MANUAL OF M IN ERALO GY, INCLUDING OBSERVATIONS ON MINES, ROCKS, REDUCTION OF ORES, AND THE APPLICATIONS OF THE SCIENCE TO THE ARTS, WITH 260 ILLUSTRATIONS, DESIGNED FOR THE USE OF SCHOOLS AND COLLEGES BY JAMES D. DANA, A. M., Member of the Soc. Caes. Nat. Cur. of Moscow, the Soc. Philomathique et Paris, the American Academy of Arts and Sciences at Boston, etc.; Author of a " System of Mineralogy." NEW HAVEN: HENRY Hi. PECK. 1376. Entered according to Act of Congress, in the year 185T, by DUIRRIE & PECK, In the Clerk's Office of the District Court of Connecticut. PREFACE TO THE FIRST EDITION. IN the preparation of this Manual, the author has endeavored to meet a demand often urged, by making it, as far as possible, practical and American in character. Prominence has been given to the more common species, while others are but briefly noticed in smaller type, or are mentioned only by name. The uses of minerals and their modes of application m the arts have been especially dwelt upon. The value of ores in mining, their modes of reduction, the yield of mines in different countries, and the various applications of the metals, have been described as minutely as was consistent with the extent of the work. The various rocks are in like manner included. At the same time, the subject has been presented with all the strictness of a scientific system. The classification adopted throws together ores of the same metal, and associates the earthy species as far as possible in natural groups. This order is preferred by very many teachers of the science, and has advantages which for mang purposes counterbalance those of a more perfectly natural system The account of the ores of each metal is preceded by a brief state.ment of their distinctive characters; and after the descriptions. there follow general remarks on mines, metallurgical processes, ana other useful information. As the rarer mineral species are not altogether excluded, but are briefly mentioned each in its proper place in the system, the student, should he meet with them, will be guided by the Manual to some knowledge of their genera! characters, and aided in arranging them n his cabinet IV Thelst of American localities appended to the work, the descriptiols of mineralogical implements, and the notice of foreign weights, measures and coins, will be found convenient to the student. The author must refer to his larger work for more minute information on the localities of minerals and the associations of speciesfor full lists of synonyms-a more complete account of crystal-' ograplry and its details, and more numero:s analyses, with their authorities. * * * * * * PREFACE TO THE NEW EDITION. IN bringing this Manual up to the present state of the science, numerous changes and additions have been required. The arrangement, however, remains unaltered, except in the order of some of the metals. The Table of American localities has been nearly doubled in length, giving it the completeness it has in the author's "Treatise on Mineralogy." A chapter has also been added on the chemical composition and formulas of minerals, in which the subject is explained with simple illustrations, and a list of the more prominent species with their chemical formulas is given, following the order of the descriptive part of the work. Nzw HAVEN, 1857. TABLE Or CONTENTS. CaPf I.-GENERAL CHARACTERISTICS OF MINERALS,.. 13 CHAP. II.-CRYSTALLOGRAPHY: OR THE STRUCTURE OF MINERALS, i9 Fundamental forms of crystals,.... 2: Cleavage,....... 3: Secondary forms,... 34 Compound crystals,... 42 Dimorphism,..... 44 Irregularities of crystals,...... 45 Measuring angles of crystals,.. 47 Massive minerals,.... 52 Columnar structure,.... 52 Lamellar and granular structure,... 53 Pseudomorphous crystals.... 54 CHAP. III.-PHYSICAL PROPERTIES OF MINERALS. Luster,...... 55 Color,....... 56 Diaphaneity,-Refraction, and Polarization,. 58 Phosphorescence,...... 61 Electricity and Magnetism,..... 62 Specific gravity,.... 63 Hardness,....... 64 State of aggregation-Fracture,... 65 Taste-Odor....... 66 CHAP. IV.-CHEMICAL PROPERTIES OF MINERAL,. 66 Action of acids,.... 66 Blowpipe,....... 67 CHAP. V.-CLASSIFICATION OF MINERALS,.. 71 CHrP. VI.-DESCRIPTION OF MINERALS,... 76 1. Gases,...... 76 2. Water,....... 78 3. Carbon and compounds of carbon,. ~. 80 4. Sulphur,...... 97 5. Haloid minerals,.....100 1. Ammonia,..... 100 2. Potassa,.... 101 3. Soda,.... 102 4. Baryta,. 108 5. Strontia,....110 6. Lime,.... 112 7. Magnesia..,. 123 8. Alumina,....127 1* vi CONTENTS. 6. Earthy minerals, (silicates or aluminates,).132 1. Silica,......132 2. Lime,... 141 3. Magnesia,...... 143 1. Hydrous silicates,.... 143 2. Anhydrous silicats.... 150 4. Alumina,...... 158 1. Uncombined,.... 158 2. Combined with other oxyds,.. 160 3. Hydrous combinations with silica,. 161 4. Anhydrous combinations with silica,. 72 5. Combinations of a silicate and fluorid, 94 6. Combination of a silicate and sulphate,. 196 7. Silicate with a chlorid. 5. Glucina,.... 197 6. Zirconia....... 200 7. Thoria,...... 202 7. Metals and metallic ores,. 202 1. Easily oxydizable metals,.... (6 1, 2, 3. Cerium and Ytrium, Lanthanum,. 206 4. Titanium,.... 209 5. Tin,...... 213 6. Molybdenum,.... 217 7. Tungsten,.... 218 8. Vanadium,.... 219 9. Tellurium,.. 219 10. Bismuth,..... 220 11. Antimony,.... 222 12. Arsenic,..... 225 13. Uranium,..... 228 14. Iron,..... 229 15. Manganese,.. 258 16, 17. Chromium, Nickel,... 262 18. Cobalt,.....266 19. Zinc,...... 269 20. Cadmium,.... 276 21. Lead,.... 276 22. Mercury,.. 287 23. Copper,... 290 2. Noble Metals. 1. Platinum, Iridium, Palladium,.. 808 2. Gold,..... 312 3. Silver,....323 CHAP. VII.-CHEMICAL COMPOSITION AND FORMULAS OF MINERALS, 336 CAAP. VIII.-RocKs OR MINERAL AGGREGATES,. 348 CHAP. IX.-CATALOGUE OF AMERICAN LOCALITIES OF MINERALS,. 374 BRIEF NOTICE OF FOREIGN MINING REGIONS,... 403 MINERALOGICAL IMPLEMENTS,..... 408 WEIGHTS, MEASURES AND COINS,.... 410 TABLES FOR THE DETERMINATION OF MINERALS,.. 414 INDEX,.... 441 GLOSSARY AND INLJEX OF TERMS.* ACICULAR, [Lat. acus, a needle,] 53. Assay. The material under chem. Adamantine, 56. ical or blowpipe examination. Adit. [Lat. aditus, an entrance.] Astringent, 66. The horizontal entrance to a Asteriated. [Gr. aster, star.] Havmine. ing the appearance of a stai Alkali An oxyd having an acrid within. taste, and caustic; as potash, Augitic. Containing augite. soda. Auriferous. [Lat. aurum, gold.) Alkaline. Like an alkali. Containing gold. Alliaceous, [Lat. allium, garlic,] 66. Axes, 24; of double refraction, 59. Alloy. A mixture of different metals (excluding mercury) by fusion Basaltic, 339. together. Also, the metal used Bath stone. A species of limestone; to deteriorate another metal by called also Bath oolite; named mixture with it. from the locality, in England. Alluvial. [Lat. alluo, to wash over.] Bevelment, beveled, 35. Of river or fresh-water origin. Bitter, 66. Amalgam. [Gr. malagma, a sof- Bittern, 106. tened substance.] A compound Bituminous. Containing bitumen; of mercury and another metal. like bitumen. Amalgamation, 326. Bladed. Thin blade-like. Amorphous, [Gr. a, not, and morphe, Blast furnace, 233. shape,] 54. Blowpipe, 67; tests, 69,70: impleAmygdaloidal, 339. ments, 68, 69. Anhydrous. [Lat. a, not, and Blue-jo'n. Name for fluor spar, hudor, water.] Containing no used in Derbyshire, where it often water. has a bluish-purple color. Arborescent. [Lat. arbor, tree.] Botryoidal, [Gr. botrus, abunch of Branching like a tree. grapes,] 53. Arenaceous. [Lat. arena, sand.] Boulder, bowlder. Loose rounded Consisting of, or having the gritty mass of stone. nature of, sand Breccia. Argentiferous. [Lat. argentum, Brittle, 53, 65. silver.] Containing silver. Argillaceous. [Lat. argilla, clay.] Calcine. [Lat. calx, burnt limeLike clay; containing clay. stone.] To heat, in order to drive Arsenical odor, 66. off volatile ingredients, and make Asparagus green. Pale green, with easy to be broken or pounded. much yellow. Calcination. The process of calAssay. [Same etymology as essay.] cining. To test ores by chemical or blow- Carat, 82 pipe examination; said to be in Carbon. Pure charcoal. the dry way, when done by means Carbonate. A salt containing carof heat, (as in a crucible,) and in bonic acid. Carbonated; conthe wet way, when by means of taining carbonic acid, as carboacids and liquid tests. nated springs. * The number after a word signifies the page where it is explained, The etymo!oSy i; given in brackets, wheilever it was deemed important Vi1I GLOSSARY AND INDEX OF TERMS. Carbonize. To convert into char- Delicate delineations branching coal. like a tree; due to infiltration o! Carburet. A compound of an ele- oxyd of iron or manganese. ment with carbon, not acid. Density. Specific gravity. Catalan forge, 237. Desiccate. To dry, to exhaust of Celandine green. Green with blue moisture. and gray; from the plant called Diaphaneity, 58. celandine. Dichroism, 57. Cementation, 238. Dimetric system, 32. Chalybeate. Impregnated with Dimorphism, 44. iron, 80. Divergent, 53. Chert. A siliceous stone containing Disintegrate. To fall to pieces; a some lime; also, hornstone. result of exposure and partial deChlorid. Combination of an ele- composition. ment with chlorine. Disseminated. Scattered through Chloritic. Containing chlorite. a rock or gangue. Chromate. A salt containing chro- Dodecahedron, rhombic, 25; isosmic acid. celes,39, fig. 65; pentagonal 37; Cinereous. [Lat. cinis, ashes.] scalene, 40. Resembling ashes. Dolomitic. Pertaining to dolomite. Cleavage 33. Dressing of ores. The picking and Coke, 90. sorting of ores, and washing preColumnar, 52. paratory to reduction. Compound crystals, 42. Drusy, 54. Conchoidal, 65. Dull, 56. 3oralloidal. Having a resemblance to coral. Earthy. Soft like earth, and withCretaceous. [Lat. creta, chalk.] out luster. Pertaining to chalk. Ebullition. The state of boiling. Cropping out. The rising of layers Effervescence, 67. of rock to the surface. Effloresce. To change to a state Crucible. [Lat. crux, a cross.] A of powder, by exposure; arises pot made of earth or clay for from the escape of water. melting, or reduction. Elastic, 53, 65. Electricity ofminCruciform, [Lat. crux, a cross,] erals, etc., 62. 43. Elements, 72. Crystal, [Greek krustallos, ice,] 19; Ellipsoid, 42. systems of crystallization, 24, Elutriation. [Lat. elutrio,to poun 32. from one vessel to another.] Cube, 25. Mixing a powdered substance Cupel, cupellation, 317, 328. (as powdered flint) with water, Cupreous. [Lat. cuprum, copper.] and then after the coarser partiContaining copper. cles have subsided, carefully deCurved crystals, 42. canting the liquid and putting it Decrepitate. To crackle and fly away to settle, in order to obtain apart when heated. the impalpable powder which is Deflagrate. To burn with vivid finally deposited. combustion. Elvan. In Cornwall, the granite Deliquesce. To change to a liquid, masses forming broad veins in on exposure; arising from the the killas, and containing the attraction of moisture. stockwerks. Dendrites. [Gr. dendron, tree.] Enamel. A glass having an ap cl.)so \vsv.A'\, 1\D X OF rERMS. ix pearance like poi,_eaina, or like Granular. Consisting of grains. the surface of a tooth. Granulate; to reduce to grains. Evaporate. To become a vapor; to cause to become a vapor. Hackly, 65. Even fracture, 65. Hardness, scale of, 64. Exfoliate. To separate into thin Hemihedral forms, 37. leaves, or to scale off. Hepatic. [Gr. hepar, liver.] Hav. ing an external resemblance to Fault. Dislocation along a fissure, liver. as often in coal beds, 87. Hexagonal prism, 27. Feldspathic. Containing feldspar Hexagonal system, 33. as a principal ingredient; con- Homogeneous. Of the same texsisting of feldspar. ture and nature throughout. Ferruginous. [Lat. ferrum, iron.] Hyacinth red. Red with yellow Containing iron. and some brown. Fetid, 66. Hyaline. [Gr. hualos, glass.] ReFibrous, 52. sembling glass in transparency Filament. A thread-like fiber. and luster. Finery furnace. A furnace used Hydrated. [Gr. hudor, water.] in the conversion of cast iron into Containing water. bar iron. Filiform, [Lat. ilum, a thread,] 53. Ignition. [Lat. ignis, fire.] The Flexible, 53, 65. state of being so heated as to give Fluate. Containing fluoric acid. out light; at a red or white heat. Flux, [Lat. fluo, to flow,] 69. Impalpable, 53. Foliaceous, 53. Implanted crystals. Attached by Forceps, Platinum, 69. one extremity. Fracture of minerals, 65. Incandescence. White heat. Friable. Easily crumbling in the Incrustation. A coating of minera; fingers. matter. Fundamental forms, 23. Indurated. Hardened or solidified. Furnace, blast, 233; reverberatory, Infiltrate. To enter gradually, as 327; Catalan, 237. water, through pores. Infusible. In mineralogy, not fusiGallery. A horizontal passage in ble by means of the simple blowmining. pipe. Gangue, 204. Inspissate. To thicken. Gelatinize, 67. Inturnesce. To froth. Geniculate. [Lat. genu, knee.] Investing Coating or covering, as Bent at an angle, 43. when one mineral forms a coatGeode. [Gr. geodes, earth-like.] ing on another. A cavity studded around with Irised. [Lat. iris, rainbow.] Havcrystals or mineral matter, or a ing the colors of the spectrum. rounded stone containing such a Iridescence, 57. cavity. Isomorphism, isomorphous, 74. Glance. [Germ. glanz, luster.] Certain lustrous metallic sulphu- Juxtapose. To place contiguous. rets of dark shades of color. Glimmering. Glistening, 56. Killas. In Cornwall, the schistose Globular, 53. rock in which the lodes occur. Goniometer, common, 47; reflecting. 50. Lanmilar, 53. X GLOSSARY AND INDEX OF TERMS. Lapidification. [Lat.lapis, ast 1 Massive. Compact, and havingno The process of changing to sty'. regular form. Lapilla. Small volcanic cinders. Matrix. [Lat. matrix, from mater, Lavende -blue. Blue with some mother.] The rock or earthy red and much gray. material containing a mineral or Leek-green. The color of the metallic ore. leaves of garls Metallic, 55, 56. Metallic-pearly Lenticular. Thin, witn acute eages 55. Metallc-adamantine, 56. something like a lens, except that Metalliferous. Yielding metal. the surface is not curved. Metallurgy. [Gr. metallon, and Leucitic. Containing leucite. ergon, work.] The science of Levigation. [Lat. levis,light.] The the reduction of ores. process of reducing to a fine Micaceous, 53. powder. Mineralized. Changed to mineral Liquation. [Lat. liquo, to melt.] by impregnation with mineral The slow fusion of an alloy, by matter. Also being disguised in which the more fusible flows out character by combination with and leaves the rest behind, 328. other substances; thus used with Lithographic stone. A compact regard to metals when in combigrayish or yellowish-gray lime- nation with sulphur, arsenic, carstone of very even texture and bonic acid, or anything that affects'onchoidal fracture; used in lith- their malleability and other qualography. That of Solenhofen, ities. near Munich, is most noted. Molecules, 42. Lathology. [Gr. lithos, stone, and Molybdate. A salt containing logos, a discourse.] Mineralogy. molybdic acid. Lixiviate. [Lat. lixivium, lye.] Monoclinate, 33. To form a lye, by allowing water Monometric, 32. to stand upon earthy or alkaline Mountain limestone. A limestone material, and draining it off be- of the lower part of the coal selow, after it has dissolved the sol- ries; called also carboniferous uble ingredients present. limestone. Lode. [Sax. loedan, to lead.] In Muffle, 317. mining, a vein of mineral substance; usually a vein of metallic Nacreous. Like pearl. ore. The lode is said to be dead Native metal, 202. when the material affords no Nitrate. A salt containing nitric metal, acid. Lodestone, 217. Nitriary, 102. Nucleus. The center particle or Macle. A compound crystal, or one mass around which matter is aghaving a.esselated structure. gregated. Magnesian. Containing magnesia. Magnetism -f minerals, 63. Ochreous. Like ocher. Malleable, [Lat. malleus, a ham- Octahedron, pp. 23, 25, 26. mer,] 65.. Octahedral. Having the form of a Mammillary, [Lat. marmmilla, a octahedron. little teat,j 53. Odor of minerals, p. 66. Manganesian. Containing man- Oolite. [Gr. oov, egg,] p. 349. ganese. Opalescence, p. 57. Marly. Having the nature of marl; Opaline. Like eoal. containing marl. Opaiized. Changel to opal. GLOSSARY AND INDEX OF TERMS. xi Opaque, p. 58. Quartzose. Containing quartz as Ore, 202. Also, by niners, a dis- a principal ingredient. seminated ore and the including stone together; the term met- Radiated, 53. al is often used for the pure ore. Rake-vein. A perpendicular minOxyd, 73. eral fissure; Oxydizable. Capable of combining Rectangle, 24. with oxygen. Reduction of ores, 204. Oxydating flame, 68. Reduction flame, 68. Refraction, 58. Pearly 55. Refractory. Resisting the actio Percolate. To pass gradually of heat; infusible. through pores. Refrigerate. To cool. Phosphorescence, 61. Regulus. The pure state of Pisolitic, [Lat. pisum, a pea,] corn- metal, as regulus of antimony. posed of large round grains or Reniform. [Lat. ren, kidney,] 53 kernels, of the size of peas. Replacement, 35. Resinous, 55. Pistachio-green. Green with yel- Resplendent. Having a brillian low, and sonme brown. luster. Plastic. Adhesive, and capable of Reticulated. [Lat. rete, a net,! being moulded in the hands. 52, 54. Plumose. Having the shape of a Reverberatory furnace, 327. plume, or feather. Rhombohedron, 27. Polarisation, 60. Riddling Jr sifting of ores. PutPolarity, 62. ting the broken or pulverized ore Polychroism, 57. in a seive, and plunging the seive Play of colors, 57. into water, by which, the whole Plutonic rocks. Granite and allied powdered material is raised by crystalline rocks. the water and the metallic part Polyhedral. [Gr. polus, many, and sinking first, may be separated hedra face.) Having many sides. to a great extent from the rest. Polymorphism, 44. Roasting. Exposing to heat in Porous. Having minute vacuities, piles, or in a furnace, and thus visible or invisible to the naked driving off any volatile ingredient. eye; a loose texture, allowing water to filtrate through. Saccharoid. [Gr. sakchar, sugar.] Porphyritic. Like porphyry, 340. Having a texture like loaf sugar. Prisms, 23. Saline, (Lat. sal, salt.) Salt like; Pseudomorphous, 54. containing common salt. Puddling Furnace. A reverbera- Salt. In chemistry, any combinatory furnace, used in converting tion of an acid with a base, 74. cast into bar iron, after the finery Scale of hardness, 64. furnace. Schlich. The finely pulverized ore Pulverize. [Lat. pulvis, dust,] to and gangue. reduce to powder. Schistose. Having a slaty structure. Pulverulent. Like a fine powder Scopiform, (Lat. scopa, a broom.) slightly compacted. Like a broom in form. Pyritous. Having the nature of Scoria, (L. scoria, dross,) 205,341 pyrites, 212. Secondary forms, 34. Sectile, 65 Pyro-electric, 62. Semitransparent, 58. Shaft. A vertical or much in Quartation, 318. dined pit, cylindrical in form. Xii GLOSSARY AND INDEX OF TERMS. Shale, 341. Shining, 56. Tertiary strata. Strata more reSilicate, 74. cent in age than the chalk, and Siliceous. Consisting of, or con- antecedent to the recent epoch. taining silex, or quartz. Tesselated, (Lat. tesselatus, cheSilky, 56. quered.) Chequered. Silurian. A term applied to the Tesseral system, (Lat. tessera, fossiliferous rocks, older than four square tile, or dice,) 32. the coal series. Tetrahedron, (Gr. tetra, four, he Slag, 205. dra, face,) 37. Smelting of iron ores, 233. Titaniferous. Containing titanium Spathic, (Germ. spath.) Like spar. Transition rocks. The older silu Spar. Any earthy mineral having rian, which were formerly sup a distinct cleavable structure and posed to contain no trace of fos some luster, as calcareous spar. sils. St.akctitic, (Gr. stalazo, to drop or Translucent, 58. distil,) 54, 116.'ransparent, 58. Stalagmite, 116. Triclinate, 33. Specific gravity, 63. Trinetric, 33. Splendent, 56. Trimorphism, 44. Splintery. Having splinters on a Truncation, truncated, 35. surface of fracture. Tufaceous. Like tufa, 347. Stamping. Reducing to coarse Tuyeres, or twiers, 234. fragments in a stamping mill. Twin crystals, 42. Stellated, (Lat. stella, star,) 52. Strata. A series of beds of rock Unctuous. Adhesive, like grease. Streak, streak-powder, 56. Ustulation. [L. ustulatus, scorchStriated. Lined or marked with ed, or partly burnt.] Roasting parallel grooves, more or less of ores. regular. Stockwerks. In Cornwall, works Veins. I s river's use, small lodes. in beds and-veins of ore. The In geology, any seams of rock works in alluvial deposits are dis- material, intnlfettiag strata crosstinguished as stream-works. wise. Sub. In composition, signifies be- Vein-stone. The genCua of a metneath; also, somewhat, or imper- al or mineral. fectly, as submetallic, means in- Verdigris-green. Gree: iciliinir perfectly metallic. to blue; the color of verdigris. qiablimation, (Lat. sublimis, high.) Vesicular. Containing smaal vi Rising in vapor, by heal, to be cuities. again condensed. Viscous, 65. Submetallic, 55. Vitreous, (Lat. vitrum, glass,) 54 Subtranslucent, 58. Vitrification. Conversion to glass Subtransparent, 58. Volatile. Capable of passing easi Subterbrand. A name given to ly to a state of vapor. Bovey coal, or brown coal. Washing of ores. Exposing ther Subvitreous, 55. after stamping, (or before if ir Sulphate. A salt containing sul- fragments,) to running water phuric acid. which carries off the earthy ma Sulphurcous, 66. terial, it being lighter than the Sulphuret. Combination of a met- ore. al with sulphur. Zeolitic. Having the nature of a Tarnish, 57. zeolite. 163. MINERALOGY. CHAPTER I. GENERAL CHARACTERISTICS OF MINERALS. Relations of the three Departments of Nature. Viewing the world around us, we observe that it consists of rocks, earth or soil, and water; that it is covered with a large variety of plants, and tenanted by myriads of animals. These three familiar facts lie at the basis of three primary branches of knowledge. The animals, of whatever kind, from the animalcule to man, give origin to that branch of science which is called Zoology; the various plants, to the science of Botany; and the rocks or minerals, to Mineralogy. The first two of these departments embrace all natural objects that have life, and treat of their kinds, their varities of structure, their habits, and relations. The third branch of knowledge, Mineralogy, relates to inanimate nature. It describes the kinds of mineral material forming the surface of our planet, points out the various methods of distinguishing minerals, makes known their uses, and explains their modes of occurrence in the earth. Importance of the Science of Mineralogy. To the unpracticed eye, the costly gem, as it is found in the rocks, often seems but a rude bit of stone; and the most valuable ores may appear worthless, for the metals are generally so disguised that nothing of their real nature is seen. There is an ore of lead which has nearly the color and bister of Glauber salt; an ore of iron that looks like sparry limestone - an ore of silver that might be taken for lead ore, and an other that resembles wax. These are common cases, an What classes of natural objects exist? Of what does Zoology treat What Botany? Of what does Mineralogy treat? What advantage result from the study of minerals? 9 i4 GENERAL CHARACTERISTICS OF MINERALS. consequently much careful attention is required of the student to make progress in the science. Moreover, a great proportion of the mineral species are of no special value, and they occur under so many forms and colors that close study is absolutely necessary in order to be able to distinguish the useless, and avoid being deceived by them; for such deceptions are common and often lead to disastrous consequences in mining. The science of Mineralogy is, therefore, eminently prac. tical. Moreover, the very existence of many of the arts of civilized life, depends upon the materials which the rocks afford. Besides the metals and metallic ores, we here find the ingredients for many common pigments, and for various preparations used in medicine; also the enduring material so valuable for buildings and numberless other purposes: moreover, from nthe rocks comes the soil upon which we are dependent for food. At the same time, the student of Mineralogy who is interested in observing the impress of Infinite wisdom in nature around him, finds abundant pleasure in examining the forms and varieties of structure which minerals assume, and in tracing out the principles or laws which Creative power has established even throughout lifeless matter, giving it an organization, though simple, no less perfect than that characterizing animate beings. What is a Mineral? It has been remarked that Mineralogy, the third branch of Natural History, embraces every thing in nature that has not life. Is, then, every different thing not resulting from life, a mineral? Are earth, clay, and all stones, minerals? Is water a mineral? All the materials here alluded to properly belong to the mineral series. The minute grains which make up a bank of clay or earth, are all minerals, and if their characters could be accurately ascertained, each might be referred to some mineral species. It is evident, however, that the clay itself, unless the grains are all of one kind, is not a distinct species, though mineral in composition: it is a compound mass or an aggregate of different mineral grains; and this is true of all ordinary soil and earth. In the same manner very many rocks are aggregates of two or more minerals in ntimate union. Mineralogy distinguishes the species, and nables us to point out the ingredients which are mixed in the onstitution of such rocks. It searches for specimens that Is clay a mineral? What is the nature of many rocks? GENERAL CHARACTERISTICS OF MINERAIS. 15 are pure and undisguised, ascertains their qualities and their varieties, and thus prepares the mind to recognize them under whatever circumstances they may occur. a ater has no qualities which should separate it from the mineral kingdom. All bodies have their temperature of fusion; lead melts at 612~ F.; sulphur at 226~ F.; water at 32~; mercury at -39~. No difierence therefore of this kind can limit the mineraldepartments. ce is as properly a rock as limestone; and were the temperature of our globe but a little lower than it is, we should rarely see water except in solid crystal-like masses or layers. Our atmosphere, and all gases occurring in nature, belong for the same reason to the mineral kingdom. Several of the gases have been solidified, and we can not doubt that at some specific temperature each might be made solid. We can not, therefore, exclude any substance from the class of minerals be. cause at the ordinary temperature it is a gas or liquid. Quicksilver with such a rule would be excluded as well as water. A mineral, then, is any substance in nature not organized by vitality, which has a homogeneous structure. The first limitation here stated-not organized by vitality-excludes all living structures, or such as have resulted from vital powers; and the second-a homogeneous structure-excludes all mixtures or aggregates. The different spars, gems, and ores are minerals, while granite rock, slate, clay and the like, are mineral aggregates. This compound character is apparent to the eye in granite, for there is no difficulty in picking out from the mass a shining scaly mineral, (mica,) and with more attention, semi-opaque whitish or reddish particles (feldspar) will be easily distinguished from others (quartz) that have a glassy appearance. It is a popular belief, that stones grow. Yet the absence of any proper growth is the main point distinguishing min. erals from olbjects that have life. Plants and animals are nourished by the circulation of a fluid through their interior; in plants,.we call the fluid sap; in animals, blood; and increase or growth takes place by means of material secreted from this circulating fluid. The living being commences with the mere germ, and grows through youth to maturity Why should water and gases rank with minerals. What is a min. ral? What limitations are here implied? What is the nature of granite? 16 GENERAL CHARACTERISTICS OF MINERALS. and when this fluid finally ceases to circulate, it dies and soon decays. Minerals, on the contrary, have no such nourishing fluid. The smallest particle is as perfect as the mountain mass. They increase in size only by additions to the surface from some external source. The deposit of salt forming in an evaporating brine, has layer after layer of particles added to it, and by this mode of accumulation, its thickness is at. tained. Beds of an ore of iron, called bog iron-ore, are sometimes said to grow. They do in fact increase in extent. Rills of water running from the hills wash out the iron in the rocks they pass over, decomposing and altering the condi. tion of the ore, and carry it to low marshy grounds. Here the water becomes stagnant, and gradually the iron is deposited This bog ore, as the name implies, is found mostly in low marshy places, and often contains nuts, leaves, and sticks, changed to iron ore. The increase here is obviously by ex. ternal additions. In limestone caverns, and about certain lakes and streams, the water contains much carbonate of lime. As it evaporates, layer after layer of the lime is deposited, till thick beds are sometimes formed. In caverns, the water comes dripping through the roof, drop by drop, and each drop as it dries, deposits a little carbonate of lime. At first it forms but a mere wart on the surface; but it gradually lengthens, till it becomes a long tapering cylinder, and sometimes the pendant cylinder, or stalactite, as it is called. reaches the floor of the cave, and forms a column several feet in diameter. It thus appears that minerals increase, or enlarge, by accretion, or additions to the surface only. They decrease, or the surface is worn away, by the action of running water and other agents. When they decay, as sometimes happens fiom contact with air and moisture, or some other cause, the change begins with the surface, and results in producing one or more different minerals. The line of demarkation, therefore, between living beings, and minerals or inorganic matter, is strongly drawn. Characters of Minerals. In pursuing the subject of min. What are the different modes of increase in the animate and mineral kingdoms? Mention examples of increase in mineral substances, and explain the mode. GENERAL CHARACTERISTICS OF MINERALS. 17 erals, there are various qualities presented for our study We observe that stones or minerals have color; they have hardness in different degrees, from being soft and impressible by the nail, to the extreme hardness of the diamond; they have weight; they have luster, from almost a total absence of the power of reflecting light to the brilliancy of a mirror. Some are as transparent as glass and others are opaque. A few have taste. These are the most obvious characters, and characters to which the mind would at once appeal in distinguishing species. Other characters of equal importance are found in the internal and external structure of minerals. On examining a piece of coarse granite, we find that each scale of mica may be split by the point of a knife into thinner leaves. Here is evidence of a peculiar structure, called cleavage; and wherever mica is found, this peculiarity is constant. The feldspar in the same rock, if examined with care, will be found to break in certain directions with a smooth, or nearly smooth plain surface, showing a luster approaching that of glass, though somewhat pearly. It is true of feldspar also, that this cleavage is a constant character for the spe. cies, as regards direction and facility. In nearly all miner. als, this kind of structure, more or less perfect in quality, may be distinguished. In a broken bar of iron the irregularity of the grains proceeds from this cause. In granular marble, although the mass as a whole has no such structure, the several grains if attentively examined will be seen to present a distinct cleavage structure and consequent angular forms. In finer varieties, the grains may be so small that the characters cannot be observed; or again the texture of the mass may be so compact that not even grains can be distinguished. This cleavage, then, is a peculiarity of internal structure. It is intimately connected with another fact,-that these same minerals often occur under the form of some regular solid with neat plane surfaces; and are finished with a symmetry and perfection which art would fail to imitate. These forms are their natural forms, and every mineral has its own distinct system of forms. The beauty of a cabinet of minerals arises to a great extent fiom the variety of forms and What physical characters are to be observed in the study of minerals? What character depends on internal structure? Mention examples and explain. What other character depends on structure l 2* 18 GENERAL CHARACTERISTICS OF MINERALS. high finish of these gems of nature's workmanship. The mineral quartz sometimes occurs in crystals consisting of two pyramids united by a short six-sided prism, and they have generally the transparency and almost the brilliancy of the diamond, whose name they bear in common language. The " diamonds" of central New York, and many other localities. are of this kind. In other cases a large surface of rock sparkles with a splendid grouping of the pyramidal glassy crystals. We might draw other illustrations fiom almost all the mineral species. But this will suffice to show that in ad. dition to the physical characters above mentioned, there are others dependent on structure, which afford distinctions of species, apparent both in external form and internal cleavage. Still other characters are derived from subjecting species to the action of heat, and to acids or other re-agents. One mineral, when heated, melts; another is infusible, or fuses only on the edges another evaporates. By such trials, and others hereafter to be described, we study minerals in a different way, and ascertain their chemical characters. This mode of investigation more minutely pursued, leads to a knowledge of the constitution of minerals, a branch of study which belongs properly to Analytical Chemistry: the results are of the highest importance to the mineralogist. It is perceived, therefore, that the learner may (1) examine into the peculiarities of structure among minerals; (2) he may attend to the physical characters depending on light, hardness, and gravity; (3) he may acquaint himself with the effects of heat and chemical re-agents-the chemical characters. These are three sources of distinctions giving mutual aid, and a knowledge of all is necessary to the mineralogist. To learn to distinguish minerals by their color, weight, and luster, is so far very well; but the accomplishment is of a low degree of merit, and when most perfect, makes but a poor mineralogist. But when the science is viewed in the light of Chemistry and Crystallography, it becomes a branch of knowledge, perfect in itself, and surprisingly beautiful in its exhibitions of truth. We are no longer dealing with pebbles of pretty shapes and tints, but with objects modeled by a Divine hand; and every additional fact becomes to the nind a new revelation of His wisdom. Mention examples. What other characters are there? Enumerate the kinds of characters presented by minerals CRYSTALLOGRAPHY. l1 In tile study of this science, the learner will be introduced first to the structure of minerals. The subject is treated of under its usual name, crystallography CHAPTER II. CRYSTALLOGRAPHY: OR THE STRUCTURE OF MINERALS. Crystals: Crystallization. The regular forms which minerals assume are called crystals, and the process by which their formation takes place, is termed crystallization. Crystallization is the same as solidification. Whenever a liquid becomes solid there is actual crystallization. Under favorable circumstances regular crystals may form; but very commonly the solid is a mass of crystalline grains, as is the case in statuary marble, or a loaf of white sugar. In the case of the marble, crystallization commenced at myriads of points at the same instant, and there was no room for any to expand to a large size and regular outline. When on the contrary, the process is slow, simple crystals often increase to a large size. We may understand this subject of crystallization by watching a solution of salt, as it evaporates over a fire. After a while, if the process is not too rapid, minute points of salt appear at the surface, and these continue enlarging. They are minute cubes when they begin, and they increase regularly by additions to their sides, till finally they become so heavy as to sink. In other cases, if the brine is boiled away too rapidly, a mass of salt may be formed at the bottom of the vessel, in which no regular crystals (cubes) can be seen. Yet it is obvious that the same power of crystallization was at work, and failed of yielding symmetrical solids, because of the rapidity of the evaporation. Crystals of salt have been found in the beds of this mineral a foot or more in breadth, which had been formed by natural evaporation; and the whole bed is in all cases crystalline in the structure of the salt. However finely the salt may be ground Explain the terms crystal and crystallization. Are solidification and trystallization the same process? Explain the different results of crystallization by the example of salt Is every grain, however minute crystalline? 20 STRUCTURE OF MINERALS. up, as that for our tables, still the grains were crystalline in their origin and are crystalline in structure. This subject may be further illustrated by many other sub. stances. A hot solution of sugar set away to cool, will form crystals upon the bottom, or upon any thread or stick in the vessel; and these crystals will continue increasing till a large part of the sugar has become crystals. It is a common and instructive experiment to place a delicate frame. work of a basket or some other object, in a solution of sugar or alum; after a while it becomes a basket of finished gems, the crystals glistening with their many polished facets. Again, if a quantity of sulphur be melted, it will crystallize on cooling. To obtain distinct crystals, the surface crust should be broken as soon as formed, and the liquid part within be poured out; the cavity, when cold, will be found to be studded with delicate needles. The crust in this case is as truly crystallized as the needles, although but faint traces of a crystalline texture are apparent on breaking it. This was owing to too rapid cooling. Melted lead and bismuth will crystallize in the same manner. There is a substance, iodine, which when heated passes into the state of a vapor; on cooling again, the glass vessel containing the vapor is covered with complex crystals, as brilliant as polished steel. During the cold of winter, the vapors constituting clouds, often become changed to snow; this is a similar process of crystallization, for every flake of snow is a congeries of crystals, and often they present the forms of regular six-sided stars. So also, our streams become covered with ice; and this is another form of the crystallization of water. The power which solidifies, and the power which crystallizes, are thus one and the same. Crystallography, there. fore, is not merely a science treating of certain regular so. lids in Mineralogy; it is the science of solidification in general. Modes of Crystallization. In the above examples we have presented three different modes of crystallization. In one case, the substance is in solution in water, (or some solvent;) the particles are thus free to move, and as the solvent passes off by evaporation, they unite and form the crystal. Explain the case of sulphur. Give instances of crystals formil g from vapor. What does the science of crystallography embrace? What are the modes of crystallization alluded to in the examples given' CRYSTALLOGRAPHY. 21 fizing solid. In a second case, the substance is fused by heat; here again the particles are free to move as long as the heat remains; and when it passes off solidification corn mences, under the power of crystallization. In a third case, the substance is reduced to a vapor by heat; and from this state-also one of freedom of motion among the particlesit crystallizes as the heated condition is removed. In the hardening of steel, it is well known that the coarse. ness of the grains varies with the temperature used, and the manner in which the process is conducted. An increased coarseness of structure, implies that certain of the crystalline grains were enlarged at the expense of others. It teaches us that in some cases the powers of crystallization may act at certain temperatures, even without fusion or solution. The long continued vibration of iron, especially when under pressure, produces a similar change from a fine to a coarse texture; and this fact has been the cause of accidents in machinery, by rendering the iron brittle: it has led to the fracture of the axles of rail cars and of grindstones, and even the iron rails of a road may thus become weak and useless. By these several processes, the various minerals and very many of the widely extended rocks of our globe, have been brought to their present state. Perfect crystals are usually of moderate size, and gems of the finest water are quite small. As they enlarge they become less clear, or even opaque, and the faces lose their smoothness and much of their luster. The emerald, sufficiently pure for jewelry, seldom exceeds an inch in length, and is rarely as large as this; but a crystal of this species (of the variety beryl) was obtained a few years since at Acworth, New Hampshire, which measured 4 feet in length and 21 feet in circumference; it was regular in its form, yet, except at the edges, opaque. The clear garnets, fit for set. ting, are seldom half an inch through; but coarse crystals have been found 6 inches in diameter. Transparent sap. phires also, over an inch in length, are of extreme rarity; but opaque crystals occur a foot or more long. Quartz crystals attain at times extraordinary dimensions. There is one at Milan which is 3~ feet long and 5i in circumference, and it weighs 870 pounds. From a single cav. Is fluidity essential to the process of crystallization? What is saio 4f steel and iron? What is said of the size and perfection of crystals? 22 STRUCTURE OF MINERALS. ity at Zinken, in Germany, 1000 cwt. of crystals of quartz were taken above a century since. These facts indicate im. perfectly the scale of operations in the laboratory of nature. The same process by which a single group, like that just alluded to, has been formed, has filled numberless similar cavities over various regions, and distributed the quartz material through vast deposits in the earth's structure. The same powei presides alike over the solidification of liquid lavas, and the formation of a cube of salt, producing the crystalline grains constituting the former, and the structure and symmetrical faces of the latter. Constancy of Crystalline Forms. Each mineral may be properly said to have as much a distinct shape of its own, as each plant or each animal, and may be as readily distin. guished by the characters presented to the eye. Crystals are, therefore, the perfect individuals of the mineral kingdom. The mineral quartz has a specific form and structure, as much as a dog, or an elm, and is as distinct and unvarying as regards essential characters, although, owing to counteracting causes during formation, these forms are not always assumed. In whatever part of the world crystals of quartz may be collected, they are fundamentally identical. Not an angle will be found to differ from those of crystals obtained in any part of this country. The sizes of the faces vary, and also the number of faces, according to certain simple laws hereaftez to be explained; but the corresponding angles of inclination are essentially the same, whatever the variations or dis. tortions. Uther minerals have a like constancy in their crystals, and each has some peculiarity, some difference of angle, or some difference of cleavage structure, which distinguishes it from every other mineral. In many cases, therefore, we have only to measure an angle to determine the species. Both quartz and carbonate of lime crystallize at times in similar six-sided prisms with terminal pyramids; bait the likeness here ceases; for the angles of the pyramids are quite different, and also the internal structure. Idocrase and tin ore crystallize in similar square prisms, with terminal pyramidal planes; but though similar in general form, each has its own character istic angles of inclination between its planes, which angles What is said of the generality of the power of crystallization? What is said of the constancy of the crystalline forms and struc'ure of minerals? Explain by the mineral quartz, as an example. CRYSTALLOGRAPHP. 2'3 admit of no essential variation. Upon this character, the constancy of crystalline forms, depends the importance of crystallography to the mineralogist. FUNDAMENTAL FORMS OF CRYSTALS. The forms of crystallized minerals are very various. To he eye there often seems to be no relation between different crystals of the same mineral. Yet it is true that all the va. rious shapes are modifications according to simple laws of a few fundamental forms. There is perhaps no mineral which presents a greater variety of form than calc spar. Dog-tooth spar is one of its forms; nail-head spar, as it is sometimes called, is another; the one, a tapering pyrimadal crystal, well described in its name, the other broad and thin, and shaped much like the head of a wrought-nail. Yet both-of these crystals and many others are derived from the same ffin damental fbrm. After a few trials with a knife, the student will find that slices may be readily chipped off from the crystals of this mineral in three directions; and the process will obtain a solid from each, the one identical with the other in its angles. They consequently have the same nucleus or fundamental form. The fundamental forms are those from which all the other torms of crystals are derived. The derivative forms, are called secondary forms, and their planes, secondary planes. The number of fundamental forms indicated by cleavage, is thirteen. They are either prisms,* octahedrons or dodecahedrons. The prisms are eitherfour-sided or six-sided. The prisms are denominated right prisms, when they stand erect, and oblique prisms, when they are inclined. Figures 4, 5, 7, 8, are right prisms, and figures 12, 14, are oblique prisms. The sides in each case are called lateral planes, and the extremities bases. An octahedront has eight sides, and consists of two equal How do the crystals of different minerals differ? Mention examples. What is said of the forms of crystals of the same mineral? What is understood by fundamental forms? What by secondary forms or planes? How many fundamental forms are there? What kinds of prisms are there? Explain the terms lateral planes and bases. * Any column, however many sides it may have, is called a prism. t From the Greek okto, eight, and hedra, face. 24 STRUCTURE OF MINERALS. four-sided pyramids placed base to base. (Figs. 2, 6, 9 ) The plane in which the pyramids meet is called the base of the octahedron; (bb, fig. 6;) the edges of the base are called the basal edges, and the other edges the pyramidal. The dodecahedron* has twelve sides (fig. 3.) The axes of these solids are imaginary lines connecting he centers of opposite faces, of opposite edges, or of oppo. site angles. The inclination of two planes upon one another s called an interfacial angle.t The figures here added represent the forms of the bases and faces referred to in the following paragraphs. A B C D E F A, a square, having the 4 sides equal; B, a rectangle, dif fering from A, in having only the opposite sides equal; C, a rhomb, having the angles oblique and the sides equal; D, a rhomboid, differing from the rhomb in the opposite sides only being equal; E, an equilateral triangle, having all the sides equal; F, an isosceles triangle, having two sides equal. The lines crossing from one angle to an opposite are called diagonals. The fundamental forms of crystals, though thirteen in number, constitute but six systems of crystallization, as follows:What is an octahedron? What is its base? How are the basal and pyramidal edges distinguished? What is a dodecahedron? What are axes? What are interfacial angles? Explain the terms square; rectangle; rhomb; rhomboid; equilateral triangle; isosceles triangle; diagonal. How many systems of crystallization are there? * From the Greek dodeka, twelve, and hedra, face. t An angle is the amount of divergence of two straight lines from a given point, or of two planes from a given edge. In the annexed figure, ID ACB is an angle formed by the divergence of two -~ \A lines from C. If a circle be described with the angular point C as the center, and the circumference E __C 1 p DABFE be divided into 360 equal parts, the number of these jarts included between A and B will be the number of degrees in the angle ACB; that is, if 40 of these parts are included between A and B, the 1 angle ACB equals 40 degrees (40~). DF being perpendicular to EB, these two lines divide the whole into 4 equal parts, and consequently the angle DCB equals 360~-4 equals 90~. This is termed a right angle. An angle more or less than 90~ is called an oblique angle; if less, as ACB, an acute angle; if more, as ACE, an obtuse angle. ,FUNDAMENTAL FORMS Of CRYSTALS. 2. I. The first system includes the cube (fig. 1 or la, the lat ter in outline;) regular octahedron (fig. 2;) and the rhombic 1 la 2 3 3a dodecahedron (fig. 3 or 3a.) They are symmetrical solids.hroughout, in all positions, being alike in having the height, breadth and thickness equal; their three axes, represented by the dotted lines in the figures, are at right angles with one another and equal. In the cube, the axes connect the centers of opposite faces; in the octahedron and dodecahedron, they connect the apices of solid angles. This is more fully explained on a following page. The cube has its faces equal squares, and its angles all right angles. The octahedron has its 8 faces equal equilateral triangles: its edges are equal; its plane angles are 60~; its interfacial angles (angles between adjacent faces) 109~ 28'. The dodecahedron has its 12 faces equal rhombs; the edges are equal; the plane angles of the faces are 109~ 28' and 700 32'; its interfacial angles are 1200~. II. The second system includes the right square prism 4 5 6 (figs. 4 and 5,) and square octahedron (fig. 6.) They have wo equal lateral axes, and a vertical axis unequal to the What forms does the first system include? How are these forms related? Describe the forms. What forms does the second system include. and how are they related? Describe the forms ^1^^ y^\\~~~I 26 STRUCTURE OF MINERALS. lateral: that is, the width and breadth are equal, but the height is varying. All the axes a e at right angles with one another. Fig. 4 is a square prism higher than its breadth, and fig. 5 is one shorter than its breadth. The right square prism and square octahedron may be ol any height, either greater or less than the breadth; but the dimensions are fundamentally constant for the same mineral species. The square prism has its base a square. The square octahedron has its base (bb) a square, and its 8 faces equal isosceles triangles.'he lateral edges of the prismr differ in length from the basal; and the terminal or pyramidal edges of the octahedron differ in length from the basal. III. The third system includes the rectangular prism (fig. 7,) the rhombic prism (fig. 8,) and the rhombic octahe 7 8 9'Hi T dron (fig. 9.) They are similar in having the three dimen sions, or the three axes, unequal; and the axes at right angles with one another. The rectangular prism has a rectangular base, and the axes connect the centers of opposite faces. The rhombic prism and rhombic octahedron have each a rhombic base, the angle of which differs for different species. The lateral axes of the prism connect the centers of opposite edges, and in the octahedron they connect the apices of opposite angles. IV. The fourth system includes the right rhomboidal prism 10 11 12 13, P (igs:. 10, 11.) and the oblique rhombic prism (figs. 12, 13.) The lateral axes are unequal, and at right angles as in the What forms are included in the third system and how are they related? Describe the forms. What forms does the fourth system incllude and how are they related 1 FUNDAMENTAL FORMS OF CRYSTALS. 27 last system; but they are oblique to the vertical axes. Their positions are shown in the figures. The right rhomboidal prism stands erect when on its rhom. boidal base, as in fig. 11; but is oblique when placed on either of the other sides, as in fig. 10. The oblique rhombic prism is shown in- a lateral view in fig. 12, and a front view in fig. 13. V. Thefifth system includes the oblique rhomboidal prism which has the three axes unequal, 14 15 and all are oblique in their intersec- tions. Fig. 14 represents a side view of this form, and fig. 15 a front view... VI. The sixth system includes the rhombohedron and hexagonal prism, in which there are 16 16a 17 17a 18 three equal lateral axes and a vertical axis at right angles with the three. Fig. 16 is an obtuse rhombohedron, and 16a is the same in outline, showing the axes. Figs. 17, 17a, represent an acute rhombohedron. Fig. 18 is a hexagonal prism; it is bounded by six equal lateral planes; the lateral axes either connect the centers of opposite faces, as in the rigure, or of opposite lateral edges. To understand the rhombohedron, the student should have a model before him. On examining it he will find one solid angle made up of three equal plane angles, and another opposite one of the same kind; all the other solid angles are different from these. These two solid angles are called the vertical solid angles, and a line drawn from one to the other is the vertical axis of the rhombohedron. The rhombohe. dron should be held with this line vertical; it is then said to he in position. Thus placed, it will be seen to have six lat. eral angles, six equal lateral edges, and also six equal terms. nal edges, three of the terminal above and three below What forms does the fifth system include, and how does this system differ from the preceding? What does the sixth system include? What is said of the rhomnbohedron? of its position? its solid angles? 28 STRUCTURE OF MINERALS. The lateral edges in figure 17a, are distinguished fr(ir the terminal by being made heavier. Figure 19 repie sents a vertical view of fig. 16; 19 19a the three edges meeting at center are the terminal edges of one ex- 4 tremity: the exterior six are the 1 - lateral edges; and the six lateral/ angles are seen at their interseclions. In fig. 19a, the same is seen in outline, and the dotted lines represent the three late lal or transverse axes, connecting the centers of opposite lateral edges. The lateral and terminal edges differ in one set being acute and the other obtuse; in the obtuse rhombo. hedron (fig. 16) the terminals are obtuse, and in the acute rhombohedron (fig. 17) they are acute. Several of the primary forms are easily cut from wood oi chalk. Cut out a square stick, and then saw off a piece from one end as long as the breadth of the stick: this is the cube. Saw off other pieces longer or shorter than this, ant they are different right square prisms. Shave off a piece of more or less thickness from one side of the square stick, and it then becomes a rectangular stick. From it, pieces may be sawn off, of different lengths, and they will' be right rectangular prisms. Next cut a stick of a rhombic shape, (a section having the shape in figure C, page 26,) from it right rhombic prisms may be cut, of any length. Shave off more or less from one side of the rhombic stick, and it is changed to a rhomboidal form, (section as in fig. D, page 26,) and rhomboidal prisms may be sawn from it of any length. Take a rhombic stick again; and instead of sawing it off straight across, as before, saw off the end obliquely from one side-edge to the opposite; the base thus formed is oblique to the sides: then saw the stick again in parallel oblique directions, (accurately parallel,) and an oblique rhombic prism will be obtained. If the oblique direction is such that the basal plane equals the lateral, the selid is a rhombohedron. Proceeding in the same way with a rhomboidal stick, oblique rhomboidal prisms may be made. The student is advised to make these solids, either from wood, raw potatoes, or chalk,* in order to Become familiar with them. What is said of the lateral edges and angles of the rhombohedron I * Models made of chalk become quite hard if washed over w th a &trong solution of gum Arabic, or varnish. FUNDAMENTAL FORMS OF CRYSTALS. 2% By means of such models, the student may trace out im. portant relations between the fundamental forms. Take a cube, and cut off each angle evenly, inclining the knife alike to the adjacent faces; this produces figure 20. Continue taking slice after slice equally from each angle, and the solid takes the form in fig. 20a, (called a cubo-octahe..dron;) still continue taking off regular slices from each angle alike, and it finally comes out a regular octahedron, the form represented in fig. 20b. The last diminishing point in each 20 20a 20b face of the cube is the apex of each solid angle of the octahedron. It is hence apparent why the axes of the cube con nect the opposite solid angles of the octahedron. Take another cube (one of large size is preferable) and pursue the same process with each of the edges, keeping the knife, in cutting, equally inclined to the faces of the cube, and we obtain, in succession, the forms represented in figs. 21 21a 21b 21 and 21a; and finally as the plane P disappears, it comes out the rhombic dodecahedron, (fig. 21b.) Hence the same axes which connect the centers of opposite faces in the cube, connect opposite acute solid angles in the dodecahedron. So the cube, by reversing the process, may be made from an octahedron by cutting off its solid angles, passil g in succession through the forms represented in figures 20b, 20a, 20, to figure 1. The dodecahedron also yields a cube in a similar manner, giving as the process goes on, the forms rep. resented in figures 21b, 21a, 21, 1. Moreover, the octahedron and dodecahedron are easily de. How can you make an octahedron from a cube? How make a do decahedron from a cube? How the cube from an octahedron? the cube from a dodecahedron? What relation hence exists between the solids of the first system? e* 80 STRUCTURE OF MINERAI.S. rived from one another. Figure 22 represents an octahedron 22 22a with the edges truncated. On eA/7\ /^ \ ~ continuing this truncation, the /A//1A\< /^ Pplanes A are reduced in size, and the form in figure 22a is A\+y ^ \I oobtained; and another step be. yond, we have the dodecahedron, (fig. 21b.) Figure 22a repre. sents a dodecahedron with the obtuse solid angles replaced; and this replacement continued, produces finally an octahedron, the reverse of the preceding. These solids are, then, so related that they are all deriva. ble from one another; and the three actually are often presented by the same mineral. All the figures above referred to, occur as forms of galena, fluor-spar, and several other species. Instead, therefore, of considering the three solids, the cube, regular octahedron, and dodecahedron, as independent forms, we properly speak of them as constituting together one system, or as belonging to the same series of forms. Again: pursue the same mode of dissection on the angles of a square prism, taking care to move the knife parallel to a 23 23a diagonal of the prism; the form in >-AP ~? / figure 23 is first obtained, and finally\ a square octahedron, figure 23a. Y' i M Thei b The square prism and square octal A/ hedron (like the cube and regular,A/x octahedron) belong to one and the same system. The two often occur in the same mineral. Again: remove with a knife the basal edges of a rhombic 24 24a prism, moving the knife parallel to a diagonal plane of the piism, figure 24?a - e- /l \ is at first obtained, and then a rhombic l I:. octahedron, (fig. 24a.) Remove the four lateral edges of a rhombic prism, (see fig. 26a.) keeping the knife paral. lel to a vertical diagonal plane: the fi,'m in figure 25 will first be obtained and then a right rectan. >'t,?' pdv i m (fg. 25a); and conversely cut offthe lateral edges iv an you make a square octahedron fiom a square prisin? How rhombic octahedron from a rhombic prism? How a rectangular prism tromn a rhombic't FUNDAMENTAL FORMS OF CRVS ALS. 31 of a right rectangular prism, with the knit; parallel to the ver. 25 5u 2 M f. M 6 -- I M f! 26a tical diagonal planes of this prism, 26b rhombic prism (fig. 26a) is the result. The relations of these two L l <[M ".' prisms is shown in figure 26b, which represents a rhombic prism....