* m®WSI§ 3P^mXiI®S 14 THEORY OF COLOURS. in his late lectures on painting, decidedly prefers paint¬ ing in water colours to painting in oil . We shall now proceed to give a brief account of the Theory of Colours , as explained by the Philosophy of Sir Isaac Newton: One of the most interesting phenomena in nature ever subjected to philosophical research, is that which accompanies the emission of the solar light. Mankind were far from imagining that this subtile fluid, this agent of the numerous phenomena which constitute the life of nature, this generator of the varied colours which ornament the organized bodies that cover the earth and people the seas, belonged to the order of compound substances. The decomposition of it, discovered by the immortal Newton, and traced out in all its details by those astonishing experiments which compose his optics, soon became the basis of the theory which that learned author has established in regard to the nature of light, and to the origin of the colours that strike our organs of vision. Isaac Vossius, who lived before Newton, had enter¬ tained an idea, and even asserted, that the colours which tinge those objects that present themselves to our eyes existed in the solar rays. But this theory, supported by no kind of experiment capable of serving as an authority, was classed among the number of those ingenious hypotheses which occupied the philosophers of his time. The idea of Vossius was however realized by the experiments which the immortal Newton made with the prism. THEORY OF COLOURS. 15 This philosopher indeed proved that the rays of .ight, which he subjected to experiments both by ana¬ lysis and synthesis, were composed of seven primitive rays, each different from the other, not only by the variety of their colour but also by their different refran- gibility. From this decomposition of light he proved that these coloured rays, when separated from each other, and in some measure insulated, excite in us the sensa¬ tion of a fixed and primitive colour. The following is the order observed in the decomposition of a ray of light received on the refracting surface of a prism, com¬ mencing at the lowest: red, orange, yellow, green, blue, indigo, and violet *. The facility of separating colours, in analysing a bundle of rays, is the effect of the different refrangibility of each of these rays. Newton has proved also that the degree of the reflection of each coloured ray is propor¬ tioned to that of its refraction. • The ray of light having passed first through a hole in a window shutter of a darkened room, and being afterwards intercepted by a glass prism, became separated into seven distinct colours when thrown upon a dark ground ; these colours were all differently refracted, the red the least, and the violet the most. If considered as forming a circle, the proportions which each colour fills up in the circle is as follows: red 45; orange 27 ; yellow 48; green 60; blue 60; indigo 40; violet 80; in all 360. Sir Isaac next shewed that the same colours, when again put together, recomposed white light. This may be proved rudely by mixing together seven different powders having the colours and proportions above stated ; or by painting the rim of a wheel or a circular plane with the seven prismatic colours, and causing it to revolve rapidly round on the axis. In all these cases the mixture of colours will be a greyish white: for no colours can be obtained of such deli¬ cate tints as those obtained from light.— Editor. 16 THEORY OF COLOURS. The theory of colours was the necessary consequence of these experiments; the aggregate of which composes the system of optics, that masterpiece of human genius. It indeed follows from it. 1st. That a ray of light is composed of all the primi¬ tive colours, pure and unalterable, and therefore free from every secondary mixture that might weaken its essence. 2d. That every colour is produced merely by the de¬ composition of a ray of light. This phenomenon depends on the essential composi¬ tion of the bodies which concur to produce it; on the peculiar configuration of their surfaces, on their degree of density, and on their interior disposition, which ren¬ ders them capable of absorbing a certain portion of the ray of light, and of transmitting another to our senses. The coloured body appears then under the simple colour of the ray which is reflected. In some bodies the difference in the texture of their surface, in the nature of the laminae of which they are composed, as well as in their thickness, produces more varied phenomena of refraction and reflection, which concur to promote the union of several primitive coloured rays, and consequently to produce the appear¬ ance of secondary or compound colours : changing ma¬ terial colours arise from this cause. Intermediate colours might easily be made in the series of those given by the prism ; but one remarkable effect is, that the less compound a colour is, it is so much the brighter and more perfect. By rendering it gradually more complex, it is at length destroyed, the THEORY OF COLOURS. 17 ray of light being restored, such as it was before its decomposition. According to the theory of optics, white, which re¬ sults from the union of all the primitive coloured rays, and which constitutes a ray of light; black, which absorbs them entirely, and which is only the effect of that absorption, are not colours. The theory of mate¬ rial colours seems to contradict these ingenious results, which arise from a philosophical examination of the nature of light. White and black exist in substance. They seem even to concur towards increasing the num¬ ber of the primitive colours, in the order of material bodies. They become, at least, in the hands of the artist, new means and new agents to modify the tones of the positive colours of an earthy or metallic nature. The philosophy of the heavens seems to be richer in colours than that of the earth. The former admits of seven primitive colours; and four only are found in the latter, if we suppress white and black. Of this kind are yellows, reds, and greens, to which add the blue of ultramarine. * Indigo, blue, violet, and orange, are the secondary results of certain mixtures, by which art, the imitator of nature, has found means to approach those tones that belong to the seven primitive colours. By admitting white and black, which are employed on the palette of the painter, we shall have six colour¬ ing substances, with which all the different tints of nature may be imitated. It is by the help of simple or compound mixtures, that art is able to display the magic of illusion in fine paintings. 18 THEORY OF COLOURS. A knowledge of mixtures is not the least part of the art of painting. It is by means of these mixtures that the art has been enriched by establishing another order of colours ; that is to say, the factitious, secondary, or intermediate colours. It will be here proper to give a general view of the effect of these mixtures, and of the peculiar attributes of the primitive material colours. It will consist of a certain number of precepts, which are generally considered as inseparable from the art. Black increases the obscurity of all colours, and even effaces them, if the quantity be considerable and pre¬ dominant. White renders yellows, reds, and blues, lighter. The strength of the tints depends on the respective quanti¬ ties of the two substances mixed. When mixed with blue, the result is a more or less light tint, which re¬ presents the azure colour of a beautiful sky. White, judiciously mixed with yellows and reds, pro¬ duces a tint which approaches to flesh colour. If a little white lead be ground with very clear gum-water, by adding a small quantity of liquid red, and a little lemon yellow, you will obtain tints of flesh colour which may be varied ad infinitum ,. With reddish brown, the result will be beautiful crimson ; with red, a beautiful carmine colour. White, mixed with a little black, produces a more or less dark grey: with blue and a small quantity of black it gives a beautiful pearl grey. Yellow and blue give rise to several kinds of green, the brightness and splendour of which depend on the THEORY OF COLOURS. 19 manner in which they are combined : with thin liquid blue, you will obtain an exceedingly rich colour for miniature painting. Golden yellow and violet compose admirable liquid earth colours for miniature painting. A yellow colour may, in like manner, be obtained with an orange colour and yellowish green. Red or vermilion loses some of its splendour and hardness when the lights are brightened with white or with Naples yellow. Reddish brown and lemon yellow, mixed with gum- water, give an aurora colour. By adding thin liquid blue you will obtain a brown wood colour, which is a valuable discovery for miniature painting. Liquid red, mixed with violet, exhibits a rich purple : a greater or less quantity of either of these substances gives a crimson of different degrees of redness. Liquid red, with meadow green, gives a wood colour, which is employed in miniature painting to represent terraces and the trunks of trees *. Painters mix carminated lakes with cinnabar or ver¬ milion to produce the beautiful effect of bright red, in¬ tended to represent certain red parts, such as the mouth, the apertures of the nostrils, &c. All arts admit of general principles, which have been established by long experience. If those, a sketch of which has here been given, are acknowledged by the • When mention is made of a liquid colour, or of its mixture with gum- water, the case is applicable to miniature painting. The other combinations of colours relate to the other kinds of painting, and particularly to oil painting. 20 THEORY OF COLOURS. great painters; if they follow them in the execution of their masterpieces, they ought not to remain unknown to artists who devote themselves to house-painting, &c. nor to amateurs who are desirous of being initiated in every branch of this art. In general, great colourists devote their whole atten¬ tion to manage the white in shades, in order that they may avoid mealy and opaque tones. A mixture of oxide of lead and antimony, known under the name of Naples yellow, is a great assistance to them. It sup¬ plies the place of white in all cases when it is neces¬ sary to brighten the half tints, or to give reflection without experiencing all its inconveniences. With yellow also bright greys may be produced'in the shades, by mixing it with different blacks, and even with ultra- marine, when the composition is required to be rich and highly finished. Artists often agree in employing denominations wdiich express the state or extent of the composition of a sub¬ stance. Thus painters have given the name of virgin tints to those which are composed of only tw r o sub¬ stances, such as white and blue, white and red, white and yellow', white and lake, and so of the other simple combinations wdiich would result from the mixture of other colours without the white ; such, for example, as the green produced by Naples yellow and Prussian blue; the orange colour which results from a mixture of Naples yellow and red lead; the violet produced by a mixture of vermilion and Prussian blue. These vir¬ gin tints form second local colours, which some painters THEORY OF COLOURS. 21 introduce on their palette; like secondary colours, which are not simple shades of a coloured body, but the mixture of two or more primitive colours. All simple or compound colours, and all the shades of colour which nature or art can produce, and which might be thought proper for the dilferent kinds of paint¬ ing, would form a very extensive catalogue, were we to take into consideration only certain external cha¬ racters or the intensity of their tint. But art, founded on the experience of several centimes, has prescribed bounds to the consumption of colouring substances, and to the application of them to particular purposes. To cause a substance to be admitted into the class of colouring bodies employed by painters, it is not suffi¬ cient for it to contain a colour: to brightness and splendour it must unite also durability in the tint or colour which it communicates. But though a coloured substance may seem impro¬ per for the usual purposes of the different kinds of painting, it does not thence follow that it ought to be rejected entirely. Colours, the employment of which cannot be generalized without inconvenience, are ap¬ plied every day to particular uses in distemper and in the art of varnishing. Such, for example, are certain colours extracted from vegetables, which compose the light and dark Dutch pinks ; and which painters, jea¬ lous of the duration of the tints they employ, justly omit from their grand compositions. Such, also, are other substances furnished by the mineral kingdom, orpiment and realgar, which do not harmonize with 22 THEORY OF COLOURS. the colours most in use, and which at length develope destructive qualities, which they extend even to all ( metallic colours in contact with them, or which are near them. This destructive effect arises from the arsenic which forms a part of them. That piece of board distinguished by the name of the a painter’s palette is a real repository of the primitive co- lours, arranged in a line. Another line, parallel to the former, is destined for the compound or secondary co- i lours. The simple colours are white, Naples yellow, t ochre de rue , Sienna earth, still more beautiful than ochre de rue , red or burnt ochre, red earth or binut ochre de rue , vermilion, lake, Prussian blue, Saxon blue, ultramarine, black from burnt vine twigs, ivory black, &c. All these colours are ground in oil of poppy, and have the necessary consistence. Sometimes, when colours are applied to strata of paint, or to too recent sketches, the paint sinks, and assumes a grey appearance, which conceals the real colour of the tints. White of egg, beat up with a little spirit of wine, and then applied with a clean dry sponge, will restore their former lustre; but in all cases, with¬ out excepting those even which require celerity of ex¬ ecution, the painter who is desirous to ensure the dura¬ bility of his work, will take care not to apply varnish until the colours have become thoroughly dry, under the white of egg, which will not be the case until the end of a year. After this interval, the same sponge which served to apply the white of egg, if dipped in a little water* will remove it, under the form of a yellowish 4 DIFFERENT KINDS OF PAINTING. 23 froth. As long as gentle friction with the sponge pro¬ duces froth there is reason to conclude that the white of egg is not entirely removed. This intermediate application of white of egg, be¬ tween the period when valuable paintings are finished and that when they are varnished, is attended with two advantages, as it defends the colours from the prejudicial action of the air, and frees them from a yellowish tint which arises from the oil, or perhaps from the colours themselves. If these conditions be strictly observed, the colours will appear under the varnish in all the beauty and richness of their tints. Some of the English painters, too anxious to receive the fruits of their com¬ position, neglect these precautions. Several artists even paint with varnish, and apply it with the colours. This precipitate method gives brilliancy to their compositions at the very moment of their being finished; but their lustre is temporary, and of short duration. It renders it impossible for them to clean their paintings ; which are besides liable to crack and to lose their colour. In a word, it is not uncommon to see an artist survive his works, and to have nothing to expect from posterity. It will be now desirable that the young artist should become acquainted with the different kinds of 'paint¬ ing which have been practised in various ages. Some of these have been alluded to in the preceding part of this Introduction; but w r e shall here present the reader with the result of our researches on this curious as well as useful subject. Painting in Distemper is generally considered the first kind of painting adopted by the ancients. Dis- 24 DIFFERENT KINDS OF PAINTING. temper was a sort of water colour painting, the ground of which was whiting mixed with yolk of egg. The vehicle employed for the colours was^a mixture of yolk of egg with the milky juice expressed from the young stalks of the fig-tree, except in the case of blue, or of colours inclining to blue, on which occasion the vehicle w'as common g lue.' s In this process every colour was used that was proper for any mode of painting. The strongest size was always used in the last coating of colours. There is, besides, reason for assuming that such pictures were, at least in the time of Apelles, varnished. Painting in Fresco is performed on a ground of plas¬ ter spread over a wall, or other surface, of which plaster the artist puts on only so much as he can paint over while it remains in a moist state : for if artificial means be used to delay the drying, the colours become spotted and imperfect when dry. The materials of painting in fresco are also limited, as no pigment can be used that will not bear the action of lime. Hence, although some admirable paintings were formerly executed in fresco, the extreme difficulty and nicety of such an art have caused it to be laid aside. Encaustic Painting has been sufficiently described in page 4. Painting in Oil scarcely needs to be described; it consists in mixing the colouring material with either linseed, nut, or poppy oil, &c. by finely levigating them together, and applying the paint of a suitable consist¬ ence to the cloth or other material to be painted. The discovery of mixing oils with the colours for painting. DIFFERENT KINDS OF PAINTING. 25 is ascribed to John Van Eych, of Bruges, who died in 1441. The discovery soon spread over Europe, and has ever since Jbeen the most usual mode in which painters have chosen to depict their objects. Yet there are some serious objections, nevertheless, to this mode of painting; one of which is the constant tendency which oil has to become discoloured by age, and hence to alter the colours with which it is combined in the painting ; indeed, Mr. Craig considers minting in water colours, of which we have next to speak, as far preferable to that in oil. It should be stated here, that some of the earliest painters in oil laid on their colours on red, or other dark grounds, so that the subjects of their pictures have become scarcely dis¬ cernible, while the productions of others who painted thinly over a white ground remain to the present time, with very small variation of the original colour. Hence a white ground is of the utmost importance in paint¬ ing. By white ground here is not to be understood a snowy white, but rather the yellowish white which is given to what is termed by the painter primed cloths , and on which most oil paintings are now executed. Painting in Water Colours , as now practised , had its origin with Mr. Sandby, and so far as his principle has been pursued, it is founded in the soundest deductions of reason and philosophy. It consists, of course, in the admixture of the colouring materials with some gummy matter which is soluble in water, and then applied of a suitable consistence to the ground, which, for water colour painting, should be the pure surface of a fine white paper. One of the principal objections to paper c 26 DIFFERENT KINDS OF PAINTING. is its not being to be obtained in one piece of a size sufficiently large for a large picture; and another, its extreme frangibility. But it has been contended, never¬ theless, that even Titian, and others, painted a part of their pictures in distemper, and afterwards executed the remainder in oil; and that water colour painting, such as it is now understood and practised, is the most permanent mode of painting at present known *. It is not, however, our province to determine this question; we must therefore proceed to notice, Painting in Crayons. Crayon, the French name for 'pencil , is a solid substance, either natural or artificial, adapted for making marks on paper or other materials. Crayons for painting are, of course, formed of different materials and of various colours. They were at first called chalks, from chalk , itself a white crayon, and serving as a basis of many other colours. Painting in crayons has its admirers, and where the picture can be kept dry it will continue for a long time to retain its colour, although we do not think this style of painting is one which will ever be greatly in request. Indeed it is by many considered “ as transient and fleeting as the flower of the field.” Painting in Enamel consists in painting with metal¬ line colours, ground, and used like other colours with a pencil, then covering them with a powdered enamel, which is vitrified by fire in a furnace. This art is very * A paper on Printing in imitation of Coloured Drawings, by Mr. W Savage , will be found in vol. 43, p. 67, of the Transactions of the Society of Arts, which those interested in drawing should consult. It is not consistent with the objects of this work to do more than notice that paper here.— Editor. COLOURS. 27 ancient, and appears to have been first practised on earthenware. Pictures in enamel are still occasionally painted ; but the art of enamelling is chiefly employed in the embellishment of porcelain, and other earthen¬ ware. Among modem painters in enamel Mr. Bone is particularly distinguished. Writers on the higher branches of painting, among whom we may mention here Mr. Craig , to whose lec¬ tures we have before alluded, usually consider the fol¬ lowing as the Colours necessary to the painter : blue , yellow , orange , red , purple , violet , and green ; to which must be added black and white , although white implies, in optics, the presence of, and black the absence of, every colour. Colours are also distinguished by the painter into warm and cold. By warm colours are understood those which attract and appear to approach the eye : they are yellow , orange , and red , and such compounds as de¬ cidedly incline to them. The cold colours are violet , blue , and green , and such mixed colours as have blue for their principle. Yet the three compound colours, as denomi¬ nated optically, may be either warm or cold, as partak¬ ing most of the red or yellow on one side, or of the blue on the other. Hence, although our definitions of warm and cold colours are true to a certain extent, they are, nevertheless, liable to considerable modification. To the colours have been attached emblematical i significations; thus yellow has been understood to re¬ present lustre and glory; red , power and love; blue , C 2 28 COLOURS. divinity; purple, authority ; violet, humility ; and green, servitude. Colours are harmonized by their intermediate com¬ pounds : red and yellow by orange; blue and yellow by green ; and red and blue by purple or violet. Colours may be contrasted, and even beautified, by placing them on other colours of a compound nature, in which one element is the same as the colour to be contrasted. White suits well on any darkish-coloured ground, and with any light one, except yellow and blue,both ofwhich lose a great part of their brightness by the vicinity. Light-yellow has much clearness and beauty on purple and green ; light blue suits well on green, violet, and yellow not very pale; light-green, inclining to yellow, has a good effect on purple, violet, and blue; but red upon red, purple upon red, or blue upon a darker blue, should never be allowed, unless there be means of con¬ trasting the upper colour so by some opposite one in its neighbourhood, as to restore the degree of colour it will seem to have lost by being placed on a darker tint of its own kind. But though the preceding directions constitute the chief in regard to the disposing of his colours, which the painter in the higher branches of his art may se¬ curely follow, yet his subject must be so contrived that near each colour there shall be introduced some small portion of its opposite, that the value and true colour of each may be made evident, without enforcing it so as to injure the principle of harmony, which is above all considerations to be studied. Thus, near white must HOUSE PAINTING. 29 be introduced some small portion of dark, or its white¬ ness will not appear ; near orange or scarlet, parts that have a tendency to blue, grey, or cool green ; near purple, somewhat of yellowish green ; and near blue, something inclining to orange, tawny, or red brown. Having given in the preceding parts of this Introduc¬ tion some historical sketches of the progress of the art of painting, as well as some account of the theory of light and colours, we will now descend from the superior branches of the art to the humble, yet nevertheless more useful and convenient, art of House Painting. Here it may be observed, that many colouring bodies which artists who paint pictures reject are, notwith¬ standing, extensively employed by the house painter. The changes which take place in the tone of colours do not produce such important effects as in a painting, where very often the least change in the tints destroys the harmony, contradicts the rules of perspective, and substitutes for the real tones of nature tones which are absolutely foreign to it. In the application of the colours which house painters, &c. intend for varnish, the transition is insensible, be¬ cause it is general. Nothing offends the eye which becomes accustomed to that transition, which may even deviate from the first tone; and if the effect no longer appears to be the same, where remembrance recalls the first moment when the painting possessed all its fresh¬ ness, it however exhibits nothing disgusting. This consideration is sufficient to authorize the use of more common, and consequently less expensive colouring c 3 30 HOUSE PAINTING. substances, in cases in which the artist has to supply an extensive consumption. It will be here useful to make a few observations on the Laws of Harmonious Colouring adapted to House Painting , and this we are enabled more effectually to do, by reference to a very ingenious treatise on the sub¬ ject published at Edinburgh a short time since by Mr. D. R. Hay , who defines harmonious arrangement of colours to be such combinations as, by certain prin¬ ciples of our nature, produce on the sense, by which they are perceived, the effects of pleasure or delight. “ These combinations,” says Mr. Hay , “ which had been previously recognized as the foundation of excel¬ lence in colouring, long before any theory had been advanced on the subject, received full confirmation, from the phenomena discovered by Buffon , and illus¬ trated by succeeding philosophers, to which he gave the name of accidental colours , and which are ob¬ served when the eye becomes fatigued by the con¬ tinued action upon the retina of the light of any par¬ ticular colour. “ If we look steadily for a considerable time upon a spot of any given colour, placed on a black or white ground, it will appear surrounded with a border of another colour. For instance, if a spot be red, a green border will appear, and if we direct our eye to another part of the white or black ground, we shall perceive a green spot of the size and form of the red spot. This is the accidental colour of red; and by this means the accidental colour of every tint may be found. “ The strength or intensity of a colour is therefore HOUSE PAINTING. 31 much increased by being placed near its contrasting or accidental tint; and it will be observed that its value, in reference to brilliancy, will not be in the ratio of its actual strength or intensity, but will depend much for its force and beauty on the manner in which it is grouped or disposed in respect to the parts immediately contrasted with it. Thus red derives peculiar clearness from being contrasted with green—blue with orange— yellow with purple; and their various mixtures and compounds will be subject to the same laws. “ In arranging the colour’s for an apartment, whether a few or a great variety are to be employed, the effect of the whole, as well as the several component parts, will depend on the skilful arrangement, as pointed out by the accidental or contrasting colours. But as the direct union of two such opposite elements as any of the prismatic or original colours with its contrasting one, is harsh and unpleasant, a third is required to make a full concord; this is called the harmonizing colour , and will consist of the original, diluted with the colour in the next weakest degree of brightness—thus orange will form the harmonizing colour to yellow, red to the orange, violet to red, &c. “ But as harmony consists more in the media which unite the several colours, than in the colours them¬ selves, and as the greatest distinctions in nature are reconciled by an imperceptible adjunct, it becomes necessary, in completing the arrangement of colours for an apartment, that a neutralizing colour, possessing the properties of both contrast and harmony should be introduced. This will always be found the most diffi- C 4 32 HOUSE PAINTING. cult part; it is this which gives tone, keeping and repose to the whole, and prevents that confusion which an assemblage of parts of equal strength will always produce. “ An able writer attributes the inexpressibly pleasing effect of the mode of house-painting practised by the Italians to their knowledge of the rules of harmony alone; and observes that their bold and vivid tints melt into each other with all the skill and harmony of a piece of brilliant music. This proficiency, he adds, is not confined to the decoration of palaces, but is seen in dwellings of a much humbler cast, and indeed in general practice. “ In the opinion of the same author, house-painting might, with study and acquirement of correct taste, and more extensive information, resume its rank as a liberal art. “ The house-painter’s styles must not only be as various as the uses of the apartments which he de¬ corates, but must vary according to the different tastes of his employers. He must also take into consideration not only the style of architecture, the situation, whether in town or country, but the very rays by which each apartment is lighted, and whether they proceed directly from the sun, or are merely reflected from the northern sky. He must confine himself to neither a vivid, sombre, nor cold style of colouring; all must be equally at his command, and, in all, the same strict attention to harmony must be observed. “ The house-painter has often another very serious difficulty to encounter—a variety of highly and va- HOUSE PAINTING. S3 riously coloured furniture is shown to him, to which the colouring of the different parts of the room must be suited. It is here that his powers of balancing, har¬ monizing, and uniting are called forth; it is this which obliges him, as Sir Joshua Reynolds says of the artist, ever to hold a balance in his hand, by which he must decide the value of different qualities, that when some fault must be committed, he may choose the least. “ In toning and harmonizing the colours in a pic¬ ture, an artist has the assistance of light and shade, and can make his shade accord with the tone in such a manner as to improve the general harmony; but as the house-painter’s colours are all liable to be placed in full light, they must be toned in themselves, to prevent that unnatural crudeness so annoying to the eye In treating of the colours for house-painting indivi¬ dually , Mr. Hay makes some very pertinent observa¬ tions which are of considerable importance to the painter, for which we cannot here find room, but must refer the ingenious artist to the work itself. We may, notwithstanding, observe, that he names ten colours as those which are principally used, or from which are compounded the numerous tints that we find prevail in the different kinds of painting. Most of the colours mentioned admit of almost an infinite variety of shades; even of white have been named eight dif¬ ferent tints, from the purest to that of French ivhite , * The Laws of Harmonious Colouring adapted to House Painting , by D R. Hay, of the firm of Nicholson and Hay, House Painters, Edinburgh.— Edinburgh, printed for D. Lizars, 1828. c 5 34 HOUSE PAINTING. which is, properly speaking, the lightest shade of purple. Of red , too, besides scarlet , crimson , 'pink , and rose, how many others exist ? Of yellows , greens , and blues what an almost innumerable variety ! Indeed it has been said that there are one hundred and ten standard colours , and that their various tints and mixtures could be multiplied to thirty thousand ! However we cannot go into such details. But it will be, nevertheless, ex¬ tremely convenient to give a tabular view of the chief colours, and their contrasting and harmonizing colours, as a guide to the young artist. For the facts we are indebted to Mr. Hay's work ; the tabular arrangement is our own. t Chief Colours. Contrasting Colours. Harmonizing Colours. White .Black .. Light shade of Yellow. „ _ _ . ( Orange, Pomona, or Yellow .Deep Purple. £ Yellowish Green. Orange .Intense Blue. Red. Red (Scarlet).Intense Green. Crimson. . ^ Blue (ultramarine).. Orange.. Indigo. Green. • Intense Red. Yellow. Purple or Violet- • • • Yellow ... Crimson. Black. .White i Light shade of Yellow [Grey or Dove.] Indigo is the medium between the deepest blue and violet. HOUSE PAINTING. 35 It must be admitted that, notwithstanding the pre¬ ceding colours , with their contrasts and harmonizing tints are, under all circumstances, the best that can be mentioned, especially for house painting, yet the in¬ genious artist will, doubtless, occasionally refer to what is stated in regard to colours and their contrasts, when applied to the higher branches of the art, in a pre¬ ceding section. He cannot fail, besides, to observe, that red is a very good contrast to white; that a grey or dove colour harmonizes well with white or black, &c. In truth, after all, considerable latitude is allowable in the combination, contrast, and harmonization of co¬ lours. No one can, nevertheless, for a moment doubt that white and black are complete contrasts, and are seen to the greatest advantage when placed in juxta¬ position : the same may be said of many other colours. We must now conclude these introductory observa¬ tions. In the next chapter we shall describe the dif¬ ferent substances which the painter employs. CHAPTER II. Descriptive account of the Earthy, Metallic, and other mineral substances used in Painting, with a detail of the processes employed to extract them, and of the methods of preparing and modifying them. The account given in our Treatise on Varnishes, of the substances which enter into their composition, must tend to regulate the application of them in a more certain manner. The substances which are applied to painting are much more numerous, and the pro¬ cesses by which many of them are obtained, are more varied, and require, therefore, in the painter his most sedulous attention, in order that the best results from his art may be obtained. We have deemed it necessary to arrange the sub¬ stances used in painting under three heads. In the present chapter we shall treat of earthy, metallic , and mineral substances; in the next of animal and ve¬ getable colouring substances; and under the third head we shall treat of the vehicles used for the colours of paints, as well as of certain Gums, Glues, and Driers. In regard to the colouring substances used in painting, it may be mentioned generally, that in those earths or other substances in which a red colour is predominant, iron may be suspected as the basis of such colour; there are, nevertheless, several exceptions to this, in- COLOURiNG SUBSTANCES. 37 stanced in red lead and vermilion , as well as the vegetable and animal reds; although in the two last named, many philosophers have attributed their colours to the presence of iron finely attenuated. For some time after the discovery of oxygen, it was supposed that the red colour of the blood was owing to the iron contained in it; but this opinion is not, at the present time, generally entertained. Many of the earths also owe their brown and yellow colours to the presence of iron, instanced in the nu¬ merous ochres and umbers; in dyeing, the most per¬ manent buffs are produced by the intervention of iron Yellow is besides obtained from lead , quicksilver , and arsenic; as well as innumerable vegetable substances. It may be noted, however, that the most permanent colours are those obtained from earthy and metallic substances. Blue and Green colours, in natural pigments in par¬ ticular, often indicate the presence of copper; yet we find both blue and green produced by iron; blue also by cobalt ; and the fine blue of ultramarine by some colouring material not yet, perhaps, determined, al¬ though it has been stated to be a particular combina¬ tion of iron and sulphur. The chief blacks are produced by incineration of vegetable or animal matter, the basis of all such being, of course, charcoal. But some blacks, not of a very in¬ tense kind, are also obtained from minerals; these are mostly sulphurets or oxides of some metal; an indif¬ ferent charcoal is also obtained from the fuel called coal. The whites are obtained either from the earths , 38 COLOURING SUBSTANCES. metallic oxides, metallic carbonates, or animal shells, bones, fyc. It is rather remarkable that no white matter, used as a pigment is extracted from vegetables; it is true we have the alkaline salts, many gums, and starch ; but these may be considered as either ingredients in or vehicles for other colouring matters. In analysing, therefore, new substances offered to the notice of the painter, it will be desirable to keep the preceding observations in view, in order that our analytical processes may be, in all probability, much shortened, and the best results of our inquiries most satisfactorily obtained *. It is necessary also here to observe, in order to faci¬ litate the knowledge of the terms used in this treatise, that modern chemistry having attained the rank of an exact science in many of its combinations, and espe¬ cially of those substances used in painting, a know¬ ledge of that science is extremely necessary for the painter, in whatever department, who is desirous of becoming a proficient in his art. It is not consistent with the limits of this work to give an epitome of che¬ mistry, but it may be nevertheless useful to state that many of the preparations of lead, iron, Sac. used in • Persons who desire to obtain a competent knowledge of Chemistry are referred to those able modern writers who have treated with perspicuity and talent on that science ; they are numerous, but Braude's and Thomson's Che¬ mistry may be particularly mentioned, as well as lire's Chemical Dictionary, and Berzelius on the Blow-pipe , translated, with the addition of valuable notes by Mr. Children. Jennings's Family Cyclopaedia may be also men¬ tioned as containing much useful chemical information. COLOURING SUBSTANCES. 39 painting, have now applied to them different names from those which they formerly had, in consequence of the component parts of those substances having been correctly ascertained. Thus red lead or minium is now called red oxide of lead , it being found that it is a compound of lead and oxygen; the term red is added to it to distinguish it from other oxides of the same metal, possessing larger or smaller portions of oxygen. White lead is now called carbonate of lead , being composed of lead and carbonic acid. Litharge , it should also be mentioned, is an oxide of lead , but it contains less oxygen than red lead. The process of obtaining most of the oxides of metals was formerly called calcination , but now more properly oxidation. This last term has, however, a much more extensive meaning than calcination, which implies a process carried on by the agency of heat. Oxidation is often produced by heat; but it also takes place in the ordinary temperature of the atmosphere, and is exemplified in the rusting (i. e. oxidation) of many of the metals: hence the rust formed on metals, whether lead, copper, or iron, &c. is an oxide produced by the metal absorbing oxygen from the atmosphere. The rust of copper used for producing a beautiful green in painting, formerly, and now usually called verdigris , is, however, a sub-acetate of copper; that is, copper combined with the acetic acid, by a process well known in the wine countries, where the acetic acid exists in the husks and stalks of grapes after the juice is expressed from them. See the preparations of copper , lead , iron , 40 COLOURING SUBSTANCES. The chief acids with which the painter has concern, are the sulphuric acid , formerly called oil of vitriol; the nitric acid, formerly called aquafortis ; muriatic acid (the basis of which is chlorine) formerly spiri t of salts; the acetic or pyrolignous acid , in a diluted state called vinegar ; and the carbonic acid , called by its dis¬ coverer, Dr. Black, fixed air; the base of this last is carbon , or pure charcoal , which, united to oxygen, forms that gaseous acid so universally known in all kinds of fermented liquors. The sulphuric acid (consisting of sulphur and oocygen), combines with various bodies, forming sul¬ phates; it is found abundantly combined in nature with almost innumerable substances. With lime it forms gypsum , so well known; alabaster is also one of the forms of sulphate of lime; white chalk , marble , and other lime stones are carbonates of lime. Sul¬ phuric acid combines also with many of the metals, forming likewise sulphates; thus green copperas, pro¬ perly sulphate of iron, is a combination of iron and sulphuric acid; blue copperas is a combination of copper and the same acid, and now called sulphate of copper; white copperas is composed of zinc and the same acid, and now called sulphate of zinc; while sugar of lead is composed of lead and the acetic acid, and hence more properly denominated acetate of lead. The other acids mentioned also combine with many of the metals and other bodies, forming respectively nitrates, muriates, &c. &c. The combinations of sulphur with many bodies, without being previously converted into an acid, are 4 COLOURING SUBSTANCES. 41 called sulpliurets. It is found in nature thus com¬ bined with many metals. Galena , the ore whence the greater part of the lead of commerce is obtained, is a sulphuret of lead. Native cinnabar is a sulphuret of mercury , and is the chief ore whence quicksilver or mercury is obtained. Sulphur may be artificially com¬ bined with some metals, forming sulphurets; thus quicksilver poured into melted sulphur combines with it, forming a reddish black mass, which, being sub¬ limed, becomes the factitious cinnabar of the shops, properly red sulphuret of mercury; this, being finely levigated, becomes the vermilion , so well known to the painter. It should be noted, in concluding these chemical preliminaries, that some gases affect the colours, and more especially the more delicate colours of paints, much more than others, although w r e are not in pos¬ session of sufficient data to give rules on this subject; nor can we name all the gases which are more imme¬ diately injurious to colours. It is a curious fact, that when white lead is exposed to the vapours of sulphuretted hydrogen , it becomes black, being converted into a sulphuret. This white pigment, employed with oil, and covered with varnish, which excludes the air, may however be preserved for many hundred years, as the paintings of the fifteenth century prove. When the varnish is abraded or de¬ cayed, the whites of ceruse are apt to contract black specks and spots, which ruin fine paintings: minia¬ tures, in water colours, are frequently injured in the same way. 42 COLOURING SUBSTANCES. M. Thenard having turned his attention to these facts, discovered, a few years since, that water, which he calls oxygenated water , that is, water having six times its usual volume of oxygen, on being applied to a fine picture of Raphael, spotted black, removed the stains, as if by enchantment, without affecting the other colours in the slightest degree. Hence it is also concluded, that white paint, of which lead is the basis, so soon turns yellow in crowded cities, in consequence of the atmosphere in such cities being highly impregnated with sulphu¬ retted hydrogen. In corroboration of this, it may be also observed, that, in the open country, and in the open air, free from the contamination of smoke, white lead paint becomes -even whiter by exposure to air. Besides the effect of air on paint, its colours are more or less affected by the presence or absence of light; and although varnish excludes air, the painting is still, of course, more or less pervious to light, which occasion¬ ally alters the colours of even varnished pictures. In what the affections of light on colours consist does not appear to be accurately known; but that light does, in very many instances, alter the colours of paint, is proved beyond dispute. Whatever be the causes of the discolouration of paint, the subject is highly deserving the attention of the ingenious painter, and more especially of him who is engaged in the higher branches of the art; and not¬ withstanding his colours are often protected from the immediate contact of air by a varnish. BOUGIVAL WHITE. 4 3 On the chief Whites used as Pigments. As whites are pigments which constitute the bases of many other colours, as well as forming, with oil and other vehicles, important pigments of themselves, we shall first treat of the chief substances which are usu¬ ally employed for white , although not exactly in the order which we have prescribed in this chapter. Bougival White. Painters often employ white substances for grounds. White lead is distinguished by great durability. It forms an excellent priming, proper for receiving other colours ; but there are a great many cases, particularly in painting in distemper, which admit the use of a more common and less expensive white, such as that of Bougival, Spanish white, white of Troye, &c. Bougival white takes its name from the place whence it is extracted, near Marly, a few leagues from Paris. It is a very fine marly earth. Normandy, Auvergne, and many other districts, contain beds of a white earthy matter, commonly known as tobacco-pipe clay. This earth, when very white, is much better for house¬ painting than earth of a calcareous nature, such as chalk. The celebrated Wedge wood, whose manufac¬ tory of earthemware equals the finest porcelain, was exceedingly nice in his choice of this clay, some of which he obtained from Normandy. But the same nicety is not necessary in painting. Body and white¬ ness are the principal characters required. Bougival 44 CREMNITZ WHITE. white, if not a pure clay, possesses that whiteness which assigns it a conspicuous place in the order of colouring bodies. It is sold in oblong cakes, into which it is cut, after the small stones and sand mixed with it have been separated by washing. Washed chalk is often substituted for it, but it is easy to detect the fraud. Washed chalk gives less body to painting than clay, and does not unite so well 'with oil when applied to that kind of painting. According to some experiments made with Bougival white, from Marly, it contains nearly one-third of chalk. This mixture renders it inferior in oil painting to real Spanish white, and to white of Moudon. Cremnitz White. The composition of Cremnitz white seems still to be very uncertain. Three substances, which have nothing in common but the name given to them, are sold under this denomination. Expeiiments made with specimens obtained from different colourmen, did not justify the opinion that this white is merely oxide of tin; in several was found oxide of bismuth; and in two par¬ ticular cases carbonate of lead. It did not appear that any of them contained oxide of tin. Two of these specimens seemed to be mixed with a great deal of chalk. The Cremnitz white, which con¬ tained this mixture, was in cakes of about two or three inches square, and different in thickness; but it never exceeded an inch. Cremnitz white, made with bismuth oxidated by CREMNITZ AND BRIAN£ON WHITES. 45 means of nitrous acid, or in any other manner, pos¬ sesses no advantage over that which has lead for its basis. It is more liable to be altered by the action of the light, and of the vapours which arise from stagnant water, privies, &c. Another Cremnitz White. The following is a beautiful pearl white: Take the oxide resulting from the rapid solution of tin in nitric acid, to which add a fourth part of oxide of zinc, and an eighth of white clay, extracted from Briangon chalk washed in distilled vinegar. (See below). This mixture, when thoroughly washed, dried and sifted through a silk sieve, gives a very white powder of a mean gravity; and so secure from all changes effected by the action of the light and of va¬ pours, that no composition of this kind can be com¬ pared to it. It is certainly too expensive for house painting; but it may be useful for objects which require other processes than those employed in common. It would, no doubt, be attended with great advantage in painting pictures. Were it necessary to substitute any other metallic substance, lead ought to be preferred to bismuth. To prepare Briangon White. Select the whitest specimens, and rasp them with a piece of the skin of the sea-dog. Put the powder into a jar, with a quart of good vinegar for every pound of the powder : stir the mixture daily for two weeks, and decant the vinegar without agitating the deposit : then 46 SPANISH WHITE. pour clean water over the deposit, and, having stirred it, throw the whole upon a filter, by which means the water of the first washing will be separated. Continue to pour more water over the sediment on the filter, till the w^ater which passes is found to be insipid. Then spread out the filter with the sediment on a hair sieve, sheltered from dust, and dry it till it appears under the form of a white powder. The vinegar here separates from this argillaceous matter all the soluble parts, which might alter its unctuosity; and particularly the ferru¬ ginous particles which are often mixed with it. The division of Briancon chalk-may be effected by pounding it in water, which must be frequently de¬ canted when it contains only the fine parts. Spanish White. Spanish white is a pure clay, which may be washed in vinegar to separate such calcareous parts as are mixed with it. But this process ought to be employed only in particular cases, when it is necessary to have it exceedingly pure. Its argillaceous nature contributes to the solidity of the ground, when it is employed in oil painting or for varnish. It acquires body; but in these cases it must be used very dry, like all other earths. When moist, their union with oil and varnish is im¬ perfect : they granulate under the brush. Rolls of washed chalk, which possess none of the qualities required in Spanish white, are often sold in the shops under the same denomination. The difference, however, between real Spanish white and the chalk attempted to be sold in its stead, may be GYPSUM. 47 easily ascertained. Nothing is necessary but to pour upon the specimen a few drops of nitric acid or strong vinegar. If the Spanish white be pure, there will be no effervescence ; if an effervescence takes place, it is owing to a mixture of chalk. In this case, take some small fragments of the white and immerse them in half a glass of vinegar: if they disappear entirely with effer¬ vescence, the whole is calcareous ; if any part remains, it will be argillaceous. The quantities of each of these earths may then be estimated merely by the eye. Gypsum , or Sulphate of Lime. Gypsum, or sulphate of lime , is a genus of calca¬ reous earths, consisting of several species. The chief of which are alabaster and plaster of Paris. When deprived of its water of crystallization, either by being powdered and boiled alone in an iron vessel, or baked in an oven, or calcined in an open fire, it is exceedingly useful in the arts. In this state it is employed in building, and in decorations for apartments. It is often used also with success in agriculture. Plaster of Paris , as prepared gypsum is usually called, when mixed with water, in order to be cast in moulds, is subject to certain rules. To give it a proper consistence, the water wdiich it has lost by calcination is sufficient. If too large a quantity be added, it weakens its force, prevents it from acquiring body, and renders it what is called drowned plaster. In preparing it to be employed as a white colour in house-painting, it ought to be mixed w T ith a great deal of water. This superabundance of liquid keeps all its 48 ARTIFICIAL SULPHATE OF LIME. parts separated, and favours the required division. When divided in this manner, it forms a very valuable article for whitewashing apartments, and for painting in distemper. The last operation is very simple. When diluted with a great deal of water, stir the mass with a broom, and suffer the powder to be precipitated. Decant the supernatant water as soon as it is clear ; then wash the matter a second time, and dry the sediment after the liquor has been poured off. This wdiite is exceedingly fine, and more delicate than that of chalk when the calcined gypsum is pure ; that is to say, without any mixture of clay. Plasterers do not hesitate to substitute this substance in the room of white lead, wdiich is not superior in beauty, but which is more durable and dearer. When too thick a coating is applied, it rises in scales, which is not the case when white lead is employed. Artificial Sulphate of Lime. Put eight pounds of rock lime into a four-gallon pan; pom* water upon it by degrees till it falls into powder; fill the pan with water, and let the lime be well mixed with it; when it has subsided for a minute, place a fine hair sieve on the top of a cask sufficiently large, and pass the thin part of the mixture through it; add more water to the lime in the pan, mix well, and pour the more liquid part as before through the sieve. This process is to be repeated till six gallons of the mixture are obtained. Into another cask put eight pounds of alum and six gallons of water; when the alum is dis- WHITE OF MOUDON. 