.-ijt t i ‘ 'f ^ ■ : <■ .. •' ; '' 'I ■f. ■ f, H ff-7> P' 6 ' ■',' I J J#" \ rk,v*^ \ mi Mmmn u-p' m ‘ : CHEMICAL LECTURES, Publickly Read at London, In the Years 1731, and 1732; •And at Scarborough, in 1733; % For the Improvement of \ ARTS, TRADES, AND 1 NATURAL PHILOSOPHY. By PETER SHAW, M. D. F. R. S. Fellow of the Royal College of Phyficians in London, Andoneof His Majesty’s Phyficians in Ordinary. The Second Edition, Corredted. LONDON: Printed for T. and T. L on g m a n, in pater Nojier Row *, J. S H u c K B u R G H, in Fleet-Street ; and A. M I L L A R, in the Strand, MDCCLV. Digitized by the Internet Archive in 2016 I https://archive.org/details/chemicallecturesOOshaw C iii } TO THE R-ight Honourable the Lord Vifcount Lonfdale^ Lord PRivy-SEiiL, ^c. My Lord, \ S your Lordfhip was pleafed to ho- ^ nour thefe Ledlures with your No- tice in Manufcript, I take the Liberty of laying them before you in Print ; being dehrous the Publick fhould know, that their Deiign was approved of by fo un- exceptionable a Judge. a 2 For, ■ iv DEDICATION. Fcr, beiides your uncommon Skill in Civil Policy, the Laws, and all the Branches of Publick Buhnefs ; you have, like the Illulirious Lord Bacon, a Talent for the Improvement ot Arts, and a Pleaftire, and Sagacity, in purfuing na- tural Enquiries, Were I not, therefore, fenfible, my Lord, that your Candour is as extenfive as your Learning, I fhould be cautious of thus fubmitting thefe Bender Enqui- ries to your View ; as they are neither condudled dn a Manner fuitable to your corredl and exquifite Tafle; nor purfued to fuch a Length, as your great Knov/- ledge in Phiiofophical Matters may jufliy require. But this gives me farther Encourage- ment, that 1 do not know a more ufe- ful DEDICATION. V ful Subject, than the prefent, to a Tra- ding Nation; nor a Perfon better quali- fied than your Lordfhip, to perceive its Tendency, and diredt its Improvement. I am MY LORD, Your Lordship’s Scarborough, July 15. 1733- Mojl obliged^ and demoted kumble Servant, Peter Sh^w. ADVERTISEMENT. T H E following LeBures had the Honour to be read before a noble Audience^ who candidly overlooked their Failings., and requefled their Publi- catio7i. As the Defgn is of large Extent, little more than a Sample of the whole could at prefent be given ; the far- ther Improvement of it being left to others. Ehe Experhnents here en7ployed, thd many of them new, are generally frmple ; or performable with little Cofi, and Ap- paratus : But if a few particzdar In- fruments, a fid ‘Trials, hereafter 'inti- mated, were to be made, and properly ufed, much greater Difcoveries might be reafonably expeBed. [ vH] G L O S S A R Y: O R Explanation of .the Technical Terms in this Work. A dd. By Acids are meant all'thofe Things that tafteTour *, as Vinegar, Tartar, Juice offCrabs, Lemons, Spirit of Nitre, Spirit of Salt, and which, when mixed with a due Proportion of an Alkali^ conftitute a neutral Body, wherein neither Acid nor Alkali pre- vails *, whence it alters not the Colour of Sy- rup of Violets. See Alkali and Neutrals. Adits, See Burrows. Alcohol. Is, pure and perfect Spirit of Wine, with- out the leail Particle of Water, or Phlegm. Alkali. Is a Word of extenfive Signification, and chemically denotes a large Tribe of Bodies. For all Bodies may be chemically confidered under three Tribes •, or as being either Alkalies., Acids.,‘ or Neutrals. Alkalies have this efiTential Property, - that when mixed, or united, with Acids., they conftitute Neutrals. But a more common Mark of an Alkali is, that it turns Syrup of Wiolets green, as an Acid turns it red ; w'hilft the Admixture of a Neutral Body does a 4 not vni A GLOSSARY. not alter the Colour of that Syrup. Thus Pot- Afh, Salt of Tartar, and all fixed vegetable Salts ; as likevvife all volatile animal Salts and Spirits, arc artificial Alkalies'^ as Chalk, the teftaceous Bodies, are natural Alkalies, And thus, in the vegetable Kingdom, Onions, Leeks, Garlick, Muflard, Cfr. are Alkaline \ as Sorrel, Wood-Sorrel, the Juice of Lemons, Oranges, Verjuice, are Acid, Their Dif- ference alfo is manifefl from the Tafte, when the Habit of thus diftinguifhing them is ac- quired. Acids Neutrals. Amclgamaticn. is the Difiblution, or Mixture of any Metal with Quickfilver : But Iron, of all the Metals, v/ill not amalgamate, or unite therewith. AJfaying. Is the Art of difeovering how much pure Metal is contained in any Ore, or Coin, afiigned. Hence to make an EJfay,^ is to pro- duce a Lump, or Grain, of pure Metal, from any fmall Quantity of Ore, or Coin. Axioms, By Axioms are meant a Kind of Corol- laries, Confequences, orRefults, of certain Ex- periments, Fadts, Obfervations, or particular Dodlrines ; fo as to recapitulate a certain ufe- ful T ruth, contained in the preceding Partof the Work, and fee it in a clearer Light, with re- gard to Theory, or Speculation •, As Canons, or Rules, regard Experience or Pradfice. See Canons . Balneum Mari^. Or W ater-Heat, is no more than a Velfel of Water, fet in a Furnace, or over the Fire, with another Vcfiel put into the Wa- ter *, which latter Veffel contains the Matter, or Subjedl, ol the Operation. Buddling Dtfljes. Are flaallow Dilhes, like the Balbns oi a Fair of Scales, for the wafhing of , Ores by the Fiand. Burrows, IX A GLOSSARY. Burrows, In Mining, are the Paflages leading into a Mine, and cut thro’ the Sides of a Hill, or Mountain, fo large that the Workmen may conveniently wheel out the Ore in Barrows, or carry it along in Bafl^ets. Calcination. Is the burning of a Body in an open Fire, in order to difcharge its more volatile Parts, or reduce it to Powder, Canons. Are Rules of Pradice, or Diredlions, for producing Effeds, or performing Ope- rations ; and have the fame Regard to Pradice, as Axioms have to Theory. See Axioms. Caput Mortuum, Is that Part of the Matter, which remains behind after Dillillation, or Sublimation. Cementation. Is the clofe burning of a hard or metalline Body, with certain opening Powders, flrew’d betwixt its groffer Parts *, fo as to foften, tinge, or impregnate them, with the PTmes of fuch Powders ; or it is the Introdudion of any Mineral, or Metallic Fumes into the folid Plates of a Metal, by Means of a proper Fleat, applied to a clofe Veflcl, or double Crucible, wherein the Plates are laid, with the pulverized Matter ftrew’d between them. Clarification. See Depuration. Concentrating, Is bringing the required Parts of a Subjed clofer together; as Salt-Water is concentrated by evaporating the aqueous Humidity ; and Wine by freezing out, or fe- parating its Water, in the Form ol Ice. Copelling^ or Cupelling. Is putting metallic Mat- ters upon a cover’d VelTel of Bone-Afhes in a naked Fire, to try v^hat Gold or Silver they will afford. Cryftallization. Is the Operation, whereby Salts dilTolved in Water fhoot into Glebes, of par- ticular X A GLOSSARY. ticular Figures, according to the Nature of each Salt. Decantation, Is the pouring off a clearer Liquor from a groffer Sediment, after ftanding. Defiagration. Is fetting explofive Matters on Fire in a Crucible, or other Veffel, and fuffering ' them to burn out ; as when Nitre, or Tartar, are thrown into a red hot Crucible, or to any melted Matter, whilfl it continues in the Fire. Depuration. Is the making of any Matter pure, of freeing it from the Drofs, Dirt, or other heterogeneous Parts, wherewith it may happen to be mixed : So Honey is depurated, or cla- rified, by heating it, and taking off the Scum that rifes to the Top. Bigeftion. Is fuffering folid and liquid, or groffer and finer Matters, to ftand together in a gentle ' Heat for fome Time, that the Liquor may ex- traifl the Virtues of the folid Ingredients; or the whole become more fubtile and uniform, Diftillation. -Is the raifing of Liquids into Vapour by Heat ; and condenfing that Vapour into a Liquid again. Elicofaccharum. Is an intimate Mixture of any effential Oil, with Sugar ; by grinding them together in a Mortar. Elements. See Principles. Elixation. Is the walking a Matter with Water, in order to get out what will diffoive therein. ' Emfyreuma. Is a naufeous Tafte, or Odour, proceeding from the Subject being fcorched, or over heated, in the Operation ; as when Milk is burnt to, as they call it. Ejjential., or Chemical Oils. Are the native Oils of Vegetables, drawn from them by Diftii- latlon with Water. Evaporation. XI A GLOSSARY. "Evaporation. Is the fetting a Liquor in a gentle Heat, to difcharge its fuperfluous Humidity, or obtain its dry Remainder. Faints. Are the Liquor that runs from the Still, upon diftilling any inflammable Spirit, after all the Proof-Spirit is come over. See Proof. Filtration. Is fuflering any Liquor to pafs thro’ Cap- Paper, or rather a peculiar Kind of filtring Paper, into a clean VeflTel, or Glafs ; the Paper being cut conically for the Purpofe, and put into a Glafs Funnel, or laid upon a Stone Co- lander, or Strainer. Form. Is the particular A6 lT. or Law of Nature, whereby a Thing' is produced. Flux. Is any Matter added to an. Ore, or me- tallic Matter, in order to make it melt, or run the eafier, and yield a greater Quantity, or a purer Metal. Fiilmination. Is the fame as Deflagration^ which feL Fufing. Is the fame as Melting, being a Term generally applied to the melting of Metals, and metallic Matters, with a ftrong Heat. Inflation. Is fuffering Matters to fland and di- gefl: in the Heat of the Sun, inftead of ufing the Heat of a Furnace. or Laque. Is a Kind of Extrafl, or thick Body of Colour, prepared chiefly from vege- table Subjefls, for Painters Ufe. Of thefe Laques there are feveral Sorts ; but in a more particular Senfe, it fignifies the 'Red Laque ob- tained by boiling Stick-Lac in Water. Lavaderos. In Mining, are the Houfes, or lar^e Troughs,' where the Ore is walked. Limation. Is the filing of a Metal, or metallic Subllance, fo as to reduce it into fmall Parts, called-the Tilings of that Metal. Lixivium. XU A GLOSSARY. Lixivium. Is the fame Thing as Lee, or a So- lution of Salts, by boiling any faline Matter in Water. Load. In Mining, is the fame as Ore. Lotion. Is the wafliing of a Body in Water, to get out its Salt, or whatever elfe will diffolve in Water. Low-Wines. Are a weak Spirit, or the firft Runnings of the Still, in diftilling Brandies or Spirits, from W^afh or "Wines, and mixed along with the fecond Running, or more watry Part. Meyifiruum. Is any Body applied to another, fo as to diffolve it, and intimately mix its Parts with the Parts of the other : in which Refpeft the former may be called the Solvent^ and the latter the Solvend. Mercury. Is another Name for ^ickfiher. Metallurgy. Includes the whole Art of working Metals from the Ore to faleable Metal. Muffle. Is an arched earthen Inftrument made to cover a Tell, in Cupelling, fo as that the Coals, or Affies of the Fire, may not fall in upon the Subjeft. See Cupelling. Mujt. Is the unfermented Juice of the Grape ; or any other liquid fermentable Subftance, be- fore it enters the A6l ot Fermentation. See Stum. LJeutrals^i or Neutral Bodies. Are fuch Bodies as manifeft no Signs of either Alkali., or Add., upon any of the Trials known, and allowed to difcover them •, as particularly not by the Tafte, or the Admixture of Syrup of Violets, kAc. See Acid and Alkali. Bcr Leliquium. Is the running of diffolvable Things into Liquor, by barely expofing them to the open Air, or to the moift Air of a Cellar. Phlegm. Is the fame as Water, or aqueous Li- quor. Pre- A GLOSSARY. Precipitation. Is the depofiting of a Sediment; either by a Liquor {landing at Reft, or when any Addition is ufcd for the Purpofe. Principles. Are the different fimple Matters, whereof a Body is compofed. Proof. In Spirits is meant of a certain Trial, or Way of examining their Strength, by the Bub- bles that arife on their Surface Uj-on fhaking them in a Phial. ^iartation. Is the Separating of Gold from Sil- ver, by Means of Aqua- Forth or Aqua- Regia. ^intejjmce Is the Mixture of an eftential Oil with Alcohol. ReAification. Is purifying a Subject, by repeat- ing the Operations ; as Brandy is purified, or feparated, from its Phlegm, by repeated Di- ftillation. ReduEiion. Is the reducing.^ or recovering a Metal from its Calx., or Afhes \ and may likewife be applied, when any Body deftroyed, as to its natural Form, or Appearance, is made to af- fume that Form again. Refrigeratory. Is a VeiTel of cold Water, thro’ which a winding metalline Pipe takes its Courfe, from the Plot Still, fo as to bring off the Liquor cool, by Diftillation. Regulus. Is an impure, or imperfedt metallic Subftance, that falls to the Bottom of the Cru- cible in die melting of Ores, or impure metal- lic Subftances. Scoria. See Slag Separating-Glafs. Is a bellied Glafs, open at top, and ending in a hollow Stem below •, fo that a Mixture of Oil and Water being put therein, and fuffered to reft till they feparate, the W ater may be poured off from the Oil. XlV A GLOSSARY. ^lag. Is the Drofs, Cruft, or Scoria^ found at the Top of a melted Metal, or metallic Mat- ter ; being often in the Form of a vitrified Mafs, or Giafty Subftance, and proceeding from the Flux employed, and united with fomc ftony recrementitious Matter contained in the Ore. But when a large Proportion of a faline Flux is ufed, the Slag will relent, or even diF folve in the Air. Solvent, See Menftruum. Stum. Is Mujiy clarified by ftanding and racking, then put up into matched Cafks, that is. Calks impregnated with the Fume of burning Brim- ftone, fo as to be preferved found in an unfer- mented State. See Muft. Sublimation. Is the raifing of a dry Body by Heat into Flowers, or a foiid Cake, at the Top ot the containing Veflel \ being a Kind of Diftil- lation fuited to dry Bodies. Suhfidence. Is the fuffering a Liquor to fettle, and fine itfelf, by ftanding. Sulphur, Is another Name for Brimftone *, but in a more Technical Senle, denotes the fat, un- (ftuoLis, or oily Principle in Bodies \ or that Part of them, which is truly inflammable. ^hc'nnometer . Is an Inftrument contrived to mea- fure the Degrees of Heat. Thofe made with Spirit of Wine, ferve for the lefTer Degrees, and thofe with Oil, or Quickfilver, for the greater. I’riture. Is the grinding, or rubbing any foiid Body to Powder in a Mortar, or upon a grind- ing, or levigating Stone. ^orrefadlicn. Is the roafting, or fcorching, of a Body by the Fire, in order to difeharge a Part cither unneceffary or hurtful, in another Ope- ration, A GLOSSARY. ration ; as Sulphur is difcharged from an Ore, before the Metal can be obtained to advantage. 'Turnfol. Is a red Colour prepared from the Juice of the Sun-Flower, and fermented Urine : which Colour being, in a fluid State, drank up by Linen-Rags, and dried, is the Thing fold by the Dry-Salters to the Dyers and the Wine- Coopers, for dying Cloths, and tinging Wines red. Vitrification. Is the turning of a Body to Glafs in the Fire. Wajh. Is the fame Thing as fermented Wort, or any fermented Liquor, fitted/to afford an inflammable Spirit, or Brandy, by Diftillation. x\r' TABLE [ xvi ] Table of C ON T E N T S. L E C T. I. Of Philosophical Chemistry. I . \ ^ Account of the Office and QhjeEis of Chemiftry Page i-6 2 'The chemical Treatment of Bodies 7-20 3 Rules for making new Dif cover ies 20, 21 4 The Deftgny and Manner of Execution i, 2 5 Philofophical Chemiftry defined i 6 The Objects of Chemiftry claffied 2 • 7 Bodies bow to be divided 8 General Structure of the Earth 9 Earthy in particular^ analyfed 6, 7 10 The Black Flux 8 11 Ores how analyfed B, 9 12 JVater divided^ and analyfed 9, 10 13 The Atmofphere divided^ and Air analyfed 10,1 1 14 Inftrmnents of Chemiftry 1 1, 14 ^ 15 The pbyfical Agents of Nature ibid. 1 6 The Kinds of chemical Oivifion 1 5 17 Fluickfilver fuhtilely divided ibid. 1 8 Brandy analyfed 1 6 19 Aggregates and Mix ts explained ibid. 20 Senfible Bodies compofed of infenfible ibid. 2 1 Recompofition illuftrated 1 7 22 ^ickftiver recovered ibid. 23 Relations^ and Changes ^ of Bodies 18 24 The Refolutions^ and Mixtures of Chemiftry ib. 25 The Produbiions of Mixture ibid. z 6 The phyfical Caufes of chemical Effebls 19 2 7 AJ- XVll Table of C O’ N T E N T S. 2 7 Advantages of improving Chemijiry 1 9 28 T' he general Subjects of all the Lebiures ibid. 29 Rules for condutling Philofophical Chemijiry 20> 2 I 3 o Axioms and Canons of the LeBure 22-24 L E C T. U. Of Fire. 1 Fire, 'what 25-27 2 Fluids expand with Heat 2 7 3 Fhree Species of Fire 28, 2^ 4 Fuel, what 29-31 5 Air necejfary to Fire 3 1 6 Air fpoiled by Fire 3 2 7 Fuel, how charred 33 8 fuperficial ibid. 9 Fhe Effects of Fire 34 10 Fhe Kinds of Heat 3 5 11 Fhe Degrees'" of Purity in Fires ibid. 1-2 The Degrees of Heat 36-38 13 Axioms and Canons 3S-41 L E C T. III. Of Air. 1 Fhe Atmofphere what, and how to he examined 42 2 Receives Vapours 43, 44 3 Fhe AiPs Prejfure and Elafticity 44, 45 4 Nature and EffeFis of the Atmofphers 46 5 thermometers explained, ibid. 6 Water in Air ^ 47 ? 4^ 7 Frejh^ Air required in Refpiration 48, 49 8 Air in Liquors • 49? 50 9 How far Air promotes Solutions I o Air in Solids ^ ^ 5 5 2 I I Axioms and Canons 53 - 58 - a a LECT. xvni Table of CONTENTS. L E C T. IV. Of Earth. 1 ^he Species of Earths 59'^5j 7i 2 Mould analyfed by Water 60-63 3 By Fire 63 4 into Clay 64 5 Pottery^ &c. improve able 65 6 Ffuicklime deprived of its Salt 66 7 Marcafites^ what 6y^ 6S 8 Mundick analyfed 6^^ 6g 9 Alab after calcined ^9? 70 10 reduced to two general Kinds 71 1 1 Axioms and Canons 7 1 - 74 L E C T. V. Of Water. 1 Water defined 75 2 Found in dry Bodies^ and the dry eft Air 75-77 3 Contains Earth 79 4 Its Properties^ Office, and life 80 5 Which the moft fertilizing 8 1 6 Its diffiolving Power ibid. ' 7 Its Contents ^3, 84 8 Common Water ex amhi d 85, 86 9 Mineral Waters ex aminA 87-89 10 Pyxmont. Water imitated ' 90, 91 IT Axioms and Canons 9 ^ - 94 - L E C T. VI. Of Menstruum Sr 1 Menftruums what ' 95 ^ 9 ^ 2 Fhe Menftruums of Nature 96 3 Fhe Powers of Water as a Menftruum 97-99 4 The XiX Table of CONTENTS, ne dijfohing Power of A\co\\o\ lOO 102 PLe difolving Power of Oil 102, 103 Phe Relation betwixt Oils and Metals 103, 104 Bread difiilled 104, 105 Lead atnalgamated 105? 9 Gold and Silver difj oh ed 107, 108 10 Aqua- fords, and Aqua-Regia, how made 108 11 Ufes of the Solution of Silver 108, 109 1 2 Silver^ how recoverable after Solution 1 09 13 Ufes of the Solution of Gold ibid. 14 The Digeftcr explained 110 15 Bone J opened by it "ibid. 1 6 Axioms and Canons 1 1 1 - 1 1 6 L E C T. VII. Cf Fermentation and Putrefaction. I Phe Nature^ Ofice^ and Ufe of Fermentation and Putrefadiion 117, &c. 2 PFine-t how made 118-124 3 Vinegar^ how made 124-127 4 Vappidity and PutrefadHon fucceed Fermenta- tion 128-130 5 Phe Changes produced by Fermentation 1 30, 1 3 1 6 Inflammable Spirit^ how procured 1 3 1 7 Proof in Spirits^ what 132 8 Sphdt of Wine y how obtained ibid. 9 Its Ufes 133 I o Vinegar yields no Alcohol ibid. II Piitrefadiion^ in Vegetables^ what 134 1 2 Its Ufe in Prade^ and in the animal 0 economy J 35 > *36 1 3 Animal Putrefadiion^ what 1 3 6 1 4 Fermentation determined 137 j 5 Phe Chemiftry of Nature in Bodies 138 a a 2 16 Mi- t 16 17 Table of C O N T E N T S. Mineral I’ermentaiiGn^ what 138 , 139 Axioms and Canons ^ 1 40 - 1 44 L E C T. VIII. Cf Analytical Chemistry. I Principle in Chemftry\ what 145 2 Wormwood analy fed 148-154 3 Bone analyfed 154 156 4 animal Principles purified 156-158 5 Cinnabar analyfed J59-162 6 Refult of the Analyfis of Minerals 162 y Axioms and Canons 162- 1 67 L E C T. IX. Of Synthetical Chemistry. 1 Synthetical Cbemijlry^ what 168, 169 2 Mitre analyjed and recompofed 1 69 • 1 70 3 Brandy analy fed and re compofed 172, 17 3- 4 Cinnabar recompofed 174-176 Bone recompofed 176-177 Perfect and imperfect Recompcfdion 179 y Axioms and Canons 1 80-18^ L E C T. X. Cf Vegetable Curation. 1 Vegetable Curation^ what 184, 185 2 T'he Prcccfs of Malting 1 8 5 - 1 8 7 3 Malting improve able 1 8 7 - 1 9 1 4 Vegetable Juu es how cured ^ 9 ^ * 93 3 Wort infpijfated ^ 93*^95 6 IP aft cured and preferved 195, 196 7 PerfeV Curation^ what 196, T9 7 ^ Axioms and Canons ^ 97 “ ^99 L E C T. Table of CONTENTS. XXI : LEG T. XL Of Wines and Spirits 1 Artificial Muft prepared 2 Sweets what , 3 "Tbeir Ufes 4 JVines how fined ^ ^beir Difeafes^ how cured 6 V/hite IFines, how tinged red 7 Wines concentrated by Frojl 8 Prick'd Wines^ how recover'd 9 Brewing for DiftillaHon }o Axioms and Canons Appendix. 11 Phe T'heory of vinous Fermentation 12 Practical Obfervaiions thereon L E C T. XII. Of Distillation. 1 Fiftillaticn^ what 2 Fhe Arts concern'd therein 3 Biftillation of Wafio 4 Proof-Spirit Fine- Stilling Retlfication of Spirits 7 Proof of Spirits 8 Cordial Waters^ how made 9 Compound Dijlillation improved j o Axioms and Canons L E C T. XIII. Of Oils and Salts. 1 Oils how exprefied 2 Effences how made 3 EJfsntial Oils 20I--203 203, 204 204—207 207--209 209 2 10 -212 212-214 214, 215 215-217 217 — 221 221—229 229 — 241 242 242, 243 244—246 246—248 248 249-251 251-255 ‘ 255 255, 256 257-260 262-266 266, 267 267 — 271 4 Effen - xxii 4 5 6 7 8 9 10 1 1 12 23 1 2 3 4 5 6 7 8 9 10 1 1 12 1 2 3 4 5 6 7 Table of CONTENTS. EJfential Oils, how adulterated 271-274 Empyreumatic Oils rectified 274-276 Sugar refined 276-278 Elccofaccharums . 279, 280 ’Tartar refined 280-282 Nitre r^ned 283, 284 Pot-AJh, how made 285-287 — Its Kinds and Ufies 286-288 Soap, how made 288, 289 Axioms and Canons 289-293 L E C T. XIV. Of Colours. ’The Prifmatic Colours 294-296 Colours how changed 296-305 The Prifmatick Colours imitated 305 Laques prepared 306-30S Carmine 307 The PrufTian Blue 308-310 Animal Colours 310-312 Metalline Colours 312 317 Callico Printing improveahle 313^314 The Indian Colours 315 Colours improved 3 H- 3*7 Axioms and Canons 3^7^319 L E C T. XV. Of the common Pharmacy. Hifiory of Pharmacy 321 - 3 M Simple Waters 325 328 Tinihires and Infufions 328-332 Syrups 332-335 Eleliuarks ■335-339 Oils, Unguents, Cerates and^Plaifiers 340-343 Axioms and Canons 343 > 345 LECT. Table of CONTENTS. xxjii , L E c T. XVI. Of simple Pharmacy. I 356 5 Alterants 357 , 358 6 Strengtheners 358, 361 7 Anodynes 361, 362 8 Regulation of Pharmacy 362-364 9 Axioms and Canons 364-366 L E C T. XVII. Of Mineralogy. 1 Requifites to Mineralogy 3 ^ 7"‘375 2 Roafiing of Ores 3 S tamping and Wajhing 3 8 o- - 3 8 2 4 Fluxes 3S3— 3S6 5 Axioms and Canons 3 ^ 7 - ' 3 9 r L E C T. XVIII. Of Metallurgy.- 1 Metallurgical Operations 392 2 AJfaying 393 " 39 ^ 3 Smelting 394 4 Variation 39 7- -400 5 Gold and Silver Ores affayed and /melted 397-400 6 Ores of Copper ^ Tin^ Lead^ and Iron^ how af- fayed and /melted 401—409 7 Brafs and Princess Metals how made 409, 410 8 Steely how made 412 9 Axioms and Canons ^ 41 2 --4 15 L E C T. xxiv Table of CONTENTS. L E C T. XIX. Of P Y ROTEC HNY. 1 Gunpowder^ how fyiade and tried 2 Pulvis Fulminans 421 --423 3 The firing Mixture of Iron and.Sulphur 423-425 4 Artificial Cor uf cations 425,426 5 A flaming Mixture of cold Liquors 42 7 --42 9 6 Solid and liquid Phofphor us 42 9 --4 3 4 7 Other Kinds of Phofphor us 4 3 4- - 4 3 7 8 Axioms and Canons 438,439 L E C T. XX. Of Enlarging Chemistry. 1 Chemiftry^ howdivifihle and improveahle 440-449 2 Sal- Ammoniac^ how made to advantage 450-452 3 Amber diffolved 452-454 4 A hard Glafs^ how made 454- -456 5 Silvering Amalgam ' 456, 457 6 A curious Glue . 457-^459 7 Copper advanced nearer to Gold 459--- 46 1 8 Rules for improving Chemifiry and Arts 461 464 9 Axioms and Canons 464, 465 IQ Conclufion 466, 467 LECTURE I. CONTAINING ^ I. An Account of the Office and Objects oj Chemiftiy. II. "^fhe Chemical Treatment of Bodies. III. Rules for making new Difcovcrics in the Art. I. 'HE Defign of thefc Lefturcs is M enlarge the Bounds of Chemiftry,y%;z. JL- by applying it to the Advancement of Natural Philofophy, the Illuftra- tion and Improvement of the known Arts, and the Difcovery of new ones. 2. In profecuttng this Defign we would fpeak The Man- to the Eye, rather than the Ear-, or indeed to the ner of Underflanding, rather than the Senfes ; and by 'means of appofice Experiments, fcientifically ex- plained, lead to the Difcovery of Phyfical Axioms^ and Rules, of Pra 5 Uce for producing ufeful Ef- feds, in the way of a Philofophical Chemiftry. 3. Philofophical Chemiftry we define, a rational Philo/o- Arc of (i) dividing or refolving all the Bodies/»^^>^^ within our Power (2) by means of all the Inllru- ' ments we can procure 5 (3.) as well into integrant as confticuent Parts j and (4.) joining thefe Parts together again ; (5.) foas to difcover the Pfinciples, Relations, and Changes of Bodies; (6.) make va- rious Refolutions, Mixtures, and Compofitions ; (7.) find out the phyfical Caufes of phyfical Ff- fe6ls; and (8.) hence improve the State of natural Knowledge, and the Arts thereon depending. B 4. To 7he Ob- je^s of 2 . Lecture the First. TheBu/t' 4. To explain this Definition, in a concife general manner, is the Bafinel's of our firft Lee- ^ ture \ and to illuflrate it fully, will be the Bu- finefs of all the reft. 5. Our Definition confifts of eight Parts ^ the firft whereof regards the Ohjefls of Cbemijlry, (i.) Thefe Objefls are all the Bodies within our Power. We fhould therefore, if it were pradti- Chtmifry, take a particular View of the Contents of the terraqueous Globe. To.abridge the Labour, we fhall Tingle out the more capital and ufeful Sorts *, and range them in fome Order, by way of Specimen, or Sample, of that grand Repofitory of infinite Materials The Produdlions of the Earth are divided into, I. Minerals. II. Vegetables^ and III. Animals. I. Minerals are fubdivided into (i.) Metals and their Ores, (2.) Salts, (3.) Sulphurs, (4 ) Stones, (5.) Earths, and (6.) Semi-metals. Cl ASS I. The Metals are. Gold, ^ CJafed. II. ^ickftlver. Lead, Silver, Copper, Iron, Lin. Salts. Ranged according to their fpe- cific Gravities, and compared with their Ores refpedtively. Alum, Artificial Salt, Bay Salt, Borax, Nitre, Rock Salt, or Sal Gem, Sal Ammoniac. ^ In the Courfe, a Set of Specimens v/ns exhibited, in conformity v/ith the following Lift, III. SuL- Of Philofophical Chemifry. III. Sulphurs. Amber ^ Arfenic^ ubhite ^yellow ^ and redy Auripigmentumy Bitmneny Brimjioney Commony — Native y Coaly Jety PetreoL IV. Transparent Stones. From the Dia- Ranged according to their mond to C Hardnefs, which is their Cri- CryJiaL 3 terion, as Gravity is of Metals. 'V, Opafce Stones. Alahajlery AmianthuSy Emeryy Flinty HamatiteSy Loadjloney Marble y and Porphyry y Lapis Calaminaris y Talcy Tripoli y &:c. VI. Earths. Boky Chalky Marly Grey Ocrey Ruddle y Terra Lemniay &:c. VII. Semi-metals. The Vitriolic are, Vitriol y green and blue, viz, of Iron and Copper; JVhite Vitrioly with other foreign kinds. "Vlll. The Sulphureous Se M i-M E T A Ls are, Antimonyy ^ifmuthy ) B 2 Cin- 4 Lecture the First. Cinnabar^ native^ Mundick^ Pyrites^ Zinck^ &c. II. Vegeta BLEs are divided into Herbs ^ Berries^ Flowers^ Fruits^ Grains^ Seeds ^ Roots y Barks y Woods y Juices^ and Excrejccnces, Qlafs^, Herbs. Angelicay Baulmy Hyjfop^ Ro‘ Jemary y Lavender y Sage, Fan- fyy Fhymey JVormwoody &c. II. Berries. Bay Berries y Coffee y Kermesy Ju- niper y &c. III. Flowers. JaJmiUy Saffrony Lillies ^ Mari- ^ goldsy RofeSy Elder-Flowers y Violets y Flowers of Broom y Holly -Oaky &c. IV. Fruits. Cocoa-NutSy Nutmegy Jamaica- Peppery Long- Peppery Fama- rindSy Caffia FfulariSy Pome- granate y &c. V. Gr A I N s. Ricey Indian Wheat y SagOy Millet y&cc. VI. Se e ds. Beecb-mafty Cardamomy Gran. Paradif Mufiard- Seedy Sun-jloser Seedy &c. VII. Roots. Alkane ty Galangaly GentiaUy Liquo- rice y Madder y Orris ^ Furmericky^c. VIII. Barks. Caff ay Cinnamon y Clove-Barky Cor- tex Peruv. MacCy Oak-Barky Winter's Barky &c. IX. Woods. Cedary Guaiacumy Logwoody Rho- diumy SaunderSy &c. X. Juices are fubdivided into natural, and ar- tificial ; or into FcarSy and infpiffated Juices. Fears y or natural Juices, of the Sycamore, the Birch, In- Of Philofophkal Chemipry. 5 Jnfpijjated Juices z.xt ^widitd into (|.) Gums^ (a.) Baljams^ (3.) Rofins^ and (4.) Sugars. (i.) Gums. Aloes^ Gum Arabic., AJJa Fcetida., Am^ moniacum^ Benjamin^ Bdellium^ Galbanum^ Qamboge^ Majlich^ Myrrhs Gum Elemi^ Opopanax^ * Gum SandaraCy Gum Lac^ Cum Tragacanth^ Xr. (a.) Bal3AMS. Balfam Capiviy Qpobaljamumy Balfam of PerUy TolUy ^c. The turpentines y Wax^ &c. XII. (3.) Rosins. CamphirCy Frankincenfey Rofm of Guaiacumy Roftn of Jalaps Scam- monyy Burgundy Pitchy Common Rofiny Sang. DraconiSy kffc. Xni. (4..) SuQARS. Honey y Mannuy Sugary &c. XIV. Excrescences. Jews EarSy Agaricky Mf^toBy the MoJfeSy Gallsy See. III. Animals. Clafs 1. Entire Animals., AntSy BeeSy Cantha- ridesy Cochinealy MUlepedeSy ViperSy See. II. Their solid Parts Boney Hart*s-horny Ivory y Cuttle BonCy Elk's Hoofy Human Skully Caftory See. III. Concreted Animal Juices. Goat's Blood and human Blood dryedy Lardy Marrow y Sperma Cctiy Sec. TV. Excrements. Albwn Gracumy Civet y Musky Pigeon's Dungy Silky Sec. 6. Bodies have been ufLially confidered uudev Bodies three general Clafle^, called by the Names of Vegetable, Animal, and Mineral Kingdoms. Divifion is, perhaps, too fcanty ; as excluding tnany Particulars of the marine and atmofpherical Regions. For in the Sea are found Coral, Shells, Spunge, Bitumen, Ambergreafe, Mixtures of B 3 Salt, 6 7he gene- ral Struc- ture of th< Barth, Barth in particular Lecture the First. Salr, Slime, Ficculencies, and the corrupted Parts of Fifli, 13 c. which may pofilbly be irreducible to any of the three Kingdoms. And the At- mofphere abounds with Air, Light, Water, Me- teors, Exhalations and Effluvia of the Earth, dif- ferently combined ; fo as not to appear diftindlly either of a Vegetable, Animal, or Mineral Na- ture. 7. The OhjeBls of Chemijlry^ therefore, are taken from the three larger Mafles, or Regi- ons, of the Globe ; viz, the Earthy Water and Atmofphere 8. Our Knowledge of the Earth reaches but a little below its Surface. So far as Men have ^dug, it appears a Compages of numerous folid Siibffances, ranged in a diforderly manner ; which may be phyfically necefflary, to afford different Partitions, or Beds, of Soil, Gravel, Clay, Stone, Coal, Marcafites, Ores, Gems, i 3 c, each ferving as a Matrix to the other. q. By Earth is commonly meant the Soil, •Mould, or Coat, wherein Vegetables grow. This Coat, which is but of little Depth, is the dire6t and immediate Seat of Vegetation. And with this Earth we chufe to begin our Experiments *, propofing (i.) A general Analyfis of Garden Mould; (2.) The ‘Preparation of a general kind of Flux, for the affaying of Ores. (3.) The general Method of affaying Ores for their Metal. (4,) A general Analyfis of common Water. (5.) A general Analyfis of the Air. (6.) A general Example of the Method of reducing Bodies to their integrant Parts. (7.) A general Example of refolving Bodies into their conftituent Parts ; and (8.) An Example of Reduffion, or the Me- thod of recompofing, or recovering. Bodies after Solution. IJ. Of Philofophical Chcmifry. 7 II. Ex PERIMENT I. 'The Analyfis of Garden Mouldy begun. 10. We took two Pounds of frefh, black rich Garden Mould, and flirred it well in Quarts of fair Water, gently warmed, then letting the grofTer Part fettle to the Bottom, we liltred the Liquor thro’ Cap-Paper ; and found that it pafled confiderably muddy, or impregnated with the finer Parts of the Earth *, which it would not eafily depofite upon many Days (landing in a quiet Place 11. The Defign of the Experiment is to ob- tain a proper Liquor for difcovering the Mat- ter which .the Earth affords to Plants in Vege- tation, or the natural Juices, and natural Salts,- of Garden Mould •, becaufe nothing feems capa- ble of rifing in Vegetation, but what is foluble in moderately warm Water, and will pafs the Pores of Paper, fomewhat in the fame manner as it does the natural abforbing Veffels, or Strai- ners of a Plant. Whence the filtred Liquor of our Experiment may be examined by chemical Treatment ; as by Evaporation, or the way of trying Mineral Waters^ &c. as we fhall fee here- , after in our fourth Ledure. 12. Ores are the next ufeful Species of Earth the general Treatment whereof, for obtaining their Metal, depends upon the Ufe of the Bla^ Flux. * See this Experiment carried a greater length in teif. IV. Exp. I. and II. B 4 Ex- 8 Lecture'the First.., Ex PE R I ME NT II. The Method of making the Black Fluic^ for the af- d faying of Ores/^ 7he Black 1 3." We took onc Part Nitre, and two Parts FUx. common Tartar*, and reducing each to Powder, we mixed them together, and deflagrated the whole in a Crucible, by lighting the Mixture a-top ; which thus turns to a kind of Alkaline Coal^ that is to be pulverized, and kept in a clofe Glafs, to prevent its diflfolving, as it would do in a moifl: Air. 14.. This Flux is of general Ufe ; "and to have it ready at hand, fhortens the Bufinefs of making Affays in Metallurgy ; and renders the Operation more exadf, than when crude Tar- tar and Nitre are employed ; becaufe the De- flagration might thus carry off iome Part of the Ore, and defraud the Account. For the fame Reafon, the Mixture is here diredled to be fired a-top*, otherwife a confiderable Part might be Joft in the Deflagration ; which would prove much more tumultuous and violent if the Matter was thrown into a red-hot Crucible. Experiment III. ^he general Method of analyfing Ores, Ores ana- tyfed. 15. We took two Ounces of Copper Ore re- duced to Powder, and mixed it, in a Mortar, with twice its Weight of the black Flux ; then, in a Wind Furnace, fufed it brifkly, that it m.ight run thin, for about four Minutes : when, fufFering the Crucible to cool, we broke it, beat off the Slag, and weighed the Metal. 16. This Experiment ihews the Method of treating any unknown Ore, to difcovcr, in the way 9 Of Philofophical Ch&mijiry. way of Aflay, or Proof, the Kind and Proportion Metal it contains. 17. The of the Effedl depends upon Rath- Separation of the terreftrial, fulphurcous, or other heterogeneous Parts of the Ore, ‘which are here cither vitrified, or otherwife detained by the Flux-, whofe Property it is to vitrify Earth in the Fire, and ftrongly join with Sulphur; at the fame^ time that it does no: alter the' Metal, but leaves it to its own nature ; whence, by its fuperior Gra- vity, it finks pure to the bottom of the Crucible -, as being now made fluid, and fet free from the heterogeneous Parts before mixed in among \ia), c 18. TFater is generally divided into frit Water di- frefli, with regard to the Ocean and Rivers*. But it Teems divifible into as many different Spe- cies, as the Earth is into Beds. Thus there arc Mineral Waters of various kinds, according; to the Mineral Subftances they run over, and become impregnated with: tho* this Impregnation fome- times happens in the way of Vapour, or Exha- lation. Water, therefore, in the general, may be as mixed a Body, as Earth in the general ; and perhaps neither of them naturally exifts in any confiderable Degree of Purity h). Experiment IV. A general Analyfts of common Water, 19. (i.) We found that common warm Water Water throws up numerous Bubbles, and explodes, in analyfeL the exhaufted Receiver of the Air-Pump ; and therefore contains what may, by way of diftinc- tion, be called .®ther or Spirit, <2/ See the Left, on Metallurgy. b) See Ua. V. (2)lt ID Th^ At- fnnfphere dinjided. The Air anahfed. Lecture the First. (2.) It contains a merely aqueous part, diftind from ^ther, and from the Sediment'; as appears in diftilling common Water, (^3.) It contains a dry folid Matter, which is either earthy or laline, as appears upon a full Evaporation; and alfo from the Infides of Tea- Kettles, which, after long Ufe, are lined with a flony Matter, that beats off in Flakes or Cruds. 20. That Water is accounted beft and whole- fomeff, which is lighteft, moft fpirituous, and freed from earthy Sediment ; and thefe Properties are ufually found in pure Rain Water: this being naturally diftilled, or raifed by the Sun’s Heat, from the Ocean and Rivers, into the Atmofphere, and from thence returned again, much after the manner of common Diftillation a), 21. The Atmofphere is a kind of dry Fluid, no lefs effential to the Earth than the moift one. It Teems as heterogeneous as the Earth or Water, tho’ more rarified. It is diffimilar in its Parts, like the Body of the Earth ; and has fomething analogous to Beds, or particular Portions abound- ing with different kinds of Effluvia, according to the Differences of the Countries and Places over which it extends. Thus over Mount Mtna^ or other Vulcanos^ it muff neceiTarily be impregnated, after the manner of certain Mineral Waters, with the Fumes of burning Minerals ; over the Ifland Ceylon^ with Aromatic Effluvia ; over London with the Smoke of Sea- Coal h)^ Experiment V. A general Analyfn of the Air begun. 22. A proper Analyfis of the Air, or any inte- grant part of the Atmofphere, has hitherto fcarcc been attempted. It) Sec LeSi. V. b) See Lcdi. III. (l.) That Of Phitofophkal Chemtjlry. i i (i.) That it is an elaftic Fluid appears by its diftcnding Bladders, and breaking Glaffes, in the cxhaufted Receiver of the Air-Pump. (2.) That it is eflential to Life, appears by Animals dying without it. (3.) That it may receive invifible In- fluences or Alterations, as well as vifible Effluvia, appears from its becoming poifonous by paffing thro’ Fire ; and by its containing grofsSmoak, and the fine Particles of fermenting or putrefying Bodies : And (4.) that it is naturally a Com- pound, appears by the Water it depofites in dry- Salt of Tartar ; and by its changing the Colours of various Bodies, iSc. 23. We fhall hereafter attempt a more particu-- lar Analyfis of the Atmofphere^ in order to a Choice of the beft Places for Flealth, Habitation, and the Exercife of particular Arts; on account of certain Properties in certain Places, arifing from the different Mixtures, or Compofitions, of the Air in different Parts a). 24. The Inftruments of Chemlflry are all thofe^^^ we can any way procure b). There are feveral Inftruments continually at work, for the im- mediate Produdion of Effcdls, in the three larger Maftes, or Kingdoms, bf the Globe, viz, the Fdarth, Water, and Atmofphere. We evidently find, that Metals and Minerals are formed within the Earth; Vegetables on its- Surface, fhooting into the /\ir ; Meteors in the Atmofphere ; and Men, Beafts, and Birds in the Confines of the two : The Phyfical Caufes of all which are to be diligently fought out, as fo many Rules ofPrafUce, 25. The principal phyfical Agents in Nature appear to be, (i.) Heat. (2.) Cold. (3.) Air, the integrant Parts of the Atmofphere. (4.) Wa- . ter. And (5.) proper Beds, or Matrices, This is a) See LcB, III. P) See above §. 3. Matier 12 Lecture the First. Matter of dired Obfervation ; and might occa- fion the eftabliftiing of the four common Elements, Fire, Air, Water and Earth. The Sun. 26. (j.) T\iQ Sun is the principal Source of Heat upon the Earth’s Surface, and the Con- fines of the Earth and Atmofphere. Without this, all the Bodies upon our Globe would doubtlefsgrow rigid, lifelds, and fixed. ’Tis this that ftirs within them, as the main Spring of their Adions. -Hence Vegetation, and Animalization, are evi- dently promoted ; and hence the Ocean and the Atmofphere continue in a fluid State a ), C$ld. 27. (2 ) Cold is correlative to Heat ; and tho’ perhaps no more than a lefs Degree, or Abfence, thereof, yet has, in the natural State of things, an inftrumental Efficacy *, as in the condenfing of Solids b )j the coagulating of Fluids c J, the fepa- rating of Salts d)^ Spirits e)^ ^c. And by means of Cold and Heat, ufed alternately, it fhould feem that fome capital Operations of Nature are per- formed, efpecially in the vegetable Kingdom, by the Reciprocation of Day and Night, Summer and Winter/). 28. (3.) Air, or any integrant Part of the At- mofphere, is an elaftic Fluid, that expands with Heat, and contrads with Cold ; fo as apparently to generate Motion, and produce Effeds. It ani- mates Fire, and has a great Influence upon the Life of Animals : it alfo mixes in among, and unites itfelf with. Bodies ; fo as to conftitute a ma- terial Part thereof I*/ It is the great Receptacle of 0) See Le^^i. II. pajjim. h) Which are rarified by Heat, but contrafled by Cold, e) As aqueous Liquors into Ice. d) As Salt i§ feparated in the Freezing of Salt-Water. e) As Spirit is ieparated in the Freezing of Wine, uri- jious Spirits, and diililled Vinegar. f ) See Le^. III. p) See Le^. Lil. Effluvia Of Philofophical Chemifry. 1 3 Effluvia from the Earth, the Matrix of Meteors, the continual Support of Birds, Beads, Plants, and Men ; and is in fome degree nutrimental a). is not only contained in the Earth, jfTater, as in a Refervoir, but likewife floats in the At- mofphere. In both Cafes it is actuated, ratified, and put in motion by Heat *, fo as to prove indru- mental in producing Effedls. Thus it produces Clouds, Rains, Dews, Springs, and Rivers. It refrelhcs the Earth, recruits Vegetables, and is the Support of Fifli and other Animals, by convey- ing Nutriment to all their Parts. It is alfo the fird and immediate Inftrument of Fermentation, Putrefaction, Corruption, and Change, in all ve- getable and animal Subjeds^j. 30. (5.) Proper Beds, or Matrices^ alfo appear Matrias, to have an indrumental Agency in the Production of natural Bodies. Every SubjeCt of an Operation is ncceflarily contained in fomething that ma^ (i.) afford it a Lodgment, (2.) make fome Re- fidance, and (3.) convey to it Heat, Cold, Water, or Air, or determine their ACtions upon it. Thus in Vegetation, the Matrix Earth fupports the Seed, refids its Swelling, and conveys a drained, or prepared, Moidure to it. The Ma^ trices of Gems and Ores not only afford a proper Lodgment to the SubjeCt-Matcer, but alfo refid its Growth, by the Preffure of their Sides ; which, however, give way a little, and at the fame time drain and convey fuitable Juices to the SubjeCf. And fomething of this kind is obferved of the Fcctus in Utero^ the Hatching of Eggs, ^c, info- much that Clofenefs, moderate Refidancc, or a flow yielding of the Sides of the Matrix, and a draining of the Juices through them (unlefs fup- a) As it adds to the Subftance of Vegetables and Animals. See Mr. V tgetable Staticks, and hereafter III. b) See Uff. VII and XII. 14 Lecture the First. plied from within^ feem requifite for the Forma- tion and Produdion of all Vegetable, Animal, and Mineral Subftances. Whence we are furnifhed with a capital Rule for the Improvement of Che- miftry, natural Philofophy, and Arts; and taught that, in order to imitate Nature, Chemiftry mud not be confined to the foleUfeof Fire, as its In- ftrument, but occafionally employ Water, Cold, Air, Earth, and proper or Veflels. Artificial 31. natural Inftruments^ there Infiru- is a great Variety of artificial ones belonging to Chemiftry, which feem to raife the Power of this emijry, fome refpeds, above the Power of Na- ture. Thus, by means of particular Menftriiums, it performs Operations which Nature of herfelf does not: for inftance, of all the Metals, only Iron and Copper are found naturally converted into Vitriol ; whereas Chemiftry makes Vitriols even of Gold, Silver, Tin, and Lead. And hence the Produdions of Art may be much more nu- merous, than the Produdions of Nature ; indeed they may be increafed at pleafure, to the great En- richment of Arts, and the Enlargement of the Kingdom of Man a ). Vejfehy ^2. Another Set of Inftruments belonging to ^tenfih' Chemiftry are V^fiels, Furnaces^ and Utenftls -, of which there is a great Variety, for different Pur- pofes, and capable of producing numerous Changes in Bodies, by Amalgamation, Cementation, Fufion, Fermentation, Putrefadion, Redudion, Cfc. AnenjuSit, 33. We add to the above-mentioned a new Set, viz. The Air-Pump^ the Condenfor^ Bigeftor^ Microfcopes^Burning-Concaves^ Prifms^ Lenfes., Por- table Furnaces and every other Inftrument that can be invented, or procured, of advantage to the Art. a) In this Light may the numerous Produftions of the Chemical Trades be confider’d ; fuch as the Elfedts of Fer- mentation, Diftillation, Dying, Soap making, the Art of ■ Glafs, Metallurgy, iAc. 34. There Of Philofophical Chemijlry. 15 24. There are two capital Ways wherein Che- miltry divides its Subjeds, by the feveral Inftru- merits above-mentioned; viz. mto integrant Parts, and into conftituent Parts. By integrant Parts we underftand fimilar Parts, or Parts of the fame na- ture with the Whole ; fo Filings of Iron have the fame Nature and Properties as Bars of Iron. Un- der this general Operation, fall thofe particular ones of Triture, Filing, Solution, Amalga- mation, Sublimation, And by confiituent Parts^ we mean diflimilar Parts, or Parts of a different Nature from the Whole ; as when arti- ficial Cinnabar is divided into Quickfilver and Sul- phur : and under this general Operation come all kinds of Analyfes or Refolutions. ^ Ex PERIMENT VI. A general Example of reducing Bodies into their in- tegrant Parts, 35. We took an Ounce of Quickfilver in fmall Glafs, and poured upon it two Ounces Aqua fortis ; then fet the Glafs in a Sand- Heat to warm’: red Fumes fcon appeared ; and the Mer- cury, or Quickfilver, difappeared. We added a Difolid Rod of the fame Metal; then heating that End in the Fire till it was red, and applying it to the Ring, we found the Rod fo fwell’d, that it would not now enter the Hollow which it fitted exadlly . when cold. 10. This Experiment dire6Uy ftiews no more than that Iron expands upon being heated ; but as it has alfo been found to fucceed in many- other Solids, it may be made general, till the contradictory Inftances are produced in the way of Exceptions a ). ' Experiment II. Hhat Fluids expand with Heat, 11. We filled the fpherical Cavity of a bellied Glafs, having a long and {lender Neck, at three different times, with (i.) Mercury, (2.) Water, and, (3.) Spirit of Wine, to the fame height ; then plunging the Glafs, fucceifively, into Wa- ter (kept in the fame Degree of Heat, in all the three Trials, as appeared' by a Thermometer) we found that each Fluid fwelled very remark- ably, or rofe up to a confiderable Height in eij Cedar Wood has, upon fome Trials, been thought not* to expand with Heat, or contrad with Cold. the 28 ‘Three Kinds of Fire, Celejiial, Zuhterrei* neous. Culinary, T'he Sun''s Heat, Tlhe Purity tf the Sh»s H eat, Lecture the Second. the Neck of the Glafs, above what it flood at betore the Glafs was placed in the hot Water. 12. This Experiment feems to hold of Fluids univerfaily : fo that tor the prefent we may allow the Motion of Expanfion, or Rarifadion in Bodies, to be infeparable from Heat, or Fire in the general. II. 13. We proceed to confider xh\s general Fire in its three Kinds, viz. Celejiial^ Subterraneous.^ and Culinary. 15. By Celejiial Fire we principally mean that of the Sun, without regard to the Fire of the fixed Stars ; tho’ this perhaps may be of the fame nature. 15. By Subterraneous Fire we undcrfiand that which manifefts itfelf in fiery Eruptions of the Earth, Vufcanos, or burning Mountains ; and by any other Etfecls it produces in Mines, or the more central Parts of the Earth. 16. By Culinary Fire we mean that vulgarly employed in all Chemical Operations, and the common Occafions of Life. 17. The Sun’s Heat appears to be the aduat- ing Principle, or general Inflrument of all the Operations of Nature in the Animal, Vegetable, Atmofpherical, Marine, and Mineral King- doms a). 18. Confidered in itfelf. Fire feems to exifb in greatefl: Purity and Perfeflion in the Celeftial Regions ; at leaft we are not fenfible of any Smoke it yields : for the Rays of Light come to us from the Sun, unmixed with any of that grofs, terreftrial Matter found in Culinary and Subter- raneous Fires. But allowing for this Difference A ) See LiSi, I. i^. the of Fire. 29 the Effe6ls of the Solar and Culinary Fire ap- pear to be the fame. 19., The Effe6ls of Subterraneous Fires will alfo Suhter- be found nearly the fame with thofe produced ramous by Culinary Fire. Burnt Coals, Cinders, and ap- melted Minerals are thrown up by Vsfuvius^ and other Vulcanos. Warm m.ephitical Exhalations, natural hot Springs, Steams, Vapours, Smoke, Cfr. are found in feveral parts of the Globe, riling much in the fame manner as if they were produced by the Heat of a Furnace. Whence it can fcarce be doubted that Subterraneous Fires are of the fame nature with the Culinary. 20. And as all the three kinds agree in giving the Motion of Rarifa6lion to Bodies, it feems no way improper to reduce them to one; or to ha^e a ' quit, for the prefent, the Celeftial and Subterra- near A. neons, and keep to the Culinary Fire, which 'i^gneement, more within our power, and every where ready at hand to be employed in Experiments. 21. All Culinary Fire requires fome Pabulum Fuelnvhat, or Fuel, wherein it either refides or is collected. A leading Experiment therefore, in our prefent Enquiry, is the Analyfis of Fuel; to difeover its conlfituent Parts, and learn which of them is more immediately adapted to receive or propa- gate Fire. Experiment III. Fhat Oil is ejfential to Fuel. 22. We put a Pound of common Billet-Wood, AkadUr reduced to fmall Pieces, into an earthen Retort, Expert-"^ and diftilled v^ith a naked Fire into a large Glafs Receiver. There came over(i.) an acid Water, (2.) a redifh tart Liquor, (3.} Smoke, and a grofs 3 © ‘That Coals Qnxe their Injiamma- hility to OIL Lecture the Second grofs, black, burnt Oil. The fire being made and kept up ftrong at lafl, no more Liquor or Oil afcen'dedi but (4.) a black Matter, exadtly refembling Charcoal, remained behind: this being taken out and burnt in the open Air, fell into Aflies ; which by Diffolution in Water af- forded (5.) a little fixed Salt, and (6.) an earthy Subftance. 23. This Experiment appears to be general, or to fucceed alike in all Wood, Coals, or folid Fuel. We feparated the acid Water or red- difli Liquor from the Oil by the Filtre ; and then found that thefc aqueous Liquors would not burn in the Fire ; no more would the Afhes, the Salt, or the Earth, either fingly or in compofition : fo that of all the Subftances thus obtained from the Wood, the black Coal and the Oil are the only inflammable ones. But the Coal remains inflammable merely upon account of the grofs Oil ftill lodged and clofely locked up therein, and according to its peculiar nature, fcorched, or turned black by the Heat employed in the Operation. " 24. If farther Evidence be wanted toprove’that the Oil remaining in the Coal gives it its Black- nefs and Inflammability; let it be confidered, (i.) That all fcorched Oils turn black; and that the more volatile Oil, which here comes over into the Receiver, is black. (2.) That no other part of the Wood, feparated by the Analyfls, is in- flammable, befides the black Oil ; not the Coal itfelf after it is become white or reduced to Afhes by open Fire and Air, which is an Ope- ration fufficient to diflodge the grofs black Oil, that could not be raifed by a lefs F'orce. (3.) That no other chemical Caufe can well be af- figned for this Blacknefs and Inflammability. (4,) That Wood, Pic-Coal, prove lefs imflam- mable. of Fire. 31 mable the more they are deprived of their Oil. (5.) And laftly, that the Calces of Metals, ren- dered abfolutely uninflammable by Calcination, appear to attrad this Oil out of burning Fuel, fo as thence to recover their inflammable Prin- ciple and true metalline Form a). 25. But without farther Proof we may ven- ture, for the prefent, to conftitute Oil the foie Principle, or inflammable Matter in f uel ; and on this footing it will be proper to reduce our Enquiry to the more oily Species of Bodies, and make our Experiments chiefly upon thofe. Experiment IV. That Fire will not confume Fuel without the Ad- mijjion of Air, 26. Having exadtiy fitted a hollow Cylinder of Iron with a ftrong Skrew at each end, we in- cluded a long Piece of Charcoal in the Cavity ; then fkrewing both ends tight, we detained the Cylinder in a ftrong Fire for feveral Hours; letting it afterwards cool and taking out the Charcoal we found it ftill black and no way ap- parently confumed, altered, or diminifhed. 