id sid tid token lemma pos 6969z032s60 1 1 the the DET 6969z032s60 1 2 phaseout phaseout NOUN 6969z032s60 1 3 of of ADP 6969z032s60 1 4 high high ADJ 6969z032s60 1 5 global global ADJ 6969z032s60 1 6 warming warm VERB 6969z032s60 1 7 potential potential ADJ 6969z032s60 1 8 refrigerants refrigerant NOUN 6969z032s60 1 9 has have VERB 6969z032s60 1 10 environmental environmental ADJ 6969z032s60 1 11 , , PUNCT 6969z032s60 1 12 economic economic ADJ 6969z032s60 1 13 , , PUNCT 6969z032s60 1 14 and and CCONJ 6969z032s60 1 15 engineering engineering NOUN 6969z032s60 1 16 implications implication NOUN 6969z032s60 1 17 . . PUNCT 6969z032s60 2 1 these these DET 6969z032s60 2 2 refrigerants refrigerant NOUN 6969z032s60 2 3 are be AUX 6969z032s60 2 4 often often ADV 6969z032s60 2 5 azeotropic azeotropic ADJ 6969z032s60 2 6 mixtures mixture NOUN 6969z032s60 2 7 of of ADP 6969z032s60 2 8 high high ADJ 6969z032s60 2 9 value value NOUN 6969z032s60 2 10 hydrofluorocarbons hydrofluorocarbon NOUN 6969z032s60 2 11 ( ( PUNCT 6969z032s60 2 12 hfcs hfcs PROPN 6969z032s60 2 13 ) ) PUNCT 6969z032s60 2 14 which which PRON 6969z032s60 2 15 must must AUX 6969z032s60 2 16 be be AUX 6969z032s60 2 17 separated separate VERB 6969z032s60 2 18 for for ADP 6969z032s60 2 19 their their PRON 6969z032s60 2 20 sustainable sustainable ADJ 6969z032s60 2 21 reuse reuse NOUN 6969z032s60 2 22 and and CCONJ 6969z032s60 2 23 recycle recycle NOUN 6969z032s60 2 24 . . PUNCT 6969z032s60 3 1 however however ADV 6969z032s60 3 2 , , PUNCT 6969z032s60 3 3 energy energy NOUN 6969z032s60 3 4 efficient efficient ADJ 6969z032s60 3 5 and and CCONJ 6969z032s60 3 6 economically economically ADV 6969z032s60 3 7 feasible feasible ADJ 6969z032s60 3 8 azeotropic azeotropic ADJ 6969z032s60 3 9 separations separation NOUN 6969z032s60 3 10 are be AUX 6969z032s60 3 11 a a DET 6969z032s60 3 12 significant significant ADJ 6969z032s60 3 13 challenge challenge NOUN 6969z032s60 3 14 in in ADP 6969z032s60 3 15 the the DET 6969z032s60 3 16 chemical chemical NOUN 6969z032s60 3 17 engineering engineering NOUN 6969z032s60 3 18 community community NOUN 6969z032s60 3 19 , , PUNCT 6969z032s60 3 20 often often ADV 6969z032s60 3 21 requiring require VERB 6969z032s60 3 22 the the DET 6969z032s60 3 23 design design NOUN 6969z032s60 3 24 of of ADP 6969z032s60 3 25 novel novel ADJ 6969z032s60 3 26 solvent solvent NOUN 6969z032s60 3 27 materials material NOUN 6969z032s60 3 28 , , PUNCT 6969z032s60 3 29 e.g. e.g. ADV 6969z032s60 3 30 , , PUNCT 6969z032s60 3 31 ionic ionic ADJ 6969z032s60 3 32 liquids liquid NOUN 6969z032s60 3 33 . . PUNCT 6969z032s60 4 1 here here ADV 6969z032s60 4 2 , , PUNCT 6969z032s60 4 3 we we PRON 6969z032s60 4 4 propose propose VERB 6969z032s60 4 5 a a DET 6969z032s60 4 6 multi multi ADJ 