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OU <">■ f oK O * „0 r^O^ o v ^5 'o.l* A v^ a5°^ a5°^ v^ .'^'* ** * 4r ^ • > V °^ ° " ° *v** •«■- w -A %^ ^°*-fc % - /#\ /#\ / .-*X./ ->^:- -./ ••''' 1 "" ■\°^ . ,0 ,\ v O * » » o < v ^ • "^ A^ s -^ G" ♦ .* *.jtfkX ../\-ifc\, .**,*&•> M «> °s> o_ •> r oV .0 -t\ > ^ A" *W °> ^ :»: ^ *° v* .-ate- V^ ;isate-."^^'/iaK\"V j> % #"% I-* ^ V c o " ° . *^> J 4- *; *J-v 1* <>'ffi\ vC ^!l^s"'" '*p> 4 <** -^ ^ .' <&* ^ : ^ V -V. v •p C,"'^ 'WW' A.V<^ -^lii^ t^^rv 'jtifcS J^^^kS ^*a&k°» ^-^t^ ^ *; ' V fife V ffe V ^ V -'181' V ; ft % Bureau of Mines Information Circular/1986 Columbium Availability— Market Economy Countries A Minerals Availability Appraisal By Federick W. Miller, R. J. Fantel, and D. A. Buckingham UNITED STATES DEPARTMENT OF THE INTERIOR Information Circular 9085 Columbium Availability— Market Economy Countries A Minerals Availability Appraisal By Federick W. Miller, R. J. Fantel, and D. A. Buckingham UNITED STATES DEPARTMENT OF THE INTERIOR Donald Paul Hodel, Secretary BUREAU OF MINES Robert C. Horton, Director As the Nation's principal conservation agency, the Department of the Interior has responsibility for most of our nationally owned public lands and natural resources. This includes fostering the wisest use of our land and water resources, protecting our fish and wildlife, preserving the environment and cultural values of our national parks and historical places, and providing for the enjoyment of life through outdoor recreation. The Department assesses our energy and mineral resources and works to assure that their development is in the best interests of all our people. The Department also has a major responsibili- ty for American Indian reservation communities and for people who live in island territories under U.S. administration. V Library of Congress Cataloging-in-Publication Data Miller, Frederick W. Columbium availability -market economy countries. (Bureau of Mines information circular;9085 )• Bibliography: p. Supt. of Docs, no.: I 28.27: 1. Niobium industry. 2. Market surveys. I. Fantel, R. J. (Richard J.) II. Buckingham, D.A. (David A.) III. Title. IV. Series: Information circular (United States. Bureau of Mines);|9085 TN295.U4 [HD9539.N542] 622 s [338.27499] 86-600050 Ill PREFACE The Bureau of Mines is assessing the worldwide availability of selected minerals of economic significance, most of which are also critical minerals. The Bureau iden- tifies, collects, compiles, and evaluates information on producing, developing, and ex- plored deposits, and on mineral processing plants worldwide. Objectives are to classify both domestic and foreign resources, to identify by cost evaluation those demonstrated resources that are reserves, and to prepare analyses of mineral availability. This report is one of a continuing Series of reports that analyze the availability of minerals from domestic and foreign sources. Questions about, or comments on, these reports should be addressed to Chief, Division of Minerals Availability, Bureau of Mines, 2401 E St., NW., Washington, DC 20241. CONTENTS Page Page Preface 'in Beneficiation methods 9 Abstract 1 Smelting methods 10 Introduction 2 Columbium deposit costs and evaluation 10 Acknowledgments 2 Costing methodology 10 Columbium industry 3 Operating costs 10 Evaluation methodology 5 Capital costs 12 Methodology 5 Columbium availability 12 Deposit selection criteria 5 Economic evaluation methodology 12 Resources 7 Total availability 13 Geology 8 Annual availability 16 Mining and processing of columbium 8 Conclusion 19 Mining methods 8 References 20 ILLUSTRATIONS 1. Location of MEC pyrochlore deposits 3 2. Estimated MEC mine production, 1983 4 3. Estimated MEC ferrocolumbium production, 1983 5 4. Flow chart of evaluation procedure 6 5. Mineral resource classification categories 6 6. Demonstrated columbium resources 7 7. Typical process flowsheet for pyrochlore mill 9 8. Operating cost comparison for columbium mines and deposits 11 9. Estimated capital cost required to develop nonproducing deposits 12 