M 4 Digitized by the Internet ^ Archive in 2013 http://archive.org/details/practicaltreatisOOhood A PRACTICAL TREATISE ON WARMING BUILDINGS BY HOT WATER; AND AN INQUIRY INTO THE LAWS OF RADIANT AND CONDUCTED HEAT. TO WHICH ARE ADDED, REMARKS ON VENTILATION, AND ON THE VARIOUS METHODS OF DISTRIBUTING ARTIFICIAL HEAT, AND THEIR EFFECTS ON ANIMAL AND VEGETABLE PHYSIOLOGY. BY CHARLES HOOD, F.R.A.S. ILLUSTRATED BY NUMEROUS WOOD-CUTS. LONDON: WHITTAKER & Co. AVE MARIA 1837. LANE. LONDON : GILBERT & RIVINGTON, PRINTERS, ST. John's square. PREFACE. A NATURAL inclination for philosophical inquiries, first led me to investigate the principles of the invention for heating buildings by the circulation of hot water ; and the many favourable opportunities that have occurred for proving the accuracy of my theoretical views, have encouraged me to persevere in the investigation. Frequent applications having been made to me, by persons who were aware that the subject had engaged my attention, to recommend to them a practical treatise on its principles and application, the utility of such a work, in forwarding the progress of the discovery, became obvious. And finding that nothing relating to the invention had hitherto been published, except a few scattered and unimportant notices, it appeared probable that the materials I possessed might form a treatise which would be A 2 iv PREFACE. useful, not only in showing the practical application of the invention, but also in explaining the scientific principles upon which the various effects depend. The following pages are therefore offered, in the hope of supplying the desideratum. The different parts of the subject have been arranged, as far as possible, under distinct heads. The primary object has been to explain the principles, in a manner perfectly clear and intelligible to such as are unacquainted with those branches of physical science on which the philosophy of the invention is based : and, while endeavouring to remove the erroneous notion, which is entertained by some persons, that a certain degree of danger is insepar- able from the plan, to show that danger can occur only through a misapplication of the principles. In order to pursue the inquiry in a popular manner, all abstruse calculations and scientific tech- nicalities have been, as much as possible, avoided ; and the most simple definitions the subject would admit of have been adopted, as far as is consistent with perspicuity. The Rules, Calculations, and Tables, which are given in the body of the work, have, nearly all, been constructed expressly with reference to the present inquiry; and the Tables given at the end of the volume are compiled from the best authorities : the whole comprising, it is hoped, all the information which the subject requires. PREFACE. V In extenuation of any omissions or errors which may be found, it should be borne in mind that, hitherto, no attempt has been made to give a com- prehensive view of this invention. The increasing attention of the public to the subject, however, ren- ders the present time the most proper for the publi- cation of such a treatise as the one now offered : and though probably much remains to be disco- vered relating to the invention, the communication of what is already known is the surer way of ex- tending the sphere of its utility, than by waiting until its principles shall be more fully revealed by time, in the hope of producing a more complete work. But although no excuse is thus intended to be offered for any errors, other than such as are trivial and unimportant, if any omissions be found, the plea may be urged, and will, perhaps, be admitted — Bis dat qui cito dat. To conclude these prefatory remarks : it may be observed that in pointing out, and freely com- menting on the erroneous principles which have, in some instances, been both theoretically and practically promulgated by others, it is under the impression that such errors, carrying with them in general considerable plausibility, might, if uncon- futed, lead not only to inconvenience, but even to danger; more particularly, as, on account of their emanating from men of ability, others may also be liable to fall into similar mistakes. However invi- Vi PREFACE; dious, therefore, the task of pointing out sucli errors may seem, it appeared to be necessary, when writing on this subject, not only to exhibit what were con- sidered to be the true principles, but also to show where erroneous notions have been adopted. This must be the apology for the freedom with which the opinions and inventions of others are descanted on in the following pages ; and, as these are not the production of an inventor, who is expatiating on the advantages of his own particular plan, they will, it is hoped, be found a candid inquiry into the merits of the various descriptions of apparatus which are brought under consideration, pointing out their philosophical principles, and displaying their utility in a practical manner. C. H. Em^l Street^ Blackfriars, September, 1837. CONTENTS. PAGE Introduction 1 CHAPTER I. On the cause of circulation of the water, and its consequences 7 CHAPTER II. On the application of the principles 24 CHAPTER III. On the proportionate sizes of various parts of the apparatus 5 1 CHAPTER IV. On permanence of temperature, depending on the form and size of the boiler and pipes 57 CHAPTER V. On the size and construction of furnaces 75 CHAPTER VI. On the laws of heat 82 CHAPTER VII. Experiments on cooling 100 viii CONTENTS. CHAPTER VIII. PAGE On the application of the laws of heat, to determine the proper size of an apparatus for heating any description of building 108 CHAPTER IX. On peculiar modifications of the hot- water apparatus . .127 CHAPTER X. General application and summary 155 CHAPTER XI. On ventilation 169 CHAPTER XII. On the various methods used for distributing artificial heat. 188 Tables, &c 205 Index 213 ERRATA. Page 35, line 2 of note, /or " also directly" read ** the friction directly." — 89, — 11, /or " (a'— 1)" read " (a'— 1)." A PRACTICAL TREATISE, &c. INTRODUCTION. The practice of employing hot water, circulating through iron pipes, for diffusing artificial heat, has now become so general, that its merits are acknow- ledged as an invention of utility. The last twelve years, though they have not actually been witness to the discovery of the plan, have, at least, revealed nearly all that is known respecting its practical application ; for, previously, the range of its opera- tion was confined rather to a few cases of expe- riment, than extended to any general or useful purposes. It can scarcely excite surprise, that prejudices should formerly have existed against this invention, while its merits and its principles were alike imper- fectly known. Even at the present time they are B 2 INTRODUCTION. but partially understood ; and, therefore, to investi- gate these two subjects, is the proposed object of the present treatise, with the view of facilitating its application, and extending the sphere of its utility. There is scarcely any branch of science or of art, in which an acquaintance with the laws of Nature does not enable us to derive greater advantages in its application, than we could otherwise possess. Although it is true that we are still ignorant of the more subtile agents which exist in the vast chain of causation, the laws which regulate the various phenomena of nature, are sufficiently known to afford the most beneficial assistance to every branch of the arts and sciences: and the most recon- dite of scientific discoveries, as well as the most valuable inventions and improvements in the arts, are not more demonstrative of the truth of this assertion, than are those of the most simple characters. For an illustration of the utility of this know- ledge, we may refer to the law of gravity ; not only because it is, of all natural phenomena, the most constant in its operation, and the most universal in extent, but because its influence is closely con- nected with the present subject of inquiry. That all falling bodies gravitate with the same velocity, and, therefore, descend through a certain definite space in a given time, is, we know, an effect INTRODUCTION. 3 of which gravity is the cause. It is on the operation of this invariable law, that many of our most valu- able inventions depend. Its influence is equally exerted on all objects ; as well the most dissimilar, as the most alike ; as well the most mighty, as the most minute. It is from this cause that we obtain the unerring action of our pendulums and clocks ; and it is by this also we obtain the circulation of hot-water, with which we warm our dwellings. But by a knowledge of the cause of these effects, of the extent of its operation, and of the laws by which it acts, we can, by varying the circumstances of a gravitating body, alter also the velocity of its de- scent. And we accomplish this by bringing other causes into operation, which modify the result, not- withstanding the immutability of the laws of gravity. Thus, we can modify and subject to our will, one of the most constant and universal agents in Nature, by a knowledge of the physical laws. The study of the laws which govern natural phe- nomena, — which in all cases are so simple, so beau- tiful, so perfect, — is, therefore, one of the most fruitful sources of inquiry which the mechanician can pursue. Without it all his plans will either be modified copies of existing inventions, or they will degenerate into wild speculations, unsupported on any reasonable foundation. This is particularly observable in the case before us. The numerous failures which have occurred B 2 4 INTRODUCTION. in the practical application of the invention of heating buildings by the circulation of hot water, are all distinctly roferrible to the want of this kind of knowledge, and not to the object aimed at being itself unattainable. But whenever the physical laws are intended to be employed as the principal agents in producing any mechanical effect, it is an indispensable condition that simplicity of action be kept in view. While it may further be observed, that the endeavours to trace and elucidate the operating causes of the various phenomena, which occur in the course of practical experiments, are the surest means of facilitating original discoveries, as well as of promoting new adaptations of recognised principles. The origin of the invention of employing hot water for diffusing artificial heat, appears to be hid in considerable obscurity. It is not improbable that, similar to many other discoveries, it has been evolved at various periods from the Alembic of Time. It seems, in one instance at least, to have been used in France about sixty years since. After fading from recollection for a space of about forty years, it appears to have been re-invented by the Marquis de Chabannes, and subsequently by Mr. Bacon and Mr. Atkinson. And it was the latter, who, un- doubtedly, first gave to the apparatus the arrange- ment, under which it is now generally used in its most simple form. INTRODUCTION. 5 The variations since made in its more complicated arrangements, appear to have been very gradually adopted. Each time that an apparatus has been erected, the experimentalist has deviated in some small degree from the model of that which pre- ceded ; apparently afraid of venturing on too great a variation, yet requiring, from contingent circum- stances, some alteration of its form and application. This mode of proceeding, though natural v^hile the principles were not thoroughly understood, has frequently led to both inconvenience and loss, in consequence of the numerous failures to which it has given rise, by unintentional deviations from the principles. In the present attempt to elucidate the subject, it will however be shown, that success needs not be uncertain, provided only, that the laws of physics be justly applied and strictly adhered to. Neither the capabilities of this method of warm- ing, nor the various useful purposes to which it is applicable, are at present fully appreciated. There are no buildings, however large, to which it cannot be advantageously adapted, nor any that present insurmountable difficulties in its practical applica- tion. It is an invention only yet in its infancy, but which gives promise of a maturity that will confer the greatest advantages w^here its employ- ment is the most extensive. Its merits, however, will best appear by the 6 INTRODUCTION. plainest statements of facts. We shall proceed, therefore, at once, to the main object which has been proposed ; an investigation of the principles of this invention, as applied to the warming of buildings. CHAPTER I. Cause of Circulation of the Water — Force of Gravity — Pressure of Water — Effect produced on the Circulation by increased Height of the Pipe. Art. 1. In endeavouring to explain the princi- ples of the various forms of apparatus in which hot water, circulating through iron pipes, is employed as a means for distributing artificial heat, the first object should be to point out, as clearly as possible, the power which produces circulation of the water ; for without a clear perception of this part of the subject, there will always be an uncertainty as to the results which will obtain, when any departure is made from the most simple form and arrangement of the different parts of the apparatus. It is this circulation which causes all the water in the appa- ratus to pass successively through the boiler, and then communicates the heat that is thus received from the fuel, to the various buildings or apartments which it is designed to warm. Without this cir- culation, those parts of the apparatus which are remote from the fire would not receive any heat ; 8 CAUSE OF CIRCULATION because water is so bad a conductor, that it is only when there exists perfect freedom of motion among its particles, that it acts at all as a conductor of heat, so far, at least, as regards any practical and useful effect. It is in a complete and perfect circu- lation, therefore, that the efficiency of a hot water apparatus depends, and that the greatest amount of heat is obtained by it from a given quantity of fuel. 2. The only treatise hitherto published, in which any attempt has been made to explain the cause of circulation of the water in this description of appa- ratus, is Mr. Tredgold's work on heating by steam ; and the effect is there referred entirely to an erro- neous cause. In the Appendix to that work, the cause of motion is thus explained. " If the vessels A, B, and pipes, be filled puj. with water, and heat be applied to the vessel a the effect of heat will expand the water in the vessel A, and the surface will, in consequence, rise to a higher level a, d, the former general level surface being b. The density of the fluid in the vessel A will also decrease in consequence of its expansion ; but as soon as the column c, d (above the centre of the upper pipe) is of a greater weight than the column laii is not very dissimilar to that adopted by the Marquis de Chabannes, about twenty years ago. 44. In such an arrangement of pipes as fig. 10, the circulation depends entirely upon the quantity of heat given off by the coil c ; for. it is evident that, when the boiler B and pipe a are heated, the di- rect motion will arise in consequence of the greater weight of the water in the coilc and pipe d, above that which is in the boiler and pipe b, a. But as the water in the pipe e, below the dotted line, will be lighter than that in the pipe f, the tendency in that part of the apparatus will be towards a retrograde motion. The result of these two forces will be, that if the water in the whole length of pipe w, a% is heavier than that of the whole length j/, z, in a suffi- cient degree to overcome the friction, circulation of the water will take place; and the velocity of motion will depend upon the amount of this difference in weight. 45. Another form, though somewhat more com- plicated, may be given to this arrangement of the apparatus. In fig. 1 1 , B represents the boiler ; and BELOW THE BOILER. 45 tlie effective or direct motion is, in this case, caused by the water in the ^ig. ii . coil and pipe c, d, being so much hea- vier than that in the boiler and pipe B, a, that it over- comes the retro- grade motion which is produced by all the other parts of the apparatus. Thus the water in A, being Jieamer than that in z, k ; and that in f, (below the dotted line) being lighter than that in /, 7n, has, in both cases, a tendency to retrogression ; and this will be more considerable in proportion as the pipes z, k, and g, h, &c., are more distant from each other. The motive power, therefore, entirely depends upon the quantity of heat given off by the coil ; for the water must be cooled down many degrees, in order to give it a sufficient preponderance over the water in B, a, to cause a circulation. 46. If the coil, in the tw^o last figures, be placed in any position lowTr doM^n than it is here shown, the effect will be proportionally less ; and if placed below the dotted lines, it would be scarcely possible to obtain any circulation at all. Nor would there be any circulation if the coil M ere omitted, because the mere descent of the water through a straight 4(3 ACCUMULATION OF pipe, would not cool it sufficiently to give the neces- sary preponderance to the descending pipe, unless some other contrivance, for the purpose of cooling the water an equal extent, were adopted. 47. Many other arrangements of the apparatus answering the same purpose as these last two figures, might be contrived ; but it may be observed, that these des(^riptions have been introduced principally to show that the notion that it is impossible to make water descend and circulate below the boiler, is erroneous. It, however, requires great judgment in adopting any such form of the apparatus as this, for many concurring circumstances are essential for its complete success. 48. In a complicated arrangement of the appa- ratus, it is sometimes so very difficult to detect the various causes of interference, and the impediments which arise are often apparently so insignificant in their extent, that even when ascertained, they are frequently neglected. Those, however, who bear in mind how small is the amount of motive power in any apparatus of this description, will not consider as unimportant, any impediment, however small, which they may detect ; but in the more complicated forms of the apparatus, so many causes become opera- tive, that the reason of failure may sometimes elude the detection of even an experienced practitioner. 49. The necessity of making provision for the escape of the air from the pipes, has already been AIR IN PIPES, 47 mentioned. It may be observed, that in such forms of the apparatus as described in the last three figures, the difficulty of its expulsion is much increased, as there are several points where it will collect and stop the circulation, unless proper means be taken to prevent this result. In the apparatus fig. 9, the air will collect at three points /, m, and n ; and the nature of the outlets provided for its escape, will depend, in some measure, upon the plan adopted for supplying the apparatus with w^ater. It fre- quently requires the greatest care and the closest attention, to discover where the air is likely to lodge, as the most trifling alteration in the position of the pipes will entirely alter the arrangements with respect to the air vents. Want of attention to this has been the cause of many failures ; and the dis- covery of the places where the air will accumulate, is, occasionally, a matter of some difficulty. For although it be true, in a general sense, that the air will rise to the highest part of the apparatus, it will frequently be prevented getting to those parts by alterations in the level of the pipes, and by other causes. This is the case at fig. 9, where, it will be seen, the air which accumulates in that part of the apparatus is prevented from escaping to a higher level, by the vertical angle at f, on the one side, and z, on the other. In the apparatus, fig. 11, the air will accumulate at y, and at and must be car- ried olf by proper outlets. 48 EXPANSION OF WATER. 50. When a boiler lias an open top, or merely a loose cover laid on it, no particular care is necessary respecting the supply of water. It can generally be poured in at the boiler, taking care not to fill it quite full, so as to allow for the expansion of the water when heated, as otherwise it will overflow. But when (as in figures 7, 9, 10, and 1 1,) the boiler is close at the top, it is usual to place a supply cistern on a level with, or above the highest part of the apparatus, so as to keep it always full of water. But as water expands about -^-^ part of its bulk, when it is heated from 40° (the point of its greatest condensation,) to 212°; it is indispensably necessary to provide for a part of the water returning back to the supply cistern, when this expansion takes place. The cistern, however, needs not contain so much water as part of the whole contents of the appa- ratus ; for it is found, in practice, that a much less quantity than this returns back into the cistern on the apparatus being heated. This arises from the fact of the water not reaching to so high a tempera- ture as 212°, and also in consequence of its being generally at a higher temperature than 40°, before it is heated, and by both these causes, the expansion is considerably lessened ; for if the water be raised from 50° to 180°, the expansion will only be about part of its bulk, and the expansion of the iron itself, by giving an increased capacity to the appa- ratus, will also tend still farther to diminish the quantity of water returned back into the cistern. SUPPLY CISTERNS. 49 Fig. 12. 51. The usual plan for a supply cistern is shown in fig. 12. The cistern is placed in some convenient situation, and then attached, by a small pipe, to any part of the apparatus, — usually, to the lower pipe, as it is then less likely to allow of the escape of vapour, than if it were fastened to the top of the boiler. X^..^--^^^ But a still better plan is to bend the pipe, attached to the cistern, into the form shown by which is a preventive to the escape of any heat or vapour at that part, as the legs of the inverted syphon x generally remain quite cold. 52. One very important part of the subject of expansion, is the necessity which exists for allowing sufficient room for the elongation of the pipes when they become hot. Want of attention to this has caused several accidents ; for the expansive power of iron, when heated, is so great, that scarcely anything can withstand it. The linear expansion of cast iron, by raising its temperature from 32° to 212°, is •0011111, or about -^-^ part of its length, which is nearly equal to \\ inches in 100 feet. Therefore it is necessary to leave the pipes unconfined, so that they shall have free motion lengthways, to this extent at least ; and instead of confining them, as sometimes has been done, facilities should be pro- vided for their free expansion, by laying small rollers E 50 EXPANSION OF PIPES. under them at various points : for as the contraction on cooling is always equal to the expansion on heat- ing, unless they can readily return to their original position when they become cool, the joints are very likely to get loose, and to become leaky. « CHAPTER III. On the Resistance by Friction — Relative Sizes of Main Pipes and Branch Pipes — Size of Connecting Pipes, Cocks, &c. 53. When treating, in the preceding chapter, on the velocity of the circulation of the water, it was observed that the theoretical velocity is always reduced by friction. Although the calculations of the friction of water, in passing through pipes, is in- tricate ^ the 7'elatwe friction for different sizes of pipes is easily ascertained ; and this appears to be all that is necessary to be acquainted with, for the pur- pose of the present inquiry. 54. The friction occasioned by water passing through small pipes, is very much greater than in those which are larger. This arises from two causes : the increased surface with which a given quantity of water comes into contact, by passing through a small pipe ; and the greater velocity with which the water ^ See Art. 34. E 2 52 FRICTION OF PIPES. circulates, in consequence of losing more heat per minuted 55. The relative friction for different sizes of pipe, when the velocity with which the water passes is the same in all, may be seen in the following Table : Diameter of Pipes ^. 1. 2. 3. 4. inches. Friction 8. 4. 2. VS. 1. Taking the friction, in pipes of 4 inches diameter, as unity, — that of a pipe 2 inches diameter is twice as much, and a 1-inch pipe four times as much as the pipe of 4 inches; the friction being as the surface directly^ and the whole quantity of water inversely.^ 56. The friction which arises from increased velo- city, is nearly as the square of the velocity ; but this calculation is unnecessary to enter into here, because the velocitv of circulation of the water, in a hot- water apparatus, is constantly subject to fluctuation : for as the friction increases with the velocity of cir- culation, so the velocity is checked by the increased friction; and it finally assumes a mean rate, propor- tioned to the friction on the one hand, and the theoretical velocity on the other, calculated ac- ^ See Chap. IV, art. 72. This latter remark of course only applies to water circulating in a hot-water apparatus : the former applies to all cases of hydraulics. ^ Nicholson's Journal, Vol. iii., page 31. MAIN PIPES. 53 cording to the rule (art. 33,) in the preceding chapter. 57. Closely connected with the subject of friction, is the question of the proper size for leading, or main pipes. It has been supposed by many, that where two or more circulating pipes are attached to one main pipe, the area, or section, of the main pipe, ought to be equal to the sum of the areas of all the branch pipes. This has led to the most incon- venient arrangements having been resorted to in particular cases. In some instances, pipes of 9 inches diameter have been used for the main pipes, where those of 4 inches would have answered the purpose infinitely better. 58. It has been already explained (art. 36) why the motion of water is more rapid in an upright, than in a horizontal pipe. If four branch pipes are supplied by one upright main pipe, this latter needs be very little, if any, larger than the circulating pipe : but if only two, or even three, branches are to be supplied by one main pipe, it will be quite unne- cessary that the main pipe should be any larger than the branches, unless the length of the horizontal pipe be unusually great. If the branches exceed this number, it may be desirable to increase the diameter of the main pipe, in a moderate degree : but the motion of the water through it, however, will be just so much the more rapid, in proportion as there are more branches for it to discharge the water 54 MAIN PIPES. into : for it is evident, that if the outlet from the boiler be by a pipe 4 inches diameter, the flow of water will be more impeded, than if a pipe of 6 inches diameter were used; and the water will be specifically lighter in the boiler than in the descending pipe, in a greater degree in the former case, than in the latter ; and this will consequently cause a more rapid circulation through the apparatus : but though the friction of the water will be greater in the ascending pipe by this arrangement, yet it will not be of much importance, except when very small pipes are used. 59. Another advantage will arise from this ar- rangement, in consequence of a small pipe, under these circumstances, losing less of its heat than a large one. For, suppose four branch pipes, 4 inches diameter, are to be supplied by one main pipe ; one pipe of 8 inches diameter would have the same sectional area as the four pipes of 4 inches diameter : but if instead of being 8 inches diameter, the main pipe be made only 4 inches diameter, then the water must travel four times as fast through this pipe, as it would do through the one of 8 inches diameter, in order to supply the same quantity of heat to the branch pipes. This it will do very nearly ; and it may easily be deduced, that, under these circumstances, the water will only lose one half as much heat by passing through the small pipe, as it would in passing through the larger one. 1 CONNECTING PIPES. 55 60. On the same principle, it will frequently be found exceedingly convenient, when two rooms or buildings, somewhat distant from each other, are required to be warmed by one boiler, to make the connecting pipe between them much smaller than the pipe used for radiating the heat to warm the buildings. For, on the principle already mentioned, there will be a saving, as well in heat, as in the cost of the apparatus, by reducing the size of the pipe in that part which is not required to give off heat, but which is merely used to connect different parts together \ 61. The same rule may likewise be followed, where stop-cocks are required occasionally to shut off the communicatioa between different parts of an apparatus, so as only to warm one particular room or part of a building. The cocks used for this purpose, need not be near so large as the bore of the pipes ; for exactly in proportion as they are smaller, so ^ As all alterations in the size of the pipe, either by enlarging or contracting its diameter, materially alters the velocity of circulation of the water, care should be taken that these altera- tions be not made without some decided advantage appears to be attainable by so doing. Venturi found by experiment, that enlargements in a pipe reduced the velocity of discharge as follows : — When a given quantity of water was discharged through A straight pipe in 109'' A pipe with 1 enlargement, required .... 147'' 3 5 192'' 240" 56 STOP-COCKS. much the more rapidly will the water pass through the obstruction \ Some judgment, however, must be exercised in all such cases : for both with con- necting pipes and cocks, if the size be very dispro- portionate, the free circulation of the water will of course be impeded. In most cases, a cock of 2 inches diameter, will be sufficiently large to use with pipes of 4 inches diameter; and a cock of IJ inch diameter, with pipes of 3 inches diameter: but for very small pipes, the relative proportions should perhaps be more nearly equal, on account of the increased friction. 62. Though some of these propositions may ap- pear to be at variance with the laws of hydraulics, they will nevertheless be found correct; because several of the effects are to be referred either en- tirely to hydrostatic laws, or to a complicated result of hydrodynamics ; and therefore they are not to be judged of by simple hydraulic principles. In fact, the correctness of the theories advanced in this treatise, which are of a practical character, and admit of verification, have been tested, more or less extensively, by actual experiment, and do not, therefore, rest merely on hypothetical reasoning. ^ As this may at first appear doubtful, it should be borne in mind, that this kind of obstruction to the circulation, will cause a greater di{Ference between the temperature of the flow pipe and the return pipe ; and, when this occurs, the velocity of the circulation must always be increased. CHAPTER IV. Permanence of Temperature— Rates of Cooling, for different sized Bodies — Relative Size of Pipes and Boilers — Objections against Small Boilers — Proper Size of Boilers, for any given Length of Pipe. 63. One of the greatest advantages which the plan of heating by the circulation of hot water possesses over all other inventions for distributing artificial heat, is, that a greater permanence of temperature can be obtained by it, than by any other method. The difference between an apparatus heated by hot water, and one where steam is made the medium of communicating heat, is no less remarkable in this particular, than in its superior economy of fuel. 64. It seldom happens that the pipes of a hot- water apparatus can be raised to so high a tempera- ture as 212° ; and in fact, it is not desirable to do so ; because steam would then be formed, and would escape from the air vent, or safety pipe, without affording any useful heat. Steam pipes, on the 58 COMPARISON OF HEAT contrary, must always be at 212° at the least, be- cause, at a lower temperature, the steam will con- dense. A given length of steam pipe, will therefore afford more heat than the same quantity of hot- water pipe : but, if we consider the relative perma- nence of temperature of the two methods, we shall find a very remarkable difference in favour of pipes heated with hot water. 65' The weight of steam at the temperature of 212°, compared with the weight of water at 212°, is about, as 1 to 1694 ; so that a pipe which is filled with water at 212°, contains 1694 times as much matter as one of equal size filled with steam. If the source of heat be withdrawn from the steam pipes, the temperature will soon fall below 212°, and the steam immediately in contact with the pipes will condense : but in condensing, the steam parts with its late^it heat ; and this heat in passing from the latent to the sensible state, will again raise the temperature of the pipes. But as soon as they are a second time cooled down below 212°, a further portion of steam will condense, and a fur- ther quantity of latent heat will pass into the state of heat of temperature ^ ; and so on until the whole quantity of latent heat has been abstracted, and the ^ The heat of temperature is that which is appreciable by the thermometer; and the term is used in contra-distinction to latent heat, which is not capable of being measured in a direct manner by any instrument whatever. IN WATER AND STEAM. 