id sid tid token lemma pos vh53ws87v3q 1 1 understanding understand VERB vh53ws87v3q 1 2 the the DET vh53ws87v3q 1 3 growth growth NOUN vh53ws87v3q 1 4 and and CCONJ vh53ws87v3q 1 5 properties property NOUN vh53ws87v3q 1 6 of of ADP vh53ws87v3q 1 7 oxygen oxygen NOUN vh53ws87v3q 1 8 phases phase NOUN vh53ws87v3q 1 9 on on ADP vh53ws87v3q 1 10 platinum platinum NOUN vh53ws87v3q 1 11 surfaces surface NOUN vh53ws87v3q 1 12 is be AUX vh53ws87v3q 1 13 fundamental fundamental ADJ vh53ws87v3q 1 14 to to ADP vh53ws87v3q 1 15 many many ADJ vh53ws87v3q 1 16 heterogeneous heterogeneous ADJ vh53ws87v3q 1 17 catalytic catalytic ADJ vh53ws87v3q 1 18 reactions reaction NOUN vh53ws87v3q 1 19 of of ADP vh53ws87v3q 1 20 industrial industrial ADJ vh53ws87v3q 1 21 importance importance NOUN vh53ws87v3q 1 22 . . PUNCT vh53ws87v3q 2 1 at at ADP vh53ws87v3q 2 2 pressures pressure NOUN vh53ws87v3q 2 3 of of ADP vh53ws87v3q 2 4 commercial commercial ADJ vh53ws87v3q 2 5 applications application NOUN vh53ws87v3q 2 6 , , PUNCT vh53ws87v3q 2 7 o o NOUN vh53ws87v3q 2 8 exists exist VERB vh53ws87v3q 2 9 on on ADP vh53ws87v3q 2 10 pt pt PROPN vh53ws87v3q 2 11 surfaces surface NOUN vh53ws87v3q 2 12 in in ADP vh53ws87v3q 2 13 a a DET vh53ws87v3q 2 14 variety variety NOUN vh53ws87v3q 2 15 of of ADP vh53ws87v3q 2 16 states state NOUN vh53ws87v3q 2 17 or or CCONJ vh53ws87v3q 2 18 phases phase NOUN vh53ws87v3q 2 19 , , PUNCT vh53ws87v3q 2 20 intermediate intermediate ADJ vh53ws87v3q 2 21 between between ADP vh53ws87v3q 2 22 a a DET vh53ws87v3q 2 23 chemisorbed chemisorbed ADJ vh53ws87v3q 2 24 layer layer NOUN vh53ws87v3q 2 25 and and CCONJ vh53ws87v3q 2 26 the the DET vh53ws87v3q 2 27 bulk bulk ADJ vh53ws87v3q 2 28 oxide(s oxide(s NOUN vh53ws87v3q 2 29 ) ) PUNCT vh53ws87v3q 2 30 . . PUNCT vh53ws87v3q 3 1 substantial substantial ADJ vh53ws87v3q 3 2 motivation motivation NOUN vh53ws87v3q 3 3 for for ADP vh53ws87v3q 3 4 understanding understand VERB vh53ws87v3q 3 5 the the DET vh53ws87v3q 3 6 properties property NOUN vh53ws87v3q 3 7 and and CCONJ vh53ws87v3q 3 8 development development NOUN vh53ws87v3q 3 9 the the DET vh53ws87v3q 3 10 different different ADJ vh53ws87v3q 3 11 o o NOUN vh53ws87v3q 3 12 phases phase NOUN vh53ws87v3q 3 13 derives derive VERB vh53ws87v3q 3 14 from from ADP vh53ws87v3q 3 15 different different ADJ vh53ws87v3q 3 16 o o NOUN vh53ws87v3q 3 17 phases phase NOUN vh53ws87v3q 3 18 having have VERB vh53ws87v3q 3 19 distinct distinct ADJ vh53ws87v3q 3 20 catalytic catalytic ADJ vh53ws87v3q 3 21 properties property NOUN