•f3*J*«- ' . •■'■i'lMuA' rjlf*_^l. r\^s -OL-OOA NEW ELUCIDATION OF COLOURS, ORIGINAL PRISMATIC, ^nd MATERIAL; SHOWING THEIR CONCORDANCE IN THREE PRIMITIVES, YELLOIF, RED, and BLUE; AND- THE MEANS OF PRODUCING, MEASURING, AND MIXING THEM: WITH SOME OBSERVATIONS on THE ACCURACY of SIR ISAAC NEWTON, Who "From tlie whitening uiulistingiiislied lilaze Collecting every ray into its kind. To the charmed eye educed the gorgeous train Of Parent Colours." Thomson . By JAMES SOWERBY, F.L.S. &c. Designer of English Botany, and Exotic Botany; Author of English Fungi, British Miupralogy, British MisccUaDy, the Botanical Drasving Book, &c.— No. '2, Me.id PKicp, Lambc h, Surrey. Hoution: Printed by Richard Taylor and Co. .Shoe-Lane. MDCCC-IX. TO THE MEMORY OF THE GREAT SIR ISAAC NEWTON I indulge an incUnatmi with much humility to dedicate this gift of Nature, as a part belonging to the foundation of light and colours, first laid by his penetrating genius ; presum- ing that collecting, measuring, and arranging them is a ne- cessary if not an. essential appendage. I had dedicated this more naturally, it might be thought, to the Honourable Presi- dent, Sir Joseph Banks, Bart, and to the Fellows of the Royal Society. The Dedication to the Memory of Sir Isaac Newton being admitted, the latter follows of course, as every thing re- lating to the philosophical scheynes of that great man naturally comes under their cognizance ; and they, like his heirs, under such circumstances I hope will he pleased to accept it, JAMES SOWERBY. London. INTRODUCTION. When I first proposed to publish on Colours, it was merely with an intent of simplifying the means of mixing them, and that chiefly with regard to such as are used for painting in water or oil, with a particular desire to show a means of agreement and ready reference among naturalists and others, as to their identity. This led me to inquire for some permanent and constant means of comparison, from some original source that might always be consulted, and leave no room for doubt. Observing a sort of originality in the prismatic tints of stones, and that I could trace their order, I began with them ; but, after all, finding them too fixed as it were for some purposes, and that it would be desirable to mix or unmix the original prismatic tints with the same order as common colours, and perceiving a strange want of agreement in this particular among philosophers, &c., I was the more anxious, especially as to the ob- taining the same three primitives as were pretty universally allowed to common colours, viz. Yellow, Red and Blue ; for should Nature agree in this, which seemed to me a desideratum, I might then find a means of producing them so as to mix them perfectly, and be able to come to some fair conclusion. I made a few inquiries upon the subject, but to no purpose, as it was generally thought impossible: and having a further desire to measure them, it seemed to be consi- dered as a vanity. I was however satisfied, that as there was some- thing wanted to make the desired agreement, so it might possibly B 2 INTRODUCTION. be found out. I therefore determined, if in my power, to find it oat ; and was much sooner favoured with the discovery than I ex- pected, and that too to a nicety that surprised me much, especially as it was so easy and likely to be brought to perfection, not only to correct former errors, but to serve as a firm basis for future inquiries. Indeed, it may seem a wonder, in the present rapidly improving age, that any thing remained to be done towards the elucidation of colours, either evanescent or natural. I presume, however, that this work in its present form is likely to fill up some important desi- derata ; and if it is not established as a book of reference, which is much wanted, I hope it will help at least to call one forth, as such a book may be of infinite service in many departments of science, for the subject promises already to branch into many divisions for different purposes. One truth established helps another ; and it may give a hint even to the astronomer Dr. Herschel, who has paid so much attention to the subject of prismatic colours, that strong opposites, such as light and dark, may not be proper in the use of telescopes, as when they are next each other, in particular, they may produce the most brilliant prismatic tints by the help of the angle of a lens*. Thus a middle tint I should presume best for lining telescopes. I find a middle tint in my schemes best to neutralize colours (black I believe is in general use for telescopes kc. but 1 do not know what Dr. Herschel uses). Again, calculation by means of a prism has been used to assist in examining some of the constellations ; if the sun's width at a known distance is such as to show a white space when viewed in a prism, it must be broader or nearer than those constellations that do not show a white space: — thus the smaller objects of our hemisphere show only the four colours of Dr. Wollaston's narrow ray of light, or C. A. Prieur's white thread or silk, which will be understood in the sequel. It is somewhat curious, that the middle tints brought in contact by smallness or narrowness exclude light or white, and be- * Dr. Herschel probably broke his coloured glasses by some such contrast. INTRODUCTION. 