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Thomas Hillman UNITED STATES DEPARTMENT OF THE INTERIOR Information Circular 8933 Manganese Nodule Resources of Three Areas in the Northeast Pacific Ocean: With Proposed Mining-Beneficiation Systems and Costs A Minerals Availability System Appraisal By C. Thomas Hillman UNITED STATES DEPARTMENT OF THE INTERIOR James G. Watt, Secretary BUREAU OF MINES Robert C. Horton, Director As the Nation's principal conservation agency, the Department of the Interior has responsibility for most of our nationally owned public lands and natural resources. This includes fostering the wisest use of our land and water re- sources, protecting our fish and wildlife, preserving the environmental and cultural values of our national parks and historical places, and providing for the enjoyment of life through outdoor recreation. The Department assesses our energy and mineral resources and works to assure that their development is in the best interests of all our people. The Department also has a major re- sponsibility for American Indian reservation communities and for people who live in Island Territories under U.S. administration. # This publication has been cataloged as follows: Hillman, C. Thomas Manganese nodule resources of three areas in the northeast Pacific Ocean. (Information circular / United States Department of the Interior, Bu- reau of Mines ; 8933) Bibliography: p. 38-40. Supt. of Docs, no.: I 28.27:8933. 1. Manganese nodules— Pacific Ocean. 2. Ocean mining— Pacific Ocean. 3. Ore-dressing. I. Title. II. Series: Information circular (United States. Bureau of Mines) ; 8933. TN295.U4 [TN490.M3] 622s [553.4'629] 83-600014 For sale by the Superintendent of Documents, U.S. Government Printing Office Washington, D.C. 20402 CONTENTS Page 1 Abstract 1 Introduction 2 I Acknowledgments 3 I Location and geography 5 Geology 5 Geological setting 5 Deposit description 6 Mineralogy 7 Resources 8 Discussion 8 Grade and abundance estimates 8 Minable resources 12 Mining and processing technology 13 Discussion 13 Operational integration of a proposed recovery system 15 Mining 16 Transportation 20 Slurry terminal 21 Cuprion processing 23 Manganese recovery 27 Waste disposal 28 Capital and operating costs 28 Discussion 28 Capital costs 29 Operating costs 31 Cost summary 32 Financial analysis 33 Production and supply 35 Summary 37 References 38 Appendix A. — Discussion of abundance and resource estimates 41 Appendix B. — Sample station locations, abundance estimates, and analyses for study areas A, B, and C 43 ILLUSTRATIONS 1. Location of the northeast Pacific high-grade zone and DOMES Sites A, B, and C 3 2. Sediment map of the northeast Pacific Ocean, with locations of study areas A, B, and C 4 3. Manganese nodule deposit in the northeast Pacific Ocean 6 4 . Manganese nodule polished cross section 7 5. Station locations, nodule occurrences, and grades in study area A.... Pocket 6. Station locations, nodule occurrences, and grades in subarea AII(a) 10 7. Station locations, nodule occurrences, and grades in study area B.... Pocket 8. Station locations, nodule occurrences, and grades in subarea BIII(a).... 11 9. Station locations, nodule occurrences, and grades in study area C... Pocket 10. Station locations, nodule occurrences, and grades in subarea CI 12 11. Hydraulic deep ocean mining system 17 12. Plan view of slurry receiving terminal and pumping station 22 13. Cuprion process flowsheet for recovery of nickel, copper, and cobalt.... 25 14. Generalized flowsheet of a proposed ferromanganese plant 28 1 5 . Pro j ect development schedule 34 11 TABLES Page 1. Summary of mean elemental contents, study areas A, B, and C 9 2. Average abundance and subarea size, study areas A, B, and C 9 3. Estimated minable and recoverable resources, subareas All, Bill, and CI. 13 4. Deposit characteristics affecting minability, ventures 1, 2, and 3 19 5. Mining parameters for ventures 1, 2, and 3 20 6. Characteristics of proposed 70,000-dwt nodule transports 20 7. Summary of transportation data, ventures 1, 2, and 3 21 8. Cuprion ammonia leach plant, major inputs and wastes 27 9. Mine capital costs, ventures 1, 2, and 3 29 10. Transportation capital costs, ventures 1, 2, and 3 29 11. Cuprion and ferromanganese plant capital costs, ventures 1, 2, and 3.... 30 12. Mine operating costs, ventures 1, 2, and 3 31 13. Transportation operating costs, ventures 1, 2, and 3 31 14. Cuprion and ferromanganese plant operating costs, ventures 1, 2, and 3.. 32 15. Capital cost summary, ventures 1, 2, and 3 33 16. Operating cost summary, ventures 1, 2, and 3 33 17. Total commodity revenues, ventures 1, 2, and 3 35 18. Projected rates of return, ventures 1, 2, and 3 35 19. Comparison of U.S. consumption of nickel, copper, cobalt, and manganese with potential production from ventures 1, 2, and 3 36 B-l. Subarea AI — location, abundance, and analytical data 43 B-2. Subarea All — location, abundance, and analytical data 44 B-3. Subarea AIII — location, abundance, and analytical data 47 B-4. Subarea AIV — location, abundance, and analytical data 48 B-5. Subarea AV — location, abundance, and analytical data 49 B-6. Subarea AVI — location, abundance, and analytical data 50 B-7. Study area A — location, abundance, and analytical data outside subareas. 51 B-8. Subarea BI — location, abundance, and analytical data 52 B-9. Subarea BII — location, abundance, and analytical data 53 B-10. Subarea Bill — location, abundance, and analytical data 54 B-ll. Study area B — location, abundance, and analytical data outside subareas. 56 B-12. Subarea CI — location, abundance, and analytical data 57 B-13. Subarea CII — location, abundance, and analytical data 59 B-14. Study area C — location, abundance, and analytical data outside subareas. 60 Ill UNIT OF MEASURE ABBREVIATIONS USED IN THIS REPORT bbl/d barrel per day kn knot cm centimeter kW*h kilowatt hour meter square meter cubic meter cm z square centimeter m cm 3 cubic centimeter m 2 cm/s centimeter per second m 3 d day min ° C degree Celsius mm dwt deadweight ton m/s d/yr day per year MW g/cm 2 gram per square centimeter nmi g/cm 3 gram per cubic centimeter m 3 /min g/L gram per liter pet h hour t ha hectare t/d h/d hour per day t/h hp horsepower t/km 2 kg/cm 2 kg/d kg/m 2 km kilogram per square centimeter kilogram per day kilogram per square meter kilometer t/yr vol pet wt pet km 2 square kilometer yr minute millimeter meter per second megawatt nautical mile cubic meter per minute percent metric ton metric ton per day metric ton per hour metric ton per square kilometer metric ton per year volume percent weight percent year MANGANESE NODULE RESOURCES OF THREE AREAS IN THE NORTHEAST PACIFIC OCEAN: WITH PROPOSED MINING-BENEFICIATION SYSTEMS AND COSTS A Minerals Availability System Appraisal By C. Thomas Hillman 1 ABSTRACT The practical concern of economic minability of large, high-grade man- ganese nodule deposits in the northeast Pacific Ocean is addressed in this Bureau of Mines report. Principal objectives are to (1) estimate tonnage and grade of deposits with significant potential and (2) de- scribe and estimate profitability of operations designed to mine and process deposits with greatest apparent potential. Analysis of data from over 800 ship stations identified three areas for detailed study. Average metal contents of these areas range from 1.30 to 1.45 wt pet nickel, 1.00 to 1.24 wt pet copper, 0.21 to 0.26 wt pet cobalt, and 26.8 to 27.8 wt pet manganese. Estimated recov- erable nodule resources are 67.0, 66.9, and 148.8 million dry metric tons (t). A system to mine, transport, and process nodules from the three sites is described and costed. Although hypothetical, the system utilizes hydraulic mining and Cuprion (Kennecott) processing, which have been successfully tested at pilot scale. Nickel, copper, and cobalt are the three primary products, but ferromanganese is a considered option. Estimated capital requirements are approximately $1.5 to $1.7 billion for three-metal production. If ferromanganese were recovered, an addi- tional investment of about $130 million would be required. Operating costs range from $71 to $83 per dry metric ton of nodules without man- ganese, and from $103 to $123 per dry metric ton with ferromanganese. Discounted cash flow analyses predict low returns, ranging from 2.7 to 5.2 pet with ferromanganese and from 4.1 to 6.0 pet without. 1 Physical scientist, Western Field Operations Center, Bureau of Mines, Spokane, WA. INTRODUCTION Deep ocean manganese nodule deposits, representing a very large source of the metals nickel, copper, cobalt, and manga- nese, are the subject of continuing in- ternational controversy. The central issue is ownership and control, because the largest and highest grade deposits generally are in the deep ocean beyond territorial limits. Despite controversy, a substantial amount of exploration has occurred during the last 10 to 15 yr. Various mining consortia with U.S., Canadian, European, and Japanese partners have prospected large areas of the world's oceans, especially the region known as the northeast Pacific high-grade zone. This area extends from about 110° W to 160° W longitude and 5° N to 20° N latitude, and is presently the area of primary commercial interest. Indica- tions are that many potential minesites have been discovered and explored to varying degrees (28) . 2 Because of high exploration costs, uncertain political climate, and the competitive nature of the business, most information has been kept proprietary. This policy ,- although proper, fuels the ownership controversy, because there is a belief by many that manganese nodules represent a source of tremendous profit for those in a position to grasp it. The fact that large, high- grade deposits exist, however, does not guarantee profit can be attained from their exploitation. While much has been written concerning nodule resources, conceptual mine-process systems, and economics, no published work is available which addresses the question of profitability of mining a specific 2 Underlined numbers in parentheses re- fer to items in the list of references preceding the appendixes. nodule deposit. Therefore, the purposes of this report are to analyze available information on deposits in the northeast Pacific high-grade zone in an attempt to identify areas of high grade and abun- dance, and determine their minability and profitability based on existing technol- ogy and economics. A final purpose, irrespective of profitability, is to ana- lyze the potential beneficial impacts nodule production could have on the U.S. supply of nickel, copper, cobalt, and manganese. The study was performed as part of the Bureau of Mines minerals availability program to inventory and assess the availability of nonfuel minerals. The basis for this program consists of evalu- ations of individual deposits. Each de- posit report normally includes geological and geographical descriptions , resource- reserve estimates, mining and beneficia- tion plans, and an economic analysis. These same elements are present in this report, which is in reality a specialized and expanded minerals availability depos- it report. Resource information was gathered dur- ing the past 5 yr, through Bureau of Mines grants to Scripps Institution of Oceanography and Washington State Univer- sity, and by contacts with personnel of the U.S. Geological Survey (26-28). Much data were developed as a spinoff of proj- ect DOMES (Deep Ocean Mining Environ- mental Study) carried out by the National Oceanic and Atmospheric Administration (NOAA). DOMES was a detailed investiga- tion of the deep ocean environment of three potential minesites (A, B, and C) and a determination of possible effects of nodule mining. Figure 1 shows the northeast Pacific high-grade zone and locations of the three DOMES sites. FIGURE 1. - Location of the northeast Pacific high-grade zone and DOMES Sites A, B, and C. Resource data consist of nodule assays (dry weight percent), populations (per- cent of seafloor covered with nodules), and abundances (weight per unit area) from more than 800 ship stations situated in three broad areas encompassing DOMES Sites A, B, and C (Fig. 2). Because of apparent high grade and abundance, spe- cific deposits within these areas are believed to have significant economic potential. A proposed system to mine, transport, and beneficiate nodules from these areas is described and costed. Although no attempt was made to opti- mize either capacity or location of processing facility, the system repre- sents a likely approach to recovery of these resources. A financial analysis, based on derived costs, was completed us- ing a Bureau of Mines mine simulator com- puter program (MINSIM4). A discussion of results precedes a short analysis of the potential for reducing U.S. depen- dence on imports of nickel, cobalt, and manganese. ACKNOWLEDGMENTS The author expresses appreciation to Dr. John Flipse, ocean mining consultant, College Station, TX; Benjamin V. Andrews, ocean transportation consultant, Menlo Park, CA; and Dr. Francis Brown, process engineer, EIC Corp., Newton, MA; who pro- vided technical and cost information. r f LOCATION AND GEOGRAPHY The northeast Pacific high-grade zone, presently the area of greatest commercial interest, stretches from south of Baja California at 110° W longitude to nearly 160° W longitude south of Hawaii; it encompasses approximately 10 million km 2 . Study areas A, B, and C are about 4,600, 3,800, and 3,300 km, respectively, south- west of Los Angeles, CA. The best de- posits generally lie between the promi- nent Clipperton and Clarion Fault zones . Climate in the entire region is typical of the trade winds zone. The northeast trade winds blow steadily, but moderate- ly, throughout the year (37) . Rainfall is slight, increasing somewhat near the equator. Tropical storms and typhoons, usually lasting 1 or 2 days, occur pri- marily in summer months. A 10-yr survey indicates an average of 3.6, 4.4, and 2.9 storms per month for July, August, and September, respectively. The average for 1966-75 was 15 storms per year. Air tem- peratures at sea level average 25° C for the year; monthly averages vary only a degree or two ( 48 ) . Surface currents in the region of interest are largely controlled by wind (37) . The prevailing current , the North Equatorial Current, generally flows from an east-northeast direction, split- ting into several branches and eddies . Velocity measurements during the fall of 1975 and 1976 averaged 17 cm/s at the surface. The current decreases to zero at a depth of approximately 160 m and then reverses, flowing eastward at a ve- locity of 5.4 cm/s at 300-m depth. Data on bottom currents in study area C are not available, yet existing water mass characteristics and theoretical studies indicate a net eastward flow at low velocities (37). Measurements at the other two study areas indicate average velocities of 2.1 cm/s in DOMES Site A, and 5.2 cm/s in DOMES Site B. A mean westward movement was recorded ( 37 ) , but may be a result of the short duration of the measurement. Assumptions made, based on the previous discussion, are that surface and bottom currents would not significantly hinder mining operations, but that tropical storms would preclude mining from 30 to 40 days each year. GEOLOGY GEOLOGICAL SETTING The area of interest falls within the Eastern Pacific Sedimentary Basin. Sea- mounts are in all parts of the basin, but are most prevalent near the east and west margins. Groups of sediment-covered abyssal hills ( 33 ) , characteristically elongated and parallel to one another, are the most dominant topographic fea- ture. Crest-to-crest distances are vari- able, but typically range from 5 to 10 km (36) . Local relief is generally low, but may reach 300 m. Slopes average 2° to 6° and generally do not exceed 15° except in areas of current scour or fault scarps (38) . Commonly , parallel scarps impart a stairstep effect on hillsides accompanied by sediment slumping and exposure of underlying basement rock. Water depths ranging from 3,600 to 5,500 m increase to the north and west away from the Clipperton and Clarion Fault zones and the East Pacific Rise (spreading center). Accretion of basalt crust within the narrow spreading center and progressive outward movement results in a pattern of systematic aging in a westerly direction ( 39 ) . Crustal ages are mostly Oligocene in study area C, Paleocene in study area B, and Late Cre- taceous in study area A. In the northeast Pacific Ocean, distri- bution of sediments is strongly influ- enced by proximity to volcanic islands and other topographic highs , biological productivity of surface waters , and the increase of calcium carbonate solubility with depth (49) . Pelagic clays are dominant north of the Clarion fracture zone and in large irreg- ular areas south of it (fig. 2). These sediments are reddish-brown to chocolate colored, and are composed mainly of the clay minerals illite, smectite, and kao- linite. Because dissolution of fossil remains is nearly as rapid as deposition, organic remains are generally less than 30 pet. This is attributable to a de- crease in biological activity away from the equator, and an increase in water depths. Sediment accumulation rates are very low, probably from 1 to 3 mm per 1,000 yr (37). Between the Clipperton and Clarion fracture zones, siliceous ooze and sili- ceous clay are the most widespread sedi- ments. These are mostly clay minerals, but contain significant organic remains; in the case of ooze, at least 30 pet. Organic material is predominantly Quater- nary radiolaria, diatoms, sponge spic- ules, and silicof lagellates. Accumula- tion rates are believed to be from 3 to 8 mm per 1,000 yr. Calcareous sediments cover tops of iso- lated seamounts and the seafloo'r in the southwest corner of the high-grade zone, but the most widespread occurrences are south of the Clipperton fracture zone. Coccoliths and foraminifera are the chief constituents; other materials include siliceous fossils, volcanic glass, and clay minerals. Accumulation rates are variable, ranging from 10 to more than 100 mm per 1,000 yr depending on depths and surface activities (49) . Volcanic ash is the dominant sediment surrounding the Hawaiian Islands, over- lapping and burying siliceous ooze and clay northwest of study area A. Terrige- nous sediments, graded and ungraded, blanket the ocean floor adjacent to the North American Continent, but do not ex- tend beyond a few hundred kilometers. Sediment accumulation rates and thick- nesses in these environments are extreme- ly variable. In the three study areas, total sediment thicknesses are thought to average as follows, in meters: area A, 250; area B, 200; and area C, 100. Wet bulk densities of sediments probably average from 1.2 to 1.3 g/cm 3 (37) . Sed- iments higher in biogenic debris are slightly less