id sid tid token lemma pos b5644q79k0b 1 1 molecular molecular ADJ b5644q79k0b 1 2 quantum quantum PROPN b5644q79k0b 1 3 cellular cellular PROPN b5644q79k0b 1 4 automata automata PROPN b5644q79k0b 1 5 ( ( PUNCT b5644q79k0b 1 6 qca qca PROPN b5644q79k0b 1 7 ) ) PUNCT b5644q79k0b 1 8 is be AUX b5644q79k0b 1 9 a a DET b5644q79k0b 1 10 computing compute VERB b5644q79k0b 1 11 paradigm paradigm NOUN b5644q79k0b 1 12 that that PRON b5644q79k0b 1 13 solves solve VERB b5644q79k0b 1 14 many many ADJ b5644q79k0b 1 15 of of ADP b5644q79k0b 1 16 the the DET b5644q79k0b 1 17 problems problem NOUN b5644q79k0b 1 18 plaguing plague VERB b5644q79k0b 1 19 current current ADJ b5644q79k0b 1 20 microprocessors microprocessor NOUN b5644q79k0b 1 21 . . PUNCT b5644q79k0b 2 1 molecules molecule NOUN b5644q79k0b 2 2 suitable suitable ADJ b5644q79k0b 2 3 for for ADP b5644q79k0b 2 4 qca qca PROPN b5644q79k0b 2 5 are be AUX b5644q79k0b 2 6 generally generally ADV b5644q79k0b 2 7 mixed mixed ADJ b5644q79k0b 2 8 - - PUNCT b5644q79k0b 2 9 valent valent ADJ b5644q79k0b 2 10 and and CCONJ b5644q79k0b 2 11 organometallic organometallic ADJ b5644q79k0b 2 12 in in ADP b5644q79k0b 2 13 nature nature NOUN b5644q79k0b 2 14 . . PUNCT b5644q79k0b 3 1 the the DET b5644q79k0b 3 2 aim aim NOUN b5644q79k0b 3 3 of of ADP b5644q79k0b 3 4 this this DET b5644q79k0b 3 5 thesis thesis NOUN b5644q79k0b 3 6 is be AUX b5644q79k0b 3 7 to to PART b5644q79k0b 3 8 describe describe VERB b5644q79k0b 3 9 the the DET b5644q79k0b 3 10 synthesis synthesis NOUN b5644q79k0b 3 11 and and CCONJ b5644q79k0b 3 12 characterization characterization NOUN b5644q79k0b 3 13 of of ADP b5644q79k0b 3 14 a a DET b5644q79k0b 3 15 variety variety NOUN b5644q79k0b 3 16 of of ADP b5644q79k0b 3 17 molecules molecule NOUN b5644q79k0b 3 18 . . PUNCT b5644q79k0b 4 1 the the DET b5644q79k0b 4 2 majority majority NOUN b5644q79k0b 4 3 of of ADP b5644q79k0b 4 4 the the DET b5644q79k0b 4 5 molecules molecule NOUN b5644q79k0b 4 6 were be AUX b5644q79k0b 4 7 targeted target VERB b5644q79k0b 4 8 with with ADP b5644q79k0b 4 9 the the DET b5644q79k0b 4 10 aim aim NOUN b5644q79k0b 4 11 of of ADP b5644q79k0b 4 12 studying study VERB b5644q79k0b 4 13 their their PRON b5644q79k0b 4 14 utility utility NOUN b5644q79k0b 4 15 for for ADP b5644q79k0b 4 16 molecular molecular ADJ b5644q79k0b 4 17 qca qca PROPN b5644q79k0b 4 18 . . PUNCT b5644q79k0b 5 1 this this DET b5644q79k0b 5 2 thesis thesis NOUN b5644q79k0b 5 3 is be AUX b5644q79k0b 5 4 a a DET b5644q79k0b 5 5 portion portion NOUN b5644q79k0b 5 6 of of ADP b5644q79k0b 5 7 a a DET b5644q79k0b 5 8 larger large ADJ b5644q79k0b 5 9 collaborative collaborative ADJ b5644q79k0b 5 10 work work NOUN b5644q79k0b 5 11 that that PRON b5644q79k0b 