id sid tid token lemma pos qf85n873c8r 1 1 a a DET qf85n873c8r 1 2 temperature temperature NOUN qf85n873c8r 1 3 - - PUNCT qf85n873c8r 1 4 dependent dependent ADJ qf85n873c8r 1 5 crystallographic crystallographic ADJ qf85n873c8r 1 6 phase phase NOUN qf85n873c8r 1 7 change change NOUN qf85n873c8r 1 8 has have AUX qf85n873c8r 1 9 been be AUX qf85n873c8r 1 10 observed observe VERB qf85n873c8r 1 11 in in ADP qf85n873c8r 1 12 [ [ X qf85n873c8r 1 13 co(tpp)(no co(tpp)(no SPACE qf85n873c8r 1 14 ) ) PUNCT qf85n873c8r 1 15 ] ] PUNCT qf85n873c8r 1 16 . . PUNCT qf85n873c8r 2 1 crystal crystal NOUN qf85n873c8r 2 2 structures structure NOUN qf85n873c8r 2 3 at at ADP qf85n873c8r 2 4 multiple multiple ADJ qf85n873c8r 2 5 temperatures temperature NOUN qf85n873c8r 2 6 reveal reveal VERB qf85n873c8r 2 7 that that SCONJ qf85n873c8r 2 8 the the DET qf85n873c8r 2 9 system system NOUN qf85n873c8r 2 10 changes change VERB qf85n873c8r 2 11 from from ADP qf85n873c8r 2 12 a a DET qf85n873c8r 2 13 system system NOUN qf85n873c8r 2 14 with with ADP qf85n873c8r 2 15 eightfold eightfold ADJ qf85n873c8r 2 16 disorder disorder NOUN qf85n873c8r 2 17 at at ADP qf85n873c8r 2 18 250 250 NUM qf85n873c8r 2 19 k k NOUN qf85n873c8r 2 20 to to ADP qf85n873c8r 2 21 one one NUM qf85n873c8r 2 22 that that PRON qf85n873c8r 2 23 is be AUX qf85n873c8r 2 24 more more ADV qf85n873c8r 2 25 ordered ordered ADJ qf85n873c8r 2 26 below below ADP qf85n873c8r 2 27 195 195 NUM qf85n873c8r 2 28 k. k. NOUN qf85n873c8r 2 29 interestingly interestingly ADV qf85n873c8r 2 30 , , PUNCT qf85n873c8r 2 31 at at ADP qf85n873c8r 2 32 190 190 NUM qf85n873c8r 2 33 k k X qf85n873c8r 2 34 , , PUNCT qf85n873c8r 2 35 it it PRON qf85n873c8r 2 36 was be AUX qf85n873c8r 2 37 possible possible ADJ qf85n873c8r 2 38 to to PART qf85n873c8r 2 39 trap trap VERB qf85n873c8r 2 40 the the DET qf85n873c8r 2 41 structure structure NOUN qf85n873c8r 2 42 in in ADP qf85n873c8r 2 43 its its PRON qf85n873c8r 2 44 transition transition NOUN qf85n873c8r 2 45 state state NOUN qf85n873c8r 2 46 , , PUNCT qf85n873c8r 2 47 resulting result VERB qf85n873c8r 2 48 in in ADP qf85n873c8r 2 49 three three NUM qf85n873c8r 2 50 distinct distinct ADJ qf85n873c8r 2 51 structures structure NOUN qf85n873c8r 2 52 of of ADP qf85n873c8r 2 53 [ [ X qf85n873c8r 2 54 co(tpp)(no co(tpp)(no X qf85n873c8r 2 55 ) ) PUNCT qf85n873c8r 2 56 ] ] PUNCT qf85n873c8r 2 57 . . PUNCT qf85n873c8r 3 1 the the DET qf85n873c8r 3 2 phase phase NOUN qf85n873c8r 3 3 change change NOUN qf85n873c8r 3 4 is be AUX qf85n873c8r 3 5 reversible reversible ADJ qf85n873c8r 3 6 and and CCONJ qf85n873c8r 3 7 has have AUX qf85n873c8r 3 8 given give VERB qf85n873c8r 3 9 insight insight NOUN qf85n873c8r 3 10 into into ADP qf85n873c8r 3 11 the the DET qf85n873c8r 3 12 nature nature NOUN qf85n873c8r 3 13 of of ADP qf85n873c8r 3 14 nitrosyl nitrosyl ADJ qf85n873c8r 3 15 disorder disorder NOUN qf85n873c8r 3 16 in in ADP qf85n873c8r 3 17 the the DET qf85n873c8r 3 18 porphyrin porphyrin NOUN qf85n873c8r 3 19 system system NOUN qf85n873c8r 3 20 as as ADP qf85n873c8r 3 21 a a DET qf85n873c8r 3 22 dynamic dynamic ADJ qf85n873c8r 3 23 disorder disorder NOUN qf85n873c8r 3 24 . . PUNCT qf85n873c8r 4 1 the the DET qf85n873c8r 4 2 reproducibility reproducibility NOUN qf85n873c8r 4 3 of of ADP qf85n873c8r 4 4 the the DET qf85n873c8r 4 5 phase phase NOUN qf85n873c8r 4 6 change change NOUN qf85n873c8r 4 7 has have AUX qf85n873c8r 4 8 been be AUX qf85n873c8r 4 9 studied study VERB qf85n873c8r 4 10 through through ADP qf85n873c8r 4 11 both both DET qf85n873c8r 4 12 dsc dsc NOUN qf85n873c8r 4 13 measurements measurement NOUN qf85n873c8r 4 14 and and CCONJ qf85n873c8r 4 15 crystallographic crystallographic ADJ qf85n873c8r 4 16 unit unit NOUN qf85n873c8r 4 17 cell cell NOUN qf85n873c8r 4 18 indexing indexing NOUN qf85n873c8r 4 19 on on ADP qf85n873c8r 4 20 several several ADJ qf85n873c8r 4 21 crystals crystal NOUN qf85n873c8r 4 22 . . PUNCT qf85n873c8r 5 1 in in ADP qf85n873c8r 5 2 an an DET qf85n873c8r 5 3 attempt attempt NOUN qf85n873c8r 5 4 to to PART qf85n873c8r 5 5 understand understand VERB qf85n873c8r 5 6 the the DET qf85n873c8r 5 7 reason reason NOUN qf85n873c8r 5 8 for for ADP qf85n873c8r 5 9 the the DET qf85n873c8r 5 10 phase phase NOUN qf85n873c8r 5 11 change change NOUN qf85n873c8r 5 12 , , PUNCT qf85n873c8r 5 13 [ [ X qf85n873c8r 5 14 fe(tpp)cl fe(tpp)cl X qf85n873c8r 5 15 ] ] PUNCT qf85n873c8r 5 16 and and CCONJ qf85n873c8r 5 17 [ [ X qf85n873c8r 5 18 mn(tpp)(no)(meoh mn(tpp)(no)(meoh X qf85n873c8r 5 19 ) ) PUNCT qf85n873c8r 5 20 ] ] PUNCT qf85n873c8r 5 21 were be AUX qf85n873c8r 5 22 synthesized synthesize VERB qf85n873c8r 5 23 and and CCONJ qf85n873c8r 5 24 studied study VERB qf85n873c8r 5 25 crystallographically crystallographically ADV qf85n873c8r 5 26 at at ADP qf85n873c8r 5 27 multiple multiple ADJ qf85n873c8r 5 28 temperatures temperature NOUN qf85n873c8r 5 29 . . PUNCT