dense, because they con- tain more water. Vane shear strength, which is an indicator of load-bearing strength, is variable, but may average about 20 g/cm 2 at the sediment surface. This increases rapidly to 100 g/cm 2 at a depth of 15 cm. Below 15 cm, sediment strengths are believed to remain nearly constant (37) . DEPOSIT DESCRIPTION Nodule deposits occur mainly as irregu- lar, single-layer fields at the sediment- water interface (fig. 3). Additional nodules buried in sediment within a meter of the ocean floor surface compose an amount approximately equal to 25 pet of those on the surface. Few nodules occur below 1-m depth ( 39 ) . Within the high- grade zone, nodule sizes range from less than a millimeter (micronodules) to many centimeters in diameter. Nodule popula- tions range from to nearly 100 pet. Highest populations and grades are usu- ally associated with siliceous oozes and clays (19) . Sedimentation rates are very low, usually a few millimeters per 1,000 yr; total sediment thickness is less than 300 m. ''*-. fi <&+ "As** V«^ V v. Am rfi ***** &X&S& FIGURE 3. - Manganese nodule deposit in the northeast Pacific Ocean. Note irregular distri- bution and partial burial of nodules. Individual nodules are dull, earthy brown to lustrous blue black, with vari- able shapes. Characteristically, small nodules are spheroidal, and progressively larger nodules are ellipsoidal, and finally discoidal. Sorem and Fewkes ( 43 ) attribute this phenomenon to unequal growth. Bottom portions, nested in sedi- ment, accrete more rapidly than exposed tops. Irregular shapes, differing from the typical forms, are common. This characteristic is a result of natural ag- glomeration of smaller nodules, and the tendency of nodules to reflect the mor- phology of irregularly shaped nuclei. Surface textures range from smooth to granular, the apparent result of differ- ent growth patterns of constituent ox- ides. Porosity and internal surface area of individual nodules are high, about 50 pet and 200 to 300 m 2 , respective- ly (35). As a result, most nodules con- tain about 30 wt pet sea water; wet spe- cific gravity ranges from 2.0 to 2.5 MINERALOGY Ferromanganese nodules are typically composed of one or more nuclei surrounded by discontinuous layers of manganese and iron oxides. This imparts an onionpeel structure observed in cross section (31) . Clay layers occur at irregular intervals between the oxide phases, possibly sig- naling periods of nongrowth. Radial and concentric fracturing are nearly univer- sal in larger nodules (fig. 4). According to Sorem and Fewkes (43) , northeast Pacific nodules are composed mainly of dense top layers of amorphous iron oxides, whereas the bottom layers are generally intergrowths of the hydrous crystalline manganese oxides, todorokite and birnessite. Minor quantities of the mineral, 6-Mn0 2 also occur. Todorokite and birnessite are believed to contain the bulk of nickel and copper present in nodules. These two metals may be carried by lattice substitution, ion exchange, or FIGURE 4. - Manganese nodule polished cross section. The large clay-rich nucleus is sur- rounded by concentric layers of metal-rich oxides (light) and clay (dark). (Courtesy IF 1/ Plenum and Washington Slate Unii: entity.) adsorption ( 35 ) . The cobalt association is more obscure. However, recent work indicates that in high-cobalt nodules the element is preferentially enriched in manganese oxide phases. Conversely, in nodules with lower cobalt, iron oxides contain most of the element (21). RESOURCES DISCUSSION In this report, grades assigned to deposits are based on X-ray fluorescence spectrometry and atomic absorption analy- ses of nodules. Analytical data were ob- tained from many sources and have been carefully screened. As an example, as- says of specific nodule parts, such as nuclei, outer layers, etc., were dis- carded and only analyses of whole nodules or representative portions retained. 3 Detailed studies of samples from DOMES Site C (11) show that the arithmetic mean of metal contents at individual sample sites can be predicted within ±10 pet, and at a 90-pct confidence level, with relatively few assays. For example, at 76 pet of the sites sampled, means for nickel, copper, cobalt, manganese, iron, and zinc can be estimated from less than 20 nodule analyses per site. If only nickel and copper are of interest, the mean can be predicted at 86 pet of the sample locations with analyses of just 11 nodules per site. The study (11) also shows that variations in metal contents may be greater between nodules in the same sample than between sample averages from nearby, yet different locations. This phenomenon is probably the result of variations in metal content between dif- ferent size nodules. Comparisons of hun- dreds of analyses by Frazer (22) support the observations of Fewkes (11-13) , and indicate arithmetic means can be accu- rately predicted for sample stations in large areas of the high-grade zone with relatively few analyses. Nodule abundances (weight per unit area) and consequently resource quanti- ties calculated from them are more 3 See Frazer (^2 ) , Fisk (J_4) , and Frazer and Fisk (20-21 ) for data, references, and discussion. See Fewkes (11-13) for additional information and discussion. difficult to determine. Despite the fact that nodule deposits cover very large areas of the seafloor, local nodule popu- lations are extremely variable. Over distances of a few meters, abundances may range from near to 10 or 15 kg/m 2 . Ideally, sampling is conducted on a grid basis, with bottom photography or tele- vision surveys between sample points. By necessity, however, estimates in this re- port are based on randomly located sam- ples and on series of photographs taken sequentially along linear track lines. This is because the original purpose of the work was research, rather than re- source evaluation. Factors relating to abundance and re- source estimates from seafloor photo- graphs and in situ sampling are discussed in appendix A. Because detailed site- specific data are unavailable to calcu- late photograph correction factors and because some sampling devices may lose portions of samples, estimates in this report are probably conservative, and are considered "minimum" values. Costing and system descriptions in succeeding sec- tions are based on these minimum values. GRADE AND ABUNDANCE ESTIMATES Based on available data, estimates of grades and abundances are made for depos- its in study areas A, B, and C. These three large areas are divided into sev- eral smaller ones (subareas) on the basis of station locations, nodule grades, and abundances. Rectangular boundaries are used for convenience and do not neces- sarily enclose or delimit any single deposit. In reality, an area large enough to support commercial mining may contain several distinct deposits. Assigned grades are simply the average of arithmetic means of samples at indi- vidual sites within subarea boundaries. Abundances are likewise averages of abundance estimates for individual sta- tions. Abundance estimates determined from actual samples were not differenti- ated from those derived from photographs , nor was any greater significance attached to them. regarded by some ( 18 ) to be a minimum requirement for a potential minesite. Of the remaining subareas only AIV appears to contain deposits grading well below the estimated requirement of 2.3 wt pet nickel plus copper. Station locations, average grades, and other information are illustrated in fig- ures 5 through 10 (figs. 5, 7, and 9 are in pocket at end of report). Figures 6, 8, and 10 are enlargements of intensely sampled areas, which could not be proper- ly shown on a small-scale map. Numbers next to sample points are keyed to cor- responding index numbers in Appendix B, which is a series of tables containing index numbers, locations, population es- timates, abundance estimates, nodule assays, and statistical summaries. Indi- vidual tables are included for each sub- area within study areas A, B, and C. Data for samples outside subarea bound- aries are listed in separate tables. Table 1 is a summary of analytical data contained in Appendix B. Grades assigned to deposits in subareas All, AIII, Bill, CI, and CII average 2.3 wt pet or greater nickel plus copper. This figure is A summary of available abundance data and subarea size is contained in table 2. For convenience, abundances are given in both wet kilograms per square meter and dry metric tons per square kilometer. Subareas All, AIV, and CI appear to con- tain significantly high abundances, while AIII and Bill apparently contain medium abundances , and AV has low abundances . No estimates are available for the re- maining five subareas. Consideration of grade, abundance, and size (square kilometers) indicates three of the subareas (All, Bill, and CI) have the greatest economic potential, because deposits are high grade, and occur over large areas in sufficient abundance to support mining for a reasonable length of time (i.e., 20 yr) . The proposed mining and benef iciation systems and economic analyses address these three subareas only. TABLE 1 . - Summary of mean elemental contents, study areas A, B, and C, weight-percent 1 Subarea Ni Cu Co Mo Mn Fe 1.20 0.98 0.21 0.04 24.2 7.4 All 1.30 1.00 .21 .05 27.8 7.1 AIII... 1.30 1.19 .22 .05 26.5 7.3 AIV .96 .67 .28 20.2 10.0 1.41 1.20 .21 26.2 5.7 AVI.... 1.13 1.10 .17 .04 24.3 6.9 1.10 .84 .23 22.0 6.1 BII 1.18 .92 .23 .06 24.3 6.3 Bill... 1.45 1.24 .25 .07 27.2 5.2 1.33 1.04 .26 .07 26.8 6.9 CII 1.39 .96 .17 .07 27.7 8.5 L Dry-weight basis NOTE. —Blank available. indicates no information TABLE 2. - Average abundance and subarea size, study areas A, B, and C Subarea AI... All.. AIII. AIV.. AV... AVI.. BI.., BII., Bill, CI.., CII., Esti- mates 12 9 16 15 74 59 Abundance 1 Wet, kg/m 2 NAp 8.8 6.2 9.2 3.4 NAp NAp NAp 5.3 11.7 NAp Dry, t/km 2 NAp 6,200 4,300 6,400 2,400 NAp NAp NAp 3,700 8,200 NAp Subarea size , km 2 43,700 36,000 17,000 22,100 24,100 18,500 12,500 10,900 64,600 57,600 35,800 Not applicable; no estimates, nodules contain approximately 30 wt pet free water. NAp L Wet 10 146.1° 146.0" 145.9' 145.8' 141-144 150 <***» <»133 1 49— ^^^^ 1 46- 1 48 CXK K1 •145 71-75? I 65 " 70 • 57 9.5° 151-154 173 76-80 58-64 ,140 9.4' J&157-160 Ojm<9. ,172^ 131f3(fl29 128 \ ( **^ a 10810 ]j£ 109-112 LEGEND O Ni plus Cu 2.3 wt pet Numbers next to symbols coincide with index numbers in Appendix B. 5200 9.3° 9.2' 10 -I Scale, km Bathymetric contours in meters below mean sea level 146.1° 146.0° 145.9° 145.8 FIGURE 6. - Station locations, nodule occurrences, and grades in subarea All(a). 11 140.2° 140.1' 140.0° 451,452 495 496,497 4gg 444 M87 *y ^443484 ^ a'a 481 454 489 498 500 445 446 50 1-^P\ 448^ a •! SO 5 * *0 AT a5o^ 442 441 # A-485 r\A— 482 ^V 440 ^50^488,490,491 486 492/^0) 439 LEGEND ^ No nodules observed or recovered As Nodules present, no assay O Ni plus Cu< 1.8 wt pet 3 Ni plus Cu 1.8-2.3 wt pet • Ni plus Cu>2.3 wt pet Numbers next to symbols coincide with index numbers in Appendix B I 10 Scale, km Bathymetric contours in meters below mean sea level 11.2 s 11.1' 11.0* 10.9 C 140.0° 140.1° 140.2° FIGURE 8. - Station locations, nodule occurrences, and grades in subarea Blll(a) 12 127.0° 126.0° 125.0° 16.0° 15.0° 14.0 126.0° 125.0° FIGURE 10. - Station locations, nodule occurrences, and grades in subarea CI. 14.0° MINABLE RESOURCES Gross tonnage estimates for potential minesites can be very misleading. A series of practical considerations sig- nificantly lower the resource quantity that will actually be recovered. At any given site in the northeast Pacific there are fault scarps, basalt outcrops, exces- sive slope angles, and other seafloor features that reduce the usable portion of a deposit area to an estimated 75 pet of initial size ( 34 ) . Of the remaining area, the abundance of deposits in pos- sibly one-third of it is insufficient to warrant mining. This means that about half the original area has a minable re- source. Furthermore, not all minable re- source will be recovered because pickup efficiencies of presently envisioned mine 13 TABLE 3. - Estimated minable and recoverable resources, subareas All, Bill, and CI Average abundance dry t/km 2 . . Minable area 1 km 2 . . Minable resource million dry t.. Minable nodules traversed pet. . Pickup efficiency pet. . Mining efficiency 2 pet . . Recoverable resources ^ million dry t.. All 6,200 18,000 111.6 70 85 60 67.0 Bill 3,700 32,300 119.5 70 80 56 66.9 CI 8,200 28,800 236.2 70 90 63 148.8 *50 pet of total minesite area. 2 Minable nodules traversed times pickup efficiency. 3 Minable resource times mining efficiency. systems are expected to be no more than 80 to 90 pet. Pickup efficiency will vary because of dissimilar abundances, and other physical factors. Also, maneu- vering and control limitations mean that only about 70 pet of the minable nodules will be traversed, thus mining efficiency will average about 60 pet. Considering all these factors, approximately 30 pet of the potential resource from a given deposit area will be recovered. This low percentage will probably increase with mining experience. Based on the above analysis, table 3 contains estimates of both minable and recoverable resources for subareas All, Bill, and CI. These estimates serve as a resource base for the proposed mining-transportation-benef iciation sys- tems described in succeeding sections. MINING AND PROCESSING TECHNOLOGY DISCUSSION Major ocean mining consortia are in various stages of designing, building, and testing manganese nodule mining and processing systems. Presently, two mining-lift systems have been tested in both experimental facilities and at sea. The first, a continuous line bucket sys- tem consists of a 10-cm-diameter polypro- pylene line with drag buckets attached at regular intervals. A loop is played overboard and allowed to trail on the ocean floor. Traction devices on either one or two ships provide lateral movement as the loop is towed forward. Buckets remain attached as the rope moves through the friction drives and are emptied. The obvious advantage of this system is its simplicity. However, tests by the CNEXO (French) and Sumitomo consortia in the 1970' s, were not successful, apparently because of tangling and low nodule recov- eries. Development of this system ap- pears to have been terminated. The second system is hydraulic and con- sists of a nodule collector unit attached to a mining ship by a steel pipeline. The pipe serves as both a towing means and a conduit for raising nodules. Lift is provided by either submersible hydrau- lic pumps or high-pressure air injected at a predetermined depth (air lift). Bubbles create upward movement in the pipe column as they rise and expand. One-fifth scale tests of hydraulic units were successfully conducted in 1978 by both the INCO and Deepsea Ventures con- sortia. Approximately 1,300 t of nodules were dredged from two sites in the north- east Pacific. Water depths were approxi- mately 4,500 and 5,000 m. A variety of processing schemes have been proposed for recovering value metals from nodules; the most promising have been tested in small pilot plants. Sig- nificant research has been directed towards development of four processes: (1) the Kennecott (Cuprion) process and 14 (2) the high-temperature sulfuric acid leach, both designed to recover primarily nickel, copper and cobalt; (3) the INCO process; and, (4) Deepsea Ventures pro- cesses, recovering manganese as well as nickel, copper, and cobalt. The Deepsea Ventures (Ocean Mining As- sociates) process is based on reaction of the manganese-iron hydroxide matrix with hydrochloric acid (HC1) to produce solu- ble iron and manganese chlorides, and thereby releasing metal values. Ferric chloride is removed by solvent extraction and oxidized to produce recyclable HC1 and iron oxide. Copper, and then nickel, cobalt, and molybdenum are separated by liquid ion exchange (LIX) from the chlo- ride solution and electrowon in separate chloride circuits. Manganese metal is recovered by either fused salt electroly- sis or reduction with aluminum metal. Alternately, manganese oxide can be re- covered by high-temperature hydrolysis of MnCl 2 . The number and diversity of patents is- sued on the process suggests problems have been experienced (35) . One diffi- culty is the large consumption - of HC1 (makeup requirement about 50 pet) during initial reduction and accompanying pro- duction of chlorine, which is not uti- lized in the remainder of the process. The gas must be marketed as a byproduct, exchanged with a polyvinyl monomer pro- ducer for excess hydrogen chloride, or reconverted to HC1. Although only minor problems occur in metal extraction and electrowinning from chloride solutions, Deepsea Ventures has not developed a satisfactory method to convert the man- ganese oxide intermediate product to a usable end product (f erromanganese) . According to Monhemius (35) , Metallurgie Hoboken-Overpelt , a new member of the consortium through its corporate ties with Union Miniere (Belgium) , recently developed system modifications that may resolve some of these problems. The INCO process is a combination of pyrometallurgical and hydrometallurgical methods that have been used in the processing of terrestrial ores. Stock- piled ore, containing about 30 pet water, is dried and then selectively reduced at 1,400° C. Two phases are produced; a manganese-rich slag and an iron- nickel-copper-cobalt alloy. The alloy is oxidized to remove most iron and manga- nese; and next converted to a sulfide matte by the addition of pyrite, gypsum, and coke. It is then reoxidized (blown) to remove residual iron. Slags are re- turned to reduction and smelting fur- naces. The remaining matte is ground and pressure leached with sulfuric acid; metals are recovered by solvent extrac- tion, electrowinning, and precipitation. Ferromanganese, with acceptable manganese to phosphorous ratios, is produced from the manganese slag by reduction smelting with lime at 1,600° C. INCO's method has some distinct advan- tages. First, nearly all manganese and much of the iron is removed in a molten slag, which can be used to produce ferro- manganese. Second, other valuable com- modities are concentrated into an alloy phase, which weighs less than 10 pet of the original feed (35) . Treatment of this smaller quantity of material is relatively cheap compared with other processes and most of the commercial technology already exists (8). The prin- cipal disadvantage of this process is the high energy requirements for drying and smelting. The high-temperature sulfuric acid leach process, which has been investi- gated in European laboratories (_7) , is an adaptation of the technique used to re- cover nickel from laterites at Moa Bay, Cuba. Raw, wet nodules are ground, mixed with concentrated sulfuric acid, and heated to about 250° C. At this