id	sid	tid	token	lemma	pos
vh53ws87s5s	1	1	this	this	DET
vh53ws87s5s	1	2	dissertation	dissertation	NOUN
vh53ws87s5s	1	3	focuses	focus	VERB
vh53ws87s5s	1	4	on	on	ADP
vh53ws87s5s	1	5	the	the	DET
vh53ws87s5s	1	6	development	development	NOUN
vh53ws87s5s	1	7	of	of	ADP
vh53ws87s5s	1	8	a	a	DET
vh53ws87s5s	1	9	2d	2d	NOUN
vh53ws87s5s	1	10	planar	planar	ADJ
vh53ws87s5s	1	11	surface	surface	NOUN
vh53ws87s5s	1	12	enhanced	enhance	VERB
vh53ws87s5s	1	13	raman	raman	NOUN
vh53ws87s5s	1	14	spectroscopy	spectroscopy	NOUN
vh53ws87s5s	1	15	(	(	PUNCT
vh53ws87s5s	1	16	sers	ser	NOUN
vh53ws87s5s	1	17	)	)	PUNCT
vh53ws87s5s	1	18	substrate	substrate	NOUN
vh53ws87s5s	1	19	and	and	CCONJ
vh53ws87s5s	1	20	demonstrates	demonstrate	VERB
vh53ws87s5s	1	21	its	its	PRON
vh53ws87s5s	1	22	utility	utility	NOUN
vh53ws87s5s	1	23	through	through	ADP
vh53ws87s5s	1	24	in	in	ADP
vh53ws87s5s	1	25	situ	situ	ADJ
vh53ws87s5s	1	26	detection	detection	NOUN
vh53ws87s5s	1	27	and	and	CCONJ
vh53ws87s5s	1	28	the	the	DET
vh53ws87s5s	1	29	monitoring	monitoring	NOUN
vh53ws87s5s	1	30	of	of	ADP
vh53ws87s5s	1	31	the	the	DET
vh53ws87s5s	1	32	dynamics	dynamic	NOUN
vh53ws87s5s	1	33	of	of	ADP
vh53ws87s5s	1	34	macromolecular	macromolecular	ADJ
vh53ws87s5s	1	35	particles	particle	NOUN
vh53ws87s5s	1	36	via	via	ADP
vh53ws87s5s	1	37	correlation	correlation	NOUN
vh53ws87s5s	1	38	spectroscopy	spectroscopy	NOUN
vh53ws87s5s	1	39	.	.	PUNCT
vh53ws87s5s	2	1	a	a	DET
vh53ws87s5s	2	2	highly	highly	ADV
vh53ws87s5s	2	3	-	-	PUNCT
vh53ws87s5s	2	4	enhancing	enhance	VERB
vh53ws87s5s	2	5	sers	ser	NOUN
vh53ws87s5s	2	6	substrate	substrate	NOUN
vh53ws87s5s	2	7	was	be	AUX
vh53ws87s5s	2	8	fabricated	fabricate	VERB
vh53ws87s5s	2	9	via	via	ADP
vh53ws87s5s	2	10	thermal	thermal	ADJ
vh53ws87s5s	2	11	evaporation	evaporation	NOUN
vh53ws87s5s	2	12	of	of	ADP
vh53ws87s5s	2	13	noble	noble	ADJ
vh53ws87s5s	2	14	metals	metal	NOUN
vh53ws87s5s	2	15	into	into	ADP
vh53ws87s5s	2	16	a	a	DET
vh53ws87s5s	2	17	nano	nano	NOUN
vh53ws87s5s	2	18	-	-	PUNCT
vh53ws87s5s	2	19	porous	porous	ADJ
vh53ws87s5s	2	20	aluminum	aluminum	NOUN
vh53ws87s5s	2	21	oxide	oxide	NOUN
vh53ws87s5s	2	22	(	(	PUNCT
vh53ws87s5s	2	23	aao	aao	PROPN
vh53ws87s5s	2	24	)	)	PUNCT
vh53ws87s5s	2	25	template	template	NOUN
vh53ws87s5s	2	26	.	.	PUNCT
vh53ws87s5s	3	1	characterization	characterization	NOUN
vh53ws87s5s	3	2	of	of	ADP
vh53ws87s5s	3	3	the	the	DET
