id	sid	tid	token	lemma	pos
pv63fx74c3h	1	1	this	this	DET
pv63fx74c3h	1	2	thesis	thesis	NOUN
pv63fx74c3h	1	3	explores	explore	VERB
pv63fx74c3h	1	4	the	the	DET
pv63fx74c3h	1	5	mechanisms	mechanism	NOUN
pv63fx74c3h	1	6	by	by	ADP
pv63fx74c3h	1	7	which	which	PRON
pv63fx74c3h	1	8	uranyl	uranyl	NOUN
pv63fx74c3h	1	9	peroxide	peroxide	NOUN
pv63fx74c3h	1	10	complexes	complex	NOUN
pv63fx74c3h	1	11	form	form	NOUN
pv63fx74c3h	1	12	,	,	PUNCT
pv63fx74c3h	1	13	the	the	DET
pv63fx74c3h	1	14	detailed	detailed	ADJ
pv63fx74c3h	1	15	structural	structural	ADJ
pv63fx74c3h	1	16	features	feature	NOUN
pv63fx74c3h	1	17	of	of	ADP
pv63fx74c3h	1	18	pyrophosphate	pyrophosphate	NOUN
pv63fx74c3h	1	19	functionalized	functionalize	VERB
pv63fx74c3h	1	20	nanoclusters	nanocluster	NOUN
pv63fx74c3h	1	21	,	,	PUNCT
pv63fx74c3h	1	22	the	the	DET
pv63fx74c3h	1	23	spectroscopic	spectroscopic	ADJ
pv63fx74c3h	1	24	signatures	signature	NOUN
pv63fx74c3h	1	25	of	of	ADP
pv63fx74c3h	1	26	uranyl	uranyl	ADJ
pv63fx74c3h	1	27	peroxide	peroxide	NOUN
pv63fx74c3h	1	28	monomers	monomer	NOUN
pv63fx74c3h	1	29	,	,	PUNCT
pv63fx74c3h	1	30	the	the	DET
pv63fx74c3h	1	31	effect	effect	NOUN
pv63fx74c3h	1	32	of	of	ADP
pv63fx74c3h	1	33	ph	ph	NOUN
pv63fx74c3h	1	34	on	on	ADP
pv63fx74c3h	1	35	the	the	DET
pv63fx74c3h	1	36	identity	identity	NOUN
pv63fx74c3h	1	37	of	of	ADP
pv63fx74c3h	1	38	the	the	DET
pv63fx74c3h	1	39	products	product	NOUN
pv63fx74c3h	1	40	formed	form	VERB
pv63fx74c3h	1	41	in	in	ADP
pv63fx74c3h	1	42	the	the	DET
pv63fx74c3h	1	43	uranium	uranium	ADJ
pv63fx74c3h	1	44	-	-	PUNCT
pv63fx74c3h	1	45	peroxide	peroxide	NOUN
pv63fx74c3h	1	46	-	-	PUNCT
pv63fx74c3h	1	47	pyrophosphate	pyrophosphate	NOUN
pv63fx74c3h	1	48	system	system	NOUN
pv63fx74c3h	1	49	,	,	PUNCT
pv63fx74c3h	1	50	and	and	CCONJ
pv63fx74c3h	1	51	stability	stability	NOUN
pv63fx74c3h	1	52	of	of	ADP
pv63fx74c3h	1	53	uranyl	uranyl	ADJ
pv63fx74c3h	1	54	peroxide	peroxide	NOUN
pv63fx74c3h	1	55	nanoclusters.the	nanoclusters.the	DET
pv63fx74c3h	1	56	composition	composition	NOUN
pv63fx74c3h	1	57	of	of	ADP
pv63fx74c3h	1	58	uranyl	uranyl	ADJ
pv63fx74c3h	1	59	peroxide	peroxide	NOUN
pv63fx74c3h	1	60	nanoclusters	nanocluster	NOUN
pv63fx74c3h	1	61	(	(	PUNCT
