No. 9112 Set 2 o* t ,t».. W A v . « g°\C^^o r.\/ A"; \S .M*v \/ #k * %'*???-- #> v^ f V V A°* ;- ."leu A '^V <^ *^7.s* G^ *CL "o V O * ON o- .o -^ -.-e-^"V V v V .*3ta \/ .-^r. %,♦♦ .^--. \/ .•^^•. %,** <5y ^ V <<* ♦'♦. -.soiiiif; ^'"^ o o' t ow ) * tt a^'^u J »^Hier»° ^"^ °,w\¥; a^'^ -. 5^111^ *° ^"^ °< i~ .r »r •% ^\. •^ *o ^o* ^^ *4°* ^..V^-fO' X^'/ V^V %*^V V'^^ %/ A G ^ v °« iVl V s 'o.T* A <. *7TVT* ,G^ 'o, *••** A *6? 4° ^ '~ *bY b V . .4- ^ ^. V "Pj. 4 "O *o . » " A g° *^m^:, o s ' n*V 1 ^* ^o -J <<* ,f u ^ *•'• A V» •" X ^r^ / \^.'\/ V-^V V^ f \/ v-^v v^- : '&M° ***** -MM;- ^ ; ^&°° ***<** -*^fe- ^^ : ^fe° *w* -^ ^\ ''Wg?s J*\ °Wws^% *-i5P^ ^^% a -w^s ****** ^1§R ; «/\ °*y *^W$ A? ^V^^VcP \,^^^*\^ °o/%^ , \o' 5 *%,^^^* J^ °o.*^^ # \o ' *^T* .G v w "o. '".T* A ^>, *o . » * A ^ .. ^ ' ^ G ... °v < v p ^°^ tP-^ Bureau of Mines Information Circular/1986 Magnesium Availability — Market Economy Countries A Minerals Availability Appraisal By D. R. Wilburn UNITED STATES DEPARTMENT OF THE INTERIOR Information Circular 9112 l\ Magnesium Availability — Market Economy Countries A Minerals Availability Appraisal By D. R. Wilburn UNITED STATES DEPARTMENT OF THE INTERIOR Donald Paul Hodel, Secretary BUREAU OF MINES Robert C. Horton, Director As the Nation's principal conservation agency, the Department of the Interior has responsibility for most of our nationally owned public lands and natural resources. This includes fostering the wisest use of our land and water resources, protecting our fish and wildlife, preserving the environment and cultural values of our national parks and historical places, and providing for the enjoyment of life through outdoor recreation. The Department assesses our energy and mineral resources and works to assure that their development is in the best interests of all our people. The Department also has a major responsibility for American Indian reservation communities and for people who live in island territories under U.S. administration. \& >* ^ f'J t / Library of Congress Cataloging-in-Publication Data Wilburn, D. R. (David R.) Magnesium availability — market economy countries. (Information circular; 9112) Bibliography: p. 23 Supt. of Docs, no.: I 28.27:9112 1. Magnesium industry and trade. I. Title. II. Series: Information circular (United States Bureau of Mines); 9112. TN295.U4 [HD9539.M25] 622 s [553.4'9291 86-600289 Ill PREFACE The Bureau of Mines is assessing the worldwide availability of selected minerals of economic significance, most of which are also critical minerals. The Bureau identifies, collects, compiles, and evaluates information on producing, developing, and explored deposits, and mineral processing plants worldwide. Objectives are to classify both domestic and foreign resources, to identify by cost evaluation those demonstrated resources that are reserves, and to prepare analyses of mineral availability. This report is one of a continuing series of reports that analyze the availability of minerals from domestic and foreign sources. Questions about, or comment on, these reports should be addressed to Chief, Division of Minerals Availability, Bureau of Mines, 2401 E St., NW„ Washington, DC 20241. CONTENTS Page Preface iii Abstract 1 Introduction 2 Commodity overview 2 Background 2 Use 2 Marketing and pricing structure 4 World magnesium production, consumption, and trade 4 Identification and selection of deposits 7 Methodology 9 Geology 10 Dolomite 10 Magnesite and brucite 10 Seawater 10 Lake brines 10 Well brines 11 Magnesium resources 11 Extraction and processing technology 13 Page Seawater and brines 13 Extraction 13 Processing 13 Magnesite, brucite, dolomite, and olivine 13 Extraction 13 Nonmetallic magnesia processing 13 Magnesium metal processing 14 Electrolytic processing 14 Thermic processing 14 Production costs 14 Capital investments 15 Operating costs 15 Magnesium availability 16 Total availability 17 Annual availability 20 Factors affecting availability 21 Conclusions 22 References 23 Appendix. — Areas and source materials excluded from this study 24 ILLUSTRATIONS Page 1. Domestic magnesium metal end use pattern, 1984 3 2. Domestic magnesium compound consumption pattern, 1984 3 3. Minerals Availability program deposit evaluation procedure 9 4. Mineral resource classification categories 11 5. Total potential magnesium metal availability from evaluated MEC properties 18 6. Total potential deadburned and caustic calcined MgO availability from evaluated MEC properties 19 7. Total potential domestic availability of deadburned MgO from evaluated properties 20 8. Annual availability of magnesium metal, deadburned MgO, and caustic calcined MgO at various prices ... 21 9. Energy costs as a percentage of total operating costs 22 TABLES Page 1. Industrial uses of magnesium compounds 3 2. Market prices for selected magnesium products, January 1982 to January 1985 . 4 3. Production statistics for metallic and nonmetallic magnesium products, 1970-84 5 4. Principal magnesium producing, exporting, and importing countries 6 5. U.S. import duties for selected magnesium products 7 6. Deposits selected for evaluation 8 7. Demonstrated MEC magnesium resources, January 1985 12 8. Production costs for selected producing operations from various source materials 16 9. Operating cost breakdown for producing magnesium operations 16 10. Total production cost summary for selected magnesium products from producing operations and various source materials 16 11. Byproduct commodity prices, January 1984 16 12. Availability of magnesium metal and MgO compounds from selected MEC properties including a 15-pct DCFROR at selected cost ranges 18 13. Summary of domestic and foreign magnesium demand forecasts 21 14. Energy requirements for magnesium metal production 21 UNIT OF MEASURE ABBREVIATIONS USED IN THIS REPORT op degree Fahrenheit MMst million short tons ft foot pet percent gal/min gallon per minute St short ton in inch st/yr short ton per year in/yr inch per year wt pet weight percent kW-h/lb kilowatt hour per pound wtd av weighted average lb pound yr year MAGNESIUM AVAILABILITY— MARKET ECONOMY COUNTRIES A Minerals Availability Appraisal By D. R. Wilburn 1 ABSTRACT The Bureau of Mines investigated the potential availability of magnesium from 45 properties in market economy countries (MEC's). The 38 significant deposits evaluated have demonstrated resources of approximately 29 billion short tons (st) magnesium- bearing material containing 416 million short tons (MMst) magnesium oxide (MgO). Using data it gathered, the Bureau determined the magnesium production potential for each property including a 15-pct rate of return on invested capital. Total and annual availability assessments for the next 30 yr were completed for magnesium (Mg) metal, deadburned MgO, and caustic calcined MgO. At a January 1984 market price of $1.34/lb Mg metal, the properties evaluated could economically produce an estimated 13 MMst Mg metal. At a market price of $400/st nonmetal magnesium product, these properties could economically produce 109 MMst deadburned MgO and 43 MMst caustic MgO. These properties could produce approximately 301,000 st Mg metal, 3.0 MMst deadburned MgO, and 430,000 st caustic MgO annually at current full production levels and 1984 market prices until at least the year 2000. Total 1984 MEC production assessed in this study was 153,000 st Mg metal and 4.3 MMst nonmetallic MgO products. 'Physical scientist, Minerals Availability Field Office, Bureau of Mines, Denver, CO. INTRODUCTION Magnesium is considered by the Bureau of Mines to be a critical commodity for the United States because of its extensive use in a variety of industrial and military applications. Its low density has encouraged its use in structural applications where it competes with aluminum. Refractory applications, particularly by the iron and steel industry, represent the largest tonnage use of magnesium in compounds. Magnesium as a mineral commodity is marketed in manj r product forms; availability estimates in this study are restricted to magnesium metal and nonmetallic magnesium in the forms of deadburned (refractory grade) and caustic calcined (chemical-grade) magnesia (MgO). Magnesium can be recovered from ores, seawater, or naturally occurring brines that are found in numerous countries. The high energy cost associated with magne- sium recovery has limited its past availability and encouraged the magnesium industry to increase research efforts to reduce processing costs. Recent reductions in energy-related processing costs are discussed in this study. This study presents an analysis of the resources, engineering, economics, and other factors that influence the availability of magnesium. Because of the number and diversity of occurrences and the lack of reliable data in some countries, only the most significant potential sources in market economy countries (MEC's) 2 were evaluated; other areas with future potential are discussed in the appendix. The resource and cost data presented in this report can be used in the development or modification of a domestic minerals policy and can be of direct benefit to programs concerned with mineral stockpile assessment, minerals exploration, extraction technology research, tax restructuring, substitute mineral studies, and land uti- lization. No comprehensive world magnesium resource data have been reported since 1960. This study updates past work (4f with more recent data and summarizes available industry data on magnesium and magnesium compounds as of January 1984. Current and potential availability data for magnesium are presented with explanatory text in a series of curves that relate resources to total production cost. Domestic property information was provided by personnel at Bureau field operations centers, foreign data collection was performed under contract. Personnel of the Bureau's Minerals Availability Field Office evaluated the data, aggregated it, and performed the economic evalua- tion analyses. Technical assistance was provided by Jack T. Elmer, Manager — Magnesia Operations, National Refractories and Minerals Corp., Moss Landing, CA. Selected production data were provided by Deborah A. Kramer, Bureau commodity specialist, Washington, DC. COMMODITY OVERVIEW BACKGROUND Magnesium, the eighth most abundant element in the earth's crust, is recovered from numerous sources in both metallic and nonmetallic forms. Magnesium metal or compounds are extracted from such diverse sources as magnesium-bearing ores, seawater, and well and lake brines. The most common ores in which magnesium occurs contain magnesite, brucite, dolomite, and olivine. Use of magnesium ores and compounds began in the early 18th century during the early development of the ferrous metals and chemicals industries in Europe. By the early 1940's, mining and processing of domestic magnesium ores had been expanded to supply material for the production of refractories, chemicals, and magnesium metal. Development of technology to produce magnesium compounds other than magnesia progressed slowly until the outbreak of World War II, when demand increased rapidly. Technology to recover magnesium from brines, seawater, and dolomite had been developed after World War I. Consequently, when imports were inter- rupted by the beginning of World War II, the domestic magnesium industry was able to meet the demands for magnesium products. 