27. This Experiment, compared with the com- mon Obfervation that Fuel burns and confumes quickly in the open Air, fhews that Air is ne- ceflfary to the Cor.fumption of Fuel; or that its burning and confuming depend upon the Rari- faefion, Diflodgment, brifle Agitation, and Dif- charge of the Oil it contains ; which is the phy- ^ fical Caufe of the Effecft. And hence we have the a) Let proper Trial be made, whether the fixed Oil cannot be feparated from powdered Charcoal by a ftrong Lixivium of Pot-afti and C^icklime, fo as to form a Soap, or otherwife exhibit this Oil to the Eye. See Lett. XVJIL 22. reafon 32 Lecture the Second. reafon of the known Rule or Method of extIn- guifhing Fire by fmotheriiig it, or keeping it clofe from the Air. 28. But that the bare Motion of confined Air, or its pafTing feveral times through lighted Fuel, is not capable of confuming it, appears by the following Experiment. Experiment V. ^hat Air which has pajfed thro" Fire , or ignited Fuel^ is unfit to animate Fire again, 29. We caufed a wooden Box to be made, perfedly clofe and tight, with Glafs Windows on the fides. At the bottom of this Box was a Per- foration exa6lly fitted with a hollow wooden Plug, that joined to a tight leathern Pipe. This Pipe at the other end communicated with the Clack of a pair of Fland-Bellows, the Nofe whereof entered at a Hole on one fide of the Box *, fo that by this Contrivance it was eafy to draw the Air out of the Box into the Cavity of the Bellows, and return it into the Box again, without admitting any other Air befides that originally contained in the Box. We now fet a little Cha- fing-Difh of live Coals in the middle of the Box, and fccuring all the Joints tight from the exter- nal 7 \ir, wc plied the Bellows ; which, indead of increafing foon totally extinguillied the Fire ; tho’ the Coals were by no means burnt to Allies, but remained black and frefh when cold. 30. Hence it is manifeft, that even a bridt Motion of fuch Air as has already paffed through burning Fuel, is fo far from animating, that it deadens or quenches Fire a)^ in the fame manner a ) Let ,a proper Experiment be devIied, to fbevv what Al- teration the Air fufrirs by painng through Lire. as of Fire. 3 3 damped or fmothered ; the Oil of the Fuel not being carried off for want of frefh Air. ^r. This method of damping Fuel, or fuffer- ing it firft to burn a little and then extinguifhingc^«rr^ /« //- feverally into an Air-Pump Receiver, and haufling the Air obferved numerous Bubbles to arife and efcape from each Liquor, burfting upon its Surface. 28. And in like manner is Air difeharged from Liquors by boiling them over the Fire : This is pradtifed upon Water, in order to make See LeA. YU.paffim, E it 50 Lecture the Third. it alTord Ice without Blebs or Bubbles ; and a- gain upon Oil defigned for "Thermometers^ &c. But fuch Liquors as have b.en thus dil'charged of their loofe Air, will be found to recover it again by (landing open ; as if loofe Air were a natural Ingredient in Liquor. Experiment VIIL l.hat the external Air may promote Solution. 29. We ftt fome Spirit of Sal Ammoniac and ^ 7 tes 7 lu- Copper-Filings in vacuo^ and compared this with tion. a like Parcel Handing for the fame time in the open Air : that in vacuo had not coloured its Menflruum, whilft that in the open Air afforded a rich blue Tincture. Hence it appears that the free Accefs of the external Air may promote Solu- tion in fome Cafes ; where it feems to a6l by increa- fing the Motion or Adion of the Menflruum. Experiment IX. That the external Air does not promote Solution in all Cafes. Tetin 30. Upon two Drams of whole Crab’s Eyes fome Cafes poured in vaciio two Ounces of diftilled Vine- gar, having firft boiled it to get out the Air. A great Ebullition was immediately produced, the Gage funk, and Air was generated. 31. Upon comparing this with the fame Expe- riment made in the open Air, we found that the Ebullition was much greater in vacuo than in the open Air. 32. Hence we learn that Air may be generated upon the mixture of certain Bodies, where it did not appear before. 33. But Of Air. 5 1 35. But Experiments of this Kind muft be made with Caution; the Quantity of Air thus ge- nerated in fome Cafes being able to raife tiie Re- ceiver, and throw it to a confiderable Diftance. 34. There is wanting an Account of all the Mixtures that will produce Air in fo violent a Degree ; among them may be reckon’d Oil of Vitriol with Oil of Tartar per deliquium.^ Fortis with Iron Filings.^ Spirit of Nitre with Oil of Carawa)\ Cfc. 35. And thus Air may be generated betwixt Solids and Fluids, and betwixt Fluids and Fluids, by bare Mixture. The following P^xperiment will' Ihew that Air may be extricated out of Solids, and that it makes a conftituent Part thereof. Experiment X. Fhat Air enters the Compofition of Solid Bodies, 36. We put a Piece of hard Tallow into. an Iron ^irin So- Retort with a long Neck ; then laying the krge'^^^^* End of the Retort in a naked Fire, the fmall one being plunged into Water, wediftilled in the ufual Manner, and obferved that large Bubbles of Air continually role and difcharged themlelves thro’ the Water into the Air of the R.oom. At length ceafing the Operation, and collebling all the vi- able Matter either left behind or come over into the V/ater, we found a very confiderable Lofs of Weight, owing to the Air having been feparated or forced by the (Irong Heat from the reft of the i Tallow ^ I 37. If it be obje6led that the Lofs of Weight [might, in great Meafure, be owing to the Iron of !iche Retort, which when hot has the Property of drinking in Oil or Tallow ; it may be obfer- ' * The Experiment was not made with requifite Care and ; Caution. E 2 ved. 52 Lecture the Third. ved (i) That the Effe 61 : is nearly the fame when an Iron Retort is employed that has been ufed for the fame Operation before *, (2) That the Ex- periment anfwers proportionably when made in Glafs i (3) That other Bodies befides Tallow, particularly Hartfhorn, Bone, Tartar, yield plenty of Air, when treated in the fame manner *, (4) As there is fo large a Quantity of Air- Bubbles difeharged in the Operation, and as Air is proved to be a ponderous Body a the Lofs of Weight may be fairly attributed to the efcape of the Air. But (f ) a proper Gage may be contrived to determine the exad Proportion of the Air thus feparated, with refpefl to the original Matter or Subjedl employed b), 3S. This Experiment is of great Importance in Natural Philofophy and Chemiilry. When fully verified and duly profecuted it may fhew (i) that all natural Bodies confifi: of a very large Proportion of Air, as one Part of their original Compofition ; (2) That Air is neceflfarily required to the Formation and Growth of Animals, Ve- getables and Minerals; (3) That when Bodies are diffolved or refolved a great Part of them turns into Air again ; as when a Candle is burnt or Fuel confijmed ; or as when Vegetables, Ani- mals and Minerals ferment, putrety or corrupt ; or as when Bodies are chemdcally analyfed or treated by Heat. 39. (4) That the Matter which in the Diflilla- tion of Hartfhorn, Tartar, and many other things explodes and puffs thro’ the Luting, or fome- times, when confin’d, burlls the Glafifes or Vef- fels, is the Air fet free by the Fleat. a) See above, Exp. II. b) See Mr. Hale'$ Vegetable Static:, under ehe Analyfis of the Air. 40. Of Air. 40. (5) That the Air thus naturally conden- fed, confined, and intermix’d as a conftituent Part in Bodies, has a great Share in their Diflblution *, for being violently ratified it breaks the parts in pieces and flies off, 41. ( 6 ) But leaving the Experiment to be further verified, and made general, if capable thereof, we fhal! anticipate no more, but pro- ceed to reap the Fruits of the prefent Enquiry, II Axioms and Canons derived from the Enquiry, 1. We learn from,the preceding Enquiry that the Atmofphere, confidered as a Whole, and a- gain as confiding of an infinite Number of Ingre- dients, is the Phyfical Caufe of numerous Effed:s5 not only in the Air itfelf, but likewife upon the Surface of the Earth, in the fubterraneous Regions, 'in the Exercife of numerous Arts, and particularly in Chemical Operations a'). 2. That it is the phyfical Office and Ufe of the Atmofphere to affift in raifing the Vapours and Exhalations of the Earth h\ and to ferve as a general Matrix for them c), wherein they are all blended together and fermented, or fome way changed in their Nature, fo as to perform new Offices, or recruit the vegetable, animal, and mineral Kingdoms, when fuch enriched Vapours fail back again in Rain or Dew to the Earth d), 3. That it is the Nature of Air to infinuate itfelf into Fluids unite and fix in Solids, fo as 'a) See above, Exp.ll. III. IV. V. VI. VII. VIII. IX. X, b) See Ex{>. I. c) See Leil. I §. 16. al) See §.25, 26. ief alihi pajjlm, i) §. zj, 28. 54 Lecture the Third. naturally to make a conftituent Part of both a), 4. Hence may be conceived, in general, how all the Changes happen in this great Chaos the At- mofphere ; viz. according as floating Particles of different Kinds chance to meet, fo as to form confiderable Aggregates or Colledions ; and ac- cording as thele are favoured by the requifite De- grees of Heat, Cold, Drynefs or Moifture. So, for example, a Cloud of nitrous Spirit meeting with a Cloud of oily Particles might fuddenly pro- duce Corrufeations, as in the mixing of Spirit of Nitre and an eflTential Oil i?). And in this man- ner may the Generation and Phenomena of all the Meteors be chemically explained. And thus the Occurfions of various Parts of different Bodies in the Atmofphere may be the Caufe of the Me- teors, fiery Winds, Explofions, Thunder, Light- ning, the Aurora Borealis, and other Phsenome- na, which vve can imitate by certain Mixtures, in the way of Philofophical Chemiflry c). 5. That the Atmofphere is an univerfal In- ftrument, in the Hands both of Nature and of Art, for producing Effedfs, whether on the Surface of the Globe, in the Bowels of the Earth, in the Air itfelf, in the Laboratory, or in other human Works d). Thus it caufes Fire to burn, and Bellows are but Engines to convey it thereto. 6. That as Air defeends, and adts m.ore forcibly in the iubterraneous Regions, on Account both of its greater Denfity there, and of the fubterraneous §. 27, 28, 56, 37, 38. h) See Exp. I. c) See Mr. Lemerys Philofophical and Chemical Explana- ticn of Subterraneous Fires, F.arthcuakes, Hurricanes, I’hun- derand Lightning, in the Frc 7 ich Memoirs, Anno 1700, See the whole Le^ure See alfo LeSl, I. • Heat ; Of Air. ' - 55 Heat; hence Vulcanos and more violent Fires may happen there than upon the Earth’s Surface a). And poffibly this greater Heat and Power of the Air below is necefTary to the Produdion of Minerals and Metals h), 7. Hence we may learn the phyfical Caufe why in the open Air diftilled aromatick Oils lofe their native Spirit, grow thick, and terebinthinate; why Wines grow flat or lofe their Brifknefs ; why pale volatile urinous Spirits grow red; why Mi- neral Waters lofe their Virtue; and how Air has in all refpedls a powerful Influence upon Liquors ; as being a dry Fluid in brifle Motion, whereby it eafily lays hold of and carries off all the moft fubtile and volatile Parts of Fluids, leaving the grofler behind, and thus changes the Texture, Colour, and Confiflence thereof c). 8. That the Atmofphere is, perhaps, the mofl compounded and diflimilar Mals in Nature ; confifting of an elaftic Part, and the Vapours and Exhalations arifing from all the folid and fluid Bodies of the Globe, Salts, Oils, Minerals, Metals, Cfc. d), ' 9. That the Air is the Caufe of numerous Ef- fe6i:s, ill aferibed to other Cauf^s by the ancient Chemifls, who for want of the Air-Pump and other Contrivances, were ignorant of the genuine Properties and Effe6ts of the Air e). 10. That the component Parts of the Atmo- fphere are coarfer than thofe of Fire. For the a) See LeSi. II. b) See above, Exp. X. See alfo the tenure on Metillurgy hereafter. c) ^t&Exp. I. VI. IX. k §. 18. d) See Exp, I. tSc. e) See£^v^. Ylll.IX. X. E4 com- 56 Lecture the Third. component Parts of the Atmofphere will not pafs thro’ Glafs a). Stones, Metals, &c, as Fire does. Alio Water, Lixiviums, Oils, pafs where Air cannot •, as we fee in Bladders, Wet-Leather of the Air-Pump, &c. Hence the Air may be arti- ficially excluded from many Bodies. I?). 11. That the Atmofphere is continually at work upon all the Bodies Subjedl to its Power, in the way of a Menftruum; whence Iron Handing in the open Air is corroded •, imperfedl Glafs dif- Iblved ; Salts and Sugars run into Liquor •, and the Bodies of Animals, Vegetables and Minerals prey’d upon r). 12. That there is a continual Reciprocation betwixt the Earth and the Atmofphere *, they mutually diftilling, as it were, or throwing off Matters from one into the other. Thus the Earth, by the Sun’s Hear, fublimes fome Parts of all things into the Atmofphere, and the Atmofphere again precipitates them to the Earth d). , 13. That the different Succefs of Chemical Operations may be greatly owing to the parti- cular Vapours or Effluvia floating in the Labo- ratory where fuch Operations are performed f). Thus if Salt of Tartar be run per deliquium^ wlaere Vinegar is diftiliing, it becomes regenera- ted Tartar ; a thing very different from the in- tended Oil. 14. As Air always adheres to the Surfaces of Bodies, and as the Surfaces of Bodies are enlarged by pulverizing them /) i when we would exclude cT^, See Exp. II, III. V!I. VIII. IX. 1) See Exp. II. III. VII. VIII. IX. c) See Exp. I. II. V. VI. VII. VJJI. IX. Se^ alio below, Jx. 20 . d) See Exp. J. Sc Le^. I. fojjlm. f) See Exp. I. /) bxExp.lL Air Of Air. 57 Air in Chemical Operations, the Subjed Ihould not be pulverized. 15. That the open Air has a powerful Effica- cy in many Chemical Operations, efpecially in Mixture a\ where it often adls mechanically by its Weight and Motion ; as in the mixing of Oil of Turpentine with Salt of Tartar, which does not fucceed in mcuo^ or in high mountainous Places. 16. That the Accefs of Air is not neceflary to certain Fermentations, or Ebullitions, and Solu- tions •, fome of them proving more violent in vacuo^ than in the open Air h ), 17. That no Degree of Cold, or Condenfa- tion, has hitherto been able to deprive Air of its Fluidity, or render it confiftent c). If there were fuch a Power exerted in Nature, it would deftroy all Animals and Vegetables, and perhaps flop the Growth of Minerals a), 18. By comparing the prefent Enquiry with the preceding, it appears that Fire cannot fepa- rate Oil from Bodies, without the Admiffion of the free Air. Whence in the roaffing of fulphure- ous Ores, or obtaining of white Afhes from Bones or Vegetables, we are direded to ufe an open Air, as well as a naked Fire. 19. That the Air is in a Kind of perpetual Motion e). Whence it performs all thofe natu- ral Offices, that cannot be performed in a Va- cmm. Thus leaven’d Paffe will not ferment or rife, nor Wine work, nor Fleffi putrefy, nor Fru:t corrupt, after the ufual manner, when placed in vacuo, a) See Exp VIII. b) See Exp, IX. A See IV. d) See Exp. VI. & X. e] See Exp. I.&IV. SzsslIHqAx. 12. & 17. 20. That 58' Lecture the Third. 20. That as all kinds of Particles naturally float in the Air a), the Air may on this Account aft as an univerfal Menftruum, and in time dif- folve any Body expofed to its Adlion ; becaufe, in tradtofTime, the Particles capable of difiblving it mufl: neceflfarily come at it I?). 21. That many Arts may be a(Tifl:ed, or car- ried on to better Advantage in fome places than in others, by the means of certain Particles floating in the Air of one Place more than ano- ther. Thus ’tis faid that the Scarlet Dye is better (truck at Leyden^ than in other Places of Hol- land^ where the Water and Atmofphere are not fo impregnated with the Effluvia, Exhalations, or line Particles of the Dye c). 23. Hence alfo we are directed to chufe pro- per Seats for Health, and Habitation, as well as for Operations and the Exercife of Arts d). See Exp. I. Sc alihi pajjtm, b) See Jx. II. f) ScQ Exp. I. & alibi pajjim. d) There are various Methods of trying the Wholefomenefs or Un wholefomenefs of Airs and Places ; as by finding their Degree of Moifture feveral ways ; by the Changes of Colour produced in white Linen, or ftained Paper, left out in the Air ; by expofing Copper-Plates to (hew the Colour of the Vitriol thereby made ; and many other Expedients might be contrivM tor that Purpofe. [ See Mr. Natural Hiftory of the Air.] LEC- [ 59 ] LECTURE IV. CONTAINING The Solid or Earthy Matters of the Terrefrial Globe clajfedy and examined^ under (i.) Garden Earths (2.) Bolar Earths (3.) Saline Earths ; (4.) Sulphureous Earths ; . (5.) Stony Earths ; and^ (6.) Metallic Earths. I. TXT E now come to enquire into the Sub- y Y earthy Contents of the Globe \jeei. more particularly into the Parts concerned in Vegetation. 2. We fhall begin with the Earth’s Surface, and defeend down gradually, fo far as Men have hitherto dug. 3. The Earth’s Surface is generally found Upper vered with Verdure, or a Vegetable Coat, znd Coat of in fome Places with Sand, Duft, or Mud. the Earth, 4. Under this fuperficial Coat there ufually lies a Bed of Mould, or Underturf-Earth, of different Depths, from one Foot to two, three, or more, in different Places. (1.) This Mould, or Underturf-Earth, is the proper Matrix of Vege- tables, and will come to be firfl: examined in Order. 5. We fhall next proceed to the other Spe.c\ts The Species of Earths that lie beiow, viz. (2.) the Bolar -^of Earths. (3.) the Saline ; (40 Sulphureous; (5.) the Stony ; and (6) the Metallic. For under thefe fix , 6o Mould a- naiy fed by Water. Lecture t h e. F o u r t h. fix general Clafles, we apprehend, may all the earthy or folid Matters of the Globe be ranged. 6. It will therefore be our Endeavour to give a general Example of the Method of treating every Species, fo as to difcover their Natures, Offices, and Ufes. Experiment I. 7 he farther AnaJyfis of Gar den- Mould or Underturf - Earth hy Water a). 7. (i.) We took four Pounds of freffi, black , and crumbly Garden-Mould, that was efteemed the bed fort, and had lain, for a Year, expofed to the Atmofphere, without being exhaufted in Ve- getation. (2.) This Mould we elixated in fair and freffi boiling Water, till all that was capable of diflbl' ving therein was got out or extracted by the Water, (3.) Having thus obtained a Lixivium or So- lution of our Subjedl, we filtred it thro’ thick doubled Paper, in order to have it tranfparent, and at lead free from any grofs terreftrial Parts, that might otherwife lodge therein. (4.) This Solution, therefore, contains all the Parts of the Subjedt that are foluble in boiling Water h). (5.) To bring thefe Parts nearer together, that they mighr manifeft themfelves to the Senfes, and particularly to the Tafte, v/e exhaled away the more aqueous Fluid in the Form of Vapour. ' (6.) Then comparing the concentrated Solu- tion, with a Portion of the former that re- a) See Lebt. I. Exp. I. b) SeeZfO?. J, Exp. 1. mained . Of Earth. 6 1 mained unevaporated, we found it tafte mani- feftly Wronger or more faline. (7.) To gain a fuller Information, we evapo- rated a Portion ftlll higher, and fet it to cry- ftallize, if any Salt would fhoot a), (8.) To a Part of the filtred Solution we ad- ded Syrup of Violets, to djfcover whe- ther the Solution was acid, alkaline, or neutral ; and found it rather the latter h). (9.) We wafhed the remaining terreflrial Matter in feveral Waters, every time decanting the upper muddy Liquor, after a little (landing, in order to procure the pure Sand contained in the Mould ; and found the Sand to be a large Pro- portion of the whole. 8. This Experiment, or rather Combination of Experin)ents, fhews us a Method of refolving the matrix Earth of Vegetables into the confti- tuent Parts thereof, without altering their natural Form and Properties. Whence it fliould feem that a true Judgment might be formed of Moulds, both in general and particular, fo far as this Infor- mation reaches, and a Rule be obtained for their artificial Mixture or Compofition. Thus we find the Mould under Examination contains a certain Proportion of fine Earth, capable of being fuf- pended in Water ; much more of a grofler hea- vier Part that readily finks in Water \ perhaps a little neutral Salt •, and a large Proportion of Sand. Hence if this Mould had come from the Ifland Ceylon., for inftance, having there ftrved for the Growth of Cinamon, we might be directed by this Analyfis to make or mix up a Mould that fnould refemble it, with a View to produce Cinamon *) The Succefs was not carefully noted. h) See the Method of examining Mineral Waters^ in the following Ledure, ' in Lecture the Fourth. in England. But to make the Experiment fuccefs- ful, no Ids Regard muft be had to the State and Ingredients of the Atmofphere, than to the State and Ingredients of the Soil a). 9. To render the prefent Experiment more in- ftrudive and ufefal, for dilcovering the Prin- ciple of Vegetation, and the Nature of Earths and Plants, it were proper to compare it with a fiiiiilar Analyfis of certain vegetable Subjeds. Thus by bruifing a tender Plant, elixating ail its foluble Parts with warm Water, exhaling the fuperfluous Moifture, and letting the Remainder to cryflallize, we obtain the native faline part of the Plant, in the form of a folid Salt, which appears either of the tartareous or nitrous kind, according to the Nature of the Plant b). 10. Tho’ any alkaline Plant, as CrefTes, were v^^atered in its Growth with a Solution of Nitre, which upon Diflillation affords much acid Spirit, the Plant would ftill prove alkaline : and the fame holds of every Plant and Salt hitherto tried c). Whence there appears to be in Plants a Power of changing any other Salt into their own. And hence we find, upon Experience, that Compofls abounding in Sea-Salt, Nitre, or urinous Salts, all agree to promote Vegetation. 11. But as there may be certain more fixed Parts naturally contained in Mould, than will diffolve in boiling Water *, and as thefe Parts may pofTibly be loofened, digefted, and rendered capable of afeending into Vegetables, by the a) SeeZ^^. Iir. d) See M. Homberg cn the Nature of Vegetable Salts. Memoir . de C Acad. An. 1699 . c') I could wi(h the Experiment were tried with Sugar, Alum, Pot-Alh, tAc. both in Alkaline and acid 'Vegetables. But Care (hould be taken not to ufe too much of the Salts, which in that Cafe would deftroy the Nature of the Mould. long- Of Earth. 63 long-continued Adtion of the Sun and Atmo- fphere •, it may be proper to try a more powerful Analyfis of the fame Subjedt. ExPE RI ME NT II. ^he Analyfis of Garden Mould by Fire, 12. Having weighed two Pounds of the Fire, kind of Virgin* Mould as was ufed in the prece- ding Experiment, we put it into an earthen Retort, and committed it to a naked Fire, working by flow Degrees of Heat into a Glafs- Receiver ^ and at lafl; keeping the Retort ignited for fome time. There came over (i.) a Water ; (2.) an Oil; and (3.) a volatile Spirit almofl: like Spirit of Hartfliorn, or as if the Subject: had been animal * ; and (4.) there remained behind a dry Caput mortuum^ or apparently fixed and inert Earth. 13. We elixated Part of the Caput mortuumy and then dried it; by Triture we reduced ano- ther Part into one fimilar, homogeneous Pow- der ; with a defign to put each Parcel into a (e- paratq Pot, and expofe them to the open Air, for a Year, to try whether they would then prove fertile. 14. It appears by this Experiment, that our Garden-Mould was of a Vegetable or Animal Nature, in refpedt of the Salts or Juices it con- tained ; and only Mineral, with regard to its fixed Matter. In both which refpedls it greatly refem- bles the natural Compofition of Animals and Vegetables. And hence we fee the phyfical Reafon, why animal and vegetable Subflances * If it be fuppofed, that the CompoO, which might have been ufed to this Mould, was not fufficiently rotted or chan- ged, fo as ftill to retain its own vegetable or animal Na- ture ; let the Experiment be repeated with Earth, which has been known to have lain feveral Years fallow. are 64 Loam made into Clay. Lecture the Fourth. are proper Compods for Land. If we were to enquire how Mould comes to be of this Nature, it might in good Meafure appear from our for- mer Doctrine of the natural Contents of the At- mofphere *, which being animal and vegetable, as well as mineral, continually fall upon the Sur- face of the Earth. And hence Gardeners find a manifeft Difference between the Soil of London that of open Country Places, on Account of the Quantity of Smoke daily precipitated out of the Air upon the Gardens of London. And the like is to be underftood of other Cities and Countries refpe6tively. i^. By comparing the prefent Procefs with the fame performed upon a vegetable, an ani- mal, and a mineral Subdance ; it appears that one fimple fixed Earth is the Bafis of all animal, vegetable, mineral, and earthy Matters *, or the true Stamen^ Support, and Skeleton of Flefh, Bone, Wood, Metals, and Earths, i^c. being in itfelf of a fixed unalterable Nature. 1 6. We next proceed to Bolar F.arths^ which feem divifible into two Species, according as they are more or lefs tenacious ; in which view Lca 7 n and Clay may reprefent them all. And even thefe two feem only to differ in refpecSt of the Finenefs or Coarfenefs of their component Parts, which renders them more or lefs tenacious, ding- ing, or adhefive. Experiment III. Lhat Finenefs of Parts in Earths may give Cohefion^ Strength., and Solidity. 17. (i.) We mixed common Loam into a Mafs with Water, and then dry’d it ; to lliew that, compared with Clay, it would eafily break, crumble, and fall into Powder. But (2.) beating fome Of Earth. 65 fame Loam fine in a Mortar, and mixing it well with Water, it clung like Clay ; and when dry’d, adhered much more tenacioufly than before. 18. This Experiment not only fhews that Popery Loam and Clay, or all the Bolar Earths, are hence im^ nearly the fame thing, when their component pro 331- E) See Becher^s Ehyjica Juhterranea paffira. |. f) See Exp, I. k. II. a) Sec all the Experiments, e") vSee above, § 5, 26, 38. 74 Lecture the Fourth. in itfelf the moft fixed and unchangeable Body iij Nature a). 9. That a high Degree of Trituration, or re- ducing the Particles of certain Bolar Earths, Clays, and ftony Earths to an extreme Finenefs, may contribute to the Improvement of the Art of Pottery. For which Purpofe, Trituration, Sifting, Subfidence in Water, and Decantation, might be ufed to advantage i?), 10. That the making of Lime may be im- proved for the Purpofes of Building, Manure, and Water-Works, by a due Choice of the Ma- terials, and a fuitable Calcination c). 11. That fome confiderable Ufe and Improve- ment might, with proper Skill and Application, be made in the Bufinefs of Marcafites and Mun- dicks ; Bodies ufually efteemed as Refufe, and intradable Stuff d), 12. That Marcafites, by attradmg the Moi- fture of the Air, may be the efficient Caufe of fub- terraneous Fires, hot Springs, Damps in Mines, Mineral Waters, d), 15. That the Matter of Metals may poffibly lie loofe, immature, or unconcoded in certain Mineral Matters, fo as in the Fire to fly away with the Sulphur, or other Parts of the Mineral ; unlefs detained, and brought to greater Perfec- tion either by Nature or Art d), 14., That Fire may have the fame Effed as Air or Time, on certain ftony Matters, and ^lake them loofe, crumbly, and incoherent e), а) See § 15. б ) See Exp. Iff, c) See Exp. IV. § 25. Exp VI. § 3^. d) Exp. V. e) Exp. V'. & § 35. LEG- [ 75 ] L E C T U R E V. CONTAINING ^ Natural and Chemical Examination of Waters, I. prefent Bufinefs is the Chtmicdl The Suh- I J Examination of Waters ; with a view><^?- to manifeft their Natures, their Ufes to the Earth, and all vegetable, animal, and mine- ral Subftances ; but particularly to Man, fo far as we can difcover them. 2* By the general Name of Water we under- Water de^ ftand.an extremely fluid, limpid, infipid, andA^^* inodorous Liquor. This Definition is obvious, and taken from the dire6t Teftimony of the Senfes ; but by enquiring phjlofophically into the Nature of Water, we fhall find it pofTelTed of many unexpected Properties. Experiment I. That Water is contained in many folid and^ to ap- pearance^ dry Bodies. 3. We took a Piece of the hardefl: and dryefl: Found in Bone we could procure, and diftilling it in an Earthen Retort with Degrees of Fire, obtained a very large Proportion of Water, along with much Oil, and volatile Salt * See this Experiment farther profecuted in Le£i, VIII, Fxp. II. 4. This 76 Lecture the Fifth. 4. This Experiment holds true even of the oldeft Hartlhorn^ the dryeft and hardeft Woods, Earths, and pulverized Stones. Whence if ap- pears, that Water may lie concealed in folid Bo- dies, and make a conftituent Part thereof; as we formerly fliew’d of Air a). For we do not here mean that Water infinuates itfelf into the fuper- ficial Pores of Bodies, as Wood, Skins, Leather, Parchment, Strings, &c. fo as to fwell them in moift Weather, and leave them fhrunk in dry ; but that it remains permanently intermixed as an efTential Ingredient, or Part of folid Bo- dies, as in Stone, or Brick after baking, Of this we gave an eminent Inftance in our laft Ledlure b), where we fhew’d that Gypfum^ with Water, prefently concreted to a ftony Hardnefs. 5. If any doubt fhould arife, whether the Li- quor obtained from the Bone in our Experiment be truly aqueous, we might fhew it to Satisfadion, by feparating the Oil, and turning all the volatile Salt contained therein to Sal-Ammoniac, by Means of a fufficient Quantity of Spirit of Sea- Salt ; then redifying the Liquor by repeated Di- ftillation, and bringing it over in Form of a pel- lucid, infipid, and inodorous Fluid c), 6. It ; Lea, III. Exp. X. h) Exp.w. cj To purify this Liquor abfolutely, is a very laborious Talk; but as fome of the firft Drops come over limpid, and almoft infipid, ber'bre the Oil and Salt begin to rife, this may af- ford a ftrong Sufpicion that the fucceeding Drops are alfo aqueous, only mix'd with Oil and volatile Salt. For tho' the Bone were ever fo thoroughly dried by the Fire, and the VelTels employ’d ever fo free from Moiilure, a large Propor- tion of the aqueous Liquor would ftill be obtained. Befides, the foul and fetid Liquor has been fo far cleared from the volatile Salt and Oil, as to appear limpid, and prove infipid. Of Water > 77 6. Ic is therefore certain, that all Vegetables, and even the moft folid Parts of Animals, natu- rally contain a large Proportion of aqueous Pluid, or adual Water, in their Compofition ; and that it remains in them unaltered in its own Nature, fo as, when fet free, to refume the Form of Wa- ter, after having been detained, or circulated therein for numbers of Years. Whence it fhould fcem, that Water pafles thro’ all Natural Bbdies, unchanged either by Accretion, Growth, Appo- . fition. Fermentation, Putrefadion, Digeftion, Diftillation, being chemically recoverable again from Vegetables and Animals, Wines, Vinegars, and Spirits. ExPE R I ME N T II. *That JVater may be collefled from the dryeft Ah\ or in the hvtteft Climate, 7. (i.) We put half a Pint of common Water h the dry- into a cylindrical Glafs, wiped perfectly dry on Mr, the Outfide ; then added to the Water, two Ounces and three Quarters of pulverized and dry Sal-Ammoniac. We now ftirr’d them brifkly to- gether ; whereupon the Water floating in the ex- ternal Air was, by the Coldnefs thus produced as the Salt diflblved within, condenfed on the Outfide of the Glafs, and trickled down in fmall Veins into the fhallow Bafon fet underneath to receive it. and inodorous. And as it approached nearer to common Water, after every Rectification, there is no doubt but, if a fiifficient Quantity were procured, it might by Degrees be brought exactly to refemble common Water, diftilled and treated in the fame Manner. But the eafieft Way is to im- pregnate common Water with the Oil and Salt of the Bone ; fo as to make it refemble the Mixture that comes from the Bone into the Receiver upon Diftillation. See more to this Purpofe in Le^. VIII. Exp, I. <5 14. 8. This 78 ^he Expe riment extended and op“ plied. Lecture the Fifth. 1. This Experiment holds in all Climates and Places, of whatever Heights, where it has been tried. Whence, by the Law of Indudion, we may make it univerfal, till any contradidtory In- ftance appears. Thus therefore it may hold in the moft parched Countries and hotteft Seafons, fo as to afford an agreeable Method of cooling potable Liquors, and rendering them morerefrefh- ing. For if the Glafs containing the Salt and Water be fet in any Liquor, the Liquor will be- come cooler as the Salt diffolves. And if any confiderable Improvement could be made in the Contrivance, it might ferve in fome Meafure to fupply the thirfly Traveller in parched Defarts, and Sailors with frefh Water at Sea : nay, it has been a Pradlice among the latter to hang out Fleeces of Wool on the Sides of the Ship over Night, and to fqueeze frefh Water out of them in the Morning. 9. The fame Experiment, being carried higher, affords us a Method of procuring a Degree of freezing Cold, in the hotteft Countries, at all Seafons of the Year. For if a Quantity of dry and pulverized Sal-Ammoniac be feparately in- cluded in one well-clofed Glafs, and a proper Quantity of common Water in another, and if both thefe Glaffes be put into the firft Solution, whilft the Salt is diffolving, both the confined Salt arid Water will foon acquire the fame De- gree of Coldnefs as the firft Solution ; and being then taken out, and mixed together, they will form a fecond Solution much colder than the firft. And thus by repeating the Experiment twice or thrice, with frefh Salt and Water, a Degree of freezing Cold may be foon obtained in the hotteft Climate. E X P E R I- Of W ater. Experiment III. That an Earthy Subjlance is naturally contained in Water, 10. (i 0 We filled three fcveral Glafles with pure Rain Water, Spring-Water, and Water, and let them ftand clofe covered for fome Days before they were exhibited : there was an earthy Sediment then depofited in all three, but moft in the Thames -^ the Seditnent whereof was not only larger, but alfo more foul and muddy than in the Rain-Water; tho’ here alfo it was dirty, perhaps becaufe not carefully colledcd : whereas in the Pump-Water, it was white, fcaly, flaky, and fhining, like fine Spangles of Talc, 11. This Experiment alfo is univerfal, fo far as it has been tried with Care, and holds true of the Waters of all Species and all Countries ; particularly in thofe called Mineral Waters, from which an earthy Subftance may ufually be preci- pitated by Art, in a confiderable Proportion : For Example, by the bare Addition of Salt of Tartar. 12. Certain Experiments carefully made, and repeated, Ihew that the terreftrial Matter natu- rally contained in Water, has a principal Share in the Growth and Increafe of Vegetables ; all the Plants that thrive in Water, appearing to en- large their Bulk in Proportion to the earthy Matter furnifhed by the Water. Whence pure Elementary Water feems but a Kind of Ve- hicle to convey this nutrimental or fubftantial Part, and depofite it in the Veflels through which the Water moves, in order to its general Exit at the Surface of Vegetables Yet we are not here * See Dr. Wood-ward^ Experiments to this Purpofe, in the Philofo^hical Pranfaokns, 79 Water cemtains Earth, tQ 8o Lecture' the Fifth. to exclude the Inftrumental Efficacy of the two other Elements, Fire and Air. Now this appear- Office and Jng to be the general Office of Water, in the whole Vegetable and Animal Kingdoms, viz. the Con- veyance or Diflribution of the alimentary Matter to all their Parts, it may be proper to confider its Phyfical Properties, which wonderfully fit it for this Office. 13. The Figure of its component Parts ap> ties pc^rs to be fmooth and fpherical, like thofe of Quickfilver, whence it becomes extremely move- able and penetrating. Thus it readily enters the Pores of Wood, Leather, Skins, Chords, Mufical Strings, ^c. and thus it likewife becomes ca- pable of moving and agitating Particles of Mat- ter lefs a6live than itfelf, and fo proves the more immediate Phyfical Agent of Fermentation, Pu- trefadlion. Solution, And thus it alfo con- veys earthy and faline Matters thro’ our Filtres of Paper, Stone, ^c. and even raifes fome Propor- tion of them in Diftillations. 14. Its Particles likewife appear to be ex- tremely minute, and fo to have a large Share of Surface. Hence Water is admirably^ fitted for a Solvent, or for readily entring the Pores of Salts, and coming into full Contad with all their Par- ticks. And thus it will pafs, where Air cannot, on Account of its Moiflure, or lubricating Power, whereby it foftens mucilaginous Matters, and will therefore foak thro’ the clofe Pores of a Bladder. And being thus qualified, it feems ex- tremely well fitted to enter or flide thro’ the fine ' Canals and Vefiels of Plants ; fo as to convey nutritious, faline, or earthy Particles along with Itfelf ; and having depofited them by the Way, and being now robbed of all that is ufeful to the tndivkluais, it at length perfpires into the open Armofphere, in order to be there recruited and fitted of Water. • , 8i fitted for frefli Service. And the fame kind of Office it performs in Animal Bodies. 15 . Hence we may learn the phyfical Reafon ihatofRi- why River- water is more fertilizing than Rain, viz. becaufe it contains more earthy Matter •, and why fuch Meadow and Failure Lands, as lie commodious to be overflowed by muddy Rivers, yield greater Crops than fuch as are watered by other Means. Hence the incredible Fertility of Egypt appears to proceed from the turbid Overflowing of the Nile., and the fame is- to be underflood, in fomeDegree, of other Rivers, as the Ganges the 'Thames^ &c a). Experiment IV. "That Water faturated with one Body will (till dlf- folve another. 16. (i.) We took four Ounces of pure cold fyd'tJJoU Rain-water, and diffolved therein as much dry common Salt, reduced to Powder, as it would Rower of take up. The Salt ufed being Part of a known Quantity, we weighed the Remainder, to find precifely how much had been employ’d, and found it about an Ounce-, which therefore gave the Meafure of the Power that the Water had to diflTolve common Salt, with the Degree of Heat then prefent in the Atmofphere. To this fatu- rated Solution of Sea-Salt we added about' two Scruples of dry pulverized Nitre, and found that itdiflTolved therein, tho’ no more common Salt could be taken up by the Vv ater. 17. This Experiment is only particular-, for the dilTolving Power of Water is different on a) See Boyle'*s Abridgment. Vol. I. fag. 248. and . Lowthorf s Abridgment of the Philofophical Tranl'aflioris, Vo\. ll. pag. G different 82 Lecture the Fifth. different Subjefts a). Whence a Set ofExpcri- ments fhould be ma'^c, to fhcw this Power on all the Salts, and other SubjecSis, whether mu- cilaginous, gummy, earthy or others, that arc capable of diflblving in Water. Such a Set of Experiments might prove of confiderable Ufe in phyfical and chemical Enquiries, and help to redlify the Mind, which is extremely apt to form general Rules from a few particular In- ftances. Whence Water has often paffed for a Kind of univerfal Solvent tho’ there are nume- rous Bodies which it will not difiblve b). And from this erroneous Notion of a general diflblv- ing Power in Water, the Enquiry into Mineral Waters has been in great Meafure either flop- ped, or perverted c), 1 8. The limited Power which Water has, of diflblving common Salt, appears remarkably in the Ocean ; which we fee, by our Experiment, may naturally contain about one fourth Part of fuch Salt ; or, with an additional Heat, confide- rably more; tho’ its Charge is always limited by the Nature of the Thing, and cannot be above one certain Proportion. This, however, is found to differ in different Seas, or Bays ; the Water of fome being found to yield more Salt than others, according to the greater Heat or Exhalation of Vapor in thofe Seas or Bays ; or again, perhaps, according to the Opportunity which the Water has had of running upon a more faline Bottom 19. But when Water has diflblved its full Proportion of common Salt, we fee, by the . a) As will appear hereaFter. LeH. VI. Exp. T. As Stones, Metals, Glafs. Gems, Amber, Shells, Coral, Sponge, Cloth, See hereafter Le 6 i. VI. §. 15. c') See the appendix to Ks-jj Experiments and Qhjer^ationi upon Mineral Waters^ lately publiihed. Experi' of Water. 83 Experiment, that it may ftill diflblve fome Quantity of another Salt. And how far this Power may extend, as to the Matters at the fame time diflblvable in Water, has not been hitherto fufiiciently afcertained a). 20. Nor is the Method, wherein different Salts range themfelves in the fame Water, pre- cifely determined. That they do not intermix, fo as inextricably to entarigle and confound their Particles among one another, appears from Cryftallization. For if feveral different Salts be diffolved together in the fame Parcel of Wa- ter, they may be made to (hoot feparately out of it again, by repeated Evaporation and Cryftai- lization, each in its own natural Form and Fi- gure, or pure and unmixed with the reft. But the Power of Water as a Solvent will again come to be confidered in our next Le 5 iure upon Men^ Jiruums b). Experiment V. *the natural Ingredients or different component Parts of Water, 21. (i.) We took a Pint of the pureft 'R.dXn- The Con^ "Water, decanted from its natural Sediment, and tents of put it into a bellied Glafs, with a long flendef Stem ; then marked the Part of the Stem to which the Water rofe, and fet it in the exhauft- ed Receiver, where we found it manifeftly ex- panded, and difeharged many Bubbles of Air. (2.) We put the fame Water into a clean Glafs Retort, and diftilling with a gentle Heat into a Glafs-Receiver, there came over a pure light Water, or merely aqueous Liquor j leaving a a) See Dr. Gre-io and Bofe P'lfjim, /»} See Leii, VI. E^. 1, G 2 fmall 84 Lecture THE Fifth. fmall Quantity of dry and whitifh terreftrial Mat- ter behind. 22. This Experiment requires a farther, and much more exad Profecution. We fee it re- folves Water into three diftind, and, to appea- rance, different Parts; viz, (i ) Air, (2.) ele- mentary Water, and (3.) Earth. The Truth of this Analyfis feems confirmed by other Experi- ments. For Water, by boiling, is alfo deprived of the Air it naturally contains. And fo it like- wife is by ftrong Freezing, the Ice becoming gradually lefs porous, and more purged of its Air-Bubbles ; alfo Water upon thawing always leaves a Quantity of earthy Sediment behind. But neither this Experiment of Freezing and Thawing, nor the Re-diftillation of Water, has been carried fo far as to fhev/, with Certainty, whether any, and what Proportion of the Water is thus adually convertible into Earth; or whe-- ther a Quantity of earthy Matter, before difiblv- ed or finely difperfed in the Water, is thus only aggregated, or colleded together and left be- hind, in a dry, folid, or earthy Form, upon Evaporation. 23. The Determination of this Point is of Confequence to Fhyficks. The Circumftances that tend to invalidate the Experiment by Di- flillation are, (i.) That the Water fuffers a great Diminution of its Quantity in the Operation ; fome Part flicking to the Sides of the VefTel^ employed every Time, and fome tranfuding thro* the Luting : whence the Account is defrauded. And (^2.) that in tranfvafing the Liquor, it every Time licks up the Dufl naturally contained in the Atmofphere, and at the fame Time lofes Particles of Water, which are thus carried off by the Air ; whence, upon numerous Repetitions of the Ex- periment, a large Proportion of the Earth ob- tained Of Water. 85 cained may proceed from the Dull of the At- mofphere a)» ^ 24. The Experiment by Congelation feems attended with fewer Difficulties, and might per- haps be brought to determine the Point with lefs Exception, by ufing a Circle of Freezings and Thawings, alternately repeated, with Care to fe- parate the Earth each Time. 25. What we here term Elementary Water, is the pure aqueous Part which comes over in Di- ftillation, commonly called by the Name of diftilled Water. This diftilled Water is found to be lighter and purer than the natural ; pro- vided it acquire no Foiilnefs, or heterogenous Parts in the Operation, And it is obfervable that, if the Operation be flopped in the Middle, a groffer Water remains befiind than what came over. Whence, for all curious chemical and ceconomical Ufes, the Water employed fhould not boil too long; as particularly in the making of Tindlures, Tea, Coffee, Experiment VI. more commodious Methods of examining Water » 26. By Means of the Inffrument called the Common Hydroftatical Balance, we took the fpedfic Gra- Water vity of the Water propofed, and diredlly judged of its Goodnefs by its Lightnefs. 27. This Experiment is a good Subftitute for feveral other Ways of examining the Purity and Goodnefs of Waters, both common and mine- ral. For it appears by numerous Inftances, that light Waters are, Cceteris paribus^ the beft, pureft and wholefomeft. a) See Mr. Boy'e\ Philofophical Works, and Boerhaa^ve^s $,heiniftry. 86 Lecture the Fifth. 28. But as the prefent Method requires the Ufe of a curious Inilrument, and a confiderjble Degree of Accuracy and Attention, other more expeditious, tho’ not more exadf. Trials have been invented j particularly by the Ufe of Water^ Poifes *, which arc Inftruments of Ivory, Glafs* made hollow-bellied, fo as to float in Wa- ter, higher or lower, according as the fpecific Gravity thereof is more or lefs ; And the in- ftruments being graduated or divided by Lines on the Stem, readily (hew to the Eye the Difference betwixt the fpecific Gravities of any two Waters propofed j tho’ not with the ut- moft Exadlnefs. 29. The Foundation of both Experiments is this, that the Bodies diiTolved or licked up by Water, in its pafling thro’ the Caverns, or fuper- ficial Parts of the Earth, are generally either fa- line or earthy; which being both more ponde- rous than pure Water, it follows, that the ligheft Waters are leaft impregnated with them, and therefore fitteft for the finer Ufes, where no fuch grofs, faline, or earthy Matters are required ; as they are not particularly in the healthy human Body, where the ordinary Office of common Water is to convey and diftribute Nutriment to all the Parts, to dilute and wafh off the Over- proportion of animal Salts, as it evidently does in Sweat and Urine. 30. By Means of the prefent Experiment we find, that the pureft Rain-Water is of nearly the fame fpecific Gravity with diftilled Water; nei- ther of them, when obtained pure, precipitating any grofs earthy Matter upon the Addition of Oil of Tartar pr deliauium^ as many Spring- Waters do. 31. Common-Waters are diflinguiflied into Hard and Soft^ and accordingly are ufed for dif- ferent Operations, Thus foft Water is found beft for of Water. 8 7 for extra^llng certain 'l'in6lures freeing Metal- lic Calces from their Salts, ^c. And hard Wa- ter is beft for the tem.jering of Steel, the mak^ ing of artificial Wines, and Malt-Liquors in- tended for long keeping. 3 2. Hard ¥/aters are fuch as contain a foreign, faline or terreftrial Matter; and accordingly be- come fofter by long (landing, or by a fmall Ad- dition of Salt of Tanar; both which tend to pre- cipitate the terreftrial Subftance out of them. Experiment VII. "The more commodious Methods of examining Mineral Waters, 33. (i.) To half a common Wine-Glafs Mineral Tyrmont Water we added a Dram of the Syrup Waters of Violets, whereby a greenilli Colour was pro- duced. (2.) To a like Qtiantity of the fame Wa- ter we added a few Grains of feraped Galls; and firft, a purple, then a blackiih Colour prefently enfued. (3.) We evaporated a Quantity of the fame Water, and a fmail Proportion of an ochry Subftance was left behind. (4.) We fet a Glafs of the fame Water, cold, in the Receiver of the Air-Pump, and found, upon with-drawing the Air, that the Water fparkled violently, and difeharged a numerous Qiiantity of fmall Bubbles at its Surface •, like what happens in the Conflid of an acid and alkaline Liquor. 34. This Experiment holds in all the Cafes of Chalybeate Waters only, and not of Mineral Wa- ters in general. By Mineral Waters, in general, are meant all thofe wherein any Medicinal Vir- tues, befides thofe of common Water, are found. Thefc Mineral Waters are of various Kinds : we may confider them under the general Titles ©f Chalybeate^ Purgative., and Alterative, G 4 35. The 88 Lecture the Fifth, 35. The more ufeful and commodious Addi- tions for examining thefe three Kinds of Mineral Waters, are. Galls ^ Syrup of Violets^ and Oil of Tartar per deliquium. 36. Galls tv in them any fmall Propor- tion of Vitriol or diffolved Iron*, as having the Property of immediately ffriking a purple, or black Colour, in all Waters, where any fuch Subftance is lodged. 37. Syrup of Violets in the fame Manner difco- vers any fmall Predominancy of an Acid or Al- kali therein*, by changing the Water red, if an Acid, and green, if an Alkali prefjdes. 38. 0/7 difcovers any fmall Propor- tion of earthy Matter, lefs capable of diiTolving in Water than that Salt*, by precipitating fuch earthy Matter, in Form of a white Cloud, to the Bottom of the containing Glafs, where it colledls, and appears like a fubtile white Powder. 39. I'hefe Particulars may be fhewn, and proved fatisfadorily, by adding to pure Water a little of a known Acid, Alkali, diffolved Iron, and fubtile Earth, or fine light Sediment of aii earthy Water, and then applying the Syrup of Violets, Galls, and Oil of 'Partar refpedively. 40. Suppofe, therefore, any unexperienced Water to be examined; hrfc, drop into it a little Syrup of Violets, and if this does not alter its Colour, but keeps its full natural Bluenefs, the Water is neither Acid nor Alkaline. If Galls do not turn the Water black, it is not Irony, nor Vitriolic *, and if Oil of Tartar does not preci- pitate a white Powder, the Water holds no confi- iiderable Proportion of earthy Matter. 41. The prefent Set of Experiments is capa- ble of great Enlargement, by Means of many other Additions, fitted to produce a Change of Colour, or a Precipitation in Waters, according as of Water. 89 .they are impregnated with Matters of certain Kinds. Thus a Solution of Silver, by caufing a Thicknefs or light Precipitation, difcovers a mi- nute Proportion of Sea-Salt contain’d in Waters. And there is fcarce a Salt, an Earth, or a Mine- ral, hitherto known, but the Induftry of the Chemift has found Means of difcovering, if it be contained in any common or Mineral Water ; efpecially, if to this we add the Ufe of Evapora- tion, or the Way of bringing the folid Contents of fuch Waters to a dry Eorm. So that if this whole Affair were to be properly conducled, wt apprehend it might in a fhort Time terminate in a certain Difcovery of the Contents of ail the Mineral Waters of the Kingdom *, to the great Advantage of ordinary Life, and a confiderable Improvement in the Art of Medicine, and many other mechanical Arts and Trades, depending upon the proper Choice and Ufe of Waters. Exp E R I MENT VIII. ^hat Mineral Waters are imitable by Art. 42. We took a Quart of the lighted and pu- Pyrmont red Water we could procure, and added to about thirty Drops of a drong Solution of Iron made with Spirit of Salt, a Dram or more of Oleum ^artari per deliquium^ and twenty, thirty, or forty Drops of Spirit of Vitriol ; biit fo as that the Alkali of the Oil of Tartar might pre- vail : we now diook all brifkly together, and pou- red out a Glafs for, tading; upon which, it was found very remarkably to rcfemble Pyrmont- Water. • 43. This Experiment, tho’ but particular, may afford us a general Rule for imitating any Mineral Water propofed. The Rule is, by a proper Analyfis to find the Contents of fuch a ‘ ‘ Water, 90 Purging Waters imitated. Lecture the Fifth. Water, and their Proportions, by Evapora- tion, the Addition of tinging Ingredients, Qc, as above mentioned a) *, then, by Means of fyntheti- cal Chemiftry to compofe a fimilar Mixture. Thus, for Example, we learn, by a proper Ana- lyfis, that the Ingredients or different conftituent Parts of Water rj, are a fubtile aqueous Fluid, a volatile Iron, and a predominating Alkali; adjoined together into one brifk, pun- gent, fpirituous Water : And upon this Analyfis our preceding Imitation was founded, by means whereof, if the Proportions bejuftly hit, the arti- ficial Fyrmont-^ 2XZX will greatly refemblc the na- tural, and produce fimilar Effeds in the Body ; as has been found upon Experience d), 44. The Imitation of this fpirituous Kind of chalybeate Water is by much the moft difficult; and may perhaps be rendered more perfe6l, if, in- iliead of ufing the Solution of Iron in Spirit of Salt, the pureft common Water be boiled in a clofe Veffel, wdth a fmall Proportion of Okre, foft Iron Ore, or Pyrites; the reft of the Pro- cefs being conducted as above fet down. 45. The Imitation of the common purgative Mineral Waters is facile: Thus Water is imitated by barely difiblving three or four Drams of Epfom Salt in a Quart of pure Water, made fomewhat brifk or quick with a few Drops of Spirit of Vitriol and Oil of Tartar deliauium, fo as to let the Alkali prevail. And the fame is to be underftood of any other Water, the Contents of which are exactly known. a) Sea Exp. YU, §. 