49 solved, pour the solution into the mixture of lime, which must be stirred well with a wooden spatula for half an hour; let it remain for three hours, and then stir it again. The next morning it will be fit for use. If too thick, water must be added : it should be about the consistence of thick cream. See Vanherman's House Painter, page 17. This preparation is sometimes called satin~white , and is used chiefly by paper stainers. Although this is called artificial sulphate of lime , the chemical artist must not forget that alum is composed of alumina, potash, and sulphuric acid; and as, in the above process, no means are taken to separate the potash and alumina, the mixture not only contains sul¬ phate of lime , but also alumina and potash. White of Moudon or of Morat, Is obtained from the Pays-de-Vaud, in Switzerland; it is an argentine, silky white, of an exceedingly fine grain. The names are given to it, because the place where it is extracted is in the neighbourhood of Moudon and Morat. It is a real Spanish white, a pure clay, which is employed with success in our manufactories of paper-hangings. Our druggists often sell it as an ab¬ sorbing earth, under the name of nitrous panacea, and even under that of magnesia; though it stands the action of acids without giving the least signs of effer¬ vescence. This earth would^afford a great resource to a manufactory of white lead: when united to that oxide, it forms, in oil painting, pearl or dark greys, which are durable, and possess great lustre, D 50 WHITE LEAD. White Lead , or Carbonate of Lead. Lead, when in the state of an oxide, or as a white carbonate, has the peculiar property of combining with the fixed oils, with which it forms an indurated sub¬ stance, which resists the action of the atmosphere, and tends admirably to preserve the materials over which it is laid. White lead has been therefore long used as one of the chief pigments. It is unfortunately of a very poisonous nature : and although many attempts have been made to supply an article equally useful, without such deleterious qualities, they have not been hitherto successful. White lead , carbonate of lead , or' ceruse , as it was formerly called, is prepared in the large way, by ex¬ posing sheet lead to the action of the vapour of vi¬ negar. It is found in the shops in the form of a heavy white powder, interspersed with occasional lumps; it is in¬ soluble in water. It is often adulterated with chalk, which may be discovered by pouring distilled vinegar on the suspected carbonate, and then adding oxalic acid to the solution. The formation of a precipitate proves the presence of the chalk. Flake white appears to be merely carbonate of lead, rendered more pure by being washed, and levigated with water, and formed into drops by being passed through a funnel, and laid on chalk to dry. It may be however made, by dissolving litharge in diluted nitrous acid, and adding prepared chalk to the solution. White lead is obtained by different processes; the following is considered one of the best. WHITE LEAD. 51 Sheets of lead about two feet long, five inches broad, and a quarter of an inch thick, are rolled up in loose coils, and placed in earthern pots, each capable of holding six pints of fluid, but into it as much vinegar only is poured as will rise so high as not to touch the lead, which rests on a ledge half way down. The pots are then buried in fresh stable litter, where they remain for about two months, during which time the vapours of the vinegar, elevated by the heat of the dung, oxidize the surface of the lead, and the oxide combines with the carbonic acid gas evolved from the fermenting ma¬ terials of the bed. The carbonate appears as a white scaly brittle matter on the surface of the lead, and is separated by spreading the coils upon a perforated wooden floor, covered with water, and drawing them to and fro by rakes, which process detaches the white lead, and causes it to sink through the water and the holes of the floor to the bottom of a vessel placed below. It is afterwards ground in mills with water, and then dried in earthern pans, placed in stoves. It was formerly ground dry, by which method, from its deleterious nature, the workmen suffered severely. To obtain white lead of a very fine quality, it ought to be levigated several times. It is sometimes pre¬ served for delicate purposes under water, in glass vessels; but it is, nevertheless, more commonly to be obtained as flake white , or in the still more common form as above described. Mr. John Sadler obtained a patent, in 1821, the process described in which, for obtaining white lead, consists in decomposing the subacetate of lead, com- d 2 52 WHITE LEAD. monly called Goulard's extract, by submitting it to the action of carbonic acid, either in closed or open vessels, when a precipitate is formed, which is the carbonate of lead, or white lead. This precipitate is separated and dried in the same way as white lead is usually treated. Whether, upon the whole, this be a preferable method to the common ones now in use, we do not particularly know, but we presume it must be, or a patent would not have been obtained for it. Yet we do not exactly comprehend how a subacetate can be decomposed by the weaker acid—the carbonic ; and can scarcely think agitation alone equal to the effects said to be produced. Is all the process specified ? Another patent for the manufacture of white lead by the agency of steam, was obtained by Mr. John Ham, of Bristol, in 1826. We think this deserving the notice of the manufacturer; but our limits prevent detail. See Journal of Arts, vol. xiv. p. 90. As the preparation of white lead is of considerable importance, we cannot omit a notice of one other patent obtained by Mr. Groves, in 1826, for converting sulphuret of lead, commonly called lead ore, into white lead, by the agency of nitrate of potash and sulphuric acid. From the specification, as described in the Journal of Arts, vol. xiv. page 369, and from the con¬ centrated sulphuric acid employed, we are obliged to consider this preparation a sulphate, and not a car¬ bonate of lead ; and we are not prepared to state that a sulphate of lead is equally useful as a pigment with the carbonate. Indeed, from the strong attraction which the sulphuric acid has for almost all bases with which ROUEN WHITE,—CARBONATE OF LIME. 53 it is combined, we should say, a priori, that no sul¬ phate is so likely to form a good oil pigment as a car¬ bonate. To the inquirer in regard to pigments, it may be useful to know that native sulphate of lead is found in Anglesea, Cornwall, and in Scotland, crystal¬ lized in prisms and octoedra. For other preparations of lead, see forwards. Rouen White. Rouen white is a marl, consisting of clay and car¬ bonate of lime. It is obtained pure, by mixing the marl with water, to separate from it the sandy or coarse particles. The water is decanted, while still turbid with the lightest matter, which forms a sediment by rest. When this deposit has acquired the consistence of a paste, it is taken out, and divided into small masses of about a pound weight each. The mixture of chalk with clay renders the latter less fit than if pure for painting in oil, or for varnish. This white, however, is better for that purpose than the white of Troyes. White Chalk or friable Carbonate of Lime, White of Troyes, Whiting. All these substances are carbonates of lime. They are often mixed with impurities, from which they are freed, as already described under Rouen white. Chalk is well known to every one; it abounds in the eastern and southern districts of this country. When levigated and washed, it is called whiting, which is found in the shops in powder, in lumps, and sometimes d 3 54 CARBONATE OF LIME. in balls. Troyes white is sold in large square cakes, weighing ten or twelve pounds each, and in rolls and cylinders of from sixteen to twenty ounces. It is cut also into long square sticks, to give it the appearance of tobacco-pipe clay, none of the qualities of which it possesses. This is a fraud which may be easily de¬ tected by means of strong vinegar, which, with chalk, produces an effervescence; but which has no action on tobacco-pipe clay, nor on real Spanish white. The use of chalk for the common white-washing of apartments is generally prevalent; but gypsum is far superior. It serves also for different grounds, either coloured or not, which are applied in distemper. It is rendered more durable by being mixed up with size. But if it be employed as priming, intended to receive colouring parts, the washing it is subjected to in the manufactories is not sufficient: it must be made to undergo the same operation a second time, when not separated from those parts which escape washing on too large a scale. The application of it in the prepa¬ ration of paper-hangings, is prejudicial to certain colours, and particularly to Prussian blue. Chalk, carefully washed, is not attended with the inconve¬ nience of altering and destroying the colours. Carbonate of lime of every kind is proper only for painting in distemper ; with oil and varnishes it becomes brown; and with the latter it has the inconvenience of splitting. Besides, it is not fit for priming, like clay mixed with a little white lead. Colours which contain chalk have no lustre, and they are not durable, even though the chalk be mixed with a little white lead. PREPARATIONS OF ZINC. Oxide of zinc , or flowers of zinc. The discovery of a white colour, unalterable by the action of oil, light, and vapour, has long been a desi¬ deratum to painters. All the known compositions of this kind were attended with the inconvenience of assuming, after a certain period, tints different from those which the artist was desirous of fixing. A brownish or yellowish appearance destroyed the effect, and left the painter very far short of what he intended. Guyton de Morveau suggested oxide of zinc as a substitute for white lead and the oxide of bismuth. But, nevertheless, the use of this article as a pigment has not been hitherto much adopted. It is obtained by fusing zinc in an earthein tube placed obliquely in a furnace. The metal soon in¬ flames, and emits thick white fumes, wdiich are con¬ verted into white flakes that adhere to the sides of the tube, and are called flowers or oxide of zinc. If the zinc contain iron, the oxide will be of an orange-yellow colour: the metal is purified by throw¬ ing into it, while in fusion, a small portion of the flowers of sulphur. The following is Vanlierman's mode of obtaining the oxide of zinc. Put zinc into a large deep crucible, placed in a fur¬ nace, and inclining to an angle of forty-five degrees, and having a cover to shut up occasionally, to increase the fusion; when the metal is melted, take off the cover, and stir the mass with an iron rod, when, if the heat be sufficient, on the contact of air, a crust will be formed, which must be removed, by scraping into a d 4 56 PREPARATIONS OF ZINC. pan, placed in front of the crucible. Stir the melted matter again, and a crust will again be formed : thus proceed till all the metal is converted into oxide. The dearness of zinc, as compared with lead, h&s hitherto prevented the use of this article as a pigment; and although, if cheaper, from its comparative harm¬ lessness it would no doubt be more employed, yet we very much question whether, were it even cheaper than lead, it would supersede the use of that valuable yet pernicious pigment: for we believe that no substance has been yet discovered which enters into such in¬ timate union with expressed oils as lead. In order to obtain the oxide of zinc pure, it should be washed with water in a similar why to that which we have directed for the purification of some of the earths, namely, by mixing it with water, suffering it to remain a short time, till the grosser particles have sub¬ sided, and then pouring off the supernatant liquid, containing the fine impalpable oxide which will subside to the bottom, when removed to another vessel. The oxide may be dried on chalk stones, and afterwards ground with linseed oil in a similar way to that of grinding white lead. Sulphate of Zinc , or White Vitriol. Sulphate of zinc , white vitriol, or white copperas , is a combination of the sulphuric acid and zinc. This article is prepared in Germany by roasting blende or sulphuret of zinc, and afterwards exposing it to the air, when the sulphur attracts oxygen, and is con¬ verted into sulphuric acid ; the metal being at the same BARYTA. 57 time oxidized, combines with the acid. After some time the sulphate is extracted by solution in water; the solution being evaporated, the mass is run into moulds. Thus prepared, the white vitriol of commerce generally contains a small portion of iron, sometimes of lead. Sulphate of zinc is now, we believe, pre¬ pared also in the large way in this country from the ores of zinc with which some parts of this country abound, particularly the Mendip hills, in Somerset¬ shire. If, however, this article be desired perfectly pure, it may be made by dissolving metallic zinc in a weak solution of sulphuric acid in water; and, after the effervescence is over, filtering the solution, and boiling it till a pejlicle begins to form on the surface, when it should be set by to crystallize. But such pure sulphate of zinc is rarely if ever required in painting. Sulphate of zinc is used chiefly as a drier when mixed in small quantity with oil paints : it is not, how¬ ever, calculated for white, and other delicate colours, it being apt to deteriorate the colour. But it may be nevertheless advantageously used to increase the drying quality of oxide of zinc when ground in oil, as well as for many of the earthy dark-coloured paints. Baryta. Baryta , barytes, ponderous spar, or heavy earth, is a natural product not uncommon in this country. It is found most usually combined with either the sul¬ phuric or carbonic acid, forming with them a sulphate or carbonate respectively. Sulphate of barytes, or cawk, is inodorous and in- d 5 58 SULPHATE OF BARYTES* sipid, yet poisonous. Its colour is white, with shades of yellow, red, blue, and brown; it is transparent, semi¬ transparent, or only translucent; it is hard, brittle, and heavy, its specific gravity being 4.7. It breaks with a straight foliated structure; the fragments are shining and pearly. At a high temperature it fuses into a white enamel, and was used by Wedge wood in the manufac¬ ture of jasper ware. Mr. William Duesbury , of Bosel, Derbyshire, ob¬ tained in 1825 a patent for the purification of impure native sulphate of barytes, from its colouring matters, so as to render it equally fit for the purpose of the arts to which the white sulphate of baTytes is usually ap¬ plied. The process is described in vol. xii. page 288 of the Journal of Arts. The patentee describes this article as being a substitute for white lead ; but that it is more particularly applicable to water than to oil; on walls in distemper, as grounds for washes, and in the patterns of printed paper hangings—in all these it is found to be a constant white. The carbonate of barytes , although inodorous and insipid, is highly poisonous. Its colour is white, or yellowish grey; it is translucent, with a shining, some¬ what resinous lustre; its specific gravity is 4.33. Like the sulphate, it may be fused into a white enamel by the blow-pipe, and dissolves in diluted nitric acid. It has been found in large quantities near Murton in Cumberland, and also at a lead mine near Minsterly in Shropshire. It is sometimes called Cocks' comb spar. According to Mr. Brande, artificial sulphate of barytes is used as a pigment, under the name of perma- CARBONATE OF BARYTES. 59 nent white. Mr. Vanherman, a practical painter, says that the natural sulphate acts on gums and mucilages, and changes the whiteness. He therefore recommends the carbonate. Both may, however, be right, as it is very possible that the natural sulphate contains some matter which is injurious, to its whiteness, and from which the artificial sulphate may be free. (See the notice of Duesbury's patent above). Mr. Vanlierman directs the natural carbonate of barytes to be thus prepared : The spar is first reduced to powder under iron stampers, and ground under the stone on edge in water, the fine particles being made to pass, as the grinding goes on, into a back, about three-fourths full of water, attached to the trough of the edge stone by a pipe with a brass cock. There must be a second back, communi¬ cating by a pipe with the first, into which the barytes is left to precipitate; when a sufficient quantity is col¬ lected, it is to be put out on chalk stones, and thence to a stove or other place to be dried. This preparation, as a^water-white for ceilings, does not require grinding ; but for miniature painting it should be levigated and washed over, and then mixed with gum water. If made into cakes, like other water colours, it would be an acquisition to the colour-box. Vanherman calls this article Album perpetuus , and says that it is the only article yet discovered that re¬ tains a durable white as a water colour. As oil paint it is not desirable, except as a stone colour, or mixed with white lead ground in oil, in the proportion of three-fourths of the latter to one of the d 6 60 LIME. former, which is a good second for priming and second colouring. In this respect it does not, however, appear to be superior to many other of the simple earths, as it does not combine with oil like the preparations of lead. The water-colour painter should not forget that car¬ bonate of barytes is a deadly poison, and that the pen¬ cils imbued with it ought not to be put into the mouth. In addition to the various whites which we have described, a few others must be also mentioned, which are occasionally used in some of the processes of painting. Lime. Pure or caustic lime, called in common language quick-lime , rarely enters into the composition of paints; but some kinds of lime, obtained from hard and com¬ pact lime-stone, are excellent for the white-washing of cielings, being merely slacked by water and then made into a thin pap, and laid on with a proper brush. It is true, in the neighbourhood of London, as such lime is not plentiful, it is usual to employ whiting , that is, levigated and washed chalk, with size, for such pur¬ poses ; but there is a dulness about such colours. Lime made from compact lime-stone, and properly selected, produces a much more lively and brilliant white. We may just add, that for most purposes of chemical com¬ bination with metallic solutions, where colour is of con¬ sequence, lime from lime-stone will, in general, be found superior to lime from chalk: we may also state, that mortar made with the lime obtained from good lime- OXIDE OF BISMUTH—PEARL WHITE. 61 stone, will always be found superior to that made with chalk. Pearl White , or Oxide of Bismuth . The nitric acid dissolves bismuth (a reddish white metal somewhat harder than lead, and of the specific gravity of 9.85. It is found in Cornwall, and in various other parts of Europe) very quickly, and the solution being evaporated affords crystals; these being dissolved in water render that fluid milky, and a white precipi¬ tate is produced, which is an oxide of bismuth, or ma- gistery of bismuth , as it was formerly called. This pig¬ ment is used chiefly as a paint by the ladies for the skin, the use of which however we cannot recommend. Such preparations of bismuth are liable to be turned black by sulphuretted hydrogen: hence, as water colours, when exposed to the air, in towns particularly, they tarnish. A pearl white is also sometimes made from finely pulverized oyster-shells, cleared, of course, from their sordes. Another may be also made from egg-shells. We may just mention that from all the shells of fish, as well as from egg-shells, can be obtained, by calcina¬ tion in a strong fire, a very good, and in many cases a very useful quick-lime. It should be observed of lime, as well as of chalk, oys¬ ter-shells and egg-shells , when used as paints, whether calcined or not, that when mixed with metallic, and many other salts, they frequently decompose them, and often destroy their colours; care should therefore be taken to avoid such mixtures. 62 PREPARATIONS OF SILVER AND GOLD. Calcined hartshorn is also considered a useful earthy white for water colours; and although not so liable to be decomposed by the metallic, or other salts, as some of the preceding whites, it will be always advisable to avoid mixing it with such bodies. Preparations of Silver and Gold. Silver and gold are used as colouring materials chiefly in the state of leaf for plating or gilding in¬ numerable metallic and other substances. The modes of preparing and applying gold and silver leaf it is not here necessary to describe, as the former processes be¬ long to the gold-beater , and the latter to the carver and gilder; yet as gold in particular is occasionally used by the painter, it may be useful to observe, that a gold colour is applied in several ways, either by direct ap¬ plication of the leaf to the parts intended to be gilt, or by dissolving gold in nitro-muriatic acid, or aqua regia, which is made with two parts of muriatic acid and one of nitric acid; by evaporation a muriate of gold is ob¬ tained that may be applied in various ways; or by grinding gold leaf with honey or sugar, and afterwards washing away the honey or the sugar; a gold powder will be thus obtained that can be applied to various purposes of painting figures of a gold colour, particu¬ larly in enamel and porcelain painting. The Purple Precipitate of Cassius Is produced by mixing a solution of muriate of tin with a solution of muriate of gold , prepared as above di- MOSAIC GOLD—COBALT. 63 reeled. This precipitate is employed chiefly in paint¬ ing porcelain. A preparation, although having no gold in it, is used as a pigment for giving a gold colour to small statue or plaster figures; and also, it is said, to be mixed with melted glass, to imitate lapis lazuli; it has been long known in the arts under the name of Aurum Mosaicum , Musivum , or Mosaic Gold. It is thus made : Melt twelye ounces of tin, and add to it three ounces of mercury ; triturate the amalgam with seven ounces of sulphur and three of muriate of ammonia. Put the mixture into a matrass bedded rather deep in sand, and keep it for several hours in a gentle heat, which is afterwards to be raised and con¬ tinued for several hours longer. If the heat has been moderate, and not continued too long, a golden-coloured scaly porous mass, the mosaic gold, will be found at the bottom of the vessel; but if the heat has been too strong the mass will be black, and consequently spoiled. This composition is a sulphuret of tin. Preparations of Cobalt. Cobalt is a metal of a reddish grey colour and diffi¬ cultly fusible ; its specific gravity is 7.7. It is found in nature combined with oxygen, with arsenic, with sul¬ phur, with iron, &c. The finest specimens are ob¬ tained in Saxony ; but many cobalt ores are also found in various parts of Great Britain. The colouring power of oxide of cobalt on glass and verifiable mixtures is astonishingly great, one grain of 64 AZURE—ZAFFRE—SMALT. which gives a full blue to 240 grains of glass; conse¬ quently the more oxide of cobalt the glass contains the more intense the colour becomes. Its chief use is in colouring porcelain, earthenware, and glass; but the painter also occasionally employs it in oil painting, and some kinds of distemper. It is brought principally from Germany to this country in the state of zaffre > smalt , or azure . Hence we find mixtures of cobalt under various names; as, Azure , Enamel Blue , Zaffre , Smalt , Saxon Blue , Vitreous Oxide of Cobalt , fyc. The vitreous oxide of cobalt is manufactured on a large scale in Saxony, where mines of cobalt are abun¬ dant ; hence it has acquired the name of Saxon blue. This oxide of cobalt requires great care before it can be applied to delicate kinds of painting. It must be ground for a very long time; and as the glass is exceedingly hard, this mechanical labour, to many painters, is highly disagreeable. It is designed for drapery of a soft blue colour; but it is attended with the fault of being somewhat dry, and this is owing to the vitreous nature of its composition, which prevents it from ad¬ hering to the canvas, and from forming a body with other colours. Were it not for the tenacity of the oil, which serves it as a cement or varnish, it would fall into dust. Zaffre is prepared by calcining the ores of cobalt, by which the sulphur and arsenic with which the cobalt is combined are volatilized, and an impure oxide of cobalt remains, which is mixed and fused with about twice its weight of powdered flints. THENARD’s BLUE—ULTRAMARINE. 65 Smalt and azure are made by fusing zafire with glass; or by calcining a mixture of equal parts of roasted cobalt ore, common potash, and ground flints; a blue glass is thus obtained, which while hot is dropped into water, and afterwards reduced to a very fine powder. Strewing smalt is a coarse granulated smalt, of a shining blue colour; it is used chiefly for the purpose of being strewn over the ground of some painting, par¬ ticularly sign painting. Besides these preparations of cobalt, another, a very beautiful colour, may be mentioned, called Thenard\s Blue , Which is made by dissolving roasted cobalt ore in di¬ luted nitric acid, then evaporating the solution to dry¬ ness and dissolving the residue in water; to this solu¬ tion add phosphate of soda; the precipitated powder must be well washed in water, and while moist mixed with eight times its weight of alumina, prepared by the addition of ammonia to a solution of alum; the alumina must be used before it is dry. The compound is then to be spread on thin plates, dried in a stove, and reduced to fine powder, which must be, lastly, exposed to a red heat for half an hour in a covered crucible. For Egyptian Azure , see Preparations of Copper. Ultramarine. Ultramarine is extracted from lapis lazuli , lapis cyanus or azure stone , which is of a bright blue colour, and so hard as to strike fire with steel. The finest spe- 66 ULTRAMARINE. cimens are brought from China, Persia, and Great Bu- charia. The best method of obtaining ultramarine appears to be the following: Put the lapis lazuli into a crucible placed in a strong fire ; when it is red hot throw it into distilled vinegar, or pyrolignous acid ; repeat this till all the lapis falls into powder; grind this powder in vinegar, and lay it on blotting paper to dry; when dry let it be ground very fine w ith linseed oil on a porphyry slab; on the great fineness of this grinding depends both the quality and the quantity of the ultramarine. Next melt together three ounces and a half of black resin, three ounces of yellow resin, tw r o ounces and a half of Burgundy pitch, to which when melted add two ounces and a half of Venice turpentine; while all these are in a melted state add to them three ounces and a half of the lapis lazuli, weighed before it is ground in the oil. When all these ingredients are well mixed, pour, the whole mass into a basin of clear water; when it is sufficiently cool knead it well with the hand under the water, and continue squeezing it until the blue colour exudes from it; when the water is charged with the ultramarine pour it into another basin, and the colour will fall to the bottom of the w r ater, which should be carefully poured off, and the ultramarine dried in the sun or before the fire. Hot water may now be poured on the mass, and again kneaded with it, when a fresh quantity of colouring matter will be obtained, but inferior to the first. The process may be repeated as long as any colouring matter can be obtained. 8 ULTRAMARINE ADULTERATIONS. 67 Ultramarine is a truly valuable colour, and superior to Saxon or enamel blue in the richness and mellow¬ ness of its tone. It is not sandy like Saxon blue ; it never deceives by the effect of time the hope of the artist who has applied it. In this point of view alone it is worth a greater price than has been fixed on it. Method of ascertaining whether Ultramarine he adulterated. As the price of ultramarine, already very high, may become more so on account of the difficulties of ob¬ taining lapis lazuli, it is of great importance that painters should be able to detect its adulterations. Pure ultramarine, when brought to a red heat in a cru¬ cible, stands that trial without changing its colour. As small quantities only are subjected to this test, a com¬ parison may be made, at a very little expense, with the part which has not been exposed to the fire. If adul¬ terated, it becomes blackish or paler. This proof, however, may not always be conclusive when ultramarine of the lowest quality is mixed with azure or Saxon blue ; but if it be mixed with oil, it is found to have very little body compared with its bright¬ ness. It is well known that vitreous matters, such as azure, exhibit no more body than finely ground sand would do: ultramarine treated with oil assumes a brown tint. From the researches of C. Guyton, an account of which was read at the National Institute at Paris, in 1800, it would seem that ultramarine is a particular combination of iron and sulphur. 68 PREPARATIONS OF IRON-PRUSSIAN BLUE. According to Mr. Brande , however, “ Lapis lazuli consists of silica 46, carbonate of lime 28, alumina 14, sulphate of lime 6.5, oxide of iron and water 5. The blue colour is probably derived from some principle which has hitherto escaped analysis.” The possibility of making ultramarine was first ob¬ served when the blue matter found in a soda furnace was shewn, by Vauquelin, to have the properties of that pigment; since then the experiments of Gmelin and Guimet have proved successful, but the processes are expensive. By following Gmelin’s process, M. Hermb- stadt has obtained most beautiful ultramarine. See Journal of Science , N.S. vol. iv., page 216; and also Nos. 11, page 182, and 12, page 412. An artificial ultramarine , has been also lately pre¬ pared in France by M. Tunel, the process for making which he keeps at present secret; it is sold at less than half the price hitherto paid for this pigment. For the difference between lapis lazuli and lapis ar- menus , see bice, under the preparations of copper. See also the preparations of gold. Preparations of Iron. Iron is a metal too well known to need being de¬ scribed here. It is the basis of many useful pigments. Prussian Blue. Prussiate of Iron. Prussian blue is a combination of iron with an acid of a peculiar nature, called the Prussic or hijdrocyanic acid , which, by the latest chemical researches, consists of Prussine or cyanogen , a gaseous body, and hydrogen. PRUSSIAN BLUE. 69 Prussic acid is a liquid, having a strong pungent odour, very like bitter almonds; its taste is acrid, and it is highly poisonous. It exists in many vegetables ; and is obtained in some quantity by distillation with water from the kernels of many of the drupaceous fruits, and from the leaves of many plants of the laurel tribe, &c. Our business is not, however, with the Prussic acid, but with its compound, Prussian blue, so called from its having been discovered by Diesbach, a colour- maker of Berlin, in 1710. Prussian blue is usually thus prepared : equal parts of subcarbonate of potash and dried blood, or shavings of horn, are heated red hot in a crucible, and six or eight pints of water are poured upon the mixture when quite cool. The solution, being filtered, contains hy- drocyanate of potash, together with subcarbonate of ! potash and some other products. It is then mixed j with a solution, containing two parts of alum, and one of sulphate of iron ; a precipitate is obtained, at first of a green hue, but which, by being washed with di¬ luted muriatic acid, acquires a fine blue tint, and being dried, is the Prussian blue of commerce. The affinity of the Prussic acid for iron is great, so that the acids generally do not decompose Prussian blue ; but nevertheless the alkalies and lime do so. Many other forms might be given for the manufac¬ ture of Prussian blue, but our limits prevent their ad¬ mission ; one, however, lately made public by M. Gau¬ tier (see the Journal of Science, vol. 24, page 208), those interested in the subject are invited to consult. Prussian blue is much used in house and in other 70 ARTIFICIAL SAXON BLUE. kinds of painting. It is, however, often attended with one inconvenience. When ground with oil it assumes l a yellow tint, which some correct by a little violet lake. This yellow tint seems to arise from the action of the oil. Another fault which seems to confine the I use of this colour is, that the blue it produces is hard, and does not harmonize with that fine carnation which gives charms to the physiognomy when artfully inter¬ sected by beautiful veins. Ultramarine alone answers this purpose when employed by the hand of an artist. Artificial Saxon Blue. Saxon blue may be successfully imitated, by mixing a divided earth with Prussian blue at the moment of its formation and precipitation. Into a solution of 144 grains of sulphate of iron pour a solution of prussiate of potash *. At the time of the formation of the prussiate of iron add, in the same vessel, a solution of two ounces of alum, and pour in at the same time the solution of potash,—but only in such quantity as may be supposed necessary to decom¬ pose the alum: for a superabundant proportion of alkali might alter the prussiate of iron. It will be therefore much better to leave a little alum, which may after¬ wards be carried off by washing. As soon as the alkaline liquor is added, the alumina precipitated becomes perfectly mixed with the prussiate of iron, the intensity of which it lessens by bringing * Prussiate of potash is now to be obtained at almost any of the colour shops, it being an article very commonly used in dyeing. OXIDES OF IRON—PRUSSIAN RED. 71 it to the tone of common Saxon blue. The matter is then thrown on a filter, and after being washed in clean water, is dried. This substance is a kind of blue ver- diter, the intensity of which may vary according to the greater or less quantity of alum decomposed. It may be used for painting in distemper. Oxides of Iron , Being perfectly innoxious, axe not liable to the same objections as those of lead and of arsenic ; but they do not combine so intimately and effectually with oil as those of lead. The brown, red, and purple oxides of iron are nevertheless, when ground in oil, very useful pigments. Indeed, it has been stated that the only simple purple known is the purple oxide of iron , called formerly colcothar of vitriol and crocus martis ; this colour is sometimes called pompadour, by others purple brown. It is made by simply calcining sulphate of iron in an open vessel till it acquires the desired colour; or it may be'made by mixing iron filings into a paste with sulphur and water, and afterwards calcining the mass in a crucible in a strong heat, till the sulphur is dissipated and the colour required obtained. Prussian Red. The Prussians prepare by means of an open fire (from, we presume, common sulphate of iron), a red oxide of iron, which is calcined several times, and the washing is conducted in such a way as to prepare several sedi¬ ments by one operation, differing in beauty according to the time employed in the subsiding. The first sedi- 72 OCHRES. ment formed in a determinate time is coarser than the second, and so on in succession. The last sediment is, of course, the finest. The red obtained by this process is delicate, and has occasionally a place on the palette of the painter. The colours obtained from artificial oxides of iron are deeper than those of the natural ochres or oxides , an account of which will be subsequently given: in short, the artificial oxides of iron are more pure than the natural ones found in the yellow, brown, and red ochres ; hence their superiority as pigments, whether they be obtained from the decomposition of the sulphate of iron, or in any other way. It may be added too, that to increase the intensity of the red of any of the oxides of iron, after being washed and dried, they must be again submitted to the action of fire in a crucible, so that the access of air to them might be easy, in order that the oxidation may be rendered more complete. Of course, such nicety in these colours*for house painting is not in general re¬ quired. The different reds obtained from the decomposition of sulphate of iron, as well as from the residua of the operation by which nitrate of potash is decomposed to convert it into nitric acid, are much sought after by porcelain painters, &c. OfOchres , the chief colour ing ingredient in which is Iron. Ochres are mixtures of argillaceous and calcareous earths and oxides of iron, to which last substance their colour is generally owing. VENETIAN RED—INDIAN RED. 73 Of all the metals iron is that which yields most rea¬ dily to the chemical action resulting from its contact with different substances, while exposed to humidity and to the air. Salts, acids, sulphur, arsenic, and even water become, under certain circumstances, the origin of modifications of it. Spanish Brown , Venetian Red , Indian Red , and all the Yellow Ochres are natural products, and appear to be combinations of oxide, and occasionally carbonate of iron, with argillaceous and other earths. When washed, or otherwise freed from gross impurities, they form useful pigments for common purposes. Many of the yellow ochres when burnt become of a red colour, and are then occasionally used for more delicate pro¬ cesses. Spanish brown and some other browns are obtained plentifully in the West of England; so are also several of the yellow ochres; Venetian Red is brought from Venice ; but it is also produced in France, Germany, and many other places. Indian Red , Called sometimes Persian ochre , because brought, we presume, from Persia, is a fine purple, used chiefly if not entirely in portrait and other delicate painting. This is a dear colour. According to a paper in the 46th volume of the Transactions of the Society of Arts , a red earth is sold at Quebec at 3d. per pound, ob¬ tained from the Magdalen Islands, in the Gulph of St. Lawrence, which is said to be as beautiful and useful as Indian red. 74 OCHRES—YELLOW-RED. Natural Yellow Ochres In many cases save the artist the trouble of artificial oxidation, nature producing them of very yarious colours on a large scale. They are produced in all countries in the neighbourhood of volcanoes, and in some where no evidence of volcanic procedure exists. They form ar¬ ticles of commerce, having various shades of yellow, and are known to painters under various names : as Dutch or Spruce ochre, English ochre , Bristol ochre , Oxford ochre , &c. The Diitch ochre is generally con¬ sidered the best; but some English ochres obtained in the Mendip hills, in Somersetshire, afford a very bright yellow. They unite readily with oil, but require some of the oxides or the acetate of lead to make them dry speedily. jRed Ochre. Natural Red Ochre is very abundant in volcanic coun¬ tries ; as is the case in Auvergne, where very beautiful kinds are found; clay forms the greater part of it, which renders it soft to the touch. Red ochres are also plentiful in other places not volcanic, as the Men¬ dip hills, in Somersetshire. Ochres are easily purified by simple washing. They mix readily with water, and the sand and stones which they contain being heavier than themselves, subside. The water, turbid with the ochre, is decanted, by mak¬ ing it pass into a trough lower than the vessel in which it was washed; when the ochre has subsided the clear water is drawn off. The ochre is then taken out, and being dried is divided into small masses. UMBER. 75 When an ochre is composed of oxide of iron and clay, it resists the action of most acids. If an effer¬ vescence be produced, the composition is of a marly nature. Calcareous earth is found in these ochres in different proportions. In this case the ochre is drier. It possesses less body than an ochre which is entirely argillaceous, when employed in oil or varnish painting. It is seen by this short view of these ochres that iron, by its different degrees of oxidation, natural or arti¬ ficial, becomes the base of several kinds of colour; and that it renders a very extensive service to painting. In this respect no metallic substance is equal to it. See a preceding section on the oxides of Iron. Besides the preceding ochres, which are used as pig¬ ments, the following earths, as they are commonly called, require some notice. Umber, Brown Ochre, Is found in the shops under two names, Turkey Umber and English Umber. They are both of a colour more or less brown, but Turkey Umber is most esteemed; it is found in Umbria, a district of Italy, whence it de¬ rives its name ; but the best comes from Turkey, or rather from the island of Cyprus, where it occurs in beds. i Turkey umber is brought to this country in masses of various sizes, some almost in a state of powder. Its colour is clove-brown ; it is soft, easily cut, and readily falls to pieces in water. Its specific gravity is 2 . 06 . It consists of oxide of iron, oxide of manganese, Silica, and alumina. 76 TERRA DE SIENNA. It is very much employed in painting browns. When slightly burnt it acquires a more intense colour. An inferior umber is obtained in this country, and called English Umber. The umbers are all useful browns in oil, and occa¬ sionally in other painting, particularly when burnt. Terra de Sienna , A brown bole, or ochre, with an orange hue, brought from Sienna, in Italy, and used in painting both in its crude and in its burnt state. It is used chiefly when ground in oil to give the dark shading in imitation of mahogany; as burnt spruce ochre is to give the red, both being laid upon a ground of yellow. Several pigments are known under the name of Terra Yerte, or Green Eartlt. The following may be particularly noticed: Green Earth of Saxony. Nature often prepares colours, to which art can make no addition, when artists know how to limit the use of them. Of this kind is the green earth of Saxony, Hun¬ gary, and Italy. These coloured earths are sometimes silicious, some¬ times argillaceous; their colours depend chiefly on the oxide of iron, or the oxide of copper which they contain. The earth of Kerhausen, in Hungary, is of this kind. When earths thus contain colour¬ ing matter they may be employed in distemper, but they are not often fit for oil painting until they have been corrected. The colour would otherwise become TERRA VERTE—COLOGNE EARTH. 77 a dark and obscure green; in this case the colour requires to be mixed with one part or a part and half of white lead. Green earth of Saxony, requires also a nearly similar correction for this kind of painting. Green Earth of Verona , Terra Verte, or Mountain Green , Occurs near Verona , wdience its name, and also in many other parts of Europe; it is frequent in the amygdaloid or almond-stone, found in various parts of Great Britain and Ireland. It is of a celandine green colour, and sometimes has darker shades. When mixed with oils it has not the same fault as the greens mentioned in the last article. It is equally proper for distemper and oil painting; but it is more commonly used in the first way by artists in water-colours, and by them called mountain green. The colour of this earth was formerly supposed to be produced by an oxide of copper; but, according to the analysis of it in Dr. Ure’s Dictionary of Chemistry, its colouring matter is oxide of iron 28. mixed with 53. of silica, potash 10. and a small portion of magnesia. The colour is durable, but not so bright as what may be obtained artificially from copper. See other Greens under the Preparations of Copper. Cologne Earth Has been by some considered an umber; its colour is black or blackish brown, mixed with brownish red ; it is light, and bums with a disagreeable smell; found near Cologne; it is used both in water colour and oil E 3 78 CASSEL EARTH—BLACK LEAD. painting. It appears to be a kind of bitumen. An in¬ ferior earth of the same kind is occasionally met with in England. Cassel Earth is also occasionally used for dark shad¬ ing in miniature painting; but Mr. Craig, in his lec¬ tures, speaks of “ the disagreeable brownness of Cassel earth.” Black Lead, Carburet of Iron, Graphite, Plumbago. This substance was for a long time supposed to be a preparation of lead, whence its name; but the accurate analyses of modem chemistry have determined that it consists of carbon, or pure charcoal, and iron. It is, however, a very indestructible substance; and as an ingredient in the formation of crucibles, and as pencils and crayons for drawing, &c. it demands a notice in this work. It is found in various parts of the world, but the best is produced at Borrowdale, in Cumberland, whence Great Britain and the greater part of Europe are sup¬ plied with it. Its goodness may be known by rubbing the powder between the finger and thumb: if it leave a smooth polish it is good; if it produce little or no polish, or fall from the fingers easily after it is rubbed, it is not good. There has been lately introduced a black lead called Mexican black lead, by some said to be imported from Mexico, by others from Spain. From the specimens which w'e have seen, its softness and extreme friability render it unfit in its cmde state for pencils ; it is, ne¬ vertheless, a very pure black lead, and for a variety of ARTIFICIAL BLACK LEAD PENCILS. 79 manipulations equal, if not even superior, to Cumber¬ land lead. The following method of making Artificial Black lead Pencils Demand attention:—Melt together fine Cumberland or Mexican black lead, in powder, and shell lac. Let this compound be repeatedly powdered and re-melted till it becomes of a uniform consistence; it is then to be sawn into slips, and mounted in the usual way Of course the proportion of the ingredients proper for forming pencil lead can only be determined by actual experiments. As shell lac is soluble in rectified spirits of wine, we conceive that its being previously softened by heat with that menstruum would render its mixture at once with the black lead, by kneading, complete, and the re-melting as directed above avoided. Black lead pencils can now be obtained in the shops of different degrees of blackness, so that, in Drawing , a variety of shades are introduced, and this beautiful art thus rendered, by the use of such pencils alone, a very pleasing kind of painting, and peculiarly suited to the accomplishments of a lady. To this we may add, that black lead ground in water in a similar manner to ordi¬ nary paints, and afterwards dried, and again reduced to powder, and tied in muslin, can be used for giving in¬ numerable shades to drawings in a very expeditious manner. For this novel method of painting the So¬ ciety of Arts awarded Mr. G alp in, of Charmouth, their silver Isis medal. Journal of Arts, vol. xiii. p. 35. 80 CRAYONS. Crayons. Crayon is the French term for pencil; hence the pencils made of black lead, blood-stone, red chalk, charcoal, &c. are crayons ; the term is, however, more extensively applied, and chiefly to a composition of coloured earths made into a paste, and then rendered of the proper size and shape for use. The following is well recommended as a general paste for crayons: Take of spermaceti three ounces; boiling water one pint; melt the spermaceti in the boiling water, and add to the mixture one pound of bone-ashes, finely levi¬ gated ; the colouring matter must of course be added besides, to impart to the crayons the tint required. Let the paste be well kneaded, and when about half dry form it into crayons. Some use instead of the above, pipe-clay mixed of course with the various colours; and, instead of water, ale-wort to make the paste. The perfection of crayons consists chiefly in their softness ; it being impossible to paint with them when hard. In all compositions for crayons white lead and flake white must be carefully avoided, as the slightest touch with either of these will ton black. Alumina , that is, pure clay, or chalk , well purified by washing, &c. is the best basis for crayons. Many coloured earths may, however, be made into crayons without any admixture, by merely being washed, kneaded, rolled, and dried. Colours naturally so hard as not to mark easily on paper, require to be mixed CRAYONS—ROAD DUST. 81 with alumine, or other earth of a loose texture, by which their hard quality may be corrected. Carmine is thus treated for crayons: grind the carmine upon a grinding-stone with rectified spirits of wine till it become smooth; the different tints of this colour are then given by mixing it in various propor¬ tions with either alumina or purified chalk thus : to three parts of carmine add one of the white earth;—to one part of carmine add another of earth;—to one- fourth of carmine add three-fourths earth;—and the lightest tint should be made of the white earth, faintly tinged with carmine. As these different tints are levi¬ gated, they should be laid immediately on a chalk stone, that the moisture may be absorbed, so as to render the mass sufficiently dry to be formed into crayons, which may be known by its losing most of its adhesiveness when taken in the hand: when formed into pencils they may be laid on glass to dry. These directions are sufficiently ample for forming crayons of any kind or colour by the exercise of a very little ingenuity. Drawing Slate or Black Chalk is greyish, or bluish black; it consists of silex, alumina, carbon, and oxide of iron; its specific gravity is 2.11. The best kinds come from Italy; it is also found in France, Spain, and the Isle of lsla in the Hebrides. It is used in crayon¬ drawing, whence its name. Road Dust. This article, obtained from the breaking down and E 5 82 ROAD DUST. pulverization of the materials with which our public roads are made and repaired, has been latterly a good deal employed, when mixed with other matters, as a common paint. The constituents of road-dust must yary with the materials of which the road is made or repaired. Roads made and repaired with lime-stone produce, of course, a calcareous powder, chiefly a car¬ bonate of lime, yet, from the attrition which the ma¬ terials undergo, such dust, when fresh, is well calcu¬ lated, with a certain mixture of quick-lime, for making plastering mortar; it is hence concluded, that the at¬ trition on the road decarbonizes, in a slight degree, the lime-stone. The roads near London are repaired with flints, and occasionally with granite; hence the road-dust around the metropolis consists chiefly of siliceous matter; in all road-dust there is, besides some decaying vegetable matter, and a small portion of animal matter, produced from the dung of animals. We thus see of what road- dust must be composed; and although we are not quite disposed to dignify this material with the name of Crotia, as a late writer* on house-painting has done, it may, nevertheless, be occasionally used, as we shall subsequently point out, with advantage for coarse pur¬ poses. One condition is necessary in the use of this material, namely, that it should be either reduced to an impalpable powder, before being mixed with oil or other liquid, or subsequently ground fine with oil, as, unless so treated, when dried it will readily rub off. * Every man his own House Painter and Colourman, 8$c. by T. H. Vanherman. PREPARATIONS OF MANGANESE. 83 The best mode of purifying it is by washing, as men’ tioned for many of the w T hite earths. Black Oxide of Manganese. Manganese is a metal of comparatively modern dis¬ covery; it is of a grey colour, somewhat resembling iron externally; but it posseses neither ductility nor malleability; it is, nevertheless, brittle, though not pul- verizable; it is also difficult of fusion, but readily melts with most of the other metals, quicksilver excepted. When exposed to the air it becomes an oxide: its specific gravity is 8. It is usually found in nature as an oxide; that called the Black oxide , in Derbyshire Black wadd, is the most common. It is to be obtained in various places in this country; in Devonshire, Somersetshire, Derbyshire? &c. as well as in other parts of the world. There are several varieties of this oxide, varying in colour from iron-grey to black ; all are brittle; several soil the fingers. It is a peroxide, and is not soluble in acids It is used for obtaining oxygen gas, by being merely exposed to heat in a retort or other proper vessel; it is also largely employed by bleachers in the preparation of chlorine ; it is used too in glass-making, having the property of freeing it from colour when fused with it, hence it is called Glass-maker's soap ; when added in excess it imparts a red or violet colour; it is also em¬ ployed in porcelain painting; and being mixed with the materials of common earthenware before they are formed into vessels, it imparts to them a black colour. Besides the peroxide, there are several other oxides of this metal. One, a protoxide, is made by digesting the E 6 84 BLACK WADD—PARKER’S CEMENT. peroxide in muriatic acid, which absorbs a portion of its oxygen, and leaves an oxide of a deep olive green , which might form, we presume, a very useful pigment. The Black oxide of manganese is remarkable for pro¬ ducing spontaneous inflammation when mixed with some oils, particularly linseed oil; the cause of this phenomenon is not at present known : but it is evident, that although the oxides of manganese form many use¬ ful dark colours as pigments, care is necessary in mixing them with oils, that they should be those only in which combustion is not excited by the mixture. For common out-door work black wadd has been latterly employed as a paint, particularly for iron; the proper vehicle for it is oil of tar: for, as we have before stated, with linseed oil it produces combustion. According to Mr. Brockedon , (Transact . of the Society of Arts , vol. 46.) the black manganese of the shops is a very useful grey colour of much body; it dries almost immediately with oil. Parker's Cement Has also been recommended by Vanlierman as a coarse, yet cheap and useful paint for barns, coarse paling, carts, waggons, &c.; it is of a dark chocolate colour, and is particularly useful as ground for other paints. It is made into a paint by simply mixing it with raw and boiled linseed oil in equal parts, or com¬ mon linseed oil with white vitriol (sulphate of zinc) as a drier, would, we presume, answer equally well. This cement is composed, according to Gray (Suppl. to Phar. page 226) of the indurated marl, called clay* PREPARATIONS OF ARSENIC—KING’S YELLOW. 85 balls, or the waxen vein found in the London clay strata, by calcining and grinding them without any admixture whatever. Preparations of Arsenic, Arsenic is a metal of a steel-blue colour, brittle, and easily fusible; its specific gravity is 8.3. It may be distilled at a temperature of 360. Its vapour has a strong smell of garlic , by which, when exposed to heat, many of its combinations are know n. When heated in the air it readily takes fire, burns w r ith a blue flame, and produces copious wdiite fumes of oxide. Oxygen combines wfith arsenic in two proportions, one forming the oxide of Arsenic, Arsenioas acid , Arsen ic or com¬ mon white Arsenic of the shops ; the other, the Arsenic Acid. The arsenic as found in this country is brought chiefly from Bohemia. It is imported in casks, and consists of semi-transparent lumps, white, brittle, and of a glassy fracture; when reduced to powder it is of a dull white colour, and much heavier than pow r dered cream of tartar. All the preparations of arsenic are violent poisons. Native arsenic has been found in various countries of Europe, and also in Cornwall. Arsenic is an occasional ingredient in glass; the fol¬ lowing are its chief preparations as pigments. King's Yelloiv , Is a preparation of arsenic and sulphur; it is a beauti¬ ful yellow, but is, nevertheless, somewhat fugacious. It is besides poisonous, and is now r generally dis¬ approved in consequence of its deleterious qualities. 