id sid tid token lemma pos ms35t724v04 1 1 the the DET ms35t724v04 1 2 aims aim NOUN ms35t724v04 1 3 of of ADP ms35t724v04 1 4 this this DET ms35t724v04 1 5 dissertation dissertation NOUN ms35t724v04 1 6 are be AUX ms35t724v04 1 7 to to PART ms35t724v04 1 8 explore explore VERB ms35t724v04 1 9 isotope isotope NOUN ms35t724v04 1 10 labeling labeling NOUN ms35t724v04 1 11 of of ADP ms35t724v04 1 12 biologically biologically ADV ms35t724v04 1 13 important important ADJ ms35t724v04 1 14 saccharides saccharide NOUN ms35t724v04 1 15 , , PUNCT ms35t724v04 1 16 and and CCONJ ms35t724v04 1 17 establish establish VERB ms35t724v04 1 18 new new ADJ ms35t724v04 1 19 correlations correlation NOUN ms35t724v04 1 20 between between ADP ms35t724v04 1 21 nmr nmr NOUN ms35t724v04 1 22 parameters parameter NOUN ms35t724v04 1 23 and and CCONJ ms35t724v04 1 24 molecular molecular ADJ ms35t724v04 1 25 structures structure NOUN ms35t724v04 1 26 with with ADP ms35t724v04 1 27 a a DET ms35t724v04 1 28 particular particular ADJ ms35t724v04 1 29 focus focus NOUN ms35t724v04 1 30 on on ADP ms35t724v04 1 31 trans trans ADJ ms35t724v04 1 32 - - NOUN ms35t724v04 1 33 glycoside glycoside ADJ ms35t724v04 1 34 scalar scalar ADJ ms35t724v04 1 35 couplings coupling NOUN ms35t724v04 1 36 and and CCONJ ms35t724v04 1 37 their their PRON ms35t724v04 1 38 application application NOUN ms35t724v04 1 39 to to ADP ms35t724v04 1 40 the the DET ms35t724v04 1 41 studies study NOUN ms35t724v04 1 42 of of ADP ms35t724v04 1 43 glycosidic glycosidic ADJ ms35t724v04 1 44 linkage linkage NOUN ms35t724v04 1 45 conformation conformation NOUN ms35t724v04 1 46 . . PUNCT ms35t724v04 2 1 the the DET ms35t724v04 2 2 work work NOUN ms35t724v04 2 3 is be AUX ms35t724v04 2 4 divided divide VERB ms35t724v04 2 5 into into ADP ms35t724v04 2 6 five five NUM ms35t724v04 2 7 parts part NOUN ms35t724v04 2 8 . . PUNCT ms35t724v04 3 1 chapter chapter NOUN ms35t724v04 3 2 2 2 NUM ms35t724v04 3 3 reports report VERB ms35t724v04 3 4 a a DET ms35t724v04 3 5 novel novel ADJ ms35t724v04 3 6 synthesis synthesis NOUN ms35t724v04 3 7 of of ADP ms35t724v04 3 8 the the DET ms35t724v04 3 9 disaccharide disaccharide NOUN ms35t724v04 3 10 , , PUNCT ms35t724v04 3 11 alpha alpha NOUN ms35t724v04 3 12 - - PUNCT ms35t724v04 3 13 d d NOUN ms35t724v04 3 14 - - PUNCT ms35t724v04 3 15 gal-(1 gal-(1 ADJ ms35t724v04 3 16 - - PUNCT ms35t724v04 3 17 3)-beta 3)-beta NUM ms35t724v04 3 18 - - PUNCT ms35t724v04 3 19 d d NOUN ms35t724v04 3 20 - - PUNCT ms35t724v04 3 21 galome galome NOUN ms35t724v04 3 22 , , PUNCT ms35t724v04 3 23 which which PRON ms35t724v04 3 24 is be AUX ms35t724v04 3 25 the the DET ms35t724v04 3 26 main main ADJ ms35t724v04 3 27 cause cause NOUN ms35t724v04 3 28 of of ADP ms35t724v04 3 29 antibody antibody NOUN ms35t724v04 3 30 - - PUNCT ms35t724v04 3 31 mediated mediate VERB ms35t724v04 3 32 hyperacute hyperacute ADJ ms35t724v04 3 33 rejection rejection