INTEENATIONAL EXHIBITION, LONDON, 18 7 1. POTTEKY. OBSERVATIONS ON THE MATERIALS AND MANUFACTURE OF TERRA-COTTA, STONE-WARE, FmE-BRICK, MAJOLICA, AND ENCAUSTIC TILES, "vnTH EEMAEKS ON THE PRODUCTS EXHIBITED. By ARTHUR BECKWITH, CIVIL ENGINEER. NEW YORK: D. VAN NOSTRAND, PUBLISHER, 23 Murray St. and 27 Warren Sr. 1872. CjOMS IP 7S7 IS7I Entered according to act of Congress, in the year 1872, by D. VAN NOSTEAND, in the Office of the Librarian of Congress at Washington. PREFACE. In making a brief report upon the Pottery displayed in the Exhibition, relating to objects of use and ornament in every house and family, the opportunity presented itself to examine the processes of manufacture employed in the prin- cipal branches of the ceramic art. In describing these, I have endeavored to add to the enumeration and treatment of the materials employed, a summary of their different qualities for their respective uses, together with analysis drawn from reliable sources, and a slight sketch of the origin and progress of these great in- dustries. To render the subject more intelligible, I found it impos- sible not to enter somewhat into technical details, which I hope will not prove wholly without interest. Aethue Becewith. 9071 INTRODUCTION. The International Exhibition, held this year in London, contains a very complete collection of Pottery in all its branches. The machinery employed in its manufacture is also exhibited, but only to the extent of a small portion of the various machines employed. The following pages contain a notice of the principal objects of interest in each department, and a summary of the various processes of manufacture, with the differences between them. The composition of almost every kind of Pottery is fre- quently guarded as a trade secret, but of late years, with indifferent success. The materials available in each locality, which form the basis of local manufactures, differ in their chemical element, and especially in the mode of their aggre- gation. In Pottery, the mode of aggregation or grouping of the chemical elements, exerts an all-important influence (see Fire-brick), and even when the exact composition of a ware is known, it cannot be reproduced by merely bringing together in correct proportion, the right chemical elements. To use the different available materials, direct experiment with them must be made from the start ; and as the substances ex- tracted from the earth vary from year to year, these experi- ments must be repeated subsequently, in order to maintain the quality of the products. In the presence of modern chemical analysis and micros- copical research, it avails little to keep secret the composition of wares. Analysis reveals the proportion of the primary elements ; the microscope goes far to determine their mode of grouping ; and as to the choice of natural materials, this is inevitably, even when the composition is known, the subject of direct experiment. 6 POTTERY WARES. Before proceeding further it may be well to recall that the term Pottery is comprehensive, including all things fashioned of earth and hardened by heat, from the rough baked clay in the shape of bricks and massive articles, to the fine china clay worked up to the lightest and most transparent porcelain. The term Pottery, as distinguished from Porcelain, is some- times used to indicate only opaque earthen-ware, but the variation in the degree of transparency of semi-vitreous substances is so gradual that the boundary hne determining where the one ends and the other begins cannot be well traced. All pottery wares may be divided into unglazed and unvit- rified ware, which is absorbent and permeable to water, and glazed and partly vitrified ware, which is non-absorbent and impervious. At an early period, glazes consisted of a coating of wax or oil and ochreous earth, or an alkaline solution to vitrify the surface, until the discovery of an adherent vitreous glaze, which could be fused upon the surface of the porous clay. Later, in Southern Europe, a glaze composed of siHca and lead was used, and the Moors, by adding oxides of lead and tin to glass, formed an opaque white enamel, which was imitated in Italy, and various metallic colored enamels were discovered. Pottery wares may also be divided into hard and soft ware, according to the materials used and the temperature at which they are solidified in the furnace, which results in a marked difference of texture. Thus common brick and earth- enware are soft, while fire-crockery and stone-ware are hard. And porcelain, likewise, is either like the hard Oriental china- ware, or the soft English porcelain, which receives its greatest fire in the biscuit or unglazed condition. Hard porcelain was known to the Chinese many years B. C, and imported into Europe by the Portuguese about the year 1500, but its composition remained unknown there until, in 1709, Bottcher, in Saxony, accidentally discovered it, and Cookworthy, in England, discovered the china clay. 7 PORCELAIN, Excellent qualities of china claj are found in Cornwall, West Devon, Central France, Northern Germany and America ; they all seem without exception to be formed by a process of natural or artificial washing from the decomposed felspar of certain kinds of granite. Felspar contains 62 silica, 20 alumina, 15 potash, and 3 of water, lime, magnesia and iron. The materials from Cornwall are artificially prepared, and the uniformity of quality thus obtained makes them more valuable than the natural china clay which varies more in quality. One hundred parts of the finest china clay, or kaolin, contain : Silica 46, alumina 40, oxide of iron, lime, magnesia together 1, water 13. When more silica is present, especially in a free state, as fine or coarse sand, 10 or 12 per cent, of which is sometimes found mixed in the clay, as in Cornish stone, the china is rendered coarser. The process of natural washing of porcelain clays has been performed on a large scale in Cornwall and Devonshire. The decomposed granite has been washed through an ex- tended valley, leaving the coarser particles of quartz behind, and conveying only the particles of fine clay to the lower parts of the valley, where they are found covered by a bed of local gravel. These deposits are cut with a spade into cubical blocks called " china stone," and partially dried and removed, leaving large pits. When the kaolin is artificially prepared, the decomposed rock is washed in a series of tanks, in the first of which the heavier particles of quartz, mica, and impurities are collected, while the fine particles, consisting of the decomposed felspar, are allowed to settle in the succeeding tanks. The water is run off, the sediment is dried in sheds and cut into cubical blocks of about one foot, and sent to market. The soda granites, in which the felspar contains soda instead of potash, decompose most readily and are most used for porcelain. There are differences in texture and appearance between the English porcelain called " china " and the " hard por- •8 celain " manufactured in China, France, and Germany. The body and glazes of hard porcelain are composed of the same purely granitic materials, used only in different proportions, and under the very high temperature employed they vitrify together. As this high temperature would be destructive to coloring, the colors are laid on over the glaze subsequently to it, and fixed by again firing at a lower temperature. The result is a certain dead opacity in the appearance of the coloring. The composition of Enghsh or soft porcelain is more complex ; a large proportion of calcined bone is mixed with the china clay and Cornish stone to produce an effect of white transparency, and small proportions of gypsum, sand, chalk, alum, soap, soda, lime, nitre, and salt are added. This body receives its strongest firing first, and the glaze and colors are then applied and fired at a lower heat. The glaze is formed of oxide of lead or tin, with borax and silica, potash or soda, resembling that of old Sevres. This glaze vitrifies separately from the body, and forms over it a coating similar to glass ; it sometimes incorporates the colors in such a way that the subjects painted over it appear through the glaze as under a glass, presenting a briUiant and finished appearance, Hke the soft Sevres porcelain of the last century. The hard porcelain differs from the soft in being closer grained, denser, more translucid, capable of supporting greater heat, presenting many crystalUne specks in the frac- ture, and its glaze is harder, not so easily scratched by the knife, and incorrodible by acid. Hard porcelain is not man- factured in England ; twenty years ago Messrs. Minton tried to manufacture it, but abandoned the attempt. The nature of the fuel used in England, which is coal, together with the softer nature of the clays, are attended with greater difficulties than the use of wood, as in France. There are some advantages in the matter of colors in making soft porcelain, for turquoise, Bleu de Koi, and transparent green can be freely employed on English china, and they have more brilliancy, especially by candle-light, than the colors of the hard porcelain. The fusibility of the softer 9 lead glaze, by incorporating the colors, produces this trans- parency. The plasticity of the body also allows of greater perfection of form, and it is of a purer white. Analysis of English porcelain, by Couper, show a compo- sition of : Sihca 40 per cent. Alumina , 21 to 25 per cent. Lime 10 " 14.22 Magnesia 0 " 0.43 Phosphate of lime and some iron. 26.44 " 15.3 " Alkalies and loss 2 " 6 The bones used are chiefly imported from South America. Those of oxen are best, those of horses and hogs contain too much iron. They are deprived of grease by boiling in hot water, then calcined openly or first distilled in closed vessels and then burnt in contact with the air. The white ashes are ground and tempered before use. This phosphate of lime has a strong whitening power, and is considered to act me- chanically to form the skeleton of the ware. As much as fifty per cent, is sometimes introduced. The biscuit fire lasts twenty-five to fifty hours, and is con- ducted in kilns, similar to those for earthen-ware. The fire for the glaze lasts fifteen to twenty hours. The glaze contains : Oxide of lead 20 to 23 per cent. Oxide of tin 0 " 3 Cormsh stone 20 " 33 Flint 7 " 17 Flint glass 0 " 20 Crystallized borax 19 " 25 Soda and potash 0 " 8 and instead of Cornish stone sometimes thirty-eight to forty- two per cent, of felspar. A fraction of smalt is occasionally introduced. The elements of hard porcelain are kaolin fluxed with felspar. Examined under the microscope this porcelain 10 shows a framework of minute opaque particles of burnt kaolin, cemented by the fluxing elements, which are fused to a transparent glass (Ehrenberg). Occasionally, to diminish the shrmkage, quartz sand or ground porcelain are added, and to increase plasticity, the alumina is increased. When felspar is wanting, there are substitutes, such as pegmatite (a granite), dust from granitic roads, kaolin melted up with carbonate of potash, gypsum and chalk. The ma- terials are ground particularly fine and well washed. All the devices of kneading, balling, beating, etc., which produce an intimate and homogeneous mixture, are applied. Warm water, which dissolves earths and alkalies, is recommended to remove those causes of softening. The analysis of porcelains from China, Sevres, Berlin, Dresden, etc., show a composition between : Silica 63 to 75 per cent. Alumina • 18 " 35 " Potash 0 " 5 Soda 0 " 3 " Lime 0 " 5 " Magnesia 0 " 1.5 " Iron, as little as possible. Laurent analyzed the best chinas, and the composition he found has since served as a model at Sevres, viz. : Silica 58, Alumina 34.4 Lime 4.5 Potash 3, In Vienna, 72 per cent, of kaolin was fluxed with 12 felspar, 12 quartz, 4 gypsum. The Dresden china contains even 26 per cent, felspar. The glazes of Dresden and Munich are formed of : Burnt quartz 35 to 37. Kaolin and ground porcelain 46 " 48. Limestone and gypsum 16 " 18. 11 The glaze of Sevres is simply pegmatite, wLicli contains silica, 76, alumina, 16, potash, 8. The glaze used being of the same composition as the mixture which fluxes the kaolin, it readily unites with the latter in the fire, and porcelain can be made in one firing, as in china, the object being moulded, painted and glazed in the clay state, and completed in one firing. It is usual, however, to heat the body first to 30° or 60° Wedgwood, so that it may rapidly absorb the water of the glaze when subsequently dipped in it. The degree of this first heat requires attention, for if too high the ware will no longer absorb the glaze. By greasing any part, it will not take the glaze. The second firing requires the strongest heat used for any pottery (130" to 160° W.), to obtain a sufficiently hard glaze, and great care in modulating the heat. The total shrinkage reaches up to 17 per cent., the quarter of which occurs in the first fire. The ware must be separated from the products of combustion. The ovens are various. The Qinori or Sevres Oven, is in three stories, the two lower directly heated by fires at the sides, the upper one by waste heat. The Berlin Oven has 4 stories, the lower one is used exclusively as a combustion chamber from which the gases ascend to the three others suc- cessively. It is said to give higher heat than the Sevres. Among the best are those fired with gas ; the preceding one, and that of Thomas, are somewhat of this kind, the flame being direct, but those of Venier and Gustavsberg are more perfect. They resemble somewhat Bosch's oven (see Stone- ware.) The gas generator is separate and under perfect control ; the gases are introduced in the centre of the floor of the oven, ascend, are reverberated, and drawn through 18 apertures in the floor into flues in the outer walls, which lead to a second story chamber, and thence to a third, where a central chimney exhausts them. Preliminary heating of the air produces a higher temperature. An analogous oven is being tried at Berlin, in which the successive chambers are placed side by side, instead of being superposed. This 12 disposition allows of the continuous principle being applied, as by Hoffmann. There is still room for improvement in porcelain ovens, since 1 lb. of porcelain requires the heating of 15 lbs. of other material, irrespective of the masonry of the ovens, for all of which, 8 lbs. of coal are necessary. Porcelain Exhibited. — In examples of common En- glish pottery, the mere manufacture is of the highest and soundest quality, though the design and harmony of colors are not unfrequently deficient in comparison. The high technical excellence of modern ceramic art is well represented at the Exhibition. Dr. Wall, the founder of the Royal Worcester Porcelain Works, first turned to account the discovery of Cornish stone, and these works exhibit very fine porcelain ; espe- cially of a dark blue color. In decoration they have avoided the use of too great diversity of color in the same work ; the brilliant positive hues they use, in connection with the human figure, have been objected to as less effective than half tints. The transparency of their porcelain is noted. Their Parian is admired, and they also exhibit Majolica. Copeland & Sons make a