10. Recoverable columbium from evaluated mines and deposits 14 11. Total cost and total recoverable columbium from MEC mines and deposits 15 12. Total cost and total recoverable columbium from Americas as compared with data for all selected deposits 15 13. Total cost and total recoverable columbium from nonproducers at 0- and 15-pct DCFROR 16 14. Potential annual production from producing mines 17 15. Potential annual production from selected nonproducers at selected ranges of total production costs 17 16. Potential annual production from nonproducers for selected years 18 17. Potential annual production from selected mines and deposits excluding Brazil 18 TABLES 1. Columbium deposit ownership and status data 2 2. Summary of columbium resources in market economy countries 7 3. Breakdown of operating cost expressed as a percentage of total costs H 4. Mine, mill, and smelter operating cost by principal component 12 5. Breakdown of capital costs required to develop nonproducing columbium deposits in North America and Africa ... 12 6. Total recoverable tonnages of columbium and ferrocolumbium 14 UNIT OF MEASURE ABBREVIATIONS USED IN THIS REPORT °c degree Celsius mt/h metric ton per hour g gram mt/yr metric ton per year g/mt gram per metric ton mm millimeter h hour Mmt million metric tons kg kilogram /*m micrometer m meter pet percent min minute lb pound mt metric ton yr year COLUMBIUM AVAILABILITY— MARKET ECONOMY COUNTRIES A Minerals Availability Appraisal By Frederick W. Miller, 1 R. J. Fantel, 1 and D. A. Buckingham 2 ABSTRACT The Bureau of Mines has investigated the availability of columbium from 19 deposits (3 producers and 16 nonproducers) in 7 market economy countries (MEC's). Brazil has the largest recoverable columbium resource, posessing approximately 2.39 million metric tons (Mmt), or 69 pet of the MEC total (3.47 Mmt). The Western Hemisphere countries of Brazil, Canada and the United States contain 3.14 Mmt of recoverable columbium or 90 pet of the MEC total. Columbium recovered as a byproduct of tin mining is not included as part of MEC resources in this study. Currently producing mines are Araxa and Catalao in Brazil, and Niobec in Canada. These three mines have 2.42 Mmt of recoverable resources or approximately 69 pet of the MEC total. It is estimated that these mines, operating at full capacity, could satisfy cumulative MEC demand (based on an annual growth rate of 5.1 pet) for the next 20 yr. The United States is totally dependent upon foreign sources for its columbium supply. The majority of U.S. columbium is imported from Brazil in the form of steelmaking- grade ferrocolumbium. Canada has been the sole source of pyrochlore concentrates since Brazil discontinued exports in 1981. The United States also imports small (but impor- tant) quantities of columbium as columbite concentrates from Nigeria and Brazil, as col- umbite contained in tin slags from Thailand and Malaysia, and as synthetic concentrates from the Federal Republic of Germany. 'Physical scientist. 2 Geologist. Minerals Availability Field Office, Bureau of Mines, Denver, CO. INTRODUCTION The primary use of columbium (niobium) is as an alloy- ing element in steels and superalloys. It has been estimated that 85 to 90 pet of columbium production in market economy countries 3 (MEC's) is presently consumed by the steelmaking industry in the form of ferrocolumbium (1).* Columbium occurs primarily in two mineral forms, pyrochlore (Na, Cah Cb^O, OH, F>7 and columbite 6 (Fe, Mn) (Cb, Ta)20 6 . Mill concentrates produced from either mineral form contain approximately 60 pet columbium pentoxide (CD2O5), equivalent to about 42 pet Cb (2). Columbium con- centrates are principally recovered from pyrochlore minerals and, to a lesser extent, from columbite minerals. The most common upgraded form of columbium produced from pyrochlore concentrates is steelmaking-grade fer- rocolumbium. Recently, technology has been developed to convert this ferrocolumbium to columbium oxide suitable for the manufacture of high-purity ferrocolumbium, nickel- 3 Information on columbium resources located in the U.S.S.R. or other cen- trally planned economy countries (CPEC's) is not available and is not ad- dressed in this evaluation. 