86 ORPIMENT—REALGAR—SCHEELE’s GREEN. The following is the form by which it may be, however, obtained. Sublime in a retort 20 parts of pulverized arsenic with one part of flowers of sulphur in a sand heat. The colour will be found in the upper part of the glass, whence it must be carefully removed, and levigated till it becomes a fine powder. It may be rendered a deeper or lighter colour by increasing or diminishing the pro¬ portion of sulphur. Orpiment, or Yellow Sulphuret of Arsenic, Is also a combination of arsenic with sulphur. When slightly calcined it forms souci yellow. This substance is now also disapproved as a pigment, for the same reason as is assigned for the disuse of King’s Yellow. Realgar , or Red Sulphuret of Arsenic, Is obtained by slowly melting together metallic arsenic and sulphur, or by heating white arsenic with sulphur. It is said, that the only difference between this article and orpiment consists in the proportion of the sulphur which they respectively contain; that orpiment con¬ tains the least and realgar the most sulphur. But Mr. Brande says, that orpiment only differs in form, and of course, colour, from realgar. The same objections to the use of realgar as a pigment, as to the two pre- : ceding articles, have been made. Sclieele's Green, Is a useful pigment; it is prepared by mixing arsenite of potash with a solution of sulphate of copper; PREPARATIONS OF COPPER—VERDIGRIS. 87 a fine apple-green precipitate is the result, and is called, from its discoverer, Scheele's Green . The same complaints have not been made against this article as against others above named, into which arsenic enters as a compound. Or, precipitate a solution of 2 lbs. of sulphate of copper in water, by a solution of eleven ounces of white arsenic and 2 lbs. of sub-carbonate of potash in two gallons of boiling water; wash the precipitate. By varying the proportions of sulphate of copper, arsenic, and sub-carbonate of potash, a beautiful blue pre¬ cipitate may be obtained. For another preparation into which arsenic enters, see the Preparations of Copper, article Schweinfurfs Green . Preparations of Copper. Copper, in its metallic state, rarely, if ever, enters into the composition of a paint, but combined with acids, and particularly with the acetic acid, its uses as a pigment are important. Verdigris . Subacetate of Copper. Verdigris is a bluish green substance, manufactured chiefly in the south of France, at Montpellier, and in the environs of that city. It is made by spreading the husks and stalks of grapes, after the juice is expressed from them for wine, upon plates of copper, in jars. The acetic acid which is produced in the husks, &c. by their being moistened, and having the acetous fermentation excited in them, combines with the copper, and converts the 88 FRENCH VERDIGRIS. surface of the plates into a green rust. This rust is scraped off, and is the verdigris of the shops, which is brought to this country in leathern bags of various sizes, from ten to twenty pounds each. It is now, how¬ ever, prepared in this country, but none which we have seen equals the French verdigris. Verdigris is very liable to adulteration ; when bought in 'powder it may always be suspected ; and the means of detecting such adulteration are difficult. As a pig¬ ment, if adulterated, its defects will be often visible enough when used. Verdigris makes one of the most elegant and permanent greens with which we are ac¬ quainted. In powdering this substance, care should be taken that it does not enter the mouth, either by breathing or otherwise, as it is a deleterious poison. In regard to the manufacture of verdigris, we may just mention, that Montet, a chemist of Montpellier, gave a correct detail of the operation in the Memoirs of the Academy of Sciences , for 1750 and 1753, but which it is not necessary here to repeat. It is, however, essentially as we have above stated. Verdigris should be chosen dry, of a bluish green colour, and as free from spots as possible. It is much employed in oil painting and in distemper, as well as for colouring prints and drawings; but it requires more care in the application than any other colour, whether used alone, which is seldom the case, or employed in compositions. It may be considered as one of the first ingredients in mixtures; but is not sufficiently pure for delicate painting w ithout purification; and, therefore, DISTILLED VERDIGRIS. 89 when used for that purpose, it is subjected to the fol¬ lowing process. We may just add here, that the best medium for making verdigris an oil paint, is oil of tur¬ pentine, or rather, turpentine varnish, in which last it is best to be ground, in order to preserve the delicacy of its colour. When it is ground in linseed oil, the colour is very much deteriorated, and becomes, in fact, a dirty yellow green not to be desired. Distilled Verdigris. Acetate of Copper. Distilled verdigris is found in commerce attached to sticks in elegant green crystals. It may be, however, obtained by digesting verdigris in acetic acid, and by evaporating the solution, it will be found in green pris¬ matic crystals. Acetate of copper, when new, is of a beautiful trans¬ parent green colour; when old and pulverulent, it is a dull green. In this last state it is more proper for oil paintings. In general, all colours of a saline nature, intended to be ground with oil, must be deprived of their water of crystallization; this is accomplished by re¬ ducing them to powder, and exposing them to the sun, or to the heat of a stove, before they are mixed with the oil. Colours prepared with crystallized verdigris, ace¬ tate of copper, are much brighter than those obtained from common verdigris or the subacetate of copper. But the high price of this colour frequently prevents it from being employed. It is, therefore, reserved for painting expensive articles; and is applied by the var- 90 LIQUID VERDIGRIS. nisher also to certain delicate articles, such as works of papier mache, metals, &c. Those who paint pictures grind this colour with oil of poppies, and put it into small bladders, which they prick, and extract by pressure the quantity they are desirous of using. This colour covers exceedingly well. It possesses transparency, and is employed with suc¬ cess for glazing to represent sheets of water. When applied to metal, the reflection of the light produces a very fine effect, which is still heightened by the colour. This pigment, when mixed with copal varnish, and applied to foil, produces a very rich effect. Liquid Verdigris for colouring Maps , 8fC. Put an ounce of pulverized verdigris into the bottom of a matrass, with eight or ten ounces of good distilled vinegar. Place the matrass on a warm sand bath, and shake it from time to time, till the liquid has ac¬ quired a beautiful dark green colour inclining to blue. Leave the mixture at rest, that it may become clear, and pour it into a clean vessel, which must be closely shut. This preparation is used for colouring maps and prints. The colour may be lowered, if necessary, by adding a little water or distilled vinegar in the shell into which the brush is dipped. Having disposed of subacetate and acetate of copper, we shall now proceed to supply the artist with several forms for useful pigments; none of which, however, equals the articles which have just been described, ENGLISH VERDIGRIS. 91 English Verdigris. Take of sulphate of copper twenty-four pounds ; of acetate of lead twelve pounds; of sulphate of zinc sixteen pounds; of alum two pounds. Let them be all coarsely powdered, put in a pot over the fire, and stirred till they are united into a mass. Or , Take of sulphate of copper twenty-four ounces, dis¬ solved in a sufficient quantity of water; of sugar of lead thirty ounces, dissolved also in water; mix the solutions, filter, and crystallize by evaporation. This quantity will yield about ten ounces of crystals, and is esteemed by some persons superior paint to common verdigris. Or, A verdigris may be made by putting plates of copper into a cask, between layers of vine twigs, and moisten¬ ing them with sour wine. Or, Take clippings of copper two pounds; muriate of ammonia one pound; moisten them w r ith water; when the corrosion is complete, wash the pigment. Or, Take sulphate of copper one pound; alum, or Epsom salt, one pound; dissolve these in two quarts of water, and filter. Add subcarbonate of potash sufficient to precipitate the pigment; wash it thoroughly, and diy it. 92 EGYPTIAN AZURE—OTHER BLUES. Or, Copper may be corroded with vinegar, tartar, and common salt. We do not give the method of preparing the sulphate of copper , blue vitriol , or blue copperas , so often di¬ rected to be used in the preceding and some subsequent forms, because it is an article now to be obtained so readily at any of the colour-shops. We may, however, just state that it is sometimes obtained by evaporation from the water of some copper-mines; at others, by roasting copper pyrites, in the same way as mentioned under sulphate of zinc; or by direct solution of copper in diluted sulphur acid; in either case, the liquor is boiled down, and set by to crystallize. Some of the manufacturers of copper articles at Birmingham pre¬ pare also, at a cheap price, a sulphate of copper. Egyptian Azure. Take fifteen parts, by weight, of carbonate of soda, twenty of powdered opaque flints, and three of copper filings; let these be heated together for two hours in a strong fire ; the result is, when powdered, a substance of a fine deep sky-blue, similar in every respect to the blue used by the ancient artists, the excellence of which a duration of seventeen hundred years has fully proved: this composition is easily and cheaply made. See Sir Humphry Davy in Phil. Transact . for 1815. Other. Blues, Whose composition is either copper or cobalt, may be here named. SCHWEINFURT GREEN. 93 Flanders , ox Antwerp blue , has a colour bordering on the green; it is used chiefly in landscapes. Saunders ’ blue is used for a shade to ultramarine, mazarine blue, &c. Schweinfurt Green. Dissolve in a copper vessel, by heat, one part of ver¬ digris, in a sufficient quantity of pure vinegar; add to the solution one part of white arsenic ; a dirty green precipitate results, which must be dissolved by the addition of more vinegar; let the mixture be boiled ; a granular precipitate falls in a short time of a most beautiful green colour, which must be separated from the liquor, and washed and dried. This green has a bluish shade; a deeper and more yellow green, of equal beauty, may be produced by dissolving a pound of common potash in a sufficient quantity of water, and adding to the solution ten pounds of the above green colour; warm the whole over a moderate fire; but if it be boiled too long, the colour approaches Scheele’s green; but it always surpasses it in beauty and splen¬ dour. The remaining alkaline fluid may be used in making Scheele’s green, for which, and some other preparations into which copper enters, see the Prepa¬ rations of Arsenic. A fine Green for Oil Paint. Dissolve any quantity of sulphate of copper in four times its weight of boiling water; dissolve, likewise, some carbonate of potash in water; and also some borate of soda (borax) in water; pour the solution of 94 MOUNTAIN GREEN-MOUNTAIN BLUE. potash to the first solution, in sufficient quantity to ; decompose the sulphate of copper, then add the solu¬ tion of borax till the colour has acquired its greatest intensity. The precipitate must be washed by re¬ peated affusion of water, and then dried. It may be I ground in oil, with the addition of acetate of lead. I The addition of turpentine and white-lead will, accord¬ ing to Vanherman (from whom the substance of this form is taken) gives additional body and lustre. We should, however, be very much disposed to question whether white lead will improve the colour; that tur¬ pentine varnish will do so, we do not, however, doubt: most of the preparations of copper combine well with terebinthine vehicles. Mountain Green , or Green Bice , Or green chrysocolla , is a native copper ore, and is essentially an oxide of copper, of a lighter or deeper green; it is found under different forms in China, Ger¬ many, and Siberia; that which is found in the last- named country is in stalactites, and termed malachite. Mountain green is also obtained by art, the mode of obtaining whieh does not appear to be publicly known; it may be, most probably, procured by some of the pro¬ cesses named under the head Several Colours for Stain¬ ing Rooms , below. Mountain Blue, Or blue chrysocollu , is also an ore of copper ; it is of a deep blue colour, and may be also, we presume, readily imitated by art from some of the solutions of copper. BLUE BICE—BLUE VERDITER. 95 In short, there appears to be scarcely any end to the tints of green and blue to be obtained from copper for pigments. See the following preparations. Blue Bice Is a pigment in the form of a blue powder. It has the best body of all bright blues used in common work, as house painting, &c. It should be ground very fine ; it is as durable a colour as prussian blue. This article is obtained from lapis armenus , a stone, the basis of which is chiefly carbonate, or sulphate of lime: it was formerly brought from Armenia , whence its name, but it now comes from Germany and the Tyrol. It is of a blue colour, mixed with green, white, and red. It has a good deal of resemblance to lapis lazuli , the chief difference between which and lapis ar¬ menus consists in this last being more soft, and instead of having spangles of gold, it has green spots. Encyclo¬ pedic , Tome XXV. Art. Pierre d'Armenie. According to Fourcroy, the blue colour of this stone is produced by an oxide of copper; we have, therefore, arranged bice as one of the copper preparations. Blue Verditer. We are indebted to M. Pelletier for an interesting detail of the various processes he employed to procure to his country the fruits of a new manufacture, which may be seen in the Annales de Chimie, Yol. XIII. p. 47. Dissolve copper, cold, in diluted nitric acid, and pro¬ duce a precipitation of it by means of quick-lime, so that 4 96 GREEN VERDITER. all tlie acid shall be absorbed. Let the precipitate be washed, and spread out on a piece of linen cloth to drain; place this green precipitate on a grinding-stone, and add a little quick-lime, in powder, when the green colour will be immediately changed into a beautiful blue. The proportion of lime added should be from seven to ten parts in a hundred. Let the colour be dried. Blue verditer is proper for distemper and for varnish: but it is not fit for oil painting, as the oil renders it very dark. If used with oil it ought to be brightened with a great deal of white. Green Verditer. Green verditer does not require the same care in the preparation as the preceding. It is the general result of the precipitation of copper, dissolved in nitric acid, effected by means of chalk or a white marl. In the latter case, the divided clay, which forms part of it, gives pliability to the verditer, when employed as a colour. If too much charged with copper it w^ould not be fit for oil 'painting, as the oil would produce too dark a green. In this case it must be corrected by the addition of a little white lead or Spanish white. This colour, however, is much better calculated for distemper; and the painter may supply its place in oil-painting with verdigris, mixed with two or three parts to one of white lead. With small proportions of verditer, the lightest shades of sea-green may be represented. COLOURS FOR STAINING ROOMS—STUCCO. 97 Several Colours for Staining Rooms. Besides this and the preceding precipitate of Blue verditer from nitrate of copper, several verditers having green or bluish shades, may be also prepared from solutions of sulphate of copper (Blue vitriol) in water, the precipitate being made by the addition of either quick-lime, chalk, or the fixed alkalies. They are all suited for water-colours, or rather for the colouring of apartments, being employed with a proper size. A mixture for staining rooms bf an elegant green colour may be made thus: take of sulphate of coppery four pounds; whiting (that is, levigated chalk), three pounds; water, one gallon. Dissolve the sulphate of copper in the water, gradually made hot in a vessel of stone-ware; when it is dissolved, add the whiting in fine powder, and mix them well together; a sufficient quantity of size must be added to prevent the colour being rubbed off the wall. Stucco may also have imparted to it an elegant green, by mixing a solution of sulphate of copper with the ingredients of which the stucco is made, provided that lime or chalk enter into its composition, in order that the sulphate of copper may be decomposed; but care must be taken in smoothing the stucco, that a copper , not an iron trowel be used, or the colour will be spoiled, in consequence of the stronger affinity which iron has for the sulphuric acid in the sulphate of copper. F 98 PREPARATIONS OF QUICKSILVER. Preparations of Quicksilver, Native Cinnabar , Factitious Cinnabar , Vermilion , or Red Sulphuret of Mercury. The metallic combinations which constitute the greater part of ores, depend on operations which nature performs in silence; which she varies, and which it was reserved for modern chemistry to discover. Native Cinnabar, the natural combination of sulphur and mer¬ cury, affords a specimen of these results. Seven parts of mercury and one of sulphur form Factitious Cinna¬ bar, that brilliant needly mass, of a beautiful red colour, the brightness of which depends on proper proportions of the two component principles, as well as on the greatest possible division of them. This pre¬ paration assumes a very high colour under the muller, and when divided in this mechanical manner, it ex¬ changes the name of cinnabar for that of vermilion. It is manufactured chiefly in Holland; but a very fine vermilion is brought also from China.' It is sometimes adulterated with red-lead. The adulteration may be detected by exposing the suspected article to heat in a crucible; if lead be mixed with it, it will remain at the bottom of the crucible, while the real vermilion is vo¬ latilized by the heat. The best is of a deep rich crim¬ son colour. The sulphur is liquified in large earthem jars, or in iron pots, and the mercury is mixed in the proper pro¬ portions. These two matters become heated to such a degree, by the mere effect of the combination, as to inflame; and when this result takes place, the cinna- 8 VERMILION—TURBITH MINERAL. 99 bar is more easily sublimed, because the excess of sulphur is destroyed. The matter when cold is pul¬ verized and sublimed in flat earthen vessels, which are covered by other vessels of the same substance. These subliming vessels are arranged in long sand furnaces, called galleries, where the sublimation is effected only by a very strong heat. If the first sublimation does not produce cinnabar of a beautiful colour when ground, the matter is subjected to a second sublimation, the effect of which is to destroy the quantity of sulphur greater than that essen¬ tial to the most perfect combination, in regard to the tone of colour required in vermilion. The art of preparing fine vermilion is in very few hands. It is suspected that some material is used in its levigation which very much improves its colour; that material has been by some supposed to be urine. We have stated the quantity of mercury may be seven parts to one of sulphur, but the London and Dublin Dispensa¬ tories direct forty ounces of quicksilver to eight ounces of sulphur. Vermilion is employed in various kinds of painting; for colouring sealing-wax; and, in general, for all ornaments which require a high and strong colour agreeable to the eye. It has no rival but in carmine, which, though it produces a mellower and fuller colour, is no less pleasing. Turbith Mineral , or Sub-oxysulphate of Mercury , Is a compound of quicksilver and sulphuric acid, and used occasionally as a pigment, of a bright lemon f 2 100 PREPARATIONS OF LEAD—NAPLES YELLOW. colour; but it is necessarily dear, and is not now much in request. It was formerly used in medicine, but is now expunged from the London Pharmacopoeia. Its mode of preparation may be seen by reference to the Phar. Collegii Regalis, Lond.\ published in 1788, page 83, under the article Hydrargyrus vitriolatus, or vitri- olated quicksilver , but which it does not appear neces¬ sary that we should here describe. Preparations of Lead. White Lead has been already noticed under the Whites in the preceding part of this chapter; we shall here treat of the remaining preparations into which lead enters as a pigment. Naples Yellow. The nature of Naples yellow has not been long known. The secret of preparing it was in the posses¬ sion of a Neapolitan, who mixed calcined lead with a third of its weight of powdered antimony, and exposed the mixture to a potter’s furnace. From the researches of Fougeroux de Bondaroy, (Memoires de VAcademie des Sciences , 1772,^ the formula was modified in the following manner:— Take twelve ounces of white lead, two ounces of the common antimony (sulphuret of antimony), half an ounce of calcined alum, and an ounce of muriate of ammonia, all in powder; and having mixed them tho¬ roughly, put them into a capsule or dish of crucible earth, and place over it a covering of the same sub¬ stance. Then expose it at first to a gentle heat, which NAPLES YELLOW—PATENT YELLOW. 101 must be gradually increased till the capsule is mode¬ rately red. The oxidation arising from this process requires at least three hours’ exposure to heat before it is completed. The result of this calcination is Naples yellow, which must be ground with water on a 'por¬ phyry slab, by means of an ivory spatula, as iron or steel imparts a green colour to it. The paste is then dried and preserved for use. It is a yellow oxide of lead and antimony. There is no necessity of adhering so strictly to the doses as to prevent their being varied. If a golden colour be required in the yellow, the proportions of the antimony and muriate of ammonia must be increased. In like manner, if you wish it to be more fusible, in¬ crease the quantities of antimony and calcined alum. Sulphuret of antimony, which contains a little iron, is the most proper for this composition. Naples yellow is fit for every kind of painting, not excepting that on porcelain and enamel. Patent Yellow , or Montpellier Yellow. Patent yellow is a compound of oxide and chloride of lead. It was for many years prepared only by the patentee in this country, who was extremely jealous of his process: the patent has, we presume, long since expired. This pigment is made by submitting litharge and common salt, in certain proportions, to the action of an intense fire in suitable crucibles. The following is the substance of the process given in the former editions of this work. Take fifty pounds of litharge, finely powdered; dis- f 3 102 PATENT YELLOW. solve twelve pounds of common salt in about fifty pounds of water; mix a portion of this solution with the litharge, so as to form a thin paste; let the whole remain for some hours; when the surface begins to grow white, stir.the mass with a strong wooden spatula; as the consistence of the mass increases, add more of the solution; and if the whole be not sufficient to keep the paste of the same consistence, add simple water. The stirring is a necessary part of the process. The paste will be then very white, and in the course of twenty-four hours becomes uniform and free from lumps. It is then to remain for the same space of time, stirring it at intervals to complete the decomposition of the salt. The paste is now to be well washed to carry off the caustic soda which adheres to it; to extract the whole of it, the mass is also put into a strong linen cloth and subjected to a press. The remaining paste is distributed in flat vessels; and these vessels are exposed to a strong heat, in order to effect a proper oxidation, which converts it into a solid, yellow, brilliant matter, sometimes crystallized in transverse striae. This is patent, or Montpellier yel¬ low, which may be applied to the same purposes as Naples yellow. The soda separated by the washing may be con¬ verted to many purposes in the arts. The following form is given for making Patent Yel¬ low in Grafs Supplement to the Pharmacopoeias , 1818. Common salt 1 cwt., litharge 4 cwt., ground to- OXIDES OF LEAD. 103 gether with water, kept for some time in a gentle heat, water being added to supply the loss by evaporation, the natron then washed out with more water, and the white residuum heated till it acquires a fine yellow r colour. Patent yellow is a very bright and permanent yellow, especially for oil colours; but it has been latterly in a great measure superseded by Chrome Yellow, or Chromate of Lead, which will subsequently be de¬ scribed. The Oxides of Lead. Lead readily combines with oxygen, even without heat, or the intervention of any other body, except at¬ mospheric air and moisture. Oxygen combines, how¬ ever, with lead in various proportions, forming with it several oxides of different colours. The oxides used in painting and the arts are usually obtained by the means of heat. According to Fourcroy (Elements of Chemistry , Vol. 2, page 386,) the white dust formed on the surface of lead exposed to the action of common air is not a pure oxide of lead, but oxide of lead combined with carbonic acid absorbed from the atmosphere. The same author also states, that all the oxides of lead, and more especially minium , absorb carbonic acid when exposed to the air: in order, therefore, to preserve oxide of lead pure, it should be kept from the contact of air; or the carbonic acid which it has absorbed from the air may be separated by heating it before it is used, if such a process should be deemed necessary. For other observations on white lead , see page 50. f 4 104 OXIDES OF LEAD—MASSICOT-LITHARGE. Lead exposed to heat readily melts, and its surface then becomes covered with a pellicle of a grey colour; i if this pellicle be removed, it is immediately succeeded by another; and so on till the whole mass is, at length, j reduced to a grey powder. This oxide is not used in painting; it is, however, used largely in the glazing of earthenware. It is generally considered as in the lowest state of oxidation. Massicot , or Yellow Oxide of Lead . After the preceding operation, if the temperature be increased, the grey oxide assumes a yellow colour, and when this colour is sufficiently developed, it is dis¬ tinguished by the name of massicot , or more correctly, yellow oxide of lead . This oxide was employed in painting before Naples or patent yellow was known; but it is now little, if at all used. Litharge , or Vitreous Oxide of Lead , Is usually considered of the same degree of oxidation as massicot; yet it contains, w T e believe, more oxide than that substance. It is obtained on a large scale at the lead-works, by causing streams of air from powerful bellows to be poured on melted lead, the surface of which is immediately converted into litharge, that is at once blown off by a blast of air. The colour of litharge varies; but the best is in shining scales of a reddish hue, and is, if pure, wholly soluble in olive, linseed, and other expressed oils; in a small quantity by being merely mixed with them, and occasionally shaken; but in large quantities by being OXIDES OF LEAD—LITHARGE. 105 boiled at once with them, and having a portion of water added to moderate the heat. The best litharge is made in or near London. Litharge is used in painting chiefly as a drier, being ground in oil, and mixed with the colours; it is also boiled with linseed oil to render it more disposed to dry. It is also largely used for the manufacture of patent yellow, as before mentioned. Of course it can¬ not be applied as a drier to white and other delicate colours; but for all dark and coarse colours it is an extremely useful ingredient. This pigment was formerly known in commerce under two names, Litharge of Gold and Litharge of Silver: the distinctions are now unknown. It is not only very remarkable that most of the oxides of lead, and especially litharge, readily combine with the fixed and some of the animal oils, but also that this combination is of a singular and intimate kind, so as to form, under ordinary circumstances, an indestructible compound. Thus, in regard to litharge, if five pounds of powdered litharge be boiled in eight pints of olive oil, with a small addition of water to modify the heat, in a few hours the litharge combines with the oil, forming a hard and white mass when cold, which is known in Pharmacy by the common name of Diachy¬ lon . This disposition of lead, thus to combine with fixed oils, renders it very useful as a pigment, a sub¬ stitute for which, although all its preparations and combinations, and even the effluvia from them are poisonous, has not yet, unfortunately, been found. 106 RED LEAD. Red Lead—Red Oxide of Lead — Minium. This pigment is obtained by exposing Massicot to the flame of a reverberatory furnace for forty-eight hours, or till it becomes of a fine red colour; in this process it appears that frequent stirring is necessary, in order that every portion of the oxide should come in contact with the air, so that an absorption of oxygen should take place. Red Lead is employed extensively in house and coach painting, and for reds, and as a ground to ver¬ milion, which is applied to the painting of decorations requiring durability. It combines with the fixed oils in a similar way to litharge, by producing a hard and indestructible com¬ pound; but in boiling it with oil, unless the heat be much urged, its colour still remains red; if the heat be in excess, the compound becomes of a brown colour. Of course, red lead, as a paint, requires with the fixed oils no drying material, as unless soon used after being ground in oil, it hardens into an unmanageable mass. The same observation applies to patent yellow *. * In the last edition of this work, three degrees of the oxidation of lead were described; the grey oxide was called the first; Massicot and Litharge the second; and Red Lead the third. We have not preserved this nomen¬ clature in the present edition, because we do not believe that our knowledge of the different oxides of lead is yet sufficiently accurate to warrant the arrangement. That the grey oxide contains a slight dose of oxygen, mas¬ sicot and litharge more, and red lead yet more oxygen, we do not doubt; but Dr. Thomson mentions four oxides; Dr. Ure says “there are cer¬ tainly two , perhaps three oxides of leadMr. Brande says there are three oxides of lead; massicot he calls the protoxide; Red Lead the deutoxide; and an insoluble brown substance the peroxide ; this last being, according to him, lead saturated with the highest dose of oxygen, namely, fifteen parts to ninety-seven parts of lead; while red lead contains only 97 parts of lead and CHROME YELLOW. 107 Chrome Yellow—Chromate of Lead. Chrome is a metal discovered by Vauquelin in 1797. Its colour resembles iron; its specific gravity is 5.9. It is brittle and difficult of fusion. Chromic acid, or the red peroxide of chrome, is most easily procured from na¬ tive chromate of lead, first found in its natural state in Siberia; it may also be procured from native Chromate of Iron. Chromate of lead, a beautiful yellow colour, was for some time, on account of its scarcity and high price, confined to the use of portrait painting; but, for some time past, it has been prepared artificially in this country, so as to have superseded, in a great degree, the use of patent yellow among coach-painters and house-painters throughout the kingdom. Besides the extreme richness and beauty of its colour, this pigment is said to possess so much body, that one pound of it will go as far as four pounds of patent yellow. It is so fine that it requires no laborious grinding, but will spread readily under the brush, and may be laid on with varnish; it is not poisonous like King’s yellow; it will stand better than most other pigments; sul¬ phuretted hydrogen-gas only impairing its beauty; against which, however, it may be protected by var¬ nish. It makes also a beautiful green with Prussian blue. Care should be taken to obtain it pure, as it is 11.25 parts of oxygen. From these differences, we are led to conclude, that the doses of oxygen in lead, in the different preparations of it, are much more numerous than are stated by chemists; we fear the desire of sys¬ tematizing, of proving that oxygen always combines with the metals in definite proportions, is extremely detrimental to the progress of chemical philosophy. Editor. F 6 108 CHROME YELLOW. apt to be adulterated with white lead or patent yellow, from both which it cannot be distinguished by the eye, except in its want of beauty and intensity of colour; patent yellow is, however, a much more heavy pigment than Chrome yellow: of course, chemical analysis would soon detect these adulterations, but artists are not often willing to enter into such inquiries. The following method of preparing this substance is from Vanherman. “ To one pound of chromate of iron, dissolved in two gallons of warm water, add two pounds of white lead ground in water; mix these ingredients well, and then add one pound of sugar of lead; stir the whole and suffer it to precipitate, when you will obtain a deep yellowy which may be put in the filter and afterwards f dried. If the colour be required of a light or lemon tint, more sugar of lead must be added.” A Dr. Bollman some years since prepared chrome yellow at Battersea of a very superior kind; but we are not acquainted with the process which he employed. Chromate of lead is now applied to dyeing cloth in this country; a chromate of potash is first obtained, and the cloth being submitted to a w*eak solution of acetate of lead a decomposition takes place ; the potash unites with the acetic acid in the acetate of lead and the chro¬ mic acid in the potash combines with the lead, thus forming a beautiful yellow colour. In a similar way we suspect sometimes the chromate of lead for the painter is now obtained. Oxide of Chrome , a fine Green. This article, as a pigment, is prepared thus: a chro- OXIDES OF CHROME—BLUE, 109 mate of mercury is formed as usual by precipitation from chromate of potash, and a nitrate of mercury, as neutral and concentrated as possible. The oxide of chrome, obtained by heating the chromate of mercury, will bear the greatest perfection of colour if it be put into an unglazed porcelain crucible, and exposed to the heat of the furnace during the time required for baking the porcelain. The oxide produced will be a fine grass green . Blue Oxide of Chrome. The concentrated alkaline solution of chrome is to be saturated with weak sulphuric acid, and then to every 8 lbs. is to be added 1 lb. of common salt, and half a pound of sulphuric acid; the liquid will then become green. To be certain that the yellow is totally de¬ stroyed, a small quantity of the liquor is to have pot¬ ash added to it and filtered; if the acid be still yellow a fresh portion of salt and of sulphuric acid must be added; the fluid is then to be evaporated to dryness, re-dissolved and filtered by caustic potash. It will be a greenish blue colour, and being washed must be col¬ lected upon a filter.— Bull . JJniv. We give the two preceding forms, presuming that they are both elegant and useful pigments; but we know nothing of their use. Dichromate of Lead , Is of a full red colour, and is prepared by digesting a solution of the yellow chromate of potash upon car¬ bonate of lead, at a boiling temperature, in the pro¬ portion of one part of the former to two of the latter, stirring up the solid matter very frequently. 110 ACETATE OF LEAD. This pigment stands the glazing heat of a potter’s kiln, and is a good red on ordinary kinds of stone-ware. It is also, we presume, a good oil-colour. See Journal of Science, No. XII. N. S. Page 359. Acetate of Lead or Sugar of Lead, Although not in itself a pigment, is so very useful when mixed with many paints, that in a description of colouring materials, it ought not to be passed over. Sugar of lead, as found in commerce, is usually im¬ ported from the continent in large packages; it has a crystalline yellowish white hue not very unlike some kinds of raw sugar, whence, and from its sweetish taste, it has obtained its common name. It may be obtained very easily from many of the oxides of lead, or from white lead, by means of the acetic acid. It is rather remarkable, that the colleges of London, Dublin, and Edinburgh, give different forms for its preparation in their respective pharmacopoeias. It is, however, obtained by digesting white lead in about ten times its weight of distilled vinegar or pyrolignous acid; the solution being filtered or purified by decantation, and evaporated till a pellicle appears on the surface, it is set by to crys¬ tallize; the crystals are, of course, the acetate of lead. The chief use of this article in painting is as a drier; and particularly so for white and other oil paints where a delicacy of colour is wanted to be pre¬ served, as it appears to possess scarcely, if any, tinge- ing property. The painter should not forget that this, as well as all the other preparations of lead, is highly poisonous. ANIMAL AND VEGETABLE COLOURS. Ill CHAPTER III. Descriptive Account of the Animal and Vegetable colouring substances used in painting , with a detail of the process employed to obtain them , and of the methods of preparing and modifying them. Of Lakes. * The term lake is applied to those colours which are obtained by precipitating the colouring matter with some earth or oxide. It appears that the word lac or lake is derived from India, and that it is there employed to express a colour or a solid colouring part. The prin¬ cipal lakes are carmine , Florence lake , and madder lake . But almost all vegetable colouring matters may be pre¬ cipitated into lakes of more or less beauty by means of alum or oxide of tin. The preparation of the crayons used in painting is not, however, confined to the chemical process above mentioned: there is one which is simpler and less tedious; it is that which serves as a basis to the pre¬ paration of Dutch and other pinks. It consists in mix¬ ing a fine argillaceous matter with the coloured solu¬ tion, and subjecting the whole to careful evaporation, or in exposing the liquid paste on pieces of chalk covered with a clean cloth, to prevent the colour from adhering to the chalk. 112 OF LAKES. This method is more economical than the chemical process; but it requires a very nice choice in the quality of the white designed for the operation, and in particu¬ lar the precaution of previous washing, to remove the fine sandy parts with which even the finest white clays are mixed. Lakes differ both in colour and quality. They are more or less capable of resisting the action of the air and the light. The lakes most in request are those called carminated (a term derived from carmine , a co¬ lour which we shall presently describe) because they strongly resist the destructive influence of light. Their colouring part is extracted from cochineal. They are imitated with colouring parts extracted from some ve¬ getable substances; but the latter produce generally inferior lakes, their colouring parts being easily altered by the combined action of air and light. Such are, however, still of some use when reserved for temporary articles, as printed calicoes, paper hangings, &c.; but they must be entirely banished from the pallet of the painter who sets any value on the opinion of posterity. It is not easy to distinguish whether a lake has really been prepared from cochineal, or from some vegetable colouring substance. Means have been found, by cer¬ tain re-agents and various mixtures, to give such splen¬ dour to inferior lakes, that the most skilful painters are often embarrassed in their choice. The dread of em¬ ploying uncertain colours renders them timid, and often makes them neglect colours the duration of which they cannot foresee. If vinegar, we axe told, be poured upon lakes, the CARMINE. 113 colouring part of which has been derived from Brasil wood or madder, &c. they will instantly turn yellow ; but we shall soon see what little confidence ought to be placed in this and other processes, an attention to which, and their results, demands more time than an artist is in general disposed to bestow upon them. As, however, the subject is important, we prepared some real as well as false carminated lakes, that we might subject them to the action of some re-agents. The annexed table exhibits the results of those com¬ parative experiments. Carmine. This kind of fecula, so fertile in gradations of tone by the effect of mixtures, and so grateful to the eye in all its shades; so useful to the painter, and so agreeable to the delicate beauty, is only the colouring part of a dried insect, known under the name of cochineal . A mixture of 36 grains of chouan seed, 18 grains of autour bark, and as much alum, thrown into a decoc¬ tion of 6 gros of pulverized cochineal and 5 pounds of water, gives at the end of horn five to ten days, a red fecula, which, when dried, weighs from 40 to 48 grains. This fecula is carmine. The remaining decoction, which is still highly coloured, is reserved for the pre¬ paration of carminated lakes. The above was the process given for obtaining car¬ mine in the second edition of this work. The following is from Ure’s Dictionary of Chemistry, article Lake. 114 CARMINE-CARMINATED LAKE. Another process for Carmine. Take four ounces of finely powdered cochineal, four or six quarts of rain-water that has been previously boiled in a pewter kettle; boil the cochineal in this water for six minutes; some add, during the boiling, two drachms of powdered cream of tartar. Eight scruples of rock-alum are then to be added, and the whole kept upon the fire one minute longer. As soon as the gross powder has subsided to the bottom, and the decoction is become clear, the latter is to be decanted into large cylindrical glasses, covered over and kept undisturbed till a fine powder is observed to have settled at the bottom. The superincumbent liquor is then to be poured off from this powder, and the powder gradually dried. From the decanted liquor, which will be still much coloured, the rest of the colouring matter may be se¬ parated by the addition of the solution of tin, when it will yield a carmine little inferior to the first product. A pound of good cochineal will produce about an ounce and a half of carmine, and about a pound and a quarter of red lake. Carminated Lake , No. I. The decoction which floats over the coloured pre¬ cipitate, carmine, being still highly coloured, the addi¬ tion of alum, which is afterwards decomposed by a so¬ lution of carbonate of soda, precipitates the alumina, which in precipitating carries with it the colour of the CARMINATED LAKE. 115 solution. According to the quantity prescribed for the r composition, two or three ounces of alum may be em- j ployed. The greater or less quantity of this substance, 5 the base of which combines with the colouring fecula, determines the greater or less intensity in the colour of t the lake resulting from it. When the process is con¬ ducted on a small scale, the precipitate may be received on a filter; it is then washed with warm water; and when it has acquired the consistence of soft paste, it is formed into small cakes or sticks. It is this substance which constitutes the beautiful carminated lakes used for crayon painting. In operating on a large scale, the whole of the alka¬ line liquor judged necessary after a few trials to decom¬ pose the quantity of alum intended to be employed, may be divided into three or four separate portions. As many cloth filters as there are alkaline portions be¬ ing then prepared, the first portion of alkaline liquor is poured out, and the coloured precipitate resulting from it is received on one of the filters : the coloured liquor which passes through the filter receives the second por¬ tion of alkaline liquor, and the latter produces a second precipitate which is received on a new filter. This operation is then continued till the last portion of alka¬ line liquor has been employed. The lakes deposited on the filters are washed in warm water; and when they have drained, they are carried along with their cloth to the chalk driers. The first precipitation gives a car¬ minated lake of a very high colour; the second is some¬ what lighter; and the rest go on decreasing in the same manner. By these means the artist obtains from the 116 CARMINATED LAKE. same solution various shades of colour which are much mellower, and more delicate than those resulting from a mechanical mixture of white clay in different propor¬ tions, or lake saturated with colour by one operation. If the manufacturer of crayons prefers in these opera¬ tions to mix the solution of cochineal with fine white clay, well washed, he may obtain the same shades by diluting different quantities of clay with one measure of the decoction of cochineal. For example, a pound of decoction saturated with colour, and a quarter of a pound of clay; the same quantity of decoction, and half a pound of clay ; a pound, and so on. This opera¬ tion, which is conducted in the same manner as that for Dutch pink, is speedier than that performed by a chemi¬ cal decomposition with alum and an alkali. The lakes obtained are exceedingly beautiful; but unless the clay be very fine they never have the brightness, softness, and mellowness of the former; as the saline matters employed form a mordant which is not furnished by the second method. A beautiful tone of violet, red, and even of purple red, may be communicated to the colouring part of cochineal by adding to the infusion of it a solution of tin in nitro-muriatic acid (aqua regia). The effect will be greater, if, instead of this solution, a solution of muriate of tin be employed. Carminated lake from scarlet cloth. Carminated lake may be composed also, without em¬ ploying cochineal in a direct manner, by extracting the CARMINATED LAKE. 117 colouring matter from any substance impregnated with it, such as the shearings of scarlet cloth. Boil one pound of fine wood ashes in forty pints of water in an iron vessel for a quarter of an hour; then filter the solution through a piece of linen cloth till the liquor passes through clear. Put the liquor on the fire, and having brought it to a state of ebullition, add two pounds of the shearings or shreds of scarlet cloth dyed with cochineal, which must be boiled till they become white ; then filter the liquor again, and press the shreds, to squeeze out all the colouring part. Put the filtered liquor into a clean vessel and place it over the fire. When it boils, pour in a solution of ten or twelve ounces of alum in two pounds of spring water which has been filtered. Stir the whole with a wooden spatula till the froth that is formed be dissi¬ pated ; and having mixed with it two pounds of a strong decoction of Brasil wood, pour it upon a filter. After filtration wash the sediment with spring water, and re¬ move the cloth filter containing it to the chalk driers. The result of this operation will be a beautiful lake ; but it has not the soft velvety appearance of that obtained by the first method. Besides, the colouring part of the Brasil wood which unites to that of the cochineal in the shearings or shreds of scarlet cloth, lessens the unalte- rability of the colouring part of the cochineal. For this reason purified potash ought to be substituted for the wood ashes. In this process the alum undergoes decomposition by the solution of wood ashes, which is a carbonate of 118 FLORENTINE LAKE. potash. The alumina, in precipitating, combines with the colouring matter of the cochineal, which the alkali has taken from the scarlet cloth. This method is more complex than the preceding. Besides, it is not economical for colour-makers who may be at a distance from cloth-dressers. Another carminated Lake , called Florentine Lake . Take the sediment of cochineal, which remains after the preparation of carmine, together with the red liquor that remains after the preparation of the same, and boil them in the requisite quantity of water; then let the whole be precipitated with the solution of tin; the pre¬ cipitate must be frequently edulcorated with water. Boil also two ounces of fresh cochineal and one of cream of tartar in a sufficient quantity of water; let the decoction be poured off clear and precipitated with the solution of tin, and the precipitate be washed. Dis¬ solve, at the same time, two pounds of alum in water; precipitate the alumina with a lixivium of potash, and let the white earth be washed repeatedly in boiling water. Lastly, mix both precipitates together in their liquid states, put upon a filter and dry the mixture. For the preparation of a cheaper lake instead of cochineal, one pound of Brazil wood may be treated in the preceding manner.— Ure. CARMINATED LAKE FROM MADDER. 119 False carminated Lakes , in which the colouring 'part is different from that of Cochineal . Carminated Lake from Madder. No. II. Notwithstanding the unfavourable opinion entertained in regard to lakes extracted from vegetables, a colour¬ ing substance is found in the root of madder, to which the addition of alum gives a very warm tone of ex¬ ceedingly bright purple red, and of such durability as places this lake far above that obtained from a decoction of Brasil wood. Boil one part of madder in from twelve to fifteen parts of water till it be reduced to about two parts. Then strain the decoction through a piece of strong linen cloth, which must be well squeezed; and add to the decoction four ounces of alum. The tint is then a beautiful bright red, which the matter will retain if it be mixed with proper clay. In this case expose the thick liquid which is thus produced on a linen filter, and subject it to one washing to remove the alum. The lake, when taken from the driers, will retain this bright primitive colour given by the alum. But if in the process for making this lake decompo¬ sition be employed, by mixing an alkali with the solu¬ tion, the alum w r hich is decomposed deprives the solu¬ tion of its mordant, and the lake obtained after the sub¬ sequent washings appears of the colour of the madder bath without any addition: it is of a reddish brown. 120 MADDER LAKE. In this second operation seven or eight ounces of alum ought to be employed for each pound of madder. This kind of lake, obtained by decomposition, is ex¬ ceedingly fine; but it does not possess that bright red colour so much sought after : it may, however, be com¬ municated to it, if the washed precipitate be mixed before it be dry with solution of alum. If arseniate of potash or sugar of lead be added to the solution of alum and madder, a rose-coloured lake will be obtained on the addition of carbonate of soda. It is that marked No. 3 in the comparative table. The following is another process of obtaining lake from madder, communicated to the Society of Arts by Sir H. C. Englefield, a few years since. Another process for Madder Lake. Enclose two ounces troy of the finest crop madder in a bag of fine and strong calico, large enough to hold three or four times as much. Put it into a large marble or porcelain mortar, and pour on it a pint of cold, clear, soft water. Press the bag in every direction, and pound and rub it about with a pestle as much as can be done without tearing it; and when the water is loaded with colour, pour it off. Repeat this process till the water comes off slightly tinged, for which about five pints will be sufficient. Heat all the liquor in an earthen or silver vessel till it is near boiling, and then pour it into a large basin, into which a troy ounce of alum dissolved in a pint of boiling soft water has been previously put. Stir the mixture together, and, while stirring, pour in gently about an ounce and a half of 5 LAKE FROM BRASIL WOOD. 121 saturated solution of subcarbonate of potash. Let it stand till cold to settle; pour off the clear yellow liquor; add to the precipitate a quart of boiling soft water, stirring it well; and when cold separate, by fil¬ tration, the lake, which should weigh half an ounce. If less alum be employed the colour will be some¬ what deeper; with less than three-fourths of an ounce, the whole of the colouring matter will not unite with the alumina. Fresh madder root is equal, if not superior to the dry. Lake from Brasil Wood. Brasil wood affords two different carminated lakes, and of very rich colours, if the process which facili¬ tates the removal of its colouring part to the alumina disengaged from the alum, or to proper clay, be varied. These two shades are obtained by employing chemical decomposition, or by simple mixture without decompo¬ sition. The two processes we use are as follow: Boil four ounces of the raspings of Brasil wood in fifteen pounds of pure water, till the liquor is re¬ duced to a pound and a half or two pounds. The liquor has then a dark red colour, inclining to violet; but the addition of four or five ounces of alum gives it a bright red, inclining to rose-colour. When the liquor has been strained through a piece of linen cloth, if four ounces of carbonate of soda be added with caution, on account of the effervescence which takes place, the colour, which by this addition is deprived of its mor¬ dant, will resume its former tint, and deposit a lake G 122 LAKE FROM BRASIL WOOD. which, when washed and properly dried, has an exceed¬ ingly rich and mellow violet-red colour. If only one half of the quantity of carbonate of soda be employed for this precipitation, the tint of the lake becomes clearer; because the solution still retains the undecomp'osed aluminous mordant. In the last place, if the method employed for Dutch pink be followed, by mixing the aluminous decoction of Brasil wood with pure clay, such as Spanish white and white of Morat, and if the mixture be deposited on a filter to receive the necessary washing, you will ob¬ tain a lake of a very bright dark rose-colour. The lake which we have prepared in this manner, making use of pure clay from Morat, is marked No. 5 in the comparative table. The first lake is harder than the second, because, not¬ withstanding the washing, it retains salts which adhere strongly to the clay; but the second is too soft. Its colour, heightened by the mixture of alum, seems to have a superiority over the aluminous lake of madder, which brings it near to the lakes made from cochineal. By the same processes a very beautiful lake may be extracted from logwood. In general, lakes of all co¬ lours, and of all the shades of these colours, may be prepared from substances, the colouring part of which is soluble in boiling water; because it is afterwards communicated by decomposition to the alumina pre¬ cipitated from alum, by means of an alkali; or the tincture may be mixed with a pure and exceedingly white argillaceous substance, such as real Spanish white, or white of Morat. It is the property of alumina, OBSERVATIONS ON LAKES. 