nflfl IBlli WW IBl 11111 Hill IHil sSS ■HP ?H8K HffiTO liillli Illllili! . .. fflmm W&m 1 IB ■ -•■ ''■■'■;•■ ! iini ^ .& %■<* /**ife;S* /^^k^ /y^x ^° K* S * A* v ^ °' s * A *o.*« & «5 <2* £°<* .o > ^ -J .,/\l^-/*j £ 9* & ,* v ^ : A \ V * v ,0° ^i (5 * -i 4^ '-Wm^Z i9-r_ , » o „ o " .IT *\ ' ^7 ^ ^ ' o " • „ <* rf>Sl^% *©o .^\<^'X»» " ' ,0*V" 0* ..^ *©, ^ : x^^^ • A v ^ J% ■ * 4? <$> o^Vji&AK * aV -5* . * ^ y ^. > f>" . V . o * 4.1 4- V ** > ^> *o . k * A <. ^ ^ .v ***** :£Mk\ v^ ^ A V r. " « . " * 4> ^ 0^ t - 1 ' O V ' : JK: ^ * '^ V :SS A / #fe V*^ \/ri / ^ ••%^« ** v \ -S8K.' /\ -.^^.- ^% ~-WM: j>\ l^p. ; ^% -. Bureau of Mines Information Circular/1986 Availability of Rare-Earth, Yttrium, and Related Thorium Oxides— Market Economy Countries A Minerals Availability Appraisal By T. F. Anstett V UNITED STATES DEPARTMENT OF THE INTERIOR Information Circular 9111 Availability of Rare-Earth, Yttrium, and Related Thorium Oxides— Market Economy Countries A Minerals Availability Appraisal By T. F. Anstett UNITED STATES DEPARTMENT OF THE INTERIOR Donald Paul Hodel, Secretary BUREAU OF MINES Robert C. Horton, Director TNaIS win i As the Nation's principal conservation agency, the Department of the Interior has responsibility for most of our nationally owned public lands and natural resources. This includes fostering the wisest use of our land and water resources, protecting our fish and wildlife, preserving the environment and cultural values of our national parks and historical places, and providing for the enjoyment of life through outdoor recreation. The Department assesses our energy and mineral resources and works to assure that their development is in the best interests of all our people. The Department also has a major responsibility for American Indian reservation communities and for people who live in island territories under U.S. administration. Library of Congress Cataloging-in-Publication Data Anstett, T. F. (Terrance F.) Availability of rare-earth, yttrium, oxides— market economy countries. and related thorium (Information circular; 9111) Bibliography: p. 13 Supt. of Docs, no.: I 28.27: 9111 1. Earths, Rare. 2. Yttrium earths. 3. Thorium ores. I. Title, n. circular (United States. Bureau of Mines); 9111. Series: Information -TN295.U4 [TN490.A2] 622 s [553.4'94] 86- -600187 PREFACE The Bureau of Mines is assessing the worldwide availability of selected minerals of economic signficance, most of which are also critical minerals. The Bureau identifies, collects, compiles, and evaluates information on producing, developing, and explored deposits, and mineral processing plants worldwide. Objectives are to classify both domestic and foreign resources, to identify by cost evaluation those demonstrated resources that are reserves, and to prepare analyses of mineral availability. This report is one of a continuing series of reports that analyze the availability of minerals from domestic and foreign sources. Questions about, or comments on, these reports should be addressed to Chief, Division of Minerals Availability, Bureau of Mines, 2401 E St., N.W., Washington, DC 20241. CONTENTS Page Preface iii Abstract 1 Introduction 2 Methodology 2 REO characteristics and uses 3 Geology and mineralogy 3 REO production and demand 4 World production 4 Demand outlook 4 REO resources in evaluated properties 5 Mining and beneficiation 7 Mining 7 Page Beneficiation : 7 Postmill processing 8 Processing industry structure 8 Production costs 8 REO availability 9 Total availability 10 Annual availability n Availability of individual REO, Y 2 3 , and Th0 2 . . 12 Conclusions 13 References 13 Appendix.— Property descriptions 14 ILLUSTRATIONS 1. Minerals Availability program deposit evaluation procedure 2 2. Mineral resource classification categories 5 3. Total recoverable REO, by country and property status 7 4. Total recoverable REO, by property status and DCFROR 10 5. Cumulative potential annual REO availability, producers 11 6. Potential annual REO availability, nonproducers 12 A-l. Location map, Australian east coast properties 14 A-2. Location map, Australian west coast properties 15 A-3. Location map, Brazilian properties 16 A-4. Location map, Canadian and U.S. properties 17 A-5. Location map, Indian and Sri Lankan properties 18 TABLES 1. Individual REO contained in major source minerals 3 2. World mine production of REO, 1981-84 4 3. Ownership and status of evaluated REO properties 6 4. Demonstrated REO resources of evaluated properties, January 1984 7 5. Average mining and milling costs 9 6. Average percentage of revenues by mineral concentrate type 9 7. Market prices of mineral sand concentrates and associated minerals, January 1984 10 8. Cumulative total REO potentially available 10 9. Individual REO, Y 2 3 , and Th0 2 contained in evaluated properties 12 VI UNIT OF MEASURE ABBREVIATIONS USED IN THIS REPORT km kilometer mt metric ton m meter mt/h metric ton per hour mm millimeter mt/yr metric ton per year yr year yr year AVAILABILITY OF RARE-EARTH, YTTRIUM, AND RELATED THORIUM OXIDES— MARKET ECONOMY COUNTRIES A Minerals Availability Appraisal By T. F. Anstett 1 \ ABSTRACT The Bureau of Mines estimated the potential availability of rare-earth oxides (REO), including yttrium, and thorium, which is also contained in the rare-earth bearing minerals monazite and bastnasite, from 38 properties in market economy countries (MEC's). Only nine of the properties evaluated produce or would produce REO as the primary product; the others contain REO as a byproduct, chiefly from mineral sands operations recovering rutile, ilmenite, and zircon. Nearly 77% (2,578,000 mt) of the total 3,355,000 mt of recoverable REO evaluated is from producing properties. It is estimated that 21% (705,000 mt) of this total is from properties that could not realize a positive rate of return at the January 1984 market prices for the recovered commodities. At production capacities assumed for this evaluation, the amount of REO potentially available from producers ranges from an estimated 46,500 mt in 1986, to a peak of 50,900 mt in 1992, to 49,900 mt by the year 2000. Total MEC production in 1984 was estimated at 40,700 mt. Assuming demand does not increase sharply, producing properties can continue to fulfill overall REO demand through at least the end of this century. 'Geologist, Minerals Availability Field Office, Bureau of Mines, Denver, CO. INTRODUCTION The Bureau of Mines investigated the potential avail- ability of the rare earths, a group of chemically related commodities having important industrial applications. This report addresses the availability of rare-earth oxides (REO) (and yttrium oxide) in concentrate from 29 foreign and 9 domestic properties. The amount of thorium contained in monazite, an important thorium source material, was also estimated. Detailed information concerning domestic thorium resources and processing methods and costs is contained in other publications (1-2). 