NOUN ms35t724v04 3 34 in in ADP ms35t724v04 3 35 xenotransplantation xenotransplantation NOUN ms35t724v04 3 36 . . PUNCT ms35t724v04 4 1 this this DET ms35t724v04 4 2 disaccharide disaccharide NOUN ms35t724v04 4 3 was be AUX ms35t724v04 4 4 selectively selectively ADV ms35t724v04 4 5 labeled label VERB ms35t724v04 4 6 with with ADP ms35t724v04 4 7 13c 13c NOUN ms35t724v04 4 8 in in ADP ms35t724v04 4 9 a a DET ms35t724v04 4 10 manner manner NOUN ms35t724v04 4 11 that that PRON ms35t724v04 4 12 allows allow VERB ms35t724v04 4 13 accurate accurate ADJ ms35t724v04 4 14 measurement measurement NOUN ms35t724v04 4 15 of of ADP ms35t724v04 4 16 all all DET ms35t724v04 4 17 available available ADJ ms35t724v04 4 18 inter inter ADJ ms35t724v04 4 19 - - ADJ ms35t724v04 4 20 residue residue ADJ ms35t724v04 4 21 carbon carbon NOUN ms35t724v04 4 22 - - PUNCT ms35t724v04 4 23 based base VERB ms35t724v04 4 24 nmr nmr PROPN ms35t724v04 4 25 spin spin NOUN ms35t724v04 4 26 - - PUNCT ms35t724v04 4 27 couplings coupling NOUN ms35t724v04 4 28 sensitive sensitive ADJ ms35t724v04 4 29 to to ADP ms35t724v04 4 30 linkage linkage NOUN ms35t724v04 4 31 conformation conformation NOUN ms35t724v04 4 32 . . PUNCT ms35t724v04 5 1 these these DET ms35t724v04 5 2 j j NOUN ms35t724v04 5 3 - - PUNCT ms35t724v04 5 4 couplings coupling NOUN ms35t724v04 5 5 were be AUX ms35t724v04 5 6 interpreted interpret VERB ms35t724v04 5 7 using use VERB ms35t724v04 5 8 karplus karplus ADJ ms35t724v04 5 9 - - PUNCT ms35t724v04 5 10 type type NOUN ms35t724v04 5 11 equations equation NOUN ms35t724v04 5 12 derived derive VERB ms35t724v04 5 13 from from ADP ms35t724v04 5 14 density density NOUN ms35t724v04 5 15 functional functional ADJ ms35t724v04 5 16 theory theory NOUN ms35t724v04 5 17 ( ( PUNCT ms35t724v04 5 18 dft dft NOUN ms35t724v04 5 19 ) ) PUNCT ms35t724v04 5 20 calculations calculation NOUN ms35t724v04 5 21 and and CCONJ ms35t724v04 5 22 mathematical mathematical ADJ ms35t724v04 5 23 modeling modeling NOUN ms35t724v04 5 24 . . PUNCT ms35t724v04 6 1 chapter chapter NOUN ms35t724v04 6 2 3 3 NUM ms35t724v04 6 3 reports report VERB ms35t724v04 6 4 a a DET ms35t724v04 6 5 simplified simplified ADJ ms35t724v04 6 6 cyanohydrin cyanohydrin NOUN ms35t724v04 6 7 synthetic synthetic ADJ ms35t724v04 6 8 route route NOUN ms35t724v04 6 9 to to PART ms35t724v04 6 10 prepare prepare VERB ms35t724v04 6 11 a a DET ms35t724v04 6 12 series series NOUN ms35t724v04 6 13 of of ADP ms35t724v04 6 14 2 2 NUM ms35t724v04 6 15 - - PUNCT ms35t724v04 6 16 amino-2 amino-2 NUM ms35t724v04 6 17 - - PUNCT ms35t724v04 6 18 deoxy deoxy NOUN ms35t724v04 6 19 - - PUNCT ms35t724v04 6 20 d-[1 d-[1 NOUN ms35t724v04 6 21 - - PUNCT ms35t724v04 6 22 13c]aldohexoses 13c]aldohexoses NUM ms35t724v04 6 23 and and CCONJ ms35t724v04 6 24 their their PRON ms35t724v04 6 25 methyl methyl NOUN ms35t724v04 6 26 glycosides glycoside NOUN ms35t724v04 6 27 . . PUNCT