id	sid	tid	token	lemma	pos
bk128912n2h	1	1	the	the	DET
bk128912n2h	1	2	primary	primary	ADJ
bk128912n2h	1	3	focus	focus	NOUN
bk128912n2h	1	4	of	of	ADP
bk128912n2h	1	5	this	this	DET
bk128912n2h	1	6	dissertation	dissertation	NOUN
bk128912n2h	1	7	is	be	AUX
bk128912n2h	1	8	the	the	DET
bk128912n2h	1	9	development	development	NOUN
bk128912n2h	1	10	of	of	ADP
bk128912n2h	1	11	the	the	DET
bk128912n2h	1	12	chemistry	chemistry	NOUN
bk128912n2h	1	13	of	of	ADP
bk128912n2h	1	14	organo	organo	NOUN
bk128912n2h	1	15	-	-	PUNCT
bk128912n2h	1	16	zintl	zintl	PROPN
bk128912n2h	1	17	clusters	cluster	NOUN
bk128912n2h	1	18	.	.	PUNCT
bk128912n2h	2	1	the	the	DET
bk128912n2h	2	2	goal	goal	NOUN
bk128912n2h	2	3	of	of	ADP
bk128912n2h	2	4	the	the	DET
bk128912n2h	2	5	project	project	NOUN
bk128912n2h	2	6	was	be	AUX
bk128912n2h	2	7	to	to	PART
bk128912n2h	2	8	put	put	VERB
bk128912n2h	2	9	into	into	ADP
bk128912n2h	2	10	place	place	NOUN
bk128912n2h	2	11	the	the	DET
bk128912n2h	2	12	necessary	necessary	ADJ
bk128912n2h	2	13	building	building	NOUN
bk128912n2h	2	14	blocks	block	NOUN
bk128912n2h	2	15	so	so	SCONJ
bk128912n2h	2	16	as	as	SCONJ
bk128912n2h	2	17	to	to	PART
bk128912n2h	2	18	bring	bring	VERB
bk128912n2h	2	19	germanium	germanium	NOUN
bk128912n2h	2	20	deltahedral	deltahedral	ADJ
bk128912n2h	2	21	clusters	cluster	NOUN
bk128912n2h	2	22	inline	inline	VERB
bk128912n2h	2	23	with	with	ADP
bk128912n2h	2	24	mainstream	mainstream	ADJ
bk128912n2h	2	25	organic	organic	ADJ
bk128912n2h	2	26	chemistry	chemistry	NOUN
bk128912n2h	2	27	.	.	PUNCT
bk128912n2h	3	1	in	in	ADP
bk128912n2h	3	2	order	order	NOUN
bk128912n2h	3	3	to	to	PART
bk128912n2h	3	4	accomplish	accomplish	VERB
bk128912n2h	3	5	this	this	PRON
bk128912n2h	3	6	,	,	PUNCT
bk128912n2h	3	7	it	it	PRON
bk128912n2h	3	8	was	be	AUX
bk128912n2h	3	9	necessary	necessary	ADJ
bk128912n2h	3	10	to	to	PART
bk128912n2h	3	11	achieve	achieve	VERB
bk128912n2h	3	12	a	a	DET
bk128912n2h	3	13	number	number	NOUN
bk128912n2h	3	14	of	of	ADP
bk128912n2h	3	15	phases	phase	NOUN
bk128912n2h	3	16	of	of	ADP
bk128912n2h	3	17	progression	progression	NOUN
bk128912n2h	3	18	,	,	PUNCT
bk128912n2h	3	19	namely	namely	ADV
bk128912n2h	3	20	:	:	PUNCT
bk128912n2h	3	21	(	(	PUNCT
bk128912n2h	3	22	a	a	X
bk128912n2h	3	23	)	)	PUNCT
bk128912n2h	3	24	develop	develop	VERB
bk128912n2h	3	25	techniques	technique	NOUN
bk128912n2h	3	26	for	for	ADP
bk128912n2h	3	27	synthesizing	synthesize	VERB
bk128912n2h	3	28	organo	organo	NOUN
bk128912n2h	3	29	-	-	PUNCT
bk128912n2h	3	30	zintl	zintl	PROPN
bk128912n2h	3	31	clusters	cluster	NOUN
bk128912n2h	3	32	,	,	PUNCT
bk128912n2h	3	33	(	(	PUNCT
bk128912n2h	3	34	b	b	X
bk128912n2h	3	35	)	)	PUNCT
bk128912n2h	3	36	carry	carry	VERB
bk128912n2h	3	37	out	out	ADP
bk128912n2h	3	38	subsequent	subsequent	ADJ
bk128912n2h	3	39	mechanistic	mechanistic	ADJ
bk128912n2h	3	40	investigations	investigation	NOUN
bk128912n2h	3	41	,	,	PUNCT
bk128912n2h	3	42	(	(	PUNCT
bk128912n2h	3	43	c	c	X
bk128912n2h	3	44	)	)	PUNCT
bk128912n2h	3	45	modify	modify	VERB
bk128912n2h	3	46	the	the	DET
bk128912n2h	3	47	solubility	solubility	NOUN
bk128912n2h	3	48	properties	property	NOUN
bk128912n2h	3	49	of	of	ADP
bk128912n2h	3	50	the	the	DET
bk128912n2h	3	51	clusters	cluster	NOUN
bk128912n2h	3	52	,	,	PUNCT
bk128912n2h	3	53	(	(	PUNCT
bk128912n2h	3	54	d	d	NOUN
bk128912n2h	3	55	)	)	PUNCT
bk128912n2h	3	56	increase	increase	VERB
bk128912n2h	3	57	the	the	DET
bk128912n2h	3	58	clusters	cluster	NOUN
bk128912n2h	3	59	's	's	PART
bk128912n2h	3	60	compatibility	compatibility	NOUN
bk128912n2h	3	61	with	with	ADP
bk128912n2h	3	62	reaction	reaction	NOUN
bk128912n2h	3	63	conditions	condition	NOUN
bk128912n2h	3	64	for	for	ADP
bk128912n2h	3	65	organic	organic	ADJ
bk128912n2h	3	66	transformations	transformation	NOUN
bk128912n2h	3	67	,	,	PUNCT
bk128912n2h	3	68	and	and	CCONJ
bk128912n2h	3	69	(	(	PUNCT
bk128912n2h	3	70	e	e	NOUN
bk128912n2h	3	71	)	)	PUNCT
bk128912n2h	3	72	carry	carry	VERB
bk128912n2h	3	73	out	out	ADP
bk128912n2h	3	74	broad	broad	ADJ
bk128912n2h	3	75	investigations	investigation	NOUN
bk128912n2h	3	76	into	into	ADP
bk128912n2h	3	77	their	their	PRON
bk128912n2h	3	78	reactivity	reactivity	NOUN
bk128912n2h	3	79	.	.	PUNCT
bk128912n2h	4	1	each	each	PRON
bk128912n2h	4	2	of	of	ADP
bk128912n2h	4	3	these	these	DET
bk128912n2h	4	4	segments	segment	NOUN
bk128912n2h	4	5	have	have	AUX
bk128912n2h	4	6	been	be	AUX
bk128912n2h	4	7	dealt	deal	VERB
bk128912n2h	4	8	with	with	ADP
bk128912n2h	4	9	in	in	ADP
bk128912n2h	4	10	turn	turn	NOUN
bk128912n2h	4	11	.	.	PUNCT
bk128912n2h	5	1	after	after	ADP
bk128912n2h	5	2	introducing	introduce	VERB
bk128912n2h	5	3	the	the	DET
bk128912n2h	5	4	foundations	foundation	NOUN
bk128912n2h	5	5	of	of	ADP
bk128912n2h	5	6	zintl	zintl	PROPN
bk128912n2h	5	7	chemistry	chemistry	NOUN
bk128912n2h	5	8	(	(	PUNCT
bk128912n2h	5	9	chapter	chapter	NOUN
bk128912n2h	5	10	1	1	NUM
bk128912n2h	5	11	)	)	PUNCT
bk128912n2h	5	12	,	,	PUNCT
bk128912n2h	5	13	the	the	DET
bk128912n2h	5	14	first	first	ADJ
bk128912n2h	5	15	method	method	NOUN
bk128912n2h	5	16	for	for	ADP
bk128912n2h	5	17	synthesizing	synthesize	VERB
bk128912n2h	5	18	organo	organo	NOUN
bk128912n2h	5	19	-	-	PUNCT
bk128912n2h	5	20	zintl	zintl	NOUN
bk128912n2h	5	21	clusters	cluster	NOUN
bk128912n2h	5	22	is	be	AUX
bk128912n2h	5	23	discussed	discuss	VERB
bk128912n2h	5	24	,	,	PUNCT
bk128912n2h	5	25	namely	namely	ADV
bk128912n2h	5	26	the	the	DET
bk128912n2h	5	27	'	'	PUNCT
bk128912n2h	5	28	halide	halide	NOUN
bk128912n2h	5	29	'	'	PUNCT
bk128912n2h	5	30	route	route	NOUN
bk128912n2h	5	31	(	(	PUNCT
bk128912n2h	5	32	chapter	chapter	NOUN
bk128912n2h	5	33	2	2	NUM
bk128912n2h	5	34	)	)	PUNCT
bk128912n2h	5	35	.	.	PUNCT
bk128912n2h	6	1	this	this	DET
bk128912n2h	6	2	technique	technique	NOUN
bk128912n2h	6	3	allows	allow	VERB
bk128912n2h	6	4	organo	organo	NOUN
bk128912n2h	6	5	-	-	PUNCT
bk128912n2h	6	6	zintl	zintl	NOUN
bk128912n2h	6	7	clusters	cluster	NOUN
bk128912n2h	6	8	to	to	PART
bk128912n2h	6	9	be	be	AUX
bk128912n2h	6	10	synthesized	synthesize	VERB
bk128912n2h	6	11	by	by	ADP
bk128912n2h	6	12	reacting	react	VERB
bk128912n2h	6	13	naked	naked	ADJ
bk128912n2h	6	14	ge94clusters	ge94cluster	NOUN
bk128912n2h	6	15	with	with	ADP
bk128912n2h	6	16	r	r	NOUN
bk128912n2h	6	17	-	-	PUNCT
bk128912n2h	6	18	x	x	NOUN
bk128912n2h	6	19	substrates	substrate	NOUN
bk128912n2h	6	20	to	to	PART
bk128912n2h	6	21	form	form	VERB
bk128912n2h	6	22	[	[	PUNCT
bk128912n2h	6	23	ge9	ge9	NOUN
bk128912n2h	6	24	-	-	PUNCT
bk128912n2h	6	25	r]3-	r]3-	PROPN
bk128912n2h	6	26	,	,	PUNCT
bk128912n2h	6	27	[	[	X
bk128912n2h	6	28	r	r	NOUN
bk128912n2h	6	29	-	-	PUNCT
bk128912n2h	6	30	ge9	ge9	NOUN
bk128912n2h	6	31	-	-	PUNCT
bk128912n2h	6	32	r]2-	r]2-	NOUN
bk128912n2h	6	33	,	,	PUNCT
bk128912n2h	6	34	and	and	CCONJ
bk128912n2h	6	35	[	[	X
bk128912n2h	6	36	r	r	NOUN
bk128912n2h	6	37	-	-	PUNCT
bk128912n2h	6	38	ge9	ge9	NOUN
bk128912n2h	6	39	-	-	PUNCT
bk128912n2h	6	40	ge9	ge9	NOUN
bk128912n2h	6	41	-	-	PUNCT
bk128912n2h	6	42	r]4-	r]4-	PROPN
bk128912n2h	6	43	.	.	PUNCT
bk128912n2h	6	44	investigations	investigation	NOUN
bk128912n2h	6	45	show	show	VERB
bk128912n2h	6	46	this	this	DET
bk128912n2h	6	47	route	route	NOUN
bk128912n2h	6	48	to	to	PART
bk128912n2h	6	49	be	be	AUX
bk128912n2h	6	50	general	general	ADJ
bk128912n2h	6	51	,	,	PUNCT
bk128912n2h	6	52	and	and	CCONJ
bk128912n2h	6	53	applicable	applicable	ADJ
bk128912n2h	6	54	to	to	ADP
bk128912n2h	6	55	primary	primary	ADJ
bk128912n2h	6	56	,	,	PUNCT
bk128912n2h	6	57	secondary	secondary	ADJ
bk128912n2h	6	58	,	,	PUNCT
bk128912n2h	6	59	and	and	CCONJ
bk128912n2h	6	60	tertiary	tertiary	ADJ
bk128912n2h	6	61	carbon	carbon	NOUN
bk128912n2h	6	62	centers	center	NOUN
bk128912n2h	6	63	.	.	PUNCT
bk128912n2h	7	1	moreover	moreover	ADV
bk128912n2h	7	2	,	,	PUNCT
bk128912n2h	7	3	it	it	PRON
bk128912n2h	7	4	is	be	AUX
bk128912n2h	7	5	independent	independent	ADJ
bk128912n2h	7	6	of	of	ADP
bk128912n2h	7	7	steric	steric	ADJ
bk128912n2h	7	8	bulk	bulk	NOUN
bk128912n2h	7	9	,	,	PUNCT
bk128912n2h	7	10	as	as	SCONJ
bk128912n2h	7	11	evidenced	evidence	VERB
bk128912n2h	7	12	by	by	ADP
bk128912n2h	7	13	the	the	DET
bk128912n2h	7	14	characterization	characterization	NOUN
bk128912n2h	7	15	of	of	ADP
bk128912n2h	7	16	[	[	X
bk128912n2h	7	17	ge9	ge9	NOUN
bk128912n2h	7	18	-	-	PUNCT
bk128912n2h	7	19	c10h15]3from	c10h15]3from	NUM
bk128912n2h	7	20	reactions	reaction	NOUN
bk128912n2h	7	21	with	with	ADP
bk128912n2h	7	22	the	the	DET
bk128912n2h	7	23	bulky	bulky	ADJ
bk128912n2h	7	24	,	,	PUNCT
bk128912n2h	7	25	tertiary	tertiary	ADJ
bk128912n2h	7	26	bromoadamantane	bromoadamantane	NOUN
bk128912n2h	7	27	.	.	PUNCT
bk128912n2h	8	1	the	the	DET
bk128912n2h	8	2	second	second	ADJ
bk128912n2h	8	3	method	method	NOUN
bk128912n2h	8	4	for	for	ADP
bk128912n2h	8	5	synthesizing	synthesize	VERB
bk128912n2h	8	6	organo	organo	NOUN
bk128912n2h	8	7	-	-	PUNCT
bk128912n2h	8	8	zintl	zintl	PROPN
bk128912n2h	8	9	clusters	cluster	NOUN
bk128912n2h	8	10	,	,	PUNCT
bk128912n2h	8	11	the	the	DET
bk128912n2h	8	12	'	'	PUNCT
bk128912n2h	8	13	alkyne	alkyne	PROPN
bk128912n2h	8	14	'	'	PUNCT
bk128912n2h	8	15	route	route	NOUN
bk128912n2h	8	16	,	,	PUNCT
bk128912n2h	8	17	is	be	AUX
bk128912n2h	8	18	discussed	discuss	VERB
bk128912n2h	8	19	in	in	ADP
bk128912n2h	8	20	chapter	chapter	NOUN
bk128912n2h	8	21	3	3	NUM
bk128912n2h	8	22	.	.	PUNCT
bk128912n2h	9	1	reactions	reaction	NOUN
bk128912n2h	9	2	between	between	ADP
bk128912n2h	9	3	ge94and	ge94and	NOUN
bk128912n2h	9	4	both	both	CCONJ
bk128912n2h	9	5	terminal	terminal	ADJ
bk128912n2h	9	6	and	and	CCONJ
bk128912n2h	9	7	internal	internal	PROPN
bk128912n2h	9	8	alkynes	alkynes	PROPN
bk128912n2h	9	9	(	(	PUNCT
bk128912n2h	9	10	r	r	NOUN
bk128912n2h	9	11	-	-	PUNCT