59 whole of the steam condensed, in which state it will possess just as much heating power, as a similar bulk of water at the like temperature ; that is, the same as a quantity of water occupying YrtT P^^^ the space which the steam originally did. 66. The specific heat of uncondensed steam com- pared with water, is, for equal weights, as '8470 to 1 : but the latent heat^ of steam being estimated at 1000°, we shall find the relative heat obtainable from equal weights of condensed steam, and of water, reducing both from the temperature of 2 1 2° to 60°, to be as 7*425 to 1 ; but for equal bulks, it will be as 1 to 228 ; that is, bulk for bulk, water will give out 228 times as much heat as steam, on reducing both from the temperature of 2 1 2° to 60°. A given bulk of steam will therefore lose as much of its heat in one minute, as the same bulk of water will lose in three hours and three quarters. 67. When the water and the steam are both contained in iron pipes, the rate of cooling will, however, be very different from this ratio ; in conse- quence of the much larger quantity of heat which is contained in the metal itself, than in the steam with which the pipe is filled. ^ The results of different experiments on the subject of the latent heat of steam, although somewhat various, are yet suffi- ciently near for all practical purposes. Watt's experiments give 900° to 950°; Lavoisier and Laplace, 1000°; Mr. Southern 945°; Dr. Ure, 967° to 1000°; and Count Rumford, 1000°. 60 PERMANENCE OF 68. The specific heat of cast-iron being nearly the same as water (see Table V.) ; if we take two similar pipes, 4 inches diameter, and ^ of an inch thick, one filled with water, and the other with steam, each at the temperature of 212°; the one which is filled with water will contain 4*68 times as much heat as that which is filled with steam : there- fore if the steam pipe cools down to the tempera- ture of 60° in one hour, the pipe containing water would require four hours and a half, under the same circumstances, before it reached the like tempera- ture. But this is merely reckoning the effect of the pipe and of the fluid contained in it. In a steam apparatus this is all that is effective in giving out heat : but in a hot- water apparatus, there is likewise the heat from the water contained in the boiler, and even the heat from the brick work around the boiler ; which all tends to increase the effect of the pipes, in consequence of the circulation of the water continuing long after the fire is extinguished; in fact, as long as ever the water is of a higher tem- perature than the surrounding air of the room. From these causes, the difference in the rate of cooling, of the two kinds of apparatus, will be nearly double what is here stated : so that a building warmed by hot water, will maintain its tempera- ture, after the fire is extinguished, about six or eight times as long as it would do if it were heated with steam. TEMPERATURE. 61 69. This is an important consideration wherever permanence of temperature is desirable ; as, for instance, in hot-houses, conservatories, and other buildings of a similar description : and even in the application of this invention to the v^^arming of dwelling-houses, manufactories, &c.; this property, which water possesses, of retaining its temperature for so long a time, and the very great amount of its specific heat, prevents the necessity for that constant attention to the fire, which has always been found so serious an objection to the general use of steam apparatus. 70. The velocity with which a pipe or any other vessel cools, when filled with a heated fluid, depends principally upon two circumstances — the quantity of fluid that it contains, relatively to its surface ; and the temperature of the air by which it is surrounded ; or, in other words, the excess of tem- perature of the heated body, above that of the surrounding medium. The subject of the radiation of heat, and the rate at which a heated body cools, under various circumstances, will be fully considered in another chapter. But for temperatures below the boiling point of water, and under such circum- stances as we are now considering with regard to hot-water pipes, the velocity of cooling may be esti- mated simply in the ratio of the excess of heat, which the heated body possesses above the tempe- rature of the surrounding air. The variation in the G2 RATE OF rate of cooling, arising from a difference of the superficies to the mass, is, for bodies of all shapes, inmrsely^ as the mass divided hy the superficies. There- fore, the relative ratios of cooling, for any two bodies of different shapes and temperatm-es, is the inverse numbers obtained by dividing the mass by the superficies, multiplied by the direct excess of heat above the surrounding air ; provided the tem- perature of the heated bodies be below 212°. Thus suppose the relative ratio of cooling be required, for two cisterns filled with hot water, one a cube of 18 inches, at the temperature of 200°; the other a parallelepiped, 24 inches long, 15 inches wide, and 3 inches deep, at the temperature of 170°; the sur- rounding air in both cases being 60°. Then, as, INCHES. INCHES. The cube contains 5832, divided by 1944, the superficies = .3* The parallelepiped contains . 1080, do. 954, do. =113 The inverse of these numbers is, to call the cube 1-13, and the parallelepiped 3*0. Then multiply 1*13 by 140 (the direct excess of temperature of the cube), and the answer is 158*2 : and multiply 3*0 by 110 (the direct excess of temperature of the parallelepiped), and the answer is 330*0. There- fore, the parallelepiped will cool, in comparison with the cube, in the proportion of 330 to 158, or as 2*08 to 1 : so that if it requires two hours to cool the cube, a half, or a quarter, or any other propor- tional part of its excess of heat, the other vessel will COOLING. 63 lose the same proportional part of its excess of heat in one hour. 71. It is evident that these different velocities of cooling, are quite independent of the effect that the respective bodies will produce, in warming a given space; for as the cube contains upwards of six times as much water as the other vessel, so it would warm six times as much air, if both vessels were of the same temperature. But if six of the oblong vessels were used, they would heat just the same quantity of air as the cube; but the latter would require rather more than 2^ hours, to do what the oblong vessels would accomplish in one hour, suppo- sing the temperature to be the same in both cases. In the previous example, the temperatures are sup- posed to be different : otherwise the relative ratio of cooling, of the two vessels, would have been as 2^ to 1, instead of 2 to 1 as stated. 72. In estimating the cooling of round pipes, the relative ratio is very easily found ; because the in- verse number of the mass divided hy the superficies^ is exactly equal to the inverse of the diameters. There- fore, supposing the temperature to be alike in all, If the diameter of the pipes be - 1. 2. 3. 4 inches. The ratio of cooling will be - - 4. 2. 1*3. 1 That is, a pipe of 1 inch diameter will cool four times as fast as a pipe of 4 inches diameter; and so on with the other sizes. These ratios, multiplied 64 SIZE OF PIPES. by the excess of heat which the pipes possess above that of the air, will give the relative rate of cooling when their temperatures are different, supposing they are under 2 1 2° of Fahrenheit : but if the tem- peratures are alike in all, the simple ratios given above, will show their relative rate of cooling, with- out multiplying by the temperatures. When the pipes are much above 212°, as, for instance, with the High Pressure system of heating, the ratio of cooling must be calculated by the rules given in the Vlth Chapter. 73. The unequal rate of cooling of the various sizes of pipes, renders it necessary to consider the purpose to which any building is to be applied, that is required to be heated on this plan. If it be desired that the heat shall be retained for a great many hours after the fire is extinguished, then large pipes will be indispensable ; but if the retention of heat be unimportant, then small pipes may be advantageously used. It may be taken as an inva- riable rule, that, in no case, should pipes of greater diameter than 4 inches be used, because, when they are of a larger size than this, the quantity of water they contain is so considerable, that it makes a great difference in the cost of fuel, in consequence of the increased length of time required to heat them. (See art. 156.) For hot-houses, green-houses, con- servatories, and such like buildings, pipes of 4 inches diameter will generally be found the best ; though SIZE OF BOILERS. 65 occasionally, pipes of 3 inches diameter may be used for such purposes, but never any of a smaller size. In churches, dwelling-houses, manufactories, &c. pipes of either 2 or 3 inches diameter will, perhaps, upon the whole, be found the most advantageous; for they will retain their heat sufficiently long for ordinary purposes, and their temperature can be sooner raised, and to more intensity, than larger pipes : and, on this account, a less number of super- ficial feet will suffice to warm a given space. 74. Tn adapting the boiler to a hot water ap- paratus, it is not necessary, as is the case with a steam boiler, to have its capacity exactly propor- tional to that of the total quantity of pipe which is attached to it : on the contrary, it is some- times desirable even to invert this order, and to attach a boiler of small capacity to pipes of large size. It is not, however, meant, in recommending a boiler of small capacity, to propose also that it should be of small superficies; for it is indispen- sable that it should present a large surface to the fire, because, in every case, the larger the surface on which the fire acts, the greater will be the economy in fuel, and, therefore, the greater will be the effi^ct of the apparatus. 75. The sketches of the boilers, figs. 13, 14, 15, 16, 17, & 18, and the section of the circular boiler, fig. 19, are several diflferent forms which present F 66 SHAPE OF BOILERS. various extents of surface in proportion to their capacity. Fig. 13. Fig. 14. Fig. 15. Fig. 16. Fig. 17. Fig. 18. Fig. 19. All except the two first, however, have but a small capacity, relatively to their superficies, com- pared with boilers which are used for steam. There is no advantage whatever gained by using a boiler which contains a large quantity of water; for, as the lower pipe brings in a fresh supply of water, as rapidly as the top pipe carries the hot water, off, the boiler is always kept absolutely full. The only plausible reason which can be assigned for using a boiler of large capacity, is, that as the apparatus then contains more water, it will retain its heat a proportionably longer time. This, though true in fact, is not a sufficient reason for using such boilers: for the same end can be accomplished, SHAPE OF BOILERS. 67 either by using larger pipes, or by having a tank, connected with the apparatus, which can be so contrived, by being enclosed in brick, or wood, or some other non-conductor, as to give off very little of its heat by radiation, and yet to be a reservoir of heat for the pipes after the fire has been extinguished. If this tank communicates with the rest of the apparatus by a stop-cock, the pipes can be made to produce their maximum effect in a much shorter time than if this additional quantity of water had been contained in the boiler; and a more econo- mical and efficient apparatus will be obtained. The circulation will likewise be more rapid from a boiler which contains but a small quantity of water ; because the fire will have greater effect upon it, and will render the water which is contained in it, relatively lighter than that which is in the descending pipe. 76. In proposing the adoption of boilers of small capacity, however, it is necessary to accompany the recommendation with a caution against running into extremes ; for this error has been the cause of the inefficiency of apparatus in many instances. The sketch, fig. 1 8, is an instance of this sort, in which an absurd extreme has occasionally been adopted. The contents of a boiler of this shape, sometimes does not exceed a couple of gallons, even when applied to a very large furnace; and though this boiler presents a large surface to the fire, the space allowed F 2 68 REPULSION OF WATER for the water is so small, that the neutral salts and alkaline earths, deposited by the water which evapo- rates from the apparatus, contracts the water-way, already far too small, and effectually impedes the circulation, and also prevents the full force of the fire from acting on the water. 77. But perhaps the more immediate cause of failure, of this shaped boiler, arises in a different way. The quantity of water which it contains being so very small, and the heat of the fire, there- fore, very intense upon it, a repulsion is caused between the iron and the water, and the latter does not receive the full quantity of heat. This extraor- dinary effect is not hypothetical : it has been proved to exist, by the most satisfactory experiments ; particularly some which were made by the Members of the Franklin Institution of Pennsylvania. The repulsion between heated metals and water, they ascertained to exist, to a certain extent, even at very moderate degrees of heat ; being appreciably different at various temperatures, below the boiling point of water. But, as the temperature rises, the repulsion increases with great rapidity ; so that iron, when red hot, completely repels water, scarcely com- municating to it any heat, except, perhaps, when under considerable pressure. 78. The boiler in question, however, seldom or never reaches the temperature of luminosity, though it is still sufficiently high to make a considerable BY HOT IRON. 69 difference in the heating of the water. Added to this, the form of it prevents the full effect of the heat being communicated to the pipes : for the extreme smallness of the water way, prevents the rapid com- munication between the various parts, and therefore the upright, or flow pipe, receives its principal supply of heat from that portion of the boiler immediately underneath where it is fixed, instead of that equa- ble communication of heat from all parts, which is the ordinary process in boilers of good proportions. There is likewise a probability that steam would form in this boiler, which would still farther interfere with the circulation of the water. But were the water way to be enlarged, all these inconveniences and probable causes of failure would proportionably decrease. 79. Though all these causes of inefficient action may not exist simultaneously, yet they may act at different stages of the working of the apparatus. But they all apply equally to every boiler, in which the rational limits of the surface, relatively to the size, have given place to wild chimeras and fan- ciful notions, not based on sound principles of phi- losophy. 80. It is obvious that the extent of surface which a boiler ought to expose to the fire, should be pro- portional to the quantity of pipe that is required to be heated by it : and it is not difficult to estimate these relative proportions with sufficient accuracy. 70 SURFACE OF BOILERS notwitlistanding the various circumstances which modify the effect. Reckoning the surface which a steam boiler exposes to the fire, at 4 square feet, for each cubic foot of water evaporated per hour ^ ; and calculating the latent heat of steam at 1000°; we shall find that the same extent of boiler surface, which would evaporate a cubic foot of water, of the temperature of 52°, into steam, of which the tension is equal to one atmosphere, would supply the requi- site heat to 232 feet of pipe, 4 inches diameter, when its temperature is to be kept at 140° above that of the surrounding air. The following propor- tions for the surface which a boiler for a hot-water apparatus ought to expose to the fire, will be found useful. Surface of Boiler . ■ n- o • r»- o D v. exposed to the Fire. 4 m. Pipe. 3 in. Pipe. 2 in. Pipe. 31 square feet, will heat 200 feet, or 266 feet, or 400 feet. 5i 300 . . 400 . . 600 7 ...... 400 . . 533 .. 800 8i 500 . . 666 . . 1000 12 700 . . 933 . . 1400 17 1000 . . 1333 . . 2000 81. A small apparatus ought, perhaps, to have rather more surface of boiler, in proportion to the ' The surface of a steam boiler which it is necessary to expose to the action of the fire, in order to evaporate one cubic foot of water per hour, varies from 2 to 10 square feet, according to the rapidity of the draught, and the intensity of the heat of the furnace. When the very small surfaces are used, mechanical means are requisite for blowing the fire. EXPOSED TO THE FIRE. 71 length of pipe, than a larger one ; as the fire is less intense, and burns to less advantage in a small, than in a large furnace. It depends, however, upon a variety of circumstances, whether it will be expe- dient to increase the quantity of pipe, in proportion to the surface of the boiler, beyond what is here stated; for although many causes tend to mo- dify the eifect, the above calculation will be found a good average proportion, under ordinary circum- stances. The effect depends greatly upon the quality of the coal, the height of the chimney, the rapidity of draught, the construction of the furnace, and many other particulars ; but it will always be found more economical, as regards the consumption of fuel, to work with a larger surface of boiler at a moderate heat, than to keep the boiler at its maxi- mum temperature. 82. But beside all these causes that modify the effect, there is another that will greatly alter the proportions which may be employed. The data from which the calculation of the boiler surface is made, assumes the difference to be 1 40° between the temperature of the pipe and the air of the room which is heated ; the pipe being 200°, and the air 60°. But if this difference of temperature be reduced, either by the air in the room being higher, or by the apparatus being worked below its maximum temperature ; then, in either case, a given surface of boiler will suffice for a greater length of pipe. For 72 SURFACE OF BOILERS if the difference of temperature between the water and the air, be only 120°, instead of 140°, the same surface of boiler will supply the requisite degree of heat to ^ more pipe; and if the difference be only 100°, the same boiler will supply above ^ more pipe than the quantity before stated. It will, there- fore, frequently occur in practice, that the quantity of pipe in proportion to a given surface of boiler, may be considerably increased beyond the amount which is given in the preceding Table : because, in forcing houses, for instance, the temperature of the air will always be above 60° ; and in the warming of churches, workhouses, or other large buildings, the temperature of the water will generally be consi- derably below 200° — the pipe not being required to be worked at its greatest intensity — and, therefore, in both these instances, a larger propor- tion of pipe may safely be applied to a given sized boiler. 83. In order to estimate the quantity of surface, which is acted upon by the fire, an allowance must be made for the flues which circulate round the exterior of the boiler. Thus, suppose the boiler, fig. 1 5, to be 30 inches long ; there will be about 8{- square feet of surface exposed to the direct action of the fire : and suppose also there are four exter- nal flues, one on each side, and two on the top of the boiler, each being 1 2 inches wide ; we may reckon that one half the effect is produced by these flues. EXPOSED TO THE FIRE. 73 which would have obtained, had the direct action of the fire been employed on the like extent of sur- face ; therefore the flues will be equal to 5 square feet of surface exposed to the direct action of the fire, making altogether 13f square feet, as the avail- able heating surface of a boiler of this shape and size. This would be sufficient to heat about 800 feet of pipe 4 inches diameter, when the excess of its temperature above that of the surrounding air, is 140°, as before stated. A boiler of the same shape, and 24 inches long, has about 1 1 square feet of sur- face, when calculated by the preceding rule : a boiler 36 inches long, has \Q\ square feet of surface ; and a boiler 42 inches long has 19 square feet of surface; the increase being directly proportional, in the sim- ple ratio, to the length. 84. A circular boiler 30 inches diameter, like fig. 19, with a 9-inch circular flue round the outside, will expose, as nearly as possible, the same extent of sur- face as a boiler 30 inches long, of the shape last de- scribed ; and therefore the one will be as effective as the other. The surface of other sizes of this shaped boiler can be easily calculated ; but instead of vary- ing in the simple ratio of the length or diameter, it will be found to be proportional to the square of the diameter^ so that the proportion of surface increases more rapidly than in the arched boiler. Thus a circular boiler 24 inches diameter, has 8f square 74 SURFACE OF BOILERS. feet of surface exposed to the fire ; a 30-inch has 13f square feet; a 36-inch, 19f square feet; and a 42-inch, 26 1 square feet: the small sizes having less surface, and the large sizes having more, than the arched boilers of the shape of fig. 15. CHAPTER V. On the Construction and Dimensions of Furnaces. 85. Although the construction of the furnace for a hot-water apparatus, is a matter of some import- ance, it is not intended to enter here at any great length into the subject. To investigate the various inventions for furnaces which have been brought forward, would occupy much space ; and such a course of inquiry appears to be unnecessary, because most persons who erect hot-water apparatus have had some experience in the construction of the ordinary descriptions of fire-work, and this, in fact, is all that is needful, or indeed desirable, for fur- naces which are used for this purpose. The in- tense heat that is required for some descriptions of steam-engine furnaces is here unnecessary ; but a moderate heat, economically applied, and the furnace constructed so that the fuel shall burn for several hours without attention is the object to be attained, and which is by no means difficult to accomplish, with a moderate degree of care. 76 CONSTRUCTION OF 86. The difficulties which attend the erection of furnaces for a hot-water apparatus, are comparatively trifling to those required for steam boilers. When a boiler is required to supply pipes for warming a building by steam, its size must be much larger than one for warming the same building with hot water. In the former case the capacity of the boiler must be considerably larger than that of the whole length of pipe : in the latter, its capacity may be half, or a quarter, or a tenth, or even a twentieth of the capacity of the pipes, without causing any diminution of the effect, provided (art. 76) this re- duction in the size of the boiler, be not carried to an extravagant length. 87. In large steam boiler furnaces, in order to permit of the flue extending round the boiler, an extremely brisk fire and rapid draught are required, otherwise the heated and inflamed gases will not be of a sufficiently high temperature to impart heat to the boiler ; but they will, in fact, before completing the circuit of the flues, and reaching the chimney, act as a cold body, and abstract heat from the boiler instead of imparting it. No such difficulty, however, occurs with boilers for hot water apparatus. A very moderate draught will suffice to carry the heated smoke, and inflamed gases, round a boiler of the comparatively limited size which is here required; and they will act as a heating body to a boiler of this kind, when at a temperature which would make FURNACES. 77 it act as a cold body to a steam boiler ; because, in the latter case, the water is seldom of a less tem- perature than 220° to 230°, while, in the former, it is rarely above 180° to 200°. 88. Passing over then, as unnecessary for the present purpose, many ingenious forms which have been given to furnaces, it will be sufficient to describe the simple plan of construction which is most usually adopted. The heat should be confined within the furnace as much as possible, by contracting the farther end of it, at the part called the throat, so as to allow only a small space for the smoke and inflamed gases to pass out. The only entrance for the air should be through the bars of the grate, and the heated gaseous matter will then pass directly upward to the bottom of the boiler, which will act as a reverbatory, and cause a more perfect combustion of the fuel than would otherwise take place. The lightness of the heated gaseous matter causes it to ascend the flue, forcing its passage through the throat of the furnace with a velocity proportional to the smallness of the passage, the vertical height of the chimney, and the levity of the gases, arising from their expansion by the heat of the furnace. 89. In this arrangement, the whole of the air which supports the combustion passes through the fire from below ; and any air admitted at the furnace door, between the fuel and the boiler, reduces the 78 ADMISSION OF AIR. intensity of the heat. The only case where the admission of air above the fuel will be at all advantageous, is when coal which emits a vast quantity of flame is used, and which, therefore, contains a large quantity of hydrogen, and propor- tionably less oxygen, than Newcastle coal. Some of the Staffordshire and Scotch coals are of this description ; and here, a portion of air admitted at the top of the fuel, will promote the more perfect combustion of the gaseous products of the coal. But, even in this case, less heat will be received by the boiler, in a given time, unless the air be warmed before it enters the furnace ; for as air will not support combustion until it attains a temperature of from 900° to 1000°, of Fahrenheit, if a current of cold air passes between the fuel and the boiler, a certain portion of heat is required to raise the temperature of the air, which heat would, otherwise, have been received directly by the boiler. 90. In all ordinary cases, then, the greatest economy, as well as the greatest effect, will be pro- duced by admitting air only through the ash-pit of the furnace ; and the rapidity of combustion of the coal will depend upon the quantity of air admitted through the bars, and upon the velocity of its ad- mission. 91. The quantity of coal which is required to be burnt in each particular furnace, must determine the area of the bars : and as this been ascertained 1 DIMENSIONS OF BARS. 79 experimentally for steam boilers, it is merely neces- sary to reduce it to a standard suitable for a hot water boiler. Supposing the ordinary kind of fur- nace bars to alford about 30 inches of opening for the air, in each square foot of surface — measured as the bars are placed in the furnace, and allowing half-inch openings between the bars, when the bars them- selves are about 1^ inches wide, — then the relative proportions between the area of the bars and the length of pipe should be as follows : — Area of Bars. 4 in. Pipe. 3 in. Pipe. 2 in. Pipe, 75 Square inches will supply 150 feet, or 200 feet, or 300 feet. 100 200 . . 266 . . 400 . . 150 300 . . 400 . . 600 . . 200 400 . . 533 . . 800 . . 250 500 .. 666 . . 1000 . . 300 600 . . 800 . . 1200 . . 400 800 . . 1066 . . 1600 . . 500 1000 . . 1333 . . 2000 . . Thus, suppose there are 600 feet of pipe, 4 inches diameter, in an apparatus ; then the area of the bars should be 300 square inches : so that 13 inches in breadth and 23 inches in length will give the requi- site quantity of surface. But when it is required to obtain the greatest heat in the shortest time, the area of the bars should be increased, so that a larger fire may be produced*. ' The above proportions for the area of the bars may, in many cases, be considerably reduced, particularly in the larger appa- ratus ; because these proportions are calculated to give the maxi- 80 SIZE OF FURNACES. 92. In order to make the fire burn for a lonjr time without attention, the furnace should extend beyond the bars both in length and breadth ; and the coals which are placed on this blank part of the furnace, in consequence of receiving no air from below, will burn very slowly, and will only enter into complete combustion when the coal which lies directly on the bars has burned away. 93. This plan of constructing furnaces is so well known as scarcely to need further description : it may, however, be observed, that the size of this blank, or dumb part of the furnace, should be com- parative to the length of time the fire is required to burn ; being larger or smaller in proportion as the fire is required to burn for a longer or a shorter period. As the maximum effect of the furnace is but seldom required, the register to the ash-pit door, and the damper to the chimney, must be used to regulate the draught, and thus limit the consumption of fuel. 94. The relative sizes of the furnace bars, and of the boiler, which have been stated in this and the preceding chapter, are all given with reference to certain lengths of pipe, which they will respectively heat. But to complete the calculations, it is neces- sary to ascertain the actual amount of heat which mum effect, and in many cases this is never required : a less quantity of coal will, therefore, be used, and, of course, a less area of the bars will be sufficient. SIZE OF FURNACES. 81 a given quantity of pipe will afford, under the various circumstances which occur in the application of it to the warming of buildings of different de- scriptions. Before entering into this inquiry, how- ever, it may be necessary to premise some observa- tions on the general laws of heat. G CHAPTER VI. General Laws of Heat — Radiation and Conduction — Law of Cooling in Air and other Gases — Ratio of Cooling — Law of Cooling by Radiation — Laws of Radiation — Effect of Surface on Radiation — Effect of Colour on Radiation — Capacity of Bodies for Caloric. 95. However various are the methods by which artificial heat is distributed in the warming of build- ings, they are all subject to certain conditions, which constitute the primary laws of heat; and in the present chapter some of these laws, which bear upon the subject before us, will be considered. 96. Heated bodies give off their caloric by two distinct modes, — radiation and conduction. These are governed by different laws ; but the rate of cooling by both modes increases considerably in pro- portion as the heated body is of a greater tempera- ture above the surrounding medium. This variation was long supposed to be exactly proportional to the simple ratio of the excess of heat ; that is to say, supposing any quantity of heat given off in a certain time at a specified difference of temperature, at double that difference, twice the quantity of heat would be given off in the same time. This law was LAWS OF HEAT. 83 originally proposed by Newton in the Principia; and, although rejected as erroneous by some philo- sophers, it was followed by Richmann, Kraft, Dalton, Leslie, and many others, and was usually considered accurate, until the masterly and elaborate experi- ments of M. M. Petit and Dulong proved that, though approximately correct for low temperatures, it becomes extremely inaccurate at the higher de- grees of heat ^ 97. The cooling of a heated body, under ordi- nary circumstances, is evidently the combined effects of radiation and conduction. The conductive power of the air is principally owing to the extreme mo- bility of its particles ; for, otherwise, it is one of the worst conductors we are acquainted with ; so that, when confined in such a manner as to prevent its freedom of motion, it is a most useful non-con- ductor. 98. The proportion which radiation and con- duction bear to each other, has in general been very erroneously estimated. Count Rumford considered the united effect, compared with radiation alone, was as 5 to 3 ; and Franklin supposed it to be as 5 to 2. ' As the present inquiry relates merely to simple heat, the recent important experiments of Nobili and Melloni on radiation by luminous hot bodies — which prove the existence of two distinct kinds of heating rays given off at the same time from the same body — do not affect the question ; as it is only at a tem- perature amounting to luminosity, that these effects occur. g2 84 LAWS OF HEAT. 99. No such general law, however, can be de- duced ; for the relative proportions vary with the temperature, and with the peculiar substance or surface of the heated body. For, while the cooling effect of the air hy conduction is the same on all sub- stances, and in all states of the surface of those sub- stances, — radiation varies materially, according to the nature of the surface. 