~ within a rectangular prism. It is obvious on comparing these figures, that the lateral axes which connect the centers of opposite faces in the rectangu. Iar prism, connect the centers of opposite lateral edges in tie rhombic prism. These three forms, the right rhombic prism, rhombic octahedron, and rectangular prism, are so closely related, that one may give origin to the other, and all may occur in the same mineral. This is often the case, as in the minerals celestine and heavy spar. Again: set the right rhomboidal prism on one of its lateral faces, and then slice off each lateral edge, (lateral, as so situated,) keeping the knife parallel with the diago- 27 nal plane, and an oblique rhombic prism is obtained. Figure 27 represents the process begun. and figure 13, as well as the interior of figure 27, the completed oblique rhombic prism. Lastly: take a rhombohedron, and after placing it in position, fig. 16,) look down upon it from above, (fig. 19;) the six lateral edges are seen to form a regular six-sided figure around the axis. If these edges be cut off parallel lo the axis, a six-sided prism (having a three-sided pyra. mid at each extremity) must, therefore, result. This pro. cess is shown begun in figure 28, and completed in figurt How is a rhombic prism derived from a rectangular? What relation hence between these prisms? How can yen make an oblique rhombic prism from a right rhomboidal? How a right rhomboidal from an oblique rhombic? Explain the relation betw en the rhombohedron ao d hexagonal prism, and how one is reduced to he other. 82 STRUCTtRE OF MINERALS. 28a. Looking down again on the model as lefore, the lat eral angles are seen to form six equi-distant points around tnh axis; and if these angles are removed in the same manner, another six-sided prism is obtained, differing, however, from the former in having the faces of the pyramid at each end, five-sided, instead of rhombic. Figures 29, 30, illustrate the process. Conversely, we may make a rhombohedron otc of 28 28a 29 30 31 R P. It"F a hexagonal prism, by cutting off three alternate basal edges at ore extremity of the prism, and similarly, three at the other extremity alternate with these, as in figure 31. In figume 30, the process is farther continued, and the rombohedron is shown as a nucleus to the prism. By cutting off slices parallel with R, the rhombohedron is at last obtained. The close relation of the rhombohedron and hexagonal prism is hence obvious. Calcareous spar has the rhombohedron as its primary, and very often occurs in hexagonal forms. The same is true of quartz and many other species. From the above transformations, the study of which, with the aid of a knife and a few raw potatoes or lumps of chalk, Inay afford some amusement as well as instruction, the student will understand more fully the six systems of crystallization.* These six systems have received the following names: 1. Monometric or tesseral system, (from the Greek monos, one, and metron, measure, alluding to the three axes being equal in length.) Includes the cube, octahedron and dodecahedron, (figs. 1, 2, 3.) 2. Dimetric system, (fiom dis, two times, and metron, alluding to the vertical axis being unequal to the other two.) Give the names of the systems of crystallization, and mention the torms each includes. * In some text books, the student may read about certain integral',rms, the cube, the three-sided pyramid and t iree-sided prism, from ^ hich it is stated all the other forms may be made. The idea of such frms has nothing to do with crystallography, or the actual ccnstitu iotl of crystals. CL,AVA(GE. 33 Includes the square prism and square octahedion, (figs. 4. 5, 6.) 3. Trimetric system, (from tris, three times, and metron, alluding to the three axes being unequal.) Includes the right rhombic prism, right rectangular plism and rhombic octahe. dron, (figs. 7, 8, 9.) 4. Monoclinic system, (from monos, one, and klino, to incline, one axis being inclined to the other two which are at right angles.) Includes the right rhomboidal prism and oblique rhombic prism, (figs. 10, 11, 12. 13.) 5. Triclinic system, (from tris and klino, the three axes being oblique to one another.) Includes the oblique rhomboidal prism, (figs. 14, 15.) 6. Hexagonal system. Includes the rhombohedron ana hexagonal prism, (figs. 16, 17, 18.) CLEAVAGE. It has already been stated that crystals of calcareous spar may be chipped off easily in three directions, and by this means, the fundamental form, a rhomlohedron, may be obtained. In all other directions only an irregular fracture takes place. This property of separating into natural layers, is called cleavage, and the planes along which it takes place, cleavage joints. Cubes of fluor spar may be cleaved on the angles, with a slight pressure of the knife, and the process continued affords successively the forms represented in figures 20, 20a, and nnally the completed octahedron, as already explained. A lead ore, called galena, yields cubes by cleavage. Micaoften improperly called isinglass —may be torn by the fingers into elastic leaves more delicate than the thinnest paper. In many species cleavage is obtained with difficulty, and in others none can be detected. Quartz is an instance of the latter; yet it may sometimes be effected with this mineral by heating it and plunging it while hot into cold water. The following are the more important laws with respect to this property: Cleavage is uniform in all varieties of the same mineral. It occurs parallel to the faces of a fundamental form or along the diagonals. It is always the same in character parallel to similar faces What is cleavage? How does it differ in different minerals? Wha are the laws relating to cleavage. 34 STRUCTURE OF MINERALS. of a crystal, being obtained with equal ease, and affording planes of like luster: and conversely, it is dissimilar paral. lel to dissimilar planes. It is accordingly the same, parallel to all the faces of a cube; but in the square prism, the basal cleavage differs from the lateral, because the base is unequal to the lateral planes. Often there is an easy cleavag6 parallel to the base, and none distinct parallel to the sides, as in topaz; and so the reverse may be true. The thirteen fundamental forms enumerated, are the solids olbtained from the various minerals by cleavage. Some minerals present peculiar cleavages of a subordinate character, independent of the principal cleavage. Calc spal; for example, has sometimes a cleavage parallel to the longer diagonal of its faces. The facts on this subject are of considerable interest, yet not of sufficient importance to be dwelt on in this place. SECONDARY FORMS. If crystals always assumed the shape of the primary form, there would be comparatively little of that variety and beauty which we actually find in the mineral kingdom. Nature first taught to heighten the brilliancy of the gem by covering its surface with facets. To the uninstructed eye, these cubes and prisms with their numberless brilliant surfaces, often appear as if they had been cut and polished by the lapidary: yet the skill and finish of the work, most perfect in the microscopic crystal, has but feeble imitation in art. Not unfrequently, crystals are found with one or two hundred dis. tinct planes, and occasionally even a much larger number; and every edge and angle has the utmost perfection, and the surfaces an evenness of polish, that betrays no rude workmanship, even under the highest magnifying glass. Cavities are occasionally met with in the rocks, studded on every side with crystals-a crystal grotto in minature-sparkling when brought out to the sun like a casket of jewels. Even amid the apparent confusion, there is wonderful order of arrangement in the crystals: the corresponding planes gen. erally face the same way, so that the sparkling effect appears in successive flashes over the surface, as every new set of facets comes in turn to the light. Add to this view, their delicate colors-the rich purple of the amethyst, the soft yellowish shades of the topaz, the deep green of the eme. On what does the beauty of crystals to a great extent depend? MLOlrfIl'ATtO. S OF'lvS'rYfALS. 35 ra.d-and it will be admittedI that the powers of crystalliz. ation scarcely yield to vitality in the forms of beauty they produce. These results are not more wonderful than the simplicity of the laws that lead to them. The various secondary forms proceed from the occurrence of planes on the angles or edges of the fundamental forms, which planes are called secondary planes. Figures 20, 21, are secondaries to the cube, and the planes a and e are secondary planes; figures 28, 29, 30, are secondaries to the rhombohedron, and the planes e and a are secondary planes.* These secondary planes however numerous, con. form in their positions to a certain law called the law of symmetry. Previous to stating this law a few explanations are added. The cube, it has been remarked, has six equal square faces. The twelve edges are therefore all equal, and so also the eight angles. in the square prism the vertical edges differ in length fiom the basal, and are therefore not similar. In the rectangular prism, not only the vertical differ from the basal, but two of the basal at each extremity differ from the other two basal. This will be seen at once in the models. In the right rhombic and rhomboidal, two of the lateral edges are acute and two obtuse; these then are not similar to one another. In the oblique prisms some of the basal edges are acute and some obtuse. After tracing out the similar and dissimilar angles and edges in the primaries, with the models, the following laws may lie easily applied: Either1. All the similar parts of a crystal are similarly and simultaneously modified;* or,Explain the relation of secondary ulanes to the fundamental form. What is said of the cube? of the square prism? the rectangular prism? the right rhombic and rhomboidal? the oblique prisms? What is the first law repecting secondary planes? Note.-What is meant by replacement, bevelment, and truncation? * To avoid circumlocutions, the following technical terms a re employed in describing the modifications of crystals. Replacement. An edge or angle is replaced, when cat off by one or more secondary planes, (tigs. 520, 21, 32.) Truncation. An edge or angle is truncated, when the replacing plane is equally inclined to the adjacent faces, (figs. 20, 21.) Bevelment. An edge is beveled, when replaced by two planes, which are respectively inclined at equal angles to the adjacent faces, (fig. 32.) Truncation and bevelment can occur only on edges formed by the meet. ing of equal planes. 836 STRUCTURL OF MINERALS. 2. Half the similar parts of a crystal, alternate in position zre modified independently of the other half. In the cube, octahedron, or dodecahedron, if one edge is replaced, all the other edges will be replaced, and by the same planes. If there are two planes on one edge, (fig. 32) ~here will be two on every other edge; and the two on each will have the same inclinations. If there are three planes on one angle, (fig. 33) there will, in the same manner, be three on the other seven angles. Perfect symmetry is thus preserved, however numerous the added planes. The following figures illustrate this principle, that all the edges, anl' all the angles are modified alike. 32 33 34 35 This symmetry is well seen in the solids which the secondary planes, in the above figures, produce, if enlarged till.he primary planes are obliterated. Thus from figure 32, comes the form in figure 36, the planes e' being enlarged till the planes P are obliterated; fiom 33, comes the form in fig. 37; from 34, the form in 38; and from 35, the form in 39. The form in figure 37 has 24 faces, and is called a trapezohedron. It is common in garnet and leucite. 36 37 38 39 In figure 35, there are six planes on each angle, and as there are eight angles in the cube, the solid represented in figure 39 has forty-eight faces. Both 38 and 39 are forms of the diamond. In connection with the law above given, it is stated that half the similar parts may be modified independently of the other half. The parts thus modified are alternate with,ne another and still produce symmetrical solids. Thus the What second law is mentioned? Explain the first law ty examples MODIFICATIONS OF CRYSTALS. 37 cube may have only the alternate angles replaced; or only one of the two beveling planes shown in figure 32 may occui on each edge; or three of the six on each angle in figure 35. The following are examples; and each figure in the lower line, represents the completed form, produced by extending the secondary planes in the figure above, to the obliteration of the primaries, as explained on the preceding pages. 40 41 42 43 a ~, X ~4-~~4 45 46 47P 44 45 46 47 The replacement begun in figure 40, continued to the oblit. eration of the Ps, produces figure 44, which is a tetrahedron, or three-sided pyramid. So the planes a in figure 41. give rise to fig. 45; the planes e in 42, to figure 46, which is a pentagonal dodecahedron, so called because it has twelve pentagonal (or five-sided) faces. The forms represented in figures 40 and 41 are common in boracite, and those of figures 42, 43, in iron-pyrites. These forms with half the full number of planes are called hemihedral forms, from the Greek words for half andface. The tetrahedron is sometimes placed among the primary forms; but it is properly a secondary form, derived from the cube, in the manner here explained, or from the octahedron by the extension of four faces to the obliteration of the other four. (Compare figs. 2 and 44.) In the right square prism, the basal edges being unequal to the vertical, (because the prism, unlike the cube, is higher than broad,) these two kinds of edges are not replaced by similar planes, and the basal may be modified when the lateral are not modified, (figs. 48, 49.) The lateral edges may be truncated, because their including planes are equal; Explain the second law. What are the resulting forms called What is said of the tetrahedron? 4 88 STPUCTURE OF MINERALS. the terminal cannot be truncated, but are replaced by planes unequally inclined to the including planes. The solid angles 48 49 50 of the square prism are of one kind and are replaced alike, a in figures 23, 50; all the angles in these figures have the same number of planes, and the two adjacent planes in figure 50 are similar in their inclinations, because the lateral planes M, M, of a square prism, are equal. In the rectangular and rhombic prisms the lateral axes are unequal. Consequently in the rectangular prism, two basal edges differ from the other two, and are therefore modified independently (figs. 51, 52.) The planes e extended to the obliteration of T and P, would produce a rhombic prism (in a horizontal position,) as shown in figure 53, and another horizontal prism may be formed by the extension of the planes e, fig. 52. In the rhombic prism the basal edges coi 51 52 53 54 55 resond to the angles of the rectangular prism 55 respond to the angles of the rectangular prism fiT, (see fig. 26b) and are similar and simultaneously replaced as in figure 24. The basal angles are e unlike, one being obtuse and the other acute, and the planes of the two (fig. 54) differ in their in. clinations. The'ateral edges differ in the same manner, two being obtuse and two acute, and they are inde. pendently replaced, as in figure 55. The two planes e are similar planes, because, in a rhombic prism, M and M are equal; and the extension of these planes may produce another rhombic prism. In an oblique rhombic prism the superior basal edges dif. Explain these laws from the square prism; the rectangular and!hombic. MODIFICATIONS OF CRYSTALS 39 fet from the infierior in front, two being obtuse and two acute; consecuenitiy, they are independently replaced. Figure 56, shows the replacement of the obtuse basal. So also the front angles (iifer in the same manner, the upper (left side in fig. 57) being independent of the inferior in its modifications. 56 57 58 59 But the four lateral angles are similar (fig. 58.) Two of the lateral edges are obtuse and two acute, as in the right rhom. bic prism, and their secondary planes are therefore unlike (fig. 59.) 60 In the oblique rhomboidal prism, 61 CR7-P only two diagonally opposite edges or angles are similar, and the modi- 7 \/ / / fications of one edge are therefore I -- independent of those of all the other edges, except the one diagonallyl.~ opposite: the same is true of the angles. The difference between this prism and the oblique rhombic will thus be seen on comparing figures 56 and 60, and also figures 58 and 61: In the rhombohedron, the distinction of vertical and lateral solid angles has already been explained, and also the difference between the terminal and lateral edges. The figures given will show how these distinctions are carried out in the 62 63 64 65 modifications. In figure 62, the terminal solid angles are replaced, but none of the lateral. In figures 64, 65 and 29, the lateral angles are replaced, but not the terminal. Figure 63, has the terminal edges replaced, and figures 68 and 28. the lateral edges. Explain the laws with regard to secondary planes from the oblique rhombic prism; oblique rhomboidal; the rhombohedron. 40 STRUCTURE OF MINER LS. When the planes a' in figure 64 are a little n.ore extended, the form is changed to figure 65, or a double six-sided pyramid. It is in this way that the pyramidal form of crystals of quartz s produced from the primary rhombohedron. In figure 66. 66 67 68 69 a', as is seen, is a different plane from a' in figure 64. By enlarging the planes a', till the planes R are obliterated, figure 67 is obtained, an acute rhombohedron. This may appear a singular result: but it will be understood on considering that there are six lateral angles; and three of the planes a' incline upward, and three, alternate, incline downward; they must therefore produce an oblong solid, bounded by six equal faces, which is nothing else than a rhombohedron. In figure 68, the lateral edges are beveled by the planes e'. The planes e enlarged to the obliteration of the faces R, lead to the form in figure 69-a twelve-sided figure, or dodecahedron, and called from the shape of its faces, a scalene dodecahedron. It is the form of dog-tooth spar, a variety of calcareous spar. In figures 28, 29, the planes e and a are each parallel to the vertical axis, and they consequently produce prisms when extended, as explained on pages 31, 32. In figure 3, under Tourmaline, we have an instance of a hemihedral modification inthe hexagonal system. The extremities of the prism, as will be observed, have different secondary planes, there being in addition to the three faces R, three small triangular planes above, and three narrow linear planes below. Topaz crystals are also differently modified at the extremities, and are examples of hemihedral modifications in a right rhombic prism. Another law gives still greater interest to the study of crystallography: but it can only be briefly alluded to in thi place. When speaking of the right square prism it wa Mention some instances of hemihedral modifications, and expain. MODIFICATIONS OF CRYSTALS. 41 slated that the basal edges were nevei truncated, but. when modified, were replaced by planes unequally inclined to the basal and lateral faces of the primary. These secondary planes do not however occur at random, at any possible inclination; but there is a direct relation, in all instances, to the comparative height and breadth of the fundamental form of the mineral. The same is true of planes on the angles, and in secondaries to all the fundamental forms. Take a cube and cut off evenly one of the edges: thi removes parts of two other edges, at each end of the plane It is found that in cubic crystals these parts are either equa to one another, or one is double of the other, or treble; or in some other simple ratio. The same is true in the othei fundamental forms, except that, as stated, the relative height and breadth of the prism come into account, and influence the result. For example: in figure 70, 70 71 (a section of a cube,) P M and P b c,, N P N are equal edges, divided into equal parts; now a plane on an edge of a cube, as a b, removes, as is seen, equal parts of P M and P N; another, as.. a c, removes twice as many parts of one ~_ edge as of the other; and so other planes hav.^ like siriple ratios. In figure 71, a section of a prism, the lines P M and P N (height and breadth of the prism) are unequal: let them be divided into a like number of parts; then a plane on an edge, as a b, will cut off as many parts of P M as of P N; others, as a c, b d, twice as many parts of one as the other: and so on. a b truncates the edge in figure 70; but not so in figure 71. It is evident to the mathematical scholar that the inclination of a plane a b to P N or P M, is sufficient to determine the relative dimensions of P a and P b, or the relative height and breadth of the fundamental form. These principles give a mathematical basis to the science. Thus we perceive that the attraction which guides each particle to its place in crystallization, produces forms of mathematical exactness. It covers the crystal with scores of facets of finished brilliancy and perfection; and these What other law is there, respecting the occurrence of s.^cnary Mlanes? Explain by the figures. 4* 42 STRUCTURE OF MINERALS. facets are not only uniform in number on similar parts of a crystal, but are even fixed in every angle and every edge.* COMPOUND CRYSTALS. In the preceding pages, we have been considering simple crystals, and their secondary forms. The same forms are occasionally compounded so as to make what have been called twin or compound crystals. They will be understood 72 73 74 75 at once from the annexed figures. Figure 72 represents a crystal of snow of not unfrequent occurrence. It consists, as What is a twin or compound crystal? * On a preceding page, it has been explained that in monometric cystals the axes are equal; in dimetric and hexagonal crystals the lateral axes are equal, and the vertical is of a different length, shorter or longer. In the other systems, the trimetric and the two oblique systems, the three axes are all unequal. In the above paragraphs it has been shown that the relative lengths of the axes in a fundamental form of a crystal are fixed, and may be determined by simple calculations. These fixed relative dimensions are supposed to be the relative dimensions of the particles or molecules constituting crystals; that is if the fundamental form of a crystal is twice as long as broad, the same is true of its molecules. The molecules of a cube must therefore be equal in different directions; those of a square prism must be longer or shorter than broad, but equal in breadth and thicknesss; those of a rectangular prism 1 2 2a 3 must be unequal in three ^n^~_ /Tdirections; and the relative / inequality is determinable as 11 1; e / ijust stated. The simplest and l 3l most probable view of the forms of molecules is that they are spheres for monometric solids; and ellipsoids of different axes for the other forms. Figure 1 represents a sphere. Figure 2 represents an ellipsoid with the lateral axes equal, as emen in the cross section 2a; it is the form in the dimetric and hexagonal systems. F' gure 3 represents an ellipsoid with the lateral axes unequal (fig. 3a), as in the trimetric and oblique systems; a variation in the length of the axes will vary the dimensions, according to any particular case. CO3IPOUND i RYSTALS. 43 is evident to the eye, either of six crystals meeting in a point, or of three crystals crossing one another. Besides, there are numerous minute ciystals regularly arranged along the rays. Figure 73 represents a cross (cruciform) crystal of staurotide, which is similarly compound, but made up of ewer crystals. Figure 74, is a compound crystal of gypsum, and figure 75 one of spinel. These will be understood fiom the following figures. Figure 76 is a simple crystal of gyp- 76 77 sum; if it be bisected along a b, and a the right half be inverted and applied l l to the other, it will form figure 74, fill;! i A which is therefore a twin crystal, in 1l jil'ill-l. 1'." which one half has a reverse position ii;lllll /,i from the other. Figure 77, is a simple Ili/F ~ octahedron; if it be bisected through the dotted line, and the upper half, after being revolved half way around, be then united to the lower, it produces figure 75. Both of these therefore are similar twins, in which one of the two component parts is reversed in position.* Compound crystals are generally distinguished by their reentering angles. Besides the above, there are also geniculated crystals, as in the annexed figure. The bending has here 78 taken place at equal distances from the center of the crystal; and it must therefore havene / /, been subsequent in time to the commencement of the crystal. The prism began from a simple molecule: but after attaining a certain length, an abrupt change of direction took place. The angle of geniculation is constant in the same mineral species; for the same reason that the angles of secondary planes are fixed; and it is such that a cross section directly through the geniculation is parallel to the position of a common secondary plane. In the figure given, the plane of geniculation is parallel to one of the terminal edges. Mention illustrations. Explain their structure in the case of gypsum and spinel. What is said of geniculated crystals? * Such crystals have proceeded from a compound nucleus in which one DS the two particles was reversed. Compound crystals of the kind above described, thus differ front simple crystals in having been formed iom a nucleus of two ormore united molecules, instead of from a simple mucleus. 44 STRUCTURE OF MINERALS DIMORPHISM.-POLYMORPHISM. It was formerly supposed that the same chemical corn pound could have but a single mode of crystallization. But later researches have discovered that there are many in. stances of substances crystallizing according to two distinct systems. Thus sulphur at different times crystallizes in oblique prisms and right rhombic octahedrons, or according to the two systems monoclinic and trimetric. Carbonate of lime at one time takes on the rhombohedral form, and is then called calc spar; at another, that of a rhombic prism, and it is then termed aragonite. Again, sulphuret of iron presents us both with cubical (monometric) crystals and rhombic prisms (trimetric.) As far as investigation has gone, it has appeared that one of these forms is assumed at a lower temperature than the other; and this takes place uniformly, ~so that the temperature attending solidification, in certain cases at least, determines the forms and system of crystallization. How far other causes operate is unknown. This property is termed dimorphism, (from the Greek dis, two or twice, and morphe, form,) and a substance presenting two systems of crystallization is said to be dimorphous. In addition to the above, garnet and idocrase, the one dodeca. hedral, and the other square-prismatic, are different forms of the same substance. Rutile, which is dimetric, anatase, dimetric also, but of different dimensions, and Brookite, which is trimetric, are three distinct forms of the same substance, oxyd of titanium. In this last case, the property has been called trimorphism, (from the Greek tris, three times, and morphe, form.) As the number of forms may be still greater, the more general term polymorphism (polus, many, and morphe) has been introduced to include all cases, whatever the number of forms assumed. A polymorphous substance in its different states presents not merely difference of form. There is also a difference in hardness, specific gravity and luster, in fact, in nearly all physical qualities. Aragonite has the specific gravity 2-93, and calc spar only 2'7; the hardness of aragonite is 38, and that of calc spar but 3. May the same substance crystallize under more than one fundamen tal form? Mention examples. What is this property called? Wha' is said of oxyd of Titanium? What is trimorphism? polymorphism What other differences beside that of form are connected with poly morphism? IRREGULARITIES OF CRYSTALS. 4. Tle forms of a dimorphous substance differ in stability Aragoniite when heated gently falls to powder, arising from a change in the condition of its particles. Aragonite has been obtained by evaporating a solution of lime over a watei bath, and calc spar when the same was evaporated at the ordi. nary temperature. When a right rhombic prism of sulphate of zinc (which is dimorphous) is heated to 1260 F. certain points in its surface become opaque, and from these points, bunches of crystals shoot forth in the interior of the specimen; and in a short time the whole is converted into an aggregate of these crystals, diverging from several centers onl the surface of the original crystal. These small crystals are oblique rhombic prisms; and the same form may be obtained by evaporating a solution at this temperature or above it. Many other similar cases might be cited, but these serve to explain the principle in view. IRREGILARITIES OF CRYSTALS. Before concluding this subject, a few remarks may be added on the irregularities of crystals. Crystals of the same form vary much in length, and in the size of corresponding faces. The same mineral may occur in very short prisms, or in long and slender prisms: and some planes may be so enlarged as to obliterate others; a few figures of quartz crystals will illustrate these peculiarities. 79 80 81 82 83 Figure 79 is the regular form of the crystal. Figure 80 is he same form with some faces very much enlarged, and others very small. Figure 81 is a very short prism and yramid of quartz, such as is often seen attached to the urface of rocks; and figure 82 is a similar form very mich longated. Notwithstanding all these variations, every anigl;, What are some ofthp irrelrularities of crystals I 46 STRUCTURE OF MINER I.S. of inclination remains the same: and this is a genett taco in all crystals, that whatever distortions take place, the angles are constant. Greater diversity is given to the shapes of crystals by these simple variations, without multiplying the number of distinct forms. Figure 83 is a tapering prism of the same mineral, with a minute pyramid at the apex. The faces of this pyramid have exactly the same inclinations as those of figure 79. The constancy of the angles shows that the fundamental form of the crystal, or, in other words, the form of its mole. cules, is constant, amid all these variations of size and shape. Crystals have sometimes curved faces. The faces of diamonds are usually convex, and some crystals are almost 84 spheres. Figure 84 is one of these diamond crystals. It is the same form as is represented in figure 45. For cutting glass, they always \ select those crystals that have a natural curved edge, as others are much inferior for the purpose and sooner wear out. In figure 85 a difierent kind of curvature is represented. It is a curved rhombohe85 dron, in which the opposite faces are parallel in and pearl spar. The latter mineral from Lock. port, New York, is always curved in this way. Siill more singular curvatures are sometimes met with. In the mammoth cave of Kentucky, 86 leaves, vines and flowers are beautifilly initated in alabaster. Some of the " rosettes" are a foot in diameter, and consist of curving leaves, clustered in graceful shapes. The fiostings on our windows in winter are often miniature pictures of forests and vines with rolled tendrils. It is one among the many singular results of y crystallization. On the cool mornings of spring or autumn, in this climate, twigs of plants are occasionally found encircled by fibrous icy curls, (fig. 86,) which are attached vertically to the stem. They are formed during the night. and disappear soon after the appearance of the sun. What is said of curved crystals? What of curved crystallizationa c-, gypsum? of ice? MEASUREMENT OF CRYSTALS. 47 ON MEASURING ANGLES OF CRYSTALS. &s the angles of crystals are constant, minerals, as has been stated, may often be distinguished by measuring these angles. This is done by means of instruments called gonzometers, a term meaning, literally, angle-measurers.* These are of two kinds; one is called the common goniometer, the other the reflecting goniometer. The common goniometer depends on the 87 very simple principle that when two straight A lines cross one another, as A E, C D in the annexed figure 87, the parts will diverge equally on opposite sides of the point of in-c tersection (0); that is, in mathematical language, the angle A O D is equal to the angle C O E, and A-O C is equal to D O E The instrument in common use is here represented. 88 It consists of two arms, a b, c d, moving on a pivot at o: the arms open and shut, and their divergence, or the angle they make with one another, is read off on the graduated arc attached. in using it, press up between them, the edge of the crystal whose angle is to be measured, and continue opening the arms thus till the inner edges lie evenly against the faces that include How are the angles of crystals measured? Explain the principle of the common goniometer from the figure. Explain the common goni ometer and its use. * From the Greek gonu, angle, and metron, measure. 48 STRUCTURE OF MINERALS. the required angle. To insure accuracy in this respect, hold the instrument and crystal between the eye and the light, and observe that no light passes between the arm and the applied faces of the crystal. The arms may then be secured in position by tightening the screw at o; the angle will then be measured by the distance on the arc from k to the lefJ or outer edge of the arm c d, this edge being in the line ol o, the center of motion. As the instrument stands in the figure, it reads 450. The arms have slits at g h, n p, b3 which they may be shortened so as to make them more convenient for measuring small crystals. In some instruments of this kind the arc is detached froin the arms. When this is the case, after the measurement is made and the screw at o tightened, the arc (which has the shape of a f b in the annexed figure, except that from a to b is a solid bar) is adjusted to the upper edge of one of the arms, bringing the mark ato, the center, exactly to the center of divergence of the arms. The angle is then read off as before. With a little ingenuity the student may construct a goniometer for himself that will answer a good purpose. A semicircle may be described on mica or a glazed card, of the shape in figure 88: it should then be divided into halves at f, and again each half subdivided into nine equal parts. Each of these parts measures 10 degrees; and if they are next divided into ten equal parts, each of these small divisions will be degrees. The semi-circle may then be cut out, and is ready for use. The arms might also be made of stiff card for temporary use; but mica, bone or metal is better. The arms should have the edges straight and accurately parallel, and be pivoted together. The instrument may be used like that last described, and will give approximate results, sufficiently near for distinguishing most minerals. The ivory rule accompanying boxes of mathematical instruments, having upon it a scale of sines for measuring angles, will answer an excellent purpose, and is as con- 89 venient as the arc. The annexed -- 3, ~J~ figure will illustrate the mode of 1-t/0 1 using it. The scale is graduated _ along the margin, the middle point/ marking 900, and the divisions either side 10 degrees (as in the figure) and also single de. How is it used when the arms are detached? How may a temporary Loniometel be made? How rmay a scale of' in s be used? MEASUREMENT Of' CRYSTALS. 49 grees. The arms are so applied to the scale, that the center of motion is exactly at the extremity of the middle line, marked 90; and the leg crossing the scale (or that edge of it in the line of the center of motion) will then indicate by its position over the graduated margin, the angle desired.* In making such measurements it is important to remember that1. An angle A 0 D (figure 87) and A 0 C, together, equal 180~; so that if A O C be measured, A O D is ascertained by subtracting A 0 C from 180~. 2. In a rhomb or rhomboid, b a b and a b a, to- b gether, equal 180~; and one may be ascertained < by subtracting the other from 180~. If an obtuse angle of a rhombic prism has been measured and found to be 110~, and the acute angle on measurement is as certained to be 60~, the student should add the two together to find whether the sum is 1800; for if not, there is somf error in the measurement, and it should be repeated. 110 added to 60~ makes 170', showing in this case an errol of 10'. 3. In any polygon, the sum of the angles is equal to twice as many right angles as there are sides less two. Let the number of sides, for example, be 6: 6 less two is 4; and the angles together equal twice 4, (or 8,) right angles, which is equivalent to 8 X 90~ =720~. If we have a prism of six sides, and wish to ascertain the angles between these sides the angles should be measured successively, and the whole added together to ascertain whether the measurements ar( correct. If the sum is 720~, there is good reason to confide in them. Crystals are at times a little irregular; and this should be looked to, as part of the apparent error may at times be thus accounted for. This general principle and the What three points must be observed in making measurements? * Another mode for approximate results consists in holding the crystal with the two faces (whose inclination is to be measured) in an exactly vertical position over a piece of paper: then place a small rule parallel, as near as the eye can judge, to one face, and draw a line; next do the same for the other face. The angle between the two lines, measured either by an arc or the ivory rule just mentioned, is the. desired inclination. With practice, much skill may be acquired in, such trials. They may be made with mic,'s,opic crystals under maicroscope. 50 STRUCTURE OF MINERALS. preceding, which is only a simpler case of the same, are of great importance in the measurements of crystals. Reflecting Goniometer. The reflecting goniometer affords a more accurate method of measuring crystals that have luster, and may be used with those of minute size. The principle on which this instrument is constructed will be understood from the annexed figure (fig. 90) representing a 90 crystal, whose angle a b c is required. d/ The eye, looking at the face of the crystal b c, observes a reflected image of m, in the direction P n. On revolving,'f"Sc ~ the crystal till a b has the position of ^n ml'b cl the same image will be seen again in the same direction P n. As the crystal is turned, in this revolution, till a b d has the present position of b c, the angle d b c measures the number of degrees through which it is revolved. But d b c, subtracted from 180, equals the angle of the crystal a b c. The crystal is therefore passed in its revolution through a number of degrees, which, subtracted from 180~, give the required angle. This angle, in the reflecting goniometer of Wollaston, is measured by attaching the crystal to a graduated circle which revolves with it, as here represented (fig. 91.) 91 A B is the graduated cir. A^ cle. The wheel, m, is at. /i11 ~ tached to the main axis, and /IISI ~ moves the graduated circle 1i l gAi together with the adjuste( i^'~":llS Am_ crystal. The wheel, n, i 0'"U 3 o f':;f " connected with an axi ~~'t2 l~JR tfl lW which passes through th( 1 d ii111111 V - main axis, (which is hollow for the purpose,) and moves merely the parts to which B._yl Iill L the crystal is attached, in order to assist in its adjust. ment. The contrivances for,'ILz._..__ the adjustment of the crysta' are at p, q, r, s. To use the instrument, it must be placed on a small stand or a table, and so elevated as to allow the ob. server to rest his elbows on the table. The whole, thus Explain the principle of the reflecting goniometer. Explain the mode of using the instrument. MEASUREMENT OF CRYSTALS. 51 firmly arranged, is to be placed in front of a window, distant from the same from six to twelve feet, and with the axis of the instrument parallel to it. Preparatory to operation, a dark line must be drawn below the window near the floor, parallel to the bars of the window; or, what is better, on a slate or board placed before the observer on the table. The crystal is attached to the movable plate, q, by a piece of wax, and so arranged that the edge of intersection of the two planes forming the required angle, shall be in a line with the axis of the instrument. This is done by varying its situation on the plate, q, or the situation of the plate itself, or by means of the adjacent joints and wheel, r, s, p, as will be readily understood from the instrument. When apparently adjusted, the eye must be brought close to the crystal, nearly in contact with it, and on looking into a face, part of the window will be seen reflected, one bar of which must be selected for the trial. If the crystal is cor-:ectly adjusted, the selected bar will appear horizontal, and on turning the wheel, n, till this bar, as reflected, is observed to approach the dark line below, seen in a direct view, it will be found to be parallel to this dark line, and ultimately to coincide with it. If there is not a perfect coincidence, the adjustment must be altered until this coincidence is obtained. Continue then the revolution of the wheel, n, till the same bar is seen by reflection in the next face, and if here there is also a coincidence of the reflected bar with the dark line seen direct, the adjustment is complete; if not, alterations must be made, and the first face again tried. A few successive trials' of the faces, will enable one to obtain a perfect adjustment. The circle A B is usually graduated to half degrees, and by means of the vernier, v, minutes are measured. After adjustment, 180 on the arc must be brought opposite 0, on the vernier. The coincidence of the bar and dark line is then to be obtained, by turning the wheel, n. When ob. tained, the wheel, m, should be turned until the same coinci dence is observed, by means of the next face of the crystal. If a line on the graduated circle now corresponds with 0 on the vernier, the angle is immediately determined by the number of degrees opposite this line. If no line corresponds with 0, we must observe which line on the vernier coincides with one on the circle. If it is the 18th on the vernier, an-i the line on the circle next below 0 on the vernier marks 125 52 STRUCTURE OF MINERALS. the required angle is 121" 18'; if this line marks 125' 30' the required angle is 125~ 48'. Some goniometers are furnished with a small polished re. flector, attached to the foot of the instrument below the part s, q, which is placed at an oblique angle so as to reflect a I ar of the window. The reflected bar then answers the purpose of the line drawn below the window, (or on a slate,) and's more conveniently used. Other modes of adjustment for the crystal, are also used but they will explain themselves to the student acquainted with the above explanations, and need not here be dwelt upon. MASSIVE MINERALS, OR IMPERFECT CRYSTALLIZATIONS. Massive or imperfectly crystallized minerals either consist of fibers or minute columns, of leaves or laminae, or of grains: in the first, the structure is said to be columnar; in the second, lamellar; in the third, granular. We have a familiar example of the lamellar structure in slate rocks and imany minerals that occur in masses made up of separable laminae. The fibrous or columnar structure is common in seams of rocks, and sometimes in incrustations covering exposed sur. faces; the material of the seam or crust is made up of minute fibers or prisms closely compacted together, produced by a rapid crystallization on the supporting surface. The granular structure is well seen in loaf sugar and statuary marble. 1. COLUMNAR STRUCTURE. The following are explanations of the terms used in describing the different kinds of columnar structure. Fibrous; when the columns are minute and lie in the same direction; as gypsum and asbestus. Fibrous minerals very commonly have a silky luster: a fibrous variety of gypsum, and one of calc spar, have this luster very strongly, and each is often called satin spar. Reticulated; when the fibers, or columns, cross in various directions, and produce an appearance having some reselnblance to a net. Stellated; when they radiate from a center in all direc. tions, and produce a star-like appearance. Ex. stilbite, gypsum. What kinds of structure exist in massive minerals? Explain the ]if ferent varieties of columnar structure, fibrous; reticulatei, &c. IMPERFECT CiRSTALL (LATIONS. 53.Radiated, divergent; waen the crystals radiate from a center, without producing stellar forms. Ex. quartz, gray antimony. 2. LAMELLAR STRUCTURE. In the lamellar structure, the kmine or leaves may be thick, or very thin; they some. times separate easily, and sometimes with great difficulty. When the laminae are thin and separate easily, the struc ture is said to be foliaceous. Mica is a striking example and the term micaceous is often used to describe thi structure. When the laminae are thick, the term tabular is often ap plied; quartz and heavy spar afford examples. The laminae may be elastic, as in mica, flexible, as in talc or graphite, or brittle, as in diallage. Small laminae are sometimes arranged in stellar shapes this occurs in mica. 3. GRANULAR STRUCTURE. When the grains in the texture of a mineral are coarse, it is said to be coarsely granular, as in granular marble; when fine, finely granular, as in granular quartz; and if no grains can be detected with the eye, the structure is described as impalpable, as in chalcedony. Granular minerals, when easily crumbled by the fingers, are said to befriable. IMITATIVE SHAPES.-Massive minerals also take certain imitative shapes, not peculiar to either of these varieties of structure. The following terms are used in describing imitative forms: Globular; when the shape is spherical or nearly so: the structure may be columnar and radiating, or it may be concentric, consisting of coats like an onion. When they are attached, they are called implanted globules. Reniform; kidney-shaped. In structure, they are like globular shapes. Botryoidal; when a surface consists ot a group of rounded prominences. The prominences or globules usually consist of fibers radiating fiom the center. Mammillary; resembling the botryoidal, but consisting of.arger prominences. Filiform; like a thread. Acicular; slender like a needie. Explain the varieties of lamellar structure; of granular structure; the several imitative shapes, globular; reniform, &c. 5* b4 STRUCTURE OF MINERALS. Stalactitic; having the form of a cylinder, or cone, hanging from the roofs of cavities or caves. The term stalactite is usually restricted to the cylinders of carbonate of lime hanging from the roofs of caverns: but other minerals are said to have a stalactitic form when resembling these in theii general shape and origin. Chalcedony and brown iron ore are often stalactitic. Reticulated; net-like. Drusy; a surface is said to be drusy when covered with ninute crystals. Amorphous; having no regular structure or form, either crystalline or imitative. The word is from the Greek, and means without shape. PSEUDOMORPTIOUS CRYSTALS. A pseudomorphous* crystal is one that has a form which is foreign to the species to which the substance belongs. Crystals sometimes undergo a change of composition from aqueous or some other agency, without losing their form; for example, octahedrons of spinel change to steatite, still retaining the octahedral form. Cubes of pyrites are changed to red or brown iron ore. Again: crystals are sometimes removed entirely, and at the same time and with equal progress, another mineral is substituted; for example, when cubes of fluor spar are transformed to quartz. The petrifaction of wood is of the same kind. Again: cavities left empty by a decomposed crystal, are refilled by another species by infiltration, and the new mineral takes on the external form of the original mineral, as a fused metal the form of the mould into which it is cast. Again: crystals are sometimes incrusted over by other minerals, as cubes of fluor by quartz; and when the fluor is afterwards dissolved away, as sometimes happens, hollow cubes of quartz are left. The first kind of pseudomorphs, are pseudomorphs by al. "'.tion; the second pseudomorphs by replacement; the iV'iln is a pseudomorphous crystal? What is the first, the second I third and the tourth mode of pseudomorphism? Wnat are they ili'd * From the Greek pseudes, false, and morphe, form. LUSTER OF MINERALS. 55 third, pseudomorphs by infiltration; the fourth, pseudomorphs by incrustation.* Pseudomorphous crystals are distinguished by having a different structure and cleavage from that of the mineral imitated in form, and a different hardness, and usually little luster. A large number of minerals have been met with as pseudomorphs. The causes of such changes have operated very widely and produced important geological results. CHAPTER III.-PHYSICAL PROPERTIES OF MINERALS. CHARACTERS DEPENDING ON LIGHT. The characters depending on light are of five kinds, and arise from the power of minerals to relect, transmit, or emit light. They are as follows: 1. Luster; 2. Color; 3. Diaphaneity; 4. Refraction; 5. Phosphorescence. LUSTER. 90. The luster of minerals depends on the nature of their surfaces, which causes more or less light to be reflected. There are different degrees of intensity of luster, and also,different kinds of luster. a. The kinds of luster are six, and are named from some familiar object or class of objects. 1. Metallic: the usual luster of metals. Imperfect metallic luster is expressed by the term sub-metallic. 2. Vitreous: the luster of broken glass. An imperfect vitreous luster is termed sub-vitreous. Both the vitreous and sub-vitreous lusters are common. Quartz possesses the former in an eminent degree; calcareous spar often the latter. This luster may be exhibited by minerals of any color. 3. Resinous: luster of the yellow resins. Ex. opal, zinc blende. 4. Pearly: like pearl. Ex. talc, native magnesia, stil. bite, &c. When united with sub-metallic luster, the term metallic.pearly is applied. How are pseudomorphous crystals distinguished? What characters depend on light? Explain the varieties of luster, metallic, vitreous, &c, * This subject is farther treated of by the author in the Amer. Jour'e Science, vol. xlviii, pp. 66, 81, 397. 56 PHYSICAL PROPERrTIES OF MINERALS. 5. Silky: like silk; it is the result of a fibrous structure Ex. fibrous carbonate of lime, fibrous gypsum, and manJ fibrous minerals, more especially those which in other form have a pearly luster. 6. Adamantine: the luster of the diamond. When sub. metallic, it is termed metallic-adamantine. Ex. some varie. ties of white lead ore. b. The degrees of intensity arS denominated as follows: 1. Splendent: when the surface reflects light with great brilliancy, and gives well defined images. Ex. Elba iron ore, tin ore, some specimens of quartz and pyrites. 2. Shining: when an image is produced, but not a well defined image. Ex. calcareous spar, celestine. 3. Glistening: when there is a general reflection from the surface, but no image. Ex. talc, copper pyrites. 4. Glimmering: when the reflection is very imperfect, and apparently from points scattered over the surface. Ex. flint, chalcedony. A mineral is said to be dull when there is a total absence of luster. Ex. chalk. COLOR. In distinguishing minerals, both the external color and the color of a surface that has been rubbed or scratched, are observed. The latter is called the streak, and the powder abraded, the streak-powder. The colors are either metallic or non-metallic. The metallic are named after some familiar metal, as copper-red, bronze-yellow, brass.yellow, gold-yellow, steelgray, lead-gray, iron-gray. The non-metallic colors used in characterizing minerals, are various shades of white, gray, black, blue, gr,-en, yellow, red and brown. There are thus snow-white, reddish-white, gIcenisn-white, milk-white, yellowish-white; Bluish-gray, smoke-gray, greenish-gray, prarl-gray, ash. gray; Velvet-black, greenish-black, bluish-black; Azure-blue, violet-blue, sky-blue, Indigo-bwhe; Emeraid-green, olive-green, oil-green, grass-green, apple green, blackish-green, pistachio-green (yellowish); What is observed respecting color? COLOR OF MINERALs. 57 Sulphur-yellow, straw-yellow, wax-yellow, ochre-yellow. honey-yellow, orange-yellow; Scarlet-red, blood-red, flesh-red, brick-red, hyacinth-red, rose-red, cherry-red; Hair-brown, reddish-brown, chesnut-brown, yellowish. brown, pinchbeck-brown, wood-brown. A play of colors: this expression is used when several prismatic colors appear in rapid succession on turning the mineral. The diamond is a striking example; also precious opa. Change of colors: when the colors change slowly on turn. ing in different positions, as in labradorite. Opalescence: when there is a milky or pearly reflection from the interior of a specimen, as in some opals, and in cat's eye. Iridescence: when prismatic colors are seen within a crystal; it is the effect of fracture, and is common in quartz. Tarnish: when the surface colors differ from the interior; it is the result of exposure. The tarnish is described as irised, when it has the hues of the rainbow. Pleochroism:* the property, belonging to some prismatic crystals, of presenting a different color in different directions The term dichroismt has been generally used, and implies different colors in two directions, as in the mineral iolite, which has been named dichroite because of the different colors presented by the bases and sides of the prism. Mica is another example of the same. The more general term has been introduced, because a different shade of color has been observed in more than two directions. These different colors are observed only in crystals with unequal axes. The colors are the same in the direction of equal axes and often unlike in the direction of unequal axes. This is the general principle at the basis of pleochroism. What is a play of colors? change of colors? opalescence? iridesa ence? tarnish? dichroism and pleochroism? Mention examples of ais last property; also the law relating to it. 5 From the Greek pleos, full, and chroa, cel... From "he Greek dis, twice, and chroa. 5# PHYSICAL PROPERTIJSS OF MINERALS DIAPHANEITY. Diaphaneity is the property which many objects possess of transmitting light; or in other words, of permitting more or less light to pass through them. This property is often called transparency, but transparency is properly one of the degrees of diaphaneity. The following terms are used to express the different degrees of this property: Transparent: a mineral is said to be transparent when the outlines of objects, viewed through it, are distinct. Ex. glass, crystals of quartz. Subtransparent, or semitransparent: when objects are seen but their outlines are indistinct. Translucent: when light is transmitted, but objects are not seen. Loaf sugar is a good example; also Carrara marble. Subtranslucent: when merely the edges transmit light faintly. When no light is transmitted, the mineral is de. scribed as opaque. REFRACTION AND POLARIZATION. Light is always bent out of its course on passing from one medium into another of different density: as from air into water, or from water into air. This bending of the rays of light is called refraction. Thus if a ray of light, as R S, 92 pass into water at S, it becomes changed in direction to S U, instead of going straight in its course, R S T. The line I/ \^ s ~ a S c is a perpendicular to the surface of the water, and the greater refraction of the water is seen by the bending of the yiv toward this perpendicular. If a _ circle he described about S as a center, and the lines R a and U b be drawn perpendicular to a c, or parallel to the surfac, of the water, we see by these lines the exact relation between the amount of refraction in these two cases; for the refraction in water is as much greater than in air as U b is less than R a.* This relation is called the What is diaphaneity? Explain the terms transparent, &c. What is meant by refraction? Explain from the figure. * In mathematical language, U b is the sine of the angle of retrattion, and a R the sine of the angle a S R, the angle -of incidence; the ratio between the two sines is constant, it being alike for every angle ol incidence. REFRACTION AND POLARIZATION OF LIGHT. 59 index of refraction. It is about 1I for water, or more accu. rately, 1*335. With diamond, the ray would be bent ill the direct S V, which indicates a much greater amount of re. fraction; its index is nearly 24, or correctly, 2.439. The eye at R, looking into a diamond in the direction R S, would see an object in the direction of S V, and not in that of S T. The index of refraction has been obtained for many sub. stances, of which the following are a few: Air, 1*000 Calc spar, 1-654 Tabasheer, 1-211 Spinel, 1-764 Ice, 1'308 Sapphire, 1-794 Cryolite, 1-349 Garnet, 1-815 Water, 1-335 Zircon, 1-961 Fluor spar, 1-434 Blende, 2-260 Rock salt, 1-557 Diamond, 2-439 Quartz, 1-548 Chromate of lead, 2-974 DOUBLE REFRACTION.-Many crystals possess the property of refracting light in two directions, instead of one, and objects seen through them consequently appear double. This is called double refraction. It is most conveniently exhibited with a crystal of calc spar, and was first noticed in a pellucid variety of this mineral from Iceland, called from the locality Iceland spar. On drawing a line on paper and placing the crystal over it, two lines are seen instead of oneone by ordinary refraction, the other by an extraordinary refraction. If the crystal, as it lies over the line, be turned around, when it is in one position the two lines will come together. Instead of a line, make a dot on the paper, and place the crystal over the dot r the two dots seen will not come together on revolving the crystal, but will seem to revolve one around the other. The dot will, in fact, appear double through the crystal in every direction except that of the vertical axis, and this direction is called the axis of double refraction. To view it in this direction, the ends must be ground and polished. The divergence increases on passing from a view in the direction of the axis to one at right angles with it, where it is greatest. In some substtnces, the refraction of the extraordinary ray is greatel in the latter direction than that of the ordinary ray, and in others it is less. What is double refraction? What takes place on revolving a transparent rhomb of calc spar over a line or dot? In what direction is there no double refraction, and in which is it greatest? 60 PHYSICAL PROPERTIES OF MINERALS. In calc spar it is less, it diminishing from 1'654 to 1-483 In quartz it is greater, it increasing from 1'5484 to 1'5582 The former is said to have a negative axis, the latter a positive. This property of double refraction belongs to such of the fundamental forms as have unequal axes; that is, to all except those of the monometric system. Those forms in which the lateral axes are equal, (the dimetric and hexagonal systems, have one axis of double refraction; and those in which they are unequal, (the trimetric, monoclinic and triclinic sys tems,) have two axes of double refraction.