2 Unlike that of most mineral commodities, world production of rare earths is dominated by one mine, 'Italic numbers in parentheses refer to items in the list of references preceding the appendix at the end of this report. Mountain Pass, CA, which typically accounts for about half of annual world production. Mountain Pass is also the only MEC operation that produces the mineral bastnasite as a primary product. Nearly all of the remaining MEC production of rare earths is from the mineral monazite, a byproduct of processing mineral sands for the titanium minerals, rutile and ilmenite, and for the zirconium mineral, zircon. Domestic properties were evaluated by personnel of the Bureau's Field Operations Centers, and foreign data collection and cost estimation were performed under contract by Pincock, Allen and Holt Inc., Tucson, AZ; personnel of the Bureau's Minerals Availability Field Office, Denver, CO, evaluated the data and performed the economic analyses. METHODOLOGY Because of the byproduct nature of a large percentage of world rare-earth production, and the fact that the rare- earth-bearing mineral monazite is produced as an integral part of the recovery process of the titanium minerals (rutile and ilmenite), the most practical investigative approach to assess rare-earth availability is in terms of its availability as a function of overall profitability of the properties evaluated. Consequently, availability results are presented as a function of a measure of profitability of each property, as indicated by its discounted-cash-flow rate of return (DCFROR), defined as the rate of return that makes the present worth of cash flows from an investment equal to the present worth of all after-tax investments (3). A 0% DCFROR is commonly considered as the "breakeven" point for an operation. An outline of the evaluation procedure followed for this study is shown in figure 1. The analysis methodology is as follows: 1. The quantity and grade of rare-earth resources were evaluated in relation to physical and technological identification and selection of deposits Tonnage and grade determination Engineering and cost evaluation I Industries Location System (MILS) data MAP computer data base Deposit report preparation MAP permanent deposit files conditions that affect production from each property as of the study date, January 1984. 2. Appropriate mining and processing methods were determined for producing operations and proposed for undeveloped properties. Related capital and operating costs to process material to a marketable concentrate were estimated. Operating costs include transportation to deliver concentrates to port or process plant. It was assumed that all operations were 100% equity financed. 3. An economic analysis of each operation was performed to determine the DCFROR. Revenues generated for each property's cash flow were based on January 1984 prices of commodities that are or could be produced at each property. 4. All properties were aggregated onto total and annual availability tables and curves, which show the amount of recoverable rare earths, in terms of REO, potentially available at various DCFROR's. Availability of the individual rare earths (as REO), yttrium (as Y-jOs), and thorium (as Th0 2 ), are also shown. Taxes, royalties, cost indexes, prices, etc... Data selection and validation Variable and parameter adjustments Economic analysis Sensitivity analysis Data Availability curves Analytical reports AJ JJ Data Availability curves Analytical reports FIGURE 1 .—Minerals Availability program deposit evaluation procedure. REO CHARACTERISTICS AND USES The rare-earth elements, or lanthanides, are 15 chemically similar elements with atomic numbers 57-71. They are lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium thulium, ytterbium, and lutetium. Promethium, a fission product of uranium, has no known naturally occurring stable isotopes. Although not a member of the lanthanide series, yttrium (atomic number 39) is grouped with the rare-earth elements because it typically occurs with them in nature and has similar chemical properties. The rare-earth elements have been classified into two general groups: the light or cerium subgroup, comprising the first seven elements listed above (atomic numbers 57-63); and the heavy or yttrium subgroup, comprising the elements with atomic numbers 64-71 as well as yttrium. Despite its low atomic weight, yttrium is categorized with the heavy rare earths because its occurence, ionic radius, and behavioral properties are closer to those of the heavier rare-earth elements than to the lighter group. Important industrial applications of the rare earths in- clude: petroleum cracking catalysts; metallurgical (in- cluding iron and steel additives, alloys, and mischmetal); ceramics and glass (including polishing compounds and glass additives); and miscellaneous, including phosphors, electronics, nuclear energy, lighting, and research. Among these general use categories, petroleum catalysts accounted for 65% of U.S. consumption in 1982, metallurgical uses ac- counted for 20%, and ceramics and glass accounted for 12%; miscellaneous uses accounted for 3% (4). One of the most important applications of rare earths is in catalytic activities. Mixtures of lanthanum, neo- dymium, and praseodymium chlorides are used in catalysts for petroleum refining. Between 1% and 5% rare-earth chloride is added to zeolite catalysts to increase their effi- ciency in the conversion of crude oil to petroleum products. The demand for rare-earth chlorides for cracking catalysts is on the increase, and it is believed that more companies will become involved in their production in the future (5, p. 34). Mischmetal, produced by the electrolysis of anhydrous mixed rare-earth chlorides, has applications in the iron and steel and the lighter flint industries. In the iron and steel industry, the physical and rolling properties of the metal are improved by the use of mischmetal. Rare-earth treated, high-strength, low-alloy steels are being increasingly used in the automobile industry as structural components and in lightweight sheet applications (6, p. 740.) Rare-earth metals such as cerium, praseodymium, neodymium, samarium, dysprosium, and mischmetal are used in the manufacture of permanent magnets. These magnets, which are stronger than other magnets, are used in electric wristwatches, tachometers, traveling wave tubes, line printers, and electric motors and generators (6, p. 742). The most powerful magnets known are made from neodymium plus iron and boron. The rapidly growing rare- earth permanent magnet business is estimated to be worth $100 million annually (7). The energy concerns of the 1970's spurred development of more efficient automobile engines, experimental models of which require the use of yttria-stabilized zirconia for elevated temperature applications, and development of lanthanum-nickel intermetallics for solid-state hydrogen storage and processing. Rare-earth compounds are also used in the glass industry in a variety of applications including polishing, decolorizing, and the manufacture of special glasses. GEOLOGY AND MINERALOGY The rare-earth elements and yttrium are essential con- stituents in more than 100 minerals; however, only a few minerals occur in sufficient concentration to qualify as ore. Monazite, bastnasite, and xenotime are the most important rare-earth-bearing ore minerals. Monazite, a rare-earth phosphate, can contain approximately 70% combined REO, including 2% Y 2 3 . Most monazite concentrates range from 55% to 65% contained REO. Table 1 shows average concen- trations of the various REOs in the important ore minerals. Bastnasite, a fluorocarbonate mineral, can contain ap- proximately 75% REO and very minor amounts of Y 2 3 (0.1%). Bastnasite flotation concentrates average approx- imately 60% REO, but the concentrate can be upgraded to 70% REO by acid leaching and to 85% REO by a combina- tion of leaching and calcining. Molycorp Inc., the world's largest producer of bastnasite from its Mountain Pass prop- erty in California, produces bastnasite concentrate at all three grades. Xenotime, an yttrium phosphate mineral, is found in the same geological environment as monazite and is a ma- jor source of yttrium. Among world rare-earth occurrences, those of China and Malaysia are the most significant source of yttrium-bearing xenotime, which is produced as a byproduct of tin placer mining. Among other commercial mineral sources of rare earths and yttrium are apatite and multiple-oxide minerals such as euxenite and loparite. Although these minerals are mined for their REO content and constitute a substantial resource, they presently account for a comparatively minor percentage of REO production. Table 1.— Individual REO contained in major source minerals (5, p. 19) (Percent of total REO) Oxide Monazite Bastnasite Xenotime Y 2 3 2 0.1 60 La 2 3 23 32 \ Nd 2 3 19 13 I Sm 2 3 3 .5 1.2 Eu 2 O a .1 -1 -01 Gd 2 3 1.7 .15 3.6 Tb 4 7 -16 1 Dy 2 3 5 7.5 Ho 2 3 .09 2 Er 2 3 13 6.2 Tm 2 3 .01 127 Yb 2 3 .06 6 Lu 2 3 .006 -63 NOTE.