2 Market economy countries, as defined by the Bureau of Mines, include all countries except the centrally planned economy countries (CPEC'sl of Albania, Bulgaria, China, Cuba, Czechoslovakia, the German Democratic Republic, Hungary, Kampuchea, North Korea, Laos, Mongolia, Poland, Romania, the U.S.S.R., and Vietnam. Immediately following World War II, production of magnesium products decreased significantly in MEC's. The Germans, having made many contributions to magnesium's early development, became dependent upon imports after the war, and neither Germany has produced significant magnesium since that time. High electrical costs and large postwar inventories resulted in the reduction of Mg production in France and the United Kingdom and increased import reliance. Dow Chemical Co. plants at Freeport, TX, were the only domestic Mg metal producers to survive the war, although production of magnesium compounds continued at foreign locations. Technological advances have resulted in increased de- mand for metal and nonmetal magnesium products in recent years. USE In its pure state, magnesium is the lightest of the structural metals, with a density approximately 63 pet that of aluminum. This low density is a key factor in its use as a structural metal where weight is an important consideration; however, given the low mechanical strength of pure magnesium, it is commonly alloyed with other materials. Magnesium is used in structural alumi- 3 Italic numbers in parentheses refer to items in the list of references preceding the appendix. num-based alloys, in castings and wrought products (machinery, tools, and other consumer products), as a reducing agent, for cathodic corrosion protection, and in the manufacture of nodular cast iron. Other applications include chemicals, alloys other than aluminum, and graphic arts. Figure 1 illustrates the 1984 domestic end use pattern of Mg metal. Magnesium compounds are used in a wide variety of industries, as illustrated in table 1. The most important magnesium compound is magnesium oxide (MgO), which is commonly referred to as magnesia. Deadburned MgO, used in the manufacture of metallurgical furnace refrac- tory products, represents the largest tonnage use of magnesium in compounds. Other forms of recoverable magnesium include magnesium hydroxide [Mg(OH) 2 ]; caustic-calcined and specified (United States Pharmaco- poeia [USP] and technical-grade) magnesias; magnesium sulfate (MgS0 4 ); and precipitated magnesium carbonate (MgC0 3 «nH 2 0). Deadburned MgO is a granular MgO product obtained by calcining Mg(OH) 2 above 2,640° F to form a high-grade refractory product. Caustic calcined MgO is a reactive MgO product formed at calcination temperatures less than 1,650° F and can be used in lower grade refractories and in numerous other chemical and industrial uses. The domestic consumption pattern of magnesium compounds in 1984 is illustrated in figure 2. The iron and steel industry is the largest consumer of magnesium products; approximately 11 lb of refractory MgO is used for each short ton of steel ingot produced. MgO is also used as a stabilizing or vulcanizing agent in rubber and for other chemical products. The high electrical resistance of fused and boron- free MgO or periclase makes these products useful as insulators in electric furnaces and appliances. Magnesia serves as an wrought products 16 pet Reducing agents Cathodic protection 5 pet ■Manufacture of nodular cast iron 3 pet absorbent and catalyst in carbonate leach circuits for the recovery of uranium oxide (U 3 8 ) from uranium ores. An essential element in plant and animal metabolism, magnesium is added to fertilizers and animal feed in the form of caustic calcined MgO (11). MgS0 4 is used in pharmaceuticals, dyes, sizing, paper manufacture, fertiliz- ers, and explosives. MgC0 3 is used as a thermal insulator for boilers and pipes, in table salt to prevent caking, and in the preparation of pharmaceuticals and cosmetics. MgCl 2 is used in the production of Mg metal, industrial chemicals, and cement. There is a sharp distinction between markets for natural calcined magnesia and products of seawater or brine operations. Caustic calcined natural magnesites are TABLE 1. — Industrial uses of magnesium compounds {,11) Compound and grade Use MgO: Deadburned (refractory grades) Caustic calcined USP and technical grades Precipitated magnesium carbonate (MgC0 3 ) Magnesium hydroxide [Mg(OH 2 )] Magnesium chloride (MgCI 2 ) Basic refractories (bricks, furnace linings, etc.). Cement, rayon, fertilizer, insulation, magnesium metal, rubber, fluxes, refractories, chemical processing and manufacturing, and uranium and paper processing. Rayon, rubber, refractories, medicines, uranium processing, fertilizer, electrical insulation, neoprene compounds and other chemicals, cement. Insulation, rubber, pigments and paints, glass, ink, ceramics, chemicals, fertilizer. Sugar refining, MgO, and pharmaceuticals. Mg metal, cement, ceramics, textiles, paper, chemicals. (Total primary U.S. consumption, 1984 : 90,000 st) Other 1.5 pet (Total U.S. consumption, 1984 779,000 st contained MgO) FIGURE 1.— Domestic magnesium metal end use pattern, 1984. FIGURE 2. — Domestic magnesium compound consumption pattern, 1984 generally used for agricultural or construction markets, while the higher purity seawater and/or brine (synthetic) product tends to be used for refractory or industrial uses (5). Synthetic magnesite, however, requires up to four times more energy to produce than natural magnesite. Both natural and synthetic MgO products are used in the paper industry and in some agricultural markets. MARKETING AND PRICING STRUCTURE Magnesium metal is marketed in both wrought metal and cast metal forms, and market price varies with end product and alloy type. American Society for Testing and Materials (ASTM) standard designations have been adopted for 26 magnesium alloys (11). Magnesium alloys and aluminum alloys requiring magnesium (used in special applications) are custom manufactured and priced accordingly. Prices vary with specifications, including the amount of contained magnesium and allowable levels of impurities. Standards for refractories containing MgO are set by the consumer to meet various furnace conditions. Repre- sentative prices for Mg metal and selected magnesium compounds for the period 1982-1985 are given in table 2. Following the 1973 oil crisis, the energy intensive magnesium industry entered a period of rapidly increas- ing power costs. Magnesium metal prices had been stable at $0.35/lb to $0.38/lb for the period 1963-73, but they more than doubled to $0.82/lb by 1975. During the period 1975-83, the Mg metal price rose at an average annual rate of 6 pet (11). Expanded markets during the mid-1970's caused the magnesium industry to increase plant capacity to the point where present capacity exceeds demand. While the rate of growth in demand for magnesium products has declined since 1980, metal production capacity will most likely exceed demand for several years to come. As a result, some properties may operate below full capacity levels. The magnesium compounds industry appears to be stabilizing after a period of gradually increasing consump- tion. Since 1980, demand has showed only a slight increase and prices for magnesium products have re- mained stable. Plants are either operating at reduced rates or are gradually resuming full production rates. Exploration or development work, halted for the past several years by the sluggish economy, is gradually being resumed at some locations. The concern of major refractory producers to reduce energy consumption could lead to increased consumption of natural magnesites at the expense of the energy- intensive synthetic magnesites. Such a change would require that comparable, high-quality deadburned magnesite be obtained in large quantities as it could from seawater and brine sources. Since known natural magne- site deposits meeting these specifications are relatively rare, it is likely that current consumption trends will continue in the near future. WORLD MAGNESIUM PRODUCTION, CONSUMPTION, AND TRADE The United States leads the world in producing refined Mg metal, but it is a relatively minor producer of raw materials for magnesium compound production. Production figures for Mg metal and magnesite for the period 1970-84 are reported in table 3. In 1970, world primary Mg metal production was 242,000 st. By 1980, production had climbed to 348,000 st. Primary Mg production in 1984 was estimated to be 358,000 st. Since the 1960's, the United States has assumed an increasingly dominant role in primary Mg metal production. By 1980, the United States produced approximately 49 pet of the world's primary Mg metal. Production from CPEC's including China and the U.S.S.R., has remained stable at approximately 26 pet of world primary Mg metal. The world magnesite production was 7,521,000 st in 1960, 9,743,000 st in 1970, and 13,293,000 st in 1980. Current world magnesite production (1984) was 12,249,000 st. Domestic magnesite production has in- creased significantly from the 7 pet of world production reported in 1960, but falls short of the 55 pet level of world magnesite production achieved by the CPEC's (Czechoslo- vakia, Poland, the U.S.S.R., China, and North Korea) for 1980. Production from MEC's in 1980 was 45 pet of world production. Allegations that China and North Koreallave been dumping magnesite on world markets are being investigated, and an antidumping duty has been levied by a European Economic Community (EEC) commission on magnesium products from these countries. TABLE 2.— Market prices for selected magnesium products, January 1982 to January 1985 (2) (Dollars per short ton, except as indicated) Product Description Price (January') 1982 1983 1984 1985 $1.16 1.14 $1.34 1.32 2 $1 .34 1.32 $1.34 1.32 285 296 392 409 315 350 392 409 2 315 350 2 392 409 330 365 392 409 200 230 1,080 222 255 1,560 222 255 1,560 232 265 1,560 1,040 1,080 NA 1,460 1,480 1,660 1,460 1,480 1,660 1,460 1,480 1,660 10,000-lb lots, f.o.b. Freeport, TX. . . do Mg metal, $/lb: Ingots Diecasting alloys MgO, synthetic: Technical, chemical (92-95 pet MgO) Bulk lots, works Bagged, works Deadburned (94-96 pet MgO) Bulk lots, works Bagged, works MgO, natural: Technical, heavy (85 pet MgO) 150-mesh, bulk lots f.o.b. Nevada . Technical, heavy (90 pet MgO) 325-mesh, bulk lots, f.o.b. Nevada Mg (OH) 2 National Formula, powdered MgC0 3 : Technical, light Bagged, works, car or truck lots, freight equalized USP, light Bagged, works, truck lot, freight equalized USP, heavy do NA Not available. 1 price quoted from first week of January for each year reported. 2 Price used in this study for economic evaluation. r-cocooor-»co»-inio eo co r- co «- in i CM CM CO 6 r*. o 3 "O O E 3 CO o c O) a E E I c t- I * <8 CO « s — o "to £ s M c o 33 u 3 "O O w a. I pi UJ _j CO < sooioNnoioo m '-'-^■(ocm r» y- CM r- »- co oo »- o r» co o »co OOin-O-OOi-Oi-COCOO'3-O-i «-o»co o coot »- •» CO'* i- I^COCO '-r~-cooocMO)o>cocO'-tO' CMO)CJ> O OIOO)>-r-N inco i- co in cm (OTCOOOCM'S-CO-i-COCMCMO-' CM1DO O tt^OT- CO inco *- iD'-co CMCDmoOCMCOh-i-i-i-COO' CMf>-0 O OICMO-- CM inCO »- (DOCO oioNoootMOxonovO' CM'-IO O CDtCMCM i- f^CM »- (Don mtoioooioNincMooO' CMr^CO O OCOOOCM r^ cm i- co co co 0'»0)0)'*'-0>'-SO in cm co co in co > co r~- to m-t o> ■* cmcoco in cm com in ..TJ CD CO CO «5.5 2 if &o»l? •- Ou.roZDD> "O "> CD — ■S o CO co ,c n s 1 o £> S cl di o c Q.TJ Q E « 85 5 J c.g U) CO CO cog oi o 9 s?* s. £?-§ Ol Ttg § E -S * •> 5 u O (6 ^ m -S "O «T5n OT IgcS 2 = co i-lll ■=5 N co o c > Q« ■cj"° r 1- CO 0>_S> (/) ••=.□ CO-^ v> co > k It should be noted, however, that much of the domestic magnesium compound production is derived from sources other than magnesite. At present, magnesite makes up only 44 pet of the total domestic magnesium resources, a percentage much smaller than many other producing countries. The recent recession in the Western World, particu- larly in the domestic iron and steel industry, has affected the magnesium industry as well. World production of Mg metal has increased a slight 2.6 pet between 1980 and 1984 while domestic production has decreased 5.9 pet; world magnesite production has decreased 7.3 pet during this period, while U.S. production has decreased even more (11). Similar trends can be seen for other industri- alized MEC's. The production picture for CPEC's is healthy. The iron and steel industries in these countries are still developing, and the closely allied magnesium industry has either maintained production or increased production capacity. The CPEC share of world markets in 1984 was 28 pet for Mg metal and 63 pet for magnesite. Worldwide consumption data by end use are not available. However, it is estimated that approximately 268,000 st primary Mg metal, 25,000 st secondary Mg metal, and 5,562,000 st nonmetal magnesium compounds were consumed in 1983 (11). Consumption patterns for MgO vary widely from country to country. In the United States, approximately 60 pet of total consumption is for industrial or chemical uses, while in the United Kingdom the bulk of consumption is for agricultural use; in Austria construction use predominates; in Norway paper manufacturing is the dominant consumer of MgO (5). Approximately 20 pet of the domestic Mg metal consumption in 1984 was recovered from scrap. There is no significant recycling of nonmetal magnesium com- pounds. Magnesite, magnesia, and magnesium products are traded extensively internationally. In an average year over 2 MMst MgO is shipped across international boundaries. As a result of the wide variety of products on the market, a number of countries are both large exporters and importers; among them are Austria, Italy, the United Kingdom, Japan, and the United States. Principal producers, exporters, and importers of magne- sium products are listed in table 4. In order to protect domestic producers, tariffs on most magnesium products have been imposed by the United States. Tariff rates for Most Favored Nation (MFN) countries are gradually being reduced over a 7-yr period TABLE 4. — Principal magnesium producing, exporting, and importing countries (22) (Short tons) Production Exports Imports Country' 1980 1981" 1982 e 1980 1981 1980 1981 Brazil: Crude magnesite 788,000 618,000 505,000 Beneficiated magnesite ". 