tempera- ture, most of the copper, nickel, and co- balt are dissolved, while little iron or manganese enter solution; thereby, sub- sequent purification steps are simpli- fied, and acid consumption is minimized. Value metals are recovered from the cooled leach effluent by essentially the same sequence of steps used in the hydro- metallurgical portion of the smelting process. Because of high temperatures and acid- ities in the leaching step, care must be 15 taken in selecting materials for con- struction. Another potential drawback to this process involves disposal of spent sulfate. Disposal of sulfate as gypsum, with recycling of ammonia within the pro- cess, generates large amounts of waste. An alternate approach involves the puri- fication of ammonium sulfate for sale as fertilizer. Less information has been published on this process than with the Deepsea Ventures, INCO, and Kennecott processes. In the Kennecott (Cuprion) process, wet ore is ground, and then slurried in a mixture of seawater and recycled process liquor which contains dissolved copper and ammoniacal ammonium carbonate. The slurry passes through a series of reac- tion vessels into which carbon monoxide is introduced. Cuprous ions are produced which subsequently catalyze the reduction of the manganese-iron oxide matrix (1) . Value metals dissolve and are separated from the reduced residues by countercur- rent washing. Ammonia and carbon dioxide are recovered and recycled by steam stripping residues. Electrowon copper and nickel are produced after having been extracted from the leach liquor using a mixture of LIX 64N 1 * in kerosine. Cobalt is recovered from the remaining solution (raffinite) by precipitation with H2S and subsequent reduction. Electrowinning is employed to recover nickel and copper as high-grade cathodes. Several favorable factors characterize this process: nearly all process steps are carried out at ambient temperature and pressure; energy consumption is rela- tively low; most reagents are relatively inexpensive or recyclable; and there is only limited use of corrosive and highly toxic reagents. Apparently, these char- acteristics were successfully demon- strated in a 350-kg/d pilot plant, which was operated for 43 days at Kennecott' s Ledgemont Laboratory ( 1_) . ^Reference to specific products does not imply endorsement by the Bureau of Mines. While both the Cuprion and high- temperature sulfuric acid leach processes previously described are designed to recover primarily copper , nickel , and cobalt, it is possible that other metals such as molybdenum, would also be recov- ered. In this case, additional metals separation and purification steps would be required, but the process would not be greatly changed. Also, manganese could be recovered by a combination of physical and chemical steps. However, if manga- nese were to be recovered, materials handling and process design would be sig- nificantly altered and energy require- ments would increase considerably. OPERATIONAL INTEGRATION OF A PROPOSED RECOVERY SYSTEM Because description and costing of a nodule mine-transport-benef iciation sys- tem is very complex, only one system is described and applied to the three subareas, All, Bill, and CI (hereafter called ventures 1, 2, and 3). The system is modified for each subarea to reflect differences in transport distances, water depths, and nodule abundances. However, except to lower the projected mining rate for venture 2 which has comparatively low nodule abundance, no attempt has been made to optimize the many factors bearing on economic viability. Mining consortia and regulatory agencies involved would determine exact areas to be mined, their sizes, locations of facilities, methods employed, and production rates. The proposed system is, in part, hypo- thetical because there has been no com- mercial production experience, yet the descriptions and costs are drawn from many knowledgeable sources, both pub- lished and unpublished. Because both methods were successfully tested, the system plan includes hydraulic mining- lifting and Cuprion processing. Other benef iciation methods might be as feasi- ble, but little information is avail- able concerning process details and test results. Slurry transfer and transport of nodule ore is considered most likely, 16 because nodules are amenable to the meth- od, and much slurry handling experience exists in other areas of the minerals industry. Mining is scheduled on a 300-d/yr basis with an estimated annual production of 3.0 million dry t for ventures 1 and 3, and 2.4 million dry t for venture 2. Two ships recovering 5,000 dry t/d each (4,000 t for venture 2) would sweep the minesite in predetermined paths. Hy- draulic collectors, towed at an average velocity of 1.0 m/s (2 kn) , would dis- lodge, sort, and channel nodules to a large-diameter pipe, which would connect the collector to the ship (fig. 11). Submersible hydraulic pumps would main- tain an upward flow of water, nodules, and nodule fragments. Check-dump valves would protect the pumps , and prevent clogging in case of power failure. Aboard the mine ship, nodules would be screened, conveyed to storage holds, and dewatered by decantation. The ore would not be upgraded because chemical and physical characteristics of nodules do not lend themselves to traditional con- centration methods. Every few days, nodule ore would be reslurried and pumped through a flexible pipeline to large- capacity bulk transports where it would be again dewatered and then transported to an unloading terminal on the west coast of the United States. At the unloading facility, ore would be reslurried and pumped to nodule storage ponds on shore. From there the slurry would be transferred inland, by slurry pipeline, to storage ponds at the pro- cessing plant. The processing plant would operate 24 h/d, 330 d/yr at 100 pet capacity. Nickel and copper would be recovered as high-purity cathodes, and cobalt would be chemically precipitated, purified, and recovered as metallic or oxide powder. An add-on option is included to recover manganese by treating about one-half the Cuprion tailing and upgrading it to a f erromanganese product. Tailings from both Cuprion and ferro- manganese plants would be treated to ad- just pH and then pumped to tailings ponds of conventional design. Slag from the f erromanganese plant would be stored in an adjacent area. MINING Nodule mining in each deep ocean site would be conducted 300 d/yr at a rate of 8,000 dry t/d (11,430 t/d as mined, wet) for venture 2 and 10,000 dry t/d (14,300 t/d as mined, wet) for the other two ventures. Operations would be con- ducted around the clock, but actual pro- duction time is estimated at 20 h/d. Hourly rates would therefore be 400 and 500 dry t, respectively. Major equipment modifications, ship repairs, and drydock would likely take place during July through August, when from three to four major storms normally occur. A high- speed boat, operating from a major port, would transport personnel and supplies to the minesite. Ship-to-ship transfer would be by helicopter. Prior to actual mining, extensive char- acterization of a portion of the previ- ously explored minesite would be com- pleted. A large-scale bathymetric map would be constructed; locations of bottom obstructions, including cliffs, faults, and rock outcrops would be clearly marked. Sediment bearing strengths and other factors of local marine environment would be analyzed in detail. Based on this additional resource information, a mining plan would be drawn up at least a year in advance of each year of mining. The survey program would continue throughout the life of the operation, re- quiring the use of a survey vessel most of the time. The mining system would be composed of two mine ships, each capable of conduct- ing operations independent of the other. Each ship would be in the 100,000-dwt class; approximately 250 m long, with a 45-m beam and a draft of about 12.2 m. About 30,000 shaft hp would be required for propulsion, mining, ore transfer, and 17 NODULE TRANSPORT MINE SHIP Screening and separating equipment Support platform and derrick Bow thrusters KEY A Pipe joint B Lift pipe (steel alloy) C Vortex suppressor(s) D Check-dump valve E Hose-pipe connector F Power and communications cable G Flexible hose COLLECTOR FIGURE 11. - Hydraulic deep ocean mining system. Modified from Flipse (15-16) and Grote (24). 18 crew accommodations (_5_) . The large ship size is in part dictated by the need to have several days storage capacity, to significantly reduce the number of transports. A ship of conventional hull form, simi- lar to an ore carrier, would be used but would require many changes and additions to be able to serve as a mine ship. The most conspicuous addition, the pipe han- dling system, would consist of a derrick, support platform, pipe racks, and combi- nation crane-elevator used to move pipe from storage. The derrick and platform would be built over a rectangular hole (moon pool) cut through the hull of the ship. The moon pool would be amidships where there is the least pitch and roll. Assuming pipe support at the main strength deck, a 20- by 20-m moon pool should be sufficient to keep the pipe from striking the walls during a 30° roll ( 17 ) , the design maximum. The sup- port platform-work floor, capable of holding an estimated 5,000 t, would be mounted on a two-axle gimbal, which al- lows the trailing pipestring to remain near vertical as the ship pitches and rolls. A hydraulic support system would compensate for heave. Other onboard equipment would consist of separator and settling tanks, screens, and conveyors to separate nodules from sediments and other waste. Slurry pumps and permanent piping would be installed to route nodules to storage and sediments overboard; possibly through a flexible pipe extending to a maximum depth of 200 m (16) . Special care would be taken to retain nodule "fines," which carry most metal values. Additional tanks and pumps would be used to reslurry the ore and transfer it to bulk transport ves- sels. Total mine ship storage would be 70,000 wet t (49,000 dry t) , equivalent to the capacity of the ore transports plus 10 pet margin. To tow the collector at required low velocities and to accurately maneuver, the mine ship would have to be fitted with a sophisticated computer-controlled propulsion system. This would include bow and stern thrusters as well as a sonar locator system. The locator system would consist of hull-mounted transducers that generate sound pulses. The pulses would be picked up and returned by a set of transponders positioned on the sea- floor. The returned signals would be analyzed by a computer, which would steer the ship within a few feet of the prescribed course ( 50 ) and around obstacles. A crew (mining and operational) of about 72 (17) would require living and recreational facilities. Because of ex- tended tours of duty, these facilities might include amenities such as individ- ual quarters, a gymnasium, theater, and gameroom. Two crews for each ship would be required to permit a 30-day-on, 30- day-off work cycle typical of the off- shore oil industry. Most of the pipeline would be similar in composition to oil-drill pipe. Inside diameter would be constant at about 40 cm, while wall thickness would vary from 1.5 to 8.5 cm. Pipe section lengths from 12 to 13 m are anticipated. Sec- tions would be joined by clamp or thread- ed (tool) joints. An electrical cable would be attached to the pipe to supply power to the submersible pumps and to the nodule collector. Depending on opera- tional experience, fairings or other types of devices might be attached to reduce drag and minimize vibration of the string (24) . Near the lower end of the pipestring, a strong, flexible hose would connect the collector and steel pipe. This would allow for undulations in topography. Total length of the pipe string would be about 15 pet greater than the depth of the area being mined. Residual sediment and biogenic debris, water, and nodules would be moved up the pipeline using a multistage hydraulic pump system. Three pumps would be mounted along the string: one within a few hundred feet of the surface and the other two about one-third and two-thirds of the water depth. An "off-line" design 19 would be preferable because it would uti- lize a motor-pump design that eliminates the need for solids to pass through the impellers. Consequently, there would be less nodule-caused abrasion, pump wear, or chance of damage in case of power failure (17, 44). until the proper pipe string length had been achieved. Assuming 15 min per sec- tion, 4 to 5 days would be required to complete the job. The final pipe section would be connected to the separator and ore handling equipment , and mining would proceed as planned. The last major component of the mining system would be a skid-mounted collector having the simplest design possible until mining experience dictates otherwise. Front-mounted tines, cutter bar, or simi- lar devices would dislodge nodules en- countered by the collector and reject oversize material. Electric or hydraulic motor-powered conveyors would move ad- mitted nodules , nodule fragments , and sediment through a series of screens to the hose or dredge pipe opening where hydraulic flow would move them up the pipeline. During the screening process most of the sediment would be removed. Production demands would require a large collector, as much as 20 m in width, depending on average deposit abun- dance. The device would be strongly built to withstand inevitable collisions with undetected obstacles, and gross weights would probably range from 10 to 30 t. Actual mining would begin by preparing the collector and attaching it to the flexible hose. Depending on size, the unit would be either lowered over the side and keelhauled beneath the moon pool or lowered directly through it. Steel pipe with attached fairings and power cable would be added section by section The collector would be towed at a velocity of approximately 1 m/s (2 kn) , resulting in a pipeline trailing angle of about 7° from vertical ( 15 ) . The veloc- ity could not be increased appreciably because a 50-pct increase in speed nearly doubles the power requirements and flat- tens the trailing angle to approximately 14° or more. The large trailing angle increases pumping requirements and pipe abrasion. According to Flipse ( 15) , a flow velocity of about 4.9 m/s is suffi- cient to lift nodules through a pipe 7° from vertical. A solids to fluid ratio of about 1:7 (14 vol pet) can be expected ( 17) . Shaw ( 41 ) estimates that service life of a pipeline and collector would be about 12 and 6 months, respectively. Others expect twice this life ( 17 ) . Physical characteristics affecting min- ability of the potential minesites are summarized in table 4. Grade in each subarea is high and the resources appear sufficient to support mining at the specified rates for 20 yr or more. Vari- able water depths require different pipe string lengths but no significant changes in shipboard equipment design. Signifi- cant differences in collector sizes , how- ever, are dictated by the wide range of nodule abundances . In fact , the low nodule abundance of venture 2 subarea TABLE 4. - Deposit characteristics affecting minability, ventures 1, 2, and 3 1— All 2— Bill 3--CI Depth 5,200 6,200 1.30 1.00 0.21 0.05 27.8 67.0 4,800 3,700 1.45 1.24 0.25 0.07 27.2 66.9 4,600 Average metal content, Ni wt pet (dry basis): 8,200 1.33 Cu 1.04 Co 0.26 Mo 0.07 Mn 26.8 Recoverable resource.. 148.8 20 would require a very large dredge to maintain a reasonable, yet smaller pro- duction level than ventures 1 and 3. Increased size and weight of the larger collector would require a stronger and, very likely, heavier pipe resulting in increased loads on the gimballed support platform. Mine ship fuel consumption would increase, but pumping requirements would not, because the mining rate would not increase. Design of collectors for each minesite would vary in some aspects, depending on sediment type and bearing strengths, and minesite topography. How- ever, no significant cost differences are anticipated based on design. Table 5 summarizes mining parameters for the three ventures. Assuming 20-h days, annual production at about 95 pet capacity would be 3.0 million dry t for ventures 1 and 3, and 2.4 million dry t for venture 2. TABLE 5. - Mining parameters for ventures 1, 2, and 3 Dredge width m. . Nodules traversed 1 . .dry t/h.. Dredge efficiency pet.. Nodules rec o v erd. . . .dry t/h. . 1 14 312 85 265 19 253 80 203 10 295 90 266 1 Based on collector velocity of 1 m/s. TRANSPORTATION Relatively large 70,000-dwt bulk ore carriers or similar vessels are best suited to transport nodule ore because an economy of scale exists, and because they are probably the largest ships that can navigate most west coast port waters (^0. 