vh53ws87v3q 3 22 . . PUNCT vh53ws87v3q 4 1 an an DET vh53ws87v3q 4 2 understanding understanding NOUN vh53ws87v3q 4 3 of of ADP vh53ws87v3q 4 4 conditions condition NOUN vh53ws87v3q 4 5 leading lead VERB vh53ws87v3q 4 6 to to ADP vh53ws87v3q 4 7 different different ADJ vh53ws87v3q 4 8 o o NOUN vh53ws87v3q 4 9 phases phase NOUN vh53ws87v3q 4 10 , , PUNCT vh53ws87v3q 4 11 and and CCONJ vh53ws87v3q 4 12 interactions interaction NOUN vh53ws87v3q 4 13 of of ADP vh53ws87v3q 4 14 o o NOUN vh53ws87v3q 4 15 phases phase NOUN vh53ws87v3q 4 16 with with ADP vh53ws87v3q 4 17 reactant reactant ADJ vh53ws87v3q 4 18 and and CCONJ vh53ws87v3q 4 19 product product NOUN vh53ws87v3q 4 20 molecules molecule NOUN vh53ws87v3q 4 21 could could AUX vh53ws87v3q 4 22 more more ADV vh53ws87v3q 4 23 accurately accurately ADV vh53ws87v3q 4 24 describe describe VERB vh53ws87v3q 4 25 and and CCONJ vh53ws87v3q 4 26 even even ADV vh53ws87v3q 4 27 predicting predict VERB vh53ws87v3q 4 28 the the DET vh53ws87v3q 4 29 behavior behavior NOUN vh53ws87v3q 4 30 of of ADP vh53ws87v3q 4 31 pt pt PROPN vh53ws87v3q 4 32 catalysts catalyst NOUN vh53ws87v3q 4 33 . . PUNCT vh53ws87v3q 5 1 the the DET vh53ws87v3q 5 2 ability ability NOUN vh53ws87v3q 5 3 to to PART vh53ws87v3q 5 4 control control VERB vh53ws87v3q 5 5 the the DET vh53ws87v3q 5 6 formation formation NOUN vh53ws87v3q 5 7 , , PUNCT vh53ws87v3q 5 8 size size NOUN vh53ws87v3q 5 9 and and CCONJ vh53ws87v3q 5 10 spatial spatial ADJ vh53ws87v3q 5 11 separation separation NOUN vh53ws87v3q 5 12 of of ADP vh53ws87v3q 5 13 oxides oxide NOUN vh53ws87v3q 5 14 is be AUX vh53ws87v3q 5 15 important important ADJ vh53ws87v3q 5 16 for for ADP vh53ws87v3q 5 17 improving improve VERB vh53ws87v3q 5 18 pt pt PROPN vh53ws87v3q 5 19 and and CCONJ vh53ws87v3q 5 20 other other ADJ vh53ws87v3q 5 21 oxidizing oxidize VERB vh53ws87v3q 5 22 catalysts.molecular catalysts.molecular NOUN vh53ws87v3q 5 23 o o NOUN vh53ws87v3q 5 24 adsorbs adsorb NOUN vh53ws87v3q 5 25 on on ADP vh53ws87v3q 5 26 the the DET vh53ws87v3q 5 27 pt(111 pt(111 ADJ vh53ws87v3q 5 28 ) ) PUNCT vh53ws87v3q 5 29 surface surface NOUN vh53ws87v3q 5 30 below below ADP vh53ws87v3q 5 31 160k 160k NUM vh53ws87v3q 5 32 , , PUNCT vh53ws87v3q 5 33 but but CCONJ vh53ws87v3q 5 34 dissociates dissociate NOUN vh53ws87v3q 5 35 at at ADP vh53ws87v3q 5 36 higher high ADJ vh53ws87v3q 5 37 temperatures temperature NOUN vh53ws87v3q 5 38 forming form VERB vh53ws87v3q 5 39 a a DET vh53ws87v3q 5 40 p(2x2 p(2x2 NUM vh53ws87v3q 5 41 ) ) PUNCT vh53ws87v3q 5 42 adlayer