* Both rays in the latter are rays of extraordinary refraction. In niter, the two axes are inclined about 5' to each other; in arragonite, 18 18; in topaz, 65~. The positions of the axes thus vary widely in different minerals. POLARIZATION.-The extraordinary ray exhibits a peculiar property of light, termed polarization. Viewed by means of another doubly-refracting crystal, or crystalline plate, (called from this use of it an analyzing plate,) the ray of light becomes alternately visible and invisible as the latter plate is revolved. If the polarized light be made to pass through a crystal possessed of double refraction, and then be viewed in the manner stated, rings of prismatic colors are developed, 93,94 95' 96 and on revolving the analyzing plate, the colored rings and What is meant by positive and negative double refraction? What crystalline forms exhibit double refraction? which have one and which two axes of double refraction? What are the effects due to polarization I * The figures in the note to page 42, represent the form of the mole cules corresponding to these.three conditions: I, a sphere; 2, an ellip soid with equal transverse axes; 3, an ellipsoid with unequal latera axes. PHOSPHORESCENCE 61 intervening dark rings successively change places. If crys. talline plates, having one axis of double refraction, be viewed in the direction of the axis, the rings are circles, and they are crossed by a dark or light cross. Figure 93 shows the position of the colored rings and cross in calc spar, and figure 94, the same at intervals of 90' in the revolution of the plate. With a crystal having two axes of double refrac. tion, there are two series of elliptical rings, as in figures 95 96; these figures show the character of the rings in niter the latter alternating with the former in the revolution ofth plate. The same results are produced when the light is polarized by other means. For example, if a ray of light be reflected from a plate of glass at a certain angle, (56' 45',) it is polarized; and on causing this ray to pass through crystals, as above, similar rings are shown with the same succession of changes on revolving the analyzing plate. There are some monometric 97 crystals which have the property of polarization. The accompany- ing figure of a crystal of analcime, i tii by Sir David Brewster, exhibits a singular symmetrical arrangement of lines of prismatic colors and dark alternating lines with cross bands, producing a very brilliant effect. An irregular polarization has also been detected in some diamonds. PHOSPHORESCENCE. Several minerals give out light either by friction or when gently heated. This property of emitting light is called phphosphorescence. Two pieces of white sugar struck against one another give a feeble light, which may be seen in a dark place The same effect is obtained on striking together fragments of quartz, and even the passing of a feather rapidly over some specimens of zinc blende, is sufficient to elicit light. Fluor spar is the most convenient mineral for showing phosphorescence by heat. On powdering it, and throwing What is said of the appearance of certain crystals in polarized light What is phosphorescence? Mention examples explainir g the differen modes of exhibiting it. 6 62 PHYSICAL PROPERTIES OF MINERALS. it on a shovel heated nearly to redness, the whole takes on a bright glow. In some varieties, the light is emerald green, in others, purple, rose, or orange. A massive fluor, from Huntington, Connecticut, shows beautifully the emerald green phosphorescence. Some kinds of white marble, treated in the same way give out a bright yellow light. After being heated for a while, the mineral loses its phosphorescence; but a few electric shocks will, in many cases, to some degree, restore it again. ELECTRICITY AND MAGNETISM. ELECTRICITY.-Many minerals become electrified on being rubbed, so that they will attract cotton and other light substances; and when electrified, some exhibit positive, and others negative electricity, when brought near a delicately suspended magnetic needle. The diamond, whether polished or not, always exhibits positive electricity, while other gems become negatively electric in the rough state, and positive only in the polished state. Friction with a feather is sufficient to excite electricity in some varieties of blende. Some minerals, thus electrified, retain the power of electric attraction for many hours, as topaz, while others lose it in a few minutes. Many minerals become electric when heated, and such species are said to be pyro-electric, from the Greek pur, fire, and electric. If a prism of tourmaline, after being heated, be placed on a delicate frame, which turns on a pivot like a magnetic needle, on bringing a magnet near it, one extremity will be attracted, the other repelled, thus indicating the polarity al. luded to. The same is better shown if the ends of the crystal be brought near the poles of a delicately suspended magnetic needle. The prisms of tourmaline have different secondary planes at the two extremities, or, as it is expressed, are hemihedrally modified (page 37.) Several other minerals have this peculiar electric property, especially boracite and topaz, which, like tourmaline, are hernihedral in their modifications. Boracite crystallizes in Will electricity restore the phosphorescent property when it is lost by eating a mineral? What two modes are there of exciting electricity n minerals? What is said of the diamond as compared with other gems? What is a pyro-electric? What is said of tourmaline I wha of topaz and boracite 1 SPECIFIC GRAVITY 63 cubes, with only the alternate solid angles similarly replaced (figs. 40, 41, page 37.) Each solid angle, on heating the crystals, becomes an electric pole; the angles diagonally opposite, are differently modified and have opposite polarity MAGNETISM. —Lodestone includes certain specimens of an ore of iron, called magnetic oxyd of iron, having the power of attraction like a magnet; it is common in many ore beds where this ore of iron occurs. When mounted like a horseshoe magnet, a good lodestone will lift a weight of many pounds. This is the only mineral that has decided magnetic attraction. But several ores containing iron are attracted by the magnet, or, when brought near a magnetic needle, will cause it to vibrate; and moreover, the metals nickel, cobalt, manganese, palladium, platinum and osmium, have been found to be slightly magnetic. Many minerals become attractable by the magnet after being heated, that are not so before heating. This arises from a partial reduction, developing the protoxyd of-iron. SPECIFIC GRAVITY. The specific gravity of a mineral is its weight compared with that of some substance, taken as a standard. For solids and liquids, distilled water at 60 F. is the standard ordinarily used; and if a mineral weighs twice as much as water, its specific gravity is 2; if three times, it is 3. It is then necessary to compare the weight of the mineral with the weight of an equal bulk of water. The process is as follows: First weigh a fragment of the mineral in the ordinary way, with a delicate pair of scales: next sus- 98 pend the mineral by a hair or fiber of silk to one of the scales, immerse it thus suspended in a tumbler of water, (keeping the scales clear of the water,) and weigh it again: subtract the second weight Irom the first, to ascertain the loss by immersion, and divide the first by the dif'ference obtained: the result is the specific gravity. The loss by immersion is What ore is at times possessed of magnetic attraction? What ix said of other minerals as regards magnetism? What is specific gravity t Explain. Mention the mode of ascertaining specific gravity. 64 PHYSICAL PROPERTIES OF MINERALS. equal to the weight of the same bulk of water as the mineral.* A better and more simple process than the above, and one available for porous as well as compact minerals, is performed with a light glass bottle, capable of holding exactly a thousand grains (or any known weight) of distilled water. The specimen should be reduced to a coarse powder. Pour out a few drops of water from the bottle, and weigh it; then add the powdered mineral till the water is again to the brim and reweigh it: the difference in the two weights, divided by the loss of water poured out, is the specific gravity sought The weight of the glass bottle itself is here supposed to be balanced by an equivalent weight in the other scale. HARDNESS. The comparative hardness of minerals is easily ascertained, and should be the first character attended to by the student in examining a specimen. It is only necessary to draw the file across the specimen, or to make trials of scratching one with another. As standards of comparison, the following minerals have been selected, increasing gradually in hardness from talc, which is very soft and easily cut with a knife, to the diamond, which nothing will cut. This table is called the scale of hardness. I, talc, common foliated variety; 2, rock salt; 3, calc spar, transparent variety; 4, Jluor spar, crystallized variety; 5, apatite, transparent crystal; 6, feldspar, cleavable variety; 7, quartz? transparent variety; 8, topaz, transparent crystal; 9, sapphire, cleavable variety; 10, diamond. If on drawing a file across a mineral, it is impressed as easily asfluor spar, the hardness is said to be 4; if as easily as feldspar, the hardness is said to be 6; if more easily than What other mode is fitted for porous as well as compact miners's How is the hardness of minerals ascertained? What is the scale of hardness? Explain its use. What directions are given for trials of hardness? * For perfectly accurate results, the most delicate scales and weight should be used, and great care be observed in the trial. The purity and temperature of the water should also be attended to, and the height of the barometer. For the latter, an allowance is made for any variation from a height of 30 inches. The temperature of water at its mayimum density, or at 390 1 F., is recommended as preferable to 60~ F. FRACTURE. d: feldspar, but with more difficulty than apatite, its hardness is lescribed as 5~ or 5*5. The file should be run across the mineral three or four times, and care should be taken to make the trial on angles equally blunt, and on parts of the specimen not altered b} exposure. Trials should also be made by scratching the specimen under examination with the minerals in the above scale, as sometimes, owing to a loose aggregation of particles, the file wears down the specimen rapidly, although the par tides are very hard. STATE OF AGGREGATION. Solid minerals may be either brittle, sectile, malleable, flexible or elastic. Fluids are either gaseous or liquid. 1. Brittle: when parts of the mineral separate in powder on attempting to cut it. 2. Sectile: when thin pieces may be cut off with a knife'but the mineral pulverises under a hammer. 3. Malleable: when slices may be cut off, and these slices will flatten out under the hammer. Example, native gold and silver. 4. Flexible: when the mineral will bend, and remain bent after the bending force is removed. Example, talc. 5. Elastic: when after being bent, it will spring back to its original position. Example, mica. A liquid is said to be viscous, when on pouring it the drops lengthen and appear ropy. Example, petroleum. FRACTURE. The following are the several kinds of fracture in minerals: 1. Conchoidal: when the mineral breaks with a curved, or concave and convex surface of fracture. The word con. choidal is from the Latin concha, a shell. Flint is a good example. 2. Even: when the surface of fracture is nearly or quite flat. 3. Uneven: when the surface of fracture is rough with numerous small elevations and depressions. 4. Hackly: when the elevations are sharp or lagged, as in broken iron. Explain the use of the term brittle; sectile; malleable, &c. Explaia the use of the term conchoidal; even; uneven. 6* t('! CHEMICAL PROPERTIES OF MINERALS. TASTE. Taste belongs only to the soluble minerals; the kinds are1. Astringent: the taste of vitriol. 2. Sweetish-astringent: the taste of alum. 3. Saline: taste of common salt. 4. Alkaline: taste of soda. 5. Cooling: taste of saltpeter. 6. Bitter: taste of epsom salts. 7. Sour: taste of sulphuric acid. ODOR. Excepting a few gases and soluble minerals, minerals in the dry, unchanged state, do not give off odor. By friction, moistening with the breath, the action of acids and the blow. pipe, odors are sometimes obtained, which are thus designated: 1. Alliaceous: the odor of garlic. It is the odor of burn. ing arsenic, and is obtained by friction and more distinctly by means of the blowpipe from several arsenical ores. 2. Horse-radish odor: the odor of decaying horse-radish. It is the odor of burning selenium, and is strongly perceived when ores of this metal are heated before the blowpipe. 3. Sulphureous: odor of burning sulphur. Friction will elicit this odor from pyrites, and heat from many sulphurets. 4. Fetid: the odor of rotten eggs or sulphuretted hydrogen. It is elicited by friction from some varieties of quartz and limestone. 5. Argillaceous: the odor of moistened clay. It is given off by serpentine and some allied minerals when breathed upon. Others, as pyrargillite, afford it when heated. CHAPTER IV.-CHEMICAL PROPERTIES OF MINERALS. ACTION OF ACIDS. Acids are used in distinguishing certain minerals that are iecomposed by them. The acids employed are either the sulphuric, muriatic, or nitric. Carbonate of lime, (calcaWhat taste is astringent? sweetish astringent? saline? What wilt develop odor in some minerals? What is understood by an alliaceous odor? What mineral when heated produces this odor? What is the odor of fumes of selenium? How is a sulphureous odor obtained from certain minerals? What gas has a fetid odor? What is an argilla. ceous odor? USE OF THR BLOWPIPE. 67 reous spar,) when dropped into either of these acids gives off bubbles of gas, which effect is called effervescence. The same result takes place with some other minerals. The acid used in these tests, should be half water; and to avoid error, it is best to put a little of it in a test tube, and drop in small fragments of the coarsely powdered mineral. Some. times heat will cause an effervescence, which does not take place with cold acid. Often -effervescence arises from some impurity present, which is discontinued before the solution *f the mineral in the acid is complete. Other minerals, that do not effervesce in the acids, become changed to a jelly-like mass. For trials of this kind, the strong acids should generally be used. The powdered mineral is allowed to remain for a while in the acid, and gradually a jelly-like mass is formed. Often heat is required, and in that case, the jelly appears, as the solution cools. The minerals belonging to the zeolite family more especially undergo this change from the action of acids, and it arises from the separation of their silica in a gelatinous state. BLOWPIPE. To ascertain the effect of heat on minerals, a small instru. ment is used called a blow- 100 101 102 pipe. In its simplest form, / I (fig. 100,) it is merely a bent tube of small size, 8 to 10 inches long, terminating at I one end in a minute orifice, not larger than a pin hole. It is used to concentrate the o flame of a candle or lamp on a mineral, and this is done by blowing through it while the smaller end is just within the flame. Figures 101 and 102 ate other forms of the blowpipe, containing air chambers (o) to receive the moisture which's condensed in the tube What is effervescence, and how produced? How should the acid be sed? How are some minerals made to gelatinize? On what does W; o-operty depend? What is the object of a blowpipe? 68 CIfEMICAL PROPERTIES OF MINERALS. during the blowing; the moisture, unless thus removed, is often blown through the small aperture and interferes with the experiment. The air chamber in figure 102 is a cylin. der, into which the tube a b c is screwed at c, and the smaller piece d e f, at d. For the convenience of packing it away, there is a screw at b. The part b c, after unscrewing it, may be run into the part a b, through the large end, (a,) and screwed up again, and thus it is half the length it has when arranged for use. The mouth piece e f screws off, and is made of platinum in order that it may be cleaned when necessary by immersion in an acid. The best material for the blowpipe is silver, or if a cheaper material is desired, tinned iron with the piece ef of brass. Brass gives a disagreeable smell to the moist fingers. In using the blowpipe, it is necessary to breathe and blow at the same time, that the operator may not interrupt the flame in order to take breath. Though seemingly absurd. the necessary tact may easily be acquired. Let the student first breathe a few times through his nostrils, while his cheeks are inflated and his mouth closed. After this practice, let him put the blowpipe to his mouth, and he will find no diffi. culty in breathing as before; while the muscles of the inflated cheeks are throwing the air they contain through the blowpipe. When the air is nearly exhausted, the mouth may again be filled through the nose without interrupting the process of blowing. A lamp with a large wick, so as to give a broad flame. and fed with olive oil, is best; but a candle is more conve. niently carried about when travelling. The wick should be bent in the direction the flame is to be blown. The flame has the form of a cone, yellow without and blue within. The heat is most intense just beyond the extremity of the blue flame. In some trials, it is necessary that the air should not be excluded from the mineral during the experiment, and when this is the case, the outer flame is used. The outer is called the oxydating* flame, and the inner the reducing flame. Explain the structure and mode of use. What is said of the flame of a candle before the blowpipe? Which is the oxydating, and whicL the reducing flame? * It is so called because when thus heated, oxygen, one of the constituents of the atmosphere, combines in many cases with some part? of the assay (or substance under experiment.) USE OF THE BLOWPIPE. 69 The mineral is supported in the flame, either on charLoal or by means of steel forceps, (fig. 103,) with platinum extremities (a b); the forceps are opened by pressing 103 on the pins p p. The charcoal should be firm b and well burnt. Charcoal is especially necessary when the reduction of the assay needs the presence of carbon; and platinum when simple heat is required. Platinum foil for enveloping the mineral, and small platinum cups are also used. When nothing better is at hand, the mineral mica or kyan. ite may be employed. The fragment of mineral under trial should be less than half a pea in size, P and often a thin splinter is required. To test the presence of water or a volatile ingredient, the mineral is heated in a glass tube or test vial. The tube may be three or four inches long and as large as a quill. The flame is directed against the exterior of the tube beneath the assay, and the volatilized substance usually condenses in the upper part of the tube. By inserting into the upper end of the tube a strip of litmus or other test paper, it is ascertained whether the fumes are acid or not. Some species require for fusion the aid of what are calledJluxes. Those more commonly used are borax, salt of phosphorus, and carbonate of soda. They are fused to a clear globule, to which the mineral is added; or powdered and made up into a ball with the moistened mineral in powder. In this way some minerals are fised that' cannot he attacked otherwise, and nearly all species, as they melt, undergo certain changes in color, arising fiom changes in composition, which are mentioned in describing minerals. The above mentioned fluxes also are often required in order to obtain the metals from the metallic ores. On heating a fragment of copper pyrites with borax, a globule of copper is obtained; and tin ore heated with soda yields a globule of tin. What instruments or appliances are used for holding minerals before the blowpipe? How is the presence of water ascertained? How may its acidity be tested? How are the common -luxes employed, and what is their ue? 70 CHEMICAL PROPERTIES OF MINERALs. The following table contains the reactions of some of the metallic oxyds with the. ordinary fluxes:* Borax. Salt of Phosphorus. Soda. Titanic acid 0, colorless or 0, colorless, trp Deep yw, hot; milky w or gyh, cold Oxyd of iron 0, red,hot; ywh 0, red, hot; paler or or colorless, colorless, cold cold R, green or bh gn Oxyd of cerium 0, r; yw on O, fine r, hot; colcooling; w orless, cold enamel on flaming R, colorless or w enamel Oxyd of manga- 0, amethystine 0. amethystine Pi. trp gn,hot nese bh-gn, cold Oxyd of cobalt 0, trp blue 0, blue Pl. pale r, hot gray, cold Oxyd of chrome 0, bn, hot; pale 0, green 0. Pi. dull orgn, cold ange; op & ye\ R, emerald-gn, R, green on cooling cold Oxyd of copper 0, green 0, green Pi. gl, hot; col, R, colorless, R, colorless, hot; r op, cold hot; but sud- on solidifying denly opaque and rdh on cooling _________ cooling ___ The following are other reactions: Nitrate of cobalt in solution added to the assay after heating to redness, and then again heated, Iroduces before fusion a blue color for alumina and a pale-red for magnesia. Boracic acid fused with a phosphate produces a globule, into which if the extremity of a small iron wire be inserted, and the whole heated in the reduction flame, the globule attached to the wire will be brittle, as proved by striking it with a hammer on an anvil. Before this trial it should be ascertained that no sulphuric or arsenic acid is present, which also may form a brittle globule with the iron; nor an) metallic oxyd reducible by the iron. For what is nitrate of cobalt used? How and for what is boracic atid used? * 0 stands for oxydating flame; R for reducing flame; Ch for char coal; trp for transparent; bh bluish; yw yellow; gn green; r red; gyh grayish; w white; Pi in platinum forceps; op opaque. CLASSIFICATION OF MINERALS. 71 Tin-foil is used to fuse with certain peroxyds of metals to reduce them to protoxyds. The assay, previously heated in the reducing flame, should be touched with the end of the tin foil; a very minute quantity of a r.etallic oxyd is thus detected. Saltpeter added along with a flux to a compound contain. ing manganese, gives the amethystine color, when the quan. tity is too small to be detected without it. Potash salts, if there is no soda present, give a slightly violet tinge to the flame. Soda salts give the flame a deep yellow color. Lithia salts give the flame a reddish tinge; the silicate require the addition of some fluor spar and bisulphate of pot. ash. By adding soda and heating on platinum, the lithia stains the platinum brown. Sulphurets, Sulphates. A glass made of soda and silica becomes red or orange yellow when sulphur is present. Heated on charcoal with soda, and then adding a drop of water, they yield sulphuretted hydrogen, which blackens a test paper containing acetate of lead. Sulphurets heated in a glass tube closed below, with litmus paper above, redden the litmus paper, and yield usually a sulphureous odor. Seleniets give off a horse-radish odor. Arseniurets give off an odor like garlic, which is brought out by heating with soda in the reduction flame, if not other. wise perceptible; heated in a tube, orpiment is condensed. Fluorids. Heated with salt of phosphorus, previously melted in a glass tube, the glass is corroded; and Brazil paper placed in the tube becomes yellow. The salt of phosphorus for this trial should be free from all chlorids. Nitrates detonate on burning coals. CHAP. V.-CLASSIFICATION OF MINERALS. Under the term mineral, as explained, are included all inorganic substances occurring in nature. These substan. ces have been found to consist of various elements, some few How and for what is tin-foil used? saltpeter?-What is said of the constitution of minerals? * For fill information on the use of the blowpipe and its reactions here is no better work than B-rzcliu? on " thr Use ol the Blowpipe,"..ranslated by J. O. Whitney. 238 pp. 8vo. Boston. 1845. 72 CLASSIFICATION OF MINERALS. species being each a simple element alone, and others con. sisting of two or more elements in a state of combination The various native metals, as native gold, silver, copper, mercury, are some of the elements. Iron ores are com. pounds of the element iron with some other element or elements, as oxygen, sulphur, or oxygen and carbon, &c. Marble is a compound of three elements, calcium, oxygen and carbon. Water consists of two elements, hydrogen and oxygen. Diamond is the simple element carbon, which is dentical with pure charcoal. All the so-called elements ol matter are found in the mineral kingdom, either in a pure or combined state; and it is the object of chemical analysis to ascertain the proportions of each in the constitution of the several minerals. Upon these results depends to a great degree our knowledge of those relations of the species upon which the classification of minerals is based. The number of elemental substances in nature, according to the most recent results of chemistry, is sixty. Of these, fotrty-severn are metals, and five are gases; the remainder, as, for instance, sulphur and carbon, are solids without a metallic luster, excepting one (bromine) which is a liquid at the ordinary temperature. Of these sixty elements, very much the larger part are o" rare occurrence in nature. The rocks of the globe, with their most common minerals, are made up of about thirteen of the elements. These are the gases oxygen, hydrogen, nitrogen, chlorine; the non-metallic elements carbon, sulphur, silicon; the metals calcium, (basis of lime,) sodium, (basis of soda,) potasszum, (basis of potash,) magnesium, (basis of magnesia,) aluminium. (basis of alumina, the principle constituent of clay,) with iron. The element silicon combined with oxygen, fornls silica. In this state, it is the mineral quartz, the most common in the constitution of the rocks of the globe: it is a constituent of granite, mica slate and the allied rocks, of the hard granular quartz rock; and it is the essential part of all sandstones and millstone grits, as well as the principal ingredient of the sands of the sea shore and of most soils. Combined with lime, potash or soda, magnesia or alumina, and often with iron, it forms nearly all the other mineral in. What is the number of elements, and how many are metals? How mlany constituents are essential to the rocks of the globe, and what are they? What is said of quanrtz 7 CLASSIFICATION OF MINERALS. 73 gredients of granite, mica slates, volcanic rocks, shales, sandstones and various soils. No element is therefore more important than this in the constitution of the earth's strata. and it is specially fitted for this preeminence by its superior hardness, a character it communicates to the rocks in which it prevails. Next to silica, rank lime and carbon; for carbon with oxygen constitutes carbonic acid, and this combined with lime, produces carbonate of lime, the ingredient which, when occurring in extended beds, we call limestone and marble Again, lime combined with sulphur and oxygen, (sulphuric acid,) makes sulphate of lime, or common gypsum. Iron is very generally diffused; it is one of the constituents of many siliceous minerals, and forms vast beds of ore. Oxygen, as has been implied, is a constituent in all the rocks above mentioned, and besides, is an essential part of the atmosphere and water; it is the most universally diffused of the elements. It is united with hydrogen in the constitution of water, and with nitrogen in the constitution of the atmosphere. Chlorine combined with sodium constitutes common salt, which occurs in sea water and brine springs, and is also found in vast beds in some rock strata. It is thus seen how few are the elements essential to the framework of our globe. The various metallic ores, of less general diffusion, are however of vast economical importance to man, and multiply considerably the number of mineral species. Those important to the general student, however, are comparatively few. The whole number of well established species in the mineral kingdom is about 600; ofthese, more than two-thirds are known only to the mineralogist. It is the province of chemistry to discuss fully the nature of the elements, and their modes of combination. It is slfficient to add here, for the benefit of any who may not have the requisite elementary chemical knowledge, how the chermical names of minerals indicate their composition. Terms such as oxyd of iron, chlorid of iron, express a combnination of iron with the element oxyg;n, or chlorine; so also sulphuret of iron is a comp)ound of iron with sulphur.'Ihe force of the terminations id or uret is always as hl-re explained. Protoxyd and peroxyd imply different proportions Which are the next mo-t cominin ingredients of rocks? Mention the other ingredients a.llud'l to. WiNhat is an oxyvl i a chlorid? a su1phuret! a carhllbol te 74 CLASSIFICATION OF MINERALS. of oxygen, the latter the highest. Terms such as carbonate of lime, sulphate of lime, indicate that the substance is com. posed of an acid-carbonic acid, or sulphuric acid in the instances cited, with lime. So silicate of soda is a com. pound of soda and silicic acid (or silica); and all such compounds are theoretically said to consist of an acid and a baselime and soda, in the cases mentioned, being bases. The true foundation of a species in mineralogy must be derived from crystallization, as the crystallizing force is funda. mental in its nature and origin; and it is now generally admit. ted that identity oJ crystalline form and structure is evidence of identity of species. This principle unites certain distinct chemical compounds into the same species:-for example, a silicate of magnesia and a silicate of iron crystallizing alike, constitute but one species in mineralogy, though chemically st different. Oxyd of iron and magnesia are themselves neariy identical in molecularform and size, and on this fact depends Lteir power of replacing one another even in com. paOx compouls. They are therefore said to be isomorphous (froin the Greek;sos, similar, and morphe, form.) The;s are many g'oups of these isomorphous substances, and somt knowledge of them is necessary to enable the reader to understand why different varieties of a mineral species may dffer so widely, as they often do, in composition. Some of these groups are as follows: 1. Alumina, peroxyd of iron, peroxyd of manganese. 2. Lime, magnesia, protoxyds of iron, manganese and zinc. 3. Baryta, strontia, oxyd of lead. 4. Sulphur, selenium, tellurium. 5. Tungsten, molydenum. 6. Phosphoric acid, arsenic acid. In epidoto the alumina may be replaced by peroxyd of iron or manganese, and the magnesia in part or wholly by lime, or the protoxyds of iron or manganese. The same i, true of garnet bnd several other minerals. The rhombohedrons of carbonate of lime, carbonate of iron, and carbonate. tf magnesia, are very nearly identical in angle, because the bazes are ismorphous. This subject is illustrated by the greater part of mineral species. What a a sulphate? a silicate? What is the tes' of identity of sirtts in mnineralogy? What are isomorphous substances What..~;.: conmmnn groups of isomorphous substances in minerals? Ex",. examnp.os. CLASSIFICATION OF MINERALS. 75 GENERAL VIEW OF THE CLASSIFICATION OF MINERALS. The classification adopted in this work is based on the constitution of minerals. The following is a general view of it: CLASS I. Gases: consisting of or containing nitrogen oi hydrogen. CLASS II. Water. CLASS III. Carbon, and compounds of carbon. CLASS IV. Sulphur. CLASS V. Haloid minerals: compounds of the alkalies and earths, with the soluble acids (sulphuric, nitric, carbonic. &c. or water,) or of their metals with chlorine or fluorine. 1, Salts of ammonia; 2, of potash; 3, of soda; 4, of baryta 5, of strontia; 6, of lime; 7, of magnesia; 8, of alumina. CLASS VI. Earthy minerals: silica and siliceous or alu. minous compounds of the alkalies and earths-I, silica; 2, lime; 3, magnesia; 4, alumina; 5, glucina; 6, zirconia 7, thoria. CLASS VII. Metals and metallic ores, (exclusive of the metals of the alkalies and earths): 1, Metals easily oxydizable-cerium, yttrium, titanium, tin, molybdenum, tungsten, vanadium, tellurium, bismuth, antimony, arsenic, uranium, iron, manganese, chromium, nickel, cobalt, zinc, cadmium, lead, mercury, copper; 2, Noble metals: platinum, iridium, palladium, gold, silver. Exoiain the classification' adopted 76 GOAEOUtT MINERALJ. @LASS I.-GASES) The gases occurring native are as follows: 1. containing er consisting op nitrogen: atmosl)heric air, nitrogen. 2. containing hydrogen: carbureted hydrogen, phosphureted hydrogen, sulphureted hydrogen, muriatic acid. 3. containing carbon or sulphur: carbonic acid, sulphurous acid. ATMOSPHERIC AIR 1. Atmospheric air is the air we breathe It consists of oxygen 21 per cent. by weight, and nitrogen. 79 per cent., with a small proportion of carbonic acid. It has neither color odor, nor taste. It supports life and combustion through the oxygen which it cpntains, this gas being used or absorbed in respiration as well as in the burning of wood or a. candle. The oxygen thus consumed is restored to the air again by vegetation which gives out oxygen through the day, and in this way the quality of the atmosphere requisite for life is sustained.!T is about 815 times lighter than water, and 11,065 time? lighter than mercury. A hundred cubic inches weigh abcs 31 grains. NITROGEN GAS. Nitrogen destroys life, and has neither color, odor nor taste. It is one of the constituents of the atmosphere. It bubbles up through the waters of many springs, having been derived from air by some decompositions in progress within the earth, by which the oxygen of the air is absorbed. Lebanon springs in Columbia county, New York, and a region in the town of Hoosic, Rensselaer county, afford large quantities of this gas. There is another locality at Canoga, Seneca county, where the water is in violent ebullition from the escape of the gas; its temperature is 40' F. There are other nitrogen springs in Virginia, west of the Blue Ridge at Warm and Hot Springs; in Buncombe county, N. C.; and on the Washita in Arkansas. At Bath, in England, nitrogen is escaping from the tepid springs at the What gases occur in nature? What is the constitution of the atmosphere? its general characters? the weight? What is said of the characters of nitrogen? Where does nitrogen occur in nature? GASES CONTAINING IYD)RO EN. 77 rate of 267 cubic inches a minute, or 222 cubit feet a day. The gas from these nitrogen springs contains only 2 or 3 per cent. of oxygen, and often a very little carbonic acid. CARBURETTED HYDROGEN. Carburetted hydrogen consists of carbon 75, hydrogen 25 burns with a bright yellow flame. It is the same gas nearly that is used for lighting the streets in some of our cities. I issues abundantly from some coal beds and beds of bitumi nous slate. At Fredonia, in western New York, near Lak Erie, it is given out so freely from a slate rock, that it i used for lighting the village. A vessel containing 220 cubi feet is filled in about 15 hours. A light-house at Portland harbor, on Lake Erie, four miles from Fredonia, is also lighted with the same gas from other springs. Another carburetted hydrogen, burning with a pale blue flame, rises in bubbles through pools of water, owing to vegetable decomposition in the soil beneath. PHOSPHURETTED HYDROGEN. Phosphuretted hydrogen consists of phosphorus 91'29, and hydrogen 8'71. It takes fire spontaneously. The phos. phoric matter, called Jack-o'-lantern, sometimes seen float. ing over marshy places, is supposed to be phosphureted hydrogen. SULPIIURETTED HYDROGEN. Sulphureted hydrogen consists of sulphur 94'2, hydrogen 5'8. It has the odor and taste of putrescent eggs and burns with a bluish flame. It is abundant about sulphur springs, issuing freely from the waters, as in western New York and in Virginia. It is sometimes found about volcanoes. It blackens silver and also a common cosmetic made of oxyd of bismuth. MURIATIC ACID.-Hydrochloric Acid. Muriatic acid gas consists of hydrogen 2'74, chlorine 97'26. It has a very pungent odor and is acrid to the skin What is the composition of carbureted hydrogen? its general charac ters? mode of occurrence in nature? What is said of Fredonia Mention the characters of phosphureted hydrogen; the characters of sulphureted hydrogen; its mode of occurrence. What is said of muri atic acid? 7* 78 WATER. It is rapidly dissolved by water. If passed into a solution of nitrate of silver, it produces a white precipitate which soon blackens on exposure. It is given out occasionally by volcanoes.* CLASS II.-WATER. Water (oxyd of hydrogen) is the well known liquid of our streams and wells. The purest natural water is obtained by melting snow, or receiving rain in a clean glass vessel; but it is absolutely pure only when procured by distillation. It consists of hydrogen 1 part by weight, -and oxygen 8 parts. It becomes solid at 32 Fahrenheit, (or 0 Centigrade) and then crystallizes, and constitutes ice or snow. Flakes of r9f XV^ snow consist of a congeries of minute crys. tals, and stars like the annexed figure may TORV V v^ often be detected with a glass. Various Hi^ D other allied forms are also assumed. The _A< I rays meet at an angle of 60, and the branchlets pass off at the same angle with perfect regularity. The density of water is greatest at 39 1 F.; below this it expands as it approaches 32~, owing to incipient crystallization. It boils at 212 F. A cubic inch of pure water at 60 F. and 30 inches of the barometer, weighs 252'458 grains. A pint, United States standard measure, holds just 7342 troy grains of water, which is little above a pound avoirdupois (7000 grains troy.) Water as it occurs on the earth, contains some atmospheric air, without which the best would be unpalatable. This air, with some free oxygen also present, is necessary to the life of water animals. In most spring water there is a minute proportion of salts of lime, (sulphate, chlorid or carbonate,) often with a trace of common salt, carbonate of magnesia and some alumina, iron, silica, phosphoric acid, carbonic acid, and certain vegetable acids. These impurities constitute usually from - to 10 parts, in 10,000 parts by weight. The Long Pond water, used in Boston, Of what does water consist? What is said of snow and ice? What of the density of water? its boiling temperature? the weight of a pint? What are the usual impurities of common spring or river water? * Carbonic acid and sulphurous acid gases, are described, one under carbon, and the other under sulphur. (.ASE:S OON'TAINING HYDROGEN. 79 -.ontainl a:bou.t I a pil: in 10,0}00; the Schuylkill of Phila. delphia, about 1 part in 10,0}00; the Croton, used in New York city, 1 to 1- parts in 10,000. In the Schuylkill water the constituents of the 1 part of solid ingredients were, chlorid of sodium 1 47, chlorid of magnesium 0-094, sulphate of magnesia 0'b7, silica 0-8, carbonate of lime 18-72, carbonate of magnesia 3'51, carbonate of soda and loss 16414.* The water towards the surface is always purer than that below. Sea water contains 32 to 37 parts of solid substances in solution in 1000 parts of water. The largest amount in the Atlantic, 36-6 parts, is founid under the equator, away fiom the lald or the vicinity of fiesh water streams; and the smnailest in narrow straits, as Dover Straits where there are only 32'5 partr. In the Baltic and the Black Sea, the proportion is only one-third that in the open ocean. Of the whole, oneh[:lf'to two-thirds is common salt (chlorid of sodium.) The other ingredients are magnesian salts, (chlorid and sulphate,) amounting to four-fifths of the remainder, with sulphate and carbonate of lime, and traces of bromids, iodids, phosphates and fluorids. The water of the British channel affords, water 964-7 parts in 1000, chlorid of sodium 27'1, chlorid of potassium 0'8, chlorid of magnesium 3'7, sulphate of magnesia 2-30, sulphate of lime 1*4, carbonate of lime 0-03, with some bromid of magnesium, and probably traces of iodids, fluorids and phosphates. The bitter taste of sea water is owing to the salts of magnesia present. The waters of the Dead Sea contain 200 to 250 parts of solid matter in 1000 parts, (or 20 to 25 per cent.,) including 7 to 10 per cent. of common salt, the same proportion of magnesian salts principally the chlorid, 2~ to 3~ per cent. of carbonate and sulphate of lime, besides some bromids and alumina. The density of these waters is owing to this large proportion of saline ingredients. The brine springs of New York and other states south and west, are well known sources of salt, (see beyond under common salt.) Many of the springs afford bromine, and large quantities of it are manufactured for making daguerreotype plates and other purposes. What proportion of solid substances in sea water, and of this what roportion is common salt? What proportion magnesian salts? What s the bitter taste of sea water owing to? * Chem. Exam. by B. Silliman, Jr, Jour. Sci., ii ser., ii, 218. SO ('ARHON. Mineral waters vary much in constitution. They oftt n contain carbonate of iron, like those of Saratoga and Balls. town, and are then called chalybeate waters, from the ancient name for iron or steel, chalybs, derived from the name of a country on the Baltic. The water of Congress Spring, according to Dr. Steel, contains in a pint, chlorid of sodium 48'1, bicarbonate of magnesia 12-0, carbonate of lime 12*3 carbonate of iron 0-6, silica 0'2, iodid of sodium nearly 0.5 with a trace of bromid of potash; of carbonic acid 39'0 cubi inches and nearly I cubic inch of atmospheric air. Minute traces of salts of zinc and arsenic, lead, copper antimony and tin, have been found in some waters. What ever is soluble in a region through which waters flow, will of course be taken up by them, and many ingredients are soluble in minute proportions, which are usually described as insoluble. CLASS III.-CARBON AND COMPOUNDS OF CARBON. Carbon occurs crystallized in the diamond. In a massive form, and more or less pure state, it constitutes the various kinds of mineral coal. Combined with hydrogen, or hydrogen and oxygen, it forms bitumen, amber, and a number of native mineral resins. DIAMOND. Monometric. In octahedrons, dodecahedrons and more complex forms. Faces often curved, as in the annexed figures. Cleavage octahedral; highly perfect. 1 a 3 4 Color white or colorless; also yellowish, red, or,'ngt, What are chalybeate waters? What is the difference between the diamond and charcoal? What is the crystallization of the diamond What other chara ters are mentioned? THE DIAMOND. 81 green, broxv n or black. L ister adamantine. Transparent translucent when dark colored. H = 10. Gr = 3-483 55. Composition. Pure carbon. It burihl and is consumed at a high temperature, producing carbonic a.id gas. Exhibits vitreous electricity when rubbed. Some specimens exposed to the sun for a while, give out light when carriedto a dark place. Strongly refracts and disperses light. Dif. Diamonds are distinguished by their superior hard ness; their brilliant reflection of light and adarantine luster their vitreous electricity when rubbed, which is not afforde by other gems unless they are polished; and by the prac ticed ear, by means of the sound when rubbed together. Obs. Diamonds occur in India, in the district between Golconda and Masulipatam, and near Parma, in Bundelcund, where some of the most magnificent specimens have been found; also on the Mahanuddy, in Ellore. In Borneo, they are obtained on the west side of the Ratoos mountain, with gold and platina. The Brazilian mines were first discovered in 1728, in the district of Serra do Frio, to the north of Rio de Janeiro; the most celebrated are on the river Jequitinhonha, which is called the Diamond river, and the Rio Pardo; twenty-five to thirty thousand carats are exported annually to Europe from these regions. In the Urals of Russia they had not been detected till July, 1829, when Humboldt and Rose were on their journey to Siberia. The river Gunil, in the province of Constantine, in Africa, is re. ported to have afforded some diamonds. In the United States, the diamond has been met with, in Rutherford county, North Carolina, (fig. 4,) and Hall county, Georgia. The original rock in Brazil appears to be either a kind of laminated granular quartz called itacolumite; or a ferruginous quartzose conglomerate. The itacolimite occurs in the Urals, and diamonds have been found in it; and it is also abundant in Georgia and North Carolina. In India, the rock is a qIlartzoae conglomerate. The origin of the diamond has been a subject of speculation, and it is the prevalent opinion that the carbon, like that of coal, is of vegetable origin. Some crystals have been found with black uncrystallized particles or seams within, looking like coal; and this fact has been supposed to prove their vegetable origin. How is the diamond distinguished? What are its principal localitiesl 82 CARBON. Diamonds with few exceptions are obtained from alluvial washings. In Brazil, the sands and pebbles of the diamond rivers and brooks (the waters of which are drawn off in the dry season to allow of the work) are collected and washed under a shed, by a stream of water passing through a succession of boxes. A negro washer stands by each box, and inspectors are stationed at intervals. When a diamond is found weighing 17~ carats, the negro is entitled to his liberty. The largest diamond of which we have any knowledge is mentioned by Travernier, as in the possession of the Great Mogul. It weighed originally 900 carats, or 2769*3 grains, but was reduced by cutting to 861 grains. It has the form and size of half of a hen's egg. It was found in 1550, in the mine of Colone. The diamond which formed the eye of a Braminican idol, and was purchased by the Empress Catharine II. of Russia from a French grenadier who had stolen it, weighs 193 carats, and is as large as a pigeon's egg. The Pitt or regent diamond is of less size, it weighing but 136-25 carats, or 4194 grains; but on account of its unblemished transparency and color, it is considered the most splendid of Indian diamonds. It was sold to the Duke of Orleans by Mr. Pitt, an English gentleman, who was gover. nor of Bencolen, in Sumatra, for ~130 000. It is cut in the form of a brilliant, and is estimated at ~125,000. The Rajah of Mattan has in his possession a diamond from Borneo, weighing 367 carats. The Koh-i-noor, on its arrival in Englatld, wAcig(hed 186.016 carats. It has since been re-cut andi rdii'td onr tlhir l in weight. The diamonds of Brazil are seldom large. Maure mentions one of 120 carats, )but they rarely exceed 18 or 20. One weighing 2541 carats, called the " Star of the South," was found in 1854. It will be reduced one-half in cutting. Diamonds are valued according to their color, transparency and size. When limpid (of pure water) and no extraordinary magnitude, the value of a wrought diamond is estimated by first ascertaining the weight in carats.* The How are diamonds obtained? How are diamonds valued? * A carat is a conventional weight, and is divided into 4 grains, which are a little lighter than 4 grains troy; 74 1-16 carat grains are qual to 72 troy grains. Th( term carat is derived from the name of bean in Africa, which, in a dried state, has long been used in that country for weighing gold. These beans were early carried to India and were employed there for weighing diamonds. THE DIAMOND. 83 rule given is as follows: double the weight in calats, ana multiply the square of the product by ~2. Thus a wrought diamond weighing 1 carat, would be worth ~8; one of 4 carats, ~128; one of 10 carats, ~800. Above 20 carats. the prices rise much more rapidly. A flaw, however mi. nute, or the slightest smokiness, diminishes very much the value. The average price of rough diamonds, of first quality, of 1 carat, is ~2; of 2 carats, ~8, since it loses half its weight in cutting, and becomes then one of 1 carat wrought. The rule just given is scarcely regarded in market, as so much depends upon the purity of water. In different countries, moreover, the standard of taste as regards diamonds is very different, the market in England demanding the very first quality, while in other countries a somewhat inferior kind satisfies the purchaser. The rose diamond is more valuable than a snow-white diamond, owing to the great beauty of its color and its rarity. The green diamond is much esteemed on account of its color. The blue is prized only for its rarity, as the color is seldom pure. The black diamond, which is uncommonly rare and without beauty, is highly prized by collectors. The brown, gray and yellow varieties are of much less value than the pure white or limpid diamond. The diamond is cut by taking advantage of its cleavage, and also by abrasion with its own powder and by friction with another diamond. The flaws are first removed by cleaving it; or else by sawing it with an iron wire, which is covered with diamond powder-a tedious process, as the wire is generally cut through after drawing it across five or six times. After the portion containing flaws has thus been cut off, the crystal is fixed to the end of a stick, in a strong cement, leaving the part } rejecting which is to be cut; and another being prepared in the same manner, the two are rubbed together till a facet is produced. By changing the position, other facets are added in succession till the required form is obtained. A circular plate of soft iron is then charged with the powder produced by the abrasion, and this, by its revolution, finally polishes the stone. To complete a single facet often requires several hours. Diamonds were first cut n Europe, in 1456, by Louis Berquen, a citizen of Bruges; How are diamonds cut? 84 CARBON. but in China and India, the art of cutting appears to have been known at a very early period. By the above process, diamonds are cut into brilliant, rose and table diamonds. The brilliant has a crown or uppei part, consisting of a large central eight-sided facet, and a series of facets around it; and a collet, or lower part, of pyramidal shape, consisting of a series of facets, with a smaller series near the base of the crown. The depth of a brilliant is nearly equal to its breadth, and it therefore requires a thick stone. Thinner stones, in proportion to the breadth, are cut into rose and table diamonds. The surface of the rose diamond consists of a central eight-sided facet of small size, eight triangles, one corresponding to each side of the table, eight trapeziums next, and then a series of sixteen tri. angles. The collet side consists of a minute central octagon, surrounded by eight trapeziums, corresponding to the angles of the octagon, each of which trapeziums is subdivided by a salient angle into one irregular pentagon and two triangles. The table is the least beautiful mode of cutting, and is used for such fragments as are quite thin in proportion to the breadth. It has a square central facet, surrounded by two or more series of four-sided facets, corresponding to the sides of the square. Diamonds have also been cut with figures upon them. As early as 1500, Charadossa cut the figure of one of the Fathers of the church on a diamond, for Pope Julius II. Diamonds are employed for cutting glass; and for this purpose only the natural edges of crystals can be used, and those with curved faces are much the best. Diamond dust is used to charge metal plates of various kinds for jewelers, lapidaries and others. Those diamonds that are unfit for working, are sold for various purposes, under the name of bort. Fine drills are made of small splinters of bort, which are used for drilling other gems, and also for piercing holes in artificial teeth and vitreous substances generally. The diamond is also used for lenses for microscopes. When ground plano-convex, they have but slight chromatic aberration, and consequently a larger field, and but little loss of light, compared with similar lenses of other materials. They often have an irregularity of structure when perfectly What are the three forms usually given the diamond? For wna' purposes are diamonds used? MINERAL COAL. 85 pellucid, which unfits them for this purpose, and such lenses therefore are seldom made. MINERAL COAL. Massive. Color black or brown, opaque. Brittle oi sectile. H 1 -- 2-5. Gr- 1'2-175. Composition. Carbon, with usually a few per cent. of silica and alumina, and sometimes oxyd of iron; often con. tains a large proportion of bitumen. The bituminous varie ties burn with a bright flame and bituminous odor; while those destitute of bitumen afford only a pale blue flame, arising from the decomposition of the water present and the formation of the gas called carbonic oxyd. VARIETIES.-1. Without bitumen. Anthracite. Anthracite (called also glance coal and stone coal) has a high luster, and is often iridescent. It is quite compact and hard, and has a specific gravity from 1'3 to 1 75. It.'ually contains 80 to 90 per cent. of carbon, with 4 to 7 of water, the rest consisting of earthy impurities There is often some bitumen present. in which case it burn with colsidcrable flame. Besides 0the use of anthracite for fuel, it is often made into inkstands, small boxes, and other articles, which have a high polish, and fine specimens of this kind of ware may be ob. tained in Philadelphia. 2. Bituminous varieties. Bituminous coal varies much and indefinitely in the amount of bitumen it contains, and there is a gradual passage in its varieties into varieties of anthracite. It is softer than anthracite and less lustrous. The specific gravity does not exceed 1'5. Pitching or caking coal, as it is distinguished in England, at first breaks when heated, into small pieces, which, on raising the heat, again unite into a solid mass. Its color is velvet or grayish black. It burns readily with a lively yellow flame. but requires frequent stirring to prevent its caking, and so clogging the fire. The principal beds at Newcastle, England, afford this kind of coal. Cherry coal resembles pitch coal in appearance, but does not soften and cake. It Of what does mineral coal consist? How does anthracite diffel from other varieties? CARBON. i''very brittle, and in mining there is consequently much \a.ste. It burns with a clear yellow flame. It occurs at the Glasgow coal beds, and i. named from its luster and beauty. The splint coal (or hard coal) of the same region is harder than the cherry coal. Cannel coal is very compact and even in texture, witl little luster, and breaks with a large conchoidal fracture. It takes fire readily, and burns without melting with a clear yellow flame, and has hence been used as candles-whence the name. It is often made into inkstands, snuff-boxes and other similar articles. Brown coal, wood coal, lignite, are names of a less perfect variety of coal, usually having a brownish black color, and burning with an empyreumatic odor. It has often the structure of the original wood. The term brown coal is, however, applied generally to any coal more recent in origin than the era of the great coal beds of the world, although it may not have any distinct remains of a woody structure, or burn with an empyreumatic odor. The name lignite has sometimes the same general application, though without strict propriety. Jet resembles cannel coal, but is harder, of a deeper black color, and has a much higher luster. It receives a brilliant polish, and is set in jewelry. It is the Gagates of Dioscorides and Pliny, a name derived from the river Gagas, in Syria, near the mouth of which it was found, and the origin of the term jet, now in use. Obs. Mineral coal occurs in extensive beds or layers, interstratified with different rock strata. The associate rocks are usually clay shales (or slaty beds) and sandstones; and the sandstones are occasionally coarse grit rocks. There are sometimes also beds of limestone alternating with the other deposits. In a vertical section through the coal measures-as the series of rocks and coal seams are usually called-there may be below, sandstones and shales in alter. nating layers, or sandstones alone and then shales; there may next appear upon the shale a bed or layer of coal, one, two or even thirty feet thick; then above the ccal, other layers of shale and sandstone; and then another layer of coal; again shale and sandstones in various alternations, or What is cannel coal? brown coal or lignite? jet? How do beds of coal occur, and what are the associated rocks? MINERAL COAL. 87 perhaps layers of limestone; and then a h.ird bed of coal, and so on. By such alternations the series is completed. Immediately in the vicinity of the coal, the rock is generally rather a shale than a sandstone, and these shales are usually full of impressions of leaves and stems of plants. The clay shales are sometimes quite soft and earthy, and of a light clay color; but in most coal regions they are hard and firm, with a brownish or black color, in the vicinity of the coal layer. The sandstones are either of a grayish, bluish, or reddish color. These various layers constituting coal oeds, are some, times nearly or quite horizontal in position, as in New Hol. land and west of the Appalachians. They are very often much tilted, dipping at various angles and sometimes vertical, as is generally the case throughout central Pennsylvania; and in some cases the beds are raised in immense folds, as the leaves of a book may be folded, by a sidewise pressure. They are very commonly intersected by fractures, along which the coal seam on one side is higher or lower than on the other, owing to a dislocation, (then said to be faulted); and miners working in a bed for a while, in such a case, find it to terminate abruptly, and have to explore above or'below for its continuation. These are points of great importance in the mining of coal. There is no infallible indication of the presence of coal distinguishable in the mineral nature of rocks; for just such rocks as are here described occur where no coal is to be found, and where none is to be expected. The presence of fossil leaves of ferns, and of plants having jointed stems or a scarred or embossed surface, in the shales or sandstone, is a useful hint; the discovery of the coal itself a much better one. The geologist ascertains the absence of coal from a region by examining the fossils in the rocks; these fossils being different in rocks of different ages, they indicate at once whether the beds under investigation belong to what is called the coal series. If they contain certain trilobites, and other species which are found only in more ancient rocks, there is no longer a doubt that coal is not to be ob. tained in any workable quantities; and he arrives at the same conclusion if the remains are those of more recent What is said of the position of the beds? How do the rocks indicate whether coal is to be expected in a region or not? 88 CARBION. rocks, such as fossil fish of certain genera, or the remains or traces of birds or quadrupeds, or of such species of shells as never occur as low in the rocks as true coal teds. But if the fossils are such as have been described as characterizing a coal series, there is then reason for exploration. It is impossible in this place to give such knowledge as will be practically useful. The inquirer must refer to treatises on geology, or better to the practical geologist, whose judgment in such questions might often have saved much useless mining and wasted expenditure. Mineral coal is very widely distributed over the world England, France, Spain, Portugal, Belgium, Germany, Austria, Sweden, Poland and Russia, have their beds of mineral coal. It is also abundant in India, China, Madagascar, Van Diernen's Land, Borneo and other East India Islands, New Holland, and at Conception in Chili. But no where is the coal formation more extensively displayed than in the United States, and in no part of the world are its beds of greater thickness, more convenient for working, or more valuable in quality. There are four extensive areas occupied by this formation. One of these areas commences on the north, in Pennsylvania and southeastern Ohio, and sweeping south over western Virginia and eastern Kentucky and Tennessee, to the west of the Apalachians, or partly involved in their ridges, it continues to Alabama near Tuscaloosa, where a bed of coal has been opened. It has been estimated to cover 63,000 square miles. It embraces several isolated patches in the eastern half of Pennsylvania. A second coal area (the Illinois) lies adjoining the Mississippi, and covers the larger part of Illinois, the western part of Indiana, and a small northwest part of Kentucky; it is but little smaller than the preceding. A third occupies a portion of Missouri west of the Mississippi. A fourth covers the central portion of Michigan. Besides these, there is a smaller coal region (a fifth) in Rhode Island, which appears near Portsmouth, not far firom the railroad to Boston, and also in Mansfield, Massao chusetts. Out of the borders of the United States, on the northeast, commences a sixth coal area, that of Nova Scotia and New Brunswick, which covers 10,000 square miles, What is said of the distribution of coal over the glebe? How many coal areas are there in the United States, and what their positions What is said of the Nova Scotia and New Brunswick coal beds? M7IIERiAL COAL.. 2500 square miles of which are in Nova Scotia At Cape Breton is still another field of coal. The coal of Rhode Island and eastern Pennsylvania is anthracite. Going west in Pennsylvania, the anthracite becomes more and more bituminous; and at Pittsburg, at its western extremity, as also throughout the western states, it is wholly of the bituminous kind. The Rhode Island variety is so hard and compact and free from all volatile ingredients, that for many years it had been deemed unfit for use. The anthracite of eastern Pennsylvania affords 3 to 6 per cent. of aqueous vapor, and I to 4 per cent. of volatile combustible matter. In the Bradford coal field, lying near the eastern limits of the bituminous coal deposits, Prof. Johnson obtained I to 8 per cent. of moisture, 9 to 15 per cent. of incondensable gas, 5 to 17 of earthy matter, and 62 to 75 of carbon. In the bituminous coal of the Portage railroad, Cambria county, Penn., he obtained 18'2 per cent. of volatile com. bustible matter; in that of Caseyville, Ky., and Cannelton, Indiana, 30 to 34 per cent.; and in a coal from Osage river, Missouri, 41-35 per cent. The general fact that the proportion of bitumen increases as we go westward, is here well exhibited. Some of these results, derived from an extensive series of experiments, are thus averaged by Prof. Johnson: Moisture. Vol. Combustible!Ashes andl Fixed MoI.Miatter.! Clinker. Carbon Pennsylvania anthra- 134 384 737 8745 cites, Maryland free burn- 12580 994 7301 ing bituminous coal Pennsylvania free burning bituminous 0-82 17-01 13-35 68-82 coal, ) Virginia bituminous, 1-64 36-63 10-74 50-99 Cannelton, Indiana, Cannebituminous, 2'20 33'99 4'97 58'44 It has also been shown that this fact is connected with the geological condition of the country, the anthracite occurring in the east where the rocks are variously uplifted and thrown out of position by subterranean forces, evincing also other What is the relative geographical position of the anthracite and bituminous coal in the United States? What has probably made the dif ference in these two kinds of coal? 8* 40 CARBON. efTects of heat besides this debituminisation of the coal; while the bituminous coal occurs where such disturbances of the rocks have not taken place: and the amount of bitumen increases as we recede from the region of greatest disturbance. The heat and attendant siliceous solutions have therefore been the means of giving unusual hardness to the Rhode Island coal. Owing to the various upliftings or foldings of the strata and subsequent denudations, the beds are often exposed to view in the sides of hills or ridges, and the coal in Pennsylvania is In most cases rather quarried out than mined. The layers are at times 20 to 35 feet thick, without any slaty seams, and the excavations appear like immense caverns, whose roofs are supported by enormous columns of coal, " into which a coach and six might be.driven and turned again with ease." Besides the great coal beds of the coal era, as it is significantly called, there are small beds, sometimes workable, of a more recent date. The bed near Richmond, Va., belongs to a subsequent period; there are also beds in Yorkshire, and at Brora in Sutherland. Tertiary coal occurs in Provence, and also in Oregon on the Cowlitz. These beds of more recent coals are seldom sufficiently extensive to pay for working, and are often much contaminated by pyrites. The amount of anthracite worked in 1820, in Pennsylvania, was only 380 tons; in 1847, it amounted to more than 3,000,000 tons; and the whole amount of both anthracite and bituminous coal worked in that state, in 1847, was not less than 5,000,000 tons. In Great Britain, the annual amount of coal mined is about 35,000,000 of tons. The uses of mineral coal are well known. The Pennsylvania anthracite was first introduced into blacksmithing in 1768 or 1769, by Judge Obadiah Gore, a blacksmith, who early left Connecticut for Wilkesbarre. It is now employed in smelting iron ores, and for nearly every purpose in the arts for which charcoal was before employed. The formation of coke from pit coal, for smelting iron, is done in close furnaces or ovens. After heating up, the coal (about two tons) is thrown in at a circular opening at top, and remains for 48 hours; the doorway is gradually closed to shut off the air as the combustion increases, and finally dhe atmosphere is wholly shut off, and in this condition it How is coke prepared? GRAPHITE. 