id	sid	tid	token	lemma	pos
th83kw5519d	1	1	this	this	DET
th83kw5519d	1	2	dissertation	dissertation	NOUN
th83kw5519d	1	3	examines	examine	VERB
th83kw5519d	1	4	the	the	DET
th83kw5519d	1	5	mechanisms	mechanism	NOUN
th83kw5519d	1	6	that	that	PRON
th83kw5519d	1	7	lead	lead	VERB
th83kw5519d	1	8	to	to	ADP
th83kw5519d	1	9	the	the	DET
th83kw5519d	1	10	formation	formation	NOUN
th83kw5519d	1	11	of	of	ADP
th83kw5519d	1	12	actinyl	actinyl	PROPN
th83kw5519d	1	13	peroxide	peroxide	PROPN
th83kw5519d	1	14	cage	cage	NOUN
th83kw5519d	1	15	clusters	cluster	NOUN
th83kw5519d	1	16	,	,	PUNCT
th83kw5519d	1	17	the	the	DET
th83kw5519d	1	18	mechanism	mechanism	NOUN
th83kw5519d	1	19	of	of	ADP
th83kw5519d	1	20	aggregation	aggregation	NOUN
th83kw5519d	1	21	of	of	ADP
th83kw5519d	1	22	actinyl	actinyl	PROPN
th83kw5519d	1	23	peroxide	peroxide	PROPN
th83kw5519d	1	24	cage	cage	NOUN
th83kw5519d	1	25	clusters	cluster	NOUN
th83kw5519d	1	26	,	,	PUNCT
th83kw5519d	1	27	the	the	DET
th83kw5519d	1	28	photochemical	photochemical	ADJ
th83kw5519d	1	29	generation	generation	NOUN
th83kw5519d	1	30	of	of	ADP
th83kw5519d	1	31	actinyl	actinyl	PROPN
th83kw5519d	1	32	peroxide	peroxide	NOUN
th83kw5519d	1	33	complexes	complex	NOUN
th83kw5519d	1	34	in	in	ADP
th83kw5519d	1	35	nonaqueous	nonaqueous	ADJ
th83kw5519d	1	36	solution	solution	NOUN
th83kw5519d	1	37	,	,	PUNCT
th83kw5519d	1	38	and	and	CCONJ
th83kw5519d	1	39	the	the	DET
th83kw5519d	1	40	electronic	electronic	ADJ
th83kw5519d	1	41	structure	structure	NOUN
th83kw5519d	1	42	of	of	ADP
th83kw5519d	1	43	the	the	DET
th83kw5519d	1	44	neptunyl	neptunyl	PROPN
th83kw5519d	1	45	peroxide	peroxide	PROPN
th83kw5519d	1	46	cluster	cluster	PROPN
th83kw5519d	1	47	{	{	PUNCT
th83kw5519d	1	48	np24	np24	PROPN
th83kw5519d	1	49	}	}	PUNCT
th83kw5519d	1	50	.	.	PUNCT
th83kw5519d	2	1	in	in	ADP
th83kw5519d	2	2	order	order	NOUN
th83kw5519d	2	3	to	to	PART
th83kw5519d	2	4	study	study	VERB
th83kw5519d	2	5	the	the	DET
th83kw5519d	2	6	formation	formation	NOUN
th83kw5519d	2	7	mechanism	mechanism	NOUN
th83kw5519d	2	8	of	of	ADP
th83kw5519d	2	9	{	{	PUNCT
th83kw5519d	2	10	u24	u24	NOUN
th83kw5519d	2	11	}	}	PUNCT
th83kw5519d	2	12	i	i	PRON
th83kw5519d	2	13	have	have	AUX
th83kw5519d	2	14	also	also	ADV
th83kw5519d	2	15	developed	develop	VERB
th83kw5519d	2	16	spectroscopic	spectroscopic	ADJ
th83kw5519d	2	17	and	and	CCONJ
th83kw5519d	2	18	mass	mass	ADJ
th83kw5519d	2	19	spectrometric	spectrometric	ADJ
th83kw5519d	2	20	methods	method	NOUN
th83kw5519d	2	21	to	to	PART
th83kw5519d	2	22	characterize	characterize	VERB
