THK u DIER’S ASSISTANT IN THK ART OF DYING WOOL AND WOOLLEN GOODS. Extracted from the philosophical and chymical w^orks ofthost most eminent Authors FERGUSON, DUFAY, HELLOT, GEOFFERY, COtBERT ; AND THAT REPUTABLE FRENCH DIER MONS. DE JULIENNE. TRANSLATED FROM THE FRENCH. WITH ADDITIONS AND PRACTICAL EXPERIMENTS. BY JAMES HAIGH. Late Silk and Muslin Dier, Leeds. POUGHKEEPSIE : PUBLISHED BY PARACLETE POTTER, MAIN-STREET. P. & S. Potter, Printers, 181 S. '■■k* PREFACE. THERE are very few arts so expensive as that of dteiijg ; and although those principal corn, modities, clothing and furniture, receive their chiet improvement and value therefrom, it is nev- ertheless very far from being brought to perfec- tion. A long practice, sound judgment, and great attention, will form a good and expert dier. Many diers can w'ork with success in a number of colours only w’hich depend on each other, and are entirely ignorant of the rest, or have but a ver\ imperfect idea of them. A philosopher, who studies the art of dieing, is in some measure astonished at the multiplicity of new^ objects which it affords ; every step pre- sents new difficulties and obscurities, u'ithout hopes of any instruction from the common work- men, who seldom know more than facts ard cus- tom. Their manner of explaining tiiernseives, and their common terms, only affirnd more dark- ness, w'hich the uncommon and often useless cir- cumstances of their proceedings render more ob- scure. Before we enter into the particulars of dicing wooi, it is necessary to give an idea of the prima- ry colours, or rather of those which bcc=r this name by the arti:st ; for it will appear by reading the celebrated w’orks of Sir Isaac Newton oa Light and Colours, that they bear no aPiinitv v. ith those w hich the Philosophers call by that name. They are thus named by the workmen; because IV PREFACE* by the nature of the ingredients of which they are composed, they are the basis from whence all others are derived. This division of colours, and the idea which [ intend to give of them, are also common to the different kinds of diting. The five primary colours are blue, red, yellow, brown and black. h.ach r.f these can furnish a great number of shades, from ihe lightest to the darkest ; and from the combination of two or more of these different shades, arise all the col- ours in nature. Colours are often darktned, or made light, or considerably changed, by ingre- dients that have no colour in themselves ; such are the acid, the alkalis, and the neutral salts, lime, urine, arsenic, alum, and some others ; and in the gri^test part of dies, the wool and woollen goods ar^ prepared with some of these ingredi- ents which of themselves give little or no colour. It may easily be conceived what an infinite vari- ety must arise frorai#ie mixture of these differ- ent matters, or even from the manner of using them ; and what attention must be given to the minutest circumstances, so as perfectly to suc- ceed in an art so complicated, and in which there are many diffieiilties. It is not needful tp be very particular in describ- ing the utensils of a die house, as they are com- monly known ; this work being des'^ned for the experienced dier. A die- house shoTO, however, be erected on a spacious plan, roofed over, but admitting a good light, and as nigh as possible to a running water, which is very necessary, eL ther to prepare the wool before it is died, or to wash it afterwards. The coppers should be set at the distance of eight or tea feet, and two or PREFACE. V more vats for the blue, according to the quanti- ty of work that is to be carried on. ^ The most important point in dicing the primi-* tive blue is to set the vat properly at work, and conduct her till she is in a state to yield her blue. The siz of the, vvoad vat is not fixed, as it de- pends upon necessity or pleasure. A vat con- taining a hogshead, or half that quantity, has often been used with success ; but then they must be prevented l»y some means from cooling too sud- denlv, otherwise these small vats v\ ill fail. Another kind of vat is prepared for blue : this is called the indigo vat, because it is the indigo alone that gives it the colour. Those that use the woad vat do not commonly use the indigo one. There are two methods of dicing wool of any colour ; the one is called dicing in the great, the other in the lesser die. The first is done by means of drugs or ingredients that procure a last., ing die, resist the action of the air and sun, and are not easily stained by sharp or corrosive li- quors. The contrary happens to colours of the lesser die. The air fades them in a short time, more particularly if exposed to the sun ; most liquors stain them, so as to make them lose their first colour. It is extraordinary that, as there is a method of making all kinds of colours by the great die, the use of the lesser should be toiera-. ted ; but thl*ee reasons make it difficult, if not impossible, to prevent this practice. 1st, The work is much easier. Most colours and shades which give the greatest trouble in the great, are easily carried on in the lesser die. Most colours in the lesser are more bright and lively than those of the great. Vi PREFACE. \ 3d, For this reason, which carries more weight, the lesser die is carried on much cheaper than the great. This is sufficient to determine some men to do all in their power to carry it on in prefer- ence to the other. Hence it is that the true knowledge of chymistry, to which the art of dic- ing owes its origin, is of so much use. It may be observed, that all lasting colours are called colours of the great, and the others of the lesser die Sometimes the first are called fine, and the latter false colours ; but these expressions are equivocal, for the fine are sometimes con- founded with the high colours, which are those in whose composition cochineal enters ; therefore, to avoid ail obscurity, I shall call the first colours of the great, and the latter colours of the lesser die. Experiments, (which are the best guides in natural philosophy as well as arts) plainly shew, that the difference of colours, according to the foregoing distinction, partly depends on the prep- aration of the subject that is to. be died and part- ly on the choice of the ingredients which are af- terwards used to give it the colour, I therefore think it may be laid down as a general principle, that all the invisible process of dicing consists in dilating the pores of the body that is to be died, and dep(j^iting therein particles of a foreign mat- ter, .which are to be detained by a kind of ce- ment which prevents the sun or rain #f>m chang- ing them. 'Vo make choice of the colouring par- tiales of such a durability that they may be re- tained, and sufficiently set in the pores of the subject opened b}yhc heat of boiling water, then contracted by the cold, and afterwards plaistered over witli a kind of cement left behind with the PREFACE.' Vii salt used for their preparation, that the pores of the wool or woollen stuff ought to be cleansed, enlarged, cemented and then contracted, that the colouring atom may be contained in a lasting manner. Experiments also shew that there is no colour- ing ingredient belonging to the great die which has not more or less an astringent and precipitant quality. That this is sufficient to separate the earth of the alum ; this earth, joined to the col- ouring atoms, forms a kind of lacque, similar to that u^ed by the painters but infinitely finer. 'Phat in bright colours, such as scarlet, where alum cannot be used, another body must be substitu- ted to supply the colouring atoms (block- tin gives this basis to the scarlet die.) When all these small atoms of earthly coloured lacque have insin- uated themselves into the poies of the subject that is dilated, the cement which the tartar leaves be- hind serves to masticate these atoms ; and lastly, the contracting of the pores, caused by the cold, serves to retain them. It is certain that the colours of the false die have that defect onl\ because the subject is not suffic iently prepared ; so that the colouring parti* cles being onl) deposited on its plain surface, it is impossibie but the least action of the air or sun must deprive them of part, if not of the whole. If a method was discovered to give to the colour- ing parts of dicing woods, the necessary astric- tion which they require, and if the we>ol at the same time was prepared to receive them, (as it is the red of madder) I am convinced, by thirty ex- periments, that these woods might be made as useful in the great, as they have hitherto been in the lesser die. PREFACE. tiii What I have said shall be applied in the sequel of this treatise, where I shall shew what engaged me to use them as general principles. I should have been glad to have seen a work of this sort, (knowing the great need there is of a chymical understanding of this art) signed by the name of some person of distinction, to have given it a better face ; yet, in defect of that, I was pre- vailed upon to undertake the tedious task. I dare not flatter myself to have brought it to its last per- fection, as arts daily improve, and this in particu- lar ; but I hope some acknowledgment will be due to me for bringing this matter a little further out of that obscurity in which it has laid, and for assisting the diers in making discoveries to help to perfect this most useful art. I shall now proceed to examine the five prima- ry colours above mentioned, and give the different methods of preparing them afteV the must solid and permanent manner. ^ JAMES HAIGH. INTRODUCTION. THE materials of which cloths are made, for the most part are naturally of dull and gloomy colours. Garments would consequently have had a disagreeable uniformity, if this art had not been found out to remedy it, and vary their shades. The accidental b'uising of fruits or herbs, the effect of rain upon certain earih:> and minerals might suggest the first hint of the art of dicing, and of the materials pro'per for it. Every climate furnishes man with ferruginous earths, with boles of all colours, with saline and vegetable materials for this art. The diffi mlty must have been to find the art of applying them. But how many trials and essays must have been made, before they found out the most proper methods of applying them to stuffs, so as to stain them with beautiful and lasting colours ? In this consists the principal excellence of the dier’s art, one of the most in^ geniousand difficult which we know. Dicing is performed by means of limes, salts, waters, leys, fermentations, macerations, &c. It is certain that dicing is very ancient. The Chi- nese pretend that they owe the discovery of it to- Hoan-ti, one of their first sovereigns. One of the most agreeable effects of the art of diring, is the diversil) ing the colours of stufis. There are two ways by which this agreeable vari- ety is produced, cither by needle woik with threads of diffi < rnt colours, on an uniform ground, or by making use of yarn of different colours in the weaving. B X INTRODUCTION . The first of these inventions is attributed to the Phrys^ians, a very ancient nation ; the idbt to the Babylonians. Many things incline us to think that these arts were known even in the times of which we are now treating. The great progress the-^e arts had made in the days of Moses> sup- poses that they had been discovered long before. It appears to me certain, then, that the arts of em- broidery or weaving stuffs of various colours wore invented in the ages we are now upon. But I shall not insist on the manner in which they were then practised, as I can say nothing satis- factory upon that subject. Another art nearly related to that of dieing, is that of cleaning and whitening garments, when they have been stained and sullied. Water alone is not sufficient for this. We must communicate to it by means of powders, ashes, &.c. that deter- sive quality which is necessary to extract the stains which they have contracted. Idle ancients knew nothing of soap, but supplied the want of it by various means. Job speaks of wash- ing his garments in a pit with the herb borith. This passage shows that the method of cleaning garments in these ages, was by throwing them into a pit full of water, impregnated with some kind of asshes ; a method which seems to have been very universal in these first times. Homer describes Nausicaa and her companions washing their garments, by treading them with their feet in a pit. With respect to the herb which Job calls borith, I imagine it is salvvorth. This plant is very com* mon in Syria, Judea, Egypt, and Arabia. I'bey burn it« and pour water upon the ashes. This INTBODUCTION, XI water becomes impregnated with a very strong lixivial bait proper ior taking stains or impurities Out of wool or cloth. The Greeks and Romans used several kinds of earths and plants instead of soap. The savages oi America make a kind of soap- water of certain fruits, with which they wash their cotton beds and other stuffs. In Iceland the women make a ley (vf ashes and urine. The Persians employ boles and marls. In many countries they find eaahs ’vhich, dissolved in water, have the prop- perty nf cleaning and whitening cloth and linen. All these muhods might perhaps be practised in the primitive ages The necessitie^s of ail man- kind are much the same, and all climates present them with nearh the same resources. It is the art of applying them, v hich distinguishes polite and civilized nations from savages and barbarians. CONTENTS PART I. ©F THE ART OF DIEING WOOL AND WOOLLEN STUFFS. CHAPTER I. Of Blue . . . . • . 25 CHAPTER II. Of the Garden- Woad or Pastel- Vat • • 29 The vat set to work . . . . ib. IVIarks how to conduct a Vat regularly . 32 The opening of the Vat . . ; 36 CHAPTER HI. Of the Field Woad Vat • . ; 46 CHAPTER IV. The Indigo Vat , . • . .49 Process of makir g the Indigo in America . ib. Method of working the Indigo \ at . . 51 CHAPTER V. The cold Vat with Urine , , . 55 The hot Vat ith Urine ... 57 Re- heating ot the Vat with Urine . . 59 tOKTEXTS. xm CHAPTER Vr. or the cold Indigo- Vat without Urine * • Water of Old Iron - . . . CHAPTER VII. Of the Method of dying Blue The manufacturing of Pastel, or Garden Woad in France ... * Powder of Woad . ... CHAPTER VIII. Of Red . . . . . CHAPTER IX. Of scarlet of Grain Preparation of the wool for scarlet of Grain Liquor for the Kermes CHAPTER X. Of Flame coloured scarlet Composition for Scarlet Water for the Preparation of Scarlet Reddening Experiments on Cochineal Liquor Violet withoui Blue CHAPTER XI. Of C rimson . , , Languedoc Crimson Natural Crimson in Grain CHAPTER XII. Scarlet of Gum Lacque jB2 62 6a 65 89 91 94 95 96 97 107 109 1 2 li3 128 129 130 133 136 136 XIV CONTENTS. CHAPTER XIII. Of the Coccus Polonicus, a colouring Insect 149 CHAPTER XIV. Of the Red of Madder Purple with Madder without Blue Of Yellow Of Brown CHAPTER XV. CHAPTER XVI. CHAPTER XVII. Of Black . ... Remarks on Black Die CHAPTER XVHI. Of the Mixture of Blue and Red CHAPTER XIX. Of the Mixture of Blue and Y eilow CHAPTER XX. Of the Mixture of Blue and Brown CHAPTER XXL Of the Mixture of Bme and Black CHAPTER XXII. Of the Mixture of Red and Yellow 142 151 152 156 164 166 167 170 175 17S 176 frOWTENT S. XV CHAPTER XXIIL Of the Mixture oi' Red aiid Brown • 179 CHAPTER XXIV. Of the Mixture of YcUowand Brown • 180 CHAPTER XXV. Of the Mixture ol Brown and Black . 181 CHAPTER XXVI. Of the Mixture of the primitive Colours taken three b} three . . . . loi] Variety of Carnation Colours . . 184 CHAPTER XXVII. Of the Manner of mixing Wool of different Colours, for cloth, or mixed Colours, (Co- lours mixed in the Loom ) . . 187 CHAPTER XXVIII. Of the method of preparing the Pattern Felts, or Mixture for an Essay . . • 189 CHAPTER XXIX. Of Polish Red 191 PART II. OF THE LESSER DIE. CHAPTER I. Of the dicing of Wool by the Lesser Die 19S / xvi CONTENTS CHAPTER II. Of the dicing of flock or Goat’s Hair ^ AS'uiphuring of Wool Uiie Theory of the Dissolution of flock CHAPTER III. Of the manner of using Archil Basiard scarlet by Archil CHAPTER IV. Of Logwood or Campeachy • i The Raven Grey, , . . CHAPTER V. Of Saxon Blue and Green . , Blue on Cloth, Stuff, or Yarn Chymic for Green, CHAPTER VI. Of Brazil Wood . . . , CHAPTER VII. Of Fustic CHAPTER VIII. Of Roucou CHAPTER IX. Of the Grains of Avignon CHAPTER X. Of Turmeric • - I . IPS . 202 . ib. . 206 . 209 211 215 • 215 . 216 . 217 218 . 222 22S 225 225 cox TENTS. xvii CHAPTER XI. Of Silver Grey 227 Another excellent Silver Die . . 228 Instructions on the proof of dyed Wool and . Woollen Stuffs , , . ib# PART III. ADDITIONAL ARTICLES. CHAPTER I. Of Flowers . . . . . 237 Of Blue Flowers , . • . 238 Of Red and Yellow Flowers. • . 240 Of WhiteFlowers .... 242 CHAPTER II. Of Fruits .... 243 CHAPTER III. Of Leaves • . • 247 CHAPTER IV. Mr. Lewis’s History of Madder, and manner of treating it - . , 250 CHAPTER V. Of Fustic , . . . 254 CHAPTER VI. Of Nephritic Wood . , . 254 XViii CONTENTS. CHAPTER VII. Mr. Ferguson’s History of Logwood as a colouring Drug CHAPTER VIII. The process of Prussian Blue , CHAPTER IX. Of Alkanet Root . CHAPTER X. Of Alum ... CHAPTER XI. Chymical History nf Saunders, and its dif- ference from other Red \V(.ods CHAPTER XII. 256 258 260 262 26S OfVerdigrisc 265 DIER’S ASSISTANT IN THE ART OF DYING. THE DIER^S ASSISTANT. PART I. CHAPTER I. I OF BLUE. • WOOL and woollen stuffs of all kinds, are di- ed blue without any other preparation, tiian weU ting them well in iuke-warm water, squeezing them well afterwards, or letting them drain ; this pre- caution is necessary, that the colour may the nrore easily insinuate itself into the body of the wool, j that it may be equally dispersed throughout ; nor is this to be omitted in any kind of colours, whetlurr the subj xt be wool or cloth. As to wool in the fleece, w hich is used in man. iifltcturing cloth, as well inc mixt as other sorts, i and which they are obliged to dye before they are ' spun, they are prepared in another manner, viz. ! they are^ scoured, and thereby divested of the nat- ! Ural fat they had w hen on the body of the animal.^* As this operation ib properly the i tier’s, and is The natural fat adhering to the veool presence?, it ia the warehouse, an(f also from modis. ^6 • t indespensable in. wool which is to be died before it is spun, let the colour be what it will, 1 shall give the proper process. This operation is not every where alike, but this is the method followed in the n>anu factory of Audly in Normandy, where cloths are most beau- tifully manufacuirecl. A copper containing twenty pails is used for this purpose ; they put twelve pails of water, and four of urine, (which is generally fermented), the copper is heated, and when the liquor is so hot as to bear the hand withent sc Iding, ten or twelve pounds of wool, that still contains its natinal fat, are put in and left in the copper about a cjuarter of an hour, stirring from time to tiiTie with sticks ; it is then taken out and put to drain on a scray ; from thence it is carried in a large square basket, and placed in running water, two men stirring it tQ and fro for a considerable time with long poles, till it is entirely cleansed of its fat ; then it is taken out and placed in a basket to drain ; while this wool is thus preparing, a like quantity may be put into the copper, and thus proceed till the whole is scoured, if the liquor is too much wasted, fresh is to be added, made up of one part urine and three parts w^ater. They generally scour a bale ofw^ool at once ; if it weighed 250\b in the fat, it gener- ally loses 60ib, in scouring; but this diminution of weight varies in proportion to the wool being more or less scoured, and in proportion to the more or less fat contained therein. Too much attention cannot be paid to the scouring, as it is thereby bet- ter disposed for the reception of the dye. The fat, which is an oily transudation, and slightly partarking of the quality of urine retained / 27 by the fleece, which is too thick to let it out, is so- luble in water, consequently, as water alone could not separate it, a fourth part of urine is put into the copper, which must have been kept some days, in order to separate its volatile salts by fermentation ; (I mean that it is necessary this urine should be- gin to acquire a strong smell) ; this volatile salt, being an alkali forms with the fat a kind of soap, which is always the result of all oils and alkalis whatsoever mixed together. As soon as soap is formed bv the combination of these two principles it becomes soluble in water, and is consequently easily carried off A proof that a true soap has ,been formed in this operation, is, that the water which carries it away, whitens as long asany fat is separated from the wool : if there was a sufficient quantity of fermented urine in the copper, tlie wool will be well scoured ; if it wa^ not, all the fat would not be changed into soap* and consequently the w ool w ill remain greas/. l*he same operation might be performed with fixed alkalis, as with the lee of pot- ash or pearl ashes ; but as this lee wc uid not only come dearer than urine, it might also damage the w ool, i* the exact proportion w as not a])plied. 1 am convinced by several expy^ri- ' ments, that these caustic salts do easily destroy all animal subs^ices, as w’ool, silk, &c. I beg the reader may take notice, that though in the sequel I do not mention this operation of scour- ing, it is nevertheless necessary for all wool that is to be died before it is spun, as also that it is ne- cessary to w^et those that are spun, and stuffs of ail kinds, that the colour may be the more equal^ diffused throughout. 28 Of the five primary colours mentioned in the preface, two of them require a preparation given by noncolouring ingredients, which, by the acidity and fineness of their earth, dispose the pores of the wool to receire the colour. This is called the preparation ; it varies according to the nature of shades and colours : the red, the yellow, and the colours derived from them must be so treated ; black must have a preparation peculiar to itself ; blue and brown require none ; it is sufficient that the wool be thoroughly scoured and wetted ; and even for blue, it suffices to dip it into the vat, stir- ring it well, and letting it remain, more or less, ac- cording as the ground of the colour is wanted.. For this reason, and also that many colours previa ously require a blue shade to be given to the wool, I shall begin with it, and give thereon the most ex- act rules in my power. .It is an easy matter to dye wool blue, when the vat is once prepared, but it is not so easy to prepare the vat,, which is the most difficultpartof the Dier’sart. In all the other processes, it is sufficient to follow the simple ope* rations transmitted from masters to apprentices. Three ingredients are used in the blue die, viz. garden- woad or pastel, the woad, and the indigo. I shall give the preparation of each, beginning with the garden woad. # 29 CHAPTER II. 9F THE GARDEN. WOAD, OR PASTEL-WOAB. THE garden-woad is a plant cultivated in many parts of Holland and France, and might be in Eng« land or Ireland, to the great advantage of the hus- bandman ; it is made up in bales, generally weigh- ing from one hundred and fifty pounds to two hundred ; it resembles little clods of dryed earth, .interwoven with the fiiires of plants ; it is gather, ed at a proper season, and laid up to rot, and then made into small balls to dry. Several circumstan- ^ ces are to be observed in this preparation; on this you may see the regulations of Mons. Colbert on Dies ; the best prepared comes from the diocese . of Aiby in France. The vat set to work, A copper as near as possible to the vat is filled with water that has stood for some time, or, if such Tv^ater is not at hand, a handful of Dier’s woad or hay is added to the water, with eight pounds of crubt of fat madder. If the old liciuor from a vat that has been used in dicing from^ madder can be procured, it will save the madder, and produce a better effect. The copper being filled, and the fire lighted 2 l^ bout three iu the morning, it must boil an hour and a quaiier, (s< me diers boil it from two hours and . a half to three); it is then conveyed by a spout ia- C 2 50 to the woad vat, in which has been pr^ionsly put a peck of wheaten bran. Whilst the boiling* li- quor is emptying into the vat, the balls of woad must be put one after another into the vat, that they may be the easier broken, raked and stirred ; this is to be continued till all the hot liquor from the copper is run into the vat, which, when little more than half full, must be covered with cloths somewhat larger than its circumference, so that it may be covered as close as possible, and left in this state for four hours. Then it must be aired, that is, uncovered to be raked, and fresh air let in it ; and to each bale of woad, a good measure of ware flung in ; this is a concealed name for lime that has been slacked. This measure is a kind of wooden shovel, which serves to measure the lime grossly ; it is five inches broad and three inches and a half long, containing near a good handful ; the lime being scattered in, and the vat well raked it must be again covered, leaving a little space of about four fingers open, to let in air. Four hours after, she must be raked, without serving her with lime ; the cover is then put on, leaving as before, an opening for the air ; in this manner she must be let to stand for two or three hours. Then she may be raked well again, if she is not ^et come ta work ; that is if she does not cast bltfe at her sur* face, and that she works or ferments still, which may be known by raking and plunging with the flat of the rake in the vat ; being well raked, she is to remain' still for one hour and a half more, carefully observing whether she casts blue. She is then to be served with water, and the quantity of indigo judged necessary is to be put in ; it is commonly used in a liquid state, the full of a dye;* 1 31 house kettle for each bale of woad ; the vat being filled wiihiii six finger breadths of her brim, is to be raked and covered as before ; an hour after fib ling her with water she must be served with lime viz. two measures of lime for each bale of woad, giving more or less according to the qualuy of the w'oad, and what may be judged it will spend or take of lime. I hope the reader will excuse my plainness j this treatise being wrote for the dier, 1 must speak the language he is used to ; the philosopher will easily substitute proper terms, which perhaps the workman would rot understand. There are kinds of woad readier prepared than others, so that general and precise rules cannot be given on this head. It must also be remarked, that the lime is not to be put into the vat till she has been well raked. The vat being again covered, three hours after a pattern must be put in, and kept entirely cover ^ ed for an hour ; it is then taken out to judge, if she be fit to work. If she is, the pattern ttiiist come out green, and on being exposed a minute to the air, acquire a blue colour. If the vat gives a good green to the pattern, she must be raked, served w ith one or two measures of lime and cov- ered. Three hours after, she must be raked, and ser- ved with what lime may be judged necessary ; she is then to be covered, and one hour and a half af- ter, the vat being pitched or settled, a pattern is put in, which must remain an hour to see the effects of the woad. If the pattern is of a fine green, and that it turns to a deep blue in the air, another must fee dipt in to be certain of the effect of the yat. If 32 tills pattern is deep enough in colour, let the vat be filled up with hot water, or if at hand, with old li- quor of madder, and rake her well Should the vat still want lime, serve her with such a quantity as you may judge sufficient by the smell and hand^ ling. This done, she must be again covered, and one hour after put in your stuffs, and make your overture. 7'his is the term used for the first work- ing of wool or stufts in anew vat. Marks by which you may know how to conduct a vat regularly^ A vat is fit to work when the grounds arc of a green brown, when it changes on its being taken out of the vat, when the flurry is of a fine Turkish or deep blue, and when the pattern, which has been dipt in it for an hour comes out of a fine deep grass green. When she is fit to work, the bever has a good appearance, clear and reddish, and the drops and edges that are formed under the rake m lifting up the bever are brown. Examining the appearance of the bever, is lifting up the liquor with the hand or rake, to see what colour the liquor of the vat has under its surface. The sediment or grounds must change colour (as has been already observed) at being taken out of the bever, and must grow brown by being exposed to the exter- nal air. The bever or liquor must feel neither too rough nor too greasy, and must not smell cither of lime or lee. These are the distinguibiiing marks of a vat that is fit to work. 33 Mow to know when a Fat is cracked hy too ^reat or too small a quantity oj Lime ; extremes which must he avoided. When more lime has been put in than was suf- ficient for the woad, it is easily perceived by dip- ping in a pattern, which, instead of turning to a beautiful grass green, is only daubed with a steely green. The grounds do not change, the vat gives scarcely any flurry, and the bever has a strong o- dour of quick lime, or its lees. This error is rectified by thinning the vat, in which the diers differ ; some use tartar, others bran, of which they throw a bushel into the vat, more or less, in proportion to the quantity of lime used, others a pail of urine. In some places a large iron chafing dish is made use of, long enough to reach from the ground to the top of the vat, this chafing-dish or furnace has a grate at a foot dis- tance from its bottom, and a funnel coming from under this grate, and ascending to the top of the chafing-dish, which is to give air to, and kindle the coals which are placed on the grate. This fur- nace is sunk in the vat, near to the surface of the grounds, so as not to touch them, and is fastened with iron bars to prevent its rising. By this meth- od the lime is raised to the surface of the liquor, which gives an opportunity to take oflf with a sieve what is thought superfluous ; but when this is ta- ken out, the ne( essary quantity of ware must be carefully restored to the vat. Others again thin the vat with pearl ashi s, or tartar boiled in stale urine ; but the best cure, when she is too hardVis to put in bran and madder at discretion ; and if she be but a little too hard, it will suffice to let her 34 remain quiet, four, five, or six hours, or more^ puttin«' in only two hats full of bran, and three or four pounds of madder, wbicli arc to be lightly strewed on the vat, after which it is to be covered. Four or five hours after, she is to be raked and plunged, and according to the colour, that the fur- ry which arises from this motion, assumes and im- prints on the whole liquor, a fresh proof is made by putting in a pattern. If she is cracked, and casts blue only when she is cold, she must be left undisturbed, sometimes whole days without raking ; wdien she begins to strike a tolerable pattern, her liquor must be re- heated or warmed ; then commonly the lime, which seemed to have lost all power to excite a fermen- tation, acquires new strength, and prevents the vat from yielding its die so soon. If she is to be has- tened, some bran and madder are to be thrown on, as also one or two baskets of new woad, which helps the liquor that has been reheated to spend its lime. Care must be taken to putpatternsin each hour, in order to judge, by the green colour which they acquire , how the lime is worked on. B) these trials she may be coi^ducted with more exactness, for when ojice a vat is cracked, by too great or too small a quantity of lime, she is brought to bear with much more difficulty. If while you are en- deavouring to bring her to w'ork, the bever grow’s a little too cold, it ust be heated by taking off some of the clear, and instead thereof, adding some warm water ; for w hen thr bever is cold, the w’oad spends little or no lime ; when it is too hot, It retards the action of the w^oacl, and prevents it from spending the lime ; therefore it is better to 55 wait a little, than to hasten the vats to come to work when they are cracked, A vat is known not to have been sufficiently served with lime, and that she is cracked, when the bever gives no flur- ry, but instead lilt reol gives only a scum, and when she is plu ng which yields its colour cold, and is worked cold ; for this purpose four pounds of indigo are powdered, which is to be digested on warm ashes twenty four liours, in four quarts of vinegar ; if it is not then well dissolved, it must be ground again with the liquor, and urine is to be added little by little, with half a pound of madder, which must be well dilu- ted by stirring the liquor with a stick ; when this preparation is made, it is poured into a vessel fill, ed with 250 quarts of urine ; it matters not wheth- er it be fresh or stale ; the whole is well stirred and raked together night and morning for eight days, or till the vat appears green at the surface when raked, or that she makes flurry as the com- mon vat ; she is then fit to work, without more trouble than previously raking her two or three hours before. This kind of vat is extremely con- venient, for when once set to work, she remains good till she be entirely drawn, that is, till the in- digo has given all its colour ; thus she may be worked at all times, whereas the common vat must be prepared the day before. This vat may at pleasure be made more or less considerable by augmenting or diminishing the ingredients in proportion to the indigo intended to be made use of ; so that to each pound of indigo add a quart of vinegar, two ounces of madder, and sixty or seventy quarts of urine. This vat comes sooner to work in summer than in winter, and may be brought sooner to work by warming some of the liquor without boiling, and returning it in- to the vat ; this process is so simple that it is al- most impossible to fail. When the indigo is quite spent, and gives no more die, the vat may be charged again without setting a new one. For this purpose, indigo must be dissolved in vinegar, adding madder in pro- portioQ to the indigo^ pouring Uie whole into the r B7 ^ vat, and raking her night and morning, and eve- ning as at first, she will be as good as before ; I however she must not be charged this way above ? four or five times, for the ground of the madder t and indigo would dull the liquor, and in conse- quence render the colour less bright I did not i try this method, and therefore do not answer for I the success ; but here follows another with urine t which gives a very lasting blue, and which I pre- pared. Hot Fat with Urine, A pound of indigo was steeped twenty-four hours in four quarts of clear urine, and when the urine became very blue, it was run through a fine sieve into a pail, and tlie indigo which could not pass, and which remained in the sieve, was put with four quarts of fresh urine ; this was so continued till all the indigo had passed through the sieve with the urine ; this lasted about two hours. At four in the afternoon three hogslteads of urine wei»e put into the copper, and it was made as hot as could be without boiling. The urine cast up a thick scum, which was taken up with a broom and cast out of the copper. It was thus scummed at differ- enr times, till there only remained a white and light scum ; the urine, by this meane sufficiently purL fied and ready to boil, was poured into the wood-, en vat, and the indigo prepa ed as above, put in ; the vat was then raked, the better to mix the in- digo with the urine ; soon after, a liquor was put into the vat made of two quarts of lu ine, a pound of roach-alum, and a pound of red tartar. To make this liquor, the alum and tartar were first 58 put into the mortar, and reduced to a fine powder, upon which the two quarts of urine were poured, and the whole rubbed together, till this mixture, TV’hich rose all of a sudden, ceased to ferment : it was then put into the vat, which was strongly raked ; and being covered with its wooden cover, she was left in that state all night ; the next morning the liquor was of a very green colour ; this was a sign she was come to work, and that she might have been worked if thought proper, but nothing was died in her ; for all that was done, was only, •properly speaking the first preparation of the vat, and* the indigo which had been put in was only in- tended to feed the urine, so that to finish the prep- aration the vat was left to rest for two days always covered, that she might cool the slower ; then a second pound of indigo was prepared, ground with purified urine as before. About four in the after- noon all the liquor of the vat was put into the cop- per ; it was heated as much as possible without boiling ; some thick scum formed on it which was taken off, and the liquor being ready to boil was returned into the vat. At the same time the ground indigo W’as put in with a liquor made as above of one pound of alum, one pound of tartar, and two quarts of urine, a fresh pound of madder was also added ; then the vat was raked, well cov- ered, and left so the whole night. The next morn- ing she was come to work, the liquor being very hot, and of a very fine green, she was worked with wool in the fleece, of which thirty pounds were put into the vat. It was well extended and work- ed between the hands, that the liquor might the more easily soak into it ; then it was left at rest for an hour or two, according as lighter or deeper blues are required. 59 All this time the vat was well covered, that it might tiie better retain its heat, for the hotter she is, tlie better she dies, and when cold acts no more, \Vhen the wool came to the shade of the blue re- quired, it was taken out of the vat in parcels about the bigness of a man’s head, twisted and wrung over the liquor as they were taken out, till from green, as they w'ere coming out of the vat, they be- came blue. This change from green to blue is made in three or four minutes. These thirty pounds being thus died, and the green taken off, the vat w as raked, and suffered to rest for tvro hours, being ail that time w’ell covered ; then thir- ty pounds more were put in, which was well ex- tended with the hands, the vat was covered, and in four or five hours this wool was died at the height or shade of the first thirty pounds ; it was then taken out in heaps, and the green taken off as before. This done, the vat had still some little heat, but not sufficient to die fresh wool ; for when she has not a sufficient heat, the colour she gives would neither be uniform nor lasting, so that It must be re- heated, and fresh indigo put in as be- fore. This may be done as often as judged prop- er, for this vat does not spoil by age, provided, that whilst she is kept without working, a little air is let into her. Re .heating of the Vat with Urine. About four in the afternoon, the whole liquor •f the vat was put into a copper, and a sufficient quantity of urine added to this liquor, to make up the dificiency that had been lost by evaporation during the preceding work. This filling common- 60 ly takes eight or nine pails of urine ; the liquor was then heated and scummed as before, and when ready to boil, returned into the vat with a pound of indigo, and the liquor above described, consist- ing of alum and tartar, of each one pound, madder one pound and two quarts of urine. After raking the vat well, and covering her, she was left to rest the whole night. The next day she came to work, and sixty pounds of wool were died in her at twice as before, it is after this manner all the re-heatings must be done the evening before the dieing, and these re- heatings may extend to infinity, as the vat, once set serves a long time. I must here observe, that the greater the quan- tity of indigo put in at once is, the deeper the blue; thus instead of one pound, four, five or six pounds may be put in together ; nor is it necessary to augment the dose of alum, tartar, or madder, of which ingredients the liquor is composed ; but if the vessel hold more than three hogsheads, then the dose of these must be augmented in propor- tion. The vat I have mentioned held three; and was too small to die at one time a sufficient quan- tity of wool to make a piece of cloth, viz fifty or sixty pounds ; for this purpose it would be neces- sary that the vat should contain at least six hogs- heads, and from this a double advantage wf iild arise. 1. All the wool would be died in three or four hours, whereas dieing it at twice, it takes eight or ten hours. 