id	sid	tid	token	lemma	pos
79407w65j5c	1	1	a	a	DET
79407w65j5c	1	2	considerable	considerable	ADJ
79407w65j5c	1	3	amount	amount	NOUN
79407w65j5c	1	4	of	of	ADP
79407w65j5c	1	5	theoretical	theoretical	ADJ
79407w65j5c	1	6	and	and	CCONJ
79407w65j5c	1	7	experimental	experimental	ADJ
79407w65j5c	1	8	work	work	NOUN
79407w65j5c	1	9	has	have	AUX
79407w65j5c	1	10	focused	focus	VERB
79407w65j5c	1	11	on	on	ADP
79407w65j5c	1	12	the	the	DET
79407w65j5c	1	13	application	application	NOUN
79407w65j5c	1	14	of	of	ADP
79407w65j5c	1	15	vibrational	vibrational	ADJ
79407w65j5c	1	16	infrared	infrared	ADJ
79407w65j5c	1	17	spectroscopy	spectroscopy	NOUN
79407w65j5c	1	18	to	to	ADP
79407w65j5c	1	19	questions	question	NOUN
79407w65j5c	1	20	of	of	ADP
79407w65j5c	1	21	molecular	molecular	ADJ
79407w65j5c	1	22	structure	structure	NOUN
79407w65j5c	1	23	and	and	CCONJ
79407w65j5c	1	24	dynamics	dynamic	NOUN
79407w65j5c	1	25	of	of	ADP
79407w65j5c	1	26	aqueous	aqueous	ADJ
79407w65j5c	1	27	systems	system	NOUN
79407w65j5c	1	28	.	.	PUNCT
79407w65j5c	2	1	this	this	PRON
79407w65j5c	2	2	is	be	AUX
79407w65j5c	2	3	due	due	ADJ
79407w65j5c	2	4	to	to	ADP
79407w65j5c	2	5	both	both	PRON
79407w65j5c	2	6	the	the	DET
79407w65j5c	2	7	uniqueness	uniqueness	NOUN
79407w65j5c	2	8	of	of	ADP
79407w65j5c	2	9	molecular	molecular	ADJ
79407w65j5c	2	10	vibrations	vibration	NOUN
79407w65j5c	2	11	for	for	ADP
79407w65j5c	2	12	a	a	DET
79407w65j5c	2	13	given	give	VERB
79407w65j5c	2	14	structure	structure	NOUN
79407w65j5c	2	15	and	and	CCONJ
79407w65j5c	2	16	the	the	DET
79407w65j5c	2	17	exquisite	exquisite	ADJ
79407w65j5c	2	18	sensitivity	sensitivity	NOUN
79407w65j5c	2	19	of	of	ADP
79407w65j5c	2	20	molecular	molecular	ADJ
79407w65j5c	2	21	vibrations	vibration	NOUN
79407w65j5c	2	22	to	to	ADP
79407w65j5c	2	23	changes	change	NOUN
79407w65j5c	2	24	in	in	ADP
79407w65j5c	2	25	environment	environment	NOUN
79407w65j5c	2	26	.	.	PUNCT
79407w65j5c	3	1	thus	thus	ADV
79407w65j5c	3	2	,	,	PUNCT
79407w65j5c	3	3	a	a	DET
79407w65j5c	3	4	strong	strong	ADJ
79407w65j5c	3	5	understanding	understanding	NOUN
79407w65j5c	3	6	of	of	ADP
79407w65j5c	3	7	molecular	molecular	ADJ
79407w65j5c	3	8	vibrations	vibration	NOUN
79407w65j5c	3	9	and	and	CCONJ
79407w65j5c	3	10	spectroscopy	spectroscopy	NOUN
79407w65j5c	3	11	gives	give	VERB
79407w65j5c	3	12	chemists	chemist	NOUN
79407w65j5c	3	13	the	the	DET
79407w65j5c	3	14	ability	ability	NOUN
79407w65j5c	3	15	to	to	PART
79407w65j5c	3	16	directly	directly	ADV
79407w65j5c	3	17	probe	probe	VERB
79407w65j5c	3	18	chemical	chemical	NOUN