pv63fx74c3h	1	62	i.e.	i.e.	X
pv63fx74c3h	1	63	u	u	PROPN
pv63fx74c3h	1	64	,	,	PUNCT
pv63fx74c3h	1	65	o	o	NOUN
pv63fx74c3h	1	66	)	)	PUNCT
pv63fx74c3h	1	67	imposed	impose	VERB
pv63fx74c3h	1	68	significant	significant	ADJ
pv63fx74c3h	1	69	limitations	limitation	NOUN
pv63fx74c3h	1	70	on	on	ADP
pv63fx74c3h	1	71	our	our	PRON
pv63fx74c3h	1	72	ability	ability	NOUN
pv63fx74c3h	1	73	to	to	PART
pv63fx74c3h	1	74	study	study	VERB
pv63fx74c3h	1	75	their	their	PRON
pv63fx74c3h	1	76	formation	formation	NOUN
pv63fx74c3h	1	77	.	.	PUNCT
pv63fx74c3h	2	1	herein	herein	ADV
pv63fx74c3h	2	2	,	,	PUNCT
pv63fx74c3h	2	3	reaction	reaction	NOUN
pv63fx74c3h	2	4	mixtures	mixture	NOUN
pv63fx74c3h	2	5	yielding	yield	VERB
pv63fx74c3h	2	6	pyrophosphate	pyrophosphate	NOUN
pv63fx74c3h	2	7	functionalized	functionalize	VERB
pv63fx74c3h	2	8	[	[	PUNCT
pv63fx74c3h	2	9	(	(	PUNCT
pv63fx74c3h	2	10	uo2)24(o2)24(p2o7)12	uo2)24(o2)24(p2o7)12	PROPN
pv63fx74c3h	2	11	,	,	PUNCT
pv63fx74c3h	2	12	(	(	PUNCT
pv63fx74c3h	2	13	{	{	PUNCT
pv63fx74c3h	2	14	u24pp12	u24pp12	ADJ
pv63fx74c3h	2	15	}	}	PUNCT
pv63fx74c3h	2	16	)	)	PUNCT
pv63fx74c3h	2	17	cluster	cluster	NOUN
pv63fx74c3h	2	18	were	be	AUX
pv63fx74c3h	2	19	studied	study	VERB
pv63fx74c3h	2	20	across	across	ADP
pv63fx74c3h	2	21	a	a	DET
pv63fx74c3h	2	22	wide	wide	ADJ
pv63fx74c3h	2	23	range	range	NOUN
pv63fx74c3h	2	24	of	of	ADP
pv63fx74c3h	2	25	ph	ph	NOUN
pv63fx74c3h	2	26	conditions	condition	NOUN
pv63fx74c3h	2	27	using	use	VERB
pv63fx74c3h	2	28	31p	31p	NUM
pv63fx74c3h	2	29	nmr	nmr	NOUN
pv63fx74c3h	2	30	spectroscopy	spectroscopy	NOUN
pv63fx74c3h	2	31	providing	provide	VERB
pv63fx74c3h	2	32	insights	insight	NOUN
pv63fx74c3h	2	33	into	into	ADP
pv63fx74c3h	2	34	the	the	DET
pv63fx74c3h	2	35	mechanism	mechanism	NOUN
pv63fx74c3h	2	36	by	by	ADP
pv63fx74c3h	2	37	which	which	PRON
pv63fx74c3h	2	38	these	these	DET
pv63fx74c3h	2	39	clusters	cluster	NOUN
pv63fx74c3h	2	40	assemble	assemble	VERB
pv63fx74c3h	2	41	.	.	PUNCT
pv63fx74c3h	3	1	single	single	ADJ
pv63fx74c3h	3	2	crystal	crystal	NOUN
pv63fx74c3h	3	3	time	time	NOUN
pv63fx74c3h	3	4	-	-	PUNCT
pv63fx74c3h	3	5	of	of	ADP
pv63fx74c3h	3	6	-	-	PUNCT
pv63fx74c3h	3	7	flight	flight	NOUN
