id sid tid token lemma pos vm40xp7266g 1 1 advances advance VERB vm40xp7266g 1 2 in in ADP vm40xp7266g 1 3 nanofabrication nanofabrication NOUN vm40xp7266g 1 4 techniques technique NOUN vm40xp7266g 1 5 have have AUX vm40xp7266g 1 6 enabled enable VERB vm40xp7266g 1 7 construction construction NOUN vm40xp7266g 1 8 of of ADP vm40xp7266g 1 9 sophisticated sophisticated ADJ vm40xp7266g 1 10 nanoscale nanoscale NOUN vm40xp7266g 1 11 architectures architecture NOUN vm40xp7266g 1 12 , , PUNCT vm40xp7266g 1 13 which which PRON vm40xp7266g 1 14 allows allow VERB vm40xp7266g 1 15 electrochemical electrochemical ADJ vm40xp7266g 1 16 measurements measurement NOUN vm40xp7266g 1 17 in in ADP vm40xp7266g 1 18 low low ADJ vm40xp7266g 1 19 dimensional dimensional ADJ vm40xp7266g 1 20 nanostructures nanostructure NOUN vm40xp7266g 1 21 that that PRON vm40xp7266g 1 22 have have VERB vm40xp7266g 1 23 the the DET vm40xp7266g 1 24 capability capability NOUN vm40xp7266g 1 25 to to PART vm40xp7266g 1 26 illuminate illuminate VERB vm40xp7266g 1 27 electrochemical electrochemical ADJ vm40xp7266g 1 28 phenomena phenomenon NOUN vm40xp7266g 1 29 in in ADP vm40xp7266g 1 30 a a DET vm40xp7266g 1 31 unique unique ADJ vm40xp7266g 1 32 way way NOUN vm40xp7266g 1 33 , , PUNCT vm40xp7266g 1 34 especially especially ADV vm40xp7266g 1 35 compared compare VERB vm40xp7266g 1 36 to to ADP vm40xp7266g 1 37 conventional conventional ADJ vm40xp7266g 1 38 macroscopic macroscopic ADJ vm40xp7266g 1 39 electrochemistry electrochemistry NOUN vm40xp7266g 1 40 which which PRON vm40xp7266g 1 41 relies rely VERB vm40xp7266g 1 42 on on ADP vm40xp7266g 1 43 bulk bulk ADJ vm40xp7266g 1 44 diffusion diffusion NOUN vm40xp7266g 1 45 . . PUNCT vm40xp7266g 2 1 in in ADP vm40xp7266g 2 2 particular particular ADJ vm40xp7266g 2 3 , , PUNCT vm40xp7266g 2 4 nanopore nanopore ADJ vm40xp7266g 2 5 electrode electrode NOUN vm40xp7266g 2 6 arrays array NOUN vm40xp7266g 2 7 ( ( PUNCT vm40xp7266g 2 8 neas neas PROPN vm40xp7266g 2 9 ) ) PUNCT vm40xp7266g 2 10 , , PUNCT vm40xp7266g 2 11 which which PRON vm40xp7266g 2 12 are be AUX vm40xp7266g 2 13 composed compose VERB vm40xp7266g 2 14 of of ADP vm40xp7266g 2 15 a a DET vm40xp7266g 2 16 set set NOUN vm40xp7266g 2 17 of of ADP vm40xp7266g 2 18 ring ring NOUN vm40xp7266g 2 19 / / SYM vm40xp7266g 2 20 disk disk NOUN vm40xp7266g 2 21 nanoelectrodes nanoelectrode NOUN vm40xp7266g 2 22 in in ADP vm40xp7266g 2 23 cylindrical cylindrical ADJ vm40xp7266g 2 24 or or CCONJ vm40xp7266g 2 25 conical conical ADJ vm40xp7266g 2 26 nanopores nanopore NOUN vm40xp7266g 2 27 , , PUNCT vm40xp7266g 2 28 is be AUX vm40xp7266g 2 29 a a DET vm40xp7266g 2 30 useful useful ADJ vm40xp7266g 2 31 architecture architecture NOUN vm40xp7266g 2 32 to to PART vm40xp7266g 2 33 investigate investigate VERB vm40xp7266g 2 34 a a