123 and of all clays, to form a kind of combination with the divided oily or resinous substances with which they are in contact, and to retain them. When lakes are prepared by the medium of alum, which is decomposed by the application of an alkaline liquor, carbonate of soda is to be preferred to carbonate of potash, because the new salt, which results from the decomposition of the alum by means of the former, is far more soluble than that which might be formed by potash. The washing of the lake then succeeds better, and no salt remains to make it hard. Lakes enter into the composition of solid colours. They may be employed to colour changing spirituous varnishes; but in this particular case it would be simpler to extract the tincture from cochineal itself, since no¬ thing is required but the colouring part. It has been commonly believed that real carminated lakes, the colouring part of which is obtained from cochi¬ neal, can easily be distinguished, by means of vegetable acids, from those in which the colouring part is a vege¬ table product. The latter, as asserted, do not stand the test of immersion in these acids withoutbecoming yellow. In order, however, to ascertain the truth of the commonly received opinion, we exposed to the action of different re-agents five kinds of lake, the composition of most of which has been above so minutely detailed, that the pro¬ cesses may be applied to every substance the colouring part of which is soluble in water. We shall here exhibit a comparative table of the effects resulting from the different processes employed. The experiments were made in large watch glasses exposed to the open air; G 2 124 OBSERVATIONS ON LAKES. and as the action of the light has a more sensible in¬ fluence on some colouring parts than on others, it was thought proper to subject the mixtures to it. Re-agents act in a different manner on the same sub¬ stance. Some, to produce their effect, require only a momentary contact; while others require more time, and do not manifest their influence till they have pro¬ duced a kind of solution. This circumstance induced us to vary the experiments: we put the same mixtures into bottles closely shut, and kept an account of the results observed at the moment of contact, twenty-four hours after, and at the end of three weeks. They are exhibited, such as we observed them, in the annexed table. It should be also observed that carbonate of potash was not employed in the first experiments. This short view of these results will, no doubt, be sufficient to establish the essential differences between the various colouring parts applied to the composition of carminated lakes; and to prove the insufficiency of the means hitherto considered as the most certain, for distinguishing real carminated lakes from those which are only an imperfect imitation of them. Lemon juice, or any other vegetable acid, and particularly vinegar, to which was ascribed, but w ithout any reason, the pro¬ perty of changing to yellow the bright or purple red given to these counterfeited lakes, and even the mineral acids which we employed, exhibit characters entirely opposite in these colouring parts, which are foreign to that of cochineal. We every where see that the de¬ velopment of the red colour, under different tones of shade, is the certain result of the first contact, except Comparative Table of the results of the mixture of some re-agents with different carminated lakes, observed at different periods in close vessels. RE-AGENTS. No. 1. Lake from cochineal with alum the alkali of soda. At the time of mixture. Twenty-four hours after. Three weeks after. No. 2. Lake from madder with alum decom posed by soda. At the time c mixture. Twenty-four hours after. Three weeks after. No. 3. Lake from madder with arseniate of potash and sugar of lead. At the time of mixture. Twenty-four hours after. Three weeks after. No. 4. Lake from Brasil wood with alum de composed by soda. At the time of mixture. Twenty-four hours'after. Three weeks after. No. 5. Red from Brasil wood and alum mixed with earth of Morat. At the time of mixture, Twenty-four hours after. Three weeks after. Caustic ammonia. Acetic acid, or strong distilled vinegar. Diluted sulphuric acid. Muriatic acid. Carbonate of potash. Brightened. Not dissolved. The same tint, Not dissolved. Bright red. Dissolved. Dark rose co¬ lour. Dis¬ solved. Dark violet colour. Not dissolved. Purple. Purplish red. Beautiful red. Dissolved. Pale red. In a kind of jelly. Purple red. Red of wine lees. Altered, Blood red. In part dissolved, Chesnut. In part dissolved. Dark cinnamon colour. In part dissolved. Brick colour inclining to brown. In part dis Dark reddish brown. In part dissolved. Brighter red. Light brown. Brick red co¬ lour, or light brown. A little altered, In part dis¬ solved. Dark cinna¬ mon colour. In part dis¬ solved. Dark walnut- tree colour. In part dissolved. Dark walnut- tree colour. In part dissolved. The same. In part dissolved Brick red. Not dissolved. Brick red. Dissolved in part. Yellowish brown. Not dissolved. Dark orange. In part dis¬ solved. Brick red, as by ammonia. Light yellow. Red chesnut colour. Not dissolved. Altered. Not dissolved. Pale red. Dis¬ solved in a great part. Green colour, and destroyed. Not dissolved. Brown. In part dissolved. The same. Dissolved. Violet purple. Not dissolved. Dark red. Dis¬ solved in part. Bright scarlet. Not dissolved. Red inclining to purple. Not dissolved. Reddish brown. Not dissolved. Coffee brown. In part dis- Bright rose Reddish brown. Dark violet red. Darker. In part dissolved. Purple red. In part dissolved. Bright rose co¬ lour. Dissolved. Dark brown. In part dis¬ solved. Dark reddish brown. Not dissolved. Violet purple. Not dissolved. Purple red. Not dissolved. Scarlet red, a little dull. Dissolved in part. Red inclining rose colour. Not dissolved; Dark violet Not dissolved. Violet inclining to brown. Poppy colour. Purple. Rose inclining to poppy co lour. ^Common violet. Green colour, destroyed. Not dissolved. Reddish brown. In part dissolved. Reddish brown. In part dissolved. Walnut-tree colour. In part dissolved. Destroyed. Not dissolved. Comparative results of the mixture of the same re-agents with the same lakes exposed to the air and the sun, observed at the end of a month. No. 1. No. 2. No. No. 4. No. 5. Caustic ammonia. Acetic acid, or strong vinegar. Diluted sulphurous acid. Muriatic acid. Dry lake. Colour preserved below, and a little less bright above. Dry, and of a rose colour. Aluminous crystals of a pale rose colour. A kind of transparent saline jelly of a beau¬ tiful purple colour. Dry. Brick colour below, and a little pale above. Dry. Of a reddish brown colour. Precipitate of a light rust colour. Kind of jelly of a capuchin colour. Dry lake of a dark brick red colour, a little pale at the surface. Dry. Of a pale brick colour. Dry lake, and of a brown colour. Pulverulent lake of a dark mordorS co¬ lour. Dry lake, with a surface like talc : a little pale above, colour preserved below. Dry. Purple red colour. Precipitate of a bright brick red colour. Dry lake of a flesh colour. Dry lake colour preserved, with some white specks above. Dry. Purple colour inclining to brown. Dark red, of the consistence of thick soup. Precipitate of a dark red colour. To face page 124 . 1 L H 2 ) Ztr ?i'vki^, . £ tA^ /ft-* 2, OBSERVATIONS ON LAKES. 125 in madder red, which acids speedily destroy. They change this colour to that of rust, which is more or less dark, according to the time it has been exposed to the acid and to the influence of the light. These results seem to confirm the great similarity between the colouring part extracted from Brasil wood and that of cochineal; since acids contribute to their development in the same tone of colour, though with modifications which may readily be observed. Every one of the substances here mentioned becomes then, in the hands of an intelligent painter or amateur, the certain means of enabling him to ascertain the nature of lakes. The effects arising from the applica¬ tion of acids are not sufficiently distinct at the moment of their mixture, though they possess shades which do not escape the notice of an expert eye; but an interval of forty-eight hours will be sufficient to render their difference very sensible to persons in the least accus¬ tomed to the effect of such mixtures. The sulphuric acid employed was a mixture of the sulphuric acid of the shops and water, in the proportion of one to four. The muriatic acid was applied in the state in which it is sold. If the results be accurately compared, it will be ob¬ served that they vary in the mixtures according as they are exposed in open vessels, or in vessels closely shut. In the first case, the evaporation of the liquid may serve to account for the little influence of the re-agent. Caustic ammonia on such occasions produces no effect, in consequence of its great volatility. The muriatic acid participates in the same inconvenience. A view G 3 1 26 TURMERIC ROOT. of the two comparative tables will be sufficient to give weight to the present observation, and to determine as to the preference which ought to be given in the em¬ ployment of these mixtures to vessels which can be closed with corks. The effects may then be observed with more certainty, and to a greater extent. Some of the re-agents seize on the base of the lake, and dissolve it. This effect may furnish a new subject of observation, when it is required to discover the nature of that base which may be composed of alu¬ mina, resulting from the decomposition of alum or pure clay; or, in the last place, of chalk. This solution, then, is better perceived in vessels which prevent the evaporation of the liquid than in those which afford a free access to the exterior air. We have exhibited these particular cases in the comparisons which constitute the first comparative table by the expressions dissolved , dissolved in part , or not dissolved. In all cases the influence of light is not to be overlooked. Turmeric Root Is brought both from the East and West Indies; it produces a bright yellow colour, but as a yellow it is extremely fugacious ; treated as a lake it has more pre¬ tensions to permanence in the following preparation. The alkalies and alkaline earths change the yellow of turmeric to a brick red; hence to the chemist it is an excellent test of the presence of these substances either in spirituous or aqueous infusions. Turmeric root was formerly called terra merita. ORANGE LAKE.-GREEN LAKES.-INDIGO. 127 Orange Lake May be made from a tincture of turmeric root in spirit of wine, the colouring matter in which may be precipitated with oxide of tin, and afterwards brightened with a solution of that metal in some of the more power¬ ful acids, namely, the nitric or muriatic. Green Lakes. By pressing, and then washing in water, the sub¬ stance of many green leaves of plants, and afterwards treating it with alcohol, a matter is obtained by eva¬ poration, and purified by rewashing in hot water, of a deep green colour; it dissolves entirely in alcohol, ether, oils, and alkalies; and is not altered by expo¬ sure to air. If an earthy or metallic salt be mixed with the alco¬ holic solution, and then an alkali or a subcarbonate be added, the oxide or earth is thrown down in combina¬ tion with the green matter, forming a cake, the colour of which is moderately permanent in air. Cabbage leaves afford an abundance of such green matter, on digesting which in hot alcohol for a few hours, the whole of the colouring matter from them is dissolved, the leaves becoming crisp and white. Such lakes may be, no doubt, turned to some account by the ingenious painter.—See Branded Journal , vol. vi. p. 36. Indigo . The East and West Indies, as well as many parts of America, produce a plant called by the Spaniards anil; G 4 128 INDIGO. by naturalists its generic name is indigofer a*. When it has arrived at a certain height, and its leaves are in good condition, they are cut down and thrown into a vat, and covered with water, in which they remain till a con¬ siderable fermentation ensues, and the water acquires a violet colour. The water is then drawn off into another vessel, where it is agitated till it becomes frothy all over the surface, and every part intimately blended. The matter is then left to subside; after which the water is poured off, and the blue feculence at the bottom is dried in the pieces we find it. There are several kinds of indigo ; the Flora or Gua- timala , a South American product; the East India and Carolina indigo, all of which are subdivided in com¬ merce into various names and qualities. Good indigo is known by its exhibiting when cut with a knife, or scratched with the nail, a copper-like appearance. Flora indigo, which floats in water, is always con¬ sidered the best; all other indigoes sink in that fluid. Indigo can be applied only to painting in distemper with or without varnish. It is not proper for oil paint¬ ing, because the oil renders it black or green, and it loses in drying a part of the vigour of its tone. In general indigo is not employed: in painting pure; it is always mixed with white: if pure it would become black. White lead, indigo, and a particle of black, * According to Heyne the indigofera pseudo-tinctoria, cultivated in the East Indies, produces the best indigo ; but others extol the indigofera anil, the ind. argeniea, the ind. disperma, which yields the Guatimala kind, and some the Mexicana. —Ure, Journal of Science, No. XIII. INDIGO. 129 in proper proportions, give a beautiful pearl grey. In distemper indigo is employed for painting the sky, sea, and all the distant parts of the landscape. The use of indigo is not confined to painting in dis¬ temper. When subjected to certain chemical processes, it may be applied to miniature painting. Dissolved in sulphuric acid, and diluted with water, it gives to woollen and silk a durable and beautiful blue, varying in intensity by the quantity of indigo employed. This blue of indigo, and the yellow of indigo produced by nitric acid when mixed in certain proportions, give a beautiful and solid green, which may be employed in that kind of miniature painting which serves to ornament silk, fans, &c. These three colours, when intended for paper grounds, must be weakened with water. The mucilage proper for the latter kind of painting ought to be made not of gum arabic, but of gum tragucanth, which has more body. Besides the uses and preparations of indigo as above described, it should be noted that indigo is employed largely in domestic economy, and in coarse water¬ colours, when ground with different quantities of starch , for imparting various shades of blue. These prepara¬ tions of indigo are well known in commerce ; they are made up in small circular cakes, or in small lumps, and are designated by various names, such as Jig-blue , queen’’s-blue , &c. &c. Sometimes, indeed, instead of indigo in these mix¬ tures, Prussian blue is used ; but it is very inferior as a G 5 130 INDIGO. colouring material, and is, therefore, considered an adulteration. The chief use of jig-blue , &c. in domestic economy, is for giving to linen a blueish tinge. By mixing any of these blues with a yellow, a coarse green of various shades is readily made. For much curious information concerning indigo, the reader may consult the second volume of Bertho- let’s Dyeing , edited by Dr. Ure ; and also a paper in the Annals of Philosophy by Mr. Walter Crum; this last being, according to Dr. Ure, the most ela¬ borate and accurate analysis of indigo ever yet given. Whether a substance which Mr. Crum obtained from indigo, of a purple colour, and which he calls phenicin , may be useful as a pigment, yet remains to be seen. In all the analyses of indigo, the chief of its con¬ stituents appears to be carbon; that is, pure charcoal. Since the preceding observations on indigo were written, a paper by Dr. Ure has been published in the Journal of Science , No. XIII. p. 160, which the painter should consult. By it we learn, that although Flora indigo has been hitherto considered the best, some East Indian indigo is superior to that, and obtains a better price. From the analysis of this ingenious che¬ mist we find, that wdiile Caracca Flora indigo contains only 54J per cent, of real indigo, some of the East In¬ dian kind contains 75 per cent, and was sold at the last October sale at 7s. per pound. We may add also that another paper in No. XII. of the same Journal, on in¬ digo, deserves notice; by it we learn, that sometimes BLACKS.—LAMP BLACK. 131 in the manufacture of indigo, lime, or some of the al¬ kalies, is used, and in consequence indigo thus becomes adulterated. By the analysis there given, Calcutta in¬ digo contains 79.5 per cent, of pure indigo. Blacks . As has been before observed, some blacks of an in¬ different colour are obtained from earths and the mi¬ neral kingdom; but the best blacks, as pigments, are obtained either from animal or vegetable matters. The black obtained from galls, and other substances which contain the gallic acid and tannin, known so universally as ink , needs scarcely to be mentioned. A few blacks can be- obtained from vegetables without any prepa¬ ration, such as the juice of the cashew nut , anacardium occidentale; the toxicodendron yields also a juice which produces nearly the same effect; the cuttle-fish emits a black liquor, which might possibly be a perma¬ nent colour. But all these are necessarily difficult to be obtained; the painter is therefore obliged to have re¬ course to art for all such pigments, the basis of which, in all vegetable as well as animal matter, appears to be carbon , or pure charcoal. Lamp Black.—Soot from the decomposition of resins and oils by fire. Lamp black is produced from the thick smoke ex¬ haled by oleous and resinous bodies in a state of com¬ bustion. It is prepared in the large way from the combustion of common turpentine, or the refuse arising G 6 1 32 GENUINE LAMP BLACK. from its purification, or from yellow or black resins. But, nevertheless, the finest lamp black can be ob¬ tained from the decomposition of oil in lamps, whence it was originally procured, and whence its name. It is attended with the inconvenience of becoming red, and not, therefore, employed in delicate colours. Its chief use is in oil colours applied to the coarser kinds of painting. It may be employed, however, in the more delicate kinds of painting, if washed to separate the foreign matters from it, and then reduced to the state of pure charcoal by being made red hot in a close vessel, leav¬ ing only a small aperture for the escape of the oleous matters thus volatilized. It might seem that the same black substance would answer in all cases as a pigment; but it is well known that a black which produces an admirable effect in a fine composition, produces an inferior effect in a com¬ position of another kind. Hence the distinction and uses of several blacks; as smoke black , black from beech wood , from peach stones , from ivory , from bones , blue black , &c. Genuine Lamp Black. A beautiful black may be thus easily procured: sus¬ pend over a lamp a funnel of tin-plate, having above it a pipe to convey the smoke which escapes from the apartment from the lamp. A very black and exceed¬ ingly light carbonaceous matter will be formed at the summit of the cone, in a state of finer powder than can BEECH BLACK.—FRANKFORT BLACK. 133 be given to any other matter by grinding. This black goes a great way in every kind of painting. It may be rendered more pure by calcination, as stated above. The funnel ought to be united to the pipe, which conveys off the smoke, by means of wire, because solder w^ould be melted by the flame of the lamp. It seems almost superfluous to add, that the smoke from the combustion of innumerable vegetable sub¬ stances, when thus collected, affords blacks of different degrees of fineness. An American gentleman, in the Journal of Arts, vol. xii. p. 371, recommends the black obtained from the burning of camphor, which mixed with gum arabic is far superior, he says, to Indian ink. Beech Black.—Beech Charcoal. Beech, like every other kind of wood, furnishes by combustion a charcoal, which, when well ground and mixed with white lead, gives a blueish grey colour. When applied in distemper or in oil painting it will be proper to reduce it to an impalpable powder, free from those small brilliant specks contained in charcoal badly ground. This may be easily accomplished by grinding it with water, and re-grinding it after it has been dried. Black from Wine Lees.—Frankfort Black . Black from the calcination of wine lees and tartar, sometimes with the addition of ivory or stones of peaches and other fruit, is manufactured on a large scale in some districts of Germany; at Frankfort on 134 BLACK FROM PEACH STONES AND VINE TWIGS. the Maine, whence its name, in the environs of Mentz, and in France, by subjecting the materials to heat, in large cylindric vessels, or in pots, having an aper¬ ture in the cover to afford a passage to the smoke, and to the vapours which escape during the process. When no more smoke is observed the operation is finished. The residuum, a mixture of salts and of finely divided carbonaceous matter, is then washed several times in boiling water, and afterwards reduced to the proper degree of fineness by grinding. If this black be extracted from dry lees, it is coarser than that obtained from tartar; because the lees contain earthy matters which are mixed with the carbonace¬ ous part. This black goes a great way, and has a velvety appear¬ ance. It is the chief ingredient in copper-plate print¬ ers’ ink. The best is said to be made at Frankfort , whence its name. Black from Peach Stones. Peach stones, burnt in a close vessel, produce a char¬ coal, which, when ground, is employed in painting to give an old grey. Black from Vine Twigs. Vine twigs reduced to charcoal give a blueish black, which goes a great way. When mixed with white it produces a silver white, which is not produced by other blacks : it has a pretty near resemblance to the black of peach stones; but to bring this colour to the IVORY BLACK.—INDIAN INK. 135 utmost degree of perfection, it must be carefully- ground. Ivory Black.—Bone Black . Put into a crucible, surrounded by burning coals, fragments or turnings of ivory, or of the bony parts of animals, and cover it closely. The ivory or bones by exposure to the heat will be reduced to charcoal. When no more smoke is seen to pass through the joining of the cover, leave the crucible over the fire for half an hour longer, or until it has completely cooled. There will then be found in it a hard carbonaceous matter, which, when pounded and ground with water, is washed on a filter with warm water, and then dried. Before it is used it must be again subjected to the muller. Black furnished by bones is reddish. That produced by ivory is more beautiful. It is brighter than black obtained from peach stones. When mixed in a proper proportion with white lead, it forms a beautiful pearl grey. Ivory black is richer. The Cologne and Cassel black are prepared from ivory. Ivory black is prepared in the large way in this country from bones; it is ge¬ nerally a very indifferent black, abounding in impu¬ rities, and suited only to the coarser kinds of painting. The artist who desires a delicate ivory black should prepare it himself, as above directed. Indian Ink Is brought from China in small black pieces, having^ figures impressed upon them. It is extensively used as a dark shading in water-colours. The actual com- 8 136 BISTRE. position of this ink is not known; but Dr. Ure states, that fine soot from the flame of a lamp or candle, re¬ ceived by holding a plate over it, and mixed with clean size, made with shreds of parchment, or glove-leather, not dyed, will make an Indian ink equal to that which is imported. When made in this country, it is usually mixed with a little musk, to give it the smell of the foreign article. Bistre. Bistre is obtained from wood-soot, thus: take any quantity of the soot of dry-wood, that of beech is the best; put it into water, in the proportion of two pounds to a gallon; boil them half an hour; when the liquor has stood to settle, pour off the clear part from the sediment, and if another sediment forms, repeat the process; but it must all be done before the liquor has time to cool. Evaporate to dryness, and good bistre will be the result. The test of its goodness is, a warm deep-brown colour, and its transparency when moist¬ ened with water. Bistre has much the same effect in water-painting, as brown pink has in oil; it is, of course, used by painters to wash over their designs. Bistre dissolved in an alkaline solution, by boiling, will make a brown indelible ink. Another kind of bistre is made from the most glossy and perfectly burnt soot, reduced to a very fine powder, then baked with a little gum-water, and formed into cakes. This is a useful and permanent brown colour. LITMUS-ARCHIL. 137 Litmus. — Archil. The Canary and Cape de Verd islands produce a kind of lichen or moss, which yields a violet colour when exposed to the contact of ammonia, disengaged from urine, in a state of putrefaction, by a mixture of lime. When the usual processes are finished, it is known by the name of litmus. In the nomenclature of the dyer, however, this article is known under different names; in the process of making it, after a few days, it acquires a purplish red colour, when it is called archil; it at length becomes blue, when it is called litmus. Cudbear is also a preparation from the same lichen. Litmus is prepared on a large scale at London, Paris, and Lyons. In the last-mentioned city another kind of lichen, which grows on the rocks like moss, is em¬ ployed. This lichen is very abundant in Auvergne. The litmus resulting from it is inferior to that of the Canaries. The ammonia, disengaged by means of lime from urine in a state of putrefaction, unites with the resinous part of the plant, developes its colouring part, and com¬ bines with it. In this state the lichen forms a paste of a violet-red colour, interspersed with whitish spots, which give it a marbled appearance. Litmus is employed in dyeing, to communicate a violet colour to silk and woollen. It is used also for colouring the liquor of thermometers. The vamisher prepares his violet and lilac varnishes with it; but the colour is not durable. 138 ANNATTO. Annatto , Annotto, or Roucou. Annatto is formed from the pellicles or pulp en¬ veloping the seeds of the bixa orellana , a liliaceous shrub, rising from 15 to 20 feet high, a native of South • America. It is reduced by evaporation to a sort of extract, and dried slowly, being spread out on boards. Annatto is found in commerce under three dif¬ ferent forms. The best is in rolls, about four or five inches long, and somewhat less than an inch in diame¬ ter ; it is called Spanish Annatto , and is thus imported. It is also imported, enveloped in flags, of a soft, clayey consistence, hence called Flag Annatto. Another kind is found in the shops in cakes, weighing about four ounces each; this is prepared in England, and sold chiefly to the farmers for colouring cheese; it is a farrago of colouring ingredients, of which Annatto is only a part. Annatto, when genuine, is of a dull reddish colour. It is difficultly acted upon by water; but it readily dis¬ solves in rectified spirit of wine, to which it communi¬ cates a high orange, or yellowish-red. Hence it is used as an ingredient in varnishes, for imparting more or less of an orange cast to the simple yellows. The alka¬ line salts render it perfectly soluble in boiling water, without altering its colour; hence its use in dyeing. What is called Nankin Dye appears to be nothing more than annatto dissolved with an alkaline salt in water. The natives of the West India Islands used formerly to employ annatto for painting their bodies, &c. It is chiefly used in Europe for imparting the first tint to SAFFLOWER. 139 woollen stuffs intended to be dyed red, blue, yellow, and green, &c. It forms also part of the composition of changing varnishes, to give a gold colour to the metals to which these varnishes are applied. Safflower , Bastard-Saffron , or Cartliamus. Safflower is the flower obtained from one or two plants of the cartliamus genus, natives of the south of Europe, and the Mediterranean coasts. It is of a dark- red saffron colour; and is chiefly used in dyeing. It consists of two colouring materials: one soluble in water, and which is thrown away; the other soluble in alkaline liquors. The latter colouring part is used by the dyers, for various beautiful shades of cherry-colour, poppy, rose-colour, &c. It is also employed for dyeing feathers ; and it constitutes the Rouge , or Spanish vermilion , employed by the ladies to heighten their complexion. It is also used by varnishers in some of their compositions; but the colour is not durable. Bastard-saffron does not furnish its resinous colouring part in perfection, until it has been deprived of that which is soluble in water. For this purpose it is en¬ closed in a linen bag, and the bag is placed in a stream of running water. A man with wooden shoes gets upon the bag every eight or ten hours, and treads it on the bank until the water expressed from it is colourless. The flowers, after they have been strongly squeezed in the bag, are spread out on a piece of canvass, ex¬ tended on a frame, and placed over a wooden box, and 140 ROUGE. covered with five or six per cent, of their weight of carbonate of soda. Pure water is then poured over them; and this process is repeated several times, in order that the alkali may dissolve the colouring part. The liquor, when filtered, is of a dirty reddish-brown colour. The colouring part, whilst held in solution by an alkaline liquor, cannot be employed for colouring bodies; the soda must be combined with an acid which has more affinity for it than it has for the colouring part. The precipitated colouring matter is used for making Rouge , or Spanish vermilion, and in dyeing. When carthamus is employed for a saffron-colour, it does not appear that any use is made of the colouring part which is insoluble in water: painters seek after that only which the dyers reject. It is not improbable that a much better effect would be produced by em¬ ploying the washed carthamus alone, and forming it into a soft paste, by mixing it with the liquor contain¬ ing the colouring part, which might be afterwards pre¬ cipitated with a diluted acid. Rouge , Spanish Vermilion , or China Lake. Pour into the alkaline liquor which holds in solution the colouring part of bastard-saffron, such a quantity of lemon-juice, previously depurated by standing, as may be necessary to saturate the whole alkaline salt. At the time of the precipitation, the latter appears un¬ der the form of a fecula, full of threads, which soon falls to the bottom of the vessel. Mix this feculent part with white talc (chalk of Briangon), reduced to fine powder, and moistened with a little lemon juice RED SAUNDERS. 141 and water. Then form the whole into a paste; and having put it in small pots, expose it to dry. This colour is reserved for the use of the toilet; but it has not the durability of that prepared from cochineal. Other forms have been given for producing this pig¬ ment : it is sometimes mixed with French chalk. The fineness of the powder and proportion of the precipi¬ tate constitute the difference between the finer and cheaper rouge. When it is to be used for house-painting, &c. as for the red inclining to yellow applied to different articles, the liquor charged with the colouring part, precipitated by acid of lemon juice, is formed into a paste with white argillaceous or marly earth, which is divided into small cakes, and then dried. Red Saunders , or Red Sandal Wood. Red Saunders is the wood of the pterocarpus santa - linus , a lofty tree, a native of the mountains of India, particularly the Onore district, and of Ceylon. Red Saunders is brought home in billets, which are very heavy and sink in water. It has an aromatic odour, is extremely hard, of a fine grain, and a bright garnet red colour, which deepens on exposure to air. It yields its colouring matter to ether, to rectified spirits of wine, and to proof spirit, but not to water. This property of yielding no colour to water affords an easy mode of dis¬ tinguishing red saunders from Brasil wood. It also communicates its colour to volatile oil of lavender, but not to oil of turpentine. In consequence of its colour- 142 ALKANET ROOT.-PURPLE LAKE. ing matter dissolving in spirit of wine, it may be em¬ ployed in colouring varnishes. Alkanet Root. Alkanet root is the product of the anchusa tinc- toria , a perennial plant, native of the south of Europe, where it is cultivated in great abundance, particu¬ larly near Montpellier. It is found in our gardens, but its roots do not here acquire the beautiful co¬ lour for which the foreign are esteemed. They are brought to this country chiefly from France; they are in twisted pieces, which have a withered dusky red, easily separated bark, in which the colouring matter chiefly resides ; the smaller roots are therefore the best, as they have proportionally more bark than the larger. Alkanet root imparts a fine deep red colour to alco¬ hol, ether, oils, fats, and wax; but to water, even hot, only a brown colour. Its chief use, therefore, by paint¬ ers, is in imparting to oils a red colour more or less deep, to obtain which of the deepest hue the application of heat is necessary. Sulphate of iron strikes a black with the watery infu¬ sion of this root, and sulphate of zinc throws down a copious dark-coloured precipitate. A Purple Lake May be also obtained from alkanet root thus: take two ounces of the root finely powdered, and boil a few minutes in a lixivium made of sub-carbonate of potash sufficiently diluted; and after the liquor has grown SAP GREEN. 143 cold, precipitate the colouring matter with a strong solution of roche alum. The precipitate must be dried without being washed for use. This has been recommended for the formation of a purple lacker; but we presume it will be also found useful as a pigment. Sap Green Is made from the juice of buckthorn, being the rhamnus catharticus, an indigenous shrub, or rather tree, growing in woods, hedges, and near brooks. Buck¬ thorn berries, when ripe, are black, and somewhat smaller than black currants. They are said to be sometimes mixed with those of the black-berried alder and of the dog-berry tree; but as the buckthorn berry has four seeds, while the others bear only two and one, it may be easily distinguished. To make sap green, the juice of the berries, which are to be kept until they are perfectly ripe and well bruised, is obtained from them, being placed in hair bags and submitted to the action of a powerful press. The juice is then mixed with a little alum, dissolved in a sufficient quantity of water, and the whole evaporated over a slow fire till it is brought to the consistence of honey. The extract is then hung up in a stove or other warm place to dry. Some add, besides alum, a portion of gum arabic. When sap green is to be used, dilute it with a little water, to which it will communicate a beautiful sea- green colour. It is used in many kinds of water- 144 GAMBOGE. colours, but chiefly in fan-painting, by draughtsmen who draw plans, and other work of the same kind. It ought to be chosen compact, heavy, and of a beauti¬ ful dark green colour. We ought also to observe, when treating of the juice of buckthorn, that from the juice of the unripe berries of this plant, with the addition of alum, a yellow colour is obtained; and that the French miniature painters obtain from buckthorn berries a delicate and highly prized green, which they call verdevissa. Gamboge. Gamboge is a gum resin obtained from the stalag- matis cambogiodes or gamboge tree, a native of Siam and Ceylon. It is brought to this country in rolls or lumps of different sizes. When broken it is of an orange colour, but when moistened with water it yields a very brilliant yellow colour. A greater quantity of it is, however, dissolved by spirit of wine than by water; hence it is a very useful ingredient in many varnishes. As it imparts a beautiful yellow colour to water, it is exceedingly proper for water colours; in this respect it is used both for washing and for miniatures; indeed gamboge is used as a water colour pigment on so many occasions, that we cannot enumerate them. Gamboge is not liable to vary much in its qualities; it should be, however, smooth in its fracture, and of an orange yellow without impurities. It may be observed that it is a violent purgative, and should not be ad¬ mitted into the mouth or stomach. PINKS.-DUTCH PINKS. 145 Various Pinks. Dutch Pink. Dutch pink is a bright yellow pigment, much used in house-painting, &c., as well as in painting in dis¬ temper and in oil. It is seldom employed by artists who paint pictures, because they prefer the yellows obtained from metallic substances, which are more durable. Dutch pink consists of earthy parts combined with the colouring matter of certain plants. The basis of the best is clay. Sometimes the base is a mixture of clay and chalk, and in certain cases it is carbonate of lime (chalk) only. The last mentioned composition of Dutch pink is inferior to the other two. It is much better suited to painting in distemper than to oil painting. Dutch Pink from Woad. Woad, the isatis tinctoria , is a plant now cultivated extensively for the purposes of the dyer, not only in this country, but in France and other parts of Europe. When cultivated it is superior for dyeing to the uncul¬ tivated kind. The use of its colouring matter is not confined to dyeing, it is extended also to painting, under the denomination of Dutch pink. To make Dutch pink, boil the stems of woad in a solution of alum, and then mix the liquor with clay, marl, or chalk, which will become mixed with the colour of the decoction. WTien the earthy matter has H 146 DUTCH PINKS. acquired consistence by evaporation, form it into small cakes, or pass the coloured mass when in a semi-fluid state through a funnel upon dry chalk, when the water will be absorbed by the chalk and leave the pink in the shape of large drops, which are afterwards to be dried. Another Dutch Pink Is made with an aluminous decoction of woad and with chalk. But the use of chalk renders this pink in¬ ferior to the preceding. These compositions would perhaps acquire some additional qualities were the clay, marl, or chalk mixed with a second, or even a third, decoction of the plant. Another Dutch Pink from French Berries. The small or narrow-leaved buckthorn, rhamnus in - fectorius , an evergreen plant, indigenous to the south of Europe, produces berries which, when collected green, are called graine d' Avignon, or yellow berries, in this country French berries. These seeds, when boiled in a solution of alum, form a Dutch pink supe¬ rior to the former. A certain quantity of clay or marl is mixed with the decoction, by which means the colouring part of the berries unites with the earthy matter, and communicates to it a beautiful yellow colour. The colouring part of Dutch pinks is darker accord¬ ing as the earthy substance employed is less mixed with any of the carbonates of lime. Clay or earth of glum contributes to the durability of the colour; a DUTCH PINKS. 147 Butch pink, therefore, resulting from the decomposition of sulphate of alumina might be substituted for the mixtures here described. Brownish Yellow Dutch Pink by the decomposition of alum. Boil a pound of French berries, half a pound of the shavings of the wood of the barberry shrub, and a pound of wood ashes, for about an hour in twelve pounds of water. Then strain the decoction through a piece of linen cloth. Pour gradually into this mixture, whilst warm, a so¬ lution of two pounds of alum in five pounds of water : a slight effervescence will take place; and the alum being decomposed, the alumine which is precipitated, will combine with the colouring part. The liquor must then be filtered through a piece of fine linen, and the paste which remains on the cloth, when divided into square pieces, is to be exposed on boards to dry. This Dutch pink is brown, because the alumine in it is pure ; the intensity of the colour shows the quality of this pink, which is superior to that of the other compositions. Dutch Pink with Spanish White , and White Lead, preferable for Oil Painting. By using Spanish white and white lead, the result will be a Dutch pink, superior to any of the preceding. Boil a pound of French berries and three ounces of alum, in twelve pounds of water, to four pounds. Strain the decoction through a piece of linen, and squeeze it H 2 148 DUTCH PINK WITH SPANISH WHITE. strongly. Then mix it with two pounds of white lead, ground with water and dried, and a pound of pulverized Spanish white. Evaporate the mixture till the mass acquire the consistence of a paste ; and having formed it into small cakes, dry them in the shade. When these cakes are dry, reduce them to powder, and mix them with a decoction of yellow berries. By repeating this process a third time, you will obtain a Dutch pink containing so much colouring matter that it will be brown. In general, the decoctions must be warm when they are mixed with the earth. They ought not to be long kept, as their colour is speedily altered by the fermenta¬ tion. Care must be taken also to use a wooden spa¬ tula for stirring the mixture, Dutch pink is employed in distemper and in oil; it is said, and with some foundation, not to be durable, especially when the earthy part contains much chalk. Those, therefore, who wish to select the best must pre¬ fer that which produces the least effervescence with acids : many samples of English manufacture occasion very little effervescence. When only one decoction of woad or of French ber¬ ries is employed, the Dutch pink is of a bright-yellow colour, and is easily mixed for use. When the colour¬ ing part of several decoctions is absorbed, the compo¬ sition becomes brown, and is mixed with more diffi¬ culty, especially if the paste be argillaceous : for it is the property of this earth to unite with oily and resin¬ ous parts, to adhere strongly to them, and to incorpo¬ rate with them. In the latter case, the artist must not ENGLISH PINK.—ROSE PINK. 149 be satisfied with mixing the colour: it ought to be ground; an operation which is equally proper for every kind of Dutch pink, even the softest, when intended for oil painting. English Pink Appears to be nothing more than an inferior Dutch pink ; its colour is less brilliant, and it is therefore used for more common purposes than Dutch pink. Rose Pink Is a very delicate colour, inclining more to purple than scarlet. It is prepared from chalk coloured with a decoction of Brasil wood, with the addition of an alka¬ line salt. It is a very fugacious colour and of little value. It loses its colour, in a great measure, if even suffered to become dry; it is therefore the practice of the colourmen to keep it in a damp, dark cellar, excluded from both light and air. H 3 CHAPTER IV. On the Vehicles used for the colours of paints, as well as on certain Gums, Glue, Driers, and Putty ; and on the preservation and repairing of paintings. Water. It may seem superfluous to mention water as one of the vehicles for paints; but as this useful and necessary fluid is used in making gum-water paints,many coloured washes, and in mixing distemper colours, a few obser¬ vations on it may be useful. The preparer of colours should have constantly before him this truth, that all water obtained from the earth, whether from springs or from other sources, contains always more or less extraneous matter, and will very often affect the colours of paints, by im¬ proving them in some instances, by deteriorating them in others; and, therefore, where a colour or mixture of colours of a specific hue is desired to be produced, the purest water should always be procured. Spring water, in consequence of its sparkling brilliancy, is as a bever¬ age generally preferred ; but such water is almost always hard, i. e. it contains a large quantity of calcar¬ eous or other matter, which, on the application of soap, separates in the form of a curdy white precipitate : as it is not easy to tell, by mere inspection, to what mineral WATER—GUM-WATER—GUM ARABIC. 151 or earth the hardness of water is owing, the safest course will be to avoid the use of it in painting. The purest water is no doubt that which is distilled in glass vessels; for copper vessels, notwithstanding all our care, impart to water a portion, however slight, of the copper of which they are composed. In the absence of distilled water, rain water caught from the roof of a house covered with tiles, if in the country, is most probably the best succedaneum for distilled water, and such the painter should aim always to obtain. Next to this, water from a clear rivulet in perpetual motion is the best: yet even such often contains calcareous and other earthy matters : for although filtering stones arrest the grosser impurities of water, they do not those which are combined with it in a more intimate man¬ ner ; such is carbonate of lime, which passes the filter as readily with water as pure water alone. Gum-water Is made by dissolving gum arable , or gum tragacanth , in water; it is employed in painting various ways; sometimes as a vehicle for the colours themselves, and sometimes as a vamisli for coating the colours which have been previously painted. Gum-Arabic dissolves wholly in water ; it appears to be a pure mucilage. It is the produce of the acacia vera , a tree growing in various parts of Africa; the best, the whitest, hardest, and in the smallest tears, is brought from many of the African ports which border the Mediterranean. An inferior kind called gum Sene¬ gal, in red and larger drops, is brought from South- H 4 152 GUM TRAGACANTH—SIZE. west Africa; the mucilage from this last has not the same softness as that from gum-arabic; in all cases of painting the white gum is to be preferred. Gum Tragacanth, or Gum Dr agon, is the produce of a shrub, the astragalus verus , a native of the north of Persia, whence the gum is brought to this country by way of Aleppo. It is in thin and wrinkled worm-like pieces, of a whitish semi-transparent colour, and a slightly bitter taste, yet inodorous. It swells and softens in water, hut does not form a homogeneous fluid mucilage, unless triturated after digestion with a large portion of water. In choosing this gum for painting, that which is yellow, black, or mixed with foreign bodies, must be rejected. The thick mucilage produced by this gum, when soaked in water, is some¬ times employed by miniature painters to render the vellum on which they paint as smooth as a plate of iron; this is done by placing it on a piece of fine linen, tying it in a knot, and rubbing it over the vellum. In painting in distemper a solution of gum tragacanth is substituted for solution of gum-arabic in mixing up colours of a saline nature. The chief difference between this gum and gum- arabic appears to be that, when dry, it is less liable to crack than gum-arabic. Size Is gelatin dissolved in a greater or less quantity of water. Gelatin is obtained from various animal sub¬ stances ; from the skins of animals, from the mem¬ branes, and many other parts of fishes, &c. &c. Hence ISINGLASS—GLUE—SIZE FOR KNOTS. l&J we have gelatin under the name of glue, isinglass, &c. Size is used for distemper and other purposes iii painting. Isinglass, or fish-glue, is prepared from certain parts of the entrails of fishes; the best is obtained from the sturgeon, and is almost exclusively prepared in Rus¬ sia ; but very good gelatin may be obtained from many parts of the cod, particularly the head. The sound or air-bladders of fish generally may be employed in the preparation of isinglass. Isinglass, when pure, ought wholly to dissolve in water. The sounds of fishes are, it is said, merely cleansed, rolled into shapes, and then dried, to constitute isinglass; but the other parts re¬ quire boiling in water till they are dissolved; the liquor is then to be strained, suffered to cool, when the fat or oil is carefully taken off, and the liquor again boiled to a proper consistence, and then cut in pieces, rolled into a semicircular twist, and afterwards dried. Glue is too well known to need description. It is usually obtained by boiling the skins, or cuttings from skins, of various animals in water, and afterwards re¬ ducing the decoction by evaporating the water to a proper consistence. That which is of the palest co¬ lour and the clearest is the best. Size for Knots . It often happens that if deal, in particular, be painted without covering the knots with some impervious size previously to painting it, the terebinthine matter in the knot will ooze through the paint and disfigure it. To prevent this it is usual to cover the knot with a size H 5 154 FIXED OILS. composed of a strong solution of glue in water, mixed with a small portion of red-lead previously to laying on the paint, taking care that the size is completely dry before the process of painting commences. Fixed Oils Are so called in contradistinction to volatile oils, be¬ cause, under ordinary circumstances, they remain in vessels, although exposed to the air, whereas volatile oils have a continual tendency to escape in vapour under similar circumstances. The fixed oils are those most commonly used in painting, although some of the volatile oils, particularly oil of turpentine, are also em¬ ployed as vehicles for pigments. Of fixed oils some are obtained from vegetables and some from animals; those used principally in painting are from vegetables. Some of the animal oils also enter into the composition of coarse paints; but they are not in general good vehicles for colours. The chemical constituents of fixed oils vary; but they generally consist, as stated by chemists, of car¬ bon, hydrogen, and oxygen ; the carbon being by far the largest proportion. Fixed oils have also been separated into two substances, one white, solid, brittle, and tasteless, called stearine ; the other an oily liquid of a yellow colour, which is fluid at common tempera¬ tures, called elaine. The proportion of these in dif¬ ferent oils, both animal and vegetable, varies ; in butter the stearine is 60, the elaine 40; in oil of almonds the stearine is 76, the elaine only 24. When oil of olives is congealed by a moderate degree of cold, these two OIL OF POPPY SEEDS. 155 substances are distinctly visible; the stearine in round lumps, the elaine in a liquid state. Both these sub¬ stances will combine with alkalies and form soap. We consider spermaceti as nearly pure stearine. Oil of White Poppy Seeds. The seeds of the single white poppy , an annual plant, papaver somniferum , a native of Asia, but now T found in most of the southern parts of Europe, and also in this country, yield, by being bruised and pressed, a large quantity of a sweet and unctuous oil, which is much used for delicate processes in painting, it being nearly colourless. It acquires a drying quality by age alone ; but several methods are used to give it this necessary disposition for the painter. Processes for imparting a drying quality to Oil of Poppy Seed . Into three pints of pure water put an ounce of white vitriol in pow T der, and mix the whole with two pints of oil of white poppy seeds. Submit this mixture in a proper vessel to a degree of heat sufficient to keep it in a slight state of ebullition. When one-half or two- thirds of the water have evaporated, pour the whole into a large glass bottle or jar, and leave it at rest till the oil becomes clear; decant the clear oil for use. The oil thus prepared becomes, after some weeks, exceed¬ ingly limpid and colourless. The preceding Is the substance of the methods of imparting a drying quality to poppy oil, given in a former edition of this work. The following, which is H 6 156 NUT OIL. given in the Journal of Arts , Vol. ill. page 138, by Mr. Pack, a practical artist, is, in our judgment, to be preferred. Mr. Pack observes that 44 the oil of white poppy seed is much the best which can be used for pictures ; the Flemish and Dutch schools used no other ; next to this is linseed oil if pure; but if mixed with rape oil, as it sometimes is, it is totally unfit for the artist. Drying oil should always be prepared cold.” Mix one ounce of litharge, finely powdered, with one pint of the oil; shake the mixture very often; in a month it will be clear and thin, which constitute its excellence. Remarks. —Many artists reject every preparation of oil in which water has been employed as an interme¬ diate substance. But it will be nevertheless found occasionally useful, particularly where the artist cannot wait a month for his oil; although even when boiled as above directed, the oil takes some time to become fine and pure. The drying material may, it is true, be boiled with the oil without water; but as the heat ad¬ ministered to the oil will be so much greater, the pro¬ bability is that more or less colour will be added to it, and, consequently, for delicate colours, the oil will be totally unfit. A slight heat accelerates the clarification of oil prepared with water. Nut Oil , Is obtained from the kernels of several kinds of nuts, chiefly from walnuts or hazel-nuts, by contusion and ex- LINSEED OIL—DRYING OIL. 157 pression either with or without heat. That obtainedby heat is the most proper for the painter; but in this country nut oil is not a common vehicle ; and if sold as such> there is much reason to fear that other oils supply its place. It is nevertheless a very useful oil, and when to be obtained, is much to be preferred to linseed oil, A similar oil may also be obtained from beech nuts; another from hempseed. Linseed Oil. The oil obtained from the seed of the linum usitatis- simum , or flax plant, an annual cultivated in almost every part of Europe as well as in this country, is the most common vehicle for the colours of ordinary paint¬ ing. It is abstracted from the seeds by contusion and expression, for medical use without , but for the painter with the aid of considerable heat. Processes for imparting to Fixed Oils a drying Quality. First process. Take of nut or linseed oil eight pints; of white lead slightly calcined, sugar of lead also calcined, and of white vitriol of each one ounce; of litharge twelve ounces. A head of garlic or a small onion. All the preceding ingredients being pulverized, ex¬ cept the garlic or onion, which must be sliced, mix them with the oil, and keep the whole in a slight state of ebullition, till the oil ceases to throw up any scum, 158 SECOND PROCESS FOR DRYING OIL. till it assumes a reddish colour, and till the head of garlic becomes brown. A pellicle will then be soon formed on the oil, which indicates that the operation is completed. Take the vessel from the fire, and the pel¬ licle being precipitated by rest, will carry with it all the unctuous parts. When the oil becomes clear, separate it from the deposit, and put it into wide-mouthed bottles, where it will in time become clear, and im¬ prove in quality. Second Process for drying Oil. Take of linseed or nut oil one pint; of litharge one ounce and a half; of white vitriol half an ounce. The operation must be conducted as in the last pro¬ cess. The choice of the oil is not a matter of indifference. If for painting articles exposed to the air, or for delicate painting, nut or poppy oil will be requisite. For coarse and common painting linseed oil may be used. Negligence in the administration of the heat will often communicate a colour to the oil, in other words will burn it, and thus render it improper for delicate painting. This inconvenience may be, in some degree, avoided, by tying up the drying materials in a bag, which must be suspended by a pack-thread fastened to a stick made to rest on the edge of the vessel, so as to keep the bag at the distance of an inch from the bottom, a pellicle will be formed as in the first opera¬ tion, but it will be slower in making its appearance. In all these processes where preparations of lead are employed, care must be taken not to stir the mixture SECOND PROCESS FOR DRYING OIL. 159 too much, although some stirring is absolutely neces¬ sary ; for sometimes the oil is thus rendered too thick, and assumes the consistence of a jelly. The substance of the two preceding processes was given in the previous editions of this work. We cannot avoid considering the first in particular as con¬ sisting not only of too many ingredients; but that the ingredients themselves are in too large a quantity. We think the twelve ounces of litharge alone amply suf¬ ficient for one gallon of oil, without any one of the other ingredients. The garlic is employed merely to show the period when the whole aqueous portion of the mixture has evaporated. The previous calcination directed for white lead and sugar of lead is a mere precaution in the process : should these matters be employed without calcination, they should be added to the almost boiling oil in small portions at a time. It should be noted, generally, that the process of boiling oil , when no water is present, is one of extreme hazard: for, whereas water boils at the degree of 212° of Fahrenheit’s thermometer, oil on the contrary re¬ quires the extreme heat of about 600 degrees, wdien it becomes volatilized, and by a sudden application of additional heat, may take fire even on the approach of a candle, and explode. The rationale of the process for obtaining drying oil does not appear, even now, to be exactly understood. In the former editions of this work, it would appear that M. Tingry considered that the use of the preparations of lead was “ to free oils from their greasy principles.” 