100. The influence of the air, by its power of conduction, varies also with its elasticity or barome- tric pressure. The greater its elastic force, the greater also is its cooling power, according to the following law : — When the elasticity of the air varies in a geometrical progression, whose ratio is 2, its cool- ing power changes likewise in a geometrical progression, whose ratio is 1*366. 101. The same law holds with all gases, as well as with atmospheric air ; but the ratio of the pro- gression varies for each gas. 102. To show the relative velocities of cooling, at different temperatures, the following table, con- structed from the experiments of Petit and Dulong, is given. The first column shows the excess of temperature^ of the heated body above the sur- * The temperatures in this chapter are all expressed in degrees of the Centigrade thermometer. As the zero of this thermometer is the freezing point of water, and from that to the boiling point of the same fluid is 100°; — in order to find the number of degrees of Fahrenheit's scale, which answers to any given temperature of the Centigrade, multiply the number of degrees of Centigrade by LAWS OF HEAT. 85 rounding air; the second column shows the rate of cooling of a thermometer with a plain bulb ; and the third column gives the rate of cooling when the bulb was covered with silver leaf. The fourth column shows the amount due to the cooling of the air alone ; and by deducting this from the second and third columns respectively, we shall find what is the amount of radiation, under the two different states of surface, noticed at the top of the second and third columns. Excess of Temperature of the Thermometer above that of the Air : Centigrade Scale. Total Velocity of cooling of the naked Bulb. Total Velocity of cooling of Bulb covered with Silver Leaf. Amount of cooling due to Conduction of the Air alone. 260° 24-42 10-96 8-10 240° 21-12 9-82 7-41 220° 17-92 8-59 6-61 200° 15-30 7-57 5-92 180° 13-04 6-57 5-19 160° 10-70 5-59 4-50 140° 8-75 4-61 3-73 120° 6-82 3-80 3-11 100° 5-57 3-06 2-53 80° 4-15 2-32 1-93 60° 2-86 1-60 1-33 40° 1-74 •96 •80 20° •77 •42 •34 10° -37 •19 •14 9, and divide the product by 5 ; add 32 to the quotient thus obtained, and this sum will be the number of degrees of FahreU' heit required. As, however, in the above table, the temperatures given are only the excess, and not the absolute temperatures, the 32° to be added by this rule must be omitted. 86 LAWS OF HEAT. 103. Some very remarkable effects may be per- ceived by an inspection of the above table. It appears that the ratio of heat lost by contact of the air alone, is constant at all temperatures ; that is, whatever is the ratio between 40° and 80°, for in- stance, is also the ratio between 80° and 160°, or between 100° and 200°. This law is expressed by the formula, — v = n. t where t represents the excess of temperature, and n a number which varies with the size of the heated body. In the case represented in the foregoing table w=z 0-00857. 104. Another remarkable law is, that the cooling effect of the air is the same, for the like excess of heat, on all bodies without regard to the particular state or nature of their surface. This was ascertained by Petit and Dulong, in a series of experiments not necessary here to detail, but which abundantly prove the accuracy of the deduction ^ 105. By comparing the second and third columns in the above table, it will be immediately perceived that the loss of heat by radiation (deducting the cooling by conduction of the air given in the fourth column) varies greatly with the nature of the radi- ating surface ; though, whatever be the nature of the ^ Annals of Philosophy, vol. xiii. LAWS OF HEAT. 87 surface, the loss of heat follows the same law in all casesy though in a different ratio, 106. It should be observed that, in this table, the second, third, and fourth columns show the number of degrees of heat which were lost per minute, by the body which was the subject of expe- riment ; and, therefore, these numbers represent the velocity of cooling. 107. When the numbers in the last column are deducted from those in the second and third columns, the difference will show the loss of heat by radiation, for the plain and silvered bulb respect- ively ; the fourth column being the loss by conduc- tion of the air, which is the same for all surfaces. It will immediately be perceived, therefore, that the loss of heat by conduction and by radiation, bear no constant ratio to each other. But, while conduction proceeds by a regular geometrical progression, radiation follows another law, viz. when a body cools in vacuo surrounded by a medium whose temperature is constant, the velocity of cooling, for excess of temperature in arithmetical progression, increases as the terms of a geometrical progression, diminished by a constant quantity. This law is represented by the formula, — \-m.a' {a'—\) where a is a constant quantity for all bodies = 1*0077 ; t the excess of temperature of the radi- ating body ; the temperature of the surrounding 88 LAWS OF HEAT. medium ; and m a coefficient which varies with the size and nature of the radiating body, to be deter- mined for each particular case. It will likewise appear that, when we compare the total cooling of two different surfaces, the law is more rapid at low temperatures, and less rapid at high temperatures, for the body which radiates the least, in comparison with that which radiates with greater power. 108. But the cooling of a body by conduction of the air, differs from the effect of radiation in a remarkable manner in this particular ; — that, while the ratio of loss hy conduction continues the same, for the same excess of temperature, whatever be the absolute temperatures of the air and heated body, — radiation increases in velocity, for like ej?cess of temperature, when the absolute temperatures of the air and heated body increase. The following table shows the law of cooling by radiation, for the same body at different temperatures : Excess of Velocity of Cooling when the suiTounding medium is at Temperature the undermentioned Temperatures. of the Thermometer. 0° 20° 40° 60° 220° 8-81 10-41 11-98 200° 7-40 8-58 10-01 11-64 180° 6-10 704 8-20 9-55 160° 4-89 5-67 6-61 7-68 140° 3-88 4-57 5-32 6-14 120° 3-02 3-56 4-15 4-84 100° 2 30 2-74 3-16 3-68 LAWS OF HEAT. 89 It will be observed in this table, that, when the absolute temperatures of the surrounding medium and radiating body, are increased 20° of Centigrade, the difference between their temperatures continuing the same, the velocity of cooling is multiplied by 1*165, which is the mean of all the ratios in the above table, experimentally determined. 109. The total cooling of a body by radiation and conduction, then, we shall find to be repre- sented, under all circumstances, by this formula, — m. (at — 1) -^n,f The quantities a and h are constant for all bodies and under all circumstances ; the first being = 1-0077 and the latter = 1-233. The coeffi- cient m will depend on the size and nature of the heated surface, as well as upon the nature of the surrounding medium. The coefficient n is inde- pendent of the absolute temperature, as well as of the nature of the surface of the body ; but will vary with the elasticity and nature of the gas in which the body is plunged : t is the excess of temperature of the heated body, and Q the temperature of the surrounding medium. 110. The fact, already adverted to, that the ratio of cooling of those bodies that radiate least, is more rapid at low temperatures, and less rapid at high temperatures, than those bodies that radiate 90 LAWS OF HEAT. most, is perhaps one of the most remarkable of the laws of cooling. It was first deduced experimentally by Petit and Dulong, and it may be mathematically proved from their formulae; but it is unnecessary here to enter into the investigation. It appears, however, that, when the total cooling of two bodies is compared, the law is more rapid at low tempera- tures, for the body which radiates least, and less rapid, for the same body, at high temperatures ; though separately for conduction and for radiation, the law of cooling is, for the former, irrespective of the nature of the body, and for the latter, that all bodies preserve, at every difference of temperature, a constant ratio in their radiating power. 111. To revert to the first table in this chapter. We find the total cooling at 60° and 120° (of Centi- grade), to be, about, as 3 to 7 ; at 60° and 180°, as 3 to 13 ; and at 60° and 240° as 3 to 21 : whereas, according to the old law of Newton, they should have been respectively as 3 to 6 ; as 3 to 9 ; and as 3 to 12. But we find that the deviation in- creases greatly with the increase of temperature, and that when the ea^cess of temperature of the heated body, above the surrounding air, is as high as 240° of Centigrade (432° of Fahrenheit), the real velocity of cooling is nearly double what it would appear to be by the old and inaccurate law, varying, however, with the nature of the surface. 112. But radiant heat is subject to other laws, 1 LAWS OF HEAT. 91 beside those we have yet considered. Rays of heat diverge in straight lines from every part of a heated surface, and likewise from extremely minute depths below the surface of hot bodies, being subject to the laws of refraction the same as light. The intensity of these rays decreases as the square of the distance, and the emission of the rays is greatest in a line perpendicular to the surface. The same law obtains here, also, as with light, — that the eifect of the ray is as the sine of the angle, which it forms with the surface \ This law of the sines, first discovered by Leslie, suggests a practical caution connected with the subject before us, — namely, that the shape of the pipes used to warm a building, is not wholly unimpor- tant ; for, if flat pipes be used, and they be laid hori- zontally, the major part of the radiated heat from the 1 Suppose 2; to be a body radi- ating heat; x y a plane surface, receiving two rays, radiated from z, represented by the dotted lines p, q. Then a, 5, is the sine of the angle, the ray p forms, and c, d, is the sine of the angle, the ray q forms with the receiving surface. The heating effect is greater in — proportion as a 6 is longer than c d: and if the ray proceeded in a straight line, perpendicular to the receiving surface, the effect would be the greatest possible. The number of rays, radiated from any surface, is also found to be greatest in a line perpendicular to the surface of the radiating body. 92 LAWS OF HEAT. upper surface, will be received on the ceiling, and, therefore, will produce but little beneficial effect. The loss sustained in this way will be greater in proportion to the higher temperature of the pipes, for it will be seen by the table at the beginning of this chapter, that the relative proportion which radiation bears to conduction, increases with the temperature : at the ordinary temperature of hot- water pipes, about one-fourth the total cooling is due to radiation. 113. The radiation of heat, we have already seen, is greatly either increased or diminished, according to the nature of the surface of the radiating body. Professor Leslie has given the following as the relative powers of radiation by different substances : Lamp Black 100 Water (by estimate) 100 Writing Paper 98 Rosin 96 Sealing Wax 95 Crown Glass 90 China Ink 88 Ice 85 Red Lead 80 Isinglass 80 Plumbago 75 Thick Film of Oil 59 Film of Jelly . . • 54 Thinner Film of Oil 51 Tarnished Lead 45 Thin Film of Jelly (J of former) . . 38 Tin scratched with Sand-Paper ... 22 Mercury 20 LAWS OF HEAT. 93 Clean Lead 19 Iron, polished 15 Tin Plate 12 Gold, Silver, and Copper 12 Thin Laminae of Gold, Silver, or Cop-l per Leaf, on Glass J 114. As it has been established by the experi- ments of M. M. Nobili and Melloni, as well as by other experimentalists, that the radiating powers of surfaces, for simple heat, are in the inverse order of their conducting powers ; it follows that the above ratios of radiating power, will by no means be proportional to the total cooling of these respective bodies in air. 115. Professor Richmann, in order to ascertain the conducting power of metals, enclosed thermo- meters in hollow metallic vessels, which were heated by being immersed in boiling water, until every part had attained the same temperature. The heated vessels were then exposed to the air, and their times of cooling observed ; the difference in this respect being considered as marking their conducting power. The metals which appeared to have the greatest power of retaining heat, were brass and copper ; then iron and tin ; and lead the least of all. The decrements of temperature in a given time being as follows : Lead ........ 25 Tin 17 Iron 11 Copper and Brass . . . . 10 94 LAWS OF HEAT. The result of this experiment must, however, neces- sarily be inconclusive as regards conduction ; be- cause the rate of cooling, under such circumstances, would, if the bodies were extremely thin, be, in fact, exactly proportional to their radiating powers, which would prove nothing, a priori, as regards conduction. The result would also vary materially with the thickness of the metal. 116. The experiments of Ingenhausz and Dr. Ure, on the same subject, were on a totally different principle, and they vary but little from each other in the results. They coated the ends of rods of different metals with wax, and noted the time required to melt it, when the opposite ends were heated to a uniform temperature. Dr. Ure thus found silver, to be by far the best conductor ; next copper ; and then brass, tin, and wrought iron, nearly equal ; then cast-iron and zinc ; and lead he found by far the worst of all. 117. We might be led to conclude from all that precedes, that those metals which are the worst con- ductors, would be the most proper for vessels or pipes, for radiating heat ; because, we find that the heat lost by contact of the air, is the same for all bodies, while those which radiate most, or are the worst conductors, give out more heat in the same time, than those bodies which radiate least, or are good conductors. Such would be the case if the vessels were infinitely thin ; but as this is not pos- LAWS OF HEAT. 95 sible, the slow conducting power of the metal, op- poses an insuperable obstacle to the rapid cooling of any liquid contained within it, by preventing the exterior surface from reaching so high a tempera- ture, as would that of a more perfectly conducting metal, under similar circumstances; thus preventing the loss of heat, both by contact of the air and by radiation, the effect of both being proportional to the excess of heat of the esterior surface of the heated body. If a leaden vessel were infinitely thin, the liquid contained in it would cool sooner than in a similar vessel of copper, brass, or iron: but the greater the thickness of the metal, the more appa- rent becomes the deviation from this rule ; and, as the vessels for containing water, must always have some considerable thickness, those metals which are the worst conductors, will oppose the greatest resist- ance to the cooling of the contained liquid, although apparently in opposition to the result of the prece- ding experiments. 118. It is difficult on these grounds to account for the effect which lead paint has in preventing the free radiation of caloric, from bodies coated with it ; because, in this case, the lead must be extremely thin, and ought, therefore, to increase the amount of radiation. The effect probably arises from the total change of state which the lead undergoes by its chemical combination with the carbonic acid, in the process of making it into white lead. Practically, 96 LAWS OF HEAT. it is found to have an injurious tendency on the free radiation of heat from most bodies ; varying, how- ever, with their radiating powers. On a good radi- ator, its effect is the most injurious, on a bad one, less so : but its use should be avoided as much as possible, in all cases where the free radiation of heat is the object in view. 119. It is almost universally supposed that colour has a considerable influence on radiant heat, and also upon the absorption of heat — the two effects being similar and equal. Sir H. Davy, by exposing surfaces of various colours to the heat of the sun, proved experimentally {Beddoe's Contributions, p. 44), that the absorbing power of different colours was in this order ; — black, blue, green, red, yellow, and white : black being the best, and white the worst absorbent. In this order then, we should expect to find the radiating powers of different co- lours, and that by painting a body of a dark colour, we should increase its power of radiation. This, however, is not the case. There are the strongest reasons for supposing that the absorption and radia- tion of simple heat ; — that is, heat without light, or heat from bodies below luminosity, — are wholly irre- spective of colour, and depend only upon the state or nature of the surface. Professor Powell considers {Report on Rad, Heat, p. 290), after an elaborate examination of all the phenomena attending the heat received from the sun, that there is no simple LAWS OF HEAT. 97 radiant heat received by us from the sun's rays ; and that the simple radiant heat, which no doubt is initially radiated from the sun, is absorbed by the atmosphere of that luminary, some small portion, perhaps, which escapes, being stopped in the higher regions of our own atmosphere. The experiment of Sir H. Davy, on the absorption and radiation of solar heat, by different colours, is not therefore applicable to the case of simple heat, or such heat as is given out by bodies below luminosity. 120. The Table, art. 113, evidently shows that the radiation of heat, of the intensity used in those experiments, bears no relation to colour. This tem- perature was about 200°, and was, therefore, simple heat. By this it appears, that lamp black, and white paper, are equal in power, while Indian ink is much less, and black lead still lower in the scale ; though, as far as colour only is concerned, these last are nearly the same as lamp black. But Professor Powell has ascertained, {Rep. on Heat, p. 279.) that the radiation and absorption of simple heat, is not affected by colour, but only by the nature of the surface. He found that a thermometer bulb, coated with a paste of chalk, was affected even more than a similar one coated with Indian ink. So, likewise, Scheele found, that if two thermometers filled with alcohol, one red, and the other colourless, were exposed to the sun's rays, the coloured one would H 98 LAWS OF HEAT. rise in temperature much more rapidly than the other ; but if they were both plunged into the same vessel of hot water, they rose equally in equal times. 121. We are fully justified, then, from these and analogous experiments, in drawing the conclusion, that the radiatio7i of simple heat is not influenced by the colour of the heated body. Any difference which appears to obtain in this respect, is, therefore, solely referrible to the nature of the colouring sub- stance. 122. The last of the laws of heat to which we shall allude, is one which is, perhaps, more remark- able than any that have been mentioned. It is that which is called the capacity of bodies for calofic, or, the law of specific heat. Though the principle is simple, the law is intricate ; for it follows no constant ratio with the density, elasticity, or other known properties of matter ; though Dr. Martin considered that the capacity of bodies for heat, was nearly in the inverse order of their conducting powers. 123. The same quantity of heat which will raise the temperature of a pound of water T, will raise the temperature of a pound of oil 2°, or a pound of mercury 23° ; and almost every known substance possesses a capacity for caloric peculiar to itself. In a subsequent chapter, a practical application of this part of the laws of heat will be shown ; but to follow ^t, in an extended manner, would lead to investiga- LAWS OF HEAT. 99 tions not connected with the subject of this treatise, and only such of the laws of heat as are applicable to this inquiry, were purposed to be here inves- tigated. H 2 CHAPTER VIL Experiments on Cooling. J 24. From what has been stated in the preceding chapter, it is evident, that the velocity with which a heated body cools, depends upon various circum- stances ; and experiments are necessary, in order to obtain data for the calculations, which the known laws of heat enable us afterwards to make. 125. No experiments on cooling are extant, that appear to be suitable to the present purpose, ex- cept some that were made by Tredgold, and these are extremely erroneous in the application he has made of them. For he has neglected all considera- tions of the thickness of the body on which he experimented, and has therefore estimated, that the rate of cooling of a thin sheet-iron vessel, containing a heated fluid, is the same only as it would be, were it of any greater thickness. The same error also occurs in his experiments on the cooling of glass; and, consequently, all his conclusions on the disper- ON COOLING. 101 sion of heat, are entirely incorrect. Another source of error lies in his having estimated the quantity of water which the vessels contained, at too large an amount, in order to allow for the specific heat of the vessel. Had the total quantity of heat that the vessel contained, been the object sought, this mode of calculation would have been correct ; but it is not so, when the rate of cooling only, is the element required. The effect of each of these errors, is to make the rate of dispersion appear to be more rapid than the true velocity; and the result is, that in some of his experiments the errors amount to upwards of 16 per cent. 126. To ascertain by experiment the velocity of cooling, for a surface of cast-iron, I used a pipe 30 inches long, 2^ inches diameter internally, and 3 inches diameter externally: the ends were closed, and the bulb of a thermometer was inserted about 3 inches into the water at one end, the tempera- ture being alike in every part of the pipe. The exposed surface of the pipe was 287*244 square inches, and the quantity of water contained in it was 171*875 cubic inches. The rates of cooling were tried with different states of the surface : first, when it was in the usual state of cast-iron pipes, covered with the brown surface of protoxide of iron; next it was varnished black ; and finally, the varnish was scraped off, and the pipe was painted white with two coats of lead paint. The following Table shows 102 EXPERIMENTS the observed time of cooling, corrected and reduced to the same excess of temperature above the circum- ambient air. TABLE of the Cooling of Iron. Temperature of Room 67°. Maximum Temperature of Thermometer 152°. Thermometer Black varnished cooled, Rusty Surface. Surface. Vvhite Surface. Observed Calcu- Observed Calcu- Observed Calcu- from to Time. lated Time. lated Time. lated Time. Time. Time. 152° 150° 2' 30'' 2' 21'' 2' 16" 2' 16" 2' 19" 2' 24" 152 148 5 4 44 4 38 4 36 4 53 4 51 152 146 7 45 7 12 7 28 7 3 7 28 7 22 152 144 10 15 9 44 9 45 9 27 10 13 9 57 152 142 12 45 12 15 12 2 11 54 12 57 12 36 152 140 15 15 14 32 14 32 15 22 15 22 Minutes. The ratios of f Black Varnished Surface . . 1*21 Cooling 1° are <^ Iron Surface 1*25 therefore, ^ White Painted Surface . . . 1*28^ These ratios are in the proportion of 100, 103*3, and 105*7; but as the relative heating effect, is the inverse of the time of cooling, we shall find that 100 feet of varnished pipe, 103^ feet of plain iron pipe, or 105f feet of iron pipe painted white, will each produce an equal effect. ' These ratios of cooling, it will be observed, are for pipes of 3 inches diameter : but the cooling of any other size can be cal- culated from the data here given. ON COOLING. 103 127. Ill these experiments, it might have been expected to find greater differences between the effects of the various states of the surface, than appears really to obtain. The greatest difference only amounts to about 5^ per cent., but it would probably be greater in proportion, with an increased thickness of the coating of paint. 128. To ascertain the effect of glass windows in cooling the air of a room, the following experiments were made, with a vessel as nearly as possible of the same thickness as ordinary window glass. The temperature of the room, in these experiments, was 65° ; the thickness of the glass was "0825 of an inch ; the surface of the vessel measured 34*296 square inches, and it contained 9*794 cubic inches of water. The time in which this vessel cooled, when filled with hot water, is shown as follows : TABLE of the Cooling of Glass. Thermometer cooled, Observed Time of Cooling. Calculated Time of Cooling. Average Rate of the Observed Time of Cooling. from to 150° 150 150 150 140° 130 120 110 6' 40'' 14 15 23 30 34 6' 54" 14 43 23 40 34 1 ^1-176° per mi- nute, at an ex- cess of 65° above the Tem- perature of the [ Air. 129. From the average rate of cooling which is here given, the effect of glass in cooling the air of a 104 EXPERIMENTS room may easily be calculated. As the specific heat of equal volumes of air and water \ is as 1 to 2990, the above average will show that each square foot of glass will cool 1*279 cubic feet of air T per minute, when the temperature of the glass is V above that of the external air. 130. But by this we shall only find the effect of glass in a still atmosphere ; and, therefore, to as- certain the cooling effect of external windows, when exposed to the action of winds, farther experiments are necessary. 131. In some researches of Leslie's, on the cooling power of wind, he used a bright metallic ball filled with hot water, and noted the time of cooling when it was exposed to wind at different velocities. The result he obtained was, that the cooling effect on the ball was very nearly in a direct ratio with the velocity. But it will be obvious, by referring to the experiments of Petit and Dulong, in the preceding chapter, that the relative cooling of heated bodies, when exposed to air moving at different velocities, must depend upon the nature of the surfaces. For while the quantity of heat which is abducted by the air, is proportional to the number of particles of air which pass over the heated body in a given time, the heat that is lost by radiation is not only independent of this effect, but the relative See Art. 139. ON COOLING. 105 proportion of beat lost by radiation, differs for each particular substance. As the bright metal ball that Leslie employed in his experiments, would lose only an extremely small proportion of its heat by radia- tion, it might naturally be concluded that the rate of cooling would be nearly in a direct ratio with the velocity of the air. But with a surface of glass, the result must be very different, because the radiation is then very considerable ; and, therefore, the total cooling will be much slower than the simple ratio of the velocity. For while a surface of glass of the temperature of 120°, and at an excess of 52° above the surrounding medium, loses about two-thirds of its heat by radiation, a bright metallic surface, of the same temperature, will only lose one-eleventh part of its heat by the same cause. 132. In the following experiments it appears that the cooling effect of wind, at different velocities, on a thin surface of glass, is very nearly as the square root of the velocity. In these experiments, the velocity of the air was measured by the revolu- tion of the vanes of a fan ; the temperature of the air was 68° ; the time required to cool the thermo- meter 20° was noted for every different velocity, and the maximum temperature of the thermometer, in each experiment, was 120°. In still air it re- quired 5' 45^' to cool the thermometer this extent ; and the following table shows the time of cooling by air in motion. 106 EXPERIMENTS TABLE of the Cooling of Glass by Wind. Velocity of the Wind, in Miles, per hour. Times of CooUng the Thermometer 20°. From 120° to 100° of Fahrenheit. Observed Time of CooHng. Time, reduced to decimals of a minute. Corrected Time ; being the Inverse of the Square Root of the Velocities ; in decimals of a minute. 3-26 5-18 6'54 8-86 10-90 13-36 17-97 20-45 24-54 27-27 2' 35" 2 10 1 55 1 40 1 30 1 15 1 5 1 55 48 2-58 2-16 1-91 1-66 1-50 1-25 1-08 1-0 -91 •81 2-58 2-04 1-82 1-56 1-41 1-27 1-10 1-03 •94 -88 133. In consequence of the large quantity of glass in buildings used for horticultural purposes, the cooling effect of wind is of considerable import- ance. We see, however, that with an increased velocity, the cooling effect is considerably less in proportion, on glass than on metal : and it will be very much less on window-glass than even what is here stated ; for, as glass is an extremely bad conductor of heat, the increased thickness which windows-glass possesses over that which composes the bulb of a thermometer, will make a material difference in the quantity of heat that is lost by the abduction of the air, as there will be, in this case, a greater difference between the temperature of the ON COOLING. 107 external and the internal surface. The cooling effect of wind is therefore not near so considerable on glass as is generally supposed ; and it will pro- bably be nearly one-half less on window-glass than what is shown by the preceding experiments. CHAPTER VIII. Heat by Combustion — Quantity of Heat from Coal — Specific Heat of Air and Water — Measure of Effect for Heated Iron Pipe — Cooling Power of Glass — Quantity of Pipe required to warm a given space — Quantity of Coal consumed — Time required to heat a Building — Facile Method of Cal- culating the Quantity of Pipe required in any Building. 134. Having in the preceding chapters investigated some of the fundamental laws of heat, we proceed to consider the particular effects practically dedu- cible from them, so far as they relate to the subject of the present inquiry. 135. Very erroneous notions are entertained by many persons, as to the absolute quantity of heat contained in different substances. This subject has already been mentioned ; and, in the present chapter we shall have occasion to apply this law of specific heat in several calculations. 136. Of the effect produced by the decompo- sition of combustible materials by fire, it may also be observed that erroneous notions prevail : for HEAT FROM COALS. 109 the quantity of heat obtainable by the combustion of any substance, is not, as many persons appear to consider, illimitable, but is as fixed and determinate as any other of the laws of heat. The amount of it depends on the chemical composition of the parti- cular substance ; but this, however, is quite inde- pendent of any difference which obtains in the effect, in consequence of the perfection or imperfec- tion of the apparatus in which the combustion is performed. 137. Though every kind of fuel differs in the quantity of heat that it affords, it is unnecessary, in such an inquiry as this, to regard any other than the ordinary description used for purposes similar to that we are now considering. The calculations will therefore be made only with reference to New- castle coal of a good average quality. 138. It is stated by Watt, that 1 lb. of coal will raise the temperature of 45 lbs. of water from 55° to 212°. Rumford states the same quantity of coal will raise 36^2^ lbs. of water from 32° to 212°; and Dr. Black has estimated that 1 lb. weight of coal will make 48 lbs. of water boil, supposing it pre- viously to be at a mean temperature. These quan- tities, when reduced to a common standard, vary but little from each other. Watt's experiment of 45 lbs. of water being heated from 55° to 212°, is equal to 39^: lbs. only, if heated from 32° to 212° : and this nearly agrees with Count Rumford's calcu- 110 SPECIFIC HEAT lation ; at least the variation is not more than might be expected from a slight difference in the quality of the coal. Dr. Black's estimate is as much in excess, over the experiment of Watt, as Rumford's is in defect: we may, therefore, take the average of these three experiments, which will give as a result, that 39 lbs. of water may be heated from 32° to 2 12° by 1 lb. of coal. 139. To ascertain the effect which a certain quan- tity of hot water will produce, in warming the air of a room, there appears to be no better method than that of computing from the specific heat of gases compared with water. 140. Every substance, it has before been ob- served, has its peculiar specific heat. Now, 1 cubic foot of water by losing T of its heat, will raise the temperature of 2990 cubic feet of air\ the like extent of 1° : and by losing 10° of its heat, it will 1 The specific heat of eqval weights of water and air, by the experiments of Berard and Delaroche, is found to be as 1 to '26669: but as the volume, or bulk, of an equal weight of atmo- spheric air is to water, as 827*437 to 1, we shall have '26669 : 1 :: 827*437 = 3102, which is the number of cubic feet of air that has the same specific heat as 1 cubic foot of water. This, however, appears to be rather too high a calculation : for Dr. Apjohn, in a memoir recently published {Rep. Brit. Sci. Assoc. vol. iv.) gives the result of a new and accurate mode of deter- mining the specific heat of permanently elastic fluids, by which he makes the specific heat of atmospheric air '2767, when that of water is represented by unity. Therefore '2767 : 1 !