6969z032s60 4 7 - - ADJ 6969z032s60 4 8 scale scale ADJ 6969z032s60 4 9 design design NOUN 6969z032s60 4 10 and and CCONJ 6969z032s60 4 11 optimization optimization NOUN 6969z032s60 4 12 , , PUNCT 6969z032s60 4 13 ` ` PUNCT 6969z032s60 4 14 ` ` PUNCT 6969z032s60 4 15 data data NOUN 6969z032s60 4 16 - - PUNCT 6969z032s60 4 17 to to ADP 6969z032s60 4 18 - - PUNCT 6969z032s60 4 19 design design NOUN 6969z032s60 4 20 " " PUNCT 6969z032s60 4 21 , , PUNCT 6969z032s60 4 22 framework framework NOUN 6969z032s60 4 23 for for ADP 6969z032s60 4 24 identifying identify VERB 6969z032s60 4 25 an an DET 6969z032s60 4 26 ideal ideal ADJ 6969z032s60 4 27 il il PROPN 6969z032s60 4 28 separating separate VERB 6969z032s60 4 29 agent agent NOUN 6969z032s60 4 30 for for ADP 6969z032s60 4 31 each each DET 6969z032s60 4 32 hfc hfc ADJ 6969z032s60 4 33 refrigerant refrigerant ADJ 6969z032s60 4 34 mixture mixture NOUN 6969z032s60 4 35 . . PUNCT 6969z032s60 5 1 this this DET 6969z032s60 5 2 framework framework NOUN 6969z032s60 5 3 is be AUX 6969z032s60 5 4 an an DET 6969z032s60 5 5 iterative iterative ADJ 6969z032s60 5 6 loop loop NOUN 6969z032s60 5 7 in in ADP 6969z032s60 5 8 which which PRON 6969z032s60 5 9 data data NOUN 6969z032s60 5 10 is be AUX 6969z032s60 5 11 generated generate VERB 6969z032s60 5 12 and and CCONJ 6969z032s60 5 13 used use VERB 6969z032s60 5 14 to to PART 6969z032s60 5 15 fit fit VERB 6969z032s60 5 16 thermodynamic thermodynamic ADJ 6969z032s60 5 17 models model NOUN 6969z032s60 5 18 and and CCONJ 6969z032s60 5 19 then then ADV 6969z032s60 5 20 perform perform VERB 6969z032s60 5 21 preliminary preliminary ADJ 6969z032s60 5 22 process process NOUN 6969z032s60 5 23 design design NOUN 6969z032s60 5 24 calculations calculation NOUN 6969z032s60 5 25 and and CCONJ 6969z032s60 5 26 technoeconomic technoeconomic ADJ 6969z032s60 5 27 analyses analysis NOUN 6969z032s60 5 28 under under ADP 6969z032s60 5 29 uncertainty uncertainty NOUN 6969z032s60 5 30 . . PUNCT 6969z032s60 6 1 a a DET 6969z032s60 6 2 feedback feedback NOUN 6969z032s60 6 3 loop loop NOUN 6969z032s60 6 4 guides guide VERB 6969z032s60 6 5 data data NOUN 6969z032s60 6 6 generation generation NOUN 6969z032s60 6 7 efforts effort NOUN 6969z032s60 6 8 towards towards ADP 6969z032s60 6 9 valuable valuable ADJ 6969z032s60 6 10 experiments experiment NOUN 6969z032s60 6 11 and and CCONJ 6969z032s60 6 12 the the DET 6969z032s60 6 13 thermophysical thermophysical ADJ 6969z032s60 6 14 properties property NOUN 6969z032s60 6 15 of of ADP 6969z032s60 6 16 optimal optimal ADJ 6969z032s60 6 17 ils.this ils.this PROPN 6969z032s60 6 18 data data NOUN 6969z032s60 6 19 - - PUNCT 6969z032s60 6 20 to to ADP 6969z032s60 6 21 - - PUNCT 6969z032s60 6 22 design design NOUN 6969z032s60 6 23 framework framework