pv63fx74c3h	3	8	(	(	PUNCT
pv63fx74c3h	3	9	tof	tof	PROPN
pv63fx74c3h	3	10	)	)	PUNCT
pv63fx74c3h	3	11	neutron	neutron	NOUN
pv63fx74c3h	3	12	diffraction	diffraction	NOUN
pv63fx74c3h	3	13	provided	provide	VERB
pv63fx74c3h	3	14	unparalleled	unparalleled	ADJ
pv63fx74c3h	3	15	atomic	atomic	ADJ
pv63fx74c3h	3	16	resolution	resolution	NOUN
pv63fx74c3h	3	17	allowing	allow	VERB
pv63fx74c3h	3	18	unequivocal	unequivocal	ADJ
pv63fx74c3h	3	19	assignment	assignment	NOUN
pv63fx74c3h	3	20	of	of	ADP
pv63fx74c3h	3	21	{	{	PUNCT
pv63fx74c3h	3	22	u24pp12	u24pp12	ADJ
pv63fx74c3h	3	23	}	}	PUNCT
pv63fx74c3h	3	24	protonation	protonation	NOUN
pv63fx74c3h	3	25	state.raman	state.raman	NOUN
pv63fx74c3h	3	26	signatures	signature	NOUN
pv63fx74c3h	3	27	of	of	ADP
pv63fx74c3h	3	28	a	a	DET
pv63fx74c3h	3	29	family	family	NOUN
pv63fx74c3h	3	30	of	of	ADP
pv63fx74c3h	3	31	uranyl	uranyl	ADJ
pv63fx74c3h	3	32	triperoxide	triperoxide	ADJ
pv63fx74c3h	3	33	monomers	monomer	NOUN
pv63fx74c3h	3	34	[	[	X
pv63fx74c3h	3	35	uo2(o2)34-	uo2(o2)34-	NOUN
pv63fx74c3h	3	36	]	]	PUNCT
pv63fx74c3h	3	37	are	be	AUX
pv63fx74c3h	3	38	studied	study	VERB
pv63fx74c3h	3	39	by	by	ADP
pv63fx74c3h	3	40	combination	combination	NOUN
pv63fx74c3h	3	41	of	of	ADP
pv63fx74c3h	3	42	experimental	experimental	ADJ
pv63fx74c3h	3	43	(	(	PUNCT
pv63fx74c3h	3	44	isotopic	isotopic	ADJ
pv63fx74c3h	3	45	labeling	labeling	NOUN
pv63fx74c3h	3	46	)	)	PUNCT
pv63fx74c3h	3	47	and	and	CCONJ
pv63fx74c3h	3	48	computational	computational	ADJ
pv63fx74c3h	3	49	(	(	PUNCT
pv63fx74c3h	3	50	density	density	NOUN
pv63fx74c3h	3	51	functional	functional	ADJ
pv63fx74c3h	3	52	theory	theory	NOUN
pv63fx74c3h	3	53	)	)	PUNCT
pv63fx74c3h	3	54	approaches	approach	NOUN
pv63fx74c3h	3	55	resulting	result	VERB
pv63fx74c3h	3	56	in	in	ADP
pv63fx74c3h	3	57	assignment	assignment	NOUN
pv63fx74c3h	3	58	of	of	ADP
pv63fx74c3h	3	59	previously	previously	ADV
pv63fx74c3h	3	60	unobserved	unobserved	ADJ
pv63fx74c3h	3	61	asymmetric	asymmetric	NOUN
pv63fx74c3h	3	62	and	and	CCONJ
pv63fx74c3h	3	63	mixed	mixed	ADJ
pv63fx74c3h	3	64	asymmetric	asymmetric	NOUN
pv63fx74c3h	3	65	/	/	SYM
pv63fx74c3h	3	66	symmetric	symmetric	ADJ
pv63fx74c3h	3	67	vibrations	vibration	NOUN