bk128912n2h	9	12	cì¢'¡åác	cì¢'¡åác	NOUN
bk128912n2h	9	13	-	-	PUNCT
bk128912n2h	9	14	h	h	PROPN
bk128912n2h	9	15	and	and	CCONJ
bk128912n2h	9	16	r	r	NOUN
bk128912n2h	9	17	-	-	PUNCT
bk128912n2h	9	18	cì¢'¡åác	cì¢'¡åác	NOUN
bk128912n2h	9	19	-	-	PUNCT
bk128912n2h	9	20	r	r	NOUN
bk128912n2h	9	21	'	'	NOUN
bk128912n2h	9	22	)	)	PUNCT
bk128912n2h	9	23	result	result	NOUN
bk128912n2h	9	24	in	in	ADP
bk128912n2h	9	25	the	the	DET
bk128912n2h	9	26	addition	addition	NOUN
bk128912n2h	9	27	to	to	ADP
bk128912n2h	9	28	the	the	DET
bk128912n2h	9	29	clusters	cluster	NOUN
bk128912n2h	9	30	and	and	CCONJ
bk128912n2h	9	31	hydrogenation	hydrogenation	NOUN
bk128912n2h	9	32	of	of	ADP
bk128912n2h	9	33	the	the	DET
bk128912n2h	9	34	parent	parent	NOUN
bk128912n2h	9	35	alkyne	alkyne	NOUN
bk128912n2h	9	36	to	to	PART
bk128912n2h	9	37	form	form	VERB
bk128912n2h	9	38	alkenylated	alkenylated	ADJ
bk128912n2h	9	39	clusters	cluster	NOUN
bk128912n2h	9	40	,	,	PUNCT
bk128912n2h	9	41	[	[	X
bk128912n2h	9	42	ge9	ge9	X
bk128912n2h	9	43	-	-	PUNCT
bk128912n2h	9	44	cr'=ch	cr'=ch	PROPN
bk128912n2h	9	45	-	-	PUNCT
bk128912n2h	9	46	r]3and	r]3and	CCONJ
bk128912n2h	9	47	[	[	X
bk128912n2h	9	48	ge9-(cr'=ch	ge9-(cr'=ch	PROPN
bk128912n2h	9	49	-	-	PUNCT
bk128912n2h	9	50	r)2]2(where	r)2]2(where	VERB
bk128912n2h	9	51	r	r	NOUN
bk128912n2h	9	52	'	'	PUNCT
bk128912n2h	9	53	=	=	NOUN
bk128912n2h	9	54	h	h	NOUN
bk128912n2h	9	55	or	or	CCONJ
bk128912n2h	9	56	any	any	DET
bk128912n2h	9	57	r	r	NOUN
bk128912n2h	9	58	group	group	NOUN
bk128912n2h	9	59	)	)	PUNCT
bk128912n2h	9	60	.	.	PUNCT
bk128912n2h	10	1	the	the	DET
bk128912n2h	10	2	organo	organo	NOUN
bk128912n2h	10	3	-	-	PUNCT
bk128912n2h	10	4	zintl	zintl	NOUN
bk128912n2h	10	5	and	and	CCONJ
bk128912n2h	10	6	organometallic	organometallic	ADJ
bk128912n2h	10	7	-	-	PUNCT
bk128912n2h	10	8	organo	organo	NOUN
bk128912n2h	10	9	-	-	PUNCT
bk128912n2h	10	10	zintl	zintl	NOUN
bk128912n2h	10	11	species	specie	NOUN
bk128912n2h	10	12	,	,	PUNCT
bk128912n2h	10	13	[	[	X
bk128912n2h	10	14	ge9	ge9	NOUN
bk128912n2h	10	15	-	-	PUNCT
bk128912n2h	10	16	ch	ch	NOUN
bk128912n2h	10	17	=	=	SYM
bk128912n2h	10	18	ch	ch	PROPN
bk128912n2h	10	19	-	-	PUNCT
bk128912n2h	10	20	ph	ph	NOUN
bk128912n2h	10	21	-	-	PUNCT
bk128912n2h	10	22	ome]3and	ome]3and	NOUN
bk128912n2h	10	23	[	[	X
bk128912n2h	10	24	ge9-(ch	ge9-(ch	NOUN
bk128912n2h	10	25	=	=	NOUN
bk128912n2h	10	26	ch	ch	PROPN
bk128912n2h	10	27	-	-	PUNCT
bk128912n2h	10	28	fc)2]2(fc	fc)2]2(fc	NOUN
bk128912n2h	10	29	=	=	PUNCT
bk128912n2h	10	30	ferrocenyl	ferrocenyl	ADJ
bk128912n2h	10	31	)	)	PUNCT
bk128912n2h	10	32	respectively	respectively	ADV
bk128912n2h	10	33	,	,	PUNCT
bk128912n2h	10	34	where	where	SCONJ
bk128912n2h	10	35	structurally	structurally	ADV
bk128912n2h	10	36	characterized	characterize	VERB
bk128912n2h	10	37	by	by	ADP
bk128912n2h	10	38	x	x	NOUN
bk128912n2h	10	39	-	-	NOUN
bk128912n2h	10	40	ray	ray	NOUN
bk128912n2h	10	41	diffraction	diffraction	NOUN
bk128912n2h	10	42	,	,	PUNCT
bk128912n2h	10	43	along	along	ADP
bk128912n2h	10	44	with	with	ADP
bk128912n2h	10	45	reactions	reaction	NOUN
bk128912n2h	10	46	with	with	ADP
bk128912n2h	10	47	a	a	DET
bk128912n2h	10	48	variety	variety	NOUN
bk128912n2h	10	49	of	of	ADP
bk128912n2h	10	50	internal	internal	ADJ
bk128912n2h	10	51	and	and	CCONJ
bk128912n2h	10	52	terminal	terminal	ADJ
bk128912n2h	10	53	alkynes	alkyne	NOUN
bk128912n2h	10	54	by	by	ADP
bk128912n2h	10	55	mass	mass	ADJ
bk128912n2h	10	56	spectrometry	spectrometry	NOUN
bk128912n2h	10	57	.	.	PUNCT
bk128912n2h	11	1	zintl	zintl	PROPN
bk128912n2h	11	2	clusters	cluster	NOUN
bk128912n2h	11	3	in	in	ADP
bk128912n2h	11	4	general	general	ADJ
bk128912n2h	11	5	are	be	AUX
bk128912n2h	11	6	only	only	ADV
bk128912n2h	11	7	soluble	soluble	ADJ
bk128912n2h	11	8	in	in	ADP
bk128912n2h	11	9	a	a	DET
bk128912n2h	11	10	limited	limited	ADJ
bk128912n2h	11	11	number	number	NOUN
bk128912n2h	11	12	of	of	ADP
bk128912n2h	11	13	non	non	ADJ
bk128912n2h	11	14	-	-	ADJ
bk128912n2h	11	15	traditional	traditional	ADJ
bk128912n2h	11	16	solvents	solvent	NOUN
bk128912n2h	11	17	such	such	ADJ
bk128912n2h	11	18	as	as	ADP
bk128912n2h	11	19	ethylenediamine	ethylenediamine	NOUN
bk128912n2h	11	20	and	and	CCONJ
bk128912n2h	11	21	liquid	liquid	ADJ
bk128912n2h	11	22	ammonia	ammonia	NOUN
bk128912n2h	11	23	,	,	PUNCT
bk128912n2h	11	24	and	and	CCONJ
bk128912n2h	11	25	occasionally	occasionally	ADV
bk128912n2h	11	26	dimethylformamide	dimethylformamide	VERB
bk128912n2h	11	27	.	.	PUNCT
bk128912n2h	12	1	the	the	DET
bk128912n2h	12	2	results	result	NOUN
bk128912n2h	12	3	presented	present	VERB
bk128912n2h	12	4	in	in	ADP
bk128912n2h	12	5	chapter	chapter	NOUN
bk128912n2h	12	6	4	4	NUM
bk128912n2h	12	7	demonstrate	demonstrate	VERB
bk128912n2h	12	8	that	that	SCONJ
bk128912n2h	12	9	the	the	DET
bk128912n2h	12	10	alkali	alkali	ADJ
bk128912n2h	12	11	metal	metal	NOUN
bk128912n2h	12	12	cation	cation	NOUN