91 remains for 12 hours. The volatile matter is thus expelled, and the cokes produced are ponderous, extremely hard, of a light gray color, and having a metallic luster. To make another kind of coke, like charcoal, the pit coal is placed in a receptacle more like a baker's oven, and the air has more free access. Both of these kinds of coke are used in smelting. GRAPHITE.-Plumbago. Occasionally in six-sided prisms, with a transversely foliated structure. Usually foliated, and massive; also granular and compact. Luster metallic, and color iron black to dark steel gray. Thin laminae flexible. H = 1-2. Gr=2-09. Soils paper, and feels greasy. Composition. 90 to 96 per cent. of carbon, with the rest iron. Some specimens from Brazil contain scarcely a trace of iron. It is often called carburet of iron, but is not a chemical compound. It is infusible before the blowpipe, Doth alone and with reagents; it is not acted upon by acids. Dif. Resembles molybdenite, but differs in being unaffected by the blowpipe and acids. The same characters distinguish the granular varieties from any metallic ores they resemble. Obs. Graphite (called also black lead) is found in crystalline rocks, especially in gneiss, mica slate and granulai limestone; also in granite and argillite, and rarely in greenstone. Its principal English locality is at Borrowdale, in Cumberland. Ure observes that this mineral became so common a subject of robbery, a century ago, as to have enriched many living in the neighborhood; a body of miners would break into the mine and hold possession of it for a considerable time. The place is now protected by a strong building, and the workmen are required to put on a working dress in an apartment on going in and take it off on coming out. In an inner room two men are seated at a large table assorting and dressing the graphite, who are locked in while at work and watched by the steward from an adjoining room, who is armed with two loaded blunderbusses. This is leemed necessary to check the pilfering spirit of the CumWhat is the appearance of graphite? What is its prominent char-'tristic? its composition? Where does it occur? Where is it worked England? 92 GRAPHITE. berland mountaineers. In some years the net produce of the six weeks' annual working of the mine, has amounted to ~40,000. In the United States, graphite occurs in large masses in veins in gneiss at Sturbridge, Mass. It is also found in North Brookfield, Brimfield and Hinsdale, Mass.; at Roger's rock, near Ticonderoga; near Fishkill landing in Dutchess county; at Rossie, in St. Lawrence county, and near Amity in Orange county, N. Y.; at Greenville, L. C.; in Cornwall, near the Housatonic, and in Ashford, Ct.; near Attle. boro, in Buck's county, Penn.; in Brandon, Vermont; in Wake, North Carolina; on Tyger river, and at Spartanburg, near the Cowpens furnace, South Carolina. For the manufacture of pencils the granular graphite has been preferred, and it is this character of the Borrowdale graphite which has rendered it so valuable. At Sturbridge, Mass., it is rather coarsely granular and foliated, and has been extensively worked; the mine yields annually about 30 tons of graphite. The mines of Ticonderoga and Fishkill landing, N. Y.; of Brandon, Vt.; and of Wake, North Carolina, are also worked; and that of Ashford, Ct., formerly afforded a large amount of graphite, though now the works are suspended. The material for lead pencils, when of the finest quality, is first calcined and then sawn up into strips of the requisite size and commonly set in wood, (usually cedar,) as they ap. pear in market. It is much used now in small cylinders without wood for ever-pointed pencil cases. Graphite of coarser quality, according to a French mode, is ground up fine and calcined, and then mixed with the finest levigated clay, and worked into a paste with great care. It is made darker or lighter and of different degrees of hardness, by varying the proportion of clay and the degree of calcination to which the mixture is subjected; and the hardness is also varied by the use of saline solutions. Lampblack is sometimes addded with the clay. A superior method in use at Taunton, Mass., where the Sturbridge graphite is extensively employed, consists in finely pulverising it, and then by a very heavy pressure ob. tained by machinery, condensing it into thin sheets. These How are the best lead pencils made? How are they manufactured from the Sturbridge bed? AMBiR. 93 sheets are then sawn up of the size required. The pencil is pure graphite, and the foliated variety is preferred on account of its being freer from impurities. Graphite is extensively employed for diminishing the friction of machinery; also for the manufacture of crucibles and furnaces, and as a wash for giving a gloss to iron stoves and railings. For crucibles it is mixed with half its weight of clay. (CARBONIC ACID. (carbonic acid is the gas that gives briskness to the Sara. toga and many other mineral waters, and to artificial soda water. Its taste is slightly pungent. It extinguishes combustion and destroys life. Composition: carbon 27'65, oxygen 72*35. Besides occurring in mineral waters, it is common about some volcanoes. The Grotto del Cane (Dog cave) near Naples, is a small cavern filled to the level of the en. trance with this gas. It is a common amusement for the traveler to witness its effects upon a dog kept for the purpose. He is held in the gas a while and is then thrown out apparently lifeless; in a few minutes he recovers himself, picks up his reward, a bit of meat, and runs off as lively as ever. If continued in the carbonic acid gas a short time longer life would have been extinct. Carbonic acid combined with lime forms carbonate of lime or common limestone; with oxyd of iron it constitutes spathic iron, one of the common ores of iron; with oxyd of zinc, it forms calamine, the most profitable ore of zinc. It is found in combination also in various other minerals. AMBER. In irregular masses. Color yellow, sometimes brownish or whitish; luster resinous. Transparent to translucent. H = 2-25. Gr= 1'18. Electric by friction. Composition. Carbon 79 0, hydrogen 10-5. oxygen 10'5 Burns with a yellow flame and aromatic odor. Ohs. Occurs in alluvium and on coasts, in masses from a very small size to that of a man's head. In the Royal Museum at Berlin, there is a mass weighing 18 pounds. On For what other purposes is it used? What is carbonic acid? Combined with lime, what does it form? What is the appearance of amber? Whi-re does it occur? 94 MINERAL RESINS. the Baltic coast it is most abundant, especially between K6nigsberg and Memel. It is met with at one place in a bed of bituminous coal; it also occurs on the Adriatic, in Poland, on the Sicilian coast near Catania, in France near Paris in clay, in China. It has been found in the United States, at Gay Head, Martha's Vineyard, Camden, N. J., and at Cape Sable, near the Magothy river, in Maryland. It is supposed with good reason to be a vegetable resin, which has undergone some change while inhumed, a part of which is due to acids of sulphur proceeding from decompo. sing pyrites or some other source. It often contains insects, and specimens of this kind are so highly prized as frequently to be imitated for the shops. Some of the insects appear evidently to have struggled after being entangled in the then viscous resin, and occasionally a leg or a wing is found some distance fiom the body, having been detached in the struggle for escape. Amber is the elektron of the Greeks; from its becoming electric so readily when rubbed, it gave the name electricity to science. It was also called succinum, from the Greek succum, juice, because of its supposed vegetable origin. Uses. Amber admits of a good polish and is used for ornamental purposes, though not very much esteemed, as it is wanting in hardness and brilliancy of luster, and moreover is easily imitated. It is much valued in Turkey for mouthpieces to their pipes. Amber is the basis of an excellent transparent varnish. After burning, there is left a light carbonaceous residue, of which the finest black varnish is made. Amber affords by distillation an oil called oil of amber, and also succinic acid; and as the preparation of amber varnish requires that the amber be heated or fused, these products are usually obtained at the time. MINERAL CAOUTCHOIJC. —-Elastic Bitumen. In soft flexible masses, somewhat resembling caoutchouc or India rubber. Color brownish black; sometimes orange red by transmitted light. Gr=09 —1-25. Composition: carbon 85'5, hydrogen 13*3. It burns readily with a yellow flame and bituminous (Xindistinct parallel with M and e. Also massive, sublamellar or subfibrous. Colors light; white, pale blue, green or red. Streak uncolored. Transparent to nearly opaque. Luster usually a little pearly. H= 5 —-6. Gr=2- 6-2-75. Composition: silica 493 alumina 279 lime 22'8. Before the blowpipe it fuses slowly with intu. mescence. With borax dissolves with effervescence to a transparent glass. Dif. Its square prisms and the angle of the pyramid at summit are characteristic. In cleavable masses it resembles feldspar, but there is a slight fibrous appearance often dis. tinguished on the cleavage surface of scapolite, which is peculiar. It is more fusible than feldspar, and has higher specific gravity. Spodumene has a much higher specific gravity, and differs in its action before the blowpipe. Tabu. What have specimens with a greasy luster been called? What is the ffect of nitric acid? What is the Dsual form of scapolite crystals What are its colors and hardness? What is its composition? How does it differ from feldspar and tabular spar? MEItoNITS. 181 lar spar is more fibrous in the appearance of the surtace, and is less hard; it is also phosphorescent, and gelatinizes with acids. Obs. Found mostly in the older crystalline rocks, and also in some volcanic rocks. It is especially common in granular limestone. Fine crystals occur at Gouverneur, N. Y., and at Two ponds and Amity, N. Y.; at Bolton, Boxborough and Littleton, Mass.; at Franklin and Newton, N. J. It occurs massive at Marlboro', Vt.; Westfield, Mass., Monroe, Ct. Foreign localities are at Arendal, Norway: Wairmland, Sweden; Pargas in Finland, and also at Vesu. vius, whence comes the small crystals called meionite. Nuttallite, Wernerite, and Glaucolite are varieties of this species. Dipyre from the Pyrenees, occurring in four or eight-sided prisms, has also been considered one of its varieties. It however contains silica 55'5, alumina 24'8, lime 9'6, with 9'4 per cent. of soda, and is more allied in composition to the feldspars. Sp. gr.-=265. Occurs with talc and chlorite. MEIONITE. Dimetric. In small glassy square prisms, terminating in pyramids, and resembling scapolite; e: e= 1360 11'. Cleavage rather perfect, parallel with M and e. Colorless or white, and transparent to translucent. H5-.56. Gr-=2.5-2-75. Composition: silica 42'1, alumina 31'9, lime 26'0. Be. fore the blowpipe yields a colorless glass. Dif. Differs fiom scapolite in the angle of the summit and in composition, fiom the zeolites in being anhydrous. Obs. Found at Mt. Somma, near Naples, in small crystals in geodes in lava. Mizzonite is closely similar. It has for the angle c: e= 135~ 56', (Scacchi.) Sarcolite. Dimetric. Resembling somewhat analcime in appearance, being flesh-red to reddish white. Extremely brittle. Gelatinizes with acids. Of rare occurrence at Mt. Somma. Gehlenite. Crystals square prisms like meionite: color gray; nearly opaque. H=55 —6. Gr=2-9-3-1. Composition, silica 29-6, alumina 24-8, lime 35'3, protoxyd of iron 6-6, water 3'3. Infusible. With In what rocks does it occur? Mention the characters of spodumene How much lithia does it contain I How does it differ from feldspar and scapolite 1 16 182 ALUMINA. boiax fuses with difficulty. Gelatinizes in muriatic acid. From the Fassa valley, Tyrol. Humboldtilite. Crystals as above. Cleavage basal, distinct. Colo) brown or yellow; luster vitreous. H-5. Gr=2*9-3-2. Composition, silica 44-0, alumina 11-2, lime 32-0, magnesia 6-1, protoxyd ot iron 2-3, soda 4'3, potash 0-4. Gelatinizes with nitric acid. From Vesuvius in lava. Somervillite and mellilite are here included. PETA LITE. In imperfectly cleavable masses, affording a prism of 1420 Color white or gray, or with pale reddish or greenish shades. Luster vitreous to subpearly. Translucent. H=6 —65. (r=2'4- 2-45. Composition: silica 77'9, alumina 17'7, lithia 3-1, soda 1-3 Phosphoresces when gently heated. Fuses with dif. ficulty on the edges. Gives the reaction of lithia like spod. umene. Dif. Its lithia reaction allies it to spodumene, but it differs from that mineral in luster, specific gravity, and greater fusibility. Costor. Supposed to be petalite. Zygadite is another lithia mineral: it occurs in twins like albite. From the Hartz. Violan is.a dark violet-blue mineral, resembling glaucophane. Glaucophane occurs in cleavable masses of a dull bluish color, and in thin prisms. Translucent. Gr=1'08. H-5'5. Fusf- easily. Contains silica 565, alumina 12-2, protoxyd of iron 10 9, 1iotoxyd of manganese 0-5, magnesia 8-0, lime 2 2, soda 9-3. From the Island of Syra. Wwchtine is a black mineral rectangularly cleavable in two directions. Contains silica 56-3, alumina 13 3, protoxyd of iron 13'0, peroxyd of iron 4'0, soda 35, lime 6'0, magnesia 3'0. From Wichty in Finland. EPIDOTE. Monoclinic. In right rhomboidal prisms more or less modified, often with six or more sides. M: T=115~ 24'. \ T: 6=128' 19'; a: ta=109~ a 27; e: a-=125 16' Cleavage parallel to M; less M ^ distinct parallel to T.-Also massive granular and of a co- T lurnar structure. Describe petalite. What is the proportion of lithia in its constitutiont low does it differ from spodumene? Where does it occur? What is he form of epidote? EPIDO1E. 183 Color yellowish-green (pistachio-green) and ash or hail brown. Streak uncolored. Translucent to opaque. Lus. ter vitreous, a little pearly on M; often brilliant on the faces of crystals. Brittle. H=6- 7. Gr=3-25-3*46. Varieties and Composition. There are three prominent varieties of this species; one of a yellowish-green color, another called zoisite, of a grayish-brown or hair-brown; a third of dark reddish shades, which contains 14 per cent. oJ oxyd of manganese, and is called Manganesian epidote Thulite is another red variety, of paler color. The yellowish-green epidote is sometimes called Pistacite. The mineral Bucklandite is an iron-epidote. The green epidote consists of silica 37-0, alumina 26'6, lilne 20*0, protoxyd of iron 13*0, protoxyd of manganese 0.6, water 1'8. Zoisite consists of silica 40'2, alumina 30-3, lime 22-5, peroxyd of iron 4-5, water 2.0. Before the blowpipe, epidote and zoisite fuse on the edges and swell up, but do not liquefy. The manganesian epidote and thulite fuse readily to a black glass. Dif. The peculiar yellowish-green color of ordinary ep. idote distinguishes it at once. The prisms of zoisite are often longitudinally striated or fluted, and they have not the form or brittleness of tremolite. Obs. Occurs in crystalline rocks, and also in some sedimentary rocks that have been heated by the passage of dykes of trap or basalt. Splendid crystals, six inches long, and with brilliant faces and rich color, have been obtained at Haddam, Ct. Crystallized specimens are also found at Franconia, N. H., Hadlyme, Chester, Newbury and Athol, Mass., near Unity and Monroe, N. Y., Franklin and Warwick, N. J. Zoisite in columnar masses is found at Willsboro and Montpelier, Vt., at Chester, Goshen, Chesterfield, and else. where in Massachusetts; at Milford, Ct. The name epidote was derived by Hatty from the Greek e:pididomi, to increase, in allusion to the fact that the base of the primary is frequently much enlarged in the crystals. The mineral Allanite, p. 207, is near epidote in form and composition, although containing cerium. What are the colors and other characters of epidote? What is the co' Or of the variety zoisite? What is the composition of epidote?'sha ire its distinguishing characters? 184 ALUMINA. IDOCRASE. Dimetric. In square prisms usually modified. P a= 142' 53'; a: a=129~ 29', a: e127~ 07. Cleavage not very distinct parallel with M. Also found massive granular and subcolumnar. Color brown; sometimes passing into green. In some varieties the color is oil-green in the direc.' tion of the axis and yellowish-green at right angles with it. Streak uncolored. Subtransparent to nearly opaque. H-6-5. Gr=-3'333.4. Composition: silica 37'4, alumina 23*5, protoxyd of iron 4-0, lime 29'7, magnesia and protoxyd of manganese 5'2. Before the blowpipe fuses with effervescence to a yellow translucent globule. Dif. Resembles some brown varieties of garnet, tourmaline and epidote, but besides its difference of crystallization, it is much more fusible. Obs. Idocrase was first found in the lavas of Vesuvius, and hence called Vesuvian. It has since been obtained in Piedmont, near Christiania, Norway, in Siberia, also in the Fassa valley. Specimens of a brown color from Eger, Bohemia, have been called egeran. Cyprine includes blue crystals from Tellemarken, Norway; supposed to be colored by copper. In the United States, idocrase occurs in fine crystals at Phipsburg and Rumford, Parsonsfield and Poland, Me.; Newton, N. J.; Amity, N. Y., and sparingly at Worcester, Mass. The xanthite of Amity is nothing but idocrase. The name idocrase is from the Greek eido, to see, and krasis, mixture; because its crystalline forms have much resemblance to those of other species. Uses. This mineral is of little value except as a minera. logical curiosity. It is sometimes cut as a gem for rings. GARNET. Monometric. Common in dodecahedrons, (fig. 1,) also in trapezohedrons, (fig. 2,) and both forms are sometimes variously modified. Cleavage parallel to the faces of the dode. What is the crystallization of idocrase? its color, hardness, and luster? its composition? How does it differ from garnet and touimaline? What is the usual form of garnet? GARNET. 185 cahedron rather distinct. Also found massive granular and coarse lamellar. Color deep red, prevalent; also brown, black, green, 1 2 3 4 white. Transparent to opaque. Luster vitreous. Brittle. H=-65-7-5. Gr=-35- 43. Varieties and Composition. Garnet is a compound of three or four silicates, the silicates of alumina, lime, iron, and manganese, and the varieties of color arise from their various combinations. Oxyd of chrome is sometimes present, producing an emerald-green variety. Precious garnet or almandine is a clear deep red variety, and is used much in jewelry. A specimen from New York afforded Wachtmeister, silica 42-5, alumina 19'15, protoxyd of iron 33-6, protoxyd of manganese 5-5. Common garnet has a brownish red color. and is imperfectly translucent or opaque. Cinnamon stone, called also essonite, is of a light cinna. mon-yellow color and high luster. It differs from the pre ceding principally in containing but 5 or 6 per cent. of iron and 30 to 33 percent. of lime. Topazolite is another yellow variety, approaching topaz in color, and presenting the form in figure 3. Melanite (from the Greek melas, black) is a black garnet. containing 15 to 25 per cent. of the oxyds of iron and manganese. Pyrendite is another name for a black variety from France. Manganesian garnet has a deep red color, and is usually quite brittle. A Haddam specimen afforded Seybert, silica 35'8, alumina 18-1, protoxyd of iron 14*9, protoxyd of manganese 31-0. Grossularite occurs in greenish trapezohedrons; and con. tains 30 to 34 per cent. of lime with but little iron. Ouvarovite is a chrome garnet, containing 22-5 per cent. of oxyd of chromium, and having the rich color of the emerald. What is the color and hardness of garnet? of what does it consist what is precious garnet? What is cinnamon stone? What is ouvaro. vite? lfr~ 186 ALUMINA. Colophonite (from the Greek kolophonia, a resin) is a coarse granular variety, usually presenting iridescent hues and a resinous luster. Aplome is a deep brown garnet, sometimes inclining to orange. It presents the fuom in figure 4, and has a cleavage parallel to the shorter diagonal of the faces. For this rea. son it has been separated from the species garnet, and a cube is considered its primary form. The different varieties fuse with more or less difficulty to a dark vitreous globule. Dif. The vitreous luster of fractured garnet, without a prismatic structure even in traces, and its usual dodecahedral forms, are easy characters for distinguishing it. Staurotide differs in being infusible; tourmaline has less specific grav. ity; idocrase fuses much more readily. Obs. Garnet occurs abundantly in mica slate, hornblende slate, and gneiss, and somewhat less frequently in granite and granular limestone; sometimes in serpentine and lava. The best precious garnets are from Ceylon and Greenland; cinnamon stone comes from Ceylon and Sweden; grossularite occurs in the Wilui river, Siberia, and at Tellemarken in Norway; green garnets are found at Swartzenberg, Saxony; melanite, in the Vesuvian lavas; ouvarovite, at Bissersk in Russia; topazolite, at Mussa, Piedmont; aplome, in Siberia, on the Lena, and at Swartzenberg. In the United States, precious garnets, of small size, occur at Hanover, N. H.; and a clear and deep red variety, sometimes called pyrope, comes from Green's creek, Delaware county, Penn. Dodecahedrons, of a dark red color, occur at Haverhill, N. H., some 1~ inches through; also at New Fane, Vt., still larger; alsc Lyme, Conn.; at Unity, Bruns. wick, Streaked Mountain, and elsewhere, Maine; at Monroe, Conn.; Bedford, Chesterfield, Barre, Brookfield, and Brimfield, Mass.; Dover, Dutchess county, Roger's rock, Crown Point, Essex county, Franklin, N. J. Cinnamon colored crystals occur at Carlisle, Mass., transparent, and also at Boxborough; with idocrase at Parsonsfield, Phippsburg and Rumford, Me.; at Amherst, N. H.; at Amity, N. Y., and Franklin, N. J.,; at Dixon's quarry, seven miles from Wilmington, Del., in fine trapezohedral crystals. Melanite is found at Franklin, N. J., and Germantown, Penn. Coloph. What is colophonite? What is aplome? How is garnet distinguished? TOURMALINE. 187 onite is abundant at Willsborough and Lewis, Essex county, N. Y.; it occurs also at North Madison, Conn. The garnet is the carbuncle of the ancients. The alabandic carbuncles of Pliny were so called because cut and polished at Alabanda, and hence the name Almandine now in use. The garnet is also supposed to have been the hya. cinth of the ancients. Uses. The clear deep red garnets make a rich gem, and are much used. Those of Pegu are most highly valued. They are cut quite thin, on account of their depth of color. An octagonal garnet, measuring 8~ lines by 61 has sold for near $700. The cinnamon stone is also employed for the same purpose. Pulverized garnet is sometimes employed as a substitute for emery. When abundant, as in some parts of Germany, garnet is used as a flux to some iron ores. Pliny describes vessels, of the capacity of a pint, form. ed from large carbuncles, "devoid of luster and transparency, and of a dingy color," which probably were large gar. nets. Pyrope or Bohemian garnet. Occurs usually in rounded grains, resembling a rich garnet, but the primary form is supposed to be the cube. Cleavage none. 1-=7-5. Gr=3-69-3-8. Composition: silica 430, alumina 22'3, oxyd of chromium 1-8, magnesia 18'5, protoxyd of iron 8'7, lime 5 7; and, according to Apjohn, there are also 3 per cent. of vttria. From Bohemia, in trap tufa. Helvin., a wax yellow garnet-like mineral, occurring in tetrahedral crystals. From Saxony and Norway. TOURMALINE. Rhombohedral. Usual in prisms terminating in a low pyramid. R: R=134"* 1 2 3 03. R: e —11]2 59'; R:da=141 30; e:e=- - 1540 59'. The crystals are hemihedrally modified, or have unlike secondary planes at the two extrem- ities, as shown in figure 3. They are commonly long, and of en thlle are but three prismatic sides, which are convex and strongly furrowed. How is garnet distinguished? What are its uses? What is said of the ancient carbuncle t What is pyrope? What are the usual forms and appearance of tourmaline? 188 ALUMINA. Occurs also compact massive, and coarse columnar, the coi umns sometimes radiating or divergent from a center. Color black, blue-black, and dark brown, common; als(. bright and pale red, grass-green, cinnamon-brown, yellow, gray, and white. Sometimes red within and green externally, or one color at one extremity and another at the other. Transparent; usually translucent to nearly opaque. Luster vitreous, inclining to resinous on a surface of fracture. Streak uncolored. Brittle; the crystals often fractured across and breaking very easily. H=7-8. Gr=3-3-1. Electrically polar when heated, (page 62.) Varieties and Composition. Tourmalines of different col. ors have been designated by different names, as follows: Rubellite is red tourmaline. Indicolite is blue and bluish-black tourmaline. Schorl, formerly included the common black tourmaline, but the name is not now used. A black variety afforded, on analysis, silica 33-0, alumina 38-2, lime 0'8, protoxyd of iron, 23*8, soda 3*2, boracic aciH 1*9. A red variety from Siberia, silica 39-4, alumina 44-0, potash 1-3, boracic acid 4-2, lithia 2-5, peroxyd of manganese 5'0. The presence of boracic acid is the most remarkable point in the constitution of this mineral. It is also observed that lithia is sometimes present; over 4 per cent. have been obtained from a green tourmaline from Uton, Sweden. Before the blowpipe the dark varieties intumesce, and fuse with difficulty; the red and light-green only become milkwhite and a little slaggy on the surface. Dif. The black and the dark varieties generally, are readily distinguished by the form and luster and absence of distinct cleavage, together with their difficult fusibihty. The black when fractured often appear a little like a black resin. The brown variety resembles zoisite, though very distinct in crystallization. The light brown looks like garnet or idocrase, but is more infusible. The red, green, and yel. low varieties are distinguished from any species they resemble, by the crystalline form, the prism of tourmaline always having 3, 6, 9, or 12 prismatic sides, (or some multiple of What is the color and hardness of tourmaline? what has been called schor]? What is rubellite? What are the distinctive characters oi tourmaline? TOURMALINE. 189 3.) The electric polarity of the crystals, when heated, is another remarkable character of this mineral. Obs. Tourmalines are common in granite, gneiss, mica slate, chlorite slate, steatite, and granular limestone. They usually occur penetrating the gangue. The black crystals are often highly polished and at times a foot in length, though perhaps of no larger dimensions than a pipe-stem, or even more slender. This mineral has also been observed in sandstones near basaltic or trap dikes. Red and green tourmalines, over an inch in diameter and transparent, have been obtained at Paris, Me., besides pink and blue crystals. These several varieties occur also, of less beauty, at Chesterfield and Goshen, Mass. Good black tourmalines are found at Norwich, New Braintree, and Carlisle, Mass.; Alsted, Acworth, and Saddleback Mountain, N. H.; IHaddam, Conn.; Saratoga and Edenville, N. Y.; Franklin and Newton, N. J. Dark brown tourmalines are obtained at Orford, N. H.; in thin black crystals in mica at Grafton, N. H.; Monroe, Ct.; Gouverneur and Amity, N. Y.; Franklin and Newton, N. J. A fine cinnamon brown variety occurs at Kingsbridge, Amity, and also south in New Jersey. A gray or bluishgray and green variety occurs near Edenville. The word tourmaline is a corruption of the name in Ceylon, whence it was first brought to Europe. Lyncurium is supposed to be the ancient name for common tourmaline; and the red variety was probably called hyacinth. Uses. The red tourmalines, when transparent and free from cracks, such as have been obtained at Paris, Me., are of great value and afford gems of remarkable beauty. They have all the richness of color and luster belonging to the ruby, though measuring an inch across. A Siberian specimen of this variety, now in the British museum, is valued at ~500. The yellow tourmaline, from Ceylon is but little inferior to the real topaz, and is often sold for that gem. The green specimens, when clear and fine, are also valuable for gems. A stone measuring 6 lines by 4, of a deep green color, is valued at Paris at $15 to $20. The thin crystals of Grafton, N. H. are transparent, and may be used as sug. gested by B. Silliman, Jr., in polarizing instruments. Where have fine specimens of red and green tourmaline been found in the United States? What is said of yellow tourmaline? What iw the value of tourmaline as a gem? 190 ALUMINA. AXINITE. Triclinic. In acute edged oblique rhomboidal prisms; P:M=134 40, P:T=115~ 5', M: T= 135 10'. Cleavage indistinct. Also rarely massive or lamellar. T 1 3r Color clove brown; differing somewhat in shade in two directions. Luster vitreous. Trans. parent to subtranslucent. Brittle. H =65 — 7. Gr =3'27. Pyro-electric. Composition: silica 45, alumina 19, lime 12*5, peroxyd of iron 12*25, peroxyd of manganese 9, boracic acid 2*0, magnesia 0-2. In another specimen 5-6 per cent. of boracic acid were found. Before the blowpipe fuses readily with intumescence to a dark green glass, which becomes black in the oxydating flame. Dif. Remarkable for the sharp thin edges of its crystals, and its glassy brilliant appearance, without cleavage. The crystals are implarted, and not disseminated like garnet. In one or all of these particulars, and also in blowpipe reaction, it differs from any of the titanium ores. Obs. St. Cristophe in Dauphiny, is a fine locality of this mineral. It occurs also at Kongsberg in Norway, Normari in Sweden, and Cornwall, England; also Thum in Saxony, whence the name Thummerstein and Thumite. In the United States, it has been found at Phippsburg in Maine, by Dr. C. T. Jackson. IOLITE.-Dichroite, Cordierite. Trimetric. In rhombic and hexagonal prisms. Usually occurs in six or twelve-sided prisms, or disseminated in masses without distinct form. Cleavage indistinct; but crystals often separable into layers parallel to the base. Color various shades of blue; often deep blue in the direction of the axis, and yellowish-gray transversely. Streak uncolored. Luster and appearance much like that of glass. Transparent to translucent. Brittle. H =7 —75. Gr= 2-6-2-7. Composition of a specimen from Haddam, Ct.: silica 48-3, What is the form and color of axinite? What characters distinguish it? Why was it so called? What are the forms of iolitc? What are its colors, appearance and hardness? MICA. 191 alumina 32'5, magnesia 10, protoxyd of iron 600, protoxyd of manganese 0'1, water (hygrometric) 3-1. Before the blowpipe fuses on the edges with difficulty to a blue glass resembling the mineral. Dif. The glassy appearance of iolite is so peculiar that it can be confounded with nothing but blue quartz, from which it is distinguished by its fusing on the edges. It is easily scratched by sapphire. Obs. Found at Haddar, Conn., in granite; also in gneis at Brimfield, Mass.; at Richmond, N. H., in talcose rock The principal foreign localities are at Bodenmais in Bava. ria; Arendal, Norway; Capo de Gata, Spain; Tunaberg, Finland; also Norway, Greenland and Ceylon. The name iol:De is from the Greek iodes, violet, alluding to its color; it is also called dichroite, from dis, twice, and chroa, color, owing to its having different colors in two directions. Uses. Occasionally employed as an ornamental stone; when cut it presents different shades of color in different directions. NoTE.-Iolite exposed to the air and moisture undergoes a gradual alteration, becoming a hydrate (absorbing water) and assuming a foliated micaceous structure, so as to resemble talc, though more brittle and hardly greasy in feel. Hydrous iolite, chloropkyllite, and esmarkite, are names that have been given to the altered iolite; and fahlunite and gigantolite are of the same origin. (See pages 162, 163.) MICA.-MusCOvite. Trimetric. In oblique rhombic prisms of about 120~ and 600; but the fundamental form right rhom. bic. Crystals usually with the acute edge replaced. Cleavage eminent, parallel to P, yielding easily thin elastic laminaB of extreme tenuity. Usually in thinly foliated masses, plates or scales. Sometimes in radiated groups of aggregated scales or small folia. Colors from white through green, yellowish and brownish shades to black. Luster more or less pearly. Transparent or translucent. Tough and elastic. H=2 —2-5. Gr= 2-8-3. Composition: silica 46'3, alumina 36-8, potash 9-2, per How is iolite distinguished from quartz and sapphire? Why was i called iolite and dichroite? Describe mica. What is its composition? 192 ALUMINA. oxyd of iron 4'5, fluoric acid 0'7, water 18. Before the blowpipe infusible, but becomes opaque white. Varieties.-A variety in which the scales are arranged in a plumose form is called plumose mica; another, in which the plates have a transverse cleavage, has been termed pris matic mica. Dif. Mica differs from talc in affording thinner folia and being elastic; also in not having the greasy feel of tha\ mineral. The same characters, excepting the last, distin. guish it from gypsum; besides, it does not crumble so readily on heating. Obs. Mica is one of the constituents of granite, gneiss and mica slate, and gives to the latter its laminate structure. It also occurs in granular limestone. Plates two and three feet in diameter, and perfectly transparent, are obtained at Alstead, Acworth and Grafton, New Hampshire. Other good localities are Paris, Me.; Chesterfield, Barre, Brimfield, and South Royalston, Mass.; near Greenwood furnace, Warwick and Edenville, Orange county, and in Jefferson and St. Lawrence counties, N. Y.; Newton and Franklin, N. J.; near Germantown, Pa., and Jones's Falls, Maryland. Oblique prisms from near Greenwood are sometimes six or seven inches in diameter. A green variety occurs at Unity, Maine, near Baltimore, Md., and at Chestnut Hill, Pa. Prismatic mica is found at Russel, Mass. Uses. Mica, on account of the toughness, transparency and the thinness of its folia, has been used in Siberia for glass in windows: whence it has been called Muscovy glass. It was formerly employed in the Russian navy, because not liable to fracture from concussion. It is in common use for lanterns, and also for the doors of stoves. It affords a convenient material for preserving minute objects for the microscope, and is sometimes used for holding minerals before the blowpipe flame. The best localities of the mineral in this country for the arts, are those of New Hampshire. Lepidolite, or Lithia mica. Occurs in crystals or laminae, of a purplish color, and often in masses consisting 6f aggregated scales. A specimen from the Ural consisted, according to Rosales, of silica 47'7, How does mica differ from talc and gypsum? Of what rocks is t a constituent? What are its uses? What is the peculiarity of!eridolite? MICA. 193 alumina 20'3, lime 6-1, protoxyd of manganese 4'7, potash 11'0, lithia 2-8, soda 2-2, fluorine 10-2, chlorine 1-2. Lepidolite occurs at the albite vein in Chesterfield, Mass., and at Goshen in the same state; also at Paris, Me., with red tourmalines, and near Middletown, Ct. Fuchsite. A green mica from the Zillerthal, containing nearly 4 per cent. of oxyd of chromium. Biotite. Resembles common mica or muscovite, but crystals usually right prisms, and angle between the optical axes only I or 2 degrees or less; while in muscovite P the angle is 56 to 75 degrees. The form is usually regarded as hexagonal and not trimetric. Cololrs mostly dark green to black, sometimes white. H'=25- 3. Gr=2'7-3-1. Composition: essentially like garnet. A variety from Monroe, N. Y., afforded Smith and Brush, silica 39'9, alumina 15'0, peroxyd of iron 7-7, magnesia 23-7, soda 1-1, potash 9-1, water 1-3, fluorine 0-9, chlorine 0'4. Biotite is a magnesia mica. Obs. Occurs at Vesuvius, at Greenwood Furnace in Monroe, N. Y., and elsewhere. Most of the black and greenish-black micas are biotite. Phlogopite. A mica, near biotite in the form of the crystals, but angle between the optical axes 5 to P 20 degrees. Form trimetric. Color usually brown, yellowish brown, sometimes white. Composition: a variety from Edwards, N. Y., afforded Craw, silica 40'15, alumina 17-36, magnesia 28-10, potash 10-56, soda 0-63, fluorine 4-20. Obs. Occurs in granular limestone, being characteristic of that rock. Found at Gouverneur and other places in northern New York, Warwick, Orange Co., &c. Mlargarite, or Pearl Mica. In hexagonal prisms, having the structure of mica; and also in intersecting laminae. Luster pearly, approaching talc, but differing from that mineral in being a silicate of alumina instead of magnesia. Color nearly white, or gray. It intumesces and fuses before the blowpipe. From Sterzing in the Tyrol, associated with chlorite. Emerylite and diphanite belong here. Euphyllite is a new species, related somewhat to margarite, and found associated with emerylite and corundum in Pennsylvania and elsewhere. Rather brittle. Margarodite, or Schistose talc of Zillerthal, is near common mica, but contains 4 or 5 per cent. of water. Lepidomelane. A black iron-mica, occurring in six-sided scales or tables aggregated together. It contains silica 37'4, alumina 11-6, peroxyd of iron 27-7, protoxyd of iron 12'4, magnesia and lime 0'3, potash 9-2, water 0-6. From Warmland. Ottrelite (which includes the phyllite from Sterling, Mass.,) is an allied mineral occurring in black scales, disseminated through the rock. What are other kinds of mica 1 17 194 ALUMINA. 5. Combination of a Silicate and Fluorid. TOPAZ. Trimetric. In right rhombic prisms, usually differently modified at the two extremities. Pyro-electric. -I M M=124~ 19'. Cleavage perfect, parallel to e~/ e -- the base. Color pale yellow; sometimes greenish, blu. ish, or reddish. Streak white. Luster vitreous.' 1 Transparent to subtranslucent. Fracture subconchoidal, uneven. Composition: silica 34-2, alumina 57-5, flulorine 15-0. Infusible alone on charcoal before the blowpipe. Some varieties are changed by heat to a wine yellow or pink tinge. Dif. Topaz is readily distinguished from tourmaline and other minerals it resembles by its brilliant transverse cleavage. Obs. Pycnite has been separated from this species. It differs from topaz mainly in the state of aggregation of the particles, it presenting a thin columnar structure and forming masses imbedded in quartz. The physalite or pyrophysalite of Hisinger, is a coarse, nearly opaque variety, found in yellowish-white crystals of considerable dimensions This variety intumesces when heated, and hence its name from phusao, to blow. Topaz is confined to granitic regions, and commonly occurs in granite, associated with tourmaline, beryl, occasionally with apatite, fluor spar and tin. With quartz, tourinaline and lithomarge, it forms the mixture called topaz rock by Werner. Fine topazes are brought from the Uralian and Altai mountains, Siberia, and from Kamschatka, where they occur of green and blue colors. In Brazil they are found of a deep yellow color, either in veins or nests in lithomarge, or in loose crystals or pebbles. Magnificent crystals of a sky-blue color have been obtained in the district of Cairngorum, in Aberdeenshire. The tin mines ofSchlackenwald, Zinnwald. and Ehrenfriedersdorf in Bohemia, St. Michael's Mount in What are the forms and cleavage of topaz crystals? What are their colors? their luster and hardness? their composition? How is topa distinguished from tourmaline and other minerals? How does topa occur? TOPAZ. 19& Cornwall, etk., afford smaller crystals. The physalite varie. ty occurs in crystals of immense size at Finbo, Sweden, in a granite quarry, and at Broddbo, in a boulder. A well defined crystal from this locality, in the possession of the College of Mines of Stockholm, weighs eighty pounds. Al. tenberg in Saxony, is the principal locality of pycnite. It is there associated with quartz and mica. Trumbull. Conn., is the principal locality of this species in the United States. It seldom affords fine transparent crystals except of a small size: these are usually white, occa sionally with a tinge of green or yellow. The large coarse crystals sometimes attain a diameter of several inches (rarely six or seven,) but they are deficient in luster, usually of a dull yellow color, though occasionally white, and often are nearly opaque. The ancient topazion was found on an island in the Red Sea, which was often surrounded with fog, and therefore difficult to find. It was hence named from topazo, to seek. This name, like most of the mineralogical terms of the ancients, was applied to several distinct species. Pliny describes a statue of Arsinoe, the wife of Ptolen v Philadelphus, four cubits high, which was made of topazion, or topaz, but evidently not the topaz of the present day, nor chrysolite, which has been supposed to be the ancient topaz. It has been conjectured that it was a jasper or agate; others have imagined it to be prase, or chrysoprase. Uses. Topaz is employed in jewelry, and for this purpose its color is often altered by heat. The variety from Brazil assumes a pink or red hue, so nearly resembling the Balas ruby, that it can only be distinguished by the facility with which it becomes electric by friction. The finest crystals for the lapidary are brought from Minas Novas, in Brazil. From their peculiar limpidity, topaz pebbles are sometimes denominated gouttes d'eau. When cut with facets and set in rings, they are readily mistaken, if viewed by daylight, for diamonds. The coarse varieties of topaz may be employed as a substi. tute for emery in grinding and polishing hard substances. Topaz is cut on a leaden wheel, and is polished on a cop per wheel with rotten stone. It is usually cut in the forir of the brilliant or table, and is set either with gold foil or jour. The white and rose-red are most esteemed. What are the uses of topa::? What is the effect of heat? 193 ALUMINA. 6. Combination of a Silicate and Sulphate. LAPIS-LAZULI.~- Ultramarine. Monometric. In dodecahedrons. Cleavage imperfect Also massive. Color rich Berlin or azure /\l blue. Luster vitreous. Translucent to opaque. X/ \ H-=5'5. Gr-=23 -2-5. Composition: silica 45'5, alumina 31'8, soda 9'1, lime 3'5, iron 0'8, sulphuric acid 59, sulphur 0-9, chlorine 04, water 0'1. Fuses to a white translucent or opaque glass, and if calcined and reduced to powder loses its color in acids. The color of the mineral is supposed to be due to sulphuret of sodium. Dif. Distinguished from azurite by its hardness and by giving no indications of copper before the blowpipe; and from lazulite by its fusibility, hardness, and not giving the reaction of phosphoric acid. Obs. Found in granite and granular limestone, and is brought from Persia, China, Siberia, and Bucharia. The specimens often contain scales of mica and disseminated pyrites. Uses. The richly-colored lapis lazuli is highly esteemed for costly vases, and for inlaid work in ornamental furniture. Magnificent slabs are contained in some of the Italian cathedrals. It is also used in the manufacture of mosaics. When powdered it constitutes the most beautiful and most durable of blue paints, called ultramarine, and has been one of the most costly colors. The late discovery of a mode of making an artificial ultramarine, quite equal to the native, has afforded a substitute at a comparatively cheap rate. This artificial ultramarine consists of silica 45'6, alumina 23X3, soda 21'5, potash 1'7, lime trace, sulphuric acid 3*8, sulphur 1'7, iron 1'1, and chlorine a small.quantity unde. termined. It has taken the place in the arts, entirely, of the native lapis-lazuli. Hauyne, (including nosean and spinellane.) In dodecahedrons, and ilied to the preceding. Color bright blue, occasionally greenish. Transparent to translucent. H=6. Gr=2 28-2'5. Composition, What is the crystalline form of lapis-lazuli? What is its color? its ardness? its composition? How is it distinguished from apatite and azulite? How does it occur? What are its uses? What is said of he artificial ultramarine BERYL. 197 silica 35-0, alumina 27-4, soda 9-1, lime 12-6, sulphuric acid 12-6, with traces of chlorine, sulphur and water. The nosean afforded silica 35-9, alumina 32-6, soda 17-8, sulphuric acid 9'2, with a small per-centage of other ingredients. A variety from Litchfield, Maine, afforded Dr. Jackson nearly the same proportions-silica 35'4, alumina 31'75, soda 17'6, sulphuric acid 6'5, with oxyd of manganese 4'4,-and lime 1-8. Hauyne comes from the Vesuvian lavas and near Rome. The nosean is found in blocks with feldspar mica and zircon on the Rhine, near the Laacher See. Also at Litchfield, Maine. 7. Silicate uwith a Chlorid. SODALITE. In dodecahedrons like lapis-lazuli. Color brown, gray, or blue. H = 6. Gr-=2'25 -23. Composition: silica; 37 2, alumina 31'7, soda 19'1, sodium 4*7, chlorine 73= 100. From Greenland, Vesuvius and Brisgau. 5. GLUCINA. The minerals containing glucina are above quartz (7) in hardness, excepting one. (leucophane,) which contains largely of lime. The specific gravity is between 2'7 and 3'75. Excepting leucophane, they fuse before the blowpipe with extreme difficulty, or not at all. BERYL.-Emerald. Hexagonal. In hexagonal prisms, Usually in long, stout prisms, without regular terminations. Cleavage,... basal, not very distinct; rarely massive. Color green, passing into blue and yellow; color rather pale, excepting the deep and rich green of the emerald. Streak uncolored. Luster vitreous, sometimes resinous. Transparent to subtranslucent. Brittle. H - 7'5-8. Gr= 2-6.5-2'75. Varieties and Composition. The emerald includes the rich green variety; it owes i- color to oxyd of chrome. Beryl especially includes the paler varieties, which are col. What is sodalite? What is said of minerals containing glucinal What is the crystalline form of beryl? it colors and hardness? 17* 198 GLUCINA. ored by oxyd of iron. Aquamarine includes clear beryls of a sea-green, or pale-llnih or bhlish-green tint. The beryl consists of silica 66'9, alumina 19'0, gluciais 14'1-=100. Emerald contains less than one per cent. ot oxyd of chromium Before the blowpipe becomes clouded, but fuses on the edges with difficulty Dif. The hardness distinguishes this species from apa tite; and this character, and also the form of the crystals, from green tourmaline; the imperfect cleavage, from euclase and topaz. Obs. The finest emeralds come from Grenada, where hey occur in dolomite. A crystal from this locality, 2& inches long and about'2 inches in diameter, is in the cabinet ef the Duke of Devonshire. It weighs 8 oz. 18 dwts., and though containing numerous flaws, and therefore but partially fit for jewelry, has been valued at 150 guineas. A more splendid specimen, but weighing only 6 oz., is in the possession of Mr. Hope of London. It cost ~500. Emeralds of less beauty, but of gigantic size, occur in Siberia. One specimen in the royal collection of Russia measures 41 inches in length and 12 in breadth, and weighs 16J pounds troy. Another is 7 inches long and 4 broad, and weighs 6 pounds. Mount Zalora in Upper Egypt, affords a less dis. tinct variety. The finest beryls (aquarzarines,) come from Siberia, Hindostan and Brazil. One specimen belonging to Don Pedro is as large as the head of a calf, and weighs 225 ounces, or more than 18~ pounds troy; it is transparent and without a flaw. In the United States, beryls of enormous size have been obtained, but seldom transparent crystals. They occur in granite or gneiss. One hexagonal prism from Grafton, N. H., weighs 2900 pounds and measured 4 feet in length, with one diameter ot 32 inches and another of 22; its color was bluish-green, excepting a part at one extremity, which was dull green and yellow. At Royalston, Mass., one crystal has been obtained a foot long, and pellucid crystals are some. times met with. Haddam, Conn., has afforded fine crystals, What is the composition of beryl? What are the different varieties nd their distinctions? How is beryl distinguished from apatite and ourmaline? Where are the finest emeralds brought from? What is aid of the Siberian emeralds? What of the finest beryls? What is he size of some beryls found in the United States i EUcLAsJ f. 199 (see the figure.) Other localities are Barre, Fitchburg, Goshen, Mass.; Albany, Norwich, Bowdoinham and Topham, Me.; Wilmot, N. H.; Monroe, Conn.; leyperville, Penn. The narnm beryl is from the Greek beryllos. EUCLASE. Monoclinic. In oblique rhombic prisms; M: M=115'. Cleavage in one direction highly perfect, affording smooth polished faces. Color pale green. Luster vitreous; transparent. Very brittle. H=7-5. Gr-=29 —3'1. Pyro.electric. Composition: silica 43'2, alumina 32'6, glucina 24'2. Before the blowpipe with a strong heat it intumesces, and finally fuses to a white enamel. Dif. The very perfect cleavage of this glassy mineral is like that of topaz, and at once distinguishes it from tourmaline and beryl. It differs from topaz in its very oblique crystals Obs. Occurs in Peru, and with topaz in Brazil. Uses. The crystals of this mineral are elegant gems of themselves, but they are seldom cut for jewelry on account of their brittleness. CHRYSOBERYL. Trimetric. In modified rectangular prisms. 6: e=1 193 1 46i. i: e-125 20'. Cleavage 2 not very distinct, parallel to M. X y ^Also in compound crystals, as in llli. k fi g. 2. Crystals sometimes thick;; often tabular. Color bright green, from a light /shade to emerald green; rarely l raspberry o" columbine red by transmitted light. St.eak 1no&ored. Luster vitreous. Transparent to translucent. 1 —8'5. Gr= 3'5 -38. Composition: alumina,0'2, glucina 19 8= 00. A little ron is sometimes present. Infusible and unaltered before the blow-pipe. Alexandrite is a name given to an emerald-green variety rom the Urals, which is supposed to be colored by chrome, What is the form and cleavage of euclase? what the color and luster 1 How is it distinguished 1 What are its uses? What is the appearance. ofchrysoberyl? its hardness? its composition? What is alexandrite? 200 ZIRCONIA. and to bear the same relation to ordinary chrys leryl as emerald to beryl. Dif. Near beryl, but distinct in its often tabular crystal. lizations. and its entire infusibility. Obs. Chrysoberyl occurs in the United States in granite at Haddam, Conn., and Greenfield, near Saratoga, N. Y., associated with' beryl, garnet, etc. The name chrysoberyl is from the Greek chrysos, golden, and beryllos, beryl. Cymophane is another name of the species, alluding to its opalescence, and derived from the Greek kuma, wave, and phaino, to appear. Uses. The crystals are seldom sufficiently pellucid and clear from flaws to be valued in jewelry; but when of fine quality, it forms a beautiful gem, and is often opalescent. Phenacite. Colorless or bright wine-yellow, inclining to red, of vitreous luster and transparent to opaque. Crystals and cleavage rhombohedral. H=8. Gr=2-97. Composition, silica 54-3, glucina 45-7, with a trace of magnesia and alumina. Unaltered before the blowpipe. From Perm, Siberia, with emerald. Leucophane. Resembles somewhat a light green apatite. H=3'5. Gr=2-97. Powder phosphorescent. Pyro-electric. Composition, silica 47-8, glucina 11-5, lime 25-0, protoxyd of manganese 1-01, potassium 0'3, sodium 7'6, fluorine 6'2. From Norway in syenite, accompanying albite and elaeolite. Helvin. Helvin occurs in Saxony and Norway in tetrahedrons of a wax yellow or brownish color. H=6-6'5. Gr=3-1-3-3. Luster vitreous. It contains silica, oxyds of iron and manganese, sulphuret of manganese, with glucina and alumina. 6. ZIRCONIA. ZIRCON. Dimetrrc. In square prisms and octahedrons. M: e= 132~ 10; e: e=123' 19'. Cleavage parallelto ^ M, but not stronglymarked. Usually in crystals; but also granular. Color brownish-red, brown, and red, of clear tints; also yellow, gray and white. Streak un. colored. Luster more or less adamantine. Often transparent; also nearly opaque. Fracture con. choidal, brilliant. H =7*5. Gr=4'-0-4'8. How does chrysoberyl differ from beryl? Where and how docs it occur? What is the origin of the name chrysoberyl? What are its uses? Describe zircon? ZIRCON. 201 Varieties and Composition. 1 ransparent iwd specimens are called hyacinth. A colorless variety from Ceylon, hav. ing a smoky tinge, is called jargon; it is sold for inferio diamonds, which it resembles, though much less hard. The name zirconite is sometimes applied to crystals of gray or brownish tints. Consists of silica 3382, zirconia 6o-8. Infusible before the blowpipe, but loses color. Forms with borax a diaphanous glass. Dif. The hyacinth is readily distinguished from spinel by its prismatic form and specific gravity, as well as its adamantine luster and a less clear shade of red. Its infusibility, hardness, and other characters, distinguish it from tourmaline, idocrase, staurotide, and the minerals it resembles. Obs. The zircon is confined to the crystalline rocks, including lavas and granular limestone. Hyacinth occurs mostly in grains, and comes from Ceylon, Auvergne, Bohe. mia, and elsewhere in Europe. Siberia affords crystals as large as walnuts. Splendid specimens come from Greenland. In the United States, fine crystals of zircon occur in Bun. combe county, N. C.; of a cinnamon red color in Moria, Es. sex county, N. Y.; also at Two ponds and elsewhere, Orange county, in crystals sometimes an inch and a half long; in Hammond, St. Lawrence county, and Johnsbury, Warren county, N. Y.; at Franklin, N. J.; in Litchfield, Me.; Middlebury, Vt.; Haddam and Norwich, Conn. The name hyacinth is from the Greek huakinthos. But it is doubtful whether it was applied by the ancients to stones of the zircon species. Uses. The clear crystals (hyacinths) are of common use in jewelry. When heated in a crucible with lime, they lose Jheir color, and resemble a pale straw.yellow diamond, for which they are substituted. Zircon is also used in jewelling watches. The hyacinth of commerce is to a great extent cinnamon stone, a variety of garnet. The earth zirconia is also found in the rare minerals eudialyte and wohlerite; also in polymignite, aschynite, erstedite; also sparingly in 4ergusonite. What is the composition of zircon? What are its varieties? H w does it differ from spinel and other minerals? How does it occur What is said o' its uses? Does the earth zirconia occur in other min erals 20*2 METALS. Eudialyte. In modified acute rhombohedrons; vitreous and of a red color. R: R=730 30'. Transverse cleavage, perfect; opaque oi nearly so. It is a silicate of zirconia, lime, soda and iron, and gelatinizes in acids. From West Greenland, in white feldspar. IVohlerite. In tabular crystals of light yellow and brownish-shades; sometimes transparent. Consists mainly of silica, columbic acid, zirconia, (15 per cent.,) lime and soda. From Brevig, Norway. JEschynite. A titanate of zirconia and oxyd of cerium, with some lime and oxyd of iron. Black and submetallic, or resinous in luster H=5-6. Gr —49- 52. From the Ural. CErstedite. A titanate and silicate of zirconia. Color brown H=5-5. Gr=3.629. In brilliant crystals from Arendal, Norway. l1lalacone. Contains silica 31-3 zirconia 63'4, with water 3. Form that of zircon. Gr=3-9. H=6. Appears to be a zircon containing water. Color bluish white, brownish, reddish. Streak colorless. 