3 come green, from yellower green to darker and bluer green. May green be reckoned the inicklle tint in Nature, as grass: it seems suited to our vision. It is not a little remarkable, that many subjects partake of the prismatic order of the colours of the sun or other luminaries, especially hemispherical ones, surrounded in a dark or perhaps aerial medium. Thus the evanescent tints be- come in effect realized in an admirable manner to our senses, taking due place in Nature to the fullest extent. I have only hinted at these things, that they may be enlarged upon if it should seem useful. Certainly, some fruits, such as peaches, pears, &c., have, occasionally, nearly if not all the tints allowed to the prism in due order upon them : thus the upper part, or the next under the leaf or stalk, is a full or crimson red, and this is often softened into orange ; yellow or yellowish succeeds ; then yellowish green ; then bluer, till the dull or under side par- takes of violet, especially if the warmer rays of an evening sun glow aslant on its downy coat, or help by their reflexion. Artists are generally aware of this in their paintings, and keep the warmer co- lours above and the colder ones below: even the warmer tints in Man, who walks erect and looks on Heaven, are seen most conspi- cuously in the upper part of his features. Indeed many artists con- sider the general light and warmer tints with the cold and shady sides (if I may so call them) of the rainbow, as a sort of rule to go by: the lighter side, to blend the colours of the lighter side of the subject, when the softening into the back ground would form a violet; a warm or reddish tint would come next, which would be blended by yellowish orange into the local tint, when the heightening would succeed ; next something of the local tint which would be- gin to recede into the yellowish and shade forming a grayish green ; then would succeed a darker shade with a violet tinge, and the rest would depend upon reflexion. Now these tints being judiciously managed, give a richness that is only understood by the artist who practises with such ideas. I have introduced the peach as an B 2 4 INTRODUCTION. example ; and I remember, when a young student at the Royal Academy, to have painted from the hfe with nearly such a lesson from a worthy and most esteemed artist, who was at that time the visiting academician. It would therefore seem that light or shade on convex or concave subjects, or where shadow is, is also accom- panied with colours ; the smallest shade being compounded not only of light and shade, or black and white, but of many tints de- pending on the nature of that light; for mere black and white would give an unartist-like manner and coldness, which would be con- demned in general, even by the least discerning, although perhaps without knowing why. Light and shade or shades will be shown hereafter to have a greater effect than is usually understood, with regard to colours, and will, I have no doubt, be found useful in ' many other respects. Light and dark, as a contrast, and for effect, is very ancient, and sufficiently attracted Laban's flocks under the care of Jacob*. Light is essential in colouring some things and bleaching others; and it was once a valuable secret, that to get the brightest carmine it should in the process of making be dried in the sun. Many chemical substances are changed by exposure to light ; oils become whiter. Perhaps even this effect may be assisted with the help of a contrasting shade, that the actions may be more forcibly directed on the object. Light, on an object when seen refracted by the prism, shows its colours ; which however do not affect the general local tint of the object which seems to reflect it, but rather depend upon the darks or shadows ; and broad flat masses of any coloured object do not appear changed excepting at the extremities, or where dark or shade seems to help to collect the coloured radii : thus it may be possible to make broad tints or narrow ones with such proportions of dark or shade as may be suited for many purposes of the utmost utility in tlie arts^ manufactures, agriculture, &c. * Genesis XXX. 37 to 41. INTRODUCTION. That philosophers and artists liavc long wished for some never- fading colours to fix their ideas and universalize them, is in every age anij)ly verified ; and as coloured substances, like all other sublu- nary things, are liable to a certain decay, so it has