4 Italic numbers in parentheses refer to items in the list of references at the end of this report. 6 Columbite is the columbium-rich member of the columbite-tantalite isomorphous series. columbium, and columbium metal (2). Prior to this technology, production of high-purity oxides was possible only through the processing of columbite ores. This develop- ment has greatly increased the market importance of pyrochlore ores. The purpose of this study is to evaluate columbium resources of the MEC and to assess the production costs of recovering ferrocolumbium. Table 1 lists 19 columbium deposits in 7 MEC's included in this study; figure 1 shows their locations. The majority of MEC columbium resources are found in Brazil and Canada. The United States is a major consumer of columbium products, totally dependent upon foreign sources for all of its columbium. More importantly, the U.S. ferrocolumbium industry could be threatened by the tendency of major col- umbium mine owners to further vertically integrate their operations to produce upgraded columbium products. If these producers were to supply upgraded columbium prod- ucts at significantly lower costs, the U.S. columbium in- dustry could be at a distinct economic disadvantage. Subse- quently, if the United States lost a major share of its proc- essing capability because of increased competition from abroad, it would become totally dependent upon imports for both columbium concentrates and upgraded columbium products (2). ACKNOWLEDGMENTS The authors would like to thank Larry D. Cunningham, Columbium Specialist of the Bureau's Division of Ferrous Metals in Washington, DC, for his assistance in the review of the data used in this report. Table 1.— Columbium deposit ownership and status data Nation and deposit name Owner Status' United States: Gem Park Complex' Iron Hill 2 Brazil: Araxa Catalao Catalao Ouvidor . . . Canada: Crevier James Bay Lackner Lake Martison Lake Nemegosenda .... Niobec Oka Strange Lake Thor Lake Kenya: MrimaHill Tanzania: Panda Hill . Uganda: Sukulu Hills . Zaire: Bingo Lueshe Coca Mines, Inc Buttes Gas and Oil Co. CBMM Mineracao Cataloa de Goias S.A. Goias Niobio S.A SOQUEM Esso, Morrison, Canray, Argor Mertec Resources Develop Ltd New Venture Equities/Cambell Resources Gulf Agric Chem. Co. Ltd Teck Corp., SOQUEM St. Lawrence CB, Metals Corp Iron Ore Co. of Canada Highwood Resc, Calabros Ltd Mnma Industrial Minerals State Mining Corp. (STAMICO) Sukula Mines Limited Somikivu . . do ... NP NP P D P NP NP NP NP NP P NP NP NP NP NP NP NP NP 'P producing. 'Colorado. D Developing. NP Nonproducing. COLUMBIUM INDUSTRY Columbium serves as an alloying element in high- strength, low-alloy (HSLA) steels and superalloys. HSLA's are so named because of their relatively high strengths, ob- tained by the addition of very modest amounts of alloying elements (less than 1 pet alloying, other than carbon and manganese). This strengthening effect has led to wide- spread use of HSLA steels in oil and gas pipeline steels, in lighter, more fuel-efficient automobiles, and in the construc- tion of massive structures such as skyscrapers, bridges, and nuclear reactors (3). Columbium is also used as a "carbide stabilizer" in stainless steels to improve their resistance to corrosion when used in exhaust manifolds, fire walls, and pressure vessels. Cobalt-, nickel- and iron-based superalloys, containing between 1.0 to 5.0 pet Cb, are used to make gas-turbine engine components, rocket-nozzle subassemblies, and heat- resistant combustion equipment. New applications of columbium-containing supercon- ductors are being tested for future energy generation and transmission needs (2). Superconductors have the ability to Gam Park Complex Iron Hill Araxa Catalao Cotolao Ouvidor Crtvitr Jomts Bay Lackntr Lakt Morrison Lakt Ntmagottnda Niobec Oka Strangt Lakt Thor Lakt Mrimo Hill Panda Hill Sukulu Hills Bingo Lutsht FIGURE 1.