79407w65j5c	3	19	structure	structure	NOUN
79407w65j5c	3	20	and	and	CCONJ
79407w65j5c	3	21	environment	environment	NOUN
79407w65j5c	3	22	of	of	ADP
79407w65j5c	3	23	aqueous	aqueous	ADJ
79407w65j5c	3	24	systems.an	systems.an	NUM
79407w65j5c	3	25	accurate	accurate	ADJ
79407w65j5c	3	26	quantum	quantum	ADJ
79407w65j5c	3	27	mechanical	mechanical	ADJ
79407w65j5c	3	28	description	description	NOUN
79407w65j5c	3	29	of	of	ADP
79407w65j5c	3	30	the	the	DET
79407w65j5c	3	31	microscopic	microscopic	ADJ
79407w65j5c	3	32	chemical	chemical	ADJ
79407w65j5c	3	33	details	detail	NOUN
79407w65j5c	3	34	which	which	PRON
79407w65j5c	3	35	give	give	VERB
79407w65j5c	3	36	rise	rise	NOUN
79407w65j5c	3	37	to	to	ADP
79407w65j5c	3	38	observed	observed	ADJ
79407w65j5c	3	39	spectral	spectral	ADJ
79407w65j5c	3	40	responses	response	NOUN
79407w65j5c	3	41	leads	lead	VERB
79407w65j5c	3	42	to	to	ADP
79407w65j5c	3	43	a	a	DET
79407w65j5c	3	44	variety	variety	NOUN
79407w65j5c	3	45	of	of	ADP
79407w65j5c	3	46	unique	unique	ADJ
79407w65j5c	3	47	differential	differential	ADJ
79407w65j5c	3	48	equations	equation	NOUN
79407w65j5c	3	49	which	which	PRON
79407w65j5c	3	50	need	need	VERB
79407w65j5c	3	51	to	to	PART
79407w65j5c	3	52	be	be	AUX
79407w65j5c	3	53	solved	solve	VERB
79407w65j5c	3	54	.	.	PUNCT
79407w65j5c	4	1	in	in	ADP
79407w65j5c	4	2	chapter	chapter	NOUN
79407w65j5c	4	3	1	1	NUM
79407w65j5c	4	4	,	,	PUNCT
79407w65j5c	4	5	a	a	DET
79407w65j5c	4	6	general	general	ADJ
79407w65j5c	4	7	discrete	discrete	ADJ
79407w65j5c	4	8	variable	variable	ADJ
79407w65j5c	4	9	representation	representation	NOUN
79407w65j5c	4	10	method	method	NOUN
79407w65j5c	4	11	is	be	AUX
79407w65j5c	4	12	developed	develop	VERB
79407w65j5c	4	13	which	which	PRON
79407w65j5c	4	14	allows	allow	VERB
79407w65j5c	4	15	the	the	DET
79407w65j5c	4	16	solution	solution	NOUN
79407w65j5c	4	17	of	of	ADP
79407w65j5c	4	18	arbitrary	arbitrary	ADJ
79407w65j5c	4	19	linear	linear	ADJ
79407w65j5c	4	20	differential	differential	ADJ
79407w65j5c	4	21	equations	equation	NOUN
79407w65j5c	4	22	.	.	PUNCT
79407w65j5c	5	1	because	because	SCONJ
79407w65j5c	5	2	this	this	DET
79407w65j5c	5	3	theory	theory	NOUN
79407w65j5c	5	4	applies	apply	VERB
79407w65j5c	5	5	to	to	ADP
79407w65j5c	5	6	the	the	DET
79407w65j5c	5	7	solution	solution	NOUN
79407w65j5c	5	8	and	and	CCONJ
79407w65j5c	5	9	representation	representation	NOUN
79407w65j5c	5	10	of	of	ADP
79407w65j5c	5	11	arbitrary	arbitrary	ADJ
79407w65j5c	5	12	differential	differential	ADJ
79407w65j5c	5	13	equations	equation	NOUN
79407w65j5c	5	14	and	and	CCONJ