— Columns do not total 100% because of independent rounding. Heavy mineral sands occurring in modern placer deposits are the major source of monazite; the mineral nor- mally is produced only as a byproduct of rutile, ilmenite, and zircon mining. The placers are formed by the natural processes of weathering, transportation, and concentration at a site of accumulation of heavy minerals whose origin is a primary source rock. Beach deposits are the most signifi- cant commercial placers. The largest accumulations exist where a coastline is indented and the beach is gently slop- ing. Important deposits of this type occur in Australia, In- dia, Brazil, the Republic of South Africa, and the United States. Similar deposits occur in southeast Asia, where small amounts of xenotime are recovered as a byproduct of tin mining. An important source of REO is carbonatite deposits, ig- neous assemblages of primarily carbonate minerals occur- ring as intrusions associated with undersaturated alkali ig- neous complexes formed along major rift zones. The most significant commercial carbonatite complex is at Mountain Pass, CA, which supplies much of the world's bastnasite and accounts for nearly half of the world's annual REO pro- duction and more than 60% of MEC production. Another important world bastnasite deposit is Baiyen-ebo in the Nei Monggol Autonomous Region of China. Other carbonatite complexes, such as Palabora in the Republic of South Africa, are known to contain large amounts of REO-bearing minerals, but none has produced commercially significant quantities on a sustained basis. REO PRODUCTION AND DEMAND WORLD PRODUCTION Estimated production of REO from major world pro- ducers for the years 1981—84 is shown in table 2. The United States is the world's leading supplier of REO, almost all of which is from Molycorp Inc.'s Mountain Pass, CA, bastnasite operation; the United States also produces a small amount of REO from monazite annually. Table 2 in- cludes U.S. bastnasite production only. Australia is the world's leading producer of monazite, as a byproduct of heavy mineral sands (chiefly ilmenite, rutile, and zircon) mining. Because of its byproduct status, Australian monazite production depends upon its relatively low and extremely variable composition in the heavy mineral sands, and the economics of the marginal cost of recovering monazite. Australian monazite and xenotime producers presently sell all of their production. The country has no processing facilities beyond initial beneficiation, and the monazite con- centrate is generally exported to the United States and Europe (mainly France) for processing. Exports have in- creased steadily during the past few years. A particular problem relative to monazite concentrate marketing is the presence of radioactive thorium that typically occurs in monazite, generally in amounts on the order of 6% to 7% Th0 2 . Currently, there is only limited demand for thorium, and its presence in monazite concen- trates is generally regarded as a nuisance because safeguards must be taken and regulatory standards main- tained while handling the material. Brazil and India do not allow the export of monazite because of its thorium content and are stockpiling thorium for possible future use as a nuclear fuel (energy source). Consequently, both countries have integrated operations that separate the rare-earth metals and thorium prior to export of the rare earths. NUCLEMON, a Brazilian Government-owned entity, mines heavy minerals sand chiefly for its monazite (thorium) con- tent. From a revenue perspective, the monazite would be considered a byproduct of ilmenite and rutile production. Probably the most significant recent development in REO production is the emergence of China as the world's third largest producer, after the United States and Australia. The country is believed to possess the world's largest REO reserves (5, p. 23). The Bureau of Mines estimates China's reserve base at 38 million mt REO, or nearly 80% of the total world reserve base (8). Annual pro- duction figures are not available for China, but 1985 pro- duction was estimated to be about 10,000 mt REO. Table 2.— World mine production of REO, 1981-84 (8) (Metric tons) Country 1981 1982~ 1983 1984 MEC: Australia 7,430 5,229 7,975 9,189 Brazil 1,452 1,061 1,100 1,100 India 2,201 4,000 2,200 2,200 Malaysia 165 320 187 2,563 Thailand 84 59 77 172 United States 1 ... . 17,094 17,501 17,083 25,311 Other 109 167 165 170 ^.T 0131 MEC 28,535 28,337 28,787 40,705 CPEC 2 : Chy 13 NA NA 6,000 8,000 otner NA NA 1,500 1,500 World total 3 . . . . NA NA 36,000 50,000 NA Not available. 1 1ncludes bastnasite production only. 2 Centrally planned economy countries. 3 Rounded. DEMAND OUTLOOK The solvent extraction technology, perfected in the 1960's for europium and yttrium oxides, has been expanded to commercial-scale separation and purification of at least 11 of the 15 rare-earth elements occurring in bastnasite, monazite, and xenotime. Most rare earths presently used by industry are consumed in the form of compounds con- taining special mixtures of rare-earth elements. On a percentage basis, the use of compounds is decreasing in favor of specific "mixes" for various end uses. Demand for separated and often high-purity rare earths has increased in recent years, and this trend is expected to continue. One of the major developments in the rare-earths in- dustry is the increasing number of uses for neodymium, which is in strong demand for lasers and magnets. While the future availability of this element could be a matter of concern given its increasing demand, neodymium is the third most abundant of the rare-earth elements and should be available in sufficient quantities to satisfy all expected demand. Shortages could occur because of the processors' need to balance the output of the commercially important rare-earth elements to operate profitably (5, p. 36). Presently, a shortage in samarium is being experienced because processors do not have sufficient capacity. The de- mand for the heavy rare earths, including yttrium, has in- creased greatly for use in a variety of high-technology ap- plications. Demand is particularly strong in Japan. The large demand for yttrium used in lasers and phosphors is one factor that has prompted recent increases in the price of xenotime. Another market that is presently experienc- ing short supply is rare-earth chlorides; the strong demand is likely to continue (5, p. 36). Traditional markets for mischmetal, a natural alloy of several of the rare earths, are the iron and steel and lighter flint industries. The iron and steel industry has been adversely affected by the economic recession of the early 1980's. Additionally, recent advances in technology have reduced the requirement for mischmetal, and demand levels for the material are not likely to return to pre-1982 levels. Presently, most of the heavy rare earths derived from monazite processing are in high demand. Yttrium concen- trate, because of its relatively high yttrium content (60% Y 2 O s ) and high content of other heavy rare earths, is also in great demand. Xenotime is not as readily available as monazite, primarily because it is not as abundant and oc- curs in fewer commercial deposits. REO RESOURCES IN EVALUATED PROPERTIES A total of 38 properties were evaluated for this study. Evaluation of each property was performed on resource values sufficiently defined to be considered demonstrated according to the definitions established by the Bureau of Mines and U.S. Geological Survey (9) (fig. 2). Resource estimates for properties were available from published data, company personnel, and/or others familiar with the property. A general description of individual properties evaluated is included in the appendix. Table 3 contains pertinent in- formation for the 38 evaluated properties. Table 4 and figure 3 present a summary of demonstrated resources, by coun- try and property status. Of the 38 properties evaluated, only 9 produce or can produce rare earths as the primary product. Included in the nine properties are five in Brazil that, from a revenue stand- point, may be considered to be titanium properties, but are or could be mined primarily for their monazite content. All remaining properties evaluated can or could produce