ms35t724v04 7 1 jch jch PROPN ms35t724v04 7 2 and and CCONJ ms35t724v04 7 3 jcc jcc PROPN ms35t724v04 7 4 spin spin NOUN ms35t724v04 7 5 - - PUNCT ms35t724v04 7 6 spin spin NOUN ms35t724v04 7 7 coupling coupling NOUN ms35t724v04 7 8 constants constant NOUN ms35t724v04 7 9 involving involve VERB ms35t724v04 7 10 the the DET ms35t724v04 7 11 labeled label VERB ms35t724v04 7 12 anomeric anomeric ADJ ms35t724v04 7 13 carbon carbon NOUN ms35t724v04 7 14 were be AUX ms35t724v04 7 15 measured measure VERB ms35t724v04 7 16 and and CCONJ ms35t724v04 7 17 compared compare VERB ms35t724v04 7 18 to to ADP ms35t724v04 7 19 those those PRON ms35t724v04 7 20 observed observe VERB ms35t724v04 7 21 previously previously ADV ms35t724v04 7 22 in in ADP ms35t724v04 7 23 methyl methyl NOUN ms35t724v04 7 24 d-[1 d-[1 SPACE ms35t724v04 7 25 - - PUNCT ms35t724v04 7 26 13c]aldohexopyranosides 13c]aldohexopyranosides NUM ms35t724v04 7 27 . . PUNCT ms35t724v04 8 1 theoretical theoretical ADJ ms35t724v04 8 2 j j NOUN ms35t724v04 8 3 - - PUNCT ms35t724v04 8 4 couplings coupling NOUN ms35t724v04 8 5 were be AUX ms35t724v04 8 6 calculated calculate VERB ms35t724v04 8 7 in in ADP ms35t724v04 8 8 model model NOUN ms35t724v04 8 9 n n ADV ms35t724v04 8 10 - - PUNCT ms35t724v04 8 11 acetylated acetylate VERB ms35t724v04 8 12 aldopyranosides aldopyranoside NOUN ms35t724v04 8 13 by by ADP ms35t724v04 8 14 dft dft NOUN ms35t724v04 8 15 to to PART ms35t724v04 8 16 predict predict VERB ms35t724v04 8 17 the the DET ms35t724v04 8 18 effect effect NOUN ms35t724v04 8 19 of of ADP ms35t724v04 8 20 oh oh INTJ ms35t724v04 8 21 vs vs ADP ms35t724v04 8 22 nhcoch3 nhcoch3 ADJ ms35t724v04 8 23 substitution substitution NOUN ms35t724v04 8 24 at at ADP ms35t724v04 8 25 c2 c2 PROPN ms35t724v04 8 26 on on ADP ms35t724v04 8 27 jch jch PROPN ms35t724v04 8 28 and and CCONJ ms35t724v04 8 29 jcc jcc PROPN ms35t724v04 8 30 values value NOUN ms35t724v04 8 31 in in ADP ms35t724v04 8 32 aldopyranosyl aldopyranosyl NOUN ms35t724v04 8 33 rings ring NOUN ms35t724v04 8 34 . . PUNCT ms35t724v04 9 1 the the DET ms35t724v04 9 2 synthetic synthetic ADJ ms35t724v04 9 3 method method NOUN ms35t724v04 9 4 was be AUX ms35t724v04 9 5 also also ADV ms35t724v04 9 6 modified modify VERB ms35t724v04 9 7 to to PART ms35t724v04 9 8 accommodate accommodate VERB ms35t724v04 9 9 15nand 15nand NUM ms35t724v04 9 10 13c 13c NUM ms35t724v04 9 11 - - PUNCT ms35t724v04 9 12 labeling labeling NOUN ms35t724v04 9 13 within within ADP ms35t724v04 9 14 the the DET ms35t724v04 9 15 n n NOUN ms35t724v04 9 16 - - PUNCT ms35t724v04 9 17 acetyl acetyl NOUN ms35t724v04 9 18 side side NOUN ms35t724v04 9 19 - - PUNCT ms35t724v04 9 20 chain chain NOUN ms35t724v04 9 21 , , PUNCT ms35t724v04 9 22 methodology methodology NOUN ms35t724v04 9 23 explored explore VERB ms35t724v04 9 24 in in ADP ms35t724v04 9 25 chapter chapter NOUN ms35t724v04 9 26 4 4 NUM ms35t724v04 9 27 . . PUNCT