th83kw5519d	2	23	these	these	DET
th83kw5519d	2	24	clusters	cluster	NOUN
th83kw5519d	2	25	in	in	ADP
th83kw5519d	2	26	solution	solution	NOUN
th83kw5519d	2	27	.	.	PUNCT
th83kw5519d	3	1	actinyl	actinyl	PROPN
th83kw5519d	3	2	peroxide	peroxide	PROPN
th83kw5519d	3	3	cage	cage	NOUN
th83kw5519d	3	4	clusters	cluster	NOUN
th83kw5519d	3	5	have	have	AUX
th83kw5519d	3	6	been	be	AUX
th83kw5519d	3	7	the	the	DET
th83kw5519d	3	8	subject	subject	NOUN
th83kw5519d	3	9	of	of	ADP
th83kw5519d	3	10	synthetic	synthetic	ADJ
th83kw5519d	3	11	efforts	effort	NOUN
th83kw5519d	3	12	by	by	ADP
th83kw5519d	3	13	a	a	DET
th83kw5519d	3	14	number	number	NOUN
th83kw5519d	3	15	of	of	ADP
th83kw5519d	3	16	groups	group	NOUN
th83kw5519d	3	17	since	since	SCONJ
th83kw5519d	3	18	the	the	DET
th83kw5519d	3	19	single	single	ADJ
th83kw5519d	3	20	crystal	crystal	NOUN
th83kw5519d	3	21	structures	structure	NOUN
th83kw5519d	3	22	of	of	ADP
th83kw5519d	3	23	the	the	DET
th83kw5519d	3	24	first	first	ADJ
th83kw5519d	3	25	isolated	isolated	ADJ
th83kw5519d	3	26	clusters	cluster	NOUN
th83kw5519d	3	27	appeared	appear	VERB
th83kw5519d	3	28	in	in	ADP
th83kw5519d	3	29	2005	2005	NUM
th83kw5519d	3	30	.	.	PUNCT
th83kw5519d	4	1	herein	herein	ADV
th83kw5519d	4	2	,	,	PUNCT
th83kw5519d	4	3	the	the	DET
th83kw5519d	4	4	mechanism	mechanism	NOUN
th83kw5519d	4	5	by	by	ADP
th83kw5519d	4	6	which	which	PRON
th83kw5519d	4	7	one	one	NUM
th83kw5519d	4	8	of	of	ADP
th83kw5519d	4	9	these	these	DET
th83kw5519d	4	10	clusters	cluster	NOUN
th83kw5519d	4	11	,	,	PUNCT
th83kw5519d	4	12	[	[	X
th83kw5519d	4	13	uo2(o2)(oh)]2424({u24	uo2(o2)(oh)]2424({u24	ADJ
th83kw5519d	4	14	}	}	PUNCT
th83kw5519d	4	15	)	)	PUNCT
th83kw5519d	4	16	,	,	PUNCT
th83kw5519d	4	17	assembles	assemble	VERB
th83kw5519d	4	18	in	in	ADP
th83kw5519d	4	19	solution	solution	NOUN
th83kw5519d	4	20	is	be	AUX
th83kw5519d	4	21	examined	examine	VERB
th83kw5519d	4	22	in	in	ADP
th83kw5519d	4	23	detail	detail	NOUN
th83kw5519d	4	24	.	.	PUNCT
th83kw5519d	5	1	speciation	speciation	NOUN
th83kw5519d	5	2	data	datum	NOUN
th83kw5519d	5	3	from	from	ADP
th83kw5519d	5	4	electrospray	electrospray	ADJ
th83kw5519d	5	5	ionization	ionization	NOUN
th83kw5519d	5	6	-	-	PUNCT
th83kw5519d	5	7	mass	mass	NOUN
th83kw5519d	5	8	spectrometry	spectrometry	NOUN
th83kw5519d	5	9	is	be	AUX
th83kw5519d	5	10	complemented	complement	VERB
th83kw5519d	5	11	by	by	ADP
th83kw5519d	5	12	x	x	NOUN
th83kw5519d	5	13	-	-	NOUN
th83kw5519d	5	14	ray	ray	NOUN
th83kw5519d	5	15	diffraction	diffraction	NOUN
th83kw5519d	5	16	,	,	PUNCT
th83kw5519d	5	17	kinetic	kinetic	ADJ