5 12 includes include VERB b5644q79k0b 5 13 work work NOUN b5644q79k0b 5 14 from from ADP b5644q79k0b 5 15 the the DET b5644q79k0b 5 16 labs lab NOUN b5644q79k0b 5 17 of of ADP b5644q79k0b 5 18 lent lent ADJ b5644q79k0b 5 19 , , PUNCT b5644q79k0b 5 20 snider snider ADJ b5644q79k0b 5 21 , , PUNCT b5644q79k0b 5 22 kandel kandel PROPN b5644q79k0b 5 23 , , PUNCT b5644q79k0b 5 24 and and CCONJ b5644q79k0b 5 25 corcelli corcelli ADJ b5644q79k0b 5 26 at at ADP b5644q79k0b 5 27 the the DET b5644q79k0b 5 28 university university PROPN b5644q79k0b 5 29 of of ADP b5644q79k0b 5 30 notre notre PROPN b5644q79k0b 5 31 dame.the dame.the DET b5644q79k0b 5 32 introduction introduction NOUN b5644q79k0b 5 33 builds build VERB b5644q79k0b 5 34 context context NOUN b5644q79k0b 5 35 for for ADP b5644q79k0b 5 36 the the DET b5644q79k0b 5 37 majority majority NOUN b5644q79k0b 5 38 of of ADP b5644q79k0b 5 39 the the DET b5644q79k0b 5 40 work work NOUN b5644q79k0b 5 41 done do VERB b5644q79k0b 5 42 in in ADP b5644q79k0b 5 43 this this DET b5644q79k0b 5 44 dissertation dissertation NOUN b5644q79k0b 5 45 . . PUNCT b5644q79k0b 6 1 this this PRON b5644q79k0b 6 2 includes include VERB b5644q79k0b 6 3 a a DET b5644q79k0b 6 4 brief brief ADJ b5644q79k0b 6 5 introduction introduction NOUN b5644q79k0b 6 6 to to ADP b5644q79k0b 6 7 qca qca PROPN b5644q79k0b 6 8 and and CCONJ b5644q79k0b 6 9 electron electron NOUN b5644q79k0b 6 10 transfer transfer NOUN b5644q79k0b 6 11 in in ADP b5644q79k0b 6 12 molecular molecular ADJ b5644q79k0b 6 13 systems system NOUN b5644q79k0b 6 14 . . PUNCT b5644q79k0b 7 1 chapter chapter NOUN b5644q79k0b 7 2 2 2 NUM b5644q79k0b 7 3 focuses focus VERB b5644q79k0b 7 4 on on ADP b5644q79k0b 7 5 the the DET b5644q79k0b 7 6 synthesis synthesis NOUN b5644q79k0b 7 7 and and CCONJ b5644q79k0b 7 8 characterization characterization NOUN b5644q79k0b 7 9 of of ADP b5644q79k0b 7 10 a a DET b5644q79k0b 7 11 variety variety NOUN b5644q79k0b 7 12 of of ADP b5644q79k0b 7 13 substituted substitute VERB b5644q79k0b 7 14 1,2 1,2 NOUN b5644q79k0b 7 15 - - PUNCT b5644q79k0b 7 16 diferrocenylacetylenes diferrocenylacetylene NOUN b5644q79k0b 7 17 . . PUNCT b5644q79k0b 8 1 the the DET b5644q79k0b 8 2 synthesis synthesis NOUN b5644q79k0b 8 3 of of ADP b5644q79k0b 8 4 substituted substitute VERB b5644q79k0b 8 5 1,2 1,2 NUM b5644q79k0b 8 6 - - PUNCT b5644q79k0b 8 7 diferrocenylacetylenes diferrocenylacetylene NOUN b5644q79k0b 8 8 supports support VERB b5644q79k0b 8 9 two two NUM b5644q79k0b 8 10 goals goal NOUN b5644q79k0b 8 11 : : PUNCT b5644q79k0b 8 12 to to PART b5644q79k0b 8 13 study study VERB b5644q79k0b 8 14 substituent substituent NOUN b5644q79k0b 8 15 effects effect NOUN b5644q79k0b 8 16 on on ADP b5644q79k0b 