5 A modified hull design, intermedi- ate between conventional and shallow draft types, could carry the relatively ^Domestic ocean mining legislation (Public Law 96-283, Deep Seabed Hard Min- eral Resources Act) requires processing in the United States. Alternate sites would be on the island of Hawaii and along the gulf coast. dense ore, while maintaining a reasonably shallow draft. Extra steel would be used to compartmentalize holds and give added strength ( 4_) . Nonstructural modifications required for nodule transport vessels include piping; pumps and conveyors to receive, distribute, decant, and dewater nodule slurry; a boom to pick up and lift slurry and fuel lines aboard; and dedicated stowage tanks and piping for mine-ship fuel. Table 6 lists dimensions and other characteristics of the proposed nodule transports. For economy, the vessels are assumed to be foreign built (European) and diesel powered. A relatively small crew of 32 would be adequate, because the ships would not be equipped to reslurry and unload their cargo. Capital costs would be less for one set of slurrying equipment at dockside, as opposed to mul- tiple installations on transports. Also, onshore maintenance would be easier and cheaper. Shipboard slurrying equipment could be added later if, for instance, ocean dumping of tailings were to be initiated. At 90 pet of the nominal capacity of 70,000 long tons, each vessel would carry 64,000 t of dewatered slurry (4^) containing the equivalent of 44,800 t of dry nodule material. TABLE 6. - Characteristics of proposed 70,000-dwt nodule transports (4_) Dimensions, m: Length 226.0 Beam 36.9 Depth 18.6 Draft m.. 12.5 Horsepower 18 ,700 Speed, kn: Laden 14.5 Unladen (40 pet ballast) 16.7 Fuel consumption, bbl/d: At sea 490 In port 49 Lubricating oil bbl/d.. 2.8 21 Transport operations between the mine- site and west coast would coincide with the 300-d mine ship schedule. A typi- cal transport cycle would consist of the following four phases: • Ship-to-ship transfer of slurry, fuel, and supplies. • Transportation of slurry to an un- loading facility. • Unloading slurry, loading fuel and supplies. • Returning to mines ite under ballast. Slurry transfer would be initiated by passing a towline and large-diameter, flexible pipe to the carrier. Once at- tached, the lines would be played out approximately 200 m (15) . The mine ship would then tow the transport during pump- ing operations. This would insure a constant, safe distance and prevent ex- cessive strain on the slurry line. Normally ship-to-ship slurry pumping would be conducted simultaneously with transfer of supplies and fuel. Most sup- plies would be transferred by helicopter, but heavy equipment would require use of a mine-ship crane. Fuel would be pumped through a flexible line stored on the mine ship. On the mine ship, high-pressure water jets would be sequentially directed into holds containing dewatered nodule ore. Centrifugal pumps would feed the result- ing slurry through piping to a manifold on the main deck level; the slurry would then be routed to the main transfer line. The pumped slurry would consist of a max- imum of 40 pet solids and have a specific gravity of 1.6 or less (_5, 8). Rated capacity of individual pumps would be 500 t of solids per hour. Complete transfer would probably take 30 to 32 h, including 4 h for passing lines, connect- ing, playing out, and disconnecting (4). Based on an average speed of 15.6 kn, steaming time to and from port would take an estimated 14.2, 11.5, and 9.8 days, respectively, for venture 1, 2, and 3 transports. Minor variations would be expected because of weather and sea conditions. Unloading at an onshore slurry termi- nal, with a design pumping capacity greater than that of the mine ship, would require less actual pumping time than ship-to-ship transfer. However, as slurry carriers approach the facility it might be necessary to slow or wait for high tide to traverse access channels. Considering this and other delays in loading supplies and fuel, total in-port time would be 2 to 3 days. Table 7 gives a summary of pertinent ore transportation information. The num- ber of vessels required to meet the an- nual production goals of 2.4 and 3.0 mil- lion dry t, would depend on the number of trips each vessel would make per year and the capacity of each ship (44,800 dry t). In turn, the number of annual trips is the quotient of 300 operating days divid- ed by the estimated round trip (cycle) time. Cycle time is simply the sum of loading, unloading, and steaming times. TABLE 7. - Summary of transportation data, ventures 1, 2, and 3 Distance to port ^nmi. . Transport cycle t ime d . . Annual trips per vessel Vessels required 1 2,660 18 17 4 2,160 16 19 3 1,840 13 23 3 ^nmi is equal to 1.85 km. SLURRY TERMINAL An onshore slurry terminal, similar to that described by Dames and Moore (8) , is illustrated in figure 12. The facility, as designed, would occupy about the smallest practical land surface area and would receive, store, and pump nodule slurry to the process plant; it would not receive or load tailings for disposal at sea. A significantly larger installa- tion would be required for that purpose, 22 Nodule transport Slurry line to process plant 50 _i_ -L 100 FIGURE 12. Moore (8). Scale, m Plan view of slurry receiving terminal and pumping station. Modified from Dames & because of the large volume of waste pro- duced by processing. Major components of the unloading facility would include a dock; mooring dolphins; 20-ton-capacity cranes to service transport vessel stor- age holds; a portable slurry pump for each hold; an access trestle; water and slurry piping, water tanks, raw nodule storage ponds; a pump building; and stor- age, shop, and office buildings. Transport vessels from ventures 1 and 3 would arrive once every 4 to 4.5 days; vessels from venture 2 would arrive about once every 5 days. If loaded drafts were near channel depth limits, vessels would wait, then proceed to the terminal at high tide. Upon docking, hatch covers would be opened and, using dockside cranes, the portable slurry units would be suspended in each hold. High-pressure 23 waterlines, fed by onsite storage tanks and pumps, would be attached to slurrying nozzles. Outlets on each unit would be connected to a collector system leading to the slurry pump building and storage ponds. During unloading operations units would be lowered into the dewatered ore as special sinking jets slurried material directly below the units. Side-mounted jets would undercut and slurry surround- ing ore as a hydraulic driving mechanism slowly rotated the unit. Most material would be routed to the storage ponds. However, a portion would probably be sent directly to the pump building, and then through a pipeline to the process- ing plant. Slurry storage capacity on the 10-ha site would be approximately 110,000 m 3 , sufficient for two to three transport loads. Water requirements for reslurrying the ore would be substantial; however, most would be recycled from the process plant. Makeup water would be pumped directly from the harbor with no requirement for purification or other treatment. Supplies for the mine ships and indi- vidual transports would be delivered to the dock by truck and lifted aboard by crane. A freshwater line would supply water when required. Diesel bunkering could be accomplished by barge, making fuel storage and pumping facilities un- necessary. Tanks and storage, however, are included in facility costs in the "Capital and Operating Costs" section. The processing plant would probably be a significant distance inland because of limited availability of suitable land near developed ports. Two pipes would be laid side by side the entire distance. A larger pipe would carry nodule slurry to the plant, while a smaller one would re- turn decanted water to the terminal. As- suming a maximum distance of 40 km and relatively flat terrain, a bank of cen- trifugal pumps with two booster stations would supply sufficient pumping capacity. Storage ponds at the terminal would allow minor pipeline repairs during the oper- ating year; major replacements could be made in the off-season. The slurry line would be sized to transport nodules at essentially the same rate as received: approximately 425 and 340 t/h dry solids for the 3.0 and 2.4 million t/yr opera- tions, respectively. A 25-cm-ID pipe would be required for the former opera- tions and a 20-cm-ID pipe for the latter. Slurry densities would be somewhat lower than for other transport operations, around 30 pet solids, to allow for easy resuspension in the event of pump fail- ure. If desirable, nodule ore could be ground at the terminal; this would reduce flow velocity and pipe diameter require- ments. Operational downtime would be about 10 pet. Land usage would be about 1.0 ha for the two pumping stations and 58 ha for the pipeline. Power would be purchased from a local supplier. CUPRION PROCESSING The 3 million dry t processing plant would require approximately 90 ha of land. Requirements for the smaller 2.4 million dry t plant would not be much less. Both Cuprion plants would use sig- nificant amounts of water, which is as- sumed to be available from nearby sources. Maximum reuse of water would be practiced in the plant, and generation of electricity in the plant's utilities sec- tion would meet most power requirements. Coal would be the cheapest fuel and source of carbon monoxide reducing gas. A well-developed local infrastructure is assumed to exist nearby to support plant operations, including a pool of skilled labor, and other community services such as schools, hospitals, and fire protec- tion. Provision is made for construction of 8.0 km of paved highway and rail spur line. An assumption is made that waste will be stored a significant distance from processing facilities because of continu- ing environmental concern over waste disposal. Costs are based on a plant- to-storage distance of 100 km. Approxi- mately 480 and 600 ha of land would be needed at the disposal site for a 20-yr operation for the smaller and and larger plants, respectively. 24 During normal operations, slurried ore would be received from the pipeline and be routed to storage ponds to await processing. Ponds, 5 m deep covering 12 ha, would be sufficient for 3.0 to 3.5 months' storage, a requirement dic- tated by the inability to mine nod- ules all year round. The equivalent of 9,090 dry t/d for ventures 1 and 3 or 7,270 dry t/d for venture 2 would be pro- cessed 330 d/y. Slurry would be re- claimed from storage and transferred to a surge tank in the ore preparation sec- tion, mixed with recycled ammonia-rich liquor from the reduction and leach-wash sections (fig. 13), and then fed to hy- drocyclones for classification. Under- flow would be fed to ball mills where particles would be reduced in size and sent back to the surge tank. Minus 100- mesh overflow, containing less than 5 pet solids ( 35 ) , would report directly to the reduction section. Ninety-eight percent of the manganese oxide matrix would be reduced in a cas- cade series of reaction vessels by the action of carbon monoxide catalyzed by internally generated cuprous ions. The net effect would be to reduce man- ganese to the divalent state and produce manganese carbonate; as a result, metal- lic commodities to be recovered would be liberated. The required concentration of cuprous ions would be maintained by con- tinually sparging a carbon monoxide-rich gas into reaction vessels. Synthesis gas generated from gasified coal contains a significant amount of H 2 and acid gases (CO2, H2S) , which would be separated from carbon monoxide prior to its use in reduction (7). Dilute slurry would be passed to a clari- fier, whose overflow would be treated with ammonia and carbon dioxide, cooled, and returned to leach reactors. Thick- ened underflow would be combined with second stage wash liquor and oxidized with air to convert cuprous copper to the cupric state to facilitate metal extrac- tion by liquid ion exchange (LIX) . Also, cobalt and iron would be oxidized; iron would precipite as an insoluble hydroxide (8). Offgases would be vented to ammonia recovery. Oxidized slurry would be pumped to a countercurrent decantation (CCD) system where metals would be further solubi- lized, and where primary liquid-solid separation and washing would be made. Nickel and copper recovery would be greater than 90 pet (1_) , and cobalt re- covery about 65 pet. Manganese-rich tailings and process gas would be sent to ammonia recovery, and pregnant liquor to the LIX section for metal separation. There, nickel and cop- per would be coextracted, then selec- tively stripped (Kennecott researchers determined that coextraction of the two metals greatly simplified the process). Extraction would be carried out at 40° C in a series of three mixer-settler tanks using 40 pet LIX 64N in kerosine. Recov- ery of nickel and copper would be greater than 99.9 pet, but about 5 pet of the ammonia would also be extracted (2^) and, if not removed, would accumulate in the nickel electrolyte. Two wash sections would reduce it to an acceptable concen- tration and the recovered ammonia would be recycled to the plant ammonia recovery section. The critical reactions were demon- strated at ambient pressure and 50° C, but a holdup time of about 20 min for each of the five vessels would be re- quired ( 1_) . Autoclaves, maintained at a pressure of about 5 kg/cm 2 and 50° C may be utilized, thereby improving reaction rates and reducing the size of reactor vessels (^35 ) . Exothermic heat of reac- tion would be removed in heat exchangers and excess gas sent to ammonia recovery. A small amount of cobalt would be ex- tracted with nickel and copper and would have to be removed to prevent excess buildup. To accomplish this, hydrogen sulfide would be introduced into a sol- vent purge stream (8). The resulting precipitate would be filtered, washed, and passed to cobalt recovery. Nickel would be selectively stripped from the organic liquor by contact with 25 26 acidic return electrolyte from nickel electrowinning. Composition of the elec- trolyte would be controlled to maintain the required selectivity for nickel; ad- vance electrolyte, reporting to elec- trowinning, would contain approximately 75-g/L nickel at a pH of 3.0 and a nickel-copper ratio of 25,000:1. Strip- ping would take place in three stages of mixer-settlers of conventional design. Organic feed passing to copper strip- ping would contain copper and nickel in a ratio of about 70:1. Both metals would be stripped, in two stages, using a more acidic return electrolyte from copper electrowinning. Nickel content of the electrolyte does not affect copper elec- trowinning if concentrations are below 20 g/L. This would be accomplished by bleeding copper stripping tanks. Bleed solution would be passed through a series of cells, where copper would be electro- won to depletion, and the remaining elec- trolyte passed to vacuum evaporators, where water would be removed and nickel sulfate precipitated. The sulfate would be sent to cobalt recovery and the re- maining, strongly acidic solution re- turned to process, where it would' be uti- lized to redissolve scrap copper (8). Nickel would be electrowon from the ad- vance electrolyte in conventional cells. Cathode bags would be used as blanks for starter sheets, and boric acid and sodium sulfate would be added to regulate pH and conductivity. Starter sheets would be cleaned in sulfuric acid prior to use. Nickel scrap would be recovered by dis- solution in ammonia-rich raffinite and routing to stripping (J3) . Copper would also be recovered using conventional electrowinning technology. Starter sheets would be deposited on ti- tanium blanks in the stripping section and then installed in commercial cells. Most of the spent electrolyte would be recycled to stripping, and the remainder purged of nickel in the manner described above. Full-sized nickel and copper cathodes are to be the final products. Both commodities would be removed from cells , washed , and prepared to market. for shipment im I- Apparently, recovery of cobalt from the nickel-copper poor LIX raffinite has not been fully tested at pilot-plant scale. However, several plausible schemes exist. One method, outlined in the Dames and Moore (8) report is described here. Un- extracted nickel, copper, cobalt, and zinc are precipitated with ammonium hy- drosulfide, produced by sparging hydrogen sulfide into ammonia solution. Precipi- tate and solution are separated in a clarifier; overflow reports to ammonia recovery and underflow is sent to steam stripping for removal of ammonia. Sul fide slurry is mixed with purges from electrowinning, and pressure leached with air to preferentially dissolve and remove cobalt and nickel. Copper and zinc sul- fide precipitates are separated, washed, and sold to smelters as concentrates. Following pH adjustment, the nickel- cobalt sulfate solution passes to a heated autoclave where hydrogen gas is sparged into the vessel, thereby reducing the nickel. Ammonia is added to neutral- ize the sulfuric acid being formed. The process is completed in a series of cy- cles , with care being taken to prevent overreduction resulting in coprecipita- tion of cobalt. Once adequate density is obtained, the nickel powder is removed, washed, dried, and briquet ted for sale. The remaining sulfate solution passes to an evaporator where cobalt and small amounts of nickel and ammonium sulfates are precipitated. Nickel and cobalt salts are redissolved in strong ammonia solution and cobalt is reoxidized with air to the cobaltic state. Cobalt then remains in solution as the stream is acidified; nickel salts are precipitated and recycled to the pH adjustment step. Nickel-free solution is heated and re- duced with hydrogen in an autoclave and enough ammonia is added to neutralize any acid formed. Cobalt metal is removed, washed, dried, and briquetted for sale as cobalt powder. Sulfate purge from cobalt recovery is combined with additional ammonium sulfate from the LIX section, reacted with slaked lime, and stripped of ammonia by intro- duction of steam. Gypsum formed in this process is combined with other solid and liquid wastes and plant runoff. The material is treated as required and pumped to waste impoundment. Gypsum and other wastes may be combined with part or all of the manganese tailing depending on whether manganese is recovered for sale. Manganese carbonate tailings from the CCD wash report to ammonia recovery where they are heated and stripped of ammonia and carbon dioxide by countercurrent con- tact with steam. Gases are combined with vapors from other ammonia stripping oper- ations and are cooled and condensed. Scrubbed gases from process vents are also added and the solution recycled to CCD wash. Carbon dioxide makeup is ob- tained from boiler flues and ammonia-free gases from process vents are sent to the main stack. Concentrated ammonia solution, needed for reduction of the raw nodule slurry, is obtained by partially stripping raf- finite from cobalt recovery; the result- ing ammonia-rich vapors are combined with vapors from LIX, reduction, oxidation, and lime boil steps as well as makeup am- monia. The gas is condensed and recycled to nodule reduction. Table 8 lists material, water, and pow- er requirements of a 3 million dry t/yr 27 Cuprion plant. The table also shows wastes produced, but it does not consider additional requirements for ferroman- ganese production. Quantities for a 2.4 million t/yr operation would be ap- proximately 80 pet of these values. MANGANESE RECOVERY 6 A schematic description of an optional onsite facility to further treat part of the manganese carbonate residue (4,250 t/d) is presented in figure 14. Not all tailing is processed, because of presumed market limitations. Plant de- sign, capacity, and fixed capital costs for all three ventures are assumed iden- tical. Carbonate tailing from ammonia recovery would be pumped to the benefici- ation section where it would be washed and centrifuged. Thickened pulp would be mixed with fresh water, soda ash, caustic soda, and sodium silicate prior to flota- tion with saponified fatty acids. As much as 60 pet of the manganese carbonate could be recovered in the froth as a con- centrate assaying 35 to 40 pet manganese. After thickening to about 50 pet solids, the material would be dried and calcined in a rotary kiln to make synthetic man- ganese oxide assaying between 55 and 60 pet manganese. When cooled, calcine would be conveyed to a surge pile or directly to one of °G. D. Gale, metallurgist, Western Field Operations Center, provided design and cost information for recovery of f erromanganese. TABLE 8. - Cuprion ammonia leach plant, major inputs and wastes^ 690 8.5 434 Coal thousand t . . .Water million m 3 . . Power 2 million kW*h. . Materials and supplies 3 thou sand t.. 270 ^Quantities are adjusted from reference 8. 