adlayer PROPN vh53ws87v3q 5 43 structure structure NOUN vh53ws87v3q 5 44 with with ADP vh53ws87v3q 5 45 o o NOUN vh53ws87v3q 5 46 atoms atom NOUN vh53ws87v3q 5 47 occupying occupy VERB vh53ws87v3q 5 48 fcc fcc PROPN vh53ws87v3q 5 49 three three NUM vh53ws87v3q 5 50 - - ADJ vh53ws87v3q 5 51 fold fold ADJ vh53ws87v3q 5 52 hollow hollow ADJ vh53ws87v3q 5 53 sites site NOUN vh53ws87v3q 5 54 . . PUNCT vh53ws87v3q 6 1 the the DET vh53ws87v3q 6 2 surface surface NOUN vh53ws87v3q 6 3 saturates saturate VERB vh53ws87v3q 6 4 at at ADP vh53ws87v3q 6 5 a a DET vh53ws87v3q 6 6 coverage coverage NOUN vh53ws87v3q 6 7 of of ADP vh53ws87v3q 6 8 0.25ml 0.25ml PROPN vh53ws87v3q 6 9 in in ADP vh53ws87v3q 6 10 ultra ultra ADJ vh53ws87v3q 6 11 high high ADJ vh53ws87v3q 6 12 vacuum vacuum NOUN vh53ws87v3q 6 13 , , PUNCT vh53ws87v3q 6 14 due due ADP vh53ws87v3q 6 15 to to ADP vh53ws87v3q 6 16 strong strong ADJ vh53ws87v3q 6 17 lateral lateral ADJ vh53ws87v3q 6 18 repulsive repulsive ADJ vh53ws87v3q 6 19 interactions interaction NOUN vh53ws87v3q 6 20 between between ADP vh53ws87v3q 6 21 the the DET vh53ws87v3q 6 22 o o NOUN vh53ws87v3q 6 23 atoms atom NOUN vh53ws87v3q 6 24 . . PUNCT vh53ws87v3q 7 1 higher high ADJ vh53ws87v3q 7 2 chemisorbed chemisorbed ADJ vh53ws87v3q 7 3 o o ADP vh53ws87v3q 7 4 coverages coverage NOUN vh53ws87v3q 7 5 ( ( PUNCT vh53ws87v3q 7 6 0.25 0.25 NUM vh53ws87v3q 7 7 - - SYM vh53ws87v3q 7 8 0.75 0.75 NUM vh53ws87v3q 7 9 ml ml PROPN vh53ws87v3q 7 10 ) ) PUNCT vh53ws87v3q 7 11 or or CCONJ vh53ws87v3q 7 12 oxide oxide NOUN vh53ws87v3q 7 13 overlayers overlayer NOUN vh53ws87v3q 7 14 ( ( PUNCT vh53ws87v3q 7 15 0.75 0.75 NUM vh53ws87v3q 7 16 ml ml NOUN vh53ws87v3q 7 17 and and CCONJ vh53ws87v3q 7 18 higher high ADJ vh53ws87v3q 7 19 ) ) PUNCT vh53ws87v3q 7 20 can can AUX vh53ws87v3q 7 21 be be AUX vh53ws87v3q 7 22 obtained obtain VERB vh53ws87v3q 7 23 either either CCONJ vh53ws87v3q 7 24 by by ADP vh53ws87v3q 7 25 annealing anneal VERB vh53ws87v3q 7 26 in in ADP vh53ws87v3q 7 27 \ce{o2 \ce{o2 PROPN vh53ws87v3q 7 28 } } PUNCT vh53ws87v3q 7 29 or or CCONJ vh53ws87v3q 7 30 by by ADP vh53ws87v3q 7 31 utilizing utilize VERB vh53ws87v3q 7 32 ozone ozone NOUN vh53ws87v3q 7 33 , , PUNCT vh53ws87v3q 7 34 atomic atomic PROPN vh53ws87v3q 7 35 o o PROPN vh53ws87v3q 7 36 , , PUNCT vh53ws87v3q 7 37 or or CCONJ vh53ws87v3q 7 38 \ce{no2 \ce{no2 PROPN vh53ws87v3q 7 39 } } PUNCT vh53ws87v3q 7 40 . . PUNCT vh53ws87v3q 8 1 since since SCONJ vh53ws87v3q 8 2 oxidizing oxidize VERB vh53ws87v3q 8 3 no no PRON vh53ws87v3q 8 4 to