8 17 electron electron NOUN b5644q79k0b 8 18 transfer transfer NOUN b5644q79k0b 8 19 and and CCONJ b5644q79k0b 8 20 redox redox ADJ b5644q79k0b 8 21 chemistry chemistry NOUN b5644q79k0b 8 22 in in ADP b5644q79k0b 8 23 the the DET b5644q79k0b 8 24 1,2 1,2 NUM b5644q79k0b 8 25 - - PUNCT b5644q79k0b 8 26 diferrocenylacetylene diferrocenylacetylene NOUN b5644q79k0b 8 27 system system NOUN b5644q79k0b 8 28 , , PUNCT b5644q79k0b 8 29 and and CCONJ b5644q79k0b 8 30 to to PART b5644q79k0b 8 31 synthesize synthesize VERB b5644q79k0b 8 32 precursors precursor NOUN b5644q79k0b 8 33 for for ADP b5644q79k0b 8 34 the the DET b5644q79k0b 8 35 preparation preparation NOUN b5644q79k0b 8 36 of of ADP b5644q79k0b 8 37 more more ADJ b5644q79k0b 8 38 complex complex ADJ b5644q79k0b 8 39 molecules molecule NOUN b5644q79k0b 8 40 found find VERB b5644q79k0b 8 41 in in ADP b5644q79k0b 8 42 later later ADV b5644q79k0b 8 43 chapters.chapter chapters.chapter PRON b5644q79k0b 8 44 3 3 NUM b5644q79k0b 8 45 focuses focus VERB b5644q79k0b 8 46 on on ADP b5644q79k0b 8 47 the the DET b5644q79k0b 8 48 synthetic synthetic ADJ b5644q79k0b 8 49 extension extension NOUN b5644q79k0b 8 50 of of ADP b5644q79k0b 8 51 substituted substitute VERB b5644q79k0b 8 52 1,2 1,2 NUM b5644q79k0b 8 53 - - PUNCT b5644q79k0b 8 54 diferrocenylacetylene diferrocenylacetylene NOUN b5644q79k0b 8 55 compounds compound NOUN b5644q79k0b 8 56 from from ADP b5644q79k0b 8 57 chapter chapter NOUN b5644q79k0b 8 58 2 2 NUM b5644q79k0b 8 59 to to ADP b5644q79k0b 8 60 square square ADJ b5644q79k0b 8 61 planar planar ADJ b5644q79k0b 8 62 tetraferrocenyl tetraferrocenyl NOUN b5644q79k0b 8 63 compounds compound NOUN b5644q79k0b 8 64 . . PUNCT b5644q79k0b 9 1 this this PRON b5644q79k0b 9 2 supports support VERB b5644q79k0b 9 3 two two NUM b5644q79k0b 9 4 goals goal NOUN b5644q79k0b 9 5 : : PUNCT b5644q79k0b 9 6 incorporating incorporate VERB b5644q79k0b 9 7 functionality functionality NOUN b5644q79k0b 9 8 that that PRON b5644q79k0b 9 9 allows allow VERB b5644q79k0b 9 10 for for ADP b5644q79k0b 9 11 the the DET b5644q79k0b 9 12 exploration exploration NOUN b5644q79k0b 9 13 of of ADP b5644q79k0b 9 14 supramolecular supramolecular ADJ b5644q79k0b 9 15 interactions interaction NOUN b5644q79k0b 9 16 on on ADP b5644q79k0b 9 17 surfaces surface NOUN b5644q79k0b 9 18 with with ADP b5644q79k0b 9 19 our our PRON b5644q79k0b 9 20 scanning scan VERB b5644q79k0b 9 21 tunneling tunneling NOUN b5644q79k0b 9 22 microscopy microscopy NOUN b5644q79k0b 9 23 ( ( PUNCT b5644q79k0b 9 24 stm stm NOUN b5644q79k0b 9 25 ) ) PUNCT b5644q79k0b 9 26 collaborators collaborator NOUN b5644q79k0b 9 27 , , PUNCT b5644q79k0b 9 28 and and CCONJ b5644q79k0b 9 29 incorporating incorporate