NOUN 6969z032s60 6 24 is be AUX 6969z032s60 6 25 an an DET 6969z032s60 6 26 example example NOUN 6969z032s60 6 27 of of ADP 6969z032s60 6 28 highly highly ADV 6969z032s60 6 29 collaborative collaborative ADJ 6969z032s60 6 30 , , PUNCT 6969z032s60 6 31 integrated integrate VERB 6969z032s60 6 32 research research NOUN 6969z032s60 6 33 that that PRON 6969z032s60 6 34 bridges bridge VERB 6969z032s60 6 35 the the DET 6969z032s60 6 36 perspectives perspective NOUN 6969z032s60 6 37 and and CCONJ 6969z032s60 6 38 tools tool NOUN 6969z032s60 6 39 of of ADP 6969z032s60 6 40 the the DET 6969z032s60 6 41 experimental experimental ADJ 6969z032s60 6 42 , , PUNCT 6969z032s60 6 43 molecular molecular ADJ 6969z032s60 6 44 science science NOUN 6969z032s60 6 45 and and CCONJ 6969z032s60 6 46 engineering engineering NOUN 6969z032s60 6 47 , , PUNCT 6969z032s60 6 48 and and CCONJ 6969z032s60 6 49 process process NOUN 6969z032s60 6 50 systems system NOUN 6969z032s60 6 51 engineering engineering NOUN 6969z032s60 6 52 communities community NOUN 6969z032s60 6 53 to to PART 6969z032s60 6 54 develop develop VERB 6969z032s60 6 55 novel novel ADJ 6969z032s60 6 56 solutions solution NOUN 6969z032s60 6 57 to to ADP 6969z032s60 6 58 an an DET 6969z032s60 6 59 ongoing ongoing ADJ 6969z032s60 6 60 chemical chemical NOUN 6969z032s60 6 61 engineering engineering NOUN 6969z032s60 6 62 challenge challenge NOUN 6969z032s60 6 63 . . PUNCT 6969z032s60 7 1 here here ADV 6969z032s60 7 2 , , PUNCT 6969z032s60 7 3 we we PRON 6969z032s60 7 4 highlight highlight VERB 6969z032s60 7 5 two two NUM 6969z032s60 7 6 examples example NOUN 6969z032s60 7 7 of of ADP 6969z032s60 7 8 successful successful ADJ 6969z032s60 7 9 synergistic synergistic ADJ 6969z032s60 7 10 research research NOUN 6969z032s60 7 11 efforts effort NOUN 6969z032s60 7 12 in in ADP 6969z032s60 7 13 the the DET 6969z032s60 7 14 data data NOUN 6969z032s60 7 15 - - PUNCT 6969z032s60 7 16 to to ADP 6969z032s60 7 17 - - PUNCT 6969z032s60 7 18 design design NOUN 6969z032s60 7 19 framework framework NOUN 6969z032s60 7 20 . . PUNCT 6969z032s60 8 1 first first ADV 6969z032s60 8 2 , , PUNCT 6969z032s60 8 3 we we PRON 6969z032s60 8 4 demonstrate demonstrate VERB 6969z032s60 8 5 two two NUM 6969z032s60 8 6 workflows workflow NOUN 6969z032s60 8 7 which which PRON 6969z032s60 8 8 harness harness NOUN 6969z032s60 8 9 machine machine NOUN 6969z032s60 8 10 learning learning NOUN 6969z032s60 8 11 and and CCONJ 6969z032s60 8 12 bayesian bayesian ADJ 6969z032s60 8 13 optimization optimization NOUN 6969z032s60 8 14 techniques technique NOUN 6969z032s60 8 15 to to PART 6969z032s60 8 16 fit fit VERB 6969z032s60 8 17 cheap cheap ADJ 6969z032s60 8 18 - - PUNCT 6969z032s60 8 19 to to PART 6969z032s60 8 20 - - PUNCT 6969z032s60 8 21 evaluate