31 6,000 286,000 226,000 89,000 1 06,000 400 400 Canada: Mg metal (primary) 10,000 9,000 9,000 5,000 6,000 4,000 500 Magnesite-dolomite-brucite 69,000 76,000 75,000 France: Mg metal 9,000 7,000 10,000 4,000 5,000 4,000 4,000 Gf66C6! Crude magnesite 1 ,287,000 910,000 882,000 Deadburned MgO 439,000 303,000 298,000 467,000 310,000 1,000 300 Caustic calcined MgO 126,000 90,000 88.000 India: Mg metal 500 400 Magnesite 419,000 510,000 449,000 5,000 2,000 2,000 2,000 Ireland: Magnesium compounds NA NA NA 81 ,000 85,000 35,000 22,000 Italy: Mg metal (primary) 9,000 9,000 8,000 5,000 8,000 5,000 3,000 Magnesite 133,000 100,000 120,000 79,000 Japan: Mg metal (primary) 10,000 6,000 6,000 100 80 14,000 12,000 Mg metal (secondary) 26,000 31 ,000 24,000 Magnesite 125,000 98,000 199,000 220,000 Mexico: Magnesite 18,000 13,000 25,000 100 40 90 220 MgO products 78,000 76,000 71,000 NA NA Netherlands: Mg metal 5,000 5,000 6,000 6,000 Magnesite 4,000 2,000 17,000 20,000 Oxides and hydroxides 300 700 900 900 Other 30,000 29,000 61 ,000 44,000 Norway: Mg metal 44,000 47,000 36,000 42,000 44,000 400 400 Magnesite NA NA NA 17,000 19,000 5,000 4,000 Spain: Mg metal 1 ,000 1 ,000 Caustic calcined MgO 170,000 149,000 170,000 NA 102,000 NA 35,000 Crude magnesite 557,000 525,000 588,000 Tunisia: Magnesite NA NA NA NA NA 70 100 Turkey: Crude magnesite 910,000 864,000 998,000 NA NA NA NA United Kingdom: Mg metal (secondary) 3,000 2,000 2,000 1 ,000 800 5,000 5,000 Magnesium compounds NA NA NA 80,000 72,000 94,000 96,000 United States: Mg metal (primary) 169,000 154,000 102,000 57,000 35,000 4,000 7,000 Mg metal (secondary) 40,000 46,000 43,000 Caustic and specified MgO 157,000 160,000 148,000 52,000 37,000 12,000 12,000 Refractory MgO 731 ,000 616,000 453,000 56.000 21 ,000 73,000 77,000 Deadburned dolomite 494,000 435,000 337,000 NA NA NA NA "Estimated "Preliminary NA Not available. 'Countries that import or export magnesium products but do not produce significant amounts of magnesium or magnesium products have not been included here. ending in 1987. Non-Most Favored Nation (NMFN) tariffs remain unchanged. Tariffs for selected products are presented in table 5. Five of the 14 foreign nations included in this evaluation qualify for the U.S. Generalized System of Preference (GSP), which allows duty-free entry of imports into the' United States. The GSP was established as a temporary 10-yr program under the Trade Act of 1974, then was renewed until 1993 under the Trade and Tariff Act of 1985. Depletion allowances for selected magnesium ores are as follows: 14 pet for dolomite and magnesium carbonate (domestic and foreign); 5 pet for magnesium chloride (domestic and foreign); 10 pet for brucite (domestic and foreign); and 22 pet (domestic) and 14 pet (foreign) for olivine. TABLE 5. — U.S. import duties for selected magnesium products (11) Tariff item' MFN NMFN Jan. 1, 1984 Jan. 1, 1987 Jan. 1, 1984 Crude magnesite $0.98/st Caustic calcined MgO $2.10/st Deadburned MgO (-4 pet lime) $0.17/lb Deadburned MgO ( + 4 pet lime) 6.0 pet ad valorem Unwrought Mg metal 13.5 pet ad valorem Unwrought Mg alloys 6.8 pet ad valorem Wrought Mg metal $0.052/lb on Mg content + 2.9 pet ad valorem. Free $2.10/st $0.16/lb 6.0 pet ad valorem 8.0 pet ad valorem 6.5 pet ad valorem $0.045/lb on Mg content + 2.5 pet ad valorem. $10.50/st. $21 .00/st. $0.75/lb. 30.0 pet ad valorem. 100 pet ad valorem. 60.5 pet ad valorem. $0.40/lb on Mg content + 20 pet ad valorem. '5 of the 14 foreign nations included in this evaluation qualify for the U.S. Generalized System of Preference, which allows duty-free entry of imports into the United States. This system is in effect until 1993 under the Trade and Tariff Act of 1985. IDENTIFICATION AND SELECTION OF DEPOSITS Magnesium properties considered in this study are limited to known deposits that have significant demons- trated resources or to those properties that are either producing or that have produced in the recent past. Cumulative magnesium resources from seawater, brines, or dolomite are considered inexhaustible at current production rates; economic evaluation of total resource potential is beyond the scope of this study. Of the 45 properties investigated during this study, 38 have been economically evaluated. Properties were selected by the Bureau with the aim of including at least 85 pet of current production from MEC's. Seven MEC properties and all CPEC properties were not evaluated since data were either unavailable or unreliable. Table 6 lists the deposits included in this study. Magnesium production from olivine is minor and limited to specialized products, therefore it has not been included in this study. Resource potential from olivine sources is discussed in the appendix. Brucite deposits have been included with magnesite deposits because of similar- ity of occurrence, use, and processing technology. TABLE 6. — Deposits selected for evaluation Deposit Ownership Status 1 Mining 2 type Process 3 Products 4 Brazil: Magnesita Magnesita S.A. Canada: Haley Chromasco Ltd Mount Brussilof Baymag Mines Ltd Timmins Canadian Magnesite Mines Ltd. Gr©6c©* Fimisco FIMISCO Larco Larco S.A India: Almora Almora Magnesite S.A. Tamilnadu TamilNadu Magnesite 5 Burn Standard Burn Standard Co. 5 . . Dalmia Dalmia Cement Co. Ireland: Drogheda Premier Periclase Ltd. Quigley Quigley Magnesite Co. Italy: Cogema COGEMA Japan: Ube Onahama Minamata Ube Industries Ltd Asahi Chemical Industries . . do Mexico: Quimica del Rey Quimica del Mar Industries Penoles S.A. de C.V. . . do Netherlands: Veendam Norway: Norsk Hydro . Billiton International Metals B.V. Norsk Hydro A.S. Spain: Zubiri Magnesitas Navarras S.A. Tunisia: Zarzis Government of Tunisia Turkey: Comag Comag Kumas Kumas Sumerbank Sumerbank Genel Mudurlugu United Kingdom: Hartlepool Steetley Refractories Ltd. United States: California: Moss Landing National Refractories and Minerals Corp Delaware: Barcroft Barcroft Co Florida: Basic Magnesia Combustion Engineering Michigan: Ludington-Harbison Dow Chemical, USA, and Harbison-Walker Refractories. Midland Magnesia Dow Chemical, USA, and Martin Marietta Basic Products. M-M Manistee Martin Marietta Basic Products Morton Chemical Morton Chemical Corp Nevada: Basic, Inc Combustion Engineering Texas: Dow Freeport Dow Chemical, USA Utah: Amax G.S.L Amax Specialty Metals Washington: Northwest Alloys Northwest Alloys Inc Stevens County Deposits Harbison-Walker Inc W W DB.LB.MT DB.CC S S S PI LB DB MG CC DB S s DB DB DB DB s s s s DB.LB DB.LB DB.LB DB DB.CC DB.CC DB.CC DB sw sw.s DB DB DB DB sw DB DB sw sw sw DB.LB.PI DB.LB DB DB.CC DB.CC DB S.B sw DB.LB DB DB.CC DB SB DB DB SW.B.S NH MG S DB.LB DB.CC B DB DB S S S LB DB DB CC DB DB sw,s LB.DB CC.DB sw.s sw sw,s DB HM DB DB DB DB DB DB DB DB p W DB DB p W DB DB p s DB DB p sw,s DO MG p B AM MG p s MT MG N s DB DB oces s; LB = lightburning process; MT = = Magnatherm 1 N = not producing as of January 1984; P = producing as of January 1984. 2 B = sea or lake brines; S = surface; SW = seawater; W = brine wells. 3 AM = Amax process; DB = deadburning process; DO = Dow process; HM = hydrometallurgical process; LB process; NH = Norsk Hydro process; PI = Pidgeon process. 4 CC = caustic calcined MgO; DB = deadburned MgO; MG = Mg metal. This study assumes recovery of principal products only — other products may be recovered in limited quantities Government owned. METHODOLOGY Figure 3 is a flowsheet of the Bureau's Minerals Availability program (MAP) evaluation process, from deposit identification to the development of availability curves. The flowsheet shows the various evaluation stages used in* this study to assess the availability of magnesium from individual domestic and foreign properties. After a deposit was selected for analysis, a compre- hensive evaluation of the property was performed. Production and cost data for domestic properties were estimated by personnel at the Minerals Availability Field Office (MAFO) in Denver, CO, and the Bureau's field operations centers in Denver, CO, and Spokane, WA. Foreign data were collected by Raymond Kaiser En- gineers Inc. of Oakland, CA, under contract JO225016 U9). Design capacities were used for producing properties. For deposits not currently in production, mining, concen- trating, smelting, refining, and transportation methods were chosen based on applicable engineering principles, available deposit data, and current technology. Where possible, actual company cost data were used. In other cases, capital and operating costs were estimated from various sources. A cost estimating system (CES) de- veloped for the Bureau (3) was used for selected domestic deposits. Use of this costing system produces estimates that historically have fallen within 25 pet of actual costs. Capital expenditures were estimated for exploration, development, and mine and mill plant and equipment which include costs for mobile and stationary equipment; construction; engineering; support facilities and utilities (infrastructure); and working capital. Infrastructure includes all necessary costs for access roads, water facilities, power supply, port facilities, and personnel accommodations. Working capital is a revolving cash fund for operating expenses such as labor, supplies, taxes, and insurance. A working capital based on three months or 90 days of operating cost was used in evaluations. All capital investments incurred prior to 1970 (15 yr before the study date of January 1984) were assumed to be fully depreciated or written off. Capital costs incurred after 1969 were reported in dollar values of the year in which they occurred; however, these costs were adjusted to reflect the remaining book value of the investment as of January 1984. All capital investments subsequent to January 1984 were reported in constant January 1984 dollars. Mine and mill operating costs were developed for each deposit. The total operating cost is the sum of direct and indirect costs. Direct operating costs include production and maintenance labor, materials, payroll overhead, and utilities. Indirect operating costs include administrative costs, facilities' maintenance and supplies, and research Identification and selection of deposits Tonnage and grade determination Engineering and cost evaluation Deposit report preparation I Mineral I Industries ' Location I System I (MILS) | data • MAP computer data base Taxes, royalties, cost indexes, prices, etc MAP permanent deposit files Data selection and validation Variable and parameter adjustments Economic analysis Data Availability curves Analytical reports Sensitivity analysis u Data Availability curves Analytical reports i_r FIGURE 3.— Minerals Availability program (MAP) deposit evaluation procedure. 