vh53ws87s5s	3	4	substrate	substrate	NOUN
vh53ws87s5s	3	5	was	be	AUX
vh53ws87s5s	3	6	carried	carry	VERB
vh53ws87s5s	3	7	out	out	ADP
vh53ws87s5s	3	8	by	by	ADP
vh53ws87s5s	3	9	imaging	image	VERB
vh53ws87s5s	3	10	the	the	DET
vh53ws87s5s	3	11	surface	surface	NOUN
vh53ws87s5s	3	12	using	use	VERB
vh53ws87s5s	3	13	scanning	scan	VERB
vh53ws87s5s	3	14	electron	electron	NOUN
vh53ws87s5s	3	15	microscopy	microscopy	NOUN
vh53ws87s5s	3	16	(	(	PUNCT
vh53ws87s5s	3	17	sem	sem	PROPN
vh53ws87s5s	3	18	)	)	PUNCT
vh53ws87s5s	3	19	,	,	PUNCT
vh53ws87s5s	3	20	measuring	measure	VERB
vh53ws87s5s	3	21	the	the	DET
vh53ws87s5s	3	22	sers	ser	NOUN
vh53ws87s5s	3	23	signal	signal	VERB
vh53ws87s5s	3	24	from	from	ADP
vh53ws87s5s	3	25	a	a	DET
vh53ws87s5s	3	26	self	self	NOUN
vh53ws87s5s	3	27	-	-	PUNCT
vh53ws87s5s	3	28	assembled	assemble	VERB
vh53ws87s5s	3	29	monolayer	monolayer	NOUN
vh53ws87s5s	3	30	of	of	ADP
vh53ws87s5s	3	31	thiophenol	thiophenol	NOUN
vh53ws87s5s	3	32	,	,	PUNCT
vh53ws87s5s	3	33	mapping	map	VERB
vh53ws87s5s	3	34	the	the	DET
vh53ws87s5s	3	35	thiophenol	thiophenol	ADJ
vh53ws87s5s	3	36	sers	ser	NOUN
vh53ws87s5s	3	37	signal	signal	NOUN
vh53ws87s5s	3	38	,	,	PUNCT
vh53ws87s5s	3	39	and	and	CCONJ
vh53ws87s5s	3	40	mapping	map	VERB
vh53ws87s5s	3	41	the	the	DET
vh53ws87s5s	3	42	dark	dark	ADJ
vh53ws87s5s	3	43	-	-	PUNCT
vh53ws87s5s	3	44	field	field	NOUN
vh53ws87s5s	3	45	scattering	scattering	NOUN
vh53ws87s5s	3	46	from	from	ADP
vh53ws87s5s	3	47	the	the	DET
vh53ws87s5s	3	48	substrate	substrate	NOUN
vh53ws87s5s	3	49	.	.	PUNCT
vh53ws87s5s	4	1	the	the	DET
vh53ws87s5s	4	2	data	datum	NOUN
vh53ws87s5s	4	3	indicate	indicate	VERB
vh53ws87s5s	4	4	that	that	SCONJ
vh53ws87s5s	4	5	the	the	DET
vh53ws87s5s	4	6	substrate	substrate	NOUN
vh53ws87s5s	4	7	shows	show	VERB
vh53ws87s5s	4	8	an	an	DET
vh53ws87s5s	4	9	extraordinary	extraordinary	ADJ
vh53ws87s5s	4	10	enhancement	enhancement	ADJ
vh53ws87s5s	4	11	factor	factor	NOUN
vh53ws87s5s	4	12	(	(	PUNCT
vh53ws87s5s	4	13	108	108	NUM
vh53ws87s5s	4	14	)	)	PUNCT
vh53ws87s5s	4	15	and	and	CCONJ
vh53ws87s5s	4	16	uniform	uniform	NOUN
vh53ws87s5s	4	17	sers	ser	VERB
vh53ws87s5s	4	18	response	response	NOUN
vh53ws87s5s	4	19	(	(	PUNCT
vh53ws87s5s	4	20	rsd	rsd	PROPN
vh53ws87s5s	4	21	~10	~10	PROPN
vh53ws87s5s	4	22	%	%	NOUN
vh53ws87s5s	4	23	)	)	PUNCT
vh53ws87s5s	4	24	due	due	ADP
vh53ws87s5s	4	25	to	to	ADP