to ADP vh53ws87v3q 8 5 \ce{no2 \ce{no2 PROPN vh53ws87v3q 8 6 } } PUNCT vh53ws87v3q 8 7 is be AUX vh53ws87v3q 8 8 of of ADP vh53ws87v3q 8 9 important important ADJ vh53ws87v3q 8 10 interest interest NOUN vh53ws87v3q 8 11 to to ADP vh53ws87v3q 8 12 our our PRON vh53ws87v3q 8 13 group group NOUN vh53ws87v3q 8 14 , , PUNCT vh53ws87v3q 8 15 understand understand VERB vh53ws87v3q 8 16 how how SCONJ vh53ws87v3q 8 17 o o PRON vh53ws87v3q 8 18 occupies occupy VERB vh53ws87v3q 8 19 different different ADJ vh53ws87v3q 8 20 surface surface NOUN vh53ws87v3q 8 21 sites site NOUN vh53ws87v3q 8 22 ( ( PUNCT vh53ws87v3q 8 23 fcc fcc NOUN vh53ws87v3q 8 24 and and CCONJ vh53ws87v3q 8 25 hcp hcp NOUN vh53ws87v3q 8 26 hollow hollow ADJ vh53ws87v3q 8 27 sites site NOUN vh53ws87v3q 8 28 ) ) PUNCT vh53ws87v3q 8 29 on on ADP vh53ws87v3q 8 30 pt(111 pt(111 ADJ vh53ws87v3q 8 31 ) ) PUNCT vh53ws87v3q 8 32 at at ADP vh53ws87v3q 8 33 intermediate intermediate ADJ vh53ws87v3q 8 34 coverages coverage NOUN vh53ws87v3q 8 35 in in ADP vh53ws87v3q 8 36 the the DET vh53ws87v3q 8 37 range range NOUN vh53ws87v3q 8 38 of of ADP vh53ws87v3q 8 39 0.25 0.25 NUM vh53ws87v3q 8 40 - - SYM vh53ws87v3q 8 41 0.75 0.75 NUM vh53ws87v3q 8 42 ml ml PROPN vh53ws87v3q 8 43 could could AUX vh53ws87v3q 8 44 further far ADV vh53ws87v3q 8 45 enhance enhance VERB vh53ws87v3q 8 46 our our PRON vh53ws87v3q 8 47 no no DET vh53ws87v3q 8 48 oxidation oxidation NOUN vh53ws87v3q 8 49 studies.the studies.the DET vh53ws87v3q 8 50 occupation occupation NOUN vh53ws87v3q 8 51 of of ADP vh53ws87v3q 8 52 the the DET vh53ws87v3q 8 53 hcp hcp PROPN vh53ws87v3q 8 54 three three NUM vh53ws87v3q 8 55 - - ADJ vh53ws87v3q 8 56 fold fold ADJ vh53ws87v3q 8 57 hollow hollow ADJ vh53ws87v3q 8 58 site site NOUN vh53ws87v3q 8 59 becomes becomes AUX vh53ws87v3q 8 60 thermodynamically thermodynamically ADV vh53ws87v3q 8 61 favored favor VERB vh53ws87v3q 8 62 at at ADP vh53ws87v3q 8 63 coverages coverage NOUN vh53ws87v3q 8 64 above above ADP vh53ws87v3q 8 65 0.42 0.42 NUM vh53ws87v3q 8 66 ml ml NOUN vh53ws87v3q 8 67 and and CCONJ vh53ws87v3q 8 68 agree agree VERB vh53ws87v3q 8 69 with with ADP vh53ws87v3q 8 70 experimental experimental ADJ vh53ws87v3q 8 71 results result NOUN vh53ws87v3q 8 72 indicating indicate VERB vh53ws87v3q 8 73 the the DET vh53ws87v3q 8 74 occupation occupation NOUN vh53ws87v3q 8 75 of of ADP vh53ws87v3q 8 76 fcc fcc PROPN vh53ws87v3q 8 77 only only ADV vh53ws87v3q 8 78 sites site NOUN vh53ws87v3q 8 79 at at ADP vh53ws87v3q 8 80 lower low ADJ vh53ws87v3q 8 81 