DET vm40xp7266g 2 35 number number NOUN vm40xp7266g 2 36 of of ADP vm40xp7266g 2 37 interesting interesting ADJ vm40xp7266g 2 38 nanoelectrochemical nanoelectrochemical ADJ vm40xp7266g 2 39 characteristics characteristic NOUN vm40xp7266g 2 40 in in ADP vm40xp7266g 2 41 confined confine VERB vm40xp7266g 2 42 volumes volume NOUN vm40xp7266g 2 43 , , PUNCT vm40xp7266g 2 44 typ typ PROPN vm40xp7266g 2 45 . . PROPN vm40xp7266g 3 1 10 10 NUM vm40xp7266g 3 2 - - SYM vm40xp7266g 3 3 18 18 NUM vm40xp7266g 3 4 l l NOUN vm40xp7266g 3 5 , , PUNCT vm40xp7266g 3 6 such such ADJ vm40xp7266g 3 7 as as ADP vm40xp7266g 3 8 ion ion NOUN vm40xp7266g 3 9 / / SYM vm40xp7266g 3 10 molecular molecular ADJ vm40xp7266g 3 11 transport transport NOUN vm40xp7266g 3 12 behavior behavior NOUN vm40xp7266g 3 13 and and CCONJ vm40xp7266g 3 14 electrochemical electrochemical ADJ vm40xp7266g 3 15 kinetics kinetic NOUN vm40xp7266g 3 16 . . PUNCT vm40xp7266g 4 1 also also ADV vm40xp7266g 4 2 , , PUNCT vm40xp7266g 4 3 this this DET vm40xp7266g 4 4 small small ADJ vm40xp7266g 4 5 confined confine VERB vm40xp7266g 4 6 volume volume NOUN vm40xp7266g 4 7 makes make VERB vm40xp7266g 4 8 it it PRON vm40xp7266g 4 9 possible possible ADJ vm40xp7266g 4 10 to to PART vm40xp7266g 4 11 explore explore VERB vm40xp7266g 4 12 the the DET vm40xp7266g 4 13 dynamics dynamic NOUN vm40xp7266g 4 14 of of ADP vm40xp7266g 4 15 chemical chemical ADJ vm40xp7266g 4 16 reactions reaction NOUN vm40xp7266g 4 17 involving involve VERB vm40xp7266g 4 18 a a DET vm40xp7266g 4 19 single single ADJ vm40xp7266g 4 20 or or CCONJ vm40xp7266g 4 21 a a DET vm40xp7266g 4 22 few few ADJ vm40xp7266g 4 23 molecules molecule NOUN vm40xp7266g 4 24 . . PUNCT vm40xp7266g 5 1 the the DET vm40xp7266g 5 2 work work NOUN vm40xp7266g 5 3 in in ADP vm40xp7266g 5 4 this this DET vm40xp7266g 5 5 dissertation dissertation NOUN vm40xp7266g 5 6 addresses address VERB vm40xp7266g 5 7 three three NUM vm40xp7266g 5 8 main main ADJ vm40xp7266g 5 9 topics topic NOUN vm40xp7266g 5 10 : : PUNCT vm40xp7266g 5 11 the the DET vm40xp7266g 5 12 development development NOUN vm40xp7266g 5 13 of of ADP vm40xp7266g 5 14 massively massively ADV vm40xp7266g 5 15 parallel parallel ADJ vm40xp7266g 5 16 neas neas PROPN vm40xp7266g 5 17 for for ADP vm40xp7266g 5 18 selective selective ADJ vm40xp7266g 5 19 ion ion NOUN vm40xp7266g 5 20 / / SYM vm40xp7266g 5 21 molecular molecular ADJ vm40xp7266g 5 22 transport transport NOUN vm40xp7266g 5 23 control control NOUN vm40xp7266g 5 24 , , PUNCT vm40xp7266g 5 25 sensitive sensitive ADJ vm40xp7266g 5 26 electrochemical electrochemical ADJ vm40xp7266g 5 27 detection detection NOUN vm40xp7266g 5 28 , , PUNCT vm40xp7266g 5 29 and and CCONJ vm40xp7266g 5 30 spectroelectrochemical spectroelectrochemical ADJ vm40xp7266g 5 31 single single ADJ vm40xp7266g 5 32 enzyme enzyme NOUN vm40xp7266g 5 33 molecule molecule NOUN vm40xp7266g 5 34 studies study NOUN vm40xp7266g 5 35 in in ADP vm40xp7266g 5 36 nanoconfined nanoconfined ADJ vm40xp7266g 5 37 geometries.the geometries.the DET vm40xp7266g 5 38 first first ADJ vm40xp7266g 5 39 topic topic NOUN vm40xp7266g 5 40 focuses focus VERB vm40xp7266g 5 41 on on ADP vm40xp7266g 5 42 the the DET vm40xp7266g 5 43 demonstration demonstration NOUN vm40xp7266g 5 44 of of ADP vm40xp7266g 5 45 biomimetic biomimetic ADJ vm40xp7266g 5 46 ion ion NOUN vm40xp7266g 5 47 gating gate VERB vm40xp7266g 5 48 in in ADP vm40xp7266g 5 49 block block NOUN vm40xp7266g 5 50 copolymer copolymer NOUN vm40xp7266g 5 51 ( ( PUNCT vm40xp7266g 5 52 bcp)-coated bcp)-coate VERB vm40xp7266g 5 53 neas nea NOUN vm40xp7266g 5 54 in in ADP vm40xp7266g 5 55 response response NOUN vm40xp7266g 5 56 to to ADP vm40xp7266g 5 57 external external ADJ vm40xp7266g 5 58 stimuli stimulus NOUN vm40xp7266g 5 59 , , PUNCT vm40xp7266g 5 60 such such ADJ vm40xp7266g 5 61 as as ADP vm40xp7266g 5 62 ph ph PROPN vm40xp7266g 5 63 and and CCONJ vm40xp7266g 5 64 ionic ionic ADJ vm40xp7266g 5 65 charge charge NOUN vm40xp7266g 5 66 state state NOUN vm40xp7266g 5 67 . . PUNCT vm40xp7266g 6 1 the the DET vm40xp7266g 6 2 structures structure NOUN vm40xp7266g 6 3 consist consist VERB vm40xp7266g 6 4 of of ADP vm40xp7266g 6 5 a a DET vm40xp7266g 6 6 ph ph NOUN vm40xp7266g 6 7 - - PUNCT vm40xp7266g 6 8 responsive responsive ADJ vm40xp7266g 6 9 , , PUNCT vm40xp7266g 6 10 charge charge NOUN vm40xp7266g 6 11 - - PUNCT vm40xp7266g 6 12 selective selective ADJ vm40xp7266g 6 13 dual dual ADV vm40xp7266g 6 14 - - PUNCT vm40xp7266g 6 15 gating gate VERB vm40xp7266g 6 16 bcp bcp NOUN vm40xp7266g 6 17 membrane membrane NOUN vm40xp7266g 6 18 , , PUNCT vm40xp7266g 6 19 capable capable ADJ vm40xp7266g 6 20 of of ADP vm40xp7266g 6 21 self self NOUN vm40xp7266g 6 22 - - PUNCT vm40xp7266g 6 23 organizing organizing NOUN vm40xp7266g 6 24 into into ADP vm40xp7266g 6 25 highly highly ADV vm40xp7266g 6 26 ordered order VERB vm40xp7266g 6 27 nanocylindrical nanocylindrical ADJ vm40xp7266g 6 28 domains domain NOUN vm40xp7266g 6 29 . . PUNCT vm40xp7266g 7 1 introducing introduce VERB vm40xp7266g 7 2 the the DET vm40xp7266g 7 3 bcp bcp NOUN vm40xp7266g 7 4 membrane membrane NOUN vm40xp7266g 7 5 onto onto ADP vm40xp7266g 7 6 neas neas PROPN vm40xp7266g 7 7 allows allow VERB vm40xp7266g 7 8 the the DET vm40xp7266g 7 9 bcp bcp NOUN vm40xp7266g 7 10 to to PART vm40xp7266g 7 11 serve serve VERB vm40xp7266g 7 12 as as ADP vm40xp7266g 7 13 a a DET vm40xp7266g 7 14 ph ph NOUN vm40xp7266g 7 15 - - PUNCT vm40xp7266g 7 16 gate gate NOUN vm40xp7266g 7 17 , , PUNCT vm40xp7266g 7 18 controlling control VERB vm40xp7266g 7 19 ion ion NOUN vm40xp7266g 7 20 transfer transfer NOUN