rare earths as a byproduct, primarily of processing titanium. The three Elliot Lake (Canada) properties, all producers of uranium, could recover rare earths as a byproduct by sol- vent extraction from a barren uranium solution. These three properties, plus the Silica Mine in Tennessee and Richards Bay in the Republic of South Africa, are producers that presently do not recover rare earths. The total amount of REO potentially available annually from the 17 producers evaluated is nearly 50,000 mt at pro- duction capacities of those properties. Of the countries whose annual production is shown in table 2, only Malay- sian and Thai producers have been excluded from this evaluation because of a paucity of rare-earth resource data for those properties at the time of this evaluation. However, these countries produced about 2,500 mt REO in 1984 (table 2). Producing properties that recover rare earths as "a byproduct of titanium processing account for 961,000 mt recoverable REO, or 29% of the total recoverable REO in all properties evaluated. Nonproducing properties that could recover rare earths as a byproduct of titanium mining con- Cumulative production IDENTIFIED RESOURCES UNDISCOVERED RESOURCES Demonstrated Inferred Probability range Measured Indicated Hypothetical Speculative ECONOMIC Res erve Inferred reserve base 1 + -+- - 1 MARGINALLY ECONOMIC ba se SUB- ECONOMIC i Other occurrences Includes nonconventional and low-grade materials FIGURE 2.— Mineral resource classification categories. Table 3.— Ownership and status of evaluated REO properties Property 1 Status* Owner Deposit 3 type Mining method Products* Australia: Allied Eneabba Cable Sands Capel Cataby Cooloola Eneabba Fraser Island Jurien Bay-Cooljarloo . . . Munmorah North Capel North Stradbroke (AMC) North Stradbroke (CRL) . Yoganup Extended Brazil: Alcobaca* Anchieta* Aracruz* . Buena* . . Serra* . . . Canada: Elliot Lake: Denison Quirke-Panel . . . Stanleigh India: Chavara (IRE) . . . Chavara (KMML) Manavalakuruchi Orissa-Chatrapur Ranchi-Purulia* . Malawi: Kangankunde* Republic of South Africa: Richards Bay Sri Lanka: Pulmoddai United States: Bear Valley Big Creek* Brunswick-Altamaha . . Gold Fork-Little Valley Green Cove Springs . Mountain Pass* Oak Grove Powderhorn Silica Mine P P P Exp PP P PP PP PP P P P P Exp P Exp P Exp PS P5 P5 p p p Dev Exp Exp PS P PP PP Exp Exp P P Exp Exp P5 (AMC). Allied Eneabba Ltd Cable Sands Pty. Ltd Associated Minerals Consolidated Ltd. Metals Exploration, Alliance .... State of Queensland, Australian government AMC Murphyores, Dillingham Western Mining Corp AMC State of Western Australia AMC Consolidated Rutile Ltd Westralian Sands Ltd Brazilian Government . ..do ..do ..do . . do Denison Mines Ltd. Rio Algom Ltd ..do India Rare Earths Ltd. (IRE) Kerala Minerals and Metals Ltd. (KMML) . IRE ..do Indian Government Lonhro Ltd QIT, Union Corp.; IDL . . Sri Lankan Government Bear Valley Industries . Several Union Camp Corp Several AMC Molycorp Inc Ethyl Corp Buttes Gas and Oil Co. Tennessee Silica Sand PI PI PI PI PI PI PI PI PI PI PI PI PI PI PI PI PI PI Hr Hr Hr PI PI PI PI PI Hr PI PI PI PI PI Hr PI Hr PI Strip level Dredge . . . ..do ..do ..do Strip level Dredge . . . Strip level Dredge . . . Strip level Dredge . . . ..do Open pit . . .do. .do. do. .do. .do. Room and pillar ..do ..do Strip level Dredge . . . Strip level Dredge . . . Strip level Open pit. Dredge . . . Strip level Dredge . . ..do.... ..do.... ..do.... ..do.... Open pit. Dredge . . Open pit. ..do.... R, I, L, Z, RE I, R, Z, RE I, R, L, SR, RE IR, I, Z, RE R, I, Z, RE I, R, L, SR, RE R, I, Z, RE R, I, L, Z, RE R, I, Z, RE I. R, L, Z, RE R, I, Z, RE R, I, Z, RE I, R, L, Z, RE RE, RE, RE, RE, RE, Z, R Z, R Z, R Z, R Z, R U, RE U, RE U, RE R, I, L, Z, RE R, I, L, Z, RE I, R, SR, Z, RE R, I, L, Z, RE RE, I, Z, R, S RE S, R, Fe, Z, RE I, R, Z, RE I, RE, G, C RE, I, G, Z R, M, Z, RE I, Z, RE, Au, G R, I, L, Z, RE RE I, R, Z, RE P, RE SS, I, R, L, Z RE 1 Properties that do or could produce REO as the primary product are identified with an asterisk. 2 P = producer; PP = past producer; Exp = explored prospect; Dev = developing property. 3 PI = placer; Hr = hard rock. "The first product listed was assumed to be the primary product for this study. Au = gold; C = columbium; Fe = magnetite; G = garnet; trate; L = leucoxene concentrate; M = mixed ilmenite-leucoxene concentrate; P = perovskite concentrate; R = rutile concentrate; RE S = titanium slag; SR = synthetic rutile concentrate; SS = silica sand; Z = zircon concentrate; U = uranium. 5 Producers that do not presently recover REO. = ilmenite concen- : REO concentrate; tain 477,000 mt, or 14% of the total recoverable REO in all properties evaluated. Titanium properties thus account for 43% of the total recoverable REO in all properties evaluated for this study. Producers that recover REO-bearing minerals as the primary commodity contain 1,566,000 mt, or 47% of the total recoverable REO in all properties evaluated. Moun- tain Pass accounts for nearly the entire amount. Non- producers that could recover REO as the primary product contain 337,000 mt, or the remaining 10% of total REO con- tained in all properties evaluated. In terms of country totals (table 4), U.S. properties con- tain 1,994,000 mt recoverable REO, or 59% of the total in all properties evaluated. Mountain Pass accounts for nearly 80% of the U.S. total, and nearly half of the total in all pro- perties evaluated. Australian properties, all of which do or could produce REO (primarily in monazite) as a byproduct of titanium mining, contain 303,000 mt REO, or about 9% of the total. Of the total amount of REO contained in Australian properties, producers account for 85%. Brazilian properties account for only 15,000 mt re- coverable REO, which is less than 1% of the total in all prop- erties evaluated; producers account for 67% of total recov- erable REO in Brazilian properties evaluated. The three Elliot Lake, Canada, operations that could produce byproduct rare earths contain 14,000 mt recov- erable REO, less than 1% of the total. Properties in India and Sri Lanka contain 815,000 mt recoverable REO, or 24% of the total in all properties evaluated. Of this, the five producers, all primary titanium properties, account for 86% of the total. Malawi and the Republic of South Africa contain a total of 214,000 mt recoverable REO, all from nonproducers. Richards Bay, in the Republic of South Africa, is a titanium producer that does not presently recover monazite. Table 4.— Demonstrated rare-earth resources of evaluated properties, January 1984 Ore Feed Country and status Number of treated, grade, Recoverable properties 10 6 mt % REO REO, 1Q3 m t Australia: Producers Nonproducers Total Australia . . Brazil: Producers Nonproducers .... Total Brazil Canada: Nonproducers India and Sri Lanka: Producers Nonproducers Total India and Sri Lanka 6 Malawi and Republic of South Africa: Non- producers United States: Producers Nonproducers Total United States Grand total 38 8 5 1,214 1,218 0.04 .01 259 44 13 2,432 .03 303 2 3 3 2 .43 .34 10 5 5 3 5 241 .39 .01 15 14 5 1 553 86 .37 .19 700 115 639 .35 815 2 626 .07 214 2 7 107 876 2.09 .13 1,558 436 9 983 .34 1,994 United Stotes 4,926 .14 3,355 FIGURE 3.