10 and development. Costs not considered as operating costs but used in the analyses include transportation costs and fixed charges, including taxes, insurance, depreciation, deferred expenses, and royalties. After capital and operating costs were determined, data were entered into the Bureau's supply analysis model (SAM) (6). The Bureau developed SAM to perform an economic analysis that either presents the results as the primary commodity price (average total cost of produc- tion) needed to provide a stipulated rate of return or, for a given price, determines the expected rate of return on investment. The rate of return used in this study is the discounted-cash-flow rate of return (DCFROR), most commonly defined as the rate of return that makes the present worth of cash flows from an investment equal to the present worth of all after-tax investment. For this study, a 15-pct DCFROR was considered necessary to cover the opportunity cost of capital. Rates of return (profit) required for continued production differ from operation to operation. However, for comparison purposes, each operation was analyzed at a 15-pct DCFROR. Analyses were also performed at a 0-pct DCFROR, which includes the return of invested capital but provides no additional profit. Total production cost at a 0-pct DCFROR is equivalent to a breakeven production cost. Detailed cash-flow analyses were generated for each deposit in this study. After each deposit's total cost of production was determined, individual deposit tonnages were aggregated at increasing production costs to deter- mine magnesium availability from all deposits evaluated. The results of these analyses are presented as availability curves discussed later in this report. Total and annual availability curves were generated for Mg metal, dead- burned MgO, and caustic calcined MgO. Sensitivity analyses showing effects of source mate- rial, energy costs, processing technology, and product type were also performed. GEOLOGY Magnesium occurs in a variety of rock types, sea water, bitterns, and brines. Although magnesium is found in over 60 minerals, only dolomite, magnesite, brucite, and olivine are magnesium minerals of commercial importance. Together, these varied sources form a potential resource base for magnesium that is for all practical purposes inexhaustible. DOLOMITE Sources of high-purity dolomite [CaMg(C0 3 ) 2 ], a sedimentary rock commonly interbedded with limestone, are enormous and contribute significantly to Mg metal and magnesium compound production. Dolomite occurs as massive or bedded deposits many meters in thickness. In the United States alone, dolomite deposits containing at least 37.5 pet MgC0 3 occur in at least a dozen States. World dolomite resources are sufficient to meet the expected demand for dolomite products well beyond the year 2000. SEAWATER Magnesium occurs within seawater as the cation of various magnesium salts (MgCl 2 , MgS0 4 , and MgBr 2 ). The magnesium content of seawater averages 0.13 wt pet. Concentrations in specific areas vary widely due to geomorphic, climatic, and seasonal conditions and to other variables such as water depth. Seawater plants are located at sites of relatively high salinity, reflecting higher than average concentrations of dissolved salts. U.S. operations extract MgO from sea brines that range from 0.13 to 0.22 pet Mg. The oceans are estimated to contain 17.8 billion st of pure magnesium; rivers have the potential to contribute an additional 30 MMst Mg (9). LAKE BRINES MAGNESITE AND BRUCITE Magnesite (MgC0 3 ), the natural form of magnesium carbonate, has been a traditional source of magnesium and magnesium compounds since the 1880's. Magnesite occurs in four types of deposits: As crystalline masses replacing dolomite, as impure crystalline masses replac- ing ultramafic rocks, as cryptocrystalline masses in ultramafic rocks, and as sedimentary beds and lenses. In recent years, only deposits of crystalline magnesite replacing dolomite have been mined. These crystalline magnesite deposits occur as lenses, stockworks, or disseminations within massive dolomite deposits. Brucite [Mg(OH) 2 ], the natural form of magnesium hydroxide, is a magnesium mineral of secondary origin that usually is found in association with other magnesium minerals, particularly magnesite. It is usually associated with carbonate rocks and serpentine. Lake brines commonly occur in enclosed drainage basins. Salt concentrations are controlled by several climactic factors. Abundant solar radiation, low humidity, and low rainfall result in more concentrated brines. In these areas, water loss through evaporation exceeds water gained through precipitation. The Dead Sea brines in Israel and the Great Salt Lake brines in the United States illustrate two types of natural brines. Rainfall in the Dead Sea area averages 33 in/yr and has been relatively stable for several years. Magnesium concentration is approx- imately 4.1 pet. The Great Salt Lake region has an average rainfall between 12 to 19 in/yr; rainfall distribu- tion has been variable. Both regions, however, have higher than average magnesium salt concentrations. Higher rainfall in the Great Salt Lake area, in combina- tion with flooding of the drainage basin as a result of a breeched causeway, has resulted in magnesium concen- trations that have fallen below an average level of 3.8 pet Mg, requiring processing technology modifications. 11 WELL BRINES Well brines are extracted from two sources. Wells are used to extract seawater that has invaded near-shore aquifers. An example of this is Quimica del Rey in Mexico. Production facilities of this type are very similar to typical seawate/ plants. The second source is naturally concen- trated interstitial brines. Two major theories are pre- sented for the origins of interstitial brines. The first explanation proposes that these brines are the residium of the formation of evaporite deposits. The second attributes brine concentration to the downward percolation of meteoric waters that take minerals into solution until saturation levels are reached (19). Magnesium concentra- tions in interstitial brines are higher than those of seawater, but lower than the best lake brines. MAGNESIUM RESOURCES Magnesium and magnesium compounds can be produced (if economics are not considered) from numerous sources in virtually unlimited quantities from many countries. Seawater, which averages 0.13 wt pet Mg, is virtually an inexhaustible source of magnesium. Conse- quently, it is not the purpose of this study to estimate the total resource potential of this abundant material, but rather to present the availability of magnesium and magnesium compounds in terms of the most readily available sources (e.g., those currently producing, those with recent production, and those not yet producing but with significant production potential) in MEC's. Resources have been classified into four primary sources: seawater, brines, magnesite, and dolomite. Discussion of dolomite sources is limited to those properties producing dolomite solely for its magnesium content, rather than for its numerous other uses. Resource estimates were made at the demonstrated level according to the mineral resource classification system developed by the Bureau of Mines and U.S. Geological Survey (fig. 4) (23). Using this classification system, demonstrated resources are defined as the in situ measured plus indicated tonnages that make up the reserve base. The reserve base includes resources that are currently economic (reserves) or marginally economic (marginal reserves) and some that are currently subeco- nomic (subeconomic resources). Resource quantity and grade were determined from site inspections, deposit geology, drilling data, mine workings, and sampling. Demonstrated resources from 38 properties with significant potential for recovery of magnesium or magnesium compounds from MEC's were evaluated in this study. Total demonstrated resources from these deposits are estimated at 29,407 MMst of source material containing 416 MMst MgO, of which 74 pet is recoverable as either MgO compounds or Mg metal. Table 7 reports magnesium resource potential from evaluated MEC's. The nature of the seawater and brine sources made it impossible to estimate resources attribut- able to individual properties in a conventional manner. Resources from properties recovering magnesium prod- ucts from brine or seawater sources were reported in terms of a 30-yr production life for the purpose of economic analysis. Cumulative production IDENTIFIED RESOURCES Demonstrated Measured Indicated Inferred ECONOMIC MARGINALLY ECONOMIC SUBECONOMIC Reserve base Inferred reserve base UNDISCOVERED RESOURCES Probability range (or) Hypothetical Speculative + + Other occurrences Includes nonconventional and low-grade materials FIGURE 4.— Mineral resource classification categories. 12 TABLE 7.— Demonstrated MEC magnesium resources, January 1985 Demonstrated Identified 2 Country and primary e . , , ln sit 3 u M 9° MgO, MMst ln situ MgO Contained cn,,rra Status 1 ore 3 , grade, ore, grade, MgO, source MMst pet Contained" Recoverable 5 MMst pet MMst Brazil: Magnesite P W 46 W W W 46 W Canada: Dolomite P 11 21 2.4 2.4 11 21 2.4 Magnesite N 136 30 41 41 176 30 53 Greece: Magnesite C W 6.4 W W W 6.4 W India: Magnesite P 334 9.5 32 2.2 1,583 9.8 155 Ireland: Seawater C 2,473 .19 4.7 4.7 ( 7 ) .19 ( 7 ) Italy: Seawater P 1,031 .23 2.4 2.4 ( 7 ) 0.23 ( 7 ) Japan: Seawater P 17,007 .20 31 18 ( 7 ) 0.20 ( 7 ) Mexico: Seawater P 1,012 .20 2.0 2.0 ( 7 ) 4.5 ( 7 ) Brine P 1,128 4.5 51 51 ( 7 ) 4.5 ( 7 ) Netherlands: Brine P 29 9.0 2.6 2.6 59 9.0 5.3 Norway: Seawater P 1,356 .20 2.7 2.7 ( 7 ) .20 ( 7 ) Spain: Magnesite P W 32 W W W 32 W Tunisia: Brine N 59 6.8 4.0 4.0 1,102 6.8 75 Turkey: Magnesite P 437 27 118 49 1,105 26 287 United Kingdom: Seawater P 1,936 0.21 4.0 4.0 3,287 .21 6.9 United States: Seawater P 3,636 .21 7.6 5.1 ( 7 ) .21 ( 7 ) Brine P 1,880 1.2 23 23 ( 7 ) 1.2 ( 7 ) Magnesite C W 26 W W W 26 W Dolomite C W 39 W W W 39 W Total or average: Seawater NAp 28,451 .19-.23 54.4 38.9 ( 7 ) NAp ( 7 ) Brine NAp 3,096 1.2-9.0 80.6 80.6 ( 7 ) NAp ( 7 ) Magnesite NAp 1,499 6.4-46 285.0 165.7 3,600 NAp 636 Dolomite NAp 24 21-39 7.5 7.5 24 NAp 7.5 All sources NAp 33,070 NAp 427.5 292.7 ( 7 ) NAp ( 7 ) NAp Not applicable. W Withheld to avoid disclosing company proprietary data; included in totals. 'C = combined producer and nonproducer; N = nonproducer: P = producer. identified resources include inferred resources; seawater and some brine resources are considered virtually unlimited. 3 Resources for seawater and brines are effectively inexhaustible; for the purpose of this study a property life of 30 yr was assumed from these sources. "Figures report total MgO content of in situ ore. 5 Figures report MgO recoverable from deposits in country assuming current recovery rates. 6 CC = caustic calcined MgO; DB = deadburned MgO; MG = Mg metal. Principal products only, other products may be recovered in limited quantities. Unlimited resources. Annual production capacity, st product Product type 6 330,000 DB.CC 11,000 205,000 MG DB.CC 410,000 DB 133,000 DB.CC 200,000 DB 72,000 DB 691,000 DB.CCMG 77,000 110,000 DB DB.CC 110,000 DB 55,000 MG 105,000 DB.CC 110,000 DB 205,000 DB.CC 193,000 CC.DB 468,000 580,000 123,000 27,000 DB DB DB.MG DB 1 ,756,000 910,000 1,511,000 38,000 4,215,000 NAp NAp NAp NAp NAp for estimates of resources Of the 38 properties evaluated, 13 properties recover magnesium primarily from seawater, 8 from well or lake brines, 15 from magnesite or brucite, and 2 from dolomite. Over the next 30 yr, demonstrated recoverable MgO from seawater sources evaluated in this study are estimated to be 46.9 MMst, or 15 pet of the total recoverable MgO evaluated in this study. Approximately 76.4 MMst (25 pet) MgO are recoverable from brines during this period. The MgO content of magnesite or brucite sources amount to 175.2 MMst, or 57 pet of the total available MgO. Most of the countries of the world have the potential to recover magnesium from either seawater, brine, or dolomite. The principal magnesite-rich regions are in- cluded in table 6. Areas with magnesium recovery potential not included in this study are discussed in the appendix. 