2 Gross requirements, mostly generated internally. 3 All supplies including liquids and gases. Tailings million t . . Liquids million m 3 . . Gases thousand m 3 /min . . Manufacturing thousand t . . 3.3 4.5 10.3 125 28 Cuprion plant tailing Sump and pump Centrifuge Pulp Reagents Agitator Solution to waste Water Reagents Flotation Tailing to waste ^ I ice i Mn concentrate Thickener Kiln Overflow •Dust collector Exhaust J I Sludge Stack to waste Synthetic Mn oxide Cooler Conveyor Fluxes Reductant *^^ ^^~^^». T .*<^-— - — lron ore Stockpile Electric furnace Gases Slag Ferromanganese Dust collector Exhaust I Sludge Stack FIGURE 14. - Generalized flowsheet of a pro= posed ferromanganese plant. three 25-MW, submerged resistance fur- naces. The furnaces would be charged with calcine as well as limestone, sil- ica flux, and iron ore; coke would be added as a reductant. Daily materials consumption at full capacity would be about 1,000 t manganese oxide calcine, 320 t limestone, 90 t silica flux, 90 t iron ore, and 320 t coke. Slag would be skimmed, granulated, and combined with other wastes for disposal. Molten ferro- manganese at approximately 1,400° C would be poured in molds, cooled, and prepared for shipment. Liquid wastes from the washing and con- centration steps would be combined with tailing, treated to adjust pH, and pumped to tailing disposal. Dust and sludge would be recycled to the maximum extent possible, and after suitable treatment, purge streams would be disposed of with other manufacturing wastes. Assuming the existence of an adequate market , the ferromanganese plant would operate 330 d/y, processing about 1.4 million t of tailing and producing ap- proximately 210,000 t of ferromanganese containing 78 pet manganese. Facilities would require approximately 30 ha of land. Power would be purchased. WASTE DISPOSAL Tailings from the Cuprion plant and ferromanganese operation, would be pumped to conventional tailings impoundments which would be as much as 100 km from the process plant. Manufacturing wastes, such as lime boil and stack gas scrub- ber sludge, combustion ash, and sludge derived from water treatment operations would be treated by well-established techniques and combined with tailings for disposal. Tailing impoundments probably would be totally enclosed and lined with clay or other impermeable material. Granu- lated slag could be a secondary source of bank material if a ferromanganese plant were in operation. As active ponds fill, new ones would be constructed alongside. In accordance with county, State, and Federal regulations, inactive ponds would be covered with topsoil or treated in various ways to stabilize them. A de- canting system would remove and recycle water to the process plant. CAPITAL AND OPERATING COSTS DISCUSSION Capital and operating costs are based on equipment, capacities, and operating parameters discussed in the previous section of this report. Costs were ob- tained from many sources, some unpub- lished. Those sources most relied upon include Flipse (17), Brown ( _7_) , and A. D. Little (6), mining and benef iciation 29 costs; Andrews (4-5 ) , transportation and ship costs; Shaw (41) and Tinsley (45) , general costs. Gale (23) provided ferro- manganese plant costs. All figures are in January 1981 dollars. Indexing data were supplied by Flipse (17) and a Bureau of Mines cost index computer program. CAPITAL COSTS Tables 9, 10, and 11 contain capital cost information on mining, transporta- tion, and processing for each of the three potential mining ventures. TABLE 9. - Mine capital costs, ventures 1, 2, and 3, million 1981 dollars 1 — 3.0 million dry t/yr 2 — 2.4 million dry t/yr 3—3.0 million dry t/yr Exploration (6 yr) , Research and development... 2 mine ships pipelines (1 spare) collectors pumping systems sets of onboard equipment, Total fixed capital. . . Startup costs * Working capital (1.5 yr) 2 .. Total mine investment. $19.8 69.3 193.8 55.1 7.3 33.0 76.2 $19.8 69.3 198.0 66.1 10.1 30.6 74.8 $19.8 69.3 189.5 50.1 6.6 26.0 76.2 454.5 21.2 63.0 468.7 21.2 70.0 437.5 21.2 62.7 538.7 559.9 521.4 Startup capital covers extraordinary costs associated with nodule collector test- ing and debugging. 2 Based on operating costs about 20 pet greater than ating costs result from lower startup capacity. Dur 2.25 million t would be mined by ventures 1 and 3, venture 2. normal. The higher unit oper- ing the 1st 1.5 yr an estimated 1.8 million t would be mined by TABLE 10. - Transportation capital costs, ventures 1, 2, and 3, million 1981 dollars 1 — 3.0 million dry t/yr 2 — 2.4 million dry t/yr 3 — 3.0 million dry t/yr Transport vessels * Slurry terminal Slurry pipeline High-speed supply boat Total fixed capital Working capital (1.5 yr) 2 Total transportation investment. $256.1 36.0 18.2 1.4 $192.1 29.5 16.0 1.4 311.7 38.3 238.0 28.7 350.0 266.7 $192.1 36.0 18.2 1.4 247.7 30.5 278.2 *4 transports for venture 1, 3 transports for ventures 2 and 3. 2 Based on operating costs about 20 pet greater than estimated unit costs during full production. The higher costs result from lower startup capacity. During the 1st 1.5 yr approximately 2.25 million t would be transported by ventures 1 and 3, about 1.8 million t would be transported by venture 2. 30 TABLE 11. - Cuprion and f erromanganese plant capital costs, ventures 1, 2, and 3, million 1981 dollars 1 — 3.0 million dry t/yr 2 — 2.4 million dry t/yr 3 — 3.0 million dry t/yr CUPRION PLANT $72.7 387.0 166.2 26.4 18.4 2.4 5.1 $72.7 331.0 142.2 22.6 15.1 2.2 5.1 $72.7 387.0 166.2 26.4 18.4 2.4 5.1 678.2 78.8 590.9 65.7 678.2 78.8 757.0 656.6 757.0 FERROMANGANESE PLANT 74.8 18.0 74.8 18.0 74.8 18.0 92.8 36.5 92.8 35.2 92.8 36.5 Total f erromanganese investment. 129.3 128.0 129.3 886.3 784.6 886.3 ^ased on operating costs averaging During the 1.25-yr startup period, ventu million t of nodules, venture 2 would to f erromanganese would be about 850,000 ture 2. about 1/3 more than full production costs. res 1 and 3 would process an estimated 1.63 handle 1.30 million t. Tailing processed t for ventures 1 and 3, 650,000 t for ven- Included in mine capital are monies for 6 yr of prospecting and detailed mine ex- ploration. Once mining commences, this expense would be treated as an operating cost. Research and development capital of $142 million is split almost evenly between mine and processing ( 17) . Work- ing capital is based on 1.5 yr operating expenses for mine and transportation, and 1.25 yr for processing. Additional capi- tal is allowed for mine startup because of the extraordinary cost of testing and debugging the collector. Mining ships are assumed to be new and constructed in U.S. shipyards. Dredges, pipelines, and onboard slurry handling equipment are also assumed to be built in the United States. Transportation capital includes purchase of European-built transport ves- sels, construction of a slurry terminal and pipeline to the plant, and initial expenses of a high-speed supply boat. Capital for the Cuprion and ferroman- ganese plants does not include expenses for infrastructure, such as a townsite, but does include money for a rail spur line and road to the property; a 100-km slurry line to waste disposal; all land purchases; and installation of turbines for internal generation of power suffi- cient for most Cuprion process require- ment needs. Power for the f erromanganese plant would be purchased. The most significant differences in capital requirements among ventures 1, 2, and 3 involving raining and transportation are increased costs associated with the larger collector for venture 2 and the purchase of an additional transport for venture 1. However, the largest single factor bearing on capital costs is Cupri- on processing capacity difference between venture 2 and the other two operations. Total capital requirement is estimated to be about $100 million less for venture 2. 31 OPERATING COSTS Tables 12, 13, and 14 contain estimates of operating costs for mining, transport- ing, and processing nodule ore. Mainte- nance and repair and labor costs are by far the largest expenses, account- ing for 64 pet of total operating ex- penses. Operation of the terminal-to- plant pipeline, fuel, and fixed vessel expenses compose the bulk of transporta- tion costs. The bulk of Cuprion processing costs are attributable to miscellaneous capital charges, fuel (coal), and utilities and labor. Electrical power is by far the largest single cost item for operation of the ferromanganese plant. TABLE 12. - Mine operating costs, 1 ventures 1, 2, and 3, million 1981 dollars 1 — 3.0 million dry t/yr 2 — 2.4 million dry t/yr 3 — 3.0 million dry t/yr $18.4 2.0 27.2 5.5 8.6 .1 6.0 $18.4 2.0 30.8 5.7 9.6 .2 6.0 $18.4 2.0 26.6 Fuel 5.3 8.0 .1 6.0 67.8 3.7 72.7 4.0 66.4 3.7 71.5 $23.80 76.7 $32.00 70.1 $23.40 1 Based on operation of 2 complete systems. TABLE 13. - Transportation operating costs, ventures 1, 2, and 3, million 1981 dollars 1 — 3.0 million dry t/yr 2 — 2.4 million dry t/yr 3 — 3.0 million dry t/yr Wages, benefits, subsistence, mainte- $15.7 12.8 1.2 .8 $11.8 8.7 .9 .6 $11.8 Fuel 9.0 .9 .6 30.5 1.7 22.0 1.7 22.3 Supply vessel (including moorage).... 1.7 32.2 2.7 5.6 23.7 2.2 4.6 24.0 2.7 5.6 40.5 2.4 30.5 1.7 32.3 2.0 42.9 $14.30 32.2 $13.40 34.3 $11.40 32 TABLE 14. - Cuprion and ferromanganese plant operating cost, ventures 1, 2, and 3, million 1981 dollars 1 — 3.0 million dry t/yr 2 — 2.4 million dry t/yr 3 — 3.0 million dry t/yr CUPRION PLANT $4.0 35.9 16.5 6.9 37.0 2.4 .2 $3.3 29.4 13.5 5.6 31.7 2.1 .2 $4.0 35.9 16.5 6.9 Capital charges (maintenance, mate- 37.0 2.4 .2 102.9 5.1 85.8 4.3 102.9 5.1 108.0 90.1 108.0 FERROMANGANESE PLANT 1 Materials and supplies (including 22.2 48.9 14.4 6.3 22.2 48.9 14.4 6.3 22.2 48.9 14.4 6.3 91.8 4.6 91.8 4.6 91.8 4.6 96.4 96.4 96.4 Total annual cost (both Cost per dry metric ton: 204.4 $36.00 32.10 186.5 $37.50 40.20 204.4 $36.00 32.10 68.10 77.70 68.10 final ferromanganese 1 Includes flotation, calcining, smelting, and handling of the product. Capacity would be 1.4 million t/yr for all ventures. Calculated on basis of total dry metric tons of nodule material processed, not just quantity processed in ferromanganese plant. Operating cost differences among the three ventures somewhat parallel differ- ences in investment costs. The larger, heavier collector is primarily responsi- ble for high costs of venture 2 mining, while running an extra transport vessel over longer distances makes transporta- tion of venture 1 ore most costly. Econ- omy of scale for Cuprion processing results in slightly cheaper processing of nodules for ventures 1 and 3. COST SUMMARY Capital and operating costs discussed in previous sections are summarized in tables 15 and 16. Initial investments are large, ranging from about $1.5 to nearly $1.7 billion for a three-metal nickel, copper, and cobalt operation. A plant to process approximately 1.4 mil- lion t tails annually to produce ferro- manganese would require about $130 mil- lion additional capital. Estimates of operating costs are from $71 to $83 per dry metric ton without manganese recovery and from $103 to $123 per dry metric ton with production of ferromanganese . Probably no effective means exist to significantly reduce capital costs for 33 TABLE 15. - Capital cost summary, ventures 1, 2, and 3, million 1981 dollars 1 2 3 $538.7 350.0 757.0 $559.9 266.7 656.6 $521.4 278.2 757.0 Total 1,645.7 129.3 1,483.2 128.0 1,556.6 129.3 1,775.0 1,611.2 1,685.9 * Capacity, and consequently investment, would remain con- stant for the ferromanganese plants except for slightly less working capital for venture 2; a result of capacity. lower startup TABLE 16. - Operating cost summary, ventures 1, 2, and 3, 1981 dollars per dry metric ton 1 2 3 $23.80 14.30 36.00 $32.00 13.40 37.50 $23.40 11.40 36.00 Total 74.10 32.10 82.90 40.20 70.80 32.10 106.20 123.10 102.90 mine, transportation, or benef iciation systems as conceived and described. How- ever, operating costs, particularly mine operating costs, might decrease as expe- rience is gained. Other mine systems such as a continuous line bucket, could possibly cost less to build and operate, but technical feasibility has yet to be demonstrated. Scaling down to 1 million dry t/yr, for example, would reduce capi- tal, but increase unit operating costs. A reduction in transportation costs could be realized for ventures 1 and 2 by placing the processing plant nearer the minesite, possibly on the island of Hawaii. The number of transports and distances traveled would be reduced but increased energy and land costs could possibly offset savings. A savings of plant capital could be accomplished by purchasing power for operations instead of installing genera- tors or by using oil-burning rather than coal-burning equipment. Both actions, however, would probably result in sig- nificant increases in operating costs. FINANCIAL ANALYSIS 7 Financial analyses were carried out us- ing the Bureau of Mines MINSIM4 computer program ( 47 ) . This program calculates either the discounted cash flow rate of return (DCFROR) or determines a product value requisite to achieve a given 7 B. B. Gosling, physical scientist, Western Field Operations Center ran the computer program and provided expert advice. DCFROR. Both analyses were conducted for ventures 1, 2, and 3, with and without additional investment for a ferromanga- nese plant. The target DCFROR used for the metal value determination option was 15 pet, an amount considered minimally attractive to any potential mine opera- tor. Considering the high technical and political risks, a DCFROR of twice this amount (30 pet) would be more in line for a deep ocean mining venture. 34 Several assumptions were made in the analyses which have a material impact on results. First, financing is assumed to be 100 pet equity capital. Therefore, there are no finance charges such as cap- italized interest during construction or interest expense during the subsequent operational period, when loans are nor- mally amortized. Because of the high degree of uncer- tainty in predicting reasonable values 10 to 15 yr hence, no escalation factors for costs or metal prices have been applied. The assumption is that average costs and revenues will escalate at the same rate as inflation. Included in the analyses are allowances for State and Federal in- come taxes, property taxes, and a 0.75- pct excise tax on gross value required by the Deep Seabed Hard Mineral Resources Act. Depletion allowances of 15 pet for copper and 22 pet for nickel, cobalt, and f erromanganese are also included. A relatively aggressive project devel- opment schedule for all three ventures is depicted in figure 15 (see reference 30 for detailed discussion of investment timing). Research and development, pros- pecting, and exploration costs before year 1 are previously written off and not included in the financial analyses. Because of the requirement for extraordinary physical detail, minesite exploration would begin immediately and would continue through year 29, except for years 7 through 9 when the explora- tion ship and crew would participate in full-scale mining tests. Plant construc- tion would occur in years 5 through 8 and ship construction would take place in years 6 through 9. Modifications devel- oped during full-scale testing of the first ship would be incorporated in the second ship. Partial production would begin in year 10, and full production would be scheduled for years 12 through 30. For financial purposes, exploration cost is considered a capital cost prior to startup and an operating cost thereafter. Table 17 shows total revenues derived from each venture based on the following prices, in January 1981 dollars: Nickel: Per kilogram $7.72 Per pound 3.50 Copper: Per kilogram 1 .97 Per pound .89 Cobalt: Per kilogram 15.44 Per pound 7 . 00 Ferromanganese (78 pet Mn) : Per metric ton 502.00 Per long ton 510.00 i i i Research and development ' 1 Plant and ship construction Startup Detailed ■ ■ Full production exploration J— L i i i i i •H i i i i I i I i i i 10 20 15 YEARS FIGURE 15. - Project development schedule. 25 30 35 TABLE 17. - Total commodity revenues, ventures 1, 2, and 3, million January 1981 dollars Nickel Copper Cobalt 3-metal total Ferromanganese (78 pet Mn) 4-metal total 1 $5,309 1,042 1,212 7,563 2,052 9,615 $4,737 1,034 1,154 6,925 1,606 8,531 $5,432 1,084 1,500 8,016 1,978 9,994 The January 1981 cobalt price was consid- ered artificially high; therefore, it was set at twice the nickel price — the ap- proximate historical (1957-76) ratio be- tween the prices. Nickel, by far the most important com- modity, would produce 54 to 56 pet of the revenue for four-metal operations and 68 to 70 pet for three-metal plants. If, despite the significant increase in sup- ply, cobalt prices were to remain high, cobalt would rival nickel as the major revenue producer. Discounted cash flow rate of return forecasts by the Bureau's MINSIM4 program are shown in table 18. All results are based on descriptions, costs, and sched- uling contained in this and previous sec- tions. Projected rates of return are very low. Venture 3, three-metal opera- tion, is potentially the the most profit- able, followed by venture 3, four-metal operation. Interestingly enough, inclu- sion of a ferromanganese plant decreases the apparent profitability of all three ventures. TABLE 18. - Projected rates of return, ventures 1, 2, and 3, percent Venture 3-metal process 4-metal process 1 4.1 5.0 6.0 3.5 2 3 2.7 5.2 Additional MINSIM4 runs were completed for each venture to determine revenue increases required to produce a DCFROR of 15 pet. In general, a 60- to 80-pct increase in total revenue would be re- quired to achieve this modest return on capital for three- and four-metal opera- tions. It is doubtful that such a real gain in metal prices will occur in the near future. PRODUCTION AND SUPPLY In all likelihood, no significant pro- duction of manganese nodules will occur in the foreseeable future. Economic, political, and, to a lesser extent, tech- nical factors combine to exert a large negative influence. Poor economics, a situation illustrated by the financial analyses in the previous section, is largely the result of depressed metal markets and high energy, labor, and mate- rial costs. Political uncertainty continues because the longstanding questions of rights and ownership of deep sea mineral resources continue unresolved despite passage of the Law of the Sea (LOS) Treaty. A total of 47 countries, including the United States, United Kingdom, Federal Republic of Germany, and Japan, did not sign the treaty even though certain ■'grandfather'* rights were accorded existing ocean min- ing consortia. The principal objection by industrialized nations is their lack of meaningful participation in future plan- ning and regulatory processes. Specifi- cally, resource development, production quotas, technology transfer, licensing, and taxation would be virtually con- trolled by developing countries. U.S. legislation (Public Law 96-283) , estab- lishing a domestic regulatory regime for mining deep ocean minerals , is presently being used as a basis for negotiations 36 between nonsignatories. The intent is to establish a series of reciprocat- ing states agreements through which min- ing could take place outside the LOS Treaty. The major technological problem is whether full mine production can be reached and sustained for the life of the project. Collector effectiveness and re- liability are probably the biggest un- knowns. Certain aspects of ore handling and processing will require additional research and development, but appear to be well within current technological capabilities. If, in spite of the aforementioned problems, development does occur, then the U.S. supply position of cer- tain strategic metals would improve materially. Information in table 19 illustrates this point. U.S. consumption of nickel, copper, cobalt, and manganese in 1978 is listed, as well as projected consumption in years 1990 and 2000. The significant 1978 reliance on imports of nickel, cobalt, and manganese is also indicated. This reliance is expected to continue at a high level. Inspection of annual production figures from proposed ventures 1, 2, and 3 show that just one operation would produce from 12 to 13 pet of the projected nickel requirements, 31 to Al pet of cobalt needs, and 10 pet of the manganese requirements in 1990, and somewhat less of projected needs in year 2000. Production from all three TABLE 19. - Comparison of U.S. consumption 1 of nickel, copper, cobalt, and manganese with potential production from ventures 1, 2, and 3 Ni Cu Co Mn Consumption, thousand t: Actual , 1978 163.7 272.2 399.2 80 1,879 2,500 3,200 20 8.8 12.5 15.9 95 1,236 Projected, 1990 1,615 Projected, 2000 .