been but weakly attempted lately; besides, the dilVicuIty of finding a means of agree- ment in the modifying and arranging them has been a desideratum, as late works have abundantly, showed. Enamel, perhaps, is as durable as any substance, and has with much jiropriety been pro- posed; but the uncertainty of an ability to procure an equality throughout a single tint, puts us nearly in the same predicament as with other coloured schemes. This vve shall find true in our attempt, as will be too evidently seen in the present examples. We presume our method of arranging will much assist both the colours and the mind, and even this scheme might be desirable in enamel or glass for the sake of durability; but 1 may question even if the best ena- meling artists can place colours so well, (which in no way degrades their greater merit,) as it is seldom they have occasion for the ex- perience of an object so trifling to the best of such ailists*. Upon the whole, the necessity of supplying this desideratum need not be dwelt upon, as the numerous attempts to do it are a suflicient acknowledgement, and argue much for its utility. In my researches it has luckily fallen to my lot to find one resource or monitor in Nature, which is as constant as the light from which it is deduced, and the regularity or certainty depends upon very simple materials. The use of a true original for colours, and a regularity of arrange- ment, is almost infinite; for to the artist in any line it will be a solid satisfaction to know when he treads on a sure foundation, laid by unerring Nature. The mineralogist, the botanist and the zo- ologist may in future agree in their descriptions and ideas, so as to identify them to all parts of the world, and the remotest ages. * Perhaps it may succeed somewhat in transparent oil, but water colours are most convenient for a book. 6 INTRODUCTION. It was observed to me by a very good friend, " that as the seven tints were permanent, that was an evidence of tlieir sufficiency as primitives and their original derivation, and that water was perfect in itself, although it was found to consist of hydrogen and oxygen." The latter was once thought a pure element, and led to wrong con- clusions. The former being thought perfect, it will be evident, has also caused wrong conclusions; and as water is not necessary to be formed to produce one of its original parts, hydrogen or oxygen, so, it will be less necessary to mix yellow and red and yellow and blue* to make a yellow ! when yellow is originally and necessarily so, to form the very ingredients so unhappily combined, and leading into continued and self-proving errors. Thus water does not form hy- drogen and oxygen, but hydrogen and oxygen form water. Yellow, red, and blue, I presume, therefore, will more properly form the re- mainder of the seven prismatic tints, than either two or more of the seven will form a single primary colour. I would not have insisted so much on this subject, but that the present improving state of natural science seems to demand a concordance of the primitives of prismatic tints and substantial colours, which appear so much to depend on each other ; and it has been understood by many, from the time of sir Isaac Newton, that the prismatic tints may be imi- tated by what I would consider as simple primitives, viz. yellow, red, and blue. Now to me it seems that, if these are allowed to be the proper primitives of the prismatic tints or colours, there will be a perfect concordance on the most permanent footing. I should not have set about this work without a confidence of its utilit)', although I had not intended or expected to carry it quite so far. I therefore may not have arranged it so regularly as I wish, * It has been, by some, a long mistaken notion, that as yellow is placed between «range and green among the seven tints, it was a natural result from them, when the ■contrary is so naturally and truly the case, as is proved by the very first hypothesis, seeing that yellow and red make orange, &c. INTRODUCTION. as every thing did not present itself to me at once, like an old sub- ject, but rather as a new. I therefore hope some allowance will be made by the discerning, more especially in the philosophical jjart ; as the intention is, to generalize the subject : and the author does not jjretend to be either a great philosopher or artist ; for, if he had been the first, he probably would have wanted enough of the latter to answer the peculiarities of the present intention, and vice versa. A NEW ELUCIDATION OF COLOURS, X. HERE may seem a want of order, in commencing this work with showing rather a finished series than the beginning of one. I have, however, in this instance thought it necessary to give general ideas, and afterwards to begin in as simple a manner as I could ; and, by descending to certain particulars, endeavour to lead