id sid tid token lemma pos 9880vq30002 1 1 the the DET 9880vq30002 1 2 use use NOUN 9880vq30002 1 3 of of ADP 9880vq30002 1 4 molten melt VERB 9880vq30002 1 5 boric boric ADJ 9880vq30002 1 6 acid acid NOUN 9880vq30002 1 7 as as ADP 9880vq30002 1 8 a a DET 9880vq30002 1 9 reactive reactive ADJ 9880vq30002 1 10 flux flux NOUN 9880vq30002 1 11 for for ADP 9880vq30002 1 12 synthesizing synthesize VERB 9880vq30002 1 13 actinide actinide ADJ 9880vq30002 1 14 borates borate NOUN 9880vq30002 1 15 has have AUX 9880vq30002 1 16 been be AUX 9880vq30002 1 17 developed develop VERB 9880vq30002 1 18 in in ADP 9880vq30002 1 19 the the DET 9880vq30002 1 20 past past ADJ 9880vq30002 1 21 three three NUM 9880vq30002 1 22 years year NOUN 9880vq30002 1 23 providing provide VERB 9880vq30002 1 24 access access NOUN 9880vq30002 1 25 to to ADP 9880vq30002 1 26 a a DET 9880vq30002 1 27 remarkable remarkable ADJ 9880vq30002 1 28 array array NOUN 9880vq30002 1 29 of of ADP 9880vq30002 1 30 exotic exotic ADJ 9880vq30002 1 31 materials material NOUN 9880vq30002 1 32 with with ADP 9880vq30002 1 33 both both CCONJ 9880vq30002 1 34 unusual unusual ADJ 9880vq30002 1 35 structures structure NOUN 9880vq30002 1 36 and and CCONJ 9880vq30002 1 37 unprecedented unprecedented ADJ 9880vq30002 1 38 properties property NOUN 9880vq30002 1 39 . . PUNCT 9880vq30002 2 1 [ [ X 9880vq30002 2 2 thb5o6(oh)6][bo(oh)2]'¢2.5h2o thb5o6(oh)6][bo(oh)2]'¢2.5h2o NOUN 9880vq30002 2 3 ( ( PUNCT 9880vq30002 2 4 ndtb-1 ndtb-1 PROPN 9880vq30002 2 5 ) ) PUNCT 9880vq30002 2 6 possesses possess VERB 9880vq30002 2 7 a a DET 9880vq30002 2 8 cationic cationic ADJ 9880vq30002 2 9 supertetrahedral supertetrahedral ADJ 9880vq30002 2 10 structure structure NOUN 9880vq30002 2 11 and and CCONJ 9880vq30002 2 12 displays display VERB 9880vq30002 2 13 remarkable remarkable ADJ 9880vq30002 2 14 anion anion NOUN 9880vq30002 2 15 exchange exchange NOUN 9880vq30002 2 16 properties property NOUN 9880vq30002 2 17 with with ADP 9880vq30002 2 18 high high ADJ 9880vq30002 2 19 selectivity selectivity NOUN 9880vq30002 2 20 for for ADP 9880vq30002 2 21 tco4− tco4− NOUN 9880vq30002 2 22 ; ; PUNCT 9880vq30002 2 23 . . PUNCT 9880vq30002 3 1 in in ADP 9880vq30002 3 2 addition addition NOUN 9880vq30002 3 3 , , PUNCT 9880vq30002 3 4 ndtb-1 ndtb-1 PROPN 9880vq30002 3 5 was be AUX 9880vq30002 3 6 determined determined ADJ 9880vq30002 3 7 to to PART 9880vq30002 3 8 show show VERB 9880vq30002 3 9 real real ADJ 9880vq30002 3 10 utilities utility NOUN 9880vq30002 3 11 to to PART 9880vq30002 3 12 solve solve VERB 9880vq30002 3 13 the the DET 9880vq30002 3 14 ' ' PUNCT 9880vq30002 3 15 technetium technetium NOUN 9880vq30002 3 16 problem problem NOUN 9880vq30002 3 17 ' ' PUNCT 9880vq30002 3 18 . . PUNCT 9880vq30002 4 1 uranyl uranyl NOUN 9880vq30002 4 2 borates borate VERB 9880vq30002 4 3 form form VERB 9880vq30002 4 4 noncentrosymmetric