- 1,814 97 Potential annual production, 2 thousand t: 35.9 32.0 36.7 27.6 27.4 28.7 4.1 3.9 5.1 163.8 163.8 163.8 104.6 83.7 13.1 491.4 Amount of projected consumption supplied, pet: 1990: 13 12 13 1 1 1 33 31 41 10 10 10 38 3 105 30 2000: 9 8 9 <1 <1 <1 26 24 32 9 9 9 26 <3 82 27 ^Consumption figures do not include utilization of recycled metals, primary production. Projected (46) annual growth of primary usage 1978 base is as follows, in percent: Ni , 3.7; Cu, 2.4; Co, 2.5; Mn, 2 Venture production based on the following recoveries, in percent 92; Cu, 92; Co, 65. Production of Mn for each venture would be 163 (210,000 t ferromanganese (78 pet Mn)). only from a 1.4. : Ni, ,800 t Source: References 9, 32, 40, 42, and 46. 37 ventures would probably eliminate need for imported cobalt, and drastically re- duce U.S. reliance on foreign nickel and manganese, while having a very minor ef- fect on the domestic copper industry. SUMMARY Based on analysis of available resource data for study areas in the northeast Pacific Ocean, three subareas appear to contain manganese nodule deposits with the best potential for economic mining. These encompass or are adjacent to the three DOMES Sites and are designated sub- areas All, Bill, and CI. Subarea All (36,000 km 2 ) contains an estimated 67.0 million dry t of recoverable resource, with a grade of 1.30 wt pet nickel, 1.00 wt pet copper, and 0.21 wt pet co- balt. Subarea Bill (64,600 km 2 ) contains an estimated 66.9 million dry t of recov- erable nodules , with an apparent grade of 1.45 wt pet nickel, 1.24 wt pet copper, and 0.25 wt pet cobalt. Subarea CI (57,600 km 2 ) contains an estimated recov- erable resource of 148.8 million dry t of nodules grading 1.33 wt pet nickel, 1.04 wt pet copper, and 0.26 wt pet co- balt. Estimated manganese grade for the three subareas ranges between 26.8 and 27.8 wt pet. Costing of the proposed system to mine, transport, and beneficiate the nodule ore, indicates initial investments and operation costs will be large. For three-metal recovery of nickel, copper, and cobalt, anticipated capital invest- ments range from $1.5 billion to $1.7 billion (January 1981 costs); estimated operating costs are from $71 to $83 per metric ton of ore. If manganese is also recovered in an optional 1.4 million t/yr f erromanganese plant, estimated capital costs would increase nearly $130 million; operating costs would add an additional $32 to $40 per metric ton of nodules mined. It may be difficult to significantly reduce costs of the system as conceived and described. Scaling down capacity, purchasing power for the Cuprion plant rather than installing generators, or switching from coal- to oil-burning equipment would reduce capital require- ments , but would raise unit operating costs. Transportation costs, both capi- tal and operating, would be lower if processing were carried out closer to the minesite possibly on the island of Hawaii. Fewer transport vessels would be needed and distances traveled would be shorter. However, increased land and energy costs could partially offset savings. Operating costs, particularly those associated with mining, could be lowered as experience is gained. Financial analyses of proposed opera- tions predict discounted cash flow rates of return ranging from 2.7 to 6.0 pet. Operations with ferromanganese recovery may be slightly less profitable than those without. At best, these rates of return are only a fifth of the approxi- mately 30-pct return that might be needed to attract venture capital. Presently, it is difficult to envision any manganese nodule operation, based on current tech- nology and economics , that can realize more than a marginally acceptable profit. If mining of nodules does occur in the near future, a significant lessening of U.S. reliance on imported nickel, cobalt, and manganese would be achieved. Just one proposed venture could supply the following percentages of projected U.S. demands for 1990: nickel, 12 to 13; cobalt, 31 to 41; and manganese, 10. Production from all three ventures would drastically reduce dependence on imported nickel and manganese and essentially eliminate the need for foreign cobalt. Detrimental effects on the domestic cop- per industry would be negligible. 38 REFERENCES 1. Agarwal, J. C, H. E. Barner, N. Beecher, D. S. Davies , and R. N. Kust. Kennecott Process for Recovery of Copper, Nickel, Cobalt, and Molybdenum From Ocean Nodules. Min. Eng. , v. 31, 1979, pp. 1704-1707. 2. Agarwal, J. C, N. Beecher, D. S. Davies, G. L. Hubred, V. K. Kakaria, and R. N. Kust. Processing of Ocean Nod- ules: A Technical and Economic Review. J. Met., v. 28, No. 4, 1976, pp. 24-31. 3. American Association of Petroleum Geologists. Geographic Map of the Circum-Pacif ic Region-Northeast Quadrant. Tulsa, OK, 1977. 4. Andrews, B. V. Relative Costs of U.S. and Foreign Nodule Transport Ships (contract 7-13775, B. V. Andrews Trans- portation Consultant). U.S. Dept. of Commerce-NOAA, Office of Marine Miner- als, Rockville, MD, 1978, 70 pp.; NTIS PB 283194. 5. Andrews, B. V. (B. V. Andrews Transportation Consultant) . Private com- munication, 1981; available upon re- quest from C. T. Hillman, BuMines , Spo- kane, WA. 6. Arthur D. Little, Inc. Technolog- ical and Economic Assessment of Manganese Nodule Mining and Processing (Revised) (contract 14-01-0001-2114). U.S. Dept. of the Interior, Office of Minerals Pol- icy and Research Analysis, Washington, DC, 1979, 75 pp. 7. Brown, F. (E.I.C. Corp.). Private communication, 1981; available upon re- quest from C. T. Hillman, BuMines, Spo- kane, WA. 8. Dames & Moore, and E.I.C. Corpora- tion. Description of Manganese Nodule Processing Activities for Environment Studies, Vol. III. Processing Systems Technical Analysis (contract 6-35331). U.S. Dept. of Commerce-NOAA, Office of Marine Minerals, Rockville, MD, 1977, 540 pp.; NTIS PB 274912 (set). 9. DeHuff, G. L. , and T. S. Jones. Manganese. Ch. in Mineral Facts and Problems, 1980 Edition. BuMines B 671, 1981, pp. 549-562. 10. Felix, D. Some Problems in Making Nodule Abundance Estimates From Seafloor Photographs. Marine Min., v. 2, 1980, pp. 293-302. 11. Fewkes, R. H. , W. D. McFarland, W. R. Reinhart, and R. K. Sorem. Devel- opment of a Reliable Method for Evalua- tion of Deep Sea Manganese Nodule Depos- its (grant GO274013, WA State Univ.). BuMines OFR 64-80, 1979, 94 pp.; NTIS PB 80-182116. 12. . Evaluation of Metal Re- sources at and Near Proposed Deep Sea Mine Sites (grant GO284008, WA State Univ.). BuMines OFR 108-80, 1980, 239 pp.; NTIS PB 80-228992. 13. Fewkes, R. H. , W. D. McFarland, and R. K. Sorem. Manganese Nodule Re- source Data, Sea Scope Expedition (grant GO284008, WA State Univ.). BuMines OFR 144-81, 1981; NTIS PB 82-142571. 14. Fisk, M. B., J. Z. Frazer, J. S. Elliott, and L. L. Wilson. Availability of Copper, Nickel, Cobalt, and Manganese From Ocean Ferromanganese Nodules (II) (grant GO254024, Scripps Inst. Oceanog- raphy). BuMines OFR 140(l)-80, 1979, 63 pp.; NTIS PB 81-145963. 15. Flipse, J. E. An Engineering Ap- proach to Ocean Mining. Pres. at Off- shore Tech. Conf., Houston, TX, May 1969, Paper 1035, 15 pp. 16. . Deep Ocean Mining Pollu- tion Mitigation. Pres. at Offshore Tech. Conf., Houston, TX, May 1980, Paper 3834, 5 pp. 39 17. Flipse, J. E. (J. E. Flipse Marine Mining Consultant). Private communica- tion, 1981; available upon request from C. T. Hillman, BuMines , Spokane, WA. 18. Frazer, J. Z. Manganese Nodule Reserves: An Updated Estimate. Marine Min., v. 1, 1977, pp. 103-123. 19. Frazer, J. Z., and G. Arrhenius. World-wide Distribution of Ferromanganese Nodules and Element Concentrations in Se- lected Pacific Ocean Nodules. U.S. Na- tional Science Foundation-IDOE, Washing- ton, DC, 1972, 51 pp.; NTIS PB 234011. 20. Frazer, J. Z. , and M. B. Fisk. Availability of Copper, Nickel, Cobalt, and Manganese From Ocean Ferromanganese Nodules (III) (grant GO264024, Scripps Inst. Oceanography). BuMines OFR 140 (2)-80, 1979, 112 pp.; NTIS PB 81-145971. 21. Geological Factors Related to Characteristics of Seafloor Manganese Nodule Deposits (grant GO264024, Scripps Inst. Oceanography). BuMines OFR 142-80, 1980, 41 pp.; NTIS PB 81-145831. 22. Frazer, J. Z., M. B. Fisk, J. El- liott, M. White, and L. Wilson. Availa- bility of Copper, Nickel, Cobalt, and Manganese From Ocean Ferromanganese Nod- ules (grant GO264024, Scripps Inst. Oceanography). BuMines OFR 121-79, 1978, 141 pp.; NTIS PB 300 356. 23. Gale, G. D. (U.S. Bureau of Mines). Private communication, 1981; available upon request from C. T. Hill- man, BuMines, Spokane, WA. 24. Grote, P. B., and W. Gayman. A Technical Basis for the Development of Deep Ocean Mining Regulations (contract J0177131, Sci. Applications, Inc.). Bu- Mines OFR 87-80, 1979, 310 pp. 25. Heezen, B. C. , and M. Tharp. Bathymetric and Nodule Assessment Map Series, Northeast Equatorial Pacific Ocean. U.S. Geol. Surv. Misc. Invest. Series. Maps 1-1094 A - 1-1094 0, 1978. 26. Hillman, C. T. Manganese Nodule Resources of Site C, Northeast Equatorial Pacific Ocean. Unpublished BuMines re- port, 1980, 43 pp.; available for consul- tation at Western Field Operations Cen- ter, Spokane, WA. 27. Hillman, C. T., and R. D. Weldin. A Preliminary Evaluation of a Deep Ocean Polymetallic Nodule Deposit. Unpublished BuMines report, 1976, 38 pp.; available for consultation at Western Field Opera- tions Center, Spokane, WA. 28. Hillman, C. T., and N. Wetzel. Manganese Nodule Resources Within the Northeast Pacific High Grade Zone. Un- published BuMines report, 1980, 85 pp.; available for consultation at Western Field Operations Center, Spokane, WA. 29. Horn, D. R. , B. M. Horn, and M. N. Delach. Sedimentary Provinces, North Pacific. Chart compiled by Lamont- Doherty Geol. Observatory, Columbia Univ., Palisades, NY, 1973. 30. Jugel, M. K. Deep Seabed Mining Industrial Development — Approaches and Their Timing. NOAA Draft Report, July 22, 1982, 15 pp.; available for consulta- tion at Office of Marine Minerals, Rock- ville, MD. 31. Kollwentz, W. Prospecting and Ex- ploration of Manganese Nodule Occur- rences. Ch. in Review of the Activities; Edition 18, Manganese Nodules - Metals from the Sea. Metallgesellschaf t AG, 1975, pp. 12-26. 32. Matthews, N. A., and S. F. Sibley. Nickel. Ch. in Mineral Facts and Problems, 1980 Edition. BuMines B 671, 1981, pp. 611-627. 33. Menard, H. W. Marine Geology of the Pacific. McGraw-Hill, 1964, 271 pp. 34. Moncrieff, A. G., and K. B. Smale- Adams . The Economics of First Generation Manganese Nodule Operations. Min. Congr. J., v. 60, No. 12, 1974, pp. 46-50. 40 35. Monhemius , A. J. The Extractive Metallurgy of Deep Sea Manganese Nodules. Ch. in Topics in Nonferrous Extractive Metallurgy. Soc. Chem. Ind., 1980, pp. 42-69. 36. Mudie, J. D. , J. A. Grow, and J. S. Bessey. A Near-Bottom Survey of Lineated Abyssal Hills in the Equatorial Pacific. Ch. in Marine Geophysical Researches 1. D. Reidel Publ. Co., 1972, pp. 397-411. 37. Ozturgut, E., G . C. Anderson, R. E. Burns, J. W. Lavaelle, and S. A. Swift. Deep Ocean Mining of Manganese in the North Pacific, Premining Environ- mental Conditions and Anticipated Mining Effects. U.S. Dept. of Commerce-NOAA Tech. Memorandum ERL MESA-33, 1978, 133 pp.; available upon request from C. T. Hillman, BuMines , Spokane, WA. 38. Piper, D. Z. (comp.). Deep Ocean Environmental Study: Geology and Geo- chemistry of DOMES Sites A, B, and C, Equatorial North Pacific. U.S. Geol. Surv. OFR 77-778, 1977, pp. 217-266; available for consultation at U.S. Geo- logical Survey libraries in Menlo Park, CA, Golden, CO, and Reston, VA. 39. Ryan, W. B. T. , and B. C. Heezen. Smothering of Deep Sea Benthic Commun- ities From Natural Disasters. 1976, 132 pp.; NTIS PB 279527/AS. 40. Schroeder, H. J., and J. H. Jolly. Copper. Ch. in Mineral Facts and Prob- lems, 1980 Edition. BuMines B 671, 1981, pp. 227-244. 41. Shaw, J. L. The Economics of an Ocean Mining Project. Pres. at 4th In- ternat. Ocean Development Conf., Tokyo, Japan, 1976, 14 pp.; available upon request from C. T. Hillman, BuMines, Spo- kane , WA . 42. Sibley, S. F. Cobalt. Ch. in Mineral Facts and Problems, 1980 Edition. BuMines B 671, 1981, pp. 199-214. 43. Sorem, R. K. , and R. H. Fewkes. Manganese Nodule Research Data, and Meth- ods of Investigation. IFI/Plenum, 1979, 723 pp. 44. Sullivan, A. F., and F. A. Ruggeri. Submerged Pumps for Deep Ocean Min- ing. CIMBull., v. 67, No. 752, 1974, pp. 80-85. 45. Tins ley, C. R. Manganese Nodule Mining Industry: A Study of Expected In- vestment Requirements. Ch. in Manganese Nodules, Dimensions, and Perspectives. D. Reidel Publ. Co., 1979, pp. 119-138. 46. U.S. Bureau of Mines. Mineral Commodity Summaries. 1981, pp. 36, 49, 94, 104. 47. . MINSIM4/0PEN Documenta- tion. Unpublished internal document, 1979, 58 pp.; available upon request from B. B. Gosling, BuMines, Spokane, WA. 48. U.S. Navy. Marine Climatic Atlas of the World, Volume II, North Pacific Ocean. Director, Naval Oceanography and Meteorology, 1977, 388 pp. 49. Van Andel, T. H. , G. R. Heath, and T. C. Moore. Cenozoic History and Paleoceanography of the Central Equato- rial Pacific Ocean: A Regional Synthesis of Deep Sea Drilling Data. Geol. Soc. Am. Memoir 143, 1975, 134 pp. 50. Welling, C. G. Next Step in Ocean Mining — Large Scale Test. Min. Congr. J., v. 62, No. 12, 1976, pp. 46-51. 41 APPENDIX A.— DISCUSSION OF ABUNDANCE AND RESOURCE ESTIMATES Abundance is defined as the weight of nodules per unit area of seafloor, and is usually given in either wet or dry kilo- grams per square meter. This expression may be easily converted to metric tons per square kilometer by multiplying by a factor of 1,000. Therefore, an abun- dance of 6 kg/m 2 would be equivalent to 6,000 t/km 2 . Dry abundance is only about 70 pet of wet abundance, because nodules are extremely porous and contain approxi- mately 30 wt pet water. Therefore, a wet nodule abundance of 10 kg/m 2 would equal 7 kg/m 2 dry. Resource quantities are generally ex- pressed in dry metric tons and are ob- tained by multiplying average dry abun- dance by the size (square kilometers) of the site being considered. If, for ex- ample, an area covers 10,000 km 2 and has an average wet abundance of 8.6 kg/m 2 , the resource quantity would be calculated as follows: 1 . Convert wet abundance to dry abundance — 8.6 kg/m 2 (wet) x 0.70 = 6.0 kg/m 2 (dry). 2. Convert dry abundance to metric tons per square kilometer — 6.0 kg/m 2 (dry) x l x 10 6 m 2 /km 2 = 6.0 x 10 6 kg/km 2 (dry). 6.0 x 10 6 kg/km 2 * 1,000 kg/t = 6,000 t/km 2 . 3. Determine resource quantity of 10,000-km 2 area— 6,000 t/km 2 (dry) x 10,000 km 2 = 60,000,000 t (dry). Calculated in this manner, the total tonnage is considered a gross estimate, and should be reduced by a series of practical considerations to get a reason- able estimate of recoverable resource (see text). Abundances, the basis for resource es- timates, are derived from bottom sam- pling, seafloor photographs, and tele- vision video tapes. Bottom samples provide the best data. To determine abundance, recovered nodules are simply weighed and the weight is then divided by the area of seafloor sampled (a constant for each sampling device). Box cores and certain grab samplers , such as the 0kean-70 (Japanese) , take a large sample and thereby afford the most accurate estimate. Also, because of specialized construction and weight of these devices, there is a low probability that portions of the sample will be lost. Additionally, box core samples are rela- tively undisturbed and can be used for a variety of studies. The main drawback is that use of these devices is time consum- ing and expensive, because they must be lowered and raised by cable. Conversely, use of free-fall devices is comparatively cheap. Many can be launched overboard (without tether) and recovered in rela- tively short periods of time, but there is a continuing risk that an incom- plete sample will be taken or portions lost during ascent. Therefore, estimates based on grab samples are apt to be less than true abundances. Seafloor photography and television are excellent tools for judging continuity between sample points. However, diffi- culties exist in converting apparent nod- ule populations in photographs or video tapes to abundances . One problem is that individual nodule weights must be esti- mated by comparing cross-sectional area with graphs developed from nearby bottom sampling. A second, more serious problem is that portions of nodules are usually obscured by a light coating of sediment. Felix (10) 1 indicates that significantly low estimates may result. Correction factors can be determined and applied if ^Underlined numbers in parentheses re- fer to items in the list of references preceding this appendix. 42 a detailed sampling program is carried out. No such detail is now publicly available. Abundances in this report are based on average estimates from 185 ship stations. Because raw data were developed on a random basis, no attempt was made to differentiate between estimates based on box cores , grab samples , or photographs , nor was more significance placed on any particular estimate method. This being the case, assigned abundances and conse- quently resource tonnages are probably low, and are considered minimum values. 