7. THORIA. The earth Thoria has been found only in a rare mineral named fiom its constitution thorite, and in the ores monazite, (p. 206,) and pyrochlore, (p. 208.) Thorite is a hydrous silicate of thoria. Color black to resin.yellow. Powder light orange to brown. Gr =46 — 5'3. From Norway. CLASS VII.-METALS AND METALLIC ORES..General condition of Metals and Metallic Ores in nature.Metals are found either native, or mineralized by combination with other substances. The common ores are compounds of the metals with oxygen, sulphur, arsenic, carbonic acid, or silica. For example, the oxyds and carbonate of iron are the common workable iron ores; sulphuret of lead (called galena) is the lead ore of the arts; arsenical cobalt is the principal source of cobalt and arsenic. Only a few of the metals occur native* in the rocks. Of these, gold, platinum, palladium, iridium, and rhodium, are with a rare exception, found only native. The bismuth What is said of thoria? How do metals occur? What are ores Give examples from ores of iron, lead, cobalt? What metals occur principally native? * By native is understood either pure, or alloyed with other metals, excluding those metals, like arsenic or tellurium, which destroy the malleability of the metal and disguise its character. Native gold is much of it an alloy of gold and silver. But aurotellurite, a compound of gold and te'l:rium with some lead and silver, is properly mineralized gold. METALLIC ORES. 208 of the shops is obtained from na'ive bismuth. Native silver native mercury, and native copper, are sometimes abundant. but are far from being the main sources of these metals. The other native metals are mineralogical rarities. Perhaps we should except from this remark native iron, which constitutes large meteoric masses, thougi very rarely if ever seen of terrestrial origin. Their associations and impurities.-The ores of the metals are often much disguised by mixtures with one another or with earthy material. Thus a large part tof; iron ore worked in England and this country is so mixc. with clay or silica, that its real character might not be sus pected without some experience in ores. Occasionally ores contain phosphate of iron or some arsenical ores or certain sulphurets, scattered through them; and on account of the difficulty of separating the phosphorus, sulphur, or arsenic, the ore is rendere( comparatively useless. By this intimate mixture of species, tue difficulties of reducing ores are much increased. When different ores are not intimately commingled, they are frequently closely disseminated together through the rock. We find ores of lead and zinc often thus associated; also of cobalt and nickel; of iron and manganese; the ores of silver, lead and copper, and often cobalt and antimony; platinum, iridium, palladium and rhodium. Position in rock.- Metals and their ores occur in the rocks in different ways: 1. In beds or layers between layers of rock, as some iron ores; 2. Disseminated through rocks in grains, nests, or crystals, or extended masses, as is the case with iron pyrites, cinnabar, or mercury ore, and much argillaceous iron; 3. In veins, intersecting different rocks, as ores of tin, lead, copper, and nearly all metallic ores; 4. Very frequently, metallic ores, instead of occurring in true veins, are found in rocks near their intersection with a mass or dike of igneous rock, as in the vicinity of a porphyry or trap dike. This is the case with much of the cop. per ore in Connecticut and Michigan, as well as with much What is said of native iron? How are ores often disguised? Explain by example. How do they occur together? What is an effect of this mixture? What are the positions of ores in the rocks? 204 METALS. silver ore and mercury in South America and elsewhere and often the igneous rock itself contains the same metals disseminated through it. Gangue.-The rock immediately enveloping the ore is called the gangue. A vein often consists for the most part of the rock material called the gangue; and the ore either intersects the gangue in a continued band, or more corn monly, is partly disseminated through it in some places, and is continuous for long distances in others. Often a good vein gradually loses its character, the metal disappears, and the gangue alone is left; but by following on for some distance, it will often resume its former character. The usual gangue in metallic veins is either quartz, calc spar, or heavy spar; less frequently fluor spar. Calc spat is the gangue of the Rossie lead ore; heavy spar of much of the lead ore of the Mississippi valley; fluor spar in some places of the lead of Derbyshire, England.: Reduction of Ores.-In the reduction of an ore, the object is to obtain the metal in a pure state. It is necessary for this purpose to separate, 1, the gangue; 2, the impurities or minerals mixed with the ore; and 3, the ingredient with which the ore is mineralized-as the sulphur, for example, in the common ore of lead. 1. Much of the gangue will be separated in the process of mining and selecting the ore. Another portion is in many cases removed by pounding the ore coarsely, while a current of water is made to pass over it; the water carries off the lighter earthy matters and leaves the heavier ore behind. This process is called washing. With a fusible native metal, as bismuth, it is only necessary to heat the pounded ore in crucibles, and the metal flows out. A fusible ore, as gray antimony, is separated from the rock in the same manner. In the case of gold, which is usually in disseminated grains, mercury is mixed with the pounded rock after washing, which unites with the gold; and thus the gold is dlisolved out from the gangue as water dissolves a salt; 1 Ipor. izing the solvent, mercury, the gold is afterwards obtained. With iron ores, there is no special effbrt to separate the gangue beyond what is done in the process of mining. What is the gangue? What is said of the ore in the gangue? Whal are the common kinds of gangue? What is meant by the reduction of an ore? What is necessary for this purpose l How is the gai-gue separated? How with a fusible inetal or ore? How with gold? METALS. 205 2. The separation of the mineralizing ingredients when ihe ore is pure, is sometimes effected by heat alone; thus the common ores of mercury and lead, both sulphurets, will give up the sulphur in part when heated. In most cases, some material is added to combine with the mineralizing ingre. dient and carry it off; as when certain iron ores (oxyds of iron) are heated with charcoal, the charcoal takes the oxygen (forming the gas carbonic acid which escapes) and leaves the iron pure. 3. When two or more metals are mixed in the ore, one is sometimes removed by oxydation, or in other words, it is burnt out. Thus lead containing silver, is heated in a draft of air; the lead unites with the oxygen of the air and forms an earthy slag, while the silver, which is not thus oxydated, remains untouched. Such a process, carried on in a vessel of bone-ashes, or some material of the kind, which will absorb the oxyd of lead formed, is called cupellation. (See beyond under gold.) Much of the iron in the ordinary cop. ptr ore (copper pyrites) is removed in the common process of reduction in England by repeated fusions and stirring, while exposed to a draft of air. 4. When there are impurities present, or a mixture of the gangue, which is commonly the case, a. material is sought for which will form, when heated, a fusible compound with the gangue and impurities; and this material is called a fux. Most iron ores are associated with quartz or clay, quartz be. ing pure silica, and clay containing 75 per cent. of silica. Common limestone readily fuses into a glass with silica, when used in the requisite proportions, and hence it is gen. erally employed as a flux in iron furnaces. A salt of soda or potash would produce the same result, for these are the ingredients which form with silica common glass. The glass formed is more or less frothy, and is called slag or scoria. Before reduction, the volatile impurities and any water present, are often removed by a process called roasting. The processes of reducing the ordinary metallic ores in the arts are combinations of the different steps here pointed out. There are other chemical methods for certain oases, which it is unnecessary to allude to in this place. How is the mineralizing ingredient separated in some cases? How in others? Explain by examples. How in cases of mixture. Ex plain the process of cupellation. How in still other cases, and explain th use of fluxes by an example. What is said in conclusion of the pro cesses of reduction? 18 METALS. 1. 2. 3. CERIUM, YTTRIUM, LAN'HANUM. Cerium and Yttrium are not used il the arts. The spe cies are infusible alone before the blowpipe or only in the thinnest splinters. YTTROCERITE. Massive, of a violet-blue color, somewhat resembling a purple fluor spar; sometimes reddish-brown. Opaque Luster glistening. H=4-5. Gr=3*4 —35. Composition: fluoric acid 25*1, lime 47'6, oxyd of ceri um, 18'2, and yttria 9'1. Infusible alone before the blow pipe. Obs. From Finbo and Broddbo, near Fahlun in Swe. den, with albite and topaz in quartz. Also from Massachusetts, probably in Worcester county, and from Amity, Orange county, N. Y. Flucerine and Basic Flucerine. These two fluorids of cerium have a bright yellow or yellowish-red color. Infusible alone in the blowpipe flame. They are from Sweden. Parisite. Occurs in bipyramidal dodecahedrons, (fig. 65, page 39,) of a reddish-brown or brownish-yellow color and vitreous fracture. Cleavage easy parallel to the base. Gr=-435. Infusible alone. Composition: carbonic acid 23-5, protoxyds of cerium, lanthanum and didymium 59 4, lime 3'2, fluorid of calcium 11'5, water 2'4. From New Grenada. Lanthanite. Trimetric. In thin minute tables or scales of whitish or yellowish color. H=2'5-3. Composition: carbonate of lanthanum 77-48, water 2409. From Bastnas, Sweden, and Saucon valley n Lehigh Co., Pa. MONAZITE. Monoclinic. In modified oblique rhombic prisms; M > M=93 10, on a — 1400 40, M: e —-136 35. Perfect and brilliant basal cleavage. Observed only in small imbedded crystals. MI If Color brown, brownish-red; subtransparent to nearly opaque. Luster vitreous inclining to resinous. Brittle. H=5. Gr=4-8-5*1. Composition: oxyd of cerium 26'0, oxyd o. lanthanum 23'4, thoria 17'95, phosphoric acid 28-5, with What is said of the blowpipe action of ores of cerium and yttrium What is the appearance and composition of yttrocerite What monazite? CERIUM AND YTTRIUM ORES. 207 oxyd of tin 2*1, protoxyd of manganese 1.9, lime 1*7. In. fusible or nearly so. Decomposed by muriatic acid, evolving chlorine. Dif. The brilliant easy transverse cleavage distinguishes monazite from sphene. Obs. Occurs near Slatoust, Russia. In the United States it is found in small brown crystals, disseminated through a mica slate at Norwich, Conn.; also at Chester, Conn., and Yorktown, Westchester county, N. Y. Cryptolite. A phosphate of the oxyd of cerium in minute prisms (arparently six-sided,) found with the apatite of Arendal, Norway Color pale wine yellow. Gr-=46. ALLANITE. Monoclinic. In oblique rhombic prisms like epidote. Cleavage only in traces. Also massive and in acicular aggregations, the needles sometimes a foot long. Color pitch-brown, brownish-black, streak greenish or brownish-gray, luster pitchy and submetallic. Opaque or nearly so. Brittle. H=55 —6. Gr=-3*3-4-2. Varieties and Composition. Allanite, cerine, and orthite are names of different varieties of this species. The last occurs in acicular crystals as well as massive. They consist of silica and alumina, with oxyds of iron, cerium, lanthanum, and lime. They fuse before the blowpipe to a black glassy globule or pearl. Dif. Allanite differs from garnet, some varieties of which it resembles, in its inferior hardness, and colored streak. Gadolinite fuses with more difficulty and glows on charcoal, be. sides gelatinizing in nitric acid. Obs. Allanite was first brought from Greenland. It occurs in Norway, Sweden, and the Ural. In the United States it has been found in large crystals in Allen's vein, Haddam Conn.; at Bolton, Athol, and South Royalston, Mass.; at Monroe, Orange county, N. Y. Pyrorthite. This appears to be an impure orthite, containing bome carbon, in consequence of which it burns when heated. Hence the name from the Greek pur, fire, and orthite. It comes.rom near Fahlun, Sweden. Mlosandrite is related to allanite. Cerite. A hydrated silicate ot cerium. Color between clove-brown and cherry-red. Luster adamantine. Crystals hexagonal. From Bastnas, Sweden. How is it distinguished from sphene? What is the appearance and composition of allanite? what are its varieties? 208 METALS. Bodenite is a cerium ore, resembling orthite. From Boden is Saxony. I'YROCHLORE. In small octahedrons, with a cleavage parallel to the faces 1 of the octahedron sometimes dis- 2 tinct. Color yellow to brown. Subtransparent to opake. Luster ^^\A,/ vitreous inclining to resinous. H —5. - Gr=3*8 —43. Composition: essentially columbic acid, with oxyds of cerium, thorium, and lime. Ti tanic acid sometimes replaces part of the columbic acid. Fuses with very great difficulty before the blowpipe. The microlite of Prof. Shepard appears to be pyrochlore. Dif. The color, difficult fusibility and colored streak distinguish this species from others crystallizing in octahedrons. It is much softer than spinel. Obs. Occurs in syenite in Norway, and also in Siberia. In the United States it is found in minute octahedrons at the Chesterfield albite vein, Mass. The following species contain yttrium or cerium as a char. acteristic ingredient: Xenotime is a phosphate of yttria,'having a yellowish-brown color pale brown streak, opaque, and resinous in luster. Crystals square prisms, with perfect lateral cleavage. H=4-5. Gr=4-6. Infusible alone before the blowpipe; insoluble in acids. From Lindesnaes, Norway. Gadolinite has a black or greenish-black color, resinous or subvitreous luster, greenish-gray streak. Crystalline form an oblique rhombic prism, with no distinct cleavage. H=6'5-7. Gr.=4'1 —44. Consists mainly of silica, yttria, glucina, and protoxyd of iron, with also the recently discovered oxyd of lanthanum. From Fahlun and Ytterby, Sweden; also from Norway and Greenland. Fergusonite is a columbate of yttria, crystallizing in secondaries to a square prism. Color brownish-black; luster dull, but brilliantly vitreous on a surface of fracture. Infusible before the blowpipe but loes its color. From Cape Farewell, Greenland. Yttro-tantalite is a tantalateof yttria containing half as much yttria as t}: preceding. There are three varieties, the black, the yellow, and the brown or cark-colored. They are infusible. From Ytterby, Sweden. and ait Broddbo and Finbo, near Fahlun. Euxenite is a columbate of yttria with some titanic acid and oxyd of uranium. Massive. Color brownish-black. Streak powder reddish brown. Infusible. From Norway. What is the appearance and composition of pyrochlore? TITANIUM ORES. 209 Tshcefkinite. Resembles gadolinite. Color velvet-black. Luster vitreous. Streak dark brown: H-=5-5-5. Gr-=45-46. It is a silico-titanate of cerium. Gelatinizes readily on heating in muriatic acid. From theIlmen Mountains, in Siberia. Polymignite is principally a titanate of zirconia, yttria, iron and cerium. It has a black color, a brilliant submetallic luster within, a dark brown streak, and a conchoidal fracture. Generally in slender striated crystals, secondaries to a rectangular prism. H-=65. Gr=4'7 —4'9. From Norway. Also, as observed by Prof. C. U. Shepard, from Beverly, Mass. Polycrase is near polymignite. Massive, and in thin linear crystals, of bright luster. Color black. Streak grayish-brown. H=5'5. Gr -5'1. With orthite in Norway. Sanarskite is a columbate of uranium, yttria and iron. Velvetblack. H=5-5-6. Gr=5'4 —57. From the Urals, also from North Carolina.Eschynite. In crystals, black to brownish yellow; luster resinous to submetallic; streak gray to yellowish brown or black. H=5-6. Gr=4'9- 51. A titanate of zirconia and cerium. From Miask in the Urals, in feldspar with mica and zircon. Rutherfordite. Blackish brown, with a vitreo-resinous fracture and no cleavage; powder yellowish-brown. From the gold mines of Rutherford Co., N. C., along with rutile, brookite. zircon and monazite. It contains 58'5 per cent. of titanic acid with 10 per cent. of lime, and perhaps cerium and yttrium. (4. TITANIUM. Titanium occurs in nature combined with oxygen, forming titanic acid or oxyd, and also in combinations with different bases. It has not been met with native. The ores are infusible alone before the blowpipe, or nearly so. Their specific gravity is between 3 0 and 4-5. With salt of phosphorus, in the inner flame on charcoal, a globule is obtained with some difficulty, which is violet blue when cold. In the species called silico-titanates, that is, containing silica and titanic acid, the titanic acid is a bate. Titanium and iron, and allied elements, are isomorphous, and analo. gous oxyds replace one another. See author's System of Min., 4th edition. How does titanium occur? What is said of its ores 1 210 METALS. RUTILL. Dimetric. In prisms of eight, twelve, or more sides, with pyramidal terminations, and often bent, a as in the figure; a: a=123 8'. Crystals // often acicular, and penetrating quartz. Some- \\ / times massive. Cleavage lateral, somewhat listinct. Color reddish-brown to nearly red; streak very pale. rown. Luster submetallic-adamantine. Transparent to opaque. Brittle. H=6-6'5. Gr —=415 —425. Composition: titanium 61, oxygen 39. Sometimes contains iron, and has nearly a black color; this variety is called nigrine. Unaltered alone before the blowpipe. Forms a hyacinth-red bead with borax. Dif. The peculiar subadamantine luster of rutile, and brownish-red color, much lighter red in splinters, are striking characters. It differs from tourmaline, idocrase, and augite, by being unaltered when heated alone before the blowpipe; and from tin ore, in not affording tin with soda; from sphene in its crystals. Obs. Occurs imbedded in granite, gneiss, mica slate, syenite, and in granular limestone. Sometimes associated with specular iron, as at the Grisons. Yrieix in France, Castile, Brazil, and Arendal in Norway, are some of the foreign localities. In the United States, it occurs in crystals in Maine, at Warren; in New Hampshire, at Lyme and Hanover; in Massachusetts, at Barre, Windsor, Shelburne, Leyden, Conway; in Connecticut, at Monroe and Huntington; in New York, near Edenville, Warwick, Amity, at Kingsbridge, and in Essex county at Gouverneur; in the District of Columbia, at Georgetown; in North Carolina, in Buncombe county; in the gold district of Georgia. Uses. The specimens of limpid quartz, penetrated by long acicular crystals, are often very elegant when polished. A remarkable specimen of this kind was obtained at Hanw over, N. H., and less handsome ones are not uncommon. Polished stones of this kind are called fleches d' amour (love's arrows) by the French. Describe rutile. Of what does it consist? How is it distinguished rom other minerals? What are its uses' ORES OF TITANIUM. 211 This ore is employed in painting on porcelain, and quite!argely for giving the requisite shade of color and enamel appearance to artificial teeth. Anatase. Brookite. These species have the same composition as rutile. Anatase occurs in slender nearly transparent octahedrons, of a brown color. A: A=970 56'. H=55- 6. Gr=3-8-3 9. From Dauphiny, the Tyrol, and Brazil. Said to accompany native titanium in slags from the iron furnaces of Orange county, N. Y. Brookite is met with in thin hair-brown crystals, attached by one edge. H=55-56. The crystals are secondaries to a rhombic prism Fron Dauphiny, and Snowdon in Wales. Said to occur at the Phenix ville tunnel on the Reading railroad, Pa. Arkansite is Brookite. SPHENE, Monoclinic. In very oblique rhombic prisms; the lateral faces having angles either of 76' 1', 113' 28' (r: r) 1 2 3 7 t: i'e ZZ nn 1360 4' (n: n), or 133' 48'. The crystals are usually thin with sharp edges. Cleavage in one direction sometimes perfect. Occasionally massive. Color grayish-brown, gray, brown or black; sometimes yellow or green; streak uncolored. Luster adamantine to resinous. Transparent to opaque. H- 5-5.5. Gr 3-2 —36. Composition: silica 30-5, titanic acid 41*3, lime 28'2. Before the blowpipe, the yellow varieties are unaltered in color, and others become yellow; on charcoal, they fuse on the edges with a slight intumescence to a dark glass. The dark varieties of this species were formerly called itanite, and the lighter sphene. The name sphene alludes o the wedge.shaped crystals, and is fiom the Greek sphcn, wedge. What is said of the crystals of sphene? What are.he color, lusttr, and hardness? the composition { 212 MI ETALS. Dif. The crystals, in general, by their thin wedge shapt readily distinguish this species when crystallized; bu, some crystals are very complex. From garnet, tourmaline, and idocrase, this species is distinguished by its infusibility before the blowpipe. Obs. Sphene occurs mostly in disseminated crystals in granite, gneiss, mica slate, syenite, or granular limestone. It is usually associated with pyroxene and scapolite, and often with graphite. It has been found in volcanic rocks. The crystals are commonly i to a an inch long; but are some. times 1 to 2 inches. Foreign localities are Arendal in Norway; at St. Gothard and Mount Blanc; in Argyleshire and Galloway in Great Britain. In the United States, it is met with in good crystals in New York, at Rogers' Rock on Lake George, with graphite and pyroxene, at Gouverneur, near Natural Bridge in Lewis county, (the variety called lederite,) in Orange county in Monroe, Edenville, Warwick, and Amity, near Peekskill in Westchester county, and near West Farms. In Massachusets, at Lee, Bolton, and Pelham. In Connecticut, at Trumbull. In Maine, at Thomaston. In New Jersey, at Franklin. In Pennsylvania, near Attleboro', Bucks county. In Delaware, at Dixon's quarry, 7 miles from Wilmington. In Maryland, 25 miles from Baltimore, on the Gunpowder. Greenovite is a sphene containing manganese. Perofakite. This is a titanate of lime. It occurs in minute modified cubes, grayish to iron-black in color. Gr=4'017. H=5-5. From the Urals. Pyrrhite. In minute regular octahedrons, of a yellowish color. Transparent; vitreous. H=6. From near Mursinsk, Siberia; also from the Western Islands, as first detected by Mr. J. E. Teschemacher of Boston. Supposed to contain titanic acid. Keilhauite, or yttro-titanite. Related to sphene. Brownish-black, with a grayish-brown powder. Gr=3-69. H=6-5. Fuses easily. Contains silica 30-0, titanic acid 29'0, yttria 9-6, lime 18-9, peroxyd of iron 6-4, alumina 6-1. From Arendal, Norway. Warwickite. It occurs in prismatic crystals, of a brownish to an irongray color, often tarnished bluish or copper-red. Luster metallic pearly to imperfectly vitreous or resinous. H=5-6. Gr=3 —3'3. Infusible alone before the blowpipe. From magnesian limestone, with ilmenite and spinel, at Amity, Orange county, N. Y. What are distinctive characteristics of the species sphene In what rocks does it occur? ORES OF TIN. 2]3 The analysis of warwickite, by Smith and Brush, has shown that it contains 20 per cent. of boracic acid, and therefore is a borotitanate. Schorlomite. Black, and often irised tarnished. Streak grayishblack. H-7 —75. Gr-380. Fuses readily on charcoal. Easily decomposed by the acids, and gelatinizes. Near gadolinite. From the Ozark Mountains, Arkansas. Besides the ores here described, titanium is an essential constituent also of ilmenite, (titanic iron); also in the zir. conia and yttria ores ceschynite, cerstedite, and polymignite, and in some other rare species; sometimes in pyrochlore. The metal titanium has seldom been obtained in the me. tallic state, and is not used in the arts. The uses of the oxyd have been mentioned. 5. TIN. Tin has been reported as occurring native. There are two ores, the oxyd and a sulphuret. It also occurs in some ores of columbium. The specific gravity of the sulphuret is between 4'3 and 44; that of the oxyd, between 6'5 and 7'1. With carbonate of soda on charcoal, a globule of tin is ob. tained. When the tin is in minute quantities in a mineral, it is well to add also some borax, and by this means, especially if any iron present be first removed, or if it be only in small quantaties, even a i per cent. of tin may be detected. Native tin is found in gray metallic grains in the gold washings of the Ural. The crystals of pure tin are either tesseral (cubic), or dimetric, this metal being dimorphous. rIN PYIUITlS.-Sulphuret of Tin. In cubes and massive. Color steel-gray or yellowish Streak black. Brittle. H-4. Gr=4'3 —46. Composition: sulphur 30, tin 27, copper 30, iron 13. Obs. This rare ore has been found only in Cornwall. where it is often called bell-metal ore, from it~ frequent ronze appearance. How does tin occur in the mineral kingdom? How is it detected y the blowpipe? What is the appearance and corrposition of tia yrites? 214 METALS. TIN ORE.-Oxyd of Tin. Dimetric. In modified square prisms and odtahedrons oftln compound: e: e=121~ 40'; a: a (over the summit) 11'23 10'; a: a (over a ter. minal edge) 133~ 31'; M: M X ee-=133~ 34'; M: e-135'. Cleavage indistinct. Also massive or in grains. Color brown or black, with a high adamantine luster when in crystals. Streak pale gray to brownish. Nearly transparent to opaque. H- 67. Gr=6'5- 71. Composition: when pure, tin 78-38, oxygen 21'62; often contains a little oxyd of iron, and sometimes oxyd of columbium. Before the blowpipe alone, infusible; with soda, affords a globule of tin. Stream tin is the gravel-like ore found in debris in low grounds. Wood tin occurs in botryoidal and reniform shapes with a concentric and radiated structure; and toad's-eye tin is the same on a small scale. Dif. Tin ore has some resemblance to a dark garnet to black zinc blende, and to some varieties oftourmaline. I is distinguished by its infusibility, and its yielding tin before the blowpipe on charcoal with soda. It differs from blend( also in its superior hardness, and in giving no fumes on char. coal before the blowpipe. Obs. Tin ore occurs in veins in the crystalline rocks granite, gneiss, and mica slate, associated often with wolfram, copper and iron pyrites, topaz, tourmaline, mica or talc, and albite. Cornwall is one of its most productive localities. It is also worked in Saxony, at Altenberg, Geyer, Ehrel. friedersdorf and Zinnwald; in Austria, at Schlackenwald and other places; in Malacca, Pegu, China, and especially the Island of Banca in the East Indies. It has also been found in Galicia, Spain; at Dalecarlia in Sweden; in Russia; in Mexico, Brazil, and Chili; in the United States, at Chesterfield and Goshen, Mass., in some of the Virginia gold mines, What is the crystallization of tin ore? Mention its other physical characters? What is its composition and blowpipe reactions? Whnt is stream tin? wood tin, and toad's eye? How is tin ore distinguished from garnet, blende, and tourmaline? ORES OF TI% 215 and in ioine and Jackson, N. H. At the last menitioned place, whvoe this ore was discovered by Dr. C. 1'. Jackson, there are sufficient indications to warrant exi loration. CENFRAL REMARKS ON TIN AND TIN ORES. The principal tin mines now worked, are those of Cornwall, Banca and Malacca, Saxony, and Austria. The Cornwall mines are supposed to have been worked long befor the Christian era. Herodotus, 450 years before Christ, is believed to allude to the tin islands of Britain under the cabalisticname Cassiterides derived from the Greek kassiteros, signifying tin.* The Phoenicians are allowed to have traded with Cornubia, (as Cornwall was called, it is supposed from the horn shape of this western extremity of England.) The Greeks residing at Marseilles were the next to visit Cornwall, or the isles adjacent, to purchase tin; and after them came the Romans, whose merchants were long foiled in their attempts to discover the tin market of their predecessors. Camden says: " It is plain that the ancient Britons dealt in tin mines from the testimony of Diodorus Siculus, who lived in the reign of Augustus and Timaus, the historian in Pliny, who tells us that the Britons fetched tin out of the Isle of Icta, (the Isle of Wight,) in their little wicker boats covered with leather. The import of the passage in Diodorus, is that the Britons who lived in those parts dug tin out of a rocky sort of ground, and carried it in carts at low water, to certain neighboring islands; and that from thence the merchants first transported it to Gaul, and afterwards on horseback in thirty days to the springs of Eridanus, or the city of Narbona, as tor a common mart. /Ethicus too, another ancient writer, intimates the same thing, and adds that he had himself given directions to the workmen." In the opinion of the learned author of the Britannica here quoted,and others who have followed him, the Saxons seem not to hae meddled with the mines, or according to tradition, to have employed the Saracens; for the inhabitants of Cornwall to this day call a mine that is given over working Attal-Sarasin, that is, the leavings of the Saracens.t The Cornwall veins, or lodes, mostly run east and west, with a diphade, in the provincial dialect-varying from north to south; yet they are very irregular, sometimes crossing each other, and sometimes a promising vein abruptly narrows or disappears; or again they spread out into a kind of bed orfloor. The veins are considered worth working when but three inches wide. The gangue is mostly quartz, with some chloWhere are the principal tin mines? What is said of the Coinwal! veins? * This term and the stannum of the Romans, or plumbum candmdum are supposed to include the white compounds of lead and other metals and it has even been doubted whether the metal tin was ordinarily included. t Manuf. in Metals; London, 1834. iii. 2. 216 METALS. rite. Much of the tin is also obtained from loose stones, (called shodes,) and courses of such stones or tin debris are called streams, whence the name stream tin. The ore taken from the mines is first pounded or stamped in a stamping mill, and then washed by running water, which carries off to a great extent the lighter impurities and leaves the heavy ore behind, with still some of the gangue. It is next roasted in a reverberatory furnace, to expel any arsenic or sulphur derived from the presence of other ores, and then again washed. After being thus purified as far as possible, the ore is usually mixed with pit-coal and a little lime, and strongly heated in either a reverberatory furnace or what is called a blowing furnace. A state of fusion is kept up for about eight hours. The metal is then drawn off into iron vessels. As it contains still some slag or earthy matters, it is remelted at a lower temperature, which does not fuse the impurities, and kept agitated for a while by wet charcoal or carbonized wood; it is then skimmed and run into blocks, weighing from 275 to 325 pounds each. The tin thus made fron the ore derived from the mines, is called block tin, and is less pure than that from the stream ore; the latter was formerly called grain tin, though now this is a general term applied to the purest kinds of tin in commerce. In an assay of tin ore, after pulverizing, washing, roasting, and weighing, the ore should be mixed with lampblack or charcoal, and heated quickly in a covered crucible to a white heat. On removing the crucible from the fire, a button of tin will be found in it. If the ore is not pure, carbonate of soda or borax may be added to the lampblack. The result is good if the tin obtained is malleable and not brittle. The tin may be farther purified by fusing it in a ladle, and pouring it into another vessel whenever the cooling has hardened the alloys, or just before the tin itself begins to harden; it will flow out, leaving the impurities behind. The best tin ores afford 65 to 70 per cent. of tin in the large way. The annual production of tin in different countries, is as follows Great Britain, - 140,000 cwt. Banca and Malacca, - - - 100,000 " Saxony, - -.. 3,500 " Austria, - - - 380 " Sweden, - - - -750 " Tin is used in castings, and also for coating other metals, especially ron and copper. Copper vessels thus coated were in use among the Romans, thongh not common. Pliny says that the tinned articles could scarcely be distinguished from silver, and his use of the words incoquere and incoctilia, seems to imply, as a writer states, that the process was the same as for the iron vares of the present day, by immersing the vessels in melted tin. The sheets of iron for tinning are cleaned with acid, heated, and then cold-rolled; again subjected to dilute acid, and afterwards scoured with sand in pure water: then two or three hundred What are the steps in the process of reduction? Describe the mode f assaying tin ore. What is the yield of Great Britain in tin? What be whole amount from the tin mines of the world? How is iron inned? ORES OF MOLYBDENUM, 217 sheets in a vertical position are immersed, first in a vat of grease, and then in a cast iron bath containing about 5 cwt. of melted tin; they remain in the tin for an hour and a half, and are then taken out. As there is now two or three times too much tin on the plates, they are made to undergo a process called washing, in a vessel of melted grain tin, by which the excess of tin is removed; after which they are cleaned and rubbed in bins of dry bran until they receive the characteristic silver polish. When tin plate slightly heated is sponged over quickly by an acid, (nitro-muriatic,) the crystalline character of the tin is brought out, and the ware so treated is called moire metallique. The plate before subjecting it to the acid should be well washed with alkali; and after the action it should be immediately washed in clean water and dried. Tin is also used extensively as tinfoil, the sheets of which are about 1000th of an inch thick; also with quicksilver it is used to cover glass in the manufacture of mirrors. It is alloyed with copper in various proportions, constituting thus 7 to 10 per cent. of bronze; 20 per cent. of the ancient bronze for weapons; 20 per cent. of the metal for cymbals and the Chinese gong; 20 to 30 per cent. of bell metal; and 30 to 40 per cent. of speculum metal. The oxyd of tin, as obtained by chemical processes, is employed on account of its hardness for forming a paste for sharpening fine cutting instruments. The chlorid of tin is an important agent in the precipitation of many colors as lakes, and in fixing and changing colors in dyeing and calico printing. The bisulphuret of tin has a golden luster, and was termed aurum musivum, or mosaic gold, by the alchemists. It is much used for ornamental painting, for paper hangings and other purposes, under the name of bronze powder. Pins are tinned by boiling them for a few minutes in a solution of 1 part of cream Qartar, 2 of alum, 2 of common salt, in 10 or 12 of water, to which some tin filings or finely granulated tin are added. Tin medals or castings, are bronzed by being washed over with a solution of 1 part of piotosulphate of iron, 1 of sulphate of copper, in 20 of water; this gives a gray tint; they are then brushed over with a solution of 4 parts of ierdigris in 11 of distilled vinegar, and then polished with a soft brush and colcothar. 6. MOLYBDENUM. Molybdenum occurs in nature as a sulphuret, and sparingly as an oxyd. Also as molybdic acid, in molybdate of lead. 1. MOLYBDENITE.-Sulphuret of Molybdenum. In hexagonal crystals, plates, or masses, thin foliated like graphite, and resembling that mineral. Color pure leadgray; streak the same, slightly greenish. Thin lamine very flexible; not elastic. H=1-1-5. Gr==4-5-4'75. In what other way is tin used? What alloys are made with it What are the characters of molybdenite? 218 METALS. Composition: molybdenum 59*0, sulphur 41'0. Infilsible before the blowpipe, but when heated on charcoal, sulphui fumes are given off, which are deposited on the coal. Dis. solves in nitric acid, excepting a gray residue. Dif. Resembles graphite, but differs in its paler color and streak, and also in giving fumes of sulphur when heated, as well as by its solubility in nitric acid. Obs. Occurs in granite, gneiss, mica slate, and allied rocks; also in granular limestone. It is found at Numedahl in Sweden, Arendal in Norway, in Saxony, Bohemia, at Caldbeck Fell in Cumberland, and in the Cornish mines. In the United States, it occurs in Maine at Blue Hill Bay, Camdage farm, Brunswick, and Bowdoinham; in New Hampshire at Westmoreland, Landaff, and Franconia; in Massachusetts at Shutesbury and Brimfield; in Connecticul at Haddam and Saybrook; in New York, near Warwick; in New Jersey, near the Franklin furnace. Mlolydic ocher. An earthy yellow or whitish oxyd of molybdenum, (or rather molybdic acid,) occurring only as an incrslauon. Occurs at Westmoreland, N. H. For molybdate of lead, see under Lead. 7. TUNGSTEN. Tungsten is found in combination with iron, lead, and lime, constituting wolfram, (p. 244,) tungstate of lead, (p. 283,) and tungstate of lime. It also occurs sparingly in some ores of columbium, as in certain varieties of the minerals pyro. chlore, columbite, and yttro-columbite. It is met with it very small quantities as an ocher, or as tungstic acid, form. ing a yellow powder on other tungsten ores. Lane's mine, Monroe, Conn., the adjoining town of Hunt. ington, and Camdage farm, Blue Hill Bay, Me., are the only American localities of tungsten ores vet discovered. Lane's mine affords wolfram and the calcareous tungsten, and also the tungstic ocher. These ores are frequent associates of tin ore. No use in the arts has been made of this netal or its com. What is its composition How does it differ frnia traphii? What are the principal ores of tungsten? Has any use been made ot them in the arts? ORES OF TELLURIUM. 219 pounds. Tungstic acid is a fine yellow, even brighter than chrome yellow; but it turns green on exposure to the sun's rays. The metal tungsten was so called from the Swedish word tung, meaning heavy, the calcareous tungsten being pecu. liarly heavy for an earthy looking mineral. It has also been called scheelium, in honor of the chemist Scheele. Tungstate of lime. In square octahedrons; A: A=100' 6' and 130 20. Cleavage octahedral, perfect. Color yel lowish-white, or brownish. Brittle. H=4 —45. Gr= 6'075. Composition, tungstic acid 7-8, lime 19'06. Infu sible alone, or only on the thinnest edges. Found with wol fram at Lane's mine, Munroe, Conn. 8. VANADIUM. Vanadium is a rare metal. It is found in nature as vanadic acid in the vanadate of lead (p. 285), and vanadate of copper (p. 302), and also combined with lime. The last mentioned has a brick-red color, a foliated structure, and a bright shining luster. 9. TELLURIUM. Tellurium occurs native, and also in combination with gold, silver, lead, and bismuth. The metal is distinguished from arsenic and selenium by giving no odor before the blowpipe; from antimony and bismuth by affording fumes in a glass tube below the temperature of fusing the glass; and when heated on charcoal, the oxyd covers the coal with a brownish-yellow oxyd, like bismuth; but the inner flame directed on this oxyd is tinged bright green, while bismuth gives no color. This last test distinguishes also the ores of tellurium. Native tellurium occurs in six-sided prisms, of a tin-white color, and ll o,las-ive. Brittle. H —2-25. G;r-6l- 6-3. Composition, pure tellurium with a little gold. From Transylvania. Telluric Ochre. Occurs with native tellurium in Transylvanla, n small whitish or yellowish masses, radiated in strlcture, and also as an earthy coating. Supposed to be tellurous acid. In what minerals is vanadium found? How does tellurium occv- is nature? How is this metal distinguished from arsenic and selenium I 220 METALS. 10. BISMUTH. Bismuth occurs native, and also in combination with sul. phur, tellurium, oxygen, carbonic acid and silica. The ores fuse easily before the blowpipe, and an oxyd is produced which stains the charcoal brownish or yellow, without rising in fumes.* Specific gravity of the ores, between 4'3 and 95 NATIVE BISMUTH. Rhombohedral. Cleavage rhombohedral, perfect. In rhombohedrons, near cubes in form, R: R —87~ 40'; gen. erally massive, with distinct cleavage: sometimes granular. Color and streak silver white, with a slight tinge of red. Subject to tarnish. Brittle when cold, but somewhat mal. leable when heated. H=2 —2-5. Gr=97-9 -8. Fuses at a temperature of 476~ F. Composition: pure bismuth, with sometimes a trace of arsenic. Evaporates before the blowpipe, and leaves a yel low coating on charcoal. Obs. Bismuth is abundant with the ores of silver and co bait of Saxony and Bohemia, and occurs also in Cornwall and Cumberland, England. At Schneeberg, it forms arborescent delineations in brown jasper. In the United States, it has been found at Lane's mine, Monroe, where it occurs with tungsten, galena and pyrites, but is not abundant; also at Brewer's mine, in Chesterfield district, South Carolina. There are other ores of bismuth, but none of them are common. Sulphuret of bismuth. Massive and in acicular crystals, of a leadgray color. H-2-25. Gr-6'55. Contains bismuth 81, sulphur What are the color and physical characters generally of native bismuth? What is its temperature of fusion? With what ores is it usually associated? * Tellurium produces a similar stain on charcoal, but on directing the inner flame on the coating, it colors the flame strongly green, while with bismuth no color is obtained. Antimony gives white fumes, producing a white coating on charcoal, and the flame directed on it is colored greenish-blue. oKES OF IsSMUTH. 221 18'7. Fuses in the flame of a candle. From Cumberland, Cornwall, Johanngeorgenstadt, and Sweden. Acicular bismuth. A sulphuret of bismuth, lead and copper, containing a trace of gold. In acicular crystals of a dark lead-gray color, with a pale copper-red tarnish. Gr-=6 1. Fuses easily, emitting fumes of sulphur. From Siberia. A cupreous bismuth, of a pale lead-gray color, contains 34 7 per cent. of copper. Tetradymite. Consists of tellurium and bismuth. It has a foliated structure, a pale steel-gray color, and soils like molybdenite Gr==7'5. From Schemnitz and Retzbanya, Brazil, Virginia and North Carolina Bismutite. In acicular crystals and massive. Color greenish or yellowish. H-=-4 —45. Gr==6'8-7'7. It is a carbonate of ihsmuth. From Cornwall; also South Carolina. Bismuth ocher is an impure oxyd, occurring massive and earthy; color greenish, yellowish, or gray ish-white. From Saxony, Bohemia and Siberia. Bismuth blende is a silicate of bismuth. Color dark hair-brown, or yellow. H-3=5 —45. Gr-==59-6'0. In dodecahedrons and massive. From Saxony. GENERAL REMARKS ON BISMUTH AND ITS ORES. The first notice of the metal bismuth is in the writings of Agricola, In 1529. It is known in the arts under the name of tin glass, from the French name etain de glace. It is obtained for the arts from the native bismuth alone, and. much the greater part of the metal comes from Schneeberg in Saxony. The American mine at Monroe, Conn., has been but little explored, and has afforded only a few small specimens. The metal is obtained by heating the powdered ore in a furnace, when the bismuth melts, and separating from the gangue, is drawn off into cast iron moulds. Bismuth is employed in the manufacture of the best type metal, to give a sharp, clear face to the letter. Equal parts of tin, bismuth and mercury form the mosaic gold used for various ornamental purposes Plumber's solder, used for soldering pewter wares and other purposes, consists of I part of bismuth, 5 of lead, and 3 of tin. Bismuth is one of the constituents of fusible metal, of which spoons are made, as toys, that will melt on putting them into a cup of hot tea; this fusible alloy consists of 8 parts of bismuth, 5 of lead, and 3 of tin; or better of 10j parts of bismuth, 5 parts of lead, and 3 of tin. It may be rendered more fusible still by adding mercury. An alloy of tin and bismuth in equal parts melts at 280~ F. But with less bismuth, tin is increased in hardness. The magestens of bismuth, a white hydrated oxyd precipitated by adding water to a solution of the nitrate, is used as a cosmetic. It contains a little nitric acid. Pearl powder is a similar preparation made in the same way from a nitrate containing some chlorid of bismuth These powders blacken when exposed to an offensive atmosphere. What is said of Bismuth and its ores? 222 M r.TALS. II; ANTIMONY. The metal antimony is occasionally found native. It is usually combined with sulphur, or sulphur and lead. It it also found in combination with arsenic, oxygen, and lime also with nickel, silver, and copper. It rises easily in white fumes before the blowpipe with. out odor, and in one or both of these particulars, it is dis. tinguished from other vaporizable metals. The ores fuse very easily, and all evaporate, some giving off fumes of sul. phur. Specific gravity below 7. NATIVE ANTIMONY. Rhombohedral. Usually massive, with a distinct lamellar structure. Color and streak tin-white. Brittle. H =33-5. Gr =6'6 —675. Composition: pure antimony, often with a little silver or iron. Fuses easily and passes off in white fumes. Obs. Occurs in veins of silver and other ores in Dau. phiny, Bohemia, Sweden, the Hartz, and Mexico. GRAY ANTIMONY.-Sulphuret of Antimony. Trimetric. In right rhombic prisms, with striated lateral faces. M: M =900 45. Cleavage in the direction of the shorter diagonal, highly perfect. M: e= 145~'29' e: e= 109 16. Commonly divergent, columnar or fibrous. Sometimes massive granular. Color and streak lead-gray; liable to tarnish. M M Luster shining. Brittle; but thin lamine, a little flexible. H=2. Gr=45- 4-62. Composition: antimony 73, sulphur 27. Fuses readily in the flame of a candle. On charcoal it is absorbed, giving off white fumes and a sulphur odor. Dif. Distinguished by its extreme fusibility and its vapo. rizing before the blowpipe. Obs. Gray antimony occurs in veins with ores of silver, lead, zinc, or iron, and is often associated with heavy spat How does antimony occur in nature? What are its blowpipe characters? What are the characters of native antimony? What is the crs stallization and appearance of gray antimony? What is its compsit'on? low is it distinguished? How does this ore occur? 26 ORES OF ANTIMONY. 223 or quartz. Its most celebrated localities are at Schemnitz, Kremnitz, and Felsobanya, in Hungary. It also occurs in the Hartz, Auvergne, Cornwall, Spain. In the United States, it has been found sparingly at Car. mel, Me., Lyme, N. H., and at " Soldier's Delight," Md. Uses. This ore affords nearly all the antimony of com. merce. SULPHURETS OF ANTIMONY AND LEAD. There are several sulphurets of antimony and lead, all of which fuse very easily, giving off white fumes, with a sulphur odor, and covering the charcoal with yellowish oxyd of lead. The color and streak are between lead-gray and dark steel-gray. Jamesonite. Occurs in right rhombic crystals, and also fibrous ox columnar. M: M —1010 20'. Streak and color steel-gray. H=22'5. Gr=555-5'8. Contains antimony 36 per cent., lead 44, and sulphur 20. From Cornwall, Siberia, and Hungary. Feather ore. In fine capillary crystallizations, like a cobweb, or plumose. Color dark lead-gray. Contains antimony 31, lead 50, sulphur 19. From the Eastern Hartz. Boulangerite. In plumose masses. Color bluish lead-gray. H= 2'5. Grt=5'97. Contains antimony 24l, lead58'0, sulphur 18. From Molicres in France; also from Lapland and Russia. Plagionite. In oblique rhombic crystals. M: M=120~ 49'. Color blackish lead-gray. Brittle. H=2-5. Gr=5'4. Contains antimony 38, lead 41, sulphur 21. From Wolfsberg in the Hartz. Zinkenite. In hexagonal prisms; also fibrous and massive. Coloi steel-gray. H=3 —35. Gr=-5'3. Contains antimony 44, lead 35, sulphur 22. From Wolfsberg in the Hartz. Geocronite, Kilbrzckenite. Massive, with an imperfect cleavage, and also granular. Color light gray. H=2 —25. Gr=6'4-6'6. Contains antimony 16'7, (which is sometimes partly replaced by arsenic,) lead 67, sulphur 16-5. From Gallicia, Kilbricken in Ireland, and Sala in Sweden. Kobellite. Radiated like gray antimony. Gr=6'3. Contains 33 per cent. of sulphuret of bismuth, along with 46 of sulphuret of lead, and 13 of suiphuret of antimony. From Hvena in Sweden. Steinmannite. In cubes with cubic cleavage, and massive. H=2'5. Gr-=683. Color lead-gray. Affords before the blowpipe fumes of sulphur and antimony, and a globule of lead containing silver. Besides these, there are alsoBerthierite, (called also haidingerite,) which resembles gray antimony, but contains 27 per cent. of sulphuret of iron with sulphuret of antimony. Another species contains 15 per cent. of sulphuret of iron. From Chazelles in Auvergne. Arsenical antimony. Granular, massive; color tin-white or reddishray. H= 2-4. Gr=6'2. Composition, antimony 36'4, arsenicu 3'6. From Allemont and Bohemia. Are there other ores of antimony? What is their general constitution' 224 31ET AT,. WHITE ANTIMONY. In white, grayish, or reddish rectangular crystals, with perfect cleavage, affording at rhombic prism of 1362 58'. Also in tabular masses, and columnar and granular. H = 25 —3. Gr=6 57. Luster adamantine to pearly. From Bohemia, Saxony, Hungary, Dauphiny. It is an oxyd of antimony containing 84'3 per cent. of antimony. The antimonic and antimonous acids have been observed in a white pulverulent form. Stiblite is the name of a compound of oxyd of antimony and an antimony acid, (an antimonate of antimony.) Red antimony is a compound of oxyd and sulphuret of antimony Occurs usually in tufts of capillary crystals, or in flakes. Color cherryred; streak brownish-red. Luster adamantine. H=1 —15. Gr=4-44-6. From Hungary, Dauphiny, Saxony, and the Hartz. Romeine is an antimonate of lime. It occurs in Piedmont in groups of minute square octahedral crystals, of a hyacinth or honey-yellow color. Scratches glass. Antinzonate of lead. A rare mineral consisting of antimonic acid 31-7, oxyd of lead 61-8, water 6-5. Amorphous, compact. Color yellow; also grayish, green, or black. Luster resinous. Gr=4.6 —4'76 From Nertschinsk, Russia. Senarmontite is tht same compound as white antimony in octahedrons. Gr=52 —5.3. From Algiers. GENERAL REMARKS ON ANTIMONY AND ITS ORES. The antimony of commerce is obtained from the sulphuret of antimony. This ore is worked at Schemnitz and Kremnitz in Lower Hungary, where it is associated with ores of silver, copper, lead, zinc, and manganese, and some gold. This region affords 6000 quintals of antimony annually. It has also been brought in considerable quantities from Borneo to Boston and then reduced. Several mines have been opened and abandoned in Auvergne and Dauphiny, but they are not now worked. There are also mines in France and Great Britain. To obtain the crude antimony of the shops, the ore is placed in crucibles having a hole at bottom, and these are inserted in other vessels: heat is applied above, and the ore melts from its gangue and flows into the vessel below, where it becomes solid. It is not altered in composition. It is reduced by carefully roasting the crude antimony in a reverberatory furnace, and thus obtaining a gray oxyd. This oxyd is then mixed with a tenth of its weight of crude tartar, placed in large melting pots, and heated in a wind furnace. The metal antimony (called regulus of antimony) is thus obtained pure, excepting generall) some little iron. By melting it again with one-fourth its weight of the oxyd of antimony, the impurities separate and form a slag above, leav ng the metal beneath. It is a silver-white, brittle metal, coarsely crys talline in texture. It fuses at about 800~ F. What ore affords the antimony of commerce? Where is it mosthl obtained? How is crude antimony obtained, and how reduced? ORES OF ARSENIC. 225 The sulphuret may be reduced also by heating it wi h iron filings; the iron takes the sulphur and liberates the antimcny. Antimony forms an important part of type metal. The proportions vary in different establishments; they have been stated at 1 of antimony to 4 to 12 of lead. A little tin is sometimes used, and also bismuth for the best type. The alloy is specially fitted for this purpose because it expands a little on cooling, filling well the mould and making a sharp, clear letter. The Britannia metal, which has superseded the use of pewter, consists of 100 parts of the best block tin, with 8 parts of the metal antimony, and either 2~ parts of each copper and brass, or parts of copper and bismuth. A soft solder is used in the manufacture of Britannia ware, consisting of fine tin alloyed with about 30 per cent. of lead. Antimony with tin, forms the metal on which music is engraved The glass of antimony, which is much used for making pharmaceutical preparations, is a mixture of the sulphuret and oxyd of antimony usually 85 of the latter to 15 of the former; it is formed by partially reducing the sulphuret to.an oxyd by roasting, and then raising the beat till the whole melts. Antimony in the condition of tartrate of antimony and potassa, is the tartar emetic of the apothecary. 12. ARSENIC. The metal arsenic occurs native, and united with oxygen or sulphur. It also occurs in combinations with various metals, as iron, cobalt, nickel, silver, copper, manganese, and antimony; also as an acid in combination with the oxyds of iron, cobalt, nickel, copper, lead, and with lime. Its ores are distinguished readily by giving off an odor like garlic when heated on charcoal before the blowpipe. Its compounds with the metals and bases have already been described. NATIVE ARSENIC. Rhombohedral. R: R=:85~ 41'. Cleavage basal, im. perfect. Also massive, columnar, or granular. Color and streak tin-white, but usually dark grayish from tarnish. Brittle. H-=35. Gr=- 5'65- 595. Volatilizes very readily before fusing, with the odor of garlic; also burns with a pale bluish flame when heated just below redness. Obs. Occurs with silver and lead ores. It is found in considerable quantities at the silver mines of Freiberg an How is crude antimony reduced? For what is antimony used What is Britannia metal? How does arsenic occur in the miners kingdom? How is it distinguished? Describe native arsenic. Wit what as it found? 226 METALS. Schneeberg; also in Bohemia. the Hartz, at Kapnik in Upper Hungary, in Siberia in large masses, and elsewhere. In the United States, it has been observed at Haverhill, N. H., in mica slate, and also at Jackson in the same state. The name arsenic is derived from the Greek arsenikon, or arrenikon, masculine, a term applied to orpiment, a sul. phuret of arsenic, on account of its potent properties. WHITE ARSENIC.-Arsenous Acid. In minute capillary crystals, and botryoidal or stalactitic. Color white. Soluble; taste astringent, sweetish. H-= 15 —Gr=3*7. Composition, arsenic 75-8, oxygen 24'2. This is the same compound with the common arsenic of the shops. It is found but sparingly native, accompanying ores of silver, lead and arsenic in the Hartz, Bohemia, and elsewhere. Uses. It is a well known poison. Pharmacolite, is an arsenate of lime, occurring in white or grayish crystals. H=2-25; Gr=2-6-2-8. Haidingerite. Haidingerite is another arsenate of lime. SULPHURETS OF ARSENIC. There are two sulphurets of arsenic. Orpiment or the yellow sulphuret of arsenic. In foliated masses, and sometimes in prismatic crystals, with a perfect diagonal cleavage. Color and streak fine yellow. Luster brilliant pearly, //" or metallic pearly on the face of cleav. / age. Subtransparent to translucent: sectile.! F H=-15-2. Gr3=834-3-5. Composition, VIM IM sulphur 39-0, arsenic 61 0. Wholly evaporates before the blowpipe with an alliaceous odor, and on charcoal burns with a blue flame. From Hungary, Koordistan in Turkey in Asia, China, and South America. Occurs at Edenville, N. Y., as a yellow powder, resulting from the decomposition of arsenical iron. Realgar, or Red sulphuret of arsenic. In oblique prisms, and also massive: cleavage much less perfect than in orpi. ment. Color fine clear red, aurora red to orange. Luster resinous. Transparent to translucent. H=-15 —2. Gr = What is white arsenic? What are the characters of orpiment wthat of realgar " 26* ORnE OF ARS:ENIC 227 8-35-3'65. Composition, sulphur 3(1, arsenic 70. Like the preceding before the blowpipe. From Hungary, Bohe. mia, Saxony, the Hartz, Switzerland, and Koordistan in Asiatic Turkey. It has been observed in the lavas of Vesuvius GENERAL REMARKS ON ARSENIC AND ITS ORES. Arsenic is most used in the state of arsenous acid, called also white arsenic. This substance is prepared principally at Joachimstahl in Bohemia, and in Hungary, and is obtained from arsenical cobalt and iron. These ores are roasted in reverberatory furnaces, (the cobalt ores for the cobalt they contain,) and the vapors (which are white arsenic) are condensed in a long horizontal chimney; after undergoing a second sublimation, usually with a little potash, it is ready for commerce. The manufacture is very destructive to life, and those engaged in it seldom live over 30 or 35 years. White arsenic, besides its use as a poison, is employed as a flux for glass, and also to give a peculiar milky or porcelain-like hue to glass ware. When too much is added, the glass becomes unsafe for domestic use. The sulphurets afford valuable pigments. Orpiment is the basis of the pigment called king's yellow. The ammoniacal solution of orpiment is recommended for dyeing. It affords a yellow which is permanent, but is injured by soap. Realgar is used in the preparation of the pyrotechnical compound called white Indian fire, which consists of 24 parts of saltpeter, 7 of sulphur, and 2 of realgar, finely powdered and well mixed. It burns with a white flame and great brilliancy. The sulphurets are obtained for commerce by distilling arsenical pyrites and iron pyrites, (sulphuret of iron,) or from white arsenic and rough brimstone; the product is realgar or orpiment according to the proportions employed. A combination of the arsenous acid with oxyd of copper, obtained by mixing arsenite of potash and sulphate of copper, produces a fine green pigment called Scheele's green. Arsenic is mixed in a small quantity (less than 1 per cent.) with lead, in the manufacture of shot, as it renders the metal more ready to break up into minute drops when caused to fall through a sieve from a height, as in the shot tower, and the grains assume a more spherical forn on the descent, besides being less malleable than if of pure lead. In shot towers, the melted lead falls usually about 150 feet into a vessel of water at the bottom of the tower. They are afterwards sifted in sieves of different degrees of fineness, from No. 1, the finest, to No. 12, and thus the several sizes of shot are separated and assorted. There are still some imperfect shot among them; and to separate them the shot are made by a shake to roll from trays a little inclined into a bin; those that are imperfect roll sluggishly and are behind in the movement, and art thus separated to be melted over again. How do orpiment and realgar differ in composition? From what ores arsei ic obtained? How is white arsenic prepared? For what is Laenic used? How are shot made! 228 META LS. 13. URANIUM. The uranium ores have a specific gravity not above 7, and a hardness below 6. The ores are either of some shade of light green or yellow, or they are dark brown or black and dull, or submetallic without a metallic luster when powdered They are not reduced when heated with carbonate oif soda; and the brown or black species fuse with difficulty on the tdges or not at all. PITCHBLENDE.