pv63fx74c3h	3	68	of	of	ADP
pv63fx74c3h	3	69	peroxide	peroxide	NOUN
pv63fx74c3h	3	70	ligands	ligand	NOUN
pv63fx74c3h	3	71	.	.	PUNCT
pv63fx74c3h	4	1	moreover	moreover	ADV
pv63fx74c3h	4	2	,	,	PUNCT
pv63fx74c3h	4	3	the	the	DET
pv63fx74c3h	4	4	identity	identity	NOUN
pv63fx74c3h	4	5	of	of	ADP
pv63fx74c3h	4	6	the	the	DET
pv63fx74c3h	4	7	signals	signal	NOUN
pv63fx74c3h	4	8	appearing	appear	VERB
pv63fx74c3h	4	9	in	in	ADP
pv63fx74c3h	4	10	the	the	DET
pv63fx74c3h	4	11	600	600	NUM
pv63fx74c3h	4	12	800	800	NUM
pv63fx74c3h	4	13	cm-1	cm-1	NOUN
pv63fx74c3h	4	14	region	region	NOUN
pv63fx74c3h	4	15	is	be	AUX
pv63fx74c3h	4	16	reassigned	reassign	VERB
pv63fx74c3h	4	17	to	to	ADP
pv63fx74c3h	4	18	the	the	DET
pv63fx74c3h	4	19	symmetric	symmetric	ADJ
pv63fx74c3h	4	20	vibration	vibration	NOUN
pv63fx74c3h	4	21	of	of	ADP
pv63fx74c3h	4	22	the	the	DET
pv63fx74c3h	4	23	uranyl.the	uranyl.the	DET
pv63fx74c3h	4	24	effect	effect	NOUN
pv63fx74c3h	4	25	of	of	ADP
pv63fx74c3h	4	26	ph	ph	NOUN
pv63fx74c3h	4	27	on	on	ADP
pv63fx74c3h	4	28	the	the	DET
pv63fx74c3h	4	29	identity	identity	NOUN
pv63fx74c3h	4	30	of	of	ADP
pv63fx74c3h	4	31	species	specie	NOUN
pv63fx74c3h	4	32	formed	form	VERB
pv63fx74c3h	4	33	in	in	ADP
pv63fx74c3h	4	34	the	the	DET
pv63fx74c3h	4	35	uranium	uranium	ADJ
pv63fx74c3h	4	36	-	-	PUNCT
pv63fx74c3h	4	37	peroxide	peroxide	NOUN
pv63fx74c3h	4	38	-	-	PUNCT
pv63fx74c3h	4	39	pyrophosphate	pyrophosphate	NOUN
pv63fx74c3h	4	40	system	system	NOUN
pv63fx74c3h	4	41	are	be	AUX
pv63fx74c3h	4	42	studied	study	VERB
pv63fx74c3h	4	43	by	by	ADP
pv63fx74c3h	4	44	combination	combination	NOUN
pv63fx74c3h	4	45	of	of	ADP
pv63fx74c3h	4	46	single	single	ADJ
pv63fx74c3h	4	47	crystal	crystal	NOUN
pv63fx74c3h	4	48	x	x	NOUN
pv63fx74c3h	4	49	-	-	NOUN
pv63fx74c3h	4	50	ray	ray	NOUN
pv63fx74c3h	4	51	diffraction	diffraction	NOUN
pv63fx74c3h	4	52	,	,	PUNCT
pv63fx74c3h	4	53	small	small	ADJ
pv63fx74c3h	4	54	angle	angle	NOUN
pv63fx74c3h	4	55	x	x	NOUN
pv63fx74c3h	4	56	-	-	NOUN
pv63fx74c3h	4	57	ray	ray	NOUN
pv63fx74c3h	4	58	scattering	scattering	NOUN
pv63fx74c3h	4	59	,	,	PUNCT
pv63fx74c3h	4	60	31p	31p	NUM
pv63fx74c3h	4	61	nmr	nmr	NOUN
pv63fx74c3h	4	62	,	,	PUNCT
pv63fx74c3h	4	63	and	and	CCONJ