*. 827*437 = 2990, which is the number given in the text. OF AIR AND WATER. Ill raise the temperature of 2990 cubic feet of air 10°, or 29,900 cubic feet 1°, and so on. J 41. In order to know the time it will take to heat a certain quantity of air, any required number of degrees, by means of hot water contained in me- tal pipes, we must calculate the effect from direct experiment ; and, as the radiating and conducting powers of different substances vary considerably, it is necessary that the experiment be made with the same material as the pipes for which we wish to estimate the effect. 142. From the data obtained by experiments on the cooling of iron pipes', it appears that the water contained in a pipe 4 inches diameter, loses '851 of a degree of heat per minute, when the excess of its temperature is 125° above that of the circumambient air. Therefore (by Art. 140), 1 foot in length, of pipe, 4 inches diameter, will heat 222 cubic feet of air 1° per minute, when the difference between the temperature of the pipe and the air is 125°. 143. To calculate the quantity of pipe that will be necessary to warm any particular room or build- ing, and to maintain it at the required temperature, the heat lost by the necessary ventilation, and by the conducting and radiating power of the glass, and of any metallic substances used in the building, must be estimated. 144. The calculations of the quantity of air re- ^ See Experiments on Cooling, Art. 126. 112 LOSS OF HEAT quired for ventilation, and the method of ventilating buildings, are considered in a subsequent chapter. (Chapter XI.) It is unnecessary, therefore, in this place to pursue the subject further than to state, that, in all public buildings, and rooms of dwelling- houses, a quantity of air equal to 3^ cubic feet for each individual the room contains, must be changed per minute, in order to preserve the whole- someness and purity of the atmosphere. 145. The loss of heat in all buildings having any great extent of glass, we shall find to be very consi- derable. It appears by experiment^ that 1 square foot of glass will cool 1*279 cubic feet of air, as many degrees per minute, as the internal tempera- ture of the room exceeds the temperature of the external air : that is, if the difference between the internal and the external temperature of the room be 30°, then 1*279 cubic feet of air will be cooled 30" by each square foot of glass, or, more correctly, as much heat as is equal to this, will be given off by each square foot of glass ; for, in reality, a very much larger quantity of air will be affected by the glass, but it will be cooled to a less extent. The real loss of heat from the room will therefore be what is here stated. 146. But though this effect is only in a still atmos- phere, as intense cold is seldom or never accom- ' Experiments on Cooling, Art. 129. IN BUILDINGS. 113 panied with high winds \ no additional allowance needs be made for this cause, provided we calculate sufficiently low for the external temperature. For the highest winds are generally about March and September: and the average temperature of the former month is 46°, and the latter 59|-°. The greatest diurnal variation of the thermometer is 20° in March, and 18° in September, so that the average temperature of the nights will be 36° in March^ and 50° in September. But we shall find (Art. 152), that when the external atmosphere is at 36°, the quantity of pipe required to warm a building to 65°, is only about one-half of what would be necessary were the external air at 10° : therefore, if we cal- culate that the external temperature will be 10°, when we estimate the quantity of pipe required to warm a building which is to be used during the night, and that it will be 25° or 26°, externally, in the case of such buildings as are only wanted to ^ That intense cold is rarely accompanied by high winds, is matter of common experience. The obliquity of the sun's rays on the higher latitudes of the Northern hemisphere, when near the time of the winter solstice, prevents the atmosphere of those places which are distant from the Tropics from receiving any considerable quantity of heat ; and, therefore, the air being all of nearly equal density, there is but little tendency to aerial currents in the lower strata. ^ These temperatures are for the neighbourhood of London. In March, 1837, the night temperature, obtained by a register thermometer, only averaged 31*1°, which is nearly 5° lower than has been known for many years. I 114 LOSS OF HEAT be warmed during the day, the required heat can then be maintained, even during the time of high winds 147. But in such situations as are very much exposed to high winds, it will be prudent to calcu- late the external temperature from zero, or even below that, according to circumstances; and, in very warm and sheltered situations, a less range in the temperature will be sufficient: a local know- ledge of the situation will therefore be necessary to guide the judgment in particular cases. 148. The difference between the cooling effect of glass which is glazed in squares, and that which is lapped, is very trifling in those buildings where the air contains much moisture. This is the case in hot- houses, where the plants are constantly steamed, and therefore, for such buildings, no farther allowance should be made on this account, for loss of heat^ ^ By reckoning the external air at the above temperatures, the wind may have a velocity of from 20 to 30 miles an hour, without producing any diminution of the internal temperature ; for it is probable that the cooling effect of wind on window glass, is not above one half as much as appears by the experiments. Art. 132. ^ The calculations of the specific heat of air, given in the note, Art. 140, are only for dry air. If the temperature be at 60°, and the air saturated with moisture, then the same quantity of heat will only raise the temperature of 2967 cubic feet of this saturated air any given number of degrees, which would have raised 2990 cubic feet of dry air to the like temperature. This 2967 cubic feet of saturated air will contain 67 cubic inches of water ; and this quantity of water will absorb as much heat during its conver- sion into vapour, as would raise the temperature of 115,922 cubic 12 IN BUILDINGS. 115 But in skylights of dwelling-houses, in consequence of the greater dryness of the atmosphere, the heated air will escape through the laps of the glass in greater quantity, in proportion as less vapour is con- densed on the surface. The height of the skylight will also make a considerable difference in the velocity of the escape of air through the laps, as it depends upon the same principles which have been explained (Art. 33), as governing the motion of water ; the increased velocity being relatively as the height and the difference of temperature be- tween the internal and external air. 149. In making an estimate of the quantity of glass contained in any particular building, the extent of surface of the wood work must be carefully ex- cluded from the calculation. This is particularly necessary in buildings used for horticultural pur- poses, where, from the smallness of the panes, the wood-work occupies a considerable space. The readiest way of calculating, and sufficiently accurate for ordinary purposes, is to take the square surface feet of air 1°. This is equal to the entire heat that 46 feet of pipe, 4 inches diameter, will give off in ten minutes, when its temperature is 140° above that of the air. The glass will, how- ever, cool much less of this saturated air, than of dry air, for the mixture of air and vapour has greater specific heat than dry air. With lapped glass the loss of heat will be less with saturated than with dry air, because the vapour when condensed upon the glass, will run down and nearly fill up the crevices between the laps, and effectually prevent the escape of the air, and thereby avoid the loss of heat. I 2 116 QUANTITY OF PIPE of the sashes, and then deduct one-eighth of the amount for the wood-work. In the generality of horticultural buildings, the wood-work fully amounts to this quantity : but in some expensively finished conservatories, &c., it is considerably less, and there- fore the allowance must be made accordingly. When the frames and sashes are made of metal, the radia- tion of heat will be quite as much, from the frame as from the glass ; therefore, in such cases, no deduc- tion must be made. 150. Some loss of heat will likewise arise from imperfect fitting of doors and windows. In these cases the circumstances vary very considerably ; but in the majority of instances, no allowance is neces- sary for these sources of loss of heat, the external temperature of the air having been reckoned suffi- ciently low to supersede the necessity of any farther deduction. 151. From the preceding calculations, the follow- ing corollary may be drawn : — the quantity of air to be warmed "per minute, in habitable rooms and public buildings, must be 3^ cubic feet for each person the room contains, and 1^ cubic feet for each square foot of glass ; and for conservatories, forcing houses, and other buildings of this description, the quantity of air to be warmed jter minute, must be \\ cubic feet for each square foot of glass which the building contains. When the quantity of air re- quired to be heated, has been thus ascertained, the FOR WARMING BUILDINGS. 117 length of pipe which will be necessary, may be found by the following Rule: — Multiply 125 by the difference between the temperature at which the room is purposed to be kept, when at its maximum, and the temperature of the external air ; and divide this product by the difference between the temperature of the pipes, and the proposed temperature of the room : then, the quotient thus obtained, when multiplied by the num- ber of cubic feet of air to be warmed per minute, and this product divided by 222, will give the number of feet in length, of pipe 4 inches diameter, which will produce the desired effect.^ When the pipes which are to be used, are 3 inches diameter, then the number of feet of 4-inch pipe, obtained by this rule, must be multiplied by 1*33, which will give the length of 3-inch pipe : or to obtain the quantity of 2-inch pipe, the length of ' Let p be the temperature of the pipe, and t the temperature 125 the room" is required to be kept at ; then = ^c, which will represent the number of feet of pipe that will warm 222 cubic feet of air 1° per minute, when p — t is different to the proportions given in art. 142. If d represents the difference between the internal and the external temperature of the room, and c the number of cubic feet of air which are to be warmed per minute, d.c then X . = F, will be the number of feet of pipe 4 inches diameter, which will warm any quantity of air per minute, according to the calculations art. 142. The rule given in the text has been arranged in such a man- ner, that it may be worked without decimals. 118 QUANTITY OF PIPE pipe 4 inches diameter, obtained by the rule, must be multiplied by 2 ; the length required of 3-inch pipe, being one-third more than 4-inch, and the length of 2-inch pipe being double that of the 4-inch, when the temperatures are the same in all. 152. By the following table, however, even the simple calculations given in this rule may be dis- pensed with. The table shows the quantity of pipe 4 inches diameter, which is required to heat 1000 cubic feet of air jier minute^ any number of degrees. The temperature of the pipes is assumed to be 200"" of Fahrenheit ; this being the most usual tempera- ture at which they can be easily maintained. But according to the length of pipe which is heated by one boiler, the temperature will sometimes be greater and sometimes less than this estimate, the tempera- ture of the water being generally higher when only a small quantity of pipe is used. When the quantity of air to be warmed 'per minute is greater or less than 1000 cubic feet, the proper quantity of pipe will be found, by multiplying the length given in the table, by the number of cubic feet of air to be warmed per minute^ and dividing that product by 1000. FOR WARMING BUILDINGS. 119 TABLE of the Quantity of Pipe, 4 inches diameter, which will heat 1000 Cubic Feet of Air per minute, any required Number of Degrees : the Temperature of the Pipe being 200° Fahrenheit. Temperature of external Temperature at which the room is required to t e kept. Fahrenheit's Scale. 45° 50° 55° 60° 65° 70° 75" 80° 85° 90° 10° 126 150 174 200 229 259 292 328 367 409 12° 119 142 166 192 220 251 283 318 357 399 14° 112 135 159 184 212 242 274 309 347 388 16^ 105 127 151 176 204 233 265 300 337 378 18° 98 120 143 168 195 225 256 290 328 368 20° 91 112 135 160 187 216 247 28] 318 358 22° 83 105 128 152 179 207 238 271 308 347 24° 76 97 120 144 170 199 229 262 298 337 26° 69 90 112 136 162 190 220 253 288 327 28° 61 82 104 128 154 181 211 243 279 317 30° 54 75 97 120 145 173 202 234 269 307 Freezing? q.^O point 5 4 7 67 89 112 137 164 193 225 259 296 34° 40 60 81 104 129 155 184 215 249 286 36° 32 52 73 96 120 147 175 206 239 276 38° 25 45 66 88 112 138 166 196 230 266 40° 18 37 58 80 104 129 157 187 220 255 42° 10 30 50 72 95 121 148 178 210 245 44° 3 22 42 64 87 112 139 168 200 235 46° 15 34 56 79 103 130 159 190 225 48° 7 27 48 70 95 121 150 181 214 50° 19 40 62 86 112 140 171 204 52° 11 32 54 77 103 131 161 194 To ascertain by the above 4;able, the quantity of pipe which will heat 1000 cubic feet of air per minute ; — find, in the first column, the temperature corresponding to that of the external air, and in one of the other columns find the temperature of the room : then, in this latter column, and on the line which corres- ponds with the external temperature, the required number of feet of pipe will be found. 153. If tbe buildiDOf which it is clesiD:ned to warm, is required to be used only during the day, the air, in this part of the country at least, is 120 QUANTITY OF COAL scarcely likely to be below 25° ; but if, — as for a forcing-house, for instance, — it is required to be warmed both day and night, then, perhaps, 1 0° will not be too low to calculate from, or 22° below freez- ing. Suppose, now, a forcing-house has to be kept at 75° in the coldest weather, — which we will sup- pose to be 10° of Fahrenheit, — then by the Table we find, under the column 75°, and on the line with 10° for external temperature, the quantity 292, which is the number of feet in length, of pipe 4 inches diameter, that are required to heat 1000 cubic feet of air per minute, the proposed number of degrees. Any other difference of temperature may be found in the same way. 154. The quantity of coal necessary to supply any determinate length of pipe, is easily ascertained from the data given in Art. 138. After the water in the pipes is heated to its maximum, the quantity of coal consumed is, obviously, just what is required to supply the heat given off from the pipes. Now, by Art. 126 we find, that when pipes, four inches diameter, are 1 46*8° hotter than the air of the room, the water contained in them loses exactly 1° per minute of its heat. By Art. 138 we find that lib. of coal will raise the temperature of 39 lbs. of water 180°; therefore, as 100 feet in length of 4-inch pipe contains exactly 544 lbs. of water, it will require 13*9 lbs. of coal to raise the temperature of this quantity of water 180°. If, therefore, the water loses r of heat per minute, or 60° per hour, this FOR WARMING BUILDINGS. 121 quantity of coal will supply 100 feet in length of pipe, for three hours, if its temperature continues constant with regard to the air of the room. On this principle the following Table has been con- structed. The temperature of the pipe is assumed to be 200° : then, knowing the temperature of the room, if we take the difference between the tem- perature of the pipe and that of the room, — by looking in the Table for the corresponding tempera- ture, we shall find under it the number of pounds weight of coal which will be required per hour, for every 100 feet in length of pipe, in order to maintain the stated temperature. Thus, suppose the pipe to be 4 inches diameter, and its tempera- ture 200°, while the room is at 75° ; then, under the column headed 125°, (which is the difference be- tween these two temperatures), we find 3*9 lbs. as the quantity required per hour for every 100 feet of pipCc The quantities stated in the Table are given in pounds and tenths of a pound. TABLE of the Quantity of Coal used per Hour, to heat 100 Feet in length of Pipe of different Sizes. Diameter of Pipe, Difference between the Temperature of the Pipe and the Room, in Degrees of Fahrenheit. in Inches. 150 145 140 135 130 125 120 115 110 105 100 95 90 85 80 4 4-7 45 44 42 41 3-9 3-7 36 3-4 3-2 31 2-9 2-8 2-6 2-5 3 3-5 3-4 33 31 30 29 2-8 2-7 2-5 2-4 2-3 2-2 21 20 1-8 2 23 2-2 2-2 21 20 19 1-8 1-8 1-7 16 1-5 1-4 1-4 1-3 1-2 1 11 M 10 10 •9 •9 •9 •8 ■8 •7 •7 •7 •6 •6 122 TIME REQUIRED 155. It should be here observed, that an appa- ratus will not always consume the same quantity of coal : in fact, it will but seldom require so much as the Table shows, because that is the calculation for the maximum effect. Suppose the quantity of pipe in a room has been accurately calculated, in order to maintain the temperature at 75° when the ex- ternal air is at 30° ; the consumption of coal, for pipes of 4 inches diameter, will then be 3*9 lbs. per hour for every 100 feet of pipe. But should the external temperature now rise to 40°, 77 feet of pipe would produce the same effect as 100 feet would in the former case : therefore, the pipe must be heated to a lower temperature, and only 3 lbs. of coal would be used, instead of 3*9 lbs. As much coal, there- fore, as would supply 77 feet of pipe at the maxi- mum temperature, would suffice for 100 feet at this reduced temperature. The quantity of fuel which is consumed will, therefore, be continually subject to variation, as it will alter with the temperature of the external atmosphere : and in general, the average quantity of coal required, will be about one-third less than the amount given in the Table. 156. It may not be amiss to estimate the length of time which will be necessary to heat a building with pipes of different sizes. This will, of course, depend upon many circumstances : nevertheless, an approximation may be made to the average time required. Suppose the pipe is to be heated to the FOR WARMING BUILDINGS 123 temperature of 200°, the water being at 40° before lighting the fire ; then the maximum temperature of the building will be attained with 4-inch Pipes, in about 4j hours 3-inch Pipes, in about 3j hours 2-inch Pipes, in about 2^ hours. But if a larger quantity of coal than that given by the Table be used ; if the surface of the boiler be much increased in proportion to the length of pipe ; if the quantity of pipe used be excessive ; or the temperature of the external air is higher than the estimated amount ; then, in each of these cases, the time required for heating will be less. But if, on the contrary, the required temperature be not attained in the time given above, then, either too small a quantity of pipe, too small a surface of boiler, or too small a quantity of coal has been used. 157. It should, however, be observed, that although the mammum temperature will not be reached, at an average, in less time than is above stated ; still, the required temperature will very often not take longer than half or two-thirds of this time, to be attained : because the quantity of pipe being always apportioned to meet the case of extreme cold, when the external temperature is above that extreme limit, the pipe, by being superabundant, will warm the same space in a shorter time. 124 RULE FOR CALCULATING 158. Various circumstances may, however, inter- fere to diminish the effect of the apparatus ; such, for instance, as damp walls, — particularly if the building is new — excess of ventilation, &c. The effect of damp walls in reducing the apparent power of an apparatus is very considerable, in consequence of the great quantity of heat which is necessary to evaporate the moisture. For it will require as much heat to vaporise one gallon of water from the walls of a building, as would raise the temperature of 47,840 cubic feet of air 10°. The true power of an apparatus can, therefore, never be ascertained, unless the building be perfectly dry. The same cause, though in a much less degree, becomes operative in buildings which are only occasionally warmed ; and a longer time will always be necessary to heat such places, than those that are in constant use. 159. For estimating the quantity of pipe which is required to warm any building, rules of a much more facile character, though, at the same time, much more loose and inaccurate than those which have been already given, may easily be constructed ; but they will answer sufficiently well in many com- mon cases. Thus, in churches and very large public rooms, which have only about an average number of doors and windows, and moderate ventilation, by taking the cubic measurement of the room, and dividing the number thus obtained by 200, the quotient will be the number of feet in lengthy of pipe THE QUANTITY OF PIPE. 125 4 inches diameter, which will be required to obtain a temperature of about 55° to 58°. For smaller rooms, dwelling-houses, &c. the cubic measurement should be divided by 150, which will give the num- ber of feet of 4-inch pipe. For greenhouses, con- servatories, and such like buildings, where the temperature is required to be kept at about 60°, dividing the cubic measurement of the building by 30, will give the required quantity of pipe ; and for forcing-houses, where it is desired to keep the tem- perature at 70° to 75°, we must divide the cubic measurement of the house by 20 ; but if the tem- perature be required as high as 75° to 80°, then we must divide by 18, to obtain the number of feet of 4-inch pipe. If the pipes are to be 3 inches diameter, then we must add one-third to the quantity thus obtained ; and if 2-inch pipes are to be used, we must take double the length of 4-inch pipe. 160. The quantity of pipe estimated in this way will only suit for such places as are built quite on the usual plan ; but for others, — and indeed in all cases where it can be done, — the method given in the former part of this chapter should be employed. (Art. 151 and 152.) 161. It should here be mentioned, that the cal- culations for the quantity of pipe required for horti- cultural buildings, have been made with regard to the most economical mode of effecting the desired object. Some of the most successful horticulturists. 126 HEAT IN FORCING HOUSES. however, have adopted the plan of using a much stronger heat in their forcing-houses, and allowing, at the same time, a much greater degree of ventila- tion than usual. This plan is stated to produce a finer fruitage ; but it will only be obtained at an increased cost in the apparatus, and by a larger expenditure of fuel. Where economy is not required, it may, perhaps, be desirable to adopt this plan ; and then the quantity of pipe which is used, must be proportionally increased above the estimates which are given in this chapter. CHAPTER IX, Various Modifications of the Hot-water Apparatus — Kewley*s Syphon Principle — The High Pressure System — Eckstein and Busby's Circulator or Rotary Float, &c. 162. Under the common and generic term of "hot- water apparatus," various plans have been brought forward by different inventors, which, though essen- tially different in some of their features from those that have been already described, are, nevertheless, merely modifications of the general principles that have been explained. In the present chapter, some of these peculiar modifications of the invention will be investigated : and it will appear, that the original principles of all are the same, but that other of the fundamental laws of Nature are here brought into action, conjointly with those that we have already examined, and give rise to an apparent diversity of operation. 163. The first notable invention of this sort 128 SYPHON PRINCIPLE. which shall be mentioned, is Kewley's syphon prin- ciple. The sketch, fig. Fig. 20. 20, shows this apparatus in its simplest form. The boiler is open at the top, and the two pipes dip into the water ; the pipe a descending only a very short distance below the surface, and the pipe b reaching nearly to the bottom of the boiler. A small flexible metal pipe, a;, is attached to the highest part of the pipes. To this an air pump is connected, and the air in the pipes being exhausted by this means, the atmos- pheric pressure forces the water up the pipes and fills them completely. This avoids the necessity of having a reservoir of water higher than the top of the boiler; for it is well known, that the usual atmospheric pressure is capable of raising a column of water in a vacuum, to about 30 feet in height, varying, however, with the degree of pressure shown by the barometer. 164. The water in the longer pipe, B, will acquire a preponderance of weight over that in the pipe A, even if it be at first of an equal temperature and density; because the pipe b only receives the particles of hot water which rise immediately under its base, while the other receives the heat from all parts of the bottom as well as the sides of the THE SYPHON PRINCIPLE. 129 boiler ; the water on the top being hotter than that at the bottom. But as soon as the water circulates through the pipes, it parts with its heat, and the whole length of the pipe b will then be colder than the pipe a, and the water will descend through b with greater force. 165. In consequence of the long pipe b being surrounded by the hot water in the boiler, the water, while descending through it, receives a small portion of heat, which lessens the difference of tem- perature of the two pipes, and reduces the velocity of the circulation. It appears probable, therefore, that additional velocity of circulation would be gained by placing the descending pipe, b, outside the boiler, and attaching it to the side in the same manner as the return pipe in fig. 5. The principal inconvenience attending this would be the difficulty of stopping the ends of the two pipes, a and b, which is now done by a simple contrivance of two plates screwed moveably to their base. This com- pletely stops the water when necessary, — the ends of the pipes being turned true to the plates, to make them water tight, — and by reversing the action of the pump, attached to the pipe ^, the soundness of the joints can then be ascertained. A leaky joint is difficult of detection by any other means, as there is no emission of water from it in the usual way ; and as the only immediate consequence of a leaky joint is the immission of air, it is not observable except K 130 THE SYPHON PRINCIPLE. by its stopping the circulation of the water, which occurs, by the air accumulating and cutting off the connection of the water between the two pipes. 166. If this plan of having the return pipe placed outside the boiler were found to increase the motive power of the apparatus, an advantage would be gained in all those cases where the pipes are required to pass under a doorway ; because, in all such cases, the boiler must be set much lower beneath the level of the floor, in the same manner, and for the same reasons, which have already been explained with regard to the common hot-water apparatus. But by increasing the motive power, a less height would be sufficient; and it would therefore prevent the inconvenience sometimes found to attend this par- ticular form of the apparatus, arising from the great depth the furnace is required to be sunk beneath the level of the pipes, in consequence of the very large size of the boiler which is generally used. 167. A singular fact is connected with this invention, which deserves notice, because it arises from a philosophical principle, which, in some other instances, has been applied in a most useful manner ; though, with this invention, it is rather disad- vantageous than otherwise. It has already been stated, that the height to which the water will rise in a vertical column, by the atmospheric pressure, is about 30 feet above the boiler. Supposing this to be the extreme limit to which the water will ascend, THE SYPHON PRINCIPLE. J31 if the pipe be elongated in the least above this, a vacuum will be formed, similar to that at the top of a barometer, and the water at the top of the pipe will, in this case, be without any 'pressure. But if, instead of 30 feet, the pipe be continued upwards only 15 feet, then the pressure on the water, in the upper part of the pipe, will be 1\ lbs. on the square inch, — or half the usual atmospheric pressure ; — and so on for other heights. Now, the boiling point of all liquids varies with the pressure. Water boils at 212°, under the mean pressure of 15 lbs. per square inch; but by reducing the pressure, it boils at a lower temperature; so that, at half the mean pressure of the atmosphere, it boils at about 186°. Suppose now that the pipes just described, rise 30 feet above the boiler, the w^ater at the top will boil at the temperature of 161°, and will form steam in the upper part of the pipe ; and this, by its great expansion, will force the water down and overflow the boiler, or the supply cistern. For at the ordinary pressure of the atmosphere, steam occupies about 1700 times as much space as the water from which it is formed, and still more at a diminished pressure ; its expansion being inversely as the pressure. When the pipes rise to other heights above the boiler than that described above, the boiling points will be as follows, — at 5 feet high, the boiling point will be 203° 10 195° 15 186° K 2 132 THE SYPHON PRINCIPLE. 20 feet high, the boiling point will be 178° 25 169° 30 161° therefore the water in the boiler must always be kept below these temperatures, according to the height to which the pipes ascend \ 168. This peculiarity, which applies only to pipes on the syphon principle, is more a philosophical fact than a practical difficulty ; for the water can gene- rally be kept at a temperature sufficiently low for any ordinary height that is required. And, in fact, the boiling point will generally be higher than the temperatures here stated ; because a small portion of air always remains in the pipes, which increases the pressure on the water, and makes the boiling point higher than the calculated amount. 169. This form of the apparatus answers the intended purpose extremely well, and has been ^ These calculations are made by Wollaston's rule for his thermometric barometer. But this rule, although accurate at moderately small differences of pressure, is undoubtedly erroneous at considerable reductions of pressure. Professor Robison esti- mates the boiling point of water, in vacuo, at only 88°, instead of 161° which Wollaston's rule shows ; and it is probable that the relative proportion between the pressure and the boiling point is in a logarithmic ratio, instead of the common arithmetical propor- tion of Wollaston's rule. This, in fact, is found to be the case at temperatures above 212°. But it is probable that, in the present case, Wollaston's rule will give a more accurate result than the other ; because, as the vacuum in the pipes cannot be at all perfect, the boiling points will be much higher than the calculated temperature ; perhaps even higher than stated in the text. THE HIGH PRESSURE SYSTEM. 133 extensively applied in practice : and it exhibits not only a considerable knowledge of the principles of science, but also great ingenuity in their application. 170. The next invention which we shall consider, is, the High Pressure hot-water apparatus. This apparatus consists of a coil of small iron pipe, built into a furnace, the pipe being carried from the upper part of the coil, and continued round the room or building which is to be warmed, forming a con- tinuous pipe when again joined to the bottom of the coil. The diameter of this pipe is one inch exter- nally, and half an inch internally. A large pipe, of about 2-i- inches diameter, is connected, either hori- zontally or vertically, with the small pipe, and is placed at the highest point of the apparatus. This large pipe, which is called " the expansion pipe," has an opening near to its lower extremity, by which the apparatus is filled with water, the aperture being afterwards secured by a strong screw ; but the ex- pansion pipe itself cannot be filled higher than the opening just named. After the water is introduced, the screws are all securely fastened, and the appa- ratus becomes completely hermetically sealed. The expansion pipe, which is thus left empty, is calcu- lated to hold about -~ as much water as the whole of the small pipes ; this being necessary in order to allow for the expansion that takes place in the volume of the water when heated, and which, other- wise, would inevitably burst the pipes, however 134 THE HIGH PRESSURE SYSTEM. strong they might be. For the expansive force of water is almost irrepressible, in consequence of its possessing but a very small degree of elasticity ; and the increase which takes place in its volume, by raising the temperature from 39° (the point of greatest condensation) to 212, is equal to about ^-V part of its bulk, and at higher temperatures the expansion proceeds still more rapidly \ 171. The temperature of these pipes, when thus arranged, can be raised to a very great extent ; for being completely closed, and all communication cut off from the atmosphere, the heat is not limited, as usual, to the point of 212°, because the steam which is formed is prevented from escaping, as it does in the common form of hot-water apparatus. The most important consideration respecting it, however, is the question as to its safety ; for most persons are aware that steam, when confined beyond a certain point of tension, becomes extremely dangerous ; and in this apparatus the boundary of what has hitherto been used in other cases is very far exceeded. 