-Oxyd of Uranium. Massive and botryoidal. Color grayish, brownish, or vel vet-black. Luster submetallic or dull. Streak powder black. Opaque. H=5'5. Gr=6 47. Composition: 79 to 87 per cent. of protoxyd of uranium with silica, lead, iron, and some other impurities. Infusible alone before the blowpipe, but forms a gray scoria with borax. Dissolves slowly in nitric acid, when powdered. Ohs. Occurs in veins with ores of lead and silver in Saxony, Bohemia and Hungary; also in the tin mines of Cornwall, near Redruth. In the United States, at Middle own and Had;lam, Conn. Uranic ochre is a light yellow pulverulent mineral, becoming orange yellow when gently heated. It is believed to be peroxyd of uranium, sometimes combined with carbonic acid. Accompanies pitchblende in Cornwall and in Bohemia. It occurs sparingly in a yellow powder with columbite and uranite at the feldspar quarry, near Middletown, Conln. Uses. The oxyds of uranium are used in painting upon porcelain, yielding a fine orange in the enameling fire, and a black color in that in which the porcelain is baked. Coractte (Le Conte). An ore resembling pitchblende, and probably that species. From the north shore of Lake Superior, in a vein 2 inches wide, near the junction of trap and syenite. Eliasite. A similar ore, containing 10- per cent. of water. URANITE. Dimetric. In short square prisms, thinly foliated parallel What is said of the ores of uranium? Describe pitchblende. What is its composition? What are the uses of the oxyds? IRON ORES. 229 to the base, almost like mica; laminae brittle and not flexible. Color bright clear yellow and green; streak a little paler. Luster of laminae pearly. Transparent to subtranslucent. 11i 2 2-5. Gr'==3 -36. Composition. There are two ores here included. the yel. Iow one containing phosphoric acid 16, oxyd of uranium 63, and lime 6, with watei 15; the other of a green color, (sometimes called chalcolite,) containing oxyd of copper in place of lime. They fuse before the blowpipe to a blackish mass, and the green variety colors the flame green. Dtf. The micaceous structure connected with the light color is a striking character. The folia of mica are not brittle like those of uranite. Obs. Occurs with uranium, silver and tin ores. It is found at St. Symphorien, near Autun, and also near Limoges, and in the Saxon and Bohemian mines. Cornwall affords splendid crystallizations of the green variety. Found sparingly at Middletown, Conn., and Chesterfield, Mass., of a yellow color. Samarskite (formerly named uranotantalite and yttro-ilmenite) is a compound of oxyd of uranium with columbic and tungstic acids, from Miask in the Ural It is of a dark brown color and submetallic luster. H=5'5. Gr=5'4- 57. Also occurs in North Carolina. Johannite or uranvitriol is a sulphate of uranium. It has a fine emerald-green color, and a bitter taste. From Bohemia. 14. IRON. Iron occurs native or alloyed with nickel in meteoric iron. Its most abundant ores are the oxyds and sulphurcns. It is also found combined with other metals, and with silica and carbonic and other acids. Its ores are widely disseininated. They are the ordinary coloring ingredients of soils and many rocks, tinging them red, yellow, dull green, brown and black. The ores have a specific gravity below 8, and the ordinary workable ores seldom exceed 5. Many of them are in. tusible before the blowpipe, and a great part become attractable by the magnet after heating, when not so before. When undisguised by other metals, they afford with borax, in the What is the color and structure of uranite? its composition? How is it distinguished from other species? What is said of the modes of occurence of iron? What characters of its ores are mentioned? 0() 280 METALS. inner flame, a bottle-green glass. By their difficult fusi bility. the species with a metallic luster are distinguished from ores of silver and copper, and also more decidedly from these and other ores by blowpipe reaction and reduction. NATIVE IRON. Monometric. In regular octahedrons; cleavage parallel to the faces of the octahedron. Usually massive, with a more or less fine granular structure. Color and streak iron-gray. Fracture hackly. Malleable and ductile. H-=45. Gr=-73 —78. Acts strongly on the magnet. Obs. Native iron, as it occurs in meteorites, is usually alloyed with nickel and other metals. Whether terrestrial native iron has been observed, is a question of some doubt. A mass fiom Canaan, Conn., reported as of this character, has been shown by Dr. A. A. Hayes to be artificial, beyond doubt. Steinbach and Eibenstock in Saxony, and the mine of Hackenberg have been mentioned as foreign localities. Another occurs in Western Africa. Meteoric iron occurs in nearly all meteorites, and almost wholly constitutes a large part of those that have been discovered.. A mass weighing 1635 pounds is now in the cabinet of Yale College; it came from Texas. It contains 90 to 92 per cent. of iron, and 8 to 10 per cent. of nickel, the alloy not being uniform throughout. Meteoric iron often has a very broad crystalline structure, long lines and triangular figures being developed by putting nitric acid on a polished surface. The coarseness of this structure differs in different meteorites, and serves to distinguish specimens not identical in origin. The Texas iron is remarkable for the large size of the crystallization. The most remarkable masses of meteoric iron occur in the district of Chaco-Gualamba in South America, where there is one whose weight is estimated at 30,000 pounds. The large Pallas meteorite weighed originally 1600 pounds; it contains imbedded crystals of chrysolite. Besides nickel, which sometimes amounts nearly to 20 per cent., meteoric iron often contains a small per centage of What is the crystallization of iron? its hardness, gravity, and other character? How does it occur native? What is said of meteoric iron? IRON ORES. 231 cobalt, tin, copper and manganese; and frequently nodules of magnetic iron pyrites are imbedded in the mass Chlorine has been detected in some specimens by Dr. C. T. Jackson. Of still greater interest is the occurrence of a phosphuret of nickel (called Schreibersite) in most iron meteorites. It is in steel-gray masses, grains or folia, imbedded in the iron, and consists, according to Dr. J. L. Smith, of phosphorus 13-9, iron 57-2, nickel 25 8, cobalt 0-3, copper a trace, silica 1-6, alumina 1-6, lime a trace, chlorine 0'1. Its special in. terest arises from the fact that no phosphuret occurs among terrestrial minerals, and could not occur in any planet where oxygen is an abundant constituent, as on the earth. This mineral therefore, as stated by Dr. Smith, confirms the tes. timony from the native iron, that these meteoric bodies in space are in general without an atmosphere like ours, although not wholly destitute of oxygen, since there are several siliceous minerals present in many of them, as chrysolite, augite, feldspar, &c. Mteoric iron is pertectly malleable, and may be worked like manufactured iron. The nickel diminishes much its tendency to rust. IRON PYRITES.-Bisulphuret of Iron. Monometric. Usually in cubes (fig. 1) simple or modifi. 1 2 3 4 ed, (2, 4,) or in pentagonal dodecahedrons (3); also in octa. hedrons. Faces of cubes often striated as in figure 1. Oc. curs also in imitative shapes, and massive. Color bronze-yellow; streak brownish-black. Luster of crystals often splendent metallic. Brittle. H-=6 —65. Gr=-48-5-1. Strikes fire with steel. Composition: iron 46'7, sulphur 53'3. Before the blow. pipe gives off sulphur, and ultimately affords a globule at. tractable by the magnet. What is the crystallization of iron pyrites? its color and other char, acters? its composition 232 ME TALS. Pyrites sometimes contains a minute quantity of gold, and is then called auriferous pyrites. Dif Distinguished from copper pyrites in being too hard to be cut by a knife, and also in its paler color. The ores of silver, at all approaching pyrites, instead of having its pale bronze-yellow color, are steel-gray or nearly black; and besides, they are easily cut with a knife and quite fusible. Gold is sectile and malleable; and besides, it does not give off a sulphur odor before the blowpipe, like pyrites. Obs. Iron pyrites is one of the most common ores on the globe. It occurs in rocks of all ages. Cornwall, Elba, Piedmont, Sweden, Brazil, and Peru, have afforded magnificent crystals. Alston Moor, Derbyshire, Kongsberg in Norway, are well known localities. It has also been observed in the Vesuvian lavas. In the United States, the localities are numerous. Fine crystals have been met with at Rossie, N. Y.; also in New York state at Scoharie, at Johnsburg and Chester, Warren county; at Champion and near Oxbow, in Jefferson county; at Warwick and Deerpark, Orange county. In Vermont, crystals occur at Shoreham; in Massachusetts, at Heath, Barre, and Boxborough; in Maine, at Corinna, Peru, Waterville and Farmington; in Connecticut, at Monroe, Orange, Milford and Stafford; in Pennsylvania, at Little Britain, Lancaster county. Massive pyrites occurs in Connecticut at Colchester, Ashford, Tolland, Stafford, and Union; in Massachusetts, at Hawley and Hubbardston; in Maine, at Bing. ham, Brooksville, and Jewell's Island; in New Hampshire, at Unity; in Vermont, at Strafford, where there is a vein in mica slate four rods wide, and also abundantly at Woodbury, and other places; in New York, in Franklin, Putnam and Orange counties, and elsewhere; in Maryland, abundant and worked at Cape Sable. Uses. This species is of the highest importance in the arts, although not affording good iron on account of the diffi. culty of separating entirely the sulphur. It affords the greater part of the sulphate of iron (green vitriol or copperas) and sulphuric acid (oil of vitriol) of commerce, and also a considerable portion of the sulphur and alum. The py. How is iron pyrites distinguished from copper pyrites? from silver ores? from gold? What is said of the occurrence of pyrites? Why docs not this ore afford good iron? What are its uses? How is vitrioi obtained from it? IRON ORES. 233 rites is sometimes heated in clay retorts, by which about 1i per cent. of sulphur is distilled over and collected. The ore it then thrown out into heaps, exposed to the atmosphere, when a change ensues, by which the remaining sulphur and iron become sulphuric acid and oxyd of iron, and form sulphate of iron or copperas.* The material is lixivated, and partially evaporated, preparatory to its being run off into vats or troughs to crystallize. In other instances, the ore is coarsely broken up and piled in heaps and moistened. Fuel is sometimes used to commence the process, which after wards the heat generated continues. Decomposition takes place as betore, with the same result. At Strafford, Ver. mont, about 1000 tons of copperas have been produced an. nualiy, valued at 2 cents a pound, or $40,000. The quanti. ty manufactured might easily be much increased. The pyrites of Cape Sable, Maryland, also affords large quantities of copperas. The lixivated liquid is often employed in Ger. many for the production of sulphuric acid; at a red heat, the acid passes off, leaving behind a red oxyd of iron, which is called colcothar. Cabinet specimens of pyrites, especially granular or amorphous masses, often undergo a spontaneous change to coppe ras, particularly when the atmosphere is moist. The name pyrites is from the Greek pur, fire, because, as Pliny staites,'" there was much fire in it," alluding to its strik. ing tire with steel. Thi.3ore is the mundic of miners. White iron pyrites. This ore has the same composition as common iron pyrites, but crystallizes in secondaries to a right rhombic prism; M -M=106~ 36'. The color is a little paler than that of common pyrites, and it is more liable to decorposition; hardness the same; specific gravity 4'6 —-485. Radiated pyrites, hepatic pyrites, cockscomb pyrites, (alluding to its created shapes,) and spear pyrites are names of some of its varieties. It occurs in crystals at Warwick and Phillipstown, N. Y. Massive varieties are nlet with at Cummington, Mass.; Monroe, Trumbull, and East Haddam, Conn.; and at Haverhill, N. H. PYRRHOTINE.-MAGNETIC PYRITES -Sulphuret of Iron. Hexagonal. Occurs occasionally in hexagonal prisms, which are often tabular; generally massive. Color between bronze-yellow and copper-red; streak dark How is sulphuric acid obtaine? and what is colcothar? What is the origin of the name pyrites? What is the crystallization and appear ance of magnetic pyrites? * This change consists in the union of oxygen with the sulphur an hion 234 METALS. grayish-black. Bri tle. H=-3 —4-5. Gr =4*4 —465 Slightly attracted by the magnet. Liable to speedy tarnish Composition: sulphur 39-5 iron 60t5. Before the blow. pipe on charcoal in the outer flame it is converted into a glo. bule of red oxyd of iron. In the inner flame it fuses ano glows, and affords a black globule which is magnetic, and has a yellowish color on a surface of fracture. Dif. Its inferior hardness and shade of color, and its magnetic quality distinguish it from common iron pyrites; and its paleness of color fiom copper pyrites. It differs from the cobalt and nickel ores in affording a magnetic globule before the blowpipe, Obs. Crystallized specimens have been found at Kongs. berg in Norway, and at Andreasberg in the Hartz. The massive variety is found in Cornwall, Saxony, Siberia, and the Hartz; also at Vesuvius and in meteoric stones. In the Ulhited States, it is met with at Trumbull and Mon. roe, New Fairfield, and Litchfield, Conn.; at Strafford and Shrewsbury, Vt.; at Corinth, New Hampshire; and in many parts of Massachusetts and New York. This ore at Litchfield is quite abundant. Uses. Same as for common pyrites. MISPICKEL.-Arsenical Iron Pyrites. Trimetric. In rhombic prisms, with cleavage parallel to jthe faces M; M: M=111 40' to 112~. Crystals.\ isometimes elongated horizontally, producing a, irhombic prism ot 1000 nearly, with M and M the | M end planes. Occurs also massive. Color silver-white; streak dark grayish-black. Luster shining. Brittle. H=5'.5-6. Gr=6'3. Composition: iron 34-4, arsenic 46-0, sulphur 19'6. A cobaltic variety contains 4 to 9 per cent. of cobalt in place of part of the iron. The Danaite of New Hampshire, consists of iron 32-9, arsenic 41'4, sulphur 17'8, cobalt 6'5. Affords arsenical fumes before the blowpipe, and a globule of sulphuret of iron which is attracted by the magnet. It gives fire with a steel and emits a garlic odor. Dif. Resembles arsenical cobalt; but is much harder, What is the constitution of magnetic pyrites? How is it distinguished from common iron pyrites? how from copper pyrites? from cobalt ld nickel ores. For what is it used? What is the form and appearance of mispickel? TRON o1rs. 235 it giving fire with steel; it differs also in yielding a mag netic globule before the blowpipe and in not affording the reaction of cobalt with the fluxes. Obs. Mispickel is found mostly in primitive regions, and is commonly associated with ores of silver, lead, iron, or copper. It is abundant at Freiberg, Munzig, and elsewhere in Europe, and also in Cornwall, England. It occurs in crystals in New Hampshire, at Franconia, Jackson, and Haverhill; in Maine, at Blue Hill, Corinn Newfield, and Thomaston; in Vermont, at Waterbury; i Massachusetts, massive at Worcester and Sterling; in Con necticut, at Chatham, Derby, and Monroe; in New Jersey, at Franklin; in New York, in Lewis, Essex county, and near Edenville and elsewhere in Orange county; in Kent, Putnam county. Leucopyrite. This is the name of an arsenical iron, containining no sulphur, or but few per cent. It resembles the preceding in color and in its crystals; M: M=1220 26'. It has less hardness and higher specific gravity. H=5 —55. Gr=7'2-7'4. Contains iron 32-4, arsenic 65'9, with some sulphur. From Styria, Silesia, and Carinthia. A crystal weighing two or three ounces has been found in Bedford county, Penn.; and in Randolph county, N. C., a mass was found weighing two pounds. MAGNETITE.-Octahedral Iron Ore. Monometric. Often in octahedrons and dodecahedrons, Cleavage octahedral; sometimes distinct. Also granularly mas- /-~a,,sive Color iron-black. Streak black. Brittle. H 55-5 6-5. Gr- 5'0 —51. Strongly attracted by the magnet, and sometimes having polarity. Composition: peroxyd of iron 69, protoxyd of iron 31; or iron 72'4, oxygen 27'6. Infusible before the blowpipe. Yields a bottle-green glass when fused with borax in the nner flame. Dif. The black streak and magnetic properties distinuish this species from the following. What are the constituents of mispickel? What is the effect before he blowpipe? How does it differ from arsenical cobalt? What is he crystallization of magnetic iron? its other physical characters? ts omposition? What is the action of magnetic iron before the blowpipe I low is it distinguished from specular iron? 236 METALS. Obs. Magnetic iron ore occurs in extensive beds, and also in disseminated crystals. It is met with in granite, gneiss, mica slate, clay slate, syenite, hornblende, and chiu. rite slate; and also sometimes in limestone. The beds at Arendal, and nearly all the Swedish iron ore, consist of massive magnetic iron. At Dannemora and the Taberg in Southern Sweden, and also in Lapland at Kurun. avara and Gelivara, there are mountains composed of it. In the United States, extensive beds occur in Warren, Essex, and Clinton counties, N. Y.; also in Orange, Putnam. Saratoga, and Herkimer counties; at Mount Desert and Marshall's Island, Maine; in Somerset, Vermont; in Bernardstown and Hawley, Massachusetts; at Franconia. Lisbon, and Winchester, New Hampshire. The mountainous districts of New Jersey and Pennsylvania afford this ore, and also the eastern side of Willis mountain in Buckingham county, Virginia. Crystals occur in New Hampshire, at Franconia in epidote; also at Swanzey, (near Keene,) Unity, and Jackson; in Vermont, at Marlboro', Bridgewater and Troy, in chlorite slate; in Connecticut, at Haddam; in Maine, at Raymond, Davis's Hill, in an epidotic rock; in New York, at Warwick, Orange county, and also at O'Neil mine; in New Jersey, at Harnburgh, near the Franklin furnace; in Maryland, at Deer Creek; in Pennsylvania, at Morgantown, Berks county; also in the south part of Chester county. Masses of this ore in a state of magnetic polarity, constitute what is called lodestone or native magnets. They are met with in many beds of the ore. Siberia and the Hartz have afforded fine specimens; also the island of Elba. They also occur at Marshall's Island, Maine; also near Providence, Rhode Island. The lodestone is called magnes by Pliny, irom the name of the country, Magnesia, (a province of ancient Lydia,) where it was found; and it hence gave the terms magnet and magnetism to science. Uses. No ore of iron is more generally diffused than the magnetic ore, and none is superior for the manufacture of iron. The ore after pounding may be separated from im purities by means of a magnet; and machines are in use in northern New York and elsewhere, for cleaning the ore on a large scale for furnaces. How does magnetic iron occur? What are its uses? What is said of lodestone? 19 IRON ORES. 237 SPECULAR IRON ORE.-HEMATITE. Rhombohedral. In complex modifications of a rhombche. dron of 85 58'; crystals occasionally thin tabular. Cleavage usually indistinct. Often massive granular; sometimes Jamellar or micaceous. Also pulverulent and earthy. Color dark steel-gray or iron-black, and often when crystallized having a highly splendent luster; streak-powder cherry-red or reddish-brown. The metallic varieties pass into an earthy ore of a red color, having none of the external characters of the crystals, but perfectly corresponding to them when they are pulverized, the powder they yield being of a deep red color, and earthy or without luster. Gr=4.55*3. Hardness of crystals 5-5 —65. Sometimes slightly attracted by the magnet. Varieties and Composition. Specular iron. Specimens having a perfectly metallic luster. Mficaceous iron. Specular iron, with a foliated structure. Red hematite. Submetallic, or unmetallic, and of a brown. ish-red color. Red ocher. Soft and earthy, and often containing clay. Red chalk. More firm and compact than red ocher, and of a fine texture. Jaspery clay iron. A hard impure ore, containing clay, and having a brownish-red jaspery look and compactness. Clay iron stone. The same as the last, the color and ap. pearance less like jasper. This is one variety of what is called " clay iron stone." Much of it belongs to the following species, and a large part also is spathic iron, as is the case with that of the Eng-'ish coal measures. Lenticular argillaceouis ore. A red ore, consisting of small flattened grains, something like an oolite. Oligiste iron, iron glance, and rhombohedral iron ore, are other names of the species specular iron. What is the crystallization of specular iron? What are its physical characters Describe the varieties. 238 METALS. Composition of the pure ore: iron 70, and oxygen 30. The varieties without a perfect metallic luster often contain more or less clay or sand. Before the blowpipe alone infusible; with borax in the inner flame gives a green glass, and a yellow glass in the outer flame. Dif. This ore is distinguished from magnetic iron ore by its red powder; and from any silver or copper ores by its hardness and infusibility. The word hematite, from the Greek haima, blood, alludes to the color of the powder. Obs. This ore occurs in both crystalline and stratified rocks, and is of all ages. The more extensive beds of pure ore abound in the primary rocks; while the argillaceous varieties occur in stratified rocks, being often abundant in coal regions and other strata. Crystallized specimens occur also in some lavas. Splendid crystallizations of this ore come from Elba, whose beds were known to the Romans; also from St. Gothard; Arendal, Norway; Langbanshyttan, Sweden; Lorraine and Dauphiny. Etna and Vesuvius afford handsome specimens. In the United States, this is an abundant ore. The two iron mountains of Missouri, situated u0 miles south of St. Louis, consist mainly of this ore, piled "in masses of all sizes from a pigeon s egg to a middle size church." One of them is 300 feet high, and the other, the Pilot knob," is 700 feet. Both the massive and micaceous varieties occur there together with red ochreous ore. Large beds of specular iron have been explored in St. Lawrence and Jefferson counties, N. Y.; Plymouth, Bartlett and elsewhere in New Hampshire; Woodstock and Aroostock. Maine, and Liberty, Maryland, are other localities; also the Blue Ridge, in the western part of Orange county, Va. The nicaceous variety occurs at Hawley, Mass., Piermont, N. H., and in Stafford county, Va. Lenticular argillaceous ore is abundant in Oneida, Herkimer, Madison, and Wayne counties, N. Y., constituting one or two beds 12 to 20 inches thick in a compact sandstone; it contains 50 per cent. of oxvd of iron. with about 25 of carbonate of lime, and more or less magnesia and clay. The coal region of Pennsylvania affords abundantly the clay iron ores, but they are mostly the argillaceous carbo nate of iron or limonite. What is the composition of specular iron? What are its distinguish mg characters? What is its mode of occurrence? What is said o the iron mountains of Missouri? IRON ORES. 39 Uses. Valuable as an iron ore, though less easily wolked when pure and metallic than the magnetic and hematitic ores. Pulverized red hematite is used for polishing metals. Red chalk is a well known material for red pencils. LIMONITE.-BROWN IRON Onl. Usually massive, and often with a smooth botryoidal or stalactitic surface, having a compact fibrous structure within Also earthy. Color dark brown to ocher-yellow; streak yellowish brown to dull yellow. Luster sometimes submetallic; oftet dull and earthy; on a sitface of fracture frequently silky H==5-5-5. Gr-=3-6- 4. Varieties and Composition. The following are the -princi. pal varieties: Brown hematite. The botryoidal, stalactitic and associated compact ore. Brown ocher, Yellow ocher Earthy ochreous varieties, of a brown or yellow color..Brown and yellow clay iron stone. Impure ore, hard and compact, of a brown or yellow color. Bog iron ore. A loose earthy ore of a brownish-black color, occurring in low grounds. Composition when pure: peroxyd of iron 85'6, (sevent-enths of which is pure iron,) and water 14'4; or it is a hydrous peroxyd of iron, containing when pure about two-thirds its weight of pure iron. Before the blowpipe, blackens and be. comes magnetic. Gives with borax in the inner flame a green glass. Dif. This is a much softer ore than either of the two pre ceding, and is peculiar in its fiequent stalactitic forms, and in its affording water when heated in a glass tube. Obs. Occurs connected with rocks of all ages, but ap. pears, as shown by the stalactitic and other forms, to have resulted in all cases from the decomposition of other iron ores, probably the sulphuret. This is an abundant ore in the United States. The following are a few of its localities. Extensive beds exist a Salisbury and Kent, Conn., in mica slate; also in the neigh What is said of the uses of specular iron? What is the appearance ot brown iron ore? its composition? Describe its varie ies. Wha are distinguis.hing characters? i loy does this ore occur? 240 MrTALS. boring towns of Beekman, Fishkill, Dover, and Amen a, N. Y.; also in a similar situation north, at Richmond and Lenox, Mass.; also at Bennington, Monkton, Pittsford, Putney, and Ripton, Vermont. Large beds are found in Pennsylvania, the Carolinas, near the Missouri iron mountains, and also iv Tennessee, Iowa and Wisconsin. Uses. This is one of the most valuable ores of iron. Il s also pulverised and used for polishing metallic buttons and other articles. As yellow ocher, it is a common materia, for paint. Gothitc, Lepzdokrokite. These are names given to crystals of a hy drous peroxyd of iron, differing in composition from brown iron ore by containing half as much water. The crystals are of a brown color, and blood-red by transmitted light when subtransparent. Streak brownishyellow to ocher-yellow. H=5. Gr=40 —4'2. Occurs with hematite at Eiserfeld in Nassau; at Clifton in Cornwall; in Siberia and elsewhere. FRANKLINITE. Monometric. In octahedral and dodecahedral crystals, and also coarse granular massive. Color ironblack; streak dark reddish-brown. Brittle. H= —-55-6-5. Gr=4-85 —51; acts slightly A Aq on the magnet.A A Composition: peroxyd of iron 66, sesquoxyd of manganese 16, oxyd of zinc' 17. Alone infusible. At a high temperature zinc is driven off, and is deposited on the charcoal; with borax on a platinum wire, in the outer flame, it gives the violet color due to manganese; and in the inner flame on charcoal, the green color due to iron. Dif. Resembles magnetic iron, but the exterior color is a more decided black. The streak is not black, and the blowpipe reactions are different. Obs. This is an abundant ore at Sterling and Hamburgh, in New Jersey, near the Franklin furnace; at the former place, the crystals are sometimes 4 inches in diameter. It is said to occur also in the mines of Altenberg, near Aix-la. Chapelle. Uses. The attempts to work this ore for zinc have not seen successful. What is said of the uses of brown iron ore 1 What is the appear. nce offranklinite? What is its composition? How is it distinguishd from magnetic iron ore t 19* IRON ORES. 241 ILMENITE.- Titanic iron. In crystallization near specular iron. R: R=85~ 59' Often in thin plates or seams in quartz; also in grains. Crystals sometimes very large and tabular. Color iron-black; streak metallic. Luster metallic oy submetallic. H=5-6. Gr=4'5 —5; acts slightly on the magnetic needle. Composition: oxyd of iron, with a variable proportion of titanic acid or oxyd of titanium. Infusible alone before the blowpipe. Crichtonite, ilmenite, menaccanite, hystatite, and iserine, alr names of some of the varieties of this species. The hystatite variety includes the washingtonite of Professor Shepard. Octahedral and cubic crystals of this mineral have been found with titaniferous sand, which are supposed to be pseudonorphous. Dif. Near specular iron, but differs in the less luster of its crystals, and its metallic streak. Obs. Crystals an inch or so in diameter occur in Warwick, Amity, and Monroe, Orange county, N. Y.; also near Edenville and Greenwood furnace; also at South Royalston and Goshen, Mass.; at Washington, South Britain, and Litchfied, Conn.; at Westerly, Rhode Island. Uses. Of no value in the arts. CHROMIC IRoN.-Chromate of Iron. Monometric. In octahedral crystals, without distinct clea. vage. Usually massive, and breaking with a rough unpolished surface. Color iron-black and brownish-black; streak dark brown. Luster submetallic; often faint. H1=5-5. Gr= 43-4-5. In small fragments attractable by the magnet. Composition: green oxyd of chromium 60*0, protoxyd of iron 20-1, alumina 11-8, magnesia 7*5. The alumina and magnesia are variable. Infusible alone before the blowpipe. Fuses slowly with borax to a beautiful green globule. Dif. The little luster of this ore on a surface of fracture is peculiar; also its fine green glass with borax. which distinguishes it from ores of iron and other metals. Describe titanic iron. Of what does it consist? How does it diffel rom specular iron t What is the appearance of chromic iron? its corn position! How is it distinguished from other ores: 242 MTK''ALS. Obs. Occurs usually in serpentine rocks, in imbedded masses or veins. Some of the foreign localities are the Gulsen mountains in Styria; the Shetland Islands; the de. partment of Var in France; Silesia, Bohemia, etc. In the United States, it is abundant in Maryland in the Bare Hills near Baltimore, and also in Montgomery county at Cooptown in Harford county, and in the north part ot Cecil county; occurs also in Townsend and Westfield, Ver mont, and at Chester and Blandford, Mass. It is also foun at Htoboken, N. Y., and at Milford and West Haven, Conn. in Pennsylvania in Little Britain, Lancaster county, an( vest Branford, Chester county, and on the Wisahicon, 11 miles from Philadelphia. Uses. The compounds of chrome are extensively used as pigments. These compounds are obtained either from chromic iron or the native chromate of lead, (see under lead.) The chromate of lead and copper (vauquelinite) is too rare to be employed for this purpose. The chromate of potash is readily formed by mixing equal parts of nitre and the powdered chromic iron and exposing the mixture in a crucible to a strong heat for some hours. The soluble part is then washed out, and the process is repeated with the insoluble portion (digesting it tirst in muriatic acid to remove the free oxyd of iron and alumina) till all the ore is decomposed. The colored liquid obtained from the washings is carefully saturated with nitric acid, and concentrated by evaporation till crystals of nitre cease to be deposited. Being then set aside for a week or two, it gradually deposits abundant crystals of the yellow chromate of potash. Chromate of lead, called also chrome yellow, is the most common chrome paint used. It is made by adding to the liquid obtained as above stated, before its crystallization, a solution of acetate of lead (sugar of lead) till it is saturated. The yellow precipitate washed out and dried, is the chrome yellow of commerce. It is used as a yellow pigment both in oil and water colors, calico printing, dyeing, and porcelain painting. This material is largely manufactured at Baltimore, Md. The native nitrate of soda of Peru, has been suggested as a sub. stitute for nitre in the above process. Another mode of this manufacture recently proposed..on. Where does chromic iron occur? What are its uses? How is tl ore treated? What is chrome yellow, and how is it made 7 ITox ORES. 243 sists in making a chromate of lime from the chrumic iron. It is as follows: 1. Pulverize very finely chalk and chromic iron, and mix the sifted material well by means of a revolv. ing barrel. 2. Calcine for nine or ten hours at a bright red heat in a reverberatory furnace, when, if complete, the whole has a yellowish-green color, and dissolves entirely in muriatic acid. 3. The porous mass after being crushed under a mill, to be mixed with hot water and kept agitated, adding a little sulphuric acid till it slightly reddens blue litmus paper. 4. Triturated chalk should then be added, and the oxyd of iron is thus removed. 5. After being left quiet for a while, the clear supernatant liquid is to be drawn off: it contains bichromate, with a little sulphate of lime. The chromate of potash may then be made from it by adding carbonate of potash; the chromate of lead, by adding acetate of lead; chromate of zinc, by adding chlorid of zinc. The bichromate of potash has a fine red color, and is much used by calico printers. It is made fiom the. chromate by adding nitric or acetic acid to its solution, (enough to give it a sour taste,) and setting it aside to crystallize. The green oxyd of chromium gives the fine green color to glass of borax in blowpipe experiments with chromic iron; and it is used to produce this tint in porcelain and enamel painting, It is the coloring ingredient of the emerald, and the emerald. colored chrysoberyl of the Urals; and occurs in some varieties of diallage and serpentine. It has been found native. Chromic acid is said to be the coloring matter of the red sapphire or ruby. With oxyd of tin, it affords a pink color, ~which is used in porcelain painting. COLU MBITE. Trimetric. In rectangular prisms, more or less modified.- 5 Also massive. Disseminated in the gangue Cleavage parallel to the lateral faces of the prism, somewhat distinct. Color iron-black, brownish-black; often with a characteristic iridescence on a surface of fiacture; streak dark brown, slightly red. dish. Luster submetallic, shining. Opaque. Describe another mode of treating chromic iron? What is the coloring ingredient of the emerald? what of the red sapphire? What are the color, luster and form of columbite 1 244 METALS. Brittle. H-=5-6. Gr=5'3 —64. American 5'3-5-71. Bavarian 5'7 -64. Composition of an American specimen. columbic acid 79i6, protoxyd of iron 16'4, protoxyd of manganese 4'4, oxyd of tin 0'5, oxyds of copper and lead 0'1. The Bavarian columbite, besides having a higher specific gravity than the American, has also a black streak. Damour has proposed for it the name Baierine; but the differences, as far as yet known, are not important. Infusible alone before the blowpipe. With borax in a fine pow(der fuses quite slowly, but perfectly, to a dark green glass, which indicates only the presence of iron. Dif. Its dark color, submetallic luster, and a slight iridescence, together with its breaking readily into angular fragments, will generally distinguish this species from the ores it resembles. Obs. Occurs in granite at Bodenmais in Bavaria, and also in Bohemia. In the United States, it is found in the same rocks, feldspathic or albitic, at Middletown and Haddam, Conn.; at Chesterfield and Beverly, Mass., and at Acworth, N. H. A crystal was found at Middletown, which originally weighed 14 pounds avoirdupois; and a part of it, 6 inches in length and breadth, weighing 6 lbs. 12 oz., is now in the collections of the Wesleyan University of that place. This mineral was first made known from American speci. mens, by Mr. Hatchett, an English chemist, and the new metal it was found to contain was named by him columbium. Tantalite or Ferrotantalite. This is an allied mineral, often called, from its locality at Kimito in Finland, kimito-tantalite. It is a neutral tantalate of iron. H=5-6.' Gr=7-2-8-0. A variety from Broddbo contains 8 per cent. of oxyd of tin, with 6 of tungstic acid. Sp. gr. -=6-5. Note.-The metal named Columbium by Hatchett, is the same that has since been called Niobium; and the Tantalum of the Swedish ores is a different metal. For other ores of columbium and tantalum, see pages 208, 209. WOLFRAM. —— Tungstate of Iron and Manganese. Trimetric. In modified rhombic or rectangular prisms; sometimes pseudomorphous in octahedrons imitative of tung. state of lime. Also massive. Color dark grayish-black; Of what does columbite consist? How does it differ from other ores? Describe wolfram. IRON ORES. 245 streak dark reddish brown. Luster submetallic, shining, ot dull. H=5-5'5. Gr —71 —7-9. Composition: Ilungstic acid 75*89, protoxyd of iron 19*24, protoxyd of manganese 4 97. Fuses with difficulty. Gives a green bead with borax, and a deep red globule with salt of phosphorus. Found often with tin ores. Occurs in Cornwall, and a Zinnwald and elsewhere in Europe. In the United States it is found at Monroe and Trumbull, Conn.; on Camdag farm near Blue Hill, Me.; near Mine la Motte, Missouri in the gold regions of North Carolina. / SILICATES OF IRON. There are several compounds of silica and oxyd of iron, none of which are of special interest in an economical point of view. Hedenbergite is a variety of augite, consisting essentially of these ingredients, (see page 151.) Iron chrysolite differs from ordinary chrysolite in containing oxyd of iron in place of magnesia. Isopyre is a black glassy amorphous mineral, found in granite. H= 6 —65. Gr=2-9-3. Consists of silica 47', alumina 139, peroxyd of iron 20'1, lime 15-4, oxyd of copper 1'9. Lievrite, (called also yenite and ilvaite.) Occurs in rhombic prisms, often with the sides much striated or fluted; color black or brownish: black. Luster submetallic. Streak black, greenish or brownish. H= 55 —6. Gr=3'8 —4'1. Contains about 50 to 55 per cent. of oxyd of iron with 14 of lime and 29 of silca. Fuses to a black globule. From the island of Elba in large crystallizations; also from Norway, Siberia, Silesia. At Cumberland, Rhode Island, yenite occurs in slender black or brownish-black crystals, in quartz, The following are hydrous species, giving off water when heated in a tube before the blowpipe. Nontronite and pinguite, are earthy almost like clay, of a yellowish or greenish color. Chloropal is a harder species, (H-=3-4,) of a greenish-yellow or pistachio-green color. Grengesite, thuringite, knebelite, and kirwanite, are other allied species. Green earth. Includes different compounds of a green earthy appearance. The green earth occupying cavities in amygdaloid is near chlorite. It is a silicate of the peroxyd of iron with some potash, magnesia and water; often with other ingredients. The green grains of the green sand of New Jersey, consist of silica 51'5, alumina 6'4, protoxyd of iron 24'3, potash 9-96, water 7-7. Hisingerite, cronstedtite, anthosiderite, polyhydrite, sideroschisolite chamoisite, stilpnomelane, and xylzte, are iames of dark brown o black species. Of what does wolfram consist? With what ores is it usually associ ated I What is said of the compounds of oxyd of iron with silica? 246 M lJ Th Crocidolite has a fibrous structure much resembling asbestus, and has been called blue asbestus. Color lavender-blue or leek-green H=4. Gr —32 3-3. From Southern Africa. Pyrosmalite occurs in hexagonal prisms with a perfect basal cleavage, and pearly surface. Color pale liver-brown, grayish, or greenish. H= 4-45. Gr=3'8. Contains 14 per cent. of chlorid of iron, and givesr off fumes of muriatic acid before the blowpipe. Iron-zeolite. A hydrous silicate of the oxyds of iron and manganese forming incrustations at a mine near Freyberg. coPPERAS..S Sulphate of Iron, or Green Vitriol. Monoclinic. In acute oblique rhombic prisms. M:M=: 82 21; P: M=80 37'. Cleavage parallel to P, perfect Generally pulverulent or massive. Color greenish to white. Luster vitreous. Subtranspa. rent to translucent. Taste astringent, sweetish, and metallic. Brittle. H=2. G1r=1'83. Composition: oxyd of iron 25'42, sulphuric acid 29'01, water 45'57. Becomes magnetic before the blowpipe. Yields a green glass with blowpipe; and a black color with a tincture of nut galls. On exposure, becomes covered with a yellowish powder, which is a persalt of iron. Obs. This species is a result of the decomposition of pyrites, which readily affords it if moistened while exposed to the atmosphere, as stated under pyrites. The old mine of Rammelsberg in the Hartz, near Goslar, is its most noted locality; but it occurs wherever pyrites is found. Copperas is much used by dyers and tanners, on account of its giving a black color with tannic acid, an ingredient in nut. galls and many kinds of bark. It for the same reason form. the basis of ordinary ink, which is essentially an infusion of nutgalls and copperas. It is also employed in the manufacture of Prussian blue. With prussiate of potash, any soluble persalt of iron, even in minute quantity, gives a fine blue color to the solution, (due to the formation of Prussian blue,) and this is a common test of the presence of iron. About 1800 tons of copperas are used in the United States annually. The colcothar of vtriol is the browish-red oxyd of iron, obtained from copperas by calcination and other processes. It is much used as a polishing powder. Coqvimbite, or white copperas, and yellow copperas, are names ot wo sulphates of the peroxyd of iron. Pittizite, fibro-ferrite, are allied What is the appearance and taste of copperas? its compositionl What is its origin in nat're? For what is it used 2 IRON ORES. 24' compounds. Apalclite is st:11 another, peculiar in containing bat 4 pI, cent. of water. VolT:iite is a double sulphate of iron, alumina, potash and water, crays tallizing like alum in octahedrons. From the Solfatara, near Naples. SPATHIC IRON.-Carbonate of Irot. —Chalybite. Hexagonal. In rhombohedrousand six-sided prisms, easily cleavable parallel to a rhombohedron of 107 Faces often curved. Usually massive, with a foliated structure, somewhat curving. Sometimes in globular concretions or implanted globules. Color light grayish to brown; often dark brownish-red, or nearly black on exposure. Streak uncolored. Luster pearly to vitreous. Translucent to nearly opaque. H=3 —4,5 Gr-3-7- 3-85. Composition, when pure: protoxyd of iron 62-07, carbonic acid 37-93. Often contains some. oxyd of manganese or magnesia, replacing part of the oxyd of iron. Before the blowpipe it blackens and becomes magnetic; bult alone it is infusible. Colors borax green. Dissolves in nitric acid, but scarcely effervesces unless pulverized. The ordinary crystallized or foliated variety is called spathic or sparry iron, because the mineral has the aspect of a spar. The globular concretions found in some amygdaloids or lavas, have been called spherosiderite. An argillaceous variety, occurring in nodular forms, is often called clay i1ro-0n;lto, and is abundant in the English coal measures. Dif. This mineral is ftliated like calc spar and dolomite, but it has a much higher specific gravity. It readily becomes magnetic before the blowpipe. Obs. Spathic iron. occurs in rock of various ages, and often accompanies metallic ores. The largest beds are found in gneiss and graywacke, and also in the coal formation. In Styria and Carinthia, it is very abundant in gneiss, and in the Hartz it occurs in graywacke. Cornwall, Alstonmoor and Devonshire, are English localities. A vein of considerable extent occurs at Roxbury, near New Milford, Conn., in quartz, traversing gneiss; at Plynouth, Vt., and Sterling, Mass., it is also abundant. It oc: Describe spathic iron. What is its constitution? What are its hemical characters 1 How does it differ from calc spar? What are ts varieties? How does it occur? 248 MET'rALS. curs also at Monroe, Conn.; in New York state in Antwerjp Jefferson county, and in Hermon, St. Lawrence county. The argillaceous carbonate in nodules and beds, is very abun. dant in the coal regions of Pennsylvania. Uses. This ore is employed extensively for the manufac ture of iron and steel. Thomaite is a carbonate of iron occurring in rhombic prisms. Gr=3'1. From the Siebengebirge mines. Junkerite has proved to be com mon spathic iron. Mesitine spar, (Breunnerite.) A carbonate of iron and manganese occurring in yellowish rhombohedrons of 1070 14'. H=4. Gr=3'33'6. This includes much of what is called rhomb spar, or brown spat which becomes rusty on exposure. Oligon spar. A carbonate of iron and manganese. Angle of rhom bohedron 107~ 3'. Color yellow or reddish-brown. Gr=3.75. VIVIANITE. Monoclinic. In modified oblique prisms, with cleavages in one direction highly perfect. Also radiated, renifornm, and globular, or as coatings. Color deep blue to green. Crystals usually green at right angles with the vertical axis, and blue parallel to it. Streak bluish. Luster pearly to vitreous. Transparent to translucent; opaque on exposure. Thin lamine flexible. H= 1-5-2. Gr= 2-66. Composition: protoxyd of iron 42'4, phosphoric acid 28-7, water 28*9. Loses its color before the blowpipe and becomes opaque; and if pulverized, fuses to a scoria, which is magnetic. Affords water in a glass tube, and dissolves in nitric acid. Dif. The deep blue color connected with the softness, are decisive characteristics. The blowpipe affords a confirmatory test. Obs. Found with iron, copper and tin ores, and sometimes in clay, or with bog iron ore. St. Agnes in Cornwall, Bodenmais, and the gold mines of Vorospatak in Transylvania, afford fine crystallizations. In the United States, good crystals have been found atImleytown, N. J. At Allentown, Monmouth county, and Mullica Hill, Gloucester county, N. J., are other localities. It often fills the interior of certain fossils. Occurs also at Harlem, N. Y., in Somerset and For what is spathic iron used? What is the color and s:ructure of vivianite? Of what does it consist? 20 TRON ORE. 249 Worcestei counties, Md., and with bog ore in Stafford county, Va. The blue iron earth is an earthy variety, containing about 30 per cent. of phosphoric acid. The mineral from Mullica Hill has been called mullicite. Anglarite, from Anglar, France, is a similar mineral, with less phosphoric acid. Triphyline occurs in cleavable masses, of a greenish-gray or bluish color. H=5. Gr=3-6. It is an anhydrous phosphate of the protoxyds of iron, and manganese, with some lithia. From Bodenmais il Bavaria, and Norwich, Mass. Triplite. Another phosphate of iron and manganese, of brown oi blackish-brown color. From Limoges, in France. Green iron stone, (kraurite,) alluaudite, melanchlor, and beraunite, are names of phosphates of the peroxyd of iron. Color of the first two, dull leek-green; structure fibrous. Luster silky. Color of the third, black; of the fourth, hyacinth-red, becoming darker on exposure. Cacoxene. This is a handsome species, occurring in radiated silky tufts of a yellow or yellowish-brown color. H=3-4. Gr=3'38. It is a phosphate of alumina and iron. It differs from wavellite, which it resembles in its mqre yellow color and iron reactions. It also resembles carpholite, but has a deeper color. It occurs on brown iron ore in Bohemia. Carphosiderite is another yellow phosphate of iron from Greenland It occurs in reniform masses. ARSENATES OF IRON. Cube ore. Occurs in cubes of dark green to brown and red colors Luster adamantine, not very distinct. Streak greenish or brownish. H1=2'5. Gr=3. It is a hydrous arsenate of the peroxyd of iron, containing 38 per cent. of arsenic acid. From the Cornwall mines; also from France and Saxony. Scorodite. Crystallizes in rhombic prisms, modified. M: M=120o 10'. Color pale leek-green or liver brown. Streak uncolored. Luster vitreous to subadamantine. Subtransparent to nearly opaque. H= 3-5-4. Gr=3'1 —3 3. Scorodite is a hydrous arsenate of the peroxyds of iron, containing 50 per cent. of arsenic acid. From Saxony, Carinthia, Cornwall, and Brazil. It occurs in minute crystals near Edenville, N. Y., with arsenical pyrites. The name of this species is from the Greek skorodon, garlic, alluding to the odor before the blowpipe. Iron sinter is a yellowish or brownish hydrous arsenate of the peroxyd of iron, containing but 30 per cent. of arsenic acid. Arseno-siderite is another fibrous arsenate, containing 34 per cent. of arsenic acid. Symplesite is a blue or green mineral, supposed to be an arsenate of the protoxyd of iron. Its crystals are right rhomboidal, with a perfect cleavage. H=2-5. Gr=2.96. From Voigtland. Oxalate of iron. This is a soft, yellow, earthy mineral of rare oc currence. It blackens instantly in the flame of a candle. Occurs is Bohemia; it is supposed to have resulted from the decomposition of succulent plants. 250 METALS. (GENERAL REMARKS ON IRON AND ITS ORES.'he metal iron has been known from the most ren.ote historical period, but was little used until the last centuries before the Christian era. Bronze, an alloy of copper and tin, was the almost universal substitute, for cutting instruments as well as weapons of war, among the ancient Egyptians and earlier Greeks; and even among the Romans (as proved by the relics from Pompeii) and also throughout Europe, it continued long to be extensively employed for these purposes. The Chalybes, bordering on the Black Sea, were workers in iron and steel at an early period; and near the year 500 B. C., this metal was introduced from that region into Greece, so as to become common for weapons of war. From this source we have'the expression chalybeate applied to certain substances or waters containing iron. The iron mines of Spain have also been known from a remote epoch, and it is supposed that they have been worked " at least ever since the times of the later Jewish kings; first by the Tyrians, next by the Carthagenians, then by the Romans, and lastly by the natives of the country." These mines are mostly contained in the present provinces of New Castile and Aragon. Elba was another region of ancient works, " inexhaustible in itA iron," as Pliny states, who enters somewhat fully into the modes of manufacture. The mines are said to have yielded iron since the time of Alexander of Macedon. The ore beds of Styria in Lower Austria, were also a source of iron to the Romans. Iron ores. The ores from which the iron of commerce is obtained, are the spathic iron or carbonate, magnetic iron, specular iron, brown iron ore or hematite, and bog iron ore. In England, the principal ore used is an argillaceous carbonate of iron, called often clay iron stone, found in nodules and layers in the coal measures. It consists of carbonate of iron, with some clay, and externally has an earthy, stony look, with little indication of the iron it contains except in its weight. It yields from 20 to 35 per cent. of cast iron. The coal basin of South Wales, and the counties of Stafford, Salop, York, and Derby, vield by far the greater part of the English iron. Brown hematite is also extensively worked. In Sweden and Norway, at the famous works of Dannemora and Arendal, the ore is the magnetic iron ore, and is nearly free from impurities as it is quarried out. It yields 50 to 60 per cent of iron. The same ore is worked in Russia, where it abounds in the Urals. The Elba ore is the specular iron. In Germany, Styria, and Carinthia, extensive beds of the spathic iron are worked. The bog ore is largely reduced in Prussia. In the United States, all these different ores are worked. The localities are already mentioned. The magnetic ore is reduced in New England, New York, northern New Jersey, and sparingly in PennsylWhat was the usual substitute for iron among the ancients? What s said of the Chalybes? What of the working of the Spanish mines? What of the Elba mines? What are the common ores of iron? What s said of the most common in England? in Sweden an. Norway? al Elba, Styria, and Carinthia? What ores abound in the United States? IRON ORES. 251 vania and other states. The brown hematite is largely worked along Western New England and Eastern New York, in Pennsylvania, and many states south and west. The earthy argillaceous carbonate like that of England, and the hydrate, are found with the coal deposits, and are a source of much iron. The several kinds of ore differ somewhat in the quality of the iron they afford; but the greatest part of the supposed difference, if we except the bog ore, depends on the mode of working, and the use of proper fluxes in the right proportion. The bog ore (a bog formation) often contains phosphorus from animal decomposition, and generally yields a brittle product, though from its fusibility good for some kinds of casting. a Mode of Assay. ) In the assay of ores in the dry way, for economical purposes, somewhat different means are used for the different ores. As in the reduction in the large way, the object is to separate the iron from the oxygen with which it is united, and from the impurities clay, lime, or quartz, if such be present. With the pure oxyds, or the carbonate in a pure state, a simple mixture of the pulverized ore and charcoal strongly heated in a crucible, will effect a reduction. But it is found better to add carbonate of lime or burnt lime, with clay, or glass, or borax, which fuse into a slag, and besides aiding the reduction, protect the reduced iron from combustion. For specular iron, with 10 parts of the ore finely pulverized, mix as much chalk or limestone, 6 to 8 parts of bottle glass, and sixteenth or a twentieth of the whole by weight of charcoal. For a magnetic iron ore, mix with 10 parts of the ore 12 of glass, and as much chalk, with one part of charcoal; or, say 3 parts of each burnt lime and burnt clay, and 2. of charcoal. For a brown hematite, 10 parts of burnt lime, as many of burnt clay, and 3 of charcoal. These proportions, taken from Mushet, are not given as invariably necessary, but simply to guide the experimenter. The fitness of the proportions is to be determined from the result. If the slag is clear and nearly colorless, the reduction is perfect. If dark colored, it contains unreduced oxyd, and too much glass or clay may have been added; if opaque or porcellanous, too much lime has been used. In the case of an argillaceous ore, the proportions of lime and glass should be determined from the proportions of lime and clay in the ore. The prepared ore with the fluxes, well mixed, is placed in a crucible lined with moistened and well compacted charcoal dust; the crucible is filled with charcoal, and closed with a luted lid of fire clay. The heat should be very slowly raised, not using the bellows for three quarters of an hour, and finally sustained for a quarter of an hour at a white heat, and then the crucible may be removed and the button of cast iron, after cooling, taken out. Reduction of ores. In the reduction of iron ores, the simplest and oldest process consists in heating the pounded ore with charcoal in an open forge, (see beyond, page 237.) By the improved process, the ore is heated in a blast furnace along with charcoal, coke, or mineral coal. What is said of the iron from different ores? Describe the general mode of assaying iron ores? What is the usual mo le of reduction' Describe the blast furnace. 252 M' TALE. and also a certain proportion of some flux, usually limestone. The lime forms a glass with the silicious impurities of the ore, while the carbon (first becoming carbonic oxyd) takes the oxygen which is in combination with the metal. A small proportion of the carbon also en ters into the metal after it is reduced, giving it the fusibility it has as cast iron. Before describing the process, a brief description may be given of A blast furnace.* The following figure (excluding the structure on th right, to be afterwards explained,) represents the essential features of furnace, in an exterior. side view. 1 er w. r 1 II - I I I tT~ — I- I I It is essentially a broad truncated four-sided pyramid of brick and stone, containing within a cavity where the ore is heated and reduced * I am indebted to Mr. S. S. Haldeman for the following figures an their descriptions. They are 1-20th of an inch to a foot. The furnaco was built for anthracite, as is explained beyond. It is a model of the fine works near Columbia, Pa., owned by the MEssrs. Haldeman. 20* IRON OK ES. 253 The annexed figure 2, exhibits the interior laid open. The mani structure is called the stack. Of the interior cavity, the lower part, 2 H, h, is the hearth, H is foursided; B B, the boshes,* having nearly the shape of a funnel, exI~ J E^ \ ^ C cept that it is square below; above l \ A 7,, \ b, is the proper furnace, usually - I _ ~ i ~\ about 30 feet high; below the crucible, lies the hearth, commonly of' I AI \ ^ y~1~ refractory grit rock. The furnac is circular, and is lined with fir |..... b - -~i A\ brick (1); next to this, is a layer oi dry sand (r,) and then one of brick I K ByS / \ (r',) constituting the inner part of the stack. The layer of sand alv m \ lows the interior to expand by. t - n\ heat, without cracking the exte-!-.~a. p. \ \ nrior; and moreover, the whole, 1, r, r', may be removed for repairs without injuring the exterior work. At t, is one of the toters, (or tuyeres,) the tubes by which the blast of air is driven into the furnace. At m, is a partial partition of fire brick, called the tymp, separating the back and front of the hearth, but not extending to the bottom or hearth-stone. The hearth-stone is made of a refractory grit rock. In each side of the four-sided stack, at bottom, there is a door-like or arched opening, (A, figs. 1,2,) which extends in to the stonework that encloses the hearth. Three of these opening are called the twier-arches, and the other is the front or working arch; the twiers enter by the twier-arches to the interior, and at t, (fig. 1,) is shown the place of entrance of one. The view in figure 1, gives a front view of a twier arch; and in figure 2, at A, there is a side view, with the twier in place. 3 To prevent the melted metal, which often rises above the P' l: a twiers, from flowing into the A blast pipe, in case of the blast l ing accidentally checked, iher.e is at V (fig. 2) a valve, which is raised by the blast and closes when it stops; and at k, a place for inserting a rod to A'~Al remove any slag that may cling to the twier. Figure 3,is a horizontal section, at bottom; A, A, A, are the twier arches, separated by the masonry of the stack; H, h, the position of the hearth or ii~ F~~~ ~crucible; m is the tymp between H and h; t, t, t, are the * This word is from the German word hbischung, a slope. H. 254 METALS twiers, the three blast tubes of which connect with a common tube that extends round, by the passage g g, (figs. 1, 3,) in the form of a semicircle, and receives the blast through the tube p. The dotted circle within corresponds to tlb inner outline of the fire brick lining of the widest part of the furnace. The melted iron runs into the lower part of the hearth, and is covered by the cinder. It is prevented from running out by the damstone c (figs. 2, 3); and farther to hinder the metal from being forced out by the blast, clay is rammed beneath the tymp around the twiers and upon the surface at h, where it is retained by heavy iron plates. These plates are raised every few hours to allow the cinder to run off, which passes out over the damstone, along the dust-plate, c i, (figs. 2, 3.) The metal is drawn off every twelve hours at the lower level a, through an aperture at the bottom of the damstone. Great economy in making iron has of late been secured by heating the blast to three to six hundred Fahrenheit. The cooling effect of the vast volumes of air thrown into the furnace is avoided;* and this is absolutely necessary when anthracite coal is used, as is the case in many works of recent construction. In the view above given,f, f, (fig. 2,) represent two (out of three) passages in the upper part of the furnace, by which the waste flame is led off, first to heat boilers at W, W, (fig. 1,) and then to a hot-oven chamber, o. In the last there is a great number of iron pipes, arranged in series; the blast by the action of the engine, is thrown through all the pipes in succession, and after being thus heated,flows on to p, (fig. 3,) whence it passses to the twiers, (t, t, t.) When the engine is separated from the furnace, the oven is usually placed upon the front side (instead of back) of the top, and the flame passes in by a single aperture. The works here figured are situated upon a side hill. It is important that the blast should not be too great, as it wastes the metal by oxydation; and at the same time it should be cufficiently copious to supply the requisite qantity of oxygen. The first step in the process of reduction, consists in roasting the ore to drive offany volatile ingredients, and open its texture. This is efiected by piling the ore in heaps, made of alternate layers of coal or coke and ore, covering up the heap loosely with earth and firing it. The carbonic acid, if it contains any, the moisture, and any sulphur present, are thus expelled, and the ore is in a looser state for reduction. The iurnace is filled with coal and slowly heated up-ten or twelve days being required for this, to avoid the effect of too sudden heat on the furnace. The charge, next to be added, consists of coal, the roasted ore, and limestone, (if this be the flux,) in certain proportions, and it is carWhat is said of the hot blast? Describe the method of heating the engine, and air of the blast. Mention the several steps in the process f reduction. * The weight of air thrown into a Glasgow furnace in 24 hours, has een estimated at 6192 cwt., or 6292 cubic feet per minute, while the hol' weight of coke, ore and limestone added in the same time, was nly f666 cwt. In ordinary cases, the weight of the air is at'east foul rmes as much as that of the charges. IRON' oRP. R. 255 ned to the top of the furnace, often by a railway, and thrown in at mtervals of an half hour or so, as the coal sinks, so that the furnace is kept full. The charge at the top of the furnace is two days or more in descending to where it comes within the direct action of the blast. The fusion of the ore finally takes place a short distance above the twiers, and its reduction is conlpleted at the same time by the burning coal and flux in a few hours the hearth fills with metal and slag, and as it accumulates, the fused iron displaces the slag which is continually running over and conveyed off by the workmen: the metal being let out below by removing a luting of clay, is run into moulds of sand, to form pigs-oblong masses of about 180 pounds each. The slag in this process serves to protect the metal from combustion as it is reduced. Its color and condition indicate the success of the reduction. If of a dark color and heavy, it shows that all the ore is not reduced, and much metal lost; probably owing to too little coal or too rapid working. If dark vitreous, with streaks of green, there is some oxyd of iron carried off by the silica, which may probably be remedied by adding more lime to take up the silica. If light colored, all is going on well.