vh53ws87s5s	4	26	its	its	PRON
vh53ws87s5s	4	27	high	high	ADJ
vh53ws87s5s	4	28	density	density	NOUN
vh53ws87s5s	4	29	of	of	ADP
vh53ws87s5s	4	30	enhancing	enhance	VERB
vh53ws87s5s	4	31	sites	site	NOUN
vh53ws87s5s	4	32	.	.	PUNCT
vh53ws87s5s	5	1	the	the	DET
vh53ws87s5s	5	2	substrate	substrate	NOUN
vh53ws87s5s	5	3	was	be	AUX
vh53ws87s5s	5	4	incorporated	incorporate	VERB
vh53ws87s5s	5	5	into	into	ADP
vh53ws87s5s	5	6	a	a	DET
vh53ws87s5s	5	7	commercial	commercial	ADJ
vh53ws87s5s	5	8	flow	flow	NOUN
vh53ws87s5s	5	9	cell	cell	NOUN
vh53ws87s5s	5	10	to	to	PART
vh53ws87s5s	5	11	facilitate	facilitate	VERB
vh53ws87s5s	5	12	the	the	DET
vh53ws87s5s	5	13	labelfree	labelfree	NOUN
vh53ws87s5s	5	14	,	,	PUNCT
vh53ws87s5s	5	15	in	in	ADP
vh53ws87s5s	5	16	situ	situ	ADJ
vh53ws87s5s	5	17	detection	detection	NOUN
vh53ws87s5s	5	18	of	of	ADP
vh53ws87s5s	5	19	single	single	ADJ
vh53ws87s5s	5	20	macromolecular	macromolecular	ADJ
vh53ws87s5s	5	21	particles	particle	NOUN
vh53ws87s5s	5	22	including	include	VERB
vh53ws87s5s	5	23	lipid	lipid	NOUN
vh53ws87s5s	5	24	vesicles	vesicle	NOUN
vh53ws87s5s	5	25	(	(	PUNCT
vh53ws87s5s	5	26	dppc	dppc	NOUN
vh53ws87s5s	5	27	)	)	PUNCT
vh53ws87s5s	5	28	and	and	CCONJ
vh53ws87s5s	5	29	polystyrene	polystyrene	NOUN
vh53ws87s5s	5	30	(	(	PUNCT
vh53ws87s5s	5	31	ps	ps	NOUN
vh53ws87s5s	5	32	)	)	PUNCT
vh53ws87s5s	5	33	beads	bead	NOUN
vh53ws87s5s	5	34	.	.	PUNCT
vh53ws87s5s	6	1	the	the	DET
vh53ws87s5s	6	2	substrate	substrate	NOUN
vh53ws87s5s	6	3	facilitates	facilitate	VERB
vh53ws87s5s	6	4	detection	detection	NOUN
vh53ws87s5s	6	5	by	by	ADP
vh53ws87s5s	6	6	providing	provide	VERB
vh53ws87s5s	6	7	enhancement	enhancement	NOUN
vh53ws87s5s	6	8	of	of	ADP
vh53ws87s5s	6	9	signal	signal	NOUN
vh53ws87s5s	6	10	from	from	ADP
vh53ws87s5s	6	11	particles	particle	NOUN
vh53ws87s5s	6	12	in	in	ADP
vh53ws87s5s	6	13	solution	solution	NOUN
vh53ws87s5s	6	14	approaching	approach	VERB
vh53ws87s5s	6	15	the	the	DET
vh53ws87s5s	6	16	surface	surface	NOUN
vh53ws87s5s	6	17	.	.	PUNCT
vh53ws87s5s	7	1	the	the	DET
vh53ws87s5s	7	2	duration	duration	NOUN
vh53ws87s5s	7	3	of	of	ADP
vh53ws87s5s	7	4	the	the	DET
vh53ws87s5s	7	5	observed	observe	VERB
vh53ws87s5s	7	6	signal	signal	NOUN
vh53ws87s5s	7	7	demonstrates	demonstrate	VERB
vh53ws87s5s	7	8	the	the	DET
vh53ws87s5s	7	9	capability	capability	NOUN
vh53ws87s5s	7	10	of	of	ADP
vh53ws87s5s	7	11	monitoring	monitor	VERB