172. On the first introduction of this plan, it was usual to make the coil consist of one-fourth part of the total quantity of pipe which was used in the ap- paratus ; and it was considered that when this pro- portion was observed, the heat of the pipes could not be raised so high as to endanger them by bursting. ' See Table IV. THE HIGH PRESSURE SYSTEM. 135 But in practice this has not always proved a preven- tive to accident, even when the proportion which the coil bears to the radiating surface is much smaller than is here mentioned, 173. The average temperature of these pipes is stated to be generally about 350° of Fahrenheit. But, a most material difference of temperature occurs in the several parts of the apparatus ; the difference, amounting sometimes to as much as 200° or 300°. This arises from the great resistance which the water meets with, in consequence of the extremely small size of the pipes, and also from the great number of bends, or angles, that of necessity occur, in order to accumulate a sufficient quantity of pipe. In these an- gles, the bore of the pipe, already extremely small, is still farther reduced, which causes the water to flow so very slowly, that a gre^it portion of its heat is given out, long before it has circulated round the building which is to be warmed. The temperature of the coil, however, is what we must ascertain, if we wish to know the pressure this apparatus has to sustain, and thence to judge of its safety : for by a funda- mental law of hydrostatics, whatever is the greatest amount of pressure on any part of the apparatus, must also be the pressure on every other part. 174. Now the temperature of this apparatus is found to vary, not only with the intensity of the heat of the furnace, but also with the proportion which the surface of the coil bears to the surface of 136 THE HIGH PRESSURE SYSTEM. the pipe which radiates the heat. In some appa- ratus, if that part of the pipe which is immediately above the furnace be filed bright, the iron will be- come of a straw colour, which proves the tempera- ture to be about ^ 450°. In other instances it will become purple, which shows the temperature to be about 530°; while, in some cases, it will become of a full blue colour, which proves that the temperature is then 560°. By this means the pressure on the pipes may be known ; for as there is always steam in some part of the apparatus, the pressure may be calculated as soon as the temperature is ascertained. By referring to Table I. we shall find that a tempe- rature of 450° produces a pressure of 420 lbs. per square inch, while a temperature of 530° makes the pressure 900 lbs.; and when it reaches 560°, the pressure is then 1150 lbs. per square inch. 175. Those who are acquainted with the working of steam engines, are aware that a pressure of 45 to 48 lbs. per square inch is considered as the maxi- mum for high pressure boilers : but we see that in this apparatus the pressure varies from ten times to twenty-four times that amount. And it will also be borne in mind, that, in consequence of the extremely small quantity of water used in these pipes, the slightest increase in the heat of the furnace will cause an immediate increase in the pressure on the See Table VI. THE HIGH PRESSURE SYSTEM. 137 whole apparatus. For it appears, by a reference to the Table last mentioned, that if the temperature of the pipes be increased 50° above the amount before stated, the pressure will be raised to 1800 lbs. per square inch ; and by increasing the temperature 40° more, the pressure will be immediately raised to 2500 lbs. per square inch; so that any accidental circumstance, which causes the furnace to burn more briskly than usual, may, at any moment, in- crease the pressure to an immense amount. 176. The pipes which are used for this apparatus are stated to be proved with a pressure of 2800 lbs. per square inch \ This is very probable : for as wrought iron, of the best quality, requires a longitu- dinal strain of 55,419 lbs. to break a bar one inch square ; so the force necessary to break a wrought iron pipe, of one-inch diameter externally, and half- an-inch diameter internally, would be 13,852 lbs., which is equal to 8822 lbs. per square inch on the internal diameter. But, on account of the expan- sive force of the water and steam being transverse to the grain of the iron, and, also, in consequence of the welded joint of the pipe not being so strong as the solid metal, these pipes will not bear any thing like the calculated amount of pressure. It is evi- dent, however, that no ordinary force can burst them ; * As pipes are always proved when they are cold, this does not at all show the strain they will bear when heated. On this subject see the following note. 138 THE HIGH PRESSURE SYSTEM. but as this casualty does sometimes occur, this great strength of the materials proves the impossibility of regulating the temperature in hermetically sealed pipes, so as to keep the expansive force of the steam within even this immense limit. 177. Although this description of apparatus has been erected by many different individuals, possess- ing various degrees of mechanical knowledge, and severally performing their work with different de- grees of excellence, much uniformity appears in the result, in those cases where failure has occurred. From a comparison of a number of cases where acci- dents have happened to apparatus erected on this system, more than one-half have arisen from the bursting of the coil, notwithstanding the increased size of the expansion pipe renders this apparently the weakest part of the apparatus ; the relative strength of pipes, with the same thickness of metal, being inversely as their diameters. 178. The cause of the explosions occurring prin- cipally in the coil, is owing to the iron becoming weaker in proportion as its temperature is raised ; so that, as the pressure increases, the iron decreases in strength to resist the strain \ Another circum- ' The temperature of maximum strength for cast iron has been estimated at about 300° ; but the " Committee on the Explosion of Steam Boilers," appointed by the Franklin Institution, con- sider that the maximum for wrought iron is somewhat higher. After the temperature of maximum strength is once passed, the decrease in the strength of wrought iron is very rapid : at a red THE HIGH PRESSURE SYSTEM. 139 stance also tends to produce the same elfect. It is found, on breaking one of these pipes after it has been used for some time in or near the fire, that the iron has lost its fibrous texture, and that it presents a crystallized appearance, similar to what is known as " cold short iron." This singular change in the texture of iron has been noticed in other instances. Mr. Lowe {Brit. Sci Rep. 1834), has found that wrought iron at a red heat, exposed to the steam of water for a considerable time, becomes crystallized ; and in many other instances also, even without the presence of steam, the same effect has been ob- served. It is not easy to account for this pheno- menon on any of the known chemical properties and habitudes of iron ; but, whatever may be the cause, the effect undoubtedly is to weaken the tenacity and cohesive strength of the metal. 179. But we shall find that, enormous as the pressure appears to be with which these pipes are proved, it is quite inadequate to the working pres- sure which they sometimes have to resist. It has been ascertained that the relative strength of wrought iron at 300° and at 800° is about as 6 to 1 ; there- fore, if the temperature of the iron, above 300°, heat, or about 800°, it is only one-sixth of the maximum ; so that in a range of less than 500° it loses five-sixths of its strength. The maximum strength of copper, on the contrary, is at a very low temperature ; for the strength increases with every reduction of temperature, down to 32°, which is the lowest that has been tried. — Journal of the Franklin Institution, 1836. 1 140 THE HIGH PRESSURE SYSTEM. increases in an arithmetical progression whose ratio is 100, the relative strength will decrease in an arithmetical progression whose ratio is 1 ; so that we shall have — Temperature, 300° 400° 500° 600° 700° 800° Strength, 6 5 4 3 2 1 Now, according to this relative decrement of strength, when the working pressure on pipes which are heated to 600°, is 1600 lbs. per square mch\ the iron at that temperature being reduced in strength one half from its maximum, the proof pressure, when the pipes are cold, should be 3200 lbs. per square inch. By the same rule we shall find, that if the pipes are to be used at higher temperatures, the proof pressure, when cold, should be as follows : — Temperature of Pipe Proof Pressure when cold, when in Use. in lbs. per Square Inch. And if we farther consider, that, after the iron has been in use for some time, at a high temperature, it loses its fibrous texture, and becomes, in its crys- tallized state, only equal in strength to cast iron, which is, at an average, less than one half the 650° 700° 750° 5,500 9,900 18,600 ' See Steam Pressures, Table 1. THE HIGH PRESSURE SYSTEM. 141 strength of wrought iron^ it will appear that the proof pressure, when cold, for pipes which are to be used in this kind of apparatus, ought, in fact, to be double the amount here stated, and therefore, very much greater than the amount to which they are actually proved. But the pressure which is here stated is obviously more than the iron could sustain; and hence the cause of the pipes bursting after they have been in use for some considerable time, if they happen accidentally to get heated to very high temperatures. 180. The question has sometimes been asked, What would be the effect on this apparatus if the expansion pipe were to be filled with water, as well as the small circulatory pipe ? The almost imme- diate consequence would be the bursting of the pipes ; for scarcely any thing can resist the expan- sive power of water. The force necessary to resist its expansion, is equal to that which is required for its artificial condensation. Now, at the tempera- ture of 386°, water expands rather more than ^ of its bulk ; and, to condense water this extent (Note, Art. 19), requires a pressure of 27, 104 lbs. per square inch: therefore, in an apparatus containing 800 feet of pipe, the bursting pressure, at this tem- perature, on the circulating and expansion pipe 1 Professor Barlow, On the Strength of Materials. — Brit, Set. Rep. vol. ii. 142 THE HIGH PRESSURE SYSTEM. together^ would be 417,022,l441bs. ! But as no- thing could resist such a force as this, the apparatus would burst before it reached even a fractional part of this immense amount. For if the pipes were filled completely full of cold water, without allowing any room for expansion, and if they were then hermetically sealed, as before described, by increasing the temperature of the water only about 60°, the expansion of the water would cause a pressure of 2000 lbs. per square inch, on every part of the apparatus, reckoned by the internal measure- ment. 181. The assertion has often been made, that the heated fluid contained in an apparatus constructed on this plan, will not scald, even if the pipes should chance to burst, because higli-pressure steam, it is well known, is not injurious in this respect. But this is quite a mistaken notion ; for high-pres- sure hot water will scald, though high-pressure steam will not; and the fluid which would issue through any fissure that might occur in these pipes, could only be partially converted into steam, unless its temperature were at least 1200°. This is ob- viously impossible ; but were it the case, the water would be all converted into steam the instant that it issued from the pipe. The reason that high- ^ The steam being an expansive force from within, the pres- sure is only exerted on the inside measurement of the pipes. THE HIGH PRESSURE SYSTEM. 143 pressure steam does not scald, is in consequence of its capacity for latent heat being greatly increased by the high state of rarefaction it instantaneously assumes when suddenly liberated : this lowers its sensible temperature, and causes it to abstract heat from every thing that it comes in contact with. The scalding effect of high-pressure hot water, on the contrary, when suddenly projected from a pipe or boiler by explosion, will always be the same, whatever its temperature, while confined within the pipe, may be ; for the instant it is liberated, a portion of it is converted into steam, and the remainder sinks to the temperature of about 212°. 182. Among the advantages which have been supposed to arise from the use of this invention, it has |beenj imagined that, in consequence of the quantity of water which the pipes contain being so small, the consumption of coal would be less with this than with any other description of hot-water apparatus. We have seen, however, (Art. 154), that the quantity of coal which is used, is in pro- portion to the heat that is given off in the room that is warmed; and a reference to the Table, Art. 154, will show that the size of the pipe makes no difference in the consumption of coal per hour, — the only difference being in the length of time required to warm the water in the first instance. But there will, on the contrary, be a greater expen- diture of fuel in this apparatus, in consequence of 144 THE HIGH PRESSURE SYSTEM. the coil affording less surface for the fire to impinge against, than would be obtained by using a boiler. In addition to this, the colder any surface may be, when exposed to the action of a fire, the more heat will it receive in a given time ; therefore, as the heat of these pipes is nearly three times as great as that of a boiler, there must be a considerable waste of fuel from this cause. 183. In consequence of the intense heat of these pipes, it is sometimes found that rooms which are heated by them, have the same disagreeable and un- wholesome smell which results from the use of hot- air stoves and flues. In reality, the cause is the same in both cases ; for it arises partly from the decomposition of the particles of animal and vege- table matter that continually float in the air, and partly from a change which atmospheric air under- goes, by passing over intensely heated metallic sur- faces \ From some experiments recorded in the PJiUosophical Transactions of the Royal Society, made with a view of ascertaining the effect pro- duced on the animal economy by breathing air which has passed through heated media, it appears that the air which has been heated by metallic sur- faces of a high temperature, must needs be exceed- * The exact nature of this change which the air undergoes has not been ascertained ; but whatever be the chemical alteration which occurs, a physical change undoubtedly takes place, by which its electrical condition is altered. THE HIGH-PRESSURE SYSTEM. 145 ingly unwholesome. A curious circumstance is re- lated in reference to these experiments, which is illustrative of this fact : — " A quantity of air which had been made to pass through red-hot iron and brass tubes, was collected in a glass receiver, and allowed to cool. A large cat was then plunged into this factitious air, and immediately she fell into convulsions, which, in a minute, appeared to leave her without any signs of life. She was, however, quickly taken out and placed in the fresh air, when, after some time, she began to move her eyes, and, after giving two or three hideous squalls, appeared slowly to recover. But on any person approaching her, she made the most violent efforts her exhausted strength would allow, to fly at them, insomuch that in a short time no one could approach her. In about half an hour she recovered, and then became as tame as before." 184. The high temperature of these pipes, and the intensity at which the heat is radiated from them, has sometimes been urged as an objection against this invention, when applied to horticultural purposes; because, any plants which are placed within a certain distance of them, are destroyed. Although, no doubt, this effect really takes place, it can be easily avoided with proper care ; for, as radiated heat decreases in intensity as the square of the distance, it only requires that the plants should be placed farther off from these pipes than from L 146 THE HIGH-PRESSURE SYSTEM. those which are of a lower temperature. In com- paring the effect of two different pipes, if one be four times the heat of the other, — deducting the temperature of the air in both cases, — the plants must be placed twice as far off from the one as from the other, in order to receive the same intensity of heat from each. The only inconvenience, therefore, is the loss of room, which, in some cases, may not be of much importance. But a more serious ob- jection by far, appears to lie in the inequality of temperature which any building heated by these pipes must have, in consequence of their being so very much hotter in one part than in another. This difference of temperature between various parts of the same apparatus, has already been stated to amount, in some cases, to as much as 200° or 300*", varying, of course, with the length of pipe through which the water passes. From what has been stated in Chapter IV., it will also be observed that, owing to the smallness of these pipes, this kind of apparatus cools so rapidly w^hen the fire slackens in intensity, that the heat of a building which is warmed in this manner, will be materially affected by the least alteration in the force of the fire, instead of maintaining that permanence of tem- perature which is so peculiarly the characteristic of the hot-water apparatus, with large pipes. 185. These inconveniences and objections against the apparatus, however, are of but secondary im- THE HIGH-PRESSURE SYSTEM. 147 portance in comparison with the question which exists respecting its security. But as there are no means of regulating the temperature in hermetically sealed pipes, so there can be none for limiting the pressure which they sustain : and it is only by me- thods far too refined for general use, that the real amount of the expansive force can be ascertained. An apparatus which to all appearance, therefore, is perfectly safe at any given time of inspection, may in a few minutes afterwards have the pressure so much increased by adventitious circumstances, as to render it extremely dangerous, particularly if its management be confided to unskilful hands: and each day that it is used must add to its insecurity, in consequence of the pipes which form the coil continually becoming thinner by the action of the fire. 186. This invention undoubtedly exhibits great ingenuity; and, could it be rendered safe, and its temperature be kept within a moderate limit, it would be an acquisition in many cases, in consequence of its facile mode of adaptation. Its safety would perhaps be best accomplished by placing a valve in the expansion-pipe, which, from its large size, would be less likely to fail of performance than one which was inserted in the smaller pipe. If this valve were so contrived as to press with a weight of 135 lbs. per square inch, the temperature of the pipes would not exceed 350° in any part : the pressure would then L 2 148 ROTARY FLOAT CIRCULATOR. be nine atmospheres, which is a limit more than sufficient for any working apparatus, where safety is a matter of importance. 187. An apparatus of a totally different character from the preceding, follows next to be described. It is an invention which, at first, appears to be sin- gularly at variance with the general principles that have been laid down in this treatise ; but, however its mode of action may at first appear to differ from the laws which have been explained, it is certain that, if they are derived from the laws of Nature, they must act equally, at all times, and under all circumstances ; for the operation of the jDhysical laws can never be suspended, though they may be occasion- ally neutralized by a superior antagonist force. In the case of two opposing forces, the resulting action is proportional to their difference of power ; but when the antagonist force is removed, each will act ac- cording to its own peculiar laws. 188. This is the case with the invention now to be described. By it, hot water is made to descend to any required depth below the boiler, — apparently in opposition to the law of gravity, — while the cold water will ascend, though of greater specific weight. 189. Eckstein and Busby's Patent Circulator, or Rotary Float, is an invention by which centrifugal force is made to overcome the force of gravity, in the circulation of hot water. The boiler, which is either open or closed at the top, has a pipe a ROTARY FLOAT CIRCULATOR. 149 attached to its circum- ference, which is carried in any direction, either downwards or around the room to be warmed, and Fig. -21. finally returns into the | | boiler, and ends exactly ^ in its centre, as shown U ''^^ - I at b, in the annexed figure. 190. The float, or circulator, has motion given to it by means of a fly, similar to a smoke-jack, which is placed in the chimney and is turned by the smoke of the fire that is used to heat the boiler, — the float being fixed on centres, and revolving freely in the boiler. The centrifugal force imparted to the water by the rapid rotation of this float, causes it to rise higher at the periphery than in the centre of the boiler ; and the velocity with which the float moves, determines the extent of this deviation from the level. The end of the pipe b, being in the centre, is then under a less pressure, or head of water, than the pipe a, — the former being, by its position, removed from the greater pressure at the sides, which is caused by the centrifugal force imparted to the water by the float, which acts on the pipe a, placed at the circumference. 191. Suppose now the velocity of rotation to be such as to impart a centrifugal force sufficient to raise the water one mch higher at the circumference 150 ROTARY FLOAT CIRCULATOR. than in the centre, — there will then be a pressure of 24 6i grains per square inch, upon the pipe a, more than upon the pipe ^, supposing the temperature of the water to be about 1 80°. This additional pres- sure will allow^ the water in the pipe a to descend 42 feet below the boiler, if it does not lose more than 6° of heat before it returns back ao^ain to the boiler- through the pipe^; if it lose 10°, then it will only descend 25^ feet, and so on for other tempe- ratures. Now, as a pipe 4 inches diameter loses •817 of a degree of heat per minute, when its tem- perature is 120° above that of the room (Art. 126); this pipe may be of as great a length as the distance through which the water will flow in seven minutes and a half, in the first case, or twelve minutes in the second. 192. The length of pipe through which the water will circulate in the abovementioned times, will depend upon the depth to which it descends below the boiler. In this apparatus, the shorter the dis- tance through which the water flows, the greater is the rapidity of circulation ; — an eflect which is the reverse of what occurs in the common form of hot- water apparatus. In general, the circulation is here very rapid ; but the distance through which the w^ater will travel is more limited than with the ^ common plan of circulation. For, suppose the water to be raised, by the centrifugal force, one inch higher at the periphery than at the centre of the boiler. ROTARY FLOAT CIRCULATOR. 151 and that it descends 42 feet ; if the water in the pipe lose 6° of heat during its transit, the circula- tion will then be extremely slow ; because, by the Table, Art. 26, we find that the difference of weight between two columns of water 42 feet high, and 6° difference of temperature, is 242 grains per square inch on the area of the pipe, which is within 4 grains of the weight of the one-inch additional height of the water in the boiler. But if the difference be- tween the temperature of the two pipes be only 4°, then the difference between the weight of the two columns will be 160 grains per square inch of the area of the pipe ; and, by Art. 33, we shall find that this will give a velocity of 81 feet per minute, so that the pipe may in this case be about 400 feet long. But if the water only lose 3° of heat during its transit through the pipes, then (by Art. 33) its velocity will be 100 feet per minute, provided it descends only 42 feet below the boiler ; and there- fore, the pipe may be about 350 feet in length. If the depth of the descent below the boiler be only one half the amount above mentioned, — or 21 feet in- stead of 42, — then the length of pipe through which the water will circulate, will be just double the amount that has been stated for the several differ- ences of temperature. 193. These calculations are all made for pipes of 4 inches diameter ; but if smaller pipes be used, the distance through which the water will circulate, will 152 ROTARY FLOAT CIRCULATOR. be less ; because, as the quantity of heat lost in a given time by different sized pipes, is as the inverse of their diameters, so also will be the distance that the water will flow, if the velocity of its motion be the same^ 194. If greater velocity be given to the fly-wheel and float, the centrifugal force, and the height of the water at the circumference of the boiler, will both be increased ; and the distances to which the pipes can be carried, may then likewise be extended. 195. By using a close boiler instead of an open one, a range of pipes may be taken upwards, which will act on the common plan of circulation, while another range of pipes may proceed from the bottom, and act on the principle which has here been ex- plained. In this case the centrifugal force, of which the additional height at the circumference of the boiler is merely the index or measure of effect, will still be of equal power, provided the velocity of the float continues the same ; and the water will therefore descend to the same extent as before. The spindle of the float must, in this latter case, ^ It will be observed from what has been stated respecting the common plan of circulation, that the whole of these effects are ex- actly the reverse of what there occurs. In that, the greater the difference of temperature between the pipes, the more rapid the circulation : in this, the circulation is more rapid in proportion as the pipes are nearer to the same temperature. In the former, the circulation is more rapid when the pipes are moderately small : in the latter, the larger the pipe, the greater the velocity of circulation. ROTARY FLOAT CIRCULATOR. 153 pass through a stuffing box on the top of the boiler, or some other contrivance to answer the same pur- pose must be adopted. 196. This invention, which is a happy application of dynamical principles, to overcome one of the most constant of Nature's laws, by the development of an antagonist force, has hitherto been but little used. It is, however, clearly capable of being efficiently applied, in those cases where the same object cannot be accomplished by any of the more simple means which have been previously described. 197. Various other forms of hot- water apparatus have been proposed by Price, Fowler, Weeks, Smal- ley, Saul, and others ; and several of these have been made the subject of patents. But none of them appear to merit particular notice, as they present no new features in principle ; the chief object which the inventors have aimed at, being some fancied advantages by adopting peculiar shapes either of the boiler, or the radiating surfaces. Some of these inventions, however, are decidedly erroneous on sci- entific principles, and, of course, objectionable in practice. One of these plans may be mentioned, in which the boiler consists of a number of cast-iron pipes, li or 2 inches diameter, which are fastened together in the form of an arch. These pipes are not only liable to crack by the unequal expansion to which they are subject, but they must also become stopped up in a short time, by the sediment from the 154 RADIATING SURFACES. water, which will, of course, prevent the circulation. Another plan, now nearly, if not wholly, laid aside, consisted in making the flow pipe of about ten or twelve times the area of the return pipe ; a contri- vance, which, by lessening the rapidity of circulation, prevented the full effect of the heat in the boiler from becoming available. 198. The advantage which may be derived from any peculiar forms of the apparatus, must depend entirely upon the purpose for which it is required. No rule can be laid down which is applicable to every case. But in all places where a long continu- ance and uniformity of temperature are required, the form of the pipes, tanks, boxes, or other radiating surfaces, must be such as to afford only a small sur- face to a large body of water; while, on the con- trary, where these objects are not matters of import- ance, the radiating surface may advantageously be increased, relatively to the quantity of water. This may be accomplished either by using smaller pipes, or by altering the shape of the radiating surfaces ; and a variety of ways of effecting this object, will naturally suggest themselves to an ingenious mind. CHAPTER X. Summary of the Subject, and General Remarks. ] 99. Having in the preceding Chapters arranged, under distinct heads, the various remarks on the principles of warming by the circulation of hot water, it may here be desirable to bring under general review, the principal facts which it has been the object of this work to explain. There are, be- sides, many minor points connected with the inven- tion, that could not conveniently be brought under notice in any of the foregoing divisions, under which the subject has been treated, but which, neverthe- less, may be found useful to those who are inves- tigating its principles and application. 200. A correct knowledge of the cause of circu- lation of the water, it has already been observed, is absolutely necessary to the successful application of this invention in many of its more complicated arrangements. Some estimate must be formed of 1 156 GENERAL SUMMARY. the amount of the motive power possessed by an apparatus of this sort, otherwise it will be impossible to ascertain what will be the result of any particular position or determinate length of the pipes, in many peculiar cases ; as, for instance, in such forms of apparatus as figures 10, 11, and 21. It is also necessary, in order to make provision for the escape of the air from an apparatus of this kind, to have some knowledge of the laws which regulate the mo- tion of fluids, in order to ascertain where the air will lodge, and why it should accumulate in one place rather than another. No circumstance con- nected with the subject requires greater caution than this. In every part of the apparatus where an alteration of the level occurs, a vent for the air must be provided ; because, from the extreme levity of air compared with water (Art. 13), it is impossible that the air can ever descend, so as to pass an obstruction lower than the place where it is confined. Thus, in fig. 7, if the air accumulate in the pipe between a and ^, it is evident that a vent at c, although it would take off the air from ^, /^, and from c, D, could not receive any portion of that which is confined between a, or between e, f, because, in that case, it must descend through the pipe e,f^ before it could escape. The principle is the same in all cases, however large, or however small the descent may be : and the accidental misplacing of a pipe in the fixing, by which one end may be made a little GENERAL SUMMARY. 157 higher then the other, will as effectually prevent the escape of air through a vent placed at the lower end, as though the deviation from the level were as many feet, as it may, perhaps, be indies. It is, how- ever, impossible to give multiplied examples of this part of the subject, for probably no two instances, precisely similar, may occur; but it deserves the most serious attention in following out its practical consequences, for many failures have arisen from its neglect. 