noncentrosymmetric ADJ 9880vq30002 4 5 structures structure NOUN 9880vq30002 4 6 with with ADP 9880vq30002 4 7 extraordinarily extraordinarily ADV 9880vq30002 4 8 rich rich ADJ 9880vq30002 4 9 topological topological ADJ 9880vq30002 4 10 relationships relationship NOUN 9880vq30002 4 11 . . PUNCT 9880vq30002 5 1 neptunium neptunium NOUN 9880vq30002 5 2 borates borate NOUN 9880vq30002 5 3 are be AUX 9880vq30002 5 4 often often ADV 9880vq30002 5 5 mixed mixed ADJ 9880vq30002 5 6 - - PUNCT 9880vq30002 5 7 valent valent ADJ 9880vq30002 5 8 and and CCONJ 9880vq30002 5 9 yield yield VERB 9880vq30002 5 10 rare rare ADJ 9880vq30002 5 11 examples example NOUN 9880vq30002 5 12 of of ADP 9880vq30002 5 13 compounds compound NOUN 9880vq30002 5 14 with with ADP 9880vq30002 5 15 one one NUM 9880vq30002 5 16 metal metal NOUN 9880vq30002 5 17 in in ADP 9880vq30002 5 18 three three NUM 9880vq30002 5 19 different different ADJ 9880vq30002 5 20 oxidation oxidation NOUN 9880vq30002 5 21 states state NOUN 9880vq30002 5 22 . . PUNCT 9880vq30002 6 1 plutonium plutonium NOUN 9880vq30002 6 2 borates borate VERB 9880vq30002 6 3 display display VERB 9880vq30002 6 4 new new ADJ 9880vq30002 6 5 coordination coordination NOUN 9880vq30002 6 6 chemistry chemistry NOUN 9880vq30002 6 7 for for ADP 9880vq30002 6 8 trivalent trivalent NOUN 9880vq30002 6 9 actinides actinide NOUN 9880vq30002 6 10 . . PUNCT 9880vq30002 7 1 finally finally ADV 9880vq30002 7 2 , , PUNCT 9880vq30002 7 3 americium americium ADJ 9880vq30002 7 4 and and CCONJ 9880vq30002 7 5 curium curium NOUN 9880vq30002 7 6 borates borate NOUN 9880vq30002 7 7 show show VERB 9880vq30002 7 8 dramatic dramatic ADJ 9880vq30002 7 9 departures departure NOUN 9880vq30002 7 10 from from ADP 9880vq30002 7 11 plutonium plutonium NOUN 9880vq30002 7 12 borates borate NOUN 9880vq30002 7 13 , , PUNCT 9880vq30002 7 14 and and CCONJ 9880vq30002 7 15 form form VERB 9880vq30002 7 16 the the DET 9880vq30002 7 17 first first ADJ 9880vq30002 7 18 trivalent trivalent NOUN 9880vq30002 7 19 actinide actinide ADJ 9880vq30002 7 20 compounds compound NOUN 9880vq30002 7 21 that that PRON 9880vq30002 7 22 do do AUX 9880vq30002 7 23 not not PART 9880vq30002 7 24 have have VERB 9880vq30002 7 25 lanthanide lanthanide NOUN 9880vq30002 7 26 analogues analogue NOUN 9880vq30002 7 27 . . PUNCT 9880vq30002 8 1 there there PRON 9880vq30002 8 2 are be VERB 9880vq30002 8 3 scant scant ADJ 9880vq30002 8 4 examples example NOUN 9880vq30002 8 5 of of ADP 9880vq30002 8 6 families family NOUN 9880vq30002 8 7 of of ADP 9880vq30002 8 8 actinides actinide NOUN 9880vq30002 8 9 compounds compound NOUN 9880vq30002 8 10 that that PRON 9880vq30002 8 11 extend extend VERB 9880vq30002 8 12 past past ADJ 9880vq30002 8 13 plutonium plutonium NOUN 9880vq30002 8 14 to to PART 9880vq30002 8 15 examine examine VERB 9880vq30002 8 16 the the DET 9880vq30002 8 17 bonding bonding