to a natural re- sult. I therefore show them even the first and the last series of prismatic tints, viz. light colours and dark ones, as they are in their nature of much consequence, having been very little if at all noticed in natural order, especially the browns and other ternaries. Thus we have, as it were, white as the first beginning of colours, and brown to black the termination of them to our senses. We shall find in the sequel that these include all colours, and that a certain position or arrangement will make them evident, with the most beautiful order and unerring regularity. I am pleased to find these first examples in minerals, whose agency is no less conspicuous in this department, than of the first necessity in most others, showing us much of the nature of light and colours, from the most evanes- cent* to the more solid or material. They help us much to judge of their permanency, and seem the best vehicles to trace them in, and from their first source ; for we may produce them at pleasure, * Changeable, in many substances, according to the course of the light they are viewed by. and make our general observations on them at any time. We may press together or open tiie lamina; which have been j)artially separated, of gyi)sum for instance, in order to produce the colours, either concentrically or otherwise, and this may be repeated, or we may allow them to be stationary for future use or practice, and to serve as one of our resources for a natural proof or example, and we may even measure with some accuracy the space allowed in jiUites for the different tints. (See Dr. Young's excellent paper*.) Thus Tab. \. a,b, c, d, e,f, are representations of colours, that are or may be produced in the flaws of or betwixt the laminae of transparent stones, such as the diamond, gypsum, or selenite, mica, carbonate of lime, &c. (See Brit. Mn. tab. 2.) I have a specimen of mica showing a minute opening or division of 'the laminae of about the eighth of an inch in diameter, having a yellow centre, which I place first; as it succeeds, in the increasing order of density, next to light. It is surrounded by light blue, passing through purplish brown to very dark, when, by degrees, it again passes into faint brown-}- wilh a light margin, and then the stone appears to be close and solid sur- rounding it; PL 1. a. In another part of the same specimen, I have a red centre, to which succeeds the yellow, and the yellow is succeeded by the blue, and the other rings succeed in due order as the first ; PI. I. b. A third flaw has blue in the centre, as in c, with the red, yellow, and the usual rings in the same succession. It is not often that we can find one colour only shown in these sub- stances, they being more commonly a succession of rings. I have however met with dark brown with a lighter margin, passin"' to light or white as at d, and e shows the stone grayish in the centre with the white margin, surrounded by the brown and other rings, as it were reversed in order: it is in fact the curved margin of the va- rious and unequal divisions or fissures in the substance. In general the external or extreme mai-gin finishes with brown, as most of these, whether narrow or broad, do. The other more commonly * Phil. Trans. 1802. t Browns have scarcely, if at all, been considered by authors on this subject. c 10 concentrates with yellow, red, or blue, or a mixture depending upon a natural and regular phaenomenon : (viz.) That as we have seen in a, b, c, that blue is on the inner side of the dark circle, if there is much proportional breadth, so commonly a white or light space suc- ceeds, passing into yellow, orange, and red ; and sometimes the ar- rano-ements in succession approach nearer and nearer, and the white is obliterated, and yellow is facing or nearer the light blue : again, the yellow and blue pass into each other in narrow or nearer circles, and produce green very often at the expense of the marginal tints, if I may so call the blue on one hand, and the red on the otlier. Something like this, or duller and deeper, appears at fig. g, and the semicircles surrounding show it more distinctly, although placed here for a no less curious example. I have perhaps enlarged too much on this subject here. I, how- ever, thought it essential not only to begin with these general pre- mises, but to show some common varieties in the arrangement of prismatic colours, by which we ma^^ perceive that there is a perfect rule for proportion in it, however unequal it may at first appear, which seems to me to have been hitherto a desideratum ; and as I expect to prove much from the nature of this particular appearance, I have dwelt the longer upon it ; which is the more necessary, seeing how orderly sir Isaac Newton produced certain colours by the pres- sure of two glasses, and how naturally and truly he enumerated them without quite