35, 36, 37, &c. b ) See hereafter the Lediure on Synthetical Chemlflry. c) See above E.xp. VII. d) See New Experiments and Obfervations upon Mineral Waters. 46. And of Water. ' 91 46. And by a little farther Experience and Expe» Application, we apprehend that thefe Imita-^^^^ tions might be brought to a great Degree of perfedion ; fo as to render the Trouble and Charge of importing foreign Waters, or going to drink them abroad, in a Manner unneccfiary. But the Imitation of the alterative Waters, fuch as thofe of Bath., Buckjlon^ Holt., has hitherto fcarce been attempted ; nor can be ra- tionally, for Want of their refpedive juft Ana- lyfes, upon which fuch Imitations fhould always be grounded. Axioms and Canons. 1. We have feen, (i.) that Water is natu- rally contained in fome of the dryeft and har- deft Bodies, and in the dryeft A.ir ; (2.) that it- felf naturally contains Air, and an earthy Sub- ft'ance*, (3.; that it is the proper Menftruum of Saits, dilfolving more of one and lefs of another ; (4.) that one good Sign of its Purity and W'holefomenefs is its Levity ; (5 J that the In- gredients of a mineral Water may be difcovered by chemical Experiments •, and (6.) that mine- ral Waters are imitable by Art, guided by fuch Difcovery a ), 2. That Water is of infinite Ufe in all the Works both ot Nature and Art, as without it there could be no Generation, Nutrition, or Accretion performed in all the animal, vegeta- ble, mineral, marine and atmofphericai Regions. The Blood could not flow in the Veins, nor the Sap in the Veftels of Vegetables, nor the Particles of Minerals concrete and grow together, without Vfater. It is this that makes the iargeft Part of <5) See the LeBure our 92 Lecture the Fifth. our Blood, our Drink, and our Aliment. Without it there could be no Corruption, Fer- mentation, or DilTolution carried on a) \ no Brewing, no Diftilling, no Wines, no Vinegars, no Spirits h), 3. That we meet with Water under an infi- nite Variety of Forms, and in an infinite Va- riety of Bodies ; as of Air, Vapour, Clouds, Snow, Hail, Ice, Sap, Wines, Blood, Flefh, Bone, Horn, Stones ^c. through all which it feems to pafs unaltered, as an Agent or Inflru- ment that fufFers no Alteration by Re-adlion, but remains capable of refuming the Form of Water again upon Occafion c). In which refpe6t it greatly rcfembles that other Proteus Quickfil- ver, which wemeet within the Form of Fumes, Clouds, Sublimate, Precipitate, ^c. from which it may be reduced to running Mercury again d). 4. That Water, in its common State, ap- pears to be a Combination of all the Elements together, as containing a Quantity of Fire, which keeps it fluid, a Quantity of Air, and a Quantity of Earth e), Wdience it can be no Wonder that Water alone, as it appears to the Senfes, fhould fuffice for Vegetation, in fome Cafes where little Earth is wanted *, or for fup- porting animal and mineral Life, where no great Degree of Nutriment is required. And hence it proves a Gluten or Cement to fome Bodies, and a Solvent to others. Thus it confolidates Brick, Plaifter of Paris ^ Stone, Bone, Cfc. but difTolves Salts, and fubtile Earths approaching to Salts, and becomes the inffrumental Caufe of their Adion f). d) See Le^. I. b) See the whole Work fajjim, r) See Exp. I. See alfo LeEi. I IT. d) See Mr, Boyle palTim. e) See Led, I. II. III. IW f) See Led. I. the preceding Ledure pafiini ; and again, the Ledure upon Fermentation, That of IVater. 93 That Water conveys Nourifliment, or a more fixed and folid Matter, to the Parts of Vegetables, where that being depofited the finer Fluid perfpires into the Atmofphere a ) i which gives us the phyfical Caufe of the Dampnefs and Unwholefomenefs of woody Countries, which they remarkably find in America, For^ all large Vegetables a6t after the Manner of Pumps, continually drawing in large Quantities of Wa- ter at their Roots, and difcharging it at their Leaves ; which intimates a Method of colleding Water in dry Countries, and alfo of making Salt-Water frefii. 6. That the Water in pafiing thro’ Plants, after having depofited its more terreftrial Part, does not always go off pure, but impregnated with the finer Effluvia, or more fubtile Particles of the Vegetable; thus making an Atmofphere round every Plant, odoriferous or otherwife ac- cording to its Nature: which fupplies us with a Rule for procuring the odoriferous Waters of Vegetables by Diftillation b), 7. That the Particles, which are not fine enough to go off thus along with the Water, are left behind upon the Surface of the Leaves and Flowers of Plants; being now thickened or ffrained from their moifter Parts, and remain- ing in the Form of Honey, Manna, Gums, Bal- fams, according to the Nature of the Vege- table c). And hence appears the phyfical Caufe of Plants proving more odoriferous and fweet, when the Weather is both warm and moift ; as immediately after a Summer’s Shower. 8. That the chemical Operator fhould form to himfelf an Hygrometer d)y for the Service of his ; See Exp. HI. ^c. h) See Exp, III. 1 2. d’c. See Exp. ill. ^7 As of Sponge, Salt of Tartar, Oil of Vitriol, Oit-beards, ^ c, which attract the Moiilure of the Air. Labo- 94 - Lecture THE Fifth. Laboratory, to determine the Proportion of Water at all Times contained in the Air ; which continually mixes with his Preparations, diffe- rently 'augments their Weight, and promotes or hinders many ot his Operations a)^ as we find , particularly in making the Oleum Sulphuris per Campanam, zndi Oleum Tartari per deliquium^ both of which fucceed beft in a moift Air. 9. That pure Water makes the largefb Part of mineral Waters, where it is impregnated as a Menftruum with feveral Ingredients, which it diffolves or takes up in its Paffage thro’ the Earth c\ 10. Lajlly^ The preceding Enquiry affords ' confiderable Light for difcovering pra6licablc Ways of making Sea- Water frefh and potable ; and of preparing Waters by Art, fo as to ren- der them fitter for the common oeconomical Ufes, and the Service of many particular Arts ; as Me- dicine, Pharmacy, Chemiftry, Brewing, Diftil- ling, ^c. d) a ) See Exp. II, See alfo LeSi. Ill, b) SzcExp. VII. VIII. c ) See 7, 12, 14, & Ax. 5, ^ c. d) See §. 40. L E C- [ 95 ] LECTURE VI. CONTAINING An Enquiry into the Nature and Ufe of Menjlruums^ or Solvents. i.TWTE have now gone thro’ the common Introduc- V V Elements, Fire, Air, Earth, and^^'®«* Water : we next proceed to Menfiruums^ which make a large Branch of Natural Philofophy, and a more peculiar and immediate PartofChemiftry. 2. By Menjlruums we underfband all thofe Bo- Menfru- dies, which, in a fluid, or fubtilized State, are«wiwW. capable of interpofing their fmall Parts betwixt the fmall Parts of other Bodies, fo as to divide them fubtilely, and form a new uniform Com-- pound of the two. 3. Hence folid Bodies, as well as Fluids, 2x0 Solid and capable of becoming Menflruums, when their Parts are fubtilely divided, fo as to receive others uniformly between them-, whether this fubtile Divifion and joint Interpofition of Parts be ef- fedted by Fnfion, Triture, or the like. 4. Thus when two Metals, being fufed x.ogt- 7he Def- ther, mutually interpofe their fubtile Parts be- tween each other, and unite into one uniform Mafs, they become Menftruums to each other. And fo when common Sulphur and common Mercury are barely rubbed together, till the Mafs becomes every Way uniform and fimilar, the'Sulphur proves a Menftruum to the Mercury, and the Mercury a Menilruum to the Sulphur; 96 ^he Men- Jiruums Oj Nature, The Pur- port of the Ejcperi- ments. Lecture the Sxith. and both uniting form that black uniform Powder called jfEthiops Miner alis, 5. Whence it appears, that the Term Men- ftruuni is equally applicable to both the Todies concerned ; the one being as much a Menftruum as the other. So when Water diflblves Sugar, it mayas judly be faid that the Sugar diflblves the Watery tho’ Cuftom, and the common Forms of Speech, which have little Regard to juft and philofophical Notions, do not authorize the ExprefTion. ; 6. And hence it may appear that the common ' Elements, which we have confidered in the fore- going Ledures, are in a proper Senfe the Men- Jiruums of Nature^ which fhe eroploys for pro- ducing her ordinary Effects. For Fire mixes uni- formly among Bodies, and divides their Parts ; fo does Air, Water, and elementary Earth, as we have all along Ihewn. We fuppofe it will not therefore appear foreign, but direflly con- ducive to our Purpofe, to have beftowed a Lec- ture upon each of thefe Elements, by way of Foundation for our Courfe ; as thefe are not only the principal Agents of Nature, but are alfo concerned in every chemical Operation. 7. The prefent Bufmefs will be to fhew, (i.) the different diffolving Powers of Water, on dif ferent Bodies. (2.) The fame of Alcohol. (3.) The fame of Oil. (4.) The fame of unlikely Subftances. (5.) The fame of Quickfilver. (6.) The fame of the common Menflruums, Aqua Fortis and Aqua Regia, And (7.) the fame of the Digeftor : thus proceeding gradually from the weakeft up to the ftrongeft diffolving Powers hitherto known in Chemiftry. Exper^x Of Menfruums. Experiment 1. ^hat Water ^ as a Menftruum, dijjolves more of one Body^ and lefs of anoiher, 8 . We took three fimilar and equal GiafPes differ each containing two Ounces of the fame Kuid of Water, cold ; into the firff we pur a certain weighed Qjanrity of Epjom S ilt, viz two Ounces, ^ the greatclt Part whereot was loon diilo-v'ed *, iiitoitruum. the fecond we put a certain weighed Quintity’ of dry and pulverized common Salt, ViZ, five Drachmis, which likewife loon difiolved almofb entirely ; into the third we put a certain weighed Quantity, viz. eight Grains, of finely pulverized Cream of Tartar^ whereof fcarce any l^art appea- red to difibive in the cold. We fet all the GlafiTes in Balneo Maria^ till the Water of the Balneum boiled, and then obferved that more of each Sait was taken up refpedfively. 9. It might be proper, for the further provement of Chemiftry and Natural Philofophy, to form a Table of the Time and Quantity wherein all the known Salts are difiblvable in Water. Epfom Salt, we fee, preiently difiblves in about an equal Qjantity of Water *, common Salt difiblves in about four times*, Nitre in a- bout five or fix t mes; and Salt of Tartar in a- bouf twice its own Qjantity of Water : but Cream of Tartar recjuires twenty times its own Q^.iantity of boiling Water to difibive it. 10. Such a Table, ^ regularly formed, m’ght eafe the Trouble of refining Salts, by fhewing at once, without future Trial or Lofs of Time, how much Water each ^alt required to difibive it, for Clarification, Filtration, or Cryfiallization. 11. It w'ould likewife lupply us with a ready and commodious Way of feparating any Mixture H of 9? Accounted for. Lecture the Sixth. of Saks, by fhewing which would firft (hoot out of the Mixture upon Cryffallization. For the Rule is, that the Salt which requires the largeji Proportion of Water to dijfolve it will jlooot the firfi. And thus Nitre,, requiring a larger Pro- portion of Water to d.flblve it than common Salt docs, the former is, in the ordinary way of refining, totally feparated from the latter by Cry- ftallization. And unlefs this were to happen, the Aqua- For tis prepared from Nitre would prove a kind of Aqua-Regia^ and, inftead of diflblving Silver, would diffolve Gold ; For Aqua- Regia is made from a Mixture of Nitre and Sea-Salt, or Sal Ammoniac, which contains the Spirit of Sea- Salt ^ . 12. The fame Table might alfo dire6l us to a ready and commodious Method of feparating two Salts, without waiting for Cryftailization. Thus fuppofe Tartar of Vitriol mixed with Epfom Salt, if Water be poured upon the Mixture, it will prefently diflblve the Epfom Salt, leaving the Tartar of Vitriol untouched, fo that it may be decanted clear from it •, becaufe Tlpfom Salt eafily and plen- tifully diflblves in cold Water, whereas Tartar of Vitriol diflblves flowly and fparingly in it. And the fame is to be underftood of ocher Mixtures of Salts. 13. If the phyfical Reafon be demanded, why one Salt diflblves more readily in Water than ano- ther, we recommend it to farther Examination whether all Salts do not diflblve in Water with greater or lefs Facility, and in greater or lefTs Proportion, according as they contain more or Icfs of a grofs, unduous Subftance, unfuitable to the Nature, or to theFinenefs and Lubricity of Parts required in Water. The comparing of * See hereafter Exp. VI. Epfom Of Menjiruums. gg Epfom Salt, Salt of Tartar, common Salt, with Nitre, Alum, crude Tartar, feem to make this more than a Conjedure. 14. Vitriols alfo, being a Species of Salts, thence become foluble in Water. But pure Water has ' not the Power of difiblving Metals, unlefs they are firft reduced to a Saline or Vitriolic Form i Nor does Water ad as a Menftruum upon Oils, Rofins, Amber, Sulphur, Whence its Power, as a dired Solvent, is limited For Salts it feems the appropriated Menftruum \ but, with the Affiftance of other things, it may dilTolve a great Number of other Bodies : Thus, by the In- terpofition of Wax, it will difTolve Oil by fimple Triture ; by means of the Yolk of an Egg it will dlBblve Turpentine ; and by means of acid Spirits it will difiblve Chalk, Earths, and Metals. 15. In our prdent Experiment v/e find thedif- folving Power of Water increafe with Heat *, and this holds till the Water boils : after which, as the Heat remains the fame, fo does the difiblving Power, and as this Heat decreafes, To does that Power, letting Part of the Salt fall down again. Whence it fhould feem as if Pleat was the original Cauie of the dilTolving Power. 16. But on the other Hand, there are Experi- ments wherein the Power of Water, as a Men- flruum^ decreafes, as the Degree of Heat inCreafes; as in boiling the White of an Egg-, where the V/ater, as it grows hot, coagulates the Subjed: which it would difiblve when cold. We alfo ob- ferve the fame of Blood, a firm Mixture of Flower and Water, The Inffances of this Kind fhould therefore be collcded, and go along with the former, to prevent the Mind from runn- * SsQl^ct. V. §. 17, 18, &c. Pi 2 ing lOO Lecture the Sixth. ing into Error, by concluding hadily from too few Experiments, which has greatly prejudiced Chemidry and Natural Philofophy. Experiment II. dijjolving Po'iver of Alcohol. Alcohol nvhat. Camphtre We took an Ounce of Alcohol^ and by de- dipl^ed grees added to it an Ounce of folid Cam ph ire ; inSpiritof which it nearly difibivcd, in a very (hort Time, without any Ebullition, or apparent Alteration of Fluidity or Tranlparency. We afterwards poured in a large Proportion of fair Water, which weakening the Solution, and uniting with the Alcohof c'aufed it to let go the Camphire *, fo that now it all rofe, white, folid, and perfecfl, to the Top of the Mixture. 1 8. Alcohol, or highly rediEed Spirit of Wine, is a Liquor obtained from vegetable Subjeds, by Fermentation, Diftillation, and Rediification af It appears related to Oil, becaufe totally inflam- mable ; and when carefully examined, to* be the eflential Oil of the Vegetable, intimately broke, and ground in among the Particles of Water ^ fo as to form one uniform Liquor, not eafily fe- parable again into different Parts Z>). 19. We learn, by the prefent Experiment, that it has the Power of diffolving about its own Weight of Camphire *, which when duly exami- ned, appears to be a particular Kind of volatile, or eflential Oil, coagulated into a white and folid Subflance^) : And, as fuch an Oil, it is here plen- tifully diflToIved in Alcohol. ItsUfes. 20. This Alcohol is a capital Menftruum in Chemiftry, and fitted to diflblve Roflns, as well n) See the LeSlure upon DifiiUatlon hereafter. h) See hereafter XV 1. Exp. lU. as 1 01 Of Menjiruums. as Oils; tho* it does not thus mix inextricably with either, but leaves them leparable again by I the bare Addition of Water, which it dilTolves more readily than either Oil or Rofin, and ‘ therefore lets them go to join with this, accord- ing to the Law of Precipitation. For whenever P cne Body has dijjolved another^ if a third he ad- I' ded to the Solution^ which third has a greater Re- lation to either of the former^ than they have to each other ^ their Union is feparated^ and the third Body dijjolved injiead of the Jirji or fecond *, one of which is now at Liberty to rife^ or fall to the Bottom^ ac- cording to its fpecijic Gravity : as we faw remark- ably in the prefent Experiment, where the Cam- phire, didbivcd in the Spirit of Wine, was foon made to float upon the Surface, by the Addition of Water, which has a greater Appetite of Union, or Relation, to Spirit of Wine, than that Spine has to Camphire. And the phyfical Reafon hereof may appear from what was jufl: now faid of the Compofition of this Spirit, or its being an inti- mate Mixtiu*e of Water and volatile Oil 21. Hence Alcohol is an intermediate Sub- ftance betv/ixt Oil and Water, and related to both, tho’ participating more of Water than of Oil : And according to thefe Relations, its Ac- tion as a Menftruum may, we conceive, be pro- perly explained. 2 2 . By means of this Menjiruum the Tindlures of Myrrh^ Gum Lac^ Guataam^ mod of the Varnifhes, and many medicinal Tinctures, Eli- xirs, and Solutions are prepared ; tho’ for thefe Purpofes it ufually requires to be acuaied with Salt of Tartar. But our prefent Buflnefs is to con- flder the Power of Ample Menjiruums^ rather than of fuch as are mixed ; for that were an infinite Field, and would lead us too far for the prdtnt, * See 1 8. ' H3 Tho’ 102 OiUif Johjes Lead, The Expe yiment ex Uitdsd. Lecture the Sixth, Tho’ the Difcovery of powerful, yet innocenc Menftruums^ by means of Compofition, fhould be earneftly recommended to the Diligence of every Chemift, as that on which the Improvement of numerous Arts depends. ExPER-IMENT III. T^hat Oil 'imll intimately dijfolve Lead, 23. We put two Ounces of crude Lead into ah Iron Ladle, and added thereto twelve Ounces of Oil-Olive ; then fetting them over a clear Fire, the Lead evidently meked before the Oil began to boil, and at length the Lead difappeared, or united and became one with the Oil. By flop- ping the Operation at any time, we could eafily learn how much of the Lead was dilTolved in the Oil, both by the increafed Confidence of the Oil, and the Diminution of the Lead. 24.. The fame Experiment may hold alfo of * Tin, and of Tin and Lead mixed. How far it is applicable to the other Metals has not been hitherto fatisfadorily tried. Some have fuppofed that Oil will difTolve Copper and Iron : But it fhould be carefully exami’ned whether the efFe6b be not owing to an Acid concealed in the Oil ; for it is the known Property of Acids to difTolve thefe Metals. This has been obferved, that if Oil be well boiled, to get out its aqueous Parts, it is the better fitted to preftrve U.enfils of Iron, Brafs, or Copper, from Rufl:. Whence Marrow is reckoned better for this Purpofe, than other Fats or Oils more fubjedl to harbour aqueous Moiflure. And if a little Cerufe, or Black Lead, be added in the boiling, the Oil becomes flili more proper for this Purpofe. Now it is the Pro- perty of Cerufe, and black Lead, to drink up Acids j and therefore it may be hence concluded, that Of Menjlruurns. that fome acid Parts, naturally contained in Oils, arc the Cauie of their Rafting or Diflolving the Iron, Brals, or Copper, on which fuch Oils are 25. The Preparation, or Subftance, obtained //^ xjfeu in the prefenc Experiment, being taken from the Fire at different times of the Operation, makes either a Balfam, a Cement, or a Plaifter ; and fo is fit for various U^es. As a Balfam,and a Plaifter, it is ferviceable in Chirurgery. As a Cement, it is excellent in Water-Pipes*, and being laid upon hot Brick-work, or the like, fits it for holding Water. It alfo ferves to hold crack’d Glaffcs together, fo that they fhall be as firm ia the Crack, as in the Sound Parts. 26. But a more phyfical Ufe of the Experi- ment is, to fhew the great Affinity which the fofc and fluid Body of Oib, as a Menftruum^ has with the folid Bodies of Metals, and how they may mutually, not only diffolve, but dilguife and con- ceal each other ; fo that Metals fhall be contained in Bodies where the Eye would never fufped: them. 27. The prefent Experiment alfo affords fome Light .in the Dodtrine of Solders, or, the Mix- tures of metalline Matters, that will run with a kfs Degree of Heat than the Metal propoled to be folder’d, and tenacioufly lay hold thereof. For Oil, or Greafe, is an ufeful Thing to facili- tate the running of thefe Solders ; as we fee in the Soldering of Lead and Tin, where the Plum- ber ufes his Tallow, as the Tinman does his Rofin ; by means whereof the Solder and the Me- tal are the better foften’d, and in fome Meafurc diflblved and incorporated together. TheReU- 28. We defire that this great Affinity be- twixt Oils and Metals may be remember’d ; laid. H4 being Mefa/s. iOA T V* X JLi Thread dijiilkd. Tlfes of the Experi- tiieai. Lecture E Sixth. being of extenfive Confequence in the Bufinefs of Metals, and more particularly in the lublimer Metallurgy •, where catain Exprefiions, concerning the SullJjur of Metals may be underftood to ad- vantage, by t.king them to mean an adually in- flammabie Subltance, or Oil. Experiment IV. ^hat innocent and unlikely SuhjeEls may afford pow~ erful Menftruums, Jhewn in Bread. 29. We rook two Pounds of common brown Bread, cut it into fmall Pieces, and put it into a Gtals Retort. We placed the Retort in a Sand- Eleat, and luring on a Receiver, diftilled with a moderate Fire, io long as any aqueous Liquor came over : at length luffering all to coo), we took off the Receiver, and by the Filtre feparated the Liquor obtained, to clear it of its Oil. This Liquor we redlincd fiom its Phlegm in Balneo Maries^ and afterwards difHiied’ it over again in a Sand- Heat, to as to obtain a moderately ffrong, acid, limpid Fdquor, under the name of the redified Spirit of Bread. 30 In this manner we obtain from common Bread a large Proportion of an aqueous Liquor, mixed with acid Parts, fo as to be capable of ex- trading the red Colour out of Coral, or even Garnets. But to procure this Liquor in its greatefl Strength and Perfedion, we fhould make Ufe of Rye Bread, or fome of the coarier forts. 31. The Experiment being duly profecuted, affords us the Analyfis of Biead *, a Subfiance capable of recruiting and forming all the folid Parts of our Bodies. And no wonder, fince ic contains nv^^arly the fame Principles as animal Matters. For Blood, Flefh, or Bone, upon their Analyfis, refolve into Water, Oil, volatile Salt, Of Menfrumns. 105 and Earth •, the whole, by Dccoftion, making a Kind of mucilaginoiis, or gelatinous Subftance with Water: And in the fame manner Bread boils with Water into a gelatinous or mucilaginous Sab- ftance, and when diliilled. refolves into Water, an acid Spirit, Oil, and Earth. The principal Difference between them is, that Bread affords a volatile A id by Diftillation, whereas Flefh, or Blood, affords a volatile Alkali, Whence it fhould feem, that there is in the Body a certain Power of Changing the Matter of an Aitd into that of an Alkali *. 32. To gain a clearer Information from Extended. prelent Experiment, we could wifli it were repeated with fuch Bread as contains no Sea-Salt, which is a common ingredient in the ufual Kinds of Bread. For Sea-Salt affords a confiderable Pro- portion of acid Spirit upon Diftillation, and this Spirit may have a great Share in diffolving the Bodies fuppofed to be diffolved by the Spirit of the Bread. But however that Matter may prove, the Experiment ihews a pov/erful Menftrmm is obtainable from an innocent and unlikely Sub- jedt. And the fame has been found to hold of many other Preparations ; as Wine-Vinegar, tartarized Tartar, (Ac. Whence the like Experi- ments fhould be tried upon other common Sub- jeds , fuch as the Yolks and Whites of Eggs ; Renner, Curd, Whey, Milk, Butter-Milk, Cheefe, Urine, lAc. in order to difeover whether fervice- able Menfiruums might not be thus procured, EX'P E R I M E N T V. ^hat ^dekfther dijjohes Metals, 33. We melted two Ounces of clean Lead in Amalga<^ an Iron Ladle, and in another Ladle we heated mation of * Sec more to this purpofe in LeSl. VII. the io6 ^he Expe r intent ex tended, •vjtth its Vjes, Lecture the Sixth. the fame Quantity of Quickfilver till it juft began to fume ; then we poured the Quickfilver to the Lead, and ftirr'd them both together with an Iron Rod : upon letting them cool, they made a white, hardifh, homogeneous Mafs ; a part of which, being ground with more frefh Quick- filver, readily and intimately mixed therewith. 34. This Experiment fucceeds with ail the - Metals, except Iron ; which therefore appears of a lefs mercurial Nature than the reft. The Operation itfelf is called Amalgamation^ that is, the intimate Mixing of a Metal with Quickfilver, and is the Foundation of Gilding and Silvering. For an Amalgam of Gold being rubbed upon a well polifhed Plate of pure Silver, and the Plate afterwards expofed to fuch a Degree of Pleat as will evaporate the Quickfilver of the Amalgam, the Plate is left gilt. The Cafe is the fame when Copper is to be filver’d. And thus Gold, or Silver, is uniformly diffufed through the Body of the Quickfilver *, whence a fingle Grain of Gold, Silver, Lead, or Copper, may be divided to an almoft inconceivable Degree ; or fpread uniformly through a Mafs of a thoufand Pounds Weight of Quickfilver, every the fmalleft Par- ticle of which fliall contain a Quantity of Gold proportionable to the Whole. And hence it appears that Quickfilver is a true Menjiruum to all the Metals, except Iron ; diifolving them as perfedlly as Water diflblves Salt. 35. The prefent Experiment alfo fhews us how Quickfilver may be adulterated with a Pro- portion of Lead : but the Fraud is eafily difeo- vered, by putting a little Quantity of fuch de- bafed Quickfilver into an Iron Ladle, and exha- ling away all the Mercury which will thus leave the Lead behind. 36. Wc Of Menflruums. 107 36. We may likewife hence underftand the fraudulent Tricks of fome pretended Aichemifts, who feigning an Cccafion for the Ufe of Mer- cury in their ProcelTcs, do beforehand fecretly diffolve, or procure to be diffolved therein, a certain Proportion of Gold or Silver \ which not flying off along with the Qiiickfilver in the Fire, the credulous By-flanders are made to believe, that the bafer Metals employed are enriched with the nobler in the Operation. The Inftan- ces of fuch Frauds are many, and have brought a great Stain upon the Art of Alchemy. But they are eafily detected, by expofing a Part of the Operator’s Mercury to the Fire ; for the Quickfilver going off in fume will leave the Silver and Gold behind. Expe rime NT VI. fhat Aqua-Fortis, cr Spirit of Nitre ^ is the Men- ftruum for Silver \ and Aqua-Regia the Men- ftruum/?r Gold. 37. We took two Drachms of the finefl: Silver Gold and reduced to Filings, and poured upon it twice its Siherdif- Weight Aqua-Fortis \ then let the con- tainingGlafs in a gentle Heat, under a Chimney, till the Solution was perfectly made. 38. We took ten Grains of Leaf-Gold, and poured upon it two Drachms of Aqua- Regia ; then let the Glafs in a Sand Heat to warm tho- roughly. After the Gold was diffolved we ad- ded a Grain or two more, till the Menjiruum was fully faturated, and then decanted the clear yellow Solution. We afterwards put a few Grains of Silver into Aqua-Regia^ and a few Grains of Gold into Aqua-Fortis ; and kept the containing Glafs warm,' in the fame manner as before, but found no Solution enfue in either cafe. 39. Thus io8 Prcof-A- qu'i- Foitis n^hat. made. Aqua-R£‘ gia Thus, by the Addition of Water, it be- comes Brandy, or Spirit, which extrads many Tiniflures that neither pure Water nor pure Ah'ohol will feparately extradt. Whence we have a good Inftrudion lor attempting a new Set of Menftruums by Mixture, or the Compofition of tv^o or three Ample Solvents. And if the requi- fite Care and Skill were employed in this Matter, many ufeiul Difcoveries might be juflly expeded from it. Indeed, the mixing of two Menftruums may fometimes deftroy the Virtue of both : thus Spirit of Nitre and Ample Water will each of them feparately diAblve the human Calculus^ but when mixed they will not touch it. This In- ftance however is only particular, and there are a large Number producible on the contrary Ade ; which may rationally recommend a farther Pro- lecution of this Enquiry. 4. That Metals are foluble in Oils, and in add Spirits, fo as not tobeeafily difeovered therein r). Whence a Rule may be drawn for a prudent Suf- penfion of the Judgment, and a rational Dif- rt) Exp. T. Seealfo he £ l . V. F) Exp.U. c) Exp. 111. VI. truft Of Menfruums. 113 tnifl: of the Senfes in chemical Operations : And alfo, a Caution againfl; being impoied upon by the vain Pretences of Alchemifts a), 5. 1 hat the Power of a Menliruum is not to be judged of by its Innocency with regard to the animal Body. The acid Spirit of Bread is inno- cent and wholefome, yet capable of diffolving Coral and Gems h). Pure Oil-Olive will diffolve Lead and Tin. The White of an Egg, boiled hard, and fulfer’d to run per deliquium^ dilTolves the tough Body of Myrrh. The Inftances of this Kind are extremely numerous. They well de- ferve to be colledled and tabled, that the Mind may be thereby cured of the Prejudice it has too readily imbibed, as if Corrofives only were Solvents. 6. That the A6lion of Menfiruums depends upon a certain Secret and reciprocal Relation be- twixt the Solvent and Solvend, fcarce cognizable by the diredt Senfes, nor hitherto well made out by Inftances and Induction. Alkali and Acid, Attra( 5 lion and Repulfion, Sympathy and Anti- pathy, feem rather Words coined to exprefs the Adion, than to aflign the phyfical Caufes there- of. And hence the Action of new Menfiruums cannot be determined, or rationally conjedurcd, beforehand ; becaufe it depends upon a Caufe not hitherto known. 7. That Menfiruums have not their full Adlion, unlefs reduced to a tiuid or fubcile State c). Wa- ter in the firm and folid Form of Ice does not a6t on Salts ; but they foon begin to difTolve each other upon Contad Metals do not ad on Me- tals, in the Way of Solution, till they are fufed : Nor does Sulphur difTolve Quickfilver, till they are both reduced, either to a fluid or very fub- a) See above, §. 26, 33 —36. b) Exp. IV. c) See the Ledure, fajUtm. I tile II4- Lecture THE Sixth. tile State, by Triture, or by Melting, And this appears to be the Cafe in all Indances. Whence, in order to promote the Adion of Menfirmms^ we are direded to reduce both the Solvent and Solvend to minute Parts, or as near as poihble to a fluid State, whether by Heat, Triture, Fu- fion, orotherwife. A.nd hence appears the phy- fical Caufe of the Angular Efficacy of Fire, Air, V/ater, and Trituration in promoting the Adion of Menjiruums a). 8. That Quickfilver is a true Solvent of Me- tals, incorporating with them, as Water does whth Salts b) *, by which Means one Metal may be rea- dily united with another, in any Proportion, by Ample Triture c). And hereby alfo many Ope- rations in the fublimer Metallurgy are chiefly performed d). 9. That acid Spirits are not, equally, proper Menjiruums to all the Metals *, thus Spirit of Nitre, tho’ it diflTolves the reft, will not difTolve Gold e). So neither is Quickfilver itfelf a proper Men- Jiruum to them all •, for it does not diflblve Iron/j. And the true phyfical Reafon hereof feems not hitherto fatisfadorily difeovered, tho’ numerous Conjedures have been made about it 10. That all the Bodies in nature may become Menjiruums to one another, each of them being, by fome Means or other, capable of having their fmall Parts uniformly interpofed betwixt the fmall Parts of any of the reft. Thus even Metals may, by Art, be made to dilTolve in Water •, as we evidently fee from numerous Solutions ot Metals ' a) See the five preceding I.eftures, pojfini. h) Exp. J and See allb Uii. V. 0 See above, f 33, 34 d: See hereafter the I enures on Mineralogy and MetaU lur^y. i) ^e.cExp.Y]. J) Exp. V. in Of Menjlruums. ^ in acid Spirits : thefe Spirits being no more than Water charged with the [ine or more volatile Karts of Salts. 11. That the Caufe of Solution commonly af- figned, viz. the AdmifTion of the fine Particles of one Body into the Pores of another, whofe Figure is fitted for their Reception, is not jufl or ade- quate, but hypothetical and ill-prefumed, fince v/e find that fome Bodies will uniformly difTolve their own Quantity of others * as Water does of Epfom Salt, Alcohol of efTemial Oils, Mercury of Metals, one Metal of another, , whereas the Sum of the P’ores, or Vacuities, of every Body muft be necefiarily fefs than the Body itfelf ; and confequently thofe Pores cannot receive a Quantity of Matter equal to the Body wherein they exift : for this were to make the contained Matter bigger than the Pores that contain it. 12. That the difTolving Power of Water may be immenfely increafed by means of the Digeftor.^ an Inftrument not hitherto introduced into Che- miflry, tho’ probably applicable to the great Im- provement of that Art ; as being a Contrivance, which at once determines the Adtion of a Solvent upon the Solvend, with all the Advantages of Heat, Air, and Water, brifkly agitated and' con- fined, under a State of ComprefTure, fo as to make them ad like different Sets of Stampers upon the Matter to be changed. For this Engine at once employs all the four Agents required to make the greateft Part of Mcnftruiims ad with Advantage; viz. Fire, Air, Water, andTriture. Whence there are fome folid Grounds of Hope, that it may, under a proper Regulation, greatly contribute to the Improvement of Chemifbry, Na- tural Philofophy, and Arts. » Exp. i.n.v. I 2 13. Upon ii6 . Lecture THE Sixth. 13. Upon the whole it fhould feem, that many defirable Improvements are derivable to Arts from an Improvement in the Bufinefs of Men- ftruums The Difcovery of that common Men- ftruum^ Aqua-Fortis^ introduced the Art of AfTay- ing, and the Scarlet Dye. That of Alcohol in- troduced the Arts of Varnifhing and Japanning^ numerous Pigments for Painters, Colours for Dyers, Tan-Liquors for Tanners, the Staining of Bone, Horn, Ivory, Marble, various Kinds of Ink, Tin6lures, and Solutions, in Medicine, Che- miftry, and other Arts, have all refulted from n the Difcovery of Menftruums, Yet the Subjedf feems almoft as new and rich as ever *, fo that nu- merous other Difcoveries, of the fame Kind, would not exhauft it. * See the whole Enquiry, fajjim. [ ”7 ] lecture VII. CONTAINING An Enquiry into the Nature.^ Office y and Ef- feEls of Fermentation and Putrefadlionj in the Vegetabky Animaly and Mineral Kingdoms, T H E Purport of this Ledlure is to enquire into the Nature, Effeds, and Ufes of^v^f?. "ermentation and Putrefadion, as they are the latural Means of converting one Body into an- )ther *, in order to acquire a farther Knowledge n the Cbemijlry of NalurCy and thence derive bme ferviceable Rules for the Improvement of '^hilofophical Chemiftry. 2 But as the Subjedfs of Fermentation and ^utrefadlion feem to have been imperfedily treated )y Authors, and to lie buried, as it were, in Ob- curity, we lhall endeavour to let fome Light in !pon them by particular Experiments, and our ^Explanations of them-, fo as to fhew the Steps of Mature and Arty in conducting and regulating hefe capital OperationSy for altering and changing egetable, animal, and mineral Subjects in the bree grand Regions of Nature, viz. the Earthy )cean and Atmofphere. 3. That we may proceed the more clearly, we TheQrder, lall bemn with Fermentation in vegetable Sub- iCts, and trace it thro’ all its Stages •, till at :ngth it terminates in Putrefa£Hony which reduces egetable Subjects to an animal Nature. We lall next confider the fimilar Procefs in animal I 3 Subjects^ Ii8 Lecture the Seventh. Subjeds ; and laftly^ examine whether any Thing ot the fame Kind obtains among Minerals. I- . I To begin with vegetable Subjecls : Experiment I. ^he Nature and Ufes of vinous Fermentation ; or the II Way of changing the natural Juices of Vegetables into Wines. Wine 4 . We took a Quarter of an hundred of whole, We’/z'ow or unbruifed, Malaga Raifms, and put to them Gallons of cold Spring- Water, in a wooden Vefiel or Cafk, which we let loofely cover’d in a warm Place, that the Contents might ferment for fome Weeks. We found that the Water foaked thro’ the Skins of the Raifms, dilTolved their in- ternal fweet or faccharine Subftance, and became impregnated therewith, as a Menjtruum \ that the Liquor manifeftcd an internal Struggle and Com- motion of its Particles, throwing up numerous fmall Bubbles to the Surface, with a confiderable hilTing Noife ; and that when the Fermentation was finifhed, the Liquor was become an actual nev/V'/ine, as appear’d by the Tafte, Smell and Effeds, having depofited a large Quantity of grofs, earthy Pediment, called Lees, at the Bot- tom, different from the Huflcs, or Skins, and Stones of the Raifms. fhe Expe- 5- This Experiment i^ univerfal, or fhews the ; rimentex- general Manner of making Wines, and all other unded, fpirituous potable Liquors, or Drinks, by Fer- mentation. For, v/ith a flight Change of Cir- cumftances, it is applicable to the Brewing of Beer from Malt •, Mead or Metheglin from Ho- ney ^ Cyder and Ferry from Apples and Pears refpec- Of Fermentation and PutrefaSHon. 1 1 9 refpeflively ; artificial, or made Wines, as they are vulgarly called, from Cherries, Goofeberries, Currants, Elder Berries, Blackberries, Plumbs, Oranges, or other Fruit; alfo, from the Tap- pings of certain Trees, as the Birch, the Maple, the Sycamore, and more eminently from the Juice of the Sugar Cane, Treacle, or common Sugar and Water. For any ot thefe vegetable Juices, being duly fermented, afford as real and perfect Wine, according to their feveral Natures, as the richefi: Grapes of the beft Wine-Countries. 6. To bring any of thefe Juices into a found ^p- Wine, the Rule is to evaporate them, if they are naturally too thin, till they become of equal ^ Richnefs tvith the Juice of the Grape, in Wine- Countries and in good Wine- Years. ITis may commodioufly be done, by Means of the com- mon Water-Poife *, which fhews the Strength or Richnefs of Solutions to the Eye. And in ge- neral, any vegetable Juice, or Solution, is ac- counted fufficiently rich for making a ftrong Wine, when it will fuppoic a new laid Egg on its Surface. 7. The Wines made at prefect in England lie under a Difrepute ; the Reafon whereof feems chiefly owing, to the irlartihcial Manner wherein they are ufually prepared, fecondly^ to a certain Rumour fpread about them, as if they were unwholefome, crude, indigeflible, too lufcious, too tart or griping, and apt to occafion the Plead ach, &c. 8. Thofe, who have never been in Wine Coun- tries, nor othgrwife made themfelves acquainted with the Nature and common Preparation of 1 4 * See Lect. V. Exp. VI. Wines, I 20 Lecture the Seventh. Wines proceed in their Judgment of them accord- ing to Report, popular Notions, and the imme- diate Information of the Senfes. Thus, for In- fiance, Red-Port Wines, to pleafe the common Palate, mud be bright, deep-colour’d, rough, rich and racy, two or three Years old, and when this or any other Notion comes once to be edabl idled as the Criterion of Vv' ine, the Cooper is thereby dire(5fed how to hit the general 1 ade, and make a faleable Commodity. Upon the fame Foundation Philofophical Chemijlry indru6ls us to imitate the Wine-Cooper, and from almod any fweet and tart vegetable Juice, to make faleable Wines, even Sacks, Mountains, Sherries, or Ports ; all of which by the way, are ufually mixed Liquors, tho’ the Bads of them all is the Juice of the Grape. lo This Juice of t’ e Grape being cliemically examin’d and confidered, proves to be no more than a large Proportion of real Sugar difiblved in Water, with the Addition only of a certain Fla- vour in the Juice of the Grape, according to the Nature of the Vine. Whence we lay it down as an Axiom^ and the Refult of a careful En- quiry, that a faccharine Subjtance is the Bafis of Wines, For Sugar is not peculiar to the Sugar- Cane, but obtainable alfo from Grapes *, and ac- cordingly we often find large Grains thereof in dried Raifins ; particularly in thofe of Malaga^ that have lain for fometime, and fweated together, by which Means they run into Candy, a faccharine Efflorefcence, and adlual Grains of Sugar. So again, it is cudomary in France to evaporate the Juice of the Grape till it becomes coaguluble in the Cold, and in this State to ufe it as a moid Sugar, under the Name of Refine. And the fame Thing is to be underdood as pracdicable in Malt, or Of 'Fermentation and PutrefaSUon. I2i or Wort, and the fweet Juices of all Vegetables that aiiord a Wine by Fermentation 11. Hence therefore we may derive a Set of ^uks. Rules, for boiling down, or otherwife procuring the eiientiai Matter of Winrs in a fmall Bulk, and preferving it found and ferviceable for many Years, in order to the Making of all Kinds of Wines, Vinegars, and Brandies, even in Coun- tries where no Vines grow. And this Difeovery alfo affords great Light into the true Nature and Ules of vinous and acetous Fermentation, 12. To illuffrate and confirm this Difeovery Praaice, by an Example, upon the Footing of the prefent Experiment : Take two hundred Weight and a half of double refined Sugar; put it into a Pipe, or Wine Veffel of two Hogfheads *, fill the Vef- fel within four Gallons of the Top with pure Spring-Water *, fet in a warm Place, orWine- Vauit; and three or four Pounds of frefh Ale- Yeafl, or rather of new W^ine-Yeafl ; and the Liquor in a few Months time will ferment into a found, colourlcfs, and flavourlefs Wine, and remain fufceptible of any Colour or Flavour at Pleafure •, fo as with the Stain called Furnfol., to be made of the true Claret-Colour; and with a little effential vegetable Oil, of any particular ' Flavour required. And this is'here deliver’d as an Experiment that fucceeds to great Perfedlion ; fo as to fhew a rational and practicable Method of producing Wines in the Sugar Colonies, or eJfe- where, that fliall rival thofe of France.^ Italy, or Spain ; and if the Nature of Fermentation be well underftood, the Procefs may be greatly fliortened in point of Time, as well as improved in other Refpedis. 13. And fo much for the Ufe of our prefent Experiment, with regard to Trade, and Oeco- * See an EfTay upon the Art of Breiving and DlJUllation. See alfo hereafter, Lea. XI. pajjitn. nnmv . 122 Philo- sophy. Lecture the Seventh. nomy. Its philofophical Ufes are no lefs confi- derable. And firft, it fhews that the proper fer- menting Matter of every fermentable Subjedl is but fmall, compared with the Quantity of Wine it affords. Thus, for Example, we fee that four Pounds of Raifins may be diluted, and ferment- ed, with eight Pounds of Water, into what is accounted a tolerably flrong Wine. And yet even Raifins themfelves contain a large Propor- tion of Water,befides their diredly faccharineSub- ftance •, which faccharine Subftance is reducible to a dry Form, as we find in Sugar. And who- ever would thoroughly enquire into the Nature, the Ufes, and the Means of im^roYrngvinous and acetous Fermentation, cannot perhaps do better than to chufe Sugar for his Subjedb *, a chemical Analyfis w^hereof will fhew the Principles necef- farily required in this Operation. Thefe Prin- ciples appear to be an acid Salt, an Oil, andEartli fo united together, as to be capable of difiblving perfectly in Water. 14. Hence we alfo fee the phyfical Caufe of the fermentable Nature of River- Waters which be- ing kept in clofe Cafks have been obferved to ferment, and their Vapor, or Spirit, to take Fire at the Approach of a Candle. For much vege- table Matter, as Leaves, Grafs, the Juices of Plants, Cfr. being by the Rains wafhed down into Rivers, fuch vegetable Matters rnufl: neceffarily there run into a fermenting State, as Raifins do by the Addition of Water ; the running or flux- ible State of the Rivers being no Hindrance to this fermentative Motion, after it is once begun by Stagnation. For we fee that Beer and new Wine will ferment afrefh upon being fhook, and carried upon Drays, or Carts. 15. All fermentable Bodies do not require Fer- ments to begin their Motion of Fermentation. RaifmS| Of Fermentation and PutrefaBion. 123 Railins, we fee, require none ; much lefs does the frefh exprefled Juice of the Grape, or other ve- getable Juices, in the Summer-Seafon, or in a warm Air. But all fweet vegetable Juices, that have felt much of the Fire, as Treacle, or Wort high boiled, Rob of Malt, Rob of Flder, or the like, ufually require a conliderable Proportion of a vinous Ferment to make them work. In ge- neral, Ferments are no more than Matters al- ready in the A6f of Fermentation, or that foon run into this Ad: Of tht! firft Kind are the Flow- ers of Wine, Yeaif, fermenting Beer, or ferment- ing Wine, Ore. and of the fecond, arc the new expreffed vegetable Juices of Summer-Fruits, Ofe. 16. Water, we find, is abfoiutely neceflary to begin and procure a fermentative Motion in ve- getable Subftances. For Raifins, or Sugar, being kept dry, will never ferment. And this holds univerfally of ail the Subjeds of vinous and ace- tous Fermentation. Whence Water is an Inftru- ment that muff be necelfarily employed in thefe Kinds of Fermentation, whether natural, or ar- tificial a). 17. As the Water which naturally, and in large Quantities, perfpires from the Surface of Ve getables, efpecially in hot Climates, does not go off pure, but carries along with it a confiderable Proportion of fermentable Matter into the At- mofphere ^), there may be an adually vinous Fermentation begun and carried on in certain Parts of that Region, efpecially where the Winds are flill, or the Air ftagnant. And what phy- fica! Effeds and Ufes this Fermentation in the Ac- mofphere may have, fcarce feems to have been confider’d •, nor fhould they be rafhly judged of, till a more thorough Enquiry is made. At See LeSI. I. III. V. b) See Le^. V. Schiedam [24 ’’inegar \ade. Lecture the Seventh. Schiedam in Holland^ a larger Quantity of inflamm- able Spirit is faid to be obtained from Malt, than in any other Place, where there are fewer Mak- Dikillers. This is probably owing to the Air of that Place being impregnated with the ferment- ing Vapours, that continually exhale from their numerous fermenting Backs and Stills. And the fame is found to hold proportionably of Wines fermented in large Vaults or Cellars, where many Calks of Wine are at once, or fuccelTively, fet to work. 1 8. Warmth, with the free Admiflion of the external Air, is neceffary to expedite the Ackion of vinous Fermientation , for if our Raifins and Water were to Hand either in a very cold Place, or to be kept entirely from the Accefs of the com- mon atmofpherical Air, either no Fermentation, or a very weak and flow one, would enfue ^ as has been experienced. 19. The i.ees remaining at the Bottom of the Cafx, in our prefent Experiment, are, if ufed frefh, a true Kind of Ferment^ that will fet any lefs fermentable Subjedl at work, and determine its Fermentation to the vinous Kind. They contain a large i'roportion of efTential Oil, and fome Tartar. And hence we fee that vinous Fermen- tation confiks, frji.y in an intekine Struggle or Commotion of the Fluid ; and, fecondly^ in a Se- paration of a grofier Part, which did not appear in that Form before. Experiment II. Fhe Nature^ and Ufe of acetous Fermenta- tion *, or the Method of turnmg vegetable Matters into Vinegar, 20. We took the Skins of the Raifins, and the Sediment left behind, after a Wine was made in the Of Fermentation and PutrefaSUon. 125 the manner of the preceding Experiment, and poured three or four times their Quantity of boiling Water upon them, fo as to make a thin aqueous Mixture. Then we fet the containing Cafic, loofeJy cover’d, in a warmer Place than was ufed for the Wine, and found the Liquor, in a few Weeks time, became a clear and found Vinegar ; which being drawn off from its Sediment, and preferved in another Cafk, welLftopped, conti- nued long perfed and fit for Ufe. 21. This Experiment fhews us a cheap The Expe~ ready Way of making Vinegar from ref ufe Ma- riment tx- terials ; fuch as the Huflcs of Grapes, decayed Raifins, the Lees of Wine, Grounds of Ale, Beer, which are frequently thrown away as ufelefs. Thus in many Wine Countries, the Marc^ Rape, or dry Preffings of the Grapes are thrown in heaps, and fuffered to putrefy unregarded ; tho’ capa- ble of affording as good Vineg ar, as the Wine it- felf would make. In fome places they bury Copper- Plates in thefe Hulks, in order to make Verdigreafe : but this Pradlice feems chiefly con- fined to the Southern Parts of France. Our pre- fent Experiment fhews us how to convert them to another Ufe ; and the Diredlion extends to all the Matters that have once undergone, or are fit to undergo, a vinous Fermentation ; for all fuch Matters will afford Vinegar. Thus ail ourSum- mer-Fruits in England.^ even Black-berries ; all the refufe Wafhings of a Sugar-Houfe, Cyder- Prelfmgs, or the like, will make Vinegar, by means of Water, the open Air, and Warmth. 22. The whole Procefs, whereby this ^eProcefs is effedled, deferves to be attentively confider’d. phyfically And firft, the Liquor to be thus changed, being confiderd. kept warmer than in vinous Fermentation, in a few days begins to grow thick or turbid, and without throwing up Bubbles, or making any 126 Lecture the Seventh. any confiderable Tumult, as happens in vinous Fermentation, depofites a copious Sediment. The EfFedl of this Separation begins to appear firft on the Surface of the Liquor, which gathers a white Skin that daily increafes in Thicknefs, till at length it becomes like Leather *, and now, if it be continued longer in this State, the Skin turns blue, or green, and would at laft grow folid, and then putrefy : therefore in keeping down this Skin as it grows, and thrufting it gently to the Bottom of the VefTel, confifts much of the Arc of Vinegar- m.akiag, efpecially from Malt. largerOh- E is to be particularly obfervcd, that, if Jer^ation. the Wine of our firil Experiment were not bunged dovrn when arrived at its vinous State, but fuf- fer’d ftill to remain open and expofed to a warm i\ir, it would fpontaneoudy become Vinegar *, and the fooner, if a fo mew hat greater Degree of Heat, than fervedforthe Making of Wine, were employed. Whenie we might have ufed the Wine of our firu Experiment for this Purpofe, inilead of adding Water to the Hufks and Se- diment, or Lees •, but we chofe the latter Way, lo fhew that even fuch refufe Matters will af- ford Vinegar ; and again, to intimate how far the Art of Vinegar- making may be ftill im- proved, both in England where they brew a Wort from Malt, and in fome Wine-Coun- tries where they make their beft Wines into Vinegars. 