— Total recoverable REO, by country and property status. MINING AND BENEFICIATION MINING BENEFICIATION Since commercial amounts of rare-earth-bearing minerals occur in placers, veins, and igneous intrusive com- plexes, mining methods include placer (predominantly dredging), open pit, and underground. For heavy mineral operations recovering monazite as a byproduct, such as those in Australia and India, dredg- ing is the most common mining method employed. Floating cutter-head dredges are the most common type of machinery used if the mineral sands are loose and occur at depths of less than 20 m. Preliminary concentrating occurs on the dredge, or on barges alongside, using Reichert cones, spirals, jigs, tables, and similar equipment. Where floating dredges are not practicable (e.g., deposits that are several kilometers inland and where water is in short supply), or the size, shape, and lithology of the ore body are impractical for dredges, other mining methods are employed. Draglines, front-end loaders, and trucks are used in most cases. The only producing open-pit hardrock operation evaluated for this study is Mountain Pass, where bastnasite ore is produced from a tabular carbonatite intrusive ore body. Kangankunde, an undeveloped hardrock property in Malawi, would probably also utilize open-pit mining methods. The only underground operations evaluated for this study were the Elliot Lake district uranium mines in On- tario, Canada. There, room-and-pillar methods are used to extract uranium ore from quartz pebble conglomerates. Monazite occurs as a secondary mineral in the uranium ore. The Mountain Pass operation utilizes flotation to proc- ess the bastnasite ore. Kangankunde, the other hardrock property evaluated, would also use flotation methods. In- itial concentration of placer sands occurs in wet mills, with final concentration and mineral separation in dry mills. In some cases, prior to wet concentration, ore goes through a feed preparation stage (to wash clay particles), which can include a number of separate processes depending on the amount of clay and throughput rate. A wet screening stage is used to prepare suitably sized feed for the wet gravity concentrator. Wet mills can be land-based or floating. In a typical operation, ore from a dredge or slurry sump is pumped at 25% to 30% solids to the wet mill, where ore is fed into one or more stages of Humphreys spirals and/or Reichert cone concentrators, producing a preliminary heavy mineral con- centrate. Rough, heavy mineral concentrate from the wet mill is transported, usually by truck or barge, to the dry mill for further processing. Dry mills use various stages of magnetic, electrostatic, and gravity separation techniques to produce ilmenite, rutile, leucoxene, zircon, and monazite concentrates. The specific flowsheet of a dry mill depends on the type of ore and the heavy mineral assemblage to be recovered. In general, a dry mill separation process consists of high- tension electrostatic separators to separate conducting from nonconducting minerals. The relatively nonmagnetic monazite is separated from the more magnetic zircon fraction. A unique beneficiation process was used at Denison Mines' Elliot Lake operation in Canada, where a Y 2 3 -REO concentrate was produced as a byproduct from the barren uranium solution. The process included leaching, solvent extraction, and precipitation to produce a 63.5% concen- trate, of which Y 2 3 is the major component, averaging 40% in the concentrate. POSTMILL PROCESSING Solvent extraction is the most important process used to separate the rare earths. The process is based on the dif- ferent affinities of the rare-earth elements between a solu- tion of rare earths in water and a chelating agent in an organic solvent. The stages involved in the production proc- ess are (1) chemical reduction, (2) removal of non-rare-earth elements, (3) fractionation of rare-earth mixtures, and (4) precipitation, calcination, and grinding. The procedure can include several stages; for example, Rhone-Poulenc's La Rochelle, France, chemical separation plant is equipped with more than 1,000 mixers-settlers to achieve the parti- tion of the rare-earth elements. A comprehensive discus- sion of chemical separation techniques and processes is pro- vided by Subbarao and Wallace (10). One disadvantage of the solvent extraction technique is that operating costs for small-capacity units are high because the same number of personnel are required regardless of plant size. Consequently, the production of rare earths in small demand (e.g., holmium, erbium) is more costly than that for lanthanum or yttrium. Rhone-Poulenc uses a chromatographic ion exchange process using resins from small-scale rare-earth separations that do not warrant setting up a full-scale solvent extraction circuit (11). PROCESSING INDUSTRY STRUCTURE The rare-earth industries in Brazil, Malaysia, and India are to a large extent vertically integrated operations because the governments of those countries prohibit the ex- port of monazite. Five European countries (France, the Federal Republic of Germany, Austria, Norway, and the United Kingdom) process rare earths. Japan has a large number of companies that process rare earths from all cur- rently produced rare-earth-bearing mineral ores. In spite of its importance as the world's leading monazite producer, Australia presently has no rare-earth separation facilities. However, Allied Eneabba has announced plans to construct a plant to process 12,000 mt/yr monazite and 100 mt/yr xenotime (12). Rhone-Poulenc of France is a major world REO proc- essor. It processes both monazite and xenotime, but xenotime composes only about 1% of the raw material (5, p. 28). The company has a plant at La Rochelle on the French Atlantic coast, and in 1981 it opened a second pro- duction plant at Freeport, TX, with a planned production capacity of 4,000 mt/yr, which will effectively double the company's overall capacity when it reaches completion. The Freeport plant produces light rare-earth compounds from an intermediate rare-earth hydroxide concentrate, and the heavy rare-earth residue is sent to La Rochelle for final separation into high-purity rare earths. Most of the thorium produced in the process is sold in nitrate form for gas man- tle manufacture and thorium metal production; however, a small quantity of Th0 2 is sold to the nuclear industries in several countries. In the United States, Molycorp Inc., the world's largest producer of REO from its Mountain Pass operation, is a fully integrated company, producing rare-earth concentrates, compounds, and metals at its plants in York and Washington, PA, Louviers, CO, and at Mountain Pass, CA. In 1982, Molycorp started up an additional rare-earth separation circuit at its Mountain Pass complex for the production of samarium, gadolinium, lanthanum, prase- odymium, and neodymium oxides. In addition to Molycorp, an important U.S. rare-earth producer is the Davison Chemical Division of W. R. Grace and Co., which imports monazite from Australia to its plant at Chattanooga, TN, for the production of rare-earth chlorides. The chlorides are produced solely for internal use in the manufacture of petroleum cracking catalysts (5, p. 26). Two companies, Ronson Metal Corp. and Reactive Metals and Alloys Corp. (Remacor), produce mischmetal at processing plants in the United States. Although this study is restricted to MEC countries, an important development in the rare-earth processing market has been the recent emergence of China as a major producer. The country has the world's largest reserves of contained REO, and since the 1970's it has become a major processor. The Yao Lung Chemical Plant in Shanghai can process and separate 2,000 mt/yr REO, primarily from monazite. Prod- ucts available for export include phosphor preparations (e.g., Y 2 3 and EujOj) and magnetic materials such as samarium and samarium-cobalt alloys (5, p. 24). The country exports to Europe, the United States, the Soviet Union, and Japan. PRODUCTION COSTS Operating costs and capital investments for the ap- propriate mining, milling, and transportation methods were obtained or estimated for each property evaluated. In most cases, actual costs were available from published material, company personnel, other persons familiar with the opera- tion, or from confidential, unpublished studies. Total operating cost is a combination of direct and in- direct costs. Direct costs include production and maintenance labor, materials, payroll overhead, and utilities. Indirect operating costs include administration, facilities maintenance and supplies, research, and technical and clerical labor. Capital expenditures were obtained or estimated for ex- ploration, acquisition, development, and mine and mill plant and equipment. Capital expenditures for mining and milling facilities include the costs of mobile and stationary equipment, construction, engineering, infrastructure, and working capital. Operating and capital costs for "typical" Australian heavy mineral sands operations are induded in a recent Bureau report (13). Mine and mill operating costs for evaluated properties are shown in table 5. Costs are weight- averaged on the basis of annual ore capacity. It would be meaningless to present operating costs in terms of REO product, since nearly all properties produce REO as a byproduct of titanium mining. In fact, for several proper- k ties, REO is a relatively minor byproduct in terms of total revenues. Table 5.