bk128912n2h	12	13	(	(	PUNCT
bk128912n2h	12	14	normally	normally	ADV
bk128912n2h	12	15	k+	k+	ADP
bk128912n2h	12	16	)	)	PUNCT
bk128912n2h	12	17	of	of	ADP
bk128912n2h	12	18	organo	organo	NOUN
bk128912n2h	12	19	-	-	PUNCT
bk128912n2h	12	20	zintl	zintl	NOUN
bk128912n2h	12	21	clusters	cluster	NOUN
bk128912n2h	12	22	can	can	AUX
bk128912n2h	12	23	be	be	AUX
bk128912n2h	12	24	exchanged	exchange	VERB
bk128912n2h	12	25	for	for	ADP
bk128912n2h	12	26	quaternary	quaternary	ADJ
bk128912n2h	12	27	ammonium	ammonium	NOUN
bk128912n2h	12	28	cations	cation	NOUN
bk128912n2h	12	29	,	,	PUNCT
bk128912n2h	12	30	r4n+	r4n+	PROPN
bk128912n2h	12	31	.	.	PUNCT
bk128912n2h	13	1	three	three	NUM
bk128912n2h	13	2	cation	cation	NOUN
bk128912n2h	13	3	exchanged	exchange	VERB
bk128912n2h	13	4	organo	organo	NOUN
bk128912n2h	13	5	-	-	PUNCT
bk128912n2h	13	6	zintl	zintl	NOUN
bk128912n2h	13	7	salts	salt	NOUN
bk128912n2h	13	8	were	be	AUX
bk128912n2h	13	9	structurally	structurally	ADV
bk128912n2h	13	10	characterized	characterize	VERB
bk128912n2h	13	11	by	by	ADP
bk128912n2h	13	12	x	x	NOUN
bk128912n2h	13	13	-	-	NOUN
bk128912n2h	13	14	ray	ray	NOUN
bk128912n2h	13	15	diffraction	diffraction	NOUN
bk128912n2h	13	16	:	:	PUNCT
bk128912n2h	14	1	[	[	X
bk128912n2h	14	2	me4n]2[ge9-(ch	me4n]2[ge9-(ch	NOUN
bk128912n2h	14	3	=	=	X
bk128912n2h	14	4	ch2)2]ì¢	ch2)2]ì¢	NOUN
bk128912n2h	14	5	ââå¢0.5en	ââå¢0.5en	PROPN
bk128912n2h	14	6	,	,	PUNCT
bk128912n2h	14	7	[	[	PUNCT
bk128912n2h	14	8	et4n]2[ge9-(ch	et4n]2[ge9-(ch	PROPN
bk128912n2h	14	9	=	=	NOUN
bk128912n2h	14	10	ch2)2	ch2)2	VERB
bk128912n2h	14	11	]	]	X
bk128912n2h	14	12	,	,	PUNCT
bk128912n2h	14	13	and	and	CCONJ
bk128912n2h	14	14	[	[	X
bk128912n2h	14	15	pr4n]2[ge9-(ch	pr4n]2[ge9-(ch	NOUN
bk128912n2h	14	16	=	=	NOUN
bk128912n2h	14	17	ch2)2	ch2)2	VERB
bk128912n2h	14	18	]	]	X
bk128912n2h	14	19	,	,	PUNCT
bk128912n2h	14	20	where	where	SCONJ
bk128912n2h	14	21	[	[	PUNCT
bk128912n2h	14	22	ge9-(ch	ge9-(ch	NOUN
bk128912n2h	14	23	=	=	NOUN
bk128912n2h	14	24	ch2)2]2is	ch2)2]2is	NOUN
bk128912n2h	14	25	synthesized	synthesize	VERB
bk128912n2h	14	26	by	by	ADP
bk128912n2h	14	27	the	the	DET
bk128912n2h	14	28	reaction	reaction	NOUN
bk128912n2h	14	29	of	of	ADP
bk128912n2h	14	30	ge94with	ge94with	PROPN
bk128912n2h	14	31	tms	tms	PROPN
bk128912n2h	14	32	-	-	PUNCT
bk128912n2h	14	33	cì¢'¡åác	cì¢'¡åác	PROPN
bk128912n2h	14	34	-	-	PUNCT
bk128912n2h	14	35	tms	tms	PROPN
bk128912n2h	14	36	.	.	PUNCT
bk128912n2h	15	1	the	the	DET
bk128912n2h	15	2	vinyl	vinyl	NOUN
bk128912n2h	15	3	disubstituted	disubstitute	VERB
bk128912n2h	15	4	cluster	cluster	NOUN
bk128912n2h	15	5	is	be	AUX
bk128912n2h	15	6	also	also	ADV
bk128912n2h	15	7	structurally	structurally	ADV
bk128912n2h	15	8	characterized	characterize	VERB
bk128912n2h	15	9	with	with	ADP
bk128912n2h	15	10	[	[	PUNCT
bk128912n2h	15	11	k-18	k-18	NOUN
bk128912n2h	15	12	-	-	PUNCT
bk128912n2h	15	13	crown-6]+	crown-6]+	NOUN
bk128912n2h	15	14	in	in	ADP
bk128912n2h	15	15	[	[	PUNCT
bk128912n2h	15	16	k-18	k-18	PROPN
bk128912n2h	15	17	-	-	PUNCT
bk128912n2h	15	18	crown-6]2[ge9-(ch	crown-6]2[ge9-(ch	PROPN
bk128912n2h	15	19	=	=	NOUN
bk128912n2h	15	20	ch2)2	ch2)2	NOUN
bk128912n2h	15	21	]	]	X
bk128912n2h	15	22	ì¢	ì¢	NUM
bk128912n2h	15	23	ââå¢en	ââå¢en	PROPN
bk128912n2h	15	24	.	.	PUNCT
bk128912n2h	15	25	by	by	ADP
bk128912n2h	15	26	exchanging	exchange	VERB
bk128912n2h	15	27	the	the	DET
bk128912n2h	15	28	alkali	alkali	ADJ
bk128912n2h	15	29	metal	metal	NOUN
bk128912n2h	15	30	cation	cation	NOUN
bk128912n2h	15	31	for	for	ADP
bk128912n2h	15	32	tetraoctylammonium	tetraoctylammonium	NOUN
bk128912n2h	15	33	cations	cation	NOUN
bk128912n2h	15	34	,	,	PUNCT
bk128912n2h	15	35	[	[	X
bk128912n2h	15	36	oc4n]+	oc4n]+	NOUN
bk128912n2h	15	37	,	,	PUNCT
bk128912n2h	15	38	the	the	DET
bk128912n2h	15	39	organo	organo	NOUN
bk128912n2h	15	40	-	-	PUNCT
bk128912n2h	15	41	zintl	zintl	NOUN
bk128912n2h	15	42	clusters	cluster	NOUN
bk128912n2h	15	43	can	can	AUX
bk128912n2h	15	44	be	be	AUX
bk128912n2h	15	45	solubilized	solubilize	VERB
bk128912n2h	15	46	in	in	ADP
bk128912n2h	15	47	a	a	DET
bk128912n2h	15	48	variety	variety	NOUN
bk128912n2h	15	49	of	of	ADP
bk128912n2h	15	50	conventional	conventional	ADJ
bk128912n2h	15	51	organic	organic	ADJ
bk128912n2h	15	52	solvents	solvent	NOUN
bk128912n2h	15	53	such	such	ADJ
bk128912n2h	15	54	as	as	ADP
bk128912n2h	15	55	thf	thf	PROPN
bk128912n2h	15	56	,	,	PUNCT
bk128912n2h	15	57	dioxane	dioxane	PROPN
bk128912n2h	15	58	,	,	PUNCT
bk128912n2h	15	59	dmso	dmso	PROPN
bk128912n2h	15	60	,	,	PUNCT
bk128912n2h	15	61	acetonitrile	acetonitrile	ADJ
bk128912n2h	15	62	,	,	PUNCT
bk128912n2h	15	63	and	and	CCONJ
bk128912n2h	15	64	diethyl	diethyl	PROPN
bk128912n2h	15	65	ether	ether	NOUN
bk128912n2h	15	66	,	,	PUNCT
bk128912n2h	15	67	and	and	CCONJ
bk128912n2h	15	68	even	even	ADV
bk128912n2h	15	69	solvents	solvent	NOUN