24. What we would chiefly obferve, for the prefent, is, that acetous Ferfnentation requires a ftronger Heat than the vinous \ and that Wines having once finifhed their Fermentation, as Wines, do not naturally ftop there ; but, unlefs prevented by the Care of the Operator, proceed directly on to Vinegars ^ where again they make no Of Fermentation and PutrefaBion. 127 no Stop j but, unlefs prevented here alfo, fpon- taneoufly go on to Vappidity, Ropinefs, Moul- dinefs, and Putrefadlion. From which larger Oblervation we would deduce this Axiom : That, to fpeak philofophically, the Intention or Ten- dency of Nature is^ to proceed from the very Begin- ning of vinous Fermentation^ diredily^ in one con- tinued SerieSy to PutrefalHony and thence again to a new Generation \ which appears to be the grand Circle wherein all natural Things are moved, and all the Phyfical, or rather Chemi- cal, Phenomena of the Globe produced. 25. And hence we fee how, by the Interpofi- tion of Man, this general Procefs of Nature may be (lopped at different Periods, with different Views ; fo as to procure to ourfelves Wines, Vinegars, and, as will appear hereafter, * parti- cular Salts and Oils. 26. Another Corollary from the larger Ob- Corolla- fervation above laid down, is, That the Word ries. Fermentation has been ufually applied to (ignify only a fmall Part of this grand Operation of Na- ~ture. Thus one limits the Word to the Pro- du( 5 lion of Whines; another, to the Pfodudlion of Wines and Vinegars ; and feme would diftinguifh it from PutrefaBion : whereas either the Term Ferment atioHy or fome other, (Irould be made general, and denote the Genus y or univerfal Operation y whereof Vinification y Acetificationy and PutrefaBiony are only Species. At leaft we fhould thus attempt to follow and exprefs Na- ture, in the Fa6ls that are obferved, and not proceed, in an arbitrary, narrow*, or inadequate Manner, to impofe Terms, and drefs out Nature according to our particular Hypothefes and Conceits. But the Obfervation itfelf, on which ^ Sec below, Exp. VI. VH. this 128 V appidity and Putre- f action fuc- ceed Fer- mentation. Phyfical JJfe of the Expert- ment. Lecture the Seventh. this Do6lrine is founded, being of moment to the right Underflanding of the whole Affair of Fermentation and Futretadlion, we proceed to illuftrate and confirm the laft Fare of it by an Experiment, as the two former Farts have been already a). Experiment III. "That Wines and Vinegars., or all fermented vege- table Juices., have a natural Tendency to Putre- faction, 27. We took a Gallon of thick, muddy Vi- negar, produced after the Manner of our fecond Experiment, and letting it ftand open, in a hotter Place than was required to make it Vinegar, it became in a tew days a vappid, naufeous, and putrefied Liquor, throwing up a large Quantity of a dry powdery Subftance to the Top, and de- pofiting a iefs Quantity of a groffer Matter at the Bottom *, foon after which the Body of the Liquor became clear again. 28. We might fhorten the prefent Experiment, and fave the Trouble of making either a Wine, or a Vinegar, to fliew it. f or if a Quantity of Mujl were fet in an open Veffel, in a hot Stove- Room, where the Air had free Accefs, the Work would foon be performed, and theputri- fied Liquor be produced almoft at once, with- out flopping at the State either of Wine or Vi- negar*, according to the larger Obfervation de- liver’d above b). 29. The p'^efent Experiment has a confide- rable philofophical Ufe, as affording Light to the Underflanding, and leading us tar into a Knowledge of our Subjed. And ( i.) it gives us the phyfical Reafon why Wines and Vinegars, a) See Exp. I. II. h) §.24, 26. unlefs Of Fermentation and PutrefaSiion. 129 unlefs made exceeding flrong, will not keep, but corrupt and putrefy, in hot Countries. For the Heat being there fo great, as to keep the lighter feculent Parts of thofe Liquors fufpended for ibme time in the Body of the Liquor, Corruption (which proceeds from a tumultuary Motion of all the different Parts of a compound Body toge- ther a neceffariiy enfues. 30. (2.) Hence alfo we learn the phyfical Rea- fon why Wines and Vinegars require to be racked from their Lees, in order to preferve them found, ^ or keep them from running into Putrefadion, to which we find they are ftrongly inclined; the Tendency of Nature being ever confiant in urging them to that State. And the Cafe appears to be much the fame in animal, and even mineral Subftances; as we fhall fee hereafter h), 31. (3). This Experiment, therefore, furnifhes us with a Rule for preferving vegetable Liquors from the laft Stage of Fermentation, that is, Pu- trefadion or Corruption ; viz, by firfl: clarify- ing, and afterwards fecuring and defending them from the open Air, and too much Heat. Thus, for example, we can preferve the natural Juices of Quinces, Oranges, Lemons, Plants, found and uncorrupt, by fir ft clearing them of their grofier Parts by the Fiitre ; or in fome Cafes by Boiling and common Straining ; then putting them up in Giaffes, pouring Oil on the Top, and fetting them in a cool Place. And in the fame Manner we find fome of the more delicate and curious Wines are long prel'erved found and fprightly : for the grofier Feculencics being firft removed, the Oil poured on the Top prevents the external ^ Air from entering; and by keeping the GlafTes a) See §. 27. and hereafter 5 ’at^'). VI, and VII. Ses alfa *■ the Iiord Bacon'^ Syl-va Sylvarum pajjim, b) Exp. VII. VIII. K fro.m 130 Lecture the Seventh. from the Sun, or open Day, too much Heat does not come at them. Vhfical 32. (4) it IS here remarkable, what a large and Che- Qjanclty of Iblid, earthy Matter is naturally con- tamed in all fermentable Liquors. Thus, if a pellucid Solution of the fineft Sugar in Water be expofed to vinous Fermentation, it foon grows turbid, throws an earthy Skin to the Top, and depofites much terreftrial Matter at the Bottom in the Form of Lees. If the Wine be now drawn off clear and expofed to acetous Fermentation, here again it throws off much terreftrial Matter, both in the Form of a Skin at Top, and of Lees at the Bottom. Thirdly, if tranfparent Vinegar be ex- pofed to putrefactive Fermentation, here again it feparates a confiderable Qtiantity of Earth, both at the Bottom and at Top. All which fhews that the Separation of a grofs Matter is effential to thefe feveral kinds of Fermentation, and that a copious Earth may lie concealed in fermentable Juices, and tranfparent Fluids, till it finds an Oc- cafion of manifefting itfelf to the Senfes. Chan- Before we proceed to animal and mine- ^cedbyFer- Fermentation, it is proper to examine what mentation, ^^e the Changes wrought upon vegetable Sub- jects by vinous and acetous Fermentation. This we may find, in fome Meafure, by comparing Muft, or a bare Solution of Raifins in Water, with the Wine and Vinegar which the fame Muft, or Raifins and Water afford, in Vinifica- tion and Acetification *, and in this Light they may be compared by the bare Ufe of the Senfes; but their internal and effential Differences will better appear by a chemical Analyfis, or Diftilla- tion. 34. Muft, or a Solution of Raifins in Water, which makes a Kind of Muft correfponding to the natural Juice of the Grape, is a fweet, clam- my Of Fermentation and PutrefaSlion. 1 3 1 my and fomewhat odorous Fluid, which being committed to Diftiilation affords not the lead in- flammable Spirit. But after having pafTed thro’ the Courfe of vinous Fermentation, it acquires feveral Properties it had not before. For ex- ample: it is more tranfparent and thin-, lofes of its Sweetnefs j has fome Degree of Acidity and Roughnefs; proves more odorous, and affords a large Proportion of inflammable Spirit as ap- pears by the following Experiment* Experiment IV* ^hat vinous Fermentation produces an injlammahlc Spirit, 35. We took three Gallons of new Wine, procured from Raifins and Water in the manner of our firft Experiment, and committed it to the Alembic or Still, which being made to work gently, till the Liquor that came over, being thrown upon the hot Still-Head, would no longer take Fire by applying the Pdame of a Candle to the rifing Vapour, we thus obtained a con- fiderable Proportion of Brandy^ and a weaker Spirit, 36. This Experiment fhews us the common Method of making Brandies in Wine- Countries, or a Spirit from Malt, Melaffes, Cyder, i^c,ment, in others. For the fined French and Rheniflj Brandies, the Rums and the Arracks of the In- dies^ are obtained in the Manner of this Experi- ment ; all of them being ufually didilled a fecond time over, and made up^ as they call it, with . Water, or the weak aqueous Liquor of the fecond Running, as in our prefent Experiment, to a certain Strength, or fuppofed Standard, termed faleable Proof, K 2 37. This 132 Proof in Spirits •fjohat. Philojdphi- calVfe, Spirit of Wine honv btained. Lecture the Seventh. 37. This Proof is judged of by the Head, or Crown of Bubbles, rifing upon the Surface of the Liquor when fliook in a long (lender Vial, and by the Manner wherein thefe Bubbles vanifh. For if they are too large and vanifh too foon, the Spirit is deemed above Proof', if too fmall, and they go off too foon, it is laid to be below Proof But this is a fallacious Method of Judging; be- caufe there are certain knov/n Ways of making a Spirit bear this Trial, when it is in Reality either above or below Proof. P^or the proper Meaning of the W^ord i^s, that a Proof - Spirit fhould contain about one half Water, and the other half Alcohol a ). 38. The philofophical Ufe of the Experiment is to fliew, that an inflammable Spirit is produced by the Adtion of vinous Fermentation, from a vegetable Subjed and Water, wherein no Signs of any fuch Spirit before appeared. In- fomuch that this may be juflly efteemed the Criterion, or infeparable EfFedl, of vinous Fer- mentation. 39. The Ways of obtaining this inflammable Spirit, to the bed Advantage, will be confldered hereafter h),. In the mean time it may be ob- ferved, that this Spirit being rediflilled, fo as to de- prive it totally of its aqueous Part, is the Spirit of Wine, or Alcohol, vvhofe diflTolving Power was fhewn, in the iafl Ledlure upon Menftru- urns c ) ; and this Method is the only one that is known of procuring it. For no Subjeds but thole of the vegetable Kingdom are found to af- a) See this Matter farther explained in Lebt. XII. ExpAY. See alfo Led. I. Exp. VII. b ) Led. XI. and XII. c) See Led, VI, Exp. II. ford of "Fermentation and PutrefaBions 133 ford it ; and that only by means of a previous vinous Fermentation. 40. It fhould iikevvife be obferved, that thisT'^^^t^^ Alcohol is one of the mod eflential Parts of Wine ; the Spirit fo that, when it is withdrawn, the Wine lofes its Nature ; as we fee by the Remains of the pre- fent Experiment. And when properly ufed, it is a certain Remedy for mod Difeafes incident to Wines ; as keeping them found and free from Corruption. Whence we have another Rule for preferving vegetable and animal Subdances from Putrefadlion. For this Liquor proves a kind of Balfam to them all, and is accordingly ufed, with Succefs, for preferving even animal Subdances ; as we fee in anatomical Preparations, Experiment V. ^hat acetous Fermentation aholijhes the inflammable , Spirit produced by vinous Fermentation. 41. We put a C^art of fharp Vinegar into a Glafs Retort, and didilled, in a Sand-Heat, withy^/^^^^ Degrees of Fire,- into a Glafs Receiver, but Alcohol found not the lead inflammable Spirit come over; only an acid aqueous Liquor, commonly called diftilled Vinegar ; which, indead of burning, quen- ches Fire. 42. Hence it appears, that acetous Fermenta- , tion has a very diferent Effedt from the vinous; and that the inflammable Spirit produced in the jnent. former, is either concealed, altered, exhaled, de- droyed, or fome Way abolifhed, in the latter. A part of this Spirit is unquedionably exhaled by the Heat employed in Acetiflcation; yet Part alfo remains behind under a different Modification, fo as to be recovered by Art in an inflammable Form; as we find by didiiling the Sugar of K 3 Lead^ 12 ^ Lecture the Seventh. Lead^ which is only Lead dilTolved in Spirit of Vinegar. 43. Our Experiment affords us a Criterion of acetous Fermentation, as before we had of the vinous. For if an acid uninflammable Liquor comes firfl; over by D»ftillat‘on from a vegetable Subje6t, previoufiy fermented, this wdll determine that Fermentation to have been of the acetous Kind. 44 Thus, therefore, we are plainly led to allow of two very different kinds of Fermenta- tion, in the fame vegetable Subjed: ; and we con- ceive that fome other Species may be found upon due Enquiry. Experiment VL # That vegetable Matters turn of an animal Na^ ture by a hot Fermentation^ or Putrefaction, p r 45 We took a large Quantity of frefh, green Cabbage-Leaves, and prdied them hard down getables. With Weights in an open Tub, bored full of Holes on the Sides and fet in a warm Place. By Banding in this State for fome Days, the Leaves conceived a Heat in the middle, which fpread to the more external Parts, till at length' nearly the whole was converted into a pappy, putrefied Sub- ftance, whofe Confiftence would not well fuffer it to feparate into a thicker and a thinner Part. This Subffance being diftilled in a Glafs Re- tort, afforded the iame Kind of volatile Salt and Oil, as if it had been an animal Subfta nee 7 heExfe- 46. This Experiment is general, and fucceeds rimeni m all tender, juicy, vegetable Subjedls ; fo uM. acid and alkaline Tribe of Plants, the fweet and the bitter, the aftringent, and e- moliient, r^blve into this fame pappy, pu- trefied of Fermentation and PutrefaSilon. 135 treficd Subflan'Ce. We obferve it alfo in Hay that is (tacked wet; in Horfe-luter thrown on Heaps; in the Grape-Hu(ks, or Apple-Pumice, after prelfing for Wine or Cyder; and the larger the Heap, and the greater Weight the Matter fuftains, the greater the Heat; provided the Accefs of the Air be not prevented. 47. Hence we fee the Way employed by Na- /« jjfe, ture for changing all vegetable into animal Sub^ fiances^ or of reducing the Matters of both King* doms to a Similarity; fo that the one may be ufed for feveral Purpofes inftead of the other. And thus Nature annually makes large Quantities of Compoft, from the refufe Weeds, Leaves, Trafh of the Fields, Woods, and Gardens ; for this ve- getable Matter thus putrefying, and becoming fofc and pulpy, is eafily diluted by the falling Rains, and thence dirperfed over the Face of a Field, and carried into the Pores of the Earth. And thus the Chemift may, by Diftillation from fuch putre- fied vegetable Subjeds, procure volatile Salts and volatile Spirits, hardly to be diftinguifiied from thofe of Hartfhorn, at lead: the volatile Salt and Spirit fo obtained might ferve together with Sea-Salt, for making of Sal- Ammoniac For it appears that the Matter of the fixed Salt in Vegetables is, by this Operation, truly volatili- ^ zed. Whence not a Grain of fixed Salt can be pro- cured from the largeft Quantity of this putrefied Matter, provided the Operation were compleatly performed. 48. This Experiment has various Ufes, not only in Trades., but alfo in natural Philofophy and Medicine. And firfl, it fhews an artificial as well as natural Method of converting any, or all of the different Subjeds of the vegetable a) See he£i, XX. I. K 4 Tribe 136 Lecture the Seventh. Tribe into the fame undiftinguifhabie' Subftance, totally deftroyingall the fpecific Differences which before diferiminated that great Variety. And the fame Obfervation reaches allb to animal Bodies, as we fliall fee hereafter Inthcani. It alfo throws confidcrable Light upon the malOeco- p^ocefs of animal Digsftion, as performed in the Stomach and Inteftines ; it fhews us the Nature of Gangrenes, Mortifications, and carious Bones in the Body ; and the phyficai Realbn why no fixed Salt Is found in the Blood, Bones, or Flefh : All which Particulars may be farther iiluffrated and confirmed, by confidering the like Frocefs in an animal Subjed. II Experiment VII. animal Bodies naturally undergo a Fermenta- ticn^ or Putrefadiion^ after Death, Animal 50. If any large animal Body, as that of a . Putrefac- Horfe or a Dog, for example, be expofed in a non, diQ2Ld State to the open Air and ^the Summer’s Sun, it begins in a few Days to fwell, purge, and emit a naufeous Stench. At length the Form of the Carcafs is defroyed by the Commotion, and refolved into a putrid, fetid, fercoraceous Matter; a large Part in the mean Time flying off into the Air, fo as to leave but a fmali Proportion of a mucilaginous, pappy Subftance, which foon grows dry, or turns to a Kind of Earth. But a Quantity of this Matter being colleded before it grows dry, and diftilled, it is faid to afford the burn-« ing PhofphGrus^ as putrefied Urine is known tb do. Exp. VII. 51. This of Fermentation and Putrefaction. 137 51. This* Experiment or Obfervacion is uni- Extended- verfa), and holds .equally of Birds, Beads, and Fifh. Whence Rivers, the Ocean, and the At* mofphere itfelf, muft neceflarily be impregnated with fermenting, putrefying, and putrefied Par- ticles, which mixing with other Matters, and being difperfed through the immenfe Bodies of thofe Fluids, they undergo therein fuch Changes, whether by uniting with the Salts of the Air and Ocean, or otherwife, as prove not unfrequently deflrudive or noxious to the Creatures that in- habit thofe Elements. For this putrefied Mat- ter appears to be in itfelf a Kind of Poifon, in- feding the Air wherein it fpreads ; fo as to oc- cafion peflilential Difeafes near the Places where great Battles have been fought, when the un- buried Carcafes of the Slain thus refolve and go off into the Atmofphere. Many other Inftances we have of the poifonous Nature of putrefied ani- mal Subfiances, in rotten Eggs, mortified Flefh, and the like : whence this leems to be another particular Species of Fermentation, 52. It has been difputed, whether there be a Fermenta- real Fermentation in the prefent Cafe. But (up- tion deter- pofing this not to be a Difpute about Words, it fhould feem that there is a proper Species of Fermentation, peculiar to animal Subjects, as there is one peculiar to Vegetables. Till this Point be fettled, we fliould not lay down vegetable Fermentation, as the Ted and Standard of Fer- mentation in general, and fo judge of all other Kinds according as they approach to, or recede from, this Standard. For want of didinguifhing in this Cafe, all true Fermentation Teems denied to the Blood and Juices, circulating in a liv- ing animal Body, as well as to the Sap of Ve- getables. But were the Enquiry into Fermen- tation profecuted in its full Latitude, and not arbitrarily 138 Ch^mfiry of Nature in Bodies. Mineral Fermenta- tioJi, Lecture the Seventh. arbitrarily confined to any fingle Species, per- haps many natural and art’ficial Operations would prove to be adtual Fermentations. To fay that there is no Fermentation in the Blood, because it affords no inflammable Spirit upon Diftillation, is in effedl the fame as to fay that B'ood is not Wine. Whereas the Queftion is not whether there be a vegetable Fermentation in the Blood, but whether there be not an animal one \ the Criterion whereof is the Produdlion of a volatile urinous Salt, as the Produdion of an inflammable Spirit is the Criterion of vinous Fer- mentation. 53. And here is a Door opened for enquiring into the Chemiftry of Nature, as it is exercifed in the Bodies of Men ; fo as to difcover the na- tural Means whereby vegetable Subftances taken in at the Mouth, by the Way of Aliment, are prevented from running into vinous or acetous Fermentation •, but are, on the contrary, changed into a balfamic, undtuous, and milky Liquor, or Chyle, that turns red in the Arteries, recruits the Blood, and nourifhes the Body. For all this feems to be the Effedt of a peculiar mentation^ the Laws and Procefs of which are little confidered. And in this View, the feveral Juices of the Body, as the Saliva, Bile, Pan- creatic Juice, &c. may be regarded as animal Menjiruums^ adled upon, and made to adl in the Body, by determinate Motions, for determinate Ends. Ill, Experiment VIII. That there may be a Kind of Fermentation in mine- ral and metallic Bodies. 54. We took an Ounce of Lead and as much Billnuth, and melted them together in an Iron Ladle; permentation and Putrefaction. 139 Ladle; then heating two Ounces of Quickfilver in another Ladle, we mixed all the three me- tallic Matters together as an Amalgam ; which, when cold, appeared perfedly uniform or homo- geneous, and totally pafled thro’ the Lores of Leather in a running Form. But this Mixture being fuhered to cool, and (land quiet for fome Hours, a grofs Matter feparated from it by De- grees, and floated upon the reft ; which was left io thin and fluid, as to pafs through Leather, leav- ing the grofs metallic Matter behind. 55. Hence it fliould feem that even metal- pxfe- lic Matters may have their peculiar Fermenta- riment ex- tions, as well as vegetable and animal Subjedls. For when the prefent Experiment comes to be carefully confidered, it appears to have all the Requifites of Fermentation. For here is, (i.) a fluid Form, (2.) an uniform Matter, (3.) an inteftine Motion, and (4 ) an adlual Separation of a grofler Matter, leaving a thinner behind. All which Particulars we have found to hold in the feveral Species of Fermentation above exami- ned. 56. There are many more Inftances of an apparent Fermentation in mineral Bodies, one or two whereof it may be proper to mention. Thus, if an aqueous Solution of the common green Vi- triol be expofed to the Air in the Summer-time, and kept continually fupplied with frefh Water as the former exhales, the grofter metallic Part of the Vitriol will fubflde, and the reft gradually fhoot upwards all round the Veflel, in Form of an undluous, crufty Matter ; till the whole Body of the Vitriol is thus fuccefiively fo altered that' the Part fhot into the crufty, undtuous Form, v/ill neither become Vitriol again, nor corrode any frefh Metal ; and in ail ’ other Refpedfs it appears a different Thing from Vitriol. And hence 140 • Lecture the Seventh. hence feem to proceed the Complaints of the Makers of Vitriol, that in rainy, windy, and cloudy Weather, their Vitriol-Stones, which lie open to the Air, .will not fometimes yield a folid cryftal- line Vitriol, but only an unduous Matter. This may therefore appear to be a Fermentation in all its Forms, as being attended with a fpontaneous inteftine Motion, a fpontaneous Separation of confbituent Parts, and a remarkable Alteration of the Subjed. 57. It alfo makes to the prefent Purpofe that folid and hard Pyrites, or Vitriol-Stones, being expofed to the Air and moiftened with Water, will, like a vegetable Subjed^), grow hot, fume, and even take Fire, as was obferved in our fourth Ledure, and afterwards, afford Vitriol •, a Thing very different from the Stones them- felves^j. So that, upon the whole, we may conclude, that in a proper Senfe, there is an adual Fermenlation cxercifcd, not only in the vegetable and animal, but alfo in the mineral Kingdom. V. Axioms and Canons. I. All the Inflances being duly confidered, and a large View of Things taken in, we may define Fermentation^ in general, a fenfible inter- nal Motion of the confiituent Particles of a moifl, fluid, mixed, or compound Body ; by the Continuance of which Motion, thofe Particles are gradually removed from their former Situations, or Combinations; and again, after fome vifible Separation is made, joined together in a diffe- rent Order and Arrangement. And thus the a) See above, Exp. VI. ^ ) See Leet. IV. Exp. V. whole of Fermentation and PutrefaEHon. whole Procefs of Fermentation confifts of two different Operations, viz, an Analytical one, -whereby the Particles are refolved, and a Syn^ thetical one, whereby they are new ranged : So that whenever thefe two different Effects are found to be produced, in diredl Sequence, with the Circumftances above deferibed, we need not fcruple to call the Operation by the Name of Fermentation^ whether it happen in the Blood, ^ or other animal, vegetable, or mineral Sub- ftances a\ 2. That all feparable, mixed, or compound Bodies may be the Subjects of this general O- peration ; but that the eafier they are feparable by Means of Water, Air, and Hear, the more readily they ferment h). Thus the fweet or fac- charine Part of Malt, more readily diflfolving in warm Water, ferments eafier than unmalced Corn, which is more clammy and will not difffolve fo foon. • And hence the Flefh of ani- mal Bodies putrifies fooner than the Bones. And this appears to hold in all Inftaiices c), 3. That this general Fermentation is divifi- ble into many diftin6l Species, particularly in- to vegetaUe^ animal^ and mineral d)\ the vege- table Kind again into vinous^ acetous^ and pi- trefa 5 Hve ; the vinous again into mucilaginous, mouldy, and putrefadive ; and fo of the ace- tous, (Ac, Whence we may deduce a Canon for adjufting all the different Species of Fermenta- tion *, which being once fixed might put an End to infinite hypothetical Difputes upon this Subjed, and lead to farther Difeoveries both in Nature and Art. a) See the whole Ledure, ^afjim. See Exp, I. VI. c) See Exp, 1. VI. VII. dj See the whole Ledure, pajfim. I4I 4, That 142 Lecture the Seventet. 4.. That it is in the Power of Man to pre- vent, flop, and rcgiiLle thefe natural Operations at any afTigned Point of Time. Indeed it is thus we come by our Wines and Vinegars ; it is thus that Men difeovered the Art of Embalm- ing ; It is thus we prefer ve many vegetable, and animal Juices, in their natural or unfer- mented State ; It is thus we preferve Yeaft, and Wine-Lees, Subje6ls extremely apt to pu- trefy ; It is thus we can at any Time flop the Courfc of vinous Fermentation, and produce a fweet, or half fermented Wine ; It is thus we ‘cure the Fretrings, or other Difeafes of Wines ; and thus we flop Mortifications in the Body, and Caries in the Bones. And mod of the Ar- tifices employed for thefe Purpofes, depend upon a Knowledge and Regulation of the phyfical Caufes and Inflruments that produce the Change; which Caufes and Inflruments, as we above dif- eovered, are chiefly. Hear, Moiflure, and the external Air a), 5. That a faccharine Matter is the Balls of * Wines, Vinegars, and inflammable Spirits b). 6 . That a great variety of found, perfeft, and wholefome Wines may be made, in Countries that do not naturally afford Grapes, by a prudent Ufe of Sugar, or Raifins and Water c). 7. That the Matters called Ferments are of Ufe in beginning, regulating, and determining the Species of Fermentation c). Thus frefh Yeafl: determines the Fermentation of Wheat - Flour to make our common Bread, which would prove of another Kind, if the Flowers or Lees of Vinegar were ufed. And thus fpecifle or de- Cl ) See the whole Lefture, h) See I. 15. &;c. ■ c) See Exp. I. terminate of Fermentation and PutrefaBion. 143 terminate Ferments have their correfpondent Ef- fects. If Sugar, Honey, Manna, Treacle, or new Wine be added to Vinegar, themfelves are foon changed into Vinegar, without (lopping to make Wine ; becaufe the acetous Ferment, or Vi- negar, over-rules them. And fo Vinegar is foon- eft made in a Cafk that has before contained the fame Liquor. And if the beft Wine were put into a Cafk that had held putrefied Vinegar, the Wine would not now make Vinegar, but immediately run into Corruption. So great and fo decifive a Power have fpecitic Ferments ; the Ufe whereof is therefore evident, and may afford confiderable Rules in Chemiftry, pra( 5 lical Phi- lofophy, and ilrts. 8. Thar the Degrees of Fermentation differ with the Degrees of Heat employed a ), Thus we faw vinous Fermentation required a lefs De- gree of Heat than the acetous ; the acetous a lefs than the putrefadlive; which latter may even confift with a Degree of Ignition b). 9. That a particular Kind of Fermentation may be carried on in the living Bodies of Ani- mals and Vegetables, which are largely fup- plied with the requifite Inftruments of Fer.men- tation, viz. Water, Air, and Heat: And in Fact both Vegetables and Animals appear to have an inteftine Motion in all their circulating Fluids, which continually depofice a groffer Matter in the Canals and Parts they move through. Whence, by our Definition of Fermentation c)^ this natu- ral A6t may be accounted a Species of Fermenta- tion, producing a Change in the nutriiuental Mat- ter of Vegetables and Animals, and converting it into their own Subftance. a) See Exp. I, II, III, IV, V, VI, b) See Exp. VI. c) See Jx. I. 10. That 144 Lecture the Seventh. 10. That when Vegetables or Animals die, there foon begins a different Kind of Fermenta- tion in all their Parts *, tending now not to the Re- pair, but to the entire Deftrudlion, of their orga- nical Veffels, the confufed Mixture of their folid Parts and Juices, and a Volatilization of their whole Subftance^^J. 1 1 That dry or folid Bodies cannot, in that State, undergo a proper Fermentation : for tho* they may in that State be feparated into minute Particles, yet they cannot range themfelves toge- ther in any new Order, nor depofite a greffer Part, without being agitated by fome Fluid, or fufpend- ed therein for fome Time. And hence, in over- heated Mines, the Ore is thus analytically de- ftroyed, and cannot range itfelf into a metalline, or any other regular Order again, for want of the requifite Moifture or Fluidity *, whence the Matter appears like a Heap of rotten Earth, or what the Miners call Dead Metal h) of which we have a remarkable Inftance in the over-heated or fired Mixture of Sulphur and Iron-Filings c). 12. That the terreftrial, marine, and atmorphe- rical Regions have each their proper Fermenta- tion^ different in Kind, and fubdivifible into par- ticular Species, whereby the Changes of all Bodies one into another are naturally performed d) % And that in Imitation hereof, by a thorough Knowledge of the natural Agents that produce thefe grand Effedls, Art likewife may produce extraordinary Changes in Bodies e). a ) See Exp. V. VI. F) See Exp V III. c) See XIX Exp.Wl. d) See the preceding Ledures upon the Elements, See alfo that upon Menjlruumsy and the leveral Experiments in the preient Lediure, e) See Ledi, I. pajjim. L E C- C'145 1 L E C T U R E VIII. CONTAINING Analytical Chemiftryi or^ the Art of Ana-> lyf ng Vegetable^ Animal, and Mineral Sub- fiances, and refoking them into difierent Parts or Principles, • L i. H E whole of Chemiftry may be com- Suhjeei, I prehended under the Arc of refolving Bodies into their Principles, and of compofing new Compounds from thofe Principles, by Means of the common Elements, Fire, Air, Water, Earth, and particular Menjiruums. We fhall accordingly in our prefent Ledure, endea- vour to enquire into the Bufinefs of chemical Re- folution, in the vegetable, animal, and mineral Kingdoms, with a View to difeover what ufeful Principles may be thence obtained ; intending, in our next Ledure, to confider the correlative Bu- finefs of Compofition : fo that the two together may contain a fummary Account of the Nature, Office, and Ufe, both of analytical and fynthe- tical Chemiftry ; of which the one takes Bodies to Pieces, or reduces them to their component Matters, and the other, by putting thefe Matters or different ^Pieces together again, in various Manners, forms a large Set of new Produdions, that would be unknown to Nature without the Interpofition of Art. And fuch Productions, for Inftance, are. Brandy, Soap, Glafs, &c. 2. But before we enter upon the Enquiry it- Prinripi^^ felf, it is neceifary we Ihould diftinCtly explain ^ujkat. L what 146 Lecture the Eighth. what we mean by the Word Principle^ about which many Difputes have been railed We mull therefore oblerve, that the more intelligent among the modern Chemifts do not underftand by Principles thofe original Particles of Matter, ot which all Bodies are by the mathematical and mechanical Philofophers fuppofed to confifl. Thofe Particles remain undifcernible to the Senfe, tho’ affilled with the molt finifhed Inftruments ; nor have their Figures and original Differences been determined by a juft Induction. Leaving, therefore, to other Philofophers the fublimer Dif- quifition of primary Corpufcles, or Atoms, of which many Bodies and Worlds have been formed in the Fancy, genuine Chemiftry contents itfelf with grOiier Principles, which are evident to the Senfe, and known to produce Effe6ls in the Way of corporeal Inftruments. And thefe groffer Principles are every Way fufheient to anfwer the Purpofes of philofophical Chemiftry, which con- fifts wholly in Experiment, and the Explanation of Fafts and fenfible Operations. Where, by the Way, it may be obferved, that Chemiftry is an Art extremely well fuited to the Nature of Man, as it requires nothing more than the Ufe of fuch Faculties as he evidently finds himfelf poffeffed of. But when once we leave the Oracles of Senfe, and introduce metaphyfical Speculations and No- tions into Chemiftry, it then becomes a corrupt Fountain of Flypothefis and Illufion. To redi- fy Chemiftry, therefore, the Rule is to keep clofe to the Information of our Senfes, the Laws of Induvftion, and the Ufe^of material and fenfible Principles. 3. Thefe fenfible Principles, fo far as we know them, are fignihcantly expreffed by the common Words, fVater., Earth Salt., Sulphur., and Mer- airy : to which might be added the Air, if a Way were of Analytical Chemiftry. 147 were known to fix it, fo as to render it more fen- fible, tangible, and corporeal 4. By Water we underftand a fenfible, tranf- Water. parent Liquor, without Tafle or Odour*, that freezes with a certain Degree of Cold, and liqui- fies from that State with a certain Degree of Heat ; that extinguilhes Fire, By the Chemifts this is otherwife called Phlegm. 5. By Earth we underftand an infipid, dry. Earth. powdery Subftance, that will neither dilTolve in Water, nor burn away in a ftrong Fire ; but, with the Addition of fixed Salt, melts into Glafs. 6. By Salt we underftand any fenfible Body^^^^* that readily diffolves in Water, taftes fharp or pungent upon the Tongue, and has a great Dif- pofition to unite with Earth, fo as to appear in a Iblid Form \ as in common Salt, Alum, ^c. 7. By Sulphur we mean any Matter that will readily burn and difappear in the Fire, and that will not eafily, or of ftfelf, mix with Water. 8. And laftly, by Mercury we underftand a Mercury. fenfible Body that has the Fluidity, Gravity, and Appearance of common Quickfilver. 9. We do not lay down thefe as adequate Defi- nitions, but only -as fenfible Marks whereby the Things meant may be readily known and diftin- guifhed for ordinary Ufe. Juft Definitions can be drawn only from a full and perfedt Difcovery of the Nature and Properties of Bodies, which we are far from knov/ing ; nor do we ufually meet with any of thefe Principles in a pure and per- fed State, unmixed with other Bodies. When they appear to the Senfes to be thus far purified, they are the Principles \>e mean, or what we See Le^. III. Exf X. L 2 empha- 148 Worm- fiuood fwaly/ed. 7he Expe- riment 7T ge- neral Lecture the Eighth. I emphatically call the Chemical Principles-^ tho’ they may be every one of them deftru6lible, as to that Form : but then they ceafe to be che- m.ical Principles. 10. And thus we have endeavoured to fettle the chemical Meaning of the Word Principles^ and to lay down Marks or Criterions for difeover- ing and diftinguifhing them, when we meet with them hereafter in the following Experiments. 11. Thefe Experiments we fhall endeavour to make as general as we can, and give an Example in each of the three Kingdoms, as they are called, viz, the Vegetable, Animal, and Mineral Expe r I me n t I. "fhat Vegetables are refoluhle^ by Fire^ into four of the chemical Principles^ viz. Water, Oil, Salt, and Earth. 12. We took two Pounds of common Worm- wood cutfmall, which we put into a Glafs Retort in a Sand-Heat, and diftilling with Degrees of Fire, and a frequent Change of Receivers, we ob- tained (i.) an aqueous Liquor, and (2.) an Oil. Then taking out the Remainder, and burning, or calcining it, in the open Air, it turned to a grey Kind of Afhes ; which being boiled in fair Water communicated thereto (3.) a Salt. This Salt we obtained in a dry Form, by letting the Solution ftand at Reft for fome Time, then decant- ing the clear Liquor, and exhaling the fuper- fluous Water. And (4.) we found an earthy Subftance remaining at the Bottom of the Wa- ter wherein the Afhes were boiled, 13. This Experiment being well attended to is very inftruftive, and fliews that the chemical Princi- Of Analytical Chemijlry. 149 Principles above-mentioned are not imaginary or fictitious Things ; but Things palpable, and evi- dent to the Senfes. For here we have a Water, .an Oil, a Salt, and an Earth, all afforded us by a vegetable Subject. And the Experiment may be made general without much Variation : for all the vegetable Subjects hitherto examined, in this Manner, refolve themfelves into the fame gene- ral Principles, which differ only (i.) in Refped of the Kind of Salt ; that being in fome more volatile, in others more fixed ; in fome acid, in others alkaline; and (2.) in the Nature or parti- cular Properties of the Oil ; which in fome Plants is thinner and more fluid, in others more grofs and^vifeous; But all the Principles thus obtained agree to the general Definitions above laid down So that there appears to be no Vegetable in Nature, but what is thus refo- luble into Water, Oil, Salt, and Earth. 14. To obtain thefe Principles pure, we muft TbeWater (i.) feparate all the Oil that may chance to main fufpended in the Water, This is effeded, in a confiderable Degree, by the Filtre ; which being kept continually filling up, fo as that the lighter Oil may not come in Contact: with the Paper, the aqueous Part is thus tranfmitted to- lerably free from Oil. (2.) But flill there may remain fome fmall Proportion of oily and faline Matter therein } If the faline Matter be acid, the way to deflroy it is, to mix a little Chalk, or any pure and fixed alkaline Salt, with the Li- quor. By this means alfo more of the Oil will be fet free ; fo that being now filtred again, and gently diflilled with a foft Heat, the aqueous Part will rife much purer, and pafs for Water in the Judgment of the Senfes. (3.) the Plant » Sea. 4—8. was 150 Tfo Oil ^urijied. 7he Salt fiurified. Lecture the Eighth. was alkaline, and an alkaline Salt abound in the aqueous Liquor, let it be made neutral with one that is acid; and thus again the Water may be feparated pure, by means of the Filtre and Re- diftillation. And this is the Method of mani- fefting CO the Senfes, that the chemical Principle IVatcr is naturally lodged in, and may be fepa- rated from all vegetable Subftances 15. In order to procure the Sulphur^ or oily Principle, pure, the un6luous Matter, obtained by this general Procefs, may be wafhed from its adhering Salts and grofler Earth in warm Water, barely by fhaking them in a Glafs to- gether, and then feparating the Oil from the Water by means of the common feparating Glafs; where, if the Oil be fpecifically heavier than Water, it finks to the Bottom, and may be fuffer’d to run out firft *, if fpecifically lighter, it floats a-top, and may by the Finger applied to the Bottom of the Glafs, or fome other Con- trivance, be kept behind, when all the Water and feculent Parts are run from it. 16. To obtain the faline Principle pure ; (i.) if it be of the volatile urinous Kind, the Matter may be diflTolved in Water, and made to pafs the Filtre ; then fet in a gentle Heat to fublime : for it will thus rife and leave the W'ater behind, as being much more volatile than that. (2.) If it be required ftill purer, the befl: Method hi- therto known is, to fublime it from finely pul- verized Chalk ; then to faturate it with a clean Spirit of Sea-Salt, fo as to convert it into a true Sal- Am.moniac ; which being mixed with Salt of Tartar, and again fee to fublime, the volatile Salt will rife highly purified, fo as long to retain its Whitenefs. (3.) But if the faline * See LcSl. V. Exp. I. Matter Of Analytical Chemiftry. 15s Matter obtained be of the fixed Kind, the Method of purifying it is, to diffolve it in fair cold Water ; fufl'er the Solution to fubfide ; then decant the clear Liquor, and evaporate it in a clean Iron Pan or Glafs Veffel, conflantly flirr- ing it, till it becomes dry and white : (4.) Or to purify it llill farther and render it periedly white, let it be put into a clean Crucible, and expofed for a while amidfl the Flame of burning Charcoal, but without Melting it. 17. Laftly, to obtain the earthy \nTh Earth its Purity, let it be thoroughly calcined, boiled in feverai Waters, in order to get out all its Salt; then dry it over a clear Fire, or in the Sun, And if thefe feverai Operations be performed in Perfedlion, we then obtain what we pro- perly mean by the chemical Principles of Vege- tables. 18. And tho’ it be not always neceffary for the Purpofes of Chemiftry, or the common Calls of Life, to bring thefe Principles to the Degree of Purity here mention’d, yet there are many Cafes that abfolutely require them to be fo puri- fied ; otherwife the Operations in which they are employed may eafiiy mifcarry : and this we defire may be noted as one confiderable Reafon of the Failure of particular Experiments and Ope- rations, both in Chemiftry itfelf, and in many of the chemical Arts ; particularly the Art of Glafs, Diftillation, iPc. ig. The Ufes of this leading Experiment are Ups ofths numerous ; we fliall touch upon a few of them. And firft, we may learn from it that thefe che- mical Principles are found in different Quanti- ties in different Vegetables, or in the fame at different Seafons or Times of Growth. Thus, for inftance, Olives, Almonds, Mace, ipc. con- tain fuch an Over-Proportion of Oil, to the other L 4 Prin- 152 Lecture the Eighth. Principles, that it may be copioufly got from them barely by Prdfure. I'he Vine in the Spring affords a larger Proportion of fixed alka- line Salt than at any other Seafon f and the fame holds of the Wood ufually burnt for Pot-afh. And thus we find that the aqueous and falihe Principles prefide in Vegetables in the Spring, but the oily in the Summer and Autumn •, that all young Plants abound more with Water, than fuch as are full grown ^ and that Oil is moil plentifully contained in the oldefl Trees, and thofe of the colder Climates. Whence we are direded to the proper Times, Seafons, and Places for felling the Timber defigned for Pitch, Pot- afh, Fewel, and Charcoal. 20. By applying this Experiment to different Vegetables it has been found, that Vegetables are naturally diflinguifhable into two grand Tribes, viz, the Acid and the Alkaline ; the firft affording a volatile Acid, and the other a volatile Alkali, upon dry Diflillation. Thus Guaiacum, Cedar, Box, Cinamon, Cloves, Sor- rel, Mint, Baulm, ^c, afford an Acid ; but Garlick, Leeks, Onions, Horfe-radifh, Scurvy- grafs, Muftard, ^c, afford an Alkali ; which, when redfified, is hardly diflinguifhable from that of animal Subftances, fo as nearly to re- femble the Spirit and Salt of Hartfhorn a), 21. This Experiment alfo fliews us the Me thods of making or procuring Tar, Charcoal, fixed Salt, and elementary Earth, from Vege- tables •, four capital Things in Arts and Trades. Tar is the fcorched Oil of undtuous Wood, forced out by Fire, as the grofs Oil is in the prefent 'Ex ferment h). Charcoal is Wood burnt clofe a) See Le^. VII. Exp. VI. b See alfo II. Exp. III. to of Analytical Chemifry. to Blacknefs a) \ Soap, a Mixture of fixed Salt and Oil ; Glafs, a mixture of Earth and fixed Salt and elementary Earth makes all the Tefts and Coppels for refining of Gold and Silver. 22. j^gain, the prefent Experiment fhews us the Nature of vegetable Fumes, by which, in the Way of animal Curation, Fifh and Flefh are long preferved, free from Putrefadtion or Corruption. For where-ever green Wood, or any acid vege- table Matter is burnt, the acid Particles rife With the Smoke, and in this Form penetrate and lodge in animal Subftances expofed thereto *, fo that this Smoke a6ls upon them in the fame Manner as the Fume of Spirit of Sea-Salt or Ni- tre would do. And whether it be not a nitrous Acid which thus tinges the Hams, Herrings, Cfc. red in drying, we recommend to farther Exami- nation. 23. Our Experiment alfo confirms what was before obferved that the Force of Fire is not fufficient to reduce a vegetable Subfiance to Afhes without the Help of the Air, and that fo long as the fixed Oil, which caufes the Blacknefs, re- mains in a vegetable Coal, it will afford no fixed Salt by Decodlion in Water c). Whence for mak- ing Pot-afh, and all the fixed Salts, to Advan- tage, .we have this Rule, thoroughly to calcine the Subjedl, fo as to leave no fixed Oil behind. 24. And hence we are alfo inflrudled in the phyfical Nature of a vegetable Coal,' and fee how it may have fuch confiderable Effedfs upon Metals, in the Way of zFlux\ fince we find it contains a fixed Oil, firmly united to the Matter of a fixed Alkali ; whence, to ufe this Coal as a Flux, is the fame Thing as to ufe a fixed Salt a) See alfo Lea. II. III. h) Lea. II Exp. IV. c) Sec Lea, II. Exp, IV. ‘ • in- 153- 154 - 'Bone ana> iyfcd. V:e Expe- riment ex- tended. : Lecture the Eighth. intimately united with a fixed Oil, which ope- rates powerfully upon Ores, as we have formerly ihewn And fo\much for the Amlyfis of Ve^ getables. II. Experiment II. That animal Matters are refoluhle^ by Fire^ int& the four chemical Principles^ Water, Oil, Salt, and Earth. 25. We took four Pounds of animal Bones, that had been well boiled to get out their Mar- row or Fat, and then thoroughly dried again ; and breaking them into fmall Lumps, we put them., dry 'as they were, into an earthen Retort, luted on a Glafs Receiver, and diflilled, wdth Degrees of Fleat, in a naked Fire. There firft came over in Drops an aqueous limpid Liquor, which we referved apart, . by changing the Re- ceiver. Then increafing the Fire there came over white Fumes, a volatile Salt, and a Quan- tity of Oil. The VefTels being fuflered to cool , we found the Bones turned black in the Retort ; but being calcined in a naked Fire, with the AdmifTion of the free Air, they turned to white Afhes. Then boiling thefe white Afhes in Water, we found by Evaporation that they communicated no fixed alkaline Salt thereto. 26. 'I'his Experiment is general, or fucceeds, with little Variation, in all other animal Sub- je6ls, v/hether they be Flefh, Blood, Serum, Fifh, Birds, Snakes, the Whites of Eggs, Horn, Hair, Hoofs, Silk, or the like *, the principal Difference being only, that thefe Subftances * See Lea. I. Exp. III. See alfo hereafter the Letlures isipon Mineralooy and Metallurgy. refpedively of Analytical Chemijlry. 155 refpecflively contain more or lefs Earth, Water, Salt, and Oil. Thus Blood being diftilled in its natural State, or as it is drawn from the Vein of a healthy Perfon, will yield about fevcn-eighchs of its Quantity in Water. And if any animal Sub- je6l be not well purged of its Oil, by boiling in common Water, before it is committed to Di- ftillation, it thence affords a greater Quantity of a burnt empyreumatical Oil, that ftrongly taints and impregnates the volatile Salt and Water, with a naufeous Scent and Tafle ; which are hard to get rid of, even by repeated Redfifications. 27. The Principles feparated by the p refen t Experiment appear to be, in general, the fame' with thofe before gained from a vegetable Subje6l. They may be feparately purified and made ele- mentary, after the fame Methods as we there laid down. And thus, by comparing the Pro- ductions of both Procefies together, we fhall find that we have a Water, an Oil, a Salt, and an Earth in both Cafes. 28. The two Waters feem fcarce to differ, when reduced to the fame Degree of Purity ; no more do the Oils and the Earths ; but all the Salt in the prefent Cafe is volatile *, the Aflies containing no fixed Salt at all : whence this ap- pears to be the principal chemical Difference betwixt vegetable and animal Subjecfi:s, that the vegetable Kind yield a fixed Salt by Calcination, and the animal Kind, one that is volatile by Di- flillation. But this holds only of the acid Species of Vegetables •, for the alkaline Species yields little or no fixed Salt upon Calcination. So that betwixt the alkaline Tribe of Vegetables, and the whole animal Kingdom, there feems to be little Difference ; either in this, or any other chemical Refped But tho^ fome Difference ^ See lea, VII. Ext, VI. fhould 156 Lecture the Eighth. fhould be found betwixt the animal and vege- table Oils, as there is thought to be in the Making of Soap, and fome other Inftances ; yet the Principles of animal and vegetable Subjefts may be juftly reputed the fame, as both equally agree to our general Definitions of Water, Oil, Salt and Earth a) But when the feveral Prin- ciples of Vegetables and Animals are reduced to the fame Degrees of Purity and Finenefs, there feems, fo far as our Trials have gone, to be no fenfible Difference between them. Thus the pure elementary Earth of Vegetables ferves for the making of Tefts and other Purpofes, as well as the elementary Earth of Animals \ folid Soap is made of vegetable Oils, as well as of animal Fats ; and the volatile Salt of alkaline Vegeta- bles, or even of acid Vegetables when putrified, is not to be diftinguifhed from the volatile Salt of Animals, when both are thoroughly purged and purified. ^ 9 * the Labour and Difficulty required, malTrin- to bring thefe Principles to a high Degree of ciples Purity, has proved a chief Caufe of their being purified- thought different ; for we fee that the Oil tena- cioufly adheres to the volatile animal Salt* and thus adds fome Qualities that do not properly belong to that Salt. But if a volatile animal, and a volatile vegetable Salt, be each feparately converted into Sal-Ammoniac, by Means of Spirit of Sea-Salt, no fenfible Difference can be found betwixt them. And thus, if a vegetable Oil and an animal Oil were equally purified, fubtilized, and freed from all the Matters that do not effentially belong to them, they would not fenfibly differ. At leaft, this feems confirmed by feveral Experiments hfi d) See above, §4—8.^ h See Dr. Cox% Papers in the Philofcphtcal Tranfadions, 30. And of Analytical Chemiftry. 157 33. And hence may fome Advantages be rived to Arts and Trades, by making the Sub- jed:s of one Kingdom ferve for thofe of the other, where the one is cheaper than the- other. Thus, as we before obferved a volatile Spirit and Salt, like thofe of Hartfhorn, may be drawn from the alkaline Species of Vegetables, and all putrefied Plants ; at leaft from Bones, purged of their Fat by boiling in Water. 31. The prefent Experiment has many other Ufes and among the reft remarkably (hews how a perfectly dry, infipid, fcentlefs, and folid Bo- dy may yield a great Variety of Taftes and Odours, barely by being applied to the Fire. For the impure Water, the volatile Spirit, the Salt and the Oils, have each a particular Tafte and Odour. And tho’ the Subjcd itfelf were fixed, we fee it neverthelefs affords feverai vola - tile Matters. And as this fixed Subftance was originally compofed of a fluid Matter, we are hence taught that the animal Solids and Fluids have the fame common Nature ; their Difference confifting only in a greater or lefs Proportion of Water and Earth. For Blood, upon the like Analyfis, affords more Water and lefs Earth than Bone. 32. This Experiment likewife fhews us that a Bone may be entirely divefted of its Water, Salt, and Oil, without lofing its priftine Fi- gure and Dimenfions. For after thofe Principles are feparated from it, the elementary Earth, tho’ abfolutely dry and friable, ftill hangs toge- ther in the natural Form and Figure of the Bone ; which thus remains exhaufted of all that Matter, which the Fire was able to carry off, without affeifting the elementary Earth itfelfi * See VI. VI. Whence 1^8 LecturetheEighth. Whence we evidently fee that the Ufe of this elementary Earth, in vegetable and animal Bo- dies, is to afford a Lodgment, a Support, or Skeleton to the other Principles, which are much more diffipable and deftrublible than itfelf. 