13 EXTRACTION AND PROCESSING TECHNOLOGY Magnesium and magnesium products are recovered from a variety of sources. Each source requires specialized mining tend processing methods, with method selection dependent upon the desired marketable form. SEAWATER AND BRINES Extraction The simplest source of magnesium to recover is seawater or magnesium-rich lake brines. Water is simply pumped from the shallow source area by means of centrifugal pumps. Pump intake is arranged in a series of weirs or sumps in order to prevent the pumps from being clogged with fish or other contaminants. The Barcroft operation in Delaware uses a slight variation of this method. Water is pumped by means of submersible well pumps with pump intakes located 3 in below the sediment surface. Sediment in this case acts as the filtering mechanism. Magnesium-rich natural brines such as those recov- ered from the Michigan Basin are extracted by means of deep wells. Extraction methods and equipment are similar to that used in the oil industry. Well fields are usually put into production by contract drilling firms on a "turnkey" basis. Michigan brine wells are sunk to depths ranging from 4,000 to 5,200 ft. Well castings are cement-sealed from the surface to the top of the brine producing aquifer. Pumping rates range from 20 to 120 gal/min. Brines are transported to processing facilities by a network of steel or fiberglass pipelines. Similar brine recovery techniques are employed worldwide. The main consideration in selecting reactants for this process are their purity and economic availability. After the reactants have been selected, the limitations of pumping and thickening equipment prevent switching to more dilute reactants without loss of capacity. A plant using dolomite, for example, cannot change to limestone without suffering a production loss. Changing to a more concentrated reactant, however, may be possible. When dolomite is used as a reactant, approximately half of the resulting magnesium in the MgO product comes from the dolomite; when limestone is used, all the product MgO comes from the seawater or brine. In order to obtain an equivalent production rate in terms of market- able product, twice the volume of liquid must be processed when limestone is used than when dolomite is used. If a MgO product is desired, the filter cake is treated in either a multiple-hearth furnace or a rotary kiln and fired to a temperature of approximately 1,640° F (11). At this temperature, the water is driven from the Mg(OH) 2 , leaving caustic calcined MgO. This form of magnesia can be marketed or can be pelletized and refired in a rotary kiln. The kiln is fired up to a temperature above 2,640° F (11); the crystalline makeup of the MgO changes and deadburned MgO is formed. MgS0 4 (epsom salts) can be produced by dissolving MgO in H 2 S0 4 with subsequent crystallization, or by reacting Mg(OH) 2 with S0 2 . Various grades of MgC0 3 can be produced by combining solutions of MgS0 4 and Na 2 C0 3 followed by precipitation, filtration, and drying (11). MAGNESITE, BRUCITE, DOLOMITE, AND OLIVINE Extraction Processing Processing methods employed are selected based upon source material type and product forms desired. Methods employed at specific operations are reported in table 6. Seawater or well-brines are processed similarly, but minor differences occur at the initial stages of processing. If the solutions are used as feed for producing caustic calcined or deadburned MgO, carbonate levels are first reduced so insoluble calcium compounds do not precipitate with Mg(OH) 2 in the subsequent reaction process. Brines are first combined with slaked lime to precipitate soluble bicarbonates as CaC0 3 , while seawa- ter is commonly treated with H 2 S0 4 to liberate C0 2 . Subsequent processing steps for these two sources are identical. The treated solution is then heated to approx- imately 131° F and placed into reaction vessels where calcined oyster shells, limestone, or dolomite are added. Magnesium ions in the water react with the slaked carbonates to produce a Mg(OH) 2 precipitate. This Mg(OH) 2 slurry is concentrated in thickeners, washed with fresh water in a countercurrent system, and then filtered. The resulting filter cake can either be dried and marketed at this point as Mg(OH) 2 or it can undergo further processing to attain another magnesium product. Magnesite, brucite, dolomite, and olivine are the principal rock sources of magnesium. Open pit mining methods are most commonly used. Mining consists of stripping overburden and drilling, blasting, loading, and hauling ore. Pit design is based on surface mapping and assay information derived from exploratory drilling. Waste and ore are commonly drilled by percussion or rotary drills. Holes are loaded with ANFO and primed with dynamite. Shovels and front-end loaders transport the broken ore to trucks for shipment to processing facilities. Hand cobbing of broken material is employed at some locations, primarily in India and Turkey. Crushers located in the pit are utilized at other locations. Overburden and waste removal varies significantly for each operation. Waste-to-ore ratios range from zero to as much as 3:1. Pit slopes for domestic operations are generally maintained at 60°. Pit benches can vary from 10 to 40 ft. Nonmetallic MgO Processing Magnesium is recovered from mineralized areas containing magnesite, brucite, or dolomite. The first step in processing these ores is to crush either run-of-mine or hand-cobbed ore in multiple stages at either the mine site or the processing facilities. Dolomite at this point is 14 simply directed to rotary or shaft kilns where it is calcined to a temperature of 1,640° F. If deadburned dolomite is desired, the kilns are heated to temperatures up to 3,450° F (11). Magnesite and brucite ores undergo more rigorous beneficiation before calcination. After undergoing a series of crushing stages, ore is screened, washed, and classified to remove slimes. Depending upon ore quality, flotation or heavy-media separation may be required to prepare the feed for calcination. Two forms of magnesia are commonly produced, caustic calcined MgO or deadburned MgO. Caustic calcined MgO is obtained by heating the feed material in either rotary or shaft kilns to above 1,640° F. Deadburned material is produced by pelletizing and additional kilning at temperatures up to 3,450° F. In some cases, raw feed is mixed with flue dust and briquetted prior to deadburning. Both brick and maintenance grade refractory MgO products can be produced (11). Magnesium Metal Processing Two principal processes are currently utilized for Mg metal recovery: electrolytic reduction of MgCl 2 and thermic (silicothermic) reduction of MgO. Exact process methodology varies from operation to operation. Electrolytic Processing Several basic electrolytic cell designs are in use today; the three main cells currently employed are the Dow cell, the I.G. cell, and the diaphragmless cell. Detailed descriptions of cell design have been published (8). Cell design differs in electrode positioning and utilization of a diaphragm for separating the electrodes. In each cell direct current breaks down the MgCl 2 into chlorine gas and molten magnesium. The metal is formed at the cathode and rises to the surface of the bath where it is guided into storage wells. Metal is cast into desired forms. Chlorine and HC1 gases generated at the anodes are collected and pumped to other facilities for further treatment and use (10). Dow Process Raw materials for this process consist of seawater and dolomite. In this process, calcined dolomite is reacted with seawater to precipitate Mg(OH) 2 . The precipitate is neutralized with HC1 to produce MgCl 2 . This solution is partially dewatered to approximately 25 pet water and fed directly into Dow electrolytic cells. Norsk Hydro Process Raw materials for this process are also seawater and dolomite, or brines with a high MgCl 2 content. Norsk Hydro A/S employs two different preparation processes. In the original Norsk Hydro process, seawater and calcined dolomite are combined and the resultant Mg(OH) 2 is precipitated and chlorinated as with the Dow process. In the revised Norsk Hydro process, MgCl 2 brine is totally dehydrated and chlorinated in fluidized beds. The Norsk Hydro process differs from the Dow process in that only fully dehydrated MgCl 2 is fed into the electrolytic cells, whereas the Dow process feed is MgCl 2 with a H 2 content of 25 pet (10). Norsk Hydro A/S has until recently employed modified I.G. electrolytic cells, but is currently replacing them with diaphragmless cells of its own design. AMAX Process This process makes extensive use of solar evaporation to concentrate MgCl 2 from brine. The brines are pumped to a series of solar evaporation ponds where a 7.5 pet Mg concentrated brine is obtained. CaCl 2 is used to remove various sulfates from the brine, which is further concen- trated and dehydrated in a spray dryer. Anhydrous MgCl 2 is melted and Mg metal separated in an I.G. electrolytic cell. Thermic Processing Magnetherm Process This process uses dolomite for the magnesium source and ferrosilicon as a reducing agent. It is the most widely used of the thermic processes. Calcined dolomite, ferrosili- con, and alumina are ground, heated, and briquetted, then fed into an electric furnace, which is operated under a vacuum at a temperature of 2,900° F. The alumina serves as a fluidizing agent in the process and reduces the melting point of the slag produced as the result of the dolomite-silicon reaction. Magnesium vapors are conden- sed, and Mg metal is then cast in desired forms. Pigeon Process Raw material used in this process is dolomite. Ferrosilicon is also used as a reducing agent. Dolomite and ferrosilicon are mixed, briquetted, and heated in a retort under vacuum to 2,000° F. The resulting chemical reaction produces magnesium vapor, which is condensed in a water-cooled condensing section of the retort. PRODUCTION COSTS Capital investments and operating costs for mining, milling, processing, and transportation were developed based on actual data or estimated from best available sources. Based upon this economic data, costs at 0- and 15-pct DCFROR were generated for each property. The 0-pct DCFROR cost estimate includes applicable mining, concentrating, and processing costs; transportation costs to the processing facility; capital recovery and taxes. The 15-pct DCFROR cost also includes profit. Post-processing- plant transportation costs have been included as separate costs. Magnesium production costs vary greatly depending upon such factors as source material, processing metho- dology, size of operation, deposit location, ore characteris- tics, energy and labor costs, tax structure, and degree of product integration and diversification. The diversity of 15 source materials and marketed products available make economic comparisons between properties difficult. In this study, properties were grouped in terms of primary product and source material. CAPITAL INVESTMENTS Where applicable, capital investments include costs for exploration; development; mine, mill, and processing facilities and equipment; working capital; and infrastruc- ture. Because of differences in processing techniques, costs are reported by source material and final product. Capital costs reflect either development costs to construct "greenfield" facilities and begin production or the additional capital investment necessary to recondition preexisting facilities and construct any additional facili- ties necessary to enable a property to resume operations. Most of the magnesium operations under consideration have been operating for many years. Many of the original capital investments have been written off or depreciated. Capital investments for these operations are limited to replacement, modifications, or expansions, and do not reflect the total cost required for development of a new or "greenfield" operation. Costs have been reported in terms of investment dollars per short ton of annual product capacity. Investments made for producing operations evaluated in this study vary greatly depending on the type and degree of plant modification required. Much of the difference is attributed to the high degree of variation in the infrastructure required from property to property. A property located in a highly industrialized region requires significantly less infrastructure than one located in a remote region, where additional townsite, transportation, and