th83kw5519d	5	18	analyses	analysis	NOUN
th83kw5519d	5	19	,	,	PUNCT
th83kw5519d	5	20	raman	raman	ADJ
th83kw5519d	5	21	spectroscopy	spectroscopy	NOUN
th83kw5519d	5	22	,	,	PUNCT
th83kw5519d	5	23	and	and	CCONJ
th83kw5519d	5	24	small	small	ADJ
th83kw5519d	5	25	-	-	PUNCT
th83kw5519d	5	26	angle	angle	NOUN
th83kw5519d	5	27	x	x	NOUN
th83kw5519d	5	28	-	-	NOUN
th83kw5519d	5	29	ray	ray	NOUN
th83kw5519d	5	30	scattering	scattering	NOUN
th83kw5519d	5	31	(	(	PUNCT
th83kw5519d	5	32	saxs	saxs	PROPN
th83kw5519d	5	33	)	)	PUNCT
th83kw5519d	5	34	,	,	PUNCT
th83kw5519d	5	35	enabling	enable	VERB
th83kw5519d	5	36	a	a	DET
th83kw5519d	5	37	full	full	ADJ
th83kw5519d	5	38	description	description	NOUN
th83kw5519d	5	39	of	of	ADP
th83kw5519d	5	40	the	the	DET
th83kw5519d	5	41	formation	formation	NOUN
th83kw5519d	5	42	mechanism	mechanism	NOUN
th83kw5519d	5	43	and	and	CCONJ
th83kw5519d	5	44	the	the	DET
th83kw5519d	5	45	role	role	NOUN
th83kw5519d	5	46	of	of	ADP
th83kw5519d	5	47	each	each	DET
th83kw5519d	5	48	reagent	reagent	NOUN
th83kw5519d	5	49	.	.	PUNCT
th83kw5519d	6	1	using	use	VERB
th83kw5519d	6	2	this	this	DET
th83kw5519d	6	3	mechanistic	mechanistic	ADJ
th83kw5519d	6	4	understanding	understanding	NOUN
th83kw5519d	6	5	,	,	PUNCT
th83kw5519d	6	6	a	a	DET
th83kw5519d	6	7	rational	rational	ADJ
th83kw5519d	6	8	synthesis	synthesis	NOUN
th83kw5519d	6	9	of	of	ADP
th83kw5519d	6	10	the	the	DET
th83kw5519d	6	11	cluster	cluster	NOUN
th83kw5519d	6	12	is	be	AUX
th83kw5519d	6	13	developed	develop	VERB
th83kw5519d	6	14	and	and	CCONJ
th83kw5519d	6	15	the	the	DET
th83kw5519d	6	16	proposed	propose	VERB
th83kw5519d	6	17	mechanism	mechanism	NOUN
th83kw5519d	6	18	is	be	AUX
th83kw5519d	6	19	analyzed	analyze	VERB
th83kw5519d	6	20	in	in	ADP
th83kw5519d	6	21	terms	term	NOUN
th83kw5519d	6	22	of	of	ADP
th83kw5519d	6	23	the	the	DET
th83kw5519d	6	24	structures	structure	NOUN
th83kw5519d	6	25	of	of	ADP
th83kw5519d	6	26	known	know	VERB
th83kw5519d	6	27	uranyl	uranyl	ADJ
th83kw5519d	6	28	peroxide	peroxide	NOUN
th83kw5519d	6	29	cage	cage	NOUN
th83kw5519d	6	30	clusters	cluster	NOUN
th83kw5519d	6	31	.	.	PUNCT
th83kw5519d	7	1	the	the	DET
th83kw5519d	7	2	reactions	reaction	NOUN
th83kw5519d	7	3	of	of	ADP
th83kw5519d	7	4	these	these	DET
th83kw5519d	7	5	cage	cage	NOUN
th83kw5519d	7	6	clusters	cluster	NOUN
th83kw5519d	7	7	are	be	AUX
th83kw5519d	7	8	studied	study	VERB
th83kw5519d	7	9	in	in	ADP
th83kw5519d	7	10	aqueous	aqueous	ADJ
th83kw5519d	7	11	solution	solution	NOUN
th83kw5519d	7	12	using	use	VERB
th83kw5519d	7	13	similar	similar	ADJ