33. And as our Experiment fucceeds alike in all animal Matters, and even in the Jelly ob- tained from a Bone by long Boiling, till the ele- mentary Earth is elixated, or drained of the other Principles *, v>/e hence learn that the Matter of thefe other Principles proceeds only from the Juices of the Body, where, as well as in the Jelly, they appear in an almoft infipid and in- odorous State, yet are capable, by Diftillation, of affording Subftances fo highly fapid and odorous, as we find the volatile Salt and Oil to be. Whence this Conclufion naturally follows, that thefe Iffinciples did not exift in a volatile State in the Body, as requiring even a greater Degree of Heat, than that of boiling Water, to fepa- rate them. 34. We may farther obferve that the prefent Experiment affords us the moft volati'e Sub- -ilance hitherto known ; for well-purified animal Salt is more volatile than Spirit of Wine, and rifes in Diftillation before it. Hence this Salt readily evaporates in the open Air, and being laid upon the Palm of the Hand goes off infen- fibly, without any Effedt *, tho’ if it were preffed clofe to the Skin, by a (licking Plaifter, it would prove corrofive •, and in this Manner it is fome- times ufed, (or making Iffues in Children, inftead of the ftronger Caufticks. III. Ex- of Analytical Chemiflry. 159 III. Experiment III. ^hat certain mineral or metallic Bodies may contain four of the chemical Principles^ viz. Sulphur, Salt, Earth, and Mercury. 35. We took two Ounces of native Cinnabar Cinnahar reduced to fine Powder, and mixing it with fix anahfed. Ounces of Quick- lime, we put the whole into an eathern Retort, and diftilling into a Bafon of Water, we found a confiderable Quantity of running Mercury at the Bottom thereof The Matter remaining behind in the Retort being boiled in a Lixivium of Pot-afh, and the Solu- tion precipitated with Allum, lets fall a fine Kind of Brimftone called Lac Sulphuric^ which will fublime into true Flowers of Brimftone, that may be melted, and run into a Roll. This Brim- ftone being burnt, in the common Method, un- der a Glafs Bell, refolves into an acid Liquor, leaving an uninflammable, fcurfy, terreftrial Mat- ter behind ; which being treated as an Ore, fome- times affords a fmall Proportion of Metal, either Iron or Copper. 36. We have here an inflrudlive Experiment, which being fully explained might lead to con- fiderable Difcoveries. It fhews that a true run- ning Mercury may lie concealed in metallic Ores, or ftony Earths ; for native Cinnabar is but an Ore of Mercury, confifting, as we fee, of two different Matters, Sulphur and Quickfilver, which * We endeavoured to feparate the Sulphur from the Cin- nabar, by boiling fome pulverized Cinnabar in a ftrong lJxi~ tvium of Pot afh and Quick-lime, expefting the Mercury Ihould fall to the Bottom in a running Form j but had no Succefs at the End of two or three Hours. filver i i6o The ExU‘ riment ^jhet> €>' extendible Lecture the Eighth. filver, which are feparable by Diftillation with Qiiick-lime or Iron Filings ; and fomerimes by- long Boiling in a ftrong alkaline Lixivium, 37. It were highly proper, if poflible, to ren- der the prefent Experiment general •, and, if the Nature of the Thing would admit thereof, apply it to extract a running Mercury from Metals, as we have here done from a native Ore or mineral Subftance. For the more intelligent Chemifts agree, that the true Analylis of metalline Mine- rals depends upon what is called their Mercuriji- cation\ that is, the obtaining Mercury from them. And for this Purpofe there are three Methods propofed. The firft is by Means of a cer- tain Mercury, fo prepared as to have a dilTolving Power, and to take up the Mercuries of Metals, in the fame Manner as Water diffolves Salt from Afhes. The fecond is by Means of certain re- generating Salts, particularly Sal- Ammoniac which fliall detain the more earthy Parts of Metals, and leave their Mercuries feparable ffom them by Sublimation or otherwiie. And the third Me- thod is by Means of a large Zm, or double Convex Glafs *, in the Focus whereof, if any Metal be applied, its mercurial Part is faid to feparate and go off in Fume, which when col- leded and condenfed appears to be running Mercury. 38. The firft Method would be eafy, if the proper Mercury for the Purpofe could be readily procured. The fecond is extremely laborious, and requires much Patience, and Reiteration. But the third feems eafy enough, and pradticable to Advantage, when a Glafs of three or four Foot in Diameter is at hand, the Sky ferene, and the Sun ftiines ftrong * See M. B.omherg\ E^eperiments, with the Duke of Or- hanii Lens, in the French Msfnoirs, S 9 - Let of Analytical Chemijlry. i6i 39. Let us not be mifapprehended as if we were here launching out beyond the Conhnes of ge- nuine Chemiftry, whofe Ofiice it is to keep clofe to the Senfes, without indulging any Degree of Speculation and Hypothecs : we only mean to give an Occafion for proper Trials to be made, which alone can determine whether running Mer- curies are obtainable from Metals, or whether a fixed Metal may not be obtained from running Mercury. Indeed we fhould be wanting to the Art we are endeavouring to improve, if we did not, at a time when almoft; every Chemift in England is preparing the Mercurius pr^ecipitatus per fe^ requeft them to try whether a fmall Por- tion of their fluid Mercury is not by the Opera- tion fixed into a folid Grain of Metal ; and if fo, what Metal it is, and whether more of it be not procurable by grinding their Precipitate, ex- pofing it again to Digeflion, and repeating this Operation for a Number of Times fuccelTively, till it may happen that Part of it will bear the Cupel. 40. In the fame View we recommend it, to thofe who defire the Improvement of Chemiftry, that they would procure a double Convex- Glafs, three or four Feet in Diameter, and try whether, when a Metal is expofed to the hocus thereof, the metallic Matter- which goes oft in Fumes, being colledled by a proper VefTel dextroufty ap- plied and plunged in cold Water, may not be thus condenfed, and afTume the running Form and other Properties of an actual Quickfilver. If thefe Experiments fucceed, they may richly repay the Coft, by ufeful Knowledge at leaft. 4 I. 'But to proceed ; Vv^e are farther to obferve from the foregoing Experiment, that as common Brimftone refolves itfelf into an acid Liquor and an earthy Matter, v/e find that certain mineral M or 1 62 Lecture the Eighth. or metallic Subfiances will, by a proper Analyfis, afford the four chemical Principles above men- tioned *, viz running Mercury, Sulphur, Salt, and Earth. But it is not fuppofed to hold uni- verfally, that all mineral Subftances fliould afford a running Mercury upon their Analyfis ; but on- ly fuch of them as are properly metallic. ^efult of Analyfis of Minerals has the Analy^ been Carried, it fhould feem that all Metals con- fis of Mi- tain a running Mercury, fixed in them, as Water nerals, jg fixed in dry animal or vegetable Subfiances ^), and joined with a Sulphur, or an inflammable Part, and an Earth ; befides a little Salt in fome of them h). The Folfil Salts refolve into a large Quantity of Acid, which is always united with fome Sulphur, and a fmall Proportion of Earth. Mofl Stones refolve into a large Proportion of Earth, and a fmall Quantity of aqueous and ful- phureous Vapour. And Earths refolve into a mere terreflrial Subftance, a little aqueous Acid, and a fmall Proportion of Sulphur. 43. Upon the whole therefore we may conclude, that the five Principles above laid down, viz. Water, Earth, Salt, Sulphur, and perhaps Mer' cury, are the true Chemical Principles of vege- table, animal and mineral Subfiances r). Axioms Canons. ♦ I. It appears from our preceding Enquiry, That genuine Chemifhry confifls in a legitimate Ufe of the Senfes, keeping entirely to fenfible fl) See LeS. III. ad finem, b) See M. Homberg upon the Chemical Principle?, in the Trench Memoirs. c) No notice is here taken of Air as a Chemical Principle, for the Reafon before alTigned. See above, § 3. See alfo Le<^. UI. faJItm. Things Of Analytical Chetnlfiry. 163 Things, or the Law of Indudlion, for its Prin- ciples and Explanations a) \ but, if it once in- dulges hypothetical Notions, Fidtion, Iliufion, and Darknefs enfue, inftead of fure Rules, ufeful Difcov^eries, and Light to the Underftanding. 2. That the common chemical Principles are juftly faid to be Water, Earth, Salt, Sulphur, and Mercury •, whereby many chemical Effecfls are explicable to common Senfe and Reafon, fo far as to afford Rules of working, to the Advantage of the Art and of ordinary Life b), 3. That as animal and vegetable Subfiances are refolvable into the fame Principles there is no NecelTity for making more than two Diflinc- tions or Claffes of chemical Principles, n^iz. the Vegetable and Mineral ; which feem to differ chiefly in this, that the metallic Species of Mine- rals may afford a running Mercury, whereas the vegetable and Ample mineral Species will not. 4. That the different Combinations of thefe Ave chemical Principles make all that vafl Variety of natural and artiAcal Bodies, which have hitherto been analyfed by the Fire ; the Difference of thefe. Bodies appearing to arife from, the different Pro- portions wherein thefe Principles are mixed. Whence, unlefs we except the Air, there feems no Neceflity for introducing a larger Number of Principles, to account chemically for all the va- rious Phasnomenaof Nature and Art. 5. That the correfpondent animal and vegetable Principles may in many Cafes be ufed for one an- other \ fo as to render volatile Salts and Oils cheaper, and leffen the Expence attending their Ufe in particular Arts and Trades h]. a] See the who^c LecTture, fojjlm, h) See I. II. M 2 6 . That 164. Lecture the Eighth. 6. That in order to leffen the Trouble and Ex- pence of procuring the volatile Salts of animal Subjects, thefe Subjects hiould be firfl purged of their Oil and undluous Parts by boiling in Wa- ter : after which they may be made to afford vo- latile Salts and Spirits, as pure as unboiled Plart- Ihorn, or purer a). But care muft be taken not to boil the Subjedl too long, otherwife a Jelly will alfo be drawn out of it; which Jelly plenti- fully contains the Matter of the volatile Salt. 7. That the unreflified volatile Salts of vege- table and animal Subftances are true Sales volatiles cleoft\ that according to the Difference of the Oil abounding in them, they are properly d iff ingu idl- ed into Sait ol Hartfhorn, Salt of Ox bone. Salt of human Blood, of Silk But that when thefe Oils are totally feparated from them, they be- come one and the fame undiftinguifhable vola- tile Salt }?), 8. That the fo called volatile Spirits of vege- table and animal Subffances, confifl only of a large Proportion of Water, impregnated with fome of the volatile Oil and Salt of theSubjedls; and that they may accordingly be refolved by Redtifi- cation into thefe three Principles ; fo that there is no Neceffity for introducing a fpirituous Prin- ciple h), 9. That it is the Admixture of Oil which gives the Colour to volatile Salts and volatile Spirits ; for when this Oil is totally feparated from them, the Salt is permanently white, and the Spirit pellucid c), a) SesExp.il. U) See Exp. I, II. f) See Exp. II. JO. That Of Analytical Chemiflry. 165 10. That volatile Salts are obtainable from ail Kinds of Land Animals, the amphibious and fubterraneous Tribes, Birds, Fifn, and Reptiles; from alkaline Vegetables without Putrefadion ; from other Vegetables after Putrefadion ; from Soot, Horns, Hoofs, and all refufe animal and vegetable Matters, fuch as the Pith of Horns, Urine, the Blood of Slaughter-houfes, dfr. and that as pure and perfed as from Hartfhorn : Which alfords a Rule for making volatile Al- kalies and Sal-Ammoniac cheap in England, 1 1. That elementary Earth, a Subftance fixed and ofitfelf unalterable in the Fire, Air, or Wa- ter, conftitutes the firm Bafis, or Skeleton, of all animal and vegetable, Subftances ; and that Wa- ter, Salt, and Oil mixed, and wedged betwixt the Particles of this Earth, confiitute all animal and vegetable Subftances a). 12. That there is only one Kind of volatile alkaline Salt, when reduced to abfolute Purity, the apparent Difference betwixt the volatile Salts depending entirely upon the different Oils where- with they are mixed h), 13. d'hat by endeavouring to purify the che- mical Principles too high, we do but deftroy their Natures r), or lofe the Properties whereby they produce their fpecific Effeds. Thus Oils are, by numerous repeated Diftillations, loft in the form of Oils, and turned into Earths ; volatile Salts fly away in repeated Sublimation ; and fixed Salts turn to Earth by repeated Solution and Filtration d), 14. That animal Bodies naturally contain no fixed Salt, tho’ the acid Vegetables, which are a) See Exp, I, II. \ See Exp. I, II. See alfo hereafter the Ledlure upon Oils. r) See Exp. 1, II. 4) See Mr, Boyk\ Sceptical Chemiji, M 3 ufed 1 66 Lecture the Eighth. ufed as Food, contain it plentifully a). Whence there is lodged in the Body a Power of convert- ing the Matter of fixed Salt into the Matter of volatile Salt. 15. That the volatile animal Salts, and the fixed vegetable Salts, differ chiefly with regard to their Volatility and Fixednefs, and the Effe6ts thereon depending ; but agree in other Refpedls. Thus they both make an Efiervefcence, and turn neutral, when faturated with Acids j they are both corrofive, hot and fiery, a), 16. That a principal Reafon of the Difficulties attending the Analyfis of Bodies, is the natural Affinity, or Relation, which fome of the chemi- cal Principles have to others ; whence they cohere Itrongly together, fo as not to be well feparated pure ^). Thus part of the volatile Oil of Animals ufually rifes with the fame degree of Heat as the volatile Salt, and intimately mixes there- with, ^c: Whence, to improve Chemiftry, we ffioLild feek out for other analyfing Powers be- fides Fire. And fuch an one in the prefen t Cafe is Water *, which imbibing the volatile Salt, more flrongly than it does the Oil, thus makes a more perfect Separation ; whereas Fire chiefly a6ls as an Analyfer, when there is a confiderable Difference between the Volatility of Bodies ; as in a Mixture of Water, Alcohol, and volatile Salt, all which rife feparately after one another ; the volatile Salt firfl, the Alcohol next, and the Wa- ter lafl. 17. That the Mercuries of Metals may be real things, and procurable different Ways; and that poffibly thefe Mercuries, or the common running Mercury, may be convertible into Me- zz J See Exp. T, IT. See Exp. 1,11,111, cal Of Analytical Chemiflry. 167 tal. But this Matter requires a farther Exami- nation, and fhoLild be brought under the diredt Evidence of Senfe a ). 18. Laflly, that there are certain Inftruments and chemical Operations, which though little attended to may afford great Light to the Un- derftanding, and prove highly advantageous in chemical Fhilofophy and Arts : we inflance, for the prefent, the Mercurification of Metals, the powerful Furnace of the Sun, the artificial Ufe of the common Elements, a) all which we recommend to the farther confideration of che- mical Fhilofophers. a) See III. M 4 L E C- [ «68 ] 7ke Sub- joa. LECTURE IX. CONTAINING Synthetical Chemiftry; c?\ the Art of lie - compojing Bodies. I. 'T N our laft Leftiire we endeavoured to ex- ^ plain what the more intdligcnt Chcmifls underftand by analytical Chemijiry., or the Reio- lution of Bodies ; in the prefent we propofe to give fonie Inftances of Recompofition, or the compounding of Bodies from their feparated Parts or Principles, fo as to compofe the Ori- ginal whole again. This indeed is exiremely difficult to effedf univerfally *, yet it may be done in fome cafes fo accurately, that the recornpofed Body fhall be perfedfly undillinguiffiable, by the Senfes, from that which had never been Icparated by the hire. And if the Art of Chemiitry were perfedl it would be able thus to recompofe, at leaft in fome tolerable manner, all the Bodies it divides. At prefent it is far from this Perfection, efpecially in the vegetable and animal King- doms-, where, by re alb n of the vafcular I'exture of the Parts, fuch a Recompofition feems almofl: impracticable, unlefs the natural or organical Structure be fome way or other preferved, or artificially imitated. We are therefore carefully to dillinguifli betwixt the Regeneration of orga- nized, and the Regeneration of unorganized Bodies. As the latter is much the more fimple and eafy, we ffiall begin with that, and afeend by degrees to the more complex Kinds fo as to fiievv Of Synthetical Chemifiry: i6g fliev/ where this Regeneration may be rationally expeded, and where it is lefs to be hoped for ; together with the ways of carrying this Fart of Chemiftry to greater Perfection. '2. This Synlhetical Chemiftry^ taken in i\\q Syfjtbefical ftriCl Senfe, for the Recompofition of Bodies Chen:ipry\ from their own Principles, is rather of phiiofo- phical than ordinary Ufe. And it will doubtiefs be alked, to what Purpofe do we ftudioufly en- deavour to recover thofe Bodies by Art, which Nature affords us in plenty ? We anfwer, it would fhew an extreme Perfection and Power in Chemiftry to be able to do this, and prove, either that Bodies might be taken to pieces by the Fire, without altejing or injuring their natu- ral Parts, or at leaft that any accidental Altera- tion brought upon them by the Analyfis, might eafily be reCfihed or aboliftred by a Recompo- fition. But here we are to guard again ft a Fallacy : for fuppofing the Art of Chemiftry fo far ad- vanced as to reinftate Bodies after their Ana- lyfis, we muft not thence conclude that Nature originally ufes the fame Means to compofe them. The Ways fhe ufes for this Purpofe would ftill be a new Enquiry, and ought to be diligently profecuted, for the farther Improvement of Phi- lofophical Chemi(try. 4. Our firft Example of Recompofition is taken from Nitre, the fecond from Brandy, the third from Cinnabar, and the laft from Bone. Experiment I. Phe Regeneration^ or Recompofition of Nitre ^ from its own acid Spirit and fixed Alkali. 5. We took two Pounds of refined Sak-Petre reduced to Powder, and putting it into a Glafs- redulerto Retorts 5 /zV/V. lyo Lecture the Ninth. Retort poured upon it a third of its own Weight of redlified Oil of Vitriol; then placing the Retort in a Sand-heat, and' luting on a large Receiver, we diftilled with degrees of Fire, up » to the higheft that Sand would give. Then fuf- fering all to cool, we thus obtained a pure and ftrong Spirit of Nitre ; which came over in red Fumes, and cannot, by any Experiment, be found to participate of the Oil of Vitriol ufed in its Preparation. And a fix- 6. On the other hand, we took a Pound of ed Salt, purified Nitre reduced to Powder, and melt- ing it in an earthen Crucible, caft little pieces of Charcoal into it fucceffively, till the Defla- gration ceafed, and the Salt at the Bottom of the Crucible appeared fiuggifh, or would no longer keep fluid, with that Degree of Heat which melted it before. Then increafing the Fire, fo as to make the Salt run again, we poured it out upon a clean metalline Plate, where it con- geal’d into a Subftance called fixed Nitre. 7. And thus, at two different Operations, we refolved the fame Subjecfl, Nitre, into two very different Parts ; which being put together again, after a proper Manner, conflitute the original Salt again, in all its Forms. Recom- 8. For if the alkaline Solution of fixed Nitre pfed. in Water, be exactly fatu rated with the acid Spirit of Nitre, till no more Effervefcence ap- pears, and yet the Mixture be not made alka- line ; this compound Liquor will, by ftanding, fhoot into true and perfedl Cryflals of Nitre, as we found upon Trial. And the Experiment fucceeds no lefs, if any other fixed alkaline Salt, as that of Tartar, Pot-afli, be ufed inftead of fixed Nitre. 9. And in the fame manner may common Salt be regenerated from any fixed alkaline Salt, and- Of Synthetical Che?nijlry. 171 and the acid Spirit of Sea-Salt ; or Alum, from any fixed alkaline Salt and Spirit of Alum; fo as to afford us Inflances of the juftefl Recom- pofition perhaps hitherto known in Chemiflry, 10. It is remarkable in this Experiment, that V/es, the two Subllances which compofe the Nitre are extremely different; the one being highly odo- rous and volatile, the other inodorous and fixed ; the one a violent Acid, the other a violent Al- kali ; but upon mixing, they unite into a neutral Sait, of the very fame Nature and Properties with that which afforded them. 11. From this Experiment fome have ventured to affirm that Nitre is naturally generated in the fame manner ; but this fhould not be allowed till it is fhewn that fuch an Acid and fuch an Al- kali are to be found diftindl in the places where Nitre grows. And we cannot too well remem- ber, that there may be feveral phyfical Ways of effecting the fame Thing; all which Ways are not to be prefumed, but fought. 12. To this Clafs of artificial Recompofitions may be added the Reprodudlion of Sulphurs and Vitriols ; tho’ the Experiments do not commonly fucceed in Perfedtion. Indeed, as we above ob- ferved that the Thing itfelf is chiefly of philofo- phical Ufc, for that Reafon very few have endea- voured to profecute it. 13. In our prefent Experiment we may ob- ferve that the Nitre, tho’ in both Cafes it fuffers a great Violence of Fire, is neither fcorched nor rendered empyreumatical ; which in other Cafes, where the Subject is more oily, feems a principal Caufe of the Difficulties found in the regeneration of Bodies; particularly fuch as Sugar, Turpen- tine, Amber, Whence we are directed to analyfc thefe undtuous Bodies, with fuch a degree of Heat as fhall hot fcorch their Oil, if we de- firc 172 Br^andy analyjed. Lecture the Ninth. fire to recompofe them ; or elfe to find out fome more proper Analyfer for them than the Fire ; fuch as particular Solvents, capable of fe- parating, and others of reuniting their compo- nent Parts, without having this defi:ru(fi:ive Effedl. 14. The Solvents here intimated might have confiderable Ufes, it a competent Set of them were difcovered, as diredlly tending to the Im- provement both ot analytical and fynthetical Che- miflry. Thus Water in fome Cafes is a better Analyfer than Fire, as we fee particularly in the feparating of Salts from Earths ; and thus fome Chemifts are faid to have a Method of re- covering analyfed Amber, or Amber diftilled for its Salt and Oil ; and that by means, not of the Fire, but of an artificial compound Salt ; the In- fiances of which Kind fhould be colledted. Experiment IL Brandy refolded into its component Parts^ and recompofed, 15. (i.) To a Pint of Brandy we added half a Pound of dry Salt of Tartar, then fet the con- taining Glafs in a gentle FIcat of Sand ; where we obferved the Salt to difiblve into a Liquor, by attracting to itfelf the Water of the Brandy, leaving a Spirit of Wine floating on the top. This Spirit we decanted upon a little more dry Salt of Tartar, and found that this fecond Salt fcarce relented. Then pouring the Spirit into a Glafs Receiver, we diftilled it gently over, and thus obtained a highly rectified Spirit of Wine. (2.) In the fame manner we diftilled the faline So- lution left behind upon decanting the Spirit, and thus obtained the Water of the Brandy in confi- derable Purify, leaving the Salt of Tartar behind, in Of Synthetical Chemijlry. 173 m a dry Form. (3.) In the lafl: Place, we mix- Andre- ed the Spirit and the W ater together, and di-* re. IV. See alfo Lect. VI. Exp. VII. b) See above § 28. See alfo Lect VI. Ex^* VII, c) See Lset. VIII. and the prefent pojjini, ii) Sac Exp. 1. f) See Lect. VII. pajjim. the Of Synthetical Chemiflry. the common Elements do not contribute fome Part of their Subftance, as well as Energy, in the Change From fuch an Enquiry, con- duced in a regular Manner, it Ihould feem that fome capital Canons might be derived for im- proving this grand Part of operative Philofophy. ^ See the preceding Leflures upon the Elements. [ 184] LECTURE X. CONTAINING The Curat ion of Vegetables , or the Means of preparing and fitting ^vegetable Sub^ jeBs for various Ufes, viz. Brewing, Di- ftiiling, Vinegar-Making, &c, fhSuh’ \7\T ^ proceeding to examine into ;ea, V ¥ Nature of Seminal Vegetation, and the Curation or Prefervation of Vegetables, with a View to the Improvement of Chemiftry and the Arts thereon depending.* Its Extent. 2. The Subjedt is of large Extent, and if duly profecuted, might tend to the Enrichment of the prefent Arts, or the Difeovery of new ones. For on regulating the Growth, and on the Cura- tion of Vegetable Produdlions, depends the Per- fedlion of Corn, Wines, Malt, Bread, Sugar, Tobacco, Spice, Drugs, Simples, Dying-Stufrs, and the like. And new Difcoveries either in Ve- getation, or Curation, might eafily introduce new Trades; as has been the Cafe in Sugar, Tobacco, V/ines, Spirits, dsfe. fhe Pro- 3- Experiments in Vegetation, we here cedure. propofe to fliew the Methods of regulating or condudfing this natural Power for the Service of Arts ; by diredling it to anfwer particular Ends, Thus by (lopping (hort tov/ards the Beginning of Vegetation in Barley, we procure Malt ; and by permitting the Grapes to hang till they grow not only ripe, but almoft dry, upon the Vine, we procure rich fweet* Wines. And thus we may of fegetable Curation. 185 may ftop Vegetation at any Period, or continue it longer than ordinary, - according as the Occafions of different Arts require. 4. By Experiments in Curation we would fhew CuratUn the Methods of colleding, preparing, and fe- curing vegetable Commodities; fo as that they may long remain found, perfed, and fit for Ser- vice. And thus our prefent Ledure will confift of two Parts ; the one relating to the ways of growing Vegetables, according to the Ufes for which they are intended, and the other to the gathering and preferring them, fo as to have them conftantly ready at hand, when they come to be required in Uie. 5. Our firft Experiment therefore is calculated to fhew the Method of flopping the natural ceis of Vegetation in the Seed ; fo as to prepare mints. Grain, Pulfe, Nuts, Mali, and Roots, for the making of Beer, Vinegar, and Spirits. Our fe- cond is defigned to fhew the Method of curing both fermented and unfermented vegetable Juices, fo as to make them keep found and good for fe- veral Years. Our third Experiment tends to die w the Method of curing vegetable Juices by Decoc- tion, or Infpiffation, for the Service of Brewing and Diflilling. And our fourth and lafl Experi- ment will fhew the Method of curing Yeafl, the Flowers of Wine, and Wine-Lees, for the Ser- vice of feveral Arts. Thefe Experiments now follow in order. Experiment I. Method of flopping the Natural Procefs of Ve- getation^ with a view to Malting ; or the Pre- paration of Grain., Seedsy Pulfe., Nuts, Majl., and Roots, for the making of Beers, Vinegars, and Spirits, 6. We i86 Lecture the Tenth. Malting, 6. We plucked up a Parcel of Garden-Beans, after they had been fuffered to lie in the Ground about fix Weeks in the Winter-Seafbn ; and found each Bean beginning to fplit, or feparate, into its two Lohes,, whilft the Radicle was (hot out fome Inches downwards, and had begun to take Root in the Ground *, the Plume alfo, which be- . comes the Stalk of the Bean, being rifen to the height of two Inches. In this ftate we dried a few of thefe over a clear Fire, and thus found them turned to a Kind of Bean-Malt, that tafted fweetilh, bit mealy betwixt the Teeth, and dif- folved freely in warm Water ; fo as to afford a Wort, fit for fermentig with Yeaft intd a Kind of Beer or Ale. 7. This Experiment inftrudls us in the ordinary Procefs of Malting *, which, in the Cafe of Bar- ley, is conformable hereto, and in the Cafe of Malting Indian Corn is the Procefs itfelf f he Pro- 8. In making Malt from Barley, the ufual cefsof Method is to fteep the Grain in a fufficient Quan- Malting. Qp Water, for two or three Days, till it fwells, becomes plump, fomewhat tender, and tinges the Water of a bright brown, or reddifh Colour. Then this Water being drained away, the Barley is removed from the fteeping Ciftern to a Floor, where it is thrown into what they call the JVet-Coucb ; that is, an even Heap, rifing to the Height of about two Foot. In this Wet-Couch the capital Part of the Operation is performed ; for here the Barley fpontaneoufily heats, and be- gins to grow, exactly in the fame manner as in our prefent Example of Beans*, fhooting out firfl the Radicle^ and then if fuffered to continue, the Plume^ Spire^ or Blade, But the Procefs is to be flopped fliort at the Eruption of the Radicle, * See below §. 10. See alfo fome -Experiments to this Purpofe in the Philojophical Iranfa^liom, otherwife of Vegetable Cur at ion. 187 otherwife the Malt would be fpoiled. The way to ftop it is, to fpread this Wct-Couch thin over a large Floor, and keep it turning once in four or five hours, for the fpace of two Days, laying it fomewhat thicker each time. After this, the Malt is again thrown in a large Heap, and there fuffered to grow fcnfibly hot to the Hand, as it ufually will in twenty or thirty Hours time; then being fpread abroad again and cooled, it is thrown upon the Kiln, to be dried crifp without fcorching. 9. And this is the general Procefs of Malting, w'herein almoft every Maltfter has his fecret particular way of working. But to render the hejl ad^ Operation perfect, the following Cautions muft vantage, be obferved : (i.) That the Barley be newly thraflied, or at lead newly winnowed; (2.) That it be not mixed or made up of different Sorts ; (3.) That it be not over fteeped in the Ciftern, or ly there fo long as to make it foft; (4.) That it be well drained ; (5.) That It be carefully looked after in the Wct-Couch, fo as to ftop the firft Tendency of the Blade to (hooting ; (6.) To turn the Wet-Couch infide outermoft if the Barley comes (that is, fhoots) more in the middle than on the (ides ; (7.) To keep it duly turning after it is out of the Wet-Couch; (8.) To give it the proper heating in the dry Heap; (9.) To dry and crifp it thoroughly upon the Kiln, but without a fierce Fire, fo as to be fcveral Days in drying a Kiln of Pale Malt, If thefe Directions be carefully obferved, the Malt will always be good. 10. The Method of Malting Indian-Corn.^ or Virginia Wheat., is much lefs laborious. For if this Corn be buried two or three Inches deep in the Earth, and covered with the loofe Mould dug up to make room for it, in ten or twelve Days, time the Corn will fprout, and appear like a green i88 Extended, Its Effedls^ and End. Lecture the Tenth. a green Field ; at which time being taken up^ and waflied or fanned from its Dirt, it is imme- diately committed to the Kiln, and by this means it becomes good Malt, exactly as Beans fo treated would do. 11. It is obfervable of this Corn, that both its Root and Blade muft (hoot to a confiderable length, before it will make Malt. And perhaps this is the Cafe in all large-bodied Grain and Nuts a ), 12. It might be of Service to transfer this eafy Experiment to the making of Malt from Barley, Rice, and the other fmall Grains and Seeds: but the Attempt may be attended with Difficulties ; becaufe in the making of Malt, the Barley muft be fuffered to grow in its Root only, and not in the Blade ; whence it would be difficult, at firft, to hit the exadl time for taking it out of the Ground. And, again, as the Grain is fo fmall, it might prove troublefome to feparate it from the Earth or Mould. However, the thing may de- ferve to be tried h ). 13. It is a Confideration of a higher Nature to determine the phyfical Effect procured by Malt- ing, and whether the End may not be obtained by cheaper and lefs laborious Means. The phy- fical Difference betwixt malted and unmalted Corn appears to be the Produdion, or Extrication, of a fweet faccharinc Subftance in the Malt, which is wanting under that form in the Corn. And it is the fweet Subftance alone, which we require a) \t may be worth trying, whether the fame Procefs is not, with due Care, applicable to the Malting of Turnips, Potatoes, Carrots, Parfnips, ^c. b) And poffibly fome Contrivance might be found, by the means of large Hair- Cloths, or otherwife, to inclofe the Grain, fo that the loofe Earth Ihould not mix among it ; and at the fame time an Opportunity be afforded, of commodioully ex- smir^ing how far the Barley is come at any time after lying. Of Vegetable Curation. 189 in Malt for the making of Beer, Ale, Vinegar, and inflammable Spirits a). But even unmalted Corn, duly treated, may be made to afford Beer, Ale, Vinegar, and Spirits: This, therefore, may intimate to us a way of making fuch Liquors, without the formal Extrication of any remarkably fweet faccharine Subftance. According to fome Trials we have made, unmalted Corn affords half the Quantity of inflammable Spirit by Fermen- tation and Dift illation, as the fame Corn would do when malted. And fuppofe that unmalted Corn were to be made into a Kind of Dough, or Pafle fermented with Yeaft, as is ufuaj for Bread, and then baked j would not this be a cheap Subfti- tute for Malting At leaft, it deferves to be tried, how much Beer, Ale, Vinegar, and Spirit, might be procured this way, compared with that other of Malting. 14. On the other hand, if only a fweet faccha- rine Subftance be required in Malt, are there not cheaper and eafier ways of procuring it than by Malting? Do not many Trees afford fuch a fac- charine Juice, by Tapping in the Spring, with- out prejudicing the Trees ? Is not young green Corn itfelf remarkably fweet *, and does not this fweet Juice enter the Compofition of the Ear, and there remain fixed, or almofl loft in a fac- charine Form, till recovered by Malting ? Here is a Door opened for explaining the Nature of Sweetnefs, and deducing the particular Hiftory of Sugar. Such a Work, for its Ufefulnefs in Trades and ordinary Life, we wifh were extant 5 and till fome confiderable Progrefs is made there- -j) Se® Lea,V\l. Exp. I, II, IV. h) They are faid to brew after this manner in fome Coun- tries. in Lecture the Tenth. in, the Art of Malting, and all thofe that depend upon it muft remain fhortof perfection, 15. Thofe, who are difpofed to go upon the Enquiry, may pleale to compare the Art of Starch -Making with that of Malting, and par- ticularly try whether fome confiderable Ufes may not be made of the Refufe Liquors pro- duced in both Arts. The high-coloured Liquor drawn from the Barley in the fteeping Ciftern is a vegetable TinCture, that might, if not by itfelf, yet by being ufed infread of Water to ground Malt, be worth fermenting and diftilling for Spirit; and the Starch-Makers refufe Liquors have been obferved to contain a Quantity of in- flammable Spirit. 16. Our prefent Experiment may in this re- fpeCf be made general, that it fhews us there are different times of fhopping, or preventing, the farther Growth of Vegetables, for the Service of Arts. And this Dodrine may be extended to the forming a Set of general Rules, for gathering the different Parts of Plants, at different Seafons of the Year, for different Ufes. 17. Thus Roots, for inftance, to be had per- fect, fhould be gathered and dried in the Spring, before the Leaves are formed ; Leaves fhould be gathered when they are fully opened, but before the Flowers appear ; Flowers when they are not fully opened ; and fome, as red Rofes, in the Bud. Seeds are to be gathered when full ripe, and be- ginning to dry, before they fall fpontaneoufly v and Trees are generally befl felled and flawed for their Bark in the Beginning of the Spring. But all this is to be underftood of the common Ufes of the Subjects ; for there are many particular Occafions, which require them immature. Thus Buckthorn-Berries, /jfhould be ripe gathered for making of Vegetable Curation. 191 making the Syrup, but unripe, for making the Painter’s Colour called Sap-Green, Experiment II. A Method of Curing both unfermented and fermented vegetable Juices, 18. (i.) We melted Brimftone in an Iron Matching Ladle, and dipping flips of coarfe linnen Cloth or Fumi- therein, made what the Wine-Coopers commonly call Match. (2.) We took a Hip of this 7'^ . Match, and fetting one end thereof on fire, put it into the Bung-Hole of a Cafk, which being at firft loofely flopped, fuffered the Match to burn nearly out. "Then the Bung being driven in tight, we fet the Cafk afide for an hour or two, and found that this Operation communicated a violently pungent and fufe)cating Scent to the Cafk, with a confiderable Degree of Acidity, which is the Gas and acid Spirit of the Sulphur. We now filled the Cafk with a very frnall Wine, which had fcarce finiflied its Fermentation *, and bunging it down tight, we put it in a proper place to clarify. 19. This is the common Method of matching Cafk for Wines, but particularly for Stums. It is an ufeful Experiment *, for poor Wines could fcarce be kept potable a fev/ Months wihout it ; nor could Stums be prepared in large quantities by any other Method commonly known. 20. By Stum we underfland the unfermented stum Juice of the Grape, feveral times racked znd^^bat, drawn from its Sediment, the Cafk being every time thus fumigated with Brimflone, to prevent the Liquor from fermenting, as it would otherwife readily do and fo become Wine. It is the Fume of the burning Sulphur which thus flops all Ten - dency to Fermentation, and continues the natural Juice of the Grape in a fweet flate, fit to be rea- dily jg2 IfECTURE THE TenTM. dily mixed with Wines inftead of Sugar; for which purpofe it is very much ufed ih Holland^ and other Countries, as alfo for giving a new Fret^ or Brilknefs, to decayed Wines ; fo that very large Quantities of this Stum are annually imported to all Parts along with the Foreign Wines. And after the fame manner a Stum is prepared in England from the Juice of Apples, which ferves the ordinary purpofes of the Wine- Cooper. Inconnjenl- 21. The principal Inconveniences in this Me- ernes of thod of matching the Calk are thefe ; (i.) that Matching, jj- communicates a naufeous fulphureous Tafte and Smell to the Wine ; and (2.) that it is not appli- cable to red Scums, or red Wines, without greatly impairing, or almoft deftroying their Colour ; whence the Stums in common Ufe are always white, the Produce of white Grapes. And be- caufe this Method of Matching does not fuit with red Wines, hence it is, that all red Wines are ufually dofed with Brandy in order to preferve them. And for Wines in general, it might very well fuf- jfice to burn a little Spirit of Wine in the Cafk; and if they want Strength, or Spirit, to preferve them found, to add Brandy or Spirit of Wine, pro- portionabiy. By which means they may be pre- ferved without any naufeous Smell, or Tafte, which always attend the Way of matching; tho* matched Wines lofe of their fulphureous Tafte, and Odour by long keeping. But for Stums, there is no other Way commonly known and prac- tifed, to preferve them, but by ufing the Fumes of Sulphur. The Ex- 22. The Experiment however is almoft gene- feriment ral, and may be applied to advantage in the cafe extended. Qf fermented Liquors, and again to unfermented vegetable Juices ; fuch as thofe of Citrons, Quin- ces, Oranges, fcfr. which it prevents from run- ning Of Vegetable Curation. 193 ning into Fermentation or Putrefadiiion. And this Effe6l it feems to have, chiefly by fciffening the Air, or weakening its natural Elafticity For as all vinous Fermentation is found to generate Air, fo the burning of Sulphur is found to ftiffen or deftroy Air. And hence it feems to be, that the Fume of burning Brimflone readily checks the Fermentation of Liquors ; fo that if a Cafk, by fretting or fermenting, appears ready to burft: its Hoops, a Difli of burning Brimflone held un- der it will foon quell the Motion : which is one known Method of checking or fupprefTing vinous Fermentation* Experiment III. Method of curing vegetable Juices by DecofHon^ or Injpijfation, 25. We made an Infufion of Malt, in the com- tVort in- mon Manner of Wort for Beer or Ale; then let-//'#'^^^* ting it fland to clarify, we decanted the clear Li- quor, and boiled it over a foft Fire to the Con- jiflence of Treacle: in which State it will long keep found, or fit for making Beer, Vinegar, or inflammable Spirit. 24. This Experiment fhews us ageneral Way of "The Expe^ reducing fermentable Subjects to a fmall Compafs, and of fecuring them againfl external Injuries. Thus a Kind of Treacle from Malt might be procured in cheap Years, for the Service of the Vinegar-maker, the Brewer, and the Difliller. The Method is likewife applicable to any other fweet or faccharine Juice ; as that of Grapes, the Tappings of Trees, the fermentable Juices of Summer- Fruits, and of certain fweet Roots, as Parfnips, 25. Thefe infpiflated Juices, if not boiled too high or fcorched in the Operation, are eafily * See Mr. Hale‘s Vegetable Staticks* O brought 194 - Lecture THE Tenth. brought back to a due Degree of Thinnefs with Water, and fermented in the fame Manner, and for the fame Purpofes, as they might have been before they were boiled : So that Beer, Vinegar, or Spirits may be thus commodioufly procured, at any Time, even in hot Climates *, and it ftould feem that Brewers and Diftillers might alfo reap fome Advantage from a prudent Ufe of this Ex- pedient. 26. The Wine-Merchant might thus order the Juice of Grapes, or Stum, to be boiled down in Wine Countries, and fo left fit to be reduced by Water and fermented into Wines in others. And for this Purpofe the poorer Vintages might fervc, as well as the rich ; excepting only that the Rob, when reduced by W’ater, would not afford fo much Wine as the thicker or richer Juices. But the Operation mult be performed with confider- able Exadnefs, to make it fucceed fo as to pro- duce artificial Wines perfedly like the natural. 27. This Procefs aifo feems applicable to Hops, which in cheap Years, may be thus made into a Kind of Extrad, without any Lofs of their valua- ble Parts j whereby the numerous Contingencies attending that Commodity, might in good Meafure be prevented. But there w^ould here be Danger of Fraud *, becaufe the Extrads of Gentian, Centaury, or other bitter, ftomachic Vegetables might be mixed with the Extrad of Hops, fo as not to be cafily difcovered. Yet perhaps this Inconvenience would not be greater than that generally fuffered already ; for many, no doubt, are well affured by- Experience, that the Extrad of Gentian is a wholefome Bitter, which might very well fupply the Place of Hops in Brewing. 28. A Procefs fome what of this Kind is fre- quently pradifed in Wine-Countries ; viz, either by Of Vegetahh Curation. 195 by fufFering the Grapes to grow almoft dry upon the Vine ; or elfe by boiling ^own their Juice, till it becomes fufficiently thick to afford luch rich Wines as Canary or Frontignac ; whofe Strength may be readily imitated by adding a lels Proportion of Water to the Rob, or infpif- iated Juice of Grapes, in the Manner above ex- plained 29. Before we quit this Procefs we would re- commend it to be tried, upon the Juice that may be eafily expreffed from a vegetable Subjedl com- monly thrown away as ufelefs : we mean the Shells of green Peafe, which by being barely boiled in Water, communicate a faccharine Sweet- nefs thereto j fo that the Liquor has been made into tolerable Drink, and a good Spirit. Experiment IV. ^ Method of curing Teaft^ the Flower of Wine^ and alfo Wine- Lees ^ for the Service of Dijtilling^ Wine-Makingi Vinegar-Makings &c. 30. We took a Quantity of common Ale-Yeaft, Teaflcund ^nd putting it into a clofe Canvas Bag, gently andpre- fqueezed out the Moiflurc in a Screw-Prefs, till the remaining Matter was left as hard as Clay ; and in this State having packed it clofe in a tight Cafk, and fecured it well from the Air, it kept frefh and found for feveral Months \ as has been often experienced by others. 31. This is an Experiment of confiderable Ufe Ufe, to Brewers and Diftillers, who employ very large Quantities of Yeafl, and yet feem in Englajtd to have no good Method of preferving it, or rai- ling Nurferies thereof; for Want of which they fuftain a confiderable Lofs. Whereas the Brewers in Flanders make a great Profit, by fupplying the * §. 23 -- 27 . O 2 Malt- 196 ^he Expe- riment extended. Ferpa (duration mhat. Lecture the Tenth. Malt-Diflillers of Holland with Yeaft, which is’ rendered lading and fit for Carriage, after the Manner of our prefent Experiment. 32. The fame Method is practicable to much greater Advantage in the Yeafl of Wine, and in Wine-Lees, it they could be imported into England. For by this Means we might eafily imi- tate the Wines and Brandies of foreign Growths; the Lees and Yeaft of Wine readily affording an effential Oil, by Difdllation, of which a fmall Proportion will flavour a large one of Wine or Brandy. But a fliorter and more perfeCt W ay is to let any taftelefs, or other proper Wine, fret or ftand, for fomeTime, upon fuch Lees, orWine- Yeaft, whereby it will to great Advantage acquire the natural Tafte and Flavour of the Wine, to which the Lee, or Yeaft, belonged. 33. Thus we have given a few Examples of Vegetable Cjuratioit.^ on which the Improvement of 'feveral Arts* depends. We cannot go through all the Species of it, for that would be an immenfe Labour ; nor are Men hitherto arrived at the perfect Method of preferving Vegetables in their natural Form, with their Colours, Odours, and other fenfible Qualities, for anyNumber of Years. Yet fomething conflderable might be done in this Way, by proper Application. Fruits may long be preferved frefli in Spirit of Wine, firfl well faturated with the Skins and tinging Farts of the Fruit. And many of them may be tolerably preferved in perfectly fermented Liquors, which generate no more Air. The more folid Kinds of Subfi'ances may be cornmodioufly cured, by gently drying them in the Sun, Shade, or other flack Heat. Thus Peafe^ or Beans, being dried young in a flack Oven, in their proper Seafon, may be boiled green and tender, in the Winter, alnioil like thofe new gathered. Certain Ways of piC- Of Vegetable Curation. 197 preferving Fruits, and other vegetable Subjeds, both in a dry and moift Form, with Sugar, are now generally known : But there are fome extra- ordinary Means of curing feveral particular Kinds of Bodies referved as Secrets by Artifls ; tho* even thefe might be exceeded, if we had a tho- rough Knowledge of the prefent Subjed. The Defign might alfo be extended to the animal Kingdom, under the Name of Animal Curation ; the compleat Art whereof would prove highly ufeful at Sea. Axioms and C a n ,o n s. 1. We learn from the preceding Enquiry, that Men have Power to ftop the Courfe of Na- ture in Vegetation, fo as to make this Principle anfwer their own particular Ends and Defigns ; whence Arts may receive confiderable Improve- ments a). 2. That the Art of Malting is farther improve- able by a general Acquaintance with the Nature of Vegetation^ vegetable Juices, the Art of Fer- mentation, and the Art of Sugars b). 3. That the Labour and Expence attending the Art of Malting may, in fome Meafure, be faved, by procuring and feparating the fweet Juices of Vegetables as Nature affords them ; or by boiling them down to a Treacle or faccharine Subfiance c). 4. That there are different Seafons of the Year peculiarly fitted to the colleding or procuring of •thefe Juices, and all other vegetable Matters, ac- cording as they are required ripe or immature a) See Exp. I. b\ See Exp. I. n. c) See Exp. I. III. .#') See Exp, I. v o 3 f. That 198 Lecture the Tenth. 5. That the Fumes of burning Sulphur have a great anti-fermentative, anti- corruptive, or pre- lervative Power upon vegetable J uices a) •, and this without rendering the Liquors unwholefome, tho’ the Fume is difagreeable, and of itfelf fuf- focative. 6. That the Fumes of burning Sulphur have a Power of difcharging the Colour of red Wines a ) ; and on a like Account thefe Fumes are ufually employed for the Blanching of Silks, Flannels, 7. That Vegetable Curation depends chiefly upon the Exclufion of the Air and all fuperfluous Moilture; and this either fingly or conjointly h). 8. That Vegetable Curation confifts in keeping all the Principles of a vegetable Subject together iindeftroyed, in their natural Texture or Arran- gement b). 9. That all fweet vegetable Juices may be pre- ferved found and ferviccable, by infpiflfating them over a foft Fire ; fo as to throw olF their fuper- fluous aqueous Parts, and leave the fweet orfaccha- rine Subfhance behind, in a ftate fit for Fermen- tation, upon the Addition of frefh Water c). 10. That feveral bitter vegetable Juices, ca- pable of anfwering the End of Hops in Brewing, may be infpiffated by the Fire, and preferyed for that Purpofe r). 11. That thofe extremely corruptible Sub- ftances, Yeaft, the Flowers of Wine, and Wine- Lees, may be preferved found, barely by freeing them from their fuperfluous Moifture, and fecur- ing them from the external Air and too great Pleat d). a) See £x/> II. h) Exp. II, III, IV. e) See Exp. III. ^ Exp.IY. 12. That Of Vegetable Curation. 199 1 2 . That the Bufinefs of Vegetable Curation may receive great Improvements by a proper chemical Enquiry, made with a dired View to this Sub- je 6 t ; from whence many farther Advantages are derivable to Arts and Trades, particularly to the ^ Sugar-Colonies abroad, to Brewers, Wine-Ma- kers, and Diftillers in hot Countries ; and that the Enquiry likewife might be advantageoufly extended to Animal Curation ^ See Exp, IV. O4 LEC- [ 200 ] I LECTURE XI. CONTAINING Ways of illii ft rating and improving the. Arts depe?iding upon Vegetable Fermenta- tion; particularly Brewing, Diftilling, Vinegar-Making, &c, ^he !• "T FT our lafl: Le6lure we endeavoured to fhew Subjeu, ^ the Method of procuring certain vegetable Commodities, and preferving them uncorrupted, for the Service of Arts : In our prefent, we fhali confider fome Ufes of thefe Commodities, when thus preferved ; or the Ways of employing them, fo as to afford various Preparations for the com- modious carrying on of Trade, and the Bufinefs of ordinary Life. 2 . As our Confideration is retrained to the vegetable Kingdom, the Arts that will chiefly come before us at prefent are, thofe of Wines, Sweets, Malt-Liquors, Vinegars, and Brandies ; in all which we have already made fome Progrefs But there remains much behind for the Improve- ment of thefe Arts ; which lie in a State far from that Simplicity, on which their Perfedfion feems to depend. The Depgn 3* Thefe Arts v/e fliall here endeavour to im- of a:e jix- prove by four diredl Experiments. The frft ferimentsi capital, and calculated to fhew the Method ot reducing vegetable Juices, cured by Decoc- ^ S^e LeCl> X, tion. 201 of Wines and Spirits. tion or Infpiffation * , back to a State fit for affording Vinegars, Wines, and Brandies by Fermentation ; and at the fame Time to exhibit a new Method of making an artificial Muji., or Stum., as good as the natural, and equally fit for. refermenting, fretting, improving, and making Wines, Vinegars, and Spirits, in all Countries. 4. The fecond Experiment will exhibit the com- mon Methods of forcing, or fining down, ferment- ed vinous Liquors, fo as to render them expe- . ditioufly bright or clear, and fit for Ufe. 5. The third Experiment will fhew a Method of converting White Wines into Reds ; and of recovering, or improving, the Colour of decayed red Whines. 6. The fourth., a Method of concentrating Wines, Vinegars, or Malt-Liquors, for Carriage, or Exportation. 7. The fifth will fhew a Method of recovering prick’d Wines. 