port facilities may be required. Properties with larger production rates generally required larger capital expend- itures but were lower cost operations on a per ton of product basis. Capital costs associated with plants producing mag- nesium compounds vary significantly from those produc- ing Mg metal, although they may be of similar capacities and use similar raw materials. It is estimated that initial capital requirements for the production of Mg metal range from $3,175/st to $4,500/st of annual product capacity (15). Data available from this study indicates that initial capital investment for the production of MgO compounds (primarily deadburned MgO and caustic calcined MgO) fall within the range of $864/st to $l,250/st annual MgO production in 1984 dollars. As a general rule, seawater magnesia plants cost more to construct per ton of annual product capacity than do brine plants or those using a magnesite feed. Seawater plants generally utilize a more complex recovery process, particularly if multiple feed sources (e.g., seawater and dolomite or brine) are used, and use expensive water preparation equipment that treats huge volumes of relatively dilute seawater. The least costly operations are those using a magnesite feed and a simple process consisting of crushing, sizing, and calcination. This type of plant is also commonly a physically smaller plant for a given product capacity than a plant utilizing a seawater or brine source material. Capital costs for "greenfield" plants producing Mg metal vary depending upon local conditions, capacity, and processing technology. Electrolytic plants tend to operate at higher capacities than metallothermic plants with correspondingly higher initial capital investments. Ther- mic processes generally operate at capacities from 5,000 to 33,000 st/yr Mg metal and incur slightly lower capital investment. Based upon Bureau data, the capital invest- ment as of 1984 for electrolytic plants with a capacity range of 33,000 to 77,000 st/yr Mg metal is approximately $3,600/st annual capacity; electrolytic plants with capaci- ties exceeding 77,000 st/yr Mg metal have capital investments of about $3,200/st. The capital investment of plants utilizing thermic processing averages $2,700/st annual capacity; capital costs are lower for operations purchasing ferrosilicon. OPERATING COSTS Operating costs estimated for each of the properties evaluated include all necessary costs for extraction, raw materials, processing, and transportation to processing facilities. Costs for mining, processing, or purchase of necessary raw materials such as dolomite or ferrosilicon have been included in the operating cost. Because of the diverse nature of magnesium recovery technology, costs for mining and beneficiation, if required, have been included in the total processing plant operating cost; only total operating costs are reported. Costs reflect the weighted-average expense of recovering all commodities considered in this study. All costs are as of January 1984. Because of the proprietary nature of the data, detailed cost data for each property could not be reported. A summary of estimated operating and total produc- tion costs from operations included in this study are given in table 8. Costs for both Mg metal and MgO compounds are reported in terms of cost per short ton of contained MgO for all magnesium products. Both cost ranges and weighted-average costs are reported. Total production costs include additional costs for capital recovery, taxes, selected byproduct credits, and a 15-pct DCFROR. Table 9 gives a breakdown by percentage of total cost for major cost components. Labor costs range from 13 to 31 pet of the total operating cost. Energy costs range from 22 to 71 pet and in general reflect the greatest portion of operating cost. Costs for materials and supplies make up 6 to 49 pet while general-administrative costs range up to 10 pet of the total operating cost. Deadburned MgO recovery appears to be the most energy intensive. Operating costs for Mg metal from all sources range from $280/st to $2,07 1/st Mg metal product (wtd av of $l,018/st). While a breakdown of metal costs from various sources was not possible owing to the proprietary nature of the data, operating costs for seawater operations tended to be lower than those from dolomite or brine source material; operating costs from evaluated brine operations were the highest. Operating costs from evaluated properties producing magnesium compounds ranged from $22/st to $386/st product (wtd av of $172/st). Costs from seawater and magnesite properties were significantly higher than those from properties processing brines. 16 TABLE 8. — Production costs for selected producing operations from various source materials (Dollars per short ton contained MgO) Product and Operating cost 1 Total production cost 2 source Range Wtd av Range Wtd av Mg metal 3 $280-$2,071 $1,018 $760-$2,620 $1,552 MgO compounds: Seawater 129- 386 185 156- 476 276 Brines 62- 255 131 148- 329 212 Magnesite and brucite 22- 259 195 109- 451 287 All sources NAp 172 NAp iiT NAp Not applicable. 'Includes all mining, beneficiation, processing, and internal transportation costs. includes additional costs such as capital recovery, taxes, and a 15-pct DCFROR. Costs vary from those reported in table 10, as these costs reflect weighted-average cost in terms of contained MgO from all magnesium products; table 10 costs reflect costs in terms of primary magnesium product adjusted for byproduct credits. 3 Owing to the proprietary nature of the data, no breakdown of Mg metal costs by source material was made. TABLE 9. — Operating cost breakdown for producing magnesium operations (Percent) Product and source Labor Energy Materials General and and supplies administrative Mg metal: Seawater 29 Brine 29 Dolomite 29 Deadburned MgO: Seawater 25 Brine 13 Magnesite and brucite 18 Caustic calcined MgO: Seawater 31 Brine 15 Magnesite and brucite 25 39 48 22 62 58 71 37 56 59 29 18 49 6 26 9 22 21 9 10 8 7 MAGNESIUM AVAILABILITY Capital and operating cost data were aggregated and economic analyses at 0-pct (breakeven) and 15-pct DCFROR were peformed for each of the products (Mg metal, deadburned MgO, and caustic calcined MgO) evaluated in this study. As defined earlier, the DCFROR represents the rate of return that makes the present worth of cash flows from an investment equal to the present worth of all after-tax investment. A summary of the economic findings is presented in table 10. Total produc- tion costs are reported as weighted averages in terms of cost per short ton of marketable product. Cost ranges for each product and source material type are given. All costs discussed here are reported in January 1984 dollars. Magnesium operations commonly produce a wide variety of magnesium products; byproduct credits for selected magnesium compounds (e.g., caustic MgO, Mg[OH] 2 , and raw magnesite) and other byproducts were included. Table 11 reports the byproduct prices used in the study. Specialty byproducts such as chlorine from Mg metal recovery were not included as they most commonly were considered a part of a separate recovery circuit in the fully integrated plant. For each deposit with multiple magnesium products, price proportions were used to burden costs against total revenues required to meet the target rate of return. The total production cost of the deposit is not allocated to only one product but is allocated among all products, based on relative price proportions of those products. This method is useful for operations for which there is not a clearly defined primary product. Nonmagnesium byproducts were given set prices (see table 11) and any byproduct credits were deducted from the total revenues required to cover all costs at 0-pct or 15-pct DCFROR. The remaining revenues were then proportioned among all magnesium products recovered. Because of product similarity, the same market price proportions were assumed for all properties. Price proportions allow revenues to be divided between products according to their value, rather than establishing a price for one magnesium product and determining a price for another. TABLE 10. — Total production cost summary for selected magnesium products from producing operations and various source materials (Dollars per short ton primary product) Total production Weighted-average cost range total production cost Product and - - source 0-pct 15-pct 0-pct 15-pct DCFROR DCFROR DCFROR DCFROR Mg metal:' 400-2,400 760-2,620 1,346 1,552 Deadburned MgO: Seawater 131- 407 156- 580 242 290 Brines 157- 261 179- 329 178 237 Magnesite and brucite 98- 339 118- 480 211 246 Wtd av NAp NAp 213 257 Caustic calcined MgO: Seawater 180- 286 191- 315 219 246 Brine W W W W Magnesite and brucite 83- 285 100- 404 194 238 Wtd av NAp NAp iijl 240 NAp Not applicable. W Withheld to avoid disclosing proprietary data: included in totals. 'The proprietary nature of the data prevents reporting of actual production costs for Mg metal. Weighted-average costs from all source materials are reported. TABLE 11.— Byproduct commodity prices, January 1984 Price, $/st Caustic calcined MgO 315.00 Deadburned MgO 392.00 Gypsum 20.00 Magnesite 48.54 MgCI 2 58.06 Mg(OH) 2 1 12.12 Mg metal '1.34 Talc 19.50 '$/lb. 17 The total production cost can be compared to an estimated long-term market price to determine if an operation has sufficient return on investment to justify continuous operation. In the short term, if an operation shows average variable costs that are higher than the market price, the company may cease operations unless the cos£s arising from closure are higher than the cost of continuing production at a loss. State-owned or State- controlled operations may also continue production under a nonprofitable situation if the resulting foreign exchange earnings are more than foreign exchange costs incurred by the operation. A closure may require payment of unemployment, welfare, or loss of training benefits or additional costs to restart an operation. Governments may need sales revenues generated by the operation to import other needed materials into the country. The average total cost of production at a 15-pct DCFROR to produce Mg metal ranges from $0.38/lb to $1.31/lb Mg metal product (wtd av $0.78/lb Mg metal) for the properties under consideration. Given the proprietary nature of the data, actual costs could not be reported for each source material. On a relative basis, total production costs from seawater sources were lower than costs from dolomite or brine source materials; brine costs to recover Mg metal were the highest from the properties evaluated. All costs at a specified 15-pct DCFROR for the Mg metal operations under consideration are less than the January 1984 market price for 99.8 pet pure Mg metal of $1.34/lb ($2,680/st) Mg. (See table 2.) The variation in production costs among properties processing seawater, brines, and dolomite for recovery of Mg metal can be attributed to several factors. In the magnesium industry, the diversity of source material and processing methodology make economic comparisons among operations difficult. Variations in plant design and age, process technology, and capacity are significant. Seawater plants tend to operate at significantly higher capacities, resulting in economy-of-scale effects. The seawater plants also tend to be parts of larger industrial complexes where some cost elements may be absorbed by other parts of the complex. A significant advantage in electrical costs is possible with some large scale opera- tions. This may be reflected in table 9, which shows cost percentages reported for seawater and dolomite opera- tions producing Mg metal to be comparatively lower than those for brine operations. Energy requirements for each type of operation should be comparable (8). The average total cost (including a 15-pct DCFROR) to produce deadburned MgO ranges from $156/st to $580/st (wtd av of $290/st) from seawater, $179/st to $329/st (wtd av of $237/st) from brines, and $118/st to $480/st (wtd av of $246/st) from magnesite or brucite. The overall weighted-average production cost for deadburned MgO is $257/st. The January 1984 market price for deadburned MgO was $392/st MgO product. (See table 