attaining the leading and true cause or principle of that arrangement, which he was so near discovering, and which would imdoubtedly have been of the most essential consequence in such good hands. The whole agrees so well with what is said of the experiments of that great man, that, although it is well known, I cannot forbear relating it here. Sir Isaac Newton himself had observed, that as he was compressing two prisms hard together, in order to make their sides (which happened to be a little convex) to touch one ano'.her, in the place of contact they were both perfectly tran' parent, as if they had been but one continued piece of glass. Koimd the point of contact, where the glasses were a little separated II from each other, rings of different colours appeared. To observe more nicely the order of the colours produced in this manner, he took two object-j>lasses ; one of them a plano-convex one belonging to a fourteen-feet refracting telescope, and the other a large double convex one for a telescope of about fifty feet; and laying the former of them upon the latter with its plane side downwards, he pressed them slowly together ; by which means the colours very soon emerged, and appeared distinct to a considerable distance. Next to the pellucid central spot, made by the contact of the glasses, suc- ceeded blue, white, yellow and red. The blue was very little in quantity, nor could he discern any violet in it ; but the yellow and red were very copious, extending about as far as the white, and four or five times as far as the blue. The next circuit immediately sur- rounding these consisted of violet, blue, green, yellow and red : all these were copious and vivid, except the green, which was very little in quantity, and seemed more faint and dilute than the other colours: of the other four, the violet or purple was the least in extent, and the blue les.s than the yellow or red. The third circle of colours was pur}>le, blue, green, yellow, and red : in this the purple seemed more reddish than the violet in the former circle; and the green was more conspicuous, being as brisk and copious as any of the former, except the yellow; but the red began to be a little faded, inclining much to purple. The fourth circle consisted of green and red ; and of these the green was very copious, inclining on the one side to blue, and on the other to yellow : but in this fourth circle there was neither blue, violet, nor yellow, and the red was very imperiect and dirty. All the succeeding colours grew more and more im- perfect and dilute, till after three or four revolutions they ended in perfect whiteness*. It is perhaps now to be wondered that sir Isaac Newton did not take more particular notice of the fading of the violet and red, or of their becoming more of a diluted cast, and of * Probably brownish first. I have not the means of trying his glasses, but it seems a general law that has been overlooked, as a sign of obscurity perhaps. c 2 12 the three primitive tints mixing as the circles became narrower, which was the cause of the green in the third ring. As the colours were found to vary according to difi'erent distances of the glass plates from each other, our author showed that they proceeded from the different thicknesses of the plates of air intercepted between the glasses. But to return to the order in which he so naturally found the colours in the circles. — First, the three primitives and the seven prismatic tints naturally mixed from them, which I wish he had been aware of, as it would have accounted for the other rings or re- volutions. I have therefore produced an example of the order of his tints in Plate 1. figures 1, 2, 3, &c. in which it will appear that the rings which are called revolutions begin in a natural order, al- though reverse to what I have begun with, viz. first blue, whereas I have begun with yellow. This however is because his instruments were reversed, two opposite convex surfaces producing them in his scheme, and two concave opposites producing my past example. Thus, No. 1 is Blue 2 — White* 3 — Yellow 4 — Red 5 — Violet 6 — Blue 7 — Green 8 — Yellow 9 — Red 10 — Purple 1 1 — Blue 12 — Green 13 — Yellow 1 4 — Red 15 — - Greenish 16 — Dirty ish Red, &c. * White is light, dependent upon the distance of the rings or revolutions which begin or end the series, as Red or Blue, which in these cases come back to back as it were, 13 Blue, yellow, and red, omitting white as neuter, we find, are liis three first colours ; and in the next range, we only want indigo to begin or terminate the series after the red and orange, between the yellow and red, to comj)lete tlie seven prismatic tints in tiie second series ; which, if we observe the joining of tlie red and IjIlic by being viewed at a certain distance, will seem very nearly to be the real case: indeed, a proper softening of one into the other