2. At the end of three hours, in which time the woe] would be died, taken out, and the green taken off, the vat being vet very hot ; after raking and leiting her rest a couple of hf this observation, as well as in other chapters. The earthy parts of the lime precipitated next after the iron ; they are easily distinguished by the whiteness, which are yet difficult to distinguish when the colouring parts of the indigo are suffi- ciently loosened. In short, under this white earth the fecuia of the indigo deposits itstlf, and by de- grees ratifies in such a manner, that this substance which the first day was only the eighth of an inch above the precipitated lime, rose insensibly within half an inch of the surface of the liquor, and the third day grew so opaque and muddy, that nothing further could be distinguished. This rarefaction of indigo, slow in winter, quick in summer, and which may be accelerated in win- ter by heating the liquor to fifteen or sixteen de- grees, is a proof that a real fermentation happens in the mixture, which opens the little lumps of in- digo, and divides them into particles of an ex- treme fineness ; then their surfaces being multi- plied almost ad infinitum, they are so much the more equally distributed in the liquor, which deposits them equally on the subject dipped in to take the die. If fermentation comes on hastily, or in a few hours, whether on account of the heat of the air, or by the help of a small fire, a great quantity of flurry ap])ears ; it is blue, and its reflection they have also named coppery, because the colours of the rainbow appear in it, and the red and yellow here predominate ; however, this pha^uomenon is noi pecuiiar to indigo, since the same reflection is perceived in all mixtures that are in actual fer- mentation, and particularh in those which contain fat particles blended with salts, urine, soot, and several other bodies put into fermentation, show on their surface the same variegated colours. 73 The flurry of the indigo vat appears blue, be- cause exposed to the external air ; but if a small : portion of the liquor which is under it be taken up with a spoon, it appears more or less green in : proportion as it is filled with colouring particles- j In the course of this observation, I shall show the I reason of this difference, or, at least, a probable explication of this change of blue, which, as I have said before, is absolutely necessary for suc^ ! ceeding in the process described. When the vat is in this state, it has already been ; said that cotton, thread, cloths wovt from them, I tkc. may be died in her, and the colours w hich i they take are of the good die ; that is, this cotton and thread will maintain them, even after remain- ing a suitable time in a solution of white soap, ac. i tually boiling. This is the proof given them pre- ferable to any other, because the linen and cotton cloths must be w^ashed wdth soap when dirty. Though the indigo liquor which is in this state I can make a lasting die wnthout the addition of any I other ingredients ; the diers who use this cold vat 1 add, as in the other hot vats, a decoction of mad- I der and bran in common water run through a i sieve ; this is what they call beven They put I madder to insure, as they say, the colour of the ;i indigo, because this root affords a colour so ad. [I hesive that it stands all proofs ; they put the bran 1 to soften the water, which they imagine generally ! to contain some portion of an acid salt, which, according to their opinion, must be deadened. This was the opinion of French diers against in- digo in the days of Monsieur Colbert ; and as this minister could not spare time to see the experi- I meats performed in his presence, cn the founda. G 74 tion of this report, he forbade indigo to be used a- lone. But since the government has been con- vinced, by new experiments made by the late Mr. Dufay, that the stability of the blue die of this in- gredient was such as could be desired ; the new regulation of 1737 licences the diers to use it alone, or mixed with woad ; so that if they continue to use the madder, it is rather because this root giv- ing a pretty deep red, and this red mixing with the blue of the indigo, gives it a tint which ap- proaches the violet, and also a fine hue. As to the bran, its use is not to deaden the pre- tended acid salts, but to disperse throughout a quantity of sizey matter; for the small portion o£^ flour which remains in it, dividing itself into the liquor, must diminish in some measure its flu- idity, and consequently prevent the colouring par. tides which are suspended in it, being precipitat- ed too quick, in a liquor which had not acquired a certain degree of thickness. Not withsianding this distributed throughout the liquor, as well from the bran as the madder, which also affords something glutinous, the colouring particles will subside if the liquor remains some days without being stirred ; then the top of the liquor gives but a feeble tint to the body dipt in, and if a strong one is wanted, the mixture must be raked, and left to rest an hour or two, that the iron in the copperas, and the gross parts of the lime may fall to the bottom, which otherwise would mix with the true colouring particles, and prejudice their die, by depositing on the body to be died a substance that would have but little adhesion, which in drying would become friable, and of wot I : .1 n 75 where the true c ^‘ uring particle could neither in- iroduce nor deposu^tself by an immediate contact on the subject. Not to deviate from the method followed by the diers, I boiled one part of grape* madder and one of bran, in 174 parts of water ; this proportion of water is not necessary, more or less may be put, but I wanted to fill my vessel which contained 512 parts. I passed this bever through a cloth and squeezed it, putting this liquor, still hot, and which was of a blood-red, into the indigo liquor, observ- ing the necessary precautions to prevent the break- ing of the glass vessel. The whole was well stir- red, and two hours after the liquor was green, and consequently fit for dicing. I died cotton of a lasting blue, somewhat brighter than it was be- fore the addition of the red of madder. I shall now endeavour to find out the particular cause of the solidity of this colour ; perhaps it may be the general cause of the tenacity of all the rest ; for it appears already, from the experiments above related, that this tenacity depends on the choice of salts, which are added to the decoctions of the colouring ingredients, wdien the same ingredients contain none in themselves. If from the conse- quences \vhich shall result from the choice of these salts, of their nature, and of their properties, it be admitted (and it cannot be fairly denied) that they afford more or less tenuity in the homogeneous colouring parts of the dicing ingredients, the whole theory of this art will be discovered, without hav- ing recourse to uncertain or contested causes. One may easily conceive that the salts added to the indigo vats not only open the natural pores of the subject to bt died, but also unfold the col- ouring atoms of the indigo. 76 In the other preparations of d* ^\:o be mention- ed hereafter) the woolen stuiB'^art' boiled in a so- lution of salts which the Dyers call preparation. In this preparation tartar and alum are generally used. In some hours the stuff is taken out, slight- ly squeezed, and kept damp for some days in a cool place, that the saline liquor which remains in It may still act and prepare it for the reception of the die of these ingredients, in the decoction of which it is plunged to boil again. Without this prepa- ration, experience shows that the colours will not be lasting, at least for the greatest part; for it must be owned that there are some ingredients which yield lasting colours, though the stuff has not pre- viously undergone this preparation, because the ingredient contains in itself these salts. It is therefore necessary, that the natural pores of the fibres of the wool should be enlarged and cleansed by the help of those salts, which are aL -ways somewhat corroding, and perhaps they open aicw pores for the reception of the colouring atoms contained in the ingredients. The boiling of this liquor drives in the atoms by repeatejJ strokes. The pores already enlarged by these salts, are further dilated by the heat of the boiling water ; they are afterwards contracted by the ex- ternal cold when the died matter is taken out of the copper, when it is exposed to the external air, or when it is plunged into cold water. Thus the col- ouring atom is taken in, and detained in the pores or fissures of the died body, by the springiness of its fibres, which have contracted and restored themselves to their first state, and have re assum- ed their primary stiffness upon being exposed to the cold. 77 If, besides this spring of the sides of the pore, it be supp( sed that iheac series have been plaister- ed inwardly with a layer of die saline liquor, it will appear plainly that this is another means employ- ed by art to detain .he colouring atom ; for this atom, having entered into the pore, while the sa- line cement of the sides was yet in a state of solu. tion, and consequently fluid ; and this cement be- ing afterwards congealed by the external cold, the atom is thereby detained ; by the spring w hich lias been mentioned, and by this saline cement, which by chrystalization is become hard, forms a kind of mastic which is not easily removed. If the coloured atom, (which is as small as the little eminence that appears at the entrance of the pore, and without which the subject would not appear died) be sufficiently protuberant to be ex- posed to more powerful shocks than the resistance of the sides of the cement that retains it, then the die resulting from all these atoms sufficiently re- tained, will be extremely lasting, and in the rank of the good die, provided the saline coat, can neither be carried off by cold water, such as rain, nor cal- cined or reduced to powder b} the rays of the sun; for every lasting colour, or colour belonging to the good die, must withstand these two proofs. No other can reasonably be expected in stuffs de- signed for apparel or furniture. I know but of two salts in chymistry, which, be- ing once crystalized, can be moistened with cold water without dissolving ; and there are few be- sides these that can remain several days exposed to the sun, without being reduced to a flour or white powder. These are tartar, either as taken from the wine vessels, or purified, and tartar of vitrioL G 2 73 The tartar of vitriol may be made by mixing a salt already alkalized, (or that may become such when the acid is drove out with a salt whose acid is vit- riolic, as copperas and alum ;) this is easily effect- ed if it be weaker than the acid of vitriol, and such is the acid of all essential salts extracted from ve^- getables. In the process of the blue vat which I tried in small, to discover the cause of its effects, copperas and pot-ash, (which is a prepared alkali) are mixed together ; as soon as these solutions are united, the alkali precipitates the iron of the copperas in form of powder almost black ; the vitriolic acid of the copperas, divested of its metallic basis, by its ■union with the alkali, forms a neutral salt, called tartar of vitriol^ as when made with the salt of tar- tar and the vitriolic acid already separated from its basis ; for all alkalis, from whatever vegetables they are extracted, are perfectly alike, provided they have been equally calcined. More difficulties will occur with regard to the water for the preparation of other colours, such as reds and yellows. It may be denied that a tartar of vitriol can result from the mixture of alum and crude tartar boiled together ; yet the theory is the same, and I do not know that it can be other- wise conceived. The alum is a salt, consisting of the vitriolic acid united with an earth ; by adding an alkali, the earth is immediately precipitated, and the tartar soon forms ; but instead of this al- kaline salt, alum is boiled with the crude tartar which is the essential salt of wine, that is, a salt composed of the vinous acid, (which is more vol- atile than the vitriolic) and of oil, both conccntra- tcjl in a small portion of earth. 79 This salt, as is known to chymists, becomes al- kali by divesting it of its acid. Thus when the alum and crude tartar are boiled together, besides the impression which the fibres of the stdif to be died receive from the first of these salts, which is somewhat corrosive, the tartar is also purified, and by the addition of the earth, which is separated from the alum, (and which has near the same ef- feet upon the tartar, as the earth of Merviels, which is used at Montpellier, in manufacturing cream of tartar) it becomes clear and transparent. It may very probably happen, that the vitriolic acid of the alum, driving out a part of the vegetable acid of the tartar, a tartar of vitriol may be formed as hard and transparent as the crystal of tartar. Admit- ting one or other of these suppositions, consequent- ly there is in the open pores of the wool a saline cement which crystalizes as soon as the stuff which comes out of the die is exposed to the cold air, which cannot be calcined by heat, nor is solu- ble in cold water, I could not avoid making this digression. This theory is common to the indigo vat, where urine is used instead of water ; alum and crude tartar in the place of vitriol and pot- ashes. This urine vat gives a lasting die only when usedhot,and then the wool must remain in an hour or two to take the die equally. As soon as the vat is cold, she strikes no more die ; the reason of this would be difficult to discover in an opaque metal vat, but glass vessel it is easily seen. ^Klet tlijl little glass proof vat cool, and all the Hl||& col^r,^ which was suspended in it while hotf HpPpiUtedJlt by little to the bottom ; for then w taftar crystalizing itself, and reuniting in heav;» 80 icr masses than its moculas were during tlie heat of the liquor, and its solution, it sunk to the bot- tom of the vessel, and carried with it the colouring particles. When I restored this liquor to its former degree of heat, after shaking it, and letting it settle a while, I dipped a piece of cloth, which I took out one hour after, with as lasting a die as the first ; so that when this vat is used and fit to work, the tar- tar is to be kept in a state of solution, which can- not be done but by a pretty strong heat. The al- kali of the urine greens it, the alum prepares the fibres of the wool, and the crystal of tartar secures the die by cementing the colouring atoms depos- ited in the pores. There still remains a difficulty with respect to the indigo vat, in which neither vitriol, alum, or tartar are used, but only pearl ashes in equal quan- tity with the indigo, and which is pretty briskly heated to die the wool and stuffs. But before I enter into the cause of the solidity of its die, which is equal to that of the other blue vats where the other salts already mentioned enter, I must exam- ine into the nature of pearl ashes, which are the lees of wine dried and calcined : it is therefore an alkaline salt, of the nature of salt of tartar, but less pure, as proceeding from the heaviest parts of the dregs of wine, and consequently the most earthy ; besides, the alkali of the pearl ashes is never as homogeneous as the alkaline salt of tartar well caj- cined, and there are scarcely any .pearl ashes purified, from which a considerable ^uj^ity oj tar of vitriol may not be obtained ; able by an experiment which I hal it might at length be entirely convflP# Mit( 81 neutral salt ; the same may be said of pot aslies^ and of all other alkaline salts, whose basis are not that of the marine salt. The want of this homogeneous quality, is the cause that pearl-ashes never fall entirely into deli- quiumin the air; therefore since experience shows that there is a tartar of vitriol already formed in the pearl-ashes, it is evident that this indigo vat, which does not give a good die until the liquor has been so briskly heated as not to suffer the hand without scalding, will dissolve the small por- tion of tartar of vitriol that is contained in it, and consequently this salt will introduce itself into the pores of the wool to dense and cement them, and will coagulate therein on the wool being taken out of the liquor, and exposed to the air to cool. I must now give the reason why the indigo vat is green under the first surface of the liquor ; why this liquor must be green that the blue die may be lasting, and why the stuff that is taken green out of the liquor becomes blue as'soon as it is air« ed. All these conditions being of necessity com- mon to all indigo vats either cold or hot, the same explication will serve for them all. 1. The flurry which rises on the surface of the indigo liquor when it is fit die is blue, and the un- der part of this scum is green ; these two circum- stances prove the perfect solution of the indigo, and that the alkaline salt is united to its colouring ^oms since it greens them, for without they \vould fcmain blue. Jp2. These circumstances prove that there is al- the indigo a volatile urinous alkali, which ^PlTxt dkali of the pot- ash, or the alkaline earth 0f the lime displays, and which evaporates very 82 shortl}^ after the exposition of this scum to the air^ The existence of this urinous volatile appears : plainly by the smell of the vat during the fermen- tation ; when stirred, or when heated, tlie smell is sharp, and resembles that of stinking meat roas- ted. 3. In preparation of the anil, in order to sepa- rate the fecula, a fermentation is continued to pu- trefaction. All rotten plants are urinous. This volatile urinous quality is produced by the inti- mate union of salts with the vegetable oil, or is owing to a prodigious quantity of insects falling on all sides of fermenting plants, and attracted by the smell exhaling from them, wdiere they live, mul- tiply, and die in them, and consequently deposit a number of dead bodies ; therefore to this veget- able substance an animal one is united, whose salt is always an urinous volatile. This same urinous quality exists also in the woad, which is prepared after the same manner, viz. by fermentation and putrefac- tion, and which will be further explained in the abridged narrative of its preparation. 4. And lastly, if indigo or woad be distilled in a retort, either alone, or (which is much better) with some fixed saline or earthy alkali added to it, a liquor will be obtained, which by all chymi'" cal essays, produces the same effects as volatile spirits of urine. Why does not this volatile urinous quality in the indigo cause it to appear green, since it must b^ equally distributed through all its parts ? And wliy does indigo, being dissolved in plain boiling water, tinge it blue and not green ? It is becau^ this volatile urinous salt is not concreted tlrat*^ requires another body more active than boiling m water to drive it out of the particles surrounding it ; and the solution ot indigo is never perfected by water alone ; whatever degree of heat is given, it is only diluted, and not dissolved in it. Indeed this decoction of indigo blues the stuffs that are dipped, but the blue is not equally laid on, and boiling water almost instantly discharges it. I shall endeavour to answer this by an example drawn from another subject. \ Salt ammoniac, from which chy mists extract the most penetrating volatile spirit, has not that quick urinous smell by dissolving and boiling it in w'ater ; either lime, or fixed alkaline salt, must be added to disengage the urinous volatile parts. In like manner,the indigo requires fixed saline, or earthy alkalis, to be exactly discomposed, that its volatile urinous salt may be discovered, and that its colouring atoms may be reduced probably to their elementary minuteness. I now come to the second quality required. The liquor of the indigo vat must be green, that the die may be lasting ; for the indigo would not be exactly dissolved, if the alkali did not act upon it. Its solution not being as perfect as it ought to be, its die would be neither equal nor lasting ; but ns soon as the alkaline salts act upon it they must green it ; for an alkali, mixed wuth the blue Juice or tincture of any plant or flotver, immedi- ately turns it green, when equally distributed on all its colourifig parts. But if by evaporation these same parts colinn cd, or colouring, have re-united themselves into hard and compact masses, the alka- li will not change their colour till it has penetrated, divided, a*'id reduced tOem zo their primary fineness. This ia tl- cose with indi'fc;, whose fecula is the d V Cl -Le :.:dl 84 With respect to the last circumstance, which is that the staff must be green on coming out of the liquor, and become blue as soon as it is aired, without which, the blue would not be of a good die, the following reasons may be given : it is ta* ken out green because the liquoris green; if it was not, the alkaline salt put into the vat would not be equally distributed, or th^ indigo would not be ex- actly dissolved. If the alk. li was not equally distri- buted, the liquor contained i\\ the vat would not be equally saline: the bottom of this liquor would con- tain all the salt; the upper would be insipid. In this case, the stuff dipped in would neither be prepared to receive the die, nor to retain it ; l)ut when it is taken out green at the end of a quarter of an hour’s I dipping, it is a proof that the liquor was equally sa« line, and equally loaded with colouring atoms ; it is also a sign, that the alkaline salts have in- sinuated themselves into the pores of the fibres of the stuff, and enlarged them, as has been ob- served, and perhaps have formed new ones. Now there can be no doubt that an alkaline salt may have this effect on a woolen stuff, when it is evident that a very sharp alkaline ley burns and dissolves almost in an instant a flock of wool or a feather. A process in dicing, called by the Frtuch.Jbnte debourrcy that is, the melting or dissolving of flock or hair, is still a further example, the hair, which is used and boiled in a solution of pearl-ashes in urine, is so perfectly dissolved as not to leave the least fibre remaining. Therefore if a lixivium, extremely sharp, entirely destroys the wool, a ley which shall have but a quantity of alkaline salt suf- ficient to act on the wool without destroying it, will prepare the pores to receive and preserve the colouring atoms of the indigo. 85 The stuff is aired after being taken green out of the vat, and after wringing it becomes blue. What is done by airing ? it is cooled ; if it is the urinous volatile detached from the indigo which gave it this green colour, it evaporates, and the blue appears again ; if it is the fixed alkaline that causes this green, not only the greatest part is car- ried off by the strong expression of the stuff, but what remains can have no more action on the col- ouring part, because the small atom of tartar of vitriol, which contains a coloured atom still less than itself, is crystalized the instant of its exposi^ tion to the cold air, and contracting this same col- ouring atom by the help of the spring at the sides of the pore, it entirely presses out the remainder of the alkali, which does not crystalize as a neu- tral salt. The blue is roused, that is, it becomes brighter and finer by soaking the died stuff in warm water, for then the colouring particles which had only a superficial adherence to the fibres of tlie wool, arc carried off. Soap is used as a proof of the lasting of the blue die, and it must stand it, for the soap, which is only used in a small quantity in proper- tion to the water, and whose action on the died pat- tern is fixed to five minutes, is an alkali, mitigated by the oil, which cannot act upon a neutral salt. If it discharges the pattern of any part of its colour, it is because its parts were but superficially ad- hering ; besides, the little saline crystal which is set in the pore, whose use is to cement the colour- ing atom, cannot be dissolved in so short a time, so as to come out of the pore with the atom it re- tains. This treatise lavs down the essay of a method H 86 of dicing different from any hitherto offered. I appeal to philosophers, who would think little of a simple narrative of processes, if I did not at the same time give their theory. I shall follow this method in the other experiments on reds, the yellows, or other simple colours, as it is absolute- ly necessary to have a knowledge of them before entering on the compound, as these are general- ly but colours laid on one after the other, and seldom mixed together in the same liquor or de- coction. Thus having once the knowledge of what pro- cures the tenacity of a simple colour, it will be more easily known, if the second colour can take place in the spaces the first have left empty without displacing the first. This is the idea which I have formed to myself of the arrangement of different colours laid on the same stuff, for it appears to me a matter of great difficulty to conceive that the colouring atoms can place themselves the one on the other, and thus form kinds of pyramids, each still preserving their colour, so that from a mixture of the whole a com- pound colour shall result, and which, notwithstand- ing, shall appear uniform, and as it were homoge- nev)us. ToBdopt this system, we must suppose a transparency in these a'oms, which it would be difficult to demonstrate ; and further, that a yellow atom must place itself immediately on a blue one, already set in the pore of the fibre of a ^>tuff, and that it must remain there strongly bound, so that they must touch eac'h other with exo'c me smooth surfaces, and so with every new colour laid on. It is not easy to conceive all this, and it appears more probable that the firi'st colour has only taken 87 up tlie pores that it found open by the first prepa- ration of the fibres of the stuff ; that on the side of these pores there remains more still to be filled, or at least spaces not occupied, where new pores may be opened to lodge the new atoms of a second coU our, by the means of a second preparation of wa- ter, composed of corroding salts, which being the same as those of the first preparing liquor, will not destroy the first saline crystals introduced into the first pores. What has been already said with regard to the indigo vat, may also serve to explain the action of the woad vat on wool and stuffs ; it is only suppos- ing in the woad, that salts do naturally exist, pret- ty near of affinity to those that are added to the in- digo vat. It appears by the description given of these vats, that the woad vat is by much the most difficult to conduct. I am convinced that these difficulties might be removed, if an attempt was made to prepare the isatis as the anil is in the West Indies. I shall therefore compare their dif- ferent preparations. I have taken the following narrative from the memoirs of Mr. Astruc’s His^ toire JVaturelle' du Languedoc. Paris^ Cavalier 1737, in 4to, p. 330 and 331. “ According to the opinion ofdiers, woad only ‘‘ gives feeble and languishing colours ; whereas ‘‘ those of the indigo are lively and bright. This opinion I grant is conformable to reason ; the indigo is a fine subtle powder ; consequently “ capable to penetrate tlie stuffs easily, and give them a shining colour. The woad, on the con- “ tran , is only a gross plant, loaded with many “ earthy parts, which slacken the action and motion “ of the finer parts, and prevent them from acting effectually^ 88 I know but one way to remove this inconven- ** iency, that is, to prepare the wo.ad after the same “ manner the indigo is prepared ; by this means, the colours obtained from the woad would ac- quire the lively and bright qualities of those “ procured from the indigo, without diminishing in the least the excellency of the colours pro- duced by the woad. “ I have already made in small^ experiments on what I propose, and those experiments have “ succeeded, not only in the preparation of the powv der of woad, but also in the use of this powder for dicing/^ It is incumbent on those who have the public good at heart, to cause trials at large to be made, and if they have the success that can reasonably be expected, it wdll be proper to encourage those who cultivate w^oad, to follow this new method of pre- paring it, and offer premiums to enable them to sustain the expenses this new practice will engage them in, until the advantage they will reap from it may be sufficient to determine them to follow' it. I shall now propose the means to succeed in Mr. Astruc’s experiments, and these means natu- rally result from considering the method used in Languedoc for the preparation of woad, and the ingenious method by which they separate the fec- ula of the anil in America. I have already given the preparation of this last ; those who desire a full- er description may consult VHistoire des Antilles dll P, du Tertre, ^ du P. Labat. The following preparation of the pastel, or garden woad, is thus described by Mr. Astruc. * As this ingenious man has succeeded in small experimenp, it is probable he would also in the large ones ; and then this plant easily cultivated in Englano, would weQ r-ecompense tbe pains of tbe^ husbandman. 89 Tk^ manufacturing of Pastel, or Garden W oady in France, Peasants of Abbigevois distinguish two kinds of woad seed ; the one violet colour, the other yel- low ; they prefer the form*, r, because the woad that shoots from it bears leaves that are smooth and polished, whereas those that spring from the ) el- lovv are hairy ; this filU them with earth and dust, which makes the woad prepared from them of a worse quality. This woad is called pastelbourg, or bourdaigne. The woad at first shoots five or six leaves out of the ground, which stand upright whilst green ; they are a foot long, and six inches broad ; they begin to ripen in June ; they are known to be ripe by their falling down and growing yellow ; they are then gathered, and the ground cleared from weeds, w hich is carefully repeated each crop. If there has been rain, a second crop is obtain- ed in July ; rain or dry weather advances or retards it eight days. The third crop is at the latter end of August ; a fourth the latter end of September; and the fiftli and last about tlie tenth of November. This last crop is the most considerable, the inter- val being longer. The plant at this crop is cut at the root from whence the leaves spring. This woad is not good, and the last crop is forbid by the regulations. The w'oad is not to be gathered in foggy or rainy w^eather, VmX in serene w'caiher, when the sun has been out some time. At each crop the leaves are brought to the mill to be ground, and reduced to a fine paste ; this is to be done speedily, for the leaves hen led in a heat ferment, and soon rot w idi an intolerable stench, H 2 90 These mills are like the oil or bark- mills, that is, a . mill-stone turns round a perpendicular pivot in a j circular grove or trough, pretty deep, in which the i woad is ground. The leaves thus mashed and reduced to a paste, i are kept up in the galleries of the mill, or in ahe i l>pen air. After pressing the paste well with the hands and feet, it is beat down and made smooth with a shovel. This is called the woad piled. An outward crust forms, which becomes black- ish ; when it cracks, great care must be taken to close it again. Little worms will generate in these crevices and spoil it. The pile is opened in i . a fortnight, well worked between the hands, and ; the crust well mixed with the inside ; sometimes ’ this crust requires to be beat with a mallet to knead it with the rest. This paste is then made into small loayes or round balls, which according to the regulations, must weigh a pound and a quarter. These balls are well pressed in the making, and are then given to another, who kneads them again in a wooden dish, lengthens them at both ends, making them oval and smooth. Lastly, they are given to a third, who finishes them in a lesser bowl dish, by pressing and perfectly uniting them. The pastel or woad thus prepared is called tel en Cocaigne ; whence arises the proverb, Pais de Cocaigne ; w^hich signifies a rich country, be- cause this country^ where the woad grows, en- riched itself formerly by the commerce of this drug. ^L'Ahigt/ois tf 91 These balls* are spread on hurdles, and ex- posed to the sun in fine weather ; in bad weather they are put at the top of the mill. The woad that has been exposed some hours to the sun, becomes black on the outside, whereas that which has been kept within doors is generally yellowish, particu- larly if the weather has been rainy. The mer- chants prefer the former ; this makes little differ- ence as to its use ; it is in general always yellow- ish, as the peasants mostly work it in rainy weath- er when they cannot attend their rural employ- ments. In summer, these balls are commonly dry in fifteen or twenty days, whereas in autumn those of the last crop are long in drying. The good balls when broke are of a violet col- our within, and have an agreeable smell ; where- as those that are of an earthy colour and a bad smell, are not good ; this proceeds from the gath- ering of the woad during the rain, wdien the leaves were filled with earth. Their goodness is also known by their weight, being light when they have taken too much air, or rotten by not having been sufficiently pressed. Powder of woad. Of these balls well prepared, the powder of woad is to be made ; for this purpose a hundred thousand at least are required. A distant barit or a warehouse must be procured, larger or smaller according to the quantity intended to be made. It • There J8 a place m India, the name I do not recollect, where the anil is yrepared after the manner of the woad, and the indigo comes from it in lumps, •ra^ining all the useless yarti of thw plaul. ft is Teiy difficult to prepare a 92 must be paved with bricks and lined with the same to the height of four or five feet : the walls would be better to be of stone to that height, yet often the walls are only coated with earth : this coat breaking off and mixing with the woad is a great prejudice to it. In this place the balls are reduc- ed to a gross powder with large w^ooden mallets. This powder is heaped up to the height of four feet, reserving a space to go round, and is moistened with w^ater ; that which is slimy ^ is best provided it be clear ; the woad thus moistened, ferments,, heats, and emits a very thick stincking vapour. It is stirred every day for tw^elve days, flinging it by shovels full frome one side to the other, and moistening it every day during that time ; after which no more water is flung on, but only stirred every second day ; then every third, fourth, and fifth ; it is then heaped up in the middle of the place, and looked at from time to time, to air it in case it should heat. This is the pastel or garden woad powder fit for sale to the Diers. Mr. Astruc, to prove that the sale of woad for- merly enriched the higher Languedoc, quotes the following passage from a book entitled Le Mar^ chand, “ Formerly they transported from Toulon ze to Bordeaux, by the river Garonne, each year a hun» dred thousand bales of woad, which on the spot are worth at least fifteen livres a bale, which a- mounts to 1,500,000 livres ; from whence pro- ceeded the abundance of money and riches of that * 1 can see no reason why slimy water, and yet to be clear, is preferred. It appears to me that clear river water would he more secure ; with this they would avoid the inconveniences that must attend a standing water, always filled with filth ; or of a muddy water, which contains useless earth, and wbkb must make the die uneven. 93 cGuntry.” Castel in his Memoirs de H Histoire iu Languedoc, in 1633, p. 49. The comparing of these two methods of pre- paring the woad and indigo, may be sufficient to a person of understanding, who might be appoint- ed to try, by experiments, the possibility of ex- tracting a fecula from the isatis of Languedoc like that of the anil. It is neither the Dier or Manufacturer that ought be applied to for that purpose ; both would condemn the project as a novelty, and it would require many experiments, which in general they are not accustomed to. I could wish this experiment was tried in great, so that at least fifty pound of this fecula might be got, that several vats might be set in case the first should fail. Whosoever does try it, should be very careful to describe all the circumstances of the process. Perhaps it might not succeed at the first crop of the leaves of the woad, because the heat in June is not sufficient, but probably he might meet with success in August. If this succeeds, there are without doubt seve- ral other plants of the same quality as the isatis, and which yields a like fecula. It is also probable that the dark green of seve- ral plants is composed of yellow and blue parts ; if by fermentation the yellow could be destroyed the blue would remain. This is not a chimerical idea, and it is easy to prove that some use might be derived from such an experiment. 94 CHAPTER VIII. OF RED. i RED. as has been said, is one of the primaiy I or mother colours of the diers. In the great die there are four principal reds, which are the basis of the rest. These are, 1. Scarlet of grain. 2. The scarlet, now in use, or flame-coloured scarlet, formerly called i Dutch scarlet. 3. The crimson red. And, j 4. The madder red. | There are also the bastard scarlet and the bas- | tard crimson ; but as these are only mixtures of I the principal reds, they ought not to be consider- ed as particular colours. The red, or nacaret of bourrCy* was formerly permitted in the great die. All these different reds have their particular shades from the deepest to the lightest, but they form separate classes, as the shades of the one never fall into those of the other. The reds are worked in a different manner from the blues, the wool or stuffs not being im- mediately dipped in the die, but previously re- ceiving a preparation which gives them no colour, but prepares them to receive that of the colouring ingredient* This is called the water of preparation ; it is commonly made with acids, such as sour waters, ♦This colour is given with weld and goat’s hair boiled in pot ashes, and i»4i. bright orange red. 95 iliim and tartar, aqua fortis, aqua regalis, See. These preparing ingredients are used in different quantities, according to the colour and shade re- quired. Galls are also often used, and sometimes ilkalinc salts This I shall explain in the course d 1 this treatise, w hen I come to the method of ivorking each of these colours. CHAPTER IX. OT SCARLET OF GRAIN. THIS colour is called scarlet of grain, because it is made with the kermes, which was long thought to be the grain of the tree on which it is found. It iwas formerly called French scarlet, imagining to be first found out in France, and is now kno^JP by the name of Venetian scarlet, being much m use there, and more- made than in au} other place. The fashion passed from thence into France and other countries. It has indeed less lustre, and is :jg< brov.ner than the scarlet now in fashion ; buf itJ'C has the advantage of keepirtg its brightiiess longerj^ and does not spo. by mud o; acid liquors. Thi kermes is a gall insect, whi( h is bred, lives and muiiij'lies upon the ihx accuieato cocci glan* discra, C B P. Some comes fr om Nai bonne, bui greater quantifies frt.m Alicant and Valentia, and the pco'^ants of Languedoc yearl) bring it to Montpelier and Narb«jnne. The merchants who buy them to send abroad, spread them on cloths, and sprinkle them with vinegar, in order to kill the little insects that are witbm, which yield a red. % powder, which is separated from the shell after drying, and is then passed through a sieve ; this is done particularly in Spain. They then make it up in bales, and in the mid- dle of each a quantity of this powder is inclosed in a leather bag, in proportion to the whole bale. Thus each dier has his due proportion of this powder. These bales are generally sent to Mar- seilles, from whence they are exported to the Le- vant, Algiers and Tunis, where it is greatly made use of in dieing. The red draperies of the figures in the ancient tapestry of Brussels, and other manufactories of FiaRflers, are died with this ingredient; and some that have been wrought upwards of two hundred years, have scarcely lost any thing of the bright- ness of the colour. I shall now proceed to give th£ method of making this scarlet of grain, which now seldom used but for wools designed for ta- pestry. Preparation of the Wool for Scarlet of Grain. Twenty pounds of wool and half a bushel of ^%fan are put into a copper, with a sufficient quan- tity of water, and suffered to boil half an hour, stir- ring it every now and then ; it is then taken out to drain. It is necessary to observe, that whenever spun wool is to be died, a stick is passed through each hank (which commonly weighs one pound) and they remain on the stick during the course of the work to prevent their entangling. This stick al- so enables the dier to return the hanks with more ease, by plunging each part successively in the Ji- 97 ^uor, by which they take an equal die ; by raising the hank with a stick, and drawing it hjilf way out of the copper, seizing the other end of the hank with the other hand, it is plunged towards the bottom. If the wool be too hot, this may be done with two sticks, and the oftener this is repeated, the more even will be the die ; the ends of the sticks are then placed on two poles to drain. These poles are fixed in the wall above the cop- per. Liquor for the Kermes. While this prepared wool is draining, the cop- per is emptied, and fresh water put in, to which is added about a fifth of sour water, four pounds of Roman alum grossly powdered, and two pounds of red tartar. The whole is brought to boil, and that instant the hanks are dipped in (on the sticks) which are to remain in for two hours,stirring them continually one after the other after the method al- ii eady laid down. I must in this place observe, that the liquor in which the alum is put, when on thepoint of boiling, sometimes rises so suddenly ihat ircomes over the * copper, if not prevented by addirfg cold water. If, when it is rising, the spun woof is instantly- put in, it stops it and produces the same effects as cold water. The liquor does not rise so suddenly when there is a large quantity of tartar as in the process ; but 1 when the alum is used alone, sometimes above I half the liquor comes over the copper when it be- ' gins to boil, if not prevented by the method de- i scribed. I When the wool has boiled two hours in this li- quor, it is taken out, left to drain, gently squeezed and put into a linen bag, in a cool place for fivt or six days, and sometimes longer ; this is called leaving the wool in preparation. This is to make it penetrate the better, and helps to augment the ac- tion of the salts, for as a part of the liquor always flies olF, it is evident that the remaining, being ful- ler of saline particles, becomes more active, pro, vided there remained a sufficient quantity of hu, midity ; for these salts being crystahzed and dry, would have no more action. I have dwelled much longer on this preparing liquor, and the method of making it, than I shall in the sequel, as there are a great number of col- ours for which it is prepared pretty near in the same proportion, so that when this happens, I shall slightly describe it, mentioning only the changes that are to be made in the quantity of alum, tartar, sour water or other ingredients. After the spun wool has been covered five or six days, it is fitted to receive the die. A fresh liquor is then prepared according to the quantity of wool to be died, and when it begins to be lukewarm, take 12 ounces of powdered kermes for each pound of wool to be died, if a full and well . coloured scarlet is wanted. If the kermes wa^ old ^nd flat, a pound of it would be required to each pound of wool. When the liquor begins to boil, the yarn (still moist, which it will be if it has been well wrapped in the bag, and kept in a cool place) is put in. If it had been boiled a long time before, and grown dry, it must be lightly passed through luke-warm water, and well squeezed before it IS died. 99 Previous to its being dipped in the copper witji the kermes, a handful of wool is cast in, which is let to boil for a minute : this takes up a kind of black scum, which the kermes cast up, by which the wool that is afterwards dipped acquires a finer colour. This handful of wool being taken out, the prepared is to be put in. The hanks are pass- ed on sticks as in the preparation, continually stirring, and airing them one after the other. It must boil after this manner an hour at least, then taken out and placed on the poles to drain, after* wards wrung and washed. The die still remaining in theliquPs‘inay serve to dip a little fresh parcel of preparcid wool ; it will take some colour in proportion ^o the good- ness and quality of the kermes put into the cop- per. When different shades are wanted, a less quan- tity of kermes is used, so that for twenty pounds of prepared wool, seven or eight are sufficient. The quantity of wool that is to have the lightest shade is first to be dipped, and to remain no long- er in than the time sufficient toturn it and make it take the die equally. Then the next deepest shade intended is dipped, and left to remain some time longer ; after this manner the work is con- tinued to the last, wdiich is left as long as is requi.. site to acquire the necessary shade. The reason of W’orking the lightest shades first, is, that if the yarn is left too long in, no damage is done, as that hank may serve for a deeper shade, whereas, if they begin by a deeper, there would be no remedy if a failure happened in some of the hghter shades. The same caution is to be taken in all colours whose shades are to be different. 