2.) The average total cost at 15-pct DCFROR to recover caustic calcined MgO as a primary product ranges from $191/st to $315/st (wtd av of $246/st) from seawater and $100/st to $404/st (wtd av of $238/st) from magnesite or brucite. The overall weighted-average production cost, including brine sources, is $240/st MgO product, well below the January 1984 market price of $315/st MgO product (table 2) for chemical-grade caustic calcined MgO. The wide variation in cost to recover MgO compounds also reflects variations in source material, capacity, plant age, and process technology. Recovery from seawater appears to be the most costly. Magnesium-rich brines are already partially concentrated, so preliminary concentra- tion required for seawater is unnecessary; consequently, brine costs are lower. Magnesite deposits require even less concentration owing to their high raw Mg content, but mining and beneficiation costs are higher. Costs to recover caustic calcined MgO as the primary recoverable MgO product average 93 pet of the costs to recover deadburned MgO as the primary product. This is to be expected where process technology is similar and only an additional processing step is required to produce the higher grade deadburned MgO product. Because of proprietary considerations, separate costs for producing and nonproducing properties could not be provided in most cases. Nonproducing properties evalu- ated in this study have costs that average 57 pet more than costs from producing properties recovering from a similar source material. Based upon these economic analyses, total and annual availability curves were generated for magnesium metal and selected MgO compounds to indicate magne- sium resource availability. These analyses are based on the following assumptions: 1. Each operation is assumed to produce at its full design capacity. 2. Competition and demand conditions are such that each operation will be able to sell all of its output at its anticipated average total cost of production. 3. For nonproducing operations where no definite startup dates were known, preproduction development work for each property was assumed to begin in 1984. 4. Time lags related to permitting, environmental impact statements, and other possible delays affecting production were minimized. TOTAL AVAILABILITY The total potential availability of selected mag- nesium products from properties included in this study is reported in the figures and tables included in this section. Both 0- and 15-pct DCFROR availability curves are reported; discussions are limited to the 15-pct DCFROR analysis. Of the 38 properties evaluated, 5 operations recover magnesium metal, 22 operations recover dead- burned MgO, and 11 operations recover caustic calcined MgO. The total availability of Mg metal is shown in figure 5. The solid line represents the average total cost required over the assumed life of the operation to meet all costs at a breakeven, or pet, DCFROR. The broken line represents the average total cost of production including a 15-pct DCFROR on invested capital. The same relationship exists on figure 6, which shows the total availability of deadburned MgO and caustic calcined MgO. Similar data are reported for domestic deadburned MgO in figure 7. Tabulated availability data for these products at selected price ranges are reported in table 12. The January 1984 market price for Mg metal ingots was approximately $1.34/lb. Approximately 13 MMst Mg metal is potentially available at an average total cost equal to the reported market price. All properties included in this study incurred costs (including a 15-pct DCFROR) below the market price for Mg metal. The January 1984 market price for deadburned MgO was $392/st. Approximately 109 MMst deadburned MgO is potentially available from evaluated deposits which 18 «* 1.2 oo O) *- 1.0 c CO CO O O O .8 KEY 0-pctDCFROR 15-pctDCFROR , J" ± 2 4 6 8 10 12 RECOVERABLE Mg METAL, MMst FIGURE 5.— Total potential magnesium metal availability from evaluated MEC properties. 14 have production costs (including a 15-pct DCFROR) at or below this price. An additional 17 MMst would become available if the deadburned MgO price rose to $500/st (at a 15-pct DCFROR). The January 1984 market price for caustic calcined MgO was $315/st. At that price, approximately 33 MMst MgO is potentially recoverable from evaluated deposits assuming a 15-pct DCFROR. An additional 9 MMst would become available if the caustic MgO price rose to $350/lb (assuming a 15-pct DCFROR). The domestic magnesium industry has the capability to produce approximately 9.6 MMst Mg metal and 33 MMst deadburned MgO at the January 1984 market price for these products, assuming a 15-pct DCFROR. This equates to 73 pet of the Mg metal and 25 pet of the deadburned MgO potentially available from evaluated world deposits. This is well above the projected domestic consumption level for magnesium products until 2000. At the January 1984 market price, most domestic producers are profitable and achieving at least a 15-pct DCFROR. Resources are enormous so that, assuming no unforeseen changes in the magnesium industry, both domestic and MEC resources should continue to be adequate far into the future. Two important aspects of domestic magnesium com- pound availability should be noted. Some domestic properties produce a variety of low-grade magnesium compounds in addition to deadburned MgO. This study assumed, however, that all production occurred as deadburned MgO at a January 1984 market price of $392/st product. As a result, the actual margin of profit could be slightly lower than that indicated in the evaluation. Secondly, many of these operations are currently operating below their rated capacities, which would reduce their present profit margins. TABLE 12.— Availability of magnesium metal and MgO compounds from selected MEC properties including a 15-pct DCFROR at selected cost ranges (Thousand short tons) Total cost, $/st Mg metal Under 150 (5 151 to 300 301 to 400 401 to 600 601 to 1,000 2,523 1 ,001 to 2,000 8,549 2,000 to 2,700 2,210 Total 13,282 Market price' $/st 2,680 1 As of January 1984; given for comparison. Deadburned Caustic MgO calcined MgO 20,407 14,210 46,791 18,895 41 ,968 9,241 24,874 327 31 134,071 42,673 392 315 19 CO e co O a < O 800r- 700- 600- 500- 400- 300- 200- I0QH A, Deadburned MgO KEY 0-pct DCFROR 15-pct DCFROR 80 ^.j r* ife" 120^ 140 «wu 1 - 1 ~T™ 400 B, Caustic calcined MgO f- - i i 350 i I j i i 300 250 1 . r 1 — • i 1 1 / rJ - 200 — ^ — ^ 150 r j^ ^^ 4 19 24 29 34 39 44 RECOVERABLE MgO, MMst FIGURE 6.— Total potential deadburned and caustic calcined MgO availability from evaluated MEC properties. 20 oo CO O O -J < o 800 700 600 500 400 300 200- 100 KEY 0-pct DCFROR 15-pct DCFROR i — - -c f -P ± ± ± 10 15 20 25 30 RECOVERABLE DEADBURNED MgO, MMst FIGURE 7. — Total potential domestic availability of dead burned MgO from evaluated properties. 35 ANNUAL AVAILABILITY Analyses were also performed to estimate the annual production potential of the magnesium properties evalu- ated in this study. Production potential for currently nonproducing deposits was based upon deposit size (demonstrated resources), past production history, and capacities of similar producing operations. Since the general approach of this study was to evaluate the properties at full production capacity over the next 30 yr, the annual curves present total potential availability for each year shown, rather than an assessment of future production. Figure 8 shows the potential annual availability for Mg metal, deadburned MgO, and caustic calcined MgO based on a 15-pct DCFROR. At a production cost of $1.40/lb (the January 1984 market price was $1.34/lb), approximately 301,000 st Mg metal are potentially available annually between the years 1986 to 2014. All of this was available from producing operations and com- pares with 268,000 st primary Mg metal produced in 1983 (12). Based upon an anticipated growth in world magne- sium consumption at an annual rate of 3.6 pet for primary Mg metal and 0.95 pet for nonmetal magnesium, the forecasted world demand in 1990 is 350,000 st for primary Mg metal and 5,900,000 st for nonmetal magnesium; demand in 2000 is forecast as 490,000 st for primary Mg metal and 6,550,000 st for nonmetal magnesium products (11). A summary of anticipated demand is given in table 13. Deposits evaluated in this study are sufficient to supply 80 pet of 1990 and 57 pet of 2000 consumption needs for Mg metal. Assuming no additions to demons- trated resources as defined in this study, requirements not met by the properties evaluated in this study could most likely be met by properties in CPEC's, by secondary magnesium producers, or properties currently being developed but not considered in this study because of the nature of the magnesium source material. Figure 8 shows that at a total production cost of $400/st (the January 1984 market price was $392/st, approximately 3.0 MMst deadburned MgO are available annually during the period 1987 to 2002. Approximately 85 pet of this is available from current producers. By the end of 2008, production from deposits included in this study would decrease to 2.4 MMst for deadburned MgO annually at a maximum production cost of $400/st. As shown in figure 8, 430,000 st caustic calcined MgO is annually available at total operating costs below the January 1984 market price of $315/st. The forecasted world demand for all nonmetal magnesium compounds is 5.9 MMst contained Mg in 1990 and 6.6 MMst contained Mg in 2000, based upon an anticipated annual growth rate of 0.95 pet for this period (11). Assuming deadburned and caustic calcined MgO constitute 56 pet of all MgO compounds (see figure 2), operations considered in this study could potentially meet approximately 63 pet of the 1990 and 56 pet of 2000 world consumption needs for total nonmetal magnesium from deadburned and caustic calcined MgO. In 1990, CPEC's 21 are anticipated to account for 37 pet of total world production (same as in 1984). The deposits considered in this study can supply approximately 102 pet of demand from MEC's in 1990 and 92 pet in 2000. This study only considered deadburned and caustic calcined MgO prod- ucts; a wide variety of other MgO compounds are produced.-' o 2 < o /' _ 250 (0 2 _r < 200 Ul 2 1 1 1 i r Magnesium price is in Jan. 1984 dollars per pound 0-$l.40 0-$l.20 0-$0.80 0-$0.40 3.0 2.5 2.0 1 1 1 1 r Deadburned MgO price is in Jan 1984 dollars per short ton „. \__o-ieoo ■ __\ 0-J500 \ 0-$4O0 0-$300 r "\ 0-$200 - 600 1984 1989 1994 2004 2009 FIGURE 8.— Annual availability of magnesium metal, dead- burned MgO, and caustic calcined MgO at various prices. TABLE 13.— Summary of domestic and foreign magnesium demand forecasts (11) (Thousand short tons contained magnesium) 1983: Actual 1990: Probable 2000 Probable Low High Domestic: Metal: Primary Secondary . . Nonmetal 92 25 675 120 30 700 170 40 750 90 20 500 270 70 1,200 Foreign: Metal Nonmetal 176 . 4,887 230 5,200 320 5,800 180 4,000 600 7,500 World: Metal: Primary Secondary . . Nonmetal 268 25 . 5,562 350 30 5,900 490 40 6,550 270 20 4,500 870 70 8,700 Total . 5,855 6,280 7,080 4,790 9.640 FACTORS AFFECTING AVAILABILITY Magnesium availability is significantly affected by energy costs. All magnesium producing processes are energy intensive. Because of rising energy costs in the early 1980's and the need to conserve the world's energy resources, producers in recent years have devoted much research effort to reducing the amount of energy required. These efforts are expected to continue in the near future. A comparison of energy requirements for processes commonly used to recover magnesium today is given in table 14. Energy related costs range from 22 to 71 pet of the total direct operating cost, depending upon processing technology and source material. Both metallic and nonmetallic magnesium processing is energy intensive. Figure 9 illustrates the degree to which the total operating cost is influenced by energy costs. Approximate- ly 52 pet of all magnesium plants evaluated have energy costs ranging from 40 to 60 pet of the total production cost. Most producers are striving to reduce energy consumption through technological improvements at every processing stage. The principal barrier to more widespread use of magnesium is its high price relative to aluminum, its principal industrial competitor. A magnesium price reduction of 10 pet could be sufficient for a widespread conversion of aluminum die and mold castings to magnesium (7). TABLE 14. — Energy requirements for magnesium metal production (8,15) Process KWh/lbMg Electrolytic: Dow: Old cells 47 New cells 37 Norsk Hydro: Old I.G. cells 29-31 New cells 26-29 AMAX: Modified I.G. cells 33-35 Thermic: Magnatherm 33-37 22 20-30 31-40 41-50 51-60 61-70 ENERGY COST, pet of total operating cost 70 + FIGURE 9.