id sid tid token lemma pos k356931058v 1 1 herein herein ADV k356931058v 1 2 , , PUNCT k356931058v 1 3 we we PRON k356931058v 1 4 developed develop VERB k356931058v 1 5 a a DET k356931058v 1 6 calorimetric calorimetric ADJ k356931058v 1 7 method method NOUN k356931058v 1 8 to to PART k356931058v 1 9 obtain obtain VERB k356931058v 1 10 new new ADJ k356931058v 1 11 thermodynamic thermodynamic ADJ k356931058v 1 12 values value NOUN k356931058v 1 13 for for ADP k356931058v 1 14 polyoxometalates polyoxometalate NOUN k356931058v 1 15 ( ( PUNCT k356931058v 1 16 poms pom NOUN k356931058v 1 17 ) ) PUNCT k356931058v 1 18 that that PRON k356931058v 1 19 helped helped AUX k356931058v 1 20 elucidate elucidate VERB k356931058v 1 21 their their PRON k356931058v 1 22 thermodynamic thermodynamic ADJ k356931058v 1 23 landscape landscape NOUN k356931058v 1 24 . . PUNCT k356931058v 2 1 the the DET k356931058v 2 2 studies study NOUN k356931058v 2 3 were be AUX k356931058v 2 4 primarily primarily ADV k356931058v 2 5 conducted conduct VERB k356931058v 2 6 on on ADP k356931058v 2 7 uranyl uranyl ADJ k356931058v 2 8 peroxide peroxide NOUN k356931058v 2 9 nanoclusters nanocluster NOUN k356931058v 2 10 ( ( PUNCT k356931058v 2 11 upcs upc NOUN k356931058v 2 12 ) ) PUNCT k356931058v 2 13 . . PUNCT k356931058v 3 1 in in ADP k356931058v 3 2 the the DET k356931058v 3 3 16 16 NUM k356931058v 3 4 years year NOUN k356931058v 3 5 since since SCONJ k356931058v 3 6 the the DET k356931058v 3 7 discovery discovery NOUN k356931058v 3 8 of of ADP k356931058v 3 9 upcs upc NOUN k356931058v 3 10 , , PUNCT k356931058v 3 11 over over ADP k356931058v 3 12 60 60 NUM k356931058v 3 13 have have AUX k356931058v 3 14 been be AUX k356931058v 3 15 reported report VERB k356931058v 3 16 , , PUNCT k356931058v 3 17 but but CCONJ k356931058v 3 18 their their PRON k356931058v 3 19 assembly assembly NOUN k356931058v 3 20 and and CCONJ k356931058v 3 21 solution solution NOUN k356931058v 3 22 behavior behavior NOUN k356931058v 3 23 is be AUX k356931058v 3 24 still still ADV k356931058v 3 25 perplexing perplexing ADJ k356931058v 3 26 . . PUNCT k356931058v 4 1 thermodynamics thermodynamic NOUN k356931058v 4 2 can can AUX k356931058v 4 3 provide provide VERB k356931058v 4 4 a a DET k356931058v 4 5 quantitative quantitative ADJ k356931058v 4 6 analysis analysis NOUN k356931058v 4 7 to to PART k356931058v 4 8 predict predict VERB k356931058v 4 9 and and CCONJ k356931058v 4 10 study study VERB k356931058v 4 11 upc upc NOUN k356931058v 4 12 stability stability NOUN k356931058v 4 13 and and CCONJ k356931058v 4 14 solubility solubility NOUN k356931058v 4 15 , , PUNCT k356931058v 4 16 and and CCONJ k356931058v 4 17 chemical chemical NOUN k356931058v 4 18 processes process NOUN k356931058v 4 19 in in ADP k356931058v 4 20 solution.in solution.in NUM k356931058v 4 21 total total NOUN k356931058v 4 22 , , PUNCT k356931058v 4 23 the the DET k356931058v 4 24 energy energy NOUN k356931058v 4 25 landscapes landscape NOUN k356931058v 4 26 for for ADP k356931058v 4 27 10 10 NUM k356931058v 4 28 upcs upc NOUN k356931058v 4 29 , , PUNCT k356931058v 4 30 two two NUM k356931058v 4 31 mo mo NOUN k356931058v 4 32 poms pom NOUN k356931058v 4 33 , , PUNCT k356931058v 4 34 and and CCONJ k356931058v 4 35 one one NUM k356931058v 4 36 uranyl uranyl ADJ k356931058v 4 37 peroxide peroxide NOUN k356931058v 4 38 monomer monomer NOUN k356931058v 4 39 ( ( PUNCT k356931058v 4 40 building build VERB k356931058v 4 41 block block NOUN k356931058v 4 42 of of ADP k356931058v 4 43 upcs upc NOUN k356931058v 4 44 ) ) PUNCT k356931058v 4 45 were be AUX k356931058v 4 46 analyzed analyze VERB k356931058v 4 47 by by ADP k356931058v 4 48 obtaining obtain VERB k356931058v 4 49 values value NOUN k356931058v 4 50 for for ADP k356931058v 4 51 enthalpy enthalpy NOUN k356931058v 4 52 of of ADP k356931058v 4 53 formation formation NOUN k356931058v 4 54 of of ADP k356931058v 4 55 pom pom NOUN k356931058v 4 56 crystals crystal NOUN k356931058v 4 57 ( ( PUNCT