100 There are seldom more shades than one from the colour now spoken of ; but as the working part is the same for all colours, what has been said on this subject will serve for the rest. The yarn thus died, before bringing it to the river, may be passed through lukewarm water, in which a small quantity of soap has been perfectly dissolved ; this gives a brightness to the colour, but at the same time saddens it a little, that is, gives it a little cast of the crimson. As I shall often make use of the terms rotizing2C[id saddening especially in the acids, it is necessary to explain their meandg. Saddening^ is giving a crimson or violet cast to red ; soap and alkaline salts, such as ley of ashes, pot- ashes, lime, sadden reds ; thus they serve to bring them to the shade required when too bright and that they are too much rouzed. Rouzing, is doing quite the reverse ; it is giving a fire lo the red, by making it border on the yel- low or orange. I'his is performed on wool by the means of acids, as red or white tartar, cream of tartar, vinegar, lemon juice, and aqua fortis. These acids are added, more or less, according to the depth of the orange colour required. For ex- ample, if the scarlet of grain w^as w^anted to be more bright, and approach somewhat nearer to commoii scarlet, a little of the scarlet composition which shall be spoken of, must be poured into the liquor after the kermes is put in, and the brown colour of thatliquor would immediatel} be brighten- ed by the acid, and become of a brighter red ; the wool dipped in would be more liable to be spot- ted by mud and acid liquors ; the reason will ap- pear in the next chapter# 101 I have made various experiments on this colour, in order to make it fitter and brighter than what it generally is, but I never could extract a red that was to be compared to that of cochineal. Of all the liquors which I made for the prepa- ration of the wool, that winch was made with the preparations just mentioned succeeded best. By changing the natural die of the kermes, by difier- ent kinds of ingredients of mctalic solutions, &c. various colours are made, which I shall immedi- ately speak of, I shall say but little about dicing stuffs with this red, as the proportion cannot be prescribed for each yard of stuff, on account of their breadth and thickness, or the quantity of wool entering their composition ; practice alone will teach the necessary quantity for each sort of stuff ; however not to work in the dark, or to try experiments at random, the surest way will be to weigh the stuffs, and todiminishabout yne fourth part ofthe colour* ing ingredients laid dowai for spun wool, as stuffs take up less colour inwardly, their texture being more compact, prevents its penetration, whereas yarn or wool in the fleece receives it equally with- in and without. The aluni and tartar for the liquor of prepara- tion for the stuffs must be diminished in the same proportion, and they are not to remain in the pre- paring liquor as long as the wool. It may be died the next day after boiling. If wool in the fleece is died with the red of the kermes, either to incorporate it with cloths of a mixed colour, or to make full cloths, it will have a much finer effect than if the wool had been died in the red of madder. I shall mention this in d€- 12 102 scribing the compound colours in which the ker- mes is used, or ought at least to be used in prefer- ence to madder, which does not give so fine a red, but, being cheaper, is commonly substituted 'for it. Half grain scarlet, or bastard scarlet is that which is made of equal parts of kermes and mad- der. This mixture affords a very holding colour, not bright, but inclining to a blood red. It is prepared and worked in the same manner as that made of kermes alone. This die is much cheap- er, and the diers commonly make it less perfect by diminishing the kermes and augmenting the madder. By the proofs that have been made of scarlet of grain or kermes, whether by exposingitto the sun or by different proofs, it is certain there is not a more holding or a better colour ; yet the kermes is no where in use but at Venice. The mode of this colour has been entirely out since the making of flame-coloured scarlets. This scarlet of grain is now called a colour of bullock’s blood ; ne\er- theless, it has great advantages over the other, for it neither blackens nor spots, and grease may be taken out without prejudice to its colour ; but it is out of fashion and that is sufficient, 'fhis has entirely put a stop to the consumption of ker- mes in France. Scarce a dier knows it, and when Monsieur Colbert wanted a certain quanti- ty for the experiments above related, he was obli- ged to send for it to Languedoc, the merchants of Paris keeping only a sufficiency for medicinal pur- poses. When a Dier is obliged to die a piece of cloth, known yei under Uie name of scarlet of grain, as 105 he has neither the knowledge of the kermes, nor the custom of using it, he makes it of a cochineal, as I shall relate in the following chapter ; it comes dearer, and is less holding than that made of kcr- mes. The same is done in regard to spun wool designed for tapestries, and as this shade is pretty difficult to hit with cochineal, they commonly mix brazil wood, which hitherto has been a false ingredient, permitted only in the lesser die. For this reason all these kind of reds fade in a very short time, and though they are much brighter than required, coming out of the hands of the workman, they lose all their brightness ; before the expiration of a year,, they whiten or become ex- ceeding grey ; it is therefore to be wished that the use of kermes was again established. It is also certain, that if some Dier set about u sing it, there are several colours that might be ex- tracted from it with more ease and less expense than the common method ; for these colours would be better and more holding, and he would thereby acquire a greater reputation. I have made above fifty experiments with the kermes, from which some use in practice may arise; I shall only relate such as have produced the most sin- gular colours. By mixing the kermes with cream of tartar^ without alunii, and as much of the composition as would be used for the making of scarlet with cochineal, you have in one liquor an exceeding bright cinnaniCMi, for nothing but the acid enter- ing in the mixture, the red parts of the kermes , become so minute that they almost escape the sight But if* this cinnamon colour be passed trough a liquor oi Roman alum, part of this red 104 appears again ; whether it be by the addition of the alum, that drives out a part of the acid of the com- position, or the earth of the alum precipitated by the astriction of the kermes, \vhich has the effect of galls, I know not ; but this red thus restored is not fine. With cream of tartar (the composition for scar- let) and alum, in greater quantity than tartar, the kermes gives a lilac colour, which varies ac- cording as the proportion of ingredients are changed. If/^h the place of alum and tartar, ready pre- pared tartar of vitriol is substituted, which is a very hard salt, resulting from the mixture of the vitriolic acid and a fixed alkali, such as the oil of tartar, pet ashes, &c, and if, Isay, after boiling the kermes in a solution of a small quantity of this salt, the stuff be dipped in and boiled one hour, it acquires a tolerable handsome agath grey, and in which very little red is seen, for the acid of the composition having too much divided the red of the kermes, and the tartar of vitriol, not containing the earth of the alum, it could not re-unite these red atoms dispersed by precipitation. These a- gath greys are of the good die, for, as I have ob- served in the chapter treating of indigo, the tar- 'tar of vitriol is a hard salt, which is not calcined by the sun, and is indissoluble in rain water. Glauber salts mixed with the kermes entirely destroy its red, and give an earthy grey that does not stand the proof, for this salt neither resists cold water nor the rays of the sun, which reduce it into powder. Vitriol or green copperas, and blue vi- friol separated substituted for alum,, but joined 105 to the crystal of tartar, equally destroy or veii the red of the kermes, which in these two exper- iments produce the same effect as if galls or su- mach had been made use of; for it precipitates the iron of the green vitriol, and dies the cloth of a grey brown, and the copper of the blue vitriol dies it of an olive. Instead of blue vitriol, I used a solution of cop- per* in aque fortis, which also prduced an olive colour ; a convincing proot that the kermes has the precmitating quality of the galls, since it pre- cipitates the copper of the vitriol as a decoction of gall-nut would. There is great probability that what renders the red of the kermes as holding as that of madder, is from the insects feeding on an astringent shrub, which notwithstanding the changes made by the digestion of the juices of the plant, still retains the astringent quality of the vegetable, and consequently the virtue, and so gives a great- er spring to the pores of the wool to contract themselves quicker and with greater strength, when it comes out of the boiling water, and is ex- posed to the cold air ; for I have observed that all barks, roots, wood, and other matters thai have some astriction, yield colours of the good die. Violets without Blue, The white vitriol of glosar, whose basis is the zinck, being joined with the chrysial of tartar, changes the red of the kermes into violet. Thus with one colouring ingredient, and simple chaR- “^erdigrise. 106 gcs, violets are made without a blue ground ; for this compound colour, hitherto only obtained by putting a blue on a red, or a red on a blue, is made as well with cochineal, or even with mad* der, as shall be shown treating of these two ingre- dients. White vitriol being extracted from a mine, containing lead, arsenic, and several other matters, whose recrements melted afterwards with sand and alkaline salts, vitrifies into a blue mass, called safre» I suspected the white vitriol might contain a portion of this blue, which, with the red of the kermes might have changed to a violet and consequently that the mine of the bismuth, which really contains this blue matter, and the bismuth itself would produce the same effect as white vi- triol ; neither was I mistaken in my conjecture ,• for having put some of the extract of the mine of bismuth in the liquor of kermes, and some of the solution of the bismuth itself upon another decoc- tion of the same ingredient, they both died cloth of a violet colour. I shall not here give the pro^ cess of extracting the mine of bismuth, for it is a difficult operation for a dier. However if the reader is desirous to know what I mean by the extraction of the mine of bismuth, he will find the process in the Royal Academy of Sciences for the year 1737, where there is a memoir on sym- pathetic inks. As to the solution of bismuth, which produces almost the same effect, it is made after the following manner: Take four parts of spirits of nitre, and four parts of very clear water, which mix together, and dis- solve therein one part of bismouth, or tin glass, broken in small pieces, put the last little by little into the liquor, lest they should occasion too vio- 107 lent a fermentation. Acids put in too great abun- dance in the liquor of the kermes, whether it be spirits of vilriuL aqua fortis, vinegar, lemon juice, even sour water, so greatly divide the red colour- ing particles, that the cloth receives but a cin- namon colour, bordering on the aurora, if there is too much acid, and a little redder if there is less. Fixed alkaline salts, mixed with sour water and cream of tartar, in the place of alum, do not de- stroy the red of the kermes as acids do, but sad, dens and muds it if too much be put in, so that the clolh receives only a faded lilac colour. Other experiments, still more diversified than those here related, presented an infinite variety of colours, but nothing more beautiful than what may be done with cheaper drugs than the kermes ; I shall therefore pass them over. CHAPTER X. yLAME-COLOUR£D SCARLET. FLAME coloured scarlet, that is, bright-coL ©ured scarlet, known formerly under the name of Dutch scarlet, (the discovery of which Kunkel at- tributes to Kuster, a German chymist) is the finest and brightest colour of the die. It is also the most costly, and one of the hardest to bring to perfection. It is not easy to determine the point of perfection, for independent of different tastes •onceming the choice of colours, there are also general i^cie^ which make certain colours more 108 ’ in fashion at one time than another ; when this happens, fashionable colours become perfect ones. Formerly scarlets were chosen full, deep, and of a degree of brightness which the sight easily bore. At this time they must be on the orange, full of fire, and of a brightness which dazzles the eye, 1 shall | not decide which of these two fashions deserve the ' preference, but shall give the method of making them both, and all the shades which hold a medi- um between these extremes. Cochineal, which yields this beautiful colour, and is also called mesiick> or tescalle, is an insect that is gathered in great quantities in Mexico. The natives and wSpaniards, who have but small establishments there, cultivate them, that is, care- fully gather them from the plant on which they feed before the rainy season. They kill and dry those designed for sale, and preserve the rest to multiply when the bad season is over. This in- sect feeds and breeds upon a kind of prickly opun- tia, which they call topal. It may be preserved in a dry place for ages without spoiling. The cochineal sv Ivestre, or campessiane, is also brought from Vera Cruz. The Indians of old and New Mexico gather this kind in the woods ; it feeds, grows and generates there, on the wild uncultivated opuntins ; it is there exposed in the rainy season to all the humidity of the air, and dies naturally. This cochineal is always smaller than the fine or cultivated ; the colour is more holding and better, but has not the same brightness, nei- ther is it profitable to use it, since it requires four parts, and sometimes more, to d(^ what may be done with one of fine. Sometimes they have damaged cochineal at 10!) Cadiz ; this is fine cochineal that has been wetted with salt water, occasioned by some shipwreck or leakage. These accidents considerably diminish the price, the sea salt saddening the die. This kind serves only to make purples, and even those ar^ot the best. However, a person in 1735 found ihesecret to turn this to almost as much advantage for scarlet as the finest coc hineal. The discovery of this secret is easy, but let him that possesses it enjoy it, 1 shall not deprive him of the advantage he might have in it. Every dier has a particular receipt for dicing scarlet, and each is fully persuaded that his own is preferable to all others ; yet the success depends on the choice oF the cochineal, of the tvater used in the die, and on the manner of preparing the so- lution of tin, which the diers call composition of scarlet. As it is this composition evhich gives the bright flame colour to the cocifmeal die, and which witli- out this acid liquor would naturally be of a crim- son colour, 1 shall describe the preparation that succeeded best with me. Com posh ion Jar Scarlet, Take eight ounces of spirit of nitre, (wl)icb is always purer than the common aqua fortis mostly used by the diers) and* be certain that it contains •Dissolve in a small quantity of spirit of nitre as much silver as it will take ; jxita few drops of this into some of tne spirit of nitre that is to be proved : if this spirit remains transparent, it is pnrej but if a white clojid be perceirea which will afterwards form a sedi:uent, it is a sign. that there is a comuiiscture of vitriol or spirit of salt. In order therefore to render the spirit of nitre al>- soluply pure, drop the solution of silver gradually into it, so long as it shall produce the least turbidness, time being given for the spirit to become clear •betwixt each addttioc. The spirit of nitre being then poured off from tiese4- 110 no vitriolic acid ; weaken this nitrous acid by put- ting it into eight ounces of hitered river water; dis- solve in it, little by little, halt'un ounce of very white salt ammoniac, to make it an aqua regia, because spirits of nitre alone will not dissolve block- tin. Lastly, add two drachms of salt- petre; thismigh»l:)e emitted, but I observed that it was of use in making the die smooth and equal. In this aqua regia thus weakened, dissolve one ounce of the bestbiock- tin, which is first granulated or made small while melted by casting it from a height into a vessel of cold water. These small grains of tin are put into the dissolvent one by one, letting the first ■dissolve before putting in others ; this prevents the loss of the red vapours, w^hich would rise in great abundance, and be lost if the dissolution of the metal was niiide too hastily ; it is necessary to preserve these vapours, and asKunkel observed, they greatly contribute towards the brightness of the colour, either because these vapours are acids that evaporate and are lost, or contain a sulphur peculiar to saltpetre, which gives a brightness to the colour. This method is indeed much longer tlian that used by the diers, who immediately pour the aqua fortis upon the tin reduced to small pieces, and vvait till a strong fermentation ensues, and a great quantity evaporates before they weak- en it with common water. When the tin is thus dissolved, this scarlet composition is made, and the liquor is of the beautiful colour of dissolved ,gold, without any dirt or black sediment, as I used very pure tin without allay, and such as iment, will be perfectly pure ; and if this sediment which is the silver precip- itate, be evaporated to dryness, and then infa^nd in a crucible with a small quantity ofaity alVaJlf iait,itinUbe reduced to its proper metalline Ill runs from the first melting of the furnaces of Cornwall. This solution of tin is very transpa- rent when newly made, and becomes milky and opaque during the great heat of summer ; the greatest part of the diers are of opinion, that it is^ then changed and good for nothing ; yet mine, notwidistanding this defect, made as bright scar» let as if it had i emained clear ; besides, in cold weather, what I made recovered its first transpa- rency. It must be kept in a glass bottle with m- stopper, to prevent the evapoiation of the voliuile parts. As the diers do not attend to this, their compo* sition often becomes useless at the end of twelve or fifteen days. I have laid dow n the best meth. od, and, if they seek perfection, they will abandon their old practice, which is imperfect. The diers in France first put into a stone vessel with a large opening, two pounds of salt ammoni- ac, tw'o ounces of refined sait-petre, and two pounds of tin reduced to grains by water, or, which is still preferable, the filings of tin ; for when it it has been melted raid granulated, there is always a small portion converted into a calx which does not dissolve. They weigh four pounds of w^ater in a separate vessel, of which they pour about two ounces upon the mixture in the stone vessel ; they then add to it a pound and a half of common aqua fortis,, which produces a violent fermentation. When the ebullition ceases, they put in the same - quantity of aqua for.tis, and an instant after they add one pound more. They then put in the re- mainder of the four pounds of water they had set aside ; the vessel is then close covered, and the Gomposkion let to stand till the next day# 112 The saltpetre and salt ammoniac are sometimes dissolved in the aqua fortis before the tin is. put in ; they practise both methods indiscriminatMva though it is certain that this last method is best. Others mix the water and aqua fortis together, and pour this mixture on the tin and salt am- moniac. In short, every dier follows his own method. JFater for the Preparation of Scarlet. The day after preparing the composition, the water for the preparation of scarlet is made, which differs from that made in the preceding chapter. Clear the water well. For each pound of spun wool, put twenty quarts of very clear river water (hard spring water will not do) into a smallcopper. When the water is a little more than lukewarm, two ounces of the cream of tartar finely powdered, and one drachm and a half of pow^dered and sifted cochineal is added. The fire is then made a little stronger, and when the liquor is ready to boil two ounces of the composition are put in. This acid instantly changes the colour of the liquor, w^hich, from a crimson, becomes of the colour of bLcod. As soon as this liquor begins to boil, the wool is dipped in, which mtist have been previously wetted in warm ^^'ater and wrung. The wool is continually worked in this liquor, and left to boil an hour and a half; it is then taken out, slightly wrung, and w’ashed in fresh water. The wool coming out of the liquor is of a lively flesh colour, or even some shades deeper, according to the goodness of the cochineal, and the strength of the r us composition. The colour of the liquor is then entirely passed into wool, remaining almost as clear as common water. This is called the water of preparation for scar- let, and the first preparation it goes through before it is died ; a preparation absolutely necessary, without which the die of the cochineal would net be so good. Reddening. To finish it, a fresh liquor is prepared with clear water, the goodness of the water, being of the greatest importance towards the perfection of the scarlet. An ounce and a half of starch is put in,^ and when the liquor is a little more than lukewarm, six drachms and a half of cochineal finely powder- ed and sifted is thrown in. A little before the li- quor boils, two ounces of the composition is poured in, and the liquor changes its colour as in the former. It must boil, and then the wool is put into the copper, and continually stirred as in the former. It is likewi^ie boiled an hour and a half ; it is then taken out, wrung, and washed. The scarlet is then in its perfection. One ounce of cochineal is sufficient for a pound of wool, provided it be worked with attention, and after the manner laid down, and that no die re- mains in the liquor. For coarse cloth less would do, or half as much for worsted. However, if it was required, to be deeper of cochineal, a drachm or two might be added, but not more, for it would then lose its lustre and brightness. Starch softens-it. K 2 114 Though I have mentioned the quantity of the \ composition, both in the water of the preparation and the die. yet this proportion is not to be te^ken as a fixed rule. 1 he aqua iortis, used by the diers, is seldom | of an equal strength ; if, therefore, it be always i mixed with an equal quantity of water, the com- ^ position would not produce the same efiect ; but j there is a method of ascertaining the degree of a- I cidity of aqua foi tis. For example to use that on- j ly, two ounces of which would dissolve (me ' ounce of silver. This would produce a compo- sition tliat would be always equal, but the quality, of the cochineal would then produce new varie- ties, and the trifling difierence that this commonly causes in the shade of scarlet is of no great signi- fication, as more or less may be used to bring it precisely to the colour desired. If the composi- tion be weak, and the aforesaid quantity not put in, the scarlet will be a deeper and fuller in colour. On the contrary, if a little more is added, it will be more on the orange, and have what is called more fire ; to rectify which, add a little of the composition, stirring it w'ell in the copper, hav- ing first taken out the wool ; for if it was to touch any part before it w^as thoroughly mixed, it W’ould blot it. If on the contrary, the scarlet has too much fire, that is, too much on the orange, or too much rouzed, it must be passed through clear warm water ; when finish^, this sadd^is it a lit- tle, that is diminishes its bright orange ; if there still remained too much, a little Roman alum must be mixed with the hot w^atcr. For spun wool that is to have all the various shades of scarlet, about half the ccchineah and 115 half the composition for full scarlet is sufHcient. The cream of tartar must also be diminished pro- portionably in the water of preparation, 'fhc wool must be divided into as many hanks or skains as there are to be shades, and when the li- quor is prepared, the skains that are to be light- est are first to be dipped, and to remain in but a very short space of time ; then those that are to be a little deeper, which must remain in some- what longer, and thus proceeding to the deepest , the wool is then to be w^ashed, and the liquor pre- pared to finish them. In this liquor, each of these shades are to be boiled one after the other, begin- ning alway s with the lightest, and if they are per- ceived not to be of the proper shade they must be passed again through the liquor. The eye of a dier, will readily judge of the shades, and a lit- tle practice will bring this to perfection. The diers are divided in opinion of what metal the boiler should be made. In Languedoc they use those made of the finest block tin, and sever- al diers in Paris follow the same method. Yet that great dicr, M. de Julienne, w^hose scarlets are in great repute, uses brass. The same is us- ed in the great manufactory at St. Dennis. M. de Julienne, to keep the stuffs from touching the boiler, makes use of a large rope net w ith close meshes. At St. Dennis, instead of a rope net, they have large baskets, made of willow stripped of the bark, and not too close worked. As so much had been said concerning the met- al of the boiler, I tried the experiment. I took two ells of white sedan cloth, which 1 died in two separate boilers of equal size ; one was of brass, itted with a rope net, the other of block tin* The (S)chineal, the composition, and other ingredients, were weighed with the utmost accuracy and boil- ed precisely the same time. In short, I took, all possible care that the process should be the same in both, that if any difference arose it might be only attributed to the different metals of the boil- er. After the first liquor, the t wo pieces of doth were absolutely alike only that which had been boiled in the tin vessel appeared a little more streaked and uneven, which, m ail iikeliho-jd, pro- ceeded from these two ells of doth being less scoured at the mill than the two others ; the two pieces were finished each in the separate boilers, and both turned out very fine ; but that which had been made in the tin boiler had a little more fire than the other, and the last was a little more sad- dened. It would have been an easy matter to have brought them both to the same sh.ide, but that was not my intention. From this experiment, I conclude, that W'hen a brass boiler is used, it requires a little more of the composition than the tin one ; but this addi- tion of the composition makes the doth feel rough; to avoid this defect, the Diers who use brass ves- sels put in a little turmeric, a drug of the die, but which gives to scarlet that shade which is now in fashion ; I mean that flame -colour, which the eye is scarce able to bear. This adulteration is easily discovered by cutting a piece of the cloth ; if there is no turmeric, the web will be of a fine white, but yellow if there is. When the web is dyed the same as the surface, it is said that colour is webbed, and the contrary^, when the middle of the weaving remains white. The lawlui scarlet is never dyed in the web : the 117 adulterated, where the turmeric or fustic has been made UbC of, is more liable to change its colour in the air than the other. But as the brightest scar- lets are now in fashion, and must have a yellow ©ast, it is better to tolerate the use of turmeric, than to use too great a quantity of the composition to bring the scarlet to this shade ; for in this last ©else, the cloth would be damaged by it, would be sooner spotted by dirt from the quality of the acid, and would be more easily torn, because acids stiffen the fibres of the wool, and render them brit- tle. I must also take notice, that if a copper vessel is used it cannot be kept too clean. I have failed several times with my patterns of scarlet, by not having the copper scoured. I cannot help condemning the common practice of some diers, even the most eminent, who pre- pare their liquor over niglit, ^ and keep it hot till next morning, when they dip in their stuffs ; this they do, not to lose time, but it is certain that the liquor corrodes the copper in that space, and by introducing particles of copper in the cloth, pre- judices the beauty of the scarlet. They may say they only put in their composition just at the time when the cloth is ready to be dipt in the copper ; hut the cream of tartar, or the white tartar, which they put in over night, is an acid salt sufficient to corrode the copper of the vessel, and form a ver- digrise, although it dilutes itself as it forms, .still has not a less effect. It would therefore be better to make use of tin boilers, a boiler of this metal must contribute to the beauty of scarlet; but these boilers of a suffi- cient size cost much, and may be melted by the 118 ! ©egligence of the workmen, and there is a difficui- ! i ty in casting them of so great a size without sand- ■ iX flaws, which must be filled. Now if these sand^ d holes are filled with solder, there must of necessi- v ty be places in the boiler that contain lead ; this | j lead in time being corroded by the acid of the com- i position, will tarnish the scarlet. But if such a boiler could be cast without any sand-holes, it is certain such a one w^ould be preferable to all oth- ers, as it contracts no rust, and if tlte add of the liquor detaches some parts, they cannot be hurt- I ful. Having laid down the manner of dicing spun wool in scarlet, and its various shades, which arc | so necessary for tapestry and other work, it is proper to give an idea of the dicing of several pieces of stuff at one time. I shall relate this operation as it is pract’sed in Languedoc. I made the trial ‘ on some ells of stuff, which succeeded very well, ' but this scarlet was not so fine as the flame- col- oured. 'Fhere are two reasons why the wool is not died before it is spun (for fine colours) first in the course of the manufacturing, that is, either in the spinning, carding, or weaving, it would be almost impossible in a large workshop, where there are many workmen, but that some particles of w^hite wool, or some other colour would mix, which would spoil that of the stuff by blotting it ever so little ; for that reason, the reds, the blues, the yellows, the greens, and all other colours, that are to be perfectly uniform, are never died before they are manufactured. The second reason, which is peculiar to scarlet, or rather to cochineal, is, that it will not stand the 119 milling, and as the greatest part of high stuffs must be milled after they are taken from the loom, the cochineal would lose part of its colour, or at least would be greatly saddened by the soap, which produces this effect by the alkaline salt which de- stroys the brightness given to the red by the acid. These are the reasons that the cloths and stuffs arc not died in scarlet, light red, crimson, violet, purple, and other light colours, but after being en, tirely milled and dressed. To die, for example, five pieces of cloth at one timeof five quarters breadth, and containing fifteen or sixteen ells each, the following proportions are to be observed. Put into a stone or glazed earthen pot twelve pounds of aquafortis, and twenty pounds of water, to which add a pound and a hall of tin, made in grains by running it in water, or filed. The dissolution is made quicker or slower, ac- cording to the greater or lesser acidity of the aqua fort is. Idle whole is left to rest twelve hours at least, during which time a kind of black mud set- tles at the bottom of die vessel ; what swims oyer this sediment is poured off by inclination ; this liquor is clear and yellow, and is the composition which is to be kept by itself. This process differs from the first in the quan- tity of water mixt with the aqua fortis, and in tiic ^mall quantity of tin, liule of which must remain in the liquor, since aqua fortisalone cannot dissolve it, but only corrodes it, and reduces it to a calx, as there is neither salt petre, nor salt ammoniac which would form an aqua regia. However, the effect of this composition differs from the first on. ly to the eyes accustomed to judge of that colour. This composition made wiihguisait ammouiac, and which hasbeen of Icrp' use amongst a great miui- ber of manufacturers at Carcassone, who certainly imagined that its effect was owing to the sulphur of the tin, can only keep thirty-six hours in winter without spoiling, and twenty four hours in sum- mer ; at the expiration of which it grows muddy, and a cloud precipitates to the bottom of the ves-. sel, which changes to a white sediment. This is the small quantity of tin, which was suspended in the acid, but an acid .not prepared for that metal ; the composition which ought to be yello\v becomes at that time as dear as water, and if used in that state would not succeed ; it would Iiave the same effect as that which would become milky. The late M. Baron pretended to have been the first discoverer at Carcassone of the necessity of adding salt ammoniac to hinder the tin from pre- cipitating. If so, there was no one in that town that knew that tin cannot be really dissolved but by aqua regia. Having prepared the composition as I have des- cribed itafter M. de Fondriers, about sixty cubic- al f( et of W’ater are put into a large copper for the five pieces of doth before mentioned, and when the water grows warm, a bag with bran is put in, sometimes also sour waters are used ; the one and the other serve to correct the water, that is, to absorb the earthy and alkaline matters which may be in it, and which, as I have already said, saddens the dye of the cochineal, for the effect of the w ater ought to be well known, and experience will teach whether such expedients should be used, or wheth- er the water, being very pure and denulattd of salts and earthy partidcs, can be used w ithoiit such helps, 121 Be that as it will, as soon as the water begins to be little more than luke- warm, ten pounds of pow- dered cream of tartar is flung in, that is, two pounds for each piece of cloth. The liquor is then raked strongly, and when it grows a little hotter, half a pound of powdered cochineal is cast in, which is. well mixt with sticks ; immediately after, twenty^ seven poundsof the composition very clear is pour- ed in, which is also well stirred, and as soon as the liquor begins to boil, the cloths are put in, whidy are made to boil strongly for two hours, stirring them continually by the help of the wynch; they are then taken out upon the scray, and well handled three or four times from end to end, by passing the lists between the hands to air and cool them. They are afterwards washed. After the cloth has been washed, the copper is emptied and a fresh liquor prepared, to which if necessary, a bag with bran or some sour water is added, but if the water is of a good cjuality, these are to be omitted, when the liquor is ready to boil, eight pounds and aquartcrof powder ed and siftedcochine'al is put in, which is to be mixed as equally as possible throughout the liquor, and haviiig left off' stirring, it is to be observed when the cochineal rises on the surface of the water, and forms a crust oi'lhe col- our of the lees of wine ; the instant this crust opens ofitself in several places, eighteen or twenty pounds of the composition is to be added, A vessel with ^old W'ater must be at hand to cast on the liquor in case it should rise, as it sometimes does, after the composition is put in. As soon as the compostiif>n is In the coppcr,a!'d equally distributed ihroaghont the whole he cloth is cast in, and the wynch strongly turneci 122 two or three times, that all the pieces may equally take the dye of the cochineal. Afterwards it is turned slowly to let the water boil, which it must do very fast for one hour, always turning the wynch and sinking the cloth in the liquor with sticks, when by boiling it rises too much on the surface. The cloth is then taken out, and the lists passed between the hands to air and cool it ; it is then washed, after which it is to be died and dressed. In each piece of the Languedoc scai let cloth there is used, as has been shewn, one pound and three quarters of cochineal in the die and prepara- tion ; this quantity' is sufficient to give the cloth a very beautiful colour. If more cochineal was added, and a deeper orange colour required, the quantity of the composition must be augmented. When a great quantity of stuffs are to be died in scarlet, a considerable profit arises by doing them together, for the same liquor serves for the second dip which was used for the first. For ex- ample ; when the five first pieces are finished, there always remains in the liquor a certain quantity of cochineal, which in seven pounds may amount to twelve ounces ; so that if this liquor be used to die other stuffs, the cloths dipped in it will have the same shade of rose colour as if they had been died in a fresh liquor with twelve ounces of coch- ineal ; yet this quantity may vary pretty much, according to the quality or choice of the cochin- cal, or according to the fineness it has been reduc- cd to when powdered. I shall say no more of this before I finish this chapter ; but whatever colour may remain in the liquor, it deserves some atten- tion on account of the highpiice of this drug. The same liquor is then made use of for other five pie^ ®es, and less cochineal and composition arc pu 'in proportion to what may be judged to remain ; fire and time are also saved by this, and rose colour and flesh- colour may also be produced from it ; but if the diers have no leisure to make these dif- ferent liquors in twenty -four hours, the colour of the liquor corrupts, grows turbid, ^d loses the rose colour entirely. To prevent this corruption some put in Roman alum, but the scarlets which are prepared after that manner are ill saddened. When cloths of different qualities, or any other stuffs are to be died, the surest method is to weigh them, and for each hundred weight of cloth add about six pounds of chrystal or cream of tartar, eighteen pounds of composition in the water of pre- paration, as much for the reddening,and six pounds and a quarter of cochineal. Thus in proportion for ©ne pound of stuff use one ounce of cream of tartar, six ounces of composition, and one ounce of cochineal ; some eminent diers at Paris put two thirds of the composition and a fourth of the co» chineal in the water of preparation, and the other third of the composition with three fourths of the cochineal in reddening. It is not customary to put cream of tartar in the reddening, yet I am certain by experience, that does not hurt, provided the quantity does not ex- ceed half the weight of the cochineal, and it ap- peared to me to make a more lasting colour. Some diers have made scarlet with three dippings : namely, a first and second water for preparation, and then the reddening ; but still the same quan- tity of drugs is always used. I observed in the foregoing chapter, that the little use made of kermes for the brown or VeJte- 124 ti§n scarlets, obliges most diers to make them with cochineal ; for this purpose a water of prepa- ration is made as usual ; and for the reddening, eight pounds of alum are added for each hundred weight of stuff ; this alum is dissolved by itself in a kettle, with a sufficient quantity of water, then poured into the liquor before the cochineal is put in. The remainder is performed exactly as in the common scarlet; this is the Venetian scarlet, but it has not near the same solidity as if made with the kermes. There are no alkaline salts which do not sadden scarlet ; of this number are the salt of tartar, pot- ash, pearLashes calcined, and nitre fixed by fire ; therefore alum is more generally used ; and if these alkaline salts be boiled with the stuffs, they would considerably damage them, for they dis^ solve all animal substances. If the alum be cal- cined, it is still the more secure. The redder the scarlet is the more it has been saddened; from thence it appears that thesecolours lose in the liquor -that browns them a part of their ground ; however one cannot browm in the good dye but with salts. The late M. Baron observes, in a memoir he gave some time ago to the Roy- al Academy of Sciences, that of all the salts he had made use of for browning, making the colour smooth, and preserving its brightness and deep- ness, he had succeeded best with salt of urin, but, as he observes, it is too troublesome to make this salt in any quantity. I said in the beginning of this chapter that the choice of the water for dying of scarlet was very material, as the greatest part of common water saddens it, for they mostly contain a chalky, calca- . 