— Average mining and milling costs The four Indian producers and one Sri Lankan producer (January 1984 J.S. dollars per metric ton ore) together have a weighted-average mining cost of $0.53/mt Country and status M^e" Miii irtri * nd a "j 111 ^ c ° st of $1.28/mt ore. The two Brazilian pro- — — ducers, Anchieta and Buena, both of which are strip level Australia: operations with relatively small capacities (40,000 to 80,000 Producers 0.77 0.40 1.17 mt/yr), have weighted-average mining and milling costs of Nonproducers .74 .48 1.22 *i oo/ * j a>i oc/ a x- 1 1 mv t> •?• $1.82/mt and $1.85/mt ore, respectively. The Brazilian non- Brazil: producers could be brought into production at comparable No°n d p U rodu S cers '. '. .'. ]il 1 Jl ill operating costs ($1.99/mt mine, $1.92/mt mill); however, the capital expense necessary to build the mill and develop the lndia producers anka: 53 28 81 deposits, and especially the high transportation costs Nonproducers ........................ 2^05 4^35 6!40 associated with shipping the concentrates to port or process .... , ~ ... plant in Sao Paulo (as much as 1,200 km distant) render Malawi and Republic of South Africa: lu t> -i- _«.• i a- i • j. />.i Nonproducers .54 .62 1.16 *" e Brazilian properties relatively expensive in terms of the total cost of production. The same is true for the Unit Produced w w W undeveloped Indian property, Ranchi-Purulia. Nonproducers ........................ .76 .81 1 .57 Only one large-scale rare-earth property, Mountain ~~ w Withheld to avoid disclosing company proprietary data. Pass, is operating in the United States; consequently, operating costs are not disclosed for U.S. producers. Because Mining and milling costs are not shown for the Elliot Mountain Pass is an open-pit operation in a hardrock Lake, Canada, properties since they would use special leach, deposit, the operating costs are high relative to those for solvent extraction, and precipitation techniques to recover heavy mineral sands mining operations; however, the REO from a barren uranium solution. Only the costs deposit has a very high grade (12% bastnasite with 6% to associated with treating the barren uranium solution were 7% REO content) compared with that of mineral sands included in this evaluation. deposits, so that the operating costs in terms of recovered The weighted-average mine operating cost for the eight product are relatively low. Australian producers is $0.77/mt, which includes three strip The weighted-average costs for the five U.S. non- level mines and one open-pit mine averaging $1.91/mt, and producers that are mineral sands deposits (Big Creek, Bear four dredge operations averaging $0.48/mt. Since the costs Valley, Gold Fork-Little Valley, Bruswick-Altamaha, and are weight-averaged according to annual capacity, they are Oak Grove) are $0.76/mt for mining, $0.81/mt for milling, heavily influenced by the low unit costs at the North Strad- These costs are comparable with those for other world prop- broke operation of Consolidated Rutile Ltd., which is ex- erties. However, costs of transporting concentrates to ex- pected to produce nearly 40 million mt/yr ore by the late isting processing plants for titanium and rare earths would 1980's. The average mill cost is $0.40/mt for all producers. be sufficiently high, especially in the case of the Idaho The five Australian nonproducers that could recover deposits, to place them at a significant disadvantage relative byproduct monazite have a weighted-average mining cost to several other world properties. Transportation costs for of $0.74/mt, and a milling cost of $0.48/mt ore. These figures the Idaho properties are four to eight times higher than are strongly influenced by the costs at Cooloola, which is those for the western Australia properties. Additionally, the a past producer that terminated production when the area Big Creek and Gold Fork-Little Valley (Idaho) deposits have became part of the Cooloola National Park. All but Jurien multiple landowners, and the actual costs associated with Bay-Cooljarloo would be dredge operations. developing a unitized operation are not known. REO AVAILABILITY Nine of the 38 properties evaluated for this study do or Table 6 shows the distribution of revenues of the various could produce REO as the primary product. Five of these commodities that are or could be produced at the proper- properties (i.e., the Brazilian properties) would be considered ties evaluated in this study. Revenue figures were based to be titanium properties from a revenues standpoint, on January 1984 commodity prices (table 7). Figures for the although they are or could be mined for monazite because Elliot Lake, Canada, operations, which would produce REO of its thorium content. as a byproduct of uranium processing, are not included in Table 6.— Average percentage of revenues by mineral concentrate type (Based on January 1984 market prices) Country and status Rutile llemite Zircon Monazite Leucoxene Synrutile Other and bastnasite Australia: 30 54 30 17 17 16 3 3 10 10 10 Brazil: Nonproducers 13 5 31 41 25 9 31 45 India and Sri Lanka: 28 14 30 5 6 3 7 46 1 28 32 United States: 19 12 7 24 17 16 49 14 8 16 18 10 Table 7.— Market prices of mineral sand concentrates and associates minerals, January 1984 Commodity Where applicable Grade, Price, (f.o.b.) % $/mt Garnet Mill Abrasive .... . $ 10.00 Ilmenite concentrate . . Mill, Australia '54+ Ti0 2 . . 32.00 Mill, United States '54+ Ti0 2 . . 42.00 Leucoxene concentrate Mill, Western Australia 87Ti0 2 .... 225.00 Magnetite Mill NAp 23.00 Monazite concentrate . Mill 55 REO 389.00 Rutile concentrate .... Mill 95 Ti0 2 347.00 Synthetic rutile Plant, Mobile, AL, United States. 90+ Ti0 2 . . . 350.00 Titanium slag Sorel, Quebec, Canada. Richards Bay, Republic 71 Ti0 2 159.00 85 Ti0 2 181.00 of South Africa. Zircon concentrate . . . Mill, Australia 65 Zr0 2 .... 104.50 Mill, United States 65 Zr0 2 .... 182.00 1 Price does vary on Ti0 2 grade (from approximately 47% to 64% Ti0 2 ). table 6, as only the marginal costs of REO recovery were included in the evaluation. However, Y 2 3 -REO concentrate production would account for less than 1% of the total revenues from the Elliot Lake operations. Only Mountain Pass derives its total revenues from REO; therefore, the economic condition of the property is singularly dependent on the REO market. Because of the byproduct status of monazite, most properties included in this evaluation depend largely on the titanium market for their economic health. Australian producers on average derive only 3% of their revenues from monazite. Similarly, Indian and Sri Lankan producers on average derive only 7% of revenues from monazite. TOTAL AVAILABILITY Table 8 shows the cumulative total amount of poten- tially recoverable REO from all properties evaluated as a funtion of DCFROR. Figure 4 shows total potential availability by property status (producer and nonproducer), categorized by DCFROR range. Only 21% (about 705,000 mt) of the total recoverable 3,355,000 mt REO in all properties evaluated is contained in properties that could not realize a positive DCFROR at the January 1984 market prices for commodities that are or could be produced from those properties. Nearly 77% (2,578,000 mt) of total recoverable REO in all properties evaluated is contained in producing properties. A logical supposition is that the majority of these properties are operating because they can consistently produce at a pro- fit. A notable exception is the Brazilian operations, which are owned by NUCLEMON, a Government entity that has motives other than immediate profit or benefit (i.e., the need for thorium produced as a result of monazite processing). Table 8.