201. When any particular obstructions are re- quired to be overcome, in consequence of numerous alterations in the level of the pipes ; when the pipes are required to descend below tlie boiler; or, in short, when any other variation from what may be considered as the usual form and arrangement of the apparatus may be desirable, it is essentially necessary to have some data on which to found a calculation as to what will be the practical result of the required deviation ; for no partial experiment of a tentative character, or even the effect shown by a miniature model, will give any thing like an accurate idea of what will be the result, when the experiment is made on a large scale. The reason of this is obvious. It has been shown, that the greater the distance through which the water flows, the greater does the motive power become, in consequence of the water being colder in the return pipe relatively to the flow pipe. This will, therefore, prevent partial experi- 158 GENERAL SUMMARY. ments, — that is, working models, exhibiting only a particular portion of the whole apparatus, — from being conclusive : and, with a miniature model, although the decreased time and distance of transit, are compensated by the reduced size of the pipe exerting a greater cooling power on the water, the friction being much greater in small than in large pipes, the velocity will be reduced in a very sensible degree, and the results rendered wholly inconclusive. In general, the successful working of a miniature model, will be conclusive that the experiment on a larger scale will perform still better ; but the failure of the model will be no proof that the larger appa- ratus will not be successful. 202. The data on which calculations may be founded, sufficiently accurate for this purpose, have been given in the preceding Chapters; and by following out, in detail, the rules which are there given, a tolerably accurate judgment may be formed, as to the result that may be expected, under almost every form of the apparatus that may be adopted. 203. The quantity of heating surface required to warm any given space, has been fully discussed in Chapter VIII., as likewise the consumption of fuel, and other matters connected with this part of the subject. The fact, that the consumption of fuel to warm a given space, is irrespective of the size of the pipes, and the quantity of water they contain, is, perhaps, not in accordance with the generally GENERAL SUMMARY. 159 received opinion ; but, nevertheless, it will be found correct, in so far, at least, as regards the maintaining the temperature of a building at a given standard, after the water in the apparatus is heated. But by using moderately small pipes, a saving both of time and fuel will be effected ; because, the smaller the quantity of water employed, the less fuel will it require to heat it to a given temperature. For the greater expenditure of fuel which occurs in conse- quence of using large pipes, is merely owing to the larger body of water requiring a longer time to heat, than would a less quantity ; but, when once the tem- perature of the pipes has attained its equilibrium, it requires only the same quantity of fuel to continue them at that temperature, whatever the size of the pipes may be : therefore, in those buildings in which the heat is constantly maintained, it is quite unim- portant, on the score of economy, what is the size of the pipes ; but in others, pipes of a moderately small size will be found more economical than large ones, and they should therefore be used in those cases where permanence of temperature is not a matter of importance. 204. The shape and size of the radiating surfaces, or vessels, also makes a material difference in the time requisite to warm a given space to any deter- minate temperature. The greater the surface, relatively to the mass, the more of its heat will the hot body part with in a given time. (Art. 70.) A 160 GENERAL SUMMARY. very great difference obtains in this respect, in different cases : for one body will cool three or four, or even eight or ten times as rapidly as another ; and by sufficiently increasing the surface, in propor- tion to the mass, almost any degree of rapidity of heating a room or building may be attained. In many cases, however, this rapidity of heating is attended with considerable disadvantage ; for the apparatus is then unable to retain its heat for a sufficient length of time, after the fire is extin- guished. 205. In the preceding pages, all mention of the mechanical operation of fitting together the different parts of the apparatus, has purposely been avoided ; neither is it here intended to enter into the subject. The necessary knowledge for this purpose is easily acquired by a good workman, even if he do not already possess it. The only part, therefore, which it is proposed to allude to, is the erroneous notion which some persons entertain respecting the joints of the pipes. That these require to be well made, there is no question ; but to ensure their soundness or strength, it is by no means necessary, as some persons suppose, to use flange pipes : on the con- trary, not only are socket pipes both neater, and less liable to leak, but it is doubtful whether they are not even stronger than flange joints. If the joints of the socket pipes be put together with iron cement, the pipe itself will break, before the faucet end of GENERAL SUMMARY. 161 the one pipe, can be drawn out of the socket of the other. In a hot-water apparatus, there is no expan- sive force employed which could, under any circum- stances, force the pipes asunder; and, even for steam pipes, it is probable that, contrary to the usual practice, socket joints might be employed with advantage, and that economy and superior neatness, united with an equal degree of strength, would result from their use. 206. There are a great number of useful purposes to which this principle of heating is applicable, but to which it has hitherto been but sparingly applied, though it offers the promise of great utility. Such are the uses to which it may be adapted in various manufactories, — in paper-making, calico-printing, dyeing, and starch-making ; and also for druggists, seedsmen, and innumerable other purposes of general utility. For many of these purposes it is exceed- ingly convenient, as the form of the heating surface can be made of any shape to suit the peculiar object ' to which it is to be applied ; and its equality of temperature prevents all those inconveniences ^ One of the most ingenious applications of hot water that I have seen, is a kiln erected for Messrs. Keen, and Co. of Garlick Hill, Upper Thames Street. The whole floor of the kiln presents a surface which is warmed by the water circulating through it, and nothing appears which could reveal the method by which the heat is obtained. The saving is found to be very great, both in the preservation of the articles which are dried in it, and also by the great economy of fuel. M 162 GENERAL SUMMARY. that arise from unequal degrees of heat, which are consequent on most other of the existing methods of warming. 207. All the rules which have been given in the previous pages, have been framed to suit the cases of most common occurrence. There are some cases, however, where apparatus of great magnitude are required, in which these rules will not apply without modification : but as such instances are of compara- tively rare occurrence, and farther, as no person that is a novice in the practical application of this principle of warming, will be likely to undertake, for his first essay, the erection of an apparatus of gigantic dimensions, it is the less necessary to enter at length into such cases as it may be supposed will render any alteration of these principles necessary. It may, however, be observed, that cases may occur where a different construction of the boilers may be desirable, to that which has been recommended ; for instance, where, from the large quantity of heat required, a furnace of very great power would be necessary; and in that case, a boiler which exposes a large surface, while it possesses only a small capa- city, would obviously be injudicious, because the intense heat, acting on a small body of water, would, probably, generate steam of a high degree of elasti- city in the boiler, and not only produce much in- convenience, but even neutralize the effect of what might otherwise be an efficient apparatus. Some GENERAL SUMMARY. 163 cases may occur, where two moderately small boilers will be more economical and effective than one very large one ; and many cases may arise where several flow pipes, taken from different parts of a boiler, will be more advantageous than one large main pipe, particularly when the boiler is very large, or the water is required to circulate at different alti- tudes, varying considerably from each other. The size of the pipes also ought to be regulated, not only by the purpose to which the building is to be applied, but also to the quantity of pipe actually used in the building. For if the distance through which the water has to travel before it returns to the boiler, be very considerable, the size of the pipes ought not to be so small as to cause any very great degree of friction : neither ought they to be too large; because, in this case, the water will never reach so high a temperature as it otherwise would do, and therefore its effect will be proportionably less. 208. These remarks relate principally to the erection of the apparatus : others, however, may be added, which apply more to its practical working. One not unimportant subject, is the quality of the water which is used. Sometimes the foulest and most filthy water is used in a hot-water apparatus, by which a thick coating of mud is deposited, and which must, necessarily, not only much reduce the effect of the apparatus, but also injure the boiler. But a far more general, and in fact, an extremely M 2 164 GENERAL SUMMARY. common error lies in using hard water, which contains a large quantity of earthy salts. Rain-water ought always to be used when it can possibly be obtained, because all hard waters are impregnated with saline matter, which forms the sediment, or incrustation, so common in those vessels in which water is boiled. This incrustation always accumulates in the boiler of a hot-water apparatus in which hard water is used, and forms a coating, varying in substance from the thinnest lamina, to two or three inches in thick- ness. When this deposit of saline matter occurs in a boiler, not only is less heat received by the water, in consequence of the conducting power being lessened by the interposed substance, but the boiler will be much injured by the increased heat of its external surface, and more fuel will be consumed. 209. This kind of sediment can only be removed from a boiler with great difficulty. It consists, principally, of carbonate of lime and sulphate of lime, together with the sulphates of soda and mag- nesia, and several other salts, varying considerably in different localities. A weak solution of muriatic acid (1 part of acid by measure to 20 or 30 parts of w^^er) will generally reduce this concreted sediment, into a substance of less tenacity, which may then be removed with slight mechanical force. By using rain water, the inconvenience arising from these deposits will, however, be entirely avoided, and the apparatus will both last longer and be more efficient. GENERAL SUMMARY. 165 210. Some inconvenience has occasionally been experienced when a hot-water apparatus has been left for a long time without being used, and exposed to considerable degrees of cold, by the water be- coming frozen in the pipes ; for it is not only diffi- cult in such cases to thaw the water, but sometimes also the pipes crack. To prevent this, it will gene- rally be sufficient to draw oif a portion of the water, so that the horizontal pipes shall not be quite full ; for the cracking of the pipes arises from the sudden expansion which takes place in the water, at the moment of its passing into the solid state of ice. But when the apparatus is not likely to be used for a considerable time, it would be much better, if the weather be very cold, to empty the pipes entirely of water; for it is always troublesome to thaw the water when once frozen in the pipes. But in an apparatus used in a building of which the tempera- ture is always above 32°, this is obviously unneces- sary, as the water cannot then be frozen. A plan, however, might be adopted which would effectually prevent the water freezing with any ordinary degree of cold ; namely, by using salt water in the appa- ratus, instead of fresh water. This plan would cer- tainly be somewhat injurious to the apparatus, on account of the action of the salt on the iron; but the injury would not be at all extensive, and would be very slow in its operation. Perhaps in this country such a plan is unnecessary ; but should this 166 GENERAL SUMMARY. kind of apparatus be adopted in colder climates, the suggestion might be useful. The larger the quantity of salt which a given portion of water contains, the greater is the degree of cold necessary to congeal it. Thus, the quantity of salt contained in sea water is about 3|- per cent.^; this requires, according to Dr. Marcet, a temperature of about 28° to freeze it : but if the quantity of salt be increased to 4*3 per cent., the water will not freeze until the cold be reduced to 27^° of Fahrenheit, or 4^° below the ordinary freezing point of fresh water. When the water contains 6'6 per cent, of salt, it will not freeze until the temperature be reduced to 25|- of Fahrenheit; and if it contains 11*1 per cent., the temperature must reach as low as 21^ before the water will congeal. 211. The effect which would be produced on cast- iron pipes and boilers, by any of these quantities of salt, would not be of much importance ; although, in process of time, it would certainly, in some degree, corrode the apparatus^. When the apparatus has ^ This quantity varies considerably in different localities. In the English Channel the quantity is as above stated ; but on the coast of Spain it contains about 6 per cent., while the water of the Baltic only contains about 1^ per cent. Between the Tropics the quantity is very large ; — as much as 10 per cent, is stated to exist in some of the tropical seas and oceans. ^ A remarkable difference obtains in the rate at which oxyda- tion acts on cast and on wrought iron. Hard cast iron will resist oxydation about three times as long as wrought iron ; and, according to the experiments of Mr. Daniell, the same difference GENERAL SUMMARY. 167 been once filled with salt water, the waste which occurs in the water, by evaporation, should only be supplied with fresh water ; for as the salt does not evaporate, the same quantity of salt will remain in the apparatus, and will combine with the fresh water when added. 212. As water can hold in solution as much as 35 per cent, of common salt (chloride of sodium), there is no fear of any deposit forming in the boiler from this cause. The reason of a deposit forming in boilers where hard water is used, is, because the water leaves behind, on evaporation, the saline compounds which it held in solution ; and as the water which is added to supply the place of that which has evapo- rated likewise contains the same extraneous matter, the quantity presently becomes larger than the water can hold in solution, and the residue is precipitated and hardened by the heat of the fire. All the salts of lime, which are usually contained in hard water, are, likewise, soluble in this fluid only in a very limited degree. For instance, sulphate of lime, one of the most common ingredients in hard water, is soluble in it only to the extent of f per cent., and carbonate of lime in a still smaller proportion ; there- fore the precipitation begins to take place as soon as the quantity exceeds this small amount. exists in the length of time requisite to produce a given effect by- acids. The effect on soft cast iron will approach nearer to that of wrought iron, varying with its hardness. 168 GENERAL SUMMARY. 213. The necessity which exists for making suffi- cient provision for the expansion, both of the pipes and the water contained in them, has been men- tioned in Chapter II. ; and the requisite informa- tion respecting the sizes proper for the boilers, furnaces, main pipes, &c., has been given in Chapters III., IV., V. It, therefore, only remains to observe, that when these rules are followed, no doubts need be entertained, as to the successful and safe performance of any apparatus erected conform- ably to them : and, any one possessing an apparatus constructed on these principles, has, what should always be an object of paramount importance in such matters, a machine that requires no care nor attention, and of which the efficiency of performance for many years may be calculated on with certainty. It may, however, be remarked, that many appa- ratus which have proved wholly abortive, as to any beneficial effect, have failed through the most tri- fling causes ; so trifling, indeed, that it may safely be said, that alterations, which, if properly directed, would not, in some cases, have cost more than a few shillings in amount, would have converted the use- less and unprofitable machine into a perfect and efficient apparatus. In many of these instances, the apparatus has been removed and destroyed, and the whole cost sacrificed; though, had the opinion of some scientific person been obtained, this waste and destruction of property might have been avoided. CHAPTER XI. ON VENTILATION. Effects of Respiration, and the Chemical and Physical Alteration of the Air — Amount of Ventilation — Rules for Calculating the Proper Size for Ventilators — Different Methods of Producing Ventilation — Importance of Ventilation on Health. 214. No system of warming buildings, however good of itself, can be considered perfect without it is accompanied by sufficient ventilation. The best plan of artificial heat becomes inefficient without it ; but with good ventilation, even the worst system of warming may be rendered tolerable. 215. Ventilation is a subject which has always attracted far less attention than it deserved. The general principles which are known, are seldom applied in a systematic manner. In small buildings it is in general wholly overlooked ; and, in those of a larger description, where it becomes impossible entirely to neglect it, it generally fails in regard to quantity. In fact, the fundamental principles of ventilation are so simple, that almost the only diffi- 170 REMARKS ON culty, except in some few extraordinary cases, is to apportion the proper amount, so that the ventilators shall be sufficiently large, without causing any unne- cessary waste of heat. Some calculations on this subject may, therefore, perhaps, be useful. 216. In inhabited rooms, the quantity of air which is vitiated by the inmates varies considerably under different circumstances. When an individual is in a state of repose, the quantity of oxygen con- sumed, and the amount of vapour expulsed from the system, are much inferior to what they are when muscular exertion is used. It is, therefore, evident, that the ventilation of a manufactory, or of a ball room, ought to be much greater than is necessary for churches, lecture-rooms, concert-rooms, or any other building where the inmates are in a state of quietness and inactivity. 217. Lavoisier ascertained that the consumption of oxygen by a man, while engaged in strong mus- cular exertion, compared with the same individual while in a state of repose, was in the proportion of 32 to 14; and the quantity of vapour given off by the body, under different states of activity, is also found to vary in the same proportion. 218. The amount of the vapour which is discharged from the lungs, is variously stated by Menzies, Sanc- torius, Abernetliy, and Hales, at 6, 8, 9, and 20 ounces in 24 hours. The amount of perspiration from the skin, Keil found, by experiments made VENTILATION. 171 upon himself, to be 31 ounces in 24 hours, or 10|- grains per minute; but, according to Thenard, it varies from 9 to 26 grains per minute. The quan- tity of vapour thus given off from the system varies, however, not only under the different degrees of muscular exertion and repose, but also under the ever changing hygrometric condition of the atmos- phere : for the greater the quantity of vapour which the air contains, the less will it be able to carry off from the human body. For the air possesses a desiccating power on the human body ; but, of course, that power is lessened in proportion as it is nearer to the point of saturation. 219. The hygrometric condition of the atmosphere is ascertained by the dew point ^ The lower is the dew point, the more moisture will be carried off from the lungs by the air, in respiration ; and, there- fore, less will be given off by perspiration, than when the dew point is higher. This is often the case in very cold weather, when a large quantity of vapour is carried off from the lungs, and but little ' The dew point is that thermometric temperature of the at- mosphere at which vapour is condensed. By exposing a cold body to the air, a fine dew is deposited on its surface, and, by observing the temperature of this cold body, we know the exact quantity of vapour contained in the air at that time. Warm air contains a larger quantity of vapour than that which is colder ; for air has the property of taking up water in solution in a quan- tity proportional to its temperature. The Table II. shows the quantity of vapour that the air contains when the dew point is obtained in this manner. 172 REMARKS ON by perspiration. When air is respired from the lungs it is nearly of the temperature of the blood, ■which is 98° Fahrenheit ; and it is then charged with a large quantity of vapour. If we ascertain the quantity of vapour which the air contains when ex- pired, and deduct what it possessed before it was inhaled, we shall learn the amount given off by the lungs ; the quantity of air breathed per minute being known. Now, suppose the temperature of the air, before it is inhaled, to be 40°, and the dew point 30° ; as 800 cubic inches of air is the average quan- tity breathed per minute, Yy^- of a grain ^ of vapour will be received into the lungs with the air, per minute. But when the air is again expired, the temperature will be about 95°, and the dew point probably about 85° : it will then contain 5*6 grains of vapour in the 800 cubic inches ; so that upwards of 4i grains per minute are given off from the lungs under these circumstances. But if the dew point of the air, before it is breathed, be 50°, which is fre- quently the case in damp or warm weather, then only 3i grains of vapour will be given off in the same time. Dr. Dalton states, that in the torrid zone, the dew point sometimes rises to 80°, and that even in this country it occasionally reaches to 60°, while, in winter, it is sometimes below zero. This easily accounts for the variable quantity of moisture See Table II. VENTILATION. 173 which is exhaled from the body and lungs at different times. 2'20. The atmosphere, during damp weather, when it is frequently nearly in a state of saturation, is unable to carry off the full quantity of vapour from the body. This causes the oppressive sensation that is so often experienced under such circumstances ; and the slightest exertion causes the perspiration to condense upon the surface of the body, and a degree of heat is experienced, much greater than the simple thermometric temperature would occasion. This is often the case likewise in badly ventilated rooms. Here, however, another cause augments the incon- venience : for experiments have proved, that air, which has been once inhaled, loses about 10 per cent, of its oxygen, or nearly one half that it con- tains, and acquires from 8 to 8^ per cent, of carbonic acid gas. This gas, it is well known, is as destruc- tive to animal life as the oxygen is necessary for its preservation, and, therefore, air cannot be breathed a second time without serious inconvenience. For, as it is found impossible to make atmospheric air contain more than 10 per cent, of carbonic acid gas, it follows, that, if breathing a quantity of air once, impregnates it with per cent, of this gas, if it be breathed a second time, it can only receive 1|- per cent.; and, therefore, the remainder must be left in the lungs, where it exerts a most deleterious effect. The noxious qualities of this gas are well known ; 174 REMARKS ON the foul air of wells, which causes death in so many instances, consists of this deleterious matter: and it is extraordinary that the heart and muscles of any animal that has been deprived of life by breath- ing it, entirely lose their irritability, and become in- sensible even to the powerful stimulus of galvanism. 221. Although the carbonic acid gas, given off from the lungs, is rather more than 37 per cent, heavier than the oxygen which is consumed, still, in consequence of the dilatation of its volume by the increased heat, and the greater levity of the vapour given off from the lungs, the air is specifically lighter at the moment of its expiration than at its inspira- tion. For 800 cubic inches of pure air at the tem- perature of 60°, and the dew point 40°, will weigh 243*395 grains ; but 800 cubic inches of air at 95°, containing 8^ per cent, of carbonic acid gas^ and * The quantity of carbon given off from the lungs being so considerable, we cannot wonder that the subject of its origin has been a deeply disputed question. Supposing 68 cubic inches of carbonic acid gas to be given off from the lungs per minute, on an average, that quantity will contain 8'63 grains of pure carbon, which in 24 hours will amount to 28 ounces. As this frequently exceeds the total quantity of food consumed in a day, it would seem impossible that the food were the only source which yields this substance : for, besides this, if the quantity of vapour from perspiration and pulmonary transpiration, be taken at 10 grains per minute for the former, and 3 grains for the latter, they will amount to 42 ounces in 24 hours, making the vapour and carbon together amount to nearly 4jlbs.; besides other excrementitious matter from the body. Some other source, then, besides the food, must exist for obtaining the matter which supports vitality, and this probably is the air. We have already seen that expired air, VENTILATION. 175 5*6 grains of vapour, with the dew point 85°, will only weigh 232*450 grains, being nearly 5 per cent, lighter. Hence air, when expired from the lungs, always rises upwards, and will flow through ventila- tors in the ceiling, or the upper part of the walls of a room, if such be provided for its escape; but, otherwise, the vapour condenses, and the volume of the air collapses as it cools ; it then becomes heavier than the substrata of air, and sinks to the lower part of the room contaminated with impurities. is of less weight than the inspired, and it is probable that there is an absorption of it in the system to some considerable extent. It has been ascertained by Dr. Prout, that a vegetable diet diminishes the quantity of carbonic acid gas given off, and, of course, reduces the quantity of oxygen consumed; because car- bonic acid gas contains exactly its own bulk of oxygen, united to the given weight of pure carbon. The accuracy of Dr. Prout's experiments has been confirmed by divers and persons making use of the diving bell. In all hot climates, also, where, from the rarified state of the air, less oxygen is received at each inspiration than in the higher latitudes, the inhabitants feel but little desire for animal food, and use, principally, a vegetable diet ; while, on the contrary, the inhabitants of the Arctic regions use animal food almost exclusively. Dr. Richardson, who accompanied Capt. Franklyn on his voyage of discovery to the Polar seas, says, that himself and the other individuals, who composed the expedition, never felt the slightest wish for vegetable diet, but desired the most stimulating animal food, and in much larger quantities than they had ever before been accustomed to. In such a climate, in consequence of the coldness and density of the at- mosphere, the quantity of oxygen inhaled is much greater than in warmer regions, and therefore allows the larger quantity of carbon to be carried off, which the dieting on animal food pro- duces. These results, therefore, accord with Dr. Prout's ex- periments. 176 REMARKS ON 222. Such being the effects resulting from want of proper ventilation, it is necessary to inquire what is the quantity of air to be changed per minute, to maintain its purity in inhabited rooms and public buildings. 223. Although 800 cubic inches of air per minute, is a sufficient pulmonary supply for each individual, a much larger quantity is necessary to carry off the insensible perspiration. The amount of vapour from this cause, we have seen, has been variously stated by different experimentalists; but we may not, perhaps, be far wrong in estimating it, on an average, at 10 grains per minute, when the indivi- dual is not making any particular muscular exer- tions. If the temperature of a room be 60°, the air will absorb 5*7 grains of vapour per cubic foot ; but, the average dew point being about 45°, the air will previously contain 3-5 grains ; so that a cubic foot of air will only absorb an additional quantity of about 2i grains of vapour. Under these circum- stances, the perspiration from the body will saturate 4^ cubic feet of air per minute. But in estimating the quantity of air which is to be warmed, in order to allow of sufficient ventilation, this amount may be considerably reduced; because, as 45° is the average dew point for the whole year\ it will be ' This is for the neighbourhood of London. It varies, of course, in different places, and is much influenced by the prevail- ing winds. An easterly wind travelling to us from the Conti- ] VENTILATION. 177 much lower in winter and higher in summer, and, probably, will not exceed 20° or 25° on an average, during the time that artificial heat is required. Every cubic foot of air will then absorb an additional quantity of about 3^ to 4 grains of vapour ; and we may therefore estimate the quantity of air which is requisite to carry off the insensible perspiration, at 3 cubic feet, and for the pulmonary supply half a cubic foot per minute, for each individual. 224. This calculation is sufficient for estimating the quantity of air which in winter is required to be warmed per minute, as explained Art. 151. But for the purpose of summer ventilation a larger allow- ance should be made. As the dew point is much higher in summer, the air will absorb less moisture from the body, while at the same time, the exhala- tions from the body are considerably greater in summer than in winter. For summer ventilation, therefore, at least 5 cubic feet of air per minute, for each person, ought to be changed, in order to main- tain the purity of the room ; that is, 4^ cubic feet nent of Europe, and across the dry and arid countries of the Asiatic Continent, must necessarily part with much of its mois- ture, acquired from the Pacific Ocean, before it reaches us ; and, therefore, it will be to us a dry wind : while, on the contrary, a westerly wind is always charged with a large quantity of mois- ture, absorbed during its passage from the American Continent, across the Atlantic. Its passage over this ocean, — a distance of 3000 miles, — occupies a period varying from 3 to 10 days ; dur- ing which time it is constantly imbibing moisture from the ocean. N 178 REMARKS ON for tlie absorption of the insensible perspiration, and lialf a cubic foot for the pulmonary transpiration. 225. Other causes of deterioration of the quality of the air exist ; such as the consumption of oxygen, and the elimination of extraneous gases, by the burning of fires, candles, lamps, &c. : but as all gases are capable of absorbing equal quantities of vapour, it follows that, when air has been deteriorated by these causes, so as to be less fit for respiration, it is still just as capable of carrying off the vapour from the surface of the body as pure air ; and, therefore, no allowance needs be made for these causes of vitiation. 226. When the quantity of air has been ascer- tained which is necessary to be changed per minute in any inhabited room or building, the next thing is to estimate the proper size of the openings for the emission of the vitiated and foul air, and also for the admission of the fresh air which is required to supply its place. 227. When an opening is made in the ceiling or upper part of a room, the force which produces motion in the air is the same universal law which regulates the motion of falling bodies, and is pre- cisely similar to the motion of water in a syphon, — which has been already explained. (Art. 32.) The total height from the floor of the room to the point of final escape of the heated air, is the height of the syphon. The force of motion is the difference of 1 VENTILATION. 179 weight between this column of heated air and that of a column of the external air of the same height. Now air expands, when heated, of its bulk for each degree of Fahrenheit ; and the velocity of mo- tion is equal to the additional height which a given weight of heated air must have, in order to balance the same weight of cold air. Thus, suppose a room 1 2 feet in height, and the air 20° higher in the room than the external temperature, — the air will expand of its bulk, by the excess of temperature : there- fore, 12^ feet of heated air will balance 12 feet of air which is 20° lower in temperature. It has already been explained (Art. 32), that, under such circumstances, the motion of fluids is equal to the velocity which a solid body would acquire, by falling through a space equal to the excess of height which the lighter body must have in order to balance the heavier : this velocity is as the square root of 16 feet is to \Q feet per second, so is the square root of the given height to the velocity sought. This resolves itself simply into multiplying the square root of 16 feet by the square root of the given height. But as the acquired velocity of a gravitating body is equal to twice the space it falls through in a given time (Art. 32), the number thus found must be doubled. In the case of the room we have before supposed, as the additional height of the heated column of air is 6 inches, so the square root of 6 inches, reduced to the decimal of a foot, multi- N 2 180 REMARKS ON plied by the square root of 16 feet, and that product multiplied by 2, will give 5*6 feet per second, as the velocity of the air. An opening in the ceiling, 1 foot square, will therefore discharge 336 cubic feet of air per minute. 228. It will be perceived that here also, as well as in the case of the circulation of water (Art. 33), if either the vertical height or the excess of tem- perature of the room be increased fourfold, the velocity will, in either case, be twice as rapid as before. But whatever be the calculated velocity, the real discharge will not be so great as this theo- retical quantity, — not only in consequence of fric- tion, but also because the air will be cooled in its passage through the ventilating tubes, particularly if they extend beyond the roof of the building. This will considerably lessen the discharge; and we ought therefore to deduct a certain amount from the calculation, which, on an average, should be about one fourth of the whole quantity. 229. The following Table will show the discharge per minute through a ventilator 1 foot square, for various heights and differences of temperature, — the allowance which is above stated having here been made. The discharge through a ventilator of any other size may easily be calculated ; because, as the area is here 144 square inches, we have only to multiply the number of feet found by the Table, by the number of square inches in the area of the pro- VENTILATION. 181 posed ventilator, and then, by dividing that number by 144, the quotient will be the quantity sought, which will represent the number of cubic feet of air that will be discharged per minute by the proposed ventilator. TABLE of the Quantity of Air, in Cubic Feet, discharged per Minute, through a Ventilator of which the Area is 1 square Foot. Height Diflference between Temperature of Room and of External Air. Ventilator, in Feet. 5° 10° 15° 20° 25° 30° 10 116 164 200 235 260 284 15 142 202 245 284 318 348 20 164 232 285 330 368 404 25 184 26 J 318 368 410 450 30 201 284 347 403 450 493 35 218 306 376 436 486 531 40 235 329 403 465 518 570 45 248 348 427 493 551 605 50 260 367 450 518 579 635 The above Table shows the discharge through a ventilator of any height, and for any difference of temperature. Thus, suppose the height of the ventilator, from the floor of the room to the extreme point of discharge, to be 30 feet, and the differ- ence between the temperature of the room and of the external air to be 15°, then the discharge through a ventilator 1 foot square will be 347 cubic feet 'per minute. If the height be 40 feet, and the difference of temperature 20°, then the discharge will be 465 cubic feet per minute. 230. The height of the ventilator will, in some 182 REMARKS ON cases, be very considerably greater than the height of the room. Suppose, for instance, a church is required to be ventilated ; the ducts or channels which carry off the heated air will probably pass for a considerable height between the ceiling and the roof, and will, most likely, also extend above the roof. The total vertical height of all this must be measured as the height of the ventilator; but, of course, not taking into the account the lateral length which may be given to it for the purpose of uniting the several ventilators into one main trunk, or for making the extreme termination at a more convenient part of the roof. 231. As the discharge through any given height and size of ventilator, is less in proportion as the difference between the external and internal tem- perature is smaller, it follows, that it will be most difficult to obtain ventilation in hot weather. In summer, either the number or the dimensions of the ventilators should be increased; otherwise a room which is well ventilated in winter, will be extremely uncomfortable in summer. The increase in size can be effected by having moveable ventilators, which can be contracted at pleasure ; and the actual size of the trunk or channel which conveys the air away, should be sufficiently large to carry off the largest quantity of air required for summer ventilation. 232. The openings for the admission of cold air, should always be placed as near to the floor as VENTILATION. 183 possible. In size, they should be much larger than the area of the ventilators, in order that the influx of cold air may not proceed with too great velocity, and cause a draught. In fact, the size of these openings is a matter of indifference, provided only that they be sufficiently large ; for the quantity of air which enters through them depends entirely upon the quantity that passes off through the venti- lators, and not vice vei^sd : for if the passages for the cold air were double the size of the ventilators, no more cold air could enter, than a quantity equivalent to that of the heated air which escapes at the ceiling ; and none of the heated air can escape at the cold air channels, because heated air cannot descend. 233. The more numerous and divided are the openings for the admission of cold air, the less inconvenience will ; be experienced by currents : but unless a sufficient quantity of cool air be admitted in this manner, there will be a counter current of cold air forced through the ventilators, which will descend and produce a very disagreeable draught. 234. In all moderate sized buildings, this mode of ventilation will be sufficient for every purpose. But in buildings of very great magnitude, artificial means of ventilation must be adopted, because the mere difference of weight between the two columns of air, will not be enough to expel the heated air with sufficient velocity, particularly in hot weather. 184 REMARKS ON For theatres, this mode is generally inapplicable; and it has likewise been found ineffectual for the ventilation of the houses of Parliament. 235. The ventilation of the late House of Commons was, for many years, a subject of complaint, and it engaged the attention of many practical and scien- tific men. The apparatus which has recently been erected for this purpose, in the present House of Commons, under the direction of Dr. Reid, for producing ventilation by means of an immense chimney draught, appears to be a most expensive and cumbrous contrivance, for accomplishing an object obtainable by far easier means. The thorough ventilation of such a building as this, can only be procured by two methods, — draught by heat, or mechanical ventilation by a fan : but the latter of these methods possesses so many advantages over the former, that it appears surprising it should, for so many years, have been neglected ; and that, of all the numerous plans which have been tried, for ventilating the late House of Commons, the draught by heat, though applied in various ways, has been the principle of them all. Dr. Ure has recently written a valuable memoir on the subject of ventila- tion, in which he compares the advantages of these two methods; and he estimates the economy of ventilating by a fan, compared with that by chimney draught, as about 38 to I. In his calculations on this subject, however, he has apparently been led VENTILATION. 185 into an error. His experiments on. the consumption of fuel, to produce a given effect by chimney draught, were all made on furnaces used either for steam boilers, or for brewers' coppers. But, as it could only be the residual heat of the furnace which became available in his experiments, after the principal part of the heat given off by the coal had been absorbed by the boiler, it is certain that any calculation, founded on the effect produced in this manner, must be below the truth, as much probably as a half or two-thirds. But although the relative cost of fuel will not be so greatly different as Dr. Ure supposes, under any circumstances the difference between the two methods must be con- siderable. 236. The efficiency of the mechanical method of ventilation by a fan, turned by machinery, has been proved so extensively in some of the largest manu- factories in the kingdom, that it appears singular Dr. Reid should have adopted so cumbrous and expensive a contrivance as that which he has erected at the present House of Commons. Whether or not this method of ventilation be adopted in the new Houses of Parliament, I have no doubt, that, ulti- mately, the more simple, efficient, and economical plan of ventilating by a fan will be resorted to. 237. As the motion of the air through tubes and ventilators depends for its velocity upon the vertical height of the tube only, it follows, that, if several 186 REMARKS ON ventilating tubes be used in the same room, they must all be exactly of the same height ; if they are not so, it frequently happens that cold air descends through the lower tubes, and the highest one alone conveys the heated air from the building. But the horizontal length of the tube, it has already been observed, makes no difference : and it is essential in large buildings, when more than one ventilator is necessary, either to connect the various lateral tubes into one main trunk, or else to have all the various tubes exactly of a similar altitude. Whether the heated air merely rises by its want of gravity, or whether it be drawn out of the building by means of a chimney draught, as adopted by Dr. Reid in the House of Commons, or exhausted mechanically by a fan, this rule, respecting the vertical height being the same in all the tubes, must be observed. 238. To conclude these remarks : — after what has here been stated, it were unnecessary farther to insist on the importance of ventilation, as regards both the health and comfort of all those whose occu- pations, or inclinations, confine them much within doors. The important alterations which atmos- pheric air undergoes in the process of breathing, would alone be sufficient to establish the necessity of attention to this subject. But the effects which arise from this cause, are often greatly increased by bad methods of warming: and these two causes combined, are sufficient to produce the most exten- VENTILATION. 187 sive injury to the animal economy, when exposed to their influence for any length of time. In the following chapter, we shall endeavour, in following out this subject, to investigate the principles of the various methods of warming by artificial heat, and the physiological effects which result from their use. CHAPTER XIL On the different Modes of distributing Artificial Heat — Advan- tages of Radiating Heat at low Temperatures— Effects pro- duced by Hot-Air Stoves in general — Nott's Stoves — Heating by Flues — Dr. Arnott's Stoves — Gas Stoves — General Remarks. 239. Important as are the alterations which take place in atmospheric air by the process of respira- tion, not less important are those produced upon it by several of the methods now in use, for the warming of buildings ; for the effects which result from many of them are highly injurious to animal life. 240. The effect produced on the animal economy by atmospheric air which has passed over intensely heated metallic surfaces, has already been noticed (Art. 183). There are, however, other changes produced on atmospheric air, by subjecting it to the action of heat, which are extremely important. 241. When air passes over the heated surface of a hot-air stove, the small particles of animal and vegetable matter, which are always held suspended HOT-AIR STOVES. 189 in the air, are decomposed by the heat, and resolved into their various elementary gases. This is one of the causes of the unpleasant smell which usually results from the use of such stoves. But in addition to this, the hygrometric water of the atmosphere is almost entirely decomposed ; the oxygen entering into combination with the iron, and the hydrogen mixing with the air. This alteration materially affects the salubrity of the air : for not only is its desiccating influence on the lungs and skin increased to a most dangerous extent (Art. 218), but the admixture of the disengaged hydrogen with the atmospheric air, is, perhaps, even more injurious than the alteration of its hygrometric state ; or, if not, its effects are, at all events, sooner discovered. 242. Signer Cardone made some experiments on the effects which result from the breathing of hydrogen gas. He inhaled 30 cubic inches, which is about one-ninth part the total capacity of the lungs ; and the almost immediate effects he expe- rienced were an oppressive difficulty of breathing, and painful constriction at the superior orifice of the stomach, followed by abundant perspiration, tremor of the body, heat, nausea, and violent head- ach ; his vision became indistinct, and a deep murmur confused his hearing. Some of these symptoms lasted a considerable time, and were with difficulty got rid of. 243. The effects which are here described would 190 VITIATION OF not, of course, be so powerfully experienced with the quantity of hydrogen that is disengaged by the action of a hot-air stove : but neither is this quan- tity so small as might be imagined, nor is it the sole cause of the injury which results from the use of such stoves. 244. We have already seen that the particles of animal and vegetable matter, contained in the air, are decomposed by the heat ; and they then produce extraneous gases consisting of sulphuretted, phos- phuretted, and carburetted hydrogen, with various compounds of nitrogen and carbon, all of which are of a character highly inimical to the animal economy. The quantity of hydrogen which is eliminated by the decomposition of the water contained in the air, is 1325 cubic inches for every cubic inch of water which is decomposed ; and if the dew point of the air be 45° at an average, this quantity of gas will be given out from every 72 cubic feet of air which passes over the heated surface of the stove. It is, therefore, neither difficult to account for the ener- vating effects produced by hot-air stoves, in conse- quence of the air, when thus artificially dried, abstracting too much moisture from the human body, nor to foresee the injury which their constant use must produce, when used in close rooms, by breathing the extraneous gases which are evolved from the decomposition of the constituent parts of the atmosphere. ATMOSPHERIC AIR. 191 245. Though not usually susceptible of any diag- nostic effects, I have, many times, felt sensibly affected on entering rooms heated by a peculiar kind of hot-air stove, which was invented by Dr. Nott. The extreme heat of these stoves, produces, in a very powerful degree, all the effects which are above described : and perhaps no better proof needs be desired, of the justice of the foregoing remarks, as applied to hot-air stoves in general, than can be obtained by any person standing near to one of these stoves for a few minutes. The feeling of oppression which is produced is intolerably painful ; and the relief immediately experienced on going into the fresh air, at once points out the cause of the inconvenience. 246. The extreme dryness of the air, after it has been deprived of its hygrometric water by passing over a stove of this description, frequently produces violent headach ^ ; and to remedy this evil it is usual to place a vase, containing water, on the stove, which, by yielding a portion of vapour to the air, attempers its extreme dryness, and in some degree mitigates this inconvenience. The evil, how- ever, caimot be got rid of by such means ; for even ^ This is a necessary consequence of exposure to an atmosphere of excessive dryness : for the cold which is produced by the rapid evaporation of moisture from the skin, contracts the capacity of the absorbents, and causes the fluids to flow towards the head. Tension of the brain is thus produced, with all its attendant evils. 192 BRICK FLUES. if the proper quantity of moisture could be again restored to the air, the effects which result from the evolution of extraneous gases, would not be at all removed. 247. As the power of iron to decompose water increases with the temperature of the iron, the limit to which the temperature of any metallic surfaces ought to be raised, which are used for radiating heat for the warming of buildings, should not much, if at all, exceed 212°, if the preservation of health is a matter of moment. The importance of this rule cannot be too strongly insisted on. It ought to be the fundamental principle of every plan : for upon it depends the wholesomeness of every system of artificial heat. 248. The various kinds of hot-air stoves, though they differ considerably in their effects, are all nearly similar in principle. In very large stoves, the air frequently passes over a surface of iron, nearly, if not quite, red hot, and is then conducted through pipes, or tubes, into different parts of the building which is to be warmed. This plan is perhaps the most unwholesome of all ; because the surface over which the air passes is generally of a much higher temperature than in any of the other methods. 249. The heating by means of brick flues is nearly similar to the effect produced by hot-air stoves. The flues are usually of a very high tem- DR. ARNOTT'S stoves. 193 peratiire, and always produce a most disagreeable and unwholesome smell by the decomposition of the floating particles of animal and vegetable matter contained in the air; and, probably, also, by the sublimation of a small portion of sulphur from the substance of the bricks themselves, as well as by the escape of various gases, generated during the combustion of the fuel, through either the joints or accidental fissures of the flues. The hygrometric water of the atmosphere, however, is not decomposed by this method of warming, because the materials of which the flues are composed have not an aflinity for oxygen such as that possessed by heated metal : and in this particular flues are more wholesome than hot-air stoves. 250. A new kind of hot-air stove has lately been invented by Dr. Arnott, which is intended to obviate the bad effects resulting from those of the usual construction. This stove consists of an oblong case, or box, of wrought iron, about 3 feet long, 2 feet wide, and 2 feet high. It is divided across the middle by a partition which separates it into two distinct compartments, communicating with each other by small openings at top and bottom. The fire is contained in a fire-clay basket, which is placed in the first compartment, and the only air admitted is through a small circular hole at the side ; the door in the front, for supplying fuel, being made to flt as close and as nearly air-tight as possible. A o 194 DR. ARNOTT'S stoves. metal cover, attached to a series of expanding plates, closes this hole : when the heat of the stove becomes too great, the plates, by their expansion, draw the cover, which closes the hole, inwards ; thus shutting off the communication of the air, wholly or partially, according as the temperature acts with greater or less force on the expanding plates. On closing the opening in this manner, the fire immediately slackens for want of sufficient air to support combustion of the fuel ; and the temperature of the stove decreas- ing, the plates inside again collapse, and thus admit more air to the fire : the combustion can therefore be regulated so as to keep the stove at almost any temperature. The air circulates within the two chambers by the small openings which connect them, but the room is warmed by the air passing over the surface of the stove only. The smoke escapes through a flue, in the usual manner ; and as the fire never comes in contact with the surface of the stove, every part of it is kept at a low temperature, — about 200° of Fahrenheit. 251. The temperature of this stove being so low, no injurious effects are produced, as in other stoves, by decomposing the vapour and the particles of matter which are suspended in the air: but as a large quantity of carbonic oxide is generated by coke in a low state of combustion, there is a tendency for this deleterious gas to escape into the room, in con- sequence of the draught of the chimney being so DR. ARNOTT'S stoves. 195 small, that it barely causes its withdrawal from the stove \ 252. The heat afforded by this stove is so incon- siderable as to render it inapplicable, except in rooms of small size. The large dimensions of the stove is also an inconvenience ; and if its size be reduced, the effect is also decreased in the same pro- portion, which must therefore prevent its use, except in a very limited degree. 253. The efficacy and advantages of any invention for warming, do not, however, simply consist in the fact, that the apparatus employed will not decom- pose the vapour contained in the atmosphere, or eliminate any permanently elastic gases ; for if, on the contrary, a moist heat were produced, its influ- ence on the human organization would be not less injurious than we have shown results from an oppo- site condition of the atmosphere. 254. As the air is only able to contain a definite quantity of vapour (Chapter XI.), by adopting any method of artificial heat which evolves an excess of * This objection also lies against all stoves, which have a very slow draught. The effects produced by the breathing of this gas are extremely prejudicial to the animal economy. Sir H. Davy, on trying the effects of inhaling a small quantity of it, was seized with a temporary loss of sensation, succeeded by giddiness, sick- ness, and acute pains in different parts of his body ; and it was some days before he entirely recovered. But Mr. Witter, of Dublin, who tried to repeat the experiments, was immediately affected with apoplexy, and was restored with difficulty. o 2 196 GAS STOVES. moisture, the natural exhalations from the lungs and skin cannot be carried off. and pulmonary consump- tion must ultimately be induced, provided the con- tinuance of the exciting cause be of sufficient dura- tion. A notable instance of this kind of heat is that which is produced by the " gas stove," an inven- tion by which the burning of carburetted hydrogen gas is employed as a substitute for coal. The effects of this plan are, however, very prejudicial to the human frame, for the whole of the gas consumed in these stoves is converted into two new compounds, water and carbonic acid gas, — which are both exhaled into the air of the room. The quantity of water, in the form of vapour, distributed by one of these stoves, is very considerable, for each cubic foot of carbu- retted hydrogen gas w^hich is consumed, produces 2*6 cubic inches of water ; and as the consumption of gas, in a moderate-sized stove of this description, is from 12 to 15 cubic feet per hour, the total quan- tity of water given off to the air, will be from a pint to a pint and a quarter per hour. 255. The large quantity of oxygen gas, which is abstracted from the air to support the flame of the carburetted hydrogen, would not of itself be of much consequence, provided the nitrogen, which is by this means set free, could escape, as it does in other stoves, without mixing with the air of the room. But, in consequence of these stoves having no flues, GAS STOVES. 197 the whole of the nitrogen or azotic gas \ which is eliminated from the atmosphere, amounting to eight times the quantity of hydrogen consumed, or about 100 to 120 cubic feet per hour, together with about 12 or 15 cubic feet of carbonic acid gas, mixes with the air in the room, and must be breathed by the inmates, there being no outlet by which it can escape. 256. The plan which has recently been tried of introducing flues into these stoves, in order to carry off the unwholesome products of the combustion, would be a very great improvement, were it not that in carrying off the extraneous gases and the steam, the heat received in the room, is, at the same time, so much reduced, as to render the stoves compara- tively valueless, as regards their heating effect. If the whole of the water, which is formed by a stove burning for 15 hours, at the rate of 15 cubic feet of gas per hour, escapes uncondensed in the state of steam, which is the form it assumes before it be- comes water ; as much heat will be carried off, as would, had the steam been condensed at the tem- perature of 60°, have heated 1 16,790 cubic feet of air 10°. To this must be added, the loss from the heated air that escapes through the flue, which is probably about as much more ; and, together, the ^ The name of azote (derived from two Greek words, signifying without life,) was given to this gas, on account of its peculiarly fatal effects on animal life. 198 GAS STOVES. amount thus lost is nearly one-half the heat which the stove affords under the most favourable circum- stances. This may be proved by the following cal- culation, showing at the same time, the relative cost of warming by gas and by coal. 257. The experiments of Dr. Dalton have proved that by the combustion of one pound in weight of carburetted hydrogen gas, as much heat is generated as will melt 85 lbs. of ice. Now, a cubic foot of car- buretted hydrogen weighs 292*89 grains, and, in a stove burning 15 cubic feet an hour, for 15 hours a day, there will be 225 cubic feet, or 9*4 1 lbs. of gas consumed, which would, therefore, melt 799 lbs. of ice; and the cost of this quantity of gas, at the usual average price, would be two shillings and threepence. The latent heat of water being 140°, it requires as much heat to melt 1 lb. of ice, and to raise its temper- ature from 32° to 33°, as would raise the temperature of the same weight of water 141°; and as the cubic foot of water weighs 62*33 lbs., therefore, the same quantity of heat that would melt 799 lbs. of ice would heat 12*8 cubic feet of water 140°^ or 179.2 cubic feet 10°. By referring to Art. 140, we shall find that 1 cubic foot of water will raise the tem- perature of 2990 cubic feet of air as many degrees as the water loses ; and the combustion of 225 cubic feet of carburetted hydrogen gas would therefore raise the temperature of 535,808 cubic feet of air 10°. The quantity of coal which will produce the GAS STOVES. 199 same effect is easily ascertained. By Art. 138, we find that 1 lb. of coal will heat 39 lbs. of water 180°, or 702 lbs. of water 10°. This is equal to 11,170 lbs., or 179*20 cubic feet of water being heated 10° by 15*91 lbs. of coal : and this number of cubic feet of water multiplied by 2990 (Art. 140), will give 535,808 cubic feet, as the quantity of air that would be heated 10° by 15*91 lbs. of coal, which is exactly the same result as is obtained by the combustion of 225 cubic feet of carburetted hydrogen gas. The only difference would be that the gas would cost 2s. 3(/., and the coal no more than 3g?., or, to allow for extra expenditure of fuel, from imperfect con- struction of the stove, say the coal will cost 5g?. ; so that a gas stove, without a flue, will cost about five times as much for fuel, as a hot-air stove which burns coal, and about ten times as much as coal, if the gas stove has a flue ^ 258. It requires no deep researches into the prin- cijjles of physiology, to appreciate, in some degree, at least, the merits of a niethod of artificial heat, which is free from all the noxious effects which we have seen result from the use of most of the inventions that have been described. Although many persons ^ This latter amount may be reduced by making the flue of the stove very long and very large in diameter, so as to condense the steam by exposing to it a large surface. This would save a con- siderable portion of heat, but the form and size of the flue would probably be very inconvenient. 200 PHYSIOLOGICAL EFFECTS. are not aware of the full extent of the injury that results from these causes, the merest sciolist in the investigation of natural phenomena must acknow- ledge, that the more we deviate from the simplicity of Nature's laws, the more fatal are the effects on that most delicate of all her works — organic life. And it needs no farther arguments to prove that it must be injurious to breathe an atmosphere contaminated by extraneous gases, which have not the power of supporting animal life, or that extracting from the air its natural humidity, or, on the contrary, loading it with vast quantities of moisture, must produce consequences inimical to the health of organized beings. 259. Nor is it only to animal life that these results ensue. It is equally on all departments of organized existence, in the vegetable as well as the animal kingdom, that the injurious effects of erro- neous principles of warming exert their influence ; for it will readily be conceded that we cannot violate the one class of laws with impunity, any more than we can the other. It is therefore only conformable to what might be anticipated, that practical gar- deners have almost universally acknowledged the superior healthiness and productiveness of plants cultivated in houses which are warmed by the circu- lation of hot water. 260. The perfect freedom from all these noxious effects which have been described, is not the least PHYSIOLOGICAL EFFECTS. 201 important of the advantages afforded by this method of distributing artificial heat. It would, however, be attended with disadvantages of a formidable cha- racter, if it were applied to any inhabited rooms which are not supplied with proper ventilation. In a room warmed by stoves of the common con- struction, the open fire-place itself affords sufficient ventilation in ordinary cases ; but with all other modes of warming, ventilation must be supplied, if it be wished to avoid the evils resulting to the human frame, from breathing a vitiated atmosphere, whether it be rendered impure by having passed through the lungs, or in consequence of extraneous gases either generated or evolved by peculiar me- thods of warming. 261. This remark would have been superfluous, were it not that cases have occurred where the evils that have arisen from defective ventilation have been erroneously attributed to this plan of warming by hot water ; and the vapour which is given off from the lungs of the inmates of a room, and, under these circumstances, is condensed upon the windows, has been supposed to arise from the water in the appa- ratus being converted into steam, and escaping through the joints of the pipes. If this were a solitary opinion, it might, like many others equally erroneous, merely excite a smile from those who are better acquainted with the subject ; but as this has been seriously objected against the invention, by 202 DEPOSITION OF VAPOUR many who ought to know better, it may be worth while to state the cause more at length. 262. The quantity of vapour given off from the lungs, and also by exhalation from the skin, has been estimated at from 12 to 13 grains per minute. If, in consequence of imperfect ventilation of inha- bited rooms, the air cannot escape after it has received this additional quantity of vapour exhaled from the body, it must, as soon as it has acquired a larger quantity of moisture than the temperature of the eternal air will support in the form of vapour (Art. 219), deposit a portion of it upon the glass; because, the glass being nearly of the same tempera- ture as the external air, whatever quantity of the internal air comes in contact with it, its temperature is immediately lowered, and the excess of its vapour is condensed upon the surface of the glass. Thus, suppose the temperature of the air in a room to be 65°, and the dew point 55°, then, if the temperature of the external air be only 35°, as much of the air in the room as comes in contact with the glass, will deposit whatever vapour it contains above the quan- tity that a temperature of 35° will enable it to sus- tain. Under these circumstances, the amount deposited on the glass will be (Art. 219) about 2 grains for each cubic foot of air that is cooled by the glass ; and the same effect, though in a less degree, will take place on all the other cold surfaces in the room. As each square foot of glass will cool 1 ON WINDOWS. 203 one and a quarter cubic feet of air per minute, from the internal to the external temperature (Art. 145), we shall find that, under the circumstances we have supposed, — which is purposely taken as an extreme case, — the quantity of vapour deposited in this man- ner will amount to 2^ grains per minute, on each square foot of glass. 