43 APPENDIX B. —SAMPLE STATION LOCATIONS, ABUNDANCE ESTIMATES, AND ANALYSES FOR STUDY AREAS A, B, AND C This appendix contains a series of tables with all available sample data for each subarea. Tables B-7, B-ll, and B-14 contain information from additional sam- ples taken from locations nearby, yet outside subarea boundaries. TABLE B-l. - Subarea AI — location, abundance, and analytical data Index North latitude West longitude Population, 1 pet Abundance , kg/m 2 Analysis, wt pet, dry basis No. Ni Cu Co Mo Mn Fe 206 11.132 148.072 1.43 1.19 0.22 29.30 6.20 207 10.978 148.325 1.32 1.12 .21 25.40 6.53 208 11.030 148.382 1.48 1.12 .19 25.00 6.30 209 11.018 148.498 1.24 1.03 .20 0.05 25.00 5.44 210 11.513 148.578 1.09 .95 .17 22.40 5.30 211 11.803 148.662 1.35 1.31 .20 .06 28.70 5.78 212 11.233 148.833 NPr 213 11.817 148.933 20-50 .75 .50 .25 20.00 9.90 214 11.167 148.950 20-50 215 11.487 149.183 1.10 .77 .24 .02 22.00 7.62 216 12.023 149.300 1.31 1.22 .23 .03 27.30 6.45 217 11.433 149.283 .79 .50 .18 17.20 14.50 218 11.667 150.117 1.28 .95 .23 24.00 6.95 219 11.970 150.308 1.23 1.08 .19 .03 24.50 7.54 1.20 0.23 12 0.98 0.26 12 0.21 0.03 12 0.04 0.02 5 24.23 3.48 12 7.38 Standard Number of 2.56 12 NPr Nodules present, no additional information available. 1 Amount of seafloor covered with nodules. NOTE. — Blank indicates no information available. 44 TABLE B-2. - Subarea All — location, abundance, and analytical data Index North latitude West longitude Population, 1 pet Abundance , kg/m 2 Analysi s, wt pet, dry basis No. Ni Cu Co Mo Mn Fe 32 9.035 145.000 1.43 1.01 0.17 0.06 30.90 6.30 33 8.980 145.110 1.42 1.17 .18 .06 30.10 5.90 34 8.955 145.807 1.62 1.35 .17 .06 28.30 4.64 35 8.867 146.440 13.87 36 8.902 146.443 11.25 1.47 1.08 .32 27.40 6.30 37 8.932 146.445 10.62 1.56 1.18 29.50 5.44 38 8.965 146.445 3.12 39 9.047 146.457 4.37 1.89 1.52 32.00 3.65 40 9.050 146.487 8.75 1.52 1.06 31.00 5.66 41 8.997 146.497 18.12 1.31 .74 23.20 7.77 42 8.958 146.492 1.87 1.71 1.23 26.30 5.53 43 8.932 146.493 6.25 1.55 1.23 .17 29.40 5.20 44 8.897 146.492 14.37 1.78 1.43 30.70 5.04 45 9.057 146.542 3.75 1.91 1.60 30.40 4.02 46 9.062 146.572 9.00 1.44 1.12 26.50 4.57 47 8.965 146.668 1.35 1.22 .19 .05 29.90 5.85 48 8.740 147.532 1.47 1.22 .18 .05 30.10 5.74 49 8.727 147.590 1.48 1.27 .18 .06 29.60 5.68 50 8.575 147.778 1.30 1.25 .16 .05 27.30 5.98 51 9.100 145.300 1.52 1.27 .26 .04 26.20 5.30 52 9.447 145.555 1.44 1.14 .22 .05 28.30 5.75 53 9.657 146.332 1.33 1.08 .21 26.20 7.07 54 9.250 146.350 >50 1.24 .80 .26 22.00 6.50 55 8.590 146.300 20-50 1.50 1.20 .20 27.00 5.00 56 8.480 147.250 <20 1.30 1.15 .25 28.00 5.00 57 9.503 145.805 , 1.60 1.30 30.00 6.00 58 9.457 145.825 1.50 1.30 30.60 6.00 59 9.457 145.828 1.50 1.30 31.20 5.30 60 9.457 145.833 1.50 1.20 32.30 5.00 61 9.457 145.838 1.50 1.30 31.20 5.40 62 9.457 145.842 1.30 1.20 30.00 5.00 63 9.453 145.842 1.40 1.20 30.00 5.00 64 9.457 145.845 1.30 1.30 29.00 5.60 65 9.498 145.828 1.40 1.10 29.80 6.00 66 9.508 145.828 1.40 1.10 29.40 6.00 67 9.502 145.828 1.40 1.10 30.00 6.00 68 9.523 145.828 1.60 1.30 30.50 5.00 69 9.512 145.828 1.50 1.30 28.30 5.30 70 9.517 145.828 1.50 1.10 30.30 6.00 71 9.505 145.850 1.50 1.10 31.00 6.00 72 9.518 145.850 1.70 1.40 33.30 4.50 73 9.515 145.850 1.50 1.30 30.70 5.50 74 9.522 145.850 1.60 1.30 29.00 5.00 75 9.520 145.855 1.50 1.20 29.00 5.50 76 9.458 145.867 1.50 1.30 31.20 5.60 77 9.458 145.870 1.50 1.30 30.40 5.80 79 9.458 145.880 1.50 1.20 31.60 5.80 80 9.458 145.885 1.60 1.30 31.40 5.70 81 9.375 145.882 1.40 1.20 31.00 6.00 82 9.373 145.885 1.30 .90 30.00 6.20 See footnote at end of table. 45 TABLE B-2. - Subarea All — location, abundance , and analytical dat a — Continued Index North latitude West longitude Population, 1 pet Abundance , kg/m 2 Analysis, wt pet, dry basis No. Ni Cu Co Mo Mn Fe 83 9.372 145.890 1.40 1.20 31.00 6.00 84 9.372 145.893 1.50 1.20 30.60 5.50 85 9.370 145.902 1.40 1.10 30.00 6.00 86 9.370 145.905 1.40 1.00 26.90 5.40 87 9.340 145.905 1.40 1.10 31.00 6.20 88 9.340 145.910 1.40 1.10 30.00 6.80 89 9.340 145.913 1.20 .80 28.40 9.00 90 9.340 145.918 .80 .60 23.00 14.00 91 9.278 145.917 1.40 1.10 31.60 6.40 92 9.362 145.922 1.20 .90 30.00 7.50 93 9.362 145.925 1.00 .80 26.00 11.00 94 9.362 145.928 1.40 1.00 31.40 6.00 95 9.362 145.933 1.30 1.00 26.00 6.00 96 9.362 145.940 1.40 1.00 27.00 6.00 97 9.335 145.932 1.10 .70 23.00 10.00 98 9.333 145.940 1.00 .60 25.00 10.00 99 9.347 145.950 .90 .50 24.00 12.00 100 9.358 145.950 1.20 .80 27.00 9.00 101 9.352 145.950 .90 .70 26.00 10.30 102 9.365 145.950 1.20 .90 22.00 8.00 103 9.362 145.950 1.20 .80 21.00 7.00 104 9.318 145.955 1.00 .80 24.00 10.00 105 9.280 145.958 1.50 1.10 24.00 10.00 106 9.297 145.958 1.20 .90 23.00 8.00 107 9.289 145.958 1.50 1.10 28.60 7.00 108 9.315 145.972 .90 .60 25.00 13.00 109 9.315 145.977 1.10 .70 28.00 10.30 110 9.315 145.982 1.10 .70 27.00 11.00 111 9.315 145.985 1.10 .70 26.00 10.50 112 9.315 145.985 1.20 .70 26.00 10.00 113 9.315 145.998 1.00 .60 24.70 11.40 114 9.315 146.000 .90 .50 25.80 12.00 115 9.315 146.005 .80 .50 26.40 12.00 116 9.315 146.008 1.40 1.20 30.30 5.70 117 9.328 145.978 1.00 .70 26.00 11.00 118 9.337 145.983 1.30 .90 28.00 8.00 119 9.308 145.987 1.30 1.10 25.00 6.00 120 9.357 146.015 1.50 1.30 28.00 5.50 121 9.265 146.017 1.50 1.20 30.00 5.50 122 9.267 146.022 1.40 1.10 30.80 5.40 123 9.272 146.027 1.40 1.10 31.00 5.60 124 9.275 146.032 1.50 1.30 30.80 5.00 125 9.278 146.035 1.50 1.10 30.50 126 9.280 146.040 1.40 1.00 29.50 6.00 127 9.322 146.018 1.45 1.20 31.50 5.50 128 9.315 146.020 1.50 1.30 27.50 5.00 129 9.313 146.023 1.00 .70 24.80 9.70 130 9.313 146.028 1.40 1.00 29.40 8.00 131 9.313 146.032 1.30 1.00 27.00 6.20 132 9.313 146.043 .90 .50 23.50 13.00 See footnote at end of table, 46 TABLE B-2. - Subarea All — location, abundance, and analytical data — Continued Index North latitude West longitude Population, * pet Abundance , kg/m 2 Analysis , wt pet, dry basis No. Ni Cu Co Mo Mn Fe 133 9.520 146.035 1.10 1.00 25.30 4.30 134 9.268 146.042 1.40 1.10 27.00 5.80 135 9.270 146.043 1.40 1.10 29.70 5.40 136 9.273 146.047 1.40 1.20 28.00 5.50 137 9.275 146.050 1.70 1.00 29.00 7.00 138 9.278 146.055 1.30 1.00 27.80 139 9.282 146.060 1.30 .90 27.80 140 9.452 146.043 1.30 1.10 30.50 6.00 141 9.523 146.048 1.00 1.00 28.00 2.80 142 9.523 146.053 1.10 1.00 28.00 4.20 143 9.523 146.060 1.10 1.00 26.40 3.50 144 9.523 146.062 1.10 .90 27.30 5.00 145 9.505 146.048 1.50 1.10 29.00 5.70 146 9.515 146.050 1.30 1.10 25.00 4.00 147 9.515 146.060 1.30 1.20 27.80 4.80 148 9.515 146.063 1.30 1.20 26.40 4.70 149 9.515 146.067 1.00 .70 25.00 7.60 150 9.515 146.070 1.00 .70 25.60 8.80 151 9.503 146.062 1.30 1.00 26.40 4.80 152 9.503 146.065 1.00 .90 26.30 7.00 153 9.503 146.070 1.00 .90 26.70 7.00 154 9.503 146.080 1.00 .80 26.00 9.70 155 9.297 146.063 1.00 .80 23.80 11.40 156 9.358 146.067 1.40 1.10 31.00 6.00 157 9.305 146.073 .90 .60 23.20 10.30 158 9.308 146.077 - .90 .50 24.50 13.00 159 9.312 146.082 .90 .50 25.30 12.00 160 9.315 146.085 .90 .60 25.20 12.00 161 9.290 146.073 1.00 .90 26.00 7.00 162 9.342 146.075 1.30 .90 28.00 8.40 163 9.322 146.075 .80 .50 27.00 12.00 164 9.333 146.075 .80 .50 27.30 11.70 165 9.332 146.075 .90 .60 26.30 12.70 166 9.327 146.075 .90 .50 26.20 13.00 167 9.270 146.075 1.00 1.00 26.00 7.00 168 9.273 146.075 1.40 1.00 27.20 6.50 169 9.265 146.075 1.20 .90 23.00 7.40 170 9.262 146.075 1.60 1.20 27.80 5.00 171 9.250 146.075 1.00 .70 24.40 9.30 172 9.310 146.088 .85 .50 24.50 13.30 173 9.480 146.115 1.30 1.00 28.00 6.00 8.78 NC 1.30 0.25 1.00 0.25 0.21 0.05 0.05 0.01 27.85 2.63 7.13 Standard deviation. . . . 2.57 12 139 139 15 9 139 136 NC Not calculated. 1 Amount of seafloor covered with nodules. NOTE. — Blank indicates no information available. 47 TABLE E -3. - Subarea AIII — locat ion, abundance, and analytical data Index No. North latitude West longitude Population, 1 pet Abundance , kg/m 2 Analysis, wt pet, dry basis Ni Cu Co Mo Mn Fe 174 8.542 148.932 1.38 1.28 0.17 0.05 30.70 6.30 175 8.483 149.417 <20 1.45 1.35 .20 26.80 5.90 176 8.250 149.500 20-50 1.15 .85 .26 22.00 7.50 177 8.450 149.783 47.2 8.30 178 8.417 149.800 >50 179 8.200 150.300 1.25 1.15 .25 25.00 5.50 180 8.400 150.283 1.35 1.25 .20 26.80 6.90 181 8.450 150.283 1.45 1.30 .20 27.60 6.30 182 8.483 150.317 >50 183 8.483 150.400 .7 .20 184 8.453 150.478 <20 185 7.750 150.683 1.44 1.54 .20 26.67 6.17 186 8.083 150.683 <20 187 7.817 150.758 <20 188 8.033 150.733 1.35 1.40 .20 29.80 6.40 189 8.150 150.717 1.30 1.15 26.50 7.50 190 8.197 150.738 40.9 7.50 191 8.475 150.742 >50 13.70 1.08 .77 .26 .04 23.93 10.08 192 8.217 150.767 NOb 193 8.133 150.767 <20 .78 .59 .42 20.81 13.73 194 8.250 150.800 20-50 195 8.458 150.778 <20 .60 1.08 .78 .25 24.62 10.29 196 8.503 150.797 20-50 11.50 1.45 1.23 .21 27.01 5.99 197 8.467 150.800 1.44 1.45 .18 27.33 4.92 198 8.400 150.800 2.4 .60 199 8.500 150.833 >50 .85 .70 .23 20.40 11.00 200 8.457 150.837 >50 12.30 1.38 1.04 .24 27.23 7.66 201 8.417 150.817 <20 1.39 1.35 .21 27.90 6.50 202 8.417 150.900 <20 1.42 1.63 .17 29.14 5.02 203 8.433 150.917 4.9 1.20 204 8.273 150.933 1.47 1.34 .21 .05 28.75 6.72 205 7.825 150.950 >50 6.21 NC 1.28 0.21 1.16 0.30 0.22 0.06 0.05 0.01 26.26 2.70 7.38 Standard deviation. . . . 2.30 ■ - Number of 9 19 19 18 3 19 19 NC Not calculated. NOb No nodules observed in photographs or no nodules recovered in samples. 1 Amount of seafloor covered with nodules. NOTE. — Blank indicates no information available. 48 TABLE B -4. - Subarea AIV — location, abundance, and analytical data Index North latitude West longitude Population, 1 pet Abundance , kg/m 2 Analysis, wt pet, dry basis No. Ni Cu Co Mo Mn Fe 1 9.900 149.950 0.75 0.39 0.20 22.65 14.22 2 9.717 149.950 1.08 .65 .21 23.00 7.7CI 3 9.683 149.900 1.27 .82 .26 22.00 7.7S 4 9.220 149.817 .90 .66 .28 17.00 10. 1C 5 8.783 149.867 .75 .50 .30 22.00 11.8C 6 8.833 149.917 1.02 .65 .28 17.80 7.9i 7 8.718 150.235 10.50 .99 .69 .33 23.35 11.6* 8 8.685 150.252 5.50 .89 .54 .36 22.90 11.7* 9 8.690 150.250 21.70 .99 .58 .24 20.90 11.4* 10 8.695 150.312 11.40 .90 .62 .31 22.30 11.6C 11 8.730 150.312 19.90 .87 .64 .27 21.50 11.11 12 9.200 150.375 1.00 .80 .25 17.00 5.0C, 13 9.333 150.583 .55 .43 .17 17.20 14. 0C 14 9.450 150.700 .33 .33 .80 4.50 9.4C 15 8.817 150.783 45.6 8.20 16 9.333 150.807 6.20 .78 .59 .42 20.80 13.7: 17 9.345 150.845 4.70 1.54 1.10 .22 23.80 8.1* 18 9.400 150.832 6.10 1.30 .86 .24 21.40 10.2] 19 9.318 150.840 9.70 1.33 1.00 .22 24.90 8.8; 20 9.450 150.817 46.9 8.10 21 9.423 150.845 >50 22 9.327 150.845 - .60 1.20 .83 .26 19.60 6.7£ 23 9.355 150.857 .10 24 9.317 150.863 58.0 8.80 25 9.317 150.875 10.20 .86 .59 .32 22.30 11.4C 26 9.397 150.880 15.20 .82 .55 .26 20.90 11.1: 27 9.500 150.883 .77 .53 .25 15.67 8.8C 28 9.533 150.900 <20 29 9.517 150.950 .83 .59 .19 15.80 8.1f 30 9.917 150.933 .95 .70 .25 23.60 10.3C 31 9.883 150.950 1.25 1.00 .20 24.40 7.1C 241 10.000 150.000 .92 .66 .25 19.00 9.6C 9.18 0.96 0.67 0.28 20.24 9.9S Standard deviation. . . . NC 0.26 0.19 0.12 4.19 2.3J Number of 16 26 26 26 26 It NC No t calculat ed. ^Amoun t of seafl oor covered with nodules. NOTE.- -Blank ind icates no i nformation ava ilable. X 49 TABLE B-5. - Subarea AV — location, abundance, and analytical data Index North latitude West longitude Population, 1 pet Abundance, kg/m 2 Analysis, wt pet, dry basis No. Ni Cu Co Mo Mn Fe 250 8.308 151.023 NOb 252 8.050 151.400 <20 1.30 1.20 0.25 24.00 6.00 253 8.275 151.122 20-50 8.10 1.31 1.09 .24 27.00 7.70 254 8.302 151.158 <20 .20 255 8.267 151.180 33.0 5.90 256 8.267 151.188 <20 1.70 1.61 1.64 .18 30.00 4.73 257 8.293 151.220 20-50 .70 1.36 1.33 .20 25.23 5.82 258 8.238 151.238 20-50 9.40 1.34 1.06 .22 27.30 8.91 259 8.475 151.152 NPr 260 8.467 151.150 1.19 1.05 .18 25.40 7.30 261 9.005 151.182 .10 262 9.027 151.203 6.5 1.60 263 9.038 151.187 <20 1.60 1.53 1.45 .17 25.13 4.92 264 9.038 151.190 <20 265 9.042 151.177 <20 1.60 1.62 1.56 .26 30.40 3.78 266 9.053 151.183 3.80 267 9.058 151.185 <20 4.90 1.46 1.31 .22 24.22 5.57 268 9.080 151.157 <20 .70 269 9.080 151.185 <20 7.60 1.72 1.55 .27 29.90 4.25 270 9.065 151.237 <20 3.60 1.59 1.49 .29 29.50 4.66 271 9.100 151.500 <20 1.30 1.10 .25 19.00 5.50 272 9.033 151.567 1.25 1.06 .15 26.80 5.30 273 8.400 151.800 NOb 274 8.417 151.883 1.36 1.18 .18 23.30 4.81 275 9.367 151.967 <20 1.28 .09 .17 25.30 4.25 276 9.450 152.017 >50 277 9.383 152.033 1.30 1.05 .20 26.80 7.50 3.43 NC 1.41 0.16 1.20 0.36 0.21 0.04 26.20 2.96 5.69 Standard deviation. ... 1.45 Number of 15 16 16 16 16 16 NC Not calculated. NOb No nodules observed in photographs or no nodules recovered in samples. NPr Nodules present, no additional information available. 1 Amount of seafloor covered with nodules. NOTE. — Blank indicates no information available. 50 TABLE B-6. - Subarea AVI— lo cation, abun dance, and analytical data Index North latitude West longitude Population, * pet Abundance, kg/m 2 Analysis, wt pet, dry basis No. Ni Cu Co Mo Mn Fe 278 8.033 152.150 20-50 279 7.950 152.250 20-50 1.20 1.10 0.25 22.50 7.00 280 7.970 152.287 1.24 1.08 .24 23.01 7.27 281 8.050 152.300 NOb 282 8.133 152.267 >50 .84 .55 .21 19.45 9.55 283 8.098 152.603 .96 .72 .22 19.86 9.24 284 7.945 152.805 1.35 1.32 .15 26.10 5.25 293 8.342 152.952 NOb 294 8.321 152.959 1.11 1.20 .14 0.04 26.40 5.74 295 8.314 152.961 NOb 296 8.326 152.967 NOb 297 8.305 152.964 .90 1.03 .15 .04 26.40 6.47 298 8.296 152.965 1.08 .93 .18 .04 24.60 7.94 299 8.281 152.968 1.01 .99 .16 .03 22.40 6.56 300 8.272 152.970 1.20 1.25 .21 .04 24.41 7.79 301 8.264 152.972 1.01 .86 .20 .03 24.00 9.24 302 8.366 152.986 NOb 303 8.363 152.986 NOb 304 8.371 152.988 NOb 305 8.380 152.989 NPr 306 8.375 152.989 1.28 1.65 .13 .04 25.90 5.44 307 8.390 152.991 NOb 308 8.394 152.992 .90 1.03 .15 .04 26.40 6.47 309 8.400 153.000 NPr 310 8.285 153.009 NOb 311 8.321 153.009 NOb 312 8.347 153.016 1.02 .99 .18 .03 23.30 7.49 313 8.382 153.026 NOb 314 8.337 153.027 NOb 315 8.326 153.027 NOb 316 8.326 153.027 NOb 317 8.328 153.031 NOb 318 8.324 153.035 NOb 319 8.332 153.031 1.05 1.05 .17 .04 25.70 6.37 320 8.369 153.032 .94 .90 .17 .03 22.50 7.59 321 8.319 153.037 .92 .99 .16 .04 24.40 7.28 322 8.315 153.040 1.07 1.09 .16 .04 26.60 6.93 323 8.351 153.038 324 8.381 153.039 1.12 1.21 .14 .04 25.90 5.98 325 8.306 153.047 1.59 1.44 .19 .03 25.30 5.77 326 8.380 153.050 NOb 327 8.383 153.056 NOb 328 8.381 153.062 NOb 329 8.383 153.069 NOb 333 7.885 153.550 <20 1.45 1.39 .09 26.70 4.83 334 8.417 153.450 20-50 1.49 1.40 .22 23.40 4.59 340 8.095 153.915 1.16 1.15 .15 .05 23.90 7.75 1.13 0.20 23 1.10 0.24 23 0.17 0.04 23 0.04 0.01 16 24.31 2.05 23 6.89 Standard Number of 1.36 23 NOb No nodules observed in photographs or no nodules recovered in samples, NPr Nodules present, no additional information available. Amount of seafloor covered with nodules. NOTE. — Blank, indicates no information available 51 TABLE B-7. - Study area A — location, abundance, and analytical data outside subareas Index North latitude West longitude Population, 1 pet Abundance , kg/m 2 Analy sis, wt pet, dry basis No. Ni Cu Co Mo Mn Fe 221 11.933 146.448 1.31 1.03 0.23 0.04 26.70 6.45 222 9.133 146.817 1.00 .75 .20 19.60 7.00 223 9.450 147.300 20-50 .70 .40 .35 20.00 12.00 224 9.083 148.750 1.04 .75 .21 21.60 6.80 225 9.350 148.733 <20 22.20 1.35 1.02 .24 26.80 7.30 226 10.283 148.700 >50 1.20 .86 .24 27.10 7.55 in 10.283 148.750 1.40 1.05 .19 28.00 6.50 228 7.400 149.033 1.45 1.30 .15 29.60 5.20 229 7.700 149.050 <20 230 7.750 149.100 <20 1.00 .75 .25 22.00 10.20 231 8.875 149.100 <20 232 9.700 149.250 <20 233 9.275 149.400 1.35 1.25 .25 19.00 5.00 234 9.650 149.400 1.28 1.16 .16 26.10 6.10 235 9.683 149.517 <20 236 10.350 149.450 <20 1.00 .70 .30 21.50 9.50 237 12.717 149.067 1.10 .95 .30 24.00 8.90 242 10.633 150.033 20-50 .95 .60 .20 18.80 7.20 243 10.300 150.500 >50 .50 .40 .40 18.00 11.00 244 12.650 150.167 .58 .35 .35 21.07 14.43 245 12.600 150.233 >50 .75 .45 .40 22.80 14.10 246 7.567 150.700 NOb 247 7.450 150.767 <20 1.42 1.68 .15 27.90 5.58 248 7.417 150.833 NPr 249 9.900 151.042 >50 251 7.433 151.783 1.43 1.39 .15 25.73 4.60 285 8.663 152.630 .62 286 8.663 152.630 .12 287 8.663 152.630 .25 288 8.950 152.867 .66 .61 .22 17.02 8.84 289 8.950 152.867 1.33 .41 .78 22.61 10.94 290 9.983 152.950 5.62 291 9.983 152.950 6.25 292 9.983 152.950 1.53 1.11 29.40 6.52 330 8.933 153.083 <20 .95 .80 .20 24.50 8.50 331 9.900 153.117 <20 332 7.350 153.200 <20 335 9.700 153.550 <20 1.00 .60 .35 23.00 13.80 336 9.733 153.550 <20 .67 .39 .34 24.10 15.90 337 9.733 153.600 >50 .84 .52 .34 21.40 12.64 338 9.717 153.617 >50 339 9.617 153.697 1.37 1.59 .13 25.45 5.76 341 11.367 153.617 .25 1.33 1.12 .12 20.20 5.00 342 11.367 153.617 .25 1.33 1.14 .14 21.80 5.10 343 11.367 153.617 1.88 1.38 1.22 .14 25.30 5.85 344 10.935 153.307 >50 22.20 .52 .26 .24 19.80 12.51 345 11.010 153.333 <20 .40 1.16 1.02 .16 23.90 5.86 346 10.968 153.418 <20 4.00 1.31 1.08 .15 25.20 5.60 347 11.007 153.435 <20 1.80 1.15 1.08 .10 25.60 5.75 348 10.947 153.445 >50 10.80 .75 .44 .24 19.10 11.10 349 11.005 153.470 20-50 8.00 .90 .45 .22 18.80 8.56 350 11.013 153.478 20-50 7.00 351 10.977 153.477 20-50 12.00 352 10.993 153.480 20-50 6.40 .73 .49 .15 19.00 9.72 353 10.860 153.497 >50 14.00 .78 .50 .26 19.60 11.94 354 11.110 153.522 1.80 5.45 NC 1.07 0.30 0.83 0.37 0.24 0.12 0.04 NC 22.95 3.41 8.56 Standard d 3.15 Number of 19 38 38 37 1 38 38 NC Not calculated. NPr Nodules present, 1 Amount of seafloor NOb No nodules observed no additional information covered with nodules. NOTE. — Blank indicates no information available in photographs available. or no nodules recovered in samples , 52 TABLE B-8. - Subarea BI — location, abundance, and analytical data 'Index North latitude West longitude Population, 1 pet Abundance, kg/m2 Analysis, wt pet, dry basis No. Nl Cu Co Mo Mn Fe 523 13.922 139.772 1.26 1.26 0.21 30.00 6.45 524 13.928 139.780 1.31 1.39 .19 27.50 3.95 525 13.767 140.017 1.16 .94 .14 23.15 6.65 526 13.750 140.050 1.20 .85 .21 19.73 5.40 527 13.887 140.057 1.42 1.32 .22 30.40 4.20 528 13.667 140.067 1.07 .77 .24 22.20 7.37 529 13.733 140.083 1.00 .73 .24 17.00 7.80 530 13.717 140.100 .97 .68 .21 16.80 6.30 531 13.717 140.133 1.00 .64 .16 15.30 4.60 532 13.700 140.150 1.32 .90 .44 27.70 5.77 533 13.700 140.167 1.31 1.17 .17 26.80 5.60 534 13.700 140.200 1.41 1.22 .20 29.90 5.50 535 13.683 140.233 1.40 1.22 .19 28.50 5.00 536 13.683 140.283 1.36 1.00 .43 36.40 5.17 537 13.683 140.333 1.35 1.08 .41 28.90 5.10 538 13.683 140.333 1.41 1.14 .14 20.80 6.40 539 13.683 140.383 1.63 1.55 .10 31.70 4.96 540 13.667 140.433 1.45 1.46 .10 31.00 4.58 541 13.650 140.450 .88 .80 .23 20.20 5.30 542 13.650 140.467 1.07 .79 .44 26.30 5.79 543 13.647 140.470 1.09 1.06 .21 22.90 4.93 544 13.617 140.500 .86 .56 .14 18.20 7.20 545 13.633 140.500 1.43 1.20 .22 29.60 5.11 546 13.617 140.517 .32 .24 .14 7.50 5.20 547 13.617 140.533 1.37 1.10 .23 23.80 5.00 548 13.600 140.550 .88 .60 .24 18.10 10.70 549 13.617 140.550 .77 .62 .15 15.80 6.50 550 13.600 140.567 .86 .71 .20 15.50 5.80 551 13.600 140.583 1.16 .86 .20 23.60 6.30 552 13.583 140.600 1.02 .76 .16 16.30 4.80 553 13.583 140.617 .77 .45 .24 19.90 4.84 554 13.567 140.617 1.30 1.02 .23 27.60 6.50 555 13.583 140.617 ' 1.16 .88 .18 21.40 7.80 556 13.569 140.633 .89 .48 .52 22.00 9.24 557 13.567 140.633 1.02 .77 .22 21.10 7.60 558 13.567 140.650 1.58 1.08 .18 20.80 9.20 559 13.550 140.667 1.21 .74 .43 25.70 5.58 560 13.550 140.667 1.02 .82 .23 20.20 5.40 561 13.550 140.683 1.30 1.08 .12 25.70 5.16 562 13.550 140.683 1.04 .56 .44 23.60 6.98 563 13.517 140.717 .97 .83 .16 19.20 5.90 564 13.533 140.717 1.24 .89 .16 21.30 5.45 565 13.500 140.717 1.02 .64 .18 14.60 5.30 566 13.567 140.717 1.06 .87 .24 19.10 5.60 567 13.483 140.733 .92 .58 .18 14.30 5.20 568 13.467 140.733 .94 .61 .21 19.40 6.75 569 13.400 140.750 .94 .64 .28 18.30 7.40 570 13.433 140.750 .90 .64 .18 18.40 7.50 571 13.417 140.750 .95 .72 .22 18.10 6.10 572 13.400 140.767 .97 .63 .27 18.50 9.90 573 13.483 140.750 1.04 .49 .46 22.80 6.63 574 13.450 140.750 .90 .52 .22 19.20 6.29 575 13.450 140.750 .86 .61 .23 16.40 6.00 576 13.483 140.750 1.33 .95 .24 24.20 6.00 577 13.467 140.750 1.07 .81 .21 22.10 5.35 578 13.467 140.750 .67 .52 .13 12.90 5.50 579 13.233 140.833 .61 .29 .42 27.60 5.11 1.10 0.25 57 0.84 0.29 57 0.23 0.10 57 22.03 5.54 57 6.09 Standard d Number of 1.38 56 'Amount of seafloor covered with nodules. NOTE. — Blank indicates no information available. 53 TABLE B-9. - Subarea BII — location, abundance, and analyti .cal data Index North latitude West longitude Population, 1 pet Abundance , kg/m 2 Analysis , wt pet , dry bas is No. Ni Cu Co Mo Mn Fe 580 13.160 141.008 0.57 0.39 0.20 22.65 12.70 581 13.003 141.213 1.46 1.20 .26 28.80 4.75 582 12.850 141.583 1.00 .73 .12 16.80 5.80 583 12.833 141.583 .92 .51 .30 20.90 8.38 584 12.850 141.617 .94 .64 .28 17.90 7.40 585 12.850 141.617 1.12 .83 .24 6.61 586 12.833 141.617 1.25 .96 .21 23.80 5.40 587 12.817 141.633 1.36 1.07 .20 27.80 4.96 588 12.817 141.667 1.33 1.05 .38 28.70 5.60 589 12.817 141.667 1.43 1.11 .22 30.50 4.84 590 12.817 141.683 1.51 1.16 .23 32.00 5.50 591 12.800 141.700 1.39 1.17 .21 30.20 4.80 592 12.800 141.717 1.63 1.29 .18 24.80 7.70 593 12.800 141.717 1.43 1.08 .19 30.70 4.19 594 12.783 141.733 1.14 .91 .26 23.40 5.40 595 12.783 141.733 1.39 1.06 .20 30.50 4.68 596 12.767 141.750 .88 .57 .18 18.80 6.35 597 12.767 141.750 1.39 1.22 .19 29.20 6.16 598 12.767 141.767 1.10 .79 .16 23.60 6.80 599 12.750 141.783 1.24 .92 .25 22.60 5.70 600 12.683 141.783 1.03 .78 .24 19.80 5.90 601 12.733 141.800 .97 .69 .24 18.90 11.90 602 12.733 141.817 1.32 1.07 .14 24.70 5.96 603 12.717 141.842 1.43 1.26 .13 29.10 6.24 604 12.717 141.850 .84 .71 .29 18.50 5.50 605 12.717 141.850 1.37 1.35 .20 21.50 4.70 606 12.700 141.883 1.23 .95 .22 21.80 5.50 607 12.667 141.900 1.18 .72 .22 24.30 5.82 608 12.667 141.917 .86 .61 .24 14.90 4.80 609 12.667 141.933 1.21 .92 .27 25.20 8.10 610 12.650 141.950 1.18 .95 .23 26.00 6.20 611 12.633 141.967 .93 .52 .27 19.40 9.30 612 12.633 142.000 1.48 1.33 .12 30.60 5.22 613 12.617 142.017 .98 .71 .22 18.20 5.40 614 12.600 142.058 1.30 1.05 .09 26.40 6.60 615 12.600 142.067 1.02 .81 .25 20.40 5.80 616 12.667 142.068 .83 .58 .25 23.80 6.30 617 12.583 142.150 1.25 1.21 .21 0.06 31.30 4.91 1.18 0.24 38 0.92 0.26 38 0.23 0.07 38 0.06 NC 1 24.28 4.76 37 6.26 Standard Number o 1.82 38 NC Not calculated. 1 Amount of seafloor covered with nodules. NOTE. — Blank indicates no information available, 54 TABLE B-10. - Subarea Bill — location, abundance, and analytical data Index North latitude West longitude Population, * pet Abundance , kg/m 2 Analysi s, wt pet, dry basis No. Ni Cu Co Mo Mn Fe 404 10.000 140.000 1.34 1.16 0.24 0.06 29.90 5.50 407 11.810 137.405 >50 16.00 1.68 1.25 .23 29.20 4.29 408 11.847 137.445 >50 10.00 1.66 1.20 .25 29.50 4.68 409 11.803 137.438 >50 16.30 1.66 1.20 .24 29.10 4.59 410 11.810 137.472 <20 .80 1.63 1.47 .20 29.20 3.57 411 12.183 137.683 11.30 1.54 1.24 .22 29.40 5.23 412 12.160 137.707 >50 15.60 1.56 1.20 .21 27.30 4.74 413 12.173 137.735 1.10 1.60 1.40 .30 26.90 4.64 414 12.200 137.745 <20 .20 1.57 1.44 .18 26.30 3.79 415 12.148 137.743 >50 18.70 1.65 1.21 .22 29.10 5.03 416 12.142 137.767 <20 2.60 1.46 1.36 .20 26.50 4.93 417 11.738 138.353 <20 .05 1.51 1.45 28.50 3.76 418 11.732 138.370 <20 4.00 1.50 1.50 .23 27.40 5.04 419 11.722 138.373 <20 .04 1.70 1.81 27.50 4.53 420 11.272 139.070 <20 1.90 1.61 1.20 .20 30.20 4.51 421 11.248 139.090 <20 .09 1.29 1.50 29.40 3.59 422 11.228 139.165 <20 .03 1.27 1.45 28.10 3.73 423 11.608 139.128 <20 4.50 .91 1.53 21.60 4.82 424 11.728 139.137 <20 .04 1.40 1.48 28.60 3.68 425 11.718 139.148 <20 .03 1.32 1.46 26.60 3.33 426 11.707 139.180 20-50 9.50 1.44 1.14 .18 28.60 4.90 427 11.693 139.183 20-50 .90 1.91 1.54 .20 27.80 4.32 428 10.750 139.400 1.36 .68 .30 20.80 7.40 429 10.672 139.953 1.55 1.26 .23 30.70 5.22 430 12.145 137.757 37.1 9.04 431 11.257 139.015 2.34 432 11.247 139.068 <20 3.00 433 10.650 139.100 20-50 434 10.600 139.425 <20 435 11.703 138.390 <20 436 11.675 138.432 <20 437 11.258 139.055 NOb 438 11.008 139.988 15.00 1.74 1.25 32.10 3.31 439 11.017 139.967 <20 1.13 .73 .24 22.10 7.50 440 11.057 139.997 1.58 1.10 .18 30.10 5.20 441 11.067 139.997 <20 5.35 1.52 1.40 .24 28.30 4.40 442 11.067 139.998 <20 3.95 443 11.083 140.000 5.62 1.50 1.29 27.40 3.23 444 11.117 140.000 1.52 1.40 .24 28.70 4.90 445 11.048 140.047 <20 .20 1.71 1.49 .19 30.80 4.00 446 11.048 140.045 <20 .31 447 11.012 140.067 1.37 1.25 .21 24.70 4.30 448 11.043 140.070 1.19 .86 .30 21.50 6.08 449 11.037 140.078 1.35 1.11 .27 28.40 5.85 450 11.012 140.080 1.41 1.29 .19 29.40 4.50 451 11.095 140.082 4.32 1.72 1.34 .25 33.30 4.75 452 11.093 140.082 .73 1.85 1.36 .29 30.70 4.60 453 11.035 140.088 1.03 .96 .26 25.30 6.28 454 11.035 140.090 1.46 1.12 .26 25.90 5.88 455 11.010 140.092 <20 4.27 1.12 1.15 .17 22.80 6.00 See footnote at end of table. 55 TABLE B-10. - Subarea Bill — location, abundance, and analytical data — Continued Index North latitude West longitude Population, * pet Abundance , kg/m 2 Analysi s, wt pet, dry bas is No. Ni Cu Co Mo Mn Fe 456 11.008 140.092 <20 0.10 457 11.010 140.088 1.40 1.37 0.19 28.00 4.20 458 11.012 140.088 1.46 1.43 .21 27.10 4.20 459 11.013 140.088 1.07 .98 .16 20.00 4.20 460 11.012 140.088 1.10 1.23 .32 19.20 5.10 461 10.982 140.092 1.43 1.29 .27 28.50 4.62 462 10.980 140.092 1.41 1.03 .34 26.50 6.64 463 11.010 140.095 1.43 1.28 .26 24.80 5.55 464 11.013 140.095 1.20 1.62 .48 21.70 6.50 465 11.008 140.095 1.44 1.25 .25 28.30 5.30 466 10.970 140.097 1.40 1.29 .20 29.30 4.55 467 10.967 140.097 1.63 1.42 .19 28.80 3.83 468 11.025 140.102 <20 .62 1.49 1.50 .21 30.80 4.30 469 11.013 140.105 1.56 1.17 .26 27.50 5.43 470 11.017 140.115 1.49 1.12 .30 27.00 5.95 471 11.015 140.118 1.59 1.29 .21 27.70 4.72 472 11.015 140.118 1.55 1.23 .29 28.60 5.34 473 10.927 140.135 1.64 1.29 .22 28.80 4.87 474 10.927 140.135 1.75 1.33 .27 29.60 5.40 475 10.965 140.148 1.63 1.26 .25 28.80 5.19 476 10.950 140.158 1.03 .63 .50 23.40 10.45 477 10.990 140.182 <20 .77 1.87 1.22 .36 30.60 5.75 479 10.990 140.193 20-50 5.17 1.63 .97 .38 27.80 7.70 480 10.990 140.193 20-50 5.61 1.55 .91 .38 26.50 7.64 481 11.073 139.982 9.09 482 11.050 139.983 6.87 483 11.010 139.990 5.62 484 11.073 139.992 4.65 485 11.053 139.992 9.27 486 11.023 139.998 2.24 487 11.093 139.995 5.81 488 11.047 140.000 2.17 489 11.067 140.000 NOb 490 11.050 140.000 4.25 491 11.050 140.000 12.12 1.47 1.37 .16 30.30 4.00 492 11.023 140.000 2.20 493 10.950 140.000 6.37 494 10.917 140.000 .12 495 11.100 140.017 2.00 496 11.100 140.017 .60 1.45 1.40 .17 26.40 4.70 497 11.100 140.017 1.12 1.35 .93 22.90 9.95 498 11.067 140.017 12.75 1.44 1.07 .20 30.20 5.00 499 11.075 140.002 4.30 500 11.065 140.002 4.90 501 11.055 140.002 3.70 502 11.040 140.003 4.80 503 11.022 140.004 6.40 504 11.028 140.004 3.90 505 11.043 140.012 5.20 506 11.042 140.022 7.30 See footnote at end of table. 56 TABLE B-10. - Subarea Bill — location, abundance, and analytical data — Continued Index North latitude West longitude Population, 1 pet Abundance , kg/m 2 Analysis, wt pet, dry basis No. Ni Cu Co Mo Mn Fe 507 11.044 140.038 6.00 508 11.047 140.060 6.20 509 11.018 140.083 1.00 510 11.035 140.116 4.50 * 511 11.034 140.146 8.10 512 10.983 140.163 6.90 513 9.217 139.700 1.28 .98 0.20 22.70 5.40 514 9.100 139.750 1.32 1.14 .38 22.80 6.65 515 8.850 139.833 1.41 1.35 .25 28.90 5.42 516 9.000 139.850 1.36 1.17 .21 29.80 4.50 517 8.783 139.883 1.28 1.32 .20 11.60 518 8.783 139.883 .94 .94 .26 16.80 6.70 519 8.950 139.883 1.47 1.46 .20 0.07 22.90 5.04 520 8.833 140.300 1.00 .45 .12 30.10 1.78 5.27 NC 1.45 0.21 1.24 0.22 0.25 0.07 0.07 NC 27.20 2.98 5.18 Standard deviation.... 1.37 74 75 75 75 1 74 75 NC Not calculated. NOb No nodules observed in photographs or no nodules recovered in samples. 1 Amount of seafloor covered with nodules. NOTE. — Blank indicates no information available. TABLE B-ll. - Study area B — location, abundance, and analytical data outside subareas Index North latitude West longitude Population, 1 pet Abundance , kg/m 2 Analysi s , wt pet, dry basis No. Ni Cu Co Mo Mn Fe 400 8.983 137.683 0.11 0.11 0.05 2.50 8.20 401 9.950 137.783 1.54 1.15 .19 0.08 33.00 4.08 402 9.943 137.802 1.54 1.15 .18 .08 24.24 4.97 403 8.350 138.783 .62 .47 .14 405 13.667 137.500 2.93 406 11.717 142.800 4.30 521 13.033 139.083 1.73 1.51 .38 28.90 522 13.033 139.083 1.24 1.09 .34 24.30 6.50 618 12.283 140.430 1.56 1.22 .19 29.90 4.43 619 10.983 142.617 1.23 .96 .31 .03 17.00 6.40 620 10.012 143.312 1.25 1.51 1.34 29.20 4.53 621 10.010 143.317 18.12 1.52 1.12 .25 31.80 4.60 622 10.008 143.320 21.25 1.49 1.07 .18 30.10 5.10 9.57 NC 1.28 0.49 1.02 0.40 0.22 0.10 0.06 0.03 25.09 9.22 5.42 Standard deviation. . . . 1.34 Number of 5 11 11 10 3 10 9 NC Not calculated. 1 Amount of seafloor covered with nodules NOTE. — Blank indicates no information available. 57 TABLE B-12. - Subarea CI — location, abundance, and analytical data Index No. North latitude West longitude Population, * pet Abundance , kg/m 2 Analysi s, wt pet, dry basis Ni Cu Co Mo Mn Fe 662 16.008 124.993 NPr 663 14.983 125.000 13.88 1.32 1.26 0.23 28.20 5.62 664 15.067 125.000 20.00 1.41 1.21 .28 0.07 28.80 6.75 665 14.967 125.017 1.40 1.17 .22 29.90 5.60 666 16.033 125.017 1.46 1.13 .26 .07 28.40 7.15 667 15.255 125.025 >50 13.70 668 14.933 125.067 12.50 1.38 1.05 .30 .07 28.60 7.00 669 15.033 125.067 15.62 1.43 1.15 .29 .07 28.20 7.05 670 15.000 125.067 27.75 1.42 1.19 .29 .07 27.70 7.13 671 15.067 125.083 NPr 680 15.110 125.932 NPr 681 15.230 125.943 >50 10.00 682 14.765 125.977 NPr 683 15.262 126.000 1.37 1.14 .26 .06 29.09 5.99 684 14.257 126.023 1.38 1.20 .26 .06 27.30 6.26 685 15.243 126.028 >50 15.00 686 15.242 126.047 >50 29.00 687 15.135 126.063 >50 17.00 688 15.242 126.065 20-50 15.00 689 15.130 126.078 >50 16.00 692 15.135 126.092 >50 13.00 693 15.140 126.105 20-50 11.00 695 15.192 126.112 NPr 699 15.778 126.187 NPr 702 14.908 126.622 .58 .36 .15 14.40 11.06 703 14.045 126.663 NOb 704 16.012 126.772 1.20 .78 25.10 6.92 710 15.000 125.000 1.22 1.31 .15 29.70 5.25 711 14.967 125.000 1.38 1.27 .25 28.60 6.30 712 14.967 125.000 1.40 1.17 .22 29.90 5.60 713 15.033 125.083 1.45 1.33 .22 27.90 6.35 735 15.104 125.950 >50 11.80 736 15.252 125.987 20-50 4.60 737 15.220 125.920 >50 9.12 738 15.241 126.040 >50 15.20 739 15.137 126.090 >50 12.20 740 15.231 125.974 4.90 1.34 1.21 .24 28.40 6.16 741 15.242 126.043 8.84 1.37 1.10 .28 27.50 6.68 742 15.257 125.988 1.79 1.36 1.31 .24 28.20 5.68 743 15.243 126.026 6.51 1.29 .83 .28 22.60 7.54 744 15.217 125.932 8.93 1.33 .95 .28 26.10 7.02 745 15.182 125.893 12.35 1.39 1.10 .36 28.10 6.49 746 15.205 125.868 9.95 1.19 .84 .31 26.20 8.09 747 15.207 125.953 8.48 1.26 .80 .30 26.20 8.16 748 15.188 126.025 1.34 1.02 .22 26.30 6.25 See footnote at end of table, 58 TABLE B-12. - Subarea CI — location, abundance, and analytical data — Continued Index North latitude West longitude Population, 1 pet Abundance , kg/m 2 Analysi s, wt pet, dry bas. Ls No. Ni Cu Co Mo Mn Fe 749 15.190 126.037 6.49 1.18 0.97 0.24 27.50 6.37 750 15.195 126.065 13.81 1.26 1.06 .29 27.20 6.06 751 15.193 126.098 11.44 1.26 .81 .29 27.20 6.06 752 15.137 126.107 10.21 1.33 .89 .27 26.60 6.92 753 15.137 126.062 15.23 1.32 .92 .28 27.00 6.32 754 15.140 126.045 8.81 1.31 .87 .24 25.70 6.63 755 15.132 125.990 9.24 1.23 .60 .36 23.80 9.51 756 15.138 125.955 16.84 .95 .47 .31 15.70 8.87 757 15.105 125.957 10.29 1.04 .46 .34 23.40 10.34 758 15.140 126.015 1.30 .94 .23 25.10 6.17 759 15.098 126.035 16.06 1.17 .73 .24 19.90 6.27 760 15.108 126.047 12.15 1.26 .93 .26 26.50 6.15 761 15.000 125..433 1.00 .82 .38 22.20 9.70 762 15.067 125.000 20.00 1.54 1.41 .26 31.10 6.29 763 14.983 125.000 15.00 1.46 1.40 29.20 5.64 764 14.967 125.000 11.88 1.53 1.36 .26 29.40 6.08 765 14.933 125.067 15.00 1.41 1.09 .27 29.90 6.59 766 15.033 125.067 17.50 1.49 1.21 .27 29.70 6.76 767 15.050 125.083 1.43 1.20 .25 29.50 5.78 768 15.033 125.083 1.51 1.26 .24 30.60 5.29 769 15.000 125.000 1.66 1.09 .24 25.00 6.22 770 15.760 126.008 1.19 1.08 26.50 5.60 771 15.245 126.535 1.41 1.09 .25 25.70 6.47 772 15.778 126.187 1.51 1.26 .27 28.80 5.84 773 15.297 125.922 9.80 1.38 .99 .32 27.30 8.30 774 15.297 125.473 2.60 1.43 .98 .29 27.20 8.09 775 15.343 125.447 7.70 1.33 1.21 .30 26.30 6.30 776 14.217 125.487 1.46 1.16 .19 28.10 5.50 777 15.132 125.132 1.21 .95 .18 25.20 7.82 778 15.043 125.138 1.39 1.08 .23 29.80 7.47 779 15.150 125.142 1.38 1.07 .22 31.10 7.21 780 15.148 125.162 1.04 .56 .37 26.00 12.80 781 15.100 125.167 1.17 .84 .21 25.10 7.58 782 15.000 125.067 28.75 1.45 1.19 .25 31.10 6.60 783 15.778 126.187 1.50 1.36 .26 26.60 5.96 784 15.233 126.500 1.51 1.05 .27 27.20 6.86 785 16.025 125.672 9.21 786 16.083 124.967 4.25 787 14.242 124.975 1.41 1.12 .28 26.50 6.75 788 16.050 124.983 3.50 1.02 .76 20.60 7.75 789 16.017 124.983 1.88 1.58 1.17 28.20 6.15 790 15.033 125.000 1.25 791 15.255 125.025 11.50 792 14.967 125.067 .62 793 15.067 125.083 1.30 1.24 .23 23.20 5.95 See footnote at end of table, 59 TABLE B-12. - Subarea CI — location, abundance, and analytical data — Continued Index North latitude West longitude Population, * pet Abundance , kg/m 2 Analysi s, wt pet, dry basis No. Ni Cu Co Mo Mn Fe 794 795 797 798 799 800 801 15.340 15.327 15.758 15.275 15.273 15.277 14.292 125.902 125.907 126.167 125.523 126.867 126.153 126.257 <20 <20 5.47 10.94 14.11 8.88 14.67 11.67 NC 59 1.33 0.17 64 1.04 0.23 64 0.26 0.04 60 0.07 0.00 7 26.79 3.23 64 6.91 Standard deviation. . . . 1.40 64 NC Not calculated. NOb No nodules observed in photographs or no nodules recovered in samples. NPr Nodules present, no additional information available. 1 Amount of seafloor covered with nodules. NOTE. — Blank indicates no information available. TABLE B-13. - Subarea CII — location, abundance, and analytical data Index North latitude West longitude Population, * pet Abundance , kg/m 2 Analysi s, wt pet, dry basis No. Ni Cu Co Mo Mn Fe 650 14.546 117.270 1.40 0.92 0.17 28.30 9.60 651 14.557 117.303 1.26 .95 .10 27.30 9.40 652 14.557 117.303 1.45 .96 .19 28.20 8.40 653 14.533 117.320 1.23 .87 .26 24.60 10.40 654 14.530 117.327 1.40 .91 .19 26.60 8.70 655 14.527 117.353 1.51 .93 .17 29.20 8.30 656 14.612 117.360 1.37 1.01 .14 29.60 7.20 706 14.438 117.152 1.41 1.16 .16 28.90 6.63 707 14.207 118.875 1.18 .99 .21 23.70 7.26 715 14.970 116.228 1.42 .90 .11 0.06 31.00 6.66 718 14.767 116.933 <20 1.43 .97 .14 28.50 7.20 719 14.433 117.200 1.89 1.06 .08 .08 26.80 10.30 720 14.530 117.258 NPr 721 14.553 117.287 1.45 1.02 .20 .08 29.80 8.00 722 14.577 117.310 1.52 1.02 .17 .06 28.50 8.00 723 14.587 117.337 1.14 .72 .18 .06 24.80 10.85 724 14.573 117.367 NPr 727 14.585 118.555 1.24 .90 .18 .06 26.90 8.80 1.39 0.18 16 0.96 0.10 16 0.17 0.04 16 0.07 0.01 6 27.67 2.02 16 8.48 Standard Number of 1.34 16 NPr Nodules present, no additional information available. * Amount of seafloor covered with nodules. NOTE. — Blank indicates no information available. 60 TABLE B-14. - Study area C — location, abundance , and analytical data outside subareas Index North latitude West longitude Population, 1 pet Abundance , kg/m 2 Analysis , wt pet, dry basis No. Ni Cu Co Mo Mn Fe 657 15.093 120.748 1.26 1.13 0.18 27.60 6.9C 658 14.585 121.062 1.43 1.01 .21 28.80 6.9C 659 14.603 121.032 1.32 1.03 .22 27.30 6.5C 660 14.247 123.703 1.39 1.19 .23 28.10 6.3C 661 14.917 124.200 1.22 1.39 .35 0.04 22.50 7.9: 672 13.052 125.480 .98 1.03 .21 .04 25.00 4.35 673 12.327 125.500 NPr 674 12.323 125.500 9.25 1.40 1.15 .13 .08 29.20 6.43 675 12.342 125.500 NPr 676 12.337 125.502 NPr 677 12.330 125.507 NPr 678 12.327 125.507 NPr 679 16.583 125.583 20-50 1.16 .72 .30 22.00 8.6C 690 13.683 126.083 NPr 691 13.680 126.083 NPr 694 13.755 126.112 1.37 .95 28.10 7.26 696 13.757 126.118 1.41 1.20 29.10 5.88 697 13.760 126.118 NPr 698 13.762 126.123 NPr 700 13.780 126.228 20-50 701 13.773 126.228 20-50 705 13.257 126.800 14.11 1.21 1.01 .20 .06 22.80 6.08 708 13.905 120.813 1.40 1.16 .27 28.20 7.06 709 12.530 122.458 1.29 1.39 .19 29.80 5.20 714 12.275 120.158 .62 .42 .42 22.00 19.80 716 13.673 122.307 1.11 1.05 .25 .05 22.70 7.65 717 13.765 116.630 725 11.233 117.483 10.66 1.46 1.23 31.70 6.39 726 13.450 118.417 .99 1.10 .55 31.50 4.20 728 11.427 118.757 NPr 729 14.478 119.318 20-50 16.40 730 14.837 119.663 731 13.500 119.700 732 14.835 120.142 733 12.330 122.288 1.40 1.45 .15 34.90 4.32 734 12.298 122.418 1.08 1.06 .20 25.80 4.90 796 13.750 126.183 <20 12.61 NC 1.24 0.21 1.09 0.23 0.25 0.11 0.05 0.02 27.22 3.65 6.98 3.34 Standard deviation. . . Number of samples.... 4 19 19 16 5 19 19 NC N< 3t calculated. NPr ] Nodules present, no additional ii ^formation a ivailab tie. ^Amoui at of seafloor covered with nodu les. NOTE.- —Blank ii idicates n< 3 information available. V f 5° 84 •* X*' D o . -. %b, *° • * * A V 4< : .<& ■'- J -: ■■ Subarea boundary DOMES Site B No nodules observed or recovered Nodules present, no assays Ni plus Cu<1.8 wt pet Ni plus Cu 1.8-2.3 wt pet Ni plus Cu >2.3 wt pet Numbers next to symbols coincide with index numbers in Appendix B 50 Scale, km Bathymetric contours in meters below mean sea level 8°L 144° 141 » 140" 139° Station locations, nodule occurrences, and grades in study area B. Topography adapted from Heezen (25). I HECKMAN BINDERY INC. A" FEB 84 152° FIGURE 5. • Station locations, nodule occurrences, and grades in study area A. Topography adapted from Heezen (25). \* p <* **TT** .0*" ^> '••» 4.V e> \* .. * "°"° «fev* V ' . . s * .0* &"» *+*>* HECKMAN BINDERY INC. rcj N. MANCHESTER, INDIANA 46962 1 1 LIBRARY OF CONGRESS II II III II II I IW ™X fjr 002 959 891 5 m H Ml ■