would make it too nice for our discernment ; although, if the red is pure, it ought to be only violet, which in a bad light will ap])ear as dull as common indigo, as a deep purple is dulled by the yellower rays of candle-light and lilac, and all purples ajjpear brightest by day-light. The approach or nearer a})pearance of the two revolutions will also in this instance be found to form green, where the white took place before, as the yellow and blue join to form it ; and so it is with the other rings or revolutions which approach nearer and nearer, next losing the yellow as it were by mixing, and are both duller and paler from want of that opposition to stronger light or darkness, which probably towards the end became obscure, finishing in perfect white- ness, or light reflected on the face of the glass. The middle tint, if 1 may so call it, at g, would not allow of a dark blue margin, as will be understood more perfect! \' hereafter. Having therefore produced the order of his tints, which without more instruction than his words we are enabled to do very perfectly, and as the tints come according to Nature, so we may conclude he was right, as may always be ])roved by the order of the colours ; for the prismatic tints, however irregular they may appear, or seem con- founded, are most perfectly and unerringly regular in their order: thus the rainbow, the colours in the flaws of stones, &c. follow the same rule, even to the coal called peacock coal, for the colours of which, see British Mineralogy, tab. 4Q. Thus if we look through the prism, at a window or a multitude of objects, or any varied number even of coloured things*, all will.be found to be reducible to certain ♦ A print, with many objectSj coloured or uncoloured, may be convenient to examine. 14 rules, as a given proportion of light or sliade produces proportionate colours with as much certainty as any figure in arithmetic. It may perhaps be convenient in this place to ask, whether it is the lamina^ which cause the plates of air of a certain dimension to reflect a particular tint or colour, or whether, like the rainbow, par- helion, or halo, it may not be produced by the crystallized particles of the suijstance acting as water, ice, or hail* ? Iris-like tints are to be produced many ways, and sometimes with very remarkable pha?nomena. At Weather-Cot Cave, in Yorkshire, it is said that if, at certain seasons, a jDcrson placed at the mouth of the cave look at the stream or fall of water that is precipitated from above it, he will see six or more iris-like appearances. These are probably governed by the shadow of the prominences of the rock, or perhaps the disturbed undulations of the water: either repetition seems to depend upon something analogous to the efi'ect of dark lines, which will be seen in the present theory, and the same with the repetitions in different substances, and when artifically contrived by convex or plane glasses, &c. or perhaps in this latter it may depend upon the grinding of the glass, which, however finely po- lished and perfectly smooth to our perception, is nevertheless full of the irregularities left by the tool of the workman in turning it to grind or polish it ; and this would greatly agree with the idea of the crystalline particles producing the colours in various minerals; and it may seem that a double combination of the watery particles, or mist and shadow, produced the circles around the shadows of the heads of sir Joseph Banks and his companions, in the bason of the boiling fountain of Geyer, when visiting Iceland in l/Tlj as Von * As it seems somewhat doubted, what is the form of ice in its crystallization, we can assure our readers that we have found snow in regular tetraedrons, Brit. Min. lai. 281, and in hexaedtal pyramids, produced by truncation at the edges of the tetraedrons j sometimes truncated at the top ; in hexaedral columns formed of plates curiously stel- lated with spiculae; and hail in regular tetraedrons, somewhat plated with nuclei: I have also found the tetraedron with rounded faces, somewhat like the sulphate of cop- per, British Mineralogy, tab. //, but nearer round, like a drop of water. 