vm40xp7266g 7 21 into into ADP vm40xp7266g 7 22 the the DET vm40xp7266g 7 23 nanopores nanopore NOUN vm40xp7266g 7 24 , , PUNCT vm40xp7266g 7 25 because because SCONJ vm40xp7266g 7 26 it it PRON vm40xp7266g 7 27 exhibits exhibit VERB vm40xp7266g 7 28 ph ph NOUN vm40xp7266g 7 29 - - PUNCT vm40xp7266g 7 30 dependent dependent ADJ vm40xp7266g 7 31 structural structural ADJ vm40xp7266g 7 32 transitions transition NOUN vm40xp7266g 7 33 , , PUNCT vm40xp7266g 7 34 i.e. i.e. X vm40xp7266g 7 35 , , PUNCT vm40xp7266g 7 36 being be AUX vm40xp7266g 7 37 positively positively ADV vm40xp7266g 7 38 - - PUNCT vm40xp7266g 7 39 charged charge VERB vm40xp7266g 7 40 , , PUNCT vm40xp7266g 7 41 hydrophilic hydrophilic ADJ vm40xp7266g 7 42 , , PUNCT vm40xp7266g 7 43 and and CCONJ vm40xp7266g 7 44 swollen swollen ADJ vm40xp7266g 7 45 at at ADP vm40xp7266g 7 46 ph ph DET vm40xp7266g 7 47 values value NOUN vm40xp7266g 7 48 below below ADP vm40xp7266g 7 49 pka pka PROPN vm40xp7266g 7 50 of of ADP vm40xp7266g 7 51 the the DET vm40xp7266g 7 52 bcp bcp NOUN vm40xp7266g 7 53 , , PUNCT vm40xp7266g 7 54 but but CCONJ vm40xp7266g 7 55 charge charge NOUN vm40xp7266g 7 56 - - PUNCT vm40xp7266g 7 57 neutral neutral ADJ vm40xp7266g 7 58 , , PUNCT vm40xp7266g 7 59 hydrophobic hydrophobic NOUN vm40xp7266g 7 60 , , PUNCT vm40xp7266g 7 61 and and CCONJ vm40xp7266g 7 62 collapsed collapse VERB vm40xp7266g 7 63 structures structure NOUN vm40xp7266g 7 64 at at ADP vm40xp7266g 7 65 ph ph PROPN vm40xp7266g 7 66 & & CCONJ vm40xp7266g 7 67 gt gt PROPN vm40xp7266g 7 68 ; ; PUNCT vm40xp7266g 7 69 pka pka PROPN vm40xp7266g 7 70 . . PUNCT vm40xp7266g 8 1 these these DET vm40xp7266g 8 2 structural structural ADJ vm40xp7266g 8 3 properties property NOUN vm40xp7266g 8 4 support support VERB vm40xp7266g 8 5 on on ADP vm40xp7266g 8 6 - - PUNCT vm40xp7266g 8 7 off off ADP vm40xp7266g 8 8 transport transport NOUN vm40xp7266g 8 9 switching switch VERB vm40xp7266g 8 10 at at ADP vm40xp7266g 8 11 ph ph NOUN vm40xp7266g 8 12 values value NOUN vm40xp7266g 8 13 near near ADP vm40xp7266g 8 14 the the DET vm40xp7266g 8 15 pka pka PROPN vm40xp7266g 8 16 with with ADP vm40xp7266g 8 17 excellent excellent ADJ vm40xp7266g 8 18 anion anion NOUN vm40xp7266g 8 19 permselectivity permselectivity NOUN vm40xp7266g 8 20 membrane membrane NOUN vm40xp7266g 8 21 at at ADP vm40xp7266g 8 22 ph ph PROPN vm40xp7266g 8 23 & & CCONJ vm40xp7266g 8 24 lt lt PROPN vm40xp7266g 8 25 ; ; PUNCT vm40xp7266g 8 26 pka pka PROPN vm40xp7266g 8 27 . . PUNCT vm40xp7266g 9 1 redox redox ADJ vm40xp7266g 9 2 species specie NOUN vm40xp7266g 9 3 are be AUX vm40xp7266g 9 4 charge charge NOUN vm40xp7266g 9 5 - - PUNCT vm40xp7266g 9 6 selectively selectively ADV vm40xp7266g 9 7 transported transport VERB vm40xp7266g 9 8 through through ADP vm40xp7266g 9 9 the the DET