vh53ws87s5s	7	12	the	the	DET
vh53ws87s5s	7	13	diffusion	diffusion	NOUN
vh53ws87s5s	7	14	of	of	ADP
vh53ws87s5s	7	15	macromolecular	macromolecular	ADJ
vh53ws87s5s	7	16	species	specie	NOUN
vh53ws87s5s	7	17	in	in	ADP
vh53ws87s5s	7	18	solution	solution	NOUN
vh53ws87s5s	7	19	on	on	ADP
vh53ws87s5s	7	20	the	the	DET
vh53ws87s5s	7	21	millisecond	millisecond	ADJ
vh53ws87s5s	7	22	time	time	NOUN
vh53ws87s5s	7	23	scale	scale	NOUN
vh53ws87s5s	7	24	.	.	PUNCT
vh53ws87s5s	8	1	finally	finally	ADV
vh53ws87s5s	8	2	,	,	PUNCT
vh53ws87s5s	8	3	the	the	DET
vh53ws87s5s	8	4	sers	ser	NOUN
vh53ws87s5s	8	5	substrate	substrate	NOUN
vh53ws87s5s	8	6	was	be	AUX
vh53ws87s5s	8	7	utilized	utilize	VERB
vh53ws87s5s	8	8	to	to	PART
vh53ws87s5s	8	9	demonstrate	demonstrate	VERB
vh53ws87s5s	8	10	surface	surface	NOUN
vh53ws87s5s	8	11	enhanced	enhance	VERB
vh53ws87s5s	8	12	raman	raman	ADJ
vh53ws87s5s	8	13	correlation	correlation	NOUN
vh53ws87s5s	8	14	spectroscopy	spectroscopy	NOUN
vh53ws87s5s	8	15	(	(	PUNCT
vh53ws87s5s	8	16	sercs	sercs	PROPN
vh53ws87s5s	8	17	)	)	PUNCT
vh53ws87s5s	8	18	for	for	ADP
vh53ws87s5s	8	19	assemblies	assembly	NOUN
vh53ws87s5s	8	20	interacting	interact	VERB
vh53ws87s5s	8	21	with	with	ADP
vh53ws87s5s	8	22	the	the	DET
vh53ws87s5s	8	23	substrate	substrate	NOUN
vh53ws87s5s	8	24	.	.	PUNCT
vh53ws87s5s	9	1	autoand	autoand	NOUN
vh53ws87s5s	9	2	cross	cross	NOUN
vh53ws87s5s	9	3	-	-	NOUN
vh53ws87s5s	9	4	correlation	correlation	NOUN
vh53ws87s5s	9	5	of	of	ADP
vh53ws87s5s	9	6	the	the	DET
vh53ws87s5s	9	7	time	time	NOUN
vh53ws87s5s	9	8	dependent	dependent	ADJ
vh53ws87s5s	9	9	sers	ser	NOUN
vh53ws87s5s	9	10	signal	signal	NOUN
vh53ws87s5s	9	11	allows	allow	VERB
vh53ws87s5s	9	12	for	for	ADP
vh53ws87s5s	9	13	the	the	DET
vh53ws87s5s	9	14	monitoring	monitoring	NOUN
vh53ws87s5s	9	15	of	of	ADP
vh53ws87s5s	9	16	diffusion	diffusion	NOUN
vh53ws87s5s	9	17	dynamics	dynamic	NOUN
vh53ws87s5s	9	18	for	for	ADP
vh53ws87s5s	9	19	particles	particle	NOUN
vh53ws87s5s	9	20	ranging	range	VERB
vh53ws87s5s	9	21	in	in	ADP
vh53ws87s5s	9	22	radius	radius	NOUN
vh53ws87s5s	9	23	from	from	ADP
vh53ws87s5s	9	24	50	50	NUM
vh53ws87s5s	9	25	to	to	PART
vh53ws87s5s	9	26	500	500	NUM
vh53ws87s5s	9	27	nm	nm	NOUN
vh53ws87s5s	9	28	while	while	SCONJ
vh53ws87s5s	9	29	simultaneously	simultaneously	ADV
vh53ws87s5s	9	30	rejecting	reject	VERB
vh53ws87s5s	9	31	extraneous	extraneous	ADJ