15 Troil says, thut each saw around the shadow of his own head, though not around the shadows of the heads of others, a circle of almost the same colours which compose the rainbow, and around this another circle. There are many curious instances of such pheenoniena. I have known boys to imitate the rainbow by simply sjju-ting- water from their mouths, in the sunshine, &c. to imitate fine rain, producing the rainbow tints extremely well. Somethmg like this may account for the number of circles or seo^- ments of circles in the various substances in which they happened to form, even the common air. Thus we may conceive certain un- dulations, not unaptly represented in the common crown glass of our windows (which it appears is made by taking a largi>h ball of metal* and spreading it by turning the instrument as when a mop is whirled or trundled to dry it), when the arrangement of the par- ticles of water in the air, like the rings in the glass, varying, gives each a similar eH'ect, or forms circles Now it will be found that the eye cannot see those circles, but by the proportion of light and shadow with the reflexions : and betwixt every swelling, or other cause of light and shadow, there always appear the coloured rings when looked at in the sun, or when the sun shines upon the plate so formed, or obliquely through it on a wall, &c. I'he eye is often so circum- stanced, that things not at all forming real circles have yet the co- loured appearance of them, as a shining waxed table, a greasy ap- pearance on glass, or the almost imperceptible dust that may be on some smooth surfaces, the most minute particles of damp^ breathin"- on glass and copper, or the slime of snails, and many other objects sufficiently well known, either requiring the prism to refract the tints, or forming them to the unassisted eye. These colours fre- quently obtain permanency, and we may trace them till they seem to approach solidity in heated or oxidized steel or other metals, which begin with yellow: this is followed bv orange, then the red, passing to crimson or violet, and thence to blue, as the heat is con- » In the glass fiarnace, the melted glass is called metal by the workmen-. 16 tinued; and if it is still heated, fresh sets of colours are formed; which is not only a proof of a sort of permanence of colours brought on by heat, but of their regularity in successively forming rings, which is rather universal vviiere colours are formed, especially as they de- pend upon some sort of prismatic agency: but the yellow and red are not very bright, as the steel does not reflect them so well as many other substances, although the blue is generally beautifully reflected. Nature, however, produces them all most brilliantly on some iron ores and other oxides. Having gone thus far, I found it might give much satisfaction if I were to examine the light from the full sun's rays, as an original source, in the open air. I therefore took the usual three-sided prism, and was highly gratified by observing white in the refracted reflexion of the sun, as seen of an oval form, light on the face of the prism, and the three primitive tints, a fine yellow, a rich red, and a light blue: (see Tab. 2. Jig. 1 and 2,) and I found, by turning the prism, very beautiful phaenomena took place within it, scarcely, if at all, before noticed in open light. The rays, as they become more oblique, spread over each other, the yellow over the white to the blue forms green, while the blue on tlie darker side is changed into violet and indigo. The red, by the same motion, passes over some of the yellow spreading into orange, and thus are formed the regular seven prismatic tints or spectrum. At the same time as the above, may be seen lefracted immediately from the sun's most bril- liant rays, upon any object within a few inches, a fine image of the prism bordered lengthwise, by the same three tints: {see Tab. 2, fig. 3.) This shows the primitive tints on a larger scale, and will therefore give a fuller exjjlanation of the whole. Thus the middle I call white, as the more direct light, the yellow is below it, the red lowest, and the blue on the uppermost or opposite side, blending but a little with each other, and least so when most vivid, or when the oval reflexion. Jig. 2, is nearest in form to a circle. When a strip of white paper is seen through a prism, at a proper distance, on a mahogany or dark table, blue will terminate one edge, and red another, with the same appearance as the above ; and the proper motion of the prism or paper will produce tlie green, orange, indigo, and violet, if the jjajjer is not too broad. We therefore find three original primitive tints may be formed distinctly on white paper*. Rich lights, or whites, and full or more perfect darkness opposing each other, produce the more brilliant tints. The rich light of the sun dispelling the darkness of the morning, or passing away in the evening, produces more apparent colour than at noon when the whole atmosphere is illuminated ; and a small candle in a large room, surrounded as it were by much darkness, gives as great brilliancy in the prism as the sun itself: and again, the prismatic rays col- lected from the sun require a quantitj^ of shade to show them most brilliantly: — thus they were generally refracted into a dark room. Next to this we might consider convexity and concavity ; and it will be found that they add to the brilliancy, as they allow a greater strength of light and shade. Convexity and concavity amount, by undulation, as it were, to nearly tiie same thing as light and shade (by which artists have their imitative power) ; and any light with shade will produce prismatic tints ; thus, as it were, reducing the ])ro- duction of tints to light and shade, or white and black. We shall find the means of illustrating this in every necessary example. Hence it is found, that as the appearance of colour depends upon a certain opposition of light and darkness, so much depends upon the pro- portion of each for the colour they may produce, and the degree or strength of it. I therefore look at the middle of a piece of dense smooth black paper with the prism, and perceive no colour ; if I produce a small dot, or ray of light, or streak of white, immediately certain prismatic tints are produced, according to the proportion, from * Dr. WoUaston, however, as an original in philosophy, examined a narrow ray of light, :ind found what he considered as the four primitives ; and Dr. Young, a broader ray, by which he determines seven primitives, inchiding white. I think it will be seen that the breadth of the ray will naturally vary the appearance, as ill a broad ray, or a ray of a certain proportion, they ellow and blue do not mix as in a n.irrow one, unless by turn- ing llie prism. D 18 three to seven, like those of a rainbow *. As I admit more light, of make tlie marks broader and larger, the colours become brighter and more separated, till white is admitted in the broadest, when it will appear that the white, with yellow, red and blue, only remain, and perhaps a little mixture, between the bright red and yellow, of orange-1-, and the yellow with the light or white, naturally blend into each other, and the blue is also softened into the white termi- nating at the lower edge. Having thus produced the coloured rays by a little light and much black, it may be proper to try a contrary process, by a little black and much white. We should therefore look at the middle of a piece of white pajier, or any white object, when if smooth, and free from spots or marks, we shall perceive no colour; but if a fine stroke of black be produced, pale tints or colours will be seen ; but if more black is added, the colours will be more distinct in a certain proportion. The order of the colours will com- mence as it were with the penumbra of the former experiment oa light, as light blue above passing downwards into indigo and violet, the white immediately beneath partaking of the red and yellow, as in the upper part of the white line, and the blue will not recommence till something terminates the space of white, as a wrinkle or shadow; the margin of the paper or book, a stroke with a pen, &c. producing, (and we have power of continuing) the same phaenomena at plea- sure. It was just observed, that if we added more black the colours would be more distinct in a certain proportion ; I may add, that they will be more vivid and apparently more perfect. Ultimate perfection not being in the power of mortals, it is well if we are allowed to attain to a certain degree of it ; and it is surely a hi.-I. lai. S Oft I idol Puhl^tiil hj .T.i 'S.meH,,, /.„„.h;, (^//irc/n^c'' (^yca/t:/?. 6^ Octjjgo,'. AJ<7ijf> ;! ^r^-^C±l / /f- ^A yw^ / ■y /''•■'•.^# 7kb.y. X.lSoa.Aihiirh'H ht/ Jal ^•nra^.j Xund^ti SHORTLY WILL BE PUBLISHED, A. CONCISE PRODKOMUS of the British Minerals in Mr. Sowerby's Cabinet, as a Sort of Essay towards a New, Natural, and Easy Ar- rangement, v\ith References to the Author's BRITISH MINERALOGY, made for the Use of those who will find British Mineralogy more useful for a Library than a Travelling Book. Mr. Sowerby having found no consistent reason, generally speaking, for the Foundation of any former System, pre- sumes to offer this, rather to learn the Sentiments of the Public on such a System, allowing for Errors, which he hopes to have corrected by iheir Dis- cernment. In his more extensive Application, Mr. Sowerby thinks a good Arrangement may much facilitate this useful Foundation of every Branch of Knowledge. Prospectus of IForks already published by James Sowerbv. I.BRITISH MINERALOGY, or the Minerals of England, Scotland, and I-reland ; comprehending the Combustibles, Earths, and Metals, in Coloured Figures, with Descriptions from the Primitive Crystals to their Amorphous States, as either for Ornaments, Agriculture, or other useful and scientific Purposes. By JAMES SOWERBY. No. 1 to .^3, Price 9^. 15*. Continu- ing in Numbers, published every two Months, at 5s. each. 2. SOWERBY'S ENGLISH BOTANY, or Coloured Figures of all the Plants Natives of the Empire of Great Britain, vviih their Essential Characters, Synonyms, and Places of Growth, &c.; to which are added occasional Re- marks on their medicinal Virtues, and other useful Observations. No. 1 to 210, Price 42/. 15. 6d. Continuing in Monthly Numbers at 35. per Number. The Descriptions by Dr Smith. 3. 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