coverages coverage NOUN vh53ws87v3q 8 82 . . PUNCT vh53ws87v3q 9 1 when when SCONJ vh53ws87v3q 9 2 the the DET vh53ws87v3q 9 3 1 1 NUM vh53ws87v3q 9 4 nearest near ADJ vh53ws87v3q 9 5 neighbor neighbor NOUN vh53ws87v3q 9 6 fcc fcc PROPN vh53ws87v3q 9 7 - - PUNCT vh53ws87v3q 9 8 hcp hcp PROPN vh53ws87v3q 9 9 pair pair NOUN vh53ws87v3q 9 10 is be AUX vh53ws87v3q 9 11 occupied occupy VERB vh53ws87v3q 9 12 , , PUNCT vh53ws87v3q 9 13 surface surface NOUN vh53ws87v3q 9 14 pt pt PROPN vh53ws87v3q 9 15 atoms atom NOUN vh53ws87v3q 9 16 buckle buckle VERB vh53ws87v3q 9 17 up up ADP vh53ws87v3q 9 18 into into ADP vh53ws87v3q 9 19 the the DET vh53ws87v3q 9 20 o o NOUN vh53ws87v3q 9 21 layer layer NOUN vh53ws87v3q 9 22 to to PART vh53ws87v3q 9 23 screen screen VERB vh53ws87v3q 9 24 repulsive repulsive ADJ vh53ws87v3q 10 1 o o NOUN vh53ws87v3q 10 2 - - NOUN vh53ws87v3q 10 3 o o NOUN vh53ws87v3q 10 4 interactions interaction NOUN vh53ws87v3q 10 5 . . PUNCT vh53ws87v3q 11 1 the the DET vh53ws87v3q 11 2 buckled buckled ADJ vh53ws87v3q 11 3 pt pt PROPN vh53ws87v3q 11 4 becomes become VERB vh53ws87v3q 11 5 geometrically geometrically ADV vh53ws87v3q 11 6 and and CCONJ vh53ws87v3q 11 7 electronically electronically ADV vh53ws87v3q 11 8 similar similar ADJ vh53ws87v3q 11 9 to to ADP vh53ws87v3q 11 10 pt pt PROPN vh53ws87v3q 11 11 atoms atom NOUN vh53ws87v3q 11 12 in in ADP vh53ws87v3q 11 13 bulk bulk ADJ vh53ws87v3q 11 14 pt pt PROPN vh53ws87v3q 11 15 oxides oxides PROPN vh53ws87v3q 11 16 , , PUNCT vh53ws87v3q 11 17 further far ADV vh53ws87v3q 11 18 supporting support VERB vh53ws87v3q 11 19 the the DET vh53ws87v3q 11 20 formation formation NOUN vh53ws87v3q 11 21 of of ADP vh53ws87v3q 11 22 surface surface NOUN vh53ws87v3q 11 23 oxide oxide NOUN vh53ws87v3q 11 24 chains chain NOUN vh53ws87v3q 11 25 . . PUNCT vh53ws87v3q 12 1 combining combine VERB vh53ws87v3q 12 2 \ \ PROPN vh53ws87v3q 12 3 extit{ab extit{ab NOUN vh53ws87v3q 12 4 initio initio NOUN vh53ws87v3q 12 5 } } PUNCT vh53ws87v3q 12 6 density density NOUN vh53ws87v3q 12 7 functional functional ADJ vh53ws87v3q 12 8 theory theory NOUN vh53ws87v3q 12 9 calculations calculation NOUN vh53ws87v3q 12 10 and and CCONJ vh53ws87v3q 12 11 cluster cluster NOUN vh53ws87v3q 12 12 expansion expansion NOUN vh53ws87v3q 12 13 models model NOUN vh53ws87v3q 12 14 we we PRON vh53ws87v3q 12 15 find find VERB vh53ws87v3q 12 16 new new ADJ vh53ws87v3q 12 17 thermodynamically thermodynamically ADV vh53ws87v3q 12 18 stable stable ADJ vh53ws87v3q 12 19 ground ground NOUN vh53ws87v3q 12 20 state