8. The fixth and laft will fhew a more profi- table Method, than that commonly ufed in Eng- land, of fermenting Malt for Diflillation, or the Produ( 5 lion of common inflammable Spirits. Thefe Experiments now follow in their Order. Experiment I. fo (Joew the Method of reducing vegetable Juices, cured by Infpiffation or BecoSiion, back to a State fit for affording JVines, Vinegars, and Bran- dies, by Fermentation \ and at the fame Time to exhibit a Method of making an artificial Muji, or Stum, as good as the natural, and equally fit for refermenting, fret ting, improving, or makingWines, Vinegars, and Spirits, 9. V/e took three Pounds of white Lump Su- Artificial gar well cleanfed of its Treacle, and melting it Muftpre- • Sec Lea. X. Exp. III. . in 202 ^he Expe- riment hwo de~ duced. Lecture the Eleventh. in three Quarts of fair Water, added in the boiling half an Ounce of finely pulverized Rhenijh Tartar-, which diflblved with a remarkable Ebul- lition, and gave a grateful Acidity to the Li- quor. Then taking the Veflel from the Fire, and fuffering it to cool, we thus procured a Mufi^ which in all refpedls refembled the natural tart and fweet Juice of a white flavourlefs Grape, when that Juice is well purified, and often racked from its Sediment, in order to make Stum. And if our artificial Muft be Hummed, that is matched, or well fumigated with burning Brimftone, after the Manner fhewed in our laft Ledure a it thus becomes a perfect Stum - ; which may be made of any Flavour, at the Difcretion of the Artift. 10. This Experiment is fo pregnant, that it might deferve to have its Ufes explained by an exprefs Treatife b ), It affords abundant Inftruc- tion for improving the Arts of Sweets, Stums, Wines, Vinegars, and Spirits ; it likevvife affords fome ufeful Inftrudions about the Nature of fweet and tart vegetable Juices, and the Ways of imi- tating them by Art. But thefe Particulars we can only juft touch upon for the prefent. 1 1. The Experiment itfelf was formedaipon the Analyfisof the Juice of the Grape before Fermen- tation ; which Juice, to the Senfes, appears no other than a faccharine Subftance diffolved in Water, with the Addition of a tartarous Acid : And this being fully confirmed by a chemical Refolution, it was hence eafy to exped, that if Tartar, which is the natural Salt of Wine, or of any fweet vegetable Juice fermented, could be artificially diffolved in a proper Mixture of Sugar and Waterj^ it wouM give an exaft Refemblancc «) Exp. II. i See the Appendix to this Lefture. of Of Wines and Spirits. 203 of the thing. Accordingly it was found upoil Trial that Tartar might be thus dilTolved, fo aS to communicate an agreeable Acidity to Sugar, and thus to imitate, in great PerfedHon, the natu- ral fwect Juices of Vegetables, without their par- ticular Flavours : and hence our Experiment dif- covers to us the Nature, Ufe, and Ferfedtion Of the Art of Sweets. 12. By a SMet is underftood any vegetable Juice, whether obtained by Means of Sugar, Rai- n;jhat, lins, or other Foreign or Domeftick Fruit, which is added to Wines in order to improve them. Whence we fee that the Art of Sweet-Making ttiight receive a high Degree of Improvement, by ufing pure Sugar as one general wholefome Sweet, inftead of thofe infinite Mixtures of Ho- ney, Raifins, Syrups, Treacle, Stum, Cyder, Cij’r. wherewith the Sweet-Makers fupply the Wine- Coopers, to eke out or amend their Wines. For pure Sugar being added to any poor Wine will ferment therewith, improve it, and bring it to a ptoper Degree of Strength and Vinofity. If the Wine to be thus amended is tart of itfelf, no Tartar fhould be added to the Sugar ; but if it be lufcious or too fweet, then the Addition of Tartar is proper. 13. The prefent Experiment adds no lefs Im- Extended, provement to the Art of Stums^ which may per- haps be hence brought to its Perfedlion. And here we defire the Men of Bufinefs would duly refledl, that wherever Sugars go, there go in a folid form Stums^ Wines,, Vinegars^ and Brandies \ that is, the adual Matter out of which, by the bare Addition of Water, thefe feveral Commodi- ties may be readily prepared. For it is by no Means necefiary that Sugars Ihould be imported and exported in a liquid Form, for the making 204 Farther U/es in ihi ^ retire of Wines. Jnd Vine- gars. Lecture the Eleventh. of Stums, Wines, (^'c. becaufe it is fo eafy to add the l ariar and Vv^ater in any Port they arrive at. 14. Our Experiment alfo points out the Way of perfeding die y/r/ 0/ Wines^ by reducing the .con-ponent LViatcer thereof to a fmall Bulk, and occafionally,in any Climate, bringing it back with Water into a Muff ; which Muft may be tinged of any Colour, or impregnated with any Fla- vour, To as to be fermented into a Wine of any Species or Denomination. Thus if a few Drops of the elTential Oil of Nutmeg, or Cinnamon, were to be rubbed with a little Sugar into a Kind of Elceofaccharum and then mixed with our artificial Mult, or Stum, the Wine made of it would have a very grateful Odour and Flavour. And fo if an effential Oil were procured from the Lees of any particular Wine, and introduced in- to our artificial Stum, after the fame Manner, the artificial Wine would thus have the Odour and Flavour of the natural Wine that afforded the Lees ; bating for the Roughnefs, Hardnefs, or Drynefs given by the Hufk and Stone. For our artificial Muft has no Flavour or Colour of its own, but readily receives and becomes impre- gnated with either by Art. And how far this Experiment may be ufeful in teaching a Method of making a rich concentrated Wine, for the ex- temporaneous Improvem.ent of the poorer Sorts, or for making a ferviceable Kind of extemporaneous W' ine, barely by mixing with Water, we recom- mend to the Trial of thole who have a Talent at this Kind of Experiments. 15. The Art of Vinegar -Making may alfo pof- fibly receive a high Degree of Improvement by Means of the prefent Experiment, as it affords us a Method of diffolving Tartar in Water, on which the whole Art of Vinegar- making feems to See hereafter, LcSl.yUll. Exp.lY, depend Of TVines and Spirits. 20j depend' For there are many phyfical and che- mical Reafons and Experiments, to fhew that Vinegar is no more than a particular Kind of fluid ’Tartar, And the Art of making Vinegar would then be perfedt, when it could readily, or extemporaneoufly, prepare and concentrate the Commodity ^ fo as to give it a Kind of folid or confiftent Form, which fhould render it durable, bring it into a fmall Bulk, and leave it fit to be reduced by Water into a fluid Form, for Ufe in all Climates. 1 6. We plainly fee that the original compo- nent Matter of Vinegar, which is Sugar, lies in a fmall Bulk, and may be readily converted by Water, Air, and Heat into Vinegar Sugar in the A( 5 l of Acetiflcation feems wholly converted into a fluid Tartar; and if the aqueous Liquor be feparated from Vinegar, we find the Vinegar is thereby rendered the ftronger : infomuch that if Vinegar were to be highly concentrated by Congelation, it would become almoft folid, or a Kind of adlual 'i'artar. Whence the Rule is eafy, that in order to make an almofl folid Vi- negar, we fhould endeavour to diflblve Tartar in an aqueous Liquor. Whence, for perfedting the Art of Vinegar-Making, we recommend the diflblving of Tartar largely with Sugar, or Trea- cle, and the ftrongefi: Vinegar, by repeated Im- bibitions, Heat, and a proper Management. 17. We proceed to fhew fome Ufe of our Ex- Ik the Dt- periment in the Art of Difbillation ; which Art like wife might pofTibly arrive at Perfedlion by its Means. It is generally known that a taftelefs, flavourlefs, yet perfedfly vinous and cheap Spirit, is the grand Deflderaium in the Art of Diftilling : Now fuch a Spirit feems eafily procurable from our Stum, made highly acid by the Addition of ^ See Lea, VI. Exf, II. Tartar, 2o6 Lecture the Eleventh. Tartar, and fermented till that Acidity prevails, as it foon will do, fo as to prove a true Vinofity. And thus a highly vinous, yet flavourlefs Spirit, may be obtained at a very reafonable Charge, if a Man thoroughly underitands the Art of Fer- mentation. And fuch a Spirit might be readily flavoured and converted into French Brandy, Ar- rack, or any other Kind of Spirit, that commonly fells for a much greater Price a), farther 1 8. Thefe Particulars, with fcverai others that might be mentioned, hold of our Experiment in its perfect State : for to reduce fweet vegetable Juices to a pure white Sugar, without any Par- ticipation of Treacle, is an extreamly Cu- ration^ which coft much Labour before it was difcovered. But nov/ the thing is common, we jfeem almoft to negledt it ; at leafl: do not enquire into the farther Ufes of fo capital a Difcovery, tp the apparent Detriment of the Sugar-Trade, and the Colonies thereon depending. 1 9. Thp’Curation by bare Decodtion, or In- ipiflatipn, is of a lower Clafs, yet flill it has its Ufes h)\ for even Treacle is an ufeful Sub- ibapcp : But the Rob of Malt, as we fhewed in pur laft Ledture h j, may be employed for the making of Beer, Ale, Vinegar, and Spirit, in all Climates, after the fame Manner as we here yfe Sugar. And the Perfedlion of this Curation would be, to reduce all fuch Robs to an adlual Sugar *, as with fkill might be done, we apprehend, to Advantage. Tho’ as fome Countries and Pa- lates prefer Malt -Liquors and Corn- Spirits, to Wines and the finefl: foreign Brandies, this Art of Sugar-Making need not be univerfally exten- ded to Malt and Grain. a) See hereafter XII. h) See Leff, X. Exp* III. '18. Many of Wines and Spirits. 2 < 20. Many other Ufes are derivable to Arts and natural Philofophy from our prefcnt Experiments but we have only Time to mention one more. We fee that Stums, Wines, Vinegars, and in- flammable Spirits of all Sorts, may be commo* dioufly obtained by its Means ; we now add, that the original Matter of them all may be reduced to a brown, thick, treacly, or other coloured Subilance, whether red, yellow, or black, and exported under this difguifed Form to any trad- ing Part of the World, for preparing thefe Com- modities there. And thus the Country poATefled of Sugar, might advantageoufiy fupply many others with Matter for exercifing of feveral Arts *, fuch as the Produdion of Wines, Beers, Vinegars, and Brandies. And in the fame Manner might Fa- milies be fupplied with an artifleial Mull, Stum, or Rob of Grapes, for making any Sort of Wine at home, with much greater Eafe than they now brew Beer : for the expert Artift will eafily give the proper Flavour and Colour of any Wine to this artiflcial Mull, or Rob ; fo that there fhould be nothing more required at home, for the mak- ing it into Wine, than to add the Water and the proper Ferment in the Calk. Experiment II. ^he common Method of Forcing or Fining down fer- mented vinous LiquorSy fo as to render them expe- ditioujly bright or clear y and fit for Ufe, V 2 1. Wc took an Ounce of fine Iling-Glafs beat Wim with a^Hammer into Shreds, and diflblved it boiling in a Pint of Water, fo that it became a ftiff Geliy when cold. Some of this Geliy we whilked a) Sec above, §. \2, and hereafxer Exp, III, up 2o8 Lecture the Eleventh. up into a Froth, with a little of the Wine in- tended to be fined ; then ftirred it well among the reft in the Cafk, and bunged it down tight. By this Means the Wine will ufually become bright in eight or ten Days. 22. This Method is beft fuited to white Wines : but for red ones, the Wine-Coopers commonly ule the Whites of Eggs, beat up to a Froth, and mixed in the fame Manner with the Wines. And thefe are the common Methods of Forcing at pre- fent ufed in the Wine-Bufinefs. Rationale. 23- The phyfical Reafon of the Experiment is this, that the Bodies here employed as the Forcing are vifcous or glutinous, fo as to entangle them- felves among the flying Lee, or light Feculencies, that float in the Wine ; and thus forming a Mafs fpecifically heavier than the Wine, fink thro’ the Body thereof, like a Net, carrying down all the Foulnefs they meet with in their Way. But when the Wine is extremely rich, fo that its fpecific Gravity proves greater than that of the Mafs compounded of the as it is called, and the Dregs or Lee, this Mafs rifes upwards, and floats on the Top of the Liquor, in v/hich Cafe alfo the Wine will draw off fine. Incon^jeni- 24. The principal Inconvenience of this Me- encies of thod of filling Wines is its Slownefs, as not hav- ing its Effedl in lefs than a Week, or fometimes a ° ’ Fortnight, according as the W^eather proves fa- vourable or unfavourable, cloudy or clear, windy or calm ; which appears to be Matter of conftant Obfervation. But the Wine-Merchant frequently requires a Method that fliall with Certainty make his Wines fit for tafliing in a few Hours. And a Method of this Kind there is, but kept as a va- luable Secret in a few Hands. Perhaps it depends upon the prudent Ufe of a tartarized Spirit of \¥ine and the common Forcing, as Acceffories, along Of Wines and Spirits. 209 along with Gypfum^ or calcined Alabafter, as the Principal ; all which are to be v/ell romaged, or flirred together in the Wine, for'half an Hour, before it is fuffered to reH. 25. Let it be here obferved that all Wines, Fining mi Malt- Liquors, and Vinegars, which are made and perfed in their Kind, will grow fine of themfelves barely by (landing ; fo that if they do not thus grow fine in a reafonable Time, it is a Sign they labour under fome Difeafe, that is, are either too aqueous, too acid, too alkaline, tend to Putrefadlion, or the like. In all thefe Cafes, which may be properly enough called the Difeafes of JVines^ Tuitablc Remedies are required before the Wines will grow fine. 26. To enquire particularly into the Difeafes Difeafaof of fermented Liquors, with their re fpedlive Cures, is not the prefent Defign a ) ; only we mufl ob- ferve, that the moil general Remedy hitherto known for all the Difeafes of Vv^ines, is a pru- dent Life of a tartarized Spirit of Wine, which not only enriches, but difpofes all ordinary Wines to grow fine. But Wines well prepared from ar- tificial Mufl, in the Method above-mentioned, are fubjedl to no Difeafes. And even thofe ob- tained in the common Way may be effedtually fe- cured, againft all Difeafes, by Congelation, which takes away their fuperfluous Water without Pre- judice to their vinous Parts b). 27. Skimmed Milk likewife is a proper For- FheVfeof cing for all white Wines, Arracks, and fmall Spi- rits ; but improper for red Wines, becaufe it dif- charges their Colour. Thus if a few Quarts of well iLimmed Milk be put to a Hogfhead of red Wine, it will foon precipitate the greatefl Part See the Appendix to this lecture. - b) See below Exp. IV. P of 2 10 White Wine (oloured red. ^he Ex^e^ riment improved. Lecture the Eleventh. of the red Colour, and leave the Liquor n^uch paler, or almoft white. Whence this Experi- ment fometimes becomes of Ufe in turning pricked red Wines into Whites, where a fmali Degree of Acidity is not fo much perceived. And on this Property of Milk depends that other, of Kin thereto, whereby it whitens Wines that have acquired a brown Colour from the Cafk, or by hafty Boiling before they were fermented : For in thefe Cafes, the Addition of a little fkimmed Milk will alfo precipitate the brown Colour, and leave the Wines almoft limpid, or of what they call a Water Whitenefs \ which is much coveted abroad in white Wines as well as in Brandies. Experiment III. A Method of converting White Wines into Reds ; and of recovering the Colour of decayed red Wmes, 28. We put four Ounces of what is commonly called Turnjol Rags into an earthen Veftel, and poured upon them a Pint of boiling Water ; then covering the V eftel clofe, and fuffering it to cool, we (trained off the Liquor, which we found of a very deep red Colour, inclining to purple ; fo that a fmali Proportion thereof would give a beautiful bright red, to a large one of white Wine mixed therewith. 29. For keeping, this Tindlure might be mixed with Brandy, or made into a Syrup with Sugar*, but the ufual Way with the Wine-Coopers and Vintners is to infufe the Rags cold in Wine, for a Night or more, and then wring them with their Hands. The Inconvenience of this Method is, that it gives the Wine a difagreeable Tafte, or what is vulgarly called the 'J'ajle of the Rag: whence 2II of Wines and Spirits. whence the Wines thus coloured ufually pafs among the Judges for prejfed M'^inss^ that have got this Tallc from the Canvas Bags in which the Lees were prefTed. 30. The Way of infufing the Rags in boiling Water is not attended with this Inconvenience ; but then it loads the Tindure with Water, which may prove prejudicial to the Vv^ine ; or if made into a Syrup, or mixed with Brandy, the Colour is thus diluted, or weakened *, fo that a large Quantity of thefe additional Ingredients comes to be ufed with a fmall one of the Colour, tho’ that alone be the Thing required. 31. Hence the Bufinefs of colouring Wines red Liconveui- is attended with coniiderable Inconveniencies, in thofe Countries that do not afford the tinging Grape^ which yields a Blood -red Juice, and with which the Wines of France are often ftained. In Defed thereof at Oporto they fometimes ufe ' the Juice of Elder-Berries, and fometimes Log- wood, when their Wines are not naturally red enough for this Colour, it feems, they muff have, to make them faleable. 32. The Colour afforded by our prefent Ex- Remedied. periment is not properly the Port^ but the Bour- deaux-Red^ which does not fo well fuit with Port- JVines : Whence the Foreign Coopers are often diftreffed for Want of a proper Colouring to their red Wines in bad Years. We would, therefore, recommend to them the Ufe ot an Extrad made by boiling Stick Laque in Water j which gives a rich Red, that comes tolerably cheap, and is, perhaps, the perfed red Port-Qo\ouv But. if this proves unlatisfadory, let a Method be tried of making a Laque out of the Skins of the ting- See hereafter leSi. XIV. Exp, II. 2 12 Lecture the Elevei^th. ing Grape, ox Raifm de "Teinte. Cochineal might likewife anlwer the Purpofe, tho’ it lofes of its Colour by mixing with all acid Wines. Elder- Berries give this Colour in a tolerable Degree, but not without communicating a naufeous Flavour. 33. The Produce of our prefent Experiment might anfvver well, if the Colour co ild be had pure, or made up into Cakes, without being im- bibed by Rags ; for it is very eafy to obfcure its too great Brightnefs, or vivid purple Brifknefs, by the Addition of a little burnt Sugar, Rob of Sloes, Rob of Oak, Rob of Wine, or any other Colour bordering upon the Tawny, fo as to make a true Port-Coloux. Experiment IV. A Method of condenfng or concentrating Wines ^ Vine- gars^ and Malt-Liquors^ for Exportation, Wines and 34- We took a Quart of ordinary red Port- potable Wine, included in 2iFlorenceE\2Sk^ and placing Liquors Flafk in a Mixture of one Part common Sait T^Fr^ez Snow, or beaten Ice, we found the more aqueous Part of the Wine was foon turned to Ice •, from which, by a bare Inclination of the Glafs, the thick, rich, or more vinous Part of the Wine, Vv^as eafily drained. FbeExu- 35 - Experiment is here performed too rimen/ quick, fo that fome of the thick and valuable regulated, parts of the Wine are catched and detained in the Ice. To perform it in Perfection, the natu- ral freezing Cold fhould be employed •, by which Means, Wines, Vinegars, and Malt-Eiquors may be Of Wines and Sphnfs. 213 be reduced to a fourth of their ordinary Bulk, without any confiderable Lofs of their eflential Parts ; little more than the ufelefs, or detrimental Water being thus feparated, fo as to leave all the effential Parts of the Wine admirably cured, or capable of remaining perfed, for feveral Years, as has been found upon Trial. And by a prudent Ufe and Application of this Experiment, we con- ceive that great Improvements might be made in the Wine-Trade. 36. For by a proper Contrivance, and a little Dexterity, which may be eafily gained by Ex- perience, large Quantities of the pooreft Wines might be thus, at little Expence, converted into rich ones, fo as to increafe their Value in Pro- portion to the Diminution of their Bulk. And thus alfo, by repeating the Operation, might ex- tremely rich and generous Wines, ora true Quint- eflence, be procured, for the Amendment of the thinner and poorer Sorts. And in this View it fhould be remembered, that mountainous Wine- Countries are often furnifhed with Snow, by means whereof artificial Freezing might be prac- tifed in the time of Vintage ; the bare intimation of which may give a fufEcient Hint for introduc- ing a new and ufeful Branch of Bufinefs, as Wines may be hence concentrated after Fermentation, no iefs commodioudy than the Juice of the Grape before that Operation a). And if to this be added, that the Art of Congelation is alfo capable of Im- provement from a proper Ufe of Sal-Ammoniac and Water b) ; for, as the Sal-Ammoniac remains eafily recoverable, it fhould feem that little more than a fuitable Apparatus is required to bring this a) See LeSi.'K, Exp. III. F) See Ua. V. Exp. II. F3 Bufinefs 214- Lecture the Eleventh. Bufinefs to Perfeftion, with all defirable Advan- £«ige. E X P E R I xM E N T V. A Method of recovering 'pricked Wines PnclCd TTq a Bottle of prick'd red 7 ^i?r/-Wine Tovel 7 d added about half an Ounce of tartarized Spirit of Wine ; then taking the Liquor well together, we fet it by for a few Days, expediing to find it remarkably altered for the better; as upon Trial it appeared indeed to be. 38. This Experiment depends upon the ufeful Do( 5 lrine of Acids and Alkalies a). All perfeft Wines have naturally fome Acidity ; but when this Acidity prevails too much, the Wine is faid to be prick'd^ which is a State thereof tending to Vinegar h). But the prudent Introdudfion of a fine alkaline Salt^ fuch as that imbibed by Spirit of Wine digefted upon Salt of Tartar, (for fo the tartarized Spirit of Wine is pre" pared) has a direefi; Power of taking off* the Aci- dity; to which Effed: the Spirit of Wine aJfo contributes, and is in other Refpeds a great Pre- servative of fermented Liquors c). And if the Operation be dextroufly performed, prick’d Wines may be thus recovered, and made to remain found and faieable for feme TimxC. The fame Method is likewife applicable to hard Malt- Liquors, or fuch as are but juft turned four, and not near becoming Vinegar. ' 39. An Expedient of the fame Nature is fre- quently made ufe of to recover four Small-Beer, g) See thefe Terms explr.inGcl in the prefixed to our L''6iures. * b; See LeSl. VII. Exp. II. c) See Lcbl. VII. Exp. IV. and the Appendix to the prefent Lcbiure. , i .- - •• by of Wines and Spirits. 215 by adding thereto a littJe Chalk or Powder of Oyfter-Sheils ; for Chalk and Oyfter-Shells be- ing terreflrial Alkalies, immediately take off the too great Acidity of the Liquor, and caufing an Ebullition therewith, give it a confiderable Briiknefs, if drank before the Ebullition is en- tirely finiihed. In order to continue it the longer, ’tis beft to add the Chalk, or Oyfter-Sheils, whole to the Liquor in the Calk ; but Care muft be taken to drink it out foon, otherwife the Liquor will fpoil a). Experiment VI. A more profitaUe Method., than the common., offer- menting Malt for Diftillation, in order to obtain from it a Brandy, or inflammable Spirit, 40. We took ten Pounds of Malt reduced to a fine Flour, and three Pounds of common for Dipl* Wheat-Meal ; to thefe we added, firft, i^o iation. Gallons of cold Water, and ftirred them very well together ; then five Gallons of Water boil- ing hot, and ftirred all very brifkly again. Let- ting them now ftand for two Hours, we repeated the Stirring again, and when the whole was grown cold, we added to it two Ounces of folid Yeaft, and fet it by in a warmifti Place, loofely covered, to ferment a), 41. This Experiment exhibits the Dutch Me- thod of preparing the IVaJh, as it is called, for Malt-Spirit, whereby they fave much Trouble, and procure a large Yield of Spirit ; thus com- mocUoufty reducing the two Bufineffes of Brew- a) See Le^. VII. tajjtm, P 4 mg 2i6 Jnd Ad~ ’■vantages. Regula- tion. Lecture the Eleventh. ing and Fermenting, to a fingle Operation. In England the Method is, to brev/ and rnafli for Spirit juft as they ordinarily do for Beer ; only inftead of boiling the Wort, they pump it into large Coolers, and afterwards run it into their fermenting Backs, to be there work’d, or fer- mented with Yeaft; thus bellowing twice as much Labour in the Operation, as is required ; and at the fame Time lofing confiderably of their Quan- tity of Spirit, by leaving the grofs Bottoms out of the Still, for Fear of burning. 42. In the Manner of our prefent Experiment, where the Malt is ground fine, we have all its fermentable Parts fet loofe, fo as at once to mix with the Water. And we can thus put all the Bottoms into the Still, without Danger of burn- ing ; becaufe being rendered fo fine at firft, they entirely lofe their Ciamminefs in the Fermen- tation, fo as to become light or buoyant, and thus increafe the Yield of the Spirit. 43. The Meal of unmalted Corn is found ne- ceffary to be mixed along with the Malt, to pre- vent its over-fermenting, and throwing off the Matter of the Spirit. But as Difpatch is here par- ticularly required, to avoid Expence and a large Apparatus of VeiTels, a confiderable Qiiantity of Yeaft is added to quicken the Fermentation, fo that it may be finiftied in two or three Days. 44. More Yeaft ftiould be added if the Wea- ther be cold, and lefs if it be hot *, the Converfe is to be underftood of Meal, more whereof is re- quired in hot Weather to check, and lefs in cold, to haften the Operation ; which in the prqfent Cafe is defigned to be violent, contrary to what ought to be obferved in the Fermentation for Wines, where 'the flower the Operation is per- formed, the better the Liquor will prove. Which Rule . of Wines and Spirits. 217 Rule may likewife obtain here in a Jefs Degree : for it is polTible to ferment the Wafh fo vio- lently, that it fhall foon end in Putrefadion a). And thus by rightly conducing the feveral Parts of the Procefs, we may, by Diltilladon, procure all the Spirit that Malt and Meal are capable of aiTording by Fermentation. The Method of procuring this Spirit will be iliewB in our next JLedure b). Axioms and Canons. 1. We have feen in the preceding Enquiry, that excellent Stums, Sweets, Wines, Vinegars, and Brandies, may be prepared from Sugar, in any Climate, where Water and Tartar can be procured c), 2. That Malt-Liquors, and Malt-Vinegars, may be commodioudy prepared in any hot Cli- mate, from the Rob or Treacle of Malt ; which is fit for Tranfportation, fo as to convey the de- fired Virtue of the Malt in a fmall Bulk, and retain it perfed; for feveral Years d). 3. That the Perfedion of the Art of Vinegar- Making depends upon the Converfion of Sugar in- to a fluid Tartar ; or a Method of permanently diffolving a large Proportion of Tartar in Wa- ter e). 4. That it is pofTible to reduce both Wines and Vinegars to a thick Syrupy Form/) : fince the a) Le£i.YU.paJ/im, h) See Lea. XII. Exp. I. c) See Exp. I. See alfo Lea VII. Exp. I. 4) Exp. I. See alfo Lea. X. Exp. ill. e) See Exp. I. See alfo Lea. VII. Exp. II. /) Exp. I, IV. original 2i8 Lecture the Eleventh. original Matter of them both, viz. Sugar, is folid, and fince they both may be concentrated by Froft to a high Degree of Richnefs and Thicknefs. , I 5. That a new Art may be introduced of fup- plying Foreign Countries with a proper, or rich, fyrupy, or treacly Subftance, which fhall lie in a fmall Compafs, for the making of Wines, Beers, Vinegars, and Spirits, in all Climates, with confiderable Advantage a ) : A Confidera- tion deferving the Attention of the Sugar-Colo- nies, or their Mother-Kingdoms. 6. That the fweet and tart Juices^ as thofe of Summer-Fruits, Cherries, Grapes, confift of a faccharine and tartareousSubltance; or, to fpeak explicitly, of an adlual Sugar, and an ad:ual fluid Tartar : which affords an ufeful Rule for improv- ing thefe natural Juices in bad Years, and again for imitating them by Art-, as alfo for producing Wines, Vinegars, and Brandies, without them, where Sugar and Tartar can be procured b). 7. That there is a great Affinity betwixt Su- gar and Tartar, fince they not only refide to- gether, and are intimately mixed in all fweet and tart vegetable Juices, but alfo feem readily con- vertible into each other ; for the acid and tart immature Juices of Plants become faccharine by Ripening; Wine made wholly of Sugar and Water fhoots a large Quantity of Tartar; and Sugar is wholly convertible into Vinegar, which is a fluid Tartar. Whence much Light might be derived for explaining the Nature of Vegetation, Acidity, Sweetnefs, Immaturity, Ripenefs, Vi- a) Exp. I, IV. See alfo Lea. X. Exp. III. b) Exp. I. See alfo Lea. VII. and X. pajjim. nification, Of Wines and Spirits. 2 i g nification, Acedfication, and the Art of procur- ing Tartar a), 8. That the Improvement, or Perfedlion, of feveral Arts may depend upon a fingie Experi- ment j as we remiarkably fee by our (imple Ex- periment of diiToiving Tartar in Water and Su- gar b ) ; which has a dired: Tendency to improve the feveral Arts of Sweet.s, Stums, Wines, Vi- negars, and Spirits. 9. That a very large Proportion of Water en- ters the natural Compofition of Stums, Wines, ‘Vinegars, and Spirits c ) ; as plainly appears from hence, that the effen^al Matter of them all is contained in dry Sugar, which being barely dif- folved in Water, and fermented, becomes Wine; or a Liquor that may, by Congelation, be re- duced to a fourth, or a fixth Part of its natural Bulk, without any coniiderable Lofs of its valu- able Part, or of little more than its fuperfluous Phlegm or Water d). 10. That the Difeafes of Stums, Wines, and Vinegars, are owing to an Over-Proportion of aqueous Parts; fo that if their Water be taken away, without doing Violence to the elTential Mat- ter, thofe feveral Commodities may be preferved in a State of Perfediion ; as we fee they adfually are by Concentration, or Congelation, which thus advantageouflyfeparates their aqueousParts with- out hurting the reft d). 1 1. That numberlefs new Sorts of Wines and Brandies are producible, barely by adding any well-fcented Vegetables, or their efiential Oils, or a Cl) See LeSi. VH. and X. See alfo the prefent Lecture, Exp. I. ' b) Exp. I. c) Exp. 1. and IV. J) See Exp. IV. Mix 220 Lecture the Eleventh. Mixture of fuch Oils, to a natural or artificial Muft in the Fermentation a). And the fame may be proportionably underftood of the Colours of Wines •, which might, by proper tinging Ingre- ! dients, be thus procured blue, green, yellow, or i of other Colours, if it were neceffary, as well as - pale, or red h), 12. That the phyfical Agent in the Fining of Wdnes, and other fermented Liquors, is fome proper vifeous Subfiance, which entangles the grofs Particles, and either finks with them to the Bot- tom, or rifes to the Top,^fo as to feparate and keep them feparate from 'the Body of the Li- quor ; and that, on this Foundation, better Me- thods of fining may be difeovered, than thofe liitherto commonly known and pradifed c), 13. That tartarized Spirit of IVine is a Remedy for acid Wines, and not only abates their Acidity, but alfo ftrengthens, and difpofes them to grow fine, when they are thick and turbid d). 14. That Milk, deprived of its Cream, will difeharge the Colour of red Wine, by precipitat- ing the tinging Matter to the Bottom ; and fo iikewife leffen, and take off the brown Colour, wherewith white Wines are fometimes acciden- tally tinged e). 15. That the Bufinefs of colouring red Wines artificially may be improved by a proper Ufe of an artificial Turnfoi without Rags; fuch as an Extra6l of Stick- Laque, &c. but particularly an artificial Tindlure of the Hufk or Skin of the red Grape, or a particular Laque made from the Raijin de Tcinte f ). a) Ex^. I. See all'o LeSI. VII. Exp. I. h) See Exp. ill. <:) Exp. il. (i) Exp. Sec alfo the Appendix below. e] Exp. II. j) Exp. ill. 16. That 221 Of wines' and . Spirits, 1 6. That it is in the Power of Art greatly to accelerate the Operation of vinous Fermentation, fo as to finifli the whole in a few Days Time : But that this fhould be done only when a Spirit, and not a Wine,' is intended ; becaufe fuch a hafty Fermentation fubverts or dellroys the Texture requifite in vinous Liquors a). APPENDIX to Lecture XL Sect. I. The Theory of Vinous Fermentation, 1. The extenfive Do6lrine of Vinous Fermen-= ration being little regarded, in Proportion to its philofophical and pradtical Ufes, it may be pro- per in this Place to lay down its Theory,^ after a concife axiomatical Manner fas we are the better enabled to do from the Labour which Dr. Stahl has bellowed upon this Subjedt b) and fubjoin a few Obfervations with regard to Pradice. 2. Vinous Fermentation is an inteftine Motion performed by the inllrumental Efficacy of Wa- ter ; fo as to llrike afunder, attenuate, tranfpofe, and again colle6l and recompofe, in a particular Manner, the Salt, Oil, and Earth of a ferment - able Subje the better ; as a great Body of Liquor is not fo liable to receive pernicious Alterations, from Heat, Cold, the Air, or other accidental Things. And even where nothing remarkable of this Kind has happened, it is furprizing to note the Diffe- rence betwixt a fmall Quantity and a large one, of the very fame Liquor, fermented in the very fame Manner, only the one in a fmall and the other in a large Veffel. 21. Small Wines may be brought to undergo a fecond Fermentation, by being mixed with proper fermentable Materials ; and thus may be rendered ftronger and richer, fo as to be fit for Exportation, Cfc. Otherwife it is obferved that Wines which finifli their Fermentation in eight or ten Days, will not ordinarily endure the Sea. 22. It is a neceffary Caution in all Fermenta- tion, to prevent too great external Heat, for Fear of changing the Fermentation to Putrefadlion and to remove the Wines to a cooler Place, when the Violence of the Operation is over ; that they may purge and fine themielves by Degrees, with- out Danger of turning acid, as they are apt to do in a hot Place. Or if they cannot be kept cool, they ought to be early racked from their Lees ; which tends to preferve them found, and prevents their turning eager, ropy, and foul a). 23. It ■) See Lect, VII. of Wines and Spirits. 237 23. It is to be obferved of all Liquors pre- pared by Fermentation, that the Interpofition of Water keeps not only the faline, oily, and fpiri- tuous Parts, but alfo the mucilaginous and earthy ones, in their due Arrangement and fome Degree of Connexion ; from which if they are again dif- turbed, there happens fuch a Change as cannot well be prevented from proving pernicious, but the Liquor will fuccelhvely and haftily proceed on to Corruption a'). Thus if a fermented Li- quor be agitated by a great boiling Heat, its proper Arrangement is thereby difordered, and the Liquor not only becomes manifeftly thick and turbid, but more faline and auflere, through the Separation of the fpirituous and oily Particles from the faline ones, wherewith, being before in fome Meafure connedled, their Acrimony was (heathed or abated. 24. Such Liquors tend fo much the fafler to Alteration or Putrefaction, if they are not care- fully looked after and preferved ; but efpecially if, through any great Commotion by Heat, the more intimate Connexion of the fpirituous Parts with the faline and mucilaginous, or even with the remaining aqueous ones, be difturbed and broken : Whence either the whole Mafs turns to Vinegar, or to a ropy, corrupt, putrid Sub- fiance a). But if fuch fermented Liquors arc carefully preferved at Reft, and kept from Inju- ries, they will long remain in a found and un- corrupted State ; as we continually fee in Wines and Malt-Liquors. 2 5. And farther, all thefe fermented Liquors will be fitted to refift the Alterations of the Weather or a) See VII. Seafons 238 ■ Lecture the Eleventh. Seafons of the Year, with refpeft to Heat, Cold, and a fermenting Humidity in the Air, (which is by fome efleeined the Caufe of Fretting in Wines) if their fuperfluous Water be artificially feparat- cd from them, fo as that the Liquor itfclf may be concentrated *, in which State it will remain for many Years unchangeable, through the Sum- mer’s Heat, and the Winter’s Cold 26. When a chemical Anaiyfis is made of thefe Liquors, the firft Part that rifes is inflammabk Sprit \ the next, Phlegm^ mixed with an Acid, and an efifential Oil, leaving a thick Matter, or Rob of Wine, at the Bottom ; which, when freed from its fuperfluous Moifture, is obferved to be very durable, and full of Tartar. But the bare Mixing of thefe feveral Parts together will not make the original Liquor again : Which fliews that they were all before connetled in a certain particular Manner, which was diflblved and defcroyed in the Adi of Separation ; and again, that each of thefe Produdlions received a particular new Kind of Alteration from that A6l of Separation, which will not fuffer them to reu- idte as before, without fome proper intermediate Subfiance, or a new Fermentation. 27. Hence pure Wine confifis of much Wa- ter, a moderate Quantity of inflammable Spirit, a little efiential Oil, a Proportion of acid Salt, and a certain mixed Subftance, or P^ob^ called by Becher^ the media Subfiantia Vini, And whilfl thefe feveral Parts remain firmly united together in their due Proportion, the Wine is in its per- fedc State : But as their Connexion proves loofe, or any one of them becomes deficient, or abounds in an Over -Proportion, then the Wine is faulty, * See Lict. XI. Exp, IV. and 239 Of Wines and Spirits. and expofed to Injuries and Alterations for the .worfe: And this fhews us, the true Foundation of what may be called the Health or Hifeafes of PHines. 28. That a large Proportion of Water necef- farily enters the Compofition of Wine, appears plainly by its- artificial Preparation a) \ and again from the Congelation of the natural h). But though this large Qiiantity of Water is re- quifite in the Fermentation, and ferves to carry it on the better ; yet it is not afterwards effential ^to the Wine, but rather foreign and detrimental, ^expofing and fubjeding it to Changes, which it would not otherwife undergo : Whence the fo- vereign Remedy for all Wines, is to deprive them of their fuperfiuous Water, in order to render them perfedt and unchangeable, without fome uncommon and extraordinary Violence or Ac- cident. And indeed this Remedy is fo effec- tual as to make all others unneceffary ; infomuch that the pooreft and thinned: Wines may, by its Means, be rendered perfedly durable, and full bodied h), 29. But as there may be fome Difficulty in the particular Ufe of this grand Remedy fin the large Way of Bufinefs) the next Expedient is, to ufe highly rectified and pure Spirit of Wine, in fuch Proportion as to prevent all Change for the worfe, and preferve the eifential Parts of the Wine, as it were by a Balfam. But when the Cafe is very bad, this Remedy ^of itfelf will fcarce prove fufficient, unlefs affifled by fomewhat to give a Body as that gives Strength. Whence it is highly convenient to have always at Eland a a) See Lect. VII, Exp. I. if) See Lect. XI. Exp. IV. Quan- 240 Lecture the Eleventh, Quantity of Wine made as rich as ever it will ferment ; a fu table Proportion whereof being added along with the Spirit, will have a very good Effedt ; efpecially if the Whole be quicken- ed with a little ejfential Oil of Wine^ which, in the Cafe of over-aqueous Wines, is generally defi- cient. And this being a capital Difeafe in Wines, or that to which moil of the reft are originally owing, it may be proper here to give a Form of a Remedy which has been found effectual for the Purpofe. 30. Take an Ounce of fine eflential Oil of Wine, mix and grind it with a Pound of dry Loaf-Sugar into an El^eofaccharum ; diffolve this EUoJaccharum in two Gallons of the richeft Wine ; and add to it two Gallons of the fineft Spirit of Wine, fo as that they may be well incorporated to- gether. The Dofe of this Mixture muft be proportioned to the Exigence •, but in ordinary Cafes one half will fuffice for a Pipe of Wine. 31. There is a Difeafe of Wines oppofite to the former, and that is when too much of their aque- ous Moifture is drawn from them, whence they be- come dry and parched, as it were, for Want of it. This Cafe indeed cannot well happen, except by the Method of Condenfation ; whereby Wines may have their effential Parts brought fo clofe together, as to become unfit for Drinking till fet more 'afunder, and diluted. But this muft not be attempted with Water alone, for Fear of inducing a Flatnefs. The beft Way is, to have a dilute or thin taftelefs Wine ready at Hand for the 2AI of Wines and Spirits. the Purpofe a ) ; whereby any Degree of Small- nefs may be given at Pleafure. 32. But the artificial Method of preparing Wines renders all Remedies unneceflary, as it intirely prevents their Difeafes ; fo that they need not be made either too aqueous, or too dry, but cohftantly of a perfed full Body, and therefore not fubjedt either to Acidity, Ropinefs, orFoul- nefs, when once well cleared of their grofs Lees, in the ordinary Way of Racking. 33. But in Cafe the Wine fhould not foon grov/ fine of itfelf, the Addition of a little tar- tarized Spirit of Wine will haften the Effe6l h) : Or, to make at once a general Remedy for Wines that are too poor and aqueous, or will not tho- roughly fine themfelves ; let a pure, taftelefs, " and totally inflammable Spirit be made from Su- gar *, digeft this Spirit upon a tenth Part of pure and dry Salt of Tartar for three Days; decant the Liquor, and put it to ten Times its own Quantity of a Wine made as rich as it pofTibly would ferment': Of this Preparation fix or eight Quarts will at any Time mend, improve, and fine down a Pipe of ordinary Wine. <*) See Le^. VII. Exp, I. 1) See Ua. XI. Exp. II. IV. R LEC- [ 242 ] LECTURE XIL CONTAINING Attempts to illiijlrate and improve the Arts depending upon Distillation. viz, Mdlt* Stilling, Redtifying, and Com- pounding. fheSuh- I. TJ'AVING already gone through the Arts jr I depending immediately upon vegetable Fermentation^ we next proceed to con- fider the Ways of improving the Art of DF fiillation^ which depends thereupon feconda- rily. Dljiilla- 2. The Word Diftillation is here ufed in the iion,mjhat, popular Senfe, to fignify the Art by which all inflammable Spirits, Brandies, Rums, Arracks, and the like, are procured from vegetable Sub- jedbs, by the Means of a previous Fermentation, and a fubfequent Treatment of the fermented Li- quor by the Alembic, or Hot-Still, with its pro- per Worm and Refrigeratory. 7he Arts Yhe Arts therefore at prefent to be con- are thofe of Malt-Stilling, Redtifying, ^ " * and Of Dif illation. 243 and Compounding, with the Bufinefs of the Brai;i- dy-Merchant, the Officers of Cuitoms and Ex- cife fo far as relates to Spirits, and of the feveral Dealers in Brandies, Rums, Arracks, and Cor- dial Waters. 4. The Experiments we ffiall exhibit will ffiew, (i.) the Method of Diftilling a Spirit from a fer- mented Malt- Wort, commonly called JVafb., in order to obtain Jqua or the ordinary Malt Spirit, of which many Cordial Waters are made by the Compounders, Apothecaries, and others : (2.) Our fecond Experiment will exhibit the Me- thod O'" purifying or redifying this Spirit of the firft Running, or, Low-Wines^ as they are called, into a faleable Proof- Spirit, or what they em- phatically call Proof Goods that is, a certain ftandard Spirit, ufually confilting of one half Water and the other half Alcohol : (3. J Our third Experiment will exhibit the i\rt of the rectifying Diftiller, or the Method whereby the Proof Goods of the Malt-Sciller are made into a fweeter or cleaner Spirit, for the finer Ufes of the Com- pounder and Apothecary : (4.) Ouv fourth Ex- periment will fhew the true Method of examin- ing Proof in Spirits, and difeover the Invalidity of the common Methods of judging of the Pu- rity, Genuinenefs, and Goodnefs of Brandies, Rums, and Arracks : And (5. j our fifth Expe- riment, will ffiew the Method of making Cordial or Compound Waters in Perfection. R 2 E XP E R I- 244 - Lecture THE Twelfth. •The Dipl lation of Wajh. Wims. The Expe-‘ riment ex- tended » Experiment I. ^he Method of diftilling Malt-Waflo^ or a fermented Mixture of Meal and Malt^ for Spirit. 5. We brifkly ftirred together the Malt-Wafli j prepared in the laft Experiment of our laft Lee- ,ture^ and therewith filled two thirds of a btill, , firft made hot and dewy on the Infide with boil- ing Water, and kept the whole Stirring till it al- moft begun to boil *, then we immediately clapp- ed on the Head, and luted it down. There now foon ran, in a flender Stream, from the Nofe of the Worm, a fpirituous Liquor that was in- I flammable, or burnt in the Fire. We continued i to work fo long as the Liquor that came over would, when thrown upon the hot Still -Head, catch Flame from a lighted Candle applied to the rifing Fume. 6. And thus we obtained what the Malt-Stil lers call a Malt Low-JVine \ that is, a fpirituous Liquor from fermented Malt and Meal, fo di- luted with Phlegm or Water, as that the laft Runnings of it would not burn upon the Still- Head. That which comes over after the Spirit falls off from being Proof, till it will no longer burn on the Still-Head, is called by the Name of Faints 7. This Experiment may be rendered gene- ral, by a flight Variation of Circumftances ♦, that is, it may be made to ferve as an Inftance of all the Ways of procuring inflammable Spirits, whether Brandies, Rums, Arracks, Cyder- Spirit, or the like : F"or if any Wine, Beer, or fermented Liquor Of Dtf illation: 245 Liquor from Sugar, Treacle, Roots, Fruits, be treated in the fame Manner, it will afford a Spirit differing only according to the Nature, or fpccific Tafte and Odour, of the Subjed. 8. But none of thefe Subjcds will afford the leafl drop of inflammable Spirit without a pre- vious Fermentation a). Thus though the recent Juice of the Grape, or any other fermentable Juice, were diftilled to Drinefs, yet no inflamm- able Spirit would be procured : Whence it ap- pears that inflammable Spirit is a Thing pro- duced by Fermentation b), 9. The Cautions required to render the Ex- Cautions, periment fuccefsful, and the Produdion perfed, are, (i.) That the Fermentation be well per- formed, and the Liquor become truly vinous, and of an acid Pungency c) ; (2.) that it be gently diftilled, by Means of a foft, well regulated, Fire ; (3.) that the groffer Oil, apt to rife along with the Spirit, be kept back by a proper Strain- er, or thick doubled Flannel, laid under the Nofc of the Worm. If thefe Cautions be duly ob- ferved, the Low-Wines will prove conflderably pure and vinous. 10. When all the Spirit is thus obtained there Manage- remains behind in the Still what they commonly ntent, call Bottoms ; that is, the grofs Parts of the fermented Meal and Malt mixed with Water. This grofs Matter is generally ufed for the Feeding of Hogs •, whence the Malt-Stillers See Lea, VII. Exp. IV. h) See Lea. XI. pajjim. f) See Lea, VII. and XI. .R 3 Malt- 2 4-6 Lecture the Twelfth. of England are commonly large Dealers in Hogs : But in Holland that makes a leparate Bufmefs. II. Thus Vv^e have gone through three of the principal Branches of Malt Stilling *, viz. the Brewing, Fermenting, and firft Diftilling Parts ; or the Making of the Wort, the Working it in the fermenting Back, and the difliiling it from the Walh a). There is but one Part more of this Art, viz. the Redifying Part ; or the Way of making up their Goods as they call it, to fale- able Proof : And how this is performed will be feen by the following Experiment. Experiment II. ^he Method of fimple EeEHfication^ or Bijlilling the LoW‘Wines.^ produced by the foregoing Experi- ment^ into Proof-Spirit for Sale. Proof-Si>i- 12. We took the Low-Wines produced in rU. the preceding Experiment, and diftilled them over- again in Balneo MarH., or barely by the Heat of boiling Water ; and thus we obtained a purer and higher redified Spirit than before, v/hich being let down with fair Water to a cer- tain Size or Standard called Proof h , is what the Malt-Stillers underftandby Proof-Goods, or their redihed Malt-Spirit. »?) See I.eB. XI. Ex^. VI. b) V/hat this Proof is, fee explained in the fourth Experi- ment of the prefent Ledure. 13. The of Dif illation. 247 13. The common Malt-Stillers indeed do not thus redlify their Spirit in Balneo Maria^ but barely rediftill their Low-Wines in a fmaller Still ; fo that their Spirit is not fo clean as that of our prefent Procefs. The Perfedion there- fore of the Art of Diftilling from Malt feems to require a good Method of redifying clean, as well as a careful Obfervance of the Cautions above laid down a), 14. Having thus regularly gone through the whole Art of the Malt - Stiller as it is pra<^ifed by the more intelligent Artifts, we proceed to offer a Confideration or two for its farther Im- provement. 15. The Inconveniencies of this Art regard cither the Subjedt, or the Work. The Subjedl, we fee, is Malt ; which being of a large Bulk, in Refpedt of its faccharine Part, and requiring a great Proportion of W ater to extradf this Part, hence many large Veffels, fuch as Mafh-Tuns, Coolers, Fermcnting-Backs, Coarfe-Stills, and Fine-Stills, become neceffary therein ; whereby the Labour alfo is increafed, and the Price of the Commodity enhanced. This Art, therefore, being far removed from Simplicity, is confe- quently far removed from Perfection. 16. The Remedy here fhould feem to de- Remedied, pend upon the Introduction of a new Art, fub- fervient to the Art of the Malt -Stiller^ and con- fining itfelf to the Boiling down of Malt- Wort to a Rob ^'1, fo as to fupply the Malt -Stiller with his Subjedt, in the fame Manner that the Fine-Stiller is now fupplied by the Sugar- Baker «) See §. 9. b) See lea. X. Exp. III. R4 with 24-8 Lecture the Twelfth. with Treacle : For thus the complex Bufmefs of the Malt- Stiller might be commodioufly re- duced to a great Degree of Simplicity. 17. By the fame means the Spirit of the Malt ‘Stiller would aifo become much finer than at prefent ; becaufc the Subjed would comc^ tolerably refined to his Hands, or purged of its grofs, mealy, and hufky Matter, which yields a difagreeable Oil in Diftillation ; and is alfo apt to burn in the Still, and fpoil the Spirit. We therefore recommend it to thofe who are fkilled in this Branch of Diftillation, to try whether a Spirit fuperior to that of Treacle may not be procured from the Roh of Malt^ pru- dently prepared and fermented Tine-pui- 18. There needs no particular Experiment to ftiew the bufinefs of the Fine- Stiller \ that being no more than Working, in the Manner above explained, from a Wafti made by fermenting Treacle with Yeaft; though it is ufual to add a confiderable Proportion of Malt, and fometimes a little powdered Jalaps in the fermenting Back. The Malt accelerates the Fermentation, and makes the Spirit come out the cheaper ; and the falap prevents the Rife of any crufty Head on the Surface of the fermenting Liquor, and fo leaves a greater Opportunity for the free Accefs of the Air *, which alfo fhortens the Work, by turning the foamy into the more hifling Kind of Fermentation. Exp X R j- of Diflillation. 249 Experiment III. ^he Art of the Rectifier ; or the Method whereby the Proof -Goods of the Mall- Stiller are made into a cleaner Spirit^ for the finer Ufes of the Coin- pounder and Apothecary. 19. To two Gallons of the common Proof- Spirit of the Malt-Stiller, procured after the thn c/Spi- Manner of our fecond Experiment, we added W/j. three Ounces of the Black Flux, or a Mixture of Tartar and Nitre calcined to Blacknefs * ; and drew over all that would run in an uninter- rupted Stream from the Nofe of the Worm, by Means of the Balneum MarU. The Spirit which thus came over we made up Proof with fair Water. And the Spirit thus prepared is the com- mon faleable Proof Goods of the redifying Diftil- ler, when he works to a Truth. 20. This is the Spirit we commonly meet with in Trade under the Name and Notion ofrzV. Malt-Spirit.