id sid tid token lemma pos c247dr29203 1 1 the the DET c247dr29203 1 2 synthesis synthesis NOUN c247dr29203 1 3 and and CCONJ c247dr29203 1 4 characterization characterization NOUN c247dr29203 1 5 of of ADP c247dr29203 1 6 hydrogen hydrogen NOUN c247dr29203 1 7 - - PUNCT c247dr29203 1 8 bonded bond VERB c247dr29203 1 9 cobalt cobalt NOUN c247dr29203 1 10 amine amine NOUN c247dr29203 1 11 - - PUNCT c247dr29203 1 12 disulfonate disulfonate NOUN c247dr29203 1 13 frameworks framework NOUN c247dr29203 1 14 was be AUX c247dr29203 1 15 attempted attempt VERB c247dr29203 1 16 . . PUNCT c247dr29203 2 1 syntheses synthesis NOUN c247dr29203 2 2 were be AUX c247dr29203 2 3 carried carry VERB c247dr29203 2 4 out out ADP c247dr29203 2 5 either either CCONJ c247dr29203 2 6 through through ADP c247dr29203 2 7 evaporation evaporation NOUN c247dr29203 2 8 of of ADP c247dr29203 2 9 aqueous aqueous ADJ c247dr29203 2 10 mixtures mixture NOUN c247dr29203 2 11 of of ADP c247dr29203 2 12 the the DET c247dr29203 2 13 starting starting NOUN c247dr29203 2 14 materials material NOUN c247dr29203 2 15 or or CCONJ c247dr29203 2 16 through through ADP c247dr29203 2 17 slow slow ADJ c247dr29203 2 18 diffusion diffusion NOUN c247dr29203 2 19 of of ADP c247dr29203 2 20 the the DET c247dr29203 2 21 starting starting NOUN c247dr29203 2 22 materials material NOUN c247dr29203 2 23 in in ADP c247dr29203 2 24 a a DET c247dr29203 2 25 two two NUM c247dr29203 2 26 - - PUNCT c247dr29203 2 27 solvent solvent NOUN c247dr29203 2 28 system system NOUN c247dr29203 2 29 . . PUNCT c247dr29203 3 1 crystals crystal NOUN c247dr29203 3 2 were be AUX c247dr29203 3 3 successfully successfully ADV c247dr29203 3 4 synthesized synthesize VERB c247dr29203 3 5 from from ADP c247dr29203 3 6 four four NUM c247dr29203 3 7 metal metal NOUN c247dr29203 3 8 centers center NOUN c247dr29203 3 9 ( ( PUNCT c247dr29203 3 10 hexaamminecobalt hexaamminecobalt PROPN c247dr29203 3 11 , , PUNCT c247dr29203 3 12 aquopentaaminecobalt aquopentaaminecobalt VERB c247dr29203 3 13 , , PUNCT c247dr29203 3 14 tris(ethylenediamine)cobalt tris(ethylenediamine)cobalt NOUN c247dr29203 3 15 and and CCONJ c247dr29203 3 16 diaquobis(ethylenediamine)cobalt diaquobis(ethylenediamine)cobalt ADP c247dr29203 3 17 ) ) PUNCT c247dr29203 3 18 and and CCONJ c247dr29203 3 19 four four NUM c247dr29203 3 20 organic organic ADJ c247dr29203 3 21 linkers linker NOUN c247dr29203 3 22 1,2 1,2 PROPN c247dr29203 3 23 - - PUNCT c247dr29203 3 24 ethanedisulfonate ethanedisulfonate NOUN c247dr29203 3 25 , , PUNCT c247dr29203 3 26 1,5 1,5 NUM c247dr29203 3 27 - - PUNCT c247dr29203 3 28 naphthalenedisulfonate naphthalenedisulfonate ADJ c247dr29203 3 29 , , PUNCT c247dr29203 3 30 2,6 2,6 NOUN c247dr29203 3 31 - - PUNCT c247dr29203 3 32 naphthalenedisulfonate naphthalenedisulfonate NOUN c247dr29203 3 33 and and CCONJ c247dr29203 3 34 4,4'-biphenyldisulfonate 4,4'-biphenyldisulfonate NUM c247dr29203 3 35 ) ) PUNCT c247dr29203 3 36 . . PUNCT c247dr29203 4 1 four four NUM c247dr29203 4 2 structures structure NOUN c247dr29203 4 3 will will AUX c247dr29203 4 4 be be AUX c247dr29203 4 5 described describe VERB c247dr29203 4 6 and and CCONJ c247dr29203 4 7 discussed discuss VERB c247dr29203 4 8 herein herein