ms35t724v04 10 1 chapter chapter NOUN ms35t724v04 10 2 4 4 NUM ms35t724v04 10 3 reports report VERB ms35t724v04 10 4 the the DET ms35t724v04 10 5 preparation preparation NOUN ms35t724v04 10 6 of of ADP ms35t724v04 10 7 , , PUNCT ms35t724v04 10 8 and and CCONJ ms35t724v04 10 9 nmr nmr PROPN ms35t724v04 10 10 measurements measurement NOUN ms35t724v04 10 11 of of ADP ms35t724v04 10 12 j j NOUN ms35t724v04 10 13 - - PUNCT ms35t724v04 10 14 couplings coupling NOUN ms35t724v04 10 15 in in ADP ms35t724v04 10 16 eight eight NUM ms35t724v04 10 17 compounds compound NOUN ms35t724v04 10 18 : : PUNCT ms35t724v04 10 19 alpha alpha NOUN ms35t724v04 10 20 and and CCONJ ms35t724v04 10 21 beta beta NOUN ms35t724v04 10 22 methyl methyl NOUN ms35t724v04 10 23 glycosides glycoside NOUN ms35t724v04 10 24 of of ADP ms35t724v04 10 25 n n NOUN ms35t724v04 10 26 - - PUNCT ms35t724v04 10 27 acetyl acetyl NOUN ms35t724v04 10 28 - - PUNCT ms35t724v04 10 29 d d NOUN ms35t724v04 10 30 - - NOUN ms35t724v04 10 31 glucosamine glucosamine NOUN ms35t724v04 10 32 and and CCONJ ms35t724v04 10 33 n n NOUN ms35t724v04 10 34 - - PUNCT ms35t724v04 10 35 acetyl acetyl NOUN ms35t724v04 10 36 - - PUNCT ms35t724v04 10 37 d d NOUN ms35t724v04 10 38 - - NOUN ms35t724v04 10 39 allosamine allosamine NOUN ms35t724v04 10 40 which which PRON ms35t724v04 10 41 were be AUX ms35t724v04 10 42 13c 13c NUM ms35t724v04 10 43 labeled label VERB ms35t724v04 10 44 at at ADP ms35t724v04 10 45 c1 c1 PROPN ms35t724v04 10 46 / / SYM ms35t724v04 10 47 c3 c3 PROPN ms35t724v04 10 48 of of ADP ms35t724v04 10 49 the the DET ms35t724v04 10 50 pyranose pyranose NOUN ms35t724v04 10 51 ring ring NOUN ms35t724v04 10 52 or or CCONJ ms35t724v04 10 53 at at ADP ms35t724v04 10 54 the the DET ms35t724v04 10 55 carbonyl carbonyl ADJ ms35t724v04 10 56 carbon carbon NOUN ms35t724v04 10 57 of of ADP ms35t724v04 10 58 the the DET ms35t724v04 10 59 exocyclic exocyclic PROPN ms35t724v04 10 60 nac nac PROPN ms35t724v04 10 61 group group PROPN ms35t724v04 10 62 . . PUNCT ms35t724v04 11 1 the the DET ms35t724v04 11 2 couplings coupling NOUN ms35t724v04 11 3 that that PRON ms35t724v04 11 4 depend depend VERB ms35t724v04 11 5 on on ADP ms35t724v04 11 6 the the DET ms35t724v04 11 7 c2 c2 PROPN ms35t724v04 11 8 - - PUNCT ms35t724v04 11 9 n2 n2 ADJ ms35t724v04 11 10 torsion torsion NOUN ms35t724v04 11 11 angle angle NOUN ms35t724v04 11 12 were be AUX ms35t724v04 11 13 extracted extract VERB ms35t724v04 11 14 . . PUNCT ms35t724v04 12 1 these these DET ms35t724v04 12 2 parameters parameter NOUN ms35t724v04 12 3 were be AUX ms35t724v04 12 4 used use VERB ms35t724v04 12 5 to to PART ms35t724v04 12 6 assess assess VERB ms35t724v04 12 7 the the DET ms35t724v04 12 8 n n NOUN ms35t724v04 12 9 - - PUNCT ms35t724v04 12 10 acetyl acetyl NOUN ms35t724v04 12 11 side side NOUN ms35t724v04 12 12 - - PUNCT ms35t724v04 12 13 chain chain NOUN ms35t724v04 12 14 conformation conformation