79407w65j5c	5	15	operators	operator	NOUN
79407w65j5c	5	16	,	,	PUNCT
79407w65j5c	5	17	this	this	DET
79407w65j5c	5	18	chapter	chapter	NOUN
79407w65j5c	5	19	is	be	AUX
79407w65j5c	5	20	a	a	DET
79407w65j5c	5	21	stand	stand	VERB
79407w65j5c	5	22	-	-	PUNCT
79407w65j5c	5	23	alone	alone	ADJ
79407w65j5c	5	24	mathematical	mathematical	PROPN
79407w65j5c	5	25	work.in	work.in	PUNCT
79407w65j5c	5	26	chapter	chapter	NOUN
79407w65j5c	5	27	2	2	NUM
79407w65j5c	5	28	,	,	PUNCT
79407w65j5c	5	29	the	the	DET
79407w65j5c	5	30	origin	origin	NOUN
79407w65j5c	5	31	of	of	ADP
79407w65j5c	5	32	spectroscopic	spectroscopic	ADJ
79407w65j5c	5	33	transitions	transition	NOUN
79407w65j5c	5	34	from	from	ADP
79407w65j5c	5	35	the	the	DET
79407w65j5c	5	36	interaction	interaction	NOUN
79407w65j5c	5	37	of	of	ADP
79407w65j5c	5	38	the	the	DET
79407w65j5c	5	39	electromagnetic	electromagnetic	ADJ
79407w65j5c	5	40	field	field	NOUN
79407w65j5c	5	41	of	of	ADP
79407w65j5c	5	42	light	light	NOUN
79407w65j5c	5	43	with	with	ADP
79407w65j5c	5	44	the	the	DET
79407w65j5c	5	45	charged	charge	VERB
79407w65j5c	5	46	particles	particle	NOUN
79407w65j5c	5	47	that	that	PRON
79407w65j5c	5	48	constitute	constitute	VERB
79407w65j5c	5	49	molecules	molecule	NOUN
79407w65j5c	5	50	is	be	AUX
79407w65j5c	5	51	shown	show	VERB
79407w65j5c	5	52	.	.	PUNCT
79407w65j5c	6	1	an	an	DET
79407w65j5c	6	2	explicit	explicit	ADJ
79407w65j5c	6	3	treatment	treatment	NOUN
79407w65j5c	6	4	of	of	ADP
79407w65j5c	6	5	the	the	DET
79407w65j5c	6	6	theory	theory	NOUN
79407w65j5c	6	7	of	of	ADP
79407w65j5c	6	8	molecular	molecular	ADJ
79407w65j5c	6	9	vibrations	vibration	NOUN
79407w65j5c	6	10	in	in	ADP
79407w65j5c	6	11	the	the	DET
79407w65j5c	6	12	harmonic	harmonic	ADJ
79407w65j5c	6	13	approximation	approximation	NOUN
79407w65j5c	6	14	and	and	CCONJ
79407w65j5c	6	15	coupled	couple	VERB
79407w65j5c	6	16	local	local	ADJ
79407w65j5c	6	17	mode	mode	NOUN
79407w65j5c	6	18	theory	theory	NOUN
79407w65j5c	6	19	are	be	AUX
79407w65j5c	6	20	given	give	VERB
79407w65j5c	6	21	,	,	PUNCT
79407w65j5c	6	22	along	along	ADP
79407w65j5c	6	23	with	with	ADP
79407w65j5c	6	24	commentary	commentary	NOUN
79407w65j5c	6	25	on	on	ADP
79407w65j5c	6	26	extensions	extension	NOUN
79407w65j5c	6	27	of	of	ADP
79407w65j5c	6	28	harmonic	harmonic	NOUN
79407w65j5c	6	29	theory	theory	NOUN
79407w65j5c	6	30	into	into	ADP
79407w65j5c	6	31	post	post	ADJ
79407w65j5c	6	32	-	-	ADJ
79407w65j5c	6	33	harmonic	harmonic	ADJ
79407w65j5c	6	34	methods	method	NOUN
79407w65j5c	6	35	.	.	PUNCT
79407w65j5c	7	1	a	a	DET
79407w65j5c	7	2	generalization	generalization	NOUN