bk128912n2h	15	70	as	as	ADP
bk128912n2h	15	71	non	non	ADJ
bk128912n2h	15	72	-	-	ADJ
bk128912n2h	15	73	polar	polar	ADJ
bk128912n2h	15	74	as	as	ADP
bk128912n2h	15	75	benzene	benzene	PROPN
bk128912n2h	15	76	and	and	CCONJ
bk128912n2h	15	77	toluene	toluene	NOUN
bk128912n2h	15	78	.	.	PUNCT
bk128912n2h	16	1	the	the	DET
bk128912n2h	16	2	'	'	PUNCT
bk128912n2h	16	3	alkyne	alkyne	PROPN
bk128912n2h	16	4	'	'	PUNCT
bk128912n2h	16	5	route	route	NOUN
bk128912n2h	16	6	was	be	AUX
bk128912n2h	16	7	further	far	ADV
bk128912n2h	16	8	developed	develop	VERB
bk128912n2h	16	9	by	by	ADP
bk128912n2h	16	10	showing	show	VERB
bk128912n2h	16	11	that	that	SCONJ
bk128912n2h	16	12	it	it	PRON
bk128912n2h	16	13	is	be	AUX
bk128912n2h	16	14	compatible	compatible	ADJ
bk128912n2h	16	15	with	with	ADP
bk128912n2h	16	16	a	a	DET
bk128912n2h	16	17	large	large	ADJ
bk128912n2h	16	18	range	range	NOUN
bk128912n2h	16	19	of	of	ADP
bk128912n2h	16	20	alkyne	alkyne	NOUN
bk128912n2h	16	21	substrates	substrate	NOUN
bk128912n2h	16	22	with	with	ADP
bk128912n2h	16	23	various	various	ADJ
bk128912n2h	16	24	secondary	secondary	ADJ
bk128912n2h	16	25	functional	functional	ADJ
bk128912n2h	16	26	groups	group	NOUN
bk128912n2h	16	27	.	.	PUNCT
bk128912n2h	17	1	chapter	chapter	NOUN
bk128912n2h	17	2	5	5	NUM
bk128912n2h	17	3	presents	present	VERB
bk128912n2h	17	4	the	the	DET
bk128912n2h	17	5	results	result	NOUN
bk128912n2h	17	6	of	of	ADP
bk128912n2h	17	7	a	a	DET
bk128912n2h	17	8	systematic	systematic	ADJ
bk128912n2h	17	9	investigation	investigation	NOUN
bk128912n2h	17	10	of	of	ADP
bk128912n2h	17	11	the	the	DET
bk128912n2h	17	12	reactions	reaction	NOUN
bk128912n2h	17	13	of	of	ADP
bk128912n2h	17	14	nine	nine	NUM
bk128912n2h	17	15	-	-	PUNCT
bk128912n2h	17	16	atom	atom	NOUN
bk128912n2h	17	17	deltahedral	deltahedral	ADJ
bk128912n2h	17	18	clusters	cluster	NOUN
bk128912n2h	17	19	of	of	ADP
bk128912n2h	17	20	germanium	germanium	NOUN
bk128912n2h	17	21	(	(	PUNCT
bk128912n2h	17	22	zintl	zintl	PROPN
bk128912n2h	17	23	ions	ion	NOUN
bk128912n2h	17	24	,	,	PUNCT
bk128912n2h	17	25	ge9n-	ge9n-	NOUN
bk128912n2h	17	26	)	)	PUNCT
bk128912n2h	17	27	with	with	ADP
bk128912n2h	17	28	alkynes	alkyne	NOUN
bk128912n2h	17	29	and	and	CCONJ
bk128912n2h	17	30	alkyl	alkyl	ADJ
bk128912n2h	17	31	halides	halide	NOUN
bk128912n2h	17	32	.	.	PUNCT
bk128912n2h	18	1	the	the	DET
bk128912n2h	18	2	reaction	reaction	NOUN
bk128912n2h	18	3	pathways	pathway	NOUN
bk128912n2h	18	4	were	be	AUX
bk128912n2h	18	5	probed	probe	VERB
bk128912n2h	18	6	in	in	ADP
bk128912n2h	18	7	depth	depth	NOUN
bk128912n2h	18	8	using	use	VERB
bk128912n2h	18	9	various	various	ADJ
bk128912n2h	18	10	,	,	PUNCT
bk128912n2h	18	11	appropriately	appropriately	ADV
bk128912n2h	18	12	substituted	substitute	VERB
bk128912n2h	18	13	alkynes	alkyne	NOUN
bk128912n2h	18	14	and	and	CCONJ
bk128912n2h	18	15	organic	organic	ADJ
bk128912n2h	18	16	halides	halide	NOUN
bk128912n2h	18	17	,	,	PUNCT
bk128912n2h	18	18	including	include	VERB
bk128912n2h	18	19	some	some	DET
bk128912n2h	18	20	typical	typical	ADJ
bk128912n2h	18	21	mechanistic	mechanistic	ADJ
bk128912n2h	18	22	probes	probe	NOUN
bk128912n2h	18	23	and	and	CCONJ
bk128912n2h	18	24	radical	radical	ADJ
bk128912n2h	18	25	clocks	clock	NOUN
bk128912n2h	18	26	.	.	PUNCT
bk128912n2h	19	1	the	the	DET
bk128912n2h	19	2	regioselectivity	regioselectivity	NOUN
bk128912n2h	19	3	and	and	CCONJ
bk128912n2h	19	4	stereoselectivity	stereoselectivity	NOUN
bk128912n2h	19	5	of	of	ADP
bk128912n2h	19	6	the	the	DET
bk128912n2h	19	7	reaction	reaction	NOUN
bk128912n2h	19	8	with	with	ADP
bk128912n2h	19	9	alkynes	alkyne	NOUN
bk128912n2h	19	10	was	be	AUX
bk128912n2h	19	11	examined	examine	VERB
bk128912n2h	19	12	by	by	ADP
bk128912n2h	19	13	systematically	systematically	ADV
bk128912n2h	19	14	varying	vary	VERB
bk128912n2h	19	15	the	the	DET
bk128912n2h	19	16	steric	steric	ADJ
bk128912n2h	19	17	and	and	CCONJ
bk128912n2h	19	18	electronic	electronic	ADJ
bk128912n2h	19	19	nature	nature	NOUN
bk128912n2h	19	20	of	of	ADP
bk128912n2h	19	21	the	the	DET
bk128912n2h	19	22	substituents	substituent	NOUN
bk128912n2h	19	23	.	.	PUNCT
bk128912n2h	20	1	the	the	DET
bk128912n2h	20	2	studies	study	NOUN
bk128912n2h	20	3	showed	show	VERB
bk128912n2h	20	4	that	that	SCONJ
bk128912n2h	20	5	the	the	DET
bk128912n2h	20	6	zintl	zintl	PROPN
bk128912n2h	20	7	clusters	clusters	PROPN
bk128912n2h	20	8	act	act	VERB
bk128912n2h	20	9	as	as	ADP
bk128912n2h	20	10	strong	strong	ADJ
bk128912n2h	20	11	,	,	PUNCT
bk128912n2h	20	12	anionic	anionic	ADJ
bk128912n2h	20	13	nucleophiles	nucleophile	NOUN
bk128912n2h	20	14	towards	towards	ADP
bk128912n2h	20	15	the	the	DET
bk128912n2h	20	16	alkynes	alkyne	NOUN
bk128912n2h	20	17	and	and	CCONJ
bk128912n2h	20	18	primary	primary	ADJ
bk128912n2h	20	19	and	and	CCONJ
bk128912n2h	20	20	secondary	secondary	ADJ
bk128912n2h	20	21	alkyl	alkyl	NOUN
bk128912n2h	20	22	halides	halide	NOUN
bk128912n2h	20	23	but	but	CCONJ
bk128912n2h	20	24	,	,	PUNCT
bk128912n2h	20	25	most	most	ADV
bk128912n2h	20	26	likely	likely	ADJ
bk128912n2h	20	27	,	,	PUNCT
bk128912n2h	20	28	as	as	ADP
bk128912n2h	20	29	electron	electron	NOUN
bk128912n2h	20	30	donors	donor	NOUN
bk128912n2h	20	31	in	in	ADP
bk128912n2h	20	32	reactions	reaction	NOUN
bk128912n2h	20	33	with	with	ADP
bk128912n2h	20	34	tertiary	tertiary	ADJ
bk128912n2h	20	35	alkyl	alkyl	NOUN
bk128912n2h	20	36	halides	halide	NOUN
bk128912n2h	20	37	and	and	CCONJ
bk128912n2h	20	38	halogenated	halogenated	ADJ
bk128912n2h	20	39	olefins	olefin	NOUN
bk128912n2h	20	40	.	.	PUNCT
bk128912n2h	21	1	the	the	DET
bk128912n2h	21	2	pentenyl	pentenyl	ADJ
bk128912n2h	21	3	and	and	CCONJ
bk128912n2h	21	4	methylcyclopropyl	methylcyclopropyl	PROPN
bk128912n2h	21	5	functionalized	functionalize	VERB
bk128912n2h	21	6	clusters	cluster	NOUN
bk128912n2h	21	7	,	,	PUNCT
bk128912n2h	21	8	[	[	X
bk128912n2h	21	9	ge9-(c5h9)]3and	ge9-(c5h9)]3and	CCONJ
bk128912n2h	21	10	[	[	X
bk128912n2h	21	11	ge9-(ch2ch(ch2)2)2)]2-	ge9-(ch2ch(ch2)2)2)]2-	PROPN
bk128912n2h	21	12	,	,	PUNCT
bk128912n2h	21	13	respectively	respectively	ADV
bk128912n2h	21	14	,	,	PUNCT
bk128912n2h	21	15	were	be	AUX
bk128912n2h	21	16	also	also	ADV
bk128912n2h	21	17	crystallographically	crystallographically	ADV
bk128912n2h	21	18	characterized	characterize	VERB
bk128912n2h	21	19	in	in	ADP
bk128912n2h	21	20	compounds	compound	NOUN
bk128912n2h	21	21	with	with	ADP
bk128912n2h	21	22	[	[	X
bk128912n2h	21	23	k	k	PROPN
bk128912n2h	21	24	-	-	PUNCT
bk128912n2h	21	25	crypt]+	crypt]+	NOUN
bk128912n2h	21	26	countercations	countercation	NOUN
bk128912n2h	21	27	.	.	PUNCT
bk128912n2h	22	1	chapter	chapter	NOUN
bk128912n2h	22	2	6	6	NUM
bk128912n2h	22	3	further	far	ADV
bk128912n2h	22	4	develops	develop	VERB
bk128912n2h	22	5	the	the	DET
bk128912n2h	22	6	nucleophilic	nucleophilic	ADJ
bk128912n2h	22	7	reactivity	reactivity	NOUN
bk128912n2h	22	8	of	of	ADP
bk128912n2h	22	9	zintl	zintl	PROPN
bk128912n2h	22	10	clusters	cluster	NOUN
bk128912n2h	22	11	.	.	PUNCT
bk128912n2h	23	1	specifically	specifically	ADV
bk128912n2h	23	2	,	,	PUNCT
bk128912n2h	23	3	their	their	PRON
bk128912n2h	23	4	reactivity	reactivity	NOUN
bk128912n2h	23	5	towards	towards	ADP
bk128912n2h	23	6	substrates	substrate	NOUN
bk128912n2h	23	7	with	with	ADP
bk128912n2h	23	8	two	two	NUM
bk128912n2h	23	9	different	different	ADJ
bk128912n2h	23	10	electrophilic	electrophilic	ADJ
bk128912n2h	23	11	centers	center	NOUN
bk128912n2h	23	12	is	be	AUX
bk128912n2h	23	13	probed	probe	VERB
bk128912n2h	23	14	,	,	PUNCT
bk128912n2h	23	15	namely	namely	ADV
bk128912n2h	23	16	:	:	PUNCT
bk128912n2h	23	17	(	(	PUNCT
bk128912n2h	23	18	a	a	X
bk128912n2h	23	19	)	)	PUNCT
bk128912n2h	23	20	organostannyl	organostannyl	ADJ
bk128912n2h	23	21	center	center	NOUN
bk128912n2h	23	22	+	+	CCONJ
bk128912n2h	23	23	alkyne	alkyne	NOUN
bk128912n2h	23	24	,	,	PUNCT
bk128912n2h	23	25	(	(	PUNCT
bk128912n2h	23	26	b	b	X
bk128912n2h	23	27	)	)	PUNCT
bk128912n2h	23	28	halide	halide	NOUN
bk128912n2h	23	29	carbon	carbon	PROPN
bk128912n2h	23	30	center	center	NOUN
bk128912n2h	23	31	+	+	CCONJ
bk128912n2h	23	32	alkyne	alkyne	NOUN
bk128912n2h	23	33	,	,	PUNCT
bk128912n2h	23	34	and	and	CCONJ
bk128912n2h	23	35	(	(	PUNCT
bk128912n2h	23	36	c	c	X
bk128912n2h	23	37	)	)	PUNCT
bk128912n2h	23	38	halide	halide	NOUN
bk128912n2h	23	39	carbon	carbon	PROPN
bk128912n2h	23	40	center	center	NOUN
bk128912n2h	23	41	plus	plus	CCONJ
bk128912n2h	23	42	carbonyl	carbonyl	PROPN
bk128912n2h	23	43	group	group	NOUN
bk128912n2h	23	44	.	.	PUNCT
bk128912n2h	24	1	these	these	DET
bk128912n2h	24	2	reactions	reaction	NOUN
bk128912n2h	24	3	show	show	VERB
bk128912n2h	24	4	the	the	DET
bk128912n2h	24	5	preference	preference	NOUN
bk128912n2h	24	6	of	of	ADP
bk128912n2h	24	7	the	the	DET
bk128912n2h	24	8	clusters	cluster	NOUN
bk128912n2h	24	9	for	for	ADP
bk128912n2h	24	10	organostannyl	organostannyl	ADJ
bk128912n2h	24	11	centers	center	NOUN
bk128912n2h	24	12	over	over	ADP
bk128912n2h	24	13	alkynes	alkyne	NOUN
bk128912n2h	24	14	,	,	PUNCT
bk128912n2h	24	15	and	and	CCONJ
bk128912n2h	24	16	halide	halide	NOUN
bk128912n2h	24	17	carbon	carbon	NOUN
bk128912n2h	24	18	center	center	NOUN
bk128912n2h	24	19	over	over	ADP
bk128912n2h	24	20	either	either	PRON
bk128912n2h	24	21	of	of	ADP
bk128912n2h	24	22	the	the	DET
bk128912n2h	24	23	other	other	ADJ
bk128912n2h	24	24	two	two	NUM
bk128912n2h	24	25	.	.	PUNCT
bk128912n2h	25	1	additionally	additionally	ADV
bk128912n2h	25	2	,	,	PUNCT
bk128912n2h	25	3	initial	initial	ADJ
bk128912n2h	25	4	investigations	investigation	NOUN
bk128912n2h	25	5	into	into	ADP
bk128912n2h	25	6	functionalizing	functionalizing	PROPN
bk128912n2h	25	7	zintl	zintl	PROPN
bk128912n2h	25	8	clusters	cluster	NOUN
bk128912n2h	25	9	with	with	ADP