pv63fx74c3h	4	64	31p	31p	NOUN
pv63fx74c3h	4	65	dosy	dosy	PROPN
pv63fx74c3h	4	66	nmr	nmr	PROPN
pv63fx74c3h	4	67	spectroscopy	spectroscopy	PROPN
pv63fx74c3h	4	68	.	.	PUNCT
pv63fx74c3h	5	1	results	result	NOUN
pv63fx74c3h	5	2	indicate	indicate	VERB
pv63fx74c3h	5	3	that	that	SCONJ
pv63fx74c3h	5	4	formation	formation	NOUN
pv63fx74c3h	5	5	of	of	ADP
pv63fx74c3h	5	6	uranyl	uranyl	ADJ
pv63fx74c3h	5	7	peroxide	peroxide	NOUN
pv63fx74c3h	5	8	nanoclusters	nanocluster	NOUN
pv63fx74c3h	5	9	follows	follow	VERB
pv63fx74c3h	5	10	a	a	DET
pv63fx74c3h	5	11	well	well	ADV
pv63fx74c3h	5	12	-	-	PUNCT
pv63fx74c3h	5	13	defined	define	VERB
pv63fx74c3h	5	14	stepwise	stepwise	NOUN
pv63fx74c3h	5	15	mechanism	mechanism	NOUN
pv63fx74c3h	5	16	consisting	consist	VERB
pv63fx74c3h	5	17	of	of	ADP
pv63fx74c3h	5	18	multiple	multiple	ADJ
pv63fx74c3h	5	19	assembly	assembly	NOUN
pv63fx74c3h	5	20	/	/	SYM
pv63fx74c3h	5	21	disassembly	disassembly	NOUN
pv63fx74c3h	5	22	steps	step	NOUN
pv63fx74c3h	5	23	showing	show	VERB
pv63fx74c3h	5	24	retention	retention	NOUN
pv63fx74c3h	5	25	of	of	ADP
pv63fx74c3h	5	26	basic	basic	ADJ
pv63fx74c3h	5	27	uranyl	uranyl	NOUN
pv63fx74c3h	5	28	peroxide	peroxide	NOUN
pv63fx74c3h	5	29	building	building	NOUN
pv63fx74c3h	5	30	blocks	block	NOUN
pv63fx74c3h	5	31	(	(	PUNCT
pv63fx74c3h	5	32	e.g.	e.g.	X
pv63fx74c3h	5	33	[	[	X
pv63fx74c3h	5	34	(	(	PUNCT
pv63fx74c3h	5	35	uo2)4(o2)4	uo2)4(o2)4	NOUN
pv63fx74c3h	5	36	]	]	X
pv63fx74c3h	5	37	,	,	PUNCT
pv63fx74c3h	5	38	{	{	PUNCT
pv63fx74c3h	5	39	u4}).finally	u4}).finally	PROPN
pv63fx74c3h	5	40	,	,	PUNCT
pv63fx74c3h	5	41	stability	stability	NOUN
pv63fx74c3h	5	42	of	of	ADP
pv63fx74c3h	5	43	[	[	X
pv63fx74c3h	5	44	(	(	PUNCT
pv63fx74c3h	5	45	uo2)20(o2)27(hpo4)6	uo2)20(o2)27(hpo4)6	NOUN
pv63fx74c3h	5	46	]	]	X
pv63fx74c3h	5	47	,	,	PUNCT
pv63fx74c3h	5	48	{	{	PUNCT
pv63fx74c3h	5	49	u20p6	u20p6	ADJ
pv63fx74c3h	5	50	}	}	PUNCT
pv63fx74c3h	5	51	nanocluster	nanocluster	NOUN
pv63fx74c3h	5	52	incorporating	incorporate	VERB
pv63fx74c3h	5	53	peroxide	peroxide	NOUN
pv63fx74c3h	5	54	in	in	ADP
pv63fx74c3h	5	55	an	an	DET
pv63fx74c3h	5	56	unusual	unusual	ADJ
pv63fx74c3h	5	57	µ:eta2	µ:eta2	SPACE
pv63fx74c3h	5	58	:	:	PUNCT
pv63fx74c3h	5	59	eta2	eta2	PROPN