— Energy costs as a percentage of total operating costs. CONCLUSIONS The magnesium industry appears to be stabilizing after a period of gradually increasing consumption. Since 1980, demand has shown only a slight increase and prices for magnesium products have remained stable. Plants are either operating at reduced rates or are gradually resuming full production rates. Exploration or develop- ment work, halted for the past several years by the sluggish economy, is gradually being resumed at some locations. Magnesium is in an unusual position in that it has the capability of being recovered from multiple renewable sources from almost any country in the world. High costs and processing technology complexity have historically restricted industrial production to technically advanced areas, although development in less industrialized areas is beginning to occur. Magnesium resources have been denned for the next 30 yr. Over this period, properties considered in this study contain an estimated 416 MMst contained MgO, of which 74 pet is recoverable as either Mg metal or MgO compounds utilizing current technolo- gy. There are sufficient magnesium reserves currently developed to sustain present MEC production levels at least through the end of this century. Domestic reserves are also sufficient to meet anticipated domestic consump- tion needs until 2000. Production costs vary greatly depending upon loca- tion, source of raw material, age of property, processing methodology, and marketable product desired. Capital investments for the production of Mg metal range from $3,175/st to $4,500/st annual capacity, while capital requirements for refractory MgO production range from $816/st to $l,180/st annual capacity. Operating costs also vary significantly. Magnesium metal recovery from brines appears to be the most costly on a per ton basis, while costs to recover MgO appear to be highest from seawater operations. Energy costs account for a significant portion of processing costs; the magnesium industry is currently striving to reduce energy consumption to improve the market position of magnesium. Over 13 MMst Mg metal is available from evaluated MEC properties at or below a total cost of $1.34/lb Mg, the January 1984 market price of Mg metal. Approximately 109 MMst deadburned MgO and 33 MMst caustic calcined MgO were available at or below the January 1984 market prices for those products. MEC operations considered in this study are sufficient to supply 80 pet of the projected 1990 and 57 pet of 2000 world consumption needs for Mg metal. They could potentially meet approximately 63 pet of the projected 1990 and 56 pet of the 2000 world consumption needs for total nonmetal magnesium from deadburned and caustic MgO sources. Domestic operations have the capability to supply 9.6 MMst Mg metal and 33 MMst deadburned MgO at the January 1984 market prices of these products, assuming a 15-pct DCFROR. The total domestic material available over the next 30 yr is well above the projected cumulative domestic needs for these products. As of January 1984, all domestic producers appear to be profitable. The domestic magnesium resource should continue to be adequate. If energy costs remain a prime consideration, imports from countries with lower energy costs could compete with domestically produced magnesium products. U.S. domi- nance in magnesium markets could well depend on the domestic magnesium industry's ability to reduce energy costs to a competitive level. The CPEC's share of world magnesium markets in 1984 amounted to 28 pet for magnesium metal and 61 pet for magnesite. These countries remain relatively un- affected by the recent recession in the Western World and have continued to increase magnesium production capa- bility at the expense of MEC production. Should current trends continue, the CPEC's share of world magnesium markets could be even greater in coming years. REFERENCES 23 1. Babitzke, H. R., A. F. Barsotti, J. S. Coffman, J. G. Thompson, and H. J. Bennett. The Bureau of Mines Minerals Availability System: An Update of Information Circular 8654. BuMines JC 8887, 1982, 54 pp. 2. Chemical Marketing Reporter. Current Prices of Chemicals and Related Materials, v. 221-224, Jan. 1982-Jan. 1985. 3. Clement, G. K., Jr., R. L. Miller, P. A. Seibert, L. Avery, and H. Bennett. Capital and Operating Cost Estimating System Manual for Mining and Beneficiation of Metallic and Nonmetallic Minerals Except Fossil Fuels in the United States and Canada. BuMines Spec. Publ., 1981, 149 pp. 4. Comstock, H. B. Magnesium and Magnesium Compounds. BuMines IC 8201, 1963, 128 pp. 5. Coope, B. M. Magnesia Markets — Refractory Contraction and Caustic Stagnation. Ind. Miner. (London), No. 191, 1983, pp. 57-87. 6. Davidoff, R. L. Supply Analysis Model (SAM): A Minerals Availability System Methodology. BuMines IC 8820, 1980, 45 pp. 7. Duncan, L. R., and W. H. McCracken. The Impact of Energy on Refractory Raw Materials. Ind. Miner. (London), No. 160, 1981, pp. 19-22. 8. Flemings, M. C, G. B. Kenney, D. R. Sadoway, J. P. Clark, and J. Szekely. An Assessment of Magnesium Primary Produc- tion Technology (Dep. Energy contract ACO1-76CS40284). MIT Press, 1981, 176 pp. 9. Hill, M. N. (ed.). The Sea: Ideas and Observations on Progress in the Study of the Seas. Interscience Publ., 1963, p. 10. 10. King, P. Magnesium, The International Perspective. Fin. Times Bus. Info., Ltd., London, 1983, 156 pp. 11. Kramer, D. A. Magnesium. Ch. in Mineral Facts and Problems, 1985 Edition. BuMines B 675, 1985, pp. 471-482. 12. Magnesium. BuMines Minerals Yearbook 1984, v. 1, pp. 615-620. 13. Magnesium Compounds. BuMines Minerals Yearbook 1984, v. 1, pp. 621-626. 14. Magnesium Metal Sec. in BuMines Mineral Commodity Summaries 1985, pp. 92-93. 15. Lea, D. Magnesium Extraction Processes Today. Light Met. Age, v. 40, No. 8, 1982, pp. 29-33. 16. Logerot, J. M., and J. Moyen. Magnesium Production Methods — Raw Materials and Availability. Light Met. Age, v. 40, No. 12, 1982, pp. 27-30. 17. Metal Bulletin Monthly. Costs of Magnesium vs Alumi- num. No. 97, 1979, pp. 23-26. 18. Mikami, H. M. Refractory Magnesia. Pres. at Conf. for Raw Materials for Refractories (Tuscaloosa, AL, Feb. 8-9, 1982), 40 pp,; available on request from D. R. Wilburn, BuMines, Denver, CO. 19. Raymond Kaiser Engineers, Inc. Development of En- gineering and Cost Data for Foreign Magnesium Properties (contract JO225016). BuMines OFR 84-86, 1985, 32 pp.; NTIS PB 86-236700. 20. Schmid, I. H. China — the Magnesite Giant. Ind. Miner. (London), No. 203, 1984, pp. 27-45. 21. Sorenson, H. O., and R. T. Segall. Natural Brines of the Detroit River Group, Michigan Basin. Sec. in Fourth Symposium on Salt, ed. by A. H. Coogan. North. OH Geol. Soc, Inc., Cleveland, OH, v. 1, 1973, pp. 91-99. 22. U.S. Bureau of Mines. Minerals Yearbooks 1960-83. Chapters on Magnesium and Magnesium Compounds. 23. U.S. Bureau of Mines and U.S. Geological Survey. Principles of a Resource/Reserve Classification for Minerals. U.S. Geol. Surv. Circ. 831, 1980, 5 pp. 24. Wicken, O. M., and L. R. Duncan. Magnesite and Related Minerals. Ch. in Industrial Minerals and Rocks, ed. by S. J. Lefond. AIME, 4th ed., 1975, pp. 805-820. 24 APPENDIX.— AREAS AND SOURCE MATERIALS EXCLUDED FROM THIS STUDY Magnesium or magnesium compounds may be recov- ered from numerous sources throughout the world, some of which have not been included in this study owing to lack of available or reliable information. Potential sources excluded from this report are summarized below. Discus- sions include the nature of the source material, production status as of 1984, and any available reserve-resource data. Resource material discussed below would most likely be classified as identified resources. Magnesium production from olivine deposits is approximately 440,000 st/yr. The principal producing countries are Norway, Sweden, Australia, and the United States. Domestic olivine reserves are estimated at 230 MMst, averaging 48 pet MgO, from North Carolina and Georgia and 55 MMst from Washington. While limited quantities of processed olivine are used in refractories, its principle use is in heat storage blocks (24). AUSTRIA Austria produces a range of refractory and caustic MgO products from both domestic high-iron breunnerite deposits and imported MgO. The magnesium industry in Austria has two main producers, Magnesia AG (Switzer- land) and Osterreichisch-Amerikanische Magnesit AG (OAMAG). Two other companies produce magnesite, but Magnesia AG owns a majority share of Magindag AG and OAMAG owns Tiroler Magnesit AG. These companies currently operate five mines with a total production of approximately 1,100,000 st/yr raw magnesite. The bulk of magnesite production is destined for export. ISRAEL Magnesium production from Israel comes mainly from the Dead Sea Periclase Ltd. project, which produces MgO from MgCl 2 -rich brines. At present, a unique thermal decomposition process is employed at this operation to recover both deadburned and calcined MgO products. An expansion from the current 44,000 st/yr product capacity is currently ongoing and scheduled for completion in 1987. NEPAL The Kharidunga magnesite deposit in Nepal is currently being developed to recover 55,000 st/yr dead- burned MgO. The project is managed by Nepal Orind Magnesite Ltd., a joint venture of the Nepal Government and Orissa Mining Corp. of India. Startup is scheduled for 1987 (5). NORTH KOREA North Korea is reported to have sizable magnesite deposits with demonstrated reserves of over 900 MMst contained Mg (11). Current production is estimated at 2.0 MMst/yr raw magnesite, although recent reports suggest that a major expansion program is in progress. North Korea has a present production capacity of 660,000 st/yr deadburned MgO. Detailed economic data are not avail- able. REPUBLIC OF SOUTH AFRICA CHINA China is one of the world's largest producers of natural magnesite, based upon the huge reserves of the Liaoning deposits in northeastern China. Over 2 billion st macrocrystalline magnesite have been defined, and over 30 billion st magnesite are possible from the province (20). At present three large open-cast mines are in operation and provide feed for production of 770,000 st/yr dead- burned MgO and 330,000 st/yr caustic calcined MgO. The high-quality magnesite can yield grades of 95 to 98 pet MgO; however, because of inefficient calcining techniques and the use of high-ash coke, production of high-grade products to date has been limited. China is currently developing modern technology to produce a full range of high-quality metal and nonmetallic magnesium products. Lack of detailed data prevented inclusion of this area in this study. The Republic of South Africa has produced refractory magnesia products from natural magnesite deposits. At present, the only producing operation is the Vereeniging Refractories Ltd. mine at Burgersfort, Transvaal, which produces 38,000 st/yr deadburned MgO. Future plans call for the development of a seawater magnesia plant by a new processing technique developed by Anglovaal Ltd. Preliminary studies are underway. U.S.S.R. The U.S.S.R. produces both Mg metal and magnesium compounds from its magnesite deposits and from seawa- ter. The magnesium industry is reported to be expanding rapidly in the U.S.S.R. with current production capacity exceeding 770,000 st/yr deadburned and caustic MgO and 91,000 st/yr Mg metal (11). *U.S. Government Printing Office : 1986 -168-969/51027 * 29 V J- O j * 3 , o ,f v ' ^ A^ o Xp-^ : 4^ 'M"*^ \.0^ t « 1 "* "^O jP^ I™ . < * o . *^5. ^ ^ *l§ll^ , "^ & ♦MA . ^ ** *SbS* ^ <^ <> *'7VV 4 •G' 9 V ^ e n o 4CU ^ > ^ ^0 o " o * tJ^, A^ *