160 RESINOUS DRYING OIL. But we cannot avoid considering that the combination of the oxides of lead, with the oils themselves, imparts to them more consistence, and of course a disposition to harden on exposure to air, as one of the results of the process: see what is said on this subject under a former section on the oxides of lead. Perhaps some of the oxide of lead combines with the elaine of the oil, and sinks to the bottom as feculence; but this will not, in our judgment, explain the whole phenomenon. Drying oil is employed for several purposes; when colourless it is much sought after by those who paint pictures. It enters into the composition of varnish; and serves itself as a varnish in oil-painting, either employed alone, or diluted with a little oil of turpen¬ tine. When used in house-painting, it will be advan¬ tageous to use, for the last coat, the following resinous drying oil , which exhibits all the qualities of a varnish. It is best to be applied to bodies sheltered from the rain and sun, by mixing with it delicate colours; but is well adapted also for strong colours, such as yellow, red, green, and particularly the ochres. Resinous drying Oil. Take ten pints of drying nut oil, if the paint be de¬ signed for external work, or ten pints of drying linseed oil, if for internal work; of yellow resin three pounds ; of common turpentine six ounces. Melt the resin in a gentle heat, to which add gra¬ dually the oil, so as not to coagulate the resin; add lastly the turpentine, applying only so much heat to the whole, as will render it a uniformly transparent varnish. THIRD PROCESS FOR DRYING OIL. 161 Let it remain a short time while hot to deposit a few impurities, and pour it off into wide-mouth bottles. It should be used fresh: when suffered to grow old, it deposits some of its resin. If it becomes too thick it may be diluted with a little oil of turpentine; or with oil of poppy if intended for painting sheltered from the sun. In general every first coating with oil applied to a wall, cieling, &c. ought to be exceedingly warm, to harden the surface which is to receive the painting. Third Process for drying Oil. A drying quality may be communicated to linseed or nut oil by simply keeping it in a state of slight ebul¬ lition by heat, adding to every pint three ounces of litharge reduced to a fine powder. Some painters add of litharge a fourth part of the weight of the oil employed. But this is only necessary for baked oils used in painting, where speedy drying, and the greatest durability are required : floor-cloths, and all paintings of large figures or ornaments, in which the argillaceous colours, such as the yellow and red ochres, Dutch pink, &c. require such strongly desiccative oils. But paints composed of metallic oxides, such as those of lead, copper, &c. will dry with oil, having a much less portion of desiccative ingredients. Nay, both nut oil and linseed oil wholly unprepared, if combined with litharge finely ground in oil, and then mixed with the colouring matter in the proportion to the oil employed, of three or four ounces to the pint, will dry as speedily as if prepared oil had 162 FOURTH AND FIFTH PROCESSES FOR DRYING OIL. been employed. But of course litharge can be only employed with colours which are not altered by it. Fourth Process for drying Oil. Take of nut oil two pints ; of water three pints; of white vitriol two ounces. Mix, and subject them to a slight ebullition till little water remain; decant the oil, w T hich will pass over with a small quantity of water, and separate the latter by means of a funnel; after some time the oil will be¬ come clear and very little coloured. Fifth Process for drying Oil . Take of nut, or linseed oil, six pints ; of water four pints; of white vitriol one ounce; of garlic one head sliced. Keep this mixture in a state of ebullition during the whole of the day: boiling water must from time to time be added to supply the loss of that dissipated by evaporation. The garlic will then assume a brown ap¬ pearance. Remove the oil from the fire, and after the impurities are deposited, decant it; it will become clear in the vessel in which it is kept. By this process the oil is rendered somewhat more coloured: it is used for delicate colours. Remarks —The preceding process requires the ut¬ most attention. If the water mixed with the ingre¬ dients, or that added during the process be too abun¬ dant, and if towards the end of the operation it be not SIXTH PROCESS FOR DRYING OIL. 163 all made to disappear by careful evaporation, it will unite with the oil, and communicate to it the colour and consistence almost of cream: hence, unless well conducted, the process will not succeed : but it affords nevertheless a very simple method of obtaining an oil exceedingly drying, and much less coloured than that subjected to the direct action of fire : it requires, how¬ ever, to b^ kept for some time. House painters are less interested in these processes than portrait or landscape painters, &c., because their colours are, of course, less delicate, whereas the least tint communicated to fine colours visibly alter their tone; hence researches have been made to find out for this particular case processes different from those which we have already described, not excepting even the last. In the preparation of poppy oil it will be seen that water is added, by the evaporation of which the tem¬ perature is kept at a fixed point, and hence the oil undergoes no decomposition. By varying the process it may be rendered the sole cause of the drying quality of the oil: it is on this principle the following process is founded: Sixth Process for drying Oil. Take, in the winter season, of linseed, nut, or poppy oil, any quantity, and mix it with dry snow, kneading the mixture in a bason with a wooden spatula, or in a mortar with a pestle. Form it into a solid mass, and place it in a vessel with a large aperture, which should be covered with a cloth to prevent the introduction of 164 MODIFICATION OF THE LAST PROCESS. foreign bodies. Expose the vessel in a place accessi¬ ble to cold, but sheltered from the influence of the solar rays. On the return of a milder temperature, the snow will become water, and separate from the oil, with the impurities of which the water will be charged. If a severe temperature continue two months, the oil will acquire a high degree of drying quality. A part of the oil retains then a little water, and it forms^a pellicle which, in colour and consistence, resembles Painter's Cream ; for which composition see the next page. The oil is either to be decanted from off the water, or taken off with a spoon. Rest will be sufficient to clarify it; or, to accelerate the separation of the ad¬ hering particles of water, the oil may be exposed to the heat of a water bath. Modification of the last process. If an oil, already rendered drying by one of the pre¬ ceding operations, be used in this process, with as few reacting ingredients and as little heat as possible, it becomes drying in an eminent degree. Such oil is very thick, and a part of it is so mixed with water, that the result is a glutinous and almost resinous matter, which adheres so much to the inter¬ posed liquid, that it retains that form whatever process be employed to break the union of the water and the oil On Oil of Hempseed being treated with snow, as above directed, the separation of two distinct oils has been observed; one heavier than water fell to the bot¬ tom of the vessel, while the other occupied the upper painters’ cream. 165 portion of it, and the whole of the liquid obtained from the melting of the snow formed a stratum between the two oils. The heaviest oil was very little coloured ; it was less so than the lighter oil, or even than the oil of hempseed itself before its admixture with the snow. The first stratum of oil formed two zones, the upper one being clear, the lower opake and of a chamois colour. The lighter stratum above the water was exceedingly thick, and as if resinified. The stratum of water, &c. was cloudy. Is not the separation of the oil of hempseed into two portions of different specific gravity, merely the sepa¬ ration of the stearmc and elaine of the oil ? Is not the highly drying quality of oil thus treated with snow, produced in some way by impregnating the oil with a quantity of oxygen ? and does water in the state of snow become more readily decomposed than when in a liquid state ? The heaviest oil may be used for the preparation of paste made with white lead or Cremitz white, employed to repair broken enamel. Painters' Cream. Painters who leave long intervals between their pe¬ riods of labour, cover the parts which they have painted with a preparation which preseryes the freshness of the colours, and which they can remove when they resume their work. It is thus made : Take of very clear nut oil three ounces; of mastich in tears pulverized, half an ounce; of sugar of lead two drachms avoirdupoise. 166 DRYING OIL FOR PRINTERS’ INK. Dissolve the mastich in the oil over a gentle fire, and pour the mixture into a marble mortar on the powdered sugar of lead; stir it with a wooden pestle, and add water in small quantities till the matter assume the ap¬ pearance and consistence of cream, and refuse to admit more water. By whipping up the mixture with a bunch of small twigs, 7\ ounces of water may be com¬ bined with it. Drying Oil for Printers' Ink. Printers’ ink is a real black paint, composed of car¬ bonaceous matter and linseed or other oil, which has undergone a degree of heat superior to that of the differ¬ ent drying oils already mentioned. A greater or less consistence is given to it according to the strength of the paper; and this depends on the degree of heat given to the oil, or on the mixture of a greater or less dose of carbonaceous matter. The degree of heat applied to the oil is sufficient to decompose it in part, and even to make it inflame. Should this prepared oil retain unctuosity, it would fill the eye of the letter, run upon the paper, and commu¬ nicate to it a yellow semi-transparency: a proof of the badness of the ink. Boil linseed oil for eight hours in a large iron pot, and add to it bits of toasted bread, for the purpose, it is said, of absorbing the water contained in the oil. Leave it at rest till next morning, and then expose it eight hours more to the same degree of heat, or until it has acquired the necessary consistence ; then add lamp black, worked up with a mixture of oil of turpentine 13 PROCESSES FOR DRYING OIL, FROM VANHERMAN. 167 and common turpentine. This operation is to be per¬ formed in the open air, to obviate the bad effects of the vapour of the burnt oil, and in particular to guard against accidents by fire. Observe , that the lamp-black should be the best and finest which can be obtained; and it should be, besides, subjected to the operation of burning, as directed under that article. Other blacks are sometimes used in the preparation of this ink, such as that from peach stones, &c. In regard to the common turpentine, it should be observed that the common turpentine of the shops con¬ tains, it is to be feared, sometimes a portion of some impure fixed oil, and hence is improper for this com¬ position. The article called frankincense, in the shops, is the purest and best of common turpentine, and is best for the above ink. See the following articles : Processes for drying Oil, from Vanlierman . Into a tin pan, about three feet square and one foot deep, pour three or four gallons of linseed oil, to which add four ounces of coarse litharge for each gallon of oil; stir the mixture two or three times a day with a broad spatula, agitating it well for a fortnight, when the oil will have acquired a strong drying quality equal to boiled oil. To make the same Oil white and limpid. Expose it in shallow pans to the sun and air for three or four days, and it will become as limpid as water. It must, during the exposure, be guarded from the rain; let it be afterwards strained and bottled for use. 168 PROCESS FOR REFINING EXPRESSED OILS. Linseed oil, and other expressed oils, may be de¬ prived of their colouring matter without prejudice to its quality, by adding to it gradually, in the proportion of six gallons, half a pint of sulphuric acid, and agitating the mixture well for five or six hours, then letting it rest for a day, the clear oil may be poured off, and used for the common purposes of linseed oil, or be boiled with a small quantity of sugar of lead to give it a dry¬ ing quality. Another Process for Refining Expressed Oils Has been made public by Mr. Mathew Wilks , of Dart- ford, in a specification of his patent, dated December, 1822. Into two hundred and thirty-six gallons of oil pour six pounds of sulphuric acid; mix both by agitation for three hours; well mix also six pounds of Fuller’s earth with fourteen pounds of hot lime ; add this mix¬ ture to the preceding, and agitate the whole for about three hours. Boil now this mixture with water, equal in quantity to that of the oil, for three hours, during which it must be continually agitated. The fire is then to be with¬ drawn, the whole allowed to cool, and when cold the water must be drawn off; the oil will be found clari¬ fied, and after standing some time, be fit for use.— Journal of Arts, vol. vii. p. 239. We do not know what part of the above process can be entitled to a patent; but this we know, that the pro¬ cess of boiling sulphuric acid with expressed oil for re¬ fining it, was practised in our presence more than thirty OIL OF TURPENTINE. 169 years since; and we know also, that the addition of lime is not a new invention.—See lire’s Dictionary of Chemistry , article Copal. Oil of Turpentine , Sometimes, but improperly, called Spirits of Turpen¬ tine, and, in the slang of common painters, Turps , is obtained from crude turpentine by distilling it with water in a common still. A colourless, limpid, strong, penetrating fluid comes over, having a peculiar odour, and a hot, pungent, bitterish taste ; it is also extremely light, volatile, and inflammable. It is, of course, an essential oil, and one of the lightest of its class: its specific gravity being only 792, while most of the other essential oils exceed 900. It dissolves in hot alcoho], and again separates from it as the spirit cools. In all other respects it agrees with the other essential oils. The residuum left in the still after its distillation is yellow resin. Oil of turpentine is used for various purposes in the arts; chiefly, however, as a vehicle for paints and var¬ nishes. White lead, ground in this fluid, forms the dead white so well known to painters. If oil of turpentine has been adulterated with any fixed oil its colour will sometimes indicate it; but a sure method of detecting the adulteration is the follow¬ ing : Impregnate a bit of white paper with this oil, and hold the paper before the fire. Pure oil of turpentine will evaporate completely, without leaving any traces on the paper, on which you may afterwards w r rite; but i 170 COMMON TURPENTINE—RESIN. if it be mixed with fat oil, the paper will be transpa¬ rent, and will not receive the impression of writing. The volatile nature of oil of turpentine renders it pe¬ culiarly well suited for oil painting, as by means of this fluid the paint can be worked with much ease ; and as it evaporates so rapidly, a greater body of paint is by its means laid on: hence it is, with propriety, considered a drier. What is called Ethereal Oil of Turpentine is rarely, if ever, found in the shops ; and for the ordinary pro¬ cesses in painting is not necessary. If a peculiarly pure oil of turpentine should be wanted for some spe¬ cific purpose, it may be obtained by the artist’s sub¬ mitting common oil of turpentine to another distilla¬ tion . such was formerly called ethereal or rectified oil of turpentine. Crude , or Unstrained Turpentine , is the produce of many different trees of the pine genus. It is imported in casks from various countries, chiefly, at the present time, from North America. It is this article, when hardened by age, that is called the frankincense of the shops. As we have said above, the residuum, after the distillation of oil of turpentine from this substance, is yellow resin. Black resin is merely yellow resin de¬ prived of more of its terebinthine matter by a still greater degree of heat. Gum Olihanum is sometimes called frankincense, but it is a very different substance from turpentine. Turpentine is distinguished in the shops into Com¬ mon or Horse Turpentine, Strashurgli , Venice , and Chio Turpentine. VENICE TURPENTINE—TURPENTINE VARNISHES. .171 Common , Horse , or Strained Turpentine , is of a yel¬ lowish white colour, somewhat opake, and of the con¬ sistence of honey. It is sold as being merely the tur pentine obtained from the pine, and freed from impuri" ties ; but there is reason for believing that it contains a portion of some fixed oil. Venice Turpentine , although usually described in books as an article imported from Venice , is never sold as such in the shops. It is usually made either by melt¬ ing black resin, and, after removing it from the fire, mix¬ ing with it gradually an equal weight of oil of turpen¬ tine ; or as follows : take of unstrained turpentine, com¬ monly called frankincense, three pounds and a half; of oil of turpentine one pint and a half; of linseed oil one pint. Melt first the unstrained turpentine over a mo¬ derate fire, and wdien it is melted and removed from the fire, add gradually the oil of turpentine and linseed oil previously mixed. Lastly, strain the whole, while hot, through a hair sieve. From what has been said, the preparation of Turpentine Varnishes may be easily anticipated. When a varnish is wanted, without any regard to its tenaciousness when dry, the first preparation, as Venice turpentine above, becomes a very good varnish; but if a varnish of a light colour be w r anted, united also with some tenacity, the second preparation for Venice turpentine wfill be found the best; but instead of using common linseed oil, an oil prepared by some of the processes for drying oil above should be used. We may multiply forms without end I 2 172 VARNISHES. for turpentine varnishes, but these directions will be amply sufficient for the oil painter. It is scarcely ne¬ cessary to add that turpentine varnishes, if too thick, may be always made thinner by the simple addition of oil of turpentine ; and that the union may be complete, the mixture should be subjected to a moderate heat. There are, however, a few other varnishes, into some of which turpentine enters, which it may be proper here to describe, and which the oil painter will occasionally find of use. For the convenience of reference we shall distinguish them by numbers. Varnish No. I. Which may serve as a mordant for gold , and also for dark colours. Take of boiled linseed oil one pint; of Venice tur¬ pentine eight ounces ; of Naples yellow five ounces. Heat the oil with the turpentine, and mix the Naples yellow finely powdered. Great use is made of this varnish in applying gold leaf; when the varnish is applied to solid and coloured coverings, the Naples yellow may be omitted; but in such case an ounce of litharge to each pint of varnish may be substituted : the litharge will do no injury to the ground colour. Drying Varnish , with Spirit of Wine , No. II. Take of gum juniper, in powder, eight ounces; of gum mastich, in powder, two ounces; Venice turpen¬ tine, made without any fat oil, two ounces; pounded glass four ounces; of rectified spirits of wine two pints. VARNISHES—SPIRIT OF WINE. 17 3 Mix the gums and glass first together, and then add the Venice turpentine, and lastly the spirit of wine. Keep the whole in a gentle heat, shaking it daily till all is dissolved, except the glass, which is added merely to facilitate the dissolution of the gums; or the solution may be more speedily effected by proceeding as ordered in No. IV. For other varnishes with spirit of wine, see Nos. VI. VII. VIII. Spirit of Wine is a light, transparent and colourless fluid, obtained by distillation from various fermented liquors, such as wine, malt liquors, cyder, perry, &e. When highly rectified, that is, wholly deprived of water, it is called alcohol. It is a highly inflammable sub¬ stance: its constituents are, hydrogen about 14 parts; carbon about 52 ; and oxygen about 34. The, spirit of wine usually to be obtained in the shops always con¬ tains a portion of water ; its strength is determined by its weight. Rectified spirit of wine, as directed by the College of Physicians, is in weight 835, distilled water being 1000, and contains about 5 parts in 100 of water. A wine pint of such spirit should not weigh more than 13 \ ounces avoirdupoise. The specific gravity of pure alcohol is 796. Rectified spirit of wine is employed in the preceding and many other varnishes ; it is the pro¬ per solvent of all the resins, and gums consisting chiefly of resin; as the proper solvent of gum (see gum-water) is water. Another spirit of wine is also occasionally used, called Proof-spirit; this contains of alcohol 55 parts, and of water 45 parts in 100 : a wine pint of it weighs I 3 174 VARNISHES. about 15 ounces ; it is usually obtained by merely mix¬ ing rectified spirit of wine and water in the proportions here stated, but it is rarely used in varnishes. Gum Juniper , or Sandarac , is obtained from the Juniper us Communis , or common juniper, a well known shrub. It is almost wholly soluble in alcohol, with which it forms a white varnish, which dries speedily. Powdered gum juniper is sometimes called pounce . Gum Mastich is the production of the pistacia len- tiscus, a tree native of the south of Europe and Asia. It dissolves entirely in aether; in alcohol about one-fifth remains undissolved: its chief use is in varnishes. Another species of the pistacia produces the Cliio Tur¬ pentine. Varnish No. III. For mixing up Coloured Grounds . Take of frankincense twelve ounces ; of Venice tur¬ pentine two ounces; of oil of turpentine two pints. Melt the frankincense, to which add the Venice tur¬ pentine, and lastly the oil of turpentine. In the former editions of this work glass was added to the formula: but it is quite useless: and, indeed, after what has been said under Oil of Turpentine , and Turpentine Varnishes , it was scarcely necessary to in¬ sert this form, as the ingenious painter, from our ob¬ servations, can vary the ingredients at pleasure. See what is said in regard to frankincense, under Oil of Turpentine. VARNISHES. 175 Varnish No. IV. For Valuable Paintings. Take of mastich cleaned and washed twelve ounces; of frankincense, one ounce and half: of camphor half an ounce ; oil of turpentine thirty-six ounces; of white glass pounded five ounces. Reduce the mastich and frankincense to powder; mix them with the pounded glass from which the finest parts have been separated by a fine sieve; the camphor may be readily reduced to powder by a small addition of rectified spirit of wine; mix the whole with the oil of turpentine in a short-necked glass vessel, which must be placed in water gradually warmed till it boils : keep the water boiling, and the mixture occasionally stirred, till the solution of the ingredients is complete. Remarks. If the varnish is to be applied to oil paint¬ ings which have been already varnished, the turpentine may be omitted. Opinions in regard to the varnish proper for paint¬ ings are very various. It is, however, clear that such varnish ought, if possible, to be colourless, so that no foreign tint should be communicated to the colours: it ought also to unite to the most perfect transparency pliability and smoothness. It should not, however, have too much glazing, as the reflection of light is in¬ jurious to effect. Spirit of wine renders varnishes too dry for painting, as they split and crack. Varnishes composed of essen¬ tial oils which have too much body, give too great a I 4 176 VARNISHES. thickness to the coating, so that they diminish the effect of the colours. The following formula has been employed for many years, the varnish resulting from which has been ap¬ plied with success to paintings in the most valuable collections. See the observations on the Preservation , $c. of Paintings , at the conclusion of this chapter. Varnish No. V. For Grinding Colours. Take of frankincense four ounces; of mastich two ounces; of Venice turpentine six ounces; of oil of tur¬ pentine two pints ; of pounded glass four ounces. Let these ingredients be treated in the same manner as directed in No. IV. The varnish being ready, add of prepared nut or linseed oil two ounces. Remarks. The matters ground with this varnish dry more slowly; they are then mixed up with No. III., if it be for a common painting, or with particular var¬ nishes for grounds. Another Varnish with Spirit of Wine , No. VI. Take of gum sandarac six ounces ; of gum elemi four ounces; of gum anima one ounce; of camphor half an ounce ; of rectified spirit of wine two pints ; of pounded glass four ounces. Make the varnish as directed in No. IV. or in No. II. VARNISHES. 177 No. VII. Another Varnish with Spirit of Wine. Take of gum sandarac six ounces; of shell-lac two ounces: of yellow resin, Venice turpentine, and pounded glass, of each four ounces; rectified spirit of wine two pints. Make the varnish as directed in No. II. or No. IV. Remarks. This composition is very similar to what is commonly called French Polish , so much used for furniture; for which, however, see our treatise on Varnishes. Another Varnish with Spirit of Wine , No. VIII. Take of purified mastich six ounces; of gum sanda¬ rac three ounces ; of very clear Venice turpentine three ounces; of coarsely pounded glass four ounces; of rec¬ tified spirit of wine two pints. Make the varnish as directed in No. II. or No. IV. Black Varnish No. IX. . Asphaltum and oil of turpentine, with a small quan¬ tity of drying oil, make a good black varnish. Asphaltum is a bitumen, sometimes called Jews ’ Pitch : it is a smooth, hard, brittle, black or brown sub¬ stance, breaking with a polish, easily melting by heat, and when pure burns without leaving any ashes. It is found in a soft or liquid state on the surface of the Dead Sea; but by age grows dry and hard. A similar kind of bitumen is found in various parts of the world: in I 5 178 COPAL VARNISH. China and America, particularly on the island of Tri¬ nidad ; and also in the Carpathian hills, France, &c. Its specific gravity varies from 1.07 to 1.65. It is solu¬ ble chiefly, if not only, in oils and aether. Copal Varnish. Copal , or Gum Copal , as it is sometimes improperly called, is an important article in the composition of varnishes, to many of which it gives its name. The natural history of copal does not appear to be satisfac¬ torily ascertained; it is said, however, to be the pro¬ duct of an American tree. It is usually in large drops, or tears, of a yellowish white colour, hard, and semi-trans¬ parent. It neither dissolves in water, like the pure gums, nor in rectified spirit of wine, under ordinary circum¬ stances, like other resins ; in this respect it approaches the nature of amber. It may, however, be dissolved by digestion in linseed oil, rendered drying by quick lime, with a heat very little less than sufficient to decompose the oil. See p. 157 and 159, on the boiling of oil. This solution, diluted with oil of turpentine, forms a beautiful varnish. For particular forms of several copal varnishes we* must refer to our treatise on varnishes, most of the pro¬ cesses of which are attended with considerable trouble. We may, however, here observe, that camphor added to oil of turpentine, in the quantity of half an ounce to a quart of the oil, renders it a solvent of copal; and that camphor and rectified spirit of wine form a more ready solvent of copal than even camphor and turpentine. That a good varnish may be obtained by pouring upon 8 DRIERS-TAR. 179 the purest lumps of copal, reduced to a fine mass in a mortar, colourless oil of turpentine to about one-third higher than the copal, and triturating the mixture occa¬ sionally in the course of the day. The next morning it may be poured off into a bottle for use. Successive portions of oil of turpentine may thus be worked with the same copal mass. Oil of lavender, and some other of the essential oils, are also solvents of copal, probably because they con¬ tain camphor. It should be particularly stated that the varnish made with copal and oil of lavender, although good for drawings and paints, is not fit for paintings, as it dissolves the paint beneath, and runs down while drying. Se Varley in Tilloch’s Mag. vol. 51. Of the Driers for Paints Little more needs to be said: they consist chiefly of litharge , sugar of lead , and white vitriol; to which may be added oil of turpentine , and on certain occasions spirit of wine. On common Tar , Coal Tar , and Oil of Tar. For common purposes, such as covering pales, gates, and other wood work, as well as the wood of houses, where the preservation of 'the wood is the principal object, common tar (that is, tar obtained from various species of the pine), laid on warm alone, or mixed with a portion of some red or dark-coloured ochre or earth, is a very useful preservative from the effects of the weather. The general use of tar (as well as pitch, which is merely tar deprived of its oil by distillation), i 6 180 TAR. in ships, not only for the wood-work, but for cordage, demonstrates its great utility. But the tar obtained from the pine is nevertheless comparatively dear. In the production of gas from coal a great quantity of tar is obtained, which is much cheaper than pine tar: at the present time it can be purchased for three pence per gallon. This tar is now also used pretty extensively as a.paint, without any admixture, and without heat, being merely laid on the wood-work with a brush. It should, however, be laid on, if possible, in warm weather; and in order that the painting may be effectual, two coats should be given. The chief drawback to this paint is its offensive smell; but that goes off in a few days. Some prejudice has been excited against the use of coal tar as a paint. It has been asserted that it rots the wood to which it is applied. From our own obser¬ vation and experience we do not give the least credit to this. We have, besides, made it our business to inquire both of professional and non-professional men whom we presume to be well acquainted with coal-tar and its effects, and their opinions coincide with our own. It has been suspected that the destructive quality of coal- tar is owing to the acid which it contains (pine tar, we must also remember, contains an acid), and it has been suggested that the addition of a small portion of slaked quick dime would neutralize the acid, and thus render it harmless ; this may be done, but we cannot think it necessary. Different colours, of a dark kind, may be readily OIL OF TAR—ANIMAL OILS. 181 given to coal-tar, by mixing with it red or yellow ochre, or other coloured earths. The use of oil of tar, as a vehicle for coarse paint, is described under the section oxide of manganese. On Animal Oils as vehicles for Paints. x4s we have seen, the vegetable oils obtained from poppy seed, from nuts and from linseed, with the ad¬ dition of the essential oil of turpentine, and the var¬ nishes are most usually employed as vehicles in oil painting; and they are so employed, because when pigments are mixed with them they soon become hard. Whereas many animal oils, and particularly the animal fats, are indisposed to assume such a condition; and hence are most commonly rejected by the painter. As has been mentioned in a preceding part of this chapter in regard to fixed oils generally, they consist of carbon, hydrogen, and oxygen; and it has been sup¬ posed that those oils which contain the largest quantity of oxygen dry the soonest: hence the conclusion has been drawn that, in adding oxygen to such oils by the medium of some metallic oxide, they are thus rendered drying. We doubt very much this theory; although we are not prepared to offer a more rational one, unless indeed as regards lead in particular, its general disposi¬ tion to dissolve in and to harden expressed oils, will not give us a different solution of the matter. However, in regard to animal oils, we think that as they, as well as vegetable oils, consist of two substances as proximate principles, namely siearine, a hard substance when in ordinary temperatures, and elaine , a soft substance in 182 ANIMAL OILS—PUTTY. similar temperatures, we are disposed to consider the indisposition for drying in fat and other animal oils to be owing, in part at least, to the large quantity of the elaine which they contain, and hence any thing which abstracts from them a portion of their elaine will render them more disposed to dry. We think, therefore, that a caustic alkaline salt offers such a medium; but it re¬ quires peculiar nicety in its application: for if used in so caustic a state as the ley for soap, the whole sub¬ stance of the oil will be, by long boiling, converted into that substance ; but if used in a partially caustic state, and boiled with the oil for a few hours, we pre¬ sume that some of the elaine will be combined with the alkali, without touching the stearine; and if all which we desire could not be obtained during one process of boiling, two or even three may be adopted, and pos¬ sibly such oil would be rendered much more suitable for the processes of painting. Having had much expe¬ rience in the refining of spermaceti, we throw out this hint for those who may be interested in converting fish-oil into oil fit for painting. After fish-oil has been thus purified, it may be treated with the metallic oxides in the same way as linseed or nut-oil, to render it more effectually drying. The mode of depriving oils of colour will be found under the processes for drying oil from Vanherman. Putty Is used by the painter for filling up holes which occa¬ sionally occur in wood and other work so as to render the surface smooth and even to receive the paint. It is PRESERVATION AND REPAIRING OF PAINTINGS. 183 made with dry whiting finely powdered and mixed with as much linseed oil as will form it into a stiff paste like dough, .which should be well kneaded, or well beaten with a heavy piece of wood till it is ren¬ dered uniformly smooth and tenacious. It should be kept in a glazed pan, covered with a wet cloth, or with water. If it grow hard, it may be heated by the fire, or by pouring boiling water over it, and while warm, beating it as at first, with the ad¬ dition of a small portion of oil. To render it more tenacious, some persons add to it a portion of white lead; but this does not appear necessary: and, besides, lead should never be used when it can be avoided. On the preservation and repairing of Paintings . As every thing that relates to the preservation or repairing of paintings is of great importance to artists, and amateurs, we cannot, perhaps, more appropriately conclude this chapter than by the following obser¬ vations. The variety of destructive varnishes which are often applied to paintings, occasions some complication in the means employed to remove them, in order to substi¬ tute others in their place. A new painting has often no other covering than white of egg. This varnish is of the simplest kind: it consists only of two or three ounces of proof spirit of wine (see page 173), in which one eighth of an ounce of refined sugar and the white of an egg has been dis¬ solved. The white of egg with the sugar in powder is 184 PRESERVATION AND REPAIRING OF PAINTINGS. beaten up with the proof spirit. The varnish is then applied with a very soft sponge to the picture, placed in a horizontal position. If a few drops of the juice of garlic be mixed with the varnish, or if the vessel in which the white of egg is beaten be only rubbed with it, the flies will avoid the painting. When it is necessary to remove this coating, a sponge moistened with warm water is slightly applied to the surface of the picture. A kind of froth is then formed, w hich must be washed off with water: this operation must be repeated till no more froth appears. This method will remove not only white of egg varnish, but also that made with gum arabic, isinglass, or any other matter soluble in water. There is no reason to be under any apprehension for the picture, because the water has no action on oil colours. Great masters rarely varnish their pictures after they are finished: they protect their tints by a coating of white of egg, and do not varnish till a year after, when the colours are completely dry. The method above described for removing this coating requires care and attention. After it is removed, the picture is left to dry, and the varnish is applied with proper precau¬ tions. More difficulty occurs with old paintings. Besides varnishes on which alcohol and oil produce no effect, they are often spoiled by foreign bodies, the nature of which is unknow n, and which resist the action of soap. Oil of turpentine may, indeed, remove many stains; but it attacks the colours, and softens the oil with which they are mixed. Olive oil, and also butter, may PRESERVATION AND REPAIRING OF PAINTINGS. 185 be substituted for it with advantage, these not attacking the colours, or at least having only a very slow effect on them. Resin, the basis of the old varnishes, gives some hold to an alkaline solution composed of one ounce of carbonate of potash (the pearl-ash of the shops), and eight ounces of water. This liquid is very much em¬ ployed, but it requires great care : for it may affect the colours of the painting, in consequence of the disposi¬ tion which the alkali has to combine with resin and with oil. Long habit, and the eye of a painter are therefore required to judge of the proper use of this method. Rectified spirit of wine is a powerful agent not only in removing oily stains, but also the resinous consti¬ tuents of varnish; and it does not alter the colours mixed with prepared oil; it exercising no action on them, unless some essential oil, such as oil of lavender or turpentine, has entered into their composition. It will be proper therefore to ascertain the nature of the oil which was employed, by making experiments on a comer of the picture. In general it is proper to begin cleaning the picture by first drawing a sponge dipped in warm water over the surface of it; if no froth be produced, the varnish is of a resinous nature. This washing is often sufficient to call forth the colours, and restore their original lustre. But if the painting be covered with varnish, rendered yellow by time, opake, and which obscures the colours, place it in a horizontal position, and having poured 186 PRESERVATION AND REPAIRING OF PAINTINGS, rectified spirit of wine over it, keep it moistened in this manner for some time without employing friction. If cold water be then applied to the surface, it will remove the spirit, and the portion of resin which has been dissolved or softened. Care must, however, be taken not to use friction, lest the ground should be attacked. When the surface is dry, the operation is repeated till the varnish is wholly removed. Sometimes a painting is covered with a varnish com¬ posed of fat oil and insoluble resin, such as copal. In such case the attempt will not succeed, neither spirit nor alkalies act beneficially on such varnishes. Even essential oils, which might seem proper on some occa¬ sions, would only whiten the varnish, and consequently injure the painting. If, however, the picture be of great value, and is worth the expense, (ether may be employed with suc¬ cess : its power of dissolving copal renders it peculiarly proper for this purpose; besides, a consideration of moment, it does not attack the drying oil with which the colours are mixed. This method is expensive, if pure sulphuric aether be employed; but the loss, by its rapid evaporation, may in some degree be prevented by dipping a cloth in aether, and applying it to the paint¬ ing, and then closely pressing it down with a metallic plate or piece of glass. It is scarcely necessary to add, that in the application of aether no candle or other flaming body should be brought near it, or a combus¬ tion would be the result; the same may in fact be stated of the application of rectified spirit of wine. When a picture is dirtied with smoke and dust, a PRESERVATION AND REPAIRING OF PAINTINGS. 187 sponge dipped in ox-gall, drawn over it, will restore its original splendour. If it has not been varnished, it will revive the brightness of the colours, provided it be gently rubbed ; and in this manner it may be prepared for receiving the varnish. Ox-gall is a saponaceous fluid obtained from the gall-bladder of the ox ; it is sometimes preferable to soap for removing oleous and other matters from various bodies. Flies also* dirty paintings, and hence it is necessary to wash them frequently : the operation is troublesome, and attended with danger. It is said that the odour of laurel oil, commonly called oil of bays, is disagreeable to those insects, and that it drives them away from apartments in which it is kept. As it is of a solid consistence, it may be easily employed. Some observations on restoring the colours of old pictures deserve attention in the introductory matter of the second chapter, p. 41. to which the reader is referred. Varnishes made with oil of turpentine keep much longer than those made with spirit of wine. Turpen¬ tine varnishes even improve by age : they should be kept in a place exposed to a good light, but excluded from the direct rays of the sun. In the course of some months they become thick, and acquire an oily consist¬ ence which renders the application of them much more advantageous. If the varnish, No. IV., be applied to a picture when 188 PRESERVATION AND REPAIRING OF PAINTINGS. newly prepared, the oil speedily makes its way to the colours of the painting, if it has not been before var¬ nished, and the application is less economical than if it were a year old. It will be proper, in particular, not to apply the coatings too soon after each other, espe¬ cially if the picture has been newly painted. Some amateurs injudiciously apply three coatings of varnish in the course of two or three hours. An interval of two or three days should be left after the application of the first coating, and then a second coating will be sufficient to give the painting brilliancy, and to defend it both from the attacks of moisture and of time. CHAPTER V. On the Composition of Colours. Haying in our previous chapters described the various colours used in painting, and also the vehicles most proper for them, we are now in a condition to treat of the composition of colours , to which subject we shall, therefore, devote the present chapter. Black. —In the choice of matters designed for black, considerable discrimination is necessary : for the car¬ bonaceous parts of peach stones, of beech wood, of ivory, of vine twigs, of bones, of lamp black, &c. produce black of various shades and qualities. Black from peach stones is dull. Ivory black is strong and beautiful, when it has been well levigated under the muller. Black from beech wood, when ground, has a blueish tone. Lamp black is brownish. It is im¬ proved by being kept for an hour in a red heat in a close crucible. Black furnished from vine twigs, when ground, is weaker, and of a dirty grey colour, when coarse; but it becomes blacker the more the charcoal has been divided. It then forms a black very much sought after, and which goes a great way. . Painters usually prefer blacks made from burnt vine twigs or peach stones, to black of Cassel or Cologne, and even to that of asplialtum. For a permanent, although a very inferior black in 190 COMPOSITION OF COLOURS. out-door oil painting, the black oxide of manganese is now employed. The consumption of lamp-black is greatest in common painting. The oil paint applied to iron grates and railing, and the paint applied to paper snuff-boxes, to those made of tin plate, and to other articles with dark grounds, consume a very large quantity of this black. Great solidity may be given to works of this kind by covering them with several coatings of the golden varnish No. I., which has been mixed with lamp black washed in water, to separate the foreign bodies introduced into it by the negligence of the work¬ men who prepare it. After the varnish is applied the articles are dried in a stove, by exposing them to a heat somewhat greater than that employed for articles of paper. Naples yel¬ low, which enters into the composition of black varnish, is the basis of the dark brown used for tobacco-boxes of plate iron, because this colour changes to brown when dried with the varnish. White , when employed without any mixture, is in general very dull. Those who paint decorations are accustomed to heighten it with a small quantity of blue, which renders it brighter, and less liable to be¬ come yellow by age. All whites, or all white matters, are not equally proper for painting in varnish or in oil. Chalk is only fit for distemper, because the two other kinds of painting give it a brown tint. For a distemper white, then, take Bougival white, (or other white, the basis of which is clay), and having ground it with water, mix it with size. It may be COMPOSITION OF COLOURS. 191 brightened by a small quantity of indigo or charcoal black, ground exceedingly fine. The white intended for varnish or for oil requires a metallic oxide, or carbonate, which gives more body to the colour. Take white lead, therefore, reduced to powder, and grind it with oil of poppy and a quarter of an ounce of white vitriol, or sugar of lead, for each pound of oil. Apply the second coating without the addition of the white vitriol, and suffer it to dry. Cover the whole with a coat of the varnish No. II. This colour is durable, brilliant, and agreeable to the eye. In¬ stead of white vitriol, sugar of lead may be employed, which will not affect the colour as white vitriol does. Boiled linseed oil, or even common linseed oil, might be employed in the room of oil of poppy ; but the colour of it would in some degree injure the purity of the white. Painters are accustomed to mix on the grinding slab, along with the colour, an ounce of un¬ prepared oil of poppy or nut oil, for every pound of matter to be ground, to facilitate the extension of it, and to retard the evaporation and drying of the boiled oil. White is prepared also with white lead, ground with a little oil of turpentine, added to oil of poppy, and mixed with the varnish No. III. The colour may be used also w r ith oil of turpentine mixed with oil, and without varnish, which is reserved for the tw T o last coatings. If a dull white be not required, the colour is heightened with a little Prussian blue, or with a little indigo, which is here preferable, or with a little prepared black. The latter gives it a grey cast. In 192 COMPOSITION OF COLOURS. this particular case, if a very fine durable white be re¬ quired, grind it with a little oil of turpentine, and mix it with the varnish No. II. Sometimes a white is desired without any gloss what¬ ever ; this is made by merely grinding white lead in oil of turpentine. It is an expensive colour, in conse¬ quence of the large quantity of the oil of turpentine which evaporates during the grinding. When this colour consists of white lead and the oil of turpentine only, it is called dead white ; but painters, for conve¬ nience occasionally mix linseed or other drying oils with it. And as oil of turpentine almost wholly eva¬ porates when thus combined with lead, it is advisable to iuix a portion, however small, of some drying oil or varnish with it, to render the lead more tenacious. It should not be, however, forgotten, that from the natural volatility of lead, its deleterious qualities are necessarily increased, by being combined with the oil of turpen¬ tine ; and, therefore, such a preparation of paint ought not to be encouraged. But oil of turpentine so much facilitates the operations of painting, that few painters would like to be debarred its use. Of compound Colours , consist ing principally of White Lead . Light Grey. —White lead ground with a little nut oil, or oil of poppy, and mixed with a small quantity of lamp black, forms a grey colour. With this matter, therefore, mixed w r itli black in different proportions, a great Variety of shades may be formed from the lightest to the darkest grey. COMPOSITION OF COLOURS. 193 If this colour be intended for distemper, it is mixed with water. If intended for oil painting, it is ground with nut oil, or oil of poppy ; and with the addition of oil of turpentine if designed for varnish. This colour is durable, and very pure if mixed with the varnish No. IV.: the varnish No. III. renders it so solid that it may be struck with a hammer, if after the first stratum it has been applied with varnish, and without size. These light grey grounds are much used for rooms, especially those exposed to the strong light of the sun. The varnishes above mentioned are stronger than those made with spirit of wine. They are attended with the inconvenience of emitting some smell for a few months; but this may be easily prevented by finishing with a spirituous or colourless varnish. When applied alone, and without colour, the glazing is brighter, and the colour of the ground appears with more lustre, but it is easily scratched. For the last coating the varnishes Nos. II. and VI. are proper; and for the darkest grey No. VII. Pearl grey .—If a blue be substituted for the black in the preceding composition, or if this blue be combined with a slight portion of black, you will obtain silver or pearl grey; but that the ground may not be altered by a foreign tint, the colour for the first coating must be ground with oil of turpentine mixed with a little oil of p°ppy; for the succeeding coats, grind with the var¬ nish No. IV. softened with a little oil of poppy, and mix the colour with the same varnish. The pearl grey will be still brighter, if the last coat be covered with the spirituous varnish No. II. mixed with a little colour. K 191 COMPOSITION OF COLOURS. Flaxen grey .—In this colour, which is treated as the other greys, lake is used instead of black. Take the quantity, therefore, of white lead which you may think necessary to employ, and grind it separately. Then mix it up, and add the lake and Prussian blue, also ground separately. The quantities of the last two colours ought to be proportioned to the tone of colour required to be given to the article to be painted. This colour is proper for distemper, for varnish, and oil painting. For varnish, grind it with the varnish No. V. to which a little oil of poppy has been added, and then mix it up with the varnish No. III. For oil painting, grind with unprepared oil of poppy and mix up with resinous drying nut oil. The painting is bril¬ liant and solid. It will be proper to stop up the holes formed by the heads of the nails in wainscoting, with a cement made of white lead or with putty. The first coat of colour, taking flaxen grey for an example, is white lead without any mixture, ground with oil of turpentine added to a little oil of poppy, and mixed up with oil of turpentine. If any parts of the first be uneven, it will be proper to rub it lightly with pumice stone. This operation contributes greatly to the beauty and elegance of the polish when the varnish is applied. The second coat is composed of white lead changed to flaxen grey by the mixture of a little Cologne earth, as much English red or lake, and a particle of Prussian blue. First make the mixture with a small quantity of 10 COMPOSITION OF COLOURS. 195 white lead, in such a manner that the result shall be a smoky grey, by the addition of the Cologne earth. The red which is added makes it incline to flesh colour, and the Prussian blue destroys the latter to form a dark flaxen grey. The addition of white lead brightens the tone. This coat and the next are ground, and mixed up with varnish as before. This mixture of colours, which produces flaxen grey, has the advantage over pearl grey, of defending the white lead from the action of the air and of the light, which makes it assume a yellowish tint. Flaxen grey composed in this manner is unalterable. Besides, the oil of turpentine, which forms the vehicle of the first coat, forms a colour, the tone of which decreases a little by drying. This observation ought to serve as a guide to the artist, in regard to the tint, which is always stronger in a liquid mixture than when the matter composing it is extended in a thin coat, or when it is dry. Every kind of sizing which, according to usual custom, precedes the application of varnish, ought to be proscribed as highly prejudicial when the wainscoting is made of fir. Sizing may be used for plaster, but without any mixture. A plain coating of strong glue and water spread over it is sufficient to fill up the pores in such a manner as to prevent any unnecessary consumption of the varnish. Colour of oak wood .