vm40xp7266g 9 10 bcp bcp NOUN vm40xp7266g 9 11 membrane membrane NOUN vm40xp7266g 9 12 into into ADP vm40xp7266g 9 13 neas neas PROPN vm40xp7266g 9 14 where where SCONJ vm40xp7266g 9 15 they they PRON vm40xp7266g 9 16 can can AUX vm40xp7266g 9 17 then then ADV vm40xp7266g 9 18 be be AUX vm40xp7266g 9 19 sensitively sensitively ADV vm40xp7266g 9 20 detected detect VERB vm40xp7266g 9 21 by by ADP vm40xp7266g 9 22 electrochemical electrochemical ADJ vm40xp7266g 9 23 signal signal NOUN vm40xp7266g 9 24 amplification amplification NOUN vm40xp7266g 9 25 by by ADP vm40xp7266g 9 26 redox redox ADJ vm40xp7266g 9 27 cycling cycling NOUN vm40xp7266g 9 28 at at ADP vm40xp7266g 9 29 100 100 NUM vm40xp7266g 9 30 nm nm NOUN vm40xp7266g 9 31 gap gap NOUN vm40xp7266g 9 32 dual dual ADJ vm40xp7266g 9 33 - - PUNCT vm40xp7266g 9 34 ring ring NOUN vm40xp7266g 9 35 nanoelectrodes.extending nanoelectrodes.extende VERB vm40xp7266g 9 36 this this DET vm40xp7266g 9 37 concept concept NOUN vm40xp7266g 9 38 , , PUNCT vm40xp7266g 9 39 the the DET vm40xp7266g 9 40 second second ADJ vm40xp7266g 9 41 topic topic NOUN vm40xp7266g 9 42 addresses address VERB vm40xp7266g 9 43 the the DET vm40xp7266g 9 44 active active ADJ vm40xp7266g 9 45 control control NOUN vm40xp7266g 9 46 of of ADP vm40xp7266g 9 47 mass mass ADJ vm40xp7266g 9 48 transport transport NOUN vm40xp7266g 9 49 based base VERB vm40xp7266g 9 50 on on ADP vm40xp7266g 9 51 electrowetting electrowette VERB vm40xp7266g 9 52 in in ADP vm40xp7266g 9 53 the the DET vm40xp7266g 9 54 bcp bcp NOUN vm40xp7266g 9 55 membrane membrane NOUN vm40xp7266g 9 56 when when SCONJ vm40xp7266g 9 57 formed form VERB vm40xp7266g 9 58 at at ADP vm40xp7266g 9 59 an an DET vm40xp7266g 9 60 nea nea NOUN vm40xp7266g 9 61 surface surface NOUN vm40xp7266g 9 62 . . PUNCT vm40xp7266g 10 1 potential potential ADJ vm40xp7266g 10 2 - - PUNCT vm40xp7266g 10 3 induced induce VERB vm40xp7266g 10 4 wetting wetting NOUN vm40xp7266g 10 5 and and CCONJ vm40xp7266g 10 6 dewetting dewette VERB vm40xp7266g 10 7 behavior behavior NOUN vm40xp7266g 10 8 is be AUX vm40xp7266g 10 9 characterized characterize VERB vm40xp7266g 10 10 in in ADP vm40xp7266g 10 11 ph ph NOUN vm40xp7266g 10 12 - - PUNCT vm40xp7266g 10 13 responsive responsive ADJ vm40xp7266g 10 14 bcp bcp NOUN vm40xp7266g 10 15 membranes membrane NOUN vm40xp7266g 10 16 fabricated fabricate VERB vm40xp7266g 10 17 in in ADP vm40xp7266g 10 18 hierarchically hierarchically ADV vm40xp7266g 10 19 - - PUNCT vm40xp7266g 10 20 organized organize VERB vm40xp7266g 10 21 structures structure NOUN vm40xp7266g 10 22 on on ADP vm40xp7266g 10 23 neas neas PROPN vm40xp7266g 10 24 . . PUNCT vm40xp7266g 11 1 in in ADP vm40xp7266g 11 2 these these DET vm40xp7266g 11 3 structures structure NOUN vm40xp7266g 11 4 the the DET vm40xp7266g 11 5 bcp bcp NOUN