— Cumulative total REO potentially available from 38 evaluated deposits (Thousand metric tons) DCFROR, % Producers Nonproducers Total □ 90 □ 40 1,910 1,965 2,135 2,189 2,526 702 35 65 126 1 1,910 1,965 □ 20 2,170 □ 10 2,254 □ • 2,652 703 Total 3,228 127 3,355 2,000 (1,910,000) 800 700 600 E 500 d tt 400 300 200- 100- KEY Producers Y/Z4'\ Nonproducers S3 W t~i Lfr"] <0 0-9 40-89 >90 10-19 20-39 DCFROR, % FIGURE 4.— Total recoverable REO, by property status and DCFROR. 11 About 126,000 mt, or less than 4% of the total REO in all properties analyzed, is contained in nonproducing prop- rties that could realize a positve DCFROR. Included here are the Silica Mine and Richards Bay properties, which are producing operations that are not presently recovering monazite but for which the costs of recovering monazite were included. ANNUAL AVAILABILITY Figures 5 and 6 present the amount of REO potentially available on an annual basis from producing and nonproduc- ing properties at various DCFROR ranges. Since the general approach for this study was to evaluate the proper- ties at their production capacity over the life of each prop- erty, the annual curves present total potential availability for each year shown and should not be interpreted as an assessment of future supply. The total amount of REO potentially available annual- ly from all producing properties (fig. 5) ranges from a low of 46,500 mt in 1986, to a peak of 51,500 mt in 1988-92, and declines to 49,900 mt by the year 2000. The increase between 1986 and 1988 is due to planned expansions that were included in the evaluation. Of the total amount poten- tially available in each year shown, only 6,600 mt is con- tained in properties that would not receive at least a 20% DCFROR. Total MEC production in 1984 was estimated at 40,700 mt (table 2). Clearly, the amount of REO potential- ly available from producing properties evaluated in this study (which represent 98% of total MEC production poten- tial) is sufficient to sustain present production levels through at least the end of this century. Figure 6 shows potential annual availability from non- producers on a country basis. Australian and U.S. proper- ties that could produce at positive DCFROR's together could provide only about 4,000 mt/yr REO through the year 2000. U.S. nonproducers evaluated that could not presently realize a positive DCFROR could provide 9,500 mt/yr REO over the same period; Australian nonproducers in the same category could sustain an annual output of 3,700 mt only for a few years, after which these properties could provide less than 1,000 mt/yr. Nonproducers in India and Malawi could account for a combined output of 9,200 mt/yr through 52 T T T T T =>0 % DCFROR 50 48 ro O 46 d UJ 44 42 40 J- _L 10% DCFROR T > 20 % DCFROR >40% DCFROR >90 % DCFROR J. -L 1986 1988 1990 1992 1994 1996 FIGURE 5.— Cumulative potential annual REO availability, producers. 1998 2000 12 =>0 % DCFROR oo - . 10 o UJ City or town O 100 200 300 J SOOTH AMERICA Scale, km FIGURE A-3.— Location map, Brazilian properties. MAP LOCATION Initial (wet plant) concentration for nonproducers prob- ably would be done onsite, as is presently done at the two producing operations (Anchieta and Buena). There is a dry plant at Guarapari, where concentrate from the wet plant at Anchieta, 10 km distant, is processed. The plant was tem- porarily closed in January 1982 for expansion. Buena con- centrate is processed at a nearby dry plant. Development of the Alcobaca property would require construction of a dry plant nearby. Concentrate produced at Aracruz, another undeveloped deposit, could be transported to the dry plant at Guarapari, some 100 km distant, as could concentrate from Serra, 60 km from Guarapari. For this evaluation, ilmenite and rutile from all operations were assumed to be transported to port at Vitoria, some 50 km away from the Guarapari dry plant. In all cases, monazite and zircon concentrate produced at the dry plants are (in the case of Anchieta and Buena) or would be transported to Brazil's hydrometallurgical plant at Sao Paulo, 800 km from Guarapari. In spite of the transportation requirements, and the relatively small amount of contained REO in Brazilian prop- erties compared with that in other world deposits (e.g., those that produce monazite as a byproduct of titanium mining in Australia and India), the Brazilian Government appears committed to production of monazite, largely because of its thorium content. CANADA Three Canadian properties at Elliot Lake, ON, were evaluated for this study (fig. A-4). They include Rio Algom Ltd.'s Quirke-Panel and Stanleigh Mines, and the property of Denison Mines Ltd., all of which would produce REO and Y 2 3 byproducts of uranium processing. Denison Mines first started investigating the recovery of Y 2 3 and REO in the mid-1960's, and produced a total of about 100 mt from 1974 through 1976. The plant produced a concentrate that graded approximately 40% Y 2 3 and 23% REO. Neither company presently has plans to recover REO or Y 2 3 , but these commodities were evaluated to determine their additional cost of recovery from, and potential availability in, the barren solution now produced by the uranium operations. Highwood Resources Ltd. recently announced the discovery of commercially significant quantities of yttrium 17 LEGEND /%, Property or properties 200 l 400 I 600 800 l Scale, km FIGURE A-4.— Location map, Canadian and U.S. properties. at its Thor Lake beryllium prospect near Yellowknife, NT. On the basis of preliminary assays, it is estimated that the deposit contains 3,600 mt Y 2 3 , sufficient to supply current world demand for yttrium for about 7 yr. Since informa- tion sufficient to perform an evaluation was not available at the time of this study, the Thor Lake property was not included. The Strange Lake deposit, located on the Quebec- Newfoundland border in northeastern Canada, was discovered in 1979. The deposit occurs within an alkaline complex and contains columbium, fluorite, zirconium, beryllium, and yttrium-rich rare earths. At the time of this evaluation, resource data were insufficiently known to allow for detailed analysis. Iron Ore Co. of Canada is pursuing further exploration and metallurgical studies on its prop- erty, which, if developed, could be an important source of Y 2 3 and REO. INDIA Five Indian properties were evaluated for this study, only one of which (Ranchi-Purulia, an undeveloped property) has the resources to produce rare earths as the primary product. The others, all producers, recover monazite as a byproduct of processing titanium minerals. These include two properties at Chavara, one at Manavalakuruchi, and one at Orissa-Chatrapur (fig. A-5). Together, the five prop- erties contain more than 812,000 mt recoverable REO, of which more than 85% is contained in the four properties that produce monazite as a byproduct of titanium mining. The country produced an estimated 2,200 mt REO in 1984 (table 2), most of which was shipped to the United States. Two companies, Indian Rare Earths Ltd. (IRE) and Kerala Minerals and Metals Ltd. (KMML), are responsible for all Indian production. IRE is a public company operated by the Indian Government; KMML is operated by the state government of Kerala. India prohibits the export of monazite because of its thorium content, based on thorium's future use as a nuclear fuel. IRE's mines on the west coast of India at Chavara near Quilon, and Manavalakuruchi in Tamil Nadu State, ac- count for all of that company's monazite production. The company's separation plant in Kerala State currently has an operating capacity of 4,600 mt/yr rare-earth chlorides, 78 mt/yr rare-earth fluorides, and SO mt/yr of individual REO. About 5,000 mt/yr trisodium phosphate is produced as a byproduct. IRE produces four grades of cerium oxide (Ce0 2 ) and reportedly has plans to produce yttrium, gadolinium, europium, and samarium concentrates. IRE produces 110 mt/yr thorium nitrate, small amounts of Th0 2 , and thorium pellets. The company recently began testing and partial operation of a new processing plant in Orissa, with a monazite processing capacity of 4,300 mt/yr. The plant will also produce synthetic rutile (5, p. 22; 12). KMML's mineral separation plant at Chavara (near Quilon in Kerala State) treats heavy mineral sands that are recovered from nearby deposits. Monazite constitutes 18 A ORISSA Qrltti-Chitrapur, Berhampur ; Scale, km FIGURE A-5— Location map, Indian and Sri Lankan properties. 