79407w65j5c	7	3	of	of	ADP
79407w65j5c	7	4	the	the	DET
79407w65j5c	7	5	coupled	couple	VERB
79407w65j5c	7	6	local	local	ADJ
79407w65j5c	7	7	mode	mode	NOUN
79407w65j5c	7	8	theory	theory	NOUN
79407w65j5c	7	9	to	to	PART
79407w65j5c	7	10	include	include	VERB
79407w65j5c	7	11	dynamical	dynamical	ADJ
79407w65j5c	7	12	lineshapes	lineshape	NOUN
79407w65j5c	7	13	and	and	CCONJ
79407w65j5c	7	14	a	a	DET
79407w65j5c	7	15	treatment	treatment	NOUN
79407w65j5c	7	16	of	of	ADP
79407w65j5c	7	17	pipek	pipek	PROPN
79407w65j5c	7	18	's	's	PART
79407w65j5c	7	19	inverse	inverse	ADJ
79407w65j5c	7	20	participation	participation	NOUN
79407w65j5c	7	21	ratio	ratio	NOUN
79407w65j5c	7	22	for	for	ADP
79407w65j5c	7	23	vibrational	vibrational	ADJ
79407w65j5c	7	24	non	non	ADJ
79407w65j5c	7	25	-	-	ADJ
79407w65j5c	7	26	locality	locality	NOUN
79407w65j5c	7	27	are	be	AUX
79407w65j5c	7	28	also	also	ADV
79407w65j5c	7	29	given.in	given.in	X
79407w65j5c	7	30	chapter	chapter	NOUN
79407w65j5c	7	31	3	3	NUM
79407w65j5c	7	32	,	,	PUNCT
79407w65j5c	7	33	numerous	numerous	ADJ
79407w65j5c	7	34	results	result	NOUN
79407w65j5c	7	35	of	of	ADP
79407w65j5c	7	36	the	the	DET
79407w65j5c	7	37	applications	application	NOUN
79407w65j5c	7	38	of	of	ADP
79407w65j5c	7	39	the	the	DET
79407w65j5c	7	40	coupled	couple	VERB
79407w65j5c	7	41	local	local	ADJ
79407w65j5c	7	42	mode	mode	NOUN
79407w65j5c	7	43	theory	theory	NOUN
79407w65j5c	7	44	to	to	ADP
79407w65j5c	7	45	protonated	protonate	VERB
79407w65j5c	7	46	water	water	NOUN
79407w65j5c	7	47	clusters	cluster	NOUN
79407w65j5c	7	48	are	be	AUX
79407w65j5c	7	49	given	give	VERB
79407w65j5c	7	50	.	.	PUNCT
79407w65j5c	8	1	these	these	DET
79407w65j5c	8	2	simulation	simulation	NOUN
79407w65j5c	8	3	results	result	NOUN
79407w65j5c	8	4	are	be	AUX
79407w65j5c	8	5	validated	validate	VERB
79407w65j5c	8	6	against	against	ADP
79407w65j5c	8	7	experimental	experimental	ADJ
79407w65j5c	8	8	results	result	NOUN
79407w65j5c	8	9	.	.	PUNCT
79407w65j5c	9	1	the	the	DET
79407w65j5c	9	2	coupled	couple	VERB
79407w65j5c	9	3	local	local	ADJ
79407w65j5c	9	4	mode	mode	NOUN
79407w65j5c	9	5	approach	approach	NOUN
79407w65j5c	9	6	produces	produce	VERB
79407w65j5c	9	7	accurate	accurate	ADJ
79407w65j5c	9	8	results	result	NOUN
79407w65j5c	9	9	and	and	CCONJ
79407w65j5c	9	10	gives	give	VERB
79407w65j5c	9	11	a	a	DET
79407w65j5c	9	12	fully	fully	ADV
79407w65j5c	9	13	microscopic	microscopic	ADJ
79407w65j5c	9	14	picture	picture	NOUN
79407w65j5c	9	15	of	of	ADP
79407w65j5c	9	16	the	the	DET
79407w65j5c	9	17	molecular	molecular	ADJ