vm40xp7266g 11 6 blocks block VERB vm40xp7266g 11 7 mass mass ADJ vm40xp7266g 11 8 transport transport NOUN vm40xp7266g 11 9 across across ADP vm40xp7266g 11 10 the the DET vm40xp7266g 11 11 hydrophobic hydrophobic NOUN vm40xp7266g 11 12 bcp bcp NOUN vm40xp7266g 11 13 at at ADP vm40xp7266g 11 14 ph ph PROPN vm40xp7266g 11 15 & & CCONJ vm40xp7266g 11 16 gt gt PROPN vm40xp7266g 11 17 ; ; PUNCT vm40xp7266g 11 18 pka pka PROPN vm40xp7266g 11 19 , , PUNCT vm40xp7266g 11 20 while while SCONJ vm40xp7266g 11 21 it it PRON vm40xp7266g 11 22 acts act VERB vm40xp7266g 11 23 as as ADP vm40xp7266g 11 24 an an DET vm40xp7266g 11 25 anion anion NOUN vm40xp7266g 11 26 exchange exchange NOUN vm40xp7266g 11 27 membrane membrane NOUN vm40xp7266g 11 28 at at ADP vm40xp7266g 11 29 ph ph PROPN vm40xp7266g 11 30 & & CCONJ vm40xp7266g 11 31 lt lt PROPN vm40xp7266g 11 32 ; ; PUNCT vm40xp7266g 11 33 pka pka PROPN vm40xp7266g 11 34 . . PROPN vm40xp7266g 12 1 interestingly interestingly ADV vm40xp7266g 12 2 , , PUNCT vm40xp7266g 12 3 however however ADV vm40xp7266g 12 4 , , PUNCT vm40xp7266g 12 5 mass mass ADJ vm40xp7266g 12 6 transport transport NOUN vm40xp7266g 12 7 across across ADP vm40xp7266g 12 8 the the DET vm40xp7266g 12 9 hydrophobic hydrophobic NOUN vm40xp7266g 12 10 bcp bcp NOUN vm40xp7266g 12 11 nanochannels nanochannel NOUN vm40xp7266g 12 12 at at ADP vm40xp7266g 12 13 ph ph PROPN vm40xp7266g 12 14 & & CCONJ vm40xp7266g 12 15 gt gt PROPN vm40xp7266g 12 16 ; ; PUNCT vm40xp7266g 12 17 pka pka PROPN vm40xp7266g 12 18 , , PUNCT vm40xp7266g 12 19 is be AUX vm40xp7266g 12 20 switched switch VERB vm40xp7266g 12 21 on on ADP vm40xp7266g 12 22 by by ADP vm40xp7266g 12 23 sufficiently sufficiently ADV vm40xp7266g 12 24 negative negative ADJ vm40xp7266g 12 25 potentials potential NOUN vm40xp7266g 12 26 applied apply VERB vm40xp7266g 12 27 across across ADP vm40xp7266g 12 28 the the DET vm40xp7266g 12 29 bcp bcp NOUN vm40xp7266g 12 30 membrane membrane NOUN vm40xp7266g 12 31 , , PUNCT vm40xp7266g 12 32 resulting result VERB vm40xp7266g 12 33 in in ADP vm40xp7266g 12 34 the the DET vm40xp7266g 12 35 electrolyte electrolyte NOUN vm40xp7266g 12 36 solution solution NOUN vm40xp7266g 12 37 being be AUX vm40xp7266g 12 38 introduced introduce VERB vm40xp7266g 12 39 into into ADP vm40xp7266g 12 40 , , PUNCT vm40xp7266g 12 41 and and CCONJ vm40xp7266g 12 42 then then ADV vm40xp7266g 12 43 isolated isolate VERB vm40xp7266g 12 44 in in ADP vm40xp7266g 12 45 , , PUNCT vm40xp7266g 12 46 the the DET vm40xp7266g 12 47 nanopores nanopore NOUN vm40xp7266g 12 48 . . PUNCT vm40xp7266g 13 1 the the DET vm40xp7266g 13 2 potential potential ADJ vm40xp7266g 13 3 - - PUNCT vm40xp7266g 13 4 induced induce VERB vm40xp7266g 13 5 wetting wetting NOUN vm40xp7266g 13 6 and and CCONJ vm40xp7266g 13 7 dewetting dewette VERB