— Location of MEC pyrochlore deposits. lose all resistance to direct electrical current at temperatures near absolute zero (3), and columbium has unrivaled properties of superconductivity relative to other pure metals. Therefore, most commercial superconductor devices use columbium alloys such as columbium-titanium (CbTi) or columbium-tin (CbsSn). The majority of columbium concentrates are derived from the beneficiation of pyrochlore ores. Columbite ores, including columbite and columbite-tantalite mineral ores, were once the primary source of columbium, but their significance has diminished in recent years. Advances in technology have made possible the production of high-purity oxides through further processing of ferrocolumbium pro- duced from pyrochlore concentrates (2). Previously, colum- bite ores were the major source of the oxides necessary for columbium-based alloys and superalloys. New technology, combined with the immense resource of pyrochlore ores, has almost totally replaced the use of columbite minerals as a source of columbium. Brazil is the world's largest producer and processor of col- umbium (fig. 2), most of which is recovered from two pyrochlore deposits. 6 The pyrochlore deposit at Araxa, owned by Campanhia Brasileira de Metalurgia e Mineracao (CBMM), has been in operation since 1961 and is the world's largest known col- umbium deposit. CBMM is owned by Campanhia Metropolitana de Comercio e Participacoes (55 pet) and Molycorp Inc. (a subsidiary of Union Oil Co. of California) of the United States (45 pet). Brazil's other operating pyrochlore mine, located at Catalao and owned by Mineracao Catalao de Goias S.A. (MCG), began operation in 1976. A 70-pct share of MCG was purchased by the Anglo- American Group in November 1984, with the balance (30 pet) held by Unamina, a local group of investors. Develop- ment of a third pyrochlore mine, Catalao Ouvidor, began in 1981. This deposit is owned by Goias Niobio S.A., and was tentatively slated to begin production in 1985. Partners of Goias Niobio S.A. include Produtos Metallurgico S.A. (51 pet), Metais de Goais (24 pet), and Fibase, a subsidiary of National Economic Development Bank (25 pet). The majority of Brazilian mine production concerns the manufacture of steelmaking-grade ferrocolumbium. By 1980, Araxa had vertically integrated its operation to in- clude production of high-grade columbium oxides and by 1982, it had discontinued exporting pyrochlore concentrates (4). Canada is the second largest MEC producer and its only exporter of pyrochlore concentrates. The Niobec Mine, located near the town of St. Honore in Quebec Province, has been Canada's only operating pyrochlore mine since it began production in 1976. Ownership of Niobec is split evenly be- tween Societe Quebecoise d'Exploration Miniere (SOQUEM, a corporation of the Quebec Provincial Govern- ment) and Teck Corporation. The Oka Mine, also in Quebec, is owned by the St. Lawrence Columbium & Metal Corp. It began operation in 1961 but was closed in 1976 because of labor and economic problems. Substantial reserves remain at Oka and are included in this evaluation. Owners of the Leushe deposit in Zaire completed con- struction of a 2 mt/h pilot plant in March 1984. The pilot plant was set up by a joint venture of Sovaikubi (Societe Miniere Zairoise de Nyamukubi), Coframines, and Metallurg Inc. Commercial production is expected to begin 6 Less than 1 pet of the columbium mined in Brazil is recovered as columbite from pegmatite mines that were not examined in this study. Others 3 pet Total, 8,471 mt (Contained Cb) FIGURE 2.