15655	18	9	activity	activity	NOUN
5t34sj15655	18	10	were	be	AUX
5t34sj15655	18	11	identified	identify	VERB
5t34sj15655	18	12	.	.	PUNCT