VERB b5644q79k0b 9 30 functionality functionality NOUN b5644q79k0b 9 31 to to PART b5644q79k0b 9 32 prevent prevent VERB b5644q79k0b 9 33 thermal thermal ADJ b5644q79k0b 9 34 motion motion NOUN b5644q79k0b 9 35 during during ADP b5644q79k0b 9 36 stm stm NOUN b5644q79k0b 9 37 imaging.chapter imaging.chapt ADJ b5644q79k0b 9 38 4 4 NUM b5644q79k0b 9 39 focuses focus VERB b5644q79k0b 9 40 on on ADP b5644q79k0b 9 41 the the DET b5644q79k0b 9 42 synthesis synthesis NOUN b5644q79k0b 9 43 , , PUNCT b5644q79k0b 9 44 oxidation oxidation NOUN b5644q79k0b 9 45 , , PUNCT b5644q79k0b 9 46 and and CCONJ b5644q79k0b 9 47 characterization characterization NOUN b5644q79k0b 9 48 of of ADP b5644q79k0b 9 49 a a DET b5644q79k0b 9 50 series series NOUN b5644q79k0b 9 51 of of ADP b5644q79k0b 9 52 ferrocene ferrocene PROPN b5644q79k0b 9 53 substituted substitute VERB b5644q79k0b 9 54 carboranes carborane NOUN b5644q79k0b 9 55 . . PUNCT b5644q79k0b 10 1 emphasis emphasis NOUN b5644q79k0b 10 2 is be AUX b5644q79k0b 10 3 placed place VERB b5644q79k0b 10 4 on on ADP b5644q79k0b 10 5 the the DET b5644q79k0b 10 6 characterization characterization NOUN b5644q79k0b 10 7 of of ADP b5644q79k0b 10 8 electron electron NOUN b5644q79k0b 10 9 transfer transfer NOUN b5644q79k0b 10 10 within within ADP b5644q79k0b 10 11 7 7 NUM b5644q79k0b 10 12 - - PUNCT b5644q79k0b 10 13 fc-8 fc-8 SPACE b5644q79k0b 10 14 - - PUNCT b5644q79k0b 10 15 fc+-7,8 fc+-7,8 NOUN b5644q79k0b 10 16 - - PUNCT b5644q79k0b 10 17 nido-[c2b9h10­­­](4.3 nido-[c2b9h10­­­](4.3 PROPN b5644q79k0b 10 18 ) ) PUNCT b5644q79k0b 10 19 , , PUNCT b5644q79k0b 10 20 which which PRON b5644q79k0b 10 21 is be AUX b5644q79k0b 10 22 found find VERB b5644q79k0b 10 23 to to PART b5644q79k0b 10 24 be be AUX b5644q79k0b 10 25 bridge bridge NOUN b5644q79k0b 10 26 mediated.chapter mediated.chapter PROPN b5644q79k0b 10 27 5 5 NUM b5644q79k0b 10 28 focuses focus VERB b5644q79k0b 10 29 on on ADP b5644q79k0b 10 30 the the DET b5644q79k0b 10 31 synthesis synthesis NOUN b5644q79k0b 10 32 and and CCONJ b5644q79k0b 10 33 structural structural ADJ b5644q79k0b 10 34 characterization characterization NOUN b5644q79k0b 10 35 of of ADP b5644q79k0b 10 36 1,2 1,2 NUM b5644q79k0b 10 37 - - PUNCT b5644q79k0b 10 38 fc-1,2 fc-1,2 ADJ b5644q79k0b 10 39 - - PUNCT b5644q79k0b 10 40 closo closo NOUN b5644q79k0b 10 41 - - PUNCT b5644q79k0b 10 42 c2b10h10 c2b10h10 PROPN b5644q79k0b 10 43 ( ( PUNCT b5644q79k0b 10 44 5.1 5.1 NUM b5644q79k0b 10 45 ) ) PUNCT b5644q79k0b 10 46 . . PUNCT b5644q79k0b 11 1 the the DET b5644q79k0b 11 2 compound compound NOUN b5644q79k0b 11 3 is be AUX b5644q79k0b 11 4 also also ADV b5644q79k0b 11 5 explored explore VERB b5644q79k0b 11 6 computationally computationally ADV b5644q79k0b 