125 reou3 earth and sometimes a sulphureous or vitri- olic acid ; these are commonly called hard waters, that is, they will not dissolve soap or boil vegeta- bles well. By finding a method of absorbing or precipitating these hurtful matters, all waters may be equally good for this kind of die ; thus, if aL kaline matters are to be removed, a little sour wa- ter produces this effect ; for if five or six buckets of these sour waters are mixed with sixty or sev- enty of the hard water before it comes to boil, these alkaline earths rise in a scum, which is easi- ly taken off the liquor. All that I have hitherto said in this chapter is for the instruction of diers ; I shall now make an attemj)t to satisfy the philosopher how these differ- ent effects are produced. Cochineal, infused or boiled by itself in pure wa- ter, gives a crimson colour bordering on the pur- ple ; this is its natural colour ; put it into a glass and drop on it spirits of nitre ; this colour will become yellow, and if you still add more, you will scarcely perceive that there was originally any red in the liquor ; thus the acid destroys the red“by dissolving it and dividing its parts so minutely that they escape the sight. If in this experiment a vitriolic, instead of a nitrous acid be used, the first changes of the colour wdll be purple, then purpled lilac, after that a light lilac, then flesh.colour, and lastly, colourless This bluish substance, w^hich mixes with the red to form a purple, may proceed from that small portion of iron from which oil of vitriol is rarely exempt. In the liquor of prepara- tion for scarlet, no other salt but cream of tartar is used, no alum is added as in the common pre- paring water for other colours, because it would L 2 126 sadden the dye by its vitriolic acid ; yet a calx or lime is required, which with the red parts of the cochineal, may form a kind of lake like that the painters use, which may set in the pores of the wool by the help of the crystal of tartar. This white calx is found in the solution of very pure tin, and if the experiment of the die is made in any small glazed earthen vessel, immediately on the cochineal’s communicating its tincture to the water, and then adding the composition drop by drop, each drop may be perceived with a glass or lens, to form a small circle, in which a brisk fer- mentation is carried on ; the calx of the tin will be seen to separate, and instantaneously to take the bright die, which the cloth will receive in the sequel of the operation. A further proof that this white calx of tin is ne- cessary in this operation, is, that if cochineal was used with aqua fortis, or spirits of nitre alone a very ugly crimson would be obtained ; if a solu- tion of any other metal was made use of in spirits of nitre, as of iron or mercury, from the first would be had a deep cinder grey, and from the second, a chesnut colour with green streaks, without being able to trace in the one or other any remains of the red of the cochineal. Therefore, by what I have laid down, it may be reasonable to suppose, that the white calx of the tin, having been died by the colouring parts of the cochineal, rouzed by the acid of the dissolvent of this metal, has form- ed this kind of earthy lake, whose atoms have introduced themstlve* into the pores of the wool, which were opened by the boiling water, that they are plaistered by the crystal of tartar, and these pores, suddenly contracting by the immedi- 12 ? ate cold the cloth was exposed to by airing, that these colouring particles are found sufficiently set in to be of the good die, and that the air will take off the primitive brightness, in proportion to the various matters with which it is impregnated. In the country, for example, and pa'iicularly if the situation be high, a scarlet cloth preserves its brightness much longer than in great cities where the urinous and alkaline vapours are moreabund^ ant. h’or the same reason, the country mud, which in roads is generally but an earth diluted by rain water, does not stain scarlet as the mud of toW' ns where there are urinous matters, and often a great deal of dissolved iron, as in the streets of g eat cities, for it is well known that any alkaline n:at- ter destroys the effect which an acid has produc- ed on any colour whatsoever. And for the like rea- son if a piece of scarlet is boiled in a ley of pot- ash, this colour becomes purple, and by a contin- uation of boiling it is entirely taken out ; thus from this fixed alkali, and the crystal of tartar, a soluble tartar is made, which the water dissolves and easily detaches from the pores of the wool ; all the mastic of the colouring parts is then de- stroyed, and they enter into the leys of the salts. I have tried several experiments on the die of cochineal, to discover what might be produced from the union of its red with other different mat- ters, which generally are not esteemed colouring ; but I shall only relate here such as had the most singular efi'ects. 12B T Experiments on Cochineal liquorl Zinc dissolved in spirit of nitre changes the red ©f cochineal to a slaty violet colour. The salt of lead used instead of cream of tartar, makes a lilac somewhat faded ; a proof that some portion of lead is joined to the colour of the cochi- neal. Vitriolated tartar made with pot -ash and vitriol destroys its red, and there only remains an agath grey. Bismuth dissolved in spirit of nitre, weakened by an equal part of common water, and poured on the liquor of cochineal, gives the cloth a dove- grey, very beautiful and very bright. A solution of copper in spirit of nitre not weak- ened, gives to the cochineal a dirty crimson. Cupullated silver, a cinnamon colour, a little on the brown. Arsenic added to the liquor of cochineal, gives a brighter cinnamon than the preceding. Gold dissolved in aqua regia gave a streaked chesnut, which made the cloth appear as if it had been manufactured with wool of different colours. Mercury dissolved with spirit of nitre, produces pretty near the same effect. Glauber’s salts alone destroys the red, like the vitriolated tartar, and produces like that an agath grey, but not of the good die ; because this salt easily dissolves even in cold water, and besides it calcines in the air. The fixed salt of urine gives a cinder- grey coL our, where not the least tincture of red is perceiv- ed, and like the foregoing is not of a good die, for it is a salt that cannot foriB a solid cement in the 129 pores of the wool, as it is soluble by the moisture ©f the air. w Violet without Blue. Lastly, the extract of bismuth changes the co- chineal red to a purple, almost violet, as beautiful as if this red had been put on a cloth that had been previously died of a sky-blue. From these experiments it is evident, that the salts and metallic solutions yield particles which unite themselves with the particles of the colour- ing ingredients used in dicing, and which salts and particles contribute greatly to the tenacity of the colours. Before I finish this chapter on scarlet, I must add some observations which perhaps the reader may be glad to know. Neither the mud of the streets nor several acid matters can stain scarlet, if the spotted part is im- mediately washed with plain clean water and a clean cloth ; but if the mud has had time to dry, then the spot appears of a violet black ; this can- not be taken off but by a vegetable acid, such as vinegar, lemon-juice, or a warm solution of white tartar slightly loaded with salts ; but if these aeids are not made use of with precaution and skill in takingoffthe black spot, a yellow one will succeed, because as has been said before, the acids rouze and even destroy the red of the cochineal. But there are some for w^hich the colour must be discharged, and the stuff died again. There are other salts besides alkalis which w ill discharge the colour of scarlet ; for if a piece of scarlet cloth be put into the water of preparation for that colour 150 it will lose a great part of its colour, insomuch, that if it was sewed with two or three pieces of white clothf*it would be difhcult after one hours boiling to distinguish which was the scarlet from the others ; but if it was boiled afresh in a liquor, of cochineal or in the reddening, it would regain its first colour. Scarlets abvays lose some part of their bright- I ness in the dressing, for the dressing lays the hair, and forces the fibres to be almost parallel to the i web. In this case the cloth has numerically i less surface, and consequently less rays of light are reflected from it. Besides the extremity of the hair is always most penetrated with the die which causes the brightness, and when it is laid on the cloth, the greatest part of these points appear no more. CHAPTER XL OF CRIMSON. CRIMSON, as I have already observed, is the natural colour of the cochineal, or rather, that which it gives to wool boiled with alum and tartar, which is the usual water of preparation for all colours. This is the method which is common- ly practised for spun wool ; it is almost the same for cloths, as will be seen hereafter. For each pound of wool, two ounces and a half of alum, and an ounce and a half of white tartar, are put into the copper. When the whole boils^ the wool is put in, well stirred, and left to boil for 131 two hours ; it is afterwards taken out, slightly wrung, put into a bag, and k-ft thus with its water, as for the scarlet in giain, and for all other colours. For the die a fresh liquor is made, in which three fourths of an oiuice of cochineal is added for each ptnind of wool. When the liquor is little more than luke-warm, the cochineal is put in, and when it begins to boil, the wool is cast in* which is to be well stirred with sticks ; it is to remain thus for an hour ; when taken out, wrung and washed. If degrees of shades are required, (whose names are merely arbitral y) proceed, as has been already related for the scarier, using but half the cochineal at first, and beginning with the lightest. The beauty of crimson consists in its border- ing as much as possible on the grisdelin, a colour between a grey and a violet. I made several tri- als to bring crimson to a higher perfection than most diers have hitherto done, and indeed I suc- ceeded so as to make it as fine as the false crimson, which is always brighter than the fine. This is the principle on which I worked. As all alkalis sadden cochineal, I tried soap, barrilla, pot-ash, pearl-ashes ; all these salts brought the crimson to the shade I wanted, but at the same time, they tarnished and diminished its brightness, I then bethought myself to make use of volatile alkalis, and I found that the volatile spirit of salt ammoniac produced a very good effect ; but this spirit instantly evaporated and a pretty considera- ble quantity was used in the liquor, which greau ly augmented the price of the die. I then had recourse to another expedient which SHCceeded better, the expense ©f which is trifling. 132 This was to make the volatile alkali of the salt ammoniac enter into the liquor, at the very instant that it eomes out of its basis ; and to effect this, after my crimson was made after the usual man- ner, I passed through a fresh liquor, in which I had dissolved a little of the salt ammoniac. As soon as the liquor was a little more than luke- warm, I flung in as much pot ash as I had before of salt ammoniac, and my wool immediately took a very brilliant colour. This method even spares the cochineal ; for this new liquor makes it rise, and then less may be used than in the common process ; but the greatest part of diers, even the most eminent, sad- den their crimsons with archil, a drug of the false die. Very beautiful crimsons are also made by boil- ing the wmol as for the common scarlet, and then boiling it in a second liquor, wdth two ounces of alum and once ounce of tartar, for each pound of wool, leaving it one hour in the liquor. A fresh liquor is then prepared, in which six drachms of cochineal is put for every pound of wool. After it has remained an hour in this liquor, it is taken out, and passed immediately thiongh a liquor of barilla and salt ammoniac. By this method gradations of very beautiful crimson shades are made by diminishing the quantity of the cochineal. It is to be observed, that in this process there are but six drachms of cochineal to die each pound of wool, because inthc first liquor a drachm and a half of cochineal is used for each pound. It is also necessary to remark, that, to sadden the se t rim- sons, the liquor of the alkaline salt and salt am- moniac be not made too hot, because the separa- tioft of the volatile spirit of this last salt would be too quick, and the crystal of tartar of the first li- quor would lose its proper effect by being chang- ed, as I have already said into a soluble tartar. The same operation may be done by using one part of the cochineal sylvtstre instead of the fine cochineal, and the colour is not less beautiful, for commonly four parts of sylvestre have not more effect in dyeing than one part of fine cochineal. The sylvestre may also be used in dying scarlet, but with great precaution ; it should only be used in bastard scarlets and half crimsons. I shall speak of this when I treat of these colours in partic- ular. When a scarlet is spotted or spoiled in the op- eration by some unforeseen accident, or even when the die has failed, the common remedy is to make it a crimson, and for that purpose, it is dipt in a liquor where about two pounds of alum are added for each hundred weight of wool. It is im- mediately plunged in this liquor, and left there until it has acquired the shade of the crimson de- sired. Languedoc Crimson* I shall notv shew the method they follow in Languedoc to make a very Ix^autiful sort of crim- son, or the cloths exported to the Levant, but which is not so much saddened as that which I have just spoken ©f, and which resembles much more the Venetian scarlet. For five pieces of cloth the liquor is prepared as usual, puuing bran ifnecessary. When it is more than lukewarm, ten pounds of sea. salt are put, instead of ervstai M 134 of tartar, and when it is ready to boil, twenty- sev- pounds of the scarlet composition, made after the manner of carcassine already described, are poured in, and without adding cochineal the cloth is passed through this liquor for two hours, keep- ing it always turning with the wynch, and contin- ually boiling. It is afterwards taken out, aired and washed ; then a fresh liquor is made, with eight pounds and three quarters v4cochineal pow- dered and sifted, and when it is ready to boil, twen- ty one pounds of composition are added ; the cloth is boiled for three quarters of an hour wnth the common precautions, after v/hich it is taken out, aired and washed ; it is of a very fine crim- son, but very little saddened ; if it is required to be more saddened, a greater quantity of alum is put into the first liquor of preparation, and in the second less of the composition, the sea salt is also added to this second liquor ; a little practice in this method will soon teach the dier to make all the shades that can properly be derived from crim- son. Whenever cochineal has been used, there is found at the bottom of the reddening liquor a quantity of very brown sediment, which is flung away with the liquor as useless. I examined it and found, that the liquor for the reddening of scarlet contained a precipitated calx of tin : I uni- ted this metal with a great deal of trouble ; the re- maining parts of this sediment are the dross of the white tartar, or of the cream of tartar, united with the gross parts of' the bodies of the cochineal, which is, as has already been said, a small insect, I washed these little animal parts in cold water, and, by shaking this w’ater, I collected with a 13*5 small sieve, what the agitation caused to rise on the surface. After this manner I separated these light parts from the earthy and metallic ; I dried them sepa- rately, then levigated them with equal weight of fresh crystal of tartar ; I boiled a portibn with a little alum, and put in a pattern of white cloth, which boiled for three quarters of an hour, at the end of which it was died of a very beautiful crim- son. This experiment having convinced me, that by powdering and sifting the cochineal as is common- ly practised, all the profit that might be extracted from this dear drug is not obtained, I thought proper to communicate this discovery to the diers, that they might avail themselves of it by the meth- od following. Take one ounce of cochineal powdered and sift- ed as usual ; mix with it a quarter of its weight of very white cream of tartar very crystalline and very airy; put the whole on a hard levigating stone and levigate this mixture till it is reduced to an impalpable powder ; make use of this cochineal thus prepared in the liquor and in the reddening, subtracting from the cream of tartar, which is to be used in the liquor, the small quantity before used With the cochineal. What is put to the red- dening, although mixed with a fourth of the same salt, does not piejudice its colour, it even appear- ed to me that it was more solid. Those that will follow this method will find that there is abofet a fourth more profit to be obtained by it. 136 The natural Crimsoir hi grain. In proportion for every pound of cloth or other things, take two ounces of tartar pure, and two ounces of alum ; boil them with the goods an hour and a half ; then rince the goods very well from the boiling. The kettle must be filled again with clear water and a fevv handfuls of bran put in, in order to take out the filth of the water, as well as to soften it. Scum the scurf off when it begins to boil, and put in an ounce of well powdered grain, with one dram of red arsenic and one spoonful of burnt wine lees ; this gives a pretty lustre ; then wash and rince it well, and you have a most beautiful colour. CHAPTER XII. SCARLET OF GUM-LACqUE. THE red part of the gum-lacque may be also used for the dicing t>f scarlet, and if this scarlet has not all the brightness of that made of fine co- chineal alone, it has the advantage of being more lasting. The gum Jacque, which is in branches or small sticks and full of animal parts, is the fittest for dic- ing. It must be red v\ ithin, and its external parts, of a blackish brown ; it appears by a particular examination made of it by M. Geoffroy some years since, that it is a sort of hive, somewhat like that of bees, wasps, &c. Some diers make use of it powdered and tied 157 in a linen bag; but this is a bad method, for there alw^ivs passes through the doth some resinous portion ot the gum, which melts in the boiling water of the cop[)er, and sticks to tlie cloth, where it becomes so adherent svhen cold, that it must be scraped off with a knife. Others re'Uict it to powder, boil it in water, and after it has given ail its colour, let it cool, and the rc::.irK)us parts fall to the bottom. The water -is poured out, and evaporated by the air, where it often becomes stinking, and when it has acquir- ed the consistence of thick honey, it is put up into vessels for use. Under this form it is pret- t} difficult justly to determine the quantity that is used ; this induced me to seek the means of obtaining this tincture separated from its resinous gum, without being obliged to evaporate so great a quantity of water to have it dry, and to reduce it to powder. 1 tried it with weak lime water, with a de- coction of the heart of agaric, with a decoc- tion of comfre} root, recommended in an ancient book of physic ; in all these the water leaves a pirt of the die, and it still passes too full of colour, and it ought to be evaporated to get all the dve ; this evaporation I wanted to avoid, therefore I tnade use of mucilaginous or slimy roots, which of themselves gave no colour, but whose mucilage might retain the colouring parts, so that the^^ might remain with it on the filter. The great comfrey root has as yet the best an- swered my intention ; I use it dry and in a gross powder, pulling half a dram to each quart of wa- ter, which is boiled a quarter of an h ur, passing it through a hair sieve. 1 1 immediately extract's. M 2 from it a beautiful crimson tincture ; put the ves- sel to digest in a moderate heat for twelve hours shaking it seven or eight times to mix it wdth the gum that remains at the bottom, then pour off the water that is loaded with colour in a vessel sufficiently large, that three-fourths may remain empty and fill it wdth cold water ; then pour a very small quantity of strong solution of Roman alum on the tincture ; the mucilaginous or slimy die precipitates itself, and if the water w'hich ap« pears on the top appears still coloured, add some drops of the solution of alum to finish the precipi- tation, and this repeat till the w^ater becomes as clear as common water. When the crimson mucilage or slime is all sunk to th^ bottom of the vessel, draw off the clear wha- ler, and filter the remainder ; after w’hich, dry it in the sun. If the first mucilaginous water has not extract- ed all the colour of the gum lacque, (which is known by the remaining being of a weak straw colour) repeat the operation until you separate all the die the gum-lacque can furnish ; and as it is reduced to powder when dry, the quantity to be used in the die is more exactly ascertained than by evaporating it to the consistence of an extract. Good gum-lacque, picked from its sticks, yields, dried and powdered, but little more die than one- fifth of its weight. Thus at the price it bears at present, ther€ is not so great an advantage as many may imagine in using it in the place of cochineal ; but to make the scarlet colour more lasting than it commonly is, it may be used in the first liquor or preparation, and cochineal for reddening. If scarlet is made of gum-lacque, extracted 139 cording to the method here taught, and reduced to powder, a caution is to be taken in dissolving it, which is useless when cochineal is used ; that is, if it was put into the liquor ready to boil, the dier would lose three-quarters of an hour, before it would be dissolved entirely j therefore for despatch, put the dose of this dry tincture into a large earthen vessel, or into one of tin, pour warm water on it, and when it is well moistened, add the necessary dose of the composition for scarlet, stirring the mixture w^ell with a glass pestle. This powder, which was of a dirty deep purple, as it dissolves takes fire- coloured red extremely bright ; pour the dissolution into the liquor, in which was pre- viously put the crystal of tartar, and as soon as this liquor begins to boil, dip the cloth in, keeping it continually turning. The remaining part of the operation is the same as that of scarlet with cochi- neal : the extract of gum-lacquc, prepared accord- ing to my method, yields about one ninth more of die than cochineal, at least than that which I made use of for this comparison. Ifinstead of the crystal of tartar and the com- position of some fixed alkaline salt or lime water is substituted, the bright red of the gum lacque is changed into the colour of lees of wine, so that this die does not sadden so easily as that of eoehineal. If instead of these alteratives, salt ammoniac is used by itself cinnamon or clear chescut colours are obtained, and that according as there is more or less of this salt. I have made twenty other ex- periments on this drug, which I shall not relate here, because they produced none but common colours, and which may be easier had from ingre- 140 dients of a lower price. My experiments were I with a view of improving the red of the lucque, : and the method 1 have here laid down to extract its colouring parts answers extremely well ; the more ingredients that are discovered for scarlet, the less will be the cost ; for, although these ex- periments made on cochineal, lacque, and other drugs, may appear useless to some diers, they will not be so to others who study to intprove this ; art.^ CHAPTER XIII. ©F THE coccus POLOXICUS, A COLOURING IN- SECT. THE coccus polon'icus is a little round iiisect, somewhat less than a coriander seed ; it is found sticking to the roots of \\'\^ poly^oimm coccifcruin incanam flore majore perenni of Rav, and which M. T oLirnefort has named alchymilli gr amine o fo^ Us majore fiore. According to M. Breyn, it a- bounds in the palatinate of Kiovia, bordering the Ukrania, towards the towns of Ludnow, Piatka, Stobdyzeze, and other sandy places of Ukrania and Bodolia, of Volhinia, of the grand duchy of Lithuania, and even in Prussia, towards Thorn. Those that gather them say, that immediately after the summer solstice the coccus is ripe, and full of its purple juice. They hold in their hand * The colouring parts of the Mm-lacque may be extracted by common river water, by making it a litue more thaa lukeTfarm, jjacloeiug tite powdered lacque in a coarse woollen bag« 141 a small hollow shade, made in the shape of a shep- herd’s crook which has a small handle. With one hand they hold the plant, raising it out of the ground wdth the other, armed with this instru- ment ; they then shake off these little insects, and place the plant in the same hole in order to pre- serve it. Having separated the coccus from the earth, which they do by a riddle made for that purpose, their chief care is, that it should not change into a small worm ; for this purpose they sprinkle it with vinegar, and sometimes with very cold wa- ter ; they then bring them to a warm place, or else expose them to the sun to dry ; without this, these insects would destroy themselves, and if they were dried too precipitately, they would lose their beautiful colour. Sometimes they sep- arate these small insects from their vesicles or bladders with the ends of their fingers by a gentle pressure, which they form into small round cakes. The diers pay dearer for this die when in lump than when it is in grain. Bernard de Bernitz, from whose book I have taken this, adds, that the great marechal Konits- poliki, and some other Polish noblemen, w ho had lands in the Ukrania, set this gathering of the coc- cus to the Jews at a considerable profit, and caused it to be gathered by their vassals ; that the Turks and Arminians, who bought this drug of the Jews, used it for the dicing of wool, silk, the manes and tales of their horses ; that the Turk- ish w^omen made use of it to paint their fingers’ ends of a beautiful carnation colour ; and that formerly the Dutch used to buy the coccus at a high price, and ^lixed it with an equal quantity 142 of cochineal ; that with the die of this insect and chalk, a iacque for the painters might be made as fine as the Florence Iacque ; and that a beautiful red was prepared from it lor the toilet of the ladies in France and Spain. CHAPTER XIV, CJ THE RED OP MADDER, THE root of madder is the only part of this plant which is used in dicing. Of all the reds this is the most lasting, when it is put on a cloth or stuff that is thoroughly scoured then prepared with the salts with which it is to be boiled two or three hours, without which, this red, so tenacious after the preparation of the subject, would scarce- ly resist more the proofs of the reds than any other ingredients of the false die. This is a proof that the pores of the fibres of the wool ought not only to be well scoured from the yolk or unctuous transpiration of the animal, which may have re- mained, notwithstanding the scouring of the wool after the common manner with water and urine ; but it is also necessary, that these same pores be plaistered inwardly with some of those salts which are called hard, bec.mse they do not calcine in the air, and cannot be dissolved by rain water, or by the moisture of the air in rainy weather. Such is as has been said before, the white crude tartar, the red and the crystal of tartar, of which, according to common custom, about a fourth is put into the preparing liquor, with two-thirds or three- four ilis of alum. 145 The best madder roots come generally from Zealand, where this plant is cultivated in the islands of Tergoes, Zerzee, Sommerd} ke, and Thoolen. That from the first of these islands is esteemed the best ; the soil is clay, fat, and somewhat salt. The lands that are deemed the best for the cultiva- tion of this plant are new lands, that only served for pasture, which are always fresher and moister than others. The Zealanders are beholden to the refugees of Flanders for the cultivation and great commerce of this root. It is known in trade and dicing under the names of grape madder, bunch madder, &c. It is how- ever the same root ; all the difference in regard to its quality is, that the one kind contains pith and root, and the other has the small fibres from its principal root adhering to it. Both are prepared by the same work, which I shall nor. relate the particulars of here, as it would only serve to lengthen this treatise to no purpose. They choose the finest roots for the first sort, drying them with care, grinding them and separa- ting the rind at the mill, and preserving the middle of the root ground in hogsheads, where it remains for two or three years ; for after this time, it is better for dicing than it would have been coming from the mill ; for if madder was not kept close after this manner, the aii would spoil it, and the colour would be less bright. It is at first yellow but It reddens and grows brown by age ; the best is of a sf fPron colour, in hard lumps, of a strong smell, and yet not disagreeable. It is also cultivat- ed a boud_. isle in Flanders, and several other places of the ki hgdoai, where it was found to grow spoBtaneousiy, lU The madders which are made use of in the Le- vant and in India, for the dicing of cottons, arc somewhat different from the kinds used in Eu- rope, it is named chat on the coast of Coromandel. This plant thus called, grows abundantly in the woods on the coast of Malabar, and this chat is the wild sort. The cultivated comes from Vasur and Tuccorin, and the most esteemed of all is the chat of Persia, named (lianas. They also gather on the coast of Coromandel| the root of another plant called ray de chaye^ of? root of colour, and which was thought to be a kind cAruhia tinctorum, but is the root of a kind of gtilliiim jlore albo» as it appeared by observations sent from India in 1748. It has a long slender root, which dies cotton of a tolerably handsome red, when it has received all the preparations pre- vious to the die. At Kinder, in the neighbourhood of Smyrna, and in the countries of /\kissar and of Yordas,they cu tivate another kind of madder, which is called in the countrv chioc boy a ekme hazala. This of all the madders is the best for the red die, by the proofs that have been made of it, and far more es- teemed in the l.evant than the finest Zealand mad- der the Dutch bring there. This madder so much valued is called bv the modern Greeks lizari^ and by the Arabs foiioy ^ "^rhere is another kind of madder in Canada cal- led tyssa voyana. It is a very small root, which produces pretty wear the same effect as our Euro- pean madder. * These kinds of madders give brighter reds tlian the bc>-t grape madder of Zealand, for they are dried in the air and not in a stove, The madder of Lan- guedoc, even that of Poitou eucceeds a€ weH as that of when it is dried 145 The water of preparation for madder red is pret- ty near the same as for kermes, that is composed of alum and tartar. The diers do not agree as to the proportions ; but the best appears to be four ounces of alum and one of red tartar to each pound of spun wool, and about one twelfth part of sour water, and let the wool boil in it for two hours. If it is spun wool, leave it for seven or eight days, that it may be well moistened by the dissolution of these salts ; and if it is cloth, finish it the fourth day. To die wool with madder, prepare a fresh li- quor, and when the wetter is come to a heat to bear the hand, put in half a pound of the finest grape madder for each pound of wool ; let it be W’ell raked and mixed in the copper before the wool goes in, keep the wool in an hour, during which time it must not boil.^ Shades from madder are obtained after the manner laid down for other col- ours, but these shades are little used, except in a mixture of several colours. When several pieces of cloth are to be died at once in madder red, the operation is the same, on- ly augmenting the ingredients in proportion ; and let it be remarked that in small operations the quantity of ingredients must be somewhat greater than in great, not only in madder red, but in ail other colours. These reds are never so beautiful as thb'se' W the kermes, and much less so than those of the lacque or cochineal, but they cost less, and are made use of for common stuff's whose low prices would not dearer die. Most of the reds ^ IfniadderisboiJed, its red becomes obscure, and of a brick colr^- N 146 for the army are of madder, saddened with archil or brazil, (though these drugs be of the safe die) to make them finer, and more on the velvet, which perfection could not be procured to them even with cochineal, without considerably augmenting the price. I have already said that madder put on stuffs not being prepared to receive it by the alum and tar- tar- water, did in fact give its red colour, but that which it died was blotted and not lasting, it is therefore the salts that secure the die ; this is com- mon to all other colours red or yellow, which cannot be made without a preparing liquor. Now the question is, whether these act by taking off the remains of the oily and fat transpiration of the sheep, or whether that of the two salts, particular- ly that which even cannot be carried by luke- warm water, remains to catch, seize and cement the col- ouring atom, opened or dilated by the heat of wa- ter to receive it, and contracted by the cold to re- tain it. To determine which, use any alkaline salts, such as pot- ash, the clarified lays of oak-ashes, or any other pure lixivial salt instead of alum and tartar, put in a due proportion so as not to dissolve the wool, and afterwards dip the stuff in madder li- quor. This stuff will come out coloured, but will not last, even boiling water will carry off three fourths of the colour. Now it cannot be said that a fixed alkaline salt is unfit to extract from the pores of the wool the yolk or fat of the sheep, since lixivial salts are used with success in several cases, to take the greasQ,^ut of stuffs of what kind soever they be, whilP water alone could not take off. It is also well known* that 147 with fats foreign to the stuff, and an alkaline salt, a kind of soap is formed which water easily car- ries off. Again, take a piece of stuff died in madder red, according to the usual method, boil it some time in a solution of fixed alkaline salts, a small quanti- ty will also destroy the colour, for the fixed alkali, attacking the small atoms of the crystal of tartar, or crude tartar, which lines the pores of the wool, forms a soluble tartar, which w^ater dissolves very easily, and consequently the pores being opened in the hot water of the experiment, the colouring atom came out with the saline atom that sheath- ed it. This stuff being washed in w^ater, the remaining red colour is diluted, and a colour half brown and half dirty remains. If, instead of an alkaline salt, soap is substituted, (which is an alkaline salt, mit« igated by oil) and another piece of cloth died also in madder, be boiled for a few minutes, the red will become finer, because the alkali which is in the soap being sheathed with oil, it could not at- tack the vegetable acid, and the boiling only car., ried off the colouring parts ill stuck together, and their numbers diminishing, what remains must ap- pear deeper or clearer. 1 must also add, for further proof of the actual existence of salts in the pores of a stuff prepared with alum and tartar, before dicing it with mad- der, that more or less tartar gives an infinite vari- ety -of shades with this root only ; for if the quan- tity of alum be diminished, and that of the tartar augmented, a cinnamon will be had, and even if nothing but tartar alone be put into the liquo;*^ the red is lost, and a deep cinnamon or brown 148 root colour is obtained, though of a very good die ; for the crude tartar, which is an acid salt, has so much dissolved the part which should have produced the red colour, that there only remain- ed a very small ([uanlity, with the ligneous fibres of the root, which, like all other common roots, does then yield but a brown colour, more or less deep according to the quantity used. I have al- ready proved that the acid wdiich brightens tlie red, dissolves them if too much is used, and di- vides them into particles so extremely minute, that they aie not perceptible. If in the place of tartar, any salt which is easily dissolved be put with the alum in the liquor, to prepare the stuff for the madder die, such as salt- petre, the greater part of the madder red becomes useless, it disappears, or does not slick on, and nothing is got but a very bright cinnamon, which “Will not sufficiently stand the proof, because the two salts used in the preparing liquor are not of the hardness of the tartar. Volatile urin(jus alkalis which are obtained from certain plants, such as the perilla, the archil of the Canaries, and other mosses or lichens, destroy al- so the madder red, but at the same time communi- cate another to it, for on experiment, madder pre- pared after the manner of archil with fermented urine and quick lime, produced only nut-colours, but wdiicli nevertheless are lasting ; because there cnleredjnto the liquor only the little portion of u- rinous volatile that moistened the madder which the boiling was sufficient to evaporate, and be- sides, the cloth was sufficiently furnished with the salts of the liquor made as usual, to retain the colouring parts of the die. 149 When a pure red, that for cochineal an exam- ple, is laid upon a cloth first died in blue, and af- terwards prepared with the liquor of tartar, and alum to receive and retain this red, a purple or vi- oleT is produced according to the quantity of blue or red. The red of madder has not this effect, for it is not a pure red like that of the cochineal, and as I said above, it is altered by the brow n ligneous fibres of its root, and makes on the blue a chesnut colour, more or less deep according to the prece- ding intensity of the blue first laid on. If this chesnut colour is w^antcd to have a purple cast, a little cochineal must be added. In order to avoid this brown of the root, the diers w^ho make the best reds of madder take great heed to use the liquor of madder a little more than lukewarm ; the madder tarnishes consider- ably by the heat of the water, extracting the partL cles which die brown, and unite themselves vvith the red. This inconveniency might be remedied, if at the time that the madder root is fresh a means could be found to separate from the rest of this root the red circle whit^h is underneath its brown pelicle, and which surrounds the middle pith ; but this work would augment its price, and even then it would not afford so good a red as cochineal. However, it might be attempted to die cottons red, whose price m g it bear the expenses of this prepaiation. Madder being of ail ingredients the cheapest of any that die red and of the good die, it is mixt with others to diminish the price. It is with madder and kermes that the bastard scarlets of grain are died, otherwise called half grain scar- 150 Jets, and with madder and cochineal the half- common 'scarlets, and the half-crimsons are made. To make the half grain scarlet, the water of preparation, and all the rest of the operation is to be performed after the same manner as scarlet made of the grain of kermes, or the common Ve- netian, only the second liquor is composed of half kermes and half grape madder. For the half-scarlet and flame-colour, the com- position and preparation is as usual, nothing but pure cochineal being put in, but in the reddening, half cochineal and half madder is used : here also the sylvestre may be made use of, for after having made the preparation with cochineal, for redden- ing, use half a pound of cochineal, a pound and a half of sylvestre, and one pound of madder instead of cochineal alone. That the wool and stuffs may be died as equally as possible, it is necessary that the two kinds of cochineal be well rubbed or sifted, as also the mad- der, with which they must be well incorporated before they are put into the liquor. This must be observed in all colours, where several ingredi- ents are mixt together. This half scarlet is finish- ed liked the common scarlet, and it may be sad- dened after the same maiiKcr, either with boiling water or alum. The half-crimson is made like the common crimson, only using half madder, and half coebi*. neal, the cochineal sylvestre may be used here al- so, observing only to retrench half of the common cochineal , and to replace it with three times as much of .the sylvestre. If a greater quantity of the syl- vestre was used, and more of the other taken off, the colour would not be so fine. Various shades 151 Biay be produced by augmenting or lessening the madder or cochineal. Purple with Madder without Blue. I shall finish this chapter with an experiment which afforded a pretty fine purple without cochi- neal, or without the cloth being first died blue. 1 boiled a piece of cloth weighing half an ounce, wfith ten grains of Roman alum, and six grains of crystal of tartar ; half an hour after I took it out, wrung it, and let it cool ; then added to the same liquor twenty four grains of grape madder ; after it had furnished its die to this liquor, still impreg- nated with salts I dropt in twenty four drops of a solution of bismuth, made with equal parts of wa- ter and spirit of nitre, and then dipt my doih again. Half an hour after, I took it out, wrung and washed it ; it was almost as fine a crimson as if it had been done with cochineal, it liad even a sufficient ground to have remained in that state. ' I dipt it again in the same liquor, and boiled it for a quarter of an hour ; it came out a pretty bright purple ; this purple, tried by the proof of alum, rouses and embellishes itself, and by the proof of soap it remained of a much finer red than the com- mon reds of madder. If the cloth be kept for several days moistened in its liquor of tartar and alum, and afterwards died in fresh madder liquor, plain and without salts, according to the common method till it has taken a bright cinnamon colour, and to this liquor be add- ed the same solution of bismuth, a chesnut colour, and no purple will be obtained. Thie 152 what exactness is required in describing the pro- cesses of dicing, for want of which, all books hith- erto published on this art have been useless, as they neglected to point out the necessary cir- cumstances for the success of the desirsed col- our. In this second experiment, the cloth did at first take too much salts, they remained too long in it, and there was none in the liquor of the die ; for want of alum the purple did not a[>pear, because the white earth of this salt could not precipitate it- self with the dissolved parts of the bismuth, which as has been said in the chapter of the kermes, car. ry with them the blue parts of the smalt, which is always found in the mine of bismuth, and a portion of which very probably unites itself to this half metal during the melting. This mutual precipi- tation IS performed in operation of dieing, by the help of the astringent parts of the ligneous fibres of the madder root. CHAPTER XV. or YELLOW. HITHERTO ten sorts of drugs have been named for dieing, yellow, but by the proofs that have been made it ^ certain there are but five that are sufficiently lasting to be used in the good die. Sever^fgiore might be added to these five, as yel- lows arit*"easily obtained. I shall therefore first speak of these five, which are the weld or wold, savory, green wood, the yellow wood, and the fen- ligreek, bec^Sle these only are of the good die. The three first are very common plants inlilurope, the yellow wood comes from the Indies, and fen- ugreek is fownd every where. Weld is most commonly used, as it gives the brightest die. The savory and the green wood are best for wools that are to be made greens, because their natural colour borders a little on tlie green ; the two others give shades of yellow somewhat different. The yellows most known in the art of dicing are the straw yellow, the pale yellow, and the lem* on yellow. The orange yellows commonly made are not simple colours, therefore I shall not speak of them here. For dicing yellow, the common preparing wa- ter with tartar and alum is used for wool or stuffs, in the proportion of four ounces of alum for each pound of wool, or twenty five pounds for the hun- dred, and one ounce of tartar, and the method of boiling is the same as before. For welding, after the wool or stuff is boiled, put five or six pounds of weld in a fresh liquor for each pound of stuff ; let the weld be inclosed in a linen bag, that it may not mix with the stuff, and that the bag may not rise to the top of the copper, it must be kept dow% with a heavy cross of wood. Others boil the weld till it has furnished all its die, and sinks itself to the bottom of the copper, at which time thev place on it a cross or iron circle fitted with a net of cords. Others take it out with a rake when it is sufficient- ly f^oiled : sometimes yellow wood and other in- gredients are mixed with the weld, according to the shade required, by altering the quantities and the proportions of the salts in the preparation -and the time of boiling. I know by experience, that 154 V these shades may be obtained ad injinitum. This proof I have had in the essays I made with the flower of the virga, a very great acquisition in the art of dieing, if this plant was improved, which may be easily done, since it shoots a great many stems, and whose small ones may be easily trans- planted, and produce quantities in the course of one year. Light shades of yellow are obtained in the same manner as all others spoken of, only the preparing liquor for these light yellows must be weaker. I recommend twelve pounds and a half of alum for each hundred pounds of wool, and the tartar in proportion ; but these light shades do not resist the proofs as deeper shades do, made with the full proportion of tartar. Some diers endeavouring to help this, leave the wool and stuffs for a longer time in the die, because they take it slower in proportion to the weakness of the liquor ; but if they put at the same time in the colouring liquor, wools whose preparation shall have been different, they shall take at the same time different shades. These liquors more or less strong are called half preparing liquors, or quarter- preparing liquors, and they make great use of them in light shades of wool died in the fleece, that is, before being spun, and which are intended for the manufacturing of cloths and other mixed stuffs ; because the more alum there is in the liquor of the wool, the more it is harsh and ditticult to spin, and it must spin thicker, and con- sequently the stuff is coarser. This observation is not of great consequence for spun wool which is intended for tapestry or for stuffs. I only men- tion it to shew that the quantity of ingredients may be sometimes varied without danger. 155 The yellow wood is used in chips, or in coarse shavings ; by this means it is more divided, and yields its die the better, and a less quantity will do ; which way soever it is used, it is put into a bag, that it may not mix with the wool or stuffs. The same precaution is necessary for the savory and green wood, when they are mixed with the weld to change its shade. I refer to the lesser die the five other ingredients hitherto known which die yellow, and shall only observe here in regard to the good die, that the root of the dock, the bark of the ash tree, particu- larly that which is raised after the first sap, the leaves of almond, peach and pear trees ; in short, all leaves, barks and roots, which by chewing shew some little astriction, give yellows of the good die more or less fine, according to the time they are boiled, and in proportion to the tartar and alum used in the liquor : a proper quantity of alum brings these yellows to the beautiful yellow of the weld. If the tartar is in greater quantity, these yellows will border on the orange ; and lastly, if these ingredients are too much boiled, let them be roots, barks, or leaves, the yellow obscures itself, and takes browm shades. Although son\e diers use tumeric in the good die, which gives an orange yellow, this practice is to be condemned, for it is a colour that soon passes in the air, unless it be secured by sea- salt, which some diers do, w'ho take care to keep this imposi- tion to ihemselvcs. Those who make use of it in common scarlets, to spare cochineal, and to give to their stuff a red bordering on the orange, are blameable, for the scarlets that have been died after this manner lose in a short time that bright orange, / 156 as I have already said, they brown considerably I in the air. Yet these falsifications are obliged to 1 be in some measure tolerated ; for at this time that ■ bright orange being in fashion, it would be im- possible to give it to scarlet, without putting alarg- j er dose of composition, whose acids would greatly | hurt the cloth. The fustic wood is now preferred | in scarlet. CHAPTER XVI. OF BROWN. BROWN is the fourth of the primary colours. It is placed in this rank, because it enters in the j composition of a great number of colours- I'he I working it is different from others, for commonly no preparation is given to wool to be died brown, and, like the blue, it is only dipped in hot wa- ter. The rinds and roots of walnut, the rind of the alder, santal, sumach, roudoul or sovic, soot, &c. are used in this die. The rind of the walnut is the green part that covers the nut ; they arc gathered when the nuts are entirely ripe, then filled into great casks and moistened with water ; they are thus preserved until the ensuing year and longer if required. The santal or saunders is a hard W’ood brought from the Indies ; it is commonly used ground to a very fine powder, it is preserved for some time in this state in bags, to excite (as is imagined) a slight fermentation, which they pretend makes it the better for use, but I could find no differ- ence. This wood is most commonly ground with a third part of cariatoiir wood, which softens it ac- cording to those who sell it. It is greatlv inferior to walnut rinds, for it hurts the wool by harden- ing it considerably if used in large quantities, therefore it is better not to use it for fine wools and stuffs, or at least to dra\v but the lightest shades, for then its effect will be of less consequence. It is generally mixed with galls, alder, bark, and su- mach ; it is only by this means that it gives its colour when used alone, and unmixed with the cariatour wood. It yields but very little with the liquor 5f alum and tartar unless it be rasped. Not- withstanding this defect, it is tolerated in the good die, on account r,f the solidhv of its colour, which naturally is a yellow red- brown : it browns and grows deep in the air, it lightens with soap, but looses less by the proof of alum, and still less by that of tartar. Of all the ingredients used for the brown die, the walnut rind is the best ; its shades are finer, its colour is lasting, it softens the wool, renders it of a belter quality, and easier to work. To make use of this rind, a copper is half filled, and w hen it begins to grow luke warm, the rind is added in proportion to the quantities of stufis to be died and the colour intended. The copper is then made to boil, and w hen it has boiled a quarter of an hour, the stuffs, which were before dipped in warm water, are put in. They are to be stirred and turned until they acquire the desired colour. If it is spun wool, and that the shades required are to be matched with great exactness, a sniaiiouan- 158 tity of rind is to be put in first, and the lightest are first made ; more rind is then put in, and then the deepest are made : but to work with stuffs, the deepest are generally made first, and as the colour of the liquor diminishes, the lightest are dipped ; they are aired as usual to cool them, dried, and dressed. Next to the walnut rind is the root ; it gives a great number of shades and pretty near the same ; thus they may be substituted the one for the other, according to the facility of obtaining them, but there is a difference in the manner of usincr the root. A copper is filled three quarters full of riv- er water ; the quantity of root that is thought con- venient is cut into small pieces, and added in pro- portion to the quantity of wool to be died and the {^ade required. When the liquor is hot, so as not to bear the hand, the stuffs are put in and turned, until they have the desired shade, carefully observir-g to air them from time to time, and to pass them between the hands by the lists, to make the small pieces of roots ..hat stick fall off to prevent their blotting ; but this may be remedied by inclosing the cut root in a bag, as has been said of the yellow root# The stuffs that are to be of lighter shades are then to be dipped, and to be thus continued until the root gives no more die. If it is spun wool, the lightest are to be made first to match them the better, as 1 have already said in speaking of other colours; but above all, care must be taken not to boil the liquor at first, for then this root would give all its colour to the first piece of stuff, and there would not remain sufficient for the rest# 159 The method of dicing wool with roots is not very easy, for if great care is not taken to bring the die to a proper degree of heat and to stir the wool and stuffs so that they may be equally soaked in the copper, they run the hazard of being made too deep or of being blotted, which cannot be reme- died but by giving them a chesnut, prune, or coffee colour, as I shall show when I treat of the colours and shades arising from the mixture of black and brown. To avoid this inconvenience, the stuffs must be continually turned round the wynch, and dipped piece after piece, and great care must be taken not to boil the roots too much, but always to leave some dicing substance in them. When the wool or stuffs are died after this method, they are aired, washed, and dried* The method of treating the alder bark differs not from that of the walnut root before de- scribed, except that there is less danger in boiling it at the beginning, as it gives less ground of col- our to the stuff, it is commonly used for thread, and for colours that are to be saddened with green copperas ; it has, however a good effect on wool for colours that are not very deep, and it perfectly resists the action of the air and sun. The sumach is pretty near the same ; it is used after the same manner as the green shells or inward coats of walnuts ; it still gives less ground of col- our, and borders somewhat on the green ,* it is often substituted for galls in colours that are to be saddened, and it answers perfectly well, but must? be used in larger quantities. These different matters are often mixed togeth- GT, andas they are equally good, and produce 160 pearly the same effect, they readily afford a vari- ety of shades ; and yet there is nothing but practice can teach this variety of brown shades, for they entirely depend on the eye of the di- er. To use these ingredients mixt, and ground saunders together, put four pounds of this last into a copper, half a pound of powdered galls, twelve pounds of elder bark, and ten pounds of sumach ; this quantity will die twenty five or twenty seven ells of cloth ; the whole is boiled, and having slackened the boil by means of a lit- tle cold W'ater, the cloth is put in, turned and well stirred for two hours ; after which it is taken out, aired and washed ; other stuffs that are to be of a lighter shade are then put in, and thus continued as long as the liquor affoads any col- our. The quantity of these ingredients is augmented or diminished in proportion to the height of the §hade, and the stuffs or wool are boiled more or less accordingly. 1 have already observed that by this means only the colour can be extracted from the sannders. I liave lierc treated of the sannders and the manner of using it, although it should have been classed with the lesser dies, as this woad oueht only to be used for stuffs of low prices, because of the defects before spoken of ; yet as it is work- ed almost after the same manne r as the other in- grt:dients for dicing brown, and in several places is even tolerated in the good die, as it resists the sun and air as w’ell as the others, I thought it would not be improper here to give the method of working it ; for the same reason I shall now Ul describe the method of dieing with soot, though^ permitted only in the lesser die, having less solidi- ty than the rest, besides hardening the wool, and giving a disagreeable smell \o the stuffs. The soot (wood soot) is commonly put into the copper the same time as the water, and the whole is well boiled together ; the stuff is then dipt in, which is to boil more or less, according to the shade required ; after vvhich it is taken out and aired, and those put in which are to be lighter ; they are then to be well washed and dried, but it is better to boil the soot in the water for two hours then let it settle and empty the liquor into anoth- er copper, without mixing the soot ; the wool and stuffs are put into this liquor, and are less harden- ed av d dried than when they have been mixt with the soot itself, but the colour is not solid, and it is better not to make use of it for dieing stuffs that bear a price, and more so as all its shades may be had by the foregoing ingredients, vvhich are better, more lasting, and also soften the W'ooi. The diers of the lesser die usually employ the rinds of the nut and the root of the walnut tree for their brown colours ; the working of these two ingredients being common to diers of the greater or lesser die ; but there arc places where it is difficult to obtain them, and then the saim- ders and even soot are obliged to be used in their stead. What I have hitherto said to account for the solidity of the colours of the good die, may seem not to agree with brown colours spoken of in this ehaptci, since these are firmly applied on the wool without any preparation to receive them by the 11^ m <|Uor of alum and tartar, and consequently without first introducing into the pores of the fibres a salt capable of hardening itself in the cold, and to cement the atoms that colour the brown ; but if on a chymical analysis the green shell of walnuts, the root of the walnut-tree, the rind of alder, should be proved to contain, besides their astrin- gent properties, a vitriolated tartar, which is a salt that does not calcine in the sun, and that is only dissolved by boiling water ; this I say will con- vince that these ingredients are sufficient of them- selves to produce on the stuffs, without any foreign help, the same effect as the other drugs, whose colours are not set in with solidity, but by the help of a salt capable of cementing the colouring atoms. The soot does not give so lasting a brown, be- cause it only contains a volatile and an earthy salt easily dissolved, and in fact the soot being only composed of the lightest and most volatile parts of combustible bodies, which have served as food for the fire, it could not raise tartar of vitriol along with it, which is a salt that does not rise by heat, and which is also seldom found in the wood which we commonly burn in our chimnies. As I am not willing to omit any thing within the limits of my knowledge, on the article of woollen dicing, I shall give two or three hints on the acid of vitriol. If you would have a beautiful claret on wool, stuffs, or cloih, boil in a copper of a good size, red wood or saunders in proportion to the shade you want, and two pounds of logwood, for fi;rty pounds of wool previously scoured. When the ingredients have boiled half an hour, put a pint of 163 oil of vitriol into a pail of cold water, and add it to the liquor, when the wool must be put in, and gently boiled for two or three hours. It is then to be taken up on a scray, that is, set across the copper to drain, and five or six pails of water pour- ed over it. The copper must be then run down and filled as before with fair water, and when it is hot, ten pounds of copperas and four ounces of pearl-ashes must be added, and the wool returned and well worked with a long pole to make it even. The ashes (which are a fixed alkali) act upon the logwood, and give it a fine lustre at the same time. It weakens the acid of the vitriol, and makes way for the copperas to do its part, which would otherwise be kept at a distance ; the vitri- ol does not obstruct the cloth in the fulling-mill, for the vitriol, which some suppose to be a great enemy in the mill,isdivestedofitsacid by the strong alkali contained in the chamber ley in securing, and the colour remains perfectly vivid. If for for- ty pounds of w'ool, &c ten pounds of nut galls were bruised and boiled with the above ingredi- ents, the acid therein contained would produce as brilliant a colour, and, if possible, more holding than the former ; but if galls are used, the same liquor will do the same business when the coppe- ras is added without ashes as a fresh water would when vitriol is used. If forty pounds of cloth, stuff, or worsted were boiled in a sufficient quantity of redwood or saunders, and one pint of prepared aqua fortis be added to the liquor after the goods have boiled an hour and a half, and then turned well for half an hour, the colour will be vivid and fine ; the copper must be well cooled when the spirits are put in. 164 When cloth or stuffs are died claret with oil of vitriol, great care must be taken to turn them con- tinually over the vvynch, and particularly in taking OUT, observe the instant the last end comes up to take off iiito a large tub of cold water, that all parts may cool alike, or the colour will be very uneven, as the vitriol when hot will not bear the air. Oil of vitriol is so useful a thing in dicing, that any colour, save woaded blue or green, niay, by the help of its acid, be brought to a fine claret^, black not excepted. CHAPTER XVlh OF BLACX. BLACK is the fifth of the primary colours. To^ die the best and most lively shade a vessel sulfi* ciently large is filled with soft water, and for ev- ery hundred weight of cloth, thirty pounds of log- wood in chips must be put in, with half a pail (;f elder bark and six pounds of sumach ; boil these ingredients together half an hour, when the cloth may be entered (the copper being first cooled by the addition of cold water) and broiled an hour and a half, being instantly turned on the wynch to pre- vent an unevenness of die. This operation being ended, which is called a preparation or stuffing the blacks, I shall proceed to the finishing. A pmall tub is to be placed at the side of the copper, out of which it must be filled with hot li- Uuor, in which put ten or fourteen pounds of cop- 165 peras to dissolve ; the cloth is then kept turning, whilst a man with a piggin is lading the copperas water into the copper ; the cloth is turned here at a boiling heat one hour, then taken out and cooled well in all parts alike ; when thoroughly cold, return it into the copper, with two handfuls of eopperas,and boil it gently as before for two hours, then cool it again* Whilst the second cooling is carrying on, six pounds of logwood, ten pound of bark, and two pounds of argil, with ten pounds of soda or com- mon ashes, and three pounds of copperas, must be added to the liquor ; these ingredients must be made to boil one hour, when the goods must be turned and worked one hour. Keep the wynch continually turning, always observing that the small portion of air w hich the goods receive by turning on the wynch, contributes much to the beauty of the colour. Some diers instead of ashes use cham- ber ley, but this is a bad custom. If they tvculd become good black diers, they must abandon their old practice, and by mixing their natural genius with reason and good sense, they will soon find by experience, that the acid of the argil acts only on the vitriolic acid of the copperas, and prevents a brown or rusty hue that will unavoidably proceed from the logwood ; the alkaline power of the ash- es at the same time farces it to asume its natural violet colour ; that if too great a quantity of log- wood is not used, (which would certainly preju- dice the colour) and this rule carefully observed, the black would resemble a raven’s feather ; they must be well washed at the fulling mill. I shall not entertain the reader with a tedious recital of the manner of treating those goods whose 166 superior quality renders it needful that they should previously be died blue. It is sufficient to know, that they must have a less proportion of ingredi- ents, though the operation is the same as that of the common black. When fine cloth is to be died black, great care must be taken not to let it hang on the wynch one minute ; it must be thrown oft the instant the last comes up ; otherwise its own weight when wet and hot would fill it with wrinkles that would nev- er remove. The same caution must be taken when the cloth is on the floor, to draw it between two men over a long stick by the lists, each tak- ing hold of one end with their left hand, to be con?- tinned till cold before it be returned. Remarks on the Black Die. The most essential thing to be remarked is, thal it prejudices and weakens the goods ; for this rea- son those that are died black are soonest worn out ; they are however in all other respects equal to those that are died other colours. This delect is chiefly to be attributed to the vitriolic acid of the copperas, which is only imperfectly saturated by the iron ; as iron united to any other acid, and even to vegetable acids, is capable of produ- cing black with astringent vegetables. There is great cause to think that by substituting other combinations of this metal for the copperas, this inconvenience might be remedied. These are certainly good and useful essays to attempt- It is not without cause that the blacks are directed to be aired between the dippings, as it’' infinitely contributes to the beauty of the die j 167 for it is certain that this die is different from most others which lose of their colour in drying ; this on the contrary acquires a great deal ; it is univer- sally known, that good writing ink does notap- pear any thing near so black when fresh and re- cently used, as w^ en dry and that even it grows more black during a certain s[>ace of time. The same happens to the black die. The cloth is in some measure of a grey blackish colour immedi- ately afterthe first dip ; it only acquires the beau- tiful black on being exposed to the air ; this is not the only example of the influence of the air on colours ; the blue vat exhibits something like it. CHAPTER XVIII. OF THE MIXTURE OF BLUE AND RED. IN speaking of the red I observed that there were four different kinds in the good die» We shall now explain the tfi’cct of these different reds placed on a sfuff that has been previously died blue. If a blue stuff is boiled in alum and tartar, after the maimer and proportion taught in the ar- ticle of red, and which is afterwards to be died with kermes, the following colours will result, viz. The king’s colour, the prince’s colour, the pansy, the violet, the purple, and several other like colours ; but the keimes is seldom used for these colours, on account of its high price and the quantity which would be required, but more so, because cochineal yields a liner colour 168 for this purpose, and with greater ease. I have \ alre.icly observed that kermes is seldom used, i though there are several compound colours in i which it produces a very good effect, as will be i more particularly described. When the kermes is used to lay a red on blue, it is indifferent what ground of blue is first given, or v/hether it be given before or after the stuff' is died red, because the colour of the kermes is too j solid to be changed by the lime of the vvoad vat, (unless the vat be over-loaded)or by the pearl-ash- -i es Hi the indigo. Thus if the woad vat is not too { old, it may be begun by either of these two coL ! ours at pleasure, or by that which is most conven- ient to match the shade. Although I named but a small number of colours, a great many may be draw n from these two principal ones, according as the one or the other may be more predomi- nant. The mixture of blue with fire colour scarlet is never usf d in any of theit shades. To convince myself by experience I took a piece of cloth died in scarlet, and dipt it in the blue vat, and died a second piece according to the method of dieing scarlet, having previously died it blue. The one and the other succeeded very badly, and made a kind ol dull spotted violet, so it appeared that the two colours did not unite, but that they were laid each on different parts of the wool. This no doubt is caused by the acids which enter the composition of the scarlet. But without entering here upon the physical reason of this operation, which might occasion too long a dissertation, and tedious rep'etition of what I have already said, the fact appears sufficient here j it prove^s that no 169 beautiful colour can be had from the mixture of blue and scarlet ; ii must be crimson. From the mixture of blue and crimson, the co- lumbine, the purple, the amaranth, the pansy, and the violet are formed ; these colours have also a great number of shades which depend upanthe shades of the other colour, from whence they are derived. I have said so much on the primary colours, that no difficulty can remain in the execution of the compound colours. Stuffs or spun wool are first made of one col- our, and then died of the other, precisely as if it was white ; but it must be observed in this case, that the stuff be first died blue before it is made into crimson, for the reason before given, that the alkali of the one or the other vat greatly obscures the brightness of the red of the cochu neal. To make violets, purples, and other like shades, what I have already said on crimson is to be fol- lowed, because these colours will lutvc neither brightness nor lustre, but by following the precau- tions necessary for fine crimsons. From blue, and the red of madder, proceeds al- so the king’s colour, the prince’s colour, (but in- finitely less beautiful than when the kermes is made use of ; for the red of the madder is always obscur- ed by the brown of its ligneous parts) the minime, the tan colour, the amaranth, the dry rose, ahr avs less bright than when the kermes is made use of. Nevertheless it is sometimes mixed with madder, as I have already said, to make halfigrained scar- lets, and the colours which proceed from it arc always finer than when madder alone is used on a P 170 stuff died blue ; madder is also mixed with cochi- neab as in the half crimsons, and a great number of very fine shades are drawn from them, which cannot have paiiicular names, but which border on those I have just mentioned. Some of these may be made as fine as if dearer ingredients were made use of. It is the business and profit of the dier not to use the dearest, when the same effects may be produced by the cheapest ingredients. It is impossible for me to give any instructions on this article, since use alone can teach it. The old liquor of madder and cochineal is often used, whose colours have not been entirely extracted, which makes a considerable saving, and the colour ’is not less good. I can say nothing positive on this, since the effect which will result from it depends on what colour may remain in the liquor, and on the shade intended. chapter XIX. OF THE MIXTURE OF BLUE AND YELLOW. FROM the mixture of blue and yellow but one colour is produced, which is green ; but there are a variety of shades ; the principal ones are, the yellow green, the light green, the gay green, the grass green, the laurel green, the molequin green, the deep green, the sea green, the celadon S*’^^*’* the parrot green, the cabbage green, and I shall add the duck wing green, and the celadon green without blue. All these shades, and the interme- diate ones, are made after the same manner and 171 f with the same ease. The stuff or wool died blue, light or dark, is boiled in alum and tartar, as is usually done to make a white stuff yellow, and then with weld, savory, or greening wool. All these ingredients are equally good as to solidity, but as their yellows differ a little, so do the greens that arise from their mixture. The weld and the savory are the two plants that afford the finest greens. To make the green shades which border on the yellow, the stuff* must be of a very light blue, and boiled with the common quantity of tartar and al- um to receive the yellow ; for without these salts it would not be lasting, (but for a parrot or cabbage green the blue must be very deep) and as it is on- ly to have a light yellow, the stuffs must have but a half preparation ; I have already mentioned this, sometimes even a quarter of the water for the common preparation is sufficient. When the workmen make these colours, they often use the salts without weighing them, and guess at the quantity which they think necessary for the shade intended ; a long practice may in some measure make them pretty exact, but it would be still better if they did not trust to it. I know by repeated experiments thatthese green - blue shades are as wqll made by giving the stuff the common preparation. The yellow which is afterwards applied to it is the more lasting, but on this occasion less weld is to be put into the li» quor of the die, or any other colouring matter, and the stuff must remain less time in the liquor, notwithstanding two reasons induced to the con- trary ; the first and most interesting to the dier is, that they would consume a greater quantity of 172 drugs than is necessary ; and the second, that the less alum used in the preparation, the more the softness and the quality of the wool is preserved, and the less the first die of blue is damaged ; for the alum always greys the blues a little. Thus it is better to leave the dier to his custom of regula- ting the strength of his preparation to the necessa- ry pitch to give these colours. I have said that to die green it was necessary that the wool should be previously blue ; because I think that the two colours laid on in this order hold better, and that the colour would not be so good if otherwise done. Of this I assure myself by making the greens, of which I have spoken, with the five colouring matters already known, which make a yellow of the good die ; 1 have tried a yellow of the same materials, the contrary, hav- ing dipped five yellow pieces in the woad vat, and have had as fine greens as the first. I exposed both to the summer’s sun, and they have resisted sufficiently to be esteemed of the good die ; but those which had received the blue before the yel- low lost the least, so that in particular circumstan- ces the dier must be allowed to begin first with yellow. But greens which have the blue colour last, will sully the linen more than the others ; for if the blue has been first died, all that could be taken off was done by the alum liquor, which hap» pens on the contrary when the blue was put on last ; the only remedy for this, is to scour the green well after it comes out of the copper. Cloth died king’s blue, and greened with the flower of the virga aurea Canadiensis^ make a very fine green, provided it has been boiled in a liquor with three times the weight of alum to one of white tartar ; the green is not inferior to that made of weld. I have also greened blues with ash bar^ povw dered ; they are of a very good die, but hot of a fine colour, and only fit for liveries. The- leaves of almond, peach and pear trees, &c. give yellows, which serve to make green shades, that are rather difficult to hit on at first. ' A stuff died in the king’s blue, well scoured, then boiled with four parts of alum, and one of tartar, takes a fine deep green of the shade of a duck's wing; but it must be boiled for two hours in a liquor, with a sufficient quantity of the root of sharp pointed dock grossly bruised. This root, which grows in every hedge and field, is a good acquisition to the art of dicing ; for with it, and without any other addition but the prepar- ing liquor for the stuffs, it produces an infinity of shades, from the straw colour to a pretty fine olive ; only putting more or less to the liquor, and boil- ing it from half an hour to three hours. These shades stand all manner of proof. I strongly re- commend the cultivation of this dock in damp pla- ces, for its use in dicing. The celadon green (a particular colour] is much admired by the inhabitants of the Mediterranean, and may in strict business be made in the good die, by giving a blue ground to the stuff. But this shade of blue must be so weak, that it is only a milk and water colour, which is very difficult to give smooth and equal. When this shade has been happily h‘t, it is easier to give the yellow die that suits it, with the virga aurea than w ith the weld, rhe v'lrga aurea is not known to the di- ers of Languedoc, who make most of these kind P 2 174 of colours, and as the necessary blue shades arc difficult to die, they are sometimes permitted to die celadons with verdigrise, although this colour be in the rank of the lesser die^ The Dutch make this colour perfectly, and ren- der it more lasting than it commonly is with the verdigrise. Here follows their method. Two coppers are set a little distance the one from the other. In the first is put for two pieces of cloth of forty-five or fifty ells long, eight or ten pounds of white soap cut small and perfectly melt- ed. When the liquor is ready to boil, the cloths are dipped in, and boil for half an hour. Another liquor is prepared in the next copper, and when it- is scalding hot a cloth bag is put in containing eight or ten pounds of Cyprus or blue vitriol, and ten or twelve pounds of lime, both powdered and well mixt ; this mixture must be as equal as pos- sible. The bag is moved about in the hot water, -but not boiling, till all the blue vitriol is dissolved in the liquor ; then a wynsh is put up, surround- ed by a clean linen cloth, and well fastened on ; one end of the two cloths is put on the wynch, which is turned swiftly that the cloths may quick- ly pass through the soap liquor to that of the vit- riol ; then the wynch is worked more gently, that^ the cloth may have time to charge itself with the parts of copper,, which the lime has scattered in the liquor, by separating and precipitating them from the vitriol which contained them. The cloths are left in this liquor, which must not boil until they have taken the shade of the celadon that was wanted ; then they arc taken out and well air- ed : they must be entirely cold before they arc washed, and must touch no wood before they 175 are, for the wood spots them ; for this reason the? wynch and the horse are surrounded with cloth. CHAPTER XX. OF THE MIXTURE OF BLUE AND BROWN. LITTLE use is made of the shade which arises from the mixture of blue and brown ; these are greenish greys, or a kind of olives, which are on- ly tit to match shades for tapestries ; these colours are easily made when wanted, and it is equal to begin by the blue or the brown colour to the spun wool ; but care must betaken that it be well scour- ed, as is done for the blue and the compound coh ours which are finished by dipping them in the vat.^ Any substance that dies brown may be equally made use of for these colours, and some give tha_ shade required better than, others. CHAPTER XXI. or THE MIXTURE OF BLUE AND BLACK. NO particular shade arises from this mixture, except by the mixture of blue and grey, (which are shades of the black). In this case the blue must not be very deep, and is afterwards worked the same as the black, excepting that the colour not being so dark less copperas enters in ; but I repeat again that this colour ought only to be es- 17 ^ teefned a shade of the black. Thus it may be said that no shades are made from blue and black used by themselves, and very few from blue and brown. CHAPTER XXII. OF THE MIXTURE OF RED AND YELLOW. FROM scarlet of pjrain or kermes and theyel- low are formed the aurora, the marigold, and the orange. The wool is first boiled in alum and tar- tar, and died in one of these colours, and then dipped in the second, or by mixing in the same li- quor the kermes, the weld, the savory, &c. and so dieing it at once. Yet it is easier to attain the ex- act shades by dieing it at twice ; for this reason, the wool or the stuff may be alternately passed in the one or other liquor, till it be precisely of the desired colour. The lobster and pomegranate colours are done exactly as scarlet is, that is, boiled with cream of tartar, cochineal, and the composition, after whcih they are taken ? out, aired and washed. For the finishing, a fresh liquor is prepared as for the scarlet, but without cochineal ; in its stead, a little yellow wood ground substituted ; this de- pends on the colour the stuff is intended to be of. The more it borders on the orange, the more yel- low wood is added, diminishing the quantity of the cochineal. I endeavoured to make this colour after three different methods, and succeeded in all ; the first 177 2 s that which 1 have described : the second is by putting fustic instead of yellow wood, and this saves a great deal of cochineal, and the shade of the fustic is a great deal more on the orange than the yellow wood, but these ingredients are not last- ing, and ought not to be used but in the lesser die. The method is with cochineal alone, by augment- ing the quantity of the composition, which rous- es the cochineal, and turns it to orange as much as is desired ; but this is attended with very great inconvenience. 1st, The colour becomes very expensive,because it requires more cochineal than common scarlet, as the great quantity of the com- position, which is an acid, makes it lose part of its ground. 2d, For the same reason the colour al- ways looks starved, it appears as if the cochineal had been spared, the composition having dissolv- ed part of it. 3d, This large quantity of compo- sition hardens the wool, and makes it more liable to be spotted by dirt and sharp liquor, and conse- quently this method is the worst. I mentioned that the inconveniency of the second was using the fustic, which is a wood forbid in the good die ; consequently the first ought to have the preference, if it give the lobster colour as bright as the se- cond. But this colour made by the yellow wood has not all the solidity that might be desired, as I have tried by exposing it to the sun ; this at first appears extraordinary, since the ingredients used have all the solidity possible. But the reason why they are not so good in the present case is, that the cochineal used in the scarlet composition and the cream of tartar are too solid ; thus the lobster colour loses nothing in the air. But the case is Otherwise with the yellow wood, though it be very 178 lasting on the wool boiled in alum and tartar, es- pecially when a little allum is added to the liquor of its die ; it is not the same as when the wool or stuff has received the water for the scarlet prepa- ration in which no alum can enter, and conse- quently when these sort of colours are exposed to the air, they sadden in a short time, that is, they lose part of their orange colour, produced by the mixture of the yellow with the red, and the effect of the air upon this colour is the same, though it appears different from that on all others, &c. that it commonly turns them pale ; yet this one dark- ens and browns them by taking away part of its bright orange. For it is demonstrated by several chymical experiments, that there is a vitriolic acid in the air like unto that which may be extracted from alum. Now if a stuff died lobster colour was to be passed through alight solution of alum, the acid of the salt would immediately sadden it, and the red of the cochineal would eclipse the orange die ; the same thing must then happen when such a colour is exposed to the air, which is impregnated with the same acid. Very few shades are made from the crimson and yellow, because of the price of the first, and that pretty near the same shades are made with madder and kermes, yellow and half scarlet of grain, as well as from the yellow and half crimson. It is with these different mixtures, that marigold, orange, gold yellow, and other like shades are made, which are simply produced by the mixture of the yellow and red, and sometimes by yellow alone. CHAPTER XXIII. OF THE MIXTURE OF RED AND BROWN. THE reds of the kermes and cochineal are not used in this mixture, for madder has as good an effect on those which cannot become bright be- cause of the dark obscure colour of the browm, but after they are maddered, they are dipt in the old liquors of cochineal or kermes ; yet a liquor in those ingredients is seldom purposely prepared, being too dear for such common colours which are as easily made with madder. The stuff is to be boiled wdih a quantity of alum and tartar, pro- portioned to the red shade of madder intended ; it is then passed through a liquor of this root, and afterwards dipped and worked in a liquor ofw’al- nut roots or walnut rinds ; the following colours will be produced, viz. cinamon, tobacco, chesnut, musk, bear’s hair, and numberless others, by va- rying the ground of the madder from the brown- est to the lightest, and keeping them longer or shorter in the liquor of the root. The process may begin within any one of these colours, but the red is commonly died first, as the liquor proper for the madder might hurt the brown, therefore they are not to be mixt as the red and yellow^ are sometimes. 180 CHAPTER XXIV. OF THE MIXTURE OF YELLOW AND BROWN. FROM this mixture are produced the shades of feulemort and bears hair. Soot is commonly used in these colours instead of the rinds of walnuts, or the root of the walnut tree, as it makes them finer, but care must be taken that the wool or stuff be well scoured after it is died, to take off the bad smell of the liquor ; for only the clear liquor of the soot is to be used, as has already been said. The walnut rinds are preferable to the soot, unless obliged to match a pattern of feulemort with the greatest exactness, and which may sometimes be done with the wal- nut. These are the only two browns resulting from these shades, the sumach and the alder bark not giving sufficient ground. Wool must be boiled in alum and tartar to die it yellow before it is made brown ; but if it should not have a sufficient ground of yellow, it might be passed afresh through the yellow die, notwiih- standing it has been browned, though in fact this method of seeking exactly the shade does not make so lasting a colour as when the yellow was at first sufficiently died ; for when the yellow is died first, . the brown is a great deal bright^er. 181 CHAPTER XXV. OF THE MIXTURE OF BROWN AND BLACK, FROM this mixture a great number of colours may be extracted, as coffee, chesnut, prune, musk, thorn and several like shades, whose numbers are almost infinite, and of great use. The method of working them is this : After the wool or stuffs have been made brown, as already described, and that several shades have previously been given ; as for example, a stronger brown for the coffee, chcsnut, &c. galls, sumach, and elder bark are put into a copper in proportion to the quantities of stuff to be died ; the whole is boiled for one hour, after which green copperas is to be added. I'he stuffs that are to be lightest, as the thorn, are first dipped in this liquor, then taken out, and others that are to be browner are put in, observing to add copperas to the liquor each time, and as occasion may require, which is known by its not browning tlie stuff quickly, thus continuing until all the stuffs are browned ; the liquor must not boil, nor be of a greater de- gree ^ heat than the hand can bear. When the galls and other ingredients are boil- ed, cold water is added to refresh the liquor before the stuff is put in : this is a precaution that is ab- solutely necessary, as I have often said. The stuffs arc first to be dipped in lukc warm water before they are put into the copper, lest since they were browned they should have dried ; and they 182 must be aired when they have remained some time in the browning, by passing them between the hands by the lists, without which they would per- haps spoil, blot, and be unequally died, and the brown, for want of airing, would not be lasting, , as there would not be a successive congelation of the saline parts of the vitriol. 1 have now shown all the necessary colours or j shades w'hich may be produced by the mixture i of the primitive colours taken two by two, and j • have given a minute description both of their ef- I fects and the method of producing them. There being but few colours which may not be greatly varied, it depends on the judgment of the dier to choose the easiest, provided the colour be equally | fine. CHAPTER XXVI. OF THE MIXTtTRE OF THE PRIMITIVE COLOURS, ! TAKEN THREE BY THREE. FROM blue, red, and yellow, the red olives ^ and greenish greys are made, and some other like I shades of little use only for spun wool designed I for tapestry. It would be a repetition to give j the method of using these colours, having suffi- | ciently explained it in the preceding pages. j In the mixture, where blue is a shade, it isusu- i al to begin with it ; the stuff is afterward boiled i to give it the other colours, in which it is dipped alternately one after the other ; notwithstanding tliey are sometimes mixed together, and are 183 as good, provided they are colours which require the same preparation ; for example, the madder- red and the yellow* As to the cochineal and kcrmes they are seldom used in these common colours, but only light colours which have a bloom or vi- nous hue, and which must be bright and brilliant, and then they are not used in the last liquor, that is, the stuff is only dipped in when it has receiv- ed the other colours, unless they are to be greyed a little, which is lastly done by passing them through the browning. It is impossible to give any precise rules for this work, and the least prac- tice of these rules will teach more than I could say in many volumes. Olives are made from blue, red, and brown, from the deepest to the lightest, and by giving a little shade of red, the slated greys, the lavender greys, and such like. ^ From the blue, the red, and the black, an infi- nite number of greys of all shades are made, as the sage grey, the pigeon grey, the slate grey, the lead grey, the king’s and prince’s colour, browner than usual, and a variety of other colours almost in- numerable. From ydlow, blue, and brown, are made the greens, goose dung, and olives of all kinds. From brown, blue, and black, are produced the brown olives and the green greys. From the red, yellow, and brown, proceed the oraijge, gold colour,, marigold, feuleraort, old carnations, burnt cinnamon, and tobacco of all kinds. From the red, yellow, and black pretty near the same as the last, and the deep feulemort ; as also the ox hair and brov;n nut, and others of the like kind- 184 I give this list of colours only as a table to show in general what ingredients are made use of to make these sort of colours, which also partake of several others. Four or five of these colours may be mixed to- gether ; however this is rarely done ; a minute detail on this subject would be useless, because all that may be done is oftentimes superfluous. ^ shall now only relate the manner in which I have seen about forty different shades of carnations made in spun wool ; this example will show what may be done in all other cases. There were none of those bright shades of scarlet in these which are made as in the chapter oa that colour. Variety of Carnation colour All these flesh or carnations were old carnations, or shades of it, so that they were all obliged to be taken from the mixture of the red of kermes, yel- lovv» brown, and Iflack. An unequal preparation was first given to the wool, reserving for the lighter shades those whose preparing liquors had been weakest. When they had remained as usual four or five days in the li- quor, the lighter shades were died ; these colours were disposed in four different vessels, which were always kept sufficient!) hot without boiling. A skain of w’ )ol was immediately dipped in the liquor of the kermes for a minute, it was taken out, wrung, and passed through a liquor of weld, and an instant after through a brown one, and it became of the colour required by the dier ; he immediately dipped another, which remained a lit- tle longer in each liquor : he went on after this manner, and when, after being strongly wrung, and sec med to want a little rt d or any other col- our, he dipped it in the liquor which it appeared to want. By tnis nitihod he brought all his col- ours to the desired shade, and passed ihrough ihe brown those that were required to be deeper. I was fully persuaded by this method of working, that only patience and practioe were wanting to make all the colours which can be conceived. Too much cauth’n cannot be given in this kind of work, to begin abvays with the lightest shades j for it often happens that they arc kept too long in some of these iiquots, and then that skain must be made into a darker shjde. But when once the lighter shades are matched, and in a right degra- dation, the rest are easily made. What 1 iiave been speaking of, relates only to v/ooi intended for tapestry, when it is necessary that the shades be carried on with the greatest degree of precision, without which it would be iinpossibletu imitate the flesh colours of the painter. With regard to stuffs, it seldom or never hap- pens that they are made in these gradations of shades, or that so many colours are mixed togeth- er ; two or three arc generally sufficient, since it has been shown what a variety of colours arose, from their combination, that even names cannot be found for them. I think I have omitted nothing regarding the dicing of wool or woollen stuffs in the great and good die, and I make no doubt but that by exact- ly following what I have laid down, tach colour and all the shades maybe exeegted to the greatest perfection, as well in fleece wool, spun wool, as or. stuffs manufactured in white. Q2 18d I think it yet necessary to add something in re- gard to mixed stuffs, that is, whose wool is mixed before the manufacturing of the stuff, and to teach the method by which this mixture of died wool is performed, to be afterwards carded and spun to form a colour resulting from those different wools. It may be objected, that this article rather re- lates to the manufacturing of stuffs than their dies; but to this 1 answer, that sometimes colours are made by mixing wool of different shades, whose colours would not easily be imitated by dying the stuff of a compound colour ; some of these dif- ferent shades composedof ingredients which would require a different preparation ; whereas by dic- ing ever} part of the wool separately, the mixture is made without any difficulty ; it cannot there- fore be improper .here to give the manner of mix- ing together wool of different colours, and I shall also give the man net of making mixtures for an essay or proof in small, (which is always nectssa- ty) to choose that which produces the most agree- able effect. CHAPTER XXYIL OF THE MANNER OF MIXING WOOL OF DIF- FERENT COLOUBS FOR CLOTHS OR MIXED COLOURS. Colours mixed in the Loom, ONE example of the method of mixing (after the most exact manner possible) wool of different colours, will be sufficient, and it will be easily ap- plied in ail other cases required. Suppose a mix- ed cloth of a coffee colour to be made, the follow- ing is the method of the manufacturers of Lan- guedoc, and pretty near the same is practised in all other manufactories. Three hundred and fifty pounds of wool are first died coffee colour, which is called the ground wool, that is, that which prevails in the stuffs ; af- ter which are taken five pounds of wool died in madder red or kermes, and two pounds died in king’s blue ; ihese last are called the wool of mix- ture. This wool is distributed to diff rent per- sons placed in a ring in a large room. The factor, or he that has the care of the mixture, stands with a stick in his hand in the centre of this circle, the men being at six feet distance from him ; eight or ten arc generally employed at this work, and all the wool is given to them. In the present case^ for example, six will be employed in bearing the prevailing wool or coffee colour, one the blue. and another the red ; but they must be so situat- ed that there may be three together who have the cofiee coloured wool, then he that has the red, then three with the cofiee colour, and lastly he that has the blue. When there is a greater num- ber of colours, they are thus equally distributed^ observing to divide them as much as possible, the one from the other. The men thus disposed walk slowly round the factor, keeping an equal distance, and each step they take they cast at the feet of the factor a small lock of the wool they carry, with this difference, that those that have the red or the blue, having but a small quantity to distribute, fling but little each time, whereas the others must fling much more. The factor stirs the wool with his stick whilst the men are flinging it, and that the mixture should be perfect, they must ail have distrib- uted their wool at one and the same time. The factor then mixes it again, and gives it to the car- ders. The carding makes a perfect mixture, so that no particular colour is to be distinguished, and it appears of one uniform colour ; it is afterwards spun, the cloth manufactured and brought to the mill. The importance of this mixture being ex- actly made is easily conceived, for if these colours were unequally distributed, the cloth would ap- pear full of blots. As in the composition of these mixtures it is not possible to judge exactly of the efiect which may be produced by the combination of all these colours in difierent proportions^ I shall give a meth- od of mciking a proof in small, that a colour form- after this manner by a known proportional 189 mixture, it may be executed in great, and be cer- tain that the colour of the stuff' will be equal to that of the pattern. CHAPTER XXVm. OP THE METHOD OF PREPARING IHE PAT- TERN FELTS, OR MIXTURE FOR AN ESSAY. THIS little work is very simple and very useful, as it will show in an hour what a mixt cloth will be after it is manufactured^ and even when it is entirely dressed. For this purpose, wool of different colours are taken, and alter having weigh- ed each exactly, the mixture is made whh the fingers in the proportion which is judged suffi- cient, but the whole in a very small quantity ; so that the mixture being made, it may not exceed the bigness of the fist. This wool is then moistened with a little oil, and carded several times with small cards, till all these colours are well incorporated together and perfectly well mix- ed. This wool, which is extremely open and of the square form of the card, is folded four times, and gently pressed between the h mds. It is then plunged into a strong soap wxUer, and putting it again between the hands, it is strongly pressed at different times, striking sometimes one hand on the other. It is then gently rubbed betu ixt the two hands, which hardens the wool by contracting it all manner of ways, and making it occupy less space. It is then dipped <>gain in the soap water, and continued to be felted, until it has acquii ed 190 some consistence, and that it becomes like felt ! and pretty near the same consistence as the com- mon cloth. This felt is then a true copy of what ‘ the cloth will be after its manufacturing ; for when it has been well felted, that is, that the wool has been equally and carefully extended under j the hand coming from the card, it is as equal and i as smooth as the cloth itself can be. To finish it | also as perfectly as the cloth, after it has been washed to take off the soap, it is dried and put between two papers, and pressed with an iron somewhat hot : by this means it acquires a lustre i which makes it appear like a cloth which has been j entirely dressed. ' If the colour of the felt is approved of, the mixture in great is made for the cloth, by follow- ing the same proportions exactly, and it will cer-. tainly be like the pattern, for not only the wool of different colours are as entirely mixed and closed one to the other in the felt as in the cloth, but the soap which has been made use of to felt it, has produced the same effect as that which happens to the cloth in the fulling mill, for there are several colours and particularly those that have been browned, that is, in whose compositions there are shades of black and grey, which lose in the mill part of :heir browning, so that it must alwa} s be died of a deeper colour than intended to be after finishing : this defect of solidity in tiie browning does not hinder it from standing very w^ell the action of the air, but it is easily spotted by acid liquors, as has been before said. The colours that have been saddened in the woad or indigo vat are not liable to this, they scarce lose any thingin the mill. The felt produces the same 151 efFect, and it is certain that the stiiiF will not lose more in great at the mill than the felt did with soap ; consequently this preliminary operation of the felt may be looked upon as a sure guide for the choice and assortment of wool in mixt cloths. These patterns are made still better with black soap, but it gives them a . disagreeable smell, which is not easily taken off by repeated wash- ings. The felts, when made, may be died for stuffs, in which it is required that one colour should cov- er the other, for then, after the stuff should have been mixed with the same colours as the felt, it might be di|)ped in the same die through which that had been passed, and by this means it w’ould be of the same colour as the felt , but this is not to be done to the stuff till it comes from the mill, has been sheered, and nothing remains but to dress it. This method will be of great use when it is a mixed cloth in which cochineal has been used, for it saddens too much and spoils at the mill ; so that when it is used in mixed stuffs, a fresh liquor must be made, in which the cloth must be dipped, when it requires no more dressing than that which is given to cloth died white after it is come out of the die. CHAPTER XXIX. POLISH RED. BEFORE I enter upon the colours of the lesser die, 1 shall give the process of a very excellent colour, called Polish red. 192 If yon would die forty pounds of wool this bright and lK;Idlng colour, boil ten pounds of nut galls, in a copper sufficiently large, an hour and a half ; then cool the liquor witir cold water about ten de- grees uiider a boiling heat, because the madder sl ould not boil, and add best madder in propor- tion to the shade required, from fourteen to twen- ty pounds. Work these ingredients with the wool for two hours with long poles, that it may die in all parts alike. Rince it well, and you have the true polish red. If you would have a dark colour, use a little ashes. Observe to have the wool well scoured This process will hold good in cloth and other things. 193 THE DIER’S ASSISTANT. PART II. CHAPTER I. • F THE DIEING OF WOOL BY THE LESSER Dl^ I OBSERVED in the beginning of this trea- tise, that the dicing of wool, or woollen stuffs manufactured from it, were distinguished b}^ the great and lesser die. The French regulations have fixed what the quality of the wool and stufts are to be, which are to be died by the greater or lesser die. This distinction has been founded on this principle, that stuffs of a certain value, and which generally constitute the upper part of cloth- ing, should receive a more solid and lasting col- our than stuffs of a low price, . which w’ould be dearer and become less saleable, were they oblig- ed to be died by the good die, as the good die is a great deal more expensive than the lesser, a^nd that stuffs of low price, which arc permitted to be died by the lesser die, are generally used to make' R 194 linings, so that they are little exposed to the action of the air, and if they are put to other uses they are soon worn out, on account of the weakness of their texture ; and consequently there is none, cessity for their colours being so lasting as that of a stuff of a much longer duration. I have related in the preceding treatise, wdth the greatest exactness and precision in my power, the method of executing by the good die all ima- ginable colours ; I shall do the same in that which concerns the lesser die, and shall lay^ down the method of making the same colours with other ingredients than I have hitherto spoken of, and which though they have not the solidity of the first, often have the advantage of yielding more lively colours ; besides which, the greater part give a smoother colour, and are worked with greater facility than the ingredients of the good die. These are the advantages of these substances which are called false ingredients, and though it is to be wished that their use was not so general, it must be agreed that they have their utility for stuffs less exposed to the air, or whose colour dots not stand in need of a long duration. I might also add that the colours are most com- monly sorted with greater ease, and with more expedition, in the lesser die than can be done in the great. I shall not follow the same order for this kind of die as J did for the good, since in this no pri- mary colours are known. Few serve as a ground for others ; the greatest part do not arise frr-m a combination of two or several simple colours. In short, there are colours, such as tlie blue, &c. 195 which are seldom or never made in the lesser die. This is the order which I propose to follow, and shall first set forth the names of all the ingre- dients which particularly belong to the lesser die, and then give the method of using each of these ingredients, and the extraction of all the colours they can yield. It will be found that several of these ingredients produce similar colours, so that it would have been impossible to have treated of them separately, without tiring the reader with te- dious and troublesome repetitions. The ingredients are flock or goat’s hair mad- dered, archil, logwood, brasil, fustic, roncou, grains of Avignon^ turmeric, or terra merrita. I shall not here speak of the sanders or soot, though these ingredients particularly belong to the lesser die ; 1 have already given the manner of using these last. CHAPTER II. OF THE niEING OF FLOCK OR COAT’S HAIR. THERE are two preparations very diiferent one from the other in the dieing of flock ; the first is with madder, and belongs to the great and good die ; the second is to dissolve it arid make use of it ; this belongs to the lesser die. The dic- ing with flock was formerly permitted in the good die, but was rather on account of its being extract ed from madder, than by any experiment that ha<} been made concerning its durability. I tried 196 it with great attention, and found it beyond any | doubt that there is no colour that resists the air 1 less. It is certainly for this reason that it was re- , strained to the lesser die in the new regulation of i France in 1737. Yet, as by the same regulation, it is not permitted to the diers of the lesser die to use madder, nor even to keep it in their houses ; it has been enacted, that only the diers of the great die should be suffered to madder flock, , and those of the lesser die to dissolve and use i it. This maddering of flock ought to have found I a place in the foregoing treatise, but that I chose rather to class together all operations that have any necessary connection, than to stick too scrupulous* ly to that distinction of the great and lesser die, which is the particular object of the civil govern, ment of that art, and which upon some occasions might have made me fall into some obscurities, or run into continual repetitions ; besides, the gov- ernment of dicing is not the art considered in it- selfl To madder the flock or Goat’s hair, four pounds of either of them is cut and well separated, that the die may penetrate the better. It is boiled two hours in a sufficient quantity of sour water ; then it is drained for an hour, and put into a mid- dling copper, half filled with water, with four pounds of roach alum, two pounds of red tartar, and one pound of madder. The whole is boiled for six hours, putting in hot water as the liquor wastes ; it is left ail r.ight and next day in this li- quor ; the third day it is taken out and drained in a basket. Some diers let it remain eight days, but it often happens that by this delay in a copper m vessel it is tarnished by the liquors corroding a part of the copper ; a middling copper is then filled to the two thirds with half sour water, and half common water and when theliqouris ready to boil, eight pounds of madder, well cut and crushed be- tween the hands, is added. When the madder is well mixed in the liquor, four pounds of flock or hair is put in and boiled for six hours ; it is then well washed, and the next day it is madder- ed a second time alter the same manner, only putting in four pounds of madder instead of eight, which were before used. After this se^ cond maddermg, it is well washed and dried ; it is then almost black and fit for use. It appears by this operation, that four pounds of flock or hair is loaded with thirteen pounds of the die of madder, yet there still remains some die in the liquor, which is then called an old mad- dering, and uhich is preserved for use on certaia occasions, as in tobacco, cinnamon colour, and several others. Wh en the flock is thus maddered by the diec of the great die he sells it to diers of the lesser^ who have then the iiloerty to dissolve and use it ; this is the common method, which has many dif- ficuliies, and is known but to few diers. The madder is hereby made fine. About half an hour after seven in the mornings six pails full of clear water are put into a middling copper, and when the water is luke-warm, five pounds ot pearl ashes are put in *, the whole boiled till eleven, and the liquor is then consider- ably diminished, so to be held in a lesser cop- per, into which it is emptied, observing first to kt the dregs of the pearl-ashes subside, that none but the clear may be used. K 2 198 A pail full of this liquor is afterwards put into the middling copper, having first scoured it well, and a little fire made under it ; the four pounds of maddered flock are scattered in by degrees, and at the same time a little of the luke-warm and , saline liquor of the small copper is added to keep down the boiling, which rises from time to time to the top of the copper, in -which the operation is performing. i When all the flock and the liquor of the litt’e copper are put into the middling one, a pail lull of clear water is put on the dregs of the pearl-ash- < es remaining in the little copper, 'riiis water serves i to fill the middling one as the liqour in it evap- i orates. All this flock melts, or is dissolved by ' the action of the pearl-ashes, and alter the first half hour, not the least hair is to be perceived, the liquor is then of a very deep red The whole ’ is then boiled without any addition, till three in the afternoon, that the whole dissolution of the flocks may be the more exactly performed. Then a stick is placed upon the copper, and upon this stick is placed a pail of fermented urine, in which pail a small hole has been previously made towards its lower part, and a little straw put into it, that the urine may very slowly run into the copper ; whilst it is running, the liquor is made to boil strongly, and this urine m .kes good what may be lost by evaporation. This operation continues five hours, during w hich time three pa Is full of urine are discharged into the copper, being made to run faster when the boil is stronger, than when moderate. It is here to be observed, that, on ac- count of the small quantity of flock in the exper- iment which I lay down here, five pounds only of 199 pearl-ashes are ordered ; for when thirty pounds of flock are dissoU td at one time, which is the comiiion custom of the French diers, thev jmt twelve ounces of pearl ashes to each pound of flock During the whole time of this operation, a strong volatile smell of urine is emitted, and there swims on the suriace of liquor a brown scum, but much more so after the addition of the urine. The liquor is known to ne sufficiently done when this rises no more, and that the boil rises but genth , that is what happened to the operation now related, at eight in the evening. The fire is then raked out, the copper covered, and thus left to tlie next day . Patterns had been taken at different times of the colours of the liquor from three to eight in the evening, by dipping in small pieces of pa- per ; the first were very brown, and they became continually lighter, and united themselves more and more, in proportion as the volatile part of the urine acted on the colouring parts of the liquor. Nothing now remained but to die the wool in the liquor thus prepared, and which is called melting of flock ; this is the easiest work belong- ing to the dier. A quarter of an hour before the dicing is begun, a little piece of very clean roach alum is put in, and the copper is well rakt d to melt it. As this liquor which was in the mid- dling copper had been covered the whole night, and the fire had not been put out, the licpior was still so hotasnt t to suffer the hand. TIk dear- est was taken out and brought into a small copper, with a sufficient quantity ol lukewarm v\ Jter\sume wool died yellow with weld was dipped m it ; it immedkieiy became of a fine orange, Dordering 200 @n the flame colour, that is of the colour called nacaret^ and known to the dkrs by the name of nacartt of Jiock^ because it is commonly made with melted Hock. T wenty hanks of white wool were dipped one after the other in the same liquor, beginning by those that were to have the deepest ground, and leaving them longer or shor ty in the liquor ac- cording to the shade requir* An assortment was made after this manner from the nacarer, or bright orange red, to the cherry colour. It ought to be observed, that in proportion as the liquor was consumed, fresh was taken from the middle sized copper, great care being taken not to stirtho sediment at the bottom ; a little fire was also kept under the small copper, to kee[) the liquor always in the same degree of heat. The wool is thus dipped until the whole liquor is used, and all the colour drawn out. But the lighter colours could not be died in it ; for when the colour of the liquor is once weakened, as it ought to be for these colours, it is generally loaded with filth, which would take off the brightness required in these shades. The following is the method of making shades lighter than the cherry colour. A copper is filled with clear water, and five or six hanks of wool died of the deepest die from the fi >ck, that is, from the shade that immediately follows the na- caret, are put in. As soon as the water boils, it takes out all ihe.colour the wool had, and it is in this fresh liquor that the other wool that is to be died is dipped, from the cherry colour to the palest flesh colour, observing always to begin by tiae deepest shades. 201 Most of the diers who do not know how to melt the flock, or who will not give themselves that trouble, buy some pounds of this scarlet of flock, which they use after this manner, to make all the lighter shades, which, as has been said, is done with mach ease. This operation shows what little dependance can be put on the solidity of a colour that passes 90 quickly in boiling water. And in fact, it is one of the worst colours there is in dicing, and on that account the new regu- lation has taken it from the great die, and per- mits it in the lesser for the reasons above men- tioned. ■ Thus a very bad colour may be had from an ingredient which, of all those that are used in dic- ing, is perhaps the best and the most durable ; yet when this hair, died wdth all the necessary precau- tions to insure the colour as much as possible, comes to be dissolved or melted in a liquor of pearl-ashes, its colour, by acquiring a new lustre, loses all its solidity, and can only be ranked in the number of the falsest dies. It may appear that the little solidity of this col- our proceeded from the wool having no prepara- tion, and retaining no salt before its being dipped in the dissolved flock ; but I found that this was not the cause ; for I dipped in this liquor wool boil- ed as usual, and other wool differently prepared, without finding that the colour of the latter had acquired any more solidity ; the lustre was less, that is, it came out more saddened than the wool that had been died in it without any preparation. Though I have said that wool receives no pre- paration before its being died in a dissolution of flock, it is nevertheless necessary to sulphur those 202 that are to ‘make clear shades, for that gives them a great brightness and lustre, as the dissolved flock is applied on a ground a great deal whiter than it Would be without the vapour of the sulphur, which cleanses it of all its filth. The same thing is done for the light blues, and for some other colours ; hut this operation is seldom made use of but for wool intendqj|^ for samples or pestry. Sulphuring of Wool. The diers do not do this, because of the stink of the sulphur, or rather to avoid the trouble. Nevertheless, to give an idea of it, the white wool is suspended on hoops or perches in a close room, and under this wool chaffing dishes are placed with lighted coals, on which powdered sulphur is cast. The room door is afterwards shut, that the smoke may be the longer retained and act on the wool, which is to remain till it is entirely whiten- ed ; it is then called sulphured wool ; and this is the preparation it must receive to give a brightness to the rose, cherry, and flesh colours, which are made from the dissolution of flocks. The Theory of the Dissokition of Flock. The reason why from an ingredient, such as the root of madder, perishable colours are produc- ed from dissolved flock, is not difficult to assign. In the first operation of maddering the flock, the red of the madder was fixed in the hair by the pre- paration of alum and tartar as much as possible, but as it is overloaded with this colour, it is ea- 203 sy to conceive that the superfluous colouring at^ oms being only applied on those which already filled the pores of this hair, these alone are really retained in the pores, and are cemented by the salts. The hair thus reddened by the madder so as to become almost black, would lose a great deal of the intensity of its colour, il‘ it was boiled in any liquor, was it even common water ; but to this water, pearl-ashes are added in equal weight wkhth.e flock already died, which is to be melted in it ; consequently there is a ver) strong iixivi- um of fixed alkaline salts made. I have already said in am ther place, in the foregoing treatise, that very strong alkaline ley sdestroy the naturaltexture of almost all animal substances, as also gums and resins ; in short, that an alkaline salt is their dissol- vent. In the present operation, the lixivium or the pearl-ashes is very concentrated, and very acrid, and consequently in a state to melt the hair, which is an animal substance, which it does very quick, ly, and with a strong fermentation, which, shows itself by the strong and violent elevation of the li- quor ; consequently it destroys the natural text- ture of each of these hairs, and the sides of the pores being at the same time broken and reduced to very minute parts, these sides having neither consistence nor spring to retain these salts, and the colouring particles that were sticking to them. Therefore the animal particles of the hair, the colouring parts of the madder, the saline parts of the liquor,and the alkali of the pearl ashes, are all confounded together, and form a new mixture which cannot afford a lasting die, because from these saline parts mixed together, there cannot be foritied a sufficient quantity of salts capable of 204 chrystalization, and producing moleculas, which can resist cold water and the rays of the sun. In short, it could not form a tartar of vitriol, because the alkaline salt is in too great a proportion. To roLize the deep and overloaded die of the madder first applied on the flock, and after coi\-, founded by the melting of this hair in the mixture already spoken of, pu trifled urine is added in a considerable quantity ; this is a further obstacle to chrystalization ; consequently wool not pre- pared by other salts, and dipped in a liquor thus composed, can only be covered by a superficial colour, which finds no prepared pores, or any thing saline in those pores, which may cement the colouring atoms ; therefore such a die must quit its subject on the least effort of what nature soev- er it be. But wool prepared by the liquor of tartar and alum, does not take a more lasting colour, in the liquor of the melted flock, than wool not prepared by these salts ; fora liquor which abounds with fixed alkaline salts attacks the tartar left of the pre- ceding preparation in the pores of the wool. This tartar changes its nature, and from being hard to dissolve, as it was before, it becomes a soluble tartar, that is, a salt that dissolves very easily in the coldest w'ater. It may perhaps be objected, that particles of alum remain in the pores of the prepared wool, • that from these particles of alum, as well as from a portion of the same salt which is put into the li- quor, reddened by the melting of the flock, the ^kali of the pearl-ashes must form a tartar of vitriol, which, according to my principles, ought to secure the die. 2.05 To this I answer, that the urine hinders the combination of these two salts, which is neces- sary for the formation of the tartar of vitriol i if even this hindrance did not exist, the quanti- ty of this salt, which I have named /uird in an- other place, could not be sufficient to cement the colour in the pores of the wool, or put them in a state to retain the colouring atoms. Fur- ther, the sharpness of the alkaline salts in this liquor, which is capable of entirely dissolving the hair boiled in it, would equally be able to dissolve the wool, were it boiled as the flock was. But yet, though a degree of heat is not given to the liquor, which would be necessary for this total destruction, it is easily conceived, that if the sum of the destroying action is not the same, at least a part exists, which is still sufficient to corrode the sides of the pores of the wool, to enlarge them greatly, and to render them unfit to retain the colouring atoms ; to this may be ad- ded, that the hair is melted in the liquor, and con- sequently mixed with the colouring parts of the madder in a great quantity ; that these are hete- rogeneous parts, which prevent the immediate contact of the same colouring parts, and that from all these obstacles taken together, the colour must be rendered less durable and less holding than any of the lesser die. "I'his, experience sufficiently proves, for if a skain of red wool died in this man- ner, be put into boiling water, the colour will be laken off entirely. S 206 CHAPTER III. OF THE MANNER OF USING ARCHIL.’ ARCHIL is a soft paste, of a deep red, which being simply diluted in hot water affords a num- ber of different shades ; there are two kinds, the , most common, which is not so fine or so good, ' is generally made in Auvergne, of a ichen or j sort of moss, very common on the rocks of that 1 province ; it is known under the name of Archil ( of Auvergne, or Land Archil. The other is a great deal finer and better ; it is called the Ar- , chil of Herb, or of the C’anaries, or Cape Verd Ar- i chil ; it is prepared in France, England, Holland, and other places. The workmen who prepare this herb Archil, make a secret of the preparation, but the particu* lars may be found, well related in a Treatise of J£. Pierre Antoine fdicheli, which bears for title, Nova Planturum Genera^ therefore 1 shall not here give the method of preparing it. When a dier wants to assure himself that the Archil will produce a beautiful effect, he must ex- tend a piece of this paste on the back of his hand and let it dry, afterwards washing his hand with cold water. If this spot remains with onh a lit- tle of Its colour discharged, he may judge the Archil to be good, and be assured it will suc- ceed. 1 shall now give the method of using the pre- pared archil, but I shall only treat of that of the 207 Canaries, and just mention the difference between it and that of Auvergne. A copper is fiikd with clear water, and when it begins to be lukewarm, the proper quantity of archil is put in and well stirred : the liquor is afterwards heated almost to boiling, and the wool or stuffs are dipped without any preparation, only keeping those longer in that are to be deeper. When the archil yields no more colour at this degree of heat, the liquor is made to boil to ex., tract the remainder ; but if it is archil of Auverg- ne, the colours drawn after this manner will be sadder than the first, on account of the boiling of the liquor. The Canary archil, on the contrary, wnll lose nothing of its brightness, if even the li- quor boiled from the beginning. This last, though dearer, yields much more die, so that there is. more profit in making use of it, besides its supe- riority over the other in beauty and goodness of colour. The natural colour w’hich Is drawn both from the one and the other archil, is a fine gris^de* lin^ bordering on the violet. Tl)e violet, the pan- sy, the amaranth, and several like colours are ob- tained from it, by giving the stuff a ground of blue more or less deep before it is passed through the archil. It must here be observed, that to have the clear shades of these colours as bright as they ought to be, the wool ought to be sulphured, as was said in the foregoing chapter, either before it is dipped in the archil, for griSrde Im. or before it is died blue for the violet and other like colours. This way of using archil is the simplest, but the colours that proceed from it are not lasting. It may be Lmagined thgi the colours would be better 208 by giving a preparation to the wool previous t© its being died, as i:> practised in the great die, when madder, cochineal, weld, Sec. are used ; but experience shews the contrary, and I have used the archil on wool boiled in alum and tartar, which did not resist the air more than that which had re- ceived no preparation. There is, notwithstanding, a method of using the Canary archil, and giving it almost as much duration as the most part of the ingredients of the good die; but then its natural colour of gris-cle-lin is taken off, and it acquires a red or scarlet, or rather a colour known under the name of bastard scarlet. The colours of the kermes or Venetian scarlet, and several other shades that border on the red and the orange may also be drawn from it. These colours are extracted from the archil by the means of acids, and all those that are thus made may be looked upon as much more lasting than the others, though strictly speaking, they are not of the good die. rniere are two methods of extracting these red colours from the archil. The fiisl is by incorpo- rating some acid in the composition itself that is made use of to reduce this plant to a paste (such as is known to the diers under the name of archil.) I have been assured that it may be made violet and even blue, which probably is done by the mixture of some alkalis, but I must conless I could not succeed in it, although I made above twenty trials for that purpose. I shall now pro- ceed to the second method of extracting from ar- chil, a beautiful and pretty lasting red, and which I executed four times with success. 209 Bustard Scarlet by Archil* Prepared archil jron^ the ('anaries is diluted as- usual in warm water, and a bmaU quantity of the common conipobition for bcarlei is added, which has been shoun in the preceding treatise, a solution ot Un in aqua regia, w eakent d w itti water ; tho> acid ciears tlic nquor immediatth anci gives it a scarlet coioar. The wool or slidF is then to be dipped in this liquor, and left till it has received the siiade required. If the colour should not have brjghiness enough, a little more of the composi- ti- must be put in, and pretty near the same method must be followed as i • the dicing of com- m( Ji scarlet : I tried to makv; it in two liquors as the srariet, that is, to boil the stuff with ihe com- position, a!id a small quantity of archil, and af» tervvards to finish it with a greater quantity^ of both, and 1 siKceeded equally ; but the operation is longer after this manner, and I have sometimes, made as fine a colour in one liquor. Thus the dier may take his choice of either of these meth- ods. 1 cannot exactly fix the quantity of ingredients in this opeiation. First, as it depends on the shade that is to be given to the stuff. Second, as it is a new process in dicing, I have not had suf- ficient experiments to know wfith exactness the quantity^ ofaiehii and composition which ought to be used : the success also depends on the greater or lesser acidity of the c( nip^^sition. in short, this method of dicing with archil is so easy, that by making two or three trials in small, more knowledge will be acquired from it than 1 could teach in a large volume ; I must only add, tbat- S2 210 the more the colour drawn from this ingredient approaches the scarlet, the more lasting it is. I .• have made a great number of shades from the ^ same archil, and which consequently only differed ^ by the greater or less quantity of the composition, ] and I always found that the more the archil w^ent i from the natural colour, the more lasting it became, so that when I brought it to the shade known by j the name of bastard scarlet, it withstood the action | of the air and essay proof almost as well as that . which is commonly made with cochineal or madder. If too much composition be put in the liquor, the wool will become of an orange colour, and dis- agreeable. The sanie thing also happens with co- chineal, so that this is not an inconvenience pecuU iar to this die ; besides it is easily avoided by proceeding gradually in the addition of the com- position. and by putting a small quantity at first. 1 have tried the different acids in this scarlet composition, but none succeeded well ; vinegar did not give a sufficient redness to the liquor, and the stuff died in it only took a colour of lees of wine, which even was not more lasting in the air than that of the archil in its natural state, and oth*. er acids saddened the colour. In short, it appears that (as in scarlet with cochineal) a metallic base extremely white must be united to the red of the archil, and this basis is the calx oi tin I have repeated the same operation with the archil of Au- vergne, but the colours were nut near su fine or so good. 211 CHAPTER IV. OF LOGWOOD OR CAMPEACHY. THE campeachy wood, known under the name of logwood, is of great use in the lesser die, and it were to be wished that it was not used in the good die, for the colour which that wood produces loses its brightness in a short time, and even disappears in some places on being exposed to the air ; the low price of this drug in some measure tolerates its use ; but the pi incipal reason of using it is, that by the means of different prep- arations and salts it affords a great number of col- ours and shades, which are not easily made by the ingredients of the good die alone. Yet it is pos- sible, as I have said before, to make all these col- ours without the help of logwood ; therefore it was proper to forbid the use of this ingredient in the good die. Logwood is necessary to soften and velvet the blacks ; it is this velvet hue that gives that excel- lency to the Sedan blacks. I shall now add some little matter concerning the other colours in which this wood is used, and 1 shall observe, that when any wood whatsoever is used in dieing, it must be cut into small shavings or chips, and put into a bag, that it may not stick to the wool or stuffs ; for the rough chips will not only tear the goods, but blot them in those places to which they stick. Logwoodi is us^d with galls and copperas for all 212 the shades of grey which border on the slate or lavender, the pigeon grey, the lead grey, and such like. To make these, a copper is filled v\ith clear water, and a proper quantity of galls is add- ed ,* this must be proportioned to the quantity of stuffs to be died, and to the depth of the shade re- quired. A bag of logwood is put into this liquor, and when the whole has boiled and cooled., the stuff is dipped in it, adding by little and little some copperas previous!} dissolved in water. I cannot fix any exact proportion of ingredients, as the diers of the lesser die are not accustomed to weigh them ; they work by the eye, and their bu- siness being to match low-priced stuffs for linings of cloths for which they have the patterns, they first make them lighter than is wanted, and sadden them by adding copperas till they are come to the shade required. If they find there is not logwood suf- ficient, they add more ; they do the same when they have several stuffs to pass through the same liquor, when they find the v/ood they have given has yielded all its die. This work is not difficult, and only requires practice to judge pretty nearly the quantity of ingredients to be used, and to judge by the stuff, while wet, whether, when dry, it would have the intended colour, which is done by strongly wringing the end, and blowing on it strongly : by this means, the greatest part of the humidity, which has by twisting been brought to the surface of the stuff, is driven off ; then for an instant the colour is seen pretty nearly such as it will be when dry ; but this must be done by a quick eye, for in a moment after the adjacent mois- ture is communicated to this dry place, and then you may be deceived* 213 A pretty fine violet is also made with logwood, by first boiling the wool as usual with alum and tartar, and afterwards passing it through a li- quor of logwood in which a little alum is dis« solved. But it is made much finer by bluing and aluming the stuff first, then dipping it in a liquor of Brazil mixt with a little logw’ood ; this violet, though of the lesser die, is much better than the former, because the blue ground al- ways sustains the colour, and makes it more holding. The logwood also affords a blue colour, but it lasts so ill that this wood is seldom used for dic- ing blue. Y et if from curiosity you wish to make a trial, you need only prepare a liquor with log- wood, and mix a little Cyprus or blue vitriol in it, and dip the stuffs in this without any other prepa- ration, and you have a fine blue. By the same means, green may be made in the same liquor. For this purpose, logwood, French berries, or grains of Avignon and verdigrise are put into a copper. This mixture gives the li- quor a beautiful green colour ; the wool may be then dipped to the height desired, and may be of any desired shade, by putting in more or less of the logwood and Avignon grains. But this col- our is not better than the blue, and both ought to be excluded the art of dicing ; I have given the process, merely that I might omit nothing which came to my knowledge conceriiing the art. • The use to which logwood is most commonly applied in the lesser die is for plumb, prune coL ours, purples and their shades. This wood joined with galls, readily gives »11 214 its colours to wool that has a ground of blue ; it is saddened with a little green copperas, which browns them, and by this means some shades may be easily obtained which are much more dif- ficult to hit in the great die, as the different de- grees of saddening are much more difficult to match in a blue vat, than by the help of the iron of the copperas. But these colours fade away very soon in the air, and in a few days a great difference is seen between the parts that were exposed to the air and those that were cov- ered Having experienced, as I said in the preced- ing chapter, that the scarlet composition changed the colour of the archil, and made it more last- ing, 1 tried what effect it might produce on the logwood ; but what appeared singular to me was, that whatsoever quantity of composition I put into this liquor, it never lost its violet colour. Being desirous to put this to a further trial, I died a piece of cloth with logwood, and put in^ to the liquor a quantity of composition, pretty near equal to that which I would have put for an equal dose of archil ; the cloth took a pretty good violet colour. This cloth was put in the weather for twelve summer days, and the colour proved no laetter than if no composition had been used. By adding a small quantity of crystals of tartar to another liquor composed as the former, I had a more lasting colour, but considerably dif- ferent. 215 The Raven Grey. The raven grey on worsted or stuffs is perform- ed in the following manner. In a copper sufficiently large for sixty pound weight, dissolve eight ounces of alum, and work the worsted on sticks very quick for the space of half an hour at a boiling heat ; then take it up, and add to the same liquor three or four pounds of copperas, and work it at boiling heat for half an hour longer ; while this is performing the worst- ed must be washed, and one pail full of logwood chips must be boiled in another copper about twenty minutes ; the worsted must then be turn- ed very quick in the logwood decoction about half an hour, when it must be taken out, and re- turned about ten or fifteen minutes in the decoc- tion of alum and copperas, as at first. This last operation is absolutely necessary, as it contributes much to the beauty and lustre of the colour, by’ discharging the gross particles of the logwood, and leaves a beautiful raven grey. This process will hold good for thin goods and coarse cloth, but a less proportion of logwood will do. CHAPTER V, OF SAXON BLUE AND GREEN.’ I PLACE here among the lesser dies that call- ed Saxon blue and green, which has been for some time greatly in fashion, being finer and brighter than any blue or green hitherto known 216 either in the greater or lesser die, but it bears no pn -vr ai-d in uveive days exposition to the sun, it loses a great part of its colour. Blue on Cloth, Stuff, or Yarn. Pat into a gL zed earthen-pot four pounds of gO''*d oil of vitrivd with twelve ounces of choice indigo, very finety ground and silted ; stir this chv niical mixture very hastily and frequently in order to excite a ft rmentation, and break the lumps with a stick whose bark has been stripped off. It is customary with some diers to put into this composition a little ar.timony or saltpetre, tartar, chalk, alum, or other things ; but 1 find it sufiicient to mix the oil and indigo alone, and the colours will be finer, for those neutral salts destroy the acid of the vitriol and sully the colour. In twenty-four hours it is fit for use ; then a copper of a good size is to be fided with fair water, (into which one peck of bran is put in a bag) and made pretty warm ; the bran, after yielding its flour, must be taken out, and the ch) mic mixed well with water, in a piggin, is put iu according to the shade required, having first put in a harmful of powdered tartar ; the cloth, &.c. is to be well wet, and worked very quick over the wynch for half an hour. The liquor must not be made hotter than that for madder red. Observe, .the hot acid of the vitriol would cause the blue to incline to green if too much heat was given The cloth, stuff, or yarn must be turned in this liquor very quick for half an hour, and having been previously very well scoured, the colour will be brilliant and fine ; it is best after washing to dry this colour in the shade. 2L7 Chymic for Green, Eight ounces of indigo is sufficient for four pounds of oil for green, because this mixture works green (and would even die apea^green if used very hot) and therelore would not do for blue. The indigo is better suspended in this mixture than in the former, and is supposed to go further in green. The goods being well scoured are to be alumed ; for every twenty pound weight, two pounds of alum is to be put into a copper with fair v/ater, and the goods boiled gently an hour and a half ; whilst this is performing, another copper is got ready, in which fustic chips are put to boil ; if there are any to die pea green it is best to die them first, not as practised in some die^hous- es, for this great reason, that when several parcels of goods have been through the same liquor, there remains a scurf which the acid extracts, and that is sure to stick to the next parcel that goes in ; and if pea- green vvas the last, the colour would be dulled thereby. The greens ([)ea' green except- ed) are to be turned about ten mujutes m the afuru liquor after ^hey are died, in order to deai tix nt of the stuff, and render the colour brighter, 'i'he alum liquor is not to be hotter than tb-t the hcUK.l may be borne in. Observe, if the alum was ['ut in fas is customary in some die-honser) with the fustic, it would retard its workitig so well ; for alum, being an acid, would discha* gc if used wiiii, as well as prepare for fustic. The reader will perhaps think me too tedious in this process, and Sriy (because he is not used to this method) it is a sup'eifiuous woik ; but be T 218 assured that the time lost in the process will be saved in the fustic, if attention is paid. CHAPTER VI. OF BRAZIL WOOD. UNDER the general name of Brazil wood is comprehended that of Fernambouc, St. Martha, Japan, and some others which I shall nn, because the ashes are in alkali, but practice w ill teach the truth. Another excellent Silver Die, ^ For twenty pounds weight of cloth or worsted, eight ounces of alum and twelve pounds of fenu- greek must boil with the goods l^alf an hour; then take it up, and add one pound of pearl ashes and eight ounces of Brazil wood ; boil them gent- ly with the gf)ods half an hour ; rince it and you have a beautiful colour. INSTRUCTIONS ON THE PROOF OF DIED WOOL AND WOOLEN STUFFS. AS it has been found that the methods pre- scribed for the proof of dies, by the thirty-seventh article of the French regulations for the diers in the good die^ of cloth, serges, and other vvoollt n stuffs made in 1659, and by article 220 of the general iristruct ons for the dieing of wool of ill colours, and for the culture of drugs a id ingredi- ents therein used made in 157 «, were insufficient f( r an exact judgment of the goodness or falsi- ty of sever J colours, that they might sometimes lead into error, and leave room for disputes, di^ 229 ferent experiments have been made by the French king’s order on wool designed for the manufac- ture of tapestry to ascertain the degree of good- ness of each colour, and the most convincing proofs of each. For this purpose, fine wool was died in differi’ ent colours both in the great and lesser die, and exposed to the air and sun during a proper time / the good colours kept themselves perfectly, and the false ones were carried off more or less ac- cording to their bad quality ; and as a colour is only to be accounted good inasmuch as it re- sists the action of the air and sun, this proof serv- ed as a rule to decide the goodness of different colours. After this, several proofs were made on the same wool whose patterns had been exposed to the air and sun, and it was immediately found that the same trials could not be indifferently used in proving of all colours ; for it often happened that one colour, known to be good by exposition to the air, was considerably changed by the es- say proof, and that a false colour stood the same proof. These experiments exploded lemon juice, vin- egar, sour waters, and strong waters, as it was impossible to ascertain the degree of acidity of these liquors ; and it appeared that the surest method is to use ingredients with common water, whose effects are always equal. In following this plan, it has been judged ne- cessary to divide into three classes all the colours in wdiich w^ool is died, either in the great or lesser die, and to fix the ingredients that are to be U 230 made use of in the essay proofs of the colours, comprehended in each of these three classes. The colours comprehended in the first class are to undergo the proof of Roman alum, those of the second with white soap, and those of the third with red tartar. But it is not sufficient to be assured of the good- ness of a colour by using in the proof, ingredients whose effect may always be equal ; it is also ne- cessary, that not only the duration of this trial be exactly determined, but even the quantity of water fixed ; for the proportion of water considerably augments or diminishes the activity of the ingre^ dients which are put into it. The method of pro- ceeding in these different proofs shall be set forth in the following articles : Article I. The proof of Roman Alum must be made as follows : One pound of water and half an ounce of alum are to be put in an earthen vessel or pan. The vessel is to be placed on the fire, and when the water boils strongly, the wool is put in and left to boil for five minutes, after which it is to be ta- ken out and washed in cold water ; the weight of the pattern of wool must be a drachm or there- abouts. II. — When several patterns are to undergo the proof together, the quantity of water and alum is to be doubled, or even trippled, which will no 231 ways change the strength or effect of the proof, if you observe the same proportion of water and al- um, so that for each pound of water there may be one ounce of alum. III. — To render the effect of the proof more certain, care must be taken not to try together wool of different colours. IV. Ihe Proof with White Soap is to be made after the following manner. To one pound of water add two drachms of white soap, and place the vessel on the fire ; stir it with a stick that the soap may be thoroughly dissolved ; when it is so, and the water boils strongly, the woollen pattern is put in, which is to boil for five minutes. V. — When several patterns are to undergo this proof, the same method is to be observed as in the second article, that is, to put to each pound of water two drachms of soap. VI — The proof with red tartar must be exact- ly the same, with the same proportions as the proof with alum, taking care that the tartar is fine- ly powdered and well dissolved in the water be- fore ihe pattern is put in. Vn. — The following colours are to be proved with Roman alum, viz. crimson of all shades, Venetian scarlet, flame colour or common scarlet, cherry colour and other shades of scarlet, violets and gris de lin of all shades, purples, lobster, ‘232 pomegranate, slate greys, lavender greys, vio- let greys, vinous greys, and all other like shades. VI II. — If, contrary to the orders of the regu- lations on dicing, any ingredients of the false die have been made use of for fine wool died in crim- son, the cheat will be easily found out by the proof of alum, for it changes the fine crimson a little on the violet, that is, makes it border a little on the gris de Im, but it destroys the highest shades of the bastard crimson ; thus this proof is a sure method to distinguish false crimson from fine. IX. — Scarlet of kermes or grain, commonly called Venetian scarlet, is no wise prejudiced b^ this proof ; it raises the fire colour scarlet to a purple, and gives a violet colour to the lighter shades, so that they border on the de lin, but it carries off, the greatest part of the false Bra- zil scarlet, and brings it to an onion peel colour ; it has yet a more sensible effect on the lighter shades of this false colour. I'he same proof carries off almost entirely the scarlet of flock and its shade. X. — Though the violet is not a simple colour, but formed of blue and red shades, it is never- theless of so much consequence as to merit a par- ticular inquiry. The same proof with Roman alum has scarce- ly any effect on the fine violet, whereas it con- siderably alters the false ; but it must be observ- ed, that it does not always equally carry off a great part of the shade of the false violet, because this colour has sometimes a ground of woad or 233 indigo : now this ground being of the good die, is not carried off by the proof) but the redness goes off, and the brown shades become almost blue, and the pale ones of the colour of lees of wine. XI. — With regard to half fine violets, forbid- den by the present regulations, they must be rank- ed in the class of false violets, and do not stand the proof. Xil. — The fine gris-de-lin may be known from the false by the sanie method, the difference is but trifling ; the gris de lin of the good die loses a lit- tle less than that of the false. XIII. — Fine purples entirely resist the proof with alum, whereas the false entirely lose the great- est part of their colour. Xi V. — Lobster colours and pomegranate strike on the purple after the proof, if they have been made with cochineal, whereas they will pale great- ly if fustic has been used ; the use of which is prohibited. XV. — Blues of the good die w ill lose nothing in the proof, whether of w oad or indigo ; but those of the lesser die w ill lose the greatest part of their colour. X\T. — The slate greys, lavender greys, violet greys, and vinous gre}s. lose almost all their col- our if they are of the false die ; whereas they per- fectly maintain it, if of the good. XV H --The proofs of the following colours are to be made with white soap : yellow^, jonquill . V2 2S4 or lemon colour, orange, and all the shades of yellow ; all green shades from the yellow green or light green, to the cabbage or parrot green, the reds of madder, cinnamon, tobacco, and such like. XVIII — This proof perfectly shows if the yel- lows and other shades derived from it are of a good or false die ; for it carries off the greatest part of their colour if they have been made with grains of Avignon, roucou, turmeric, fustic, or saffron, whose use is prohibited for line dies, but it no ways impairs the yellows made with savo» ry, dier’s wood, yellow wood, weld, or fenu- greek. XIX. — The same proof will also show the goodness of greens, as those of the false die lose most of their colour, or become blue if they have a ground of woad or indigo ; whereas those of the good die lose almost nothing of their shade, but remain green. XX. — The reds of pure madder lose nothing by the soap proof, on the contrary become liner, but if Brazil wood has been used, they lose their colour in proportion to the quantity ol it in the composition of the die. XXL — Cinnamon, snulF colours, and others of this cast, are scarcely altered by this proof, if of the good die, but they lose considerably if rou- cou, fustic, or dissolved flock has been made use of. XXII. — The proof of alum would be of no use, and might even lead us into errors with re- 2S5 gard to several colours belonging to this second class, for it no ways alters the fustic nor the rou- cou, \vhich nevertheless do not withstand the action of the air ; on the other hand, it car- ries oflf a great part of the savory and of the diet’s wood, which are very good yellows and greens. XXIIL — All the brown or root colours should undergo the proof with red tartar. The diets call by this name all colours that are not derived from the five primary colours ; they are made with rinds and roots of walnut, alder- bark, sumach or roudoul, santal and scot ; each of these ingredi- ents gives a great variety of shades, which are all comprehended under the general name cf brown or root colour. XXIV. — The above named ingredients in the preceding article are good, except the santal and soot, which are not quite so good, and make the wool stiff when too great a quantity is used, so that all this proof can show on these kind of colours, is, whether too much santal or soot has been put into them ; in this case they lose con- siderably by the proof with tartar but if made with other ingredients, with only a moderate quantity of santal or soot, they stand a great deal better. XXV. — Black is the only colour which can- not be comprehended in any of the three clas- ses above mentioned, and a much more active proof must be made use of. To know if the wool has had a deep ground of blue, conform- able to the regulations, the proof is to be made 236 in the following manner : take a pint or pound of water, one ounce of tartar, and the same quantity of Roman alum well po \clcred ; boil it, and then put in the pattern ; let it boil strong- ly for a quarter of an hour, and afterwards wash it in cold water ; you will then easily know if it has had the proper blue ground, for if so, the wool will remain of a dark blue almost black ; if not, it will turn very grey. XXVI. — It is common to brown certain co- lours with galls and copperas ; this operation is called browning, which is to be permitted in the good die ; but as this may cause a particu- lar effect in proving of these colours, it is to be observed that although the proof liquor ap- pears loaded with die as the browning is carried off, the wool must be reputed of a good die if it still preserves its ground ; if on the contrary it loses it, it is then deemed to be of the fidse die. XXVII. — Although the browning w'hich is made of galls and copperas, is of the good die, yet, as it hardens the wool, it is better to make use of the indigo or woad vat in preference. XXVIII. — Common greys made with galls and copperas are not to undergo any of these proofs, because these colours are of the good die, and are not otherways made ; but it is to be ob- served that they a re first to be passed through the liquor of galls, and afterwards through a second liquor, containing the copperas, which must be much cooler than the first, for by this method they are made finer and more lasting* 237 - THE DIER’S ASSISTANT. PART III. ADDITIONAL ARTICLES. CHAPTER I. or fLOWEHS. AMONG the infinite variety of colours which glow in the flowers of plants, there are very few which have any durability, or whose figurative beauty can be arrested by art, so as to be applied to any valuable purposes. The only permanent ones are the yellow. The red, the blue, and all the intermediate shade of purples, crim sons, vi* olets, &c. are extremely perishable. Many of these flowers lose their colour on being barely dried ; especially if they are dried slow'ly, as has been usually directed, in a shady and not warm place. The colours of all of them perish on keep- ing, even in the closest vessels. The more hasti- ly they are dried, and the more perfectly they are secured from the air, the longer they retain their 238 beauty. The colouring matter, extracted and ap- plied on certain bodies, is still more perishable / often times it is changed or destroyed in the hand of the operator. Of Blue Flowers. The colour of many blue flowers is extracted by infusion in water, but there are some from which water gains only a reddish or a purplish hue. Of those that have been tried, there is not one which gives any blue tincture to spirituous li- quors ; some give no colour at all, and some a reddish one. The juice prcst out from the fresh flowers is for the most part blue. The blue juices and infusions arc changed red by all acids ; the marine acid seems to strike the most florid red. I’he flowers themselves, macc-^ rated in acid liquors, impart also a deep red tinct- ure. Alkalis, both fixed and volatile, and lime water, change them to a green. Those infusions or juices, which have nothing of the native colour of the flower, suffer the same changes from the ad- dition of acid and alkaline liquors ; even when the flowers have been kept till their colour is lost, in- fusions made from them acquire still a red colour from the one, and a green from the other, though in a less degree than when the flowers are fresh. The red colour produced by acids is scarcely more durable than the original blue ; applied up- on other bodies, and exposed to the air, it gradu- ally degenerates into a faint purplish, and at length disappears, leaving hardly any stain behind. The green produced by alkalis changes to a yellow, which does not fade so soon# The green by lime water is more permanent and more beautiful. Green lakes, prepared from these flowers by lime water, have been used as pigments by the painU er. The flowers of cyanus have been greatly re- commended, as i flR.rdingelej^’ant and durable blue pigments ; but I have never been able to extract from them any Irlue colour at all. They retain their colour ii.deid, when hastily dried, longer than some oiher blut flowers, but they communi- cate nothing of it to any kind of menstrum. fi3gp fusions of theni in watery, spirituous, and oily liquors- are all more or less of a reddish cast, with., out any tendency to the blue. Alum, which is said to heighten at d preserve their blue colour, changes it like that of other blue flowers, to a purp- lish red ; acids to a deep red ; alkalis and lime water to a green. Solution of tin, added to the watery infusion, turns it to a fine crimson ; on standing, a beauti- ful red fecula subsides, but it loses all its colour by the time it is dry. The watery infusion in- spissated to the consistence of an extract made with rectified spirit, is of a purplish colour. The colour of bf)th extracts, spread thin and exposed to the air quickly fides. The flowers employed in these experiments were those of the common blue bottle of the corn field; cyanis se^efum B centaur ea catycihus serratis ; foholts iineartbus integerritnis ; trmmi dentutis linn, spec. 240 Bed Flowers, Red flowers readily communicate their own red colour to Water menstrua : among^ those that have been tried there is not one exception. Those of a full red colour, give to rectified spirit also a deep red tincture brighter, though somewhat paler than the watery infusion ; but the lighter red flowers, and th> se that have a tendency to the purplish, impart very little colour to spirit, and seem to par- take more of the nature of the blue flowers than of the pure red. Infusions of red flowers are supposed to be heightened by acids, and turned green by alkalis, like those of the blue ; but this is fai from being universal. Among those I have exaniincd, the rose colours and purplish reds were all changed nearly in the same manner as the blues, but the full deep reds were not. The deep infusion of red poppies is turned by alkalis, not to a green but to a dusky purple. Yellow Flowers, The colours of yellow flowers, whether pale or deep, are in general durable. Many of them are as much so perhaps as any of the native colours of vegetables. The colour is extracted both by wa- ter and by spirit ; the watery infusions are the deepest. Neither acids nor alkalis alter the spe- cies ofcolour, though boihcf them var\ its shades; acids rendering it paler, and alkalis deeper ; al- um likewise considerably heightens it though not so much as alkalis. Wool or silk impregnated with a solution of 241 alum and tartar, receives, on being boiled with the watery infusion, or decoction, adorable yel- low die, more or less deep according as the li- quor is more or less saturated with the colouring matter. An infusion of the flowers made in alkaline ley, precipitated by alum, gives a durable yellow Lke. Some of these flowers, particularly those of the chr} santhenmm, or corn marigold, appear (from the jirs I'inctora Fundamentalist published by Stahl) to be made use of by the German Diers. In some of the deep reddish ) ellow, or orange- coloured flowers, the yellow matter seems to be of the same kind with that of the pure yellow flowers, but the red to be of a diflerentkind from the pure red ones ; watery menstrua take up on- ly the yellow and leave the red, which may after- wards be extracted by rectified spirit of wine, or by water actuated with fixed alkaline salt. Such particularly are the saffron-coIoured flowers of carthamus. These, after the yellow matter has been extracted by water, are said to give a red tincture to ley ; from which, on standing at rest for some time, a deep bright red fecula subsides, called, from one of the names of the plant which produces it, saf flower, and from the countries whence it is commonly broiiglu to us, Spanish red, and China lake ; this pigment impregnates spirits of w’ine with a beautiful red tincture, but communicates no colour to water. I have endeavoured to separate by the same treatment, the red matter of some of the other red- dish yellow flowers, as those of the garden nian- gold, but without success- Plain water extract- ed a yellow colour, and cdkaline ley extracted af- W 242 tervvards only a paler yellow; though the diges- tions were continued till the flowers had lost their colour, the tinctures were no other than yellow, and not so deep as those obtained from the pure yellow flowers. The little yellow flosculi, which in some kinds of flowers are collected into a compact round disc, as in the daisy and corn- marigold, agree so far as they have been examined with the expanded yel- low petala. Their colour is affected in the same manner by acids, by alkalis, and by alum, and c- qually extracted by water and by spirit. But the yellow farina or fine dust lodged on the tips of the stamina of flowers, appears to be of a difierent kind. It gives a fine bright yellow to spirit, and a duller yellow to water ; the undissolv- ed part proving in both cases of a pale yellowish white. Both the watery and spiritous tinctures were brightened by alkaline liquors turned red by^ acids, and again a deep yellow on adding more of the alkali. I know no other vegetable y ellow that is changed red by acids. White Flowers* White flowers are by no means destitute of co- louring matter. Alkaline lixivia extract from some of them a green tincture, and change their colourless expressed juices to the same colour. But I have not observed that they arc turned red by acids. The flowers of the common wild con- volvulus or bind weed, which in all their parts are white, give a deep yellow or orange tincture to plain water, which like the tincture of flowers which are naturally of that colour, is rendered 243 paler by acids, heightened a little by alum, and more considerably by alkaline salts. The vapours of the volatile vitriolic acid, or of burning sul- phur, which whiten or destroy the colour of the coloured flowers, makes no change in the white. CHAPTER II. OF FRUITS. THE red juices of fruits, as red currants, mul- berries, elder berries, and morello and black cher-' ries, &c. gently inspissated to dryness, dissolve ^ again almost totally in water, and appear nearly of the same red colour as at first. Rectified spirit extracts the tinging particles, leaving a considera- ble portion of mucilaginous matter undissolved i and hence the spirituous tincture proves of a brighter colour than the watery. " The red solu- tions and the juices themselves are sometimes made dull, and sometimes more florid, by acids, and generally turned purplish by alkalis. The colours of these juices are for the most part perishable. They resist indeed the power of fermentation, and continue almost unchanged after the liquor has been converted into wine. But when the juice is spread thinly on other bodies, exsiccated, and exposed to the air, the colour quickly alters and decays : the bright lively reds change the soonest. The dark, dull red strain from the juice of the black cherry, is of consid- erable durability. The fruit of the American opuntia or prickly pear, the plant upon which the 244 cochineal insect is produced, is perhaps an ex» ception : this bright red fruit according to Labat, gives a beautiful red die. Some experiments, however, made upon the juice of that fruit, as brought into England, did not seem to promise any great advantage from it ; but the particulars I cannot now recollect. The ripe berries of buckthorn stain paper of a green colour. From these is prepared the sub- stance called sap-green, a pigment sufficiently du- rable, readily soluble in water, but not miscible vdth oil. The berries dried whilst green, and macerated in alum water, are said to yield a yellow pigment ; and when they have grown over- ripe, so as to fall off spontaneously, a purple one. Woollen cloth, prepared with alum and tartar, receives, on being boiled with the berries, a per- ishable yellow die. The French berries, or grain- ed Avignon of the French Diers, one of the most false, that is, the most perishable of the yellow dies, is the berry of a species of buckthorn smaller than that which grows wild among us. It is said that the berry of the Heliotr opium trt. coccum^ which grows wild about Montpelier, stains paper of a green colour, and that this green turns presently to a blue ; that the common blue paper receives its colour from this juice ; and that the red rags, called turnsoL employed for colour- ing wines and other liquors, are tinctured by the same juice, turned red by acids. According to M, Nissolle of the French academy of sciences (as quoted by Savary in his Dictionaire de Com. merce J the colouring juice is obtained, not from the berries, bu’ from the tops of the plant, gather- ed in August, ground in mills, and then commit- 245 ted to the press. The juice is exposed to the sun about an hour, the rags dipped in it, dried in the sun, moistened by the vapour which arises during the slacking of quick lime with urine, then dried again in the sun, and dipped again in the juice. The Dutch and others are said to prepare turn- sol rags, and turnsol in the mass, from different ingredients, among which archil is a principal one. In some plants, peony for instance, the seeds at a certain point of maturity are covered Vv'ith a fine shining red membrane ; the pellicles of the seeds of a certain American tree afford the red masses brought into Europe under the names of annotto, orlean, and roucou. The red seeds, cleared from the pods, are steeped in water for seven or eight days or longer, till the liquor be- gins to ferment ; then strongly stirred, and stamp« ed with wo^*den paddles and beaters, to promote the separation of the red skins; this process is repeated several times till the seeds are left white. The hquor passed through close cane selves is pretty thick, of a deep red colour and a very ill smell. In boiling it throws up its colouring mat- ter to the surface in form of scum, which is after, wards boiled down by itself to a due consistence, and made up, while soft into balls. The annotto commonly met with among us, is moderately hard and dry, of a brown colour on the outside, and a dull red within. It is with dif- ficulty acted on by water, and tinges the liquor only of a pale brownish yellow colour. In recti- fied spirit of wine it readily dissolves, and com- municates a high orange or yellowish red. Hence it is used as an ingredient in varnishes, for giving 246 i 3 fiore or less of an orange cast to the simple yel- lows Alkaline sails render it perfectly soluble in boiling water, without altering its colour. Wool or silk boiled in the solution, acquire a deep but not a very durable orange die. Its col- our is not changed b) alum or by acids any more than by alkalis ; but when imbibed in cloth, it is discharged by soap and destroyed by exposure to the air. Mr. Pott, in the Berlin memoirs for the year 1752, mentions a very extraordinary property of this concrete. With the vitriolic acid, it pro- duces a blue colour, ol extreme beauty, but with this capital defect, that all salts and liquors, even common water destroy it.** The specimen of annotto w hich I examined, was not sensibl} acted on by spirit of vitriol. It received no change in its own colour, and com- municated none to the liquor. Nor did any visible change ensue upon dropping the acid into tinctures of annotto made in water or in spirit. Labat informs us, that the Indians prepare an annotto greatly superior to that which is brought to us, of a bright shining red colour, almost equal to carmine ; that for ihi^ purpose, instead of steep- ing and fermenting the seeds in water, they rub them wiih the hands previously dipt in oil, till the pellicles come oflF, and are reduced into a clear paste, which is scraped off from the hands with a knife, and laid on a clean leaf in the shade to dry. De Lacet^ in his ik tes on Maregrave’s Natural History of Brazi l mentions also two kinds of an- notto, one of a permanent crimson colour, (coc- cineus) used as a fucus \ and another which gives 247 a colour inclining more to that of saffron. This last, which is our annouo, he supposes to be a mixture of the first sort wiih certain resinous matters, and with the juice of the root of the tree. Ximenes relates, that annotto with urine stains linen of such a permanent colour that it can never be washed out Perhaps tht first sort is meant. Our annotto boiled in urine, imparted to linen a deep yellowish red : the stained linen, hung out in the air in summer, in seven or eight days'lost all its colour and became white again. CHAPTER III. or LEAVES. THE green colour of the leaves of plants is ex- tracted by rectified spirit of wine and by oils. The spirituous tinctures are generally of a fine deep green, even when the leaves themselves arc dull coloured, or yellovvish, or hoary. The col- our however, seldom abides long even in the li- quor ; much less when the tinging matter is sep- arated in a solid form and exposed with a large surface to the air. The editor of the fVirtemberg Fharmacopddia observes, that the leavt s of acan- thus bran k ursine or bears breech, give a more du- . Table green tincture to spirit than th >se of any ^ otner herb. Alkalis heighten the colour both of i the tinctures and green juices. Acids weaken, desiniv, or change it to a browmish. Lime wa- ter improves both the colour and the durability. 248 By means of lime, not inelegant green lakes are procurable from ihe leaves of acanthus, liliy of the valley, and several other plants. There are very fevv herbs which comnuiuicatc any sh ire of their green colour to water ; perhaps noiie that give a green of any considerable deep- ness. It is said how ever, that the leaves of some ■plants give a green die to woollen, without the addition of any other colouring matter ; particu- larly those of the wild chervil or cow. weed [AJyrr- his sylvestris. semhiibus Isevthus, C\ B J the com- mon ragw'urt, and devil’s bit. The process with this last as described by Linnaeus (in the Sve^tsca jicad. Handle ars, 1742) is pretty remarkaoie. The peasants, he informs us in some of the Swe- dish provinces, stratify the fresh leaves with wool- len yarn, and boil them about as long as it is cus- tomary to boil fish. The whole is suffered to stand in the vessel for a night. The wool, taken out in the morning does not appear to have received any colour. The pot is again made hot, and the yarn hung over it upon a stick, covered w ith an inverted dish to confine ihe steam, for this steam is supposed to be essential to the colour. The yarn is afterwards wrung, the leaves taken out sr::;5chineal. To try the effect of loading it further with the colouring matter, it was re- turned into the liquor and boiled for a quarter of an hour longer : it had now acquired a purple colour sufficiently vivid. On varying this experiment by keeping tlie cloth moist for some days after the preparaiion with alum and tartar, then dipping it in a pl-.un decoction of madder made as usual without salts, and adding, when it had gained a bright cinnamon colour, the same solution of bismuth, the die in- stead of purple proved only a chesnut. - 1 X 254 CHAPTER V. OF FUSTIC, FUSTIC is the wood or species of mulberr}’- tree, growing in Jamaica and Bri zil, called by Sir Hans Sloane, Moi us Fructu F iridi Ligno SuU phureo linctorio. It is of a deep sulphur yel« iow colour, which it readily gives out both to wa- ter and spirit. The watery decoction dies pre- pared woollen of a very durable orange yellow ; the colour is imbibed by the cloth in a moderate warmth without boiling. The fustet or fustel of the French is a yellow wood or root very different fronr*. our fustic It gives a fine orange die to woollen, but the colour is extremely perishable in the air. 'i'hc plant grows wild in Italy and Provence, and is cultiva- ted with us in gardens on account of the beauty of its flowers. It is called Ft^nice Sumach, co~ tinus cotiaria,coccigria ; cotinus matthiolU CHAPTER VI. nephritic wood. THIS wood is brought from the eastern coun- tries in large pieces, covered with a dark blackish bark. The wood is hard, heavv , compact, of a fine grain, of a whitish or pale yellow colour on 255 the outside, and a dusky reddish brown in the heart. Of the tree we have no very certain ac- count. This wood, particularly the outer pale part, gives out both to water and to rectified spirit a deep tincture appearing, when placed between the eye and the light, of a golden colour ; in other situations, blue. Hence it is named by Caspar Baiihino^ lignum peregrinum, aqiiatn coeruleam redden. By this mark it is easily distinguished from pie- ces of a different kind of wood, which are some- times mixt with it, and which give only a yellow tincture to water. It is remark able,- that the blue colour of the in- fusion of nephritic wood is destroyed by acids, the liquor after the admixture of these appearing in all situations yellow ; and that the addition of alkalis, either of the fixt or volatile kind, in quan- tity sufficient to neutralize the acid, restores the blueness. No other woody matter is known that gives any degree of blue tincture, and no oth- er vegetable blue is knotvn that is thus destructi- ble by acids. This wood is at present rarely met with in the shops ; nor is it applied to any use, except that some have employed it medicinally, and expected from it diuretic virtues^ whence its name nephritic wood. 2^6 4 CHAPTER VIL MR. PERGirSON’s HISTORY OF LOGWOOD AS A colouring drug. LOGWOOD or Campeachy.wood' f Lignum Lrazilo simile i coetuleo tingem, J, B J the Wfod of a low prickly tree, which grows plenti- fuily about Campeachy or the Bay of Honduras, and has of late been introduced into some of the warmer of the British plantations, particularly Jamaica. It is a native of the low marshy places. The wood comes over in pretty large logs cleared from the bark. It is very hard, compact, heavy, and of a red colour. Logw'ood gives out its colour both to watery and spirituous menstrua, bur not readily to either. It requires to be rasped and ground into fine pow'- der, and boiled in several fresh parcels of the li- quors. Rectified spirit extracts the colour more easily, and from a larger proportion of the wood tbnn water does. 'I'he tinctures both in water and in spirit arc efa fine red, with an admixture, particularly in the watery one, of a vhdetor purple. Volatile al- kaline salts or spirits incline the colour more to purple. The vegetable and nitrous acids ren- der it pale, the vitriolic and marine acids deep- # en it. The w’atcry decoction, wrote with on paper, loses its redness in a few^ days and becomes wholly violet. This colour it communicates also to I 257 woollen cloth previously prepared by boiling with a soliuion of alum and tartar. The die is beauti- ful, but very perishable. It is often used by the diers as an ingredient in compound colours, for procuring certain shades which are not easily hit by other materials.. With chalvbeate solutions it strikes a black. H «.nce it is employed in conjunction with those liqueurs for staining wood black for picture frames, and with the addition of galls for dying cloth and hats black. The black dies in which thi& wood is an ingredient, have a particular lustre and softness, far beyond those made with vitriol and galls alone. The beauty however which it here imparts is not permanent, any more than its owa natural violet die. On the same principle It improves also the lus- tre and blackness of writiiig ink. Ink made with vitriol and galls does not attain to its full blackness till after it has lain some time upon the paper. A due addition of Logwi)od renders it of a deep black as it flows from the pen, especially when vinegar or white wine is used for the menstruum. Decoctions and extracts made from logwood, have an agreeable sweetish taste, followed by a slight astringency. They have lately been intro- duced into medicine, and given with success in cases where mild restringents are required. They often tinge the stools, and sometimes the urine ©f a red colour. xa 25S CHAPTER VIII. THE PROCESS OP PRUSSIAN BLUE. PRUSSIAN blue is prepared by precipitating a solution of green vitriol and alum with a lixivi- um drawn from fixed alkaline salt that has been calcined with animal coals. Commonly about three parts of alkali and two of dried ox- blood are calcined so long as any flame appears, then thrown into boiling water, and the strained decoction poured into a hot mixture of solutions of four parts of alum and one or less of vitriol. The li- quor becomes instantly thick or curdly, and looks at first of a greyish colour, which changes to a brown and in a little time to a bluish green. The matter, being well stirred together, and mixed with a quantity of hard spring water, a green pre- cipitate subsides ; spirit of salt poured upon the edulcorated powder dissolves a part and leaves the rest blue. Mr. Geofirey is the first who has given any plausible theory of this process', or any rational means for improving it. He observes that the Prussian blue is no other than the iron of the vit« riol revived by the inflammable matter of the alka- line lixivium, and perhaps brightened by an ad- mixture of the white earth of alum ; that the green colour proceeds from a part of the yellow ferru- gineous calx or ochre unrevived, mixing with the blue, and that the spirit of salt dissolves this ochre more readily than the blue part, though it will dis- 255 solve that also by long standing, or if used in too large quantity. From these principles he was led to increase the quantity of inflammable matter, that there might be enough to receive the whole of the ferrugineous ochre, and produce a blue colour at once without the use of the acid spirit. In this he perfectly succeeded, and found at the same lime that the colour might be rendered of any degree of deepness or lightness at pleas- ure. If the alkali is calcined with twice its w^eight of dried blood, and the lixivium obtained from it, poured into a solution of one part of vitriol to six of alum, the liquor acquires a very pale blue col- our, and deposits as pale a precipitate. On add- ing more and more of a fresh solution of vitriol, the colour becomes deeper and deeper, almost to blackness. He imagines with great probabili- ty, that the blue pigments thus prepared will prove more durable in the air, mingle more per- fectly with other colours, and be less apt to injure the lustre of such as are mixed with or applied to its neighborhood, than that made in the com- mon manner ; the tarnish and other inconvenien- ces to which the common Prussian blue is sub- ject, seeming to proceed from the acid and spirit, which cannot be totally'^^parated by any ablu- tion. He takes notice also of an amusing phenome- non which happens upon mixture. When the li- quors are well stirred together, and the circular motion as soon as possible stopt ; some drops of solution of vitriol (depurated by long settling) let fall on different parts of the surface, divide, spread, and form curious representations of 260 flowers, trees, shrubs, flying insects, See. in great regularity and perfection. These contin- ue ten or twelve minutes, and on stirring the liquor again, and dropping in some more of the solution of vitriol, are succeeded by a new pic- ture. Mr. Macquer has ingeniously applied the prep- aration of this pigment to the dicing of wool and silk, and found means of fixing the blue fecula in their pores. By dipping cloth first in a diluted solution of vitriol and alum, then in the ley dilated, and afterwards in water acidu- lated with spirit of vitriol, it acquires a light blue colour, which becomes deeper and deeper on repeating the dippings alternately in the same order as before ; adding to the liquors each time a little more of the respective saline matters. The blue die, he says, in beauty and lustre ex- ceeds that of indigo and woad, as far as scarlet does the madder red, and penetrates the whole substance of fulled cloth without weakening it. The colour is durable in the air, and stands boiling with alum water, but is discharged by soap, and, without certain precautions, liable to be specky or unequal. See Memoirs of the French Academy for the year 1749. # CHAPTER IX. ALKANET-ROOT. THE roots of alkanet in many respects very much resemble saunders wood, but differ from it 261 remarkably in others. They impart an elegant deep red to pure spirit of wine, to oils, to \\ax, and to unctuous substances : I do not know of any red drug that tinges oil of so fine a colour. To water they give only a dull brownish red. The spirituous liquor, on being inspissated to the consistence of an extract, instead of preserv- ing its fine red like that of saunders, changes to an unsightly brown. Volatile spirits have been said to gain from this root a beautiful violet or amethyst colour ; but I have not found that they extract any colour but a dull reddish brown. Thealkanet plant is a species of bu gloss, named by Toutnefort bu^lossum raclice^ rubra sive an- ehusa vulgcitior Jlonbu& ccerultu. It is a native of the warmer parts of Kurope, and cultivated in some of our gardens The greatest quantities are raised in Germany and France, particularly about Montpelier, from whence W'e are chitfly supplied with the roots. The alkanet root produced in Flngland is much inferior in colour to that brought from abroad ; the former being only lightly reddish, the latter of a deep purplish red. This has induced some to suspect that the foreign roots owe part of their colour to art, but a chymical examination teaches otherwise. The colouring matter is found upon experiment to be of the same kind in both, and to differ in several of its properties from that of all the other known red drugs ,* so that no artifice appears to be practicable without discovery un- less it was concentrating the colour of two roots into one, or supersaturating one root with the col- our extracted from another. 262 The principal use of alkanet-root is for col- ouring oils, unguents, lip salves, plaisters, &c* Wax tinged with it, applied on warm marble, stains it of a flesh colour, which sinks deep into the sk^ne. The spirituous tincture gives a deep red stain. The colour of this root is confined to the corti- cal parr, the pith being whitish ; hence as the small roots have more bark in proportion to their bulk than the larger ones, those also contain most col- our. CHAPTER X. or ALUM. NATURE produces no perfect alum, but af- fords the materials for it in sundry ores, pyritcc, stones, slate earth, waters and bitumens as pit coal. Some late experiments by Mr. Geoffrey and Mr. Pot have shewn that the earth of alum is contained in clay, and that a true alum may be prepared by digesting clay in the vitriolic acid. Both of these gentlemen imagine that only a par- ticular part of the clay is here extracted. Whether it existed originally in the clay, pos- sessed of the same properties which it is found to have when extracted, or whether it has suffer- ed a change in the operation, they have not deter- mined. From the ex|>eriments I have made, the latter seems to be the case. Powdered tobacco- pipe* clay, being boiled in a considerable quantity of oil of vitriol; and the fire continued to dryne^s^ 265 the matter, eicamined when .s^rown cold, discov- ers scarcely any tasre, or only a slight acidulous one. (Jn exposure to the air for a few days, the greatest part of it is found changed into lanugi- nous efflorescences in taste exactly like alum : the remainder treated with fresh oil of vitriol in the same manner, exhibits the same phenomena, and this repeatedly, till nearly the whole of the day is converted into an astringent salt. If the earth be separated again from the acid, (by dissolving the salt in water, and precipitating with any alkaline salt) it is now found to dissolve with ease in every acid ; to form with the vitriol- ic alum again ; with the nitrous, a compound resembling alum in taste ; with the vegetable acids, a substance less astringent and less ungrate- ful. CHAPTER XL CHYMICAL HISTORY OF SAUNDERS, AND ITS DIFFERENCE FROM OTHER RED- WOODS. RED saunders is a hard, compact, ponderous wood, of a dark blackish red on the outside, and a light red colour within ; of no particular smell or taste. It is brought from the Coromandel coast and from Golconda. Of the tree we have no certain account. Its principal use is as a colouring drug. Those whose business it is to rasp and grind it into powder, probably employ certain saline* or other additions to improve tlie 264 colour ; whence the remarkable dlffbreiices in the colour of powdered saunders prepared in differ^ ent places. 'Phat of Strasburgh is of the deepest and liveliest red. Some sorts are of a dead dark red, and some of a pale brick red ; some incline to purple or violet, and some to brown. The colour of this woocT resides wholly in its resin, and hence is extracted bv rectified spirit, whilst- water though it takes up a porii m of mu- cilaginous matter, gains no tinge, or only a slight yellowish one F. ^m two ounces of the wood were obtained by spirit of wine three drachms and a lulf of resinous extract, and afterwards by water, a scruple of mucilage. By appl}ing wha- ler at first, I obtained from two ounces, two drachms and six grains of a tough mucilaginous extract, which could not easily be reduced to dry- ness. The remainder sti'l \ ielded, with spirit, tw'o drachms of resin. The indissoluble matter weighed in ihr first cise, an ounce and a half and fifteen grains ; in the latter, nineteen grains less. Neither the distilled water nor spirit had any re- markable taste or smell. The red colour of s unders appears to be no other than a concentrated yellow, for by bare dilu- tion it becomes yellow. A grain of the resinous extract, dissolved in an ounce of rectified spirit, tii\ges its red, but this solution mixt with a quart of fresh spirit, gives only a yellow hue. Hoffman reports that this resni docs not give a tincture to any kind of oil. I have tried five oils, those of amber, turpentine, almonds, annlseeds, and laven- der. It gave no c(dour to the tw'o first, but a deep red to the last, and a paler red to the other two. CHAPTER XII. OF VERDIGRISE. ' IT may not be amiss to give the reader a chym- ical hint of verdigrise. Vegetable acids dissolve copper slowly, but in considerable quantity ; the solution shoots into bluish green chrystals, similar to the verdigrise, arugo or viride csris, of the shops. This prep- aration is made in large quantities in France, par- ticularly about Montpelier, by stratifying copper plates with the husks of grapes remaining after the juice has been prest out. These soon become acid and corrode the copper. Verdigrise should be chosen in cakes, not moist or unctuous, but dry, compact, and of an uniform texture, of a lively green colour through- out, as free as possible from white and black specks, and seeds or stalks of the grape. It is purified b} solution in distilled vinegar, and crys- tallization, and then called, improperly, distilled verdigrise or flowers of copper. The Dutch who prepare these crystals in large quantities, after duly evaporating the solution, set it to shoot, not, as is customary in a cold but in a warm place, as practised in making sugar- candy. If rectified spirit of wine be added to the solu.. tion, or if volaliic alkalis be added to a solution of copper and spirit of wine to this mixture, spiall blue cr\ s-als w ill be immediately foi^. :d. These are called by some antepileptic crystals of copper. 266 Highly rectified spirit of wine, digested on half an ounce, or twelve scruples of powdered verdi- grise, dissolved three scruples and a half ; ordi- nary rectified spirit, four scruples ; common malt spirits four and a half, and French brandy seven and a half. Water dissolved, out of the same quantity, five scruples. Common wine vinegar dissolved all but fifteen grains, and distilled vine- gar all but ten grains. The whole quantity of verdigrise dissolved in either kind of vinegar, could not be recovered again in a crystalline form. From the common vinegar only two scruples and five grains crystallized, and from the distilled vinegar three scruples. The residuum in the first case continued softish, in the latter dry. With French brandy there was no crystallization at all ; the whole that the spirit had taken up remaining uniformly raixt into the consistence of an extract. A HINT TO THE Diers and Cloth-Makers, AND WELL WORTH THE NOTICE OF THE MERCHANT. BY JAMES HAIGH, LATE SILK AND MUSLIN-DIER, LEEDS PREFACE. THE Author of the Dier’s Assistant thinks it his duty., ih gratitude to the professors in that noble art, to sub- scribe bis hearty thanks for their approbation of, and en- couragement given to that work, in this and every part ot England. It is well known by that body ol people, and felt too by some, that the price for dicing woollen gooda hath been much reduced of late. Many circumstances having determined me, long since, to acquire all possi- ble knowledge in the practice of dicing, 1 am tlierefore constrained once more to recommend a strict inquiry into the original quality of all the drugs they use, that there- by, if possible, they may discover some of the many hidden advantages that may justly be expected therefrom. I am astonisned that no artist has ever attempted to improve this most ingenious art on chymical principles. I begun the work in hopes that my master-piece would undertake to improve it, but in vain do I expect it, A WORD TO THE THINKING PART OF DIERS. If you were sensible of the double advantage that might be acquired in the use of m.my of your vegetable drugs, which must be first grounded on chymical experiments in miniature, which will be a certain rule to the practice at large, I am certain you would not rest till you had made some improvement. If after you have been dicing with that resinous drug, saunders, when emptying the vessel you take up a hand- ful, dry it and digesi it in a phial vvHli some pure spirits of wine, and It will afford you an excellent red water be- ing insufficient to dissolve the resin, and let out Uic prime partofihe colour. Many others might be discovered if an unwearied attention was paid. Y2 270 PREFACE. Many will censure and despise this, for no other reason than because they cannot see into it; nor will they be at any pains to learn and improve their talents They seem rather to choose the old round, like a horse in a mill, having no spirit or courage to improve, but content with each knowing the other’s method, without striving to ex- cel, and discover more complete and less expensive ways of working, and using the drugs to the best advantage. I know not how men can sit still when there is more to learn. Let it not be said of you, as of one of old, “ he liv- ed and died and did nothing perhaps he worked with his hands, but his head was asleep ; and therefore he was an unprofitable servant, and when dead, his memory was no more. Sure it is, the invitation I have to write and publish this small pamphlet is not so much to please others, or to shew any thing I have is capable ol the name of parts, but to communicate my good wishes for improvement to my brethren the Diers, and to show them my willingness to help to perfect one of the most useful arts in the world. I shall leave all to itself, and to every man’s just liber- ty to approve, or disapprove, as he pleases. And how- ever it be, the author shall not be much troubled, for he is certain no man can have a lighter esteem for him, than he has for himself ; who, however, will be best pleased, if any man shall find benefit by what he^ has written. If any should alledge a general acceptation, that, to the author, will be no prevailing argument ; for the multi tude, though most in number, are the worst and most partial judges. He does not plead the importunity of friends for the publication of this. If it is wort;'.y, it needs no apology ; it not, let it be despised ; and I re- main the same friend to trade. JAMES HAIGH. 271 A HINT TO THE DIERS, &c. BLACK being a primitive colour, and one of the most difficult to perfect, deserves a few re- marks. If I ask a Dier what ingredients com- pose a black, the answer will be this ; Logwood, sumac, bark, and copperas ; and if he know^s it, he will add a little ashes and argol in the last wet. If I ask him which of these drugs contain an acid, which an alkaline and which a neutral quality, he cannot give me an answer ; so you see he knows the effect, but a stranger to the cause, and every thing else separate from fact and custom. What a pity it is that men will not search things to the bottom, when they might be able to fiiid out the cause of miscarriages, for which goods are frequently thrown aside to be died other col- ours, greatly to the Dicr’s loss. In conversing with a sensible Dier, 1 simply asked him, What part does logwood act in the black die ? the hon« est man as simply answered, “ It helps to make it black.** No other proof was wanted to know that he also followed his forefathers in the old round. But the reader, by now, thinks it time to be informed of the business of logwood; which is (if used in a right proportion) to soften the goods and give lustre to the colour. Logwood being possessed of a most excellent astrifigent quality, fixes itself in the pores of the goods, and give s them a velvet like feel and gloss. Some will object to this asseftio>5 and say, but our blacks have not that velvet, like feeling and gloss. True, sir, but don’t you know the reason \ 272 you die your blacks without scouring, forgetting, or not knowing, that when the goods enter the boiling die liquor, they grow harsh, and the oil eontained in them forms a sort of resin, which be- comes as fixed as if it w as pitch or tar. This is one great cause why blacks are so liable to soil and dirty linen, because the die is in some sense held in an outside or superficial state. Think then, is it possible these goods should finish soft like velvet, or shine like a raven’s feather f No, on the contrary they spoil the press papers, and come out stilFand hard like buckram, (not velvet) and are often three-parts perished in rhe finishing. No greater cause can be assigned fi>r it than that of not scouring. This is the reason of the great difference so much spoken of, between the Lon- don blacks and those died at Leeds. If the Leed’s Diers would take the same pains as the Londoners do, I think they would excel, in fact, if not in name. The finishing shops in London are not more than half so well furnished with tools as those at Leeds arc ; and therefore let iht Leeds Diers be equally tight and clean in their peTormance, aiid there is nf>thing to prevent their suptrioi itv. But the master diers give a very reasonable answer to the foregoing. 'Bhey say, die price is too low, and they cannot afford to take so much pains. What a pity that the merchants do not consider this 1 if ihree pence a piece was added to the price for dicing thin goods black, it would about pa\ for the scouiing. and the goods would be finished with a briUiam lustre, and yet soft like a russel. I should speak a little to the nature and business of the other drugs, which enter the composition of black, had I not done it before {^see the article blacky Dier'^s Assistant, p, 184.^ 1 am astonished at the ignorance of the poor cloth. makers, many of whom have applied to me frequently for instructions ; one of them, on be- ing asked what sort of ware, and how much he used to die such a colour, shewing him a pattern, he answered, when 1 have a pattern given me by a merchant, I go to the salter, shew him the or- der, and he serves me with what is wanted. I con- versed with him some time, and would have in- structed him, but alas ! he had left his capacity at home, and 1 might as well have read the newspa- per to him. What a pity it is that so many hun- dreds of that noble branch of business work, as it were, blindlblded, and poverty bitten too, for Want of instructions, which they have no spirit to seek : who, when they bring a cloth to the mar- ket, are glad to sell it for one and sixpence, or two shillings in the pound profit, when they might as easily gain five or six shillings, if they knew how to use their drugs. But I despair of doing that for them, which nature has left undone ; for, with- out I could teach them to see with a dier’s eye, I might talk and write forever in vain. But there is another class of cloth-makers, to whom 1 will give a useful hint and have done. The article sky blue deserves our notice. This colour is often substituted, (e\en on fine cloth) by the Saxon blue, on account of its brilliancy and line lustre ; but like a fugitive it only stays for a season. A little experience has taught me, that if a parcel of fine wool be well scoured, then sul- 274 phured or stoved, than which nothing can make it whiter, and then died in a weak vat, it will have all the beauty of the Saxon blue, without its im- perfections. The vat used for this purpose should be set with a small quantity of indigo, on purpose for light shades, when the shades will be always brighter than when died in an old vat that has been weakened by dying dark colours. But the diers tell you that blues bear so low a price, and indigo is so dear, that they cannot afford lo set fresh vats for light shades. Here is a sufficient cause, and one very great reason of retarding the perfection of many colours It the wool before- mentioned should be obstructed in the milling, by means of the sulphur, (of which I have not had experience) I would commend the dicing of the wool after scouring only, and stove it after it is milled, which I think will answer the same pur- pose ; and the beauty of the colour will amply pay for every superfluous work. I would recommend to the diers, after washing the dark blues wc 11 at the river, to turn the cloth very quick through a warm vessel of w'ater, in which has been dissolved a little alum, and they will see a surprising change in the lustre from that simple process. I am not willing to omit any thing worth notice in the course of my experiments. I will there- fore, lightly touch the properties of common wa- ter. By a great number of experimt nts, I am thoroughly convinced, that different waters with the same ingredients strike different colours, I find that the purest and lightest water strike the best light ccjlours. All the die* houses at a distance from the river 275 in London are furnished with wood cisterns which hold perhaps from one to two hundred hogsheads of water, which is supplied from the waterworks and isal\\a}s impure, and frequently muddy; when on standing a considerable time, as is the case at some seasons of the year, it becomes putrid and emits a letid smell ; if suffered to stand long- er, it purifies itself, and bect»mes sweet and clear, as well as considerably lighter. I have sometimes filled a vessel when the water has been all of a ferment, and stunk almost beyond bearifig. which at a boiling heat was no more felt; by adding a handful of common starch and a small bit of alum all the filth is made to rise, and is taken off with a ladle for that purpose. The superior goodness of the waiei obliges us to ascribe an advan^^ge to the London diers of light colours ; add to this their remarkable cleanliness. When a vessel is boiling, they watch it carefully ; and with a mop, ke^A for that purpose, they rub oft' the scum all round at the water’s edge, so that the liquor is perlectly clear. A short remark on the die of Brazil ivoodm It is impossible to wear a red, a dove colour, a ciimsoii, pui j le, light or deep vii-k or any oth- er colour, ihc }>roducc ot Brazil od used re- cenilv man} weeks, without fading, spotting, or soiling. If there colours were died in grain they would indeed cost something more, but you have tlien a colour which will continue beautiful as long as ihe sti.ff or cloth v' ill last ; and if spotted with dirt or grease, can casil} be scoured and clean- od without danger of losing or injuring the coiouri 276 I boiled fifty pounds of Brazil chips one hour, in a copper of the hardest spring water I could find, and carefully took off the scum, turned this liquor over into a large tub, and re- heated the cop. per to boil the chips a second time, when the coL our was all extracted. I then put both liquors together, and let it stand six months, when it was ropy and thick like oil. Now having prepared a small piece of fine cloth in alum and sour bran« water, and kept it moist five days unwashed out of the alum, I boiled one nut-gall and one quart of Brazil liquor ten minutes, then rinsed my piece of cloth, and died it a very beautiful ma- ronc. But the chief remark I intend to make here, is, that I hung this piece of cloth in the open dir night and day during four severe winter months, and it had rather gained in beauty of colour, and was grown rather deeper. This is a sufficient proof that ch} mistry hath a power of securing the fine particles of those vegetables which are now called bastard drugs. Experi- ments (which are the best guides in natural phi- losophy, as well as in arts) plainly shew that a great advantage might arise in favour of the stu- dious practitioner, who is not wearied if he miss his design after twenty or thirty trials, but still pursues his plan till he has hit it ; for nothing of the kind seems to be impossible. A Experimental Observations on the Die of CochinsaL After all the common processes of dicing with cochineal, there is found at the bottom of the ves- sel a deep brown sediment. This sediment ap- 277 pears to consist of the impurities of the tartar, and the grosser parts of the powdered cochineal. This being lighdy washed with clear cold water, dried and ground on a marble, with one fourth its weight of fine tartar, into an impalpable pow- der, and then put into water with a little alum, a piece of white cloth boiled in this liquor three quarters of an hour acquired a very beautiful crimson die. This experiment evinces, that, by reducing cochineal into a powder of moderate fineness as commonly jiractised, we do not gain all the ad- vantage which this valuable commodity is capa- ble of yielding. If the cochineal, when taken from the vessel, (after the scarlets are died) is treated as above, the saving in the cochineal, whether for scarlet or crimson, will be about one- third. Though less tartar is usuall) employed in the die liquor, yet this quantity here directed does no harm ; it ap- pealed on trial that the colour was rather the more solid for it. All urinous and alkaline liquors or substances stain scarlet of a crimson, by destroy- ing the t ffect of the acid. Hence, in purecoui*. try air, scarlet retains its lustre much longer than in cities and towns, w here alk tline and urinous vap(jiirs are more abundant. The dirt of roads and sundry substances of the acrid kind, leave no stain on scarlet, if the part be washed imme- diately in pure water, and wrung in a clean linen cloth. If the dirt is suffered to dry, a blackish vit>let spot will remain, w hich can only be dis^ ch irged by mild vegetable acids, as vinegar cit- ron juice, a warm dilute solution of cream of tartar, or sour bran water ; ii' these acids, hov;- Z 278 ever, be not applied with a good deal of address, whilst they take out the blackish stain they leave a yellow one, by dissolving the colouring parti- cles of the cochineal itself. After at least a thousand experiments, I am obliged to conclude, that the dicing of wool is the most extensive branch of this art, it may be con- sidered as its basis ; but the dicing of silk, thread, and cotton, deserves also our attention. The great diiTerence between those substances, and that of wool, is well known to the calico printers, whose grand care it is to find means of making linen receive the same dies as wool does. The physical cause oi the difterence seems yet un- known ; and indeed, as before observed of dies in general, we know as yet very little. Are ani- mal filaments tubular, and the colouring atoms received within them ? are vegetable filaments solid, and the colour deposited on the surface ? or, does not their different susceptibility of colour depend rather on the different intrinsic properties of the two ? An answer to this would doubtless prove of great utility. » I should be happy to find some artist undertake <' to improve what I have in a poor way begun. . I long to see the art in perfection, one half of which is yet in oblivion. The reader may be assured, that what is here recited is purely the result of the author’s own experience, (not theory) and part of the effects of many years’ study. XU£ A / )PEaA-L mi