263. We need be at no loss, then, to discover the cause of this accumulation of vapour on the windows and walls of rooms which are badly ventilated ; and whenever the quantity of moisture thus condensed appears to be considerable, it may be taken as good evidence that the ventilation of the room is imper- fect. That the same effect does not result from the use of hot-air stoves, is in consequence of the vapour being decomposed by the intense heat ; but when this method of avoiding the inconvenience is adopted, a worse evil is produced than that which is attempted to be removed, although, perhaps, it is not so obvious to the sight. 264. Some of the preceding remarks have ex- tended to a greater length, and have assumed a more prominent place, than was intended ; but it may not, perhaps, be deemed altogether super- fluous, in concluding this Treatise, to observe, that the investigation of the physiological effects of the different systems of artificial heat, is not only inte- resting in a scientific point of view to the physiolo- gist, but it closely concerns almost every individual 204 CONCLUDING REMARKS. member of the community. It is a question which affects not merely the personal comfort of indivi- duals, but, according to the opinion of some of our ablest pathologists, it influences the health, and even affects the duration of life. Such a subject, then, cannot but be deserving of investigation: and if these observations, imperfect as they are, have the effect of directing more general attention to the inquiry, they will not have been made in vain. 205 TABLE I. TABLE of the Expansive Force of Steam, in Atmospheres, and in lbs. per square inch; for temperatures above 212° of Fahrenheit. N.B. The steam is supposed to be in contact with the water from which it is formed, and the water and steam to be alike in temperature. rees ?it. Pressure. CO Pressure. rees Pressure. Q § )spheres. lbs. It in Deg Fahrenht )spheres. lbs. It in Deg Fahrenh( )spheres. lbs. w ° Atm( w Atmc a> Atmc 212 1 15 431 23 345 646 150 2250 251 2 30 436 24 360 655 160 2400 275 3 45 439 25 375 663 170 2550 294 4 60 457 30 450 671 180 2700 308 5 75 473 35 525 679 190 2850 320 6 90 487 40 600 686 200 3000 332 7 105 499 45 675 694 210 3150 342 8 120 511 50 750 700 220 3300 351 9 135 521 55 825 707 230 3450 359 10 150 531 60 900 713 240 3600 367 11 165 540 65 975 719 250 3750 374 12 180 549 70 1050 726 260 3900 381 13 195 557 75 1125 731 270 4050 387 14 210 565 80 1200 737 280 4200 393 15 225 572 85 1275 742 290 4350 399 16 240 579 90 1350 748 300 4500 404 17 255 586 95 1425 753 310 4650 409 18 270 592 100 1500 758 320 4800 414 19 285 605 110 1650 763 330 4950 418 20 300 616 120 1800 768 340 5100 423 21 315 627 130 1950 772 350 5250 427 22 330 636 140 2100 The above Table is deduced from the experiments of M. M. Dulong and Arago. Their calculations extend only as far as 50 atmospheres ; from thence the pressures are now calculated to 350 atmospheres by their formula, viz. : — t =s/e-\ •7153 where e represents the pressure in atmospheres, and t the tem- 206 perature above 100° of Centigrade. In this equation each 100° of Centigrade is represented by unity. In reducing these temperatures from Centigrade to Fahrenheit's scale, where the fractions amount to '5, they have been taken as the next degree above, and all fractions below '5 have been rejected. TABLE IT. TABLE of the Quantity of Vapour contained in Atmospheric Air, at different Temperatures, when saturated. Temperature of Air. Quantity of Vapour per Cubic Foot : in Grains Weight. Temperature of Air. Quantity of Vapour per Cubic Foot: in Grains Weight. Temperature of Air. Quantity of Vapour per Cubic Foot : in Grains Weight. 20° 1-52 48° 3-98 76° 9-53 22 1-64 50 4-24 78 10-16 24 1-76 52 4-52 80 10-78 26 1-90 54 4'82 82 11-49 28 2-03 56 5-13 84 12-20 30 2*25 58 5-51 86 12-91 32 2-32 60 5-83 88 13-61 34 2-48 62 6-21 90 14-42 36 2-64 64 6-60 92 15-22 38 2-82 66 7-00 94 16-11 40 3-02 68 7-43 96 17-11 42 3-24 70 7-90 98 18-20 44 3-48 72 8-40 100 19-39 46 3-73 74 8-95 The above Table is computed from Dr. Dal ton's Experi- ments on the Elastic Force of Vapour. 207 TABLE III. TABLE of the Expansion of Air and other Gases by Heat, when perfectly free from Vapour. Temperature, Fahrenheit's Scale. Expansion. Temperature, Fahrenheit's Scale. Expansion. 32° 1000 100° 1152 35 1007 110 1178 40 1021 120 1194 45 1032 130 1215 50 1043 140 1235 55 1055 150 1255 60 1066 160 1275 65 1077 170 1295 70 1089 180 1315 75 1099 190 1334 80 1110 200 1354 85 1121 210 1372 90 1132 212 1376 95 1142 The above numbers are obtained from Dr. Dalton's experiments, which give an average of part, or "00207 for the expansion by each degree of Fahrenheit. Gay Lussac found it to be equal to part, or '002083 for each degree of Fahren- heit ; and that the same law extends to condensable vapours when excluded from contact of the liquids which produce them. 208 TABLE IV. TABLE of the Specific Gravity and Expansion of Water at different Temperatures. S-j . c o Weight ture, eit's c .2 Weight Is ~ .3 >j c w c Specific of -« Specific of 1 Cubic cS 1 Cubic Gravity. Inch, el X Gravity. Inch, Eh ^ in Grains. in Grains. 30° •00017 •9998 252714 121° •01236 -9878 249-677 32 •00010 •9999 252-734 124 •01319 •9870 249 473 34 •00005 •9999 252^745 •01403 •9861 249-265 36 •00004 •9999 252-753 130 •01490 •9853 249053 38 •000002 •9999 252*758 133 •01578 •9844 248 836 39 •00000 10000 252-759 136 •01668 •9836 248-615 43 •00003 •9999 252750 139 •01760 •9827 248-391 46 •00010 •9999 252734 142 •01853 •9818 248-163 49 •00021 •9997 252704 145 •01947 •9809 247 931 52 •00036 •9996 252 667 148 •02043 •9799 247 697 55 •00054 •9994 252 621 151 •02141 •9790 247-459 58 •00076 •9992 252-566 154 •02240 •9780 247219 61 •00101 •9989 252502 157 •02340 •9771 246-976 64 •00130 •9986 252 429 160 •02441 •9760 246-707 67 •00163 •9983 252-349 163 •02543 •9751 246-483 70 •00198 •9981 252-285 166 •02647 -9741 246-233 73 •00237 •9976 252 162 169 •02751 •9731 245 982 76 •00278 •9972 252 058 172 •02856 •9721 245 729 79 •00323 •9967 251-945 175 -02962 •9711 245-474 82 •00371 •9963 251-825 178 •03068 -9701 245 218 85 •00422 •9958 251^698 181 •03176 •9691 244962 88 •00476 •9952 251 -564 184 •03284 •9681 244 704 91 •00533 •9947 251-422 187 •03392 •9671 244 446 94 .00592 •9941 251-275 190 •03501 •9660 244 187 97 •00654 •9935 251121 193 •03610 •9650 243^928 100 •00718 •9928 250960 196 •03720 •9640 243-669 103 •00785 •9922 250-794 199 •03829 •9630 243410 106 •00855 •9915 250621 202 •03939 •9619 243 151 109 •00927 •9908 250-443 205 •04049 •9609 242893 112 •01001 •9901 250259 208 •04159 •9599 242-635 115 •01077 •9893 250070 212 •04306 -9585 242 293 118 •01156 •9885 249^876 In the above Table the expansions are calculated by Dr. Young's formula, 22/^ (1--002/) in 10 millionths. The diminution of specific gravity is calculated by this equation : •0000022/2 _ -00000000472 In both equations, / repre- sents the number of degrees above or below 39° of Fahrenheit. The absolute weight of a cubic inch of water, at any temperature, may be found by multiplying the weight of a cubic inch at 39°, by the specific gravity at the required temperature. 209 TABLE V. TABLE of the Specific Heat, Specific Gravity, and Expansion by Heat of different Bodies. Barometer 30 Inches. — Thermometer 60°. Air (atmospheric) . . — (dry) .... Apjohn Aqueous vapour .... Azote — oxide of Carbonic acid — oxide Hydrogen. . Olefiant gas Oxygen . . . . Water . . . . Water. . Bismuth Brass . . . — wire Cobalt Copper Gold Glass (flint) (tube) Iron (cast) (bar) Lead Nickel Pewter (fine) Platinum . , Silver Solder (lead 2 -j- tin 1) . Spelter (brass 2-|- zinc 1) Sreel (untempered) . . . (yellow tempered) Sulphur Tellurium Tin Zinc Specific Heat. •2669 •2767 •8470 •2754 •2369 •2210 •2884 3-2936 •4207 •2361 1000 S 5 1000 •0288 •1498 •0949 •0298 •1100 •0293 •1035 •0314 •0557 •1880 •0912 •0514 ■0927 Specific Gravity. 1000 •633 •9722 1-5277 1-5277 •9722 •0694 •9722 11111 Weight of 100 Cubic Inches. OJ o % a s s 1000 9-880 7- 824 8 - .396 8 600 8-900 19-250 2-760 2^520 7-248 7-788 11-350 8 279 21 470 10470 7-840 7816 1-990 6- 115 7- 291 7-191 Grains. 30519 19-321* 29-65 46-596 46-596 29-65 21 18 29-65 33 888 Ounces. 57-87 571-7 452-77 485^87 497-6 515-0 1114-0 159-72 145-83 418-9 4502 656-8 478-5 1242-4 605-8 453-7 452-31 115-1 3535 421-9 4160 Linear Expansion by 180° of Heat, from 32° to 212°. 00186671 00193000 00172244 ■00146606 00081166 •00087572 00111111 00122045 ■00284836 ■00228.300 •00099180 00208260 •00250800 00205800 •00107875 •00136900 •00217298 -00294200 — 6SI ?38 TooS *,* Air is taken as the standard for the specific gravity of the gases, and water as the standard for the solids. * Specific gravity of steam at 212°=-481. Weightof 100 cubic inches, 14-680 grains. 210 TABLE VI. TABLE of the Effects of Heat. Wedgwood's Scale. Greatest heat observed .... Hessian crucible fused .... Cast iron thoroughly melted Greatest heat of a smith's forge . . Ditto of a plate-glass furnace Ditto of a flint glass ditto . Derby porcelain vitrifies .... Welding heat of iron (greatest) . Ditto ditto (least) . . . Fine gold melts Fine silver melts Swedish copper melts Brass melts Diamond burns Red heat fully visible in day light . Iron red-hot in the twilight Charcoal burns Heat of a common fire Iron bright-red in the dark Zinc melts (680° Davy) • . Mercury boils (Black 600°) (Secondat 644°) (Petit and Dulong) (Crichton 655°)(Irvine 672°) (Dalton) Lowest ignition of iron in the dark Lead melts (Guyton and Irvine 594°) (Crichton) . Steel becomes dark blue, verging on black . . Ditto a full blue Sulphur burns Steel becomes bright blue Ditto purple Ditto brown, with purple spots .... Ditto brown Bismuth melts Steel becomes a full yellow . Ditto a pale straw colour Tin melts Steel becomes very faint yellow ...... Tin 3 + lead 2 -f- bismuth 1, melts .... Tin and bismuth, equal parts, melts Bismuth 5 -f tin 3 + lead 2, melts Table of the Effects of Heat [continued). Water boils (barometer 30 in.) . . Water freezes Milk freezes Vinegar freezes Sea water freezes Strong wine freezes Quicksilver congeals Sulphuric aether congeals . . . . Natural temperature at Hudson's Bay Great artificial cold TABLE VII. TABLE of the Quantity of Water contained in 100 Feet of Pipe, of different diameters. Diameter of Pipe. Contents of 100 Feet in length. Inches. Gallons. 1 2 •84 1 3-39 li 7-64 2 13-58 21-22 3 30-56 4 54-33 5 84-90 6 122-26 212 TABLE VIII. TABLE of the Strength, or Cohesive Force, of different Substances : By Geo. Rennie. Bars of 6 inches long and a J of an inch square will break with the following weights suspended lengthways: — lbs. Cast Iron (horizontal) 1166 Ditto (vertical) 1218 Cast Steel (tilted) 8391 Blistered Steel (hammered) . . . 8322 Shear Steel (ditto) .... 7977 Swedish Iron 4o04 English Iron 3492 Hard Gun-metal 2273 Wrought Copper (hammered) . . . 2112 Cast Copper 1192 Fine Yellow Brass 1123 Cast Tin 296 Cast Lead 114 *^* A round bar of best English Iron, one-inch diameter, when subjected to a longitudinal strain, will break with a weight of 43,520 lbs., or rather less than 19j tons. This agrees very nearly with the amount above stated. TABLE of the Relative Cohesive Strength of Metals : By SiCKENGER. Gold .... 150,955 Silver .... 190,771 Platinum . . . 262,361 Copper .... 304,696 Soft Iron . . • 362,927 Hard Iron . . . 559,880 INDEX. PAGE Air, admission of in furnaces 77 — conducting power of, for heat 83 — dry, effect of on the human body 191 — eifects produced on, by heated metals 189 — loss of heat by contact with 86 — quantity of, to be warmed in buildings 116 — quantity of vapour absorbed by 1 76 — vents in pipes, necessity for 16, 156 — vents, proper size of 17 — vents, proper position of ... , 46, 156 — and water, relative weights of 17 Angles vertical, their effect on circulation 36 Arnott, Dr., his hot-air stove 1 93 Ascent of water in vacuo 130 Bars for furnaces, size of 79 Boilers, shape of 66 small, objections against them 68 • surface of, exposed to the fire 71 surface of, required for certain lengths of pipe .... 70 Boiling point, influenced by pressure 131 Branch pipes, their effect 22, 53 Brick flues, effects of I93 Capacity of Boilers, proper proportions for 66 Carbonic oxide, effect of breathing 1 95 Centrifugal force, effect of 148 Circulation of water 7 ■ erroneous theory of 8 cause of 10 through inclined pipes 13 effects of gravity on 15 velocity of 33 below the boiler 44 Cisterns, supply, size, and position of 48 Close-topped boilers, advantage of 18 Cocks, size of 55 Coal, quantity of, to heat different sized pipes 121 Compression of water 21 214 INDEX. PAGE Conducting power of air - 83 Conduction and Radiation, erroneous theory of 83 of heat, effect of surface on 84 Condensation of vapour on windows 201 Connecting pipes, size of 55 Colour, effect of, on heat 96 Cooling, influenced by shape of surface 62 power of glass . . . . , 104,112 Cost of burning gas for fuel 198 Deposits in boilers, effect of 68 . removal of 164 Effects of heated metallic surfaces ] 44 of thickness of bodies on their cooling powers . . . .100 Elasticity of air, effect on the conduction of heat 84 Experiments on the cooling of iron pipes 1 02 Falling bodies, velocity of descent of 32 Fluids, motion of 17 Freezing of water in pipes, effects of 1 65 Friction of water in pipes, effect of , .... 34 relative amount of 52 Furnaces, construction of , 75 proper size of 79 Gas stoves, their effect , 196 hydrogen, its cost when used for fuel 198 Glass, cooling power of 104 surface of in buildnigs, how to calculate 115 Gravitation of falling bodies 31 Heat of water and steam compared 59 Heat, simple 83 loss of, by contact with air 86 radiation of, influenced by surface 86 radiant, law of 91 loss of, effect of thickness of metals on 94 effect of colours on the radiation of 96 quantity of, obtained from coals 109 Heated metallic surfaces, effect of on air 144 High pressure system of warming 133 Hot-air stoves, effect of on the human body 1 90 Hydrogen gas, effect of on the animal economy 189 Iron pipes, loss of heat in Ill strength of 137 temperature of maximum strength 138 crystallized 139 Joints of pipes 160 INDEX. 215 PAGE Kewley's syphon apparatus 128 Latent heat of steam 58 Law of the smes 91 Lead paint, effect of on radiation 95 Main pipes, proper size of 53 Metallic surfaces, effect of on air, when heated 145 Moisture reduces the effect of heating apparatus 124 Motive power 24 how to increase the 28 Nobili and Melloni, their experiments on heat 83, 93 Nott's hot-air stoves 191 Obstructions to circulation of water 41 Oxygen, quantity of consumed in respiration 1 70 Permanence of temperature 60 Pipes, expansion of 49 size of for different purposes 64 iron, loss of heat in Ill rule for calculating requisite quantity of . . . . 117,124 joints of 160 Pressure of water 11, 19 Rate of cooling influenced by shape of surface 62 Radiation of heat influenced by temperature 88 by surface 86 by thickness of body 94 • the inverse of conducting power 93 not affected by colour 98 Repulsion of water by hot iron 68 Rotary float circulator 148 Saline deposits from hard water 164 Salts, quantity of, in hard water 167 Specific heat 98 ■ of air and water 110 Steam, quantity of heat contained in 58 high-pressure, does not scald 142 Stop-cocks, size of 56 Supply cisterns, size and position of 48 Surface, effect of, on the conduction of heat 84 on the radiation of heat 86 Syphon, motion of water in 31 Table of motive power, and pressure of water 27 of friction in pipes 52 of surface of boiler, to heat a given quantity of pipe . . 70 of area of furnace bars 79 of ratio of cooling 85 216 INDCX. PAGE Table of velocity of cooling by radiation 88 of radiating power 92 of conducting power of metals 93 of cooling of iron pipes 102 of glass 103 power of wind 106 i of pipe required to heat any building 119 of coal 121 of strength of iron decreased by heat 140 of discharge of air through ventilators 181 of pressure of steam 205 of vapour in air 206 of expansion of air 207 . of specific gravity and expansion of water 208 of specific heat and expansion of various bodies .... 209 . of effects of heat 210 of contents of pipes 211 of strength of materials 212 Time required to heat buildings 123 Vapour, quantity of, from the human body 170 condensed on windows 202 Velocity of circulation 32 Ventilation, amount of, for summer and winter 177 different modes of 184 Ventilators, discharge of air through 179 Vertical angles, their effect 35 height, effect of the increase of 30 Water, a bad conductor of heat 8 . cause of circulation of 10 pressure of 19 compression of 21, 141 . • expansion of 48, 134 quantity of heat contained in 58 repulsion of, by hot iron 68 . quality of, used in boilers 164 velocity of circulation of 33 Wind, cooling power of 104 not prevalent in the coldest weather 113 allowance for the effect of 113 THE END. Gilbert & Rivington, Printers, St. John's Square, London. Green on Diseases of the Skin SECOND EDITION. 4_ Just published^ in 1 thick vol. %vo. WITH TWO ILLUSTRATIVE COLOURED PLATES, PRICE lis. BOARDS, A PRACTICAL COMPENDIUM OF THE DISEASES OF THE SKIN, INCLUDING A PARTICULAR CONSIDERATION OF THE MORE FREQUENT AND INTRACTABLE FORMS OF THESE AFFECTIONS. BY JONATHAN GREEN, M.D. 40, Great Marlborough Street, FORMERLY SURGEON IN HIS MAJESTy's NAVY, AND MEMBER OF THE ROYAL COLLEGE OF SURGEONS, LONDON, &C. &C. BY PERMISSION) DEDICATED TO SIR HENRY HALFORD, BART. Physician to thf. King, &€* &c. &c. Whittaker & Co., Ave Maria Lane ; to be had of all Booksellers. • — It has been the author's aim in this Compendium to condense within the smallest possible space; not only the results of his own experience, but the whole amount of practical information extant upon this highly important class of diseases. His most particular attention is constantly given to the characters by which they may be distinguished one from another, and to the most approved and available means of treatment recommended for the cure. REMARKS OF THE MEDICAL AND GENERAL PRESS, ON Tllli riRST EDITION. '* It is almost supcrHuous to say, that every professional reader ^yllo wishes to be successful in the management of cutaneous diseases, will find it his interest to study thoroughly the method of treatment recommended by Dr. Green."— Edinburgh Medical and Surgical Journal. The Practical Compendium of Dr. Green forms a popular and very usehil introductory work to the larger one of Ilayer. His observations on Impetjgo and Porrigo are certainly the most judicious we have ever read ; they are derived from sound pathological views. To the student of medicine we do not hesitate to recommend the Compendium of Dr. Green in preference to Bate- man's Synopsis, (no mean praise) as more simple in its descriptions, and more practically useful" in its therapeutic instructions. It is unnecessary to say more of this work." — Medico-C/iirurgical Review. _ r m i Upon the whole we are much pleased with this book; it cannot fail to be instructive, as it is replete with the results of long and successful practice."— Medical Quarterly/ Review. , , . i " We earnestly recommend those who are interested in the subject, not only to read this book, but to put the efficacy of the agents to the test."— London Medical Gazette. . " So far as the production of a compendium of all that is known on the pathology, etiology, diagnosis, and treatment of cutaneous diseases is concerned, the author seems to have succeeded in his object." — Lancet. *' It is an excellent compendium, evincing great experience and success on the part of the author." — London Medical and Surgical Journal. " We can state from our own knowledge of the benefits experienced by numerous patients, and heartily recommend both the work and the system it advocates." — Literary Gazette. " Dr. Green's book will recommend itself. It is not a mere book of nomen- clature system, but enters largely into therapeutic details, which are mostly satisfactory, laying down very precise rules for the management of herculean remedies in the treatment of maladies that have long been the opprobria medi- corum." — AthenfEum. We take leave of this work with the full conviction that the author^ has rendered an important service to the public, furnished the practitioner with a most valuable book of reference, and evinced in his elucidation of an obscure class of diseases, a thorough knowledge of their causes, treatment, and method of cure." — Metropolitan. " Such a work as the present has long been wanted. More empirical reme- dies are in use, and more mistakes made in the treatment of cutaneous diseases, than in any other class of disorders. The clearness with which Dr. Green has classed the diseases of the skin, and the remedial details into which he has so largely entered for the management of those intractable diseases in all their varieties, render the present volume a most valuable addition to medical litera- ture. It ought to obtain a place in the library of every professional adviser." — Court Journal. BV THE SAME AUTIIOU, Published by Churchill^ Medical Bookseller, prince's street, so ho, OBSERVATIONS on the UTILITY of FUMIGATING and other BATHS, with Abstracts from the Official Documents, ordering this Mode of Treating Diseases to be adopted in the French Hospitals, and which rapidly extended throughout the Continent; together with Ninety-two important Au- thenticated Cases. Price Is. 6d. also, A CHART of the DISEASES of the SKIN, wherein is defined the distinguishing Characters by which they may be known, and the effects of the Fumigating Baths in the Treatment are shown in the last column. Price Is. Qd, A SHORT ACCOUNT OF FUMIGATING, HOT AIR, AND This account lays claim to confidence, as it is supported by the first Medical Authorities, in this Country and on the Continent. The above represents the Patent Fumigating, Warm Air, and Vapour Apparatus for Baths, as introduced into England, early in 1822, by JONATHAN GREEN, M.D. They are improved upon the plan of those used on the Continent, and of those directed to be used in the Hospitals throughout France. The left view shows the Bath open, and the right a person taking the Bath, LONDON : 40, GREAT MARLBOROUGH STREET. 1837. Fumigating, Hot Air, In the treatment of various diseases Baths are very essential, and have been much overlooked in this country. In a curative point of view, immeasurably above all others are those administered in what is called the Fumigating Apparatus, by means of which Medicines of any degree of strength, and in the most favourable form for influ- encing the system, viz. the Gaseous, are administered without unplea- santness, or inconvenience to the patient. No water is used in these Baths, except for Vapour. The Medi- cines employed are such as the case may require, as Sulphur, Cam- phor, Ammonia, Mercury, &c. &c., which, being converted by Heat into the Gaseous form, surround the patient's body, the face only being excluded; and as the Heat occasions absorption of the Medi- cine, these Baths are particularly viseful in those cases, where the coats of the stomach and bowels are too weak to receive the requisite remedies in the ordinary way. The temporary application of Heat, after this method, occasions for the time an increased vigour to be given to all the internal and external functions of the body, simultaneously, by which any hidden or latent complaint is propelled outwards and through the pores of the skin, as the Bath acts much on the principle of the cupping glass, that is, drawing from within outwards. The efficacy of this mode may be inferred from a knowledge of the fact, that the milder forms of disease give way to the use of these Baths alone. They may be taken by the most delicate persons and children, being always tonic in effect, when properly administered, and persons from their use are less liable to take cold.* They are preservatives of Health, as they produce the good effects of exercise, viz., increased and equal circulation and perspiration, without fatigue. The good effects of these Baths may be further judged of, as it is indisputably admitted, that they — • I. Equalize the circulation of the blood, and powerfully tend to prevent its determination to the head, and likewise to remove giddiness, and prevent cold- ness of the hands and feet. — See Dr. Green's Observations on Fumigating and other Baths, Introduction. II. They re-establish insensible perspiration, promote sweat, consequently relieve or remove symptoms of inflammation ; therefore are indicated for gouty and rlieumatic pains, swellings of the joints, lumbago, sciatica,, &c. — See London Medical Repository/, Oct. 1823. * See Transactions of the Royal Society, Vol. LXV. p. Ill, 484, and 494. and Vapour Baths. III. They diminish nervous irritability, and have cured cases of tic doloureux. — See Observations, p. 32. IV. Most diseases of the skin, from rashes and pimples to leprosy, are best treated by this method ; in proof of which the milder forms of skin disease give way to this treatment alone. — See Medical and Physical Journal, December, lH23-^and Oct. 1827-^and London Medical Repository, Apr. 1824. V. They remove from the system the ill effects arising from the too free use of mercury. -->S'e'e Cases in Observations, ^-c. p. 54-— 58, VJ, They strengthen the stomach and give tone to the digestive organs, by increasing the secretions. — See London Medical Repository, October, 1 824= VII. They do good in all glandular and other swellings and obstructions, by equalizing the circulation and quickening the activity of the absorbent vessels. — See London Medical Repository, April, 1823. VIII. They tend greatly to relieve all dropsical swellings submitted to their operation. A common cold is always cured by these Baths, — See Observations, S)C.p.37-S9, IX. Dr. Green has yet had no case of ague which has not been cured principally by them. And all slight affections of the above diseases, he believes to be under the same control. — Sec London Medical and Physical Journal, March, 1827. After this statement, and in corroboration of it, it may be well to bring before the reader's notice, though very briefly, the origin and progress of these remedial means on the Continent, To France the honour is due for discovering this mode of curing various obstinate diseases, more successfully and speedily than by the customary methods. The early trials by these means occasioned as it were at the time a new era in the practice of Medicine. The minds of all persons in Paris were greatly biassed in its favour, and it was thought that all former modes of combatting diseases must succumb to it. The French government (ever mindful of the public Health), to set the matter at rest, and unequivocally to establish the merits or supposed merits of the remedy, or otherwise, if found wanting, to decry it, ordered separate Committees, composed of the leading Me- dical Practitioners in Paris, to assemble at the Hospitals, and inves- tigate the matter by trials, comparing these means with those already in use ; and to insure impartiality, each of these Committees was pre- sided over by an official officer appointed for the purpose, and the results of the trials of each separate Committee was kept secret until transmitted to a Central Committee. The conclusion only of the last Report to the Government by the Central Committee is all that can be adduced here ; it is as follows , — Fumigating, Hot Air, CONCLUSION OF THE REPORT OF THE CENTRAL COMMITTEE. " We have given it our most deliberate attention, and urge that it should be ur.ed in hospitals and great establishments. " 'I'he Committee think it their duty not to dissimulate on the advantages of this method, which cannot but be applicable also to the service of the Camp and the Army. Done at a meeting held this twenty-second day of August, 1815. Signed " LEROUX, DUBOIS, DUPUYTREN, RICHERAND, . ^ , ^ . ^ . HALLE 1 1* acuity ot Physic, Pans. PINEL,' PERCY, Barons and Professors of the After this the Fumigating Apparatus was ordered to be establislied in all hospitals, prisons, poorhouses, &c. — See Memoirs and Beports on the Efficacy of Fwnigations, printed hij order of the French Government, for General Instruction — Translated by Dr. Price — Published by Longman (Sr Co. The advantages of this new mode of treatment rapidly extended throughout the Continent. — See the Woi k of Dr. De Carro ( the Sir Henry Halford of Vienna) — Translated by Wallace — Published by Burgess Hill. In 1 822, at St. Louis, the largest hospital in Paris, the surprising number of 127,752 of these Baths were administered ; as each year, from their first intro- duction, had contributed to increase the estimation in which they were held. — « See Dr. Bayer's Work, Vol. I. p. xxvi. — Published by Churchill. In 1833, a work by Drs. Cazenave and Schedel, physicians to the hospital, shows that the number had increased to upwards of 150,000 at the said hospital in one year. — See Vol. I. p. xxxi. — Published by Balliere, Regent Street. In November, 1836, the writer was at the Hospital of Saint Louis, and found that in the years 1834 and 1835 upwards of the astounding number of 180,000 had been administered each year, and for the year 1836, the number, it was judged, would be about the same, the Baths being always in occupation. If it is borne in mind that these Baths are erected at the other hospitals, prisons, poorhouses, and other large establishments, it will and Vapour Baths. at once appear evident how much importance is attached to theri as curative means on the Continent, Here, it is true, they are not he] d in so much estimation ; but this is owing to their not being much known. This is not a bathing nation, and all new systems have many opposing influences to contend with — these things are managed better in France. The writer has the satisfaction of adding, that he has been required to superintend their erection at three of our Metropolitan Hospitals, and no doubt in time the remedy will attain its due share of popu- larity in this country. At present, it is mostly known to be abused, by misapplication and bad management, whereby this means of relief runs much risk of being brought undeservedly into disrepute ; it is, therefore, with pleasure, the writer can submit the following testimo- nies from the Medical Press. " The Fumigating Bath, as a Therapeutic xA-gent, is too important to be trusted in any other hands than Medical, and from personal observations, we can testify, that Ur. GREEN'S Establishment is by far the most complete in London, and as it is carefully supenntended by himself, it deserves the Patron- age of the Profession, and the confidence of the Public." — Medical and Chirur- gical Review. " In the adoption and effective application of one description of Therapeutic Agents, Dr. GREEN, though not original, has very great merit. We allude to the employment of those agents, which act directly on the cutaneous surface, in the shape of Fumigating Baths. No doubt can be entertained of the efficacy of these methods; and it is quite clear that many diseases, which are quite intrac- table under the ordinary remedies, particularly of the Skin, speedily yield to agents applied in this manner." — Edinburgh Quarterli/ Medical and Surgical Journal. THE BATES ARE THREE FOR A GUINEA. Dr. GREEN cannot interfere in the cases of any Patients coming from Medical Gentlemen, and is at home for consultation daily from \2 till 5 o'clock, (Sundays excepted). For Domestic Use, as a most Efficient VAPOUR BATH, for Local or General Purposes, the Writer can recommend the Jekyll Bath. The above shows Captain JehyWs Paienl Povlahle Vapour Balk, price Twelve Guineas, with Seat, Curtain, and Dresses, complete, accompanied with a book of cases and ample directions. The Fumigating Baths are necessavily Fixtures. But tlie above represents a Por- TABLE Vapour Bath, of very superior construction and manufacture, suitable to Invalids who cannot leave their room, or for persons travelling, as a Vapour Bath can be thus had in any place where there is a fire, and in as short a space of time as a tea- kettle can be made to boil, and during which time the bath is put m readiness. It can be used in a drawing-ioom without soiling the cleanest carpet. As a Vapour Bath, it leaves nothing more to be desired, and is so durable as to be handed down from family to family, and, including the seat for taking the bath, it occupies but a foot and a half square. The whole is packed in a mahogany box, which slides and packs between the legs of the seat. It can be used locally or generally, and with the head inclosed or not, at the discretion of the bather. They were invented by the proprietor (an amateur engineer of acknowledged excellence), and never made with a view to profit ; and since the decease of Dr. Kentish are onlv to be had by order, to and from Dr. GREEN, No. 40, GREAT MARLBOROUGH STREET. description of the plate. A. The Bath, as being taken. B. The Boiler, with the safety-valve and connecting tubes, C. The Apparatus shown in perspective. 1. The Elbow- Joint, which attaches to the Boiler. 2, Connecting Tubes. 3. Folding Tube with Key, to control the Vapour. 4. The Disperser, into which perfumes may be put. 5. The foot- stool. 6. Caned seat. 7. Telescope upright, with Spring Hoop, to suspend the Curtain. GETTY RESEARCH INSTITUTE 3 3125 01360 0156