1% of the 18% heavy mineral content of the sand. KMML's present production capacity is about 300 mt/yr monazite, but the company has plans to establish a new plant with a capacity of 1,800 mt/yr monazite by 1987. The Ranchi-Purulia deposit, located in Bihar and West Bengal States 200 km northwest of Calcutta (not shown in fig. A-5), is more than 1,000 km from India's processing plants in the southern part of the country. For this evalua- tion, it has been assumed that a beneficiation plant (with a capacity of more than 5,000 mt/yr REO in a monazite con- centrate) would be constructed near the deposit, from which five separate concentrates (monazite, ilmenite, rutile, zir- con, and sillimanite) would be shipped by rail to port at Calcutta, from which the monazite would be shipped for fur- ther processing in southern India. A new mineral sands deposit containing ilmenite, zir- con, garnet, and monazite was recently discovered in the coastal beach of the Thanjavar district of India, between Sirkali and the mouth of the Cauvery River, near Kaveripattenan. Preliminary analyses showed a higher mineral content than for the Manavalakuruchi deposit. Reserves have not been determined, but it has been reported that the deposit's monazite content is at least equal to Manavalakuruchi's (15). The property was not included in this evaluation owing to the lack of sufficient cost and resource data. MALAWI The Kankankunde deposit, part of the Chilwa car- bonatite complex in Malawi, has been under investigation since the early 1970's by Lonhro Ltd., the property's cur- rent owner. If developed, the property would be mined by open pit, treating a relatively high grade monazite ore. High iron content of the ore has necessitated special metallurgical testing, which resulted in the development of a workable process flowsheet in 1982. Political problems in neighboring Mozambique, through which the monazite concentrate could be shipped, have resulted in postponement of the property's development. An alternative transportation plan, assumed for this evalua- tion, involves transport by truck and rail to port at Dur- ban, Republic of South Africa. MALAYSIA, SRI LANKA, AND THAILAND Malaysia produced about 2,600 mt REO in 1984, near- ly all of which was from monazite, with a small amount (probably less than 5%) from xenotime, the high-grade yt- trium mineral. Malaysian rare-earth production is a byproduct of processing the tin mineral cassiterite. Beh Minerals Sdn. Bhd. has an ore concentrating plant at Lahar, in the State of Perak. Malaysian Rare Earth Corp. Sdn. Bhd. (MAREC), a joint venture between Beh Minerals and Mit- subishi Chemical Industries Ltd., has produced yttrium con- centrate containing 60% Y 2 3 since 1976; present produc- tion capacity is 80 mt/yr concentrate. At the time of this evaluation, information regarding REO grades of Malay- sian tin properties was not available; consequently, no Malaysian properties were included in this study. Monazite-bearing heavy minerals sands are located in Sri Lanka, most notably the Pulmoddai property (fig. A-5), which was evaluated for this study. Monazite production is a byproduct of titanium mining and is generally quite small, although 1982 production rose to 304 mt (5, p. 26). Thailand is a potential monazite and xenotime producer as a byproduct of recovering tin ore. Thai production is generally sporadic, but reached 162 mt monazite and 46 mt xenotime in 1982. The country exports mainly to Japan and Europe. REPUBLIC OF SOUTH AFRICA At Richards Bay in the Republic of South Africa, Richards Bay Minerals recently commissioned a monazite v extraction plant to recover the mineral as a byproduct of 19 titanium production. At the time of this evaluation (January 1984), detailed information was not available regarding the recovery operation, and the property was classified as a non- producer of rare earths. UNITED STATES U.S. production of REO in bastnasite was 25,311 mt in 1984, all of which was obtained from Molycorp Inc.'s deposit at Mountain Pass, CA (8). Production of REO from monazite properties is not readily available but was estimated to be on the order of 1,000 mt in 1982 (5, p. 24). U.S. properties evaluated for this study include: Mountain Pass, CA; Bear Valley, ID; Big Creek, ID; Gold Fork-Little Valley, ID; Brunswick-Altamaha, GA; Green Cove Springs, FL; Oak Grove, TN; Powderhorn, CO; and Silica Mine, TN (fig. A-4). Mountain Pass is the only bastnasite property evaluated, and only Mountain Pass and Big Creek have REO as the primary product. Only Mountain Pass and Green Cove Springs currently produce rare-earth minerals. Silica Mine produces only silica sand, although the deposit contains recoverable amounts of heavy minerals, including monazite. The total amount of recoverable REO from all U.S. prop- erties is nearly 2 million mt, of which more than 75% is contained in Mountain Pass and nearly 15% in the undeveloped Powderhorn deposit in Colorado. The Mountain Pass carbonatite reserves have been reported to be 36 million mt of ore grading 12% bastnasite (5, p. 25). The deposit is the world's largest producer of REO, typically accounting for nearly half of total annual world production. Molycorp is a fully integrated company, with rare-earth processing facilities at York and Washington, PA; Louviers, CO; and Mountain Pass, CA. The Mountain Pass facility produces three standard bastnasite concen- trates grading 60%, 70%, and 85% contained REO. Powderhorn is a large carbonatite-alkalic stock complex, owned by Buttes Gas and Oil Co., and located in Gunnison County, CO. The deposit was reported to contain 419 million mt identified resources, of which 271 million mt is demonstrated (16). Average grade is 12% Ti0 2 in perovskite, which also contains rare earths. Based on the proposed pro- duction level of nearly 4 million mt/yr ore, an open-pit opera- tion could produce more than 4,500 mt/yr of contained REO. Green Cove Springs, the only U.S. producer of monazite evaluated in this study, is a mineral sands property that was acquired by AMC Ltd., a subsidiary of Renison Goldfields Ltd., in 1980. The company also owns the Ene- abba and Capel properties in Australia. The Green Cove Springs operation had ceased production in 1978 under previous ownership by Titanium Enterprises, but monazite continued to be recovered from reprocessed tailings until mining restarted. The operation has a present capacity of 700 mt/yr monazite, or 400 mt/yr REO (5, p. 21). The Bear Valley, Big Creek, and Gold Fork-Little Valley heavy mineral sands properties all occur in the same general region of west-central Idaho, adjacent to the Idaho batholith, a large igneous intrusion from which the minerals were derived. Mineral sands deposits in Long Valley and Bear Valley were dredged during the 1950's for monazite; ilmenite, garnet, zircon, columbite, and the radioactive minerals euxenite and samarskite were also recovered. Although there are extensive mineral sands deposits in the west-central Idaho region, it is unlikely that develop- ment will occur in the near future. A portion of the Gold Fork property has been inundated by the Cascade reservoir, and extensive mining in Bear Valley would be a matter of environmental concern owing to its close proximity to a wilderness area. Nevertheless, the area was mined in the past and contains significant amounts of potentially impor- tant rare-earth minerals. n V He "*U £* <%> o *\ *< ,. x*' /s&kS ***&*** ^d* „-i°* iV "ot? iOv, 0> *, y ^ V^, o -0/ oHO, o5 °^ .1 1^ ..**•. "^ ,5°^ "o. 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