vm40xp7266g 13 8 transitions transition NOUN vm40xp7266g 13 9 and and CCONJ vm40xp7266g 13 10 their their PRON vm40xp7266g 13 11 effect effect NOUN vm40xp7266g 13 12 on on ADP vm40xp7266g 13 13 voltammetric voltammetric ADJ vm40xp7266g 13 14 response response NOUN vm40xp7266g 13 15 in in ADP vm40xp7266g 13 16 the the DET vm40xp7266g 13 17 bcp bcp NOUN vm40xp7266g 13 18 and and CCONJ vm40xp7266g 13 19 nea nea NOUN vm40xp7266g 13 20 structures structure NOUN vm40xp7266g 13 21 are be AUX vm40xp7266g 13 22 characterized characterize VERB vm40xp7266g 13 23 as as ADP vm40xp7266g 13 24 a a DET vm40xp7266g 13 25 function function NOUN vm40xp7266g 13 26 of of ADP vm40xp7266g 13 27 potential potential ADJ vm40xp7266g 13 28 , , PUNCT vm40xp7266g 13 29 ph ph NOUN vm40xp7266g 13 30 , , PUNCT vm40xp7266g 13 31 and and CCONJ vm40xp7266g 13 32 ionic ionic ADJ vm40xp7266g 13 33 strength strength NOUN vm40xp7266g 13 34 . . PUNCT vm40xp7266g 14 1 in in ADP vm40xp7266g 14 2 addition addition NOUN vm40xp7266g 14 3 , , PUNCT vm40xp7266g 14 4 chronoamperometry chronoamperometry PROPN vm40xp7266g 14 5 and and CCONJ vm40xp7266g 14 6 redox redox ADJ vm40xp7266g 14 7 cycling cycling NOUN vm40xp7266g 14 8 are be AUX vm40xp7266g 14 9 used use VERB vm40xp7266g 14 10 to to PART vm40xp7266g 14 11 further far ADV vm40xp7266g 14 12 characterize characterize VERB vm40xp7266g 14 13 the the DET vm40xp7266g 14 14 potential potential NOUN vm40xp7266g 14 15 response.in response.in X vm40xp7266g 14 16 the the DET vm40xp7266g 14 17 third third ADJ vm40xp7266g 14 18 topic topic NOUN vm40xp7266g 14 19 , , PUNCT vm40xp7266g 14 20 neas neas PROPN vm40xp7266g 14 21 are be AUX vm40xp7266g 14 22 used use VERB vm40xp7266g 14 23 in in ADP vm40xp7266g 14 24 a a DET vm40xp7266g 14 25 bifunctional bifunctional ADJ vm40xp7266g 14 26 zero zero NUM vm40xp7266g 14 27 mode mode NOUN vm40xp7266g 14 28 waveguide waveguide NOUN vm40xp7266g 14 29 ( ( PUNCT vm40xp7266g 14 30 zmw zmw NOUN vm40xp7266g 14 31 ) ) PUNCT vm40xp7266g 14 32 configuration configuration NOUN vm40xp7266g 14 33 that that PRON vm40xp7266g 14 34 combines combine VERB vm40xp7266g 14 35 electrochemistry electrochemistry NOUN vm40xp7266g 14 36 with with ADP vm40xp7266g 14 37 spectroscopy spectroscopy NOUN vm40xp7266g 14 38 for for ADP vm40xp7266g 14 39 single single ADJ vm40xp7266g 14 40 enzyme enzyme NOUN vm40xp7266g 14 41 molecule molecule NOUN vm40xp7266g 14 42 studies study NOUN vm40xp7266g 14 43 . . PUNCT vm40xp7266g 15 1 the the DET vm40xp7266g 15 2 potential potential ADJ vm40xp7266g 15 3 - - PUNCT vm40xp7266g 15 4 dependent dependent ADJ vm40xp7266g 15 5 fluorescence fluorescence ADJ vm40xp7266g 15 6 dynamics dynamic NOUN vm40xp7266g 15 7 of of ADP vm40xp7266g 15 8 single single ADJ vm40xp7266g 15 9 glutathione glutathione NOUN vm40xp7266g 15 10 reductase