bk128912n2h	25	10	an	an	DET
bk128912n2h	25	11	sp	sp	NOUN
bk128912n2h	25	12	carbon	carbon	NOUN
bk128912n2h	25	13	are	be	AUX
bk128912n2h	25	14	discussed	discuss	VERB
bk128912n2h	25	15	,	,	PUNCT
bk128912n2h	25	16	completing	complete	VERB
bk128912n2h	25	17	the	the	DET
bk128912n2h	25	18	sequence	sequence	NOUN
bk128912n2h	25	19	of	of	ADP
bk128912n2h	25	20	primary	primary	ADJ
bk128912n2h	25	21	,	,	PUNCT
bk128912n2h	25	22	secondary	secondary	ADJ
bk128912n2h	25	23	,	,	PUNCT
bk128912n2h	25	24	and	and	CCONJ
bk128912n2h	25	25	tertiary	tertiary	ADJ
bk128912n2h	25	26	sp3	sp3	NOUN
bk128912n2h	25	27	carbons	carbon	NOUN
bk128912n2h	25	28	from	from	ADP
bk128912n2h	25	29	alkyl	alkyl	ADJ
bk128912n2h	25	30	halides	halide	NOUN
bk128912n2h	25	31	,	,	PUNCT
bk128912n2h	25	32	and	and	CCONJ
bk128912n2h	25	33	sp2	sp2	NOUN
bk128912n2h	25	34	carbons	carbon	NOUN
bk128912n2h	25	35	from	from	ADP
bk128912n2h	25	36	alkenyl	alkenyl	NOUN
bk128912n2h	25	37	halides	halide	NOUN
bk128912n2h	25	38	or	or	CCONJ
bk128912n2h	25	39	alkynes	alkyne	NOUN
bk128912n2h	25	40	.	.	PUNCT
bk128912n2h	26	1	organo	organo	NOUN
bk128912n2h	26	2	-	-	PUNCT
bk128912n2h	26	3	zintl	zintl	PROPN
bk128912n2h	26	4	clusters	cluster	NOUN
bk128912n2h	26	5	are	be	AUX
bk128912n2h	26	6	also	also	ADV
bk128912n2h	26	7	unreactive	unreactive	ADJ
bk128912n2h	26	8	towards	towards	ADP
bk128912n2h	26	9	tertiary	tertiary	ADJ
bk128912n2h	26	10	alkyl	alkyl	NOUN
bk128912n2h	26	11	halides	halide	NOUN
bk128912n2h	26	12	,	,	PUNCT
bk128912n2h	26	13	ketones	ketone	NOUN
bk128912n2h	26	14	,	,	PUNCT
bk128912n2h	26	15	and	and	CCONJ
bk128912n2h	26	16	aldehydes	aldehyde	NOUN
bk128912n2h	26	17	.	.	PUNCT
bk128912n2h	27	1	chapter	chapter	NOUN
bk128912n2h	27	2	7	7	NUM
bk128912n2h	27	3	discusses	discuss	VERB
bk128912n2h	27	4	the	the	DET
bk128912n2h	27	5	stability	stability	NOUN
bk128912n2h	27	6	towards	towards	ADP
bk128912n2h	27	7	h2o	h2o	PRON
bk128912n2h	27	8	that	that	PRON
bk128912n2h	27	9	organo	organo	NOUN
bk128912n2h	27	10	-	-	PUNCT
bk128912n2h	27	11	zintl	zintl	PROPN
bk128912n2h	27	12	clusters	cluster	NOUN
bk128912n2h	27	13	exhibit	exhibit	VERB
bk128912n2h	27	14	.	.	PUNCT
bk128912n2h	28	1	this	this	DET
bk128912n2h	28	2	compatibility	compatibility	NOUN
bk128912n2h	28	3	with	with	ADP
bk128912n2h	28	4	h2o	h2o	PROPN
bk128912n2h	28	5	is	be	AUX
bk128912n2h	28	6	coupled	couple	VERB
bk128912n2h	28	7	with	with	ADP
bk128912n2h	28	8	their	their	PRON
bk128912n2h	28	9	non	non	ADJ
bk128912n2h	28	10	-	-	ADJ
bk128912n2h	28	11	reactivity	reactivity	NOUN
bk128912n2h	28	12	towards	towards	ADP
bk128912n2h	28	13	aldehydes	aldehyde	NOUN
bk128912n2h	28	14	to	to	PART
bk128912n2h	28	15	demonstrate	demonstrate	VERB
bk128912n2h	28	16	that	that	SCONJ
bk128912n2h	28	17	subsequent	subsequent	ADJ
bk128912n2h	28	18	organic	organic	ADJ
bk128912n2h	28	19	transformations	transformation	NOUN
bk128912n2h	28	20	are	be	AUX
bk128912n2h	28	21	possible	possible	ADJ
bk128912n2h	28	22	with	with	ADP
bk128912n2h	28	23	organo	organo	NOUN
bk128912n2h	28	24	-	-	PUNCT
bk128912n2h	28	25	zintl	zintl	NOUN
bk128912n2h	28	26	clusters	cluster	NOUN
bk128912n2h	28	27	.	.	PUNCT
bk128912n2h	29	1	proof	proof	NOUN
bk128912n2h	29	2	of	of	ADP
bk128912n2h	29	3	concept	concept	NOUN
bk128912n2h	29	4	comes	come	VERB
bk128912n2h	29	5	from	from	ADP
bk128912n2h	29	6	the	the	DET
bk128912n2h	29	7	aldehyde	aldehyde	NOUN
bk128912n2h	29	8	condensation	condensation	NOUN
bk128912n2h	29	9	reaction	reaction	NOUN
bk128912n2h	29	10	between	between	ADP
bk128912n2h	29	11	[	[	X
bk128912n2h	29	12	ge9-(ch	ge9-(ch	NOUN
bk128912n2h	29	13	=	=	NOUN
bk128912n2h	29	14	ch	ch	PROPN
bk128912n2h	29	15	-	-	PUNCT
bk128912n2h	29	16	ch2nh2)2]2and	ch2nh2)2]2and	PROPN
bk128912n2h	29	17	ferrocene	ferrocene	PROPN
bk128912n2h	29	18	carboxaldehyde	carboxaldehyde	PROPN
bk128912n2h	29	19	.	.	PUNCT
bk128912n2h	30	1	the	the	DET
bk128912n2h	30	2	former	former	ADJ
bk128912n2h	30	3	anion	anion	NOUN
bk128912n2h	30	4	is	be	AUX
bk128912n2h	30	5	structurally	structurally	ADV
bk128912n2h	30	6	characterized	characterize	VERB
bk128912n2h	30	7	by	by	ADP
bk128912n2h	30	8	x	x	NOUN
bk128912n2h	30	9	-	-	NOUN
bk128912n2h	30	10	ray	ray	NOUN
bk128912n2h	30	11	diffraction	diffraction	NOUN
bk128912n2h	30	12	in	in	ADP
bk128912n2h	30	13	[	[	PUNCT
bk128912n2h	30	14	k-(2,2,2	k-(2,2,2	SPACE
bk128912n2h	30	15	-	-	PUNCT
bk128912n2h	30	16	crypt)]2[ge9-(ch	crypt)]2[ge9-(ch	PROPN
bk128912n2h	30	17	=	=	NOUN
bk128912n2h	30	18	ch	ch	PROPN
bk128912n2h	30	19	-	-	PUNCT
bk128912n2h	30	20	chnh2)2	chnh2)2	NOUN
bk128912n2h	30	21	]	]	PUNCT
bk128912n2h	30	22	from	from	ADP
bk128912n2h	30	23	a	a	DET
bk128912n2h	30	24	reaction	reaction	NOUN
bk128912n2h	30	25	between	between	ADP
bk128912n2h	30	26	ge94and	ge94and	NOUN
bk128912n2h	30	27	propargylamine	propargylamine	NOUN
bk128912n2h	30	28	(	(	PUNCT
bk128912n2h	30	29	h	h	PROPN
bk128912n2h	30	30	-	-	PUNCT