fine show of porcelains. Their most successful colors are a purple and a rich gi'een. A novelty in their decoration consists in small subjects and figures in black, traced out with a fine gold line on a white ground, having the effect of a Silhouette. In coming to the name of Minton it is proper to recall that there are three firms, Minton & Co., Minton, Hollins & Co., of Stoke-on-Trent, and Eobert Minton Taylor, of Een- ton, in the same vicinity. The specialty of the two latter is flooring tiles, though they exhibit other goods. Messrs. Minton & Co.'s specialty is not flooring tiles, which they do not manufacture, but they exhibit largely in all other descriptions of earthen-ware and porcelain. Mr. Thomas Minton founded the firm in 1791, and to the labors of his son, Mr. Herbert Minton, are due in great part the medals which the firm acquired at all the exhibitions. The present proprietor is Mr. Colin Minton Campbell. Mr. Ar- 13 noTix directs the staff of artists who assist the firm. The excellence of their colors, and the variety in the kinds of ware they exhibit, place them among the first manufacturers. They obtain a new process of gilding by corroding the glaze with an acid and applying gold leaf upon the body. The revived and modified Orientalism of ceramic decora- tion first in Paris and now in London, is a notable feature. Oriental surface decoration seems to have due regard to the right principles, as it is always pleasing. The Persian ware of Minton's is one of the novelties of the Exhibition. Its brilliant blue rivals the turquoise in richness and texture. The brothers Deck, in Paris, first revived this art. A pair of celadon vases by Minton, on pate changeante or chame- leon ware, which from gray green by day changes to a deep pink or crimson hue under artificial Ught, and enriched by some delicately executed Cupids, are admired. John Mortlock's turquoise blue is as fine as Minton's, but the glaze applied is defective from being crackled by unequal expansion. The names of Wedgwood, Pellatt, Goode, Adams, Kerr, Phillips & Pearce, Powell & Bishop, Eose, Battam, Boucher Guy, Hancock, Garrard, Elkington are also prominent among English manufacturers. Italian, Spanish & Portuguese pottery are exhibited by the Science and Art Department. The Italian and Spanish wares exhibited are defective in coloring and glaze. The Portuguese Palissy ware shown is highly glazed, but pre- sents a striking example of utility made subservient to deco- ration. A collection of Moorish ware, lent by Mr. G. Maw, shows good forms and tasteful ornamentation. It is said that the history of the potter's art is the history of civiliza- tion, and in this sense the Egyptian pottery, lent by the Khedive, is interesting. It shows a coarse body and inferior coloring, but the forms are quaint and graceful. The yellow glaze used at Old Cairo consists of oxide of lead and pounded pebbles of silex. The green glaze contains copper in addi- tion. The body is formed of clay mixed with ashes, sand. and sometimes hemp, and slime of the Nile. Likewise Indian pottery is curious and instructive in form and color. In some specimens gray or brown mica mixed with the clay, or rubbed on it, produces a metallic effect on the surface. Canada contributes some pottery of a common description. Danish pottery is well represented. The Eoyal Copen- hagen Manufactory has a high reputation, and Bing & Grondahl exhibit good work. A plate pattern, of tendrils and flowers lightly sketched on a ribbed surface, is admired. This decoration is of a simple and pleasing kind, and in better taste than more elaborate and expensively painted dishes, in which the idea of actual use seems out of place. Hungarian porcelain, exhibited by M. F. de Farkashaza, ornamented with a light red design on a light-colored ground, is admired in the same way for its pleasing effect and good taste. The porcelain is of a fine quality, and very hard, produced at Herend. The ornamentation has a pecuhar and somewhat Japanese character. The body of the Swedish porcelain is good and haid; the correctness and grace of the decorative wares are char- acteristic. Prussian pottery is represented by some very fine white biscuit or unglazed ware from the Royal Berlin Porcelain Works, and an Urbino vase, price $260, of great beauty and richness of coloring. The porcelain is hard, and noted for the precision of manufacture. Some Belgian dishes are shown, profusely covered with paintings of merit as works of art, but which may be re- proached with the common error of making the use subser- vient to the decoration. Several Danish, Swedish, Hunga- rian, English, and other exhibitors have happily avoided this extreme. As novelties, the smoke-painted porcelain from Berne, executed by Mme. A. Leuzinge, and a set of photographs of landscapes on porcelain plates by Leth, of Vienna, are pleasing specialties. Also W. J. Goode, of South Audley street, London, exhib- 15 its etchings on the glaze, of special merit. The designs are eaten into the glaze with fluoric acid, so that they could be printed from ; and the hnes thus produced are colored. PATE-SUR-PATE, Or " clay-upon-clay." In this method of decorating porce- lain, the actual ornament is produced by the application, with the brush, of white liquid porcelain, or " engobe," used as a pigment, in successive layers upon the colored body of the ware — i. e., a given thickness is added to it, with a brush or by immersion, presenting a rough surface in rehef, which is trimmed to the required design by cutting implements and sharp scrapers. By successive applications, the painter, who requires to be also a modeller in the treatment of his subject, gains his effect of relief. When the bas-relief is completed, the object is subjected to several bakings or firings, and at the last firing it is covered with a coating of glaze. The strong oven fire vitrifies the porcelain and the pigment, embodying them together, and rendering the salient objects translucent. These portions, in vitrifying, retain a relief which forms the actual outline and the high lights, while its thinner parts enable the colored groundwork to be seen through them, and these form the transparency of float- ing draperies', clouds, or flesh, according to the design. The principle of pate-sur-pate thus differs from that of ordinary white porcelain transparencies used for lamp and window decoration, by transmitting color through the design instead of light. The clay ground generally used is a soft yellowish gray or sage green, known as celadon. The tint is tender and un- obtrusive, and its effect, seen through the thin parts of the superimposed design, is pleasing. Like most European novelties, however, it is an old acquaintance of the Chinese, from whom the idea has been derived. Pate-sur-pate was first attempted in Europe in 1847, at Sevres, under Ebelmen, and until the late war many articles in this style were pro- duced of great beauty. During the siege of Paris, Messrs. 16 Minton secured the services of Mr. Solon from Sevres, and at once began experimenting to obtain the colored clays re- quired. They met with complete success, obtaining the Sevres colors and several others in addition, and now pro- duce celadon cups and vases, graceful in form and delicate in execution. Mr. Solon's work possesses a cameo-like softness, which yet harmonizes well with the somewhat coarser grain of the body of the ware. Mr. Burty, in. his " Chefs d'oeuvres of the Industrial Arts," says of this artist : " Mr. Solon, who also signs his delicate bas-reliefs with the word " Miles," is gifted with a perfectly modern sentiment for decoration. These nymphs who push aside the reeds of the brook; these Psyches who are lighting a Diogenes lantern ; these water- nymphs reclining on the brink of the waters which flow from their bended urns ; these chimeric figures which stand erect with bulging throats ; these Medusas whose hair is composed more of strings of pearls than of snakes, — these are the dreams of an artist born in our day, and who only claims of Antiquity or the Renaissance the more exquisite details of their fancy." The prices set upon Mr. Solon's work, are $90, $70, $110, for three vases respectively 7, 10 and 18 inches high. The very high temperature employed in firing this ware, is destructive to most colors, and only those obtained from the oxides of cobalt, nickel, chrome, uranium, etc., are used. Specimens are shown with a ground of a warm chocolate color and other dark colors. The effect of these is apt to be flaky and less delicate. One of the difficulties, when figures are delineated, seems to be that the glaze has a tendency to mar the effect by destroymg the sharpness of outUne. Oxide of chrome, fired in a neutral atmosphere, produces Celadon green. In the Limoges ware, the difference is that a regular enamel or vitrified pigment is used, while in pate-sur-pate, porce- lain clay merely is used. 17 "PATE CHANGEANTE." Another peculiarity of the Sevres work is their "pate changeante " invented by the director, Mr. Eegnault, and so named from the color changing from grayish celadon by day- light, to a decided pink by candlelight. Messrs. Minton have succeeded in producing a similar dove color, which changes to a light crimson by artificial light. Oxide of chrome, fired in an oxidizing atmosphere, produces a similar color. GRAFFITO WARE. This ware recalls by its decoration, that of the walls of Pompeii ; from the objects exhibited, and the simplicity and beauty of their ornamentation, it promises to develop well. Graffito, which means scratched ware, is of ItaUan origin, and is supposed to have been first invented in the province of Perugia in the 15th century. At the period of the Renais- sance in Italy, the potters, ignoring the decorative processes with colors and enamels, then familiar to the Moors in Spain, and which Delia Robbia subsequently imitated, made use of two clays of different color. The body of their vessels they formed of the darker clay, and after drying them only sufficiently to be able to handle them, they dipped them into a liquid " slip " formed of the lighter colored clay. As soon as this coating was dry, the artist, with a sharp wooden or steel point, traced his ornament on the surface, removing the upper light-colored surface and showing everywhere on the lines of the design, the dark body beneath. The vessel was then covered with a natural sulphuret of lead ore previously triturated, which, when fired, melted on the ware and pro- duced a rich yellow glaze. This process of decoration allows the artist to express his feeling on the ware without the intervention of any assistants. After firing, some parts of the work were touched up by the application of slips of cop- per or manganese ore, which produced the green or violet patches which give additional richness to the ware. The natural colors of the clays, which form the decoration of this 18 ware, generally harmonize perfectly together and consequent- ly produce a good effect. Messrs. Minton & Maw have lately revived this process, and show fine specimens. Minton's de- signs are by W. A. Stevens. HENRI DEUX WARE ; OR, FAIENCE D'OIRON. Henri Deux ware is the only description of pottery in which clays of different colors are inlaid together. The artist having made his design, each distinct part of the ornament is stamped on separate " bats " of clay. The design is thus indented in the soft body of the ware and this indentation filled up with another colored clay, and when dry the super- fluous clay is removed from the surface. The separate bats are then placed into their proper forms side by side, in a complete mould, and a backing formed of a general coating of clay was appHed to unite them together. The plastic state of the clay required great care not to distort the design. Though this process is very similar to the 12th century art of tile making, yet the application of the encaustic pro- cess to vessels of delicate size and complicated forms was not attempted till about 1540. It is held in high esteem, and valued above its intrinsic merit on account of the scarcity of the original examples ; its revival by Minton is all the more interesting. The ornaments of Henri II. ware are in the Renaissance style, and the forms have a metallic rather than fictile char- acter. A toilette suite ordered by Henri II. for Diana of Poitiers is all that is said to have been originally manufactured ; Mr. Chaffers gives a list of the pieces known, of which there are only 63, namely 26 in England, 26 in France, and 1 in Rus- sia. The bowl that Sauvageot left to the Louvre was bought by him for 200 francs. In 1835, the ewer possessed by De Monville brought 2,500 francs. A salt-cellar at the Rattier sale, in 1859, brought 12,500 francs. A restored candlestick, plainly ornamented, went for 16,000 francs at the Lafayette sale, in 19 1862, and tlie Science and Art Department of the Kensing- ton Museum gave 18,000 francs for it. Finally, at the Pour- tales sale, a biberon was bought by Mr. J. Malcolm, of London, for 27,500 francs. Such were the values set on the original Henri II. ware, and now for a comparatively moderate outlay possession may be had of reproductions by Mintcn, quite equal to the originals. Although Minton & Co. have not attempted to copy the exact tint of the clays, their speci- mens prove that they are fully acquainted with the process. Mr. Charles Toft is the name of the maker. POTTERY MOUNTED IN DAMASCENED METALS. Senor Suloaga, of Madrid, is the only producer at the present day of the Damascene work of the Saracens, and in 1855, he exhibited a fine display of damascened fire-arms He now exhibits, in connection with Minton & Co. a com- bination of pottery with this metal work which is very effec- tive. CLOISONNE ENAMEL. A specialty undertaken of late years in Paris is the repro- duction of Chinese and Japanese cloisonne enamel. In this Oriental work, a vessel of metal, usually copper, is first made and the lines of a pattern traced on its surface. A fine wire beaten into a flat supple riband is then taken and soldered by one edge to the lines traced on the surface of the copper vessel. The wire stands on its edge, forming a number of cells or cloisons which are filled with a paste composed mainly of oxide of lead and silica, with some lime and soda, and colored as required, either with the oxide of copper, iron or cobalt. The vessel is then fired at a heat sufficient to vitrify the paste, and finally the whole surface is polished by friction. The character of the Chinese cloisonne work is coarser and bolder than that of the Japanese, and in both the con- 20 trasts of colors are successfully harmonized. Barbedienne and other Paris makers have made very gra ceful work of this description. A novelty undertaken by Messrs. Minton,is their imitation of the above cloisonne work, using only porcelain instead of metal, and painting on it with colors which have been mixed with opaque enamels, as practised also in China. This method of decoration is very effective, except when the attempt is made to imitate metallic cloisonn6 work, which is more subdued and sober in tone and glaze. The soft nature of Enghsh porcelain lends itself to the production of great richness and depth in turquoise color, when the body is covered with turquoise enamel ; when