—The basis of this colour is formed of white lead; three-fourths of this and a fourth of ochre de rue, umber earth, and yellow ochre : the last three ingredients being employed in proportions k2 196 COMPOSITION OF COLOURS. according to the required tint, give a matter equally proper for distemper, for varnish, and for oil. Colour of walnut-tree wood. —A given quantity of white lead, half that quantity of ochre de me, a little umber earth, red ochre, and yellow ochre, compose a colour proper for distemper, for varnish, and for oil. For varnish, grind with a little drying nut oil, and mix up with the varnish No. III. For oil painting, grind with oil of poppy added to drying oil or oil of turpentine, and mix up with plain drying oil or with resinous drying oil. Colour of mahogany. —The basis of this colour is spruce ochre ground in oil, which, when dry, must have a slight coating prepared from the same ochre pre¬ viously burnt and then ground in oil; this imparts the red tint: the dark tint and veins are made with terra de sienna, ground also in oil, and laid on immediately after the red tint, by which they are both amalgamated. Of course the different grains, veins, and knots in this and the preceding colours are to be made by the work¬ man according to the nature of the work to be imi¬ tated. [A more minute account of imitating Woods in Paint will he given under House Painting .] Yellow , and all its transitions to the varied tones to which it is brought by art, are often employed in paint¬ ing. The different bases of this colour, as well as reds, mixed with white, by an expert hand, give the tones which resemble flesh colour. Naples yellow , or patent yellow, and the yellow ochres, are mixed with white lead ground with water, COMPOSITION OF COLOURS. 197 if intended for distemper; or drying nut oil and oil of turpentine, in equal parts, if intended for varnish ; and mixed up with the varnish No. IV. if for delicate ob¬ jects ; or with the varnish No. III., give a very beau¬ tiful colour, the splendour of which depends, however, on the proportion of the white lead ; and this must be varied according to the particular nature of the colour¬ ing matter employed. If the ground of the colour be ochre, and if oil painting be intended, the grinding with oil added to oil of turpentine may be omitted, as the latter alone will be sufficient; with fat oil, however, more pliability and more body are obtained. Chrome yellow is also excellent as an oil colour; we have had no experience of it as a colour for dis¬ temper ; but we presume, if not mixed with any ac¬ tive reagent it will make a fine distemper colour. Jonquil is employed only in distemper. It may, however, be used with varnish. A vegetable colour serves it as a base. It is made with Dutch pink and white lead. It is ground with the varnish No. V. and mixed up with the varnish No. III. A beautiful lemon yellow may be formed by mixing together realgar and orpiment. But these colours are poisonous; it will, therefore, be better to substitute in their room Dutch pink and Naples yellow. This com¬ position is proper for distemper and for varnish. When ground, and mixed with the varnishes indicated for the preceding colour, the result is a bright solid colour without smell, if a spirituous varnish be applied for the last coat. 198 COMPOSITION OF COLOURS. For a straw colour artists recommend a mixture of white lead and orpiment, in quantities proportioned to the tone of colour required. The case is the same with regard to the composition of the golden yellow colour about to be mentioned. The success of these mixtures is not always certain; and there seems to be reason to suppose that it arises from some deception on the part of the colourman, who substitutes white of an argil¬ laceous nature for white lead. Besides wdiich it is known that a mixture of white lead and orpiment, after a time, becomes a brown colour, and therefore another basis instead of w^hite lead is desirable for such colours. See the next article. Golden yellow .—Cases often occur in which it is necessary to produce a gold colour without employing white lead. A colour is then given to a composition, the greater part of which consists of yellow. This is accomplished by Naples or patent yellow, brightened by Spanish white, or by white of Morat mixed with yellow’ ochre and realgar. The last substance, even in small quantity, gives a golden colour to the mixture, and which may be employed in distemper, in varnish, or in oil. When intended for oil, it is ground with drying or pure nut oil added to oil of turpentine, and mixed up with drying oil. A more common gold colour may be formed by mixing with ground spruce ochre a little ground burnt ochre of the same kind, which imparts the reddish tint. Buff colour. — Chamois-colour. —Yellow’ is the foun¬ dation of buff colour, which is modified by a little red lead, or still better by vermilion, and white lead in COMPOSITION OF COLOURS. 199 small quantity. This colour may be employed in dis¬ temper, in varnish, and in oil. For varnish, it is ground with one half common oil of poppy, and one half of the varnish No. V. It is mixed up with the varnish No. III. For oil painting it is ground and mixed up with the drying oil designed for it. Olive green is a composition, the shades of which may be diversified. If black and a little blue be mixed with yellow, you will have olive-colour. The yellow ochres, with a little verdigris and lamp black, form this colour; or yellow ochre and blue, such as Prussian blue, alone. It is proper for oil and for varnish. When intended for distemper, it will be necessary to make a change in the composition. Yellow ochres, in¬ digo and white lead, or Spanish white, are the ingre¬ dients which must be employed. It is ground, and mixed up with the varnishes Nos. V. and III. For oil painting, it is ground with oil added to oil of turpentine, and mixed up w r ith drying oil. Blue is derived either from vegetables, as indigo; from metallic substances, as Prussian blue and Saxon blue; or from stony mineral substances, as ultra- marine ; which last, in consequence of its high price, is particularly reserved for pictures. When Prussian blue or indigo has been employed without mixture, the colour produced is too dark. It has no splendour, and even appears black : it is, there¬ fore, usual to dilute it with white. As much white lead as may be thought necessary for the whole of the intended work is ground with K 4 200 COMPOSITION OF COLOURS. water, if for distemper; and with oil, if for varnish made with oil of turpentine, or merely with the latter, which is equally proper for oil painting; and a quan¬ tity of either of these blues sufficient to produce the required tone is added. For varnish, the white lead is generally ground with oil of poppy added to a little oil of turpentine, and is mixed up with the varnish No. IV. if the colour is de¬ signed for delicate objects, or with the varnish No. III. if for wainscoting. This colour, when ground, and mixed up with drying oil, produces a fine effect, if covered by a solid varnish made with spirit, or oil of turpentine. In the last place, if this oil colour be designed for expensive articles, such as valuable furniture subject to friction, it may be glazed with copal varnish made with oil of turpentine. This colour produces very little effect in distemper, because it is not very favourable to the play of the light; but it soon acquires brilliancy and splendour be¬ neath the transparent varnish. Painting in distemper, when carefully varnished, produces a fine effect. Prussian blue is, however, very apt to pass more or less speedily to green. It is probable that the white lead or oxide of bismuth, frequently employed to lessen the intensity of the blue, contributes to produce this change. These colours acquire a yellow tint from the action of the light, which combining with the blue gives a green colour. The oil may also produce this effect. According to this principle, therefore, which appears COMPOSITION OF COLOURS. 201 well founded, some colouring matters must tend to¬ wards the preservation of the original colour of the Prussian blue. Some painters employ with success umber and a little vermilion to fix the white of the white lead, and to prevent it from passing so easily to yellow. Blacks produce the same effect; and espe¬ cially the black from vine twigs, which combines per¬ fectly with the colour of Prussian blue. We are even assured that this mixture, made in proportions regu¬ lated by experience, exhibits, under the hand of the painter, a brighter and more brilliant tone, which after the lapse of several years, rivals, in some measure, the blue of ultramarine. It is well known that a mixture of Prussian blue and the black of vine twigs exhibits, under the muller, a colour inclining to violet. It then assumes a yel¬ lowish tint, which gradually decreases, and which dis¬ appears at the end of three or four years, and then assumes a very rich and very durable blue tone. This mixture answers the same end in house-paint¬ ing. The pearl grey assumes an azure tint, which is permanent, and which prevents the white lead from in¬ clining to yellow. Another blue made with Saxon blue .—Saxon blue gives a tone of colour different from that of the Prussian blue, and of indigo. It is employed for sky blues. The case is the same with blue verditer. Both these blues stand well in distemper, in varnish, and in oil. The first requires to be ground with drying oil, and to be mixed with the varnish No. III. If intended for K 5 202 COMPOSITION OF COLOURS. oil painting, it is mixed up with the resinous drying oil, which gives body to this vitreous matter. The blue verditer may be ground with the varnish No. VIII. added to a little oil of turpentine; and may be mixed up with the varnish No. II. if the colour is to be applied to delicate articles. Or the varnish No. V. added to a little drying oil may be used for grinding ; and the varnish No. III. for mixing up, if the paint is intended for cielings, wainscoting, or similar purposes. This colour is soft and dull, and requires a varnish that may heighten the tone of it, and give it play. A copal varnish made with oil of turpentine is proper for this purpose, if the article has need of a durable varnish. Green Colour and its Compounds. Sea Green. —Every green colour, simple or com¬ pound, when mixed up with a white ground, becomes soft, and gives a sea green, of greater or less strength, and more or less delicacy, in proportion to the respec¬ tive quantities of the principal colours. Thus, green carbonated oxides of copper, such as mountain green, verdigris, crystallized acetate of copper, green com¬ posed with blue verditer, and Dutch pink, or any other yellow, will form, with a base of a w hite colour, a sea green, the intensity of which may be easily changed or modified. The white ground for painting in distemper is generally composed of Bougival white, chalk, or Spanish w hite ; but for varnish or oil painting- white lead is employed. Sea green for distemper. —-Grind separately w r ith COMPOSITION OF COLOURS. 203 water, mountain green and white lead; and mix up with size and water, adding white lead in sufficient quantity to produce the degree of intensity required in the colour. Watin recommends the use of Dutch pink and white lead, in proportions pointed out by expe¬ rience ; because the colour thence resulting is more durable. In the case of a triple composition, you must begin to make the green by mixing Dutch pink with blue verditer, and then low^er the colour to sea green by the addition of white lead ground with water. Sea Green for varnish .—Varnish requires that this colour should possess more body than it has in distem¬ per ; and this it acquires from the oil which is mixed with it. This addition even gives it more splendour. Besides, a green of a metallic nature is substituted for the green of the Dutch pink, which is of a vegetable nature. A certain quantity of verdigris, pounded and sifted through a silk sieve, is ground separately with nut oil, half common and half drying; and if the colour is intended for metallic surfaces, it must be diluted with the varnish No. III. or with No. IV. On the other hand, the white lead is ground with oil of turpentine, or with oil to which one half of the latter has been added; and the two colours are mixed in pro¬ portions to the degree of intensity intended to be given to the mixture. It may readily be conceived that the principal portion of this composition consists of white lead. If this colour be designed for articles of considerable value, crystallized verdigris dried and pulverized ought K 6 204 COMPOSITION OF COLOURS. to be substituted for common verdigris, and the paint¬ ing must be covered with a coat of the transparent copal varnish made with oil of turpentine. The sea greens which are composed of metallic co¬ louring parts are durable, and do not change. The last compositions may be employed for sea green in oil painting; but it will be proper to brighten the tone a little more than when varnish is used, because this colour becomes darker by the addition of the yel¬ low, which the oil assumes in the course of time. Green for doors , shutters , iron or wooden railing , palisades , balustrades , and for all articles exposed to the air. —Green is, in general, agreeable to the eye: for nature seems to have adapted its particular organi¬ zation to the daily impression of this colour, which is in greater request than any other. Green being the colour of the fields, preference is given to it to harmo¬ nize with nature in the decoration of gardens and walks. White lead is usually the base of this colour. When it is required to bring it. to the most agreeable tone, grind two parts of white lead with nut oil, and one part of verdigris with oil of turpentine. Then mix up the two colours with one half common drying nut oil and one half resinous drying nut oil. This colour appears at first to be a pale blue, which the action of the light will soon convert to green, and in this state it is very durable. Remark. —What is said in a former chapter relative to grinding verdigris in oil and in varnish , should be carefully attended to in the preceding mixtures into COMPOSITION OF COLOURS. 205 which verdigris enters as an ingredient. See Verdi - gris. Compound Colours for rooms may be employed in distemper, or with varnish, and they will be more du¬ rable the less economy has been consulted in making choice of the materials, and if white lead has been pre¬ ferred to Spanish white or to chalk. In general, colours designed for varnish or for oil require a metallic white. Compound Green. —For this colour, take two pounds of white lead, four ounces of Dutch pink, and an ounce of Prussian blue or indigo. This mixture produces a green, the intensity of which may be increased or di¬ minished by the addition of yellow or blue. You must grind with oil to which a fourth part of oil of turpentine has been added, and mix up with the varnish No. III. or No. IV. Both these contribute to the durability of the colour. If you are desirous of destroying the smell of the oil of turpentine, varnish with Nos. II. VII. or VIII. Green colour for articles exposed to friction and per¬ cussion , such as the wheels of carriages , fyc. —The great wear to which carriages are exposed by friction and continual washing, requires that a durable varnish should be employed when they are painted. Whatever care may be taken by coachmen, it is impossible that continual washing should not produce an alteration in the best varnish. To render the work solid, you must first apply a ground composed of boiled linseed oil, white lead previously dried over a pretty strong fire, to make it lose the white, and white vitriol in the propor¬ tion of a quarter of an ounce to each pound of matter. 206 COMPOSITION OF COLOURS. The second coat must be composed of the preceding green colour, that is to say, two parts of white lead and one part of verdigris pulverized and ground with boiled nut oil, added to a fourth part of fat oil of poppy, and mixed up with drying oil. The third coat consists of the same colour, mixed up with copal varnish made with oil of turpentine. Red for the bodies of carriages, coach wheels , fyt \— Artists differ in regard to the composition of the first coats. Watin recommends Berri red, an argillaceous ochre, mixed with litharge. Others prefer red lead. The cheapest, however, will always be preferred. If Bern red, or other red ochre, such as Spanish brown, be employed, grind with oil half fat and half drying, to which add a little ground litharge, and mix up with drying oil for the first coat. The second should be red lead, ground with drying oil, added to one half of oil of turpentine. The third should be the same with the addition of vermilion. Varnish the whole with copal varnish made either with oil or turpentine, or with the same oil and linseed oil; for which see our treatise on varnish. The varnish should be heightened with a little vermilion; the drying may be hastened by expo¬ sure to the sun, or a strong current of air. The red is often prepared, from motives of economy, with red lead without vermilion. Red for buffets. —Varnish with vermilion is not con¬ fined merely to the wheels and bodies of carriages; it often forms the ground; and in this case it ought to be treated in the same manner. It requires, however, a little more labour. After the first coat is applied it is COMPOSITION OF COLOURS. 207 rubbed with pumice stone ; the varnish is then laid on at several times and polished. This operation will be noticed hereafter. The same colour is employed also for the decoration of buffets. Grind red lead with boiled oil, added to oil of turpentine, and mix up with the varnish No. III. The second coat is formed of vermilion, heightened with a little Naples yellow. Then apply a third coat of the varnish of the second, with but little vermilion. This varnish is very durable. It is one of those which are susceptible of a fine polish. Mixed Reds. Bright Red .—A mixture of lake with vermilion gives that beautiful bright red which is employed for varnish¬ ing small appendages of the toilette. It ought to be ground with varnish and mixed up with the same, after which it is varnished and polished. The varnish No. V. is used for grinding ; No. III. for mixing up ; and No. IV. (or copal varnish made with oil of turpentine) for varnishing. Crimson—Rose colour .—Carminated lake, that which is composed of earth of alum (alumina), combined with the colouring part of cochineal, with white lead and carmine, forms a beautiful crimson. It requires a par¬ ticle of vermilion and of white lead. The dearness of these two colours confines the use of this varnish to va¬ luable articles. Violet is made either with red and black, or red and blue ; and to render it more splendid, with red, white, and blue. To compose violet, therefore, applicable to varnish, take red lead, or what is still better, vermilion, 208 COMPOSITION OF COLOURS. and grind it with the varnish No. IV., to which a fourth part of boiled oil and a little white lead have been added; then add a little Prussian blue ground in oil. The proportions requisite for the degree of inten¬ sity to be given to the colour will soon be found by ex¬ perience. The white brightens the tint: the vermilion and Prussian blue, separate or mixed, give hard tones, which must be softened by an intermediate substance, that modifies the reflection of the light to their advantage. Cliesnut .—This colour is composed of red, yellow, and black. The English red, or red ochre of Auvergne, ochre de rue, and a little black, form a dark chesnut colour- This composition is proper for painting of eveiy kind. If English red, which is drier than that of Auvergne, be employed, it will be proper, when the colour is designed for varnish, to grind it with drying nut oil. The ochre of Auvergne may be ground with the varnish No. V., and mixed up with that of No. III. Chocolate —Is composed of red and black. The shades of chocolate may be much diversified. With Spanish brown and lamp black, and the addition Of* white vitriol as a drier, a dull yet durable chocolate is obtained. With brighter reds and ivory black, with the addition of litharge, a better chocolate is produced; and if mixed up with drying oil, with the addition of the varnish No. III. its appearance will be improved. Purple — Pompadour .—As has been stated under the oxides of iron , purple brown is almost the only simple purple known. It may be prepared with drying oil and litharge; its brilliance may be increased by a mixture with the varnish No. III. As purple is a composition COMPOSITION OF COLOURS. 209 of red and blue, a combination of these colours will afford an infinite variety of purples. General Observations on the Composition of Colours. The most experienced artists grind dark colours with linseed oil when the situation will admit of its being used ; because it is more drying. For articles without doors, nut oil is preferable. It is even customary to add to the above ingredients a little ground litharge: it hastens the drying of the colour, and gives it body. But if it is intended to cover these colours with var¬ nish, as is generally practised in regard to wainscoting, they must be mixed up with oil of turpentine to which a little oil has been added. The colour is then much better disposed to receive the varnish. Mixing up with oil of turpentine is not, however, free from inconveniences, when the paint is applied to w T hite wood. Some of these compositions fall off in scales, in consequence either of the first coat having been applied too thick, or carelessly, or of simple earths having been substituted for metallic oxides. The inconvenience in the application of colours mixed up with varnish may be obviated by putting only a small quantity of colour into the last coating of varnish, to facilitate the beauti¬ ful reflection of the light from the coloured ground, or by omitting it entirely. The varnishes applied in this manner all resist percussion, even with a hammer, with¬ out scaling off; they are both brilliant and durable. Although we have confined ourselves to the Compo¬ sition of the principal colours, it will be readily per¬ ceived that an immense variety of shades may be ob- 210 COMPOSITION OF COLOURS. tained by varying the quantities of some of the colour¬ ing substances. The ingenious artist and amateur will, of course, avail themselves of all the resources of the art, for the gratification of taste and the demands of the opulent. It may not be superfluous to add, that in applying varnishes as coverings to paint, particularly in cold weather, they work better if made somewhat warm; and even in mixing varnishes with oil colours warmth will be often found very convenient: varnishes, in this respect, differing very much from oils, in consequence of the resinous matter which they contain being ren¬ dered more liquid by heat. Of the composition of coarse paints it does not seem necessary here to speak; what is useful to be known concerning them will be found in the preceding or in subsequent parts of our work. CHAPTER VI. Of the Instruments used in the Preparation and Application of Colours—Precepts for Painting in Varnish and in Oil — Polishing. It is generally believed, and without much examina¬ tion, that the higher branches of the art of painting re¬ quire more practice or experience than funds. A pa¬ lette for the distribution of the colours, an easel to main¬ tain the pictures at different heights, a rod to support the hand which directs the pencil, a few casts to serve as a guide in the drapery and different attitudes, brushes , and a brush-holder , are, it is said, the whole apparatus of the painter. But although, doubtless, in this as well as in another branch of the fine arts, we may apply the maxim which has been long current, namely, poeta nascitur non fit , so in painting we may also say, pictor nascitur non fit — the painter is born, not made; yet it is nevertheless true, that no painter, however naturally endowed, has ever arrived at eminence in his profession without con¬ siderable practice, discipline, care, and knowledge. Hence, also, a good education; an extensive acquaint- 212 PREPARATION OF COLOURS. ance with history, both ancient and modern, as well as of mythology; a knowledge of anatomy, as far at least as regards the form and the muscles of the body; an extensive knowledge of the world; a certain ease of circumstances, capable of maintaining independence during the long period of study, and of facilitating tra¬ vel, so that he may become familiar with the beautiful productions of antiquity to correct his taste, and to fix it on the truly sublime and beautiful in composition, and to enable him to acquire correct ideas respecting every species of painting, and a regard to human na¬ ture, and in particular genius—are the chief requisites to constitute a great painter. Genius connects the great painter with the great poet, and conducts them to the same end by different routes: it is the province of both to shew us what has often been thought, but never before so well expressed. The one captivates our senses by warmth of colouring, judicious arrangement, and correctness of design; the other seizes on the mind, conducts it by the magic, the delicacy, and ele¬ vation of his thoughts, and by the harmony of his numbers. Venus displays as many graces under the pencil of Apelles as under that of Homer. The scarcity of eminent painters proves that much knowledge and great talents are necessary to arrive at excellence; a point to which all artists ought to aspire. Nor is the knowledge of the preparation and mix¬ ture of colours to be despised even by the first geniuses of painting. It is true that many artists content them¬ selves with the colours which are usually found in the PREPARATION OF COLOURS. 213 shops; hut he who is desirous of excelling in his pro¬ fession, will find that it is not always his interest to rest satisfied with the preparations offered to his notice by the tradesman ; cupidity, if nothing else, too often prompting to sophistications which require consider¬ able ingenuity to detect. Hence the necessity of his making himself acquainted with chemistry , so far at least as regards colours and some of the acids , and their multifarious combinations. By such means he will best know how to combine the various pigments without destroying either their colours or their effects in his pictures ; and he will thus, by the study of che¬ mistry, also learn the best means of rendering his colours permanent, their admixtures more effective, and his works durable. So much, however, has it been the practice to rely on the 'preparers of colours, that, in regard to water colours in particular, boxes, containing cakes of colours, are now found in almost every shop ; some of such colours are bad enough ;* others again are tolerable; but it will be a great rarity to find all the colours, even of the best boxes, unexceptionable; and hence the necessity for the artist to become acquainted with the preparation of colours himself. Such prepared colours, recommended in a late work on the art, are thirty-one in number, as follow : Indigo, Prussian blue, Antwerp blue, ultramarine, cobalt, vermilion, carmine, lake, Venetian red, Indian red, light red, madder lake, red lead, gamboge, Italian pink, terra de sienna, yellow ochre, Roman ochre, Indian yellow, gall-stone, yellow PREPARATION OF COLOURS. 214 lake, brown pink, turkey umber, burnt terra de sienna, burnt umber, Cologne earth, Vandyke brown, sepia, lamp black, Indian ink, constant white *. The work referred to seems to prefer, however, a selection from this list; namely, a box containing the twelve follow¬ ing colours: indigo, Prussian blue, yellow ochre, Ita¬ lian pink, Venetian red, lake, burnt sienna, raw umber, Vandyke brown, sepia, lamp black, carmine. Mr. Smith says, that from nine of these he composes twenty- seven tints. A reference to the introductory portion of our work will shew that the tints of paints are almost innumerable f. We may mention here, in regard to colours for minia¬ ture 'painting , that a solution of two-thirds gum ara- bic and one-third sugar-candy, so as to attach the first covering to the ivory very strongly, will be necessary. In subsequently going over, less of the vehicle may be used, because if the first coat of colours have a suffi- * The Young Artist's Assistant in the Art of Drawing in Water Colours, by Thomas Smith. London : Sherwood & Co. A useful work containing numerous exemplifying plates, to which the student in this branch of the art may advantageously apply. f Most of the paints in the above list will be found described in preceding sections of our work ; but it is to be regretted that fancy or caprice too often gives a name to a colour: one colour, sepia , in the above list, is not, how¬ ever, described among our pigments ; it is, we presume, designed for the dark-coloured substance emitted by the sepia officinalis, or cuttle fish ; sepia, as a colour, is a blackish brown. We may just mention here, that our work is not designed to give a history of every pigment which the fancy of artists might prompt them to employ, but of those only which are the most valuable and useful. PREPARATION OF COLOURS. 21 5 cient quantity of it, the moisture of those that follow will partly dissolve the gum, and incorporate them with it.— Craig’s Lectures , page 353. The preparation of colours in the large way it is not our intention to describe, except as we have already done, or shall hereafter do, when treating of particular articles or methods in the various parts of our work. It will be sufficient here to observe, that colours for the purposes of commerce are usually rendered fit for the use of the painter by being first reduced to powder in mills , whose moving power is either that of water, wind, the horse, or steam, and afterwards ground with oil or other vehicles, also in mills adapted for the purpose, so as to be readily mixed of a proper consistence by the painter himself when he proceeds to his work. In the small way, and with the finer colours, another method is adopted ; this method is within the reach of almost every body. The instruments which painters employ who prepare their own colours are, nevertheless, extremely simple and few in number. A smooth square table , or slab, of porphyry, or other hard stone. It should be sufficiently large to enable the operator to sweep over it with his arms conveniently: from eighteen inches to two feet square w ill be found large enough. A muller to levi¬ gate the materials upon the stone; a spatula, or flexible knife, to bring the colour scattered over the grinding stone by the levigation, again under the muller, or to remove it w hen sufficiently ground. Brushes of various 216 PREPARATION OF COLOURS. kinds, and pots for containing the colours, and for mix¬ ing them. These generally constitute the apparatus necessary for the preparation of paint. But as many colours cannot be used in the state in which they are purchased in the shops, an iron pestle and mortar of a suitable size will be also necessary, together with a few sieves , such as a hair sieve , a brass wire sieve , and a silk sieve * 9 to separate the grosser from the finer parts. The use of these different sieves must be regulated by the judgment of the operator; but we may observe that, Hard bodies should be pulverized and passed through the hair or silk sieve ; or, in other cases, the bias j wire sieve may be most appropriate. This preliminary is applied to the various kinds of ochres, chalk, clay, &c.; and to solid substances, such as white lead, litharge, verdigris, patent yellow, &c.; and thus renders them more completely divisible by the muller; at the same time it separates many foreign bodies which are often met with in various colouring substances. It is scarcely necessary to add, that in the pulverization of verdigris, the preparations of lead , arsenic , &c., the utmost care should be taken, as the powder arising from such sub- * The artist or amateur who desires to, obtain many of his pigments in the utmost degree of purity, will require, besides the articles here men¬ tioned, a few others which his good sense will readily suggest; but a cru¬ cible to burn umber, terra de sienna, ochre, lamp-black, &c. will be found very convenient; although the earths (which should be broken in small pieces) may be burnt in small quantities over a common fire, by being placed in the fire-shovel and heated red hot. PREPARATION OF COLOURS. 217 stances is extremely deleterious, the mouth and nose should be always covered with a handkerchief. Some colours are usually kept in powder for the use of the painter; all the verditers, and many other pig¬ ments are in this state. But several, especially of the finer kinds, are kept in drops; such is Dutch pink and the lakes. In the large way, a great many flat pieces of chalk are employed for the purpose of forming drops thus: the colour to be formed into drops is levigated or mixed with water to the consistence of a paste suf¬ ficiently thick to be forced, by a round stick, through the tube of a tin funnel of the size desired. For lakes, a small one, for Dutch pink, &c. a large one is used. When the drop is forced through the funnel, it is received upon the chalk, which, being dry, imbibes the moisture in the drop, and thus leaves it of the form desired. The drops are afterwards dried in a stove or other warm place. The amateur in lakes, &c. will find, therefore, a few lumps of chalk, and a tin funnel necessary to complete his elaboratory. It should be also added here, that whenever a funnel is employed for the purpose of decanting or otherwise using acids, it should be of stone ware or glass , as acids will be spoiled by using tin funnels. When the colours are to be used in distemper paint¬ ing, they must be ground in water, in order that the lightest particles may not escape by the action of the muller. The ground-matter is to be reduced to the consistence of thin paste; and when the muller glides over the stone without making any noise, and the trace L 218 PREPARATION OF COLOURS. it leaves on the colour is smooth and not granular, the operation is finished : this last observation applies also to colours ground in oil or varnish —impalpable smooth¬ ness being the criterion in the perfect levigation of a paint. One of the most essential points to be observed in the preparation of a colour is, as we have just said, the extreme division of its parts. Grinding in water is speedily performed, it readily loosening the earthy par¬ ticles ; but when varnish, oil of turpentine, or other oil is employed, the case is not the same. The artist who attends to the profit arising from his labour will soon be sensible of this precept: for use will teach him that a colour becomes most profitable when it is reduced to the utmost possible state of division. He will not, therefore, consider the time which he employs in the operation as mis-spent. The minute division of colours is one of the principal causes of their beauty, and of the mellowness of their tones. The touch, sight, and hear¬ ing concur to determine the sufficiency of this division. We can readily perceive that a colour grinds more easily at the commencement than at the end of the operation, the granular parts roll with greater freedom under the muller than when they are more attenuated ; this arises most probably from the air being admitted under the muller more readily at the beginning of the operation than at its conclusion. The hand which per¬ forms the circular motion may, therefore, easily dis¬ tinguish when the division of the parts has attained its utmost limits. The eye also perceives this change in the superior PREPARATION OF COLOURS. 219 fineness of the parts; the colour itself is also more intense; but the alteration may be distinguished even by the ear. At the commencement of grinding, the friction of the matter with the instrument excites a noise, which, as the operation proceeds, gradually decreases, and is scarcely heard towards the end. Sometimes in the progress of the operation, the addition of more oil, or other liquid, becomes necessary to facilitate the process, and to im¬ part to the paint a proper consistence; care however must be taken not to render it too liquid. And some¬ times, under peculiar circumstances, it may be neces¬ sary to add more colouring matter: both these states can only be judged of by the tact of the operator. A too liquid consistence is less fatiguing, but the process will not be so soon accomplished: on the other hand, it will be more rapid, as the consistence of the matter is thicker; hence time is gained at the expense of a little more fatigue. Two or three trials will indicate the proper consistence which should be given to the matter, to render the operation at once easy and expe¬ ditious. The perfection of this operation, and the speediness of its execution, depend very much on the quantity of the paint subjected each time to the action of the muller. There is, it is true, no fixed rule in regard to this point; but those who should presume that the pro¬ cess would be expedited by employing a great deal would mistake. It depends on the extent of the stone, the length and strength of the workman’s arms, and consequently the greater or less difficulty he may find L 2 220 PREPARATION OF COLOURS. in keeping the muller in continual motion: when heavy matters, such as those obtained from metallic bodies are ground, eight ounces at once will be sufficient. When the grinding is finished, the matter is removed with the flexible knife or spatula, and put into the colour-pot. The same operation is to be, of course, re¬ peated with additional portions of the ingredients, till the necessary quantity of paint is obtained. The colour is then to be diluted with the varnish, oil or other liquid to be employed, in order to give it the re¬ quisite consistence. This is wfliat is called, according to the technical term, mixing up the colour. In this respect extremes must be avoided; a paint when too liquid runs, and will not cover the thing to be painted w ith sufficient exactness; if too thick it can with diffi¬ culty be extended, disfigures the work, takes a larger quantity, and hence is more expensive, and requires more labour in its application. The paint, on being taken from the pot, ought not to drop from the brush when turned round two or three times in the hand, by raising it obliquely to check the thread which is formed. Should the paint, during the operation of applying it, become too thick, a little more varnish must be added, if it be mixed with varnish; and oil of tur¬ pentine if it be mixed with the latter, or with other oil. But if the thickness of the paint arise from the varnish, it will be proper to heat the oil of turpentine before it is added to the mixed matter, in order to prevent the coagulation of the resin in the varnish. All matters designed for priming are ground with PRECEPTS FOR VARNISHES. 221 water as regards distemper, or spirit of wine , or with essential oils, such as oil of turpentine, or with fat drying oils. Colours ground with spirit of wine, and which are mixed with varnish, should be employed im¬ mediately ; but the volatility of spirit of wine, and the rapidity of its evaporation, render this process inconve¬ nient. The varnish with which the colour is mixed up is usually employed in its stead; and each time that a quantity of colour is put on the stone, a little drying nut oil is added, if the colour can bear the slight change in the tint which results from it; or with the same quantity of oil of poppy, if the nature of the ground prevent the use of every thing which might communicate a foreign tint. When colours are ground in oil of turpentine , the operator ought to stand where there is a current of air, to avoid the vapour from the oil, which is in many re¬ spects unwholesome. In other cases the colours must be ground with drying oils, or with varnishes, the consistence of which requires that they should be mixed with a half or a third of oil of turpentine. This is the practice followed in regard to copal and amber varnish, and in regard to all colours intended for oil painting. Precepts for the application of Varnishes when used as vehicles for coloured Paints. 1st. Certain kinds of varnish designed for delicate articles, which are often exposed to friction, as boxes, &c. and certain toys, such as fans, boxes for holding counters, &c. must not contain any matter which com- L 3 222 PRECEPTS FOR VARNISHES. municates a strong smell to them, or which would render them slow in drying. In these particular cases spirit varnishes are to be preferred; the colours are then to be ground with the varnish No. VIII. to which about an ounce of oil of poppy should be added, to render it pliant; and the colours are mixed up with the same varnish. But as it evaporates very speedily, it requires to be used immediately. 2d. Under some circumstances, a more solid varnish than those mentioned in the last paragraph is required for, mixing up certain colouring parts; such in par¬ ticular as those prepared from minerals. The colours in this case must be ground with drying oil to which a little fat oil has been added. At other times the colours are mixed up with turpentine or copal varnish. 3d. There are other circumstances which require greater solidity in the varnish, and which proscribe every vehicle incapable of promoting this essential quality. In this case the colours are ground with drying oil, to which a little fat oil has been added, if the colour contains a considerable quantity of a me¬ tallic oxide. If this oil render the matter too thick, a little oil of turpentine must be mixed with it; and it is then diluted with a resinous drying oil or with a fat varnish prepared from copal , linseed oil, and oil of turpentine; or with an amber varnish similarly pre¬ pared. 4th. Painters employ two methods of varnishing apartments. Some apply the colouring substances in distemper , a process which will form the subject of a subsequent chapter, and then cover it with as many PRECEPTS FOR VARNISHES. 223 coats of coloured or uncoloured varnish as are required. Others grind and mix up the colours with varnish, which in this case serves as a vehicle. Both these methods have their advocates: but without troubling the reader with the arguments which have been ad¬ vanced in favour of each of these methods, the second appears to us to be accompanied with several advan¬ tages which the first does not possess. When, however, the plaster of an apartment is new, before the application of a coloured varnish, a size, not too strong, made by dissolving glue in water should be applied warm, that it may penetrate the plaster. But the plaster should have time to dry before it is covered with the glue. Another method favourable to the preservation of wood, and useful in preventing moisture, is to prime the wood with white lead, to which a sixteenth part of litharge has been added ; these are ground with oil and one third oil of turpentine. Colours in varnish applied to this first coat answer exceedingly well. 5th. A careful artist, who desires to impart to his colours on wainscot all the splendour of which they are susceptible, removes all the small inequalities from the surface after the application of the first coat, and parti¬ cularly those rendered more apparent by the knots and fibres of the wood, by rubbing pumice stone gently over these inequalities. This operation may be per¬ formed on every kind of painting, but in particular on that with oil of turpentine: it adds greatly to the uni¬ formity of the tone and splendour of the varnish. It should be observed that ceilings, if old, must be care- L 4 224 PRECEPTS FOR VARNISHES. fully cleaned and brushed to remove the dust from the mouldings. 6th. In all cases of house-painting, turpentine is to be preferred to spirit, or to copal varnishes. There are some spirit varnishes which may, however, answer tolerably well; but in general the consistence and tenacity of varnish made with oil of turpentine are not to be expected from spirituous varnishes. Delicate persons may dislike its strong odour; but in summer this objection is of little import. Besides, if desired, this strong odour may be prevented, by simply covering the strata of varnish with a stratum of spirit varnish as soon as the former is dry. 7th. Some colours w T hich are dear, such as vermilion and oxides of copper, are advantageously modified by a ground of some much cheaper colour. Thus, red lead is united with English red, and vermilion, which is reserved for the last stratum. The same economy in¬ duces painters to use a ground for a green colour of yellow ochre mixed with boiled oil, oil of turpentine, and varnish, before applying the green colour itself. But this ground is best suited for external objects; for apartments, white lead as a ground for green is to be preferred. 8th. When varnishes are very little coloured, as is the case when they form glazing, it is more difficult to make a regular application of them than when they are mixed with the ground. The essential point in their application is to leave no marks of the brush. It must be rapidly drawn over the surface in large strokes; forwards and backwards will be sufficient: if drawn PRECEPTS FOR VARNISHES. 225 several times over the same place, the varnish rolls under the brush. To produce uniformity in the glazing, too much varnish must not be employed at once, be¬ cause undulations and ridges will be formed which have a very disagreeable effect; nor should the strokes of the brush cross one another; when they do, the effect is as disagreeable as in the preceding case. For the application of glazing varnishes large flat brushes are employed : they perform the work very quickly. 9th. The strong smell which immediately follows the application of paints prepared with varnish arises chiefly from the evaporation of the oil of turpentine. It is sometimes also mixed with the smell of the resins which the varnishes contain, and sometimes with the odour of some of the colouring materials; such is that of verdigris. These disagreeable, and sometimes even deleterious odours, may be weakened by the diffusion of some bal¬ samic substance of an agreeable odour; but such addi¬ tion is, however, a very incomplete corrective: musk, oil of cinnamon, essence of lemon, essence of bergamot, oil of thyme, of lavender, rosemary, &c. may be em¬ ployed for the purpose; or very dry new hay will an¬ swer still better. Or several tubs filled with water have been sometimes placed in the apartment: the water appears to condense the odorous vapour similarly to a refrigerator in the common process of distillation. This method has been employed with complete success in apartments var¬ nished with verdigris and with turpentine varnish. L 5 226 PRECEPTS FOR VARNISHES. When the varnish is dry, the remaining vapours may be dissipated by nitrous fumigation , so effectual for purifying foul air : thus, pour into a glass or stoneware vessel half an ounce of oil of vitriol, and having added to it half an ounce of powdered saltpetre, stir the mix¬ ture with a glass or pipe-clay tube. The diffusion of the fumes may be facilitated by carrying the cup about the apartment. This process may, it ought however to be observed, alter the beautiful gloss of the varnish, if it be delicate and not completely dry. 10th. Colours applied under varnish, as well as those designed for oil painting, require great attention to cleanliness on the part of those who employ them. The surfaces to which they are applied should be rubbed or brushed, and even washed if necessary: they must, however, be well dried afterwards. The same care must be extended to all apartments, whether painted in oil or varnished. But varnish is more liable to be injured by dirt than oil painting, and the means of repairing it cannot always be the same, because dust adheres more strongly to varnish than to oil. A few strokes of the brush, with simple washing, will be sufficient for varnishes which are usually kept clean. If, however, the dust be incrusted, soap and water ap¬ plied with a sponge will be necessary, taking care to cleanse the sponge well after every application to the varnish. Some employ an alkaline ley called second water. When it contains only l-16th or l-20th of pearl-ash, it is called weak second water ; when 1-10th, it is called PRECEPTS FOR VARNISHES. 227 strong. Some even leave it an hour or two on the var¬ nish before it is rubbed off with a sponge dipped in common water; but this method is attended with in¬ convenience : the alkali acts strongly on delicate var¬ nishes, depriving them of their brilliancy; and if they contain vermilion, or Prussian blue, it alters or de¬ taches them. But although this process be improper for cleansing varnishes, it is exceedingly proper for oil paintings, and particularly for those with grey grounds. The quantity of pearl-ash may be even increased in cleansing these to l-8tli of the water employed. Others employ oil of vitriol diluted with water for the same purpose, in such a manner that the acidity may be equal to strong vinegar. This solution is very cleans¬ ing ; but it tarnishes the varnish, and therefore the ap¬ plication must be immediately followed by a thorough washing with pure water. This acid is, how r ever, much more proper for oil paintings than for those with var¬ nish ; but in using it for oil painting, the surface should be afterwards well dried with soft and very warm cloths. Muriatic acid w r ill answer much better for cleansing paint than oil of vitriol, it forming with the dust a deli¬ quescent salt, which washing easily removes, and when diluted with water, does not act either on resins or on the most delicate colours; but it is unfortunately dearer than vitriolic acid. But whatever be the means used to clean varnish or paintings by washing, they must not be left till they have been completely dried with clean and very warm cloths. Moisture is exceedingly hurtful to them , for this reason they ought to be protected from fogs. L 6 228 PRECEPTS FOR VARNISHES. 11th. During the process of applying oil colours, if any of them fall on the clothes, it may in general be in¬ stantly removed by rubbing the cloth strongly with crumb of bread. But oil of turpentine applied in suffi¬ cient quantity to wash out the colour both of oil paint and of varnish will be found preferable, because more effectual. 12th. If any colour be left which you wish to pre¬ serve, cover it with water, and deposit the vessel in a cool place. The brushes may be kept in the same manner, after being freed by oil of turpentine from the paint adhering to them; it will be also most convenient to wipe them. Spirituous varnishes are exceedingly drying, and pos¬ sess great splendour; for these reasons they are to be preferred. Varnishes made with turpentine are also brilliant, but they are less drying, and emit a strong odour for a long time, unless covered with a spirituous varnish. Oil painting is very durable; it is even sus¬ ceptible of some of the brilliancy of varnish, provided the colours have been mixed with the resinous drying oil, page 160; or if it be covered by a varnish made with oil of turpentine or spirit of wine; but it is slow in drying. This character, which is a proof of its soli¬ dity, causes it to be rejected by those who sacrifice every thing to expedition. The time of its drying may, however, be much shortened by the use of driers; but it must be, nevertheless, admitted that oil painting has rarely the brightness and lustre of that made with var¬ nish. Hence the preference given to paintings with varnish. But as oil painting has still its advocates, and PRECEPTS FOR OIL PAINTING. 229 is besides cheaper, and has also particular rules, we shall now proceed to give some account of it. Precepts for the application of Oil Painting. 4 Although in the preceding section w^e have treated of the application of colours when mixed with varnish , we desire to premise here that many of the observations which we have made in that section will be found ap¬ plicable to oil paintings, and therefore before the stu¬ dent peruses the following precepts, he is requested to attend carefully to what has been already advanced. Oil painting has a character of solidity which causes it often to be preferred to that executed with varnish or in distemper. Besides, there are some circumstances, independent of taste, which require the use of it; as when it is necessary to apply a colour to objects ex¬ posed to the influence of the weather. This kind of painting is used also very extensively for interior work. All kinds of oil cannot be indiscriminately used for this kind of painting, even when they form part of those which reasons, founded on experience, have indicated as alone proper for this use ; such as oil of poppy, nut and linseed oil, rendered drying by particular pro¬ cesses. Painting designed for objects exposed to rain, sun¬ shine, &c. requires nut oil to the exclusion of every other kind, because it nourishes and developes the colour. Linseed oil, in this case, destroys the colour, so that at the end of a very little time the work must be renewed; yet it ought nevertheless to be observed, that linseed oil 230 PRECEPTS FOR OIL PAINTING. is now the general vehicle for common paints, both for exterior as well for interior work. In the case of painting exposed to weather, the colours must not be ground or mixed up with nut oil to which oil of turpentine has been added; because the latter whitens the colour when exposed to the sun, in the same manner as pure linseed oil would do. Linseed oil may be recommended in painting de¬ signed for articles which are sheltered from the incle¬ mency of the weather. There are particular precepts for this kind of paint¬ ing which it will be proper never to deviate from. 1st. When it is necessary to grind and mix up bright colours, such as whites, greys, &c. nut oil or oil of pop¬ py is used. For dark colours, such as chesnut, brown and olive, pure linseed oil is preferable, if the painting be designed for internal objects. 2d. Each coat is applied cold. It is never employed in a state of ebullition, except when it may be necessary to prepare a new wall, or new and damp plaster, in order to make the paint adhere. Without this precau¬ tion the paint rises, and falls off in scales. The first coat on soft wood requires also a little heat, that it may penetrate better. 3d. No colour mixed up with pure oil, or oil to which a little oil of turpentine has been added, ought ever to form a thread at the end of the brush. 4th. The colour must be stirred in the pot from time to time, before any of it is taken up with the brush, in order that it may preserve the same consistence and the same tone. If the ground, in consequence of metallic PRECEPTS FOR OIL PAINTING. 