NOUN ms35t724v04 12 15 in in ADP ms35t724v04 12 16 combination combination NOUN ms35t724v04 12 17 with with ADP ms35t724v04 12 18 dft dft ADJ ms35t724v04 12 19 parameterized parameterize VERB ms35t724v04 12 20 equations equation NOUN ms35t724v04 12 21 . . PUNCT ms35t724v04 13 1 chapter chapter NOUN ms35t724v04 13 2 5 5 NUM ms35t724v04 13 3 reports report VERB ms35t724v04 13 4 the the DET ms35t724v04 13 5 preparation preparation NOUN ms35t724v04 13 6 of of ADP ms35t724v04 13 7 selectively selectively ADV ms35t724v04 13 8 isotope isotope VERB ms35t724v04 13 9 labeled label VERB ms35t724v04 13 10 alpha alpha NOUN ms35t724v04 13 11 , , PUNCT ms35t724v04 13 12 alpha alpha NOUN ms35t724v04 13 13 - - NOUN ms35t724v04 13 14 trehalose trehalose NOUN ms35t724v04 13 15 , , PUNCT ms35t724v04 13 16 which which PRON ms35t724v04 13 17 is be AUX ms35t724v04 13 18 important important ADJ ms35t724v04 13 19 in in ADP ms35t724v04 13 20 cryobiology cryobiology NOUN ms35t724v04 13 21 and and CCONJ ms35t724v04 13 22 other other ADJ ms35t724v04 13 23 pharmaceutical pharmaceutical ADJ ms35t724v04 13 24 applications application NOUN ms35t724v04 13 25 , , PUNCT ms35t724v04 13 26 2 2 NUM ms35t724v04 13 27 - - PUNCT ms35t724v04 13 28 deoxy deoxy ADJ ms35t724v04 13 29 derivatives derivative NOUN ms35t724v04 13 30 . . PUNCT ms35t724v04 14 1 the the DET ms35t724v04 14 2 isotope isotope NOUN ms35t724v04 14 3 labeling labeling NOUN ms35t724v04 14 4 strategy strategy NOUN ms35t724v04 14 5 allowed allow VERB ms35t724v04 14 6 the the DET ms35t724v04 14 7 measurement measurement NOUN ms35t724v04 14 8 of of ADP ms35t724v04 14 9 all all DET ms35t724v04 14 10 trans trans ADJ ms35t724v04 14 11 - - ADJ ms35t724v04 14 12 glycoside glycoside ADJ ms35t724v04 14 13 couplings coupling NOUN ms35t724v04 14 14 in in ADP ms35t724v04 14 15 alpha alpha NOUN ms35t724v04 14 16 , , PUNCT ms35t724v04 14 17 alpha alpha NOUN ms35t724v04 14 18 - - NOUN ms35t724v04 14 19 trehalose trehalose NOUN ms35t724v04 14 20 and and CCONJ ms35t724v04 14 21 its its PRON ms35t724v04 14 22 2 2 NUM ms35t724v04 14 23 - - PUNCT ms35t724v04 14 24 deoxy deoxy ADJ ms35t724v04 14 25 derivatives derivative NOUN ms35t724v04 14 26 . . PUNCT ms35t724v04 15 1 conformational conformational ADJ ms35t724v04 15 2 analysis analysis NOUN ms35t724v04 15 3 based base VERB ms35t724v04 15 4 on on ADP ms35t724v04 15 5 experimental experimental ADJ ms35t724v04 15 6 scalar scalar ADJ ms35t724v04 15 7 couplings coupling NOUN ms35t724v04 15 8 was be AUX ms35t724v04 15 9 performed perform VERB ms35t724v04 15 10 using use VERB ms35t724v04 15 11 dft dft ADJ ms35t724v04 15 12 - - PUNCT ms35t724v04 15 13 parametrized parametrize VERB ms35t724v04 15 14 karplus karplus ADJ ms35t724v04 15 15 equations equation NOUN ms35t724v04 15 16 for for ADP ms35t724v04 15 17 3jch 3jch NUM ms35t724v04 15 18 and and CCONJ ms35t724v04 15 19 3jcc 3jcc NUM ms35t724v04 15 20 . . PUNCT ms35t724v04 