appropriately decor- ated with colored enamels, the effect is admirable. UNDER-THE-GLAZE PAINTING IN OPAQUE ENAMEL COLORS. Messrs. Minton have introduced a new set of materials for painting on a densely colored body, in the same manner as body colors are used in ordinary painting ; the whole can be subsequently glazed over without affecting the most delicate touches. Mr. Mussill, their artist in this department, was acquired by them since the late French war. The colors are perfectly opaque, have the appearance of colors for canvas, and have much more body than the ordinary colors for paint- ing on porcelain. By firing they do not change or sink, and retain the spirit of the brush. They withstand perfectly the action of the glaze in the glost oven. This method of painting (see Chinese Porcelain), practised in the East, has since been imitated at Dresden, and lately been revived at Sevres and Stoke-on-Trent. The advantage it presents, of depth of tone in colors, dura- bility owing to hard firing, and economy of manufacture, since the decoration can be apphed and made fast at one firing (unlike the paintings on porcelain, that frequently re- quire several firings), make it desirable that this method should come into more general use. 21 To produce these colors, the following considerations may assist. They are obtained by mixing opaque enamels in the colors. The different colors must act alike in withstanding a hard fire, and fusing at the same high point ; in adhering to porcelain or stone-ware, and in taking the glaze uni- formly. To obtain the requisite opacity, oxide of tin, oxide of anti- ^0^7, phosphate of lime, oxide of lead with some salt, alkalies and sihca, and in general the enamels applied to majolica, fayence, and stone-ware, are available. The me- talHc oxides which supply the color, act as a flux upon the enamel, and tend to increase its fusibility. Only those oxides should be used which will stand a strong heat, and, like the oxides of iron, cobalt, chrome, titanium, uranium, manganese, and chromate of iron, possess strong coloring powers, and in consequence do not require to be used in quantity large enough to fuse the enamel too soon. To diminish the fusibihty, the steps taken in the manufac- ture of fire-bricks and of majolica enamels (which see), apply. The fritting of the glaze {i.e., preparatory melting up to a glass), and sudden immersion while hot in cold water, in- creases its refractory power, and heightens its crystalline lustre. In BerHn, white glass ground is used as an ingredient for stanniferous enamels. If the colors used are fat, the ob- ject should be heated to volatilize the fat substance before applying the glaze. PERSIAN WARE. The old, not the modem, Persian ware is distinguished by a special brilliancy and effectiveness of colors. Messrs, Min- ton. Maw, and Minton Hollins have attempted to attain the richness of vitrified colors characteristic of this ware, and in adopting Persian patterns on turquoise and plum-colored enamel grounds, they have met with considerable success in their reproductions. Messrs. Deck, of Paris, were first pro- minent in this line. According to Scheill, the Persian body contains silex, oxide 22 of lead, and kaliab ; and the Persian glaze consists of 50 white silex and 40 kaliab (ashes of a plant growing on salt soil) ; it is fritted, powdered, and mixed with gum and syrup. CAMPBELL'S PATENT MOSAIC WALL DECORATION. '' In this process, also called Permanent Fresco or Fictile Vitrification, the material for painting on consists of a num- ber of small hexagon pieces in stone-ware, highly vitrified, and joined together in placques of convenient size by a vitre- ous cement. This ground is painted on in the new opaque enamel colors, prepared to stand a very high heat, to secure the permanency of painting in any climate. Curved surfaces can be easily managed. The inventor, Mr. C. M. Campbell, is now casing the ceiling of the staircase of the South Kensington Museum after designs of Mr. Moody. Two specimens of this novel work are shown, executed by Mr. Thomas Allen. A perma- nent surface hitherto used for fresco work has consisted of wide placques of pottery ware, but the warping of these in the fur- nace has presented obstacles which this invention is adapted to overcome ; the shrinkage of each pellet being small, the general proportions are preserved. The process still remains to be tried, applied to a large surface. BELLEEK WARE. The Belleek ware from Ireland is a new appearance. Sets of tea-cups and saucers of an original character are exhibited by Mr. Mortlock. The Belleek ware is distinguished by the high lustrous silvery quality of the glaze, which attracts the eye, and recalls the nacreous coating of a sea shell. Table ornaments of this ware are shown imitating shells in form and translucency. The material used is a group of different colored clays, found recently at Belleek, in Ireland, some of which possess the 23 property of yielding upon firing, a natural enamel or " skin" like the finest egg-shell porcelain. The glaze is iridescent, like mother of pearl, and requires to be used with discrimi- nation for decorative purposes. Messrs. Kerr, Phillips & Pearce, and the Eoyal Worcester Works, produce similar ware, in which the glaze is probably one of the artificial glazes invented by Brianchon, in which the lustre is obtained by the reduction at a low heat of me- tallic substances such as nitrate of bismuth, iron, uranium, nickel, and cobalt, or chloride of gold, by an excess of carbon, introduced in the glaze in the shape of resin and essential oils of lavender or turpentine, and formerly by a reducing atmosphere of smoke. The thin metallic deposit, like all films of great tenuity, decomposes the light falling upon it into prismatic colors. The lustre is applied with a brush, thinly, and should not be absorbed by the ware. After firing at a low heat, it adheres to the surface, and does not incor- porate itself with the body like ordinary glazes. At an early period, wax and mastic were used to procure the adhesion of the lustre. JASPER WARE, More popularly known as Wedgwood ware, differs from pate-sur-pate in the method of applying the clay, which is usually white clay squeezed into moulds and then withdrawn to be attached to the surface of the body of the vases ; the ware is not glazed ; it has no more vitreous appearance than is produced by the hard fire on the mixed clay body, and pre- sents a dead texture. The ground may be of any color. Josiah Wedgwood invented jasper ware, and the firm of Wedgwood & Co. is constituted by his descendants. Although Wedgwood ware presents less varied and subtle effects than pate-sur-pate, yet the outline of the relief is generally more perfect. Most of the designs used by Wedg- wood & Co., are Flaxman's; and the beauty of their ware with blue, dove, or oHve colored ground is well known. Jasper ware may be defined as a superior quaHty of vitrified stone- 24 ware. It requires more careful preparation, and is formed of a plastic clay to which vitrifying ingredients such as Cornish stone, flint, ground glass, felspar, sulphates and carbonates of lime and of barytes (L. Arnoux) have been added. According to Salvetat fine yellow Wedgwood ware .consists of: White jasper ware contains variously 15 to 30 per cent, of plastic blue clay, 0 to 16 kaolin, 0 to 15 Cornish stone, or, summing up, 40 to 50 per cent, of these clay materials ; to which is added 25 to 45 per cent, heavy spar, 0 to 10 flint, and 0 to 2 gypsum. Sometimes 20 per cent, calcined bone is introduced. This white body may be differently colored by metallic oxides, ^ per cent, cobalt giving blue, with 1 per cent, chrome dark green, nickel light green, copper bluish green. From natural ochreous clays and quartz a reddish por- phyritic jasper ware is made. Basalt ware, susceptible of high polish, and Egyptian ware are made by introducing in the body some 40 per cent, of burnt ochre, or 16 per cent, ochre and 45 of red clay, and sometimes 10 per cent of mill cinder (iron). The researches of Ebelmen and Salvetat hfive revealed the distinct characteristics of Chinese Porcelain. The body is felspathic and hard ; the glaze is softer than that of European hard porcelain ; the colors are properly enamels, transparent or opaque ; the coloring oxides are very few. The whole is made in one firing, at a somewhat low heat. Silica Alumina Oxide of iron Lime , 66.49. 26. Magnesia Alkalies . . 6.12. 1.04. 0.15. 0.20. CHINESE PORCELAIN. 25 Tlie ware of M. Lesme, of Paris, is similar. The enamel colors are crystals (composed of 6 miniam, 2 sand, 1 borax melted, and some soda and potash) holding in solution a few hundredths of coloring oxides. The fun- damental colors are very few, viz., cobalt for blue, copper for blue and green, gold for carmine, antimony for yellow. All other tones, with one or two exceptions, are obtained by mixing these. The harmony of Chinese decoration results from the re- stricted number of coloring agents. The brilliancy results from the oxides being dissolved. For opaque enamels, white of tin or arsenic are used. The crystals are faintly colored and rubbed in water only. For deep tones they must be superposed several times, hence the relief observable. These enamels could not adhere upon a hard European glaze. Their adhesion is attributed to the peculiar nature of the glaze. The glaze is complex ; kaolin stone, vegetable ashes, and lime are used, resulting in silica 68, alumina 12, lime 14 to 21, potash and soda 6. The moulds, even for delicately embossed pieces, says Arnoux, are simply clay moulds dried in the sun. The walls of the ovens are so thick that the hand laid on outside at no time perceives the heat. The volume of air entering is regulated ; the fuel is dry wood. "When the fire is started the door of the oven is closed, leaving only room enough to insert one piece of wood. The heat is g radually raised for 30 hours. At Sevres, to increase the plasticity, the following body, called " masse Chinoise," is used for large objects (Regnier) : Kaolin clay 43 to 44, plastic clay of Dreux 21 to 25, sand from kaolin 16 to 17, quartz sand 16 to 9, chalk 4 to 5. PARIAN. Parian, like stone-ware and terra-cotta, is composed of clay mixed with vitrifying ingredients, but it differs from these, both in aspect and composition, as being composed of purely 26 granitic materials. In composition, it lies between stone-ware and English or soft porcelain. Unlike the latter, it contains frequently no calcined bone, and shrinks more. : The clay used is the Cornish clay (obtained, as previously described, from decomposed granite) and undecomposed fel- spar, which, being rich in soda or potash, acts as a flux. It is obtained from America or Sweden. The result of firing is a semi-opaque translucent substance known as Parian, and in which every sharp outline is retained. Copeland first made it in 1848. Salvetat gives the following composition of Copeland's Parian, before burning and after : Silica 58.51 63.74 Alumina 21 29.71 Oxide of Iron 1 Lime 0.14 1.41 Magnesia 0.05 0.41 Potash 11.40 Soda 5.08 4.39 Loss 6.40 Ovens for earthen-ware can be used. Continental Parian is often of a bluish white tint ; this arises from the partial exclusion of air from the ovens, and consequent reducing atmosphere (see Blue-bricks). English Parian is of a pleas- ing creamy color, owing to the abundance of air in the oven, which peroxidizes the small quantity of iron salts dissemina- ted through the mass. Parian figures are produced from this mixed clay poured in a fluid condition into plaster moulds ; the vitreous nature of the substance renders the subsequent firing a crucial test. The contraction in baking amounts to ^ usually, sometimes even ^ of the original dimensions; due weight should, there- fore, be allowed for the variable allowance the artist has to make for the shrinkage of his work. There are many other ways of making Parian. If plaster of Paris, in fine powder, is thrown in a vessel containing a saturated solution of borax, after soaking for some time 27 witli a solution of alum a hard plaster is obtained (Ansted), wliich is also called Parian, although differing in composition from the above. Copeland & Sons exhibit well modelled forms in Parian, showing fine workmanship, as well as material of great merit. The Koyal Worcester Works produce pretty statuettes. Swedish Parian, made from Cornwall clay, by the Gustaf- berg's Co., is very white and hard. Danish Parian statuettes, by Bing & Grondahl, attract at- tention ; the excellent plan of attaching the selling price to each article, which all exhibitors are invited to adopt, has been followed by them and others, in consequence of which many of their products have been sold. Parian of inferior texture and form is so common, that its popularity for sculptural works has been much injured ; nor can it be compared with carving or sculpture as an art pro- cess. The Parian of Minton, Worcester, and Copeland is sometimes glazed to facilitate cleaning. For centre-pieces, baskets, teapots, etc., this is an improvement ; but its appli- cation to statuary is frequently objected to. ART APPLIED TO USTDUSTRY. The excellence of ceramic products in the three essentials of material, form, and decoration, is perhaps most remarkable for the two latter qualities, in the examples where the name of the artist accompanies that of the manufacturer. On one hand, the highest skill in manufactures is constant- ly seen connected with the weakest efforts of design, as though mere materials and workmanship were sufficient without the quality of art. On the other, much of the best artistic talent is expended upon objects in which we may seek in vain to discover their utility. Many firms rely too much on the quality of their wares merely on account of mechan- ical excellence of material, rather than upon the artistic treatment which enhances their value. The somewhat cowardly suppression of the names of the artists who design and model the works of various manufacturers, is in a great 28 measure tlie cause. This practice is less observable in some countries, but it is still only too general. Employers of skilled labor, who think it their interest to conceal the origin of the artistic element of their manufac- tures, are doubtless moved by the fear of losing their artists upon revealing their names, or having to increase their pay. But this policy is as narrow as it is ungenerous. The interests of the artist and manufacturer are not anta- gonistic ; they are parallel. The stimulus of pubhcity when granted to the carvers in stone, the moulders in clay, the painters on earthen-ware and porcelain, excites their laudable pride and enhances the quality of their work. The mere reward of publicity attracts new artisans to these occupa- tions, and affords the manufacturer a wider choice of art- workmen. An illustrious artist no sooner lends his assist- ance, than his works are at once eagerly sought. When an artist has once attained a reputation, the manu- facturer who secures his services is generally not unwilling that his name should appear on his products, but it is essen- tial to the development of artistic merit in current manufac- tures, in its most popular form, that rising art- workmen should have the opportunity of being made known to the public. In this