state NOUN vh53ws87v3q 12 21 structures structure NOUN vh53ws87v3q 12 22 with with ADP vh53ws87v3q 12 23 an an DET vh53ws87v3q 12 24 underlying underlie VERB vh53ws87v3q 12 25 p(2x1 p(2x1 SPACE vh53ws87v3q 12 26 ) ) PUNCT vh53ws87v3q 12 27 fcc fcc PROPN vh53ws87v3q 12 28 o o NOUN vh53ws87v3q 12 29 pattern pattern NOUN vh53ws87v3q 12 30 consistent consistent ADJ vh53ws87v3q 12 31 with with ADP vh53ws87v3q 12 32 experimental experimental ADJ vh53ws87v3q 12 33 low low ADJ vh53ws87v3q 12 34 - - PUNCT vh53ws87v3q 12 35 energy energy NOUN vh53ws87v3q 12 36 electron electron NOUN vh53ws87v3q 12 37 diffraction diffraction NOUN vh53ws87v3q 12 38 patterns.the patterns.the DET vh53ws87v3q 12 39 diffusion diffusion NOUN vh53ws87v3q 12 40 of of ADP vh53ws87v3q 12 41 o o NOUN vh53ws87v3q 12 42 across across ADP vh53ws87v3q 12 43 the the DET vh53ws87v3q 12 44 pt(111 pt(111 ADJ vh53ws87v3q 12 45 ) ) PUNCT vh53ws87v3q 12 46 surface surface NOUN vh53ws87v3q 12 47 is be AUX vh53ws87v3q 12 48 mostly mostly ADV vh53ws87v3q 12 49 independent independent ADJ vh53ws87v3q 12 50 of of ADP vh53ws87v3q 12 51 surface surface NOUN vh53ws87v3q 12 52 o o PROPN vh53ws87v3q 12 53 coverage coverage NOUN vh53ws87v3q 12 54 and and CCONJ vh53ws87v3q 12 55 configuration configuration NOUN vh53ws87v3q 12 56 , , PUNCT vh53ws87v3q 12 57 both both PRON vh53ws87v3q 12 58 in in ADP vh53ws87v3q 12 59 terms term NOUN vh53ws87v3q 12 60 of of ADP vh53ws87v3q 12 61 energetics energetic NOUN vh53ws87v3q 12 62 and and CCONJ vh53ws87v3q 12 63 diffusion diffusion NOUN vh53ws87v3q 12 64 barriers barrier NOUN vh53ws87v3q 12 65 . . PUNCT vh53ws87v3q 13 1 however however ADV vh53ws87v3q 13 2 the the DET vh53ws87v3q 13 3 buckling buckling NOUN vh53ws87v3q 13 4 of of ADP vh53ws87v3q 13 5 surface surface NOUN vh53ws87v3q 13 6 pt pt PROPN vh53ws87v3q 13 7 atoms atom NOUN vh53ws87v3q 13 8 highly highly ADV vh53ws87v3q 13 9 depends depend VERB vh53ws87v3q 13 10 on on ADP vh53ws87v3q 13 11 local local ADJ vh53ws87v3q 13 12 surface surface NOUN vh53ws87v3q 13 13 coverage coverage NOUN vh53ws87v3q 13 14 and and CCONJ vh53ws87v3q 13 15 local local ADJ vh53ws87v3q 13 16 o o NOUN vh53ws87v3q 13 17 configuration configuration NOUN vh53ws87v3q 13 18 . . PUNCT vh53ws87v3q 14 1 the the DET vh53ws87v3q 14 2 strong strong ADJ vh53ws87v3q 14 3 repulsive repulsive ADJ vh53ws87v3q 14 4 o o NOUN vh53ws87v3q 14 5 - - NOUN vh53ws87v3q 14 6 o o NOUN vh53ws87v3q 14 7 interactions interaction NOUN vh53ws87v3q 14 8 within within ADP vh53ws87v3q 14 9 the the DET vh53ws87v3q 14 10 