* The proportion of fluxes depends on the ore and its condition, and no general rule can be given. With the argillaceous carbonate of iron of Staffordshire, limestone alone is used, 10 to 12 per cent. being employt d for 45 per cent. of ore, and 45 of coke. Even this addition is unnecessary when the ore is associated with much lime. For the ordinary argillaceous ores, the weight of limestone used is about one-fourth the weight of the ore, or from one-third to one-sixth. When there is no silica in the ore, it is added in nearly equal proportions with the lime and other earthy ingredients present. Previous assays must determine what is required for each variety of ore. The brown hematite is easily reduced, and requires much coal with a slow process, or only a white iron is produced; 8 to 12 per cent. of limestone is added to a charge as a flux. Good metal is strong of a dark gray color, with a granular texture, and runs fluid when melted; while the bad metal is light colored and brittle, and runs thick and sluggish. There are numbers 1, 2, 3, 4, in market, including the two kinds just described and two intermediate grades. Number 1 is best fitted for castings, as it contains the most carbon and is more fusible than the others. Cast iron sometimes contains a trace of silicium without injury, and according to Berzelius, the best Swedish iron contains after it is made into wrought iron 1-20 per cent. of silicium. Sulphur and phosphorus are highly deleterious, except when a fusible metal is desired with the strength comparatively unessential. Wrought or malleable iron. As cast iron owes its fusibility principally to the carbon present, the change of cast to wrought iron, called What is said of the slag? Or. what does the proportion of fluxes epend 7 * The slag from Merthyr Tydvil, in South Wales, afforded Berthier on nalysis, silica 40'4, lime 38'4, magnesia 5'2 alumina 11-2, protoxyd of iron 3-8, and a trace of sulphur. 256 TAL LS refining, must con.is: in trit r iiioval of this carbon ana any renlainiLg impurities. This is done by bryrning it out, and for this purpose the poorer kinds of cast iron answer as well as the best. Formerly the metal was melted three or four times, and then hammered with a large forging hammer to remove the scoria. In the next improvement, the metal while in fusion was stirred for a while to effect the more complete combustion of the carbon; and in this way it gradually lost its fusibility and became stiff enough for forging. This process is called puddling. The metal passes first through one fusion as preparatory. It is next placed on plates in a furnace of the reverberatory kind, the metal being loosely piled in the middle of the horizontal furnace; 3 cwt. is an ordinary charge. The flame plays over it, and in half an hour it begins to melt. The workmen now stir it about, occasionally dashing in a scoopful of water. The metal gives off freely bubbles of gas, which burn with a blue flame, (carbonic oxyd); in about twenty minutes the whole falls to pieces like a coarse gravel, and a lurid flame appears over it. The whole is still kept in motion and well heated, and soon it begins to unite again, when it is separated into several lumps of the size of three or four bricks. These masses as they assume a dotty consistency (sometimes called "coming into nature,") are drawn from the furnace and dolleyed or stamped into cakes with hammers. The plates are thrown while hot into water, which renders them brittle; they are then broken into pieces, again placed together in the furnace, heated to a welding heat, and finally forged under a ponderous hammer, moved by machinery, into short thick bars called blooms. 100 parts of cast iron yield about 63 of blooms. Some of the steps in this process are often neglected in making the ordinary iron. It has been found that full 24 per cent. of the gas escaping from an iron furnace is carbonic oxyd, and in the boshes this is the only gas This gas has been used as fuel in the refining of the iron, and by this means the whole expense of fuel for refining is saved. (See the Amer. Jour. Sci., vols. i. and ii., 2d ser., where the theory of the blast furnace is well explained.) The iron produced is said to be cold short if it is brittle when cold, and this has been attributed to the presence of silicium. It is termed red short when it becomes brittle on heating. Cast iron is also changed to malleable iron by covering castings with powdered hematite or other oxyd of iron, and exposing to heat below fusion. The carbon is removed by the oxygen of the oxyd. The scales of oxyd thrown off in the forging of iron are much used. This process was first introduced in 1804, and is one of great importance in the arts Malleable iron is also obtained directly from the ore by a single fusion in what is called a Catalan forge. It has a rectangular crucible or basin below the fire, about 18 inches by 21 in width and 17 inches deep. The twier enters about 9j inches above the bottom and receives the blast from a water-blowing machine; and it admits of a change of position so as to give a change of direction to the blast as is required in the Describe the manufacture of wrought from cast iron. Heow j the gas used in heating? What are cold short and red short ron? What other mode is there of rendering cast iron malleable? Describe a metne of obtaining malleable iron direct from the ore. IRON OHES. 257 different stages of the process. The ore after a previous roasting in a kiln, is pounded up and sifted; the coarser part is piled up in the forge on the side opposite the blast, and charcoal fills up the rest of the space. After the heat is well up, the finer siftings are thrown at intervals upon the charcoal fire. The basin below, which has been previously lined with two or three coats of pounded charcoal, or loam and charcoal, receives the iron as it is reduced and runs down. The slag is occasionally removed from the surface of the basin through holes opened for the purpose. The iron, when sufficiently accumulated, is taken out in a pasty state and at once forged. The process usually lasts five or six hours. A lump or bloom of malleable iron is thus produced in three or four hours. This cheap and simple process has long been used in Cat alonia, and it is hence called the method of the Catalan forge. By a slow operation, and but a small quantity of siftings, worked with an upraised twier, the proportion of steel obtained by the. process is increased. This mode of reduction is adapted only for the purer and more fusible ores; and moreover it requires a large consumption of fuel and is attended by a considerable loss. The argillaceous ore of the coal region would yield only an iron glass in a Catalan forge. By another mode of reduction, the iron ore coarsely powdered is mixed with coal in certain proportions, or a material containing the requisite amount of carbon, and the charge is heated in a reverberatory furnace till reduction has taken place. The carbon carries off the oxygen of the ore, and if the proper proportions have been employed, it leaves a mass of malleable iron behind. Steel. Wrought iron is changed to steel by a process called cementation. The best iron is heated with charcoal; a portion of carbon is thus absorbed, and the iron at the same time acquires a blistered surface, and becomes fine grained and fusible. When the blistered steel is drawn down into smaller bars and beaten, it forms tilted steel; and this broken up, heated, welded, and again drawn out into bars, forms shear steel. Cast steel is prepared by fusing blistered steel with a flux and casting it into ingots, and then by gentle heating and careful hammering or rolling, giving it the form of bars. Steel is also formed direct from certain ores of iron, more particularly when oxyd of manganese is associated with them, and especially from the spathic iron, which often contains a portion of carbonate of manganese. The oxygen of the manganese is said to remove part of the car. bon from the cast iron, and thus reduce it to the state of steel. There are 1 or 2 per cent. of manganese in the metal thus obtained. The product is of inferior quality as steel, but is largely manufactured in Germany. The wootz of India is a steel obtained from a black ore of iron, in a furnace even simpler than the Catalan forge. It is said to contain a minute proportion of silicium and aluminium. The amount of iron manufactured in the United States in 1853, (over a third in Pennsylvania,) was 1,000,000 tuns; in Great Britain, in 1852,,700,000 tuns; in France, in 1849, 514,000; in Russia, in 1845, 400,000; in Sweden, in 1846, 145,000; other parts of Europe, (Aus tria, Belgium, Germany,) 700,000 tons. \ How is steel made 1 Describe the kinds of steel. How is steel made direct from ores of iron t 258 METALS. 15. MANGANESE. The ores of manganese have a specific gira ity below 5'2. They afford a violet-blue color with borax or salt of phosphorus, in the outer flame of the blowpipe; and on heating the oxyd with muriatic acid, fumes of chlorine are given out which are derived from the acid. RHODONITE. -MANGANESE SPAR. Monoclinic? In oblique rhombic prisms, isomorphous with pyroxene; usually large massive, the cleavage often indistinct. Possibly triclinic, and the same as Fowlerite. Color reddish, usually deep flesh-red; also brownish, greenish, or yellowish, when impure; streak uncolored. Luster vitreous. Transparent to opaque. Becomes black on exposure. H=5'5 —65. Gr==34-3-7. Composition: oxyd of manganese 52'6, silica 39'6, oxyd of iron 4-6, lime and magnesia 1-5, water 2'7. The impure varieties, Bustamite, Photizite, and Allagite, contain variable proportions of carbonate of iron, lime, or manganese, beside alumina. Becomes dark brown when heated, and fuses with borax in the outer flame, giving a hyacinth red globule. Dif. Resembles somewhat a flesh-red feldspar, but differs in greater specific gravity, in blackening on long expo. sure, and in the glass with borax. Obs. Occurs in Sweden, the Hartz, Siberia, and elsewhere. In the United States it is found in masses, at Plainfield, and Cummington, Mass.; also abundantly at Hinsdale, and on Stony Mountain, near Winchester, N. H.; at Blue Hill Bay, Me. The black exterior is a more or less pure hydrated oxyd of manganese. Uses. Dr. Jackson has suggested the use of this ore for making a violet-colored glass, and also for a colored glazing on stone ware. The finely pulverized mineral, spread on stone ware as a paste, will afford a permanent glazing, which will have a black color if it be of considerable thickness, and of a deep violet-blue if quite thin. It may be used along with the usual salt glazing. What is said of the ores of manganese? What is the appearance of manganese spar? its composition and blowpipe characters? Hov is it distinguished from feldspar? For what may it te used? MANGANESE ORES. 259 It receives a high polish, and is sometimes employed fr inlaid work. Tephroitc. A silicate of manganese, occurring nassive and cleavable. Color ash-gray. H=-=5-5. Gr=4. From Franklin, N. J. Compo. sition: silica 29-8, nrotoxyd of manganese 70'2. Fuses easily to a black scoria. Knebelite is a rela ed species. Fowlerite (Paisbergite) Probably same as Rhodonite. Form tri. clinic. In crystals at Franklin, N. J., and Paisberg, Sweden. PYROLUSITE —Binoxyd of Manganese. Trimetric. In small rectangular prisms, more or less Z~-bi' 3~- modified. M: M=-93' 40'; M: e= 136' 50'. Sometimes fibrous and radiated or divergent. Often massive M M E and in reniform coatings. Color iron-black; streak black, unmetallic. H=-2 —2. Gr —-48- 5-0. -_ ~-2~ ~Composition: essentially the binoxyd of manganese, consisting of oxygen 37, and manganese 63. With borax it gives an amethystine globule. It yields no water in a matrass. Dif Differs from psilomelane by its inferior hardness, and from ores of iron by the violet glass with borax. Obs. This ore is extensively worked in Thuringia, Moravia, and Prussia. It is common in Devonshire, Somersetshire, and Aberdeenshire, in England. In the United States it is associated with the following species in Vermont, at Bennington, Brandon, Monkton, Chittenden, and Irasburg; it occurs also in Maine, at Conway, and Plainfield, in Massachusetts; at Salisbury, and Kent, in Conn., on hematite. The name pyrolusite is from the Greek pur, fire, and luo, to wash, and alludes to its property of discharging the brown and green tints of glass, for which it is extensively used. Uses. Besides the use just alluded to, this ore is exten. sively employed for bleaching, and for affording the gas oxy. gen to the chemist. PSILOMELANE. Massive and botryoidal. Color black or greenish-black. Streak reddish or brownish-black, shining. H =-5-6. Gr= 4-4A4. Describe pyrolusite. What is its constitution? What are its uses I Describe psilomelane? How does it differ from X yrolusite. 260 METALS. Composition: essentially binoxyd of manganese with one per cent. of water, and also some baryta or potassa. The compound is somewhat varying in its constitution. Before the blowpipe like pyrolusite, except that it affords water. Obs. This is an abundant ore, and is associated usually with the pyrolusite. Prof. Silliman, jr., has lately detected oxyd of cobalt mixed with this ore. It-occurs at the different localities mentioned under pyrolusite, and the two are often in alternating layers; it has been considered only an impure variety of the pyrolusite. The name is from the Greek psilos, smooth or naked, and melas, black. Uses. Same as with pyrolusite. Heteroclin and marceline are similar ores, containing 10 to 16 pel cent. of silica. WAD. —Bog manganese. Massive runiform or earthy; also in coatings and dendritic delineations. Color and streak black or brownish-black. Luster uw., earthy. H=1. Gr=-37. Soils. Composition. Consists of peroxyd of manganese, in varying proportions, fiom 30 to 70 per cent. along with peroxyd of iron, 20 to 25 per cent. of water, and often several pei cent. of oxyd of cobalt or copper. It is a hydrated peroxyd, mechanically mixed with other oxyds, organic acids and other impurities, and like bog iron ore, is formed in low places fiom the decomposition of minerals containing manganese. Gives off much water when heated, and affords a violet glass with borax. Obs. Wad is abundant in Columbia and Dutchess coun. ties, N. Y., at Austerlitz, Canaan Center, and elsewhere; also at Blue Hill Bay, Dover, and other places in Maine; at Nelson, Gilmanton, and Grafton, N. H.; and in many othei parts of the country. Uses. May be employed like the preceding in bleaching, but is too impure to afford good oxygen. It may also be used for umber paint. TRIPLITE.l —Ferruginous Phosphate of Manganese. Massive, with cleavage in three directions. Color black ish-brown. Streak yellowish-gray. Luster resinous; near ly or quite opaque. H=5 —'5. Gr —-34-3-8. What is wad? its composition? its origin? For what may it be used? What is triplite? 21 MANGANESE ORES. 261 Composition: protoxyd of manganese 33-2, protoxyd of iron 33-6, phosphoric acid 33*2, with tome phosphate of lime. Fuses easily to a black scoria, before the blowpipe; dis. solves in nitric acid, and gives a violet glass with borax. Obs. From Limoges in France. Rather abundant at Washington, Conn., and sparingly found at Sterling, Mass. Heterosite is another phosphate of the oxyds of manganese and iron, of a greenish-gray or bluish color. Contains 41-77 per cent. of phosphoric acid. Huraulite is a hydrous phosphate of the same oxyds, containing 18 per cent. of water and 38 of phosphoric acid. Occurs in transparent, oblique, reddish-yellow crystals. Both heterosite and bureaulite are regarded as either altered triphyline or triplite. Hausmannite. A sesquioxyd of manganese containing 72-1 per cent. of manganese, when pure. Brownish-black and submetallic, occurring massive and in square octahedrons; H=5-5'5. Gr==4'7 From Thuringia and Alsatia. Braunite. A protoxyd of manganese, containing 69 per cent. of manganese when pure. Color and streak dark brownish-black, and luster submetallic. Occurs in square octahedrons; H=6 —65. Gr= 4'8. From Piedmont and Thuringia. -._llanganite. A hydrous sesquioxyd of manganese. Occurs massive and in ihombic prisms. Color steel-black to iron-black. H=44'5. Gr=4-3 —44. From the Hartz, Bohemia, Saxony, and Aberdeenshire. Peloconite is an ore of manganese and iron, of a bluish-black color, and liver brown streak, with a weak vitreous luster. From Chili. Manganblende, or Alabandine. A sulphuret of manganese, of an iron-black color, green streak, submetallic luster. H=-35 —4. Gr= 3-9-4'0. Crystals, cubes and regular octahedrons. From the gold mines of Nagyag, in Transylvania. Hauerite is a sulphuret, containing twice the proportion of sulphur in the last. Color reddish-brown and brownish-black, resembling zinc blende. H=4. Gr-=346. From Hungary. There is also an arseniuret of manganese, of a grayish-white color, and metallic luster, which gives off alliaceous fumes. G=5-55. From Saxony. Diallogite. A carbonate of manganese. Color rose-red to brownish; streak uncolored. Luster vitreous, inclining to pearly. Translucent to subtranslucent. Crystals rhombohedral. H=3'5. Gr=3-59. Infusible alone. From Saxony, Transylvania, and the Hartz. Also from Washington, Conn., with triplite. GENERAL REMARKS ON THE ORES OF MANGANESE. Manganese is never used in the arts in the pure state; but as an oxyd t is largely employed in bleaching. The importance of the ore for this purpose, depends on the oxygen it contains, and the facility with which On what does the value of manganese ores depend in the art of bleach. ing? 262 M r rALS. this gas is given up. As the ores are often impure, it is riportant to ascertain their value in this respect. This is most readily done by heating gently the pulverised ore with muriatic acid, and ascertaining the amount of chlorine given off. The chlorine may be made to pass into milk of lime, to form a chlorid, and the value of the chlorid then tested according to the usual modes. The amount of chlorine derived from a given quantity of muriatic acid depends not only on the amount of oxygen in the ore, but also on the presence or absence of baryta and such other earths as may combine with this acid. The binoxyd of manganese when pure, affords 18 parts by weight of chlorine, to 22 parts of the oxyd; or 23J cubic inches of gas from 22 grains of the oxyd. The best ore should give about three-fourths its weight of chlorine, or about 7000 cubic inches to the pound avoirdupois. The chlorine for bleaching is used commonly in combination with lime. To make the chlorid of lime, the chlorine is generally obtained either through the action of muriatic acid on the oie, (3 to 4 parts by weight of the former, to 1 of the latter,) or more commonly by mixing 1 part of the ore with 14 parts of common salt, 2 or 24 parts of concentrated sulphuric acid, and as much water. As the chlorine passes off, it is conveyed into chambers containing slaked lime, by which it is absorbed. Manganese is also employed to give a violet color to glass. The sulphate and the chlorid of manganese are used in calico printing. The sulphate gives a chocolate or bronze color. The best beds of manganese ores in the United States, which have been opened, are at Brandon, Chittenden, and Irasburg, Vt. 16. CHROMIUM. The ores of chromium are the chromates of lead aid chromic iron, which are described under Lead and Iron. There is also a native chroinic ochre, supposed to consist of silica chromic acid, alumina, and iron. Wolchonskoite is an allied mineral. Miloschine or Serbian is considered a chro. miferous clay. 17. NICKEL. The ores of nickel, excepting one or two, have a metallic luster, and pale color; their specific gravity is between 3 and 8, and hardness mostly between 5 and 6, (in one, about 3.) They resemble some cobalt ores, but do not like them give a deep blue color with borax. How is manganese used? For what other purpose is manganese used? What is said of the ores of chromium? What if said of th ores of nickel? NICKEL ORES. 263 COPPER NIcKEL.-Arsenica, Nickel. Hexagonal. Usually massive. Color pale copper-red; streak pale brownish-red. Luster metallic. Brittle. H 5-5'5. Gr —73- 77. Composition: nickel 44, and arsenic 56; sometimes part of the arsenic is replaced by antimony. Gives off arsenical (alliaceous) fumes before the blowpipe, and fuses to a pale globule, which darkens on exposure. Assumes a green coating in nitric acid, and is dissolved in aqua-regia. Dif. Distinguished from iron and cobalt pyrites by its pale reddish shade of color; also from the former by its arsenical fumes, and from the latter by not giving a blue color with borax. None of the ores of silver with a metallic luster have a pale color, excepting native silver itself. Obs. Accompanies cobalt, silver, and copper ores in the mines of Saxony, and other parts of Europe; also sparingly in Cornwall. It is found at Chatham, Conn., in gneiss, associated with white nickel or chloanthite.!CLOANTHITE.2 —White Nickel. Monometric. In cubes. Color tin-white. Streak grayish. black. H-=5'5 — 6. Gr-=64- 6-7. Composition: nickel 28-40, arsenic 7034, (from Kamsdorf.) Often contains cobalt, and graduates into smaltine. It also sometimes contains iron, and this variety is the safflorite of Haidinger, or chathamite of Shepard. The ore from Chatham, Conn., affords 10 to 12 per cent. of nickel,! to 3 of cobalt, and 12 to 18 of iron. Found usually with smaltine at its various localities. Nickel glance is another arsenical ore, occurring in cubes and massive. Color silver-white to steel-gray. Contains 28 to 30 per cent. of nickel with arsenic and sulphur. H=5'5. Gr-6 1. From Helsingland, in Sweden, and also in the Hartz. Also at Schladming, in Austria, containing 38 per cent. of nickel, and having the specific gravity 6-6-6'9. This.ore has been called Gersdorfite. Nickel Stibine. An antimonial sulphuret, called sometimes Nickeliferous antimony ore, containing 25 to 28 per cent. of nickel. Color steel-gray, inclining to silver-white. In cubical crystals and also massive. H=5 —5'5. Gr=6'45. From the Duchy of Nassau. What is the crystallization and appearance of copper nickel? of what does it consist?. How is it distinguished from iron and cobalt pyrites how from silver ores? Where does it occur? 264 METALS. Antimonial nickel. Contains 29 per cent. of nickel and no sulphur. It has a pale copper-red color, inclining to violet. H=5'5 —6. Gr= 7'5. Crystals hexagonal. From the Andreasberg mountains. Nickel pyrites or capillary pyrites. A brass-yellow sulphuret ot nickel, occurring usually in delicate capillary forms; also in rhombohedral crystals. Gr=5'28. Contains 64'3 per cent. of nickel. From Bohemia, Saxony and Cornwall. Also occurs in needles at Antwerp, N. Y., and in Lancaster Co., Penn. The mineral has been named Millerite. A sulphuret of iron and nickel, of a light bronze-yellow, has been reported from southern Norway. It contains 22 per cent. of nickel. Gr-4'6. Granauite. Still another sulphuret, (called bismuth nickel,) contains 10 to 14 per cent. of bismuth, with 22 to 40'7 of nickel. Color light steel gray to silver-white; often tarnished yellowish. H=4-5. Gr=5'13. From the district of Altenkirchen, Prussia. Nickel green. An arsenate of nickel, containing 37-6 per cent. of oxyd of nickel. Color fine apple green. Occurs with other nickel ores in Dauphiny, Prussia, and elsewhere. It is found with copper nickel at Chatham, Conn. EMERALD NICKEL. Incrusting, minute globular or stalactitic. Color bright emerald green. Luster vitreous. Transparent or nearly so. H=3- 3-25. Gr-=25- 2-7. It is a carbonate of nickel, containing 28'6 per cent. of water. Infusible before the blowpipe alone, but loses its color. Obs. Occurs with chromic iron and carbonate of mag. nesia, on serpentine, in Lancaster county, Pennsylvania. An earthy oxyd of nickel and sulphuret occurs with black cobalt, at Mine la Motte, Missouri. Pimelite is a clay colored by green oxyd of nickel. Klaproth found 15'6 per cent. in one specimen. Quartz is sometimes colored by nickel. Chyroprase is a chalcedony thus colored. GENERAL REMARKS ON NICKEL AND ITS ORES. The nickel of commerce is obtained mostly from the copper nickel and chloanthite, or from an artificial product called speiss, (an impure arseniuret,) derived from roasting ores of cobalt with which arseniuretted nickel ores are mixed. The ores are nowhere very abundant, and the most productive are those of Saxony and Germany. Nickel also occurs in meteoric iron, forming an alloy with the iron, which is characteristic of most meteorites. The proportion sometimes amounts to 20 per cent. The great Texas meteorite, now in the Yale College collections, contains 8'8 to 9-7 per cent. of this metal. Nickel is obtained in the pure state from the speiss, by the following Describe the green hydrate of nickel. What is pimelite? What orea afford the nickel of commerce. Where else is it found? NICKEL O(EK.S. 265 process, proposed by WOhler: 1 part of the ore is fused with 3 of pearlash and 3 of sulphur. The arsenic forms a soluble compound with the sulphur and potash, and the nickel an insoluble sulphuret. This is well washed with water and dissolved in nitric acid; and the solution, after any lead, copper, or bismuth, that may be present, have been precipitated by a current of sulphuretted hydrogen, is precipitated by caustic or carbonated potash or soda. The washed precipitate i now acted on by an excess of oxalic acid, which forms with the peroxyd of iron, that is generally present, a soluble, and with the oxyd of nickel an insoluble, oxalate, which of course includes any cobalt that the ore may have contained. The oxalate is now dissolved in an excess of ammonia, and the solution exposed to the air. As the ammonia escapes, the nickel is deposited as an insoluble double oxalate, while the cobalt remains dissolved as a soluble double oxalate of the metallic oxyd with ammonia. The nickel salt, being ignited, leaves an oxyd which may be reduced by heating with charcoal; or it may be dissolved in acid and again converted into oxalate, which this time is free from cobalt and appears as an apple-green powder. The oxalate of nickel, being well washed, dried and ignited in a closed crucible, with an aperture for the escape of gas, leaves metallic nickel, which, if the heat be very intense, is fused to a button. Its color is between that of silver and tin. As nickel does not rust or oxydize, (except when heated,) it is superior to steel, for the manufacture of many philosophical instruments. An alloy of copper, nickel, and zinc, has been much used for various purposes, under the name of German silver, or argentane. Good German silver consists of copper 8 parts, nickel 3, zinc 3j. An inferior article is made of copper 8, nickel 2, zinc 3j. Below the proportion of nickel last stated, the alloy approaches pale brass and tarnishes readily, while the better kind has the appearance of silver, and retains well its polish. It is, however, easily distinguished from silver by a somewhat greasy feel. But " German silver" is not a very recent discovery. In the reign of William III, an act was passed making it felony to blanch copper in imitation of silver, or mix it with silver for sale. " White copper" has long been used in Saxony for various small articles; the alloy employed is stated to consist of copper 88-00, nickel 8'75, sulphur with a little antimony 0-75, silex, clay and iron, 1-75. A similar alloy is well known in China, and is smuggled into various parts of the East Indies, where it is called packfong. It has been sometimes identified with th( Chinese tutenague. M. Meurer analyzed the white copper of China, and found it to consist of copper 65'24, zinc 19-52, nickel 13, silver 2'5 with a trace of cobalt and iron. Dr. Fyfe obtained copper 40'4, nickel 31-6, zinc 25.4, and iron 2'6. It has the color of silver, and.s -emarkably sonorous. It is worth in China about one-fourth its weight of sil ver, and is not allowed to be carried out of the empire. Nickel alloyed with iron, as in meteoric iron, renders it less liable to rust;but with steel the tendency to rust is increased. Articles are now plated with nickel, by galvanic precipitation from the sulphate. How i.s nickel obtained from the ore? For what is nickel used? Whh.at is German silver? Wha is the Chinese packfong? 266 METALS. 18. COBALT. Cobalt has not been found native. The ores of cobalt having a metallic luster, vary in specific gravity from 6'2 to 7*2; and the color is nearly tin-white or pale steel-gray, inclining to copper-red. The ores without a metallic luster have a clear red or reddish color, and specific gravity of nearly 3. The ores are remarkable for giving a deep blue color to glass of borax, even when the proportion of cobalt is small. SMALTINE.-Tin-white Cobalt. Monometric. Occurs in octahedrons, cubes, and dodecahedrons, more or less modified. (See figs. 1, 2, 3, page 25, and 32, 37, page 36.) Cleavage octahedral, somewhat distinct. Also reticulated; often massive. Color tin-white, sometimes inclining to steel-gray. Streak grayish-black. Fracture granular and uneven. H=-5'3Gr=6'4- 72. Composition: essentially cobalt and arsenic; the cobalt varies from 18 to 23'5 per cent. and the arsenic from 69 to 79 per cent. A variety contains 9 to 14 per cent. of cobalt and is called radiated white cobalt; another variety contains iron. See further, Chloanthite. Gives off arsenical fumes in a candle. Colors borax and other fluxes blue, and affords a pink solution with nitric acid. Dif. The arsenical cobalts are at once distinguished from mispickel or white iron pyrites, by the blue color they give with borax; and also by their crystals and specific gravity. Obs. Usually in veins with ores of cobalt, silver, and copper. Occurs in Saxony, especially at Schneeberg; also in Bohemia, Hessia, and Cornwall. In the United States it is found in gneiss with copper nickel, at Chathan, Conn. Cobaltine. This is another arsenical ore of cobalt, containing sulphur as well as arsenic. Color silver-white, inclining to red. Contains 33 to 37 per cent. of cobalt. Forms of crystals, figures 42, 46, page 37. From Sweden, Norway, Siberia, and Cornwall. The most What is said of the ores of cobalt? Describe tin-white cobalt What is its composition? its blowpipe characters? How is it distil guished from mispicke) and white iron pyrites? COBALT ORES. 26" productive mines are those of Wehna, in Sweden. which were first opened in 1809. Cobalt pyrites is a sulphuret of cobalt, of a pale reddish or steel-gray color. H=5'5. Gr=6'3-6-4. Crystals cubic. From Sweden. and also Prussia; also Mine La Motte, Missouri. Named Linneite. Another sulphuret of cobalt, with a less proportlon of sulphur thar in the last, has been observed in Hindostan. Color steel-gray, a little yellowish. Named Syepoorite. EARTHY COBAL'r. —Black oxyd of Cobalt. Earthy, massive. Color black or blue-black. Soluble in muriatic acid, with an evolution of fumes of chlorine. Obs. Occurs in an earthy state mixed with oxyd of manganese, and in Missouri has been mistaken for black oxyd of copper. It is quite abundant at Mine La Motte, Missouri. and also near Silver Bluff, South Carolina. The analyses vary in the proportion of oxyd of cobalt associated with the manganese, as the compound is a mere mixture. Sulphuret of cobalt occurs with the oxyd. The Carolina ores afforded Dr. J. L. Smith, oxyd of cobalt 24, oxyd of manganese 76. The ore from Missouri, as analyzed by Prof. Silliman, Jr., afforded 40 per cent. of oxyd of cobalt, with oxyds of nickels manganese, iron and copper. It has also been detected with hematite, in Chester Ridge, Pa. This ore has been found abroad in France, Germany, Austria, and England, but much of it contains very little oxyd of cobalt. Uses. The ore of Missouri is exported to England in large quantities, and there purified and made into smalt, for the arts. BRYTHRINE.-COBALT BLOOM.-Arsenate of Cobalt. Monoclinic. In oblique crystals having a highly perfect cleavage and foliated structure like mica. Laminae flexible in one direction. Also as an incrustation, and in reniform shapes, sometimes stellate. Color peach and crimson red, rarely grayish or greenish; streak a little paler, the powder dry lavender blue. Lus. ter of laminae pearly; earthy varieties without uster. Transparent to subtranslucent. H = 15-2. Gr=2'95. Composition: oxyd of cobalt 37'6, arsenic acid 38'4, wa. What is said of the black oxyd of cobalt? What is the appearanc< and stnicture of cobalt bloom? of what does it consist? 268 XMTALS. ter 24*0. Gives arsenical fumes when heated, and fists; yields a blue glass with borax. The earthy ore is sometimes called peach blossom ore, from its color; and also red cobalt ochre. Dif. Resembles red antimony, but that species wholly volatilizes before the Blowpipe. From red copper ore it dif. fers in giving a blue glass with borax; moreover the color of the copper ore is more sombre. Obs. Occurs with ores of lead and silver, and other co. bait ores. Schneeberg, in Saxony, Saalfield in Thuringia. and Riechelsdorf, in Hessia, are noted European localities It is found also in Dauphiny, Cornwall, and Cumberland Occurs in the U. States, at Mine La Motte, Missouri. Uses. Valuable as an ore of cobalt, when abundant. Roselite. A rose-red mineral, related to, if not identical with, cobalt bloom. Arsenite of cobalt is a compound of arsenous acid and oxyd of cobalt, and results from the decomposition of other cobalt ores. Sulphate of cobalt, or Cobalt vitriol. It has a flesh or rose-red tint, and astringent taste. Consists of sulphuric acid, oxyd.of cobalt and water. GENERAL REMARKS ON COBALT AND ITS ORES. The two arsenical ores of cobalt afford the greater part of the cobalt of commerce. The earthy oxyd is so abundant in the United States, that it promises to be a profitable source of this metal. Cobalt is never employed in the arts in a metallic state, as its alloys are brittle and unimportant. It is chiefly used for painting porcelain and pottery, and is required for this purpose in the state of an oxyd, or the silicated oxyd called smalt and azure. Cobalt comes from Germany mostly in the silicated condition. The zaffre is prepared by calcining the ores of cobalt in a reverberatory furnace; the sulphur and arsenic are thus volatilized, and an impure oxyd remains, which is next mixed and heated with about twice its weight of finely powdered flints. By another process the ore is pulverized and roasted, to expel the greater part of the arsenic; a sulphate is then formed by heating for an hour with concentrated sulphuric acid The sulphate is dissolved in water, and a solution of carbonate of potash added to separate the iron; and when the blue color of the cobalt begins to be thrown down, the mupernatant liquid is decanted and filtered, and the cobalt is precipitated iy means of a solution of silicated potash, (prepared by heating together 10 parts of potash, 15 of finely pulverized quartz, and 1 of charcoal, and afterwards treating the melted mass with boiling water.) The silicate of cobalt thus prepared is said to be superior to that procured How does cobalt bloom differ from red antimony? From what ores is the cobalt of commerce obtained? For what is cobalt used? In what condition is it imported from Germany? What is zaffre I M, TA LS. 269 in any other way, for staining porcelain, or for the manufacture of blue glass. Snmalt and azure, which have a rich blue color, are made by fusing zatile with glass; or by calcining a mixture of equal parts of roasted cobalt ore, common potash, and ground glass. The zaffre is used for coloring glass, and for painting enamel and pottery ware. The arsenic volatilized in the above process is condensed in chambers; it constitutes the greater part of the arsenic of commerce. The separation of the nickel from ores rich in this metal, is sometimes effected by exposing the moistened ore to the atmosphere. The nickel is unaltered, while the other metals are oxydized. The annual yield of zaffre or smalt, in Saxony, amounts to 80();i cwt.; in Bohemia, mainly from Schlackenwald, 4000 cwt.; in tit Reisengebirge, in Prussia, 600 cwt.; at Kongsberg, in Norwa) 4000 cwt. 19. ZINC. Zinc occuis in combination with sulphur, oxygen, silica, carbonic acid, and sulphuric acid. It is also found in combination with alumina, constituting one variety of the species spinel. The ores of zinc are infusible, or very nearly so; hut they yield on charcoal, with more or less difficulty, white fumes of the oxyd of zinc. Specific gravity below 4*5. BLENDES.-Sulphuret of Zinc. Monometric. In dodecahedrons, octahedrons, and other allied forms, with a perfect dodecahedral cleavage. Also I massive; sometimes fibrous. 2 Color wax-yellow, brownishU&s',\ yellow, to black, sometimes green \ or red; streak white, to red- \Ic>/ / dish-brown. Luster resinous or \S /' waxy, and brilliant on a cleavage face; sometimes submetallic.Transparent to subtranslucent. Brittle. H =3'5-4. Gr-= 4-0-4-1. Some specimens become electric with friction, and give off a yellow light when rubbed with a feather. Composition: zinc 66-72, sulphur 33-28. Contains fiequently a portion of sulphuret of iron when dark colored: What are smalt and azure? How are they used in porcelain painting? What is said of the ores of zinc? What is the crystallization of blende. What are its lut.,'r, clor, and other physical characters l Of what does it consist I often also 1 or 2 per cent. of sulphuret of cadmium, espe cially the red variety. Itlulsible alone and with borax Dissolves in nitric acid, emitting sulphuretted hydrogen Strongly heated on charcoal yields fumes of zinc. Dif. This ore is" characterized by its waxy luster, per. fect cleavage, and infusibility. Some dark varieties look a little like tin ore, but their cleavage and inferior hardness distinguish them; and some clear red crystals which re. semble garnet are distinguished by the same characters and also by their infusibility. Obs. Occurs in rocks of all ages, and is associated generally with ores of lead; often also with copper, iron, tin, and silver ores. The lead mines of Missouri and Wisconsin, afford this ore abundantly. Other localities are in Maine, at Lubec, Bingham, Dexter, Parsonsfield; in New Hampshire, at Eaton, Warren, Haverhill, Shelburne; in Vermont, at Thetford; in Massachusetts, at Sterling, Southampton, and Hatfield; in Connecticut, at Brookfield, Berlin, Roxbury, and Monroe; in New York, at the Ancram lead mine, the Wurtzboro lead vein, at Lockport, Root, 2 miles s. E. of Spraker's basin, in Fowler, at Clinton; in Pennsylvania, at the Perkiomen lead mine; in Virginia, at Austin's lead mine, Wythe county; in Tennesse, near Powell's River, and at Haysboro. This ore is the Black Jack of miners. Uses. Blende is a useful ore of zinc, though more difficult of reduction than calamine. By its decomposition, (like that of pyrites,) it affords sulphate of zinc or white vitriol. ZINCITE.-RED ZINC ORE.-Red oxyd of zinc. Trimetric., Usually in foliated masses, or in disseminated grains; cleavage eminent, nearly like that of mica, but the laminae brittle, and not so easily separable. Color deep or bright red; streak orange-yellow. Luster brilliant, subadamantine. Translucent or subtranslucent H-=4 —45. Gr-=54-5'56. Thin scales by transmitted light deep yellow. Composition: zinc 80-3, oxygen 19'7=100. Infusible What is the action of zinc blende before the blowpipe? How is it distinguished H Fow does it occur? What is the appearance of red zinc ore? its cornpostion? ZINC ORES. 271 alone, Iut yields a yellow transparent glass with borax. Dis. so!ves in nitric acid, without effervescence. Dif. Resembles red stilbite, but distinguished by its in fusibility and also by its mineral associations. ()bs. Occurs with Franklinite at Franklin and Sterling, N. J. Uses. A good ore of zinc when abundant, and easily reuced. It may be readily and economically converted into ulphate of zinc, or white vitriol. Voltzite. A compound of sulphuret and oxyd of zinc. Occurs in mplanted globules of a dirty rose-red color, with a pearly luster on n leavage surface. From France. GO8LARITE.-,SULPHATB OF ZINC.- White Vitriol. Trimetric. Cleavage perfect in one direction. Crystals rhombic prisms, of 90~ 42'. Color white. Luster vitreous. Easily soluble; taste astrilgent metallic, and nauseous. Brittle. H-=2 —25.Gr=1 9- 2 1. Composition: oxyd of zinc 28O09, sulphuric acid 27'97, water 43*94. Gives off fumes of zinc when heated on charcoal, which cover the coal. Obs. Results fiom the decomposition of blende. Occurs in the Hartz, in Hungary, in Sweden, and at Holywell in Wales. Uses. Sulphate of zinc is extensively employed in medicine and dyeing. For these purposes it is prepared to a large extent from blende, by decomposition like pyrites, though this affords, owing to its impurities, an impure sulphate. It is also obtained by direct combination of zinc with sulphuric acid; zinc is exposed to the action of dilute sulphuric acid, and the solution obtained is then evaporated for crystallization. The red oxyd of zinc, of New Jersey, may become an abundant source of this salt. White vitriol, as the term is used in the arts, is one form of sulphate of zinc, made by melting the crystallized sulphate, and agitating till it cools and presents an appearance like loaf sugar. How does it differ from red stilbite? For what may it be usPd? What is the appearance and taste of white vitriol? Of what does ix ansist? How is it formld? For what is it used? Z'i2 r'TA\ LS. MITHSONI rE. —Carbonate of Zinc. Rhombohedral. R: R =107 40. Cleavage rhomb, hedral, perfect. Massive or incrusting; reniform and stal. actitic. Color impure white, sometimes green or brown; streak uncolored. Luster vitreous or pearly. Subtransparent to translucent. Brittle. H= 5. Gr = 43-445. Composition: oxyd of zinc 64'54, (four-fifths of which is pure zinc,) and carbonic acid 35'46. Often contains some cadmium. Infusible alone before the blowpipe, but carbonic acid and oxyd of zinc are finally vaporized. Effervesces in nitric acid. Negatively electric by fiiction. Dif. The effervescence with acids distinguishes this mineral from the following species; and the hardness, difficult fusibility, and the zinc fumes before the blowpipe, from the carbonate of lead or other carbonates. Obs. Occurs commonly with galena or blende, and u;ually in calcareous rocks. Found in Siberia, Hungary, Silesia; at Bleiberg in Carinthia; near Aix-la-Chapelle in the Lower Rhine, and largely in Derbyshire and elsewhere in England. In the United States, it is abundant at Vallee's Diggings in Missouri, and at other lead " diggings" in Iowa and Wisconsin; also in Claiborne county, Tenn. Sparingly also at Hamburg, near the Franklin furnace, N. J.; at the Perkiomen lead mine, Pa., and at a lead mine in Lancaster county; at Brookfield, Conn. Zinc bloom is an earthy carbonate of zinc, containing 69 per cent. of oxyd of zinc, and 15 of water. From Bleiberg, Carinthia. cALAMINB.-Silicate of zinc. Trimetric. In modified rhombic prisms, the opposite ex tremities with unlike planes. M: M =103' 54'. Cleavage perfect parallel to M. Also massive and incrusting, mammillated or stalactitic. Color whitish or white, sometimes bluish, greenish, oi brownish. Streak uncolored. Transparent to translucent. Luster vitreous or subpearly. Brittle. H-=45 —5. Gr= 3'35 —349. Pyro-electric. What is the usual appearance of calamine? What is its constitution and the effects before the blowpipe? What effect is produced by fric. tion? What are distinguishing characteristics? How does it occur What is electric calamnire? 22 ZINC ORBS. 273 Composition: silica 25'1. oxyd of zinc 67'4, water 7'5. Before the blowpipe it slowly intumesces and emits a green phosphorescent light; but alone it is infusible. Forms a clear glass with borax. In heated sulphuric acid it dissolves, and the solution gelatinizes on cooling. Dif. Differs from carbonate of lime or aragoniite by its action with acids; from a salt of lead or any zeolite, by its infusibility; from chalcedony, by its inferior hardness and its gelatinizing with heated sulphuric acid. Obs. Occurs with calamine. rn the United States, it is found at Vallee's Diggings, at the Perkiomen lead mines on the Susquehanna, opposite Selimsgrove, and abundantly at Austin's mines, Wythe county, Va., and Friedersville, Pa. Uses. Valuable as an ore of zinc. Willemite is an anhydrous silicate of zinc, of a vllowish or brownish color. H=5-.5-5 Gr=-4 —41. Occurs in large grayish hexagonal prisms with rhombohedral terminations, at Stirling Hill, N. J., being the mineral formerly called Troostite. Consists of silica 27 15, and oxyd of zinc 72-85. Also obtained at Moresnet in Belgium. Hopeite is a rare mineral occurring in grayish-white crystals or massive, with calamine, and supposed to be a plosphate of zinc. Franklinite, an ore of iron, manganese and zinc, is described under Iron, on page 240( Aurichalcite is a hydrous carbonate of zinc and copper, occurring in drusy incrustations of acicular crystals, having a verdigris green color. From Siberia, Hungary, England, and Lancaster, Pa. GENERAL REMARKS ON ZINC AND ITS ORES. The metal zinc (spelter of commerce) is supposed to have been unknown in the metallic state to the Greeks and Romans. It has been long worked in China, and was formerly imported in large quantities by the East India Company. The ores from which it is obtained are the carbonate and silicate of zinc, (calamine and electric calamine,) and to some extent the sulphuret, (blende,) and the oxyd. Blende, the black jack of English miners, was considered useless until the year 1738, when a mode of reducing it was introduced. The principal mining regions of zinc in the world are in Upper Silesia at Tarnowitz and elsewhere; in Poland; in Carinthia at Raibel and Bleiberg; in Netherlands at Limberg; at Altenberg, near Aix-la-Chapelle in the Prussian province of the Lower Rhine; in England, in Derbyshire, Alstonmoor, Mendip Hills, etc.; in the Altai in Russia; besides others in China, of which little is known. In the United States, the calamine find electric calamine occur with the lead of the west in large How is electric calamine distinguished from calc spar and chalcedony t From what ores is the metal zinc obtained? What is zinc called in commerce? When was blende first used in England? Where are zinc mines in the United States? 274 METALS. quantities, and till a recent period were considered worthless and thrown aside under the name of "' dry bone." In Tennessee, Claiborne county, there are workable mines of the same ores. Calamine is successfully worked at Friedersville, Pennsylvania. The red oxyd of zinc of Franklin, Nowv Jersey, contains 75 per cent. of pure zinc, and the ore is a valuable one. Blende is sufficiently abundant to be worked at the Wurtzboro' lead mine, Sullivan county, N. Y.; at Eaton and Warren in New Hampshire; at Lubec in Maine; and at Austin's mine, Wythe county, Virginia. The calamine and electric calamine are prepared for reduction by oreaking the ore into small fragments, separating the impurities as far as possible, and then calcining in a reverberatory furnace. This furnace differs little from that figured on a following page under Silver, except that the sole is flat. The ore is frequently stirred, and after five or six hours it is taken out; by this process, water and carbonic acid are expelled. The prepared ore is then mixed with about one-seventh by weight of charcoal, and in the English process, is reduced in large crucibles. Figure 1, represents a vertical section of the furnace, and figure 2, 1 half of a horizontal section across the line 1, 2. The oven has an arched or cupola top, (a,) and contains 6 or 8 crucibles or pots, (h, h, h, h,) 2 7 7 placed upon the sole of the earth, (i, i, i, i.) The crucibles have a holt How is calamine reduced? ZINC ORES. 275 at bottom, to which a sheet iron tube (k) is adapted, which tube extent down to small vessels of water, or condensers, (1, 1); and the sole of the hearth is perforated accordingly below each crucible. If one of the tubes becomes clogged with metal, it is cleared by a hot iron bar. In charging, the hole in the bottom of the crucible is stopped by a wooden plug, which afterwards becomes reduced to charcoal by the heat. The pots are charged and cleared out through holes (d, d, d, d) in the cupola (a.) The covers (of fire-tile, m) are placed on whenever a blue flame begins to appear, as this indicates the vaporization of the zinc. The fire is made on the grate e, through the door f; g is the ash-pit below; m, m, m, m, in figure 2, show the position of the pots as seen in a bird's-eye view. The smoke escapes from the oven by the apertures d, (fig. 1,) into a conical chimney, (b,) by which a strong draught is kept up. In this chimney there are as many doors (c, c, c, c) as there are pots; and in the cupola there are the same number of openings for inserting or removing the pots, which are afterwards closed up by brickwork; the pots are many times refilled without removal. The refuse after an operation, is shaken out through the hole in the bottom of each pot, after the tube k is removed. The zinc as it is reduced, rises in vapor and passes down the tubes into the condensers, where it collects in drops or powder with some oxyd; the metal is afterwards melted and cast into bars; and the oxyd which is skimmed off is returned to the crucibles. A charge occupies about three days, and the ore affords from 25 to 40 per cent. of zinc. In Liege, where the ore from Altenberg is reduced, the ore is heated in horizontal earthen tubes, 3 feet long and 4 to 6 inches in diameter set thickly across a furnace, and around which the heat circulates. From the description given, it is obvious how the process might be varied, and larger combinations of pots or tubes arranged. The blende is roasted in a reverberatory furnace, 8 or 10 feet square, the ore being placed in the furnace several inches deep, and kept constantly stirred for 10 or 12 hours. The roasted ore is then reduced in crucibles in the same manner as above explained. In England, the roasted blende is mixed with as much calcined calamine and twice the quantity of charcoal. The annual production of zinc in different countries is as follows: Great Britain,..1,000 tons. Upper Silesia and Poland,.. 36,000 " Belgium,.. 16,000" Carinthia,...... 1,500 " United States,... 5,000 " Brass is made directly from the ore by heating copper with calcineu calamine and charcoal. At Holywell, England, 40 pounds of copper and 60 of calamine yield about 60 pounds of bras3. It is also made from copper and roasted blende, but the product is less pure. Dr. Jack~rn states that he has obtained brass of an inferior quality by heating ogether in a crucible copper pyrites and blende after roasting them. Brass is commonly made in this country by melting together the metals inc and copper. How is blende reduced? How is brass made? 276 METALS. The proportions of zinc in its alloys with copper are given in the remarks on copper. Zinc is a brittle metal, but admits of being rolled into sheets when heated to about 212~ F. In sheets it is extensively used for rxofing and other purposes, it being of more difficult corrosion, much harder, and also very much lighter than lead. Its combustibility is a strong objection to it as a roofing material. The biddery ware of the East Indies is made from an alloy of coppet 16oz., lead 4oz., and tin 2oz., which is melted together and then mixed with l6oz. of spelter to every 3oz. of alloy. The white oxyd of zinc is much used for white paint, in place of white lead. An impure oxyd of zinc called cadmia, often collects in large quan tities in the flues of iron and other furnaces, derived from ores of zin mixed with the ores undergoing reduction. A mass weighing 600 pounds was taken from a furnace at Bennington, Vt. It has been ob served in the Salisbury iron furnace, and at Ancram in New Jersey, where it was formerly called ancramite. 20. CADMIUM. There is but a single known ore of this rare metal. It is a sulphuret, and is called greenockite. It occurs in hexagonal prisms, with pyramidal terminations, of a yellow color high luster, and nearly transparent. H =3-3 5. Gr= 4'8 —49. From Bishopton, Scotland. Cadmium is often associated in small quantities with zinc blende and calamine. In a black fibrous blende from Przi bram, L6we found 1-5 to 1'8 per cent. 21. LEAD. Lead occurs rarely native; generally in combination with sulphur; also with arsenic, tellurium, selenium, and various acids. The ores of lead vary in specific gravity from 5-5 —82. They are soft, the hardness of the species with metallic lus. ter not exceeding 3, and others not over 4. They are easily fusible before the blowpipe, (excepting plumbo-resinite); and with carbonate of soda on charcoal, (and often alone,) malleable lead may be obtained. The lead often passes off in yellow fumes, when the mineral is heated in the outer flame. or it covers the charcoal with a yellow coating. Where have we the first notice of the metal bismuth? From what source is it obtained for the arts? What is it often called in the arts How is the metal obtained? For what is bismuth used? How does lead occur in nature? What is said of the tests? LEAD ORES. 277 NATIVE LEAD. A rare mineral, occurring in thin laminae or globules Gr=11'35. Said to have been seen in the lava of Madeira at Alston in Cumberland with galena; in the county of Kerry, Ireland; and in an argillaceous rock at Carthagena. GALENA. —Sulphuret of Lead.. Monometric. Cleavage cubic, eminent. Occurs under the form of the cube and its secondaries. Cleavage cubic, perfect, and very easily obtained. Also coarse or fine granular; rarely fibrous. Color and streak lead gray. Luster shining metallic. Fragile. H =2-5. Gr=7.5-7 7. Composition: when pure, lead 86-55, sulphur 13'45. Often contains some sulphuret of silver, and is then called argentiferous galena, and at times sulphuret of zinc is present. Before the blowpipe on charcoal, it decrepitates unless heated with caution, and fuses, giving off sulphur, and finally yields a globule of lead. Dif. Galena resembles some silver and copper ores in color, but its cubical cleavage, or granular structure when massive, will usually distinguish it. Its sulphur fumes obtained before the blowpipe prove it to be a sulphuret; and the lead reaction before the blowpipe show it to be a lead ore. Obs. Galena occurs in granite, limestone, argillaceous and sandstone rocks, and is often associated with ores of zinc, silver and copper. Quartz, heavy spar, or carbonate of lime, is generally the gangue of the ore; also at times fluor spar. The rich lead mines of Derbyshire and the northern districts of England, occur in mountain limestone; and the same rock contains the valuable deposits of Bleiberg Where has native lead been found? What is the structure of galena its physical characters? its composition and blowpipe characters How is it distinguished from silver and copper ores? Where does it occur? 