11 7 . . PUNCT b5644q79k0b 12 1 possible possible ADJ b5644q79k0b 12 2 synthetic synthetic ADJ b5644q79k0b 12 3 routes route NOUN b5644q79k0b 12 4 are be AUX b5644q79k0b 12 5 discussed discuss VERB b5644q79k0b 12 6 in in ADP b5644q79k0b 12 7 the the DET b5644q79k0b 12 8 future future ADJ b5644q79k0b 12 9 work work NOUN b5644q79k0b 12 10 section section NOUN b5644q79k0b 12 11 with with ADP b5644q79k0b 12 12 the the DET b5644q79k0b 12 13 intent intent NOUN b5644q79k0b 12 14 of of ADP b5644q79k0b 12 15 creating create VERB b5644q79k0b 12 16 alternate alternate ADJ b5644q79k0b 12 17 metal metal NOUN b5644q79k0b 12 18 analogues analogue NOUN b5644q79k0b 12 19 of of ADP b5644q79k0b 12 20 this this DET b5644q79k0b 12 21 interesting interesting ADJ b5644q79k0b 12 22 compound.chapter compound.chapter NOUN b5644q79k0b 12 23 6 6 NUM b5644q79k0b 12 24 is be AUX b5644q79k0b 12 25 from from ADP b5644q79k0b 12 26 an an DET b5644q79k0b 12 27 earlier early ADJ b5644q79k0b 12 28 , , PUNCT b5644q79k0b 12 29 unrelated unrelated ADJ b5644q79k0b 12 30 project project NOUN b5644q79k0b 12 31 . . PUNCT b5644q79k0b 13 1 the the DET b5644q79k0b 13 2 focus focus NOUN b5644q79k0b 13 3 of of ADP b5644q79k0b 13 4 chapter chapter NOUN b5644q79k0b 13 5 6 6 NUM b5644q79k0b 13 6 is be AUX b5644q79k0b 13 7 the the DET b5644q79k0b 13 8 synthesis synthesis NOUN b5644q79k0b 13 9 of of ADP b5644q79k0b 13 10 imidazolium imidazolium NOUN b5644q79k0b 13 11 - - PUNCT b5644q79k0b 13 12 containing contain VERB b5644q79k0b 13 13 metal metal NOUN b5644q79k0b 13 14 organic organic ADJ b5644q79k0b 13 15 frameworks framework NOUN b5644q79k0b 13 16 with with ADP b5644q79k0b 13 17 the the DET b5644q79k0b 13 18 end end NOUN b5644q79k0b 13 19 goal goal NOUN b5644q79k0b 13 20 of of ADP b5644q79k0b 13 21 utilizing utilize VERB b5644q79k0b 13 22 these these DET b5644q79k0b 13 23 materials material NOUN b5644q79k0b 13 24 for for ADP b5644q79k0b 13 25 gas gas NOUN b5644q79k0b 13 26 separation separation NOUN b5644q79k0b 13 27 , , PUNCT b5644q79k0b 13 28 specifically specifically ADV b5644q79k0b 13 29 , , PUNCT b5644q79k0b 13 30 co2 co2 NOUN b5644q79k0b 13 31 from from ADP b5644q79k0b 13 32 n2 n2 PROPN b5644q79k0b 13 33 . . PUNCT b5644q79k0b 14 1 the the DET b5644q79k0b 14 2 work work NOUN b5644q79k0b 14 3 outlined outline VERB b5644q79k0b 14 4 in in ADP b5644q79k0b 14 5 this this DET b5644q79k0b 14 6 chapter chapter NOUN b5644q79k0b 14 7 is be AUX b5644q79k0b 14 8 incomplete incomplete ADJ b5644q79k0b 14 9 due due ADP b5644q79k0b 14 10 to to ADP b5644q79k0b 14 11 a a DET b5644q79k0b 14 12 change change NOUN b5644q79k0b 14 13 in in ADP b5644q79k0b 14 14 project project NOUN b5644q79k0b 14 15 focus focus NOUN b5644q79k0b 14 16 . . PUNCT