231 colours being used, does not retain the same tint, it may be brightened by pouring in a little of the same oil as that with which the colour has been mixed up. Some painters, who are negligent in regard to the consistence proper to be given to the colour, before it is employed, think they can accomplish the required end by adding oil of turpentine to the colour from time to time, when they think it too thick. This method, in ordinary painting, is not attended with much inconvenience; but it does not answer the purpose in delicate painting: for the addition of cold oil of turpentine lessens the splendour of the colour. The proper consistence should therefore be given at first; and if it be found necessary to add a little more of the vehicle, it ought to be warm : it requires to be well mixed before it is used. 5th. When the painting is designed for apartments, the first coat ought to be ground in oil, and mixed up with oil of turpentine. 1st. Because the latter carries off the odour of the oil. 2d. Because the colour applied over a coat mixed up with oil, to which oil of turpen¬ tine has been added, or with pure oil of turpentine, be¬ comes more brilliant, whereas it would penetrate into a coat with pure oil. 3d. Because oil of turpentine tho¬ roughly hardens the colours mixed up with it; but if mixed with oil it makes it penetrate to the colour. When you are desirous, therefore, to varnish an oil co¬ lour, the first coat ought to be mixed up with oil, and the last two with pure oil of turpentine. When you do not intend to varnish, the first coat ought to be mixed 232 PRECEPTS FOR OIL PAINTING. with pure oil, and the last two with oil to which oil of turpentine has been added. Oil of turpentine unites a practical utility to the two advantages before mentioned: it facilitates the extension of the colour. 6th. If the painting be intended for copper, iron, or any other hard substance, the smoothness of which pre¬ vents the adhesion of the colours by making them glide, a little oil of turpentine must be added to the first coat, which will cause the oil to adhere. Besides, metals in¬ tended to receive varnish or colours must be roughened a little, in order that the colour may lay hold of them: this is performed with pulverized pumice stone, or tri- poli, which is rubbed over with a piece of rag, on each coat being applied. The article must then be exposed to the sun to facilitate the extension of it, if the varnish has a considerable degree of consistence; after which it is carried to a stove to hasten its desiccation. The operation of polishing is not performed till several coats are applied and have become dry. When such var¬ nishes are used you may begin the polishing with pumice stone, and afterwards finish it with tripoli. 7th. If the wood contain resinous knots, which is the case in particular with deal, the colour runs in these knots, and does not adhere. If simple oil be employed, litharge, mixed with a little of the ground colour, is prepared separately, and reserved for these resinous parts. If the painting be in oil, and intended to be covered with polished varnish, more litharge must be added: it masks the wood, and hardens the resinous particles which exude from it. One coat will be suffi- PRECEPTS FOR OIL PAINTING. 233 cient, and will give body to the wood: the labour may be shortened by rubbing the place with a head of gar¬ lic. See page 153. 8th. Some colours, and in particular those which have an argillaceous ground, as the Dutch pinks, boles, &c., as well as lamp-black, burnt vine twigs, &c., are long in drying when employed with oil. It will, there¬ fore, be proper to add drying matter to them, according to the colour : litharge to dark colours, and white vitriol (or rather sugar of lead) to bright colours, mixed with drying oil: this method is always attended with success. Driers are, however, in general unnecessary in paints consisting of metallic oxides, particularly those of lead. 9th. If the addition of drying matter becomes neces¬ sary, it must not be added till the moment wdien the colour is applied, because it tends to render it thicker. 10th. One principle, which ought never to be for¬ gotten, because it is applicable to all kinds of painting, and more particularly to the one in question, is, that a new coat ought never to be applied till the preceding is dry. It will be proper also to brush off the dust, which sometimes covers the last coat, and which, if mixed with the new one, w r ould alter the uniformity of its tint: this observation is applicable, above all, to bright colours, such as whites and greys. 11th. All kinds of painting require that each coat should be of an uniform thickness throughout; and as this depends on the consistence, it will be proper to preserve it in the same state. Habit and experience will be a better guide, in this respect, than any precepts. Too thin a coat cracks in drying; one too thick be- 23 4 POLISHING. comes wrinkled and unsightly. The addition of a little ground colour, or of some of the vehicle, will correct one of these faults. It will not, however, be attended with any inconve¬ nience if a little more liquidity be given to the first coat than to the succeeding; because it is designed ra¬ ther to adhere to the substance which it covers, than to fix the tone of the required colour. But the succeed¬ ing ones, and particularly the last, ought to have suffi¬ cient consistence to prevent the shrinking of the paint; the addition of a little oil of turpentine will, if it be too thick, bring it to the proper point. 12th. If a solidity capable of resisting percussion and friction be required in the paint, this end will be better obtained by applying the first coat with a metallic oxide, such as patent yellow, white lead or litharge, reduced to fine powder, ground in boiled oil, and mixed up with oil to which a little oil of turpen¬ tine has been added, than by the same colour mixed up with oil. Although the process of polishing is dispensed with in all cases of varnishing or painting applied to common apartments, and to external objects, yet as the operator might be sometimes required to perform it, we shall here describe it* Polishing. The processes used in polishing are different, ac¬ cording to the nature of the varnish which requires it. Hard varnishes, such as those resulting from the solu¬ tion of amber and copal in a drying oil, or even in oil POLISHING. 235 of turpentine, as well as certain oil colours, can bear the contact of hard bodies employed for polishing. It is not, however, attended with complete success, but when the ground is charged with a determinate number of coats of a colour which, by painters, is called the priming, it gives to the whole a certain thickness and a great deal of consistence *. The priming is prepared by grinding white lead very fine in pure oil, and mixing it up with oil of turpen¬ tine. Seven or eight coats of it are applied before it is polished. The white lead employed for this purpose must have been subjected to a certain degree of heat, which destroys its whiteness, and prevents it from weakening the colours applied over it. In this state it is called by painters calcined white lead: the colour of it inclines a little to yellow. It will be proper not to give too much heat to the white lead intended for different coats of priming, because it has too much influence on the coloured grounds which it ought to support. The coats of priming are applied over a coat formed of uncalcined white lead, ground in linseed oil, and mixed up with equal parts of linseed oil and oil of turpentine. When the priming has received all the coats it requires, and when very dry, pumice stone, finely pul¬ verized, and sifted through a silk sieve, is mixed up with a sufficient quantity of water. Some of this powder is spread over a piece of cloth, rolled up in the * It ought to be noted here that priming, in its usual acceptation among painters, implies the first coat only, although here applied to many coats. Ed. 236 POLISHING. form of a ball, and the ball is moved over the surface of the colour, to polish it uniformly; to determine with precision to what degree this has been effected, the polished part is frequently washed with water. When this operation is finished, two or three coats of the colour which has been chosen are applied, the motion of the brush being softened to avoid striae; and it is then glazed with two coats of transparent and colour¬ less varnish, should this number be thought sufficient: but if the varnish itself is to be polished in the same manner as the priming; in a word, if it be required to imitate that which covers the pannels of carriages, seven or eight coats must be applied. When the last coats of the varnish form undulations which disturb the reflection of the light, it will be necessary to polish it. This last polishing may be per¬ formed with advantage, by employing tripoli, reduced to fine powder, mixed up with a little oil, and placed on a ball of serge, or, what is better, of chamois leather. The fat part may then be removed with a little bran, or with meal, rubbed over it by means of a clean linen cloth. The polishing is then completed with a bit of serge or cloth, without tripoli. It is in this manner that the varnish which supplies the place of glazing on certain kinds of furniture, and the coloured or uncoloured varnishes applied to me¬ tallic bodies or plates of metal, are polished. The latter require only uniform friction with a piece of cloth. It is very seldom that there is any need of beginning with tripoli and oil. The finest polishing is that performed by the lathe. POLISHING. 237 Those who renew the colours on the pannels and bodies of carriages, do not rub them with a piece of serge and pulverized pumice stone. They wear down the old colour to the wood, with a fragment of pumice stone and water. Some even employ a piece of felt and fine sand for this operation. This process is alone suited to work of this kind. If you wish to render the colour more drying, add half an ounce of litharge to each pound of colour. If the colour is bright, a drachm of white vitriol or sugar of lead must be substituted for the litharge. We might here, were we not circumscribed by the limits of our work, extend our views to some other branches of oil painting: such is one now in this country become a considerable object both of utility and luxury—namely, the Painting of Oiled Cloths , which are used instead of carpets for rooms, staircases, halls, and many other purposes. The same reason prevents our describing the art of printing in water colours on paper usually denominated Paper-hangings , which is at once ingenious, elegant, and useful; as is evinced by the many tasteful patterns which now deco¬ rate the dwelling houses of almost every one removed above the lowest stations in society. Although it is not within our design to lay down precepts for the per¬ formance of either of these ingenious arts, we can, nevertheless, confidently recommend our work gener¬ ally to those who practise them, assured as we are that it contains a fund of valuable information in regard to oils and colours and their combinations, by which such artists cannot fail to profit and improve. 238 POLISHING. We might here also detail some of the methods adopted for painting imitations in oil and varnish of various woods and marbles; but as this will be more ap¬ propriately described under our article House Painting, in the eighth chapter, the reader is referred to this last head, where, as well as the method of painting in water colours, called Stenciling , it will be found. CHAPTER VII. Of painting in Distemper — Glues — Sizing — Compo¬ sition of Colours for Distemper—General precepts for this branch of the art—Common Distemper — Varnished Distemper or Chipolin—Blanc de Roi or Royal White . The art of painting in distemper is much older than that of painting in oil or in varnish. It is needless to adduce any testimonies to prove this assertion, for we may assign to it the same origin as that of white wash¬ ing , which, when applied with art, is a kind of dis¬ temper. Although this kind of painting is chiefly employed in houses , and, therefore, might be with propriety arranged under our head House Painting , which will be next treated of; yet as it is occasionally employed on other subjects, we deem it most expedient to appropriate to it a distinct chapter. As in every kind of distemper Glue of some sort is the principle which gives solidity to this branch of painting, it will be useful to make some observations On the various Glues. The varnisher does not, indeed, confine the use of glue to painting in distemper : he uses it also for cover- 10 240 DISTEMPER—GLUES. ing and preserving the paint with which certain articles intended to be varnished are covered, such as paper or other substances painted in gum; boxes, fans, &c. But the kind of articles to which size is applied prescribes a choice in the matters proper for furnishing the glue. For delicate objects, pure glue, incapable of commu¬ nicating any foreign tint is required. Isinglass, or that obtained from remnants of parchment, will answer these purposes. Glovers’ clippings, and those of white leather, give a glue sufficiently pure for many kinds of distemper. The glue extracted from the clippings of sheep’s and goats’ skins may be used in the common kind of distemper. In the latter cases the work may be considerably shortened by dissolving common strong glue in a certain quantity of water. Whatever be the animal, or parts of the animal, from which it is proposed to extract the glue, that is, the gelatine , the process employed must be always the same; namely, boiling in water , and that usually for some period more or less considerable. Isinglass , being colourless, is a glue of the first qua¬ lity. The preparation of it is very simple : the twisted pieces are bruised by means of a mallet, and then torn to shreds, which are cut into small portions, and boiled in a sufficient quantity of pure water. The decoction being strained through a clean cloth, it is evaporated over a slow fire until some drops of the decoction being thrown on paper and cooled, assume the consistence of a trembling jelly. It is then left to cool. In this state it will keep five or six days in summer, and longer in winter. GLUES. 241 Sometimes brandy is employed for diluting this glue ; but as the temperature to which it is exposed dissi¬ pates all the spirit, it will be better to add brandy to isinglass, or other fish glue already prepared, and of a rather strong consistence. The addition of the brandy contributes towards its longer preservation, and acce¬ lerates its desiccation when employed, but it lessens the limpidity of the liquid. This consistence would prevent it from being freely extended over the works which are to be sized, were it not diluted, at the time of its being employed, with a little warm water. It is in the latter state of liquidity that it is applied to articles which can stand the re¬ quired degree of heat, such as wood, fans, &c. But when it is apprehended that this temperature may pro¬ duce bad effects on the colours or on the cut paper figures, for cementing which it may be employed, it is then diluted with cold water, and it is kept liquid at the temperature of the atmosphere. Certain delicate works require only a slight concen¬ tration in the solution of glue. For example, if it be re¬ quired to fix crayons, by Loriot’s process, from 150 to 200 grains of isinglass, rendered soluble in 16 ounces of pure water, diluted with two parts of spirit of wine at the time of its application, will be sufficient to give the proper degree of strength to such works, and to prevent the powder from being detached. The evapo¬ ration is very much favoured by the spirit of wine. Glue made from glovers' clippings, or from parch¬ ment, is of the second quality ; it may be obtained thus: M 242 GLUES. Put to soak in warm water, for twelve or fifteen hours, clippings of parchment, and then boil them for five or six hours: strain the whole through a piece of open linen, or through a hair sieve, to separate the insoluble membranous portions. The decoction being left at rest, will soon become a jelly: if it be made in summer, the temperature which keeps the glue long in a state of liquidity gives it time to clarify, so that the upper part will appear an exceedingly clear and colourless trem¬ bling jelly. When the clippings of parchment have been well chosen, the whole of the clear part of the glue may be separated, by means of a skimmer, from the fe¬ culent part at the bottom of the vessel. This glue may be employed in all cases where great cleanness is required, and therefore may be substituted for isinglass. It is in this state that it ought to be used for sizing, and for that beautiful kind of distem¬ per called chipolm, or blanc de roi (royal white). All objects comprehended in the distemper applied to cielings, walls, &c. do not require much nicety in the choice of the glue: hence solidity being more at¬ tended to than neatness, common glue dissolved in water is very often used Common glue may be thus prepared : take clippings of sheep’s skin, goat’s skin, and of parchment, and boil them for three or four hours in a sufficient quantity of water (seven or eight parts in weight for one of matter). When the decoction is reduced to a third, strain it through a hair sieve or piece of linen: on cooling it assumes the consistence of a strong jelly, which may be weakened according to circumstances. In conse- GLUES—SIZING. 243 quence of the consistence here mentioned, this glue is distinguished by the name of strong glue, a technical term often employed in the formulae of different compo¬ sitions, and which cannot be applied to the strong dry glue sold in the shops. The addition of two pounds of water will form a glue of moderate consistence; and eight pounds of water to the same quantity will give simply glue: it may still be rendered weaker, should circumstances require it. Such glue will not keep more than five or six days in summer, even in a cool place. If the weather be tempestuous, it will soon putrify: when it loses its con¬ sistence and becomes more liquid, it has reached the first stage of alteration, and can no longer be used in distemper. These various kinds of glue may be applied to differ¬ ent kinds of works, according to their fineness. The first is used to defend delicate painting, coloured paper, paintings in water-colours, &c. from the action of var¬ nish ; the second may be used, with the precautions al¬ ready mentioned, for the same purposes; the last is em¬ ployed for common sizing. It should be observed, that although we have given the above directions for the preparation of common glue for distemper, it is most probable that the artist will rarely, if ever, take the trouble to obtain it by that me¬ thod, but will content himself with making a solution of the common glue which he finds in the shops. Sizing Denotes that operation by which a solution of glue is M 2 244 SIZING. spread over articles intended to be painted in distemper or to be varnished. Size is applied cold : it fills up the pores of the wood, paper, &c., and deposits in them a matter impenetrable to spirit of wine and to the essen¬ tial oils, the solvents of the resins employed in the composition of varnishes. If several successive cover¬ ings of it be applied, it may even serve as a varnish it¬ self ; but being soluble in water, the least humidity, and the consequent adhesion of dust, would soon tarnish the objects to which it is applied, and destroy their neatness and brilliancy. Varnish, therefore, may be applied to this first coat without injuring the colours, and without penetrating further; and if the coats be increased so as to give to the whole a sufficient thickness, it will bear the opera¬ tion of polishing. The varnishes applied in distemper generally bring out the colours with additional lustre ; nevertheless every kind of distemper does not produce the same re¬ sult under varnish. Distemper, the basis of which is chalk, does not possess this property in its whole ex¬ tent ; it becomes brown under the first coat of varnish. This application of varnish to distemper requires then a choice in the bases, or in the colouring matters, which constitute distemper in size. Clay supports var¬ nish better than chalk; it also shrinks less; but the colours taken from metallic substances are those which, in distemper, harmonize best with the splendour of var¬ nish ; of this kind is white lead ground and mixed up with oil of turpentine for the first coat. We have here specified cases which require that size PRECEPTS FOR PAINTING IN DISTEMPER. 245 should be applied cold ; there are others which require that the jelly employed for sizing should have greater strength; that it should be thick, and consequently that it should be employed warm ; the last coat except¬ ed, which must consist of weaker glue, if intended to be covered with varnish. The substances fit to be painted in distemper are wood, walls, plaster, skins, cloth, pasteboard, paper. But, before we give examples in these three kinds of distemper, it will be proper to lay before the reader the precepts which belong to this kind of painting. General precepts for Painting in Distemper . Distemper is often employed with a view of covering it with painting which exhibits some particular subject. In this case it will be necessary, 1st, That the ground to which the distemper is to be applied should contain neither grease nor lime. 2d, That it should be covered with some preparation to render the surface very smooth. This preparation is generally made of white, because it heightens the colours better, which always borrow some¬ thing from the ground. 3d, That the consistence of the colour should be such that it may run or drop from the brush in a thread, when taken from the pot. This con¬ dition is contrary to that established in regard to paint¬ ing in oil and in varnish : here if the colour does not form a thread, it is too thick, and the work will be in danger of becoming scaly. 4th, That all the coats, the last excepted, must be applied warm, taking care, how¬ ever, that the matter does not boil: for when too hot, it injures the first coats and spoils the subject; and if M 3 246 PRECEPTS FOR PAINTING IN DISTEMPER. applied to wood it may cause it to split. -Besides, a solution of glue exposed to too high a temperature as¬ sumes a fat character, and loses its tenacity. These four conditions, according to artists, form the principal laws of this kind of painting. We shall, however, add a fifth; which is, that if the coats are to be multiplied, they ought all to be of an equal thickness. This equality depends on the strength of the glue and the quantity of the matter applied: if the coats vary in this respect the painting rises up in scales. If the ground to which the distemper is applied con¬ tain grease or lime, this inconvenience may be removed by scraping, in case it be a wall; or by a solution of pearlash, if it be wood; canvas must be cleaned by means of a ley. If the walls intended to receive any subject in paint¬ ing be very smooth, a coat of warm glue is applied? which penetrates into them and disposes the surface of the stone or plaster to incorporate with the colours. But if they are rough, a coating of Spanish white, or chalk mixed with a solution of glue, is employed to ren¬ der the surface smoother. When this coating is dry, it is scraped as clean and as even as possible. It may readily be conceived that this operation is applicable only to small inequalities : for if they were considerable or accompanied with holes, it would be necessary to equalize the surface with gypsum, and to allow the latter sufficient time to assume body, which will not be the case till it be thoroughly dry. Painting in distemper is distinguished into three COMMON DISTEMPER. 247 kinds : Common Distemper; Varnished Distemper , sometimes termed chipolin ; and Blanc de Roi, or royal white. Common Distemper. If plain distemper is to be applied to a wall or par¬ tition covered with plaster, some Spanish white or white of Troyes is thrown into water, where it may be easily broken and diluted if allowed sufficient time to soak. A little charcoal black, diluted separately in some water, is then added, to correct the too great whiteness, and to prevent it from becoming yellow. To the water mixed with white one half of a solution of strong glue in water is added, exceedingly hot, but not boiling, and it is then applied with a brush. The coatings are repeated till the tint has become uniform. This operation is simple, yet there is some difficulty in giving an uniform tone to all the parts of the work, when the surfaces to be covered are so extensive as to require repeated mixtures. One of the great incon¬ veniences of this kind of painting is, that the effect of it cannot be seen till it is dry. Care must, therefore, be taken to try each mixture on pieces of prepared wood, having the same tint as the ground, that the real tint may be obtained. It sometimes happens also, that when painting in distemper is applied to surfaces which have been already painted, the colour does not adhere, and ex¬ hibits the same phenomenon as if water were presented to oil. Of this circumstance there are two cases. The first M 4 248 COMMON DISTEMPER. is explained by the dryness of the preceding coat: an effect arising from the chalk. It rarely occurs with Spanish white, and never with white lead. The dif¬ ference in the strength of the solution of strong glue, employed for the two coats, is a second cause of this result. If the sizing of the first coat be stronger than that of the second, the only method of obviating the incon¬ venience which takes place, is the addition of a little ox-gall in the new coat. We have produced the same effect by a solution of pearlash : for if the glue be too strong, too abundant, or too much heated, it assumes an unctuous character which the chalk is not able to modify. Spanish, Bougival, or Morat white, will ensure success, in consequence of their argillaceous nature. Distemper, if intended to serve as a ground for any subjects painted in fresco or in oil colours, requires another preparation, formed of a more solid substance, wdiich may give more hold to the colours which it is to receive. White lead will answer this purpose better than Spanish white, which, however, is superior to white of Troyes. This application will remove every ' restraint in regard to the kind of painting : it may be in gum, in fine distemper, or in oil. By this attention, in regard to the choice of the matters which are to serve as the ground, the paintings with which apartments are decorated will always pro¬ duce their effect, to whatever light they may be ex¬ posed ; the greater the light, the livelier and more beautiful they appear. They participate with crayon- PAINTING IN MILK. 249 painting in the property of not being subject to those reflections of the light which prevent the beauty of a painting from being seen, except under a certain point of view. This method holds the first rank among the common kinds of distemper; but there are many cases which do not require either the same precision or very long details. In regard to those kinds of distemper employed for some particular articles in the interior part of houses, we shall give, from Watin’s work, such examples as may be useful. Painting in Milk. Take of skimmed milk, 4 pounds; lime, newly slaked, 6 ounces ; oil of poppy, linseed, or nut oil, 4 ounces; Spanish white, 3 pounds. Put the lime into an earthen vessel, or into a clean bucket, and having poured over it a sufficient quantity of milk, add gradually the oil, stirring the mixture with a wooden spatula; then pour in the remainder of the milk, and dilute the Spanish white. Milk skimmed in summer is often found to be curdled; but this is of no consequence for the present purpose. The contact of the lime soon restores its fluidity; but it must not be sour, because in that case it would form with the lime an earthy salt, which at¬ tracts the humidity of the atmosphere. The lime may be slaked by immersing it a short time in water, from which it is taken, that it may effloresce in the air. M 5 250 PAINTING IN MILK. Any of the above-mentioned oils may be employed ; but, for a white colour, that of poppy ought to be pre¬ ferred. The mixture of the oil with the lime forms a kind of calcareous soap, in which state the oil unites with the whole of the ingredients. The Spanish white is pounded and carefully strewed over the surface of the liquid with which it gradually becomes impregnated, and falls to the bottom. This process is applicable to every kind of distemper made with chalk, or with white argillaceous earths. When the white has fallen to the bottom, it is stirred with a stick. This painting may be coloured, like every other in distemper, by means of the different colouring sub¬ stances employed in common painting. The above quantity will be sufficient to give a first coat to a sur¬ face of 24 square yards. No doubt can remain in regard to the superiority of this kind of painting when compared with the results of distemper with size. It is stronger, and does not, like the latter, detach itself in scales. The albumen which composes it is not susceptible of decomposition, like glue, which gives body to common distemper. The latter, unless kept dry, becoming often decomposed by the attraction of humidity from the atmosphere, and hence the colouring body is readily brushed off in the form of dust. Besides, this preparation is less expensive, and par¬ ticularly in countries where milk is abundant. It is also attended with less trouble; it dries in an hour, and the oil which forms part of it loses its odour in passing to the saponaceous state by its combination with the lime. PAINTING FOR FIRE-PLACES. 251 One coat will be sufficient for places which are already covered with any colour, if the latter does not penetrate through it, and produce spots; two coats on new wood; one on staircases and on cielings. Painting for Fire-places and Hearths in Kitchens , fyc. The Genevese method. The Genevese employ a kind of stone, known under the name of molasse, for constructing fire-places and stoves ; it is brought from Saura, a village of Savoy : it has a greyish colour, inclining to blue, which is very agreeable to the eye. This tint is similar to that com¬ municated to common whitewashing with lime, chalk, or gypsum, the dulness of which is corrected by a little indigo, or by lamp black. Pure clay, similar in colour to molasse , is found at Yvoire: it is employed by the servant maids to scour out or conceal the spots of grease or of charcoal which stain hearths or chimney-pieces. They keep by them some of this clay mixed up with a little water, and apply it with a brush after the stains have been rubbed with a fragment of the same stone. This is a kind of plain distemper without size. Some whitewashers employ this clay in their dis¬ temper for articles much exposed to be dirtied; such as kitchens, workshops, &c. They treat it with a solu¬ tion of glue, as in the first example. The tone of its colour, which is always uniform, presents one ad¬ vantage not found in artificial mixtures, the true tone of which cannot be known till the coat is dry. Clay of a grey colour being very common, it may be M 6 252 DISTEMPER FOR PARQUETS. of great use in families who wish to imitate this part of the cleanliness of the Swiss. The advantage they might derive from it would not be confined merely to the gratification of the eye. The first step towards an improvement in the convenience of domestic life, soon leads to attempts towards other objects ; and it is in this manner that people, without any direct design, and even without perceiving it, remove from their habi¬ tations every thing that might alter the salubrity of them. The beneficial effects which result from conti¬ nued care, in regard to every thing that tends to pro¬ mote cleanliness, are too apparent not to be observed and to be justly appreciated. Diseases which become epidemical, and which often occasion great ravages^ seldom appear with the same malignant characters where cleanliness prevails. Cleanliness, therefore, minute attention to cleanliness, both of furniture and persons, together with sobriety, is the best preserver of health. This observation is not foreign to a subject which treats on the best method of giving elegant sim¬ plicity to the interior of houses. Distemper for Parquets or Floors of Inlaid Work. The name of parquets is given to boards of fir inter¬ sected by pieces of walnut-tree; or disposed in com¬ partments, of which the walnut-tree forms the frame or border; but to such works no other lustre is commu¬ nicated than that which they receive from wax, and from being frequently cleaned. Some of the floors in France, and other countries on the Continent, are con¬ structed in this manner. Floors have been also occa- RED FOR HALLS PAVED WITH TILES. 253 sionally executed of plaster, on which the lemon yellow colour employed for parquets of oak, produces a very good effect. To obtain this colour, boil in 16 pounds of water half a pound of yellow berries, and as much turmeric root and bastard saffron; add to the mixture four ounces of alum, or pearlash which is preferable ; and having strained the whole through a silk sieve, add to the strained liquor four pounds of w ater, in which a pound of glue has been dissolved. Apply two coats of this colour with a brush, and when dry wax it, and polish the surface with a rubber. Red for Corridors and Halls paved with Tiles. A brush dipped in the water which comes from a common ley, or in soapy water, or in water holding in solution a twentieth part of pearlash, is in general drawm over the tiles. This washing thoroughly cleans them, carries off the greasy spots, and disposes all the parts of the pavement to receive the distemper. They are then left to dry. On the other hand, dissolve in eight pounds of w T ater half a pound of glue, and while the mixture is boiling, add two pounds of red ochre, mixing the whole with great care. Then apply a coat of this mixture to the pavement, and suffer it to dry. A second coat is ap¬ plied with Prussian red, mixed up wdth drying linseed oil; and a third with the same red, mixed up with size. When the whole is dry, rub it with wax. Such is the method generally employed; and this succession of coats is attended with peculiar ad- 254 DISTEMPER IN BADIGEON. vantages. The first ley, penetrating into the tiles, forms a ground of adhesion to the second; and the last receives from the second a great deal of solidity, and prevents the slowness of the desiccation of the coat with oil, which would adhere to the feet or be rubbed off by the scrubber, were it not entirely dry. The third coat may be dispensed with, if pulverized litharge be mixed with the colour, which will then become more drying. The operation may be very much shortened by red¬ dening the new tiles with a preparation composed of the serous and colouring parts of ox blood, separated in the slaughter-house from the fibrous part. This pre¬ paration is exceedingly strong. If a single coat of red bole, mixed up with drying linseed oil, be then applied, it may soon after be waxed and rubbed. This appli¬ cation is solid, costs less than the former, and the colour is very permanent. A very beautiful red colour is also communicated with a solution consisting of a pound of madder coarsely pulverized, four ounces of alum, and twelve pounds of water. Two coats of it are applied to new r tiles, after which it is waxed and rubbed. This application produces a very fine effect; but it is not so durable as the preceding. Distemper in Badigeon. Badigeon is employed for giving an uniform tint to houses rendered brown by time, and to churches when it is required to render them brighter. Badigeon , in general, has a yellow tint. That which succeeds best CHIPOLIN. 255 is composed of the saw-dust or powder of the same kind of stone and slaked lime, mixed up in a bucket of water holding in solution a pound of alum. It is ap¬ plied with a brush. In and around Paris, and in other parts of France, where the large edifices are constructed of a soft kind of stone, which is yellow, and sometimes white, when it comes from the quarry, but which in time becomes brown, a little ochre de rue is substituted for the powder of the stone itself, and restores to the edifice its original tint. But at Geneva and Lausanne, and in the neighbouring cities, where buildings are constructed of molasse , the tint given by ochre de rue would be dif¬ ferent from that intended. The late Lagrange, of Ge¬ neva, invented a method, both simple and effectual, of giving to old edifices a new appearance, and of reviving their original tint: it is adapted to the nature of the stone. Nothing is necessary, but to rub the surface of the edifice with pieces of the same molasse , taking care to select the hardest: by this process the stone will acquire its former colour. Varnished Distemper or Chipolin. Painting in distemper covered with a varnish called chipolin *, and royal white, which will furnish an example of the third kind of distemper, is the most * The origin of the word Chipolin is uncertain. Some think it is de¬ rived from the resemblance between this painting and cipolin or chipolin marble. Others have supposed it originated in the use which the first painters in this branch made of the juice of onions. 256 CHIPOLIN. elegant of this sort; but the preparation it requires renders it very expensive. It is to chipolin that we are indebted for those brilliant decorations in varnish ap¬ plied to candelabra with delicate sculpture, the argen¬ tine white of which, set off with pale gold, produces such beautiful effects by reflected light; but this truly noble kind of painting, in consequence of the great labour it requires, is reserved for valuable furniture, and for ornamenting apartments in palaces. Though this kind of painting is not frequently em¬ ployed, we shall give a short account of the process, as described by Watin in his Parfait Vernisseur. The following is the order adopted in the distribution of the labour for argentine white chipolin. In regard to further details, the reader must recur to the work above mentioned,: 1st. Wash the wainscoting with a warm decoction of wormwood, to which a few heads of garlic are added. Mix this decoction with parchment glue, which, when cold, assumes the form of a jelly. This process opens the pores of the wood, and disposes it to afford the means of adhesion to the following coats. 2d. A coat of warm glue with Bougival Spanish or Morat white, which will give the work more solidity. 3d. Eight or ten coats of the same white, well mixed and exceedingly fine ; taking care to preserve the same degree of strength, and the same thickness in each coat. But care must be taken, at the same time, not to choak up the mouldings, and to apply the last coat CHIPOLIN. 257 with glue somewhat thinner than that used in the pre¬ ceding coats. 4th. Soften the surface with pumice stone, to which such a form has been given that it can be introduced into the small cavities of the mouldings and sculpture. Employ small sticks of different shapes to polish the mouldings and the plain surfaces. The process of polishing may be shortened by drawing immediately over the work a soft brush dipped in water. 5th. Clean the cavities of the mouldings and sculp¬ ture with small iron instruments prepared for that purpose. 6th. After these preparations apply two coats of colour made of white lead, to which a little Prussian blue and black has been added, and mixed up with parchment size, strained through a sieve to separate the portions of size still granulated; these two coats must be softened with a brush. 7th. Apply two other coats of thin glue, beaten up cold, and strained through a sieve, to separate the por¬ tions of jelly not diluted. They are applied cold, care¬ fully softening the work, that there may be no need of passing several times over the same place. 8th. Apply, with the same precautions, two or three coats of the varnish No. III. or with some copal varnish, and keep the place warm, to facilitate evaporation and desiccation before the dust can adhere to it: the work will then be completed. Such is the process for this pre¬ paration, which requires eighteen or nineteen coats, and a great deal of care in the execution. It is needless to remind artists of the principle already laid down, that 258 IMITATION OF CHIPOLIN. a new coat must not be applied till the preceding be dry . When the chipolin is intended for pieces of sculpture, it is customary to heighten its splendour by that of gold, which is applied and left unbumished on all the projecting parts of the work. This addition in¬ creases in a singular manner the richness and magni¬ ficence of this kind of decoration. The following method of imitating chipolin is much shorter than the former, it enabling artists to complete the operation in twenty-four hours. Imitation of Chipolin. Watin prescribes two coats of size made of Spanish white, mixed up with strong parchment glue, hot, and even boiling. But observe, the application of size so hot swells the wood and retards the desiccation; oak wainscoting is, however, less liable to swell than fir. We should apply the first two coats in this case with white lead of the first quality: the tint is solid, and brings out the coloured coats equally well. They ought to be applied with oil of turpentine. Over these two coats we would apply two others of colour mixed up with pretty strong glue, kept liquid, and would polish after the first coloured coats. These ought to be covered with two coats of spirit of varnish, or the varnish No. III. or the colour should be mixed up with the varnish. The drying is quickened by keeping a fire in the apartment which has been varnished, if the season be unfavourable. When the second coat is dry, rub it with pumice IMITATION OF CHIPOLIN. 259 stone to equalize and smooth the surface, and apply i three coats of colour. If an azury grey white be re¬ quired, mix with great care on a slab one ounce of white lead, one drachm of lamp black, and as much Prussian blue. Take a portion of this mixture, and grind it slightly on the stone with the white lead which is to compose the colour, adding the latter gradually, that the ingredients may be better mixed. Sift the whole through a silk sieve to complete the mixture. Then add four ounces of this preparation to a pound of varnish, and mix them with a brush. The varnish proper for this purpose is No. VIII. It will be proper not to mix up more matter at a time, because the var¬ nish evaporates. Spread it in as uniform a manner as possible, and when the coat is dry, rub it with a strong new piece of linen cloth to polish it. This friction, which at first requires considerable care, completes the drying of the varnish and glazes it. For the second coat take only one half of the powder, and mix it up with the same quantity of varnish as for the first; and for the third only half an ounce of powder. If you are desirous of giving lustre to the work you must add a fourth coat, not more charged with colour than the third. Then rub the surface with a cloth, to give it that splendour which always results from a perfect uni¬ formity in the extension of the varnish. This is the method which we have always employed in painting in distemper, and we recommend it for colours of every kind applied to wainscoting of white wood, which is very liable to swell under size of 260 ROYAL WHITE. every kind, and which renders the first preparation scaly. Blanc de Roi, or Royal White. This kind of distemper takes its name from the use made of it in decorating the interior of palaces. It is very much employed, and is easily executed, when not intended to be covered with varnish : wdien fresh it is - exceedingly beautiful. It is attended with the fault of becoming soon spoiled in apartments constantly inha¬ bited, and particularly in bed-rooms, because, not being defended by varnish, the exhalations and other vapours which emanate from living bodies act on the white lead, and make it first turn yellow and then black. It is employed chiefly for saloons, where the mouldings and carving have been ornamented with gold, the pale¬ ness of which is richly set off by the splendour of the colour. It is not customary to varnish white grounds when accompanied with gilding and beautiful orna¬ ments. In painting royal white, it will be proper to form the ground with a coat of Spanish white, or white of Mo- rat, mixed up with strong parchment size, and applied boiling hot; paying attention, however, to the nature of the wood, as already remarked. It requires the same operations as chipolin ; but private individuals gene¬ rally dispense with this nicety of execution, which would require a long time, and occasion a very great expense. To render it very beautiful, the insipidity of the white ROYAL WHITE. 261 1 lead should be corrected with a small quantity of Prus¬ sian blue or of indigo, in the same proportion nearly as for pearl grey chipolin. Polishing with a cloth pro¬ duces a very good effect; but the beautiful reflection of ! the light depends as much on the manner in which the last coats are applied as on the polishing which com¬ pletes the smoothing of the surface. In Switzerland, people are contented with the simple i composition of royal white, heightening its dulness with a little Prussian blue and black. This kind of painting is reserved, in particular, for the upper apartments of i country houses. Its solidity renders it superior to that with white of Troyes. But if white lead be used, it should be varnished for the reasons above stated. The splendour given by this addition, and the easy means it affords of guarding against the pernicious effects of dust, are real advantages which counterbalance the expense. Although this preparation seems attended with no insurmountable difficulty, even to the amateur, it re¬ quires in the artist who undertakes it good taste, care, and practice. Royal white, indeed, is not always pre¬ pared with that care and attention which render it va¬ luable. A skilful eye is often shocked to see the out¬ lines of well executed wainscoting disappear under the unequal and too thick daubing of the coats, in which eyen white of Troyes is often substituted for white lead. As this deception is frequently practised, people ought to be on their guard against it. The employer, who has a double interest to defend, may put the honesty of the artist to the test by a very simple experiment. mz ROYAL WHITE. Place on charcoal a small quantity of the white matter which is stated to be white lead; if it be chalk, it will become brown when you blow the charcoal; but if it be white lead, it becomes yellow, changes to a red colour, and is soon reduced to lead. This revivifica¬ tion of the lead is speedier when the fire is urged by a blow-pipe. CHAPTER VIII. House Painting. General observations on House Painting—on Brushes —on the method of rendering ground White Lead and other Paints ready for application—on Driers —on Oil of Turpentine—Mementos for the House Painter — Vanherman's Impenetrable Paint — on Stenciling—on the Imitation of various Woods and Marbles in Paint , called Graining—Transparent Blinds. — Addendum , Ultramarine. Although we have not in any one of the preceding chapters of this work, omitted, upon every proper opportunity, to introduce such observations as may be useful, not only to the professed artist, but also to the amateur in house painting , as well as to those who, desirous of avoiding expense, become their own house painters; and although we here give a chapter which treats professedly on house painting, yet we desire emphatically to impress upon the reader the absolute necessity, in order to his becoming an adroit house painter, that every preceding chapter of this work should be most carefully read and even studied. In the present chapter, if the professed artist should , 8 264 HOUSE PAINTING. not obtain much additional instruction or information, there is nevertheless a large body of persons who know little or even nothing of the art of painting, and who will, it has been suggested to us, gladly avail them¬ selves of the knowledge which this chapter is more especially designed to convey. In short, we may re¬ peat a question which has been stated to us, namely, What is the best method which a gentleman or any other person desirous of becoming his own house painter , but totally ignorant of paint and painting , can pursue , to prepare and to lay on the paint ? To the solution of this question we shall at once proceed. In the first place, then, it should never be forgotten that the best time for painting is in dry, warm, and airy weather; that although out-door work cannot be done at all in wet weather, yet that in-door work dries in wet weather much more slowly than in dry; and, therefore, for both kinds, the same dry and airy w'eather is to be preferred: we say airy , because, when in dry weather, there is a strong current of air passing, then the effluvia of the paint will be the soonest car¬ ried off, and the least injury done to the health of those who are engaged in, generally, such an unwholesome occupation as that of painting, particularly when lead enters into the composition of the paint. When the weather cannot be chosen; and more especially when in-door painting is to be done in wet weather, a good wood fire, kept in a newly painted room, will be of advantage to it: we say wood, because the smoke of wood is less injurious to white and other light coloured paints than that of coal. Fire at all HOUSE PAINTING. 265 times promotes a change and circulation of the air. The painter ought not, on any account, to paint a room which has a chimney board before the fire-place. In regard to the tools and implements necessary for preparing paint, we have described those in chapter VI., to which the reader will, of course, refer. We may, however, state here relative to the brushes , that all those which are employed in oil painting should, immediately after they have been used, be immersed in a pan of water, so that the water may cover entirely the hairs of the brush. And, in regard to white in par¬ ticular, it is most desirable that a set of brushes should be kept for this colour only; as, if not so kept, con¬ siderable trouble will be necessary to free a brush used for coloured paint from its colouring matter. Brushes may also, to preserve them pliant, and in a fit state for use, be immersed in oil; but the colouring matter with which they might be tinged will mix with the oil; oil is therefore not so proper a liquid in which to keep brushes used for different coloured paints as water. The immersion of brushes either in water or in oil is absolutely necessary ; as, in a few hours, when exposed to the air, the hairs will become so dried together, as often to be totally spoiled ; and in other cases not again in a state to be used without the application of consi¬ derable labour. When brushes should be wanted for white in par¬ ticular, and none is at hand, except those which have been employed in some coloured paints, they may be generally freed from the colour by washing them in oil of turpentine; or warm soap and water. Of course N 266 HOUSE PAINTING. before they are subjected to washing, they should be well rubbed upon some rough place to discharge the chief part of the paint which is upon them. New brushes do not, in general, answer for painting so well as those which have been for some time used: the hairs, by use, becoming finer in the points, and more suited to the laying on of the paints in an equable and smooth manner. Hence two kinds of brushes for common painting are found in the shops : one con¬ sisting of coarse hairs, and only suited, while new, for coarse purposes ; the other is known under the name ol ground tools , and consists of white and fine hair. But the common painting brushes become, by use, much finer. It is scarcely necessary to say that sash tools , that is, brushes for painting window frames and beading in particular, should be kept of different sizes to suit the different sized bars of the windows, beads, &c. It ought also to be particularly impressed upon the house painter, that especial care should be taken to brush, or otherwise clear from dust, every thing which is to be painted, previously to the laying on of the paint. For this purpose new brushes answer very well, and for which they are often used by painters ; and by such means are rendered more fit for being afterwards used as painting brushes. It will be seen by the preceding parts of our work, and more especially in chapter II. page 50, that white lead , notwithstanding many other whites have been recommended, is still the staple commodity of the house painter*. It maybe ground in oil, according to * We ought perhaps to notice here some observations of Vanherman, HOUSE PAINTING. 267 the directions given for grinding paint generally, in page 215; but few persons will, we presume, be dis¬ posed to submit to the trouble of grinding it in oil, seeing that it can be so readily obtained of the colourman. The only reason which would induce a person to grind it himself is, that he will be more certain of having it unadulterated: fpr that it is sometimes adulterated with some of the white carbonates, chalk principally, is unfortunately too true. But, how r ever, this being waived, if a large quantity of ground white lead should be wanted, it should be purchased in a cask. Casks of white lead are kept ready for sale at the colourman’s, of different sizes, and, of course, different weights, and we may add too of many different qualities: Lon¬ don white lead is generally preferred. in his work, to which we have before more than once referred. Under the head of impenetrable or anti-corrosive paint, speaking of the many mixtures employed for the purpose of defending work from the weather, and after condemning coal and other tar paints, he says, that white lead is not a much better protection, it destroying the binding quality of the oil by robbing it of its oxygen, and in less than twelve months it may be rubbed off the work like dry whiting. He goes on to say, that many gentlemen accuse their painters of adulterating the articles with whiting; but he adds, “this is not the case, for the purer the lead the more it is jnclined to this fault, and the greater the sophistication the more durable will it prove.” If this be true, the discovery is a very notable one, and worthy of every attention; but if the principles already laid down in this work, and the general expe¬ rience of mankind can be relied on, this writer must be in error. We do not expect to find every painter a chemist; but we think it behoves all writers to weigh well their statements before they make them public. We recommend, however, the curious to read Mr. Vanherman’s work : for al¬ though we are obliged to differ from him on this subject, it contains many others well worthy of attention. HOUSE PAINTING. 