th83kw5519d	7	14	spectroscopic	spectroscopic	ADJ
th83kw5519d	7	15	and	and	CCONJ
th83kw5519d	7	16	mass	mass	ADJ
th83kw5519d	7	17	spectrometric	spectrometric	ADJ
th83kw5519d	7	18	methods	method	NOUN
th83kw5519d	7	19	to	to	PART
th83kw5519d	7	20	determine	determine	VERB
th83kw5519d	7	21	the	the	DET
th83kw5519d	7	22	reactivity	reactivity	NOUN
th83kw5519d	7	23	of	of	ADP
th83kw5519d	7	24	uranyl	uranyl	ADJ
th83kw5519d	7	25	peroxide	peroxide	NOUN
th83kw5519d	7	26	cage	cage	NOUN
th83kw5519d	7	27	clusters	cluster	NOUN
th83kw5519d	7	28	and	and	CCONJ
th83kw5519d	7	29	whether	whether	SCONJ
th83kw5519d	7	30	cluster	cluster	NOUN
th83kw5519d	7	31	-	-	PUNCT
th83kw5519d	7	32	cluster	cluster	NOUN
th83kw5519d	7	33	interconversions	interconversion	NOUN
th83kw5519d	7	34	or	or	CCONJ
th83kw5519d	7	35	postsynthetic	postsynthetic	ADJ
th83kw5519d	7	36	functionalization	functionalization	NOUN
th83kw5519d	7	37	of	of	ADP
th83kw5519d	7	38	clusters	cluster	NOUN
th83kw5519d	7	39	are	be	AUX
th83kw5519d	7	40	possible	possible	ADJ
th83kw5519d	7	41	.	.	PUNCT
th83kw5519d	8	1	in	in	ADP
th83kw5519d	8	2	addition	addition	NOUN
th83kw5519d	8	3	,	,	PUNCT
th83kw5519d	8	4	raman	raman	ADJ
th83kw5519d	8	5	and	and	CCONJ
th83kw5519d	8	6	ultravioletvisible	ultravioletvisible	ADJ
th83kw5519d	8	7	(	(	PUNCT
th83kw5519d	8	8	uv	uv	NOUN
th83kw5519d	8	9	-	-	PUNCT
th83kw5519d	8	10	vis	vis	X
th83kw5519d	8	11	)	)	PUNCT
th83kw5519d	8	12	spectroscopic	spectroscopic	ADJ
th83kw5519d	8	13	analyses	analysis	NOUN
th83kw5519d	8	14	are	be	AUX
th83kw5519d	8	15	used	use	VERB
th83kw5519d	8	16	to	to	PART
th83kw5519d	8	17	probe	probe	VERB
th83kw5519d	8	18	the	the	DET
th83kw5519d	8	19	aggregation	aggregation	NOUN
th83kw5519d	8	20	behavior	behavior	NOUN
th83kw5519d	8	21	of	of	ADP
th83kw5519d	8	22	uranyl	uranyl	ADJ
th83kw5519d	8	23	peroxide	peroxide	NOUN
th83kw5519d	8	24	cage	cage	NOUN
th83kw5519d	8	25	clusters	cluster	NOUN
th83kw5519d	8	26	in	in	ADP
th83kw5519d	8	27	the	the	DET
th83kw5519d	8	28	presence	presence	NOUN
th83kw5519d	8	29	of	of	ADP
th83kw5519d	8	30	monovalent	monovalent	NOUN
th83kw5519d	8	31	cations	cation	NOUN
th83kw5519d	8	32	,	,	PUNCT
th83kw5519d	8	33	and	and	CCONJ
th83kw5519d	8	34	voltammetric	voltammetric	ADJ
th83kw5519d	8	35	and	and	CCONJ
th83kw5519d	8	36	spectroscopic	spectroscopic	ADJ
th83kw5519d	8	37	methods	method	NOUN
th83kw5519d	8	38	are	be	AUX
th83kw5519d	8	39	used	use	VERB
th83kw5519d	8	40	to	to	PART
th83kw5519d	8	41	study	study	VERB
th83kw5519d	8	42	the	the	DET
th83kw5519d	8	43	electronic	electronic	ADJ
th83kw5519d	8	44	structure	structure	NOUN