274 M F'TALS. and the neighboring deposits of Carinthia. At Freiberg in Saxony, it occupies veins in gneiss; in the Upper Hartz, and at Przibram in Bohemia, it traverses clay slate; at Sahla, Sweden, it occurs in crystalline limestone; the ore of Lead. hills, England, is in graywacke. There are other valuable beds of galena, in France at Poullaouen and Huelgoet, Brittany, and at Villefort, department of Lozere; in Spain in the granite hills of Linares, in Catalonia, Grenada and else-where; in Savoy; in Netherlands at Vedrin, not far from Namur; in Bohemia, southwest of Prague; in Joachimstahl, where the ore is worked principally for its silver; in Siberia in the Daouria mountains in limestone, argentiferous and worked for the silver. The deposits of this ore in the United States are remarkable for their extent. They abound in what has been called " cliff limestone," in the states of Missouri, Illinois, Iowa, and Wisconsin; argillaceous iron, iron pyrites, calamine, ("dry bone" of the miners,) blende, (" black jack,") carbonate and sulphate of lead, are the most common associated min. erals, together often with ores of copper and cobalt. In 1720, the lead mines of Missouri were discovered by Francis Renault and M. La Motte; and the La Motte mine is still known by this name. Afterwards, the country passed into the hands of the Spaniards, and during that period a valuable mine was opened by Mr. Burton, since called 1Mine i Burton. The mines of Missouri are contained in the counties of Washington, Jefferson, and Madison. The lead region of Wisconsin, according to Dr. D. D. Owen, comprises 62 townships in Wisconsin, 8 in Iowa, and 10 in Illinois, being 87 miles from east to west, and 54 miles from north to south. The ore, as in Missouri, is inexhaust. ible, and throughout the region, there is scarcely a square mile in which traces of lead may not be found. The principal indications in the eyes of miners, as stated by Mr Owen, are the following: fragments of calc spar in the soil, unless very abundant, which then indicate that the vein is wholly calcareous or nearly so; the red color of the soil on he surface, arising from the ferruginous clay in which the ead is often imbedded; fragments of lead (" gravel mineral,") long with the crumbling magnesian limestone, and dendritic pecks distributed over the rock; also, a depression of the What is said of the extern of the United States mines? L.EAD OE.S. 279 country, or an elevation, in a straight line; or " sinkholes;" o: a peculiarity of vegetation in a linear direction. The diggings" seldom exceed 25 or 30 feet in depth; for the galena is so abundant that a new spot is chosen rather than the expense of deeper mining. From a single spot, not exceeding 50 yards square, 3,000,000 lbs. of ore have been raised; and at the diggings in the west branch of the Pecca tonica, not over 12 feet deep, two men can raise 2000 lbs. per day; in one of the townships, two men raised 16,000 lbs in a day; 500 lbs. is the usual day's labor from the mines of average protuctiveness. Galena also occurs in the region of Chocolate river and elsewhere, Lake Superior copper region; at Cave-in-Rock in Illinois, along with fluor; in New York at Rossie, St. Lawrence county, in gneiss, in a vein 3 to 4 feet wide; neat Wurtzboro' in Sullivan county, a large vein in millstone grit; 1, Ancram, Columbia county; Martinsburg, Lewis county, N. Y., and Lowville, are other locali'ies. All these mines have been worked, but they are now abandoned. Dr. Beck siys of the Sullivan couny and St. Lawrence mines, "in the latter the ore is in small vei;s with gooi associates, and i; easily reduced; but the situation of the mines is bad. In the former, the ore is in large veins with bad associates, (zinc blende,) and is more difficult of separation and reduction; but the mines are admirably situated whether we regard the removal of the ore or the facility of transporting produce to them." In Maine, veins of considerable extent occur at Lubec; also of less interest at Blue Hill Bay, Birmingham and Parsonsfield. In New Hampshire, galena occurs at Eaton, Bath, Tamworth and Haverhill. In Vermont, at Thetford; in Massachusetts, at Southampton, Leverett, and Sterling, but without promise to the miner. In Virginia, in Wythe county, Louisa county, and elsewhere. In North Carolina, at King's mine, Davidson county, where the lead appears to be abundant. In Tennessee, at Brown's creek, and at Hays. boro', near Nashville. An argentiferous variety occurs sparingly at Monroe, Conn., which afforded Prof. Silliman 3 per cent. of silver; also at Middletown, Ct. Uses. The lead of commerce is obtained from this ore. It is often worked also for the silver it contains. It is also employed in glazing common stone ware: for this purpose Jt is ground up to an impalpable powder and mixed in watei 280 METALS. with clay; into this liquid the earthen vessel is dipped a._ then baked. Cuproplumbite is a galena containing 24-5 per cent. of sulphuret:f copper. From Chili. \ARSENURETS, SELENIDS, AND TELLURIDS OF LEAD. These various ores of lead are distinguished by the fumes before the blowpipe, and by yielding ultimately a globule of lead. Cobaltic lead ore is an arseniuret of lead, containing a trace of cobalt From the Hartz. Gives an alliaceous odor (from the arsenic) befor the blowpipe. Gr=8'44. Dufrenoysite is an arseniuret and sulphuret of lead; in dodecahe drons of a dark steel-gray color. Gr=5-55. From the Dolomite of St Gothard. Clausthalite, or selenid of lead, has a lead-gray color, and granular fracture. Gr=7'19. Gives a horse-radish odor (that of selenium) before the blowpipe. From the Hartz. There are three selenids of lead and copper which give the reaction of all the different constituents before the blowpipe. The sp. gr. of one is 56; of the second 70; the third 7-4. From the Hartz. There is also a selenid uf lead and mercury occurring in foliated grains or masses, of a lead-gray to bluish and iron-black color. Tellurid of lead. This is a tin-white cleavable mineral. Gr=8'16. From the Altai mountains. Foliated tellurium is a less rare species, remarkable for being foliated like graphite. Color and streak blackish lead-gray. H=1-1-5. Gr=7-085. It contains tellurium 32-2, lead 54-0, gold 9-0, with often silver, copper, and some sulphur. From Transylvania. iMINIUM.-Oxyd of Lead. Pulverulent. Color bright red, mixed with yellow. Gr= 4'6. It is a sesquioxyd of lead. Affords globules of lead in the reduction flame of the blowpipe. Obs. Occurs at various mines, usually associated with galena, and is found abundantly at Austin's mines, Wythe county, Virginia, with white lead ore. Uses. Minium is the red lead of commerce: but for the arts it is artificially prepared. Lead is calcined in a reverberatory furnace, and a yellow oxyd (massicot) is thus formed: the massicot is afterwards heated in the same fur. nace in iron trays, at a low temperature, by which the lead absorbs more oxygen and becomes red lead. A much better material is obtained by the slow calcination of white lead. Plumbic ocher is another similar ore, of a yellow color; it is a pro toxyd of lead. Occurs in Wythe county, Va., also in Mexico. What is minium? What are its characters? LEAD ORES. 281 ANGLESITE. —Sulphate of Lead. Primary form a right rhombic prism, with imperfect lat eral cleavage. M: M=103' 38'. Often in slender im planted crystals. Also massive; lamellar or granular. Color white or slightly gray or green. Luster adamank. tine; sometimes a little resinous or vitreous. Transparent to nearly opaque. Brittle. H=-275-3. Gr=6'25-6-3 Composition: a sulphate of lead, containing about 73 pei cent. of oxyd of lead. Fuses before the blowpipe'o a slag and yields lead with carbonate of soda. Dif. Resembles somewhat some of the zeolite minerals, and also arragonite and some other earthy species; but thit and the other ores of lead are at once distinguished by spe. cific gravity, and also by their yielding lead in blowpipe trials. Differs from the carbonate of lead in not dissolving with effervescence in nitric acid. Obs. Usually associated with galena, and results from Its decomposition. Occurs in fine crystals at Leadhills and Wanlockhead, Great Britain, and also at other foreign lead mines. In the United States, it is found at the lead mines of Missouri and Wisconsin; in splendid crystallizations at Phenixville, Pa.; sparingly at the Walton gold mine, Louisa county, Va.; at Southampton, Mass. Cupreous anglesite. A hydrous azure-blue sulphate of lead and copper. It is remarkable for a very perfect cleavage in one direction, anid another inclined to the first 102~ 45'. Gr-5'3 5-5. From Leadhills and Roughten Gill, England. Very rare. CIu USITE.t —WHITE LFAD ORE.-Carbonate of Lead. Trimetric. In modified right rhombic prisms. M: M= 1 2 3 a / 117~ 13'. M: 6=121' 24; a: a=1400 15'. Often in What is the appearance of anglesite? its composition? How is it distinguished from arragonite and the zeolites? What is the crystalization of white lead cre? )2i2 METALS. compound crystals, either six-sided prisms like aragonlte, or wheel-shaped groups of 4 or 6 rays (fig. 3.) Also massive rarely fibrous.. Color white, grayish, light or dark. Luster adamantine. Brittle. H-3 3-5. Gr=6-46-6-48. Composition: oxyd of lead 83-46, carbonic acid 16-54 Decrepitates-before the blowpipe, fuses, and with care af. fords a globule of lead. Effervesces in dilute nitric acid. Dif. Like anglesite, distinguished from most of the species it resembles by its specific gravity and yielding lead when heated. From anglesite it differs in giving lead alone before the blowpipe, as well as by its solution and effervescence with nitric acid, and its less glassy lustre. Obs. Associated usually with galena. Leadhills, Wanlockhead, and Cornwall, have afflrded splendid crystallizations; also other lead mines on the continent of Europe. In the United States, very handsome specimens are obtained at Austin's mines, Wythe county, Virginia, and at King's mine in Davidson's county, North Carolina. At the latter place it constitutes a wide vein, and has been worked for lead. It is associated with native silver and phosphate of lead. Perkiousiti aid iiie.a. Pi)t., a.fftli good crystals. It occurs also at " Vall(e's Diggings," Jefferson county, Missouri; at Brigham's mine near the Blue Mounds. Wisconsin; at "Deep Diggings" in crystals; and at other places in the West. both massive and in fitne crystallizations. Rossie, N. Y., and Southampton, Mass., have afforded this ore. Uses. When abundant,thisore is wrought forlead. Large quantities occur about the mines of the Mississippi valley. It was formerly buried up in the rubbish as useless, but it has since been collected andt smelted. It is an exceedingly rich ore, affording in the. pure state 75 per cent. of lead. Carbonate of lead is the " white lead" of commerce, sc extensively used as a paint. The material for this purpose is, however, artificially made. In most manufacturing establishments, sheets of lead are suspended over a liquid made of vinegar and wine lees, and a gentle heat is applied either What are the color and luster of white lead ore? its composition and blowpipe reaction? How is it distinguished from anglesite? How from minerals not lead ores? What use is made of white lead? How is white lead manufactured? by stoves or fiom fermenting bark the result is that the lead becomes carbonated from the acid fumes that rise fronm be neath.* The carbonate is then removed by shaking the plates smartly, and after washing and levigation, it is dried for market. According to another good process, (Thenard's,) carbonic acid, either from burning coke, brewers' vats, oi some other source, is made to pass through a solution of sub. acetate of lead, the solution of subacetate being formed by digesting litharge and neutral acetate of lead. In place of this solution, litharge moistened slightly with vinegar, has been proposed. In the processes in the arts more litharge is made than is demanded in trade, and this use of it is considered more economical than its reduction to lead. Carbonate of lead, mixed with sulphate of barytes, forms what is called Venice white. Carbonate and sulphate of lead. There are tworwhitish or grayish ores of this composition called dioxylite and leadhillite, or respectively sllphato-:arbonate and sulphato-tricarbonate of lead. The former contains 71 per cent. of carbonate of lead; the latter 47. Dioxylite has a perfect basal cleavage. Gr=6'2-6'5. Leadhillite cleaves into lalnina that are flexible like gypsum. Gr=6'8-7. From Leadhills. Caledonite is a compound of the carbonates of lead and copper and srslphate of lead, and is called the cupreous sulphato-carbonate of lead. In crystals of a deep verdigris or bluish green color. Gr=6-4. From Leadhills and Red Gill; also from the Missouri mines. PYROMORPHITE.-Phosphate of Lead. Primary form, a hexagonal prism. Cleavage lateral, in traces. Usual in clustered hexagonal prisms, /M.! forming crusts. Also in globules, or reniform, Mi i with a radiated structure. Color bright green or brown; sometimes fine orange-yellow, owing to an intermixture withi chromate of lead. Streak white or nearly so. Luster more or less resinous. Nearly transparent to subtranslucent. Brittle. H=3'5 —4. Gr=6_ 5-7-71. Composition of a brown variety: oxyd of lead 78-58, mu. riatic acid 1'65, phosphoric acid 19-73. Before the blow. pipe on charcoal fuses, an: on cooling, the globule becomes Describe pyromorphite. Of what does it consist? * A subacetate is supposed to form first, and then to be immediately decomposed by tne rising carbonlc ac.d. ,c I METALS. angular. In the inner flame, gives off fumes of lead. With boracic acid and iron, gives a phosphuret of iron and metallic lead. Dif. Has some resemblance to beryl and apatite; but is quite different in its action before the blowpipe, and much higher in specific gravity. Obs. Leadhills, Wanlockhead, and other lead mines of Europe are foreign localities. In the United States, very handsome crystallized specimens occur at King's mine in Davidson county, N. C.: other localities are the Perkiomen an,!d Phei'ville mines, Pa.: the Lubec lead mines, Me.; Lenox, N. Y.; formerly, a mile south of Sing Sing, N. Y.; and the Southampton lead mine, Mass. The name pyromorphite is from the Greek pur, fire, and morphe, form, alluding to its crystallizing on cooling from fusion before the blowpipe. Mimetene. An arsenate of lead, resembling pyromorphite in crystallization, but giving a garlic odor on charcoal before the blowpipe. Color pale-yellow, passing into brown. H=2'75 —35. Gr=6'41. From Cornwall and elsewhere; Phenixville, Pa. Hedyphane. An arseno-phosphate of lead and lime, containing 2 per cent. of chlorine. It occurs amorphous, of a whitish color, and adamantine luster. H=35 —4. Gr=54 — 55. From Sweden. cRocoIsITE.-Chromate of Lead. Occurs in oblique rhombic prisms, massive, of &t bright red color and translucent. Streak orange-yellow. H= 25 —3. Gr=6. Composition: chromic acid 31'85, protoxyd of lead 68'15. Produces a yellow solution in nitric acid. Blackens and fuses before the blowpipe, and forms a shining slag contain. ing globules of lead. Obs. Occurs in gneiss at Beresof in Siberia, and also in Brazil. This is the chrome yellow of the painters. It is made in the arts by adding to the chromate of potash in so. lution, a solution of acetate or nitrate of lead. The chromate of potash is usually procured by means of the ore chromic iron, which see, (p. 241.) Melanochroite is another chromate of lead, containin S23't4 of chromic acid, and having a dark red color; streak brick red. Crystals usually tabular and reticulately arranged. Gr=5-75. From Siberia. How is pyromorphite distinguished from beryl and apatite I What is the color of chromate of lead? its composition? What is It.alled in lhi arts, and how used? LEAD ORES. 285 Vauquelinte is a caromate of lead and copper, of a very dark green or pearly black color, occurring usually in minute irregularly aggregated crystals; also reniform and massive. H-=25-3. Gr = 5'5-58. From Siberia and Brazil. It has been found by Dr. Torrey at the lead mine near Sing Sing, in green and brownish-green mammillary concretions, and also nearly pulverulent. lelndipite. Color white, yellowish or reddish nearly opaque. Luster pearly. Gr=7-7 — 1. Contains chlorid of lead 38-4, oxyd of lead 61-6. From Mendip Hills, Somersetshire. Cotunnite is another chlorid of lead, occurring at Vesuvius in white acicular crystals. It contains 74-5 per cent. of lead. Corneous lead. A chloro-carbonate of lead. occurring in whitish adamantine crystals. Gr=6-6-1. From Derbyshire and Germany. Also said to occur at the Southampton lead mine, Massachusetts. Molybdate of lead. In dull-yellow octahedral crystals, and alsomassive. Luster resinous. Contains molybdic acid 34'25, protoxyd of lead 64-42. From Bleiberg and elsewhere in Carinthia; also Hungary. It has been found in small quantities at the Southampton lead mine, Mass., and in fine crystals, at Phenixville, Penn. Selenate of lead. A sulphur-yellow mineral, occurring in small globules, and affording before the blowpipe on charcoal a garlic odor, and finally a globule of lead. Vanadinite. A vanadate of lead, occurring in hexagonal prisms like pyromorphite, and also in implanted globules. Color yellow to reddish brown. H=2'75. Gr=6-6 — 73. From Mexico; also from Wanlockhead in Dumfriesshire. Tungstate of lead. In square octahedrons or prisms. Color green, gray, brown, or red. Luster resinous. H=25 —3. Gr=7-9-8-1. Contains.)l of tungstic acid and 49 of lead. Plumbo-resinite. In globular forms, having a luster somewhat like gum arabic, and a yellowish or reddish-brown color. H=4 -45. Gr==6-3-64. Consists of protoxyd of lead 40-14, alumina 37-00, water 18-8. From Huelgoet in Brittany, and at a lead mine in Beaujeu; also from the Missouri mines, with black cobalt. GENERAL REMARKS ON LEAD AND ITS ORES. The lead of commerce is derived almost wholly from the sulphuret of lead or galena, the localities of which have already been mentioned. This ore is reduced usually by heat alone in a reverberatory furnace. The process consists simply in burning out the sulphur after the ore is picked, pounded and washed. The galena is kept at a heat below that required for its fusion, and air is freely admitted to aid in the combustion. The sulphur is driven off; leaving the pure lead, or an oxyd formed in the process which passes to the state of a slag. The latter is heated dgain with charcoal, which separates the oxygen. A portion of quicklime is often added to stiffen the slag. In England, the whole opeation of a smelting shift takes about 41 hours, and fc.r periods may be distinguished:-The first fire for roasting the ores, which requires Whal is the source of the lead of commerce? How is the ore educed? 286 METALS. very moderate firing, and lasts two hours; the second fire for smelting requiring a higher heat with shut doors, and at the end the slags are dried up with lime, and the furnace is also allowed to cool a little; the third and fourth fires, also for smelting, requiring a still higher temperature. A furnace for using the hot Jlast with lead has been contrived. The heated blast is made to diffuse itself equally through the whole " charge," carrying with it the flame of the burning tuel, and the reduction of the ore is effected with an economy and dispatch hitherto unknown in the processes of reducing this metal.* According to another mode which has been practised in Germany and France, old iron (about 28 per cent.) is thrown into the melted ore, heated in a reverberatory furnace of small size; the iron acts by absorbing the sulphur, and the lead thus reduced flows into the bottomr of the basin. There is here a gain of time and labor, but a total loss of the iron. The mode of obtaining the silver from lead ore, is mentioned under Silver. The principal mines of lead in the world are mentioned under Galena. The following is a statement of the approximate amount of lead produced by the mines of Europe: Great Britain and' Sweden and Norway, 4,000 cwt. Ireland,..1,200,000 cwt. Prussia,.. 160,000 Spain... 600,000 " Germany,. 160,000 " Austria,.. 140,000 " Belgium,... 20,000 " Russia and Poland, 6,000 " Piedmont and SwitzFrance,... 30,000 " erland,.... 10,000 " According to the Statistical Tables of J. D. Whitney,+ the mines of the Upper Mississippi and Missouri have afforded as follows: Upper Mississippi. Missouri Mines. 1826,.. 428 tons.... 1,343 tons. 1830,.. 5,331... 1,832 1835,...8,469... 3,227 1840,.. 11,987... 2,793 1842,.. 13,992... 3,348 1845,.. 24,328 1847,.. 24,145 1850,.. 17,768... 1,500? 1853,... 13,307 The present yield of the Missouri mines is set down as not over 1500 tons. The proceeds of the western mines have been for many years on the decrease. What other method is mentioned? What country affords the largest amount of lead at the present time, and how much? What is the yield of the mines of the Upper Mississippi. What of the Lower or Mis. soi i mines? * See Ainer. Jour. Sci. xlii, p. 169. t Whitney's Metallic Wealth of the United States, p. 421. ME'TALS. 287 22. MERCURY Me cury occurs native, alloyed with silver. and in combi. nation with sulphur, chlorine, or iodine. Its ores are coitpletely volatile, excepting the one containing silver. NATIVE MERCURY. Monometric; in octahedrons. Occurs in fluid globule scattered through the gangue. Color tin-white. Gr —13-6 Becomes solid and crystallizes at a temperature of —39~ F. Mercury, or quicksilver as it is often called, (a translation of the old name " argentum vivum,") is entirely volatile before the blowpipe, and dissolves readily in nitric acid. Obs. Native mercury is a rare mineral, yet is met with at the different mines of this metal, at Almaden in Spain, Idria in Carniola, (Austria,) and also in Hungary and Peru. It is usually in disseminated globules, but is sometimes accumulated in cavities so as to be dipped up in pails. Uses. Mercury is used for the extraction of gold and silver ores, and is exported in large quantities to South Amer. ica. It is also employed for silvering mirrors, for thermometers and barometers, and for various purposes connected with medicine and the arts. Native Amalgam. This mineral is a compound of mercury and silver, containing 64 to 72 per cent. of mercury, and occurring in silverwhite dodecahedrons. H=2-2-5. Gr=10'5-14. Principally from the Palatinate; also from Hungary and Sweden. The arquerite of Berthier is an amalgam from Coquimbo, containing only 13-5 per cent. of silver. CINNABAR.-Sulphuret of Mercury. Rhombohedral. R: R=710 47. Cleavage transverse, highly perfect. Crystals often tabular, or six-sided prisms Also massive, and in earthy coatings. Luster unmetailic, adamantine in crystals; often dull. Color bright red to brownish-red, and brownish-black. Streak red. Subtransparent to nearly opaque. H 2-2 —25. Gr=6-7-8-2. Sectile. Composition: when pure, mercury 86'29, sulphur 13*71; In what condition does mercury occur? What is a characteristic of ts ores? Describe native mercury? Where is it found? For what s it used? What are the physical characters of cinnabar 288 METALS. but often contains impurities. The liver ore, or hepatic cinnabar, contains some carbon and clay, and has a brownish streak and color. The pure variety volatilizes entirely before the blowpipe. Dif. Distinguished from red oxyd of iron and chromatt of lead by evaporating before the blowpipe; from realgar by giving off on charcoal no allicaceous fumes.;bs. Cinnabar is the ore from which the principal parn;iAe mercury of commerce is obtained. It occurs mostly il connection with talcose and argillaceous shale, or other stratified deposits, both the most ancient and those of more recent date. The mineral is too volatile to be expected in any abundance in proper igneous or crystalline rocks, yet has been found sparingly in granite. The principal mines are at Idria in Austria Almaden in Spain, in the Palatinate on the Rhine, and at Huanca Velica in Peru. Mercury occurs also at Arqueros in Chili, at various places in Mexico, in Hungary, Sweden, at several points in France, and at Ripa, in Tuscany; also in China and Japan. A large mine has been discovered in Upper California. The ore there occurs in a ridge of the Sierra Azul, twelve miles south of San Jose, a few miles fiom the coast, and about half way from San Francisco to Monterey. The mouth of the principal mit e (the mine of New Alnaden) is a few yards down from the summit of the highest hill containing the ore, and is about 1200 feet above the neighboring plain. The prevail. ing rock is a greenish talcose rock. The ore is interspersed through the slate, in a yellow ochreous matrix, which forms a bed 42 feet in thickness. The richest ore is from the upper part of the bed. The supply is abundant, and of excellent quality, and one to two millions of pounds of mercury are now extracted annually. The rock is a metamorphic rock, much tilted and contorted; but its exact -age has not been ascertained. Uses. This ore is the principal source of the mercury of commerce. It is also used as a pigment, and as a coloring ingredient for red sealing wax, and it is called in the shops vermillion. The vermillion of commerce is often adulterated with red lead, dragon's blood and realgar. Its entire volatil. ity, without odorous fumes, will distinguish the pure material. Horn Quicksilver, (chlorid of mercury.) A tough, sectile ore, of a Of what does cinnabar consist? Where are the principal mines? For what is it used? ORES OF MERCURY. 289 fight yellowish or grayish color, and adamantine luster, translucent oi subtranslucent, crystallizing in secondaries to a square prism. H=12. Gr-=648. It contains 85 per cent. of mercury. lodic Mercury is a still rarer ore from Mexico. Color reddish-brown. Selenid of mercury, a dark steel-gray ore, which is wholly evapo. rated before the blowpipe. Occurs in Mexico near San Onofre. GENERAL REMARKS ON THE ORES OF MERCURY. The mines of Idria were discovered in 1497. The mining is carried n in galleries, as the rock is too fragile to allow of large chambers. rhe ore is obtained at a depth of about 750 feet, and is mostly a bituninous cinnabar, disseminated through the rock along with native merury. The latter is in some parts so abundant that when the earthy rock is fresh broken, large globules fall out and roll to the bottom of the gallery. The pure mercury is first sifted out; the gangue is then washed, and prepared for reduction. For this purpose there is a large circular building, 40 feet in diameter by 60 in height, the interior of which communicates through small openings with a range of chambers around, each 10 or 12 feet square, and having a door communicating with the external air. The central chamber is filled with earthen pans, containing the prepared earth, the whole is closed up and heat is applied. The mercury sublimes and is condensed in the cold air of the smaller chambers, whence it is afterwards removed. After filtering, it is ready for packing. These mines afford annually 5000 cwt. The above mode of reduction is styled by Ure " absolutely barbarous." He observes that the brick and motar walls cannot be rendered either tight or cool; and that the ore -ought to be pounded, and then heated in a series of cast-iron cylinder retorts, after being mixed with the requisite proportion of quicklime, (the lime aiding in the reduction of the cinnabar by taking its sulphur,) and the retorts should communicate with a trough through which a stream of water passes, for the purpose of condensing the mercury. An apparatus of this kind planned by Ure, is used at Landsberg, in Rhenish Bavaiia. The mines of the Palatinate, on the Rhine, and those of other parts of Germany, are stated by Burat to yield 7.600 quintals. The mines of Almaden are situated near the frontier of Estremadura, in the province of La Mancha. They have been worked from a 7emote antiquity. According to Pliny, the Greeks obtained vermillion from them 700 years before our era, and afterwards imported annually 100,000 pounds. The mines are not over 300 yards in depth, although so long worked. The rock is argillaceous schist and grit, in horizontal )eds, which are intersected by granitic and black porphyry eruptions. The mass of ore at the bottom of the principal vein, is 12 to 15 yards thick, and yields in the aggregate 10 per cent. of mercury. It is taken go the furnace without any kind of mechanical preparation. There are nany veins in the vicinity, several of which have been explored. The arnaces of Almadenejos are fed almost exclusively by an ore obtained jut east of the village, which is a black schist, strongly impregnated What is said of the Idria mines? How is the ore reduced? What ib a bertu process? What is said of the mines of Almaden? 2S)1I METALS. with native mercury and cinnabar, with but little visible. These mines afford annually about 25.000 cwt. of nmecury. The granitic and por. phyritic eruptions of the region have been supposed to account for the presence of the mercury in the rocks: the heat produced exhalations of mercury and sulphur, which gave origin both to the cinnabar and the native mercury. The mines of Huanca Velica, in Peru, have afforded a large amount of mercury for amalgamation at the Peruvian silver mines. Between the years 1570 and 1800, they are estimated to have produced 537.000 tons; and their present annual yield is 1800 quintals. The Chinese have mines of cinnabar in Shensi, where the ore is reduced by.the rude process of burning brushwood in the wells or pits dug out for the purpose, and then collecting the metal after condensation. 23. COPPER. Copper occurs native in considerable quantities; also combined with oxygen, sulphur, selenium, and various acids. The ores of copper vary in specific gravity from 3'5 to 8*5, and seldom exceed 4 in hardness. Many of the ores give to borax a green color in the outer flame, and an opaque dullred in the inner. With carbonate of soda on charcoal, nearly all the ores are reduced, and a globule of copper ob. tained; borax and til foil are required in some cases where a combination with other metals conceals the copper. When soluble in the acids, a clean plate of iron inserted in the solution becomes covered with copper, and ammonia produces a blue solution. NATIVE COPPER. Monometric. In octahedrons; no cleavage apparent Often in plates or masses, or arborescent and filiform shapes. Color copper-red. Ductile and malleable. H-25 —3. Gr=8-58. Native copper often contains a little silver, disseminated throughout it. Before the blowpipe it fuses readily, and on cooling it is covered with a black oxyd. Dissolves in nitric acid, and produces a blue solution with amrronia. Obs. Native copper accompanies the ores of copper, and usually occurs in the vicinity of dikes of igneous rocks. How does copper occur? tow are copper ores distinguished'? What are the characters of native copper? COPPER ORET. 291 Siberia, Cornwall, and Brazil, are noted for the copper they have produced. A mass supposed to be from Bahia, now at Lisbon, weighs 2616 pounds. The vicinity of lake Superior is one of the most extraordinary regions in the world for its native copper, where it occurs mostly in vertical seams in trap, and also in the enclosing sandstone. A mass weighing 3704 lbs. has been taken from thence to Wash. ington city: it is the same that was figured by Schoolcraf in the American Journal of Science, volume iii, p. 201 Masses from 1000 to 3700 pounds, fiom this region, hav been exposed on the wharves of Boston, Mass. This i small compared with other pieces which have since betet laid open. One large mass was quarried out in the "' Cliff mine," whose weight has been estimated at 2(i0 (os. It as 40 feet long, 6 feet deep, and averaged 6 inches in thickness. This copper contains intimately mixed with it about,- per cent. of silver. Besides this, perfectly pure silver, in strings, masses, and grains, is often disseminated through the copper, and some masses, when polished, appear sprinkled with large white spots of silver, resembling, as Dr. Jackson ob serves, a porphyry with its feldspar crystals. Crystal of native copper are also found penetrating masses of preh nite, and analcime, in the trap rock. This mixture of copper and silver cannot be imitated bj art, as the two metals form an alloy when melted together. It is probable that the separation, in the rocks, is due to the cooling from fusion being so extremely gradual as to allow the two metals to solidify separately, at their respective temperatures of solidification-the trap being an igneous rock, and ages often elapsing, as is well known, during the cooling of a bed of lava, covered from the air. Small specimens of native copper have been found in the states of New Jersey, Connecticut, and Massachusetts, where the same formation occurs. One mass from near Somerville weighs 78 pounds, and is said originally to have weighed 128 pounds. Near New Haven, Conn., a mass of 90 pounds was formerly found. Near Brunswick, N. J., a vein or sheet of copper, from a sixteenth to an eighth of an inch thick has been observed and traced along for several rods. Where has native copper been found in the United States? Wha s said of its associations with silver? What explanation;9 given of this mixture of copper and silver? 292 METALS. COPPER GLANCE.-VITREOUS COPPER ORE. Trimet ic. Cleavage parallel to the faces of a right rhomn bic prism, but indistinct. M: M=119 35'. Secondary forms, variously modified rhombic prisms. Also in compound crystals like arragonite; often massive. Color and streak blackish lead-gray, often tarnished blue r green. Streak sometimes shining. H-2-5 —3. Gr= ~5 —5'8. Composition: sulphur 20'6, copper 77-2, iron 1-5. Beore the blowpipe it gives off fumes of sulphur, fuses easily n the external flame, and boils. After the sulphur is driven off, a globule of copper remains. Dissolves in heated nitric acid, with a precipitation of the sulphur. Dif. The vitreous copper ore resembles vitreous silver ore; but the luster of a surface of fracture is less bril. liant, and they afford different results before the blowpipe. The solution made by putting a piece of the ore in nitric acid, covers an iron plate (or knife blade) with copper, while a similar solution of the silver ore covers a copper plate with silver. Obs. Occurs with other copper ores in beds and veins. At Cornwall, splendid crystallizations occur. Siberia, Hesse, Saxony, the Bannat, Chili, &c., afford this ore. In the United States, a vein affording fine crystallizations occurs at Bristol, Conn. Other localities are at Wolcott ville, Simsbury, and Cheshire, Conn.; at Schuyler's Mines, and elsewhere, N. J.; in the U. S. copper mine district, Blue Ridge, Orange county, Virginia; between New Mark. et and Taneytown, Maryland; and sparingly at the copper mines of Michigan and the Western states; also at some mines north of Lake Huron. Blue Copper is a dull blue-black massive mineral. Gr=3'8-. It contains 65 per cent. of copper. It is named Covelline. Harrisite is a copper glance, with cubic cleavage, from Canton mine, Ga., probably a pseudomorph after Galena. COPPER PYRITES.-Sulphuret of Copper and Iron. Dimetric. Crystals tetrahedral or octahedral; sometimes What are the physical characters of vitreois copper? its constitution nd chemical characters? How does it differ from silver ores? COPPER ORES. 293 compound. A: A=1090 53, and 108~ 40'. Cleavage in 1 distinct. Also massive. 2 and of various imitative shapes. Color brass-yellow, often tarnished deep yel- / low, and also iridescent. / Streak unmetallic, greenish-black, and A / but little shining. H=3-5-4. Gr= \ 4'15-4-13. Composition: sulphur 349, copper 34 0, iron 30'5. Fuses before the blowpipe to a globul which is magnetic, owing to the iron present. Gives sul phur fumes on charcoal. With borax affords pure copper The usual effect with nitric acid. Dif. This ore resembles native gold, and also iron py. rites. It is distinguished from gold by crumbling when it is attempted to cut it, instead of separating in slices; and from iron pyrites in its deeper yellow color and in yielding easil: to the point of a knife, instead of striking fire with a steel. Obs. Copper pyrites occurs in veins in granitic and allied rocks; also in graywacke, &c. It is usually associated with iron pyrites, and often with galena, blende, and carbon. ates of copper. The copper of Fahlun, Sweden, is obtained mostly from this ore, where it occurs with serpentine in gneiss. Other mines of this ore are in the Hartz, near Goslar; in the Bannat, Hungary, Thuringia, &c. The Cornwall ore is mostly of this kind, and 10 to 12,000 tons of pure copper are smelted annually. The ore for sale at Redruth is said to be by no means a rich ore. It rarely yields 12 per cent. and generally only 7 or 8, and occasion. ally as little as 3 to 4 per cent. of metal. In the latter case such poverty of ore is only made up by its facility of transport, the moderate expense of fuel, or the convenience of smelting. Its richness may generally be judged of from the color: if of a fine yellow hue, and yielding readily to the hammer, it is a good ore; but if hard and pale yellow it con. tains very largely of iron pyrites, and is of poor quality. In the United States there are many localities of this ore What forms are presented by copper pyrites? What is its color and streak? its composition? How is it distinguished from iron pyrites and gold? What is said of the modes of occurrence of this ore and of its mines I 294 M TA LS. It occurs in Massachusetts, at the Southampton lead mines, at Turner'- Falls on the Connecticut, at Hatfield and Ster. ling; in V ermont, at Strafford, where it was for a time worked, and at Shrewsbury, Corinth, Waterbury; in New Hampshire, at Franconia, Shelburn, Unity, Wa ren, Eaton, Lyme, Haverhill; in Maine, at the Lubec lead mines, and Dexter; in New York, at the Ancram lead mil e, also near Rossie, and at Wurtzboro; in Pennsylvania, at Morgantown; in Virginia, at the Phenix copper mines, Fauquier county, ~nd at the Walton gold mine, Luzerne county; in Maryland, in the vicinity of Liberty and New London, in Frederick Co., and at the Patapsco mines, near Sykesville; in North Carolina, in Davidson and Guilford counties. In Michigan, where native copper is so abundant, this is a rare ore; but It occurs at Presqu'isle, at Mineral Point, and in Wisconsin, where it is the predominating ore. In Tennessee, in Polk county, at the Hiwassee mines, where, however, only the overlying black copper is worked. Uses. This ore, besides being mined for copper, is ex. tensively employed in the manufacture of blue vitriol (sulphate of copper,) in the same manner that sulphate of iron (copperas) is obtained from iron pyrites. Cuban is a sulphuret of copper and iron, containing sulphur 39*0, iron 38-0, copper 19-8, silica 23-=99'12. ERUBESCITE.-VARIEGATED COPPER PYRITES. Monometric. Cleavage octahedral, in traces. Occurs in cubes and octahedrons. Also massive. Color between copper-red and pinchbeck-brown. Tar. nishes rapidly on exposure. Streak pale grayish-black and but slightly shining. Brittle. H=3. Gr-5. Composition: specimen from Bristol, Conn., sulphur 2577, copper 62'8, iron 11'6. Fuses before the blowpipe to a globule attractable by the magnet. On charcoal affords fumes of sulphur. Mostly dissolved in nitric acid. Dif. This ore is distinguished from the preceding by its pale reddish-yellow color. Obs. Occurs with other copper ores, in granitic and al. lied rocks, and also in secondary formations. The mines of Cornwall have afforded crystallized specimens, and it is there called from its color " horse-flesh ore." Other foreign What is the appearance and composition of variegated copper py. rites? How is it distinguished from the preceding species? 24 COPPER ORES. 295 localities of massive varieties are Ross Island, Killarney, Ireland; Norway, Hessia, Silesia, Siberia, and the Bannat. Fine crystallizations occur at the Bristol copper mine, Conn., in granite; and also in red sandstone, at Cheshire, in the same state, with malachite and heavy spar. Massive varieties occur at the New Jersey mines, and in Pennsylvania. TETRAHEDRITE.-GRAY COPPER. Monometric. Occurs in modified tetrahedrons, and also n compound crystals. Cleavage octahedral in traces. Color between steel-gray and - iron-black. Streak nearly as the color. Rather brittle. H-=3- 4. Gr-4'7-5-51. Composition: sulphur 26-3, copper 38'6, antimony 16'5, arsenic 7'2, along with some iron, zinc, and silver, amounting to 15 per cent. It sometimes contains 30 per cent. of silver in place of part of the copper, and is then called argentiferous gray copper ore, or silverfahlerz. The amount of arsenic varies from 0 to 10 per cent. One variety from Spain included 10 per cent. of platinum, and another from Hohenstein some gold; another from Tuscany 2-7 per cent. of mercury. These varieties give off, before the blowpipe, fumes of ar. senic and antimony, and after roasting yield a globule of copper. Dissolve, when pulverized, in nitric acid, affording a brownish-green solution. Dif. Its copper reactions before the blowpipe and in so. lution in nitric acid, distinguish it from the gray silver ores. Obs. The Cornish mines, Andreasberg in the Hartz, Kremnitz in Hungary, Freiberg in Saxony, Kapnik in Transylvania, and Dillenberg in Nassau, afford fine crystallizations of this ore. It is a common ore in the Chilian mines, and it is worked there and elsewhere for copper, and often also for silver. Bournonite contains sulphur 20-3, antimony 26-3, lead 40-8, copper 12.7. Its crystals are modified rectangular prisms, of a steel-gray color and streak, and are often compounded into shapes like a cog-wheel, whence it is called wheel-ore. H-=25-3. Gr=-5766. From the Hartz, Transylvania, Saxony, and Cornwall. Another allied ore, conaining 47 per cent. of antimony, is called antimonial copper; it ocDescribe gray copper ore. Mention its composition and blowpipe characters. How is it distinguished from silver ores? 296 MET ALS. curs in slender aggregated prisms, of a dark ead-gray color. Anothel containing also arsenic, is called antimonial copper glance. Tennantite is a compound of copper, iron, sulphur, and arsenic. It occurs in dodecahedral crystals, brilliant, with a dark lead-gray color and reddish-gray streak. From the Cornish mines near Redruth and St. Day. Domeykite is arsenical copper. Selenid of Copper, is a silver-white ore, affording the horse-radish odor of selenium before the blowpipe. It contains 64 per cent. of copper. From Skrigerum, Sweden. RED COPPER ORE. Morimetric. In regular octahedrons, and modified forms of the same. Cleavage octahedral. Also massive, and 1 sometimes earthy. 2 Color deep red, of various shades. Streak brownish-red. A C/ Luster adamantine or submetal- / lie; also earthy. Subtranspa- / rent to nearly opaque. Brittle. H —3'5-4. Gr=6. Composition: copper 88-8, oxygen 11 2. Before the blowpipe, on charcoal, it yields a globule of copper. Dissolves in nitric acid. The earthy varieties have been called tile ore, from the color. Dif. From cinnabar it differs in not being volatile before the blowpipe; and from red iron ore, in yielding a bead of copper on charcoal, and copper reactions. Obs. Occurs with other copper ores in the Bannat, Thuringia, Cornwall, at Chessy near Lyons, in Siberia, and Brazil. The octahedrons are often green, from a coating of malachite. In the U. States, it has been observed crystallized and massive, at Schuyler's, Somervil|s, and the Flemington copper mines, N. J.; also near New Brunswick, N. J.; at Bristol, Ct.; also near Ladenton, Rockland county, N. Y. Black Copper. Tenorite. An oxyd of copper, occurring as a black powder and in dull black masses, and botryoidal concretions, in veins or along with other copper ores- From Cornwall, and also the Vesuvian lavas. It is an abundant ore in some of the copper mines of the Mississippi valley and yields 60 to 70 per cent. of copper. It results from the What is the crystallization of red copper ore? Of what does it con sist? How does it differ from cinnabar and re i iron ore? COPPER ORES. 297 decomposition of the sulphurets and other ores. At the Hi. wassee mine, Polk Co., Tennessee, it is abundant, and is worked as an ore. It was found of excellent quality in the Lake Superior copper region, but has there been exhausted. The oxyds of copper are easily smelted by heating with the aid of charcoal alone. They may be converted directly into the sulphate or blue vitriol, by means of sulphuric acid, but are more valuable for the copper they afford. BLUE VITRIOL.-Sulphate of Copper. Triclinic. In oblique rhomboidal prisms. Also as an efflorescence or incrustation. Color deep sky-blue. Streak uncolored. Subtransparent to translucent. Luster vitreous. Soluble, taste nauseous and metallic. H —-2-25. Gr=2-21. Composition: sulphuric acid 32 1, oxyd of copper, 31-8, water 36. A polished plate of iron in a solution becomes covered with copper. Obs. Occurs with the sulphurets of copper as a result of their decomposition, and is often in solution in the waters flowing from copper mines. Occurs in the Hartz, at Fahlun in Sweden, and in many other copper regions. Uses. Blue vitriol is much used in dyeing operations and in the printing of cotton and linen; also for various other purposes in the arts. It has been employed to prevent dry rot, by steeping wood in its solution: and it is a powerful preservative of animal substances; when imbued with it and dried, they remain unaltered. It is afforded by the decomposition of copper pyrites, in the same manner as green vit. riol from iron pyrites. (p. 213.) It is manufactured for the arts from old sheathing copper, copper turnings, and copper refinery scales. The scales are readily dissolved in dilute sulphuric acid at the temperature of ebullition; the solution obtained is evaporated to the point where crystallization will take place on cooling. Metallic copper is exposed in hot rooms to the atmosphere after it has been wet in weak sulphuric acid. By alternate wetting and exposure, it is rapidly corroded, and affords a solution whic' What is blue vitriol? Describe it. What is said of its mode of oc. currence? For what is it used? How is it manufactured in the arts How is copper obtained from solutions in some mines Describe green malachite. ,98 METALS. s evaporated for crystals. 400,000 Ibs. is the annual con. iumption of blue vitriol in the United States. In Frederick county, Maryland, blue vitriol is made from t black earth which is an impure oxyd of copper with copper pyrites. The black oxyd of copper, which was found In the Lake Superior copper region, may be directly con.,erted into blue vitriol. In some mines, the solution of sulphate of copper is so aoundant as to afford considerable copper, which is obtained oV immersing clean iron in it, and is called copper of cemen. ration. At the copper springs of Wicklow, Ireland, about 500 tons of iron were laid at one time in the pits; in about 12 months the bars were dissolved, and every ton of iron yielded a ton and a half, and sometimes nearly two tons, of a precipitated reddish mud, each ton of which produced 16 cwt. of pure copper. The Rio Tinto Mine in Spain, is another instance of working the sulphate in solution. These waters yield annually 1800 cwt. of copper, and consume 2400 cwt. of iron. Brochantite. An insoluble sulphate of copper, containing 17'5 per cent. of sulphuric acid. Color emerald green. In tabular rhombic crys. tals, at Katherinenberg, in Siberia. Blackens before the blowpipe without fusing. Krisuvigite and Konigite are the same species. MALACHllTE. -Greeel Carbonate of Copper. Monoclinic. Usual in incrustations, with a smooth tuberose, botryoidal or stalactitic surface; structure finely and firmly fibrous. Also earthy. Color light green, streak paler. Usually nearly opaque; crystals translucent. Luster of crystals adamantine inclining to vitreous; but fibrous incrustations silky on a cross fracture. Earthy varieties dull. H-=3-54. Gr=4. Composition: carbonic acid 20, oxyd of copper 71-9, water 8*2. Dissolves with effervesence in nitric acid. De. crepitates and blackens before the blowpipe, and becomes partly a black scoria. With borax it fuses to a deep green globule, and ultimately affords a bead of copper. Dif. Readily distilguished by its copper-green color and its association with copper ores. It resembles a siliceous ore of copper, chrysocolla, a common ore in the mines of he Mississippi valley; but it is distinguished by its complete What is the composition of green malachite? How is it distin guished? 24* ri) FPH, -,a.' 99 solution and effervescence in nitric acid. The color also is not the bluish-green of chrysocolla. Obs. Green malachite usually accompanies other ores of copper, and forms incrustations, which when thick, have the colors banded and extremely delicate in their shades and blending. Perfect crystals are quite rare. The mines of Siberia, at Nischne Tagilsk, have afforded great quantities of this ore A mass partly disclosed, measured at top 9 eet by 18; and the portion uncovered contained at least half a million pounds of pure malachite. Other noted fbreign localities are Chessy in France, Sandlodge in Shetland, Schwartz in the Tyrol, Cornwall, and the island of Cuba. The copper mine of Chesh.:ie, Connl., has afforded hand. some specinens: also MoranItown, Perkiomen anid Phenixs ville, Penr.; Schuyler's mine, and the New Brunswick copper mine, N. J.: it occurs also in Maryland, between Newmarket and Taneytown, and in the Catoctin mountains; in the Blue Ridge, Penn., near Nicholson's Gap, and it is found more or less sparingly with all kinds of copper ores. At Mineral Point, Wisconsin, a bluish silico-carbonate of copper occurs, which is for the most part chrysocolla, or a mixture of this mineral with the carbonate. An analysis of the rough ore afforded Mr. D. D. Owen, copper 35'7, carbonic acid 10*0, water 10'0, iron 15'7, oxygen 7, sulphur 8, silex 13*0. Specific gravity 3-69 —3-87. The vein ap. pears also to the northwest on Blue River, and southeast on the Peccatonica. This ore is abundant; it has been smelted on the spot and also exported to England. Uses. This mineral receives a high polish dnd is used for inlaid work, and also ear-rings, snuffboxes, and various ornamental articles. It is not much prized in jewelry. Very large masses are occasionally obtained in Russia, which are worked into slabs for tables, mantel-pieces and vases, which are of exquisite beauty, owing to the delicate shadings of the radiations and zones of color. 4t Versailles, there is a room furnished with tables, vases, and other arti. cles of this kind, and similar rooms are to bt found in many European palaces. At Nischne Tagilsk, a block of mala chite was obtained weighing 40 tons. Malachite is sometimes passed off in jewelry as turquois, hough easily distinguished by its shade of color and much How does green malachite occur? What are its uses 300 METALS. inferior hardness. It is a valuable ore when abundant; bui it is seldom smelted alone, because the metal is liable to es. cape with the liberated volatile ingredient-carbonic acid. AZURITE.-Blue Carbonate of Copper..,ioclinic. In modified oblique rhombic prisms, the crystals rather short and stout; lateral cleavage perfect. Also massive. Often earthy. / Color deep blue, azure or Ber. / fin-blue. Transparent to nearly e opaque. Streak bluish. Luster vitreous, almost adamantine. — Brittle. H=3*5- 4'5. Gr3-5- 385. Composition: carbonic acid 25-6,-oxyd of copper 69'2, water 5'2., Before the blowpipe and in acids, it acts like the preceding. Obs. Azurite accompanies other ores of copper. At Chessy, France, its crystallizations are very splendid. It is found also in Siberia, in the Bannat, and near Redruth in Cornwall; at Phenixville, Pa., in crystals. As incrustations and rarely as crystals, it occurs near Singsing, N. Y.; near New Brunswick, N. J. Also neaT Nicholson's Gap, in the Blue Ridge, Penn. Uses. When abundant it is a valuable ore of copper. It makes a poor pigment, as it is liable to turn green. CHRYSOCOLLA.-Silicate of Copper. Usually as incrustations; botryoidal and massive. Also in thin seams and stains; no fibrous structure apparent, noi any appearance of crystallization. Color bright green, bluish-green. Luster of surface ot in. crustations smoothly shining; also earthy. Translucent to opaque. H-2 —3. Gr==2-2'3. Composition: SIBERIAN. NEW JERSEY. V. Kobell. Berthier. Bowen. Beck. Oxyd of copper 40-0 55-1 45-2 42-6 Silica 36-5 35-4 37-3 40-0 Water 20-2 28-5 17'0 16-0 Carbonic acid 2.1 loss 10 - Oxyd of iron 1'0 - - 1-4 Describe blue malachite. How does it differ from green malachit in composition? What is the appearance of chrysocolla? its compof tion? COPPER ORES. 301 The mineral varies much in the proportion of its constituents, as it is not crystallized. It blackens in the inner flame of the blowpipe without melting. With borax it is partly reduced. No effervescence nor complete solution in nitric acid, cold or heated. Dif. Distinguished from green malachite as stated undei that species. Obs. Accompanies other copper ores in Cornwall, Hun. gary, the Tyrol, Siberia, Thuringia, &c. In Chili it is abundant at the various mines. In Wisconsin and Missouri it is so abundant as to be worked for copper. It was foi. merlly taken for green malachite. It also occurs at the Soni. erville and Schuyler's mine, N. J., at Morgantown, Penn.. and Wolcotville, Conn. Uses. This ore in the pure state affords 30 per cent. of copper; but as it occurs in the rock will hardly yield one. third this amount. Still when abundant, as it appears to be in the Mississippi valley, it is a valuable ore. It is easy of reduction by means of limestone as a flux. Dioptase is another silicate of copper, occurring in rhombohedral crystals and hexagonal prisms. R: R=1260 24'. Color emeraldgreen. Luster vitreous. Streak greenish. Transparent to nearly opaque. H=5. Gr=3'28. From the Kirghese Steppes of Siberia. Besides the above salts of copper, there are the following species, which are of little use in the arts. Arsenates of Copper.-Euchroite has a bright emerald-green color, and contains 33 per cent. of arsenic acid, and 48 of oxyd of copper. Occurs in modified rhombic prisms H=3'75. Gr=3'4. From Libethen, in Hungary. Aphanesite is of a dark verdigris-green inclining to blue, and also dark blue, H=2-5-3. Gr=4-19. It contains 30 per cent. of arsenic acid and 54 of oxyd of copper. From Cornwall. Erinite has an emerald-green color, and occurs in mammilated coatings H=4-5-5. Gr=4-04. Contains 33-8 of arsenic acid and 59-4 of oxyd of copper. From Limerick, Ireland. Liroconite varies from sky-blue to virdigris-green, It occurs in rhombic prisms, sometimes an inch broad. H=2*5. Gr=2-8 —2-9. Contains 14 per cent. of arsenic acid, 49 of oxyd of copper. Olivenite presents olive-green to brownish colors, and occurs in prismatic crystals or velvety coatings. 11=3. Gr=4-2. Contains 36'7 per cent. of arsenic acid, to 56'4 of oxyd of copper. Copper Mica is remarkable for its thin foliated or mica-like structure. The color is emerald or grass-green. H=2. Gr=2'55. It contains 21 per cent. of arsenic acid, 58 of oxyd of copper, and 21 of water. From Cornwall and Hungary. Copper Froth is anoihr arsenate of a pale apple-green and verdigris gieen color. I How does chrysocolla differ from green malachite? Where is it abundant in the U. States? What is its use? 802 M1.TA,S. has a perfect cleavage. It contains 25 per -ent of arsenic acid. 43'9 of oxyd of copper, 17'5 of water, with 13-6 of carlonate of lime. From Hungary, Siberia, the Tyrol, and Derbyshire. Condurrite has a brownish-black or blue color. From Cornwall. These different arsenates of copper give an allicaceous odor when heated on charcoal before the blowpipe. Phosphates of Copper.-Pseudo-malachite occurs in very oblique crystals, or massive and incrusting, and has an emerald or blackishgreen color. H=4-5-5. Gr=4'2. Contains 68 per cent. of oxyd of copper. From near Bonn, on the Rhine, and also from Hungary Libethenite has a dark or olive-green color, and occurs in prismatic crystals and massive. H=4. Gr=3'6-3-8. Contains 64 per cent. of oxyd of copper. From Hungary and Cornwall. Thrombolite is a green phospate occurring massive in Hungary. Contains 39 per cent. of cxyd of copper. These phosphates give no fumes before the blowpipe; and have the reaction of phosphoric acid. Chlorid of Copper.-Atacamite. Color green to blackish-green. Luster adamantine to vitreous. Streak apple-green. Translucent to subtranslucent. Occurs in right rhombic prisms and rectangular octahedrons, also massive. Consists of oxyd of copper 76'6, muriatic acid 10'6, water 12'8. Gives off fumes of muriatic acid before the blowpipe and leaves a globule of copper. From the Atacama desert, between Chili and Peru, and elsewhere in Chili; also from Vesuvius and Saxony. It is ground up in Chili, and sold as a powder for letters undet the name of arenillo. A Sulphato-chlorid of Copper has been observed in Cornwall, in blue acicular crystals, apparently hexagonal. 7anadate of lead and copper. Reported as occurring in Chili Color dark brown or brownish black; texture earthy, looking like a terruginous earth. Occurs with other ores of lead and copper. Vanadate of copper. Massive and foliated, or pulverulent; folia citron-yellow, pearly. From the Ural. Buratite. A hydrous carbonate of copper, zinc, and lime, occurring in bluish radiating needles. Gr=3'2. From Chessy, France; the Altai mountains' and Tuscany. Probably sante a. Aurichalcite. Velvet Copper Ore. In velvety druses or coatings, consisting of short fine fibrous crystallization. Color fine smalt blue. GENERAL REMARKS ON COPPER AND ITS ORES. The metal copper has been known since the earliest periods. It is obtained for the arts mostly from pyritous copper, the gray sulphurets, and the carbonate; also to some extent from the black oxyd, and from solutions of the sulphate, (page 296.) Assay of Ores. For the assay of copper ores by the dry way, tkl ollowing is a common method. A portion of the prepared ore, roasted n a closed tube, will show by the garlic or sulphurous smell of the umes, and by the depositions on the tube, whether arsenic, sulphur, or oth, be the mineralizers. If this last is the case, which often happens, 00 or 1000 grains of the ore are to be mixed with (ne half of its veight of sawdust, then imbued with oil, and heated moderately in a What is the mode of assaying copper ores in the dry way t COPPER ORIES. 303 crucible, till all the arsenical fumes are dissipated. The residuum, being cooled and triturated, is to be exposed in a shallow earthen dish, made of refractory material, to a slow roasting heat, and stirred till the sulphur and cl.arcoalare burned away; what remains being ground and mixed with half its weight of calcined borax, or carbonate of soda, onetwelfth its weight of lamp black, (finely pulverized charcoal will answer,) and next, made into a dough with a few drops of oil, is then to be pressed down into a crucible, which is to be covered with a luted lid, and subjected in a powerful air-furnace, first to a dull red heat, then to vivid ignitiontor.sevenototwenty minutes. On cooling and breaking the crucible, a button of metallic copper will be obtained, which may be refined by melting again with borax in an open crucible. Its color and malleability indicate pretty well the quality, as does its weight the relative value, of the ore. It may be cupelled with lead to ascertain if it contain silver or gold; or it may be treated for the same purpose with nitric acid. If the blowpipe trial show no arsenic, the first calcination may be omitted; and if neither sulphur nor arsenic are present, a portion of the pulverized ore should be dried and treated directly with borax, lampblack, and oil. The oies of copper, (the sulphuret as well as the oxyds, carbonates: &c.) may be reduced in the wet way, by solution in strong nitric acid. The solution, if made from the sulphuret, will contain sulphuric acid and free sulphur, as well as all the bases, (iron, nickel, cobalt, lead, silver, &c.) which may have been present in the original ore. If silver is present it will be found as a heavy white curdy precipitate, at the bottom, if the nitric acid employed contained any hydrochloric acid; and if the addition of this acid to the solution occasions no such precipitate, no silver is present. If the solution is free from lead, antimony, arsenic, and other metals precipitable by sulphureted hydrogen, the copper may be thrown down as sulphuret by means of a current of this gas, the black precipitate, collected on a filter washed with water, and redissolved in aqua regia, largely diiuted, and finally precipitated by caustic potash, which throws down the black oxyd of copper. This dried and weighed will yield the true value of the ore in metallic copper. If only iron and copper are present, (which may be previously determined by the blowpipe,) they may be separated fiom their solutions in nitric acid by anmmonia, which throws down the iron as hydrated peroxyd, but redissolves the copper precipitated by the first additions of ammonia. The determination of the weight of the iron may then give the amount of copper by the difference of weight, or the copper may again be thrown down by potash as before directed. Reduction of Ores. Copper ores are reduced in England in a reverberatory furnace, and the process consists in alternate calcinations and fusions. The volatile ingredients are carried off by the calcinations, and anv metals in combination with the copper are oxydized. The usions serve to get rid of the various impurities, and finally bring out he pure metal. The calcinations or roastings are I erformed either in a furnace, or y making piles in the open air. In this latter mode, which is in use What is the mode of assaying copper ores in the wet way? How ire copper ores reduced? Describe the process of calcination? 304 METALS. on the continent of Europe, the ore, after being pounded and assorted, is piled up in high pyramidal mounds, which mounds are covered with mortar, sod, &c., and have a chimney at the center. Hemispherical cavities are dug on the upper surface for the purpose of receiving the sulphur during the roasting, which arrives liquified at the surface. This process lasts about six months. In England, at Swansea, where the ores are carried for reduction, the calcinations are performed more rapidly in a reverberatory furnace; and this is especially necessary when the ores do not contain a sufficient proportion of iron pyrites to furnish enough sulphur to sustain the combustion. After calcination, the ore is black and powdery. In the Swansea establishments, the calcined ore is introduced into the furnace, (a reverberatory smaller than that used for calcination,) and is spread over the bottom, 1 cwt. at a time. The heat is raised, and the furnace closed. When fusion has taken place the liquid mass is well rabbled or stirred, so as to allow of the complete separation of the slags from the metal; afterwards the slags are skimmed off. Then a second charge is added, and after a similar process, a third charge, if the furnace is deep enough to receive it without the metal's flowing from the door. After the last charge is reduced also, