id	sid	tid	token	lemma	pos
br86b279c69	1	1	the	the	DET
br86b279c69	1	2	primary	primary	ADJ
br86b279c69	1	3	intent	intent	NOUN
br86b279c69	1	4	of	of	ADP
br86b279c69	1	5	this	this	DET
br86b279c69	1	6	dissertation	dissertation	NOUN
br86b279c69	1	7	is	be	AUX
br86b279c69	1	8	to	to	PART
br86b279c69	1	9	develop	develop	VERB
br86b279c69	1	10	strategies	strategy	NOUN
br86b279c69	1	11	to	to	PART
br86b279c69	1	12	aggregate	aggregate	VERB
br86b279c69	1	13	zintl	zintl	NOUN
br86b279c69	1	14	ions	ion	NOUN
br86b279c69	1	15	containing	contain	VERB
br86b279c69	1	16	transition	transition	NOUN
br86b279c69	1	17	metal	metal	NOUN
br86b279c69	1	18	fragments	fragment	NOUN
br86b279c69	1	19	and/or	and/or	CCONJ
br86b279c69	1	20	atoms	atom	NOUN
br86b279c69	1	21	.	.	PUNCT
br86b279c69	2	1	development	development	NOUN
br86b279c69	2	2	for	for	ADP
br86b279c69	2	3	such	such	DET
br86b279c69	2	4	an	an	DET
br86b279c69	2	5	endeavor	endeavor	NOUN
br86b279c69	2	6	began	begin	VERB
br86b279c69	2	7	in	in	ADP
br86b279c69	2	8	the	the	DET
br86b279c69	2	9	following	following	ADJ
br86b279c69	2	10	manner	manner	NOUN
br86b279c69	2	11	:	:	PUNCT
br86b279c69	2	12	(	(	PUNCT
br86b279c69	2	13	1	1	X
br86b279c69	2	14	)	)	PUNCT
br86b279c69	2	15	identifying	identify	VERB
br86b279c69	2	16	similarities	similarity	NOUN
br86b279c69	2	17	with	with	ADP
br86b279c69	2	18	other	other	ADJ
br86b279c69	2	19	fields	field	NOUN
br86b279c69	2	20	of	of	ADP
br86b279c69	2	21	chemistry	chemistry	NOUN
br86b279c69	2	22	wherein	wherein	SCONJ
br86b279c69	2	23	successful	successful	ADJ
br86b279c69	2	24	aggregation	aggregation	NOUN
br86b279c69	2	25	was	be	AUX
br86b279c69	2	26	carried	carry	VERB
br86b279c69	2	27	out	out	ADP
br86b279c69	2	28	(	(	PUNCT
br86b279c69	2	29	2	2	X
br86b279c69	2	30	)	)	PUNCT
br86b279c69	2	31	identifying	identify	VERB
br86b279c69	2	32	suitable	suitable	ADJ
br86b279c69	2	33	transition	transition	NOUN
br86b279c69	2	34	metal	metal	NOUN
br86b279c69	2	35	containing	contain	VERB
br86b279c69	2	36	zintl	zintl	PROPN
br86b279c69	2	37	clusters	cluster	NOUN
br86b279c69	2	38	as	as	ADP
br86b279c69	2	39	precursors	precursor	NOUN
br86b279c69	2	40	for	for	ADP
br86b279c69	2	41	aggregation	aggregation	NOUN
br86b279c69	2	42	(	(	PUNCT
br86b279c69	2	43	3	3	X
br86b279c69	2	44	)	)	PUNCT
br86b279c69	2	45	combining	combine	VERB
br86b279c69	2	46	both	both	DET
br86b279c69	2	47	suitable	suitable	ADJ
br86b279c69	2	48	materials	material	NOUN
br86b279c69	2	49	and	and	CCONJ
br86b279c69	2	50	already	already	ADV
br86b279c69	2	51	published	publish	VERB
br86b279c69	2	52	techniques	technique	NOUN
br86b279c69	2	53	to	to	PART
br86b279c69	2	54	aggregate	aggregate	VERB
br86b279c69	2	55	zintl	zintl	NOUN
br86b279c69	2	56	clusters	cluster	NOUN
br86b279c69	2	57	(	(	PUNCT
br86b279c69	2	58	4	4	NUM
br86b279c69	2	59	)	)	PUNCT
br86b279c69	2	60	further	far	ADV
br86b279c69	2	61	improving	improve	VERB
br86b279c69	2	62	the	the	DET
br86b279c69	2	63	synthetic	synthetic	ADJ
br86b279c69	2	64	approaches	approach	NOUN
br86b279c69	2	65	presented	present	VERB
br86b279c69	2	66	to	to	PART
br86b279c69	2	67	address	address	VERB
br86b279c69	2	68	the	the	DET
br86b279c69	2	69	pitfalls	pitfall	NOUN
br86b279c69	2	70	in	in	ADP
br86b279c69	2	71	these	these	DET
br86b279c69	2	72	syntheses	synthesis	NOUN
br86b279c69	2	73	.	.	PUNCT
br86b279c69	3	1	these	these	DET
br86b279c69	3	2	steps	step	NOUN
br86b279c69	3	3	will	will	AUX
br86b279c69	3	4	be	be	AUX
br86b279c69	3	5	covered	cover	VERB
br86b279c69	3	6	in	in	ADP
br86b279c69	3	7	detail	detail	NOUN
br86b279c69	3	8	throughout	throughout	ADP
br86b279c69	3	9	this	this	DET
br86b279c69	3	10	dissertation	dissertation	NOUN
br86b279c69	3	11	.	.	PUNCT
br86b279c69	4	1	after	after	ADP
br86b279c69	4	2	introducing	introduce	VERB
br86b279c69	4	3	the	the	DET
br86b279c69	4	4	fundamentals	fundamental	NOUN
br86b279c69	4	5	of	of	ADP
br86b279c69	4	6	zintl	zintl	PROPN
br86b279c69	4	7	chemistry	chemistry	NOUN
br86b279c69	4	8	,	,	PUNCT
br86b279c69	4	9	noble	noble	ADJ
br86b279c69	4	10	metal	metal	NOUN
br86b279c69	4	11	aggregation	aggregation	NOUN
br86b279c69	4	12	,	,	PUNCT
br86b279c69	4	13	and	and	CCONJ
br86b279c69	4	14	ligand	ligand	NOUN
br86b279c69	4	15	protected	protect	VERB
br86b279c69	4	16	clusters	cluster	NOUN
br86b279c69	4	17	(	(	PUNCT
br86b279c69	4	18	chapter	chapter	NOUN
br86b279c69	4	19	1	1	NUM
br86b279c69	4	20	)	)	PUNCT
br86b279c69	4	21	,	,	PUNCT
br86b279c69	4	22	the	the	DET
br86b279c69	4	23	first	first	ADJ
br86b279c69	4	24	attempt	attempt	NOUN
br86b279c69	4	25	at	at	ADP
br86b279c69	4	26	aggregation	aggregation	NOUN
br86b279c69	4	27	using	use	VERB
br86b279c69	4	28	oxidation	oxidation	NOUN
br86b279c69	4	29	by	by	ADP
br86b279c69	4	30	solvent	solvent	NOUN
br86b279c69	4	31	is	be	AUX
br86b279c69	4	32	presented	present	VERB
br86b279c69	4	33	(	(	PUNCT
br86b279c69	4	34	chapter	chapter	NOUN
br86b279c69	4	35	2	2	NUM
br86b279c69	4	36	)	)	PUNCT
br86b279c69	4	37	.	.	PUNCT
br86b279c69	5	1	using	use	VERB
br86b279c69	5	2	solely	solely	ADV
br86b279c69	5	3	solvent	solvent	ADJ
br86b279c69	5	4	oxidation	oxidation	NOUN
br86b279c69	5	5	,	,	PUNCT
br86b279c69	5	6	in	in	ADP
br86b279c69	5	7	this	this	DET
br86b279c69	5	8	case	case	NOUN
br86b279c69	5	9	pyridine	pyridine	NOUN
br86b279c69	5	10	,	,	PUNCT
br86b279c69	5	11	in	in	ADP
br86b279c69	5	12	the	the	DET
br86b279c69	5	13	presence	presence	NOUN
br86b279c69	5	14	of	of	ADP
br86b279c69	5	15	a	a	DET
br86b279c69	5	16	transition	transition	NOUN
br86b279c69	5	17	metal	metal	NOUN
br86b279c69	5	18	fragment	fragment	NOUN
br86b279c69	5	19	,	,	PUNCT
br86b279c69	5	20	cr(co)3	cr(co)3	PROPN
br86b279c69	5	21	,	,	PUNCT
br86b279c69	5	22	results	result	VERB
br86b279c69	5	23	in	in	ADP
br86b279c69	5	24	the	the	DET
br86b279c69	5	25	isolation	isolation	NOUN
br86b279c69	5	26	of	of	ADP
br86b279c69	5	27	the	the	DET
br86b279c69	5	28	[	[	PUNCT
br86b279c69	5	29	bi7]3	bi7]3	SPACE
br86b279c69	5	30	–	–	PUNCT
br86b279c69	5	31	anion	anion	NOUN
br86b279c69	5	32	.	.	PUNCT
br86b279c69	6	1	although	although	SCONJ
br86b279c69	6	2	the	the	DET
br86b279c69	6	3	resulting	result	VERB
br86b279c69	6	4	anion	anion	NOUN
br86b279c69	6	5	did	do	AUX
br86b279c69	6	6	not	not	PART
br86b279c69	6	7	contain	contain	VERB
br86b279c69	6	8	a	a	DET
br86b279c69	6	9	transition	transition	NOUN
br86b279c69	6	10	metal	metal	NOUN
br86b279c69	6	11	fragment	fragment	NOUN
br86b279c69	6	12	,	,	PUNCT
br86b279c69	6	13	the	the	DET
br86b279c69	6	14	solvent	solvent	NOUN
br86b279c69	6	15	caused	cause	VERB
br86b279c69	6	16	oxidation	oxidation	NOUN
br86b279c69	6	17	from	from	ADP
br86b279c69	6	18	its	its	PRON
br86b279c69	6	19	[	[	PUNCT
br86b279c69	6	20	bi2]2	bi2]2	SPACE
br86b279c69	6	21	–	–	PUNCT
br86b279c69	6	22	parent	parent	NOUN
br86b279c69	6	23	,	,	PUNCT
br86b279c69	6	24	to	to	PART
br86b279c69	6	25	generate	generate	VERB
br86b279c69	6	26	a	a	DET
br86b279c69	6	27	naked	naked	ADJ
br86b279c69	6	28	aggregated	aggregated	ADJ
br86b279c69	6	29	anion	anion	NOUN
br86b279c69	6	30	.	.	PUNCT
br86b279c69	7	1	following	follow	VERB
br86b279c69	7	2	this	this	DET
br86b279c69	7	3	result	result	NOUN
br86b279c69	7	4	,	,	PUNCT
br86b279c69	7	5	we	we	PRON
br86b279c69	7	6	looked	look	VERB
br86b279c69	7	7	to	to	ADP
br86b279c69	7	8	applying	apply	VERB
br86b279c69	7	9	noble	noble	ADJ
br86b279c69	7	10	metal	metal	NOUN
br86b279c69	7	11	aggregation	aggregation	NOUN
br86b279c69	7	12	approaches	approach	NOUN
br86b279c69	7	13	to	to	PART
br86b279c69	7	14	transition	transition	VERB
br86b279c69	7	15	metal	metal	NOUN
br86b279c69	7	16	-	-	PUNCT
br86b279c69	7	17	zintl	zintl	NOUN
br86b279c69	7	18	clusters	cluster	NOUN
br86b279c69	7	19	containing	contain	VERB
br86b279c69	7	20	carbonyl	carbonyl	ADJ
br86b279c69	7	21	ligands	ligand	NOUN
br86b279c69	7	22	.	.	PUNCT
br86b279c69	8	1	using	use	VERB
br86b279c69	8	2	transition	transition	NOUN
br86b279c69	8	3	metal	metal	NOUN
br86b279c69	8	4	rich	rich	ADJ
br86b279c69	8	5	clusters	cluster	NOUN
br86b279c69	8	6	as	as	ADP
br86b279c69	8	7	[	[	X
br86b279c69	8	8	bi3ni4(co)6]3	bi3ni4(co)6]3	X
br86b279c69	8	9	–	–	PUNCT
br86b279c69	8	10	,	,	PUNCT
br86b279c69	8	11	we	we	PRON
br86b279c69	8	12	demonstrate	demonstrate	VERB
br86b279c69	8	13	the	the	DET
br86b279c69	8	14	same	same	ADJ
br86b279c69	8	15	approaches	approach	NOUN
br86b279c69	8	16	are	be	AUX
br86b279c69	8	17	applicable	applicable	ADJ
br86b279c69	8	18	to	to	PART
br86b279c69	8	19	zintl	zintl	VERB
br86b279c69	8	20	chemistry	chemistry	NOUN
br86b279c69	8	21	by	by	ADP
br86b279c69	8	22	generating	generate	VERB
br86b279c69	8	23	the	the	DET
br86b279c69	8	24	[	[	PUNCT
br86b279c69	8	25	bi12ni7(co)4]4	bi12ni7(co)4]4	PROPN
br86b279c69	8	26	–	–	PUNCT
br86b279c69	8	27	intermetalloid	intermetalloid	ADJ
br86b279c69	8	28	anion	anion	NOUN
br86b279c69	8	29	(	(	PUNCT
br86b279c69	8	30	chapter	chapter	NOUN
br86b279c69	8	31	3	3	NUM
br86b279c69	8	32	)	)	PUNCT
br86b279c69	8	33	.	.	PUNCT
br86b279c69	9	1	furthermore	furthermore	ADV
br86b279c69	9	2	,	,	PUNCT
br86b279c69	9	3	the	the	DET
br86b279c69	9	4	species	species	NOUN
br86b279c69	9	5	is	be	AUX
br86b279c69	9	6	unique	unique	ADJ
br86b279c69	9	7	in	in	SCONJ
br86b279c69	9	8	that	that	SCONJ
br86b279c69	9	9	it	it	PRON
br86b279c69	9	10	strongly	strongly	ADV
br86b279c69	9	11	resembles	resemble	VERB
br86b279c69	9	12	condensed	condensed	ADJ
br86b279c69	9	13	polyhedra	polyhedron	NOUN
br86b279c69	9	14	seen	see	VERB
br86b279c69	9	15	in	in	ADP
br86b279c69	9	16	transition	transition	NOUN
br86b279c69	9	17	metal	metal	NOUN
br86b279c69	9	18	clusters	cluster	NOUN
br86b279c69	9	19	.	.	PUNCT
br86b279c69	10	1	the	the	DET
br86b279c69	10	2	implications	implication	NOUN
br86b279c69	10	3	of	of	ADP
br86b279c69	10	4	this	this	PRON
br86b279c69	10	5	are	be	AUX
br86b279c69	10	6	discussed	discuss	VERB
br86b279c69	10	7	and	and	CCONJ
br86b279c69	10	8	the	the	DET
br86b279c69	10	9	electronic	electronic	ADJ
br86b279c69	10	10	structure	structure	NOUN
br86b279c69	10	11	elucidated	elucidate	VERB
br86b279c69	10	12	.	.	PUNCT
br86b279c69	11	1	we	we	PRON
br86b279c69	11	2	further	far	ADV
br86b279c69	11	3	applied	apply	VERB
br86b279c69	11	4	the	the	DET
br86b279c69	11	5	noble	noble	ADJ
br86b279c69	11	6	metal	metal	NOUN
br86b279c69	11	7	aggregation	aggregation	NOUN
br86b279c69	11	8	approach	approach	NOUN
br86b279c69	11	9	to	to	ADP
br86b279c69	11	10	clusters	cluster	NOUN
br86b279c69	11	11	deficient	deficient	ADJ
br86b279c69	11	12	in	in	ADP
br86b279c69	11	13	carbonyl	carbonyl	ADJ
br86b279c69	11	14	ligands	ligand	NOUN
br86b279c69	11	15	.	.	PUNCT
br86b279c69	12	1	using	use	VERB
br86b279c69	12	2	this	this	DET
br86b279c69	12	3	time	time	NOUN
br86b279c69	12	4	[	[	X
br86b279c69	12	5	ni@sn9ni(co)]3	ni@sn9ni(co)]3	SPACE
br86b279c69	12	6	–	–	PUNCT
br86b279c69	12	7	as	as	ADP
br86b279c69	12	8	a	a	DET
br86b279c69	12	9	starting	starting	NOUN
br86b279c69	12	10	material	material	NOUN
br86b279c69	12	11	we	we	PRON
br86b279c69	12	12	isolate	isolate	VERB
br86b279c69	12	13	the	the	DET
br86b279c69	12	14	novel	novel	ADJ
br86b279c69	12	15	fused	fuse	VERB
br86b279c69	12	16	cluster	cluster	NOUN
br86b279c69	12	17	as	as	ADP
br86b279c69	12	18	[	[	X
br86b279c69	12	19	sn14ni(co)]4	sn14ni(co)]4	X
br86b279c69	12	20	–	–	PUNCT
br86b279c69	12	21	(	(	PUNCT
br86b279c69	12	22	chapter	chapter	NOUN
br86b279c69	12	23	4	4	NUM
br86b279c69	12	24	)	)	PUNCT
br86b279c69	12	25	.	.	PUNCT
br86b279c69	13	1	unlike	unlike	ADP
br86b279c69	13	2	the	the	DET
br86b279c69	13	3	previous	previous	ADJ
br86b279c69	13	4	bi	bi	PROPN
br86b279c69	13	5	/	/	PROPN
br86b279c69	13	6	ni	ni	PROPN
br86b279c69	13	7	species	species	PROPN
br86b279c69	13	8	,	,	PUNCT
br86b279c69	13	9	the	the	DET
br86b279c69	13	10	[	[	X
br86b279c69	13	11	sn14ni(co)]4	sn14ni(co)]4	X
br86b279c69	13	12	–	–	PUNCT
br86b279c69	13	13	anion	anion	NOUN
br86b279c69	13	14	is	be	AUX
br86b279c69	13	15	rationalized	rationalize	VERB
br86b279c69	13	16	using	use	VERB
br86b279c69	13	17	modified	modify	VERB
br86b279c69	13	18	wades	wade	NOUN
br86b279c69	13	19	-	-	PUNCT
br86b279c69	13	20	mingos	mingo	NOUN
br86b279c69	13	21	rules	rule	NOUN
br86b279c69	13	22	for	for	ADP
br86b279c69	13	23	cluster	cluster	NOUN
br86b279c69	13	24	bonding	bonding	NOUN
br86b279c69	13	25	.	.	PUNCT
br86b279c69	14	1	it	it	PRON
br86b279c69	14	2	is	be	AUX
br86b279c69	14	3	also	also	ADV
br86b279c69	14	4	an	an	DET
br86b279c69	14	5	educational	educational	ADJ
br86b279c69	14	6	example	example	NOUN
br86b279c69	14	7	the	the	DET
br86b279c69	14	8	differences	difference	NOUN
br86b279c69	14	9	that	that	PRON
br86b279c69	14	10	occur	occur	VERB
br86b279c69	14	11	between	between	ADP
br86b279c69	14	12	the	the	DET
br86b279c69	14	13	cluster	cluster	NOUN
br86b279c69	14	14	bonding	bonding	NOUN
br86b279c69	14	15	counts	count	NOUN
br86b279c69	14	16	and	and	CCONJ
br86b279c69	14	17	cluster	cluster	NOUN
br86b279c69	14	18	valence	valence	NOUN
br86b279c69	14	19	counts	count	NOUN
br86b279c69	14	20	once	once	SCONJ
br86b279c69	14	21	clusters	cluster	NOUN
br86b279c69	14	22	enlarge	enlarge	VERB
br86b279c69	14	23	beyond	beyond	ADP
br86b279c69	14	24	spherical	spherical	ADJ
br86b279c69	14	25	shapes	shape	NOUN
br86b279c69	14	26	.	.	PUNCT
br86b279c69	15	1	chapter	chapter	NOUN
br86b279c69	15	2	5	5	NUM
br86b279c69	15	3	,	,	PUNCT
br86b279c69	15	4	address	address	VERB
br86b279c69	15	5	the	the	DET
br86b279c69	15	6	pitfalls	pitfall	NOUN
br86b279c69	15	7	of	of	ADP
br86b279c69	15	8	using	use	VERB
br86b279c69	15	9	naked	naked	ADJ
br86b279c69	15	10	clusters	cluster	NOUN
br86b279c69	15	11	for	for	ADP
br86b279c69	15	12	aggregation	aggregation	NOUN
br86b279c69	15	13	by	by	ADP
br86b279c69	15	14	introducing	introduce	VERB
br86b279c69	15	15	the	the	DET
br86b279c69	15	16	new	new	ADJ
br86b279c69	15	17	developing	develop	VERB
br86b279c69	15	18	field	field	NOUN
br86b279c69	15	19	of	of	ADP
br86b279c69	15	20	ligand	ligand	NOUN
br86b279c69	15	21	protected	protect	VERB
br86b279c69	15	22	-	-	PUNCT
br86b279c69	15	23	zintl	zintl	NOUN
br86b279c69	15	24	clusters	cluster	NOUN
br86b279c69	15	25	generated	generate	VERB
br86b279c69	15	26	from	from	ADP
br86b279c69	15	27	heterogeneous	heterogeneous	ADJ
br86b279c69	15	28	reactions	reaction	NOUN
br86b279c69	15	29	.	.	PUNCT
br86b279c69	16	1	the	the	DET
br86b279c69	16	2	breadth	breadth	NOUN
br86b279c69	16	3	of	of	ADP
br86b279c69	16	4	knowledge	knowledge	NOUN
br86b279c69	16	5	is	be	AUX
br86b279c69	16	6	further	far	ADV
br86b279c69	16	7	expanded	expand	VERB
br86b279c69	16	8	by	by	ADP
br86b279c69	16	9	using	use	VERB
br86b279c69	16	10	stannyl	stannyl	NOUN
br86b279c69	16	11	-	-	PUNCT
br86b279c69	16	12	halides	halide	NOUN
br86b279c69	16	13	to	to	PART
br86b279c69	16	14	generate	generate	VERB
br86b279c69	16	15	tri	tri	ADJ
br86b279c69	16	16	-	-	ADJ
br86b279c69	16	17	substituted	substituted	ADJ
br86b279c69	16	18	germanium	germanium	NOUN
br86b279c69	16	19	clusters	cluster	NOUN
br86b279c69	16	20	as	as	ADP
br86b279c69	16	21	[	[	X
br86b279c69	16	22	ge9{snr3}3	ge9{snr3}3	X
br86b279c69	16	23	]	]	PUNCT
br86b279c69	16	24	–	–	PUNCT
br86b279c69	16	25	(	(	PUNCT
br86b279c69	16	26	r=	r=	PROPN
br86b279c69	16	27	ipr	ipr	PROPN
br86b279c69	16	28	,	,	PUNCT
br86b279c69	16	29	cy	cy	PROPN
br86b279c69	16	30	)	)	PUNCT
br86b279c69	16	31	.	.	PUNCT
br86b279c69	17	1	these	these	DET
br86b279c69	17	2	tri	tri	ADJ
br86b279c69	17	3	-	-	ADJ
br86b279c69	17	4	substituted	substituted	ADJ
br86b279c69	17	5	clusters	cluster	NOUN
br86b279c69	17	6	are	be	AUX
br86b279c69	17	7	used	use	VERB
br86b279c69	17	8	as	as	ADP
br86b279c69	17	9	precursors	precursor	NOUN
br86b279c69	17	10	to	to	PART
br86b279c69	17	11	generate	generate	VERB
br86b279c69	17	12	larger	large	ADJ
br86b279c69	17	13	assemblies	assembly	NOUN
br86b279c69	17	14	with	with	ADP
br86b279c69	17	15	the	the	DET
br86b279c69	17	16	use	use	NOUN
br86b279c69	17	17	of	of	ADP
br86b279c69	17	18	transition	transition	NOUN
br86b279c69	17	19	metals	metal	NOUN
br86b279c69	17	20	,	,	PUNCT
br86b279c69	17	21	pd(pph3)4	pd(pph3)4	VERB
br86b279c69	17	22	in	in	ADP
br86b279c69	17	23	this	this	DET
br86b279c69	17	24	case	case	NOUN
br86b279c69	17	25	.	.	PUNCT
br86b279c69	18	1	the	the	DET
br86b279c69	18	2	generated	generate	VERB
br86b279c69	18	3	[	[	X
br86b279c69	18	4	ge18pd3{er}6]2	ge18pd3{er}6]2	X
br86b279c69	18	5	–	–	PUNCT
br86b279c69	18	6	(	(	PUNCT
br86b279c69	18	7	er	er	INTJ
br86b279c69	18	8	=	=	NOUN
br86b279c69	18	9	snipr3	snipr3	PROPN
br86b279c69	18	10	,	,	PUNCT
br86b279c69	18	11	sncy3	sncy3	PROPN
br86b279c69	18	12	,	,	PUNCT
br86b279c69	18	13	siipr3	siipr3	PROPN
br86b279c69	18	14	)	)	PUNCT
br86b279c69	18	15	"	"	PUNCT
br86b279c69	18	16	twinned	twin	VERB
br86b279c69	18	17	icosahedra	icosahedron	NOUN
br86b279c69	18	18	"	"	PUNCT
br86b279c69	18	19	,	,	PUNCT
br86b279c69	18	20	contains	contain	VERB
br86b279c69	18	21	a	a	DET
br86b279c69	18	22	novel	novel	ADJ
br86b279c69	18	23	architecture	architecture	NOUN
br86b279c69	18	24	and	and	CCONJ
br86b279c69	18	25	unique	unique	ADJ
br86b279c69	18	26	electronic	electronic	ADJ
br86b279c69	18	27	structure	structure	NOUN
br86b279c69	18	28	.	.	PUNCT
br86b279c69	19	1	furthermore	furthermore	ADV
br86b279c69	19	2	,	,	PUNCT
br86b279c69	19	3	the	the	DET
br86b279c69	19	4	nature	nature	NOUN
br86b279c69	19	5	of	of	ADP
br86b279c69	19	6	the	the	DET
br86b279c69	19	7	bound	bound	ADJ
br86b279c69	19	8	substituent	substituent	NOUN
br86b279c69	19	9	in	in	ADP
br86b279c69	19	10	[	[	X
br86b279c69	19	11	ge18pd3{er}6	ge18pd3{er}6	X
br86b279c69	19	12	]	]	PUNCT
br86b279c69	19	13	(	(	PUNCT
br86b279c69	19	14	er	er	INTJ
br86b279c69	19	15	=	=	NOUN
br86b279c69	19	16	snipr3	snipr3	PROPN
br86b279c69	19	17	,	,	PUNCT
br86b279c69	19	18	sncy3	sncy3	PROPN
br86b279c69	19	19	,	,	PUNCT
br86b279c69	19	20	siipr3	siipr3	PROPN
br86b279c69	19	21	)	)	PUNCT
br86b279c69	19	22	moieties	moiety	NOUN
br86b279c69	19	23	can	can	AUX
br86b279c69	19	24	lead	lead	VERB
br86b279c69	19	25	to	to	ADP
br86b279c69	19	26	positional	positional	ADJ
br86b279c69	19	27	isomerism	isomerism	NOUN
br86b279c69	19	28	that	that	PRON
br86b279c69	19	29	has	have	AUX
br86b279c69	19	30	not	not	PART
br86b279c69	19	31	been	be	AUX
br86b279c69	19	32	observed	observe	VERB
br86b279c69	19	33	before	before	ADP
br86b279c69	19	34	in	in	ADP
br86b279c69	19	35	main	main	ADJ
br86b279c69	19	36	group	group	NOUN
br86b279c69	19	37	deltahedral	deltahedral	ADJ
br86b279c69	19	38	clusters	cluster	NOUN
br86b279c69	19	39	.	.	PUNCT
br86b279c69	20	1	the	the	DET
br86b279c69	20	2	phenomena	phenomena	NOUN
br86b279c69	20	3	observed	observe	VERB
br86b279c69	20	4	between	between	ADP
br86b279c69	20	5	case	case	NOUN
br86b279c69	20	6	are	be	AUX
br86b279c69	20	7	elucidated	elucidate	VERB
br86b279c69	20	8	and	and	CCONJ
br86b279c69	20	9	rationalized	rationalize	VERB
br86b279c69	20	10	.	.	PUNCT
br86b279c69	21	1	chapter	chapter	NOUN
br86b279c69	21	2	6	6	NUM
br86b279c69	21	3	,	,	PUNCT
br86b279c69	21	4	describes	describe	VERB
br86b279c69	21	5	the	the	DET
br86b279c69	21	6	further	further	ADJ
br86b279c69	21	7	reactivity	reactivity	NOUN
br86b279c69	21	8	of	of	ADP
br86b279c69	21	9	both	both	CCONJ
br86b279c69	21	10	transition	transition	NOUN
br86b279c69	21	11	metal	metal	NOUN
br86b279c69	21	12	carbonyl	carbonyl	NOUN
br86b279c69	21	13	and	and	CCONJ
br86b279c69	21	14	hypersilyl	hypersilyl	ADJ
br86b279c69	21	15	ligated	ligated	ADJ
br86b279c69	21	16	zintl	zintl	PROPN
br86b279c69	21	17	clusters	cluster	NOUN
br86b279c69	21	18	.	.	PUNCT
br86b279c69	22	1	the	the	DET
br86b279c69	22	2	reactions	reaction	NOUN
br86b279c69	22	3	conducted	conduct	VERB
br86b279c69	22	4	,	,	PUNCT
br86b279c69	22	5	demonstrate	demonstrate	VERB
br86b279c69	22	6	that	that	SCONJ
br86b279c69	22	7	both	both	DET
br86b279c69	22	8	types	type	NOUN
br86b279c69	22	9	of	of	ADP
br86b279c69	22	10	clusters	cluster	NOUN
br86b279c69	22	11	have	have	VERB
br86b279c69	22	12	unexplored	unexplored	ADJ
br86b279c69	22	13	reactivity	reactivity	NOUN
br86b279c69	22	14	and	and	CCONJ
br86b279c69	22	15	that	that	SCONJ
br86b279c69	22	16	modern	modern	ADJ
br86b279c69	22	17	organometallic	organometallic	ADJ
br86b279c69	22	18	synthetic	synthetic	ADJ
br86b279c69	22	19	approaches	approach	NOUN
br86b279c69	22	20	can	can	AUX
br86b279c69	22	21	be	be	AUX
br86b279c69	22	22	applied	apply	VERB
br86b279c69	22	23	to	to	ADP
br86b279c69	22	24	them	they	PRON
br86b279c69	22	25	.	.	PUNCT
br86b279c69	23	1	this	this	DET
br86b279c69	23	2	avenue	avenue	NOUN
br86b279c69	23	3	of	of	ADP
br86b279c69	23	4	research	research	NOUN
br86b279c69	23	5	holds	hold	VERB
br86b279c69	23	6	great	great	ADJ
br86b279c69	23	7	promise	promise	NOUN
br86b279c69	23	8	for	for	ADP
br86b279c69	23	9	further	far	ADV
br86b279c69	23	10	exploration.lastly	exploration.lastly	ADV
br86b279c69	23	11	,	,	PUNCT
br86b279c69	23	12	this	this	DET
br86b279c69	23	13	tome	tome	NOUN
br86b279c69	23	14	ends	end	VERB
br86b279c69	23	15	with	with	ADP
br86b279c69	23	16	a	a	DET
br86b279c69	23	17	summary	summary	NOUN
br86b279c69	23	18	and	and	CCONJ
br86b279c69	23	19	discussion	discussion	NOUN
br86b279c69	23	20	of	of	ADP
br86b279c69	23	21	possible	possible	ADJ
br86b279c69	23	22	avenues	avenue	NOUN
br86b279c69	23	23	of	of	ADP
br86b279c69	23	24	research	research	NOUN
br86b279c69	23	25	.	.	PUNCT
br86b279c69	24	1	primarily	primarily	ADV
br86b279c69	24	2	focused	focus	VERB
br86b279c69	24	3	on	on	ADP
br86b279c69	24	4	the	the	DET
br86b279c69	24	5	generation	generation	NOUN
br86b279c69	24	6	of	of	ADP
br86b279c69	24	7	larger	large	ADJ
br86b279c69	24	8	assemblies	assembly	NOUN
br86b279c69	24	9	and	and	CCONJ
br86b279c69	24	10	exploration	exploration	NOUN
br86b279c69	24	11	of	of	ADP
br86b279c69	24	12	different	different	ADJ
br86b279c69	24	13	ligands	ligand	NOUN
br86b279c69	24	14	for	for	ADP
br86b279c69	24	15	use	use	NOUN
br86b279c69	24	16	in	in	ADP
br86b279c69	24	17	heterogeneous	heterogeneous	ADJ
br86b279c69	24	18	reactions	reaction	NOUN
br86b279c69	24	19	.	.	PUNCT