— Estimated MEC mine production, 1983. by the end of 1986 (5). The Leushe deposit is owned by Somikivu (Kivu Mining Co.) in which Metallurg holds a 70-pct share, the Zaire Government 20 pet, and Sominki (Societe Miniere et Industrielle du Kivu) 10 pet. Columbium is considered a strategic and critical mineral to U.S. interests because of its defense-related uses in the aerospace, energy, and transportation industries. Colum- bium has not been mined commercially in the United States since 1959, except for small unreported quantities of columbium-bearing concentrates produced in 1980-82 (J+). Therefore, the United States is totally dependent upon foreign imports of columbium, primarily in the form of fer- rocolumbium or columbium oxides from Brazil and pyro- chlore concentrates from Canada. The United States im- ports smaller amounts of columbium in the form of colum- bite concentrates from Nigeria, tin slags from Malaysia and Thailand, and synthetic concentrates made by upgrading low-grade tin slags from the Federal Republic of Germany. Imports of columbite, especially from Nigeria, have been declining steadily. The U.S. columbium processing industry consists of eight companies with nine plants integrated through the process- ing of columbium concentrates to upgraded end products, including columbium metal (2). U.S. industry is potentially threatened by the continued vertical integration of foreign mines, principally in Brazil, through the production of high- grade columbium products. Brazil's share of the U.S. fer- rocolumbium market has increased from pet 20 yr ago, to nearly 75 pet (4). It is possible that this trend will lead to total U.S. dependence on foreign sources for all columbium products. Columbium stored in the National Defense Stockpile, as of November 30, 1984, amounts to 1,271 mt (2.8 M lb) con- tained columbium, primarily in the form of concentrate and ferrocolumbium, with smaller amounts contained in carbide Total, 10,340 mt FIGURE 3.— Estimated MEC ferrocolumblum production, 1983. powder and columbium metal (4). The last sale from this stockpile was in 1976. In 1984, bids solicited by the General Services Administration to supply up to 400,000 lb of colum- bium contained in concentrates for the stockpile were re- jected because they were too expensive and did not conform to prevailing market conditions. (4). In 1983, MEC production of ferrocolumbium was estimated by the Bureau of Mines Columbium Specialist at 10,340 mt (6). Figure 3 shows the breakdown of MEC fer- rocolumbium production by country and illustrates Brazil's control of an estimated 67 pet of the industry. Important amounts of ferrocolumbium are also produced using im- ported pyrochlore and columbite concentrates in the United States, Western Europe, and Japan. European producers of ferrocolumbium include Austria, Belgium-Luxembourg, the United Kingdom and the Federal Republic of Germany. The United States is currently the largest producer of colum- bium metal. Overall U.S. consumption of columbium increased from 2,600 mt in 1983 to 3,500 mt in 1984, owing to increased consumption by steel and automotive industries (4). This reverses the 30-pct decrease reported in overall U.S. con- sumption in 1982 from the record high established in 1981 EVALUATION METHODOLOGY METHODOLOGY Data collected for this report are stored, retrieved, and analyzed in a computerized component of the Minerals Availability Program (MAP). Data for foreign mines and deposits used in the evaluation were collected by Pincock, Allen & Holt, Inc., under Bureau of Mines contract J0225022 ( to O o _) < o 1 1 KEY 1 — ■ 1 1 ie _ nr+ nrrpop 0-pctDCFROR ~ i i i i _, -"'"' i - i - i _j — ' i — ■ i 1 — J" 1 ■ i i 10- 5- 0.2 1.0 0.4 0.6 0.8 RECOVERABLE C0LUMBIUM, Mmt FIGURE 13.— Total cost and total recoverable columblum from nonproducers at 0- and 15-pct DCFR0R. I.2 However, the dominance of the Brazilian and Canadian pro- ducers, in terms of low-cost levels and sizable resources would likely inhibit any such development even at the breaP even level. ANNUAL AVAILABILITY Annual availability curves portray the potential annaul availability of recoverable columbium contained in fer- rocolumbium within a specified range of total cost. Annual curves as presented assume each operation will produce at full capacity over its life and should not be interpreted as true supply curves. An annual availability curve for the three producing mines is presented in figure 14. At a total cost of less than $6/lb, current producers have the capacity to produce up to 20,800 mt/yr Cb as contained in ferrocolumbium. However, due to low demand, estimates of actual production for 1983 amounted to only 10,000 mt from the three producing operations (6). Obviously, operating mines are producing at greatly reduced levels; in fact, at less than 50 pet of capaci- ty. Figure 14 demonstrates that at full capacity and current demand levels, producers of columbium have the potential to supply projected annual MEC demand into the next cen- tury. Annual availability curves for nonproducing deposits at a total cost of $6/lb, $12/lb and $24/lb. (including a 15-pct DCFROR) are shown in figure 15. This figure demonstrates that significantly higher prices than current levels must prevail in order to cover the high costs of production associated with these properties. At a total cost of $6/lb or less for columbium contained in ferrocolumbium, non- producers have a combined capacity of nearly 4,000 mt/yr. An additional 7,000 mt/yr is potentially available at a cost of production up to $12/lb. At a maximum total cost of $24/lb, the potential availability from nonproducers could increase to 20,000 mt/yr. Figure 16 shows potential annual availability of colum- bium and total cost for nonproducers 5, 10, and 20 yr from the study date 'N'. Figures 15 and 16 show production from nonproducers would peak 8 to 15 yr after the base year 'N', then gradually decrease. This decline in production would continue as current resources were depleted, assuming ad- ditional resources were not discovered and technological im- provements were not made to process lower-grade materials. Though unlikely, it is important to consider the effects of a cut off of production by Brazil on MEC availability of co- lumbium and its ramifications regarding U.S. industries (fig. 17). Brazilian production presently accounts for almost 70 pet of MEC ferrocolumbium. This figure assumes that the only remaining producer, Niobec, would maintain a stable level of production but could not respond to such an increased demand. To maintain the estimated 1983 produc- tion levels of 10,000 mt (fig. 16) would require a total cost of production of up to $12/lb contained columbium. In addition, it would require approximately 6 to 8 yr to achieve this pro- duction level. A total cost of approximately $24/lb would be required to reach existing capacity levels. This scenario reiterates Brazil's importance to the MEC columbium in- dustry. 17 10 1984 1988 1992 1996 2000 FIGURE 14.— Potential annual production from producing mlnoa. 2004 O 2 00 o o UJ -J 00 < & 5 o UJ or N r J ' r - 1 — Year preproduction development begins 1 1 i "T" — 1 \ \ \ 20 15 / / / / / / / / / / / ""^^l 24.00 $12.00 IO 5 ( 1 1 / .•• / : l •' ^ $6.00 • • i • i i 1 e 1 1 JL N N+2 N+4 N+6 N+8 N+K) N+12 N+14 N+16 N+18 N+20 YEAR FIGURE 15.— Potential annual production from selected nonproducers at selected ranges of total production costs. 18 25 20 -e9- cd 15 0> c o »-* o o 10 < +- o N Year preproduction development begins ± N + 201 _L N + IO 5 10 15 ANNUAL RECOVERABLE COLUMBIUM, I0 3 mt FIGURE 16.— Potential annual production from nonproducers for selected years. 20 O 3 CD 3 _J o o UJ _» m < UJ 3 o UJ £D I I — I 1 1 N Year preproduction — i 1 1 — ■ i 20 15 / / / / / / / / / / S S / " ~ ^ $24.00 \ \ V $12.00 1 1 1 \ 10 1 r ~ $6.00 5 / / /^ i i i l /••■ / 1 i i i i N+2 N+4 N+6 N+8 N+K) N+12 N+W N+16 N+18 N+20 YEAR FIGURE 17.— Potential annual production from selected mines and deposits excluding Brazil. 