NOUN 9880vq30002 8 18 of of ADP 9880vq30002 8 19 later later ADV 9880vq30002 8 20 actinides actinide NOUN 9880vq30002 8 21 . . PUNCT 9880vq30002 9 1 there there PRON 9880vq30002 9 2 are be VERB 9880vq30002 9 3 several several ADJ 9880vq30002 9 4 grand grand ADJ 9880vq30002 9 5 challenges challenge NOUN 9880vq30002 9 6 that that SCONJ 9880vq30002 9 7 this this DET 9880vq30002 9 8 work work NOUN 9880vq30002 9 9 addresses address VERB 9880vq30002 9 10 . . PUNCT 9880vq30002 10 1 the the DET 9880vq30002 10 2 foremost foremost NOUN 9880vq30002 10 3 of of ADP 9880vq30002 10 4 these these DET 9880vq30002 10 5 challenges challenge NOUN 9880vq30002 10 6 is be AUX 9880vq30002 10 7 the the DET 9880vq30002 10 8 development development NOUN 9880vq30002 10 9 of of ADP 9880vq30002 10 10 structure structure NOUN 9880vq30002 10 11 - - PUNCT 9880vq30002 10 12 property property NOUN 9880vq30002 10 13 relationships relationship NOUN 9880vq30002 10 14 in in ADP 9880vq30002 10 15 transuranium transuranium NOUN 9880vq30002 10 16 materials material NOUN 9880vq30002 10 17 . . PUNCT 9880vq30002 11 1 a a DET 9880vq30002 11 2 deep deep ADJ 9880vq30002 11 3 understanding understanding NOUN 9880vq30002 11 4 of of ADP 9880vq30002 11 5 the the DET 9880vq30002 11 6 materials material NOUN 9880vq30002 11 7 chemistry chemistry NOUN 9880vq30002 11 8 of of ADP 9880vq30002 11 9 actinides actinide NOUN 9880vq30002 11 10 will will AUX 9880vq30002 11 11 likely likely ADV 9880vq30002 11 12 lead lead VERB 9880vq30002 11 13 to to ADP 9880vq30002 11 14 the the DET 9880vq30002 11 15 development development NOUN 9880vq30002 11 16 of of ADP 9880vq30002 11 17 advanced advanced ADJ 9880vq30002 11 18 waste waste NOUN 9880vq30002 11 19 forms form NOUN 9880vq30002 11 20 for for ADP 9880vq30002 11 21 radionuclides radionuclide NOUN 9880vq30002 11 22 present present ADJ 9880vq30002 11 23 in in ADP 9880vq30002 11 24 nuclear nuclear ADJ 9880vq30002 11 25 waste waste NOUN 9880vq30002 11 26 that that PRON 9880vq30002 11 27 prevent prevent VERB 9880vq30002 11 28 their their PRON 9880vq30002 11 29 transport transport NOUN 9880vq30002 11 30 in in ADP 9880vq30002 11 31 the the DET 9880vq30002 11 32 environment environment NOUN 9880vq30002 11 33 . . PUNCT 9880vq30002 12 1 this this DET 9880vq30002 12 2 work work NOUN 9880vq30002 12 3 may may AUX 9880vq30002 12 4 have have AUX 9880vq30002 12 5 also also ADV 9880vq30002 12 6 uncovered uncover VERB 9880vq30002 12 7 the the DET 9880vq30002 12 8 solubility solubility NOUN 9880vq30002 12 9 - - PUNCT 9880vq30002 12 10 limiting limit VERB 9880vq30002 12 11 phases phase NOUN 9880vq30002 12 12 of of ADP 9880vq30002 12 13 actinides actinide NOUN 9880vq30002 12 14 in in ADP 9880vq30002 12 15 some some DET 9880vq30002 12 16 repositories repository NOUN 9880vq30002 12 17 such such ADJ 9880vq30002 12 18 as as ADP 9880vq30002 12 19 the the DET 9880vq30002 12 20 waste waste NOUN 9880vq30002 12 21 isolation isolation NOUN 9880vq30002 12 22 pilot pilot NOUN 9880vq30002 12 23 plant plant NOUN 9880vq30002 12 24 ( ( PUNCT 9880vq30002 12 25 wipp wipp PROPN 9880vq30002 12 26 ) ) PUNCT 9880vq30002 12 27 , , PUNCT 9880vq30002 12 28 and and CCONJ 9880vq30002 12 29 allows allow VERB 9880vq30002 12 30 for for ADP 9880vq30002 12 31 measurements measurement NOUN 9880vq30002 12 32 on on ADP 9880vq30002 12 33 the the DET 9880vq30002 12 34 stability stability NOUN 9880vq30002 12 35 of of ADP 9880vq30002 12 36 these these DET 9880vq30002 12 37 materials material NOUN 9880vq30002 12 38 . . PUNCT 9880vq30002 13 1 the the DET 9880vq30002 13 2 core core NOUN 9880vq30002 13 3 of of ADP 9880vq30002 13 4 the the DET 9880vq30002 13 5 this this DET 9880vq30002 13 6 dissertation dissertation NOUN 9880vq30002 13 7 is be AUX 9880vq30002 13 8 focused focus VERB 9880vq30002 13 9 on on ADP 9880vq30002 13 10 the the DET 9880vq30002 13 11 crystal crystal ADJ 9880vq30002 13 12 chemistry chemistry NOUN 9880vq30002 13 13 and and CCONJ 9880vq30002 13 14 the the DET 9880vq30002 13 15 structure structure NOUN 9880vq30002 13 16 - - PUNCT 9880vq30002 13 17 property property NOUN 9880vq30002 13 18 relationship relationship NOUN 9880vq30002 13 19 of of ADP 9880vq30002 13 20 actinide actinide ADJ 9880vq30002 13 21 borates borate NOUN 9880vq30002 13 22 that that PRON 9880vq30002 13 23 derived derive VERB 9880vq30002 13 24 from from ADP 9880vq30002 13 25 the the DET 9880vq30002 13 26 molten molten ADJ 9880vq30002 13 27 boric boric ADJ 9880vq30002 13 28 acid acid NOUN 9880vq30002 13 29 flux flux NOUN 9880vq30002 13 30 reactions reaction NOUN 9880vq30002 13 31 including include VERB 9880vq30002 13 32 thorium thorium NOUN 9880vq30002 13 33 borate borate NOUN 9880vq30002 13 34 ( ( PUNCT 9880vq30002 13 35 chapter chapter NOUN 9880vq30002 13 36 3 3 NUM 9880vq30002 13 37 ) ) PUNCT 9880vq30002 13 38 , , PUNCT 9880vq30002 13 39 uranium uranium NOUN 9880vq30002 13 40 borates borate VERB 9880vq30002 13 41 ( ( PUNCT 9880vq30002 13 42 chapter chapter NOUN 9880vq30002 13 43 4 4 NUM 9880vq30002 13 44 - - SYM 9880vq30002 13 45 7,12,14 7,12,14 NUM 9880vq30002 13 46 ) ) PUNCT 9880vq30002 13 47 , , PUNCT 9880vq30002 13 48 neptunium neptunium NOUN 9880vq30002 13 49 borates borate VERB 9880vq30002 13 50 ( ( PUNCT 9880vq30002 13 51 chapter chapter NOUN 9880vq30002 13 52 9 9 NUM 9880vq30002 13 53 - - SYM 9880vq30002 13 54 14 14 NUM 9880vq30002 13 55 ) ) PUNCT 9880vq30002 13 56 , , PUNCT 9880vq30002 13 57 plutonium plutonium NOUN 9880vq30002 13 58 borates borate VERB 9880vq30002 13 59 ( ( PUNCT 9880vq30002 13 60 chapter chapter NOUN 9880vq30002 13 61 9,12,16,17 9,12,16,17 NUM 9880vq30002 13 62 ) ) PUNCT 9880vq30002 13 63 , , PUNCT 9880vq30002 13 64 americium americium PROPN 9880vq30002 13 65 borate borate NOUN 9880vq30002 13 66 ( ( PUNCT 9880vq30002 13 67 chapter chapter NOUN 9880vq30002 13 68 17 17 NUM 9880vq30002 13 69 ) ) PUNCT 9880vq30002 13 70 , , PUNCT 9880vq30002 13 71 and and CCONJ 9880vq30002 13 72 curium curium NOUN 9880vq30002 13 73 borate borate NOUN 9880vq30002 13 74 ( ( PUNCT 9880vq30002 13 75 chapter chapter NOUN 9880vq30002 13 76 18 18 NUM 9880vq30002 13 77 ) ) PUNCT 9880vq30002 13 78 . . PUNCT 9880vq30002 14 1 during during ADP 9880vq30002 14 2 the the DET 9880vq30002 14 3 course course NOUN 9880vq30002 14 4 of of ADP 9880vq30002 14 5 these these DET 9880vq30002 14 6 studies study NOUN 9880vq30002 14 7 , , PUNCT 9880vq30002 14 8 several several ADJ 9880vq30002 14 9 important important ADJ 9880vq30002 14 10 side side NOUN 9880vq30002 14 11 results result NOUN 9880vq30002 14 12 were be AUX 9880vq30002 14 13 also also ADV 9880vq30002 14 14 serendipitously serendipitously ADV 9880vq30002 14 15 discovered discover VERB 9880vq30002 14 16 . . PUNCT 9880vq30002 15 1 these these PRON 9880vq30002 15 2 includes include VERB 9880vq30002 15 3 the the DET 9880vq30002 15 4 anion anion NOUN 9880vq30002 15 5 exchange exchange NOUN 9880vq30002 15 6 studies study NOUN 9880vq30002 15 7 of of ADP 9880vq30002 15 8 ndtb-1 ndtb-1 NOUN 9880vq30002 15 9 ( ( PUNCT 9880vq30002 15 10 chapter chapter NOUN 9880vq30002 15 11 3 3 NUM 9880vq30002 15 12 ) ) PUNCT 9880vq30002 15 13 , , PUNCT 9880vq30002 15 14 studies study NOUN 9880vq30002 15 15 of of ADP 9880vq30002 15 16 iodine iodine NOUN 9880vq30002 15 17 incorporation incorporation NOUN 9880vq30002 15 18 into into ADP 9880vq30002 15 19 uranyl uranyl NOUN 9880vq30002 15 20 borates borate NOUN 9880vq30002 15 21 ( ( PUNCT 9880vq30002 15 22 chapter chapter NOUN 9880vq30002 15 23 8) 8) NUM 9880vq30002 15 24 , , PUNCT 9880vq30002 15 25 the the DET 9880vq30002 15 26 discovery discovery NOUN 9880vq30002 15 27 of of ADP 9880vq30002 15 28 new new ADJ 9880vq30002 15 29 cation cation NOUN 9880vq30002 15 30 - - PUNCT 9880vq30002 15 31 cation cation NOUN 9880vq30002 15 32 interaction interaction NOUN 9880vq30002 15 33 bonding bond VERB 9880vq30002 15 34 mode mode NOUN 9880vq30002 15 35 for for ADP 9880vq30002 15 36 np(v np(v SPACE 9880vq30002 15 37 ) ) PUNCT 9880vq30002 15 38 ( ( PUNCT 9880vq30002 15 39 chapter chapter NOUN 9880vq30002 15 40 15 15 NUM 9880vq30002 15 41 ) ) PUNCT 9880vq30002 15 42 , , PUNCT 9880vq30002 15 43 and and CCONJ 9880vq30002 15 44 investigations investigation NOUN 9880vq30002 15 45 of of ADP 9880vq30002 15 46 novel novel ADJ 9880vq30002 15 47 interstitial interstitial ADJ 9880vq30002 15 48 incorporation incorporation NOUN 9880vq30002 15 49 of of ADP 9880vq30002 15 50 actinides actinide NOUN 9880vq30002 15 51 into into ADP 9880vq30002 15 52 natural natural ADJ 9880vq30002 15 53 materials material NOUN 9880vq30002 15 54 ( ( PUNCT 9880vq30002 15 55 chapter chapter NOUN 9880vq30002 15 56 19 19 NUM 9880vq30002 15 57 ) ) PUNCT 9880vq30002 15 58 . . PUNCT