vh53ws87s5s	9	32	signal	signal	NOUN
vh53ws87s5s	9	33	fluctuations	fluctuation	NOUN
vh53ws87s5s	9	34	.	.	PUNCT
vh53ws87s5s	10	1	when	when	SCONJ
vh53ws87s5s	10	2	the	the	DET
vh53ws87s5s	10	3	extension	extension	NOUN
vh53ws87s5s	10	4	of	of	ADP
vh53ws87s5s	10	5	the	the	DET
vh53ws87s5s	10	6	sers	ser	NOUN
vh53ws87s5s	10	7	field	field	VERB
vh53ws87s5s	10	8	away	away	ADV
vh53ws87s5s	10	9	from	from	ADP
vh53ws87s5s	10	10	the	the	DET
vh53ws87s5s	10	11	surface	surface	NOUN
vh53ws87s5s	10	12	is	be	AUX
vh53ws87s5s	10	13	approximated	approximate	VERB
vh53ws87s5s	10	14	to	to	PART
vh53ws87s5s	10	15	be	be	AUX
vh53ws87s5s	10	16	5	5	NUM
vh53ws87s5s	10	17	nm	nm	NOUN
vh53ws87s5s	10	18	,	,	PUNCT
vh53ws87s5s	10	19	the	the	DET
vh53ws87s5s	10	20	diffusion	diffusion	NOUN
vh53ws87s5s	10	21	constants	constant	NOUN
vh53ws87s5s	10	22	measured	measure	VERB
vh53ws87s5s	10	23	are	be	AUX
vh53ws87s5s	10	24	on	on	ADP
vh53ws87s5s	10	25	the	the	DET
vh53ws87s5s	10	26	order	order	NOUN
vh53ws87s5s	10	27	of	of	ADP
vh53ws87s5s	10	28	10	10	NUM
vh53ws87s5s	10	29	-	-	SYM
vh53ws87s5s	10	30	10	10	NUM
vh53ws87s5s	10	31	-	-	PUNCT
vh53ws87s5s	10	32	10	10	NUM
vh53ws87s5s	10	33	-	-	SYM
vh53ws87s5s	10	34	11	11	NUM
vh53ws87s5s	10	35	cm2	cm2	PROPN
vh53ws87s5s	10	36	/	/	SYM
vh53ws87s5s	10	37	s	s	NUM
vh53ws87s5s	10	38	,	,	PUNCT
vh53ws87s5s	10	39	a	a	DET
vh53ws87s5s	10	40	factor	factor	NOUN
vh53ws87s5s	10	41	of	of	ADP
vh53ws87s5s	10	42	40	40	NUM
vh53ws87s5s	10	43	slower	slow	ADJ
vh53ws87s5s	10	44	than	than	ADP
vh53ws87s5s	10	45	stokeseinstein	stokeseinstein	ADJ
vh53ws87s5s	10	46	predictions	prediction	NOUN
vh53ws87s5s	10	47	.	.	PUNCT
vh53ws87s5s	11	1	the	the	DET
vh53ws87s5s	11	2	slow	slow	ADJ
vh53ws87s5s	11	3	diffusion	diffusion	NOUN
vh53ws87s5s	11	4	constants	constant	NOUN
vh53ws87s5s	11	5	suggest	suggest	VERB
vh53ws87s5s	11	6	that	that	SCONJ
vh53ws87s5s	11	7	particles	particle	NOUN
vh53ws87s5s	11	8	are	be	AUX
vh53ws87s5s	11	9	interacting	interact	VERB
vh53ws87s5s	11	10	with	with	ADP
vh53ws87s5s	11	11	the	the	DET
vh53ws87s5s	11	12	substrate	substrate	NOUN
vh53ws87s5s	11	13	and	and	CCONJ
vh53ws87s5s	11	14	experiencing	experience	VERB
vh53ws87s5s	11	15	hindered	hindered	ADJ
vh53ws87s5s	11	16	diffusion	diffusion	NOUN
vh53ws87s5s	11	17	near	near	ADP
vh53ws87s5s	11	18	the	the	DET
vh53ws87s5s	11	19	surface	surface	NOUN
vh53ws87s5s	11	20	.	.	PUNCT