reductase NOUN vm40xp7266g 15 11 ( ( PUNCT vm40xp7266g 15 12 gr gr PROPN vm40xp7266g 15 13 ) ) PUNCT vm40xp7266g 15 14 molecules molecule NOUN vm40xp7266g 15 15 are be AUX vm40xp7266g 15 16 investigated investigate VERB vm40xp7266g 15 17 in in ADP vm40xp7266g 15 18 an an DET vm40xp7266g 15 19 electrochemical electrochemical ADJ vm40xp7266g 15 20 zmw zmw NOUN vm40xp7266g 15 21 , , PUNCT vm40xp7266g 15 22 where where SCONJ vm40xp7266g 15 23 a a DET vm40xp7266g 15 24 single single ADJ vm40xp7266g 15 25 au au X vm40xp7266g 15 26 ring ring NOUN vm40xp7266g 15 27 electrode electrode NOUN vm40xp7266g 15 28 embedded embed VERB vm40xp7266g 15 29 in in ADP vm40xp7266g 15 30 each each DET vm40xp7266g 15 31 nanopore nanopore NOUN vm40xp7266g 15 32 simultaneously simultaneously ADV vm40xp7266g 15 33 serves serve VERB vm40xp7266g 15 34 to to PART vm40xp7266g 15 35 control control VERB vm40xp7266g 15 36 electrochemical electrochemical ADJ vm40xp7266g 15 37 potential potential NOUN vm40xp7266g 15 38 and and CCONJ vm40xp7266g 15 39 to to PART vm40xp7266g 15 40 confine confine VERB vm40xp7266g 15 41 electromagnetic electromagnetic ADJ vm40xp7266g 15 42 radiation radiation NOUN vm40xp7266g 15 43 in in ADP vm40xp7266g 15 44 a a DET vm40xp7266g 15 45 zeptoliter zeptoliter NOUN vm40xp7266g 15 46 - - PUNCT vm40xp7266g 15 47 scale scale NOUN vm40xp7266g 15 48 observation observation NOUN vm40xp7266g 15 49 volume volume NOUN vm40xp7266g 15 50 within within ADP vm40xp7266g 15 51 the the DET vm40xp7266g 15 52 nanopores nanopore NOUN vm40xp7266g 15 53 . . PUNCT vm40xp7266g 16 1 the the DET vm40xp7266g 16 2 redox redox ADJ vm40xp7266g 16 3 state state NOUN vm40xp7266g 16 4 of of ADP vm40xp7266g 16 5 gr gr PROPN vm40xp7266g 16 6 and and CCONJ vm40xp7266g 16 7 its its PRON vm40xp7266g 16 8 response response NOUN vm40xp7266g 16 9 to to ADP vm40xp7266g 16 10 the the DET vm40xp7266g 16 11 enzyme enzyme NOUN vm40xp7266g 16 12 substrate substrate NOUN vm40xp7266g 16 13 is be AUX vm40xp7266g 16 14 monitored monitor VERB vm40xp7266g 16 15 at at ADP vm40xp7266g 16 16 single single ADJ vm40xp7266g 16 17 molecule molecule NOUN vm40xp7266g 16 18 level level NOUN vm40xp7266g 16 19 by by ADP vm40xp7266g 16 20 correlating correlate VERB vm40xp7266g 16 21 electrochemical electrochemical ADJ vm40xp7266g 16 22 and and CCONJ vm40xp7266g 16 23 spectroscopic spectroscopic ADJ vm40xp7266g 16 24 signals signal NOUN vm40xp7266g 16 25 under under ADP vm40xp7266g 16 26 external external ADJ vm40xp7266g 16 27 potential potential ADJ vm40xp7266g 16 28 control control NOUN vm40xp7266g 16 29 in in ADP vm40xp7266g 16 30 the the DET vm40xp7266g 16 31 presence presence NOUN vm40xp7266g 16 32 of of ADP vm40xp7266g 16 33 a a DET vm40xp7266g 16 34 redox redox ADJ vm40xp7266g 16 35 mediator mediator NOUN vm40xp7266g 16 36 . . PUNCT