79407w65j5c	9	18	vibrations	vibration	NOUN
79407w65j5c	9	19	in	in	ADP
79407w65j5c	9	20	terms	term	NOUN
79407w65j5c	9	21	of	of	ADP
79407w65j5c	9	22	the	the	DET
79407w65j5c	9	23	contributions	contribution	NOUN
79407w65j5c	9	24	of	of	ADP
79407w65j5c	9	25	the	the	DET
79407w65j5c	9	26	individual	individual	ADJ
79407w65j5c	9	27	internal	internal	ADJ
79407w65j5c	9	28	coordinates	coordinate	NOUN
79407w65j5c	9	29	.	.	PUNCT
79407w65j5c	10	1	analysis	analysis	NOUN
79407w65j5c	10	2	of	of	ADP
79407w65j5c	10	3	methods	method	NOUN
79407w65j5c	10	4	for	for	ADP
79407w65j5c	10	5	costreduction	costreduction	NOUN
79407w65j5c	10	6	and	and	CCONJ
79407w65j5c	10	7	the	the	DET
79407w65j5c	10	8	dependence	dependence	NOUN
79407w65j5c	10	9	of	of	ADP
79407w65j5c	10	10	coupled	couple	VERB
79407w65j5c	10	11	local	local	ADJ
79407w65j5c	10	12	mode	mode	NOUN
79407w65j5c	10	13	results	result	NOUN
79407w65j5c	10	14	upon	upon	SCONJ
79407w65j5c	10	15	choices	choice	NOUN
79407w65j5c	10	16	in	in	ADP
79407w65j5c	10	17	electronic	electronic	ADJ
79407w65j5c	10	18	structure	structure	NOUN
79407w65j5c	10	19	methods	method	NOUN
79407w65j5c	10	20	,	,	PUNCT
79407w65j5c	10	21	basis	basis	NOUN
79407w65j5c	10	22	sets	set	NOUN
79407w65j5c	10	23	,	,	PUNCT
79407w65j5c	10	24	and	and	CCONJ
79407w65j5c	10	25	the	the	DET
79407w65j5c	10	26	derivative	derivative	ADJ
79407w65j5c	10	27	truncation	truncation	NOUN
79407w65j5c	10	28	of	of	ADP
79407w65j5c	10	29	the	the	DET
79407w65j5c	10	30	potential	potential	ADJ
79407w65j5c	10	31	energy	energy	NOUN
79407w65j5c	10	32	for	for	ADP
79407w65j5c	10	33	couplings	coupling	NOUN
79407w65j5c	10	34	is	be	AUX
79407w65j5c	10	35	given	give	VERB
79407w65j5c	10	36	.	.	PUNCT
79407w65j5c	11	1	it	it	PRON
79407w65j5c	11	2	is	be	AUX
79407w65j5c	11	3	concluded	conclude	VERB
79407w65j5c	11	4	that	that	SCONJ
79407w65j5c	11	5	the	the	DET
79407w65j5c	11	6	coupled	couple	VERB
79407w65j5c	11	7	local	local	ADJ
79407w65j5c	11	8	mode	mode	NOUN
79407w65j5c	11	9	method	method	NOUN
79407w65j5c	11	10	offers	offer	VERB
79407w65j5c	11	11	hope	hope	NOUN
79407w65j5c	11	12	for	for	ADP
79407w65j5c	11	13	accurately	accurately	ADV
79407w65j5c	11	14	dissecting	dissect	VERB
79407w65j5c	11	15	the	the	DET
79407w65j5c	11	16	complicated	complicated	ADJ
79407w65j5c	11	17	infrared	infrared	ADJ
79407w65j5c	11	18	spectra	spectra	NOUN
79407w65j5c	11	19	which	which	PRON
79407w65j5c	11	20	arise	arise	VERB
79407w65j5c	11	21	in	in	ADP
79407w65j5c	11	22	condensedphase	condensedphase	PROPN
79407w65j5c	11	23	systems	system	NOUN
79407w65j5c	11	24	.	.	PUNCT