view and for those interested, I give the following list of Designers and Modellers in the Department of Pottery, which are all the names I have obtained ; but before leaving this subject, I must name Mr. Henry Cole, C. B., as the one man in England who, by his foundation of art-schools and museums, and creation of a system of art-manufactures, has done the most to provide art instruction for the people : LIST OF DESIGNERS AND MODELLERS, EI THE DEPARTMENT OF POTTERY. B. J. Morris — employe of the S. Kensington Art School — designed a frieze representing pottery manufacture ; also panels representing the months of the year. 29 Waltee Lonsdale— obtained travelling studentship of Royal Academy — designed art-tile chimney piece. W. J. GooDE — designs etchings on the glaze. E. Lessoee (late) — original designs for ornaments in mono- chrome, free and bold pencil, painted pottery, majolica, cream-colored ware for Wedgwood & Sons. A. Stevens — sculptor of the Wellington Monument for St. Paul's ; designs Graffito ware, great breadth and power. Coleman — painted heads on earthen-ware for Minton, also mosaic Head of Isaiah. Solon — executes pate-sur-pSte ; received at Paris, in 1867, a bronze medal as " Sculpteur en pate k la Manufacture Imp6riale de Sevres." Was the first artist acquired by Minton & Co., possessing the skill requisite to found this branch of industry. H. Daeling and J. Leese — engaged in Minton & Co.'s man- ufactures. Yahn — painted for Minton an effective frieze on porcelain vase in turquoise-ware. Flying Cupids and Nymphs in the Bucher style, executed before the final glaze. John Gibbs, J. Eyee, J. P Seddon — design tiles for Minton. Kate Beayfoed — designed mosaic panel for M. Hollins & Co. Lessels — mosaic table designed for Maw & Co. De. Deessee — known for his botanical knowledge applied to ornament. Designs conventionalized floral ornaments, ewers, gilt and decorated terra-cotta for Minton & Wedg- wood. D. Peaece — of Phillips & Pearce ; effective design for centre- piece for flowers in Wedgwood ware. C. F. Hueten — ^flowers, birds, skilfully painted for Copeland. T. H. BoTT (late) — designs after Maclise, for vase, in Limoges enamel manner. A. DE MoL — Belgium — Battle scenes on porcelain. E. TouETEAU — Belgium — Virgin and Child on porcelain. A. Hanstel — Belgium — Descent from the Cross, on por- celain. M. Elden — Set of 5 subjects in mosaic, representing the year, for H. Bessemer, Esq. Also art tiles for chimney pieces. Tesserse, by Maw & Co. 30 Geo. Tinwoeth — modeller, is supposed to liave modelled a fine eagle in terra-cotta for Doulton & Co. J. S. KusHTON —painted for Worcester Works, Assyrian and Algerian figures on turquoise ground ; and the Arch- angel Gabriel on a placque. Mme, a. Leuzinger — Berne — Smoke painted porcelain. Ed. Rischgitz — paints plates cleverly for Copeland. Julius Leth — ^Vienna — porcelain with photographic paints. Ball — modelled colossal terra-cotta figures for Lecture Theatre of S. K. Museum. Doulton, manufacturer. C. Fleuse — designed Gothic parapet of terra-cotta, for E. March, Berlin. O. Muller, Professor Wolff, Blankenstein — designers in terra-cotta for E. March, Berlin. Mrs. D. O. Hill — a terra-cotta statue of Dr. Livingstone in appropriate travelling costume. Aaron Green — painted birds resting on branches of bam- boo, on turquoise porcelain for Minton. M. Mussil — Austrian, attained emin ence in Paris ; now paints under the glaze for Minton. T. KiRKBY, C. Toft, W. Mellor — design graffito ware for Minton & Co. C. J. RowE — designed figures of Shakespeare's heroines for Daniel's dessert plates. Also pierced work, and views of " Mentmore," together with R. P. Daniell. A. Waterhouse — designs for Simpson & Sons' art tiles. C. Smallwood — designed and modelled a bread tray for R. M. Taylor. S. Cooper — mosaic inlaid in alabaster, for M. Hollins & Co. T. Morgan — mosaic " Head of Inigo Jones," in tesserse, by Maw & Co. Henry Sherwin — designed dinner plates for Pinder, Bourne, & Go. Thos. Allen— modelled majolica vase — Rape of the Sabines, for T, Mortlock, paintings after Boucher. J. Slater — paints vases for Minton & Co. Birds, &c. J. H. Wood — designs ewers and basins for Pellatt & Co. Milk jugs and dejeuners. 31 J. Randell — paints birds, fishes, on ewers and basins for J. Rose & Co. Kerr & Sons — design and exhibit a breakfast service of Belleek ware. Rouse — painted cattle on Rose du Barry ground for card-tray for Daniell & Son. J. R. Lees — designed ewers, basins, dessert services for Powell & Bishop. J. Ellis — executed the preceding designs of Lees. Williams & Davis — designed " View of Whitley Court " for a Tazza of Worcester Works. V. Perling — ^painted dessert services for Royal Worcester Works. Miss Margaret Tupper — original designs for tiles, card- plates, cups and saucers. C. Palmere — ^painted two dejeuner services for R. P. Daniell, one a la pompadour, in turquoise and gold, 1871; the other, " Yiews of Mentmore," Blue de roi and raised gold, from designs by C. J. Rowe. Mr. & Mrs. Steele and D. Lucas — design dessert centre- pieces for Thomas Barlow. J. Booth and J. Bate — painted roses and pearls on a coffee set, and " the Lorne " for a card-tray. E. Bejot — designs and decorates in the Persian style and in Henri II. ware. Roberts, Hill, J. Callowhill, J. Williams — landscape ; J. Bradley, spill vases. Davies, Webster — flower holders ; Clarke, Jardinieres ; Bolt, J. HoPWiCH, spill vases. E. Stephan — spill vases ; all the preceding eleven paint on porcelain for the Worcester Works. W. Cooke — painted cups and saucers for R. P. Daniell. J. S. Whitty— painted porcelain views of Highgate, Harrow, &G. KuHN figures and Gorner flowers — ^painted on porcelain for Royal Berlin Works. Mitchell — painted cattle for Minton & Co. J. B. Fidler — decorates Graffito ware for Maw & Co. 32 Babon Davillier — copies Henry II. ware for Theod. Deck of Paris. H. S. Marks, A.K.A. — ^painted a Falconer on hexagonal tes- serge. E. Monti, J. Hadley, W. Theed, L. A. Malempee, M. Noble, R. A., T. Wolner, M. C. Belleuss, J. Durham, Westma- COTT, Papworth, T. Brock, E. M. Miller, Miss S. Teery, P. MacDowell, Professor Molin of Sweden; the preced- ing fifteen model ceramic statuary. J. Gibson, R. A. — ceramic statuary, " Nymph at Bath." F. Fuller — of Florence, modelled " Nydia," of Parian gilt, for Minton & Co. F. Mantel — modelled bust of Bismarck, and vases. Walger — ^modelled bust of Count Moltke, in white biscuit, for Royal Berlin Works. Professor Scholander — designs earthen-ware vases for Ros- trands & Co. Pienne — models and decorates Faience a la Henri II., for Royal Worcester Works. H. Protat — models in the Chinese style for Minton & Co. J. Janda, Itzenplitz, Flancock, Wilmore — model ceramic statuettes. G. J. Cox, H. HOHLE, C. LUCKHARDT, C. SCHMIDT, SiMPSON — paint placques. Godfrey Sykes — modelled an excellent column for Theatre of S. Kensington Museum, and designed art tiles for Simp- son & Co. EARTHEN -WARE. Earthen- ware possesses a hard, opaque, partly refractory body, covered with a transparent glaze, and withstands cer- tain alterations of temperature. It is composed of plastic fire-clay with an addition of fine ground quartz or refractory stone, and occasionally of lime. Thus in England 83 parts of Dorsetshire clay (containing 76 silica to 24 alumina) are mixed with 17 of ground flint. The ware is brought to the state of biscuit by one firing, at 60° 33 to 100° Wedgwood, before the glaze is applied (see Stone- ware Ovens). The glaze is a colorless transparent glass of variable com- position, white lead being the base. Borax is used to heighten the lustre of the colors. Silica and alumina (de- rived from kaolin and Cornish stone), flint, felspar, alkalies, saltpetre, and chalk are variously used. To obviate a yel- lowish tinge, less than one thousandth of smalt is added, pro- ducing a bluish hue. The glaze is first burnt (for instance in Bosch's oven) to a glass, the oxide being added before or after the burning ; this glass is ground very fine, tempered with water, and the ware in the biscuit state is dipped in it, and then burnt a second time at a lower heat of 12° to 80° W. to fasten the glaze. The glaze should be hard enough not to be easily scratched by the knife. When patterns are printed on the ware, they are applied before the glaze. Cowper gives the following glaze : Silica 43.66 Alumina and Iron Oxide 9.56 Borax 20 08 Carbonate of Lead 15.19 Chalk 10.88 Calcium 0.52 to form which, Cornish stone, granite, borax and gypsum are used. For superior qualities of earthen-ware 16 to 26 per cent, kaolin is added to whiten the body, and a small quantity of Cornish stone (1 to 3 per cent.) to render it denser. This forms the basis of cream-color. Part of the Dorsetshire clay is frequently replaced by the Devon, which is somewhat inferior. The ground flint is added to whiten the body, and to di- minish the great plasticity of the Dorset and Devon clays to a point more suitable for working. The German Feines Steingut and the French fine Fai- ence correspond to English earthen-ware ; they are as white and glossy, but less dense and resisting. 34 For further details, see Tiles and Majolica. Lead Glazes. — Oxide of lead increases the fusibility, adhesion, and elasticity of a glaze, but makes it easier to scratch with the knife, and somewhat yellow. When the glaze contains free lead oxide not saturated with silica, or when the ware is not enough burned, it is deleterious for fire crockery. To detect this, drop vinegar on the ware, after a while insert a piece of clean granulated zinc, and there will be a grey deposit of lead. Before using such crockery, wash it out with hot strong vinegar. To make sanitary ware, free from lead, is not easy with- out increasing the cost. A boracic glaze may be used, or as in Berlin the gesundheitsgeschirr, the body glaze, given by Kerl, viz. : Body— Kaolin 48 Glaze— Sand 42 Pipe clay.. 37.5 Kaolin 33 Felspar. . . . 16.5 Eaw Gypsum. . . . 13 Ground Porcelain 12 COLORS FOR ALL KINDS OF POTTERY. The color of an object is due to its action upon the light falling on it. When white light strikes an object, a fraction of the light is reflected from the surface, without alteration of its white- ness ; the remainder penetrates the surface and is decom- Xoosed, at an exceedingly small depth, into colored rays ; part of the colored rays are absorbed into the body ; the remain- der are reflected, and it is these which we see, and whose color we consider to be the color of the object. Hence the influence which the state of the surface of a body has upon its colors. This property of selecting certain colored rays, and re- jecting others, is possessed by metallic oxides in an eminent degree. When these oxides are disseminated through a white mass, they impart their color to the mass. Some ox- ides, and they are the most valuable, are stable in the pres- 35 ence of other bodies and of high heat ; the colors they im- part do not alter. Owing to these qualities, metallic oxides are commonly used, as coloring agents. Bodies are transparent, when the light spoken of above as entering the body, traverses it, and is transmitted beyond. Bodies are opaque, when the light which enters is quench- ed by the numberless successive reflections it undergoes at the surfaces of the particles of the body, and does not pass beyond. By disturbing the perfect contact of the particles, a trans- parent body is rendered opaque. Example : plate glass and glass ground fine. By restoring the perfect contact of the particles, by filling the interstices with a transparent substance, the transparen- cy is restored, more or less. Example : paper and paper oiled. Partial transparency is likewise obtained, by filling the interstices with a vitreous flux. Example : porcelain. The following colors are obtained with the oxides (and sometimes salts) of the metals named. Violet — Iron, manganese with soda. Purple — Chloride of gold with tin, chloride of silver. Black — Iron, manganese, uranium, iridium. Indigo — Of violet and blue. Blue — Cobalt, carbonate of cobalt, smalt or silicate of cobalt. Zinc brightens blue colors. Turquoise — Copper with soda ; cobalt with zinc and soda phosphate. Green — Copper, with or without antimony ; chrome with cobalt. Bronze green — Nickel. Zinc and its carbonate brightens all greens. Olive green — ^Nickel with cobalt. Yellow — Antimony, with potash or sulphide, titanium, chromate of lead, chromate of barytes. Zinc brightens yel- low. 56 Buff— The preceding with iron, sepia, sienna, ochre, um- ber, earths. Orange— Uranium ; sulphide of antimony with iron. Bed- Iron, iron sulphate, copper (oxidule), ochre. Carmine — Chloride of silver. Pink — Iron and chrome with potash. Brown— Iron, chromate of iron, manganese, with or with- out cobalt, ochre and hammercinder. Qrey— Iron, cobalt, iridium, platinum, titanium. White— White clay and 5 per cent, tin oxide. ■ In pottery, the colors are either (encaustic) incorporated in the body, or applied upon the surface of the body, which has been previously dried, half burned or fired to receive them, or introduced in the glaze, or applied over the glaze. Encaustic Colors. — Encaustic colors possess all the more brilliancy, the nearer the body approaches vitrification. The coloring oxides are introduced in quantities usually of 5 to 10 per cent., and sometimes 15 to 20 per cent. They act as fluxes and increase the fusibility of the mass. The com- position of the body must be altered in some cases to coun- teract this. When the body is fired at a temperature too low to develop the required color, or when it is not of a sufficiently vitreous nature, the color is fritted before being introduced, i. e., the coloring oxide, by the addition, for instance, of 18 per cent, calcined soda and 75 per cent, silica, is melted up into a glass. This glass is ground fine and mixed with the body m various proportions of i to | and § (see Jasper Ware). This colored body may be glazed, or first painted upon in the new opaque enamel colors and then glazed. Transparent colors cannot be used to advantage upon it. Colors under the Glaze.