19 CONCLUSION Columbium is used primarily as an alloying element in high-strength, low-alloy steels and superalloys. For this pur- pose, approximately 85 to 90 pet of the columbium con- sumed is processed to ferrocolumbium for use in the steel in- dustry. Most of the remainder is upgraded to high-purity columbium products for use in cobalt, nickel, and iron-based superalloys and superconductors. Columbium has not been mined commercially in the United States for many years, and U.S. ferrocolumbium producers rely solely on colum- bium imports. A total of 19 deposits (3 producing mines and 16 non- producers) were examined to determine MEC availability of columbium. The selected deposits included all known resources of columbium, meeting the criteria for this study. In situ demonstrated resources total over 946 Mmt for the 19 deposits. Total columbiifm contained in these resources amounts to approximately 5.36 Mmt. This figure includes 3.25 Mmt in Brazil, 1.37 Mmt in North America (Canada and the United States), and 0.75 Mmt in Africa (Kenya, Uganda, Tanzania, and Zaire). In all cases, columbium oc- curs in the mineral form of pyrochlore or its barium- strontium analog, pandaite, and is found in association with the carbonatite member of alkalic-granite complexes. All pyrochlore is currently mined from carbonatite deposits. In the past, pegmatitic rocks have served as the principal source of columbium as contained in the mineral columbite. However, due to the abundance and increased utilization of pyrochlore ore, pegmatitic sources of columbite have been reduced to a less than 5-pct share of the MEC market for columbium In terms of potential total availability, Brazil is the largest and lowest-cost source of recoverable columbium in the MEC. Total recoverable columbium (contained as 65 to 66 pet in ferrocolumbium) in Brazil amounts to 69 pet (2.39 Mmt) of the MEC supply. Recoverable columbium resources from the Americas account for over 90 pet of the total MEC resources studied, totaling 3.14 Mmt. Current producers of columbium examined for this study include the Araxa and Catalao mines in Brazil, and the Niobec mine in Canada. Combined, these mines contain suf- ficient resources to supply the estimated cumulative MEC columbium demand through the year 2000, based on a 5.1-pct annual growth rate. Potentially recoverable columbium resources from MEC nonproducers total 1.05 Mmt. Of this, only 8 pet or 0.08 Mmt are available at a total cost of production (including a 1 5-pct DCFROR) at, or below, the January 1984 market price of $6/lb Cb contained in ferrocolumbium. A cost of $12/lb, comparable to twice the current market price, is re- quired to make available 40 pet of the recoverable colum- bium contained in nonproducing deposits. Even then, this amounts to only 12 pet of the total available from all studied deposits. The United States is totally dependent upon foreign sources of columbium, principally in the forms of fer- rocolumbium for steelmaking from Brazil and pyrochlore concentrates from Canada. Furthermore, Brazil has in- creased its production of ferrocolumbium and other high- grade columbium products in recent years, resulting in a decrease in U.S. production. Twenty years ago, the United States produced nearly all its ferrocolumbium; today, U.S. production has declined to 25 pet. Brazil's abundant, low- cost supplies may continue to increase U.S. dependency on that country for the high-grade columbium products used in superalloys. Analyses indicate that columbium is available from undeveloped deposits outside of Brazil but at costs of production significantly greater than current costs (even at a 0-pct DCFROR). Also, these deposits require a period of up to 8 yr to develop. As a result, Brazil is expected to main- tain its position as the world's major columbium producer, into the foreseeable future. 34S7 47 20 REFERENCES 1. Cunningham, L. D. Columbium and Tantalum. Ch. in BuMines Minerals Yearbook 1982, v. 1, pp. 259-269. 2. Cunningham, L. D. Columbium. BuMines Mineral Commodity Profile, 1983, 14 pp. 3. Manker, Edgar A. Columbium- An Outlook. CIM Bull., v. 74, No. 832, 1981, pp. 93-99. 4. Cunningham, L. D. Columbium. Sec. in BuMines Mineral Commodity Summaries 1985, pp. 38-39. 5. Mining Journal (London). Zaire Reaps Some Rewards. V. 305., No. 7822, July 19, 1985, pp. 37-39. 6. Cunningham, L. D. Columbium and Tantalum. Ch. in BuMines Minerals Yearbook 1983, v. 1, pp. 265-275. 7. Cunningham, L. D. Columbium. Sec. in BuMines Mineral Commodity Summaries 1983, pp. 38-39. 8. Kuestermeyer, A.L., and Scott, R.J. 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