268 Before the head of the cask is taken out, which it must be, of course, by loosening the hoops of one end, a tolerably long nail should be driven into the middle of the head intended to be taken out, so that the nail, when the head is loosened, may be used as a sort of handle to it. The head being removed, the hoops are now to be driven dow r n over the cask, as tight as they were before the head was removed, and all the lead ad¬ hering to the removed head must be carefully scraped off and put into the cask, for which the head will now form a convenient cover. If some of the ground lead should be immediately wanted, it may be taken out into a proper sized pan, always remembering that the lead in the pan should not fill more than one-fourth or one- fifth of its space, in order that room may be given for the addition of oil, &c. and for the convenience of mix¬ ing. The lead remaining in the cask should always be kept covered an inch deep or more with clean water: without this precaution a thick skin will soon form upon it, and thus, much of the lead will be wasted. Care should also be taken, every time that lead is taken out of the cask, to scrape down the lead adhering to the sides of it beneath the water: for if this be omitted, much waste will necessarily occur. Having thus the grouild white lead in a pan, we are now to proceed to mix it with oil, &c. so as to render it in a suitable state for being used as paint. The quantity of oil necessary for this purpose will depend upon the purpose for which the paint is designed. If it be intended as a priming , that is, a first coat on new wood, it may be mixed considerably thinner than when HOUSE PAINTING. 269 it is designed for a second or a third coat. In general, it will be found that from twelve to sixteen ounces by measure of oil are required for one pound of ground white lead.. It may be also stated here, that although, for persons who do not regard the expense, nut oil or even poppy oil may be employed, yet as linseed oil is always much cheaper than either of these, notwithstanding its smell is, for some time after it is laid on, much more offensive, it is now most commonly employed in almost all house painting where an expressed oil is required. In mixing the ground lead with the oil, some atten¬ tion is necessary: for the whole quantity of oil which is designed to be used must not be poured upon the ground lead at once, as thus doing would give the operator much more trouble: it should be mixed by the addition of small quantities of oil at a time, and thus the paint becomes most readily and easily com¬ bined with the oil into a smooth and pappy mass. Having mixed the oil and lead of a suitable consistence for painting, it will now be necessary to add a drier to it; for this purpose sugar of lead ground in oil must be added in the proportion of about half an ounce to a pound of the paint. But for a first coat, and where expedition is not necessary, the drier may be omitted; or litharge for the first coat may be added, instead of sugar of lead : we mention litharge, because it is much cheaper than the last mentioned article. But in the finishing coats of white lead paint, when delicacy of colour is of importance, sugar of lead is to be preferred. Before applying the first coat to new work, care must be taken to size the knots , as mentioned in page 153 ; N 3 270 HOUSE PAINTING. and also to stop the holes in the wood, if any, with putty , the preparation of which is described in page 182. The first coat, which may be either composed of ground white lead and oil, or of ground white lead, oil, and a slight dose of lamp black or ivory black, to impart a tinge approaching to a light lead colour*, may be laid on with a common painting brush; but the finishing coat should be laid on with the brushes com¬ monly called ground tools ; and the paint should be of a consistence sufficiently thick so as to work easily be¬ neath the brush, yet not, when it is laid on, to run down; a proof this of its being too thin. It is also most usual with painters to mix a certain portion, one or two ounces, of oil of turpentine with each pound of the paint, which enables the painter to use it thinner, and with more expedition than he otherwise could. The chief, if not all, of the oil of turpentine soon eva¬ porates from the paint, and leaves it of greater body than without the addition of the oil of turpentine it would otherwise be. However, by a person who has patience and time, good white painting may be accom¬ plished, in dry warm weather, without the least addi¬ tion of oil of turpentine. Besides the addition of the drier and oil of turpen¬ tine to white lead paint, it will be sometimes found very useful to add to it a small quantity of ground Prussian blue, to impart to it a very slight blue tinge, which in * Although first coats are usually given with white lead, yet sometimes, where dark colours are the finishing colours, the first coats are given with some dull red, or other dull-colour ; even Spanish brown is occasionally used, being a cheap paint. HOUSE PAINTING. 271 crowded and smoky towns, London in particular, with¬ out such addition, soon becomes of a dingy yellow; and indeed, even with the Prussian blue, too soon be¬ comes discoloured ; although it is believed that artists will not encourage the use of this pigment in white paint any where—their cupidity being more imperative than their science. It should not be forgotten that the more oil of turpen¬ tine is used in a paint, the less gloss will there inva¬ riably be upon it; so that when white lead is ground wholly in oil of turpentine, such paint is entirely with¬ out gloss, and well known under the name of dead ivhite : it is an expensive colour, and we do not there¬ fore recommend it; many persons, notwithstanding, prefer such deadened colours. On the other hand, if a white paint be desired of more than ordinary brilliancy, recourse must be had to some of the varnishes to mix with the ground white lead instead of oil: several of these may be employed, but No. V. page 176, will answer the purpose very well; or the boiled oil mentioned page 157, may be employed instead of common linseed oil. The operator should be, however, aware, that in preserving as much as possible the delicate whiteness of the paint, oil or varnish ought to be used which contains the least quantity of colour¬ ing matter: for, do what we will, a yellow tinge will fre¬ quently be imparted. He will therefore most probably find it a better,although perhaps a more expensive course, to varnish the paint after it is dry, with some colourless spirit varnish, such as Nos. VI. and VII. in pages 176, 177. In regard to the vehicles used for paints, notwith- N 4 272 HOUSE PAINTING. standing what we have said of oil of turpentine above, we believe it is nevertheless incontrovertibly true that the colours of oil paints are less injured generally by this oil than by any other vehicle with which we are acquainted. But it ought also be remembered by the house painter, as it is sometimes desirable that painting should be washed , that paint will undergo the opera¬ tion of washing best, which is protected by a tenacious varnish, or which has a considerable portion of oil in its composition : it is obvious that the dead white paint of oil of turpentine, or indeed any paint into which oil of turpentine, as a vehicle, largely enters, cannot endure the operation of washing without having a portion of its substance rubbed off. And if such effects have occurred to paints as mentioned by Van- herman, and to which we have alluded in the last note, it is probable, particularly in regard to white lead, that they occurred from the use of too much oil of turpentine : for, as far as we know, oil of turpentine does not chemically combine with lead as the fixed oils do. It is true that when the coat of painting is very thick , sometimes rubbing off the external surface of it, by washing with soap and water, and even perhaps with a small portion of fine sand, when the vehicle of the paint has been chiefly oil of turpentine, will im¬ prove its whiteness ; so that in this respect such paint¬ ing has an advantage. But such washing requires more discretion than is usually possessed by domestic servants. We might now proceed through the whole range of HOUSE PAINTING. 273 colours, both in oil and in distemper, which are com¬ monly used in house painting; but having been thus minute on the mixing and application of white lead, we presume that the simplest capacity will find little if any difficulty in applying our directions to the mixing and using of any other colour. Whether the private gentleman will be disposed to grind his colours himself, or at least have them ground under his own inspection, will depend upon a variety of circumstances. There can be no doubt that the purest colours will be obtained by domestic manipula¬ tion ; yet as ground yellow ochre, Spanish brown, Vene¬ tian red, and some other colours, can be obtained at the colour shops of good quality, such he will most probably purchase already ground in oil. But the finer colours, such as vermilion, verdigris, &c. he will find it best to levigate with oil at home. We have before mentioned the probability of ground white lead being adulterated; and, therefore, if a pure article be desired, that also should be ground at home; but it is a poisonous article, and should be handled with much caution. See page 50. Concerning the driers for dark colours, such as chocolate, olive, yellow, blue, brown, &c. &c. it should be mentioned that, in all these and many others into which none of the oxides of lead enter as a com¬ ponent part, litharge or white vitriol is commonly pre¬ ferred as a drier to sugar of lead. It should be noted too that the ochres, and indeed all earthy paints, re¬ quire more driers than those which are composed of metallic oxides. The quantity of either of the pre- N 5 274 HOUSE PAINTING. ceding driers needs not to exceed, on common occa¬ sions, half an ounce' for each pound of paint. But sometimes, where great expedition in drying is wanted, double the quantity mentioned, or even more, might be employed. See page 161. The common lamp black of the shops, which is often used when mixed with some of the reds, such as Ve¬ netian red, or Spanish brown for chocolate, is peculiarly troublesome, and requires much drying matter; it would be always best to subject the lamp black to the operation of burning, as mentioned under that article, before employing it, and thus get rid of its greasy pro¬ perties. Oil of turpentine may be also used in those paints as well as sometimes turpentine or other varnish, where varnish in a paint might be desired. It is scarcely necessary to add, that whatever drier is used, it should be previously well ground in oil or varnish, so that it may become intimately mixed with the paint. It may also be useful here, as a memento to the house painter, to recapitulate, in regard to colours generally, what has been before either directly or indi¬ rectly stated in this work, premising that the fifth chapter concerning the composition of colours is par¬ ticularly deserving the attention of the house painter. That the best white for oil painting is white lead; that common linseed oil, or, upon particular occasions, boiled linseed oil, is the most convenient vehicle for paints; that various shades of grey and lead colour are made by an admixture of white lead and some of the blacks—lamp black or ivory black. HOUSE PAINTING. 275 That innumerable shades of blue may be obtained by a mixture of white lead and Prussian blue. That green of the finest kind is to be obtained from verdigris; but that the inferior greens may be pro¬ duced by a mixture of the yellows from ochres, &c. with Prussian and other blues. That chocolate may be obtained from some of* the reds, such as Venetian red, Spanish brown, &c. with an admixture of black, such as lamp black or ivory black. That yellows are from ochres, patent yellow, Chrome yellow, &c. That reds are from vermilion, red lead, Venetian red, &c. That good broivns may be obtained from the umbers ; that they may be also made artificially from reds, yel¬ lows and blacks. That pompadour is from the purple oxide of iron, commonly called purple brown. That the colour of various stones may be imitated by white lead with black; by white lead with slight tinges of ochre, &c. &c. That out door work may be a chocolate composed of Spanish brown and lamp black, or Spanish brown and road dust, equal parts for red mixed with Vanherman's incorporated oil. See forwards. A white composed only of white lead and linseed, oil with a proper portion of sugar of lead ; or a green consisting of yellow ochre and Prussian blue; or, if expense be not an object, of ground verdigris with a suitable portion of white lead. N 6 ‘ 276 HOUSE PAINTING-, That for coarse paling, and where colour is of no consequence, coal tar is a useful paint; it should be laid on in warm weather and in two coats. If a more agreeable colour than itself be desired, powdered Spanish brown or a mixture of yellow ochre and pow¬ dered blue may be added to it. Concerning colours in distemper , after what has been said in the last chapter, which treats specifically of this branch of painting, it is not necessary to say much ; yet we may observe that the house painter will find in the second chapter, particularly under prepara¬ tions of copper , many facts and observations in which he will be greatly interested. We may observe also that quick lime, from compact limestone, when colour¬ less, is beyond question the most brilliant white¬ washing material; and as a valuable purifier, should be often employed, particularly in the crowded houses, of a populous city. On one branch of distemper , Stenciling, we shall, in the next section of this chapter, make a few observations. We ought not, perhaps, to quit this part of our sub¬ ject, without some notice of a paint to which Mr. Van- herman, in his work so often referred to, has ascribed so much value and importance, under the name of impenetrable or anti-corrosive paint. While we admit that the paints which he recommends under this title are of some value, we can by no means subscribe to all the eulogies which he has been pleased to pronounce concerning them. PAINT FOR PALES—INCORPORATED OIL. 277 The application of road dust , called by Vanlierman Crotia, as a basis for paint, is not very novel; we used it in Somersetshire more than twenty years ago, in the following manner, for paling. A cheap Paint for Pales , Gates , fyc. Take of road dust sifted fine, and whiting, of each four pounds and a half; blue black, and queen’s blue of each one pound and a half; of yellow ochre two pounds. All these must be pulverized very fine , to which is to be added boiling water sufficient to make the whole into a stiff paste, add to it a sufficient quantity of linseed oil bottoms, to make it of the con¬ sistence of a pap. Lay it on with a hard brush. For want of the oil bottoms, linseed oil itself may be used, but it will be, of course, more expensive. Vanherman, whose processes, we must admit, are decided improvements on the preceding, gives, in his work, various forms for invisible green , stone colour , lead colour , &c. See. but the basis of all is crotia , road dust, mixed with different colouring ingredients, to pro¬ duce. the various colours; we can do no more than give this short notice of them; those interested will, of course, consult that Gentleman’s work, in which they will also find a form for what he calls an Incorporated Oil , Consisting of linseed oil twelve parts, of boiled linseed oil one part, and of sulphate of lime* three parts. * The method of preparing Vanherman’s Artificial Sulphate of Lime is described in page 48. 278 STENCILING. These he directs to be placed in a horizontal chum, which is to be roused and whirled about for a quarter of an hour, when the union will be found complete. The proportion of this oil with any of his impene¬ trable paints is one gallon to seven pounds of the powder, or one pint to a pound. On Stenciling. The term stenciling appears to be derived, or cor¬ rupted from the verb to stain del. It has been some time in use among the painters of paper hangings , with w r hom three modes of painting their paper have been adopted. The first is effected by printing on the colours; the second by using the stencil; and the third by laying them on with a pencil, as in other kinds of paintings. Of course, all these are in distemper or water colours. Sometimes, however, varnish is used for the purpose of preparing what is called flock paper. When the colours are laid on by printing, the impres¬ sion is made by engraved blocks of wood, so that the figure to be expressed is made to project from the sur¬ face, and being charged with the colouring matter, properly prepared, imparts by pressure on the paper the colour which is desired: there are as many separate blocks as there are colours to be printed. Penciling is only used in the nicer kinds of work, and is performed in the same manner as other paintings in water or varnish. Stenciling of paper hangings is thus performed : the figure designed to be painted is cut out in a piece of leather or oil-cloth, (such piece of leather or oil-cloth is o STENCILING. 279 called a stencil) ; this being laid on the sheet of paper to be printed, is to be rubbed over with the colour pro¬ perly tempered by means of a large brush; the colour is, of course, only applied to those parts of the paper where the cloth or leather is cut away. Here, as well as in the block printing for paper-hangings, every colour designed to be applied must have a separate stencil or pattern. Latterly the term stenciling has been applied to a kind of painting, now grown somewhat common, by which an imitation of paper hangings is made by stenciling the colours at once on the naked wall, or with a wall previously covered with plain paper. The wall is first covered with the ground desired, and the several colours are laid on at different intervals after each has respectively become dry. The patterns for such stenciling are commonly cut in pasteboard; the most convenient size is about twelye or fifteen inches square, so that the pattern may be easily em¬ ployed by one person only. Great care must be taken that the edges of the pattern, on every removal, cor¬ respond exactly. Here also every colour must have a distinct pattern. In the preparation of the colours for all sorts of paper hangings and their imitations, stencil, great care and nicety are required. The principal difficulty in stenciling by the untaught house painter, will be the obtaining of his patterns ; if, however, he have any taste for drawing, this may be soon obviated; and we do not doubt that an ingenious person may, with attention and care, produce stencil paintings, with four or even more colours, which may 230 GRAINING. compete with many printed paper hangings. Of course he must have border patterns, as well as those for the body of his work. It is scarcely necessary to add, that all the pigments which may be levigated or mixed with water, can be used in stenciling; and that a suitable portion of size , or in other cases, gum water , must be mixed with the colours, to fix them permanently on the walls so that they may not be rubbed off. The proper consistence of the paint when applied will be soon learnt by the operator himself; it should be so thick as not, of course, to run on the paper or wall when laid on, yet suffi¬ ciently thin to be worked easily with the brush. On the Imitation of various Woods and Marbles called Graining. We have in Chapter V. on the composition of co¬ lours , given some general observations in regard to graining , as it is called by some, by others reining , as being more particularly designed to imitate the veins in wood and other substances; but as it is a kind of painting now become very common in houses , and withal a very pleasing and useful part of this branch of painting, we have deemed it proper to enter here a little more at large concerning it. * As a preliminary we may observe that we perfectly agree with the remarks of a late writer *, namely, that * The Decoration Painters’ and Glaziers’ Guide, 4to. by Nathaniel Whittock ; a work from which much useful information may be ob¬ tained ; we have to acknowledge our obligations in this section particu¬ larly to Mr. Whittock’s work.—Edit. IMITATION OF OAK. 281 an imitator of fancy woods should never imitate the productions of the decorative painter, however beautiful, but apply at once to nature herself as the foundation of his proficiency, and hence he will form his own style. In London, in particular, where patterns of woods of various kinds can be so readily procured, he ought never to imitate an imitation. Oak being the wood which is generally preferred for outside work, not only as being the most durable, but also because it is one of the most beautiful of our English woods, the artist will be disposed to recom¬ mend the imitation of it for street doors, shutters, &c. In fancy woods the first object of the painter is to dis¬ cover the lightest part, which in all cases of wood will be the ground colour, and of course the colour of the last coat previously to the application of the graining. The ground colour must be always quite dry before any of the graining colours are laid on. Imitation of Oak. Oak may be imitated in various ways, both in dis¬ temper and in oil; but the best, because it is the most durable, especially for outside work, is that in oil. The last coat of the ground for oak graining may be rotten- stone and white lead mixed to the tint required. The graining colour is to be spread very thinly over the surface to be grained; it is composed as follows :— Take of sugar of lead and of rotten stone, of each eight ounces. Grind them together as stiffly as pos¬ sible in linseed oil. Then melt sixteen ounces of white wax gradually in an earthen pipkin, to which, when 282 IMIITATION OF OAK. melted, add eight ounces of oil of turpentine; these being mixed, pour on the grinding stone to cool. When cold, grind them with the previously ground sugar of lead and rotten-stone. This mixture forms what is called by Whittock, an excellent megilp* ; it should be kept in a jar having a mouth wide enough to admit a pallet knife, w^ell secured from dust, will keep a long time, and be always fit for use. When used, if it be too stiff, it should be softened with a little boiled oil. This method of imitating oak requires combs of vari¬ ous sizes. These combs are made thicker than combs for the hair, and not so long in the tooth. It is usual to have the combs with the teeth regularly cut; but combs cut irregularly will give the grain more like nature; hence it has frequently happened that an old comb with some of the teeth broken out will answer better than new ones. Combs for graining may be ob¬ tained at the comb-makers in London. If, however, graining combs cannot be procured, large and small tooth combs ground down with the grindstone, and the teeth broken out irregularly, will, in the hands of an adroit painter, produce good work. A few minutes after the megilp has been laid on, the comb, being held by the handle firmly with one hand, and guided by the other, must be drawn over the work, making the grain slant or look wavy, according to the * This is one of those terms which are found in the vulgar slang of the ordinary painter, of which it is difficult, if not impossible, to ascertain the origin; and we feel reluctant to sanction its use, but as it has been previ¬ ously used by the author mentioned, w'e therefore have employed it.— Edit. OAK IN DISTEMPER. 283 sort of oak required. Other combs must be used suc¬ cessively till what is desired in the graining is accom¬ plished. Besides the combs, a piece of wash leather being doubled to a point, is also necessary to be used with a sharp touch, to take out the light parts of the oak; if the lines are wanted fine, the leather may be put on the point of a stick. It is most usual to leave the work in this state; but it has not that soft appearance which is exactly ac¬ cordant with nature. To remedy this defect take a hard tool and dab the end of it all over the work just combed ; this will break the lines and give a more natural ap¬ pearance. The megilp should not be spread over more than a square yard at a time, as it dries very fast and soon becomes unmanageable. When the whole work is combed, it should be allowed to get quite dry. The dark touches are then added with a little Vandyke brown ground in ale; and if a still further variety be required, a very thin glaze of umber ground in ale may be applied with a flat varnish brush. After the combs have been used they should be washed in oil of turpentine and well brushed in soap and water, so that they may be put away quite clean. Oak in Distemper. The colours for this are burnt and raw umber, and Vandyke brown. They should be powdered and after¬ wards ground very fine in water; they should then be suffered to dry upon the slab, and when dry be kept in 284 IMITATION OF MAHOGANY. bottles for use. When used they may be ground in beer which is sufficiently glutinous, for binding the colour on the surface to be painted. In graining oak in distemper, the ground must be prepared exactly as we have before stated, unless it should be desired of a deeper colour; in which case a little umber must be added to the ground. Before any of the distemper colour is laid on, the surface to be grained should be washed with soap and water, to cleanse it both from dirt and grease. Instead of combs, as in the preceding case, the grain¬ ing in distemper is made with tools , called in the ordi¬ nary language of the painter, reining brushes. Here also much will depend upon the taste and judgment of the artist, and much upon the finishing with a dust¬ ing brush, damp wash leather, &c. The dark veins are put in with burnt umber; and if required to be darker in parts, add a little Vandyke brown : these veins must be formed with a camel’s hair or sable pencil. When the whole of the work is quite dry it may be varnished, and is then of course completed. Imitation of Mahogany. We have given in page 196 the method of imitating mahogany in oil. The ingenious painter will readily find other methods, without being particularly directed to them. As, however, painting mahogany in distemper requires a different course, we have thought it best to give the following methods a place in our work. SPANISH MAHOGANY—SATIN WOOD. 285 Honduras Mahogany. The ground for this may be Venetian red and white lead mixed according to the tint required. The only colours necessary to represent this sort of mahogany are different tints of Vandyke brown. The first tint is spread evenly over the surface intended to be painted; while quite wet dab it with a sponge in various places ; this will take out the lights; then take the softener and blend the edges of the light parts and the wet colour together, taking care to use the softener in the direction in which the dark veins are intended to run; as soon as this is dry take a deeper tint of Vandyke brown, and with the tool form the lightest of the dark veins. These different veins of colour must be all blended together and softened with the dusting brush ; after which a badger hair softener should be used. Spanish Mahogany Is of a much finer red than Honduras mahogany; it is produced by adding a little crimson lake to the ground. In this mahogany the dark veins incline to crimson; a little Vandyke brown and lake will impart the desired tint. Satin Wood. The ground for satin wood is the same as for the lightest oak. The ground should be Oxford ochre ground in pale ale, and afterwards diluted with ale to the required consistence. Lay this thinly on the whole of the space intended to be grained. This being done, take a small piece of sponge and let it drop accidently on 286 WALNUT TREE. various parts of tlie work; wherever it touches it will take off some of the ochre just laid on. When you have produced as much dapple as required, soften the edges by passing the badger hair softener over the whole, letting the brush move quickly backward and forward, thus blending the thick edges left by the sponge, and soften it among the yellow, leaving the ground colour perfectly clear to shew the light dapple of the satin wood. When the yellow is quite dry, take the flat brush with the hairs separated, and dipping it into a very thin glaze of umber and raw terra de Sienna ground in ale, pass it over the work lightly in a wavy direction, and immediately use the softener to blend it together in parts, letting it touch a little harder upon the bright lights than in the other parts, to remove the veins, just laid on, from it. When dry, the work is finished. Walnut Tree. The ground is yellow ochre, a little umber and white. The veins are drawn on the ground with the flat brush; or, if a large surface is to be covered, with a large tool, nearly worn out, filled with raw umber ground in beer. To represent a knot, take the round part out with the sponge, as well as the light parts above and below the knot; let the work dry; and af¬ terwards shew the darkest veins by drawing the flat brush in various directions over the work, taking care that it follows in some degree the grain first laid on; mark the dark part of the knot with the same colour and the touches above and below it, blending the whole with the duster; when varnished it is complete. ROSE WOOD—BIRD’S EYE MAPLE. 287 Rose Wood. The ground for this can scarcely be too brilliant; it consists of vermilion, lake, and flake white, so as to pro¬ duce a fine rose red, inclining more to pink than scarlet. The ground being dry, take Vandyke brown nearly opaque, and with a small tool beat the colour while wet against the grain, that is, in an opposite direction to the way in which it was laid on. Before the colour is dry take a piece of wash leather on the point of a stick, and freely take out the light veins which appear to be part of the veins formed by a knot; take the darkest tint of Vandyke brown, and with a sable pencil give free and strong touches under the parts taken out with the leather, and in other parts where the ground is thinly covered. Blend and soften the whole with the badger hair softener. Lastly, varnish. It should be observed, that as rose wood is found of very different colours and grains, the preceding directions will not exactly suit every variety; the artist must himself vary his manipu¬ lations in imitating this as well as many other woods. The ground, therefore, for some of the more common kinds of rose wood may be, instead of vermilion, lake, and flake white, Indian red and white lead. Bird's Eye Maple Requires the same ground as oak. The grain is umber ground in ale. £88 CORAL WOOD-RED SATIN WOOD. I Coral Wood Is a scarce wood brought from Ceylon; it is used only in the most valuable cabinet-work. The ground is white lead and vermilion. The first broad veins are formed by vermilion, rose pink, or in good work, drop-lake. These must be finely ground in beer, and laid upon the ground with the flat camel-hair brush. When this is dry use Vandyke brown to give the additional veins; after which, a comb may be applied to give the effect of the dark vein running into the other. Let the whole be softened and, when dry, varnished. Rose pink, it is well known, is a fugitive colour ; but Whitlock says, that when thus used, and well varnished its colour remains good. Red Satin Wood. The ground is vermilion, lake, and white, over which is thinly painted a smooth coat of drop-lake ground in ale; while this is wet the lights are to be taken out with a sponge; and while the colour is damp, a comb may be passed over the whole with a light hand, and may be waved and cross the lines in parts. This colour must be dry before any other is applied. The broad veins are formed with rose pink and vermilion, to which a little crimson lake may be added. These veins are laid on with a flat brush, leaving the light parts in the centre; when dry, the small spots of black are given with a sable pencil. Lastly, let the work, when dry, be var¬ nished. \_For the various methods of staining woods see our Treatise on Varnishes .] IMITATION OF MARBLES. 289 Imitation of Marbles. Marble in the nomenclature of the chemist is a stone, chiefly, if not entirely, consisting of lime and carbonic acid, hence marbles are carbonates of lime. But in the nomenclature of the stone-mason and the painter, not only are many stones composed of carbonate of lime called marbles, but also some which contain other bodies, such are porphyry and serpentine. It is not necessary that we should describe the different marbles minutely ; it will be sufficient to observe that the chief are white or Parian marble; Cipolin or white veined marble; Bardiglio or dove-coloured marble; Luma- chella marble of a brownish grey colour; Florentine marble of a greyish colour mixed with yellowish brown, and exhibiting appearances of rocks, forests, &c.; Syria , Arragon , and Sienna marbles are yellow, with various coloured veins of ore; Brocatella marble con¬ tains a mixture of yellowish red and purple cemented by a white semi-transparent spar; green marbles dis¬ tinguished commonly by the terms verd antique; Ser¬ pentine is also a beautiful green.marble found plenti¬ fully in Cornwall and the Isle of Anglesea; porphyry is speckled and veined—it is usually reddish, brown, or green. Marbles may be, of course, imitated both in oil and in distemper; if the imitation is to be exposed to the weather, that in oil is to be preferred. The same observations apply to the imitations of marble as of wood ; the artist must go at once to nature and copy from her productions. o 290 CIPOLIN—DOVE-COLOURED MARBLE. Cipolin—white veined Marble. Ground , white; the faint vein, a reddish grey, is formed by mixing white, black and Indian red to the tint desired. The veining must be scumbled , that is spread very thinly over the ground. Painters gene¬ rally permit the work to Airy every time a fresh vein is added. These directions are for oil painting. To paint this marble in distemper, the walls must be well prepared with size and two coats of whitewash; the third coat should be whiting mixed with milk. Lamp black, Indian red, and damp blue, each ground in milk, should be also ready for use: the milk will be itself sufficiently glutinous without the addition of any other vehicle. A separate brush is used for each colour, and three or four long camel’s hair pencils, with long handles, and a stick to rest the arm upon while penciling the small veins, will be necessary. Every thing required should be ready before the work is begun, as the whole must be finished while it is wet. The w orkman must begin at the top of the room and work downwards, wetting no more than a yard or two at a time, with a very thin coat of the wdiite ground in milk. The laying on of the veins must depend of course on the taste and skill of the artist, and scarcely any prac¬ tical directions will serve him here. When the whole work is completed and dry, it may be varnished, and it will then have the effect of oil painting. Dove-coloured Marble. Ground , light lead colour; the broad veins of white and black must be scumbled and afterwards blended FLORENTINE—SIENNA MARBLE. 291 with the duster. Innumerable varieties of this imitation may be made by varying the colour of the tint. These directions are for oil colours : such imitation is rarely wanted in distemper. Florentine Marble. Ground , white, Indian red and black mixed together, forming a light reddish neutral tint; veins of umber or terra de Sienna are to be laid on while the ground is wet. The forms of rocks or ruins of houses must be given by patient working. This is for oil; for distem¬ per mix whiting in milk to the consistence of thick cream, to which add yellow ochre and red till it be¬ comes a delicate fawn colour; in another vessel have ready Indian red, and in another pure white. Dab on with a large brush, and with great freedom, the fawn colour in ten or a dozen different dabs of different sizes. If this be done with apparent carelessness the dabs will take different forms. Apply now the Indian red freely between the dabs of the fawn colour; blend the edges of the fawn and red together with a lkrge duster; next with camel’s hair pencils draw a few thin veins both of white and red over the colour previously formed. When dry let the work be varnished. Sienna Marble. Ground , yellow ochre ; the various tints which are to be first spread over the ground, are given by yellow ochre, white, and raw and burnt terra de Sienna. These must be tastefully given to the ground by a brush for each colour, and afterwards blended by the softener. o 2 292 SIENNA MARBLE. While the shading colour is wet other veins more removed from the surface are put on with a sable pencil. The colours for these are Venetian red and a little Prussian blue. For the darker veins near the surface use lake, Ve¬ netian red and blue mixed to the required tint. The work may now be dried, and if the shading be not suf¬ ficiently veined a glaze of raw and burnt terra de Sienna may be applied where required: the darkest veins should now be formed of lake and Prussian blue. The preceding is for oil. Distemper requires a ground of yellow ochre and whiting mixed with size. When the ground is dry prepare raw and burnt terra de Sienna, yellow ochre, whiting, lake, and damp blue; these must be ground separately in beer: the whiting should be mixed very thickly with the milk, of which a greater quantity is always required than of any of the other colours, it being the body colour in all distemper paint¬ ing. The shading and veins are to be laid on first with yellow ochre mixed with white, next a smaller shade of raw terra de Sienna, then a dash of white alone, and near to it some burnt terra de Sienna. When a yard or two is covered, dab the brush used in the whiting in four or five places over the work; then dip a large duster in some very thin size without any colour, and squeeze the wet out till it will not run freely : with this brush thus moistened blend the different shades. While wet put in the small veins with Indian red and blue, and over them the still smaller veins with lake and blue. Let the whole dry together. GREEN MARBLES. 29 3 Green Marbles , Such as verd antique, Egyptian green and serpentine, require the same ground, black. The first colour to be laid on the ground for verd antique is white scumbled on very thin, and according to nature. While the white is wet rub off with a piece of wash-leather the colour in the shape designed for shells or other fossil remains ; the other shells are formed like circles, &c.; these may be taken out of the white by a square piece of cork notched in two or three places: press it hard upon the work, turning it round with the finger and thumb. A tool made of the feather of a goose quill, with a great part of the feathers cut away, is now to be passed over the white to take it out in small irregular curling veins over the black; the work must now be suffered to dry. When dry it is heightened by glazing it over with distemper colour, in some places with Prussian blue, in others with raw terra de Sienna, and part is left black and white. When the distemper colour is dry, the feather of a goose quill, prepared as above directed, is to be dipped in whiting ground with milk, and the light veins are carried over the distemper colour ; the thicker veins may be touched with a sable pencil, and a few dark veins of Prussian blue may be made to curl lightly over the strong lights. When dry it will be ready for the last glaze, which must be Prus¬ sian blue and terra de Sienna so mixed that the last shall preponderate. The whole when dry will be a beautiful green, and may be varnished to finish the work. o 3 294 BLACK AND GOLD MARBLE—PORPHYRY. Other methods have been proposed for the imitation of green marbles, but we cannot detail them ; those in¬ terested in obtaining more minute particulars are re¬ ferred to Whittock's W'ork before alluded to. Black and Gold Marble. The ground , black ; the large spots yellow ochre and white mixed with a little vermilion: these must be dabbed with freedom with the brush full of colour on the ground, and while fluid small threads must be drawm from them in all directions. The yellow and white veins may both be painted at once in oil; when dry and varnished the work is complete. Porphyry . The ground for red pophyry is Venetian red bright¬ ened with a little vermilion and white to the tint re¬ quired. The first layer of spots is produced thus : mix a little of the ground colour and white, the latter pre¬ ponderating ; dip a large brush in this mixture, and, after expressing from it the greater part of the colour, strike the handle of the brush, while holding it over the work, upon the back of an old knife, and the colour which remains in the brush will fall upon the work to be spotted in small points. When sufficiently spotted let the work dry; and if necessary another sprinkling may be given of which Indian red may form the chief colouring material; the last sprinkle is white, which must be in very fine spots. The veins seen in porphyry may be added after the sprinklings are dry, with a sable TRANSPARENT BLINDS. 295 pencil, and the threads drawn out with a feather. The work is, lastly, to be varnished. Every variety of spotted marble may be thus pro duced, having regard to the ground which is the pre¬ ponderant colour both in wood as well as marble. Transparent Blinds. The material on which transparent blinds are painted is fine Scotch cambric or lawn. Care should be taken that the cloth is of equal thickness all os 7 er, and without lines, knots, or other defects: one of the pre-requisites in this process of painting is to strain the cloth in a proper manner. There are various ways of doing this; and a very little ingenuity will soon suggest to the artist the best method. The size for works of a particular kind may be isinglass dissolved by being boiled in water; but for large blinds, parchment size is commonly used. (See pages 153 and 240.) It should be laid on the cloth quite hot, with a flat brush, taking care to lay it on equally, and over every part of the cloth. Sometimes it may be necessary to cover the cloth again with the size, after the first coat is quite dry, with another coat ; when this is done, care must be taken that the first coat, is not rubbed up or otherwise disturbed. In drawing the subject on transparent blinds a very soft black lead pencil should be used; the outlines must be, however, as light as possible, as all indenta¬ tions in the cloth will be injurious. The colours used are those which are most transpa¬ rent, such are Prussian blue, lake, raw and burnt o 4 296 TRANSPARENT BLINDS. umber, raw and burnt terra de Sienna, and Vandyke brown. Various tints of the brightest transparency may be produced by these colours; but when others are required they become semi-transparent when used with mastich varnish, which is the vehicle employed in mixing the colour in this style of painting. The proper distances having been marked by the pencil, with a little Vandyke brown, let the whole sub¬ ject be properly sketched with a camel’s hair pencil, taking care, in drawing the trees, to mark wdiere the strong masses of light are to be left. As this colour must be laid on quite thin it will be dry in a few minutes. The sky will first command attention, the colours for which are Prussian blue, lake, Indian red, and yel¬ low ochre. In skies great care must be taken to let the whole appear thin and transparent, even in the darkest clouds. We might proceed thus over every part of the picture to be painted; but it is not here necessary that we should do so ; the artist and amateur who desires to excel in this particular branch will either supply what we have omitted to state by the application of his own genius and ingenuity, (and, indeed, as far as regards the execution of the subject, must rely- upon his own genius, ingenuity, and application, for obtaining excel¬ lence in this, as well as in every other branch of the higher grades of painting) or he will apply to works in which the subject is treated more in detail, such is that of Wliittock' 1 s , to which we have more than once ad verted. TRANSPARENT BLINDS. 297 We may add, in conclusion, on transparent painting, that sometimes the cloth is made transparent, by brush¬ ing it over with white wax, dissolved in oil of turpen¬ tine ; the frame on which the cloth is strained is then placed before a fire, and the dissolved wax is laid on with a brush while hot. Some also produce a beautiful effect, where a strong light is to appear, by spreading virgin wax over those parts before any size is applied, and aftewards sizing and painting in the usual way. In transparencies, where jewellery or sparkling gold is introduced, a fine effect is produced by cutting out those parts, and pasting tissue paper over the holes : the paper can be made nearly as transparent as glass, by varnishing it with mastic varnish. ADDENDUM. On Ultramarine. Concerning the valuable and beautiful colour, ultra- marine , from its present scarcity and high price, we are desirous of communicating all the information which we possess. To those, therefore, who feel interested in this pig¬ ment, an article in the Philosophical Magazine , for April, 1830, is particularly deserving their attention, and to which we refer them: for it is impossible to abridge the contents of that paper ; we learn, however, from it, that one ounce of ultramarine of the best qua¬ lity sells now at from one to two hundred francs per ounce. See also page 65 of the present work. INDEX A. Acetate of Copper. -Lead. Alabaster . Alkanet Root.. Animal Oils .. - Substances used in Painting. Annatto. Archil. Arsenic, Preparations of .... Artificial Sulphate of Lime .. Asphaltum. Aurum Mosaicum. Azure. -, Egyptian. -, Stone. B. Baryta, Barytes. Bastard Saffron. Beech Black. -Charcoal. Bice Blue . -Green .. PAGE Bismuth.. • 61 -, Oxide of. ib. Bistre. 136 Black. 189 -Beech. 133 -Bone or Ivory.135 -Chalk. 81 -Frankfort .. 133 -Lamp . 131 -Lead. 78 -Pencils . 79 -, artificial, ib. -from Peach Stones.... 134 —-Vine Twigs. ib. -Wine Lees. 133 -Wadd. 83 Blacks. 131 Blanc de Roi.261 Blue. 199, 201 -Antwerp . 93 -Bice... 95 -Black. 132 -Copperas . 92 -Enamel. 64 -Flanders . 93 -Mountain. 94 -Oxide of Chrome. 109 PAGE 89 110 47 142 181 111 138 137 85 48 177 63 64 92 65 57 139 133 ib. 95 94 300 INDEX, Blue, Prussian ..... ■ , Queen’s .. -, Saunders’. -, Saxon . -, artificial -, Thenard’s • • • -Verdi ter . -Vitriol . Bone Black . Bougival White. Brian?on White. Brown Ochre • • • -Purple ... •: -Spanish. Brushes. Buckthorn Juice ... Buff Colour . PAGE .. 68 .. 129 .. 93 •• 64 .. 70 .. 65 *. 95 .. 92 ... 135 .. 48 ... 45 .. 75 71 , 208 ** 75 ,.. 265 .. 143 ... 198 C. Calcined Hartshorn ... 62 Carbonate of Barytes. 58 - Lead. 50 -Lime. 53 Carmine. 113, 114 Carminated Lake • • • • • • 114—119 Carthamus... 139 Cassel Earth. 78 Cassius Purple, Precipitate of. 62 Cawk. 57 Ceruse. 50 Chalk. 53 -, Black. 81 Chamois Colour. 198 Charcoal, Blacks from.. 131—135 Chemical Composition of Co¬ lours . 36 Chesnut.208 China Lake . 140 Chipolin. 255 -, Imitation of.258 Chocolate .208 Chromate of Lead. 107 Chrome, Yellow. ib. --, Green Oxide of .... 108 -. Blue Oxide of* 109 Cinnabar, Native. 98 -, Factitious . 99 Cobalt, Colours from. 63 Cochineal . 113 Colcothar of Vitriol. 71 Cologne Earth . 77 Colouring, Laws of Harmo¬ nious . 30 Colours. 36 -, Cold. 27 -, Composition of.. 189—209 -, Compound, for Rooms 205 —:-, Contrasting. 34 -, Harmonizing. ib. -, Mixture of. 18 -, Preparation of* • 211—221 -, Primary . 15 -, for Staining Rooms* • 97 -, Simple. 22 -, Theory of. 14 -, Used by Painters.... 27 -the Ancients 10 -, Warm . 27 -, Water.....25, 213 Copal Varnish • • • .. 178 Copper, Acetate of.. 89 -, Preparations of • • • • 87 -, Subacetate of.. ib. Coral Wood, Imitation of • • • • 288 INDEX. 301 PAGE Crayons. 81 Cremnitz White.44, 45 Crocus Martis . 71 Crotia. 82, 277 D. Dead White.169, 192 Distemper. 239 — — . . -, Badigeon. 254 -, Common.247 --, in Milk. 249 -, for Parquets and Floors . 252 ■-, Precepts for* • • • 245 -, Varnished. 255 Drawing Slate. 81 Driers for Paints. 179, 273 Drying Oil, first Process for.. 157 -, second Process for 158 -, third Process for 161 -—, fourth Process for 162 -, fifth Process for ib. •■■■ ■ -, sixth Process for 163 -■ -, for Printers’ Ink 166 -, Resinous.. 160 -, from Vanherman 167 Dutch Pinks.145—148 E. Earth, Cassel. 78 -, Cologne. 77 -, Green of Saxony • • • • 76 -Verona. 77 Egg Shells. 61 PAGE Egyptian Azure... 92 Elaine . 154 Enamel Blue. 64 English Pink. 149 Expressed Oils, to refine .... 168 F. Fig Blue. 129 Fish Glue. 153 Fixed Oils. 154 Flake White. 50 Frankfort Black .133 Frankincense. 170 French Berries ... 146 G. Gamboge. 144 Gelatine. 152 Glue. 153, 239 Gold, Mosaic. 63 -, Preparations of. 62 Graining....280—295 Green Bice . 94 -, Compound. 205 -, for various Articles. ib. -Earth of Saxony. 76 -Verona. 77 -, Mountain.94, 96 --Olive,. 199 -Oxide of Chrome .... 108 -, Sea. 202 -, Schweinfurt. 93 302 INDEX, Green Verditer.. -, a fine, for Oil Paint .. -, for Distemper. -Doors, &c. - Varnish. Grey, Flaxen.. -> Light. -, Pearl. Gum Arabic. -Copal. -Juniper. -Mastich. -Sandarac . -Senegal. -Water. Gypsum. H. Harmonious Colouring. House Painting.... 29, 263— -, General Ob¬ servations on. -, Mementos for I. Imitations of Wood . -Marble. Indian Red. -Ink. Indigo... Ink, Indian . Instruments used in the Pre¬ paration of Colours. PAGE Iron, Preparation of. 68 -^Oxidesof.. 71 Isinglass. 153 Ivory Black . 135 K. King’s Yellow. 85 L. Lake, Carminated. 114—119 -, China. 140 -, Florentine.... 118 -, from Brasil Wood .... 121 -, Green . 127 -, Madder. 119, 120 -, Orange. 127 -, Purple. 142 Lakes.. Ill -, Comparative Table of.. 124 Lamp Black. 131,13 Lapis Armenus. 95 -Cyanus. 65 -Lazuli. ib. Lead, Acetate of. 110 -, Carbonate of. 50 -, Dichromate of. 109 -, Oxides of.103—106 -, Preparations of. 100 -, White.. • • 50 Lime . 60 -, Sulphate of.47, 48 Linseed Oil . 157 Litharge. 104 Litmus. 137 PAGE 96 93 202 204 203 194 192 193 151 178 174 ib. ib. 151 ib. 47 30 -297 262 274 280 289 73 135 127 135 211 INDEX 303 PAGE Madder Lake.119, 120 Mahogany, Imitation of... 196, 284 Manganese. 83 Maple, Bird’s Eye, Imitation of. 287 Marble, Black and Gold, Imi¬ tation of. 294 -, Cipolin, Imitation of 291 -, Dove-coloured, Imita¬ tion of . 290 -, Florentine, Imitation of. 291 -, Green, Imitation of.. 293 -, Sienna, Imitation of.. 291 Marbles. 289 -, Imitation of. ib. Massicot. 104 Metallic and Earthy Sub¬ stances used as Paints .... 36 Minium. 106 Mosaic Gold . 63 N. Naples Yellow. 100 Nut Oil. 156 O. Oak Wood, Imitation of* 195, 281 Ochre, Brown. 76 -, Bristol . 74 -, Dutch. ib. PAGE Ochre, English. 74 -, Oxford . ib. -, Persian. 73 -, Red..,. 74 -, Spruce. ib. -, Yellow.73, 74 Ochres. 72 Oil, Animal .. 181 —, Boiled... 155 — of Bays. 187 -Hempseed.157, 164 -Linseed . 157 -Nuts. 156 -Poppy Seed. 155 -Tar*-**. 84, 179, 181 -Turpentine. 169 Oils, Animal.•• 181 -, Drying.155—165 -, Expressed, to refine* • • 167 -, Fixed.. 154 -, Volatile. ib. Oil Painting, Precepts for* • • • 229 Olive Green. 199 Orpiment. 86 Ox-gall . 187 Oxide of Bismuth. 61 -Chrome, Green • • • • 108 -, Blue *••• 109 -Cobalt... 63 -Iron. 71 -, the Purple ... ib. -Lead. 103, 106 -, the Red. 106 Vitreous... 104 -Zinc Oyster Shells* 55 61 304 INDEX P. Paint, a cheap, for Pales &c • -, Vanherman’s Impene trable. Painters’ Cream. Painting Encaustic . -of the Egyptians -Greeks . • - , -Romans • PAGE 277 — in Crayons... -Distemper* - Enamel... -Fresco ... -Milk. - Miniature. -Oil. -Water Colours 276 165 4 9 *• 3 *. 2 .. 26 23, 239 .. 26 .. 24 .. 249 .. 214 12, 24 . 25 —, Genevese method of 251 —, Historical Sketch of 1 —, on House, 29, 263—297 -the various kinds of. 23 Paintings, on the Preservation and Repairing of. 183 Paper Hangings . 278 Parker’s Cement... 84 Pearl White . 61 Permanent White. 59 Pink, Dutch.145 -, English. 149 -, Rose. ib. Pinks, various. 145—149 Plaster of Paris. 47 Polishing ... 234 Pompadour. 71, 208 Ponderous Spar. 57 PACE Porphyry, Imitation of. 294 Precepts in Distemper.243 ■-!-Oil Painting • • • • 229 -Varnishing. 221 Priming. 268 Proof, Spirit of Wine . 173 Prussian Blue. 68 -- Red. 71 Prussiate of Iron. 68 Purple Brown. 71, 208 -Precipitate of Cassius.. 62 Putty. 182 Q. Queen’s Blue. 129 Quicksilver, Preparations of.. 98 R. Realgar. 86 Red for Corridors, &c.253 -Indian . 73 -Lead... 106 -SandalWood. 141 -Saunders... ib. -Sulphuret of Arsenic.... 86 ---Mercury .. 98 -Venetian. 73 Reds, various. 206, 207 Resin Black .. 169 -Yellow. ib. Road Dust. 81 Rose Colour . 207 -Pink. 149 INDEX 305 Rose Wood, Imitation of • • • • Roucou. Rouen White... Rouge...139, Royal White. S. Safflower. Sap-green.. Satin White . -Wood, Imitation of • • • • -, Red, Imitation of Saunders’ Red . Saxon Blue .. -, Artificial . Scheele’s Green.. Serpentine, Imitation of • • • • Size.... -for Knots . Sizing. Smalt ... -Strewing.. Spanish Vermilion.139, Spirits of Turpentine. Spirit of Wine.* Stearine. Stenciling. Stucco coloured. Sugar of Lead . Sulphate of Barytes. -Copper. -Iron . -Lead. -Lime. -, Artificial... PAGE Sulphate of Zinc . • • • •.. 56 Sulphuret of Arsenic, Yellow.. 86 -Red .. jb -Mercury, Red... 98 T. Tar, Coal . 180 -Common..... 179 -Oil of. 181 Terra de Sienna... 76 -Merita. 126 -Verte. 76 Tools, Ground . 266 Transparent Blinds... 295 Turbith Mineral . 99 Turmeric Root. 126 Turpentine, Crude. 170 -Ethereal Oil ofib. -Horse . ib. -Oil of. 169 -Strasburgh. 170 -Venice .. • .171 -Varnishes. ib. U. Ultramarine. 65, 298 -, Artificial. 68 -, Adulterated • • • • 67 Umber English. 75 -Turkey . ib. PAGE 287 138 53 140 260 139 143 49 285 288 141 64 70 86 293 152 153 243 65 ib. 140 169 173 154 278 97 110 57 92 71 52 47 48 306 INDEX V. Vanherman, Note on. Vanherman’s Incorporated Oil -Impenetrable Paint. -Artificial Sul¬ phate of Lime. Varnish Black. -Copal . -Drying. -Spirit.176, -Turpentine. -for Coloured Grounds -Grinding Colours -V aluablePaintings Varnishes. . 171- --—, Precepts for Using -, some Observations on.. Vehicles for Paints . Vegetable Substances used as Paints. Veining • • • • • • .. Verdevissa. Verdigris. -, Distilled. -, English . -, Liquid. Verditer Blue. -Green. V ermilion. -, Spanish • • • • 139, Violet Colour... Virgin Tints.. Volatile Oils W. PACE Walnut Wood, Imitation of 196,286 Water. 150 -Colours.25, 213, 214 White, Bougival . 43 -Brianfon. 45 -Copperas. 56 -Cremnitz .... *. 44 -Flake. 50 -Lead . 50, 266 -Moudon... 49 -Morat. ib. -Pearl. 61 -Permanent.,. 59 -Royal. 260 -Satin. 49 -Spanish. 46 -Troyes .. 53 -Vitriol . 56 Whites, the chief used as Pig¬ ments . 43 Whiting. 53 Woad. 145 Woods, Imitation of. 280 Y. Yellow.. 196 -, Chrome.107, 197 -—, Golden...198 -, Jonquil. 197 -, King’s. 85 -, Lemon. 197 -, Montpellier. 101 PACE 266 277 276 48 177 178 172 177 171 174 176 175 -179 221 187 150 111 280 144 87 89 91 90 95 96 98 , 140 207 20 154 INDEX, 307 PAGB Yellow, Naples. 100, 196 -, Oxide of Lead.104 -, Patent. 101 -, Straw . 198 Sulphuret of Arsenic.. 86 Z. Zaffre. 64 Zinc, Flowers of. 55 -, Oxide of. ib. -, Sulphate of. 56 THE END. L O N DO N : GILBERT & R1VINGTON, PRINTERS, ST. JOHN’S SQUARE. ERRATA Page 55, line 14, for earthein read earthen. - 79,- 5, for demand read demands. -- 94,- 3 from the bottom, for Chrysocollu read Chrysocolla. -165,-13, for stearinc read stearine. -20, for Cremitz read Cremnitz. - 272 ,- 17 ,/or last note, read the note page 266. * / \ ■h rJ _ r * i : !/