ADV c247dr29203 4 9 . . PUNCT c247dr29203 5 1 three three NUM c247dr29203 5 2 structures structure NOUN c247dr29203 5 3 take take VERB c247dr29203 5 4 on on ADP c247dr29203 5 5 layered layered ADJ c247dr29203 5 6 motifs motif NOUN c247dr29203 5 7 . . PUNCT c247dr29203 6 1 compounds compound NOUN c247dr29203 6 2 1 1 NUM c247dr29203 6 3 and and CCONJ c247dr29203 6 4 2 2 NUM c247dr29203 6 5 form form NOUN c247dr29203 6 6 sheets sheet NOUN c247dr29203 6 7 of of ADP c247dr29203 6 8 hexa hexa NOUN c247dr29203 6 9 and and CCONJ c247dr29203 6 10 aquopentamminecobalt aquopentamminecobalt PROPN c247dr29203 6 11 , , PUNCT c247dr29203 6 12 respectively respectively ADV c247dr29203 6 13 , , PUNCT c247dr29203 6 14 that that PRON c247dr29203 6 15 are be AUX c247dr29203 6 16 interconnected interconnect VERB c247dr29203 6 17 by by ADP c247dr29203 6 18 galleries gallery NOUN c247dr29203 6 19 of of ADP c247dr29203 6 20 disulfonates disulfonate NOUN c247dr29203 6 21 . . PUNCT c247dr29203 7 1 compound compound NOUN c247dr29203 7 2 3 3 NUM c247dr29203 7 3 forms form NOUN c247dr29203 7 4 a a DET c247dr29203 7 5 layered layered ADJ c247dr29203 7 6 structure structure NOUN c247dr29203 7 7 of of ADP c247dr29203 7 8 tris(ethylenediamine)cobalt tris(ethylenediamine)cobalt NOUN c247dr29203 7 9 sheets sheet NOUN c247dr29203 7 10 with with ADP c247dr29203 7 11 two two NUM c247dr29203 7 12 different different ADJ c247dr29203 7 13 disulfonate disulfonate NOUN c247dr29203 7 14 gallery gallery NOUN c247dr29203 7 15 arrangements arrangement NOUN c247dr29203 7 16 , , PUNCT c247dr29203 7 17 one one NUM c247dr29203 7 18 of of ADP c247dr29203 7 19 which which PRON c247dr29203 7 20 forms form VERB c247dr29203 7 21 one one NUM c247dr29203 7 22 - - PUNCT c247dr29203 7 23 dimensional dimensional ADJ c247dr29203 7 24 channels channel NOUN c247dr29203 7 25 . . PUNCT c247dr29203 8 1 compound compound NOUN c247dr29203 8 2 4 4 NUM c247dr29203 8 3 forms form NOUN c247dr29203 8 4 interconnected interconnect VERB c247dr29203 8 5 tubes tube NOUN c247dr29203 8 6 of of ADP c247dr29203 8 7 tris(ethylenediamine)cobalt tris(ethylenediamine)cobalt PROPN c247dr29203 8 8 with with ADP c247dr29203 8 9 the the DET c247dr29203 8 10 disulfonates disulfonate NOUN c247dr29203 8 11 filling fill VERB c247dr29203 8 12 the the DET c247dr29203 8 13 interiors interior NOUN c247dr29203 8 14 of of ADP c247dr29203 8 15 the the DET c247dr29203 8 16 tubes tube NOUN c247dr29203 8 17 . . PUNCT c247dr29203 9 1 compounds compound NOUN c247dr29203 9 2 2 2 NUM c247dr29203 9 3 - - SYM c247dr29203 9 4 4 4 NUM c247dr29203 9 5 display display NOUN c247dr29203 9 6 pi pi NOUN c247dr29203 9 7 - - PUNCT c247dr29203 9 8 pi pi NOUN c247dr29203 9 9 interactions interaction NOUN c247dr29203 9 10 between between ADP c247dr29203 9 11 disulfonates.every disulfonates.every NOUN c247dr29203 9 12 structure structure NOUN c247dr29203 9 13 is be AUX c247dr29203 9 14 held hold VERB c247dr29203 9 15 together together ADV c247dr29203 9 16 by by ADP c247dr29203 9 17 hydrogen hydrogen NOUN c247dr29203 9 18 bonds bond NOUN c247dr29203 9 19 and and CCONJ c247dr29203 9 20 contains contain VERB c247dr29203 9 21 solvent solvent ADJ c247dr29203 9 22 guests guest NOUN c247dr29203 9 23 . . PUNCT