16 1 these these DET ms35t724v04 16 2 studies study NOUN ms35t724v04 16 3 provided provide VERB ms35t724v04 16 4 new new ADJ ms35t724v04 16 5 experimental experimental ADJ ms35t724v04 16 6 data datum NOUN ms35t724v04 16 7 to to PART ms35t724v04 16 8 assess assess VERB ms35t724v04 16 9 linkage linkage NOUN ms35t724v04 16 10 conformation conformation NOUN ms35t724v04 16 11 in in ADP ms35t724v04 16 12 ( ( PUNCT ms35t724v04 16 13 1,1)-linked 1,1)-linked NUM ms35t724v04 16 14 pyranose pyranose NOUN ms35t724v04 16 15 disaccharides disaccharide NOUN ms35t724v04 16 16 . . PUNCT ms35t724v04 17 1 chapter chapter NOUN ms35t724v04 17 2 6 6 NUM ms35t724v04 17 3 reports report VERB ms35t724v04 17 4 the the DET ms35t724v04 17 5 synthesis synthesis NOUN ms35t724v04 17 6 of of ADP ms35t724v04 17 7 a a DET ms35t724v04 17 8 mannose mannose NOUN ms35t724v04 17 9 - - PUNCT ms35t724v04 17 10 containing contain VERB ms35t724v04 17 11 hexasaccharide hexasaccharide NOUN ms35t724v04 17 12 , , PUNCT ms35t724v04 17 13 which which PRON ms35t724v04 17 14 is be AUX ms35t724v04 17 15 a a DET ms35t724v04 17 16 constituent constituent NOUN ms35t724v04 17 17 of of ADP ms35t724v04 17 18 glycoprotein glycoprotein NOUN ms35t724v04 17 19 cd2 cd2 PROPN ms35t724v04 17 20 . . PUNCT ms35t724v04 18 1 the the DET ms35t724v04 18 2 chemistry chemistry NOUN ms35t724v04 18 3 to to PART ms35t724v04 18 4 prepare prepare VERB ms35t724v04 18 5 this this DET ms35t724v04 18 6 hexasaccharide hexasaccharide NOUN ms35t724v04 18 7 is be AUX ms35t724v04 18 8 described describe VERB ms35t724v04 18 9 , , PUNCT ms35t724v04 18 10 including include VERB ms35t724v04 18 11 characterization characterization NOUN ms35t724v04 18 12 by by ADP ms35t724v04 18 13 1h 1h NOUN ms35t724v04 18 14 and and CCONJ ms35t724v04 18 15 13c 13c NUM ms35t724v04 18 16 nmr nmr NOUN ms35t724v04 18 17 , , PUNCT ms35t724v04 18 18 and and CCONJ ms35t724v04 18 19 high high ADJ ms35t724v04 18 20 resolution resolution NOUN ms35t724v04 18 21 mass mass NOUN ms35t724v04 18 22 spectrometry spectrometry NOUN ms35t724v04 18 23 . . PUNCT ms35t724v04 19 1 nmr nmr ADJ ms35t724v04 19 2 characterization characterization NOUN ms35t724v04 19 3 of of ADP ms35t724v04 19 4 intermediates intermediate NOUN ms35t724v04 19 5 provided provide VERB ms35t724v04 19 6 an an DET ms35t724v04 19 7 important important ADJ ms35t724v04 19 8 reference reference NOUN ms35t724v04 19 9 for for ADP ms35t724v04 19 10 future future ADJ ms35t724v04 19 11 synthesis synthesis NOUN ms35t724v04 19 12 of of ADP ms35t724v04 19 13 13c 13c NOUN ms35t724v04 19 14 isotopomers isotopomer NOUN ms35t724v04 19 15 . . PUNCT ms35t724v04 20 1 a a DET ms35t724v04 20 2 strategy strategy NOUN ms35t724v04 20 3 for for ADP ms35t724v04 20 4 isotope isotope NOUN ms35t724v04 20 5 labeling labeling NOUN ms35t724v04 20 6 is be AUX ms35t724v04 20 7 also also ADV ms35t724v04 20 8 discussed discuss VERB ms35t724v04 20 9 . . PUNCT