^ which is thus fitted for making the common Cordial or compound Waters; being cleared confiderably of its foetid Oil and nau- feous Phlegm, by Redification. If it be defired Hill cleaner one of the beft Methods is, to dilute the ftrongeft Part that comes over firft, with a large Proportion of fair Water, draw off the Spirit gently again by the Balneum Marine., and then make it up proof with fine foft Water. 21. But this Method will not yet give us the hicon‘ve.. Spirit without fome naufeous and difagreeable Flavour ; nor do the Redlifiers appear acquaint- ed with any good Method for that Purpofe. » See Lea. II. Exp. II. They 250 Lecture the Twelfth. They have been groping after it, but generally in the dark, for want of a proper Knowledge of the Fads and Experiments necelTary in the Enquiry. Thus, for inftance, they feem little apprehenfive that it is the Oil of the Malt, rcrfiding in the Spirit, which occafions ail their trouble ; or that it is the eflential Oil of the Subjed which gives to Malt-Spirits, Brandies, Rums, and Arracks their particular Flavours, For if the eflential Oil could be totally feparated from Malt-Spirit, that Spirit might be rendered flavourlefs and taftelefs ; and then any other Flavour might, by Means of other eflential Oils, be introduced into it *, fo that it might be made to refemble either French Brandy, Rum, or Arrack. And in the effeding of this, with Simplicity and Cheapnefs, the Perfedion of the Art of Redifying feems to confift, 'Remedied, For this purpofe we would recommend the Way of Working from a Spirit largely dilu- ted with Water, into Water again •, for thus the elTential Oil would be doubly feparated at one Operation. But we have no great Hopes that any Diredion of this Kind can prove ferviceable to them, while they remain unacquainted with chemical Operations, and the bed Contrivances for Diftilling in the large Way with Elegance and Simplicity. 23. The Chernids, however, have helped them to a tolerable Expedient for covering the Imperfedions of the Spirit which they cannot cleanfc*, viz, by the Addition of what is called Spiritus Nitri dulcis ; a fmall Proportion whereof will give an agreeable Vinofity to a Hogdiead of Spirit. Bnt this Expedient is attended with an Inconvenience ; for the Flavour is very apt to fly od', or be lod, when the Spirit is kept in a Calk : But the Succefs proves different, when 251 Of Dijiillation. the Spirit is kept and well (lopped down in a Glafs. 24. The Art of the ReElifier might be entirely i^tpronje- fet afide as ufelefs, if the original Malt - Stiller inents. could make his Spirit perfed at a fecond Opera- tion, as we judge he might. But here again the Malt Stillers can fcarce be brought to forfake the beaten Track. If they are difpofed to improve their Art, we would recommend to them, the Brewing in Perfedion ; and fecondly^ the Keeping of their Wafh, after the Manner of dale Beer, till it has entirely loft its Malt Fla- vour, and acquired a pungent, acid, Vinofity ; and then, thirdly^ leaving out the Lees, to diftil with a well-regulated Fire. Thofe who have not tried would fcarce conceive what an agreeable Spirit may be thus procured from Malt, at the very firft Diftillation. The gainful Part of the Secret depends upon an artificial Method of making Malt Liquors expeditiotifiy ftale^ bright^ and favour- lefsy but in other refpebis vinous Experiment IV. The Method of examining Proof in Spirits ; and de- tecting the Invalidity of the common IVays of judg- ing of the Purity^ Genuinenefs^ and Goodnefs of Brandies^ Rums^ and Arracks. Z5. We took a long Phial, half filled with the common Proof-Spirit of. the Malt- Stiller^ and giving it a fmart Stroak with its Bottom againft the Palni of the Hand, there appeared ‘ on the Surface of the Liquor a Chaplet, or Crown of Bubbles, which went off, or difap- peared, in a certain ftrong Manner ; that is, it firft *) See j^ppendix to Led, XI. See alfo te£l, VII. remained 252 Erroneous. detection. Sophijlica- tion. Lecture the Twelfth. remained a while, and then went off by De- grees, without breaking into fmaller Bubbles, or rifing into larger. And when the Bubbles go off in this Manner, the Spirit is faid to be proof or merchantable 26. And by this Kind of Proof all Diftillers, Brandy-Merchants, Brokers, and the Officers of the Cuftoms and Excife, judge of the Strength and Quality of Brandies and Spirits, in all the Brandy-Countries and Sea-Port Towns of Eu- rope ; wheace it is alfp conveyed to other Parts of the World. It may therefore appear ftrange to oppofe the general Opinion and Pradice, in a particular where the Intereft of fo many trading People, watchful againft all Impofition, is con- cerned : And yet we undertake to ffiew, that this Kind of Proof is a mere Fallacy and De- ception •, for if but a little vinous or faccharinc Matter, as 'I'reacle, Syrup, Muft, the Rob of Fruits, Cfr. be added to a Quantity of highly rediified Spirit of Wine, this flight Addition will give a Brandy- Proof to that Spirit; which, therefore, by this Trial, may be made to pafs for Brandy ; that is, for a Compofition of half Water and half Alcohol, whereas in Reality it is almofl: totally Alcohol. 27. The Fraud is eafily detected ; not in the common Way pra6lifed upon the K^Sy but by burning a little of the Spirit in a Spoon ; for thus it will leave ^he faccharine Matter behind in a dry Form. 28. Whether there be any Method com- monly known in EuropCy of making a fpirituous Liquor that contains much lefs than a half of Alcohol, to pafs current for Proof- Spirit, is not fo certain : But doubtlefs this might be * See Lea. VII. Exp, IV. § 36, 37. eafily of Difillation. 253 might be eafily efFe^led ; for we fee that Arrack is Proof, or affords a ftrong Crown of Bubbles, upon lhaking, as well as Brandy ; yet Arrack contains not ufually above half the Quantity of Alcohol that Brandy does \ and if but a Drop or two of its own or any other effential Oil be added to a Pint of Proof-Brandy, this is fuffi* cient to deftroy its Proof, and make it appear much weaker than it is. 30. To prevent being impofed upon In xK\%Difcavery, Way, we might have Recourfe to the EJfay- Inftrument^ or Hydroftatical Balance. A Gallon of Alcohol is computed to weigh feven Pounds and a half, and a Gallon of Water, eight Pounds ; whence the compound Gravity of an equal ' Mixture of the two may be affigned. But it is a more fure and ready Method, to burn a little meafured Quantity of the Brandy to be tried, in a cylindrical metalline Veffel, plunged in cold Water to an equal Height with the Brandy, and when it ceafes to burn, exa6Hy meafuring the Remainder, which is the Water : Where if the Spirit has loft one half of its Mealure by Burning, the Brandy may be allowed Proof; if more or lefs, it muft be judged of accordingly 31. But befides the falfe Method of judging of Efay U. the Strength of Brandies by what is called Proof, there is another no lefs fallacious one of judg** ing of their Genuinenefs ; tho’ kept a great Secret in few Hands, as a Thing fome Dealers imagine a certain Criterion for determining whether foreign Brandies are mixed with Corn Spirits. Thefe Dealers are provided with a certain yel itsVfe. low Liquor^ a few Drops whereof being poured See a Paper by M. Geoffrey^ to this Purpofe, in the Tranch Memoirs. into 254 - Lecture THE Twelfth. into a Glafs of right French Brandy, gives it a ?' beautiful blue Colour ; by the Strength and ^ Brightnefs of which Colour they judge of the ' Genuinenefs, or unmixed State of the Commo- dity, and buy upon this Kind of Proof : Whence they may come to be much deceived ; for if an ordinary Malt Spirit was to be coloured with Oak, it would fuftain the prefent Method of Proof, and might therefore be purchafed by thefe Dealers for French Brandy. llo-w 32 . This Proo-f’Tindlure, or EJfay Liquor^ made. may be expeditioufly prepared, by dilTolving a little green Vitriol (firft calcined to Rednefs) in a weak Spirit of Sea-Salt ; v/hich thus becomes a yellow Liquor^ a Tingle Drop or two whereof being added to a Glafs of any inflammable Spi- rit coloured yellow or brown with Oak, will inftantly turn it of a beautiful bright Blue : Whence it is evident that this Kind of Trial is no more than a Fallacy, and only fhews when Brandies are tinged with Oak, as they conftant- ly are by lying long in the Cafk." And that it is the Oak which thus caufes French Brandies to turn blue with the EJfay Liquor ^ appears again from hence ; That if the belt and oldelt French Brandy be re diftilled, and thus made colourlefs, it will not turn blue with the EJfay Liquor ; be- caufe all the Tindture of the Oak, or tinging Matter of the Cafk, is left behind in the Still. Its Fallacy 33* One of the bed Methods to prevent being deteatd. impofed upon by the Mixing of Malt-Spirit with a finer, is to acquire a Habit of judging by the Tafle and Smell ; for Malt-Spirit is ufu- ally To ill redfified, by the Addition of fixed alkaline Salts, or certain flavouring Ingredients, that it may eafily be perceived by the Nofe or Palate ; efpecially if the Brandy propofed for Examination be largely diluted with Water, to prevent of Difillation. 255 prevent its over-heating the Mouth ; or elfe be burnt in a Spoon, fo as to leave the Phlegm to be tailed and fmelt by itfelf : For this Phlegm, if the Brandy were debafed by a Corn Spirit, will tafte and fmell exceedingly naufeous, very different from the Phlegm of pure French Brandy. Experiment V. ^he heft Method of making Cordial or Compound Waters, 54. We infufed a Pound of frefh Citron-Peel Ciiron in two Gallons of good Melaffes Spirit, and tVaterfre- committing the whole to the Still, drew off the^'*''^'^- Spirit gently, with Care to avoid the Faints ; then making up^ as they call it, with foft Wa- ter, fo as to leave the Liquor Proof, we added half a Pound of fine Sugar, and thus procured a genuine Citron Water, 35. This Experiment is general, and ixpe- the ufual Methods of making all the Compound rimentex- or Cordial Waters, by thofe Diflillers who are called Compounders, and alfo by Apothecaries *, tho’ Apothecaries feldom make diflilled Waters fo good as the Compounders. 36. The Perfe6lion of this Branch of Diftilla- Compound tion depends upon the Obfervance of a few Diftuia- Rules, which might be eafily complied with : And thefe Rules we fhall here lay down, as jiidg- ing them of Confequence to the Improvement not only of the Art of the Compounder, but al- fo of a Branch of Pharmacy and Medicine. 37. The firfl Rule is, "To uje a well-cleanfed Hules, Spirit^ that is freed from its own ejfential Oil. For as the Defign of compound Diflillation is to impregnate the Spirit employed with the effential Oil 256 Lecture theTwelfth. Oil of the Ingredients, it ought firft to have dc- pohted its own. 38. The fecond Rule is, ^0 fuit the Time of previous DigelUon to the Tenacity of the Ingredient Sy or the Fonder oft ty of their Oil, Thus Rhodium- Wood and Cinnamon require to be longer di- gelled before they are diftilled than Calamus Aromalicus^ or Lemon-Peel. Sometimes alfo Cohobation (that is, the pouring of the Spirit once drawn off, back upon the fame Ingredients) proves neceffary ; as particularly in making the ilrong Cinnamon Water, where the effential Oil is extremely ponderous, and hardly rifes along with the Spirit, without one Cohobation more. 39. The third Rule is. To fuit the Fire or Strength of the Diftillation to the Ponderofty of the Oil intended to be raifed with the Spirit. Thus ftrong Cinnamon Water Ihould be diftilled off brilker than the Spirit of Mint or Baulm. 40. The fourth Rule is. That a due Propor^ fion of only the finer effential Oil of the Ingredients he thoroughly united or incorporated with the Spirit^ fo as to keep out the gr offer and lefs fragrant Oil. And this may be chiefly effeefted by leaving out the Faints,, and making up to ftrong Proof with fine foft Water in their Stead. And upon the Ob- fervance of thefe four eafy Rules the Perfedlion of the Art of compound Diftillation feems to depend. 41. The Addition of fine Sugar to Cordial Waters is a Thing of lefs Moment, and may be ufed or omitted occafionally. And if thefe Di- redlions be obferved, there will be no need of fining down Cordial Waters with Allum, WTites of Eggs, Jfing-Glafs, or the like ; for they v>ill be prefently bright, fweet, and pleafantly tafted, without any farther Trouble. 42. And Of Diftillation. 257 ^42. And thus we hope to have fhewn the Way of perfeding the Art of compound DiftiUation, : even by the common Alembic, or hot Still, with- i out the Ufe of the Balneum Mari^ ; for which ^ ! there is here no Occafion, if the Artifl; be but expert in working by the Alembic. j Axioms and Canons. I I. We learn from our prefent Enquiry, that inflammable Spirits are the Creatures of vinous Fermentation ; or that they are adually produc- ed, tho* not feparated, in that Operation a). 2. That the Adion of Fermentation produces fuch a Change in the Wafh, as to render it fe- - parable by the Fire into feveral Portions of Mat- ter, befides the inflammable Spirit, fpecifically I different from what the Liquor would have af- forded by the fame Treatment before Fermen- tation h). 3. That at different Times of Diftillation there come over Liquors of different t^roperties ; and firft of all, an extremely acrid, aromatic, and biting one ; which goes off by Degrees, and ends in Acidity c), 4. That the Art of Malt-Stilling may be con- fiderably improved •, (i.) by reducing the brew- ing and fermenting Parts to one Operation ; (2.) by diftilling flow, and (3.) by keeping back the grofs Oil of the Subjed. 5. That this Art^ may be farther improved, by fermenting a clear, well-brewed Wort, and keeping it to be ftale, or till it has loft all Fia- a) See Exp. I. />) See Lect. VIT. Exp IV. See alfo /Appendix to tccl. XI. r) See Exp. I. and Appendix to Ledt. XI. s vour 258 Lecture the Twelfth. vour of the Malt •, as it will naturally do by long lying, or in a very fliort Time by the Help of a certain artificial Treatment a). ' 6. That the Perfedlion of the Art of Mah- Stil- ling requires the AlTillance of a new Art, to pro- duce a Kind of Treacle from Malt, or the Re- dudlion of the Art ot zhc Malt- Stiller to the fame Simplicity as that of the Fine Stiller a), 7. That the effential Oil of the vegetable Sub- jedl: is the Thing which gives to ail Spirits their particular Odours and Flavours b). 8. That the fineft, moft fubtil and efficacious Fart of this effential Oil always rifes firff: in Di- ffillation b). 9. That the Purity and Perfedhion of Spirits, confidered merely as Spirits, greatly depend upon their being cleanfed firff: of the effTential Oil, efpecially its grolTer Part, and next of the Phlegm c). 20. That Brandies are a Mixture of one half Vv^ater, and the other half Alcohol; that the Meafure of the Strength of Brandies is the Qiian- tity of Alcohol they contain ; and therefore that their Water may be commodioufly left behind upon Exportation or Carriage d). 1 1. That as Brandies hold fome fmall Propor- tion of effential Oil, they are in Stridnefs di- lute Quinteffences c) \ whence their Properties and Effeds may be eafily explained, in a chemi- cal Manner. a) See Exp. I. and III. h\ See Exp. I. HI. V. 0 See Exp. I, II, III. V. d) See Exp‘ 1, II, HI, IV. 12. That Of Difillation. 11. That the Perfedlion of Redifying Spi- ! rits depends upon finding out a fimple Method I of fepararing all the Uii and Water from a > Spirit a). 13. That the great Affinity betwixt the effen- tial Oil and Spirit is the phyfical Caufe of the Difficulty found in the Redification of Bran- I dies b). ' I 14. That the Perfedlion of the Art of MaU- I Stillings whereby a pure Spirit might be procured ' at the firft Operation, would fuperfede the Art of Reclifying a). 15. That the Bubble Brandy-Proof may be artificially given to high redfified Spirit of Wine, and eafiiy deftroyed in Proof-Spirit, without I weakening the Spirit c). 16. That the common Methods of trying and examining Brandies by the Bubble-Proof, and by their turning blue with a vitriolic Solution, are abfolutely fallacious, and not to be trufted for the Purpofes intended d). 17. T\\2X phyfical Proof \n Brandies is the Pro- perty they have, upon fhaking, to generate a Crown of moderately large Bubbles on their Surface, by Means of a certain Tenacity, arifing from a dated Proportion of effential Oil diiTol- ved in among them •, which Tenacity may alfo be given by other Bodies d). 18. That a fure Method of determining the Strength of Brandies is by Deflagration, or burning away their Alcohol ; then examining the remaining Phlegm by Weight or Meafure, and a) See Exp lU. 0 Exp. I, II, III V. 0 Exp. Ill, iV. J) Exp.lY. S 2 comparing 26o L'ecture the Twelfth. comparing it with the Weight or Meafure of the Alcohol a), 19. That erroneous Notions, or inaccurate and falfe Methods of Trial, may prevail, and become almoft univerfal in Trade ; fo that even the prudent Merchant (hall buy and fell upon weak Trials, whilfl: the Dete6lion, Rectification, or Adjuftment thereof, belongs to fomc other Branch of Knowledge a), 20. That the Way of perfecting the Art of compound Diftillation is, (i) To procure a well-cleanfed Spirit; (2) To ufe proper Dige- ftion; (3) To diftil briflc, or flow, as the Sub- ject requires ; and (4} To keep back the Faints, and the grofs Part of the eflential Oil of the In- gredients b), d) Exp. IV; F) Exp.Y. LEG- I [ 261 ] LECTURE XIII. CONTAINING T!he Ways of procuring Vegetable Oils and Salts ; ^ith their Ufes in feveral Arts and Trades. I. I. T 7 C 7 E proceed to illuftrate and im- The Sub- V V pi*ove the common Methods of pro-i^^* curing and employing vegetable Oils and Salts ; on which the Exercife of various Arts and Trades depends. 2. The Parts of Vegetables that chiefly abound The oily with Oil are, the Seed, the Leaves, the Fruit, e/' and the Bark. Thus the Seeds of Milliard, and of the Sun-Flower, Almonds, Nuts, Beech- Mali, afford a copious Oil by Expreffion ; and the Leaves of Rofemary, Mint, Rue, Wormwood, Thyme, Sage, fsfr. the Berries of Juniper, Olives, Indian Cloves, Nutmeg, Mace, Li’r. the Bark of Cinnimon, Saffafras, bcc. yield a confiderable Proportion of effential Oil by Diflillation 3. And much in the fame Manner is Oil or Fat contained in the Parts of Animals ; being either interfperfed among the mufcular Flefh, colledled into particular Bags or Cells, or lodged in the Cavities of the Bones, See below, Exp. II. s 3 4. Our 262 ^he De/ign of the Ex- periments. Exprejfed Otl of Al- monds. ^he Expe- riment ex- tended. Lecture the Thirteenth. 4. Our Experiment will fhew the Me- thod of procuring Oils by ExprefTion, from Nuts, Seeds, Maft, Olives, i^c. T he Expe- riment will exhibit the Method of procuring thofe called the Elfential Oils of Vegetables. The third Experiment will fhew the Method of rec- tifying thofe called the Empyreurnatic Oils. Our fourth Experiment will fliew the Method of refining Sugar. The fifth Experiment will fhew the Way of refining Tartar : Our fxth the Manner of refining Nitre., or Salt-Petre ; and our feventh will fhew the Method of mak- ing Pot-Afh. Experiment I. The Method of procuring Oil hy Exprejfion^ from Nuts-i Seeds Maft., &c. / 5. We took two Pounds of SwTet Almonds, blanched, and beat them fmall ina Stone Mortar ; then wrapping the Mafs up in a Piece of ftrong and thick Canvas, we committed it to a ftrong Screw-Prefs •, where being fqueezed betwixt two cold Iron Cheeks, it gradually parted -with a confiderable Quantity of Oil. 6. This Experiment holds of all thofe vege- table Matters that contain a copious Oil, in a loofe Manner, or in certain Cavities or Recep- tacles 3 the Sides whereof being burft by fqueezing, makes them let go the Oil they con- tain. And thus the Zeft, or Oil of Lemon- Peel, Orange Peel, Citron-Peel, may be readily obtained by Preflure, without the Ule of Fire ; for the Rinds of thofe Fruits being pref- fed green, the oily Parts will feparate from the aqueous. Of oils and Salts. aqueous, and may be rendered pure by wafliing them in fair Water *. 7. How far this Method of obtaining Oils may be applied to Advantage, feems not hitherto confidered. It has been commonly applied to Olives, Almonds, LintAeed, Rape-feed, Beech- Mad, Ben-Nuts, Wallnuts, Bay-Berries, Mace, Nutmeg, ^c. but not that we know of to Ju- niper-Berries, Cachou-Nuts, IndianClowts^ Pine- Apples, or Fir-Nuts, and m^any other Subjects that might be enumierated, both of foreign and domeftic Growth. It has however been of late applied to Muftard-feed, with good Succefs ; fo as to extradl a curious yellow, or golden-colour- ed Oil from that Seed, and at the fame Time leave a Cake behind fit for making the com- mon Table Muftard. 8. Certain dry Matters may, as well as moifl ones, be made to afford Oils by Expreflion j for when they are not fo moift as Almonds, or fit to be reduced to a Pulp in a Stone Mortar, they may be ground into a Meal, which, being fu- fpended to receive the Vapour of boiling Wa- ter, will thus be moiflened fo as to afford an Oil, in the fame Manner as Almonds ; efpecially if the Iron Cheeks employed be firfl heated, by lying in boiling Water. And thus an Oil may be procured from Lint-feed, Hemp-feed, Let- tuce-feed, White Poppy- feed, Ct’c. 9. The Oils obtained by this Treatment, fliould be fuffered to depurate themfelves by - ftanding in a moderately cool Place, to fepa- rate from* their Water, and depofite their F^ces ; from both which they ought to be carefully freed. And if in this Manner they are not ^ See below, § 9. S 4 rendered, 264 Lecture the Thirteenth. rendered fufficiently pure, they may be well wafhed and beat with frefli Water, and then thoroughly feparated/rom it again, by the Sepa- rating-Glafs ; by which Means they will be ren- dered bright and clean. 10 Particular Care muft be taken to keep fuch of thefe Oils cool as are defigned for eat- ing, or for any internal Ufe ; becaufe they are apt in a few Days Time to turn rancid and cor- rofive with the Summer’s Heat, fo as to prove very unwholdome. Hence the Phyfician and Apothecary fhould be cautious that the Oils gi- ven in Pleurifies, and other Diftempers, be frdli drawn from found Subjeds, no way tainted, or already turned rancid, as Almonds, Piftachios, and other Nuts, are apt to be : And again, that thefe Oils have felt no confiderable Heat, either in the Drawing, or by landing long in a warm i'lace. And the fame Caution fhould likewife extend to animal Oils and Fats, intend- ed either for internal or external Ufe ; fince thefe aifo become rancid, or change to a yel- low, red, or grey Colour in hot Weather, and thus become exceedingly naufeous andcorrofive ; as we fee in Butter, Bacon, and other fat Bo- dies, which then prove fit only for the Tallow- Chandler, or other ignoble Ufes. Applied to II. Our prefent Experiment is likewife ap- othei Sub plicable to the procuring of Oils or Fats from certain animal Subjeds ; for the Membranes, the fldnny, and firingy Parts of animal Bodies, which contain much Fat, being chopped fmall, and let in a Pan over the Fire, become nt for the Canvas- Bag, and by Preffure afford a large Quantity thereof ; as we fee in the Art of Chandlery, which thus extrads the oily Matter, leaving Of Oils and Salts. 265 leaving behind a hard Cake, or what they com- monly call Graves. 12. Thefe Graves^ and all the Refiduums of the prefent Procefs, after being fqueezed ever fo hard with the Frefs, will flill afford a copious OiJ by boiling in Water; fo that it might per- haps be more profitable for the "Tallow Chandler • to boil his Graves for Oil, as Bones are ufually boiled for it, than to difpofe of them in the or- dinary Manner. And it is furprizing to obferve, what a large Proportion of Oil thefe dry, and to appearance almofl exhaufted Bodies, will yield, by repeated boiling in Water, but parti- cularly by being committed to the Digeftor 13. So likewife if the Almonds remaining in Farther the Canvas, after the Exprefiion of their Oil, be ground in a Mortar with warm Water, the Wa- ter will thus extradc their remaining Oil, and turn therewith into a milky Liquor, or Emulfion. And if this Operation had been periormed upon the Almonds at firfl, before we committed them to the Prefs, we might thus have got out all their Oil, and left only a dry, chaffy, or light, huflcy, and exhaufted Matter behind. Whence we have a Method of difiblving Oils in Water, and there- by of making a Kind of artificial Milk ; which, by ftanding, will afford a Cream, and turn four, like the Milk of Animals, but not grow rancid with Heat, like Oil. Whence fucff Emulfions may, in fome Cafes, be medicinally ufed with greater Safety and Succefs than expreffed Oils. 14. Any of thefe exprefied Oils will receive 0//Wc- particular Colours and Odours at the Difcre- hurcd. tion of the Artift. For Example : If a little * See Ua.ll.Ext. VII. Alkanet- 266 Lecture the Thirteenth. Alkanet-Root be barely infufed in Oil-Olive, it gives a beautiful red Colour to that Oil, with- out altering its Tafte. So again ; if a few Drops of the eflential Oil of Cinnamon be added to a Pint of Sallad Oil, fuch Sallad Oil may be ren- dered thereby agreeable to thofe who admire the Flavour of Cinnanjon. And thus may Oil, Butter, ^c. be diverfified infinite Ways, by a proper Ufe of tinging Ingredients, and fuicable chemical Oils. Ifenceu i§. The fame Contrivance has likewife its ' Ufes in making Effences for the Service of the Perfumer ; not only where elTential Oils are pro- , curable, but alfo where thefe either cannot well be obtained, or but in fmall Quantity. The ef- fential Oil of Jaf nin FlovN^ers, Honey-Suckles, Sweet Briar, Damafk Rofes, Lilies of the Val- ley, are either extremely dear, or fcarcely obtainable by Diftillation ; and in fome of them the odorous Matter is fo fubtil as to be almoft loft in the Operation. But if Jafmin Flowers, Damafk Rofes, Lilies of the Valley, be barely infufed in fine Oil of Nuts, or Oil of Ben, drawn without Heat, and kept in a cool Place, the fubtil odorous Matter of the Flowers will thus pafs into the Oil, and richly impregnate it with their native odoriferous Spirit *, which can fcarce otherwife be procured, or feparated from the Flowers, without Lofs, or Debafement. And thefe Effences may be rendered perfedf by ftraining off the Oil at firft put on, letting it ftand again, without Fleat, upon frefh Flowers, and repeating the Operation twice or thrice. M'hat they ^ we confider the Thing attentively, we fiiall find that the Effences thus obtained are a Kind of ejfential Oils^ not greatly differing from thofe prepared by Diftillation from the Flowers, Seeds, Of oils and Salts. 267 Seeds, or Barks of odoriferous Vegetables *, for ■ all fuch ejfentid Oils are found to be little more than the native odorous Spirits of the vege- table Subjedf, wrapped up, lodged, or entan- gled in an unduous or dired oily Subftance. This oily Subftance indeed rifes, or becomes volatile, by the Heat of boiling Water ; but fo do not the Oils gained by ExprefTion ^ : Whence the principal Difference betwixt thofe natural^ and artificial efiential Oils., as we may call them, feems to confift; in the different Te- nacity, Volatility, or Fixednefs of their undu- ous or dired oily Parts, the native Spirit ap- pearing the fame in both •, tho’ indeed it is more delicate and unimpaired in the artificial Kind of effential Oils, as not having felt the Force of Fire. And hence perhaps fome con- fiderable Improvements might be made in the Art of the Oilman, Perfumer, and Apothecary ; not to mention other oeconomical Ufes, and the Art of the Dairy. Experiment II. Phe Method of procuring the effential Oils of Vege- tables by Diftillation with IVater. ly. We took eight Pounds of Juniper Effential ries, and bruifing them in a Stone Mortar, diredly put them into a Still, together with four Gallons of River- Water •, then working with briflc Fire, we drew off a Gallon of Water, and obtained along with it a confiderable Propor- tion of a fragrant effential Oil, which we See Exp, II. hereafter. fepa- 268 ^he Expe- rt me tit ex tetided. Ufes. EJJential Oils daf- fed. Lecture the Thirteenth. feparated from the Water by a Separating- Gials. 1 8. This Experiment is eafily rendered ge- neral, or made applicable to the Diftilling of the eiTential Oils from Flowers, Leaves, Barks, Roots, Woods, Gums, and Balfams, with a flight Alteration of Circumftances *, as by longer Digeftion, brifleer Diflillation, according to the Tenacity and Hardnefs^ of the Subjedl, the Ponderofity of its Oil, a), 19. If the Liquor that remains in the Still, after the prefent Operation, be ftrained, and evaporated to the Confidence of Honey, it makes the Roh of Juniper-Berries^ which may per- haps defray the Charge of the Operation, it being efleemed a valuable Medicine, and ufed as a Strengthener of the Stomach and Inteftines, as a Prefer vative from the Stone and Dropfy, and as a Cure for the Diforders of the urinary Paf- fages. 20. EiTential Oils may be divided into two Claires, according to their different fpecific Gravities *, fome floating upon Water, and others readily finking to the Bottom thereof. Thus the eflential Oils of Cloves, Cinnamon, and Saffafras readily fink*, but the Oils of La- vender, Marjoram, Mint, fwim in Water. The lighteit of thefe eflential Oils is, perhaps the Oil of Citron-Peel, which floats even on Spirit of Wine *, and the heaviefl; feems to be the Oil of Saffafras : But the fpecific Gravities of the in- termediate eiTential Oils are not hitherto ad- jufled and tabled, as for the Service of Chemifl:ry they ought to be b). a) See Led. XII. Exp. V. h] Seebebvv, 29. * 21. For Of Oils and Salts. 269 21. For obtaining the full Quantity of more ponderous Oils from Cinnamon, Cloves, t^^jnedto Saffafras, it is proper (i) to reduce the Subjeds to fine Powder *, (2) to digeft this Powder for fome Days in a warm Place, with thrice its Quantity of foft River Water, made very faline by the Addition of Sea-Salt, or fharp with Oil of Vitriol; (3) to ufe the drained Decodion, or Liquor left behind in the Still, inftead of common Water, for a frelh Dige- ftion ; (4) to ufe for the fame Purpofe the Wa- ter of the fecond Running, after being cleared of its Oil; (5) not to diftil too large a Quan- tity of thefe Subjeds at once ; (6) to leave a confiderable Part of the Still, or about one fourth, empty ; (7) to ufe a briflc Fire, or a ftrong boiling Hear, at the firft, but to fiacken it a little ^terwards ; (8) to have a low Still- Head, with a proper internal Ledge and Cur- rent leading to the Nofe of the Worm ; and (9) to cohobate the Water, or pour back the Liquor of the fecond Running upon the Matter in the Still, repeating this once or twice. 22. Thefe Cautions are all necelTary, in or- Reafons of der to diftil the ponderous eftential Oils to Pro- the Cau- fit and Perfedion. The phyfical Reafons where- on they depend may deferve to be confidered. (i) The Redudion of the Subjed to Powder, expofes all its Parts the better to the Adion of the Water and Salt ; whereby the Oil is the more mollified, attenuated, and rendered fitter to rife along with the aqueous Vapour in Diftil- lation. (2) The Digeftion is requifite for the fame Reafon ; as being no more than allowing Time for this Adion to be performed, in a mo- derate Warmth. The Water fhould rather be the foft Water of Rivers, than that of Rain, which is more corruptive or fermentative ; or than 270 Lect URE THE Thirteenth. than that of Springs, which is often hard, fo as not to mollify the Oil, but rather defend it from the Adlion of the Salt, or Acid ; which are added not only to prevent all Tendency to Fer- mentation or Corruption, that would abfolutely change or deftroy the Oil, but more particu- larly, as having a known Property of attenua- ting, liquifying, diffolving, and purifying grofs, vifcous, and tenacious Oils. Befides which, it likewife increafes the fpecific Gravity of the Water ; whereby the Subjed; is now buoyed up, fo that it cannot readily touch the Bottom of the Still, or come in the way of the Fire to be fcorched. At the fame Time this Addition aifo increafes the Heat of the Liquor, or makes it exceed that of iPiCre boiling Water ; whence the Afcent of the Oil is likewife promoted. (3) The drained Decodion is propq^ly ufed in- ftead of Water, as being already faturated with oily Particles, fo that it cannot much rob the Sub- ject. And (4.) the fame holds alfo of the Water of the fecond Running, which neceflarily con- tains fome oily Particles. (5) If too large a Quantity of the Subjed: be diftilled at once, the FIcat will neceffarily ad: unequally, or be ffrong upon fome Parts, and weak upon others *, whence, as the Oil is fo extremely ponderous, a large Fart of it will be left behind in the Sub- je6f. (6) If too much empty Space be left in the Still, it will be difficult for the ponderous Oil to afcend ; and if too intenfe a Heat be ufed, it deftroys the grateful Odour of the Oil, without raifing any confiderable Quantity ; and if the Still be filled too full, the Matter will be apt to boil over, and foul the Oil. (7) The Fire is ordered to be brifk at firft, to prevent the Oil, now in fome Meafure feparated by the Heat, from going back into the Subjed: : But 271 of Oils and Salts. i But after a Part is thus come over, if the Fire be not a little flackened, the Oil is apt to fcorch, : and come out at the Nofe of the Worm in the i Form’ of a Smoke, that cannot be catched and . condenfed 5 yet the whole Operation need not be continued long, or above two Hours, becaufe the valuable Part of the Oil foon comes over. (8.) If the Head of the Still be not low, the pon- derous Oil will have too far to rife ; and unlefs the Oil be direded to the Worm by a proper Ledge and Current, a confiderable Part will fall back into the Still, and fo prolong the Opera- tion, or lefTen the Yield. (9.) Laftly, two or three Cohobations, or Returns of the Water upon the Subjed: in the Still, mult needs bring over all the Oil that will any way rife. And Water already fomewhat impregnated with the Oil, is manifeftly better for the Purpofe than fuch as has never been ufed before. 23. The Diredions here laid down, for ob- taining the ponderous effential Oils to Advan- tage, are eafily transferred to the obtaining of the lighter : So that we need not dwell particu- larly upon them. 24. Many of thefe effential Oils being coftly Effential things, it is common to adulterate or debafe them feveral Ways, fo as to render them cheaper both to the Seller and Buyer. Thefe feveral Ways feem reducible to three general Kinds, each whereof has its Method of Detedion ; for as in Logic every Sophifm has its Redargution, fo in Chemiftry every Fallacy may be difeovered. 25. Effential Oils are adulterated, fi.j with expreffed Oils, f 2. J with Alcohol, and ('3.Jwith cheaper effential Oils. 26. (i.) If any effential Oil be adulterated 7 “/^^ with an expreffed Oil, this is eafily difeovered, difconter^ by adding a little Alcohol to.a few Drops of the fufpeded 272 Lecture the Thirteenth. fufpe( 5 led effentiaJ Oil, and diaking them toge- ther: For the Alcohol will thus diiTolve all the Oil that is truly eiiential, or gained by Diftilla- tion, but leave the exprelfed Oil untouched j where- by the Compound of the two will be feparated, fo as that their Quantities may be judged of, or the Proportion ot the Debafement found : And then by adding Water to the Alcohol, which had taken up the eflential Oil, the Water will unite with the Alcohol, and leave the eflential Oil fe- parabie in its own Form. 27. (2.) It an eflential Oil be adulterated with Alcohol, as it may be in any Proportion up to that of an equal (^lantity, without being eafily difcoverable either by the Smell or Tafte : the Way of Detection is, to let a few Drops of the fufpeded Oil fall into a Glafs of fair Water; tor if Alcohol be mixed with the Oil, the Water v/ili immediately turn milky, which it would not do if the Oil were pure. And by continu- ing to fhake the Glafs, the whole Quantity of Alcohol employed in the Adulteration will unite with the Water, and leave the Oil un- diflblved behind. ( 3 ') The third Method above mentioned, of adulterating the richer chemical Oils, is by mixing them with the cheaper eflential Kinds ; fuch In particular as the Oil of Pine- Wood, Oil cf Turpentine, &c. And this is frequently praflifed, by putting Fir-Wood, Turpentine, or Oil of Turpentine, into the Still, along with the Herbs, fuppofe Rofemary, Lavender, Ori- ganum, (sfc. in the fame Manner as Diftillers add common Malt Spirit in theDiftilling of Wine Lees And by this Means the Yield or an Oil may be confiderably increafed. But the Oils thus adulterated wdll difcov^er themfelves in Time, by the want of their natural Flavour, which of Otis and Salts, 273 ^hich is overpowered by that of the Turpen- tine, But the quicker Detedion is, to drench a Piece of Paper, or a Linen Rag, in the fufpeded Oil, and hold the Paper or Rag before a gentle Fire; for thus th^ grateful Odour of the Plant will foon fly off, and leave only the Smell of the Turpentine, 29. But if this Way of adulterating efiential Oils be pradflfed in Perfedlion, it feems fcarce difcoverable, unlefs the ^ahle of the fpecific Gra~ vities of effential Oils, above recommended were ready at Hand. For it is known to fome few that Balfam Capivi yields a large Propor- tion of elTential Oil by Diftillation with Water, even to the quantity of five or fix Ounces from a Pound; and that this Oil is much fweeter than any of thofe before faid to be ufed for Adulteration : Whence it is eafy by diftilling any of the aromatic Vegetables along with this Balfam, or by mixing their Oils with the Oil of Balfam Capivi,, to debafe them largely, with- out being greatly fubjedl to Difeovery, except by the more philofophical Chemifis, who under- hand the ufes of the Hydroftatical Balance, But it fhould be obferved whether, by long keep- ing, the chemical Oils thus adulterated with the Oil of Balfam Capivi^ will not difeharge the Ink of the written Label, faftened to the con- taining GJafs, as efiential Oils adulterated with Oil ot Turpentine, or other terebinthinaccous Oils, are found to do, on account of the acid Vapour that continually exhales from fuch adul- terated Oils. 30. The Methods already laid down for de- tecting the Sophiftications commonly praClifed in efjential Oils,, are general ; btfides which ^ See §. 20. T fome 2 74 Lecture the Thirteenth. fome Oils require peculiar Methods. Thus the efifential Oil of Camomile Flowers may be cer- tainly known to be adulterated with Copper and Oil of Turpentine, Cfc. if it retains its original blue Colour above a Year. The efifential Oil of Rue^ if genuine, remains fiuid in the Cold, and if a- dulterated, congeals. And every Fad of this Kind, of which there are many already known, fhould be duly collecled : For it is certainly of great Importance to Medicine, that the genuine efifential Oils of Vegetables fnould be well di- ftinguifhed from the adulterated, becaufe capable of producing extremely different Effeds in the Body ; a Confequence little regarded by the frau- dulent Adulterator. E X P E R I M E N T 111. A Method of verifying Empyreumatic Oils, Empyreu- 3 1 . It was obfervable in our dry Diftillations Tnatic Oil of Wood a)^ Wormvvood ^), and Bone rj, (^c, f^metned. always came over a grofs, fetid, empy- reumatic Oil, of a naufeous Smell, difagreeable Colour, and abominable Talte. To redify this Oil, we took two Pounds thereof, and w^afhed it well by the repeated Affufiou of hot Water, and ftirring them well together, till at length the Water came away confiderably pure; where- by the Oil was rendered lefs naufeous both to the Smell and Tafte : Then fecting it in an open Vefifel over the Fire, that it might difeharge the Water lodged therein by the Wafiiing, we afterwards put it into a Glafs Retort, and drev/ it over in a Sand Heat; whereby it left behind a black, a ) See Le8. II. Exp^ III. b) SteLebl. VIII. Exp. 11. /j See Lell. YHI. Exp. I. feculent. 275 of Oils and Salts. feculent, or burnt crufty Matter, and became more fluid, fweet, and mild. 32. If the Diftillation be repeated ten or T'heExpe- twelve times, either in a frefli Retort Zfdflf time, or in the fame, the Oil being conftantly returned upon its own Faces^ or Ca-put mortuum ; thefe Faces will every time increafe in Quantity, fo as to leave the Oil purer and thinner, till at length it becomes almoll as thin and fluid as Oil of Turpentine, or Spirit of Wine *, being extreme- ly volatile, tranfparent, and penetrating, but (till of a hot, pungent Tafte, and a fomewhat faint and difagreeable Odour. 33. This Oil, obtained from an animal Sub*^^-^- je6t, particularly from Blood, has been lately □fed in England^ as a Remedy for the Epilepfy, Gour, and other obftinate Difeafes, under the Name of Oleum animale. It was many Years fince ufed for the fame Purpofcs in Germany Yet doubtiefs it fhould not be given too freely as an Internal : But, as an external Medicine, it may be of Service in refolving hard# Tumours, re- moving fixed Pains, for it is extremely pe- netrating and difcutient. And on this Account it might, perhaps, be ufed to Advantage in feveral Arts that require a highly fubtilized Oil. 34. But it being chargeable to bring the grofs empyreumatic Oils to this Degree of Purity and Subtilty, many chemical Operators continue to throw them away as ufelefs •, and the rather, becaufe of that intolerably naufeous Smell and Tafie with which they affed: all Things that they couch, or come in the Way of. But as large Quantities of thefe Oils are neceiTarily obtained in the Diitillation of Harts-Horn, Blood, iFc, . * See Hoffman. Ohfervat. Fhyjico. Chym. p, 58. 59. T 2 it_ 2']6 Lecture the Thtrteenth. it may be worth trying, whether they cannot be purified in a cheaper Manner than that above defcribed : For Example ; By drawing them over from Pot-Alh; or, what is ftill more profitable, by digefting them therewith, fo as at length to turn the Mixture, by Sublimation, into a vola- tile, alkaline Salt, as good as that of Harts-Horn, Blood, putrefied Urine, And thus much for the Subje6fc of vegetable Oils. We next proceed to vegetable Salts. II. Experiment IV. ^'he Method of refining Sugar ; or bringing the fvoeet Juice of the Sugar-Cane into a white^ dry^ and folid Suhjlance, Sugar re- We took fix Pounds of coarfe or black Sugar, as it comes unrefined from the Sugar- Colonies, and ^iflblving it, over the Fire, in an equal Qiiantity of ftrong Lime-Water, we ad- ded the Whites of four Eggs, v/hificed up into a Froth, and ftirred the Whole v/ell together, in order to clarify the Sugar, after the fame Manner as Syrups are ufually clarified ; we then boiled the Liquor to a higher Confiftence than that of a Syrup, or till it would fhoot grainy in the Cold. To make it do this the better, we continued to add Lime-Water at feveral times in the boiling. Having obtaine(J this Point of Confifience, by the Sugar- Refiners called Proofs we poured the whole into a Sugar- Baker’s Earth- en Mould, flopping the Hole in the lower End, and fetting the Mould in a moderately warm Place, the Sugar, after fome Days, fet hard, or hardened j then opening the lower * . Orifice of oils and Salts. 277 Orifice of the Mould, we inverted the fharp End into a little Pot, or Sugar-Baker's Receiver^ and applied to the wider End, or on the Top of the Sugar, a Mixture of Tobacco-Pipe Clay and Water, made into a Kind of thin Pafte, or pappy Subftance. And thus the Water quitting the Clay, foaked through the Sugar, without dif- folving the grained Part, and carried down with it only the treacly Matter, lodged betwixt the Pores of the Sugar ; which treacly Matter was catched by the Receiver underneath. And thus, by keeping the Clay frequently wetting, and fometimes renewing it, all the Treacle was got out, and a pure Eoaf of White Sugar left be- hind *, which we afterwards dried in a w’arm Chamber, and kept it in a dry place. 36. The chemical Hiftory of Sugar deferves to be traced through all its Stages. The rip^cefsand Sugar Canes are ground dov/n in a Mill betwixt Iron Rollers, kept continually feeding ; fo that the expreffed Juice runs in a conftant Stream, into its proper Receiver, from whence it is foon com- mitted to the firft boiling Pan, to prevent its turning eager: there it is boiled, Icummed, and cleared of its grofler and lighter Feculencies that float a-top, and alfo drawn from its hea- vier F^ces which' fall to the Bottom. And thus the Juice is brought to a Kind of Mfllago^ or Rob For the Juice of the Sugar-Cane, when firfl: boiled down, is like the Rob of Malt, Rai- flns, the boiled Juice of the Birch or Sycamore- Tree, and would never appean.in the faline Form of Sugar, without fome Contrivance to feparate its herbaceous, feculent Parr, and a particular Addition to give it a confiflent Form. Both thefe Ends are anfwered by the Addition T 3 * See Ua, X. Exp. III. of 278 Lecture the Thirteenth. of Lime-Water : For the Rob of the Sugar-Cane being of an acid and uncStuous Nature, the Quicklime deftroys the prevalent Acidity, dif- folves and feparates the grofifer un6luous Mat- ter, and at the fame time, combining along with the truly faccharine Part, gives a Iblid and dry Confiftence. And fomething of this Elfebt Lime-Water has in every frefh Boiling; fo that by a prudent Ufe hereof the Sugar may, after repeated Operations, or by boiling it over again with more or ftronger Lime-Water, be brought aimoft to a cryftaliine P'orm. And on the Strength, Goodnefs, and Quantity of the* fine Part of the Lime, thus introduced into Su- gar, depends the Hardnefs, Whitenefs, and ihining, rocky Refplendency of Loaf-Sugar. So that the Perfection of the Refiner’s Art depends in a great Meafure upon the prudent Choice of his Lime, and the Management of his Lime-Water. 37. The treacly Matter feparated from the Sugar, is colleded together and boiled, feum- rned, and treated with Lime-Water again, to obtain from it all the Sugar that it will afford in a dry form. When no more can be procured from it by the Sugar-Baker, it is then called ^Treacle \ being before ufually termed Syritp^ which it perfedlly refembles : ’ Jnfomuch that a thorough Knowledge of the Art of preparing Syrups^ w'ith the Effedls of their Different Confidences, and their Dirpofition to ferment, turn acid, or candy, and the bed Ways of clarifying them, &c. may contribute to improve the Art of Sugars ; and accordingly it appears, that moft of the Improvements in the Refining of Sugars have been owing to Apothecaries and Chemifts. 38, Sugar, I of Oils a 7 id Salts. 279 38. Sugar, thus refined, and difcharged of its fuperfluous oily Parts, is thereby rendered dry, thirfty, or apt to imbibe aqueous Moifture or Oil ; upon which Property depends that ufeful Invention of Elaof ac char urns ^ occafionally mentioned above by means whereof we are fur- nifhed with a very advantageous Method of unit- ing Oils with Waters, Wines, Spirits, or all Manner of aqueous, vinous, or fpirituous Li- quors ; fo that fuch Liquors may be altered in their Flavours, and improved in their Virtues, at I pleafure. For, by grinding a fmall Proportion I of any eflential Oil with dry Loaf-Sugar, the Oil is thus rendered mifcible with any of the above mentioned Liquors, and at the fame Time is no Way impaired, but rather improved in its Efficacy. 39. And thus we are taught an extempora- neous Method of making all thofe fimple and compound Waters, whofe Virtues depend upon the effential Oils they contain *, which is the Cafe of mod fimple Waters, as thofe of Mint, Pen- nyroyal, Nay, fome fimple Waters may be procured in greater Perfedion by this Means than by Diftillation, as it is commonly perform- ed. Thus the fimple Water of Baulm, for In- ilance, may be made better by means of the El(eofaccharum^ of Baulm and pure Water, than by fimple Diftillation, which in this Cafe brings over but little of the eflential Oil. 4.0. And for compound Waters, they may be thus made to greater Perfedtion than we ufually meet with them. For if only the firft Part of the eflential Oils that comes over be ground with Sugar, and introduced into a very clean Spirit, the Cordial Waters fo prepared will .be ^4 * See L.a. XI. Exp. I, no 280 Lecture the Thirteenth. no way inferior to thofe diftilled in the ordinary Manner. And thus Cinnamon-Water, Clove- Water, Nutmeg- Water, Citron- Water, Cfr. which depend upon the Ufe of but one Ingre- dient, may be readily made. And if compound Waters are required from feveral Ingredients, vve need only have a compound Elaofacckarum at Hand. 41. Thefe El ^ofac char urns alfo, as they are eafily made, either fimple or compound, in great Variety, might help to improve the Art of Cookery, as affording the Virtues of Aromatics in a commodious Form, for feveral oeconomical Occafions *, and may thus be carried the long- eft Voyages without Danger of fpoiling, or of having their Virtues impaired: an Inconvenience to which the natural Spices, though ever fo well cured, are liable. 42’ Again; A proper Set of thefe EUofac- charums might afford a Variety of ferviceable Medicines, that fnould have all the Qualities re- quired in the beft ; that is, ihould be at once fimple, parable, efficacious, and pleafant : For as effiential Oils contain the fpecific Virtues of the Subjeds, or thofe Qualities which conftitutc every Plant the Thing it is, they are of Confequence fome of the moft concentrated, powerful, refto- rative, and reviving Medicines hitherto known. Experiment V. ^he Way of Refining Ear tar, Tartar re- 43* Pounds of common white fined, Tartar rt'duced to Powder, and put to it five Gallons of fair Water, in an earthen Pan, and fetting it over the Fire to boil, we in the mean Time beat up the Whites of two or three Eggs, and < of oils and Salts. 281 and whifked them in among the Liquor, which we afterwards fkimmed and drained *, then fet it to fhoot in an earthen Veffel, in a cool Place, , for two Days, at the Expiration of which we found a Parcel of whitifh Cryftals (licking to the Sides of the VeOTel. 44. This is a very troublefome and hconn^e* Operation; for Tartar requiring twenty times its own Quantity of Water to diffolve it, the Veffels, the Fire, and the whole Apparatus, mu(t of Neceffity be large to refine a fmall Quantity of this Salt; which yet is nor fufficiently refined at one Operation, though the Whites of the Eggs take up much dirty, and light earthy Matters, while the more ponderous fink to the Bottom upon (landing. Hence the Operation mud be feveral times repeated, before the Crydals will become perfedlly white; which they will fcarce ever do, if the Vefiel wherein the Operation is per- formed be metalline ; and Velfels of Earth, which this Salt does not corrode, being hard to procure fo large as they are required for the Fur- pofe, this adds to the Inconvenience. 45. It is true, for mod Ufes in Chemidry, Remedied. unrefined Tartar will anfwer as well as the re- fined , but for the Service of certain Arts, par- ticularly Dying, it is required thoroughly puri- fied : So that a more commodious Method of refining it diould be endeavoured after, that we might at lead be able to refine it in England^ as well as they do in France. 46. Tartar is of a very particular Nature ; being a folid and firm vegetable Salt, extremely hard to dififolve in Water, as containing much earthy and unduous Matters, which defend it from the Adion of Water : Vv^hence we are di- reded to fofeen the Body of this Salt, or loofea its 282 Lecture the Thirteenth. its Texture, in order to its more commodious Refinement. And this End may be obtained by a prudent Ufe of Lime-Water, or a weak Lixivium of Pot-Afh, or Salt of Tartar ; as in the Making of tartarized Tartar where com- mon Tartar is united with its own fixed Salt, and rendered eafily foluble in a fmall Proportion of Water. But there need not be fo much Alkali ufed for this Purpofe, as to deffroy the Acidity of the Tartar *, and if too much fhould happen to be added, it may be mortified with Oil of Vi- triol, fo as not to prejudice the Salt. "The E Xpe- rt r/ient per- jeded. 