chemisorbed chemisorbed ADJ vh53ws87v3q 14 11 layer layer NOUN vh53ws87v3q 14 12 at at ADP vh53ws87v3q 14 13 moderate moderate ADJ vh53ws87v3q 14 14 ( ( PUNCT vh53ws87v3q 14 15 0.25 0.25 NUM vh53ws87v3q 14 16 - - PUNCT vh53ws87v3q 14 17 0.75ml 0.75ml NUM vh53ws87v3q 14 18 ) ) PUNCT vh53ws87v3q 14 19 coverages coverage NOUN vh53ws87v3q 14 20 may may AUX vh53ws87v3q 14 21 act act VERB vh53ws87v3q 14 22 to to PART vh53ws87v3q 14 23 overcome overcome VERB vh53ws87v3q 14 24 kinetic kinetic ADJ vh53ws87v3q 14 25 barriers barrier NOUN vh53ws87v3q 14 26 and and CCONJ vh53ws87v3q 14 27 drive drive VERB vh53ws87v3q 14 28 the the DET vh53ws87v3q 14 29 structural structural ADJ vh53ws87v3q 14 30 changes change NOUN vh53ws87v3q 14 31 promoting promote VERB vh53ws87v3q 14 32 surface surface NOUN vh53ws87v3q 14 33 pt pt PROPN vh53ws87v3q 14 34 oxide oxide NOUN vh53ws87v3q 14 35 formation formation NOUN vh53ws87v3q 14 36 in in ADP vh53ws87v3q 14 37 continuous continuous ADJ vh53ws87v3q 14 38 chains chain NOUN vh53ws87v3q 14 39 . . PUNCT vh53ws87v3q 15 1 in in ADP vh53ws87v3q 15 2 agreement agreement NOUN vh53ws87v3q 15 3 with with ADP vh53ws87v3q 15 4 literature literature NOUN vh53ws87v3q 15 5 values value NOUN vh53ws87v3q 15 6 and and CCONJ vh53ws87v3q 15 7 experimentally experimentally ADV vh53ws87v3q 15 8 observed observe VERB vh53ws87v3q 15 9 results result NOUN vh53ws87v3q 15 10 , , PUNCT vh53ws87v3q 15 11 the the DET vh53ws87v3q 15 12 barriers barrier NOUN vh53ws87v3q 15 13 to to PART vh53ws87v3q 15 14 buckle buckle NOUN vh53ws87v3q 15 15 become become VERB vh53ws87v3q 15 16 lower low ADJ vh53ws87v3q 15 17 with with ADP vh53ws87v3q 15 18 increased increase VERB vh53ws87v3q 15 19 oxygen oxygen NOUN vh53ws87v3q 15 20 coverage coverage NOUN vh53ws87v3q 15 21 . . PUNCT vh53ws87v3q 16 1 our our PRON vh53ws87v3q 16 2 analysis analysis NOUN vh53ws87v3q 16 3 of of ADP vh53ws87v3q 16 4 the the DET vh53ws87v3q 16 5 energetics energetic NOUN vh53ws87v3q 16 6 and and CCONJ vh53ws87v3q 16 7 kinetics kinetic NOUN vh53ws87v3q 16 8 reproduces reproduce VERB vh53ws87v3q 16 9 the the DET vh53ws87v3q 16 10 characteristics characteristic NOUN vh53ws87v3q 16 11 needed need VERB vh53ws87v3q 16 12 for for ADP vh53ws87v3q 16 13 describing describe VERB vh53ws87v3q 16 14 experimentally experimentally ADV vh53ws87v3q 16 15 observed observe VERB vh53ws87v3q 16 16 temperature temperature NOUN vh53ws87v3q 16 17 program program NOUN vh53ws87v3q 16 18 desorption desorption NOUN vh53ws87v3q 16 19 data datum NOUN vh53ws87v3q 16 20 . . PUNCT