— The process consists in dip- ping the dried object in a slip of colored clay, formed usually of 1 colored glass ground and 2 of clay. The clay is introduced to procure the adhesion of the slip. The ware is then burnt, or, after drying, coated with a transparent glaze and then burnt. Subjects may be painted under the glaze, with more or less transparent colors, or with opaque enamel 37 colors. Before applying the glaze, all oily substances should be removed by a preliminary heating. Printing in colors under the glaze, is frequently done. Colors in the Glaze. — The ware is dipped in a trans- parent colored glaze. The glaze is frequently formed, besides the coloring oxides of: Oxide of lead from 40 to 50 per cent. Silicious sand " 30 " 40 Salt " 0 " 12 (see Earthen-ware). A. iQode of decoration consists in reserving certain parts from the colored glaze, by which the color of the body or the slip appears in those parts. This is done by covering the re- served spaces, not with oil, which spreads, but with melted tallow and wax, which solidifies on the spot. The ware is then dipped in the colored glaze, heated to expel the grease, and then dipped in a transparent glaze, which adheres to the reserved spaces. The appHcation of a colored glaze over a painting is very effective in harmonizing the whole. By stamping a depressed pattern in the biscuit, and glaz- ing, the pattern will appear in a deeper tone of glaze. Colors over tlie Glaze. — The colors are applied with a brush over the (once fired) glaze ; the ware is heated again to the melting point of the glaze, which in the melted state incorporates the colors, and appears more or less to cover them. To prepare the colors, one method consists in rub- bing the coloring oxides in water, to which gum, or sugar, is added to cause cohesion. Turpentine oil and its fat essence are more often used, also Lavender oil. Only colors which will stand high heat can be thus applied. In the case of hard porcelain, the colors melt sooner than the glaze, hence their opaque appearance, as the glaze does not cover them. Another method, applicable to all colors, consists in mixing them with substances (silicates, or borax) which when heated will give a vitreous mass, capable of unit- ing with the glaze or the body of the ware. 38 The colors thus obtained are transparent. When laid on too thick, they peel off. Colors that are volatile, vegetable and others, can not be used. Color printing can be executed over the glaze. Metallic Colors.— For gilding there are several meth- ods. The gold is fine, obtained by precipitation, and amalgamated with oxide of mercury or calomel to spread it. Sometimes gold leaf is rubbed in sugar, salt or honey, and applied. If the glaze is earthy, 8 per cent, of flux of oxide of bismuth, with a little borax, must be added to the gold. Silver is applied in a similar way. For platinimi, the metallic powder is fluxed with 10 per cent, of a boracic flux, and rubbed in oil on a glass plate. The gilding is applied with a brush over the glaze and re- quires high heat to fasten it; it must be applied and fired be- fore other colors. The gilding has a dead appearance until it is polished with agate instruments. There are other methods of gilding less permanent. In Egypt, graphite rubbed on gives a black pohsh. In India, gray and copper-colored mica, rubbed on the surface, gives a metallic effect. Lustres. — By coating the ware with a glaze, which fur- nishes a thin, adhesive, metallic film, the rays of light are decomposed into prismatic colors, producing a pearly, lus- trous appearance. (See Belleek Ware. ) The lustre may be transparent, as with the metals lead, zinc, alumina, bismuth, or colored, as with copper, man- ganese, cobalt, iron, uranium, nickel, cadmium, chrome. The transparent lustres are obtained by melting 10 metallic oxide or salt with 80 colophonium, and rubbing in 70 to 140 lavender essence. It is applied like a varnish. The large amount of carbon in lavender essence acts as an effective reducing agent to produce the thin deposit of un- oxidized metal in the glaze. The most brilliant effects are obtained by using the transparent with the following lustres : Copper lustre — Eubi lustre op Georgio — is considered to be silicate of protoxide of copper. Salvetat says nitrate of copper and a reducing gas will produce it. Or else, for 39 white enamelled ware, throw a paper containing, copper oxide into the muffle. Ueanium — MOTHER OP PEARL LUSTRE. — 10 nitrate of ura- nium, 30 colophonium, 50 lavender essence. Iron lustre. — Chloride of iron and solution of soda ; the deposit is rubbed in lavender essence. The lustre is red. By adding bismuth lustre it becomes golden yellow. Purple gold or Burgos lustre. — Dissolve in acid 25 gold, 5 tin ; mix with 50 sulphur and 20 essence of tar, and 50 es- sence of turpentine. Cantharides lustre. — A lead glass, with a little oxide of bismuth and chloride of silver, is appHed with the brush. The ware is fired ; when red, it is smoked. The lustres are brighter when laid over a brilliant glaze. To reserve certain spaces, wash off the lustre, by dissolv- ing with linseed oil. Printing in Colors. — To print on the glaze : The design is printed in linseed oil colors on damp silk paper. The paper is dipped in water, taken out, the excess of water absorbed, laid on the ware, which has been previously var- nished with turpentine oil and alum or copal, and a woollen roller or ball is passed over it. The ware is then fired. To peesit on the biscuit. — The colors are rendered more adhesive by glue. The paper is stronger and dipped in soap- water to prevent absorption of oil. Before laying the paper on the biscuit the parts not colored are cut out. The ware is heated to expel the oil, before glazing. Gelatine may be substituted to paper ; the pattern then is only printed in turpentine and nut oil, and the color in pow- der is sprinkled on it. preparation of coloring agents. Chrome oxide — from bichromate of potash calcined. Iron oxide — from iron sulphate calcined. Uranium oxide — from a blend by chlorhydric acid and ni- trate of iron, used as uranate of ammonia. Manganese oxide — found as such. 40 Zinc oxide — from a salt of zinc precipitated by carbonate of soda. Cobalt oxide — from a cobalt ore, roasted, treated by acids, and precipitated by potash carbonate. Antimony oxide — heat 2 of antimony and 5 saltpetre ; anti- moniate of potash results. Also from Naples yellow. Copper protoxide — from sulphate of copper, soda carbonate, and copper shavings. Copper peroxide — from nitrate of copper calcined. Tin oxide — from tin. The alloy of lead and tin oxidizes rapidly. Iridium oxide — from a solution of iridium, sal ammoniac, potash carbonate. Chloride of silver — silver nitrate, precipitated in the dark by chlorhydric acid. Purple gold — At Sevres, 3 gr. tin is dissolved cold in acid (4 nitric to 1 chlorhydric), and 1 gr. gold in acid. Diluted and slowly mixed. Or else, heat gold protoxide with stannate of potash. EEMAKKS. A remarkable pure blue, says Gentelle, is obtained by taking 2 parts of flux (composed of equal sand and lead oxide) and 1 part of color composed of 16 protoxide of cobalt, and 84 of the following precipitate : To a solution of soda phosphate in excess, add zinc sul- phate ; wash the resulting blue precipitate, which contains, when dried, zinc oxide 42, cobalt protoxide 13, phosphoric acid 33, water 12, and burns to a pure blue. For very white opaque enamels, the mixture of 200 oxides of lead and tin, 100 sand, 80 carbonate of potash, must be melted up and pulverized 3 or 4 times successively. When antimony is substituted for tin, the lead must be left out, or it would produce a yellow tint. This antimony enamel is better for blues and purples than the other. Clouet gives as the best : Glass, without lead, 300 ; borax, 100 ; saltpetre, 25 ; antimonium diaphoreticum, washed, 100. Colored slips for staining the surface of wares vary with 41 the colors. For common blue and green, some 7 per cent, lead oxide is introduced, while it is left out in others. Thus, for red, ochre is rubbed in water ; for violet, 1 sand, 2 potash, yV manganese, are fritted and mixed with thrice their weight of white clay ; for yellow, 1 sandj 2 potash are fritted, and 2 white clay is added. DECORATIVE TILES FOR FLOORS, WALLS, ETC. The variety of tiles come under the following commercial classification : 1. Plain Tiles (self-colored) made by pressure from dust clay. "With different colored pieces geometrical patterns can be formed. 2. Encaustic (figueed) Tiles, having a flat surface with the ornament inlaid, or slipped in various colored liquid clays. These two may have their surface covered with a transparent glaze. 3. Enamelled Tiles, that is, plain tiles having their sur- face covered with various opaque and transparent colored enamels. 4. Majolica Tiles, having the ornament in relief, the em- bossed ornament and the ground being covered with various colored enamels. (Palissy ware, more properly speaking.) 5. Earthen-waee Tiles in plain colors, glazed. — These may have their surfaces decorated by printing or painting. PLAIN" TILES. These tiles, made from colored dust clay by a sort of coin- ing process (see Tile Presses), are capable of being highly decorative when well made, and are a good instance of the pleasure arising from mere perfection of material. The clay or mixture of clays used is usually reduced to a fine powder and made slightly damp before pressing. (See Encaustic Tiles and Colors.) 42 ENCAUSTIC TILES. Encaustic tiles consist of a slab of clay of uniform color, inlaid witli a device of other clays differently colored. In this ware the colors are not superficial, but are incor- porated with the body of the clay before burning, either by pugging dry or in the condition of a liquid slip. As to the different coloring ingredients : — Many of the clays which contain less iron, such as the Stourbridge and others in proximity to the coal measures, do not come out of the fire red like brick, but white, cane or buff in all varie- ties of tint, and stand the attack of fire and weather. Eed, salmon and pink will be produced as the iron pre- dominates, altered by mixtures of other clays in their native condition or by oxides of metals. Nickel, for instance, pro- duces a bronze-green tint ; manganese brown ; protoxide of iron and manganese dead black. Carbonaceous matter gives a dark, dull-looking and rather dirty tint, which may be useful in contrast. There is no end to the variety of tints which can be ob- tained by the admixture of earths and metallic oxides. (See Colors.) To economize the inlaid colored clay material, the tile is only formed of it to the depth of about 5 of an inch from the surface, the mass of the tile being made of fire-clay. As, however, the fire-clay generally contracts very differently from the surface layer of colored clays, it is usual to apply to the back of the fire-clay, an equal thickness of about I of an inch of the colored clay, in order to preserve the flatness of the tile during the firing. The tile is made with the aid of a press, either by the wet or dry process. (See Tile Presses.) By pressing many small holes in the back of the tile, the drying is facilitated, and also the adhesion of the mortar when subsequently used on the wall. The tiles are dried for a week, then heated in a drying oven for two or three weeks, fired in a stone-ware oven for sixty hours, and left in the oven for six days more, to cool down. The lineal contraction during these operations amounts, in the wet pro- 43 cess, to twenty -nine per cent, of the size of the tile when first moulded. It is less in the dry process. For glazes, see Earthen-ware and Colors. ENAMELLED TILES. The bodies are the same as for plaia tiles, which have at most a transparent glaze, while the enamelled tiles are sus- ceptible of great variety of decoration, by the application of transparent or opaque colored enamels. By reserving spaces (by oiling or otherwise) and dipping the tile in a slip, or by direct application of the enamels, simple and effective results are obtained. For the enamels used see Majolica. MAJOLICA AND MAJOLICA TILES. The different varieties of Majolica are more easily appre- ciated when its history is recalled. The almost total extinction of the arts and sciences which followed the fall of the Roman Empire, left Europe with only the rudest knowledge of the potter's art. The Moors brought with them into Spain, in the eighth century, much of the science and knowledge of the East ; but it took sev- eral centuries for the arts thus introduced to spread over other parts of Europe. The enamelled bricks and tiles of the Moors were of superior taste and coloring, gilding was skilfully used, and the enamel possessed a yellowish lustre of peculiar brilliancy. Their bricks (azulejos), as in the Alham- bra, were formed of a light-colored clay, covered with an opaque white glaze upon which Eastern patterns were traced in colors. This manufacture was continued and is still kept up in Spain. In Italy, the art of Pottery, which attained its height during the fifteenth and sixteenth centuries, was introduced in the ninth century by the Moors of Spain and also by Byzantine Greeks. In 1115, an expedition, fitted out from Pisa, conquered the island of Majorca, and brought back as 44 spoils tlie bricks and tiles of tlie Moors, thenceforward called Majolica. The earliest known specimens of Italian majolica presented an arabesque pattern painted in yellow and green upon a blue ground and possessed a yellowish chromatic glaze. The red clay, which formed the body of the ware, was moulded and burnt, then dipped in a white opaque enamel, consisting in oxide of lead, oxide of tin, and a very white earth from Sienna. When dry, the pattern was painted on it, then washed over with a thin lead glaze and burnt a second time. From 1450 to 1530 the product is distinguished as mezza- majolica. The outline of the figures were traced in blue upon a black or white ground, and the draperies faintly col- ored ; there were no shadows and the flesh parts were not colored, and the whole was covered with a chromatic mother- of-pearl like glaze which imparted a golden and silvery lustre to its yellows and whites . Under the house of Urbino, the manufacture of mezza-majolica flourished at Pesaro and at Gubbio, where its chief artist, Georgio Andreoli, first applied a transparent ruby-colored lustre, which, with the previous golden and silvery tint, produced a lustre like burnished cop- per, and particularly brilhant over a blue ground. At the beginning of this period, the sculptor Luca della Bobbia (born 1400, died 1481), after many trials, discovered that by increasing the proportion of oxide of tin in the glaze, a hard opaque brilliant pure white enamel was produced, which he applied upon terra-cotta statues of Madonnas and saints, and architectural ornaments, and abandoned the pre- vious chromatic characteristics of the ware . His principal decorations were in white, over a blue ground. Several years after his death, this glaze came into general use at Faenza, and at Florence, whence the name of faience, which is now applied to earthen-ware covered with a white enamel. From 1530 to 1560, the artistic character of majolica at- tained its highest point, and designs of Raphael and his scholars were frequently used. After 1560, its utility had 45 been so far sacrificed to decoration, that it rapidly died out upon the introduction of porcelain. The manufacture of majolica was carried into Germany by Hirschvogel, who went, in 1603, to Urbino to learn the art, and on his return, erected a manufactory at Nurnberg ; but Ger- many possessed enamelled earthen-ware factories before then, and in Holland the potteries of Delft were already cele- brated. The manufacture of faience passed into France with Catherine de Medicis, and the Duke of Gonzago erected, in 1570, a majolica manufactory at Nevers, which was so suc- cessful that its products are hardly to be distinguished from the original majolica. Considerably prior to this, however, the potteries of Beauvais were already known in the 12th century ; and in 1555, Bernard de Palissy had discovered for himself the art of enamelling a gray paste. The originality of his decorations, and the skill and humor shown in the modelling, give particular value to his majolica ; but his art, which he kept secret, disappeared with him, until its re-in- troduction from Italy in 1570. The French Henry II. ware also preceded the introduction of faience into France. In England, delft ware and colored enamelled tiles from Holland were already imported at the time of Henry IV. The modern revival of majolica there, is due mainly to the labors of Mr. Herbert Minton. In imitating the azulejos of the Alhambra, he was very successful. The tiles of earthen- ware are burnt, then covered with an opaque white tinny glaze, upon which the outlines of the decorations are dis- tinctly traced, and filled in with a thin coat of enamel of various colors, and again burnt. Anihne colors may be used to imitate enamel. The Palissy ware, formed of embossed biscuit covered with transparent glazes of various colors, is frequently called majolica, although this term should properly be reserved for biscuit (i.e., burnt earthen-ware) coated with an opaque enamel. The majolica of Messrs. Minton & Co. differs in many respects from the modern Italian, French, and Dutch varie- 46 ties, as well as from the old majolica. The continental ware is formed of limey clays, consisting for white faience of 58 silica, 35 alumina, 7 carbonate of lime ; and for brown fai- ence, of 57 sihca, 38 alumina, 5 carbonate of lime. The Hme solidijfies the body, makes it more liable to crack over the fire, but facilitates the adhesion of the enamel, by partly melting with it and imparting to it a fat, glossy ap- pearance. Other faiences and old majolicas contain (Pich- enot, etc.) 13 to 22 per cent, of lime, and 1 to 14 per cent, of carbonic acid, the temperature required to fire the biscuit not being sufficient to expel all the carbonic acid. (Palissy ware contains only 1.5 lime.) The silica and alumina are usually in the proportion of 2.5 or 3 to 1. In England, the fire-clays used come from the coal forma- tion, contain no lime, are fired at a higher temperature, and produce a denser, harder biscuit, generally of a buff color, but the enamel is less glossy. Its greater power of resisting fire allows of its embellishment with several colors, such as turquoise blue, Chinese yellow, and crimson, requiring great heat for their development. The colors and glazes of Messrs. Minton are of remarkable excellence. Others excel in artistic designs. Knausz gives the following opaque white enamel : Oxide of lead 23.6 Oxide of tin 15.6 Silica 43.5 Alumina 1.7 Oxide of iron 0.5 Lime 3.8 Magnesia 1.6 Alkalies 10.0 The enamel may be fritted, i. e., fired once to a melting heat (about 70° W.) and ground fine. A sudden immersion in water while hot facilitates the grinding and heightens the lustre. Part or all of the coloring metallic oxides can be added after this firing. The relative proportions of oxide of lead and oxide of tin 47 vary. An increase of the lead gives a thinner, more trans- parent, fusible, and brilliant enamel, which sinks too much into the ware under high heat. An increase of the tin gives a whiter, harder, thicker, and less fusible enamel, of greater covering power. Frequently there is 2 to 4 times as much lead as tin. In white enamel these oxides constitute together 39 to 48 per cent, of the enamel ; the remainder consists of 43 to 47 silica, with 3 to 8 common salt, and 2 to 3 of soda. Sometimes a trace of lime. When required to stand a high heat, the silica should be of the cleanest quartz sand. In Germany the mixture of oxide is obtained by melting 100 lead with 50 sheet tin, in contact with the atmosphere. For colored opaque enamels 90 to 97 per cent, of the white enamel is mixed with 10 to 3 per cent, of coloring metallic oxides. Stanniferous enamels have sometimes, after a lapse of time, a tendency to peel off, owing to want of affinity of the sili- cates of lead and tin for the body of the earthen-ware. The melting point of the enamel should correspond to an inci- pient softening of the body, when, by a tendency to absorp- tion, it will adhere to the ware. If the enamel is too fusible, it will be too thoroughly absorbed by the ware, and lose its lustre. If wanting in affinity, it will collect in separate drops on the surface, which fall off later. The expansion and contraction of the enamel must approx- imate closely to that of the body, or numerous cracks will result. These occur also when the glaze is too thick. If the enamel is too refractory, it will be defaced by cavi- ties and points showing only a partial fusion. Phosphate of lime can be introduced as a whitening, and, until fluxed, infusible ingredient. Majolica tiles are better for walls, and not so good as encaustic tiles for floors. 48 EARTHEN-WARE TILES IN PLAIN COLORS, GLAZED. They may have their surfaces decorated by printing or painting. By dipping the earthen-ware tile in a slip of white or colored clg,y (see Colors under the Glaze) a smoother and differently colored surface is obtained for the decoration. The transparent glaze is colorless or diversely colored (see Colors in the Glaze). It should not be crazed. Also, spaces may be reserved from the slip or the glazes. The Persian patterns of Minton & Co., on a Persian body or slip, for wall tiles, are admired for transparency and the turquoise blue. DESIGNS FOR TILES. It is generally admitted that flat treatment is the most appropriate for floor designs. Startling contrasts of form or color, which attract our attention to the exclusion of almost everything else in the apartment, fail to produce a harmo- nious effect. Rich and full colors can be so combined as to produce a quiet and unobtrusive pattern. Any design presenting the appearance of inequality of sur- face is more objectionable in tiled floors than in carpets even, from the greater rigidity and hardness of the material. Picto- rial imitation seems a waste when destined to be trodden upon. The best result is perhaps observable when a pattern upon a ground of a simple color, or of non-contrasting colors, is used to give repose. The combination of many colors in one pattern is, of course, attended with much greater diffi- culties than the use of a few, as among all the possible com- binations, the concords are much fewer than the discords, and not likely to be hit upon except by careful study. The pleasing effect of Oriental patterns is instructive in this re- spect. Success seems more easily attained when the patterns are distinctly grouped and ornamental borders added. The richness of the material should not be concealed by profuse surface coloring, but rather brought out by distinct encaustic colors. 49 " The attempt to make each tile a decorative unit, and to multiply it over the whole floor, is rarely satisfactory. Forms of this kind occurring over large spaces are likely to prove very tedious to the eye The decoration of the floor must depend upon the use of the apartment. Large and somewhat empty entrance halls call for more pronounced treatments ; aspect and use also must determine whether the floor should be cool or warm in its coloring." — (Redgrave.) For wall tiles, breadth and quiet are more desirable even than for floors. A design producing diagonal lines, or hori- zontal lines, is not as good as vertical lines. Messrs. Minton's Persian designs and Maw & Go's Eosette patterns are particularly admired. TESSERiE.-MOSAIG BRICKS. TesserfB or blocks for mosaic brick are made by a machine exhibited by M. Hollins & Co. The small squares are made by this process in a diy condition. Formerly the clay was wet when shaped, which caused many of them to warp, as they dried before baking. They are now formed of dry- powdered clay, stamped together with great force in small moulds, so that the particles adhere together. Minton & Go's stamping press for producing mosaic bricks, makes slabs from 1| inches square, used for flooring tiles, down to the minute pieces used for delicate mosaics. It is a vertical screw press ; dies of the required shape pass through openings in a circular metal table, into matrices below. The clay finely pulverized and colored by difi'erent pigments, as desired, is heaped upon the table, and a small portion is swept into the matrices by hand at each downward stroke of the press. The cubes are arranged and dusted, and then baked. The heat vitrifies them, and they appear with an opaque glazed surface. Various pigments are adedd to the clay. The picture is made by reversing the tesserae and gumming them on a board ; the back is then covered with a cement composition, and the board taken away from the face. 50 The clay is not that used at tlie Potter's wheel, nor the same as is used for fine china. It is "Cornwall clay," a white substance obtained along the edge of a granite forma- tion, where the rock has been oxidized and disintegrated for ages by the atmosphere. The thickest veins are to be meas- ured in inches. When this disintegrated granite has been obtained, the particles of mica and other impurities are washed away, and the residue of converted quartz is " Corn- wall clay." (For fine china, there is in England an addition of bone dust and other ingredients.) This clay, when baked without the addition of coloring ingredients, forms pure white earthen-ware, of which material the tesserae are made. TERRACOTTA. Terra-cottain its application to architecture still has its ad- vocates and opponents. When properly manufactured it is one of the most durable materials which can be employed ; but, like stone or any building material, it requires inspection before use. Very fine specimens of terra-cotta made in London one hundred years ago, and exposed to the weather since, are Btill perfect. In Northern Italy many fine examples of brick and terra-cotta exist, and the extensive revival in England and Germany of this method of building, is worthy of note. The strength of well made terra-cotta is surprising. A piece of four-inch column, made by Jas. Pulham, and tested at the 1851 Exhibition, required a pressure of 400 tons to the square foot to crush it, or as much as good granite, and two to three times as much as most building stone. In a paper recently read at the Architectural Conference in London, Mr. C :barry gave some valuable results of experiments on terra- cotta, showing the crushing strength of this material to be seven and a half times greater than that of average brick. The difficulty of obtaining a really durable buHding stone, is well known to architects, and practical experience is re- quired in its selection ; architects do not agree, some prefer- ring limestones to sandstones, others sandstones, nor is it 61 settled which are the best beds. Stone varies much in every quarry ; an instance in point is the Geological Museum in London and the Houses of Parliament, both of the same magnesian limestone ; the first lasts well so far, but the latter is rapidly decaying, and many protecting coats have been tried upon it, to arrest decay. The test of the amount of water absorbed, is conclusive neither for terra-cotta nor for stone, as some materials ab- sorb more water, and yet withstand frost better than others, owing to their great cohesive strength. The quality of a stone is so difficult to discover, that the most durable stones are not unfrequently rejected. Even granites are not all durable, particularly those with a soapy fracture, which, by weathering, decompose, and furnish the china and pipe-clays so extensively used in the industries. The difficulty of finding a material that will stand heavy frosts is seen in St. Petersburg ; the Alexander Column, a granite monoHth 84 feet high, is split in several places from this cause, and in the public monuments some of the largest granite blocks are rent in two . In erecting large buildings it is difficult to supply quickly enough stone of a durable quality from one quarry. Nearly all stone is not fire-proof, but cracks when exposed to high heat. These causes, without deprecating the use of stone, point to the desirabihty of finding a durable fire-proof building material, which can be relied on always and supplied in large quantities. This presents an opening for the use of terra- cotta — a material which has stood the crucial test of firing. A simple test of the texture of terra-cotta is the point of a pen-knife, which should not penetrate the surface, and will sometimes strike fire upon it. A clear and bell-like ring is also an evidence of homogeneity and compactness, and a clean close fracture shows strength. The texture of the body and tlie precision of the forms are further indications of ac- curate firing and homogeneous material. The true qualities of terra-cotta in its application to archi- tecture consist in its merit? , as a, decorative fire-proof material, 52 spbssessing the three essentials of color, durability, and econ- omy. When treated with due regard to construction, so as to '^fulfil its part in the building as honestly as the brickwork of the wall itself, the high capacities of the material to receive artistic treatment admit of the impress of original art being reproduced for the uses of the architect, in an almost im- perishable substance. Fine works in hard stone are exceedingly difficult of execu- tion, and in soft stone soon crumble away ; the labor of the artist may be saved by taking a mould of his work, and re- producing it in terra-cotta as often as may be required ; in- deed, the great economy in the use of terra-cotta lies in producing a great number of articles of the same pattern. Where original art is required, the subject can be modelled in the actual terra-cotta clay, and passed through the kiln, from which it issues an original work of the sculptor, with- out the intervention of mechanical copying, moulding, point- ing, or carving. Modern examples of the extensive use of terra-cotta are seen in the Dulwich School, (from designs by C. Barry, Jr.), costing $500,000, and accommodating 700 boys ; the Ken- sington and other Museums ; various hotels and stores, and the great Albert Hall, which cost one million dollars. This building is of brick and terra-cotta, contains seats for 8,000 persons, and is capable of accommodating 16,000 without discomfort. The mMe structures, decorated in stone, would have cost much more. An example of successful decoration is the permanent brick and terra-cotta arcading at the International Exhibition. In the successful use of these materials, the architect, Col. ' Scott, deserves praise. TERRA-COTTA MATERIALS. Terra-cotta, or literally " burnt clay," would seem from its name to be very simple in its manufacture; yet to produce a material as strong, more durable, and less expensive than 58 stone, requires an exact scientific knowledge of the properties of many varieties of clay, and accurate observations upon their behavior in the oven. The improvements visible in many species of ceramic pro- duction, may be attributed to the increasing regard paid to the chemistry of the manufacture and the physical phenom- ena involved. In the same way, success in terra-cotta is in proportion to the exact experimental knowledge possessed of the natural properties of the various clays ; for there is no such thing as a terra-cotta clay, ready for use under condi- tions that are always applicable. By judiciously selecting and combining different clays, the best results are obtained. We will, therefore, review the natural materials which the , manufacturer of terra-cotta has to choose from. Pure clay — the hydrous silicate of alumina of chemists- is absolutely infusible in the greatest heat to which we can subject it. But pure clay is rarely found in nature ; it is usually combined with other substances. The common clays consist of silicate of alumina in coarse admixture with sand, lime, iron, carbon, alkalies, and not unfrequently much organic matter. The variety found in the composition of common clay is not surprising, when we ex- amine its origin, and see that it results from the decomposir tion of felspathic rocks and soils by weather and water, and is found lining the banks of rivers and the bottom of valleys ajid seas. Nearly all the common clays contain much lime , andiron, and are fusible at an ordinary furnace heat. The better varieties are soft to the touch, but want unctuosity. Some of these clays are adapted to brick-making ; they^ are the brick clays, and consist of silicate of alumina with admixture of silica sand, which is essential, and may even reach a proportion of 90 per cent, of silica, and still formi excellent brick. Silica in the mealy state is injurious to clay. intended for brick-making (excepting Bath brick). Also^ any considerable quantity of lime, iron, potash or soda, is unfavorable, and in a good brick clay there should not be> more than two per cent, of limei or potash, for these sub- 54 stances cause the brick to run into glass when in the kiln. Fire-clay is a variety that will bear intense heat without meltin^T in the kiln or in furnaces. The fewer different ele- ments it contains the more infusible it generally is, following in this respect the rule applicable to metallic alloys, which are fusible in proportion to the greater number of different elements they contain. This rule, which is not absolute, also accounts for the melting qualities of fluxes in general, and is applicable to common clays. The alkaline earths, iron oxide, etc., which would help to form a flux, are therefore absent in fire-clays. Many excel- lent varieties of fire-clays are found in the coal measures, and they usually result from the decomposition of the older rocks, exposed at the time of the coal period. They often contain carbon and hydrocarbons. Pottery clays are more compact, unctuous, and plastic than brick clays ; they are very tenacious and ductile, and form with water a semi-translucent mass. When pure they are practically infusible and burn white. They contract much in burning, as they part with their water only under exposure to the furnace. The more oxide of iron they con- tain the deeper is their red color after burning, and the more fusible they are . They contain ten to twenty per cent, of water, and very little lime or magnesia, while the remainder is silica and alumina, in proportions varying from two to one, to equal parts. Pottery clays seem to result from a natural separation of the objectionable parts of common clay, by the action of water and long exposure to the weather, and are found in deposits. Pipe clay is a variety of potter's clay, containing very little iron, and, like china clay, is formed from the decomposed fel- spar of certain granite rocks, either by natural or artificial washing. In terra-cotta manufacture, one of the most important clays is the potter's clay from North Devon and Dorsetshire (see Fire-Clay Analysis) ; the neighborhood of Poole sup- plies the great Staffordshire potteries, the " stone-ware " pot- 55 teries of all parts of England, and even the Continent. These clays contain a small percentage of alkalies. Also the clays of the coal measures, technically known as ** fire-clays," are greatly employed. In the terra-cotta manufactures of the North of England and Scotland, the purest lumps of fire-clay are selected by their color and texture, and used alone without any other clay, while the firms near London prepare more carefully a mixture of clays, which produces a body of better texture. The precise mixture of clays used varies with the appear- ance aimed at for the terra-cotta, and in this respect manu- facturers appear to seek different results. Some try to ob- tain the texture and pale straw-color of stone ; others a red brick color ; others again a warmer buff tint. There seems to be in every case advantage in using a mix- ture of clays, as 1a more compact, homogeneous, and better vitrified body is obtained, although at the cost of extra labor and care. One of the chief difiiculties met in manufacturing terra-cotta figures and ornamental works is the contraction the clay suffers after it has left the mould — first, in drying, and still more in the subsequent process of firing. By mix- ing the clays, a further advantage is gained in the diminished shrinkage, as fire-clay terra-cotta (i. e., unmixed) shrinks in lineal dimensions about 12 per cent from the time it leaves the mould until it leaves the kiln ; the mixed clay terra-cotta shrinks 6 per cent or less, and red clays shrink 3 per cent. To enhance the durability of the body of terra-cotta a par- tial vitrification of the mass is aimed at, by adding clays which, like the Dorset, contain a small amount of alkalies, which act as a flux to fuse the body harder. Also vitrifying ingredients, pure white river sand, old fire- brick ground fine, previously burned clay, called " grog," are added in various proportions, amounting even to twenty- five per cent. They counteract excessive shrinkage, act as vitrifying elements, and keep the color lighter. The efflorescence of the alkaline salts in the clays, acting on the silicates of the surface, tend to vitrify more particu- larly the exterior of the block, and to form a harder surface, which should be left intact. MANUFACTURE. The mixture of clays is ground under an edge runner to the consistency of flour. The mills have either revolving or stationary pans ; the former do the most work. In order thoroughly to mix and incorporate the different clays, a subsequent careful pugging is required, for which hot water is sometimes used. The mixture, when brought to the proper homogeneous cjon- sistency, is placed in a plaster mould, withdrawn, dried near the kilns, or otherwise, and baked in a kiln for 5 to 7 days,^ dxiring which time it is slowly brought to a white heat, and as gradually cooled down again. There are several varieties of kilns, such as th^ Hoffman kiln, which serve for terra-cotta and stone-ware. They are improvements only to the extent which they economize fuel, disseminate the heat uniformly, and allow of its perfect gra- dation to any desired degree. In order to avoid twisting and warping during the firing, it is necessary, besides complete mixing of clays, that the mould be shaped so as to give a uniform thickness of mate- rial throughout, and if the temperature of the kiln be well graded, the homogeneous body will not warp. To cheapen terra-cotta building blocks, they are made hollow, and filled, during the construction, with concrete or cement. Although in the kilns the products of combustion are separated from the wares, it is found that the use of sulphur- ous fuel darkens and tarnishes the surface, and it is to be avoid© DESIGNS. In treating the clay material, several fundamental princi- ples may serve as guides. In the design of an object, construction has the first claim upon our attention, and utility has precedence of decoration. T^his requires a study of the strength of materials, and where- 57 it has been neglected, as in some of the architectural pottery exhibited, the result is a prevailing sense of weakness. The general form of a piece having been determined on sbund constructive principles, its details remain to be com- pleted, in a manner that will make the object ornamental in the position it is destined to occupy. It is essential that the ornament should harmonize with the purpose of the ob- ject. This part of the design requires an artist for its execution ; the schools of design throughout England, of which there are 110, have been largely used to procure these designs, by premiums offered and competitions. In the representation of objects taken from nature, it is an efror, for decorative purposes, to attempt an exact imitation of the natural object ; the forms should be conventionalized and adapted to the material dealt with, in a way to bring out fully its true nature and qualities. The rale of not attempting to conceal the true material, arises from the pleasure which mere merit of material affords, and from the general unsatisfactory effect of all attempts at imitation. The imitation of stone in terra-cotta is an error for which manufacturers are less responsible than the buyers who re- quire it ; but the majority have happily avoided this extreme. When the pale straw stone color is produced by the addition of ingredients whose object is to increase the vitrification of the body, it is perfectly legitimate. The rich buff color of terra-cotta is usually considered the most pleasing ; it requires twenty-four hours longer firing. Although more difficult to obtain uniformity in tint, when produced it is good evidence of hard firing and homogeneous material. KEPRODUCTIONS. One of the advantages of terra-cotta is the facility with which it lends itself to the reproduction at home of features of architectural merit, wherever found in distant countries. By taking on the spot a plaster cast of a detail of cornice, bracket, column, or other object, and sending this cast from 68 abroad, it may be used for the reproduction of as many similar objects in terra-cotta as the architect requires for a new building. A practical difficulty is met in taking many casts from one plaster cast, as it requires some skill, and deteriorates the model. This difficulty is overcome by the process of gelatine moulding, as follows : The plaster model is coated with oil and soap, to prevent adhesion, and covered with a canvas for protection. Rolls of modelling clay are then laid on over the canvas, until the whole surface is covered to a suitable thickness, say 4 to 6 inches ; and against this a plaster coating or wall is built up, in, say, two parts, to form a backing for the mould. The two parts are then opened, the canvas and clay are taken out and thrown away, the two parts are replaced, and a hollow inter- val of the thickness of the clay will exist, into which hot liquid gelatine is poured. After twelve hours, the gelatine will have attained a semi-solid elastic consistency, which will allow of the mould being opened, and the gelatine impression peeled from the face of the model. The gelatine impression is replaced on the plaster wall which previously supported it, and a plaster cast is taken from it. From the latter, about four terra-cotta reproductions can be made without sensible deterioration. The advantnge of gelatine is that it re-produces minutely without deterioration every mark of the plaster model ; its elastic nature makes it especially useful for " undercut " carv- ing, as it yields while being released from the cut, and im- mediately again resumes its shape with perfect accuracy. The process as now used, for instance, for the reproduction of 64 brackets of the New Museum, Kensington, works ad- mirably. USES OF TERRA-COTTA. This material finds a ready application to architectural dec- oration, especially in connection with brickwork. It is used for : String Courses, Cornices, Vertical Separations, Terminals 59 for walls, Window Heads, "Window Mullion Tracery, Key- stones, Wall Copings, Pier Caps, Capitals and Bases of Col- umns, either in connection with marble or granite columns, or of terra-cotta columns plain or twisted, Friezes, Bas Ke- lievos. Figures and Busts, Medallions for insertion in walls Festoons, Chimney Pots and Chimney Shafts, Ventilators and Ridges. Ornamental and Plain Facing Tiles and Building Blocks, from 1 to 4| in. thick, formed into Quatrefoil and other Panels, Chequered and Vermiculated Eustics, and Diaper Work. Fire-proof Ornamental Stair Cases with Newels and Balus- trades, perforated or plain Risers, and inlaid with Majolica and other Tiles . The strength of terra-cotta gives it partic- ular value for this purpose. Garden Decorations of all kinds. Fountains, Basins, Bal- ustrades, Bridges, Tazzse, Vases, Pendant Flower Baskets, Ferndelabras, Garden Stej)s, Statuettes, Garden Edging (fixed so as not to get displaced by digging), made also with Encaustic Tile Panels, Horticultural appliances, and Window Flower Enclosures. Ornamental Conservatories, Lodges, Summer Houses, Aviaries and Dairies. Mural and other Monuments. (See list of Exhibitors.) STONE-WARE. In the fifteenth and sixteenth centuries, stone-ware, charac- terized by its dense, opaque, vitreous fracture and imper- meable and refractory nature, was already abundantly manu- factured in Germany and Holland, whence the industry was imported into England, and encouraged there by Queen Elizabeth. The materials made use of in England are the refractory white and greyish plastic pipe clays of Devon and Dorset- shire (see Fire-Clays), which are used, alone or mixed, for small articles. For larger objects, white river sand, ground 60. fire-bricks and flint are added to counteract shrinkage and warping. Salvetat's analysis of stone-ware shows a composition of; Silica from 62 to 75 per cent. Alumina " 19 "29 " Iron oxide " 1 "8.5 " Lime " 0.25" 1.0 " Magnesia " 0 "0.9 " Alkalies " 0.5 " 1.5 " The shaping of large masses, such as tanks to hold several hundred gallons, takes place on the potter's wheel. A diffi- ciilty arises from the length of time (some ten days) required to build up a tank, in the unequal drying of the parts first formed. This is counteracted by wet cloths wrapped around them. While drying subsequently for ten days, it is protected against unequal currents of air. More intricate forms are made in plaster moulds. The heat required is greater than for terra-cotta, above the melting point of silver, and is one of the highest required for any kind of pottery (100° to 120° Wedgwood). The texture of the body produced is more vitreous and dense. The man- ufacture of terra-cotta and stone-ware are advantageously carried on together, as the refuse materials from the one can be used in the other, and the less heated story of stone-ware kilns, used for terra-cotta. The consumption of fuel is a heavy item and depends largely on the kiln. In some, the Siemens regenerator is applied. In Germany, Bosch's oven is considered economical. The flame enters through apertures at the sides and centre of the floor, is reverberated, descends through other openings in the fldor, and reascends through upright flues at the circum- ference, to a central conical chimney. The objects remain about ten days in the oven, in some cases three weeks. Bonnet recommends the following refractory concrete for introduction in oven walls as a separating lining to retain 61 heat: "Mix 2^ parts clay, 1| river sand and pebbles, 1 un- slacked fat lime in powder ; water slightly and ram well." The ware is usually glazed, although its imperviousness does not require it, for better protection and smooth appear- ance. The glaze is either a salt glaze or a liquid glaze. The salt glaze, which is the cheapest, is applied when the ware has nearly reached its highest temperature in the kiln ; the fire is then managed, and when the right temperature is reached, common salt is thrown uniformly with shovels through holes at the top of the kiln. A moderate sized oven requires about 150 lbs. salt. The steam in the smoke de- composes the volatilized salt into chlorhydric acid and soda, which unites with the silica of the clay, and forms a thin film of soda glass on the surface of the ware. Silicious clays take the glaze best and become the most lustrous. When nearly half the salt has been thrown in, the fire is increased for a moment, then again reduced and some of the specimens examined. Then the remainder is thrown in, part at the top and part over the fire. All openings are then carefully closed and the oven cooled off for four or five days. The liquid glaze, containing oxide of lead, clay, and fel- spar, sometimes borax, and diversely colored by metallic ox- ides, is applied by dipping the vessel in it before burning. This constitutes the Bristol ware of smoother surface. Berthier mentions a glaze containing : SiHca 56 per cent. Alumina 7 " Lime 21 " Magnesia , 1 " Oxide of iron 12 " Oxide of manganese 3 Ground cinder, and slag from iron furnaces and mills are sometimes used. Potash, saltpetre, soda, basalt powder, have been recom- mended. The glaze is applied sometimes on the inside of vessels m only, as making them less liable to crack under alternations of temperature. At Quimper, a felspathic body is used, and the glaze con- tains no lead, as follows : Sand, 62 ; carbonate of soda, 20 ; kaolin, 8 ; lime, 8 ; borax, 2. Felspar, when introduced, opposes shrinkage, less flint can be used, it is easier ground, and the firing requires less heat. The washing of impure kaolins gives a fusible felspathic sand, which may be used. Felspathic bodies have an affinity for boracic glazes. The stone-ware on exhibition is remarkable for the perfection to which the industry has been brought, and the new practical uses to which this^ material is put with advantage. The machinery used is represented only by two potter's wheels, several crushing machines, and Boulton's patent jigger. Drain pipes up to 30 inches in diameter are made by forcing a piston by steam or otherwise through a mass of clay enclosed in an iron box, in the bottom of which is an opening of the exact external section of the pipe. The sock- ets are afterwards added on by hand. Siphons and intricate fitments are made in moulds. The water cisterns, acid pumps and tanks, distilling appa- ratus, egg-shaped sewer pipe, Doulton's lipped invert-blocks for sewers, with channels to separate the surface wash from the sewage when the latter has to be pumped in order to utilize it ; a revolving churn, said to act rapidly ; pipes to be built up in towers for the storage of muriatic acid, are all worthy of particular mention. (For further details see list of Exhibitors.) The impermeability of the material, its power to withstand the action of most acids, and, to some extent, of sudden changes of temperature without cracking, and the possibility of grinding the surface perfectly true, are its chief qualities for these uses. Stone-ware and earthen-ware manufacturers will be inter- ested in the following account from the Staffordshire Adver- tiser, of the New Over House Manufactory, Burslem : "It stands upon about an acre of ground, and all the buildings are en suite — that is to say, from the clay bank to 63 the pacldng-house all the processes are carried on in build- ings which are arranged in consecutive order. This leads to a great economy of space, time, and labor. Commencing at the slip-house, we found the machinery arranged in two stories, and driven by a 30-horse power engine, supplied from two boilers fitted with smoke-consuming doors. All the materials required are ground upon the premises, and there are two 24-chamber clay presses in constant operation The slip-house communicates direct with the clay workshops, a range of buildings 143 ft. by 27. On the ground floor occur the throwing, turning, and handling shop, the throwers' hot- house, and the flat-pressers' workroom. It is in these de- partments that some of the most ingenious and useful of recent scientific inventions appear, and for these, producer and consumer (for the benefit is shared by both) are indebted to the engineering ability of the patentee, Mr. Wm. Boulton, of Burslem. For the first time, Mr. Boulton has applied a new invention to the throwers' wheel It is exceedingly ingenious, and is under perfect control by means of a treadle. In the flat-pressers' room, there are 12 jiggers and 2 whirlers driven by a supplementary engine of 6-horse power. The whole of these appliances are worked by an invention of Mr. Boulton, which may be thus described : An endless band passes down each side of the workshop under the floor, and is operated upon by means of two descriptions of grooved pulleys. There is beneath each jigger a driving pulley, and there is also nearly opposite to that a friction pulley, and this lattet IS attached to the upright spindle which communicates the motive power to the jigger. When the workman desires to set the jigger in motion, he presses his left leg slightly, and after a time, almost involuntarily, against a lever, which action has the effect of curving the endless band, and bring- ing it into contact with the friction pulley. The jigger, of course, revolves at once, but the workman, by means of the lever just mentioned, has the speed under complete control, and can regulate it to the greatest nicety. If necessary, ai treadle can be used in place of the knee lever. By this inven- tion the workmen are delivered from the annoyances insep- 64 arable from the employment of unpunctual and inattentive boys as jigger turners ; there is also a moral and physical advantage as compared with the old plan of engaging women to work the treadles, and assist the workmen . Provision is made in the second story for nineteen hollow-ware pressers, •whose workshop runs nearly the whole length of the range, and is probably the finest workroom in the Potteries, the height to the apex of the roof being 23 ft. We were not at all surprised to hear from Mr. Hammersley that the mere fact of such a noble room being provided enabled him to secure, without difficulty, the most respectable workmen. Lap stoves are used, and they are heated by exhaust ste^im Mr. Boulton has succeeded in warming and heating the whole of the works by means of iron pipes, along which the exhaust steam is conveyed There are two biscuit ovens and three glost ovens, the latter of which are built on the cone princi- ple. There are four warehouses : the hollow biscuit ware- house, 121 ft. by 28 ; the flat biscuit warehouse, 60 ft. by 28 ; a smaller warehouse for sorting, and the principal warehouse, a room of 164 ft. by 33. Provision is made for twelve print- ers ; and in the sagger-house, which is the last place reached by the steam pipes, 40 scores of saggers are dried at one time. The manufactory has an extensive frontage to the road The tympanum is filled in with E. Minton, Taylor & Co.'s encaustic tiles. All the roads and footpaths on the factory are paved and bricked, and, indeed, it may be stated summarily, that no expense has been spared to make this factory one of the most complete, substantial, and in some parts handsome, buildings in the district." The decoration of stone-ware by grotesque figures moulded separately and superimposed before burning is well-known. Decoration in colors is hard to obtain on account of the de- structive action of the intense heat and the glaze employed. Messrs. Doulton & Co. produce a " Claret " stone-ware, by the use of oxide of chromium, which is green before burning. Also, by tracing a design with a steel point on the clay itself, and applying oxide of cobalt with a fine brush, they obtain 65 an effective method of decoration, in keeping with the char- acter of the ware. (See list of Exhibitors.) TERRO-METALLIC WARE—BLUE BRICKS. Terro-metallic ware is of a dense, vitreous, non-absorbent, very hard and durable bodj. It is for some purposes su- perior to the best stone, and is particularly adapted for road and stable pavements, copings, tiles, channel courses, solid walls and hydraulic constructions. The tiles resemble cast iron in hardness and exceed it in durabihty, as incapable of rusting. The material used is a natural clay, highly impregnated with iron, and sometimes with lime, and is more fusible than ordinary brick-clay. Clays which contain a large portion of elements soluble in chlorhydric acid are good for this pur- pose. Where these are not obtainable, lime and iron, in the shape of slag ground, are mixed with a fat clay. In England, chalk dust, sifted coke dust, and mill cinder are used. Pug- ging and moulding is done by machinery. The firing requires a high vitrifying temperature, and fuel is a heavy item, unless kilns on the continuous principle are used. A kiln with down-draught flame, from which the waste gases are conducted to a second kiln, is found economical by Eckhardt. The same substance will produce an ordinary red brick, blue ware, or a glass, according to the mode and degree of firing. For terro-metallic ware, the heat is first brought to a point at which the ware begins to soften and run to- gether, then lowered to dark red, again raised and. lowered many times. Wood and clean peat are best; coking coal is hard to manage, as the intermittence in heat is obtained by succes- sive heavy charges of fuel which are allowed to burn low.. In Holland, the firing is roughly done in open kilns, with walls 6 feet thick and 12 feet high.. 1DQ,00Q bricks are burnt 66 at a time, requiring often six weeks. This metliod gives con- siderable loss in melted and unburnt bricks. In Germany, a rectangular kiln, witli arched roof, contain- ing 90,000 bricks, is used. The walls are 4 feet thick. There are 60 flue openings in the roof, and 20 fire-place openings at the sides, without grates ; peat is used as fuel, continuously at first for 8 days, then charged intermittently every 4 hours for 4 days, and finally every 2 hours for 2 days. During the last period the flame issues abundantly from the roof. At Kouen, the Hoffman annular kiln is used. Blue-bricks are abundantly made in Staffordshire from a ferruginous clay which fuses at a china biscuit heat. The blue color does not permeate the body as for terro- metalHc ware, but only extends to about one-eighth of an inch from the surface. The fire is managed in a series of " pinches," but requires to be less intense. The blue color is obtained by repeatedly submitting the ware when highly heated to a reducing atmosphere of smoke, which reduces the red peroxide of iron to protoxide, all the salts of which are bluish and greenish. Sulphur assists this action. In Holland the process consists in closing the dampers, and throwing bundles of wood into the fire shortly before the end of the firing. FIRE-CLAY WARES. The extensive use of fire-clay wares in most of the arts gives peculiar interest to their manufacture. The obtainable quahty of refractory goods has, in certain industries, a con- trolling influence upon the economic results. The fire-brick industry of England is chiefly centred in the productions of Stourbridge and New Castle, which together make 110 milHons fire-bricks per annum, and export over $500,000 of fire-clay and 10 millions fire-bricks. Fire-Clays. — In the present state of knowledge, the physi- cal tests of clays give us better indications of its value than the chemical. Clays of the same chemical composition are sometimes of 67 opposite refractory qualities, while clays of different com- position may be equally refractory. When Brongniart and Malaguti mixed the correct chemi- ical elements of porcelain together, and tried to reproduce that substance, they failed signally, and obtained only a non- plastic and very fusible substance. This also shows how greatly the properties of a body depend on the mode of grouping of the elements. The analyses of fire-clays, in chemical works, give merely the elements, and are therefore not presented in a practical shape to the manufacturer. In examining a refractory clay, the purpose for which it is intended should be considered, for a material will answer for certain conditions that will not for others. Lightness of color indicates little ; when owing to lime, it is generally a, source of fusibility. , Experiment should be made whether the clay is best alone, or mixed with other clay, raw or burnt, and in what proportion ; what size to give to the fragments of burnt clay or quartz added ; the finer it is the more it tends to combine chemically, especially quartz. The addi- tion of large fragments produces a more porous and brittle brick, which stands better changes of temperature, and is preferred for blast-furnace boshes, &c. ; fine burnt clay makes a denser brick, which retains heat better, and is preferred for coke-ovens, &c. The corroding influence of the metals and slags to whicl^ the fire-brick is exposed, must be combated by careful preparr ation of the clay, to produce a denser brick, by giving super- ficial smoothness, and by hard burning. In building with fire-brick, the use for joints of cement containing free silicic acid (quartz) should be avoided, by previously saturating the cement with a basic burnt clay. Bricks analyzed before and after use, have shown a loss of half the silica they contained. A test of the power 'of brick to withstand these corrosive influences, is the number of times it can be melted up with oxide of lead, without being eaten through. In examining the analysis of fire-clays, attention should be paid to the proportion of iband, which makes them more 68 icaeagre, and opposes rupture, while burning. An excess of sand renders them more brittle and porous, yet they stand heat better. The sharpness and size of the grains facilitates a homogeneous composition by rubbing when being worked up. Clean quartz sand is the best; ground sandstone is good, but expensive. A high proportion of alumina increases the plasticity of clay, and, at high temperatures, also the refractory power. Thus monosilicates are more refractory than bi or tri-silicates. Free sihca, i. e., in crystals mechanically mixed, must be dis- tinguished from combined silica. Increasing the proportion of combined silica, augments ttie resistance in the fire only at lower temperatures, which, however, may often suffice in industry. But above the point of melting steel, the more combined «ilica there is, the greater is the fusibility. Also, the ware then requires a longer burning in the kiln. Clean free silica will not melt in our melting heats, unless -fluxed. A high proportion of free siHca is less injurious than when the silica is combined. Silica which has been long in tiie fire is more refractory and incorrodible. Bischof finds that any addition of fluxes above 4 per cent, rapidly increases the fusibility of the clay, in the following order : lime, magnesia, alkali, and oxide of iron least. Eichter finds them damaging, as follows : magnesia most, lime next, then iron oxide and alkali. 09 •uaaHOf) Iff '(viaxsav) zxiaag C O r-< 1-1 •iviHAivy iff 'xassiapi 20.92 61.52 1^25 1.75 •aaxHoig; ia 'flvavvg 05 O O « 1-1 i-( o> S^I^TJIO .OrH --^ • • • OD W TjJ S * ^ rH oi •oxa 'uavK^; ia 'avssY U5 1-1 'tl eO ri i-i o o _o o o _o _o o o !_o : lO (N O O O O O O U5 O 1-1 CO •aaiHX -aag ia 'avaaaxuopi 24.6 64.4 trace lo'" ■ •xazvpi 25 52 9.0 trace 12.' 6 •aaiHvj, . o o o 1-1 *aac[iioj3 ia iinov]^ M<