bk128912n2h	30	31	cì¢'¡åác	cì¢'¡åác	NOUN
bk128912n2h	30	32	-	-	PUNCT
bk128912n2h	30	33	ch2nh2	ch2nh2	PROPN
bk128912n2h	30	34	)	)	PUNCT
bk128912n2h	30	35	.	.	PUNCT
bk128912n2h	31	1	in	in	ADP
bk128912n2h	31	2	addition	addition	NOUN
bk128912n2h	31	3	to	to	ADP
bk128912n2h	31	4	water	water	NOUN
bk128912n2h	31	5	,	,	PUNCT
bk128912n2h	31	6	organo	organo	NOUN
bk128912n2h	31	7	-	-	PUNCT
bk128912n2h	31	8	zintl	zintl	PROPN
bk128912n2h	31	9	clusters	cluster	NOUN
bk128912n2h	31	10	are	be	AUX
bk128912n2h	31	11	stable	stable	ADJ
bk128912n2h	31	12	towards	towards	ADP
bk128912n2h	31	13	dicationic	dicationic	ADJ
bk128912n2h	31	14	transition	transition	NOUN
bk128912n2h	31	15	metal	metal	NOUN
bk128912n2h	31	16	complexes	complex	NOUN
bk128912n2h	31	17	,	,	PUNCT
bk128912n2h	31	18	as	as	SCONJ
bk128912n2h	31	19	evidenced	evidence	VERB
bk128912n2h	31	20	by	by	ADP
bk128912n2h	31	21	isolation	isolation	NOUN
bk128912n2h	31	22	of	of	ADP
bk128912n2h	31	23	[	[	X
bk128912n2h	31	24	fe(en)3][ge9-(ch	fe(en)3][ge9-(ch	PROPN
bk128912n2h	31	25	=	=	SYM
bk128912n2h	31	26	ch	ch	PROPN
bk128912n2h	31	27	-	-	PUNCT
bk128912n2h	31	28	fc)2]ì¢	fc)2]ì¢	PROPN
bk128912n2h	31	29	ââå¢3en	ââå¢3en	PROPN
bk128912n2h	31	30	.	.	PUNCT
bk128912n2h	32	1	chapter	chapter	NOUN
bk128912n2h	32	2	8	8	NUM
bk128912n2h	32	3	involves	involve	VERB
bk128912n2h	32	4	a	a	DET
bk128912n2h	32	5	break	break	NOUN
bk128912n2h	32	6	from	from	ADP
bk128912n2h	32	7	germanium	germanium	NOUN
bk128912n2h	32	8	-	-	PUNCT
bk128912n2h	32	9	based	base	VERB
bk128912n2h	32	10	clusters	cluster	NOUN
bk128912n2h	32	11	,	,	PUNCT
bk128912n2h	32	12	and	and	CCONJ
bk128912n2h	32	13	discusses	discuss	VERB
bk128912n2h	32	14	the	the	DET
bk128912n2h	32	15	results	result	NOUN
bk128912n2h	32	16	of	of	ADP
bk128912n2h	32	17	some	some	DET
bk128912n2h	32	18	investigations	investigation	NOUN
bk128912n2h	32	19	into	into	ADP
bk128912n2h	32	20	the	the	DET
bk128912n2h	32	21	reactivity	reactivity	NOUN
bk128912n2h	32	22	of	of	ADP
bk128912n2h	32	23	bismuth	bismuth	NOUN
bk128912n2h	32	24	-	-	PUNCT
bk128912n2h	32	25	based	base	VERB
bk128912n2h	32	26	zintl	zintl	NOUN
bk128912n2h	32	27	anions	anion	NOUN
bk128912n2h	32	28	towards	towards	ADP
bk128912n2h	32	29	ni(co)2(pph3)2	ni(co)2(pph3)2	PROPN
bk128912n2h	32	30	.	.	PROPN
bk128912n2h	32	31	two	two	NUM
bk128912n2h	32	32	heterometallic	heterometallic	ADJ
bk128912n2h	32	33	species	specie	NOUN
bk128912n2h	32	34	were	be	AUX
bk128912n2h	32	35	isolated	isolate	VERB
bk128912n2h	32	36	and	and	CCONJ
bk128912n2h	32	37	crystallographically	crystallographically	ADV
bk128912n2h	32	38	characterized	characterize	VERB
bk128912n2h	32	39	;	;	PUNCT
bk128912n2h	32	40	namely	namely	ADV
bk128912n2h	32	41	,	,	PUNCT
bk128912n2h	32	42	the	the	DET
bk128912n2h	32	43	open	open	ADJ
bk128912n2h	32	44	cluster	cluster	NOUN
bk128912n2h	32	45	[	[	X
bk128912n2h	32	46	bi3ni6(co)9]3-	bi3ni6(co)9]3-	NOUN
bk128912n2h	32	47	,	,	PUNCT
bk128912n2h	32	48	and	and	CCONJ
bk128912n2h	32	49	the	the	DET
bk128912n2h	32	50	intermetalloid	intermetalloid	NOUN
bk128912n2h	32	51	and	and	CCONJ
bk128912n2h	32	52	hypoelectronic	hypoelectronic	ADJ
bk128912n2h	32	53	closo-[ni@{bi6ni6(co)8}]3-	closo-[ni@{bi6ni6(co)8}]3-	PROPN
bk128912n2h	32	54	.	.	PUNCT
bk128912n2h	33	1	the	the	DET
bk128912n2h	33	2	species	specie	NOUN
bk128912n2h	33	3	are	be	AUX
bk128912n2h	33	4	also	also	ADV
bk128912n2h	33	5	characterized	characterize	VERB
bk128912n2h	33	6	in	in	ADP
bk128912n2h	33	7	the	the	DET
bk128912n2h	33	8	gas	gas	NOUN
bk128912n2h	33	9	phase	phase	NOUN
bk128912n2h	33	10	by	by	ADP
bk128912n2h	33	11	electrospray	electrospray	NOUN
bk128912n2h	33	12	mass	mass	NOUN
bk128912n2h	33	13	spectrometry	spectrometry	NOUN
bk128912n2h	33	14	,	,	PUNCT
bk128912n2h	33	15	and	and	CCONJ
bk128912n2h	33	16	their	their	PRON
bk128912n2h	33	17	full	full	ADJ
bk128912n2h	33	18	structural	structural	ADJ
bk128912n2h	33	19	and	and	CCONJ
bk128912n2h	33	20	electronic	electronic	ADJ
bk128912n2h	33	21	descriptions	description	NOUN
bk128912n2h	33	22	are	be	AUX
bk128912n2h	33	23	discussed	discuss	VERB
bk128912n2h	33	24	.	.	PUNCT
bk128912n2h	34	1	the	the	DET
bk128912n2h	34	2	dissertation	dissertation	NOUN
bk128912n2h	34	3	closes	close	VERB
bk128912n2h	34	4	with	with	ADP
bk128912n2h	34	5	a	a	DET
bk128912n2h	34	6	discussion	discussion	NOUN
bk128912n2h	34	7	of	of	ADP
bk128912n2h	34	8	prospects	prospect	NOUN
bk128912n2h	34	9	for	for	ADP
bk128912n2h	34	10	future	future	ADJ
bk128912n2h	34	11	work	work	NOUN
bk128912n2h	34	12	,	,	PUNCT
bk128912n2h	34	13	primarily	primarily	ADV
bk128912n2h	34	14	in	in	ADP
bk128912n2h	34	15	the	the	DET
bk128912n2h	34	16	area	area	NOUN
bk128912n2h	34	17	of	of	ADP
bk128912n2h	34	18	organo	organo	NOUN
bk128912n2h	34	19	-	-	PUNCT
bk128912n2h	34	20	zintl	zintl	PROPN
bk128912n2h	34	21	clusters	cluster	NOUN
bk128912n2h	34	22	.	.	PUNCT