47. But where an extremely pure and perfedl Cream or Cryflal of Tartar is required, we re- commend the ordinary Cryflals, or Cream of Tartar, to be diffolved in Water, made highly acid with redified Oil of Vitriol ; for if the fuperfluous Humidity be afterwards exhaled, the Tartar will thus fhoot into perfedly tranfparent and beautiful Cryflals, without at all participating of the Oil of Vitriol. And by the Help of thefe Diredlions common Tartar may be refined in great Perfedlion, and with no greater Trouble than the more foluble vegetable Salts. ijjss. 48. When the Powdered Cryflals of Tartar are mixed with half their Weight of Salt of Tar- tar, and diffolved together in boiling Water, they make a very extraordinary neutral Liquor, or Mevftruum ; and by Evaporation a neutral Sale of very uncommon Properties. This Salt eafily runs in a moifl xA.ir; and will powerfully alTift in extradling the refinous or oleaginous Parts of Vegetables, by being boiled with them in Wa- ter. The aqueous Solution of this Salt will dif- folve the tough Bodies even of Myrrh, Gum- ^ See below § 48. Lac, 283 of Oils and Salts. j Lac, and is much better fitted than Salt of i Tartar for many of the fame Purpofes where i that Salt is commonly employed. This neutral ! Salt, or tartarized Tartar, is exxellent in healing i Wounds, and cleanfing Ulcers : It is an agreeable I and iliccefsful Purgative in hypochondriacal Cafes ; I! and, diflblved in Water, makes a pleafant Kind of Purging Water, Its Virtues and Powers, I both as a Menftruum and a Medicine, feem i not hitherto fufficiently known ; whence we re- commend it to farther Experience. Experiment VI. The Method of Refining Nitre ^ or Salt-Petre, 49. We diflblved four Pounds of rough Nitre, as it comes to us from the Indies.^ by boiling in as much Water as would commodioufly fuf- fice for that Purpofe ; then fet it to fhoot for two or three Days in a covered Veflfel of Earth, with Sticks laid acrofs for the Cryftals to adhere to. Thefe Cryftals being afterwards taken out, were drained and dried in the open Air. 50. This leems to be the beft and fimpleft Method of purifying Nitre ; for thus, by its own natural Property of cryftallizing, it fhoocs pure from the Sea-Salt, or other Foulnefs that is apt to mix among it. However, if the Nitre prove unduous, it may be proper to add a little lixivium of Pot-Afh, Lime-Water, or Allum. And if by this Means it does not become fufti- ciently pure for making the beft Gun-powder, or Aqua Fortis^ it muft be diftblved again, and re- cryftallized, in the Manner of our prcfent Expe- riment ; which being repeated, with a larger Proportion of Water than before, evaporating flov/ly 284 Hlpory Nitre, Lecture the Thirteenth. flowly and fuffering the Salt to flioot in a mode- rately warm Place, without the free AdmifTion of the external Air, the Nitre will be obtained in its utmoft Purity and Perfedion. It is judged to be pure, when being thrown upon live Wood Coals, it fulminates brifkly, and will then make perfedt Gun-powder and Aq^ua Fortis, 51. The chemical Hiftory of Nitre is ft ill de- fective. This Hiftory fhould fhew, by what Means Nitre is procurable from all animal and moft vegetable Matters : For there are many Experiments and Obfervations which feem tq prove, that Nitre originally proceeds from pu- trified Vegetables ; that many uncorrupted ve- getable Subjects contain it in a large Proportion ; and that all animal Subjects contain a femivolatile Nitre *, which may be rendered more fixed, or like the common, by the Addition of Pot-Afh or Qj^iicklime a). 52. To thofc difpofed to enter upon this ufe- ful Enquiry, we recommed a full Knowledge of the Methods now in ufe for procuring Nitre from certain Earths that are dunged by Ani- mal?, and putrefied Vegetables ; the fliorteft: Ways of feparating the unCtuous Matter from the Nitre, which occafions all the Difficulty ; and a due Comparifon of the Procefs for pro- curing and refining of Nitre with that for pro- curing and refining of Sugar. There is Reafon to believe, an Enquiry of this Kind might be at- tended with fuch Succefs, as to fhew that Nitre is not peculiar to any one Country, but obtain- able in Plenty, wherever animal and vegetable SubjeCls abound Ip). o ) ScG Mr. Lemer/s Papers upon this Subjed in the French Memoirs. See alfo Dr. Stub'i Legends no liijloties, b ) See Glauber s Profferity of Germany, Expert- 285 Of oils and Salts. Experiment VII. ne Method of Making Pot^AJh, 53. Having burnt a Quantity of common Billet- Pot-A/I? Wood to grey Allies, we took feveral Pounds of thofe Allies and boiled them in Water, fo as to make a very ftrong TJxivium^ or Lie, This Lie we drained thro’ a coarfe Linen Cloth, to keep out any black Parts of the half-burnt Wood that might happen to remain in the Adies ; then we diredlly evaporated this drained Lie in an Iron- Pan over a quick Fire, alrnod to Drienefs. We took out the Matter remaining at the Bot- tom, and putting it into an Iron-Crucible, fet it in a drong Fire till the Matter melted ; and then immediately poured it out upon an Iron-Plate, where it foon cooled, and appeared in the Form of a folid Lump of Pot-Afli. 54. And much after this Manner is Pot-Afh made in the large VN^ay of Bufinefs, for the Ser- vice of the Soap-Boiler, Glafs-Maker, F'uller, But according to the Difference of the Wood or combudible Matter employed, with the Manner of burning it, and conducing the Procefs, different Kinds of Pot-Adi are pre- pared. 55. There are certain faline Plants that yield And ap- this Pot-Affi to great Advantage, as particu- plication, larly the Plant Kali ; there are others that afford it in lefs Plenty, and of an inferior Quality, as Bean-Stalks, i^c. But in general, all vege- table Subjedls afford it of one Kind or other, and may mod of them be made to yield it tole- rably perfedt, after the Manner of our prefent Experiment \ even the Loppings, Roots, and refufe 286 Difft- rence. Lecture the Thirteenth. refufe Parts of ordinary Trees, Vine prunings 56. But befides the Difference found in diffe- rent Vegetables for producing this Salt, as fome may naturally contain more or lefs of the faline, oily, or earthy Principle, than others * ; an- other Difference will arife from the Manner of burning the Subjeft, according as that is done with a greater or lefs Degree of Fire, or Admif- fion of the Air. If a vegetable Subjedl be burnt in a clofe, ftifling Manner, to a grey, or fome- what blackifli or brown Afh, thefe Afhes thus containing more of the Oil of the Subjed, will afford a more unduous Salt, that eafiiy melts in the Fire, and is better fitted for the ready mak- ing of Soap. > But if the Subjed be burnt in the open Air, fo that it have every Way free Accefs thereto, the Afhes will be white, or contain no Part of the Oil of the Subjed ; and thus the Salt will difficulty melt in the Fire, and prove fitter for the making of Glafs (where no Oil is required) than of Soap. 57. A third Difference in Pot- Afh arifes from the Length or Shortneis of Time it is detained in the melting Fire; whereby it becomes either of a grey, white, bluifh, or greeniffi Colour 5 grey or white if it be foon taken out ; and bluifh or greenifh if long detained therein. And ac- cording to thefe Differences Pot-Afn is more or lefs (harp or flrong ; a longer Continuance in the Fire always confuming the more unduous Parts, and leaving the faline ones more naked : provided no confiderable Proportion of Earth remain mixed with the Salt, which in that Cafe would foon be vitrified, or turn to Glafs, and have no faline Property at all. See Lc£l. VIII. fajjlm, 58. The Of oils and Salts. 287 58. The fixed Salts of all Vegetables, when Improve- reduced to abfolute Purity, or entirely feparated from the other Principles, appear to be one and the fame Thing *, at leaPc not manifeftly to differ Whence it fhould feem that, by a fuitable Ma- nagement, good faleable Pot-Afh might be made in all Places where vegetable Matters abound : For if, by examining Rujfia Pot afh, for Ex- ample, we find, that its fuperior Excellence de- pends upon its being clear of Earth, or upon its containing a large proportion of Oil, or fixed Salt •, thefe Advantages mayi by properly regu- lating the Operation, be given to Englifh Pot- Afhes, fo as perhaps to render the latter as good as the former. But where the Pot-Afh of any remarkably faline Vegetable is to be imitated, as that of Kali fuppofe, we would recommend a prudent Sprinkling of the Subjedt with Salt or Sea Water in the Burning. And by thefe Ways properly diverfified, any Principle that is natu- rally wanting in the Subjedl might be artificially introduced, fo as to perfed: the Art of Pot-Afh, on which the Art of Soap-making depends. 59. For to make Soap requires an intimate Union of the Salt of Pot-Afh with Oil, orany^r/, V. §.47. Of common Pharmacy. 333 Marteing deftitute of a fecure Foundation ; and cofequently is led by Rumour, Opinion, and Exmple, inftead of the true .Light arifing from carful Obfervation,and well digefted Experience. Wence it frequently happens that unlucky Eents are attributed to ufeful Medicines ; whilft fun Events were really owing to fome other Cafe. ). This Inattention is fucccedcd by Levity and Rdinefs : For when a Medicine thus fails to arwer the Expedation conceived of it, it is ufual tcrejed it with Contempt, and immediately to feizf 3^8 Lecture the Sixteenth. feize, in its Stead, the firft new one that comes ftrongiy and vehemently recommended; which again, after Trial, is frequently rejeded in the fame Manner as the former. And thus the Lives of Phyficians are often fpent in flying from one Medicine to another, without fixing upon thofe that are liable, or fuch whofe Virtues are duly determined and afcertained. 9. This perverfe Temper or ill Habit of the Mind muft therefore be cured ; or elfe Phyfi- cians will continue to fludluate, and never bring Pharmacy to a State of Perfecftion. 10. The Way of rectifying this ill Habit, we apprehend, is to acquire a Competency of found and fundamental medicinal Knowledge, by keep- ing fleady to the Ufe of a few Ample Medicines ; which are eafily prepared, no way hazardous, and yet powerful in their EfleCls : And to fliew the Way of procuring a few fuch Medicines, is the Defign of our prefent LeClure. 1 1 . We judge that all Medicines are commo- dioufly reducible to four general ClafiTes ; viz, Evacuants,, Alter mils,, Strength eners,^ and ^ieters : For as all the Caufes of Difeafes muft regard either S^uantity,, ^ality,, or Motion,^ the Medi- cines adapted to thefe Caufes will be either Eva- cuants^ Alterants,, Augmenters,, or Appeafers of Motion in the Body. 12. It muft, however, be obferved, that un- der each of thefe general Tribes of Medicines there are fome better adapted than others to the Difeafes of particular Parts. Thus it is Matter of Obfervation, that Mercury particularly affeCls the falival Glands, Cantharides the Bladder, Cfr. all which Remedies are to be colleCled, as fo many particular Inftances, under our refpec- tive general Heads of Medicines. And by duly proceeding in this Manner, it fliould feem that we Of fmple Pharmacy. 349 we might eafily fix upon a fmall Colle6lion of Remedies, able, with a proper Regimen, to cure the ordinary Difeafes. 13. At leaft, by throwing out of our prefent Colledlion fuch as are certainly found to be of fmall Efficacy, or certainly dangerous, we might greatly retrench the prefent Set of Officinals^ and bring the more ferviceable of them within the Compafs of a 'portable Cheft, And with this View we (hall endeavour to point out fome of the more efficacious, parable, fafe, and agreeable Evacuants, Alterants, Strengtheners, and Qui- eters ; all along fixing a Mark upon thofe which we take to be either unfafe or infignificant. 14. Our firft Experiment will fhew a Method of procuring a fafe Emetic-, the fccond will fhew how to prepare a fafe Purgative ; the third how to prepare a fafe Perfpirative ; the fourth how to prepare a fafe Alterant; the fifth how to prepare an innocent Strengthener ; and the fixth how to obtain a powerful Quieter, or Anodyne- Ex periment I. An eafy and Jimple Method of obtaining a fafe and gentle Emetic, 15. Two Drams of the common white Ipeca-^^ cuanha being reduced to fine Powder, and prepared, fed for two or three Days in half a Pint of white Lisbon Wine, in the Cold ; if the clear Liquor be decanted, frefh Wine may be added to the remaining Powder, fo as to extradt all the Vir- tue, which it will thus yield to Wine in the Cold. 16. This Infufion of Ipecacuanha in Wine z'p-Ufes, pears to be the mofi: fafe, gentle, and agreeable Emetic hitherto known : Whence it may in moft Cafes be properly fubftituted for the Vinum bene- di^um 350 Lecturethe Sixteenth. di5lum^ the Tart arum emeticum^ and the other an- timonial Emetics ; which arc all attended with fome Degree of Virulency and Uncertainty in their Operation. Ipecacuan. I?- The Ipecacuanha Root, upon a proper haanal^fed by Means of Water and Spirit of Wine, is found to contain a dired faline and refinous Part, whereof the faline is the larger ; whence even an aqueous Infufion of the Root will largely extradl its Virtues : So that a ftrong White Wine feems a Menfiruum well adapted to the Extradlion both of its faline and refinous Parts, on account of the large Proportion of Water, and a lefs of inflammable Spirit, that it contains. Add to this, that Emetics, as well as Purgatives, are found to a6l the freer, eafler, and quicker, when joined with Wine, or other ftrengthening fpirituous Vehicle. However, af- ter both Water and Spirit of Wine have fuccef- fively a(5ted upon this Powder, it ftill retains fome Virtue *, fo that its Power is greateft when given in Subftance : Whence our prefent Me- thod of extradling a Tindure from it with Wine only abates its Violence, and, in fome Mea- fgre, moderates its Operation-, fo as to fit it for weak Conftitutions, or render it almoft univer- fally fafe. Notimpro- 1 8 . This Root may, therefore, pafs for one *vedby Qf thofe Simples which are little or nothing im- emijiry, ^ chemical Treatment *, Nature fupply- ing it almoft ready prepared to our Hands, fo as to require no more than drying and Redudion to Powder, at moft no more than a bare Infu- fion in Wine, to render it a fafe Emetic. Farther ^9* Now, being once pofleflTed of fuch an Ufes, Emetic as this, which feems to include the Ex- cellencies of all thofe of the lame Tribe, it is doubtlefs proper to pradife the Method of Rejec- tion Of fmple Pharmacy. 351 tim upon the reft ; or at lead to examine whe- ther any of them deferve to be retained and kept in the Shops. 20. We obferved above that the common Poifimvs antimonial Emetics, of which there is a great Variety, are virulent, or in fome Degree poilbn- ous; and therefore not to be trufted, when fafer can be procured to anfwer the End. ’Tis true, fome Pradfitioners have ventured to give Arfenic itfelf, in the Quantity of a few Grains, as an Emetic •, and thus it fometimes operates violent- ly, after the Manner of the emetic Preparations of Antimony, which are nearly allied thereto. But as we certainly know, by many fatal Inftan- ces, that Arfenic is a virulent Poifon, even in a fmall Dofe *, it may feem a Kind of Madnefs to ufc it as an Emetic, when Ipecacuanha is at Hand. And the lame is to be underftood, tho* in a lefs Degree, of the Mercurius Glafs of Antimony, Antimonial Cups, the Perpetual Pills, the Sulphurs of Antimony, and indeed all other draft ic Emetics ; which have a diretft virulent Virtue, and, if given in too large a Dofe, pro- duce poifonous Effedls. And here we do not except emetic Tartar itfelf ; which, unlefs pru- dently diluted with Wine or fome Cordial Wa- ter, is apt to prove not only uncertain and chur- lifh in its Operation, but fometimes virulent or poifonous \ efpecially when exhibited in a dry Form, as in that of Pills, Powder, or Bolus : For all antimonial or other metalline Emetics, coming in a dry Form into the Stomach, feem to lodge in its membranous Coats, and ftimulacc and corrode them ; fo as to occafion Spafms, Convulfions, after the Manner of Poifons. » §. 16. 21. And 352 Lecture the Sixteenth. Reguia- 21. And tho’ Solutions of Vitriol, Verdi- tion. greafe, and various Preparations of Copper, have been, and ftill continue to be, uf^ as Emetics, and generally operate quick ; yet we can- not judge fuch Preparations fafe, or any way comparable to Ipecacuanha for Safety. And even thefe cupreous Emetics, when given in a large Dofe, have a corrofive Effect upon the membranous Parts of the Stomach \ fo as to prove, in a lefs Degree, poifonous. And thus, if the whole Tribe of Emetics were carefully ex- amined, and their Effects noted from compe- tent Experience, we judge they would moft of them be found unfafe or dangerous ; and con- fequcntly deftrve to be banifhed the Shops, as Emetics, whilft their Place may be fo well fup- plied by Ipecacuanha. And this Method of Exa- mination and Reje6lion being duly pradlifed, might, as we apprehend, thin our Shops, and reduce the Bulk of our Pharmacopoeias, to the great Advantage of Pharmacy and Medicine. Expe r iment II. An eafy Method of procuring a fafe and effectual Purgative, ACathar- 22. If in a Quart of Dulwich-Y^s^tzc we dif- ticprepa^ folve an Ounce of fine Manna, and half an Ounce of black Tamarinds, then drain off the Liquor clear, we fhall obtain an agreeable pur- ging Pci fan, or cathartic Liquor, in a Dofe luf- ficient for a full-grown Perfon of an ordinary Conftitution •, the Whole being drank at feveral Draughts, in the Space of about an Hour and half, or two Hours. 23. It appears to be Matter of Obfervation, that the common purging mineral Waters operate with Of fmple Pharmacy. 353 with more Eafe, Gentlenefs, and Safety, than mi d almoft any Cathartics of the Shops; and Q^\y Cathartic require to be concentrated by boiling, or quick- ened, in fome Cafes, to prevent the Trouble of taking two or three Quarts for a Dole. Our pre- fent Experiment, therefore, fliews the Method of quickening thefc Waters, by the Addition of innocent Purgatives ; fuch as are Manna ^ ’Tama- rinds., Ej)fom-Salt.^ Tar tar urn tartarizatum.. Tar- tarum vitriolatum^ &c. 24. The Shops and common DirpenfatoriesT'^^^/o/^;?/ abound with purgative Medicines, many of to be re- them draftic, or violent, and fome of them rulent, or almolf poifbnous ; of which Kinds we reckon Rofin of Jalap ..Elateriitm., Scammony., Gam- boge., Coloquintida., Afarum.,^^c. ail which are of a caullic Nature, when given crude and alone, fo as to prove mortal in a large Dole : Y/hence we apprehend that the crude and feparate Ufe of all fuch Purgatives (hould be baniflied ; efpe ciaily as there are numerous Inftances of their deleterious and poifonous Etre(ft% and as we are abundantly provided of fafer and more gentle Kinds ; for Example, Rhubarb^ Manna., Tama- rinds., Cajfia^ Cremor Tartari., Epfom-Salt ; and particularly the purging mineral IVaters. Or \ f Qy. render- the Ufe of the more violent purging Simples h^ed milder, (till retained, let them at lead: be boiled in Wa- ter ; which is a certain way of rendering them milder, and difeharging a great Part of thar Malignity. And for the purgative Rofins, par- ticularly thofe of Jalap and Scammony, we would recommend them to be ground fine, and beat into a Pafte, with twice or thrice their Quantity of blanched Almonds ; which, by their oily Matter, dilTolve the Texture of thefc Ro- fins, and render them more fafe and innocent * See belcw Exp. III. 354 Lecture the Sixteenth. 25. But we do not apprehend that the Art of Medicine has any Occafion for thofe violent Pur- gatives. Certainly violent Purgatives are feldom proper, and generally prejudicial. If the Wronger be ever required, we would, in (lead of the for- mer virulent Kind, recommend the fimple Pow- der of Jalap- Root *, vdiich is found to operate much more mildly, and with greater Certainty and EfFed, than its Rofin, Tindlure, or other chemical Preparations of the Root ; which is alfo the Cafe ot Mechoacan and Rhubarb. 26. We defire it may be remembered, that the deleterious or poifonous Nature of the vio- lent Purgatives above mentioned is much greater in the Body than that of the poifonous Emetics ; doubtlefs becaufe fome Part of thefe Emetics is foon thrown up again by the Stomach •, whereas the Purgatives defeend to the Inteftines, and - mix with the Juices ol the Body : Whence we have a fironger Reafon for rejeding the Ufe of thefe virulent Purgatives, than the Ufe of the virulent Emetics. 27. And thus we conceive the Matter of Pur- iion. gaiives may be reduced to a tolerable Degree of Simplicity *, yet fo as to leave Variety enough for fuiting the diiierent Difeafes and Conftitutions where Purging is required. The Nature of our Defign will only permit us to indicate, as we go along, the Pleads of this general Enquiry into the Means of reducing Pharmacy to an elegant and uieful Simplicity-, the Jntrodudion whereof is not to be expeded from private Hands. Ex P E R I- Of fimple Pharmacy, 355 Experiment III; -A facile and fimple Method of preparing a fafe and effe^ual Sudorific, 28. If an Ounce of refined Cam phi re be beat,^ and ground, in a Marble Mortar, with iv^ofic prepa- Ounces of blanched Almonds *, the Camphire'"^^’ will be thus fubtilly divided^ and brought into an uniform Mafs, fit for the forming of Pills, Bolufes, Cfc. fo as to be commodioufly taken in the Way of a Sudorific, Dil’cutitnr, or Per- fpirative Remedy *, the Dofe whereof may be affigned betwixt the Limits of three Grains and forty. 29. Sudorific, Perfpirative, and Alexiphar-L^^j^ mic Medicines, make a large Part of the com- mon Difpenfatories : We judge that their Places may be advantageoufly fupplied by a lew power- ful ones of approved Virtues \ ati'iong which we edecm this of Camphire as a principal one, or at leaft fuperior to Gafcoign^ Powder, Lapis Con- tray erv^e,, Bezoar,^ whole Virtues at bed ap- pear to be fmall. 30. We are fenfible that the Qualities ofCam- phire are not univcrfally agreed on by Phyficians ; Ibme efteeming it hot, and others cold *, fome of great, and others of little Efficacy. However, the Cafe is not to be decided by Authorities, but Expe- rience 5 which feems to declare that Camphire is one of the moll powerfu’, mod immediate, and mod innocent Perfpiratives, SudoriBcs, and Alexipharmics hitherto known : For a large Dole of it, luppofe a Scruple or more, being didolved in Spirit of Wine, and given to a healthy Perfon, does not increafe the Puife, or excite a prseter- natural Heat ^ but rather caufes a remarkable A a 2 Ccolnefs 35 ^ Farther Ufa. Lecture the Sixteenth. Coolnefs and Compofure, with a gentle Sweating, or Increafe o[ Perlpiration. So little have the Virtues of this Medicine been underdood ; or fo little can the Virtues of Medicines be dedu*' ced from their apparent Properties, or from rea- foning a friori ! 31. The natural and medicinal H ftory of this Drug well defcrves to be traced : Ic appears to be an dfential Oil, of peculiar Properties ; tho’ fome would have it a Rofin, and others a Gum. Certainly it Hands alone, as a Thing [ui generis \ or a Body wherein the Nature of Rohns, Gums, and eiTential Oils, all meet in fome Degree. It is perhaps one of the mod difcutient and fubtile Remedies hitherto difcovered : Whence it proves highly anodyne, perfpirative, and prefervatory. And we judge, from certain Obfervations and Experiments, that if the full Virtues of this Con- crete, both internal and external, were I'uffi- ciently known, ic might fupply the Place of nu- merous other Drugs and Preparations, to the Eafc and Advantage of Pharmacy. 32. In particular, we would recommend this Medicine to be ukd inftead of the common fu- dorific Decodlions of the Woods, in Cafes both of the recent and inveterate Lues Venerea : Ic may aifo be advantageoufly mixed along with the Ballams, or fine Turpentines, commonly ufed at the dole of that Didemper. In fhort, we recommend it in all infiammatory, putrid, pedilential, and even maniacal, Difeafes. And whoever has the Secret of prudently joining this fimple Medicine along with Nitre, may, as we apprehend, perform Cures fcarce to be expeded from other Medicines frequently ufed for the fame Purpofes. Ex P E R I- Of fmple Pharmacy. 357 Experiment IV. An eafy and Jimple Method of procuring a fafe and powerful Alterant. 33. If an Ounce of well purified Nitre, and two Scruples of Cochineal in Powder, ht am from boiled in five or fix Ounces of Water *, and Solution be filtred, and afterwards evaporated to Drinefs, keeping the Matter fiirring as it thickens-, a fine red or pu^'plc Powder will be left behind *, that is, the Nitre will be thus dif- guifed, aud reduced to a P'orm fit for taking in the Way of Bolus, Powder, or Solution, with any convenient Vehicle. 34. Nitre thus prepared, in order to conceal fo common a Thing, we judge to be an extremely fafe and ufeful Alteranr, capable of produ- cing confiderable Efiedis in the Body, without caufing any difturbance, or fenfible Evacuation, unlefs in the Way of a Diuretre in which Refped: it operates as an Evacuant. 35. It is remarkable of Nitre, that it may with Safety be injeded into the Blood. Mal- pighi injedled fix Ounces of its Solution into the Jugular Vein of a Dog, without obferving any other Effedl than its proving diuretic. It is far- ther obfervable of- it that it heightens the florid Colour of extravafated Blood, and excellently prelerves it from Putrefadfcion yet does not li- quify frefh and warm Blood, as has b^en ima- gined, but fomewhat thickens it, almofl in the Manner of a Mucilage : Which may give us the phyiical Reafon of many of its EfFecfls in rhe Body; as particularly its allaying Inflammations and P'evers, its (lopping FIiEmorrhag?s, curing the Spitting of Blood, ^c, A a 3 36. If 35 ^ Lecture the Sixteenth. 36 If the m'^dicinal Virtues of this fimple Medicine were to be enumerated, as they fland coniirmed by competent Exp:^irience, perhaps they would prove more numerous than thofe of almoH: any Medicine hitherto known. It has been found ferviceable in the Stone, and Stop- pages of Urine in Deliriums, in malignant Fevers, in Diarrhoeas attending the confluent Small Pox, fo as to prove a Kind of general Remedy. And as all thcfe Excellencies of the Medicine are joined with that defirable Property oi being innocent, or Icarce any Way prejudicial to the Body *, it may feem flrange that it fliould be fo little ufed, or that Medicines no Way com- parable to itfliould be preferred before it. Whence 37- Poffibly the mixing of Nitre with other aifejteemeeiMcdiCAncs may have occafioned its Virtues to be lels known, or obferved ; perhaps that Humour oi changing Medicines, almofl: every Day, may not have given it the Opportunity oi fliewing it- felf j bat chiefly that flrange Method of jum* bling many Simples together in one Medicine, feenis to hive prevented the due noting of the EfFeds of this and other Ample Remedies. We, therefore,' wifii that the Mtiiidnal Hifiory of Nitre were drav/n up, with Care and Judgment ; as be'og peifuaded, that both Pharmacy and Me- dicine might, by means thereof, be brought much nearer to Simplicity and Perfedion than they are at prufent. Experiment V. An artificial Method of preparing a powerful and innocent Strengthener. 38. We put half a Pound of the beft Peruvian Bark, reduced to fine Powder, into a proper Giafs, and poured upon it two Quarts of Spirit of Of fmple Pharmacy. ' 359 of Wine ; then Hiaking them vveil together, {tt^ne£en- them to digefl in a Saiid-heat for two or rh»ee^'^'^ Days, tili the Spirit of Wine appeared of ^ deep red Colour, inclining to t'urple. We now ftrained the Tinflure through a clofe Linen, and committed the F^ces at laff to the Prefs* Then returning the Prefilngs, or re- maining Powder, into the fame Glafs, we pour- ed thereto tv;o Quarts of drong White Wine, and again fet the Matter to digeft for two or three Days ; then drained as before. After this we put the two Liquors into a Glafs-Body, and didilled oft a large Part of the Spirit of Wine ; then evaporated the Remainder in a glazed Vef- fel, taking Care to keep the Matter dirring, and wadiing down, with fome of the Spirit of Wine, the (efinous Parts that adhered to the Sides of the Vedel. When the Matter began to grow thick, we added to it three ‘Ounces of the Syrup of Orange-Peel ; and thus brought the Whole to the Confidence of an Extradt, 39. This Method of excra6ling the Virtues OijtsH.fiory the Bark is the Invention of M. Charas *, who ex- perienced its Succefs in a large Pradlice for fifteen Years, wherein he never found it fail him, for the Cure of all Sorts of Intermittents. We have ourfelves alfo had a competent Experience of its Succefs ; and found it anfwer better than any other Preparation of the Bark we have feen : Whence we judge it the bed Manner hitherto known of preparing an Extracl: from the Bark, fo as to render it more innocent and effedtuaL 40. The Procefs was formed upon this Suppo- Rationale: fition, That the Bark contained a Rodn and a Salt for its principal component Parts •, to the Extradlion whereof the two Mendruums are well adapted. And, in Efredt, we find that Spirit of W'ine does extradt a Kind of Rodn from the A a 4 Bark ; 360 J^egimen. El'Sol'ac- c ha rums recommcn did. Lecture the Sixteenth. *, and Wine fuch a Part as renders it able to cure iome Kinds of Intermittcncs in certain Conkirutions : Whence thefe two Menlfruums, doLibilefs, take up the more medicinal l^arts of this Subfiance, leaving its more woody or fibrous Part behind •, which }:rjbably occafions that Stoppage and troubiefome Weight at the Stomach we otcen hear complained of after taking large Quantities of the Bark in Subifance. 41. The two finer and more medicinal Parts of the Bark being thus extradled, they are com- rnodioufly joined together again by the Interpo- fition of the Sugar contamed in the Syrup ; fo as to form an elegant Whole, that may be aro- matized at Pleafure with the eficntial Oil of Mint, Cinnamon, or Cloves. 42. The Dofe, and xMtthod of exhibiting this Preparation of the Bark, are the fame as the common ^ and though a much larger Dofe fliould be given, it has not been found to produce any ill Effedl Ti'he U^e of this Medicine is alfo at- tended with a quicker Recovery of the natural Complexion, Vjgour, and Phelhnefs, than the Ufe of the crude Bade. And as the Medicine appears to be thus rendered fo powerful and innocent, perhaps it may be proper to try it alfo in fomc other weakening Dilden'ipers, befides Intermitting Fevers. 43. There are many other powerful and in- nocent Screngtheners, befides this Prep^aration "of the Bark •, among the principal whereof come the capital Aromatics, Cmnamon, Cloves, Nut- meg ; or rather their efiTcntial Ods *, which being made into Elieofac char urns,, afford as poteiU Cor- dial Medicines, in a commodious Form, as can well be expected. But if more compounded Medicines are required, v/e would recommend the Ule of a cGm^Q'tnd EU'faccharum^ confining of 361 Of fmple Pharmacy. of a few le(e6t aromatic Oils, and the richeft Gums and Balfams, as one general Cordial, or compound Screngthener. And thus a Medicine might be cafily contrived, that fhould colledt in itfelf, or concentrate, the Cordial Virtues difperfed in feveral capital Ingredients. Thus for Example, Camphire, Balfam Balm of Gilead., the eflential Oils of Cinnamon, Lignum Aloes., Myrrh, iAc. are all homogeneous, and capable of being united either alone, or with Spirit of Wine, or Sugar ; fo as to be given with alldefirablc Advantage and Convenience. Experiment VI. A ready Method of procuring a fafe §uieter^ or Anodyne. 44. We took half an Ounce of Opium, z.x\diOptum^re- didblved it- with a gentle Heat in five or fix times/^''^^*. its own Quantity of fair Water *, then {training the Solution, and exhaling away the fuperfluous Moifiure, in a temperate Sand-heat, we reduced the Matter 10 a dry Subftance *, which being ground in a Glafs-Mortar, with twice its own Weight of hard Loaf-Sugar, Teems to afford us one of the belt or mildeft Preparations of Opium ; and may be given from one Grain to three or four for a Dole. 45. By diffolving the Opium in Water, we^^j. get rid of its more grofs and refinous Parts, which are found much more pernicious than the reft ; and by dividing its Parts afterwards, with Sugar, we render the Medicine more uni- form, rdbluble, and mifcible with the animal Fluids ; and can thus the better adjuft its Dofe. But (till this Medicine is not without Tome pernicious Property •, nor is there any way known 362 Lecture the Sixteenth. known to render the Ufe of Opium perfe 61 :ly iafe and innocent in all Conftitutions : For if a large Dofe of it be given, it is apt to dilfurb cr cloud the Head, caufe a Vertigo, Delirium, or Convulfions •, in particular, it proves preju- dicial to the Stomach and intellines, which it is apt to inflame and fphacdate ; thus ading, in fome D gree, as a Poifon : Whence a better Method of correding it fbould be endeavoured after, or a more innocent Remedy be ufed in its Stead. A Mixture of Nitre and Camphire, we apprehend, may fupply its Place on many Occafions, without any P'ear of Danger or Incon- venience. Regula- ^5, Thus we have endeavoured to give an *pi of a Ample and Iafe Preparation in each ^ '^'ot the four general Tribes under which we con- ceive all Medicines may be commodiouOy ran- ged •, viz. Evacuants, Alterants, Strengtheners, and Quieters. If the Method we have here ob- ferved were purfued to its due Length, it might, doubtlefs, terminate in the certain Difcovery of a few Ample, elegant, innocent, and powerful Remedies ; at ieall it would enable us to throw our, as dangerous, noxious, or poifonous, a large Part of our prefent Materia medica., and pharmaceutical Preparations ; and a confiderable Part thereof, as almofl: ufelefs, or inAgniAcant : Whence fome tolerable Degree of Per fed ion in Pharmacy might be obtained. 47. Thus all the Medicines that have Lead in their Compofition are fcarce to be trufted for internal Ufe. We have various Inftances of the poifonous Nature of this Metal ; as particularly among the Workmen at the White-Lead Houfes, the Colourmen, or Grinders of Cerufe, and thofe who any way work in Lead. And it were fufiicient to banifli the frequent internal Ufe of Saccha- Of fimple Pharmacy. Saccharum Saturni, the Tin5iura anttphthefica., &c. to read, in the Mifcelianea curiofa how many Men were poifoned by drinking acid Wine rendered Tweet v/ith Litharge. 48 . But Metals do not acl in the Body till they are once diffulved : Whence crude Mer- cury, fwallo'A^ed in large Quantities, proves harmlefs, through the Want of a Menftruum in the Stomach, to diffblve it. But when crude Mercury is diflblved by its proper Menftruum, as in the Preparation of Mercury- Sublimate, we fee it becomes one of the ftrongeft Poi- fons. Lead, Iron, and Copper, being much more eafily diftblved than Quickfilver, are fel- dom taken without fome remarkable EfFedt ; which mu ft neceiTarily prove the greater, the more of an acid, or, in the Cafe of Copper, even alkaline Humour, is lodged in the Stomach or Inteftines : Whence we derive a phyfical Rea- fon why thefe Metals often produce different Effc61;s in different Conftitutions. The internal Ufe of the Crjftah of though fometimes fuccefsfully given in dropfical Cafes, ffiould hardly be trufted, on account of their corrofive Acrimony •, which has fometimes occafioned bloody Stools, and ext'feme Weaknefs. The common Tindlures of Copper, and Solutions of blue Vitriol, can fcarce be taken internally with' Safety *, as being not only emetic, but in fome Degree corrofive and poifonous. Even the Au~ rum fiilminans^ though highly efteemed by fome as an internal Medicine, cannot be fafely given, unlefs it has been firft well wafhed from its Salts, and does not meet with a fuitable acid Solvent in the Stomach : For in both thefe Cafes it may have dire Effeds j of which there have * Decad, III. Obf. 30. been Lecture the Sixteenth. been remarLtble Inftances. Iron and Tin have rot been found fo pernicious to the Body, but ratii.r bcntn.ial ; erpecially Iron, when pru- dently prepared and ufed. Indeed, of all the Metals iron ferms to be the mod innocent, and iLfncicncly powerful, rho’ diflblved in fo weak a Mend uum as Wine. And as this is the Refulc of o .r Method of Rejcdion applied to Metals and metalline Preparations, fo we apprehend that if the fame Method were applied to the whole Materia medica^ there would thence refulc the difeovery of fafe and powerful Medicines for the Cure of all ordinary Difeafes : Whence we would recommend this Kind of Procedure to thofe who regard the Improvement of Pharmacy and Phyfic. t AXIOMS and CANONS. 1. We learn from the preceding Enquiry, That certain Simples are naturally better pre- pared for medicinal Ufe, than by the common chemical Treatment *, fuch in particular are Ipe- cacuanha, Jalap, Rhubarb, Mechoacan, Tables, or Catalogues, of which Kind of Simples ought to be formed, in order to abridge and perfedV Pharmacy a), 2. That moll of the Emetics in common Ufc, efpecially the antimonial Kind, are virulent and fomewhat poifonous, compared to that milder one of Ipecacuanha h.) 3. That many of the common violent Purga- tives are of an adually poifonous Nature, and therefore fhould be artificially correded, or elfe make room for more innocent Kinds to be ufed in their Stead ; particularly the purging mineral Waters^ Manna, Rhubarb, Cfr. Of fmple Pharmacy. 4. That the more violent and poifonous Pur- gatives, -fuch as E!aterium, Coloquintida, Scam- mony, Hellebore, may have their poiibnous Quality mitigated, or taken away, by boiling in Water and other Expedients a). 5. That the Effects of the poifonous Purgatives are conGderably greater in the Body than the Effedfs of the poifonous Emetics^). 6. That the two principal Tribes of Evacu- ants, viz. Purgatives and Emetics, are reducible to a few fimple and eafy Preparations c). 7. That Camphire has confiderable Virtues, as a Perfpirative, Sudorific, and Refolver ; be- ing capable of uniting with oily' Subftance^ and bearing a Relation to effential Oils, Rofins, Gums, and Balfams d), 8. That purified Nitre has many medicinal Virtues *, fo as advantageoufly to fupply the Place of numerous other Medicines e). 9. That this purified Nitre has a great Power of preferving the Blood uncorrupted, frefh, and florid /). 10. That many of the medicinal Virtues of Nitre do not depend upon its liquifying, but rather upon its jellying the Bloody). 11. That the Pcrfedtion of Phyfic and Phar- macy may have a confiderable Dependence upon the medicinal Hiftory of Nitre h), 12. That the Peruvian Bark may be rendered more innocent and effcdual than when given in Subftance, for the Cure of Intermittents, Cfc. by Means of a proper Treatment, or by extrad- ing and uniting its faline and refinous Parts with a fuitable intermediate Subftance /). 13. That this Bark appears to contain three very different Parts in a loofe Texture ; viz. a rofin, a fait, and a woody Subftance k), «) Exp. II. b') ib. f) Exp. I. III. d) Exp. in. ij Exp. IV. f) ib. g) ib. h)\\). i) Exp.V. h) ib. 14, That 366 Le CT UR E T H E SiXT E E NT H. 14. That pofTibly the refinoiis and faline Ex- trads of the Bark may be ferviceable in curing more Difcafes bclicies Intermitting Fevers ; and that probably the frequent Failure of the com- mon Infufions and Extrads of this Drug are owing to their containing much of its refinous Part without the laline one, or the faline Part without much of the rdinous •, and not a due Mixture and full Proportion of the two, as they are naturally found in the Bark itfelf : Whence the Subftance has generally proved more elFedual than any of thofe imperfed Extrads, Tinctures, or Infufions d), 15. That powerful Strengtheners, or Cordi- ~ als, are obtainable from a Mixture of the richeft Balfams, and effential vegetable Oils h'). 16. That Opium may be fo prepared as to become more innocent than in the common Me- thods of treating it c), 17. That a lefs noxious Quieter is wanted than Opium, and may, in fome Meafurc, be fupphed by Nitre and Camphirei). 18. That no Preparation of I,ead can be long or freely ufed internally, without confiderabie Hazard 19. That the common Solutions and Prepara- tions of Copper, Silver, Gold, and Mercury, are hardly proper for internal Uie; nor even Tin and Iron, unlcfs prudently prepared with gentle Menftruums, and cautioully given/). 20. That there are rational Grounds to exped fome confiderabie Improvements in the prelent State of Pharmacy and Medicine, by a due En- quiry, and a proper Ufe of the Means conducive to this End^). a) Exp, V. b) ib. c) Exp. VI. d) ib. . e) ib. /) ^l^s whole Le^iure, pajjim. LECTURE ( 3^7 ) LECTURE XVII. CONTAINING Mineralog Y ; or the Art of Mining: With the previous Operations to Metal- lurgy; viz. Roafting, Stampings Wafh-- ingy and the Bufinejs of Fluxes, I. E are now entering upon a large, and V V extremely ufeful Branch of Chemiftry \jeSi, the Bufinefs of Mineralogy and Metallurgy, 2. By Mineralogy we underfland that previous Part of Metallurgy, v/hich teaches the Ways o{logyi<^hat, finding, judging, and digging Mines ; with the Ufes of Salts and Earths for making Fluxes, in order to the afiaying and fmdting of Ores for their Metals. 3. By Metallurgy we underfland the Perform- ance of thofe feveral Operations required to fe-i'i’» parate Metals from their Ores, for the Ufes of Life. And according to this Diflindion we fhall beflow one Ledlure upon Mineralogy^ and another upon Metallurgy^ in the Senfe we have here ex- plained them. 4. Mineralogy is an Art that requires a confi- j^etimfites derable Compafs of Knowledge, before it can h^toMinera- pra6tiled to Advantage: For as this Art includes the Difcovery, Sinking, and Working of Mines ; it requires a competent Skill in the Nature, Efflu- via, and Effeds of mineral Matters, whether Earths, Salts, Sulphurs, Stones, Ores, Bitu- mens, 368 Lecture THE Seventeenth. mens, Gems, or Metals. It like wife requires a Knowledge of the internal Scrudure of the Earth, and its various Strata \ with a competent Skill in fubterraneOLis Architedure, Menfuration, Ely- draulics, Levelling, and Mechanics •, without which we can never judge what Mountain, Plain, or Valley, is proper to be dug; in what Manner to dig it ; how to difcharge the Water that may flow in upon the Works ; how the Beds of Ore and Stone will dip, or run; how the various Kinds of Earths, Marble, and ocher mineral or metallic Matters, are to be cut through, or broken ; or how the general Procefs of Mining fhould be conduded, in order to procure, with the leaft Expence, or bring to open Day, the principal Matter or Ore re- quired. ^alijica^ 5 . And even when all thefe Difficulties a^e tions of a conquered, no more than half the Work is cffed- MetaUiJi. ed ; and ftill the End can never be obtained without a tolerably exad Knowledge of fcveral chemical Operations ; viz. Trituration, Torre- fadion, Lotion, Calcination, Cementation, Fu- fion. Amalgamation, Vitrification, Sublimation, Diftillation, and the like : Whence it might be laid down as a Rule, That every direding Me- talfift fhould not only be tolerably verfed in the feveral Parts of Natural Philofophy, but parti- cularly be well acquainted with Chemijiry, 6: And perhaps it may not be improper to intimate, that many metallurg'cal Attempts have mifcarried, merely for Want of a competent Skill to condud therrj. The under Workmen in this Way are generally a head-ftrong, ignorant Peo- ple,- that cannot be managed without the Uie of Ibme good political Rules, and a Knowledge much fuperior to their own. Yet how little foever the Art of Mineralogy may have been under- 3^9 underftood, Hiflory afiords us numerous Exam- TheSutce/s pies of plentiful Poi tunes and irnrnenfe Ticafures raifed from mines, as well by private Perions, as by particular States and Knigdoms. But the Vulgar, and even Pbilofophers unverfed in Trade, generally reckon the Bufinds of Mining unprofperous, and at bell precarious and un- certain j eipecially when compared with Agri- culture, or other Arts exercifed more in the open Day. 7. The Truth is. Mines are liable to many Contingencies ; being fometimes poor, fome- times foqn exhauftible, fometimes fubjed: to be drowned, efpecially when deep, and fome- times hard to trace. Yet there are many In- ftances of Mines proving highly advantageous for hundreds of Years. The Mines of Potqfi are, to this Day, worked with nearly the fame Succefs as at fird; ; the Gold Mines of Crem- nitz have been worked almoft thefe thoufand Years ; and our Cornijh Tin-Mines are extreme- ly ancient. In general, the Profit of Mines, compared with that of Agriculture, is immenfe- ly greater in the fame Time, fo as to compen- fate largely for its Uncertainty. Even Lead- Mines generally yield twice or thrice the Re- turns of the richeft Soils, cultivated in the ordi- nary Manner, either by Nature or Art. What then fliall we fay of the Mines that are rich in the nobler Metals ? The neat Profit of the Sil- ver alone, dug in the Mifnian Silver-Mines of Saxony^ in the Space of eighty Years, is computed at an amazing Sum 8. Many Mines have been difeovered by Ac- Accidental cident. A Torrent firfi: laid open a rich Vein Oi the Silver- Mine at Friberg in Germany. Some- * See Peit\ Albin. in Chronic. Mifn. Miner. German. E b times 370 Lecture'the Seventeenth. times a violent Wind, by blowing up Trees, or overturning Rocks, has difcovered a Mine. The fame has happened by violent Showers, Earth- quakes, T hunder, the firing of Woods, or even the Stroke of a Plough-Share, or a Horfe’s Hoof. fhe Art of 9. The Art of Mining does not wait for thefe hiining, favourable Accidents *, but diredtly goes upon the Search and Difeovery of fuch mineral Veins, Ores, or Sands, as may be worth the working for Metal. Ho^tohe 10. The artificial inveftigation and Difeovery fraaifed. of Mines depends upon a particular Sagacity, or an acquired Habit of judging, from particular Signs, that metallic Matters are contained in cer- tain Parts of the Earth, not far below its Surface. Signs of a II. The. principal Signs of a latent metallic Mine. Vein feem reducible to general Heads *, fuch as (1) the appearance of certain mineral Waters ; (2) the Difcolourarion of the Trees or Grafs ; (3) Pieces of Ore on the Surface of the Ground •, (4) the Rife of warm Exhalations •, (5) metallic Sands, and the like : All which are fo many Encouragem.ents for making a ftriefer Search near the Places where any Thing of this Kind appears. Whence Rules of Practice might be formed for reducing this Art to a greater Cer- tainty. TV Art of 12 But v^^hen no evident Signs of a Mine ap- Boring. pear, the fleilful Mineralifl ufuaily bores the Earth in fuch Places as, from fome Analogy of Knowledge, gained by Experience (or by ob- ferving the Situation, Courfe, or Nature of other Mines) he judges may contain Metal. 13, This Method of Boring confifls in the Ufe of^ Set of Scooping Irons, made with Joints, fo as to be lengthened at Pleafure, and thruft down to a considerable Depth below the Surface of the Earth, of Mineralogy. 371 Earth; fo as when drawn out again to bring back Samples of the Earth, or mineral Matter, from the Depth to which the Iron defcended; much after the Manner that Samples of Sugar are taken out of the Hogfhead by the Inftrument called a Refi. 14. After a Mine is found, the next Thing to When be confidered is, whether it may be dug to vantage. In order to determine this, we duly to weigh the Nature of the Place, and its^^^^. Situation, as to Wood, Water, Carriage, Heal- thinefs, and the like ; and compare the Refult with the Richnefs of the Ore, the Charge of Dig- ging, Stamping, Wafliing, and Smelting. This is a Matter of common, civil, or ceconomical Prudence. . 1 5. Particularly the Form and Situation of the Spot Ihould be well confidered. A Mine muft happen either (i) in a Mountain, (2) in a Hill, (3) in a Valley, or (^) in a Flat. But Mountains and Hills are dug with much the greateft Eafe and Convenience *, chiefly becaufe the Drains and Burrows., as the Miners call them, that is, the Adits., or Avenues., may be therein readily cut, fo as both to drain off the Water, and to form Gang- ways for bringing out the Load, or Ore, Cfc. 1 6. In all rhefe four Cafes *, we are to look out Mines, for the Veins, which the Rains or other Acci- dents may have laid bare-, and if fuch a Vein/'^ opened. be found, it may often be proper to open the Mine in that Place, efpecially if the Vein proves tolerably large and rich : Otherwife the moll commodious Place, for Situation, is to be chofen for the Purpofe; viz. neither on a Flat, nor on the Top of a Mountain, but on its Sides : For the Mineralifl: is always to exercife his Judgment See B b 2 m 372 Lecture the Seventeenth. in the due Choice of a Place to begin the Work. *The heft 17. The bell Situation for a Mine is a moun- Situation tainous, woody, wholefome Spot, of a fafc, eafy Afcent, and bordering upon a navigable River. Such a Place therefore being the Standard of Goodnefs, all others may be judged of as they approach to, or recede from it. J^eguires 1 8. Wood is indifpenfably necefTary for make- Wood. ,-}^£ neceflary Inflruments, Engines, and H uts ; as alfo lor fencing the Pits, or Avenues, and fupporting the Rock, where large Caverns are made by digging away the Ore : And again, for fupplying Fewel to the melting Works ; unlefs where Pit Coal will ferve the turn. But though no Wood or Coal fhould grow upon the Spot, it may often be fupplied by iVieans of a navigable River, or cheap Carriage. And thus there are fome rich Mines, in the hotter Climates, Vv^ithout fo much as a Shrub growing near them. Water. 19* Plenty of Water fhould never be want- ' ing, and is beft: fupplied by a River, from which it may be commodioully derived, by Pipes, into the Lavaderos, Smelting-PIuts, Cfr. or even brought into the Burrows themfelves, and made to work the fubterraneous Machines. Thefe are Conveniencies not to be expedled from cafual Rains, or the Torrents of the Mountains. 20. The Roads and Conveniencies of Carri- Roads, to and from the adjacent Parts, muft be likewife regarded ; as well for the Sale of the Metal produced, as the Conveyance of Goods and the Neceffaries of Life to the V^orkmen : For it rarely happens that Provifions are afforded by the Spot v;here Metals are found. 21. The Places abounding with Mines are generally healthy } as ftanding high, and every way Of Mineralogy. 373 Way expofed to the Air : Yet fome Places And n^hoi. IVlines are found prove poifonous, and can hyjome Air. no means be dug, though ever fo rich. The Way of examining a lufpeded Place of this Kind is, to make Experiments upon Brutes, by expohng them to the Effluvia or Exhalations, in order to find the Effedts thereof. 22. But a confiderable Advantage may fome- Petals oh^ times be made, without the Labour and Expencc of Digging : For as Springs and Rivulets are frequently the Outlets of Mines, it may happen that the Sand of fuch Waters fhall be worth the waffling for Metal ; in which Manner large Qiiantities of Gold-Duft are often procured. And hence it appears to be, that the Sands of many rapid Rivers, and even the Sands of the Sea in fome Places, contain Gold ; though the latter in fo fmall a Proportion as feldom to be worth the Waffling. But the Sand of fuch Ri- vers wherein llamped Ores are continually waffl- ed may frequently deferve to be aflayed. 23, The Veins of a Mine differ greatly fvom^he diffe- each other, in Depth, Length, and Breadth, ^ent Veins. Some ftretch obliquely from the Surface towards the central Parts of the Earth ; and thefe are called deep Veins : Others lie fflallow and circu- lar, fo as to encompafs a large Space ; thefe are termed fpreading Veins : Others poffefs a great deal of Space, both in Length and Breadth • and thefe are called accumulated Veins ; being no more than a Space poffeffed by a Group of Foffils of one certain Kind. But to give the Hiftory of Veins, and Fibres, which are fmaller Veins, their Differences, their Directions, their Inter- fedions, their different Goodnefs, their Difcon- tinuations, their Rifing, Falling, ^c. would be a large Work. Let it, however, be obferved, that thefe Things feem to proceed in a certain B b 3 order, 374 Ha^ to he traced. And dug. *The Bur- ro'-ivs, ho w made. The Di T- gins