evaluate VERB 6969z032s60 8 22 surrogate surrogate ADJ 6969z032s60 8 23 models model NOUN 6969z032s60 8 24 as as ADP 6969z032s60 8 25 replacements replacement NOUN 6969z032s60 8 26 for for ADP 6969z032s60 8 27 computationally computationally ADV 6969z032s60 8 28 expensive expensive ADJ 6969z032s60 8 29 molecular molecular ADJ 6969z032s60 8 30 simulations simulation NOUN 6969z032s60 8 31 , , PUNCT 6969z032s60 8 32 enabling enable VERB 6969z032s60 8 33 rapid rapid ADJ 6969z032s60 8 34 calibration calibration NOUN 6969z032s60 8 35 of of ADP 6969z032s60 8 36 molecular molecular ADJ 6969z032s60 8 37 models model NOUN 6969z032s60 8 38 for for ADP 6969z032s60 8 39 hfcs hfc NOUN 6969z032s60 8 40 . . PUNCT 6969z032s60 9 1 then then ADV 6969z032s60 9 2 , , PUNCT 6969z032s60 9 3 we we PRON 6969z032s60 9 4 propose propose VERB 6969z032s60 9 5 a a DET 6969z032s60 9 6 rigorous rigorous ADJ 6969z032s60 9 7 thermodynamic thermodynamic ADJ 6969z032s60 9 8 model model NOUN 6969z032s60 9 9 selection selection NOUN 6969z032s60 9 10 and and CCONJ 6969z032s60 9 11 analysis analysis NOUN 6969z032s60 9 12 workflow workflow NOUN 6969z032s60 9 13 which which PRON 6969z032s60 9 14 utilizes utilize VERB 6969z032s60 9 15 data data NOUN 6969z032s60 9 16 science science NOUN 6969z032s60 9 17 tools tool NOUN 6969z032s60 9 18 , , PUNCT 6969z032s60 9 19 including include VERB 6969z032s60 9 20 information information NOUN 6969z032s60 9 21 criteria criterion NOUN 6969z032s60 9 22 , , PUNCT 6969z032s60 9 23 fischer fischer PROPN 6969z032s60 9 24 information information NOUN 6969z032s60 9 25 matrix matrix NOUN 6969z032s60 9 26 - - PUNCT 6969z032s60 9 27 based base VERB 6969z032s60 9 28 identifiability identifiability NOUN 6969z032s60 9 29 analyses analysis NOUN 6969z032s60 9 30 , , PUNCT 6969z032s60 9 31 uncertainty uncertainty NOUN 6969z032s60 9 32 quantification quantification NOUN 6969z032s60 9 33 , , PUNCT 6969z032s60 9 34 and and CCONJ 6969z032s60 9 35 model model NOUN 6969z032s60 9 36 - - PUNCT 6969z032s60 9 37 based base VERB 6969z032s60 9 38 design design NOUN 6969z032s60 9 39 of of ADP 6969z032s60 9 40 experiments experiment NOUN 6969z032s60 9 41 . . PUNCT 6969z032s60 10 1 this this DET 6969z032s60 10 2 workflow workflow NOUN 6969z032s60 10 3 enables enable VERB 6969z032s60 10 4 the the DET 6969z032s60 10 5 systematic systematic ADJ 6969z032s60 10 6 selection selection NOUN 6969z032s60 10 7 of of ADP 6969z032s60 10 8 a a DET 6969z032s60 10 9 thermodynamic thermodynamic ADJ 6969z032s60 10 10 model model NOUN 6969z032s60 10 11 that that PRON 6969z032s60 10 12 is be AUX 6969z032s60 10 13 the the DET 6969z032s60 10 14 most most ADV 6969z032s60 10 15 accurate accurate ADJ 6969z032s60 10 16 , , PUNCT 6969z032s60 10 17 predictive predictive NOUN 6969z032s60 10 18 , , PUNCT 6969z032s60 10 19 and and CCONJ 6969z032s60 10 20 interpretable interpretable ADJ 6969z032s60 10 21 from from ADP 6969z032s60 10 22 a a DET 6969z032s60 10 23 library library NOUN 6969z032s60 10 24 of of ADP 6969z032s60 10 25 candidate candidate NOUN 6969z032s60 10 26 models model NOUN 6969z032s60 10 27 for for ADP 6969z032s60 10 28 an an DET 6969z032s60 10 29 hfc hfc NOUN 6969z032s60 10 30 / / SYM 6969z032s60 10 31 il il PROPN 6969z032s60 10 32 system system NOUN 6969z032s60 10 33 . . PUNCT 6969z032s60 11 1 additionally additionally ADV 6969z032s60 11 2 , , PUNCT 6969z032s60 11 3 it it PRON 6969z032s60 11 4 guides guide VERB 6969z032s60 11 5 data data NOUN 6969z032s60 11 6 generation generation NOUN 6969z032s60 11 7 collaborators collaborator NOUN 6969z032s60 11 8 towards towards ADP 6969z032s60 11 9 the the DET 6969z032s60 11 10 most most ADV 6969z032s60 11 11 valuable valuable ADJ 6969z032s60 11 12 measurements measurement NOUN 6969z032s60 11 13 , , PUNCT 6969z032s60 11 14 facilitating facilitate VERB 6969z032s60 11 15 more more ADV 6969z032s60 11 16 efficient efficient ADJ 6969z032s60 11 17 allocation allocation NOUN 6969z032s60 11 18 of of ADP 6969z032s60 11 19 experimental experimental ADJ 6969z032s60 11 20 resources resource NOUN 6969z032s60 11 21 . . PUNCT 6969z032s60 12 1 finally finally ADV 6969z032s60 12 2 , , PUNCT 6969z032s60 12 3 we we PRON 6969z032s60 12 4 conclude conclude VERB 6969z032s60 12 5 with with ADP 6969z032s60 12 6 a a DET 6969z032s60 12 7 prospective prospective NOUN 6969z032s60 12 8 for for ADP 6969z032s60 12 9 applying apply VERB 6969z032s60 12 10 the the DET 6969z032s60 12 11 data data NOUN 6969z032s60 12 12 - - PUNCT 6969z032s60 12 13 to to ADP 6969z032s60 12 14 - - PUNCT 6969z032s60 12 15 design design NOUN 6969z032s60 12 16 framework framework NOUN 6969z032s60 12 17 to to ADP 6969z032s60 12 18 hfc hfc PROPN 6969z032s60 12 19 / / SYM 6969z032s60 12 20 il il PROPN 6969z032s60 12 21 systems system NOUN 6969z032s60 12 22 , , PUNCT 6969z032s60 12 23 but but CCONJ 6969z032s60 12 24 emphasize emphasize VERB 6969z032s60 12 25 this this DET 6969z032s60 12 26 framework framework NOUN 6969z032s60 12 27 and and CCONJ 6969z032s60 12 28 the the DET 6969z032s60 12 29 tools tool NOUN 6969z032s60 12 30 presented present VERB 6969z032s60 12 31 here here ADV 6969z032s60 12 32 are be AUX 6969z032s60 12 33 applicable applicable ADJ 6969z032s60 12 34 to to ADP 6969z032s60 12 35 many many ADJ 6969z032s60 12 36 systems system NOUN 6969z032s60 12 37 of of ADP 6969z032s60 12 38 interest interest NOUN 6969z032s60 12 39 in in ADP 6969z032s60 12 40 the the DET 6969z032s60 12 41 chemical chemical NOUN 6969z032s60 12 42 engineering engineering NOUN 6969z032s60 12 43 community community NOUN 6969z032s60 12 44 . . PUNCT