k356931058v 4 58 δhf,(c δhf,(c NOUN k356931058v 4 59 ) ) PUNCT k356931058v 4 60 ) ) PUNCT k356931058v 4 61 , , PUNCT k356931058v 4 62 enthalpy enthalpy NOUN k356931058v 4 63 of of ADP k356931058v 4 64 formation formation NOUN k356931058v 4 65 of of ADP k356931058v 4 66 aqueous aqueous ADJ k356931058v 4 67 poms pom NOUN k356931058v 4 68 ( ( PUNCT k356931058v 4 69 δhf,(aq δhf,(aq PROPN k356931058v 4 70 ) ) PUNCT k356931058v 4 71 ) ) PUNCT k356931058v 4 72 , , PUNCT k356931058v 4 73 and and CCONJ k356931058v 4 74 enthalpy enthalpy NOUN k356931058v 4 75 of of ADP k356931058v 4 76 dissolution dissolution NOUN k356931058v 4 77 ( ( PUNCT k356931058v 4 78 δhdiss δhdiss PROPN k356931058v 4 79 ) ) PUNCT k356931058v 4 80 . . PUNCT k356931058v 5 1 the the DET k356931058v 5 2 results result NOUN k356931058v 5 3 allowed allow VERB k356931058v 5 4 us we PRON k356931058v 5 5 to to PART k356931058v 5 6 predict predict VERB k356931058v 5 7 the the DET k356931058v 5 8 conversion conversion NOUN k356931058v 5 9 of of ADP k356931058v 5 10 lina lina NOUN k356931058v 5 11 - - PUNCT k356931058v 5 12 u24pp12 u24pp12 NOUN k356931058v 5 13 to to ADP k356931058v 5 14 lina lina NOUN k356931058v 5 15 - - PUNCT k356931058v 5 16 u24 u24 PROPN k356931058v 5 17 and and CCONJ k356931058v 5 18 li li PROPN k356931058v 5 19 - - PUNCT k356931058v 5 20 u28 u28 NOUN k356931058v 5 21 to to ADP k356931058v 5 22 lica lica PROPN k356931058v 5 23 - - PUNCT k356931058v 5 24 u24 u24 PROPN k356931058v 5 25 and and CCONJ k356931058v 5 26 elucidate elucidate VERB k356931058v 5 27 their their PRON k356931058v 5 28 transformations transformation NOUN k356931058v 5 29 ; ; PUNCT k356931058v 5 30 and and CCONJ k356931058v 5 31 the the DET k356931058v 5 32 enthalpy enthalpy NOUN k356931058v 5 33 of of ADP k356931058v 5 34 conversion conversion NOUN k356931058v 5 35 from from ADP k356931058v 5 36 lithium lithium NOUN k356931058v 5 37 uranyl uranyl ADJ k356931058v 5 38 triperoxide triperoxide ADJ k356931058v 5 39 monomer monomer NOUN k356931058v 5 40 to to ADP k356931058v 5 41 u24 u24 NOUN k356931058v 5 42 and and CCONJ k356931058v 5 43 u28 u28 PROPN k356931058v 5 44 was be AUX k356931058v 5 45 determined determined ADJ k356931058v 5 46 to to PART k356931058v 5 47 be be AUX k356931058v 5 48 negative negative ADJ k356931058v 5 49 , , PUNCT k356931058v 5 50 which which PRON k356931058v 5 51 is be AUX k356931058v 5 52 in in ADP k356931058v 5 53 agreement agreement NOUN k356931058v 5 54 with with ADP k356931058v 5 55 literature literature NOUN k356931058v 5 56 observations observation NOUN k356931058v 5 57 . . PUNCT k356931058v 6 1 additionally additionally ADV k356931058v 6 2 , , PUNCT k356931058v 6 3 our our PRON k356931058v 6 4 results result NOUN k356931058v 6 5 reveal reveal VERB k356931058v 6 6 that that SCONJ k356931058v 6 7 δhdiss δhdiss NOUN k356931058v 6 8 is be AUX k356931058v 6 9 highly highly ADV k356931058v 6 10 dependent dependent ADJ k356931058v 6 11 on on ADP k356931058v 6 12 the the DET k356931058v 6 13 entity entity NOUN k356931058v 6 14 of of ADP k356931058v 6 15 the the DET k356931058v 6 16 counter counter NOUN k356931058v 6 17 cations cation NOUN k356931058v 6 18 and and CCONJ k356931058v 6 19 their their PRON k356931058v 6 20 affinities affinity NOUN k356931058v 6 21 with with ADP k356931058v 6 22 the the DET k356931058v 6 23 topological topological ADJ k356931058v 6 24 features feature NOUN k356931058v 6 25 of of ADP k356931058v 6 26 the the DET k356931058v 6 27 upcs upc NOUN k356931058v 6 28 , , PUNCT k356931058v 6 29 and and CCONJ k356931058v 6 30 a a DET k356931058v 6 31 complex complex ADJ k356931058v 6 32 but but CCONJ k356931058v 6 33 linear linear ADJ k356931058v 6 34 relationship relationship NOUN k356931058v 6 35 between between ADP k356931058v 6 36 δhdiss δhdiss PROPN k356931058v 6 37 and and CCONJ k356931058v 6 38 the the DET k356931058v 6 39 cluster cluster NOUN k356931058v 6 40 solubility solubility NOUN k356931058v 6 41 exists exist VERB k356931058v 6 42 . . PUNCT