pv63fx74c3h	5	60	bridging	bridging	NOUN
pv63fx74c3h	5	61	mode	mode	NOUN
pv63fx74c3h	5	62	is	be	AUX
pv63fx74c3h	5	63	studied	study	VERB
pv63fx74c3h	5	64	by	by	ADP
pv63fx74c3h	5	65	combination	combination	NOUN
pv63fx74c3h	5	66	of	of	ADP
pv63fx74c3h	5	67	raman	raman	NOUN
pv63fx74c3h	5	68	,	,	PUNCT
pv63fx74c3h	5	69	31p	31p	PROPN
pv63fx74c3h	5	70	dosy	dosy	PROPN
pv63fx74c3h	5	71	nmr	nmr	PROPN
pv63fx74c3h	5	72	spectroscopy	spectroscopy	NOUN
pv63fx74c3h	5	73	,	,	PUNCT
pv63fx74c3h	5	74	small	small	ADJ
pv63fx74c3h	5	75	angle	angle	NOUN
pv63fx74c3h	5	76	x	x	NOUN
pv63fx74c3h	5	77	-	-	NOUN
pv63fx74c3h	5	78	ray	ray	NOUN
pv63fx74c3h	5	79	scattering	scattering	NOUN
pv63fx74c3h	5	80	,	,	PUNCT
pv63fx74c3h	5	81	and	and	CCONJ
pv63fx74c3h	5	82	single	single	ADJ
pv63fx74c3h	5	83	crystal	crystal	NOUN
pv63fx74c3h	5	84	x	x	NOUN
pv63fx74c3h	5	85	-	-	NOUN
pv63fx74c3h	5	86	ray	ray	NOUN
pv63fx74c3h	5	87	diffraction	diffraction	NOUN
pv63fx74c3h	5	88	.	.	PUNCT
pv63fx74c3h	6	1	results	result	NOUN
pv63fx74c3h	6	2	obtained	obtain	VERB
pv63fx74c3h	6	3	in	in	ADP
pv63fx74c3h	6	4	this	this	DET
pv63fx74c3h	6	5	study	study	NOUN
pv63fx74c3h	6	6	indicate	indicate	VERB
pv63fx74c3h	6	7	that	that	PRON
pv63fx74c3h	6	8	{	{	PUNCT
pv63fx74c3h	6	9	u20p6	u20p6	NOUN
pv63fx74c3h	6	10	}	}	PUNCT
pv63fx74c3h	6	11	,	,	PUNCT
pv63fx74c3h	6	12	upon	upon	SCONJ
pv63fx74c3h	6	13	dissolution	dissolution	NOUN
pv63fx74c3h	6	14	in	in	ADP
pv63fx74c3h	6	15	h2o	h2o	PROPN
pv63fx74c3h	6	16	,	,	PUNCT
pv63fx74c3h	6	17	undergoes	undergo	VERB
pv63fx74c3h	6	18	a	a	DET
pv63fx74c3h	6	19	rapid	rapid	ADJ
pv63fx74c3h	6	20	dissolution	dissolution	NOUN
pv63fx74c3h	6	21	(	(	PUNCT
pv63fx74c3h	6	22	t1/2	t1/2	NOUN
pv63fx74c3h	6	23	=	=	SYM
pv63fx74c3h	6	24	116.3	116.3	NUM
pv63fx74c3h	6	25	min	min	NOUN
pv63fx74c3h	6	26	)	)	PUNCT
pv63fx74c3h	6	27	followed	follow	VERB
pv63fx74c3h	6	28	by	by	ADP
pv63fx74c3h	6	29	reassembly	reassembly	NOUN
pv63fx74c3h	6	30	into	into	ADP
pv63fx74c3h	6	31	previously	previously	ADV
pv63fx74c3h	6	32	described	describe	VERB
pv63fx74c3h	6	33	{	{	PUNCT
pv63fx74c3h	6	34	u24	u24	NOUN
pv63fx74c3h	6	35	}	}	PUNCT
pv63fx74c3h	6	36	nanocluster	nanocluster	NOUN
pv63fx74c3h	6	37	.	.	PUNCT