th83kw5519d	8	45	of	of	ADP
th83kw5519d	8	46	the	the	DET
th83kw5519d	8	47	{	{	PUNCT
th83kw5519d	8	48	npo2@[np(o2)(oh)]24	npo2@[np(o2)(oh)]24	PROPN
th83kw5519d	8	49	}	}	PUNCT
th83kw5519d	8	50	(	(	PUNCT
th83kw5519d	8	51	{	{	PUNCT
th83kw5519d	8	52	np24	np24	PROPN
th83kw5519d	8	53	}	}	PUNCT
th83kw5519d	8	54	)	)	PUNCT
th83kw5519d	8	55	cluster	cluster	NOUN
th83kw5519d	8	56	.	.	PUNCT
th83kw5519d	9	1	finally	finally	ADV
th83kw5519d	9	2	,	,	PUNCT
th83kw5519d	9	3	a	a	DET
th83kw5519d	9	4	mechanistic	mechanistic	ADJ
th83kw5519d	9	5	study	study	NOUN
th83kw5519d	9	6	describing	describe	VERB
th83kw5519d	9	7	the	the	DET
th83kw5519d	9	8	formation	formation	NOUN
th83kw5519d	9	9	of	of	ADP
th83kw5519d	9	10	actinyl	actinyl	PROPN
th83kw5519d	9	11	peroxide	peroxide	NOUN
th83kw5519d	9	12	cage	cage	NOUN
th83kw5519d	9	13	clusters	cluster	NOUN
th83kw5519d	9	14	in	in	ADP
th83kw5519d	9	15	nonaqueous	nonaqueous	ADJ
th83kw5519d	9	16	solvents	solvent	NOUN
th83kw5519d	9	17	is	be	AUX
th83kw5519d	9	18	undertaken	undertake	VERB
th83kw5519d	9	19	and	and	CCONJ
th83kw5519d	9	20	shown	show	VERB
th83kw5519d	9	21	to	to	PART
th83kw5519d	9	22	involve	involve	VERB
th83kw5519d	9	23	the	the	DET
th83kw5519d	9	24	photochemical	photochemical	NOUN
th83kw5519d	9	25	of	of	ADP
th83kw5519d	9	26	bridging	bridging	NOUN
th83kw5519d	9	27	(	(	PUNCT
th83kw5519d	9	28	&	&	CCONJ
th83kw5519d	9	29	#	#	SYM
th83kw5519d	9	30	956;2	956;2	NUM
th83kw5519d	9	31	)	)	PUNCT
th83kw5519d	9	32	hydroxide	hydroxide	NOUN
th83kw5519d	9	33	ligands	ligand	NOUN
th83kw5519d	9	34	of	of	ADP
th83kw5519d	9	35	a	a	DET
th83kw5519d	9	36	dinuclear	dinuclear	ADJ
th83kw5519d	9	37	actinyl	actinyl	PROPN
th83kw5519d	9	38	complex	complex	NOUN
th83kw5519d	9	39	with	with	ADP
th83kw5519d	9	40	concomitant	concomitant	ADJ
th83kw5519d	9	41	evolution	evolution	NOUN
th83kw5519d	9	42	of	of	ADP
th83kw5519d	9	43	dihydrogen	dihydrogen	PROPN
th83kw5519d	9	44	.	.	PUNCT
th83kw5519d	10	1	this	this	DET
th83kw5519d	10	2	reactivity	reactivity	NOUN
th83kw5519d	10	3	is	be	AUX
th83kw5519d	10	4	shown	show	VERB
th83kw5519d	10	5	through	through	ADP
th83kw5519d	10	6	a	a	DET
th83kw5519d	10	7	combination	combination	NOUN
th83kw5519d	10	8	of	of	ADP
th83kw5519d	10	9	isotopic	isotopic	ADJ
th83kw5519d	10	10	labeling	labeling	NOUN
th83kw5519d	10	11	(	(	PUNCT
th83kw5519d	10	12	2h	2h	PROPN
th83kw5519d	10	13	,	,	PUNCT
th83kw5519d	10	14	18o	18o	NUM
th83kw5519d	10	15	)	)	PUNCT
th83kw5519d	10	16	studies	study	NOUN
th83kw5519d	10	17	and	and	CCONJ
th83kw5519d	10	18	synthetic	synthetic	ADJ
th83kw5519d	10	19	work	work	NOUN
th83kw5519d	10	20	,	,	PUNCT
th83kw5519d	10	21	and	and	CCONJ
th83kw5519d	10	22	all	all	DET
th83kw5519d	10	23	materials	material	NOUN
th83kw5519d	10	24	are	be	AUX
th83kw5519d	10	25	characterized	characterize	VERB
th83kw5519d	10	26	by	by	ADP
th83kw5519d	10	27	esi	esi	PROPN
th83kw5519d	10	28	-	-	PROPN
th83kw5519d	10	29	ms	ms	PROPN
th83kw5519d	10	30	,	,	PUNCT
th83kw5519d	10	31	uv	uv	NOUN
th83kw5519d	10	32	-	-	PUNCT
th83kw5519d	10	33	vis	vis	X
th83kw5519d	10	34	,	,	PUNCT
th83kw5519d	10	35	raman	raman	ADJ
th83kw5519d	10	36	,	,	PUNCT
th83kw5519d	10	37	and	and	CCONJ
th83kw5519d	10	38	nuclear	nuclear	ADJ
th83kw5519d	10	39	magnetic	magnetic	ADJ
th83kw5519d	10	40	resonance	resonance	NOUN
th83kw5519d	10	41	(	(	PUNCT
th83kw5519d	10	42	nmr	nmr	NOUN
th83kw5519d	10	43	)	)	PUNCT
th83kw5519d	10	44	spectroscopies	spectroscopy	NOUN
th83kw5519d	10	45	.	.	PUNCT
th83kw5519d	11	1	the	the	DET
th83kw5519d	11	2	evolution	evolution	NOUN
th83kw5519d	11	3	of	of	ADP
th83kw5519d	11	4	dihydrogen	dihydrogen	PROPN
th83kw5519d	11	5	(	(	PUNCT
th83kw5519d	11	6	1h-1h	1h-1h	NUM
th83kw5519d	11	7	and	and	CCONJ
th83kw5519d	11	8	2h-1h	2h-1h	NUM
th83kw5519d	11	9	)	)	PUNCT
th83kw5519d	11	10	is	be	AUX
th83kw5519d	11	11	confirmed	confirm	VERB
th83kw5519d	11	12	by	by	ADP
th83kw5519d	11	13	gas	gas	NOUN
th83kw5519d	11	14	chromatography	chromatography	NOUN
th83kw5519d	11	15	-	-	PUNCT
th83kw5519d	11	16	isotope	isotope	NOUN
th83kw5519d	11	17	ratio	ratio	NOUN
th83kw5519d	11	18	-	-	PUNCT
th83kw5519d	11	19	mass	mass	NOUN
th83kw5519d	11	20	spectrometry	spectrometry	NOUN
th83kw5519d	11	21	(	(	PUNCT
th83kw5519d	11	22	gc	gc	PROPN
th83kw5519d	11	23	-	-	PUNCT
th83kw5519d	11	24	ir	ir	PROPN
th83kw5519d	11	25	-	-	PUNCT
th83kw5519d	11	26	ms	ms	NOUN
th83kw5519d	11	27	)	)	PUNCT
th83kw5519d	11	28	and	and	CCONJ
th83kw5519d	11	29	incorporation	incorporation	NOUN
th83kw5519d	11	30	of	of	ADP
th83kw5519d	11	31	18o	18o	NOUN
th83kw5519d	11	32	into	into	ADP
th83kw5519d	11	33	the	the	DET
th83kw5519d	11	34	peroxo	peroxo	PROPN
th83kw5519d	11	35	ligand	ligand	NOUN
th83kw5519d	11	36	is	be	AUX
th83kw5519d	11	37	monitored	monitor	VERB
th83kw5519d	11	38	using	use	VERB
th83kw5519d	11	39	the	the	DET
th83kw5519d	11	40	o	o	NOUN
th83kw5519d	11	41	-	-	NOUN
th83kw5519d	11	42	o	o	NOUN
th83kw5519d	11	43	symmetric	symmetric	ADJ
th83kw5519d	11	44	stretching	stretch	VERB
th83kw5519d	11	45	mode	mode	NOUN
th83kw5519d	11	46	in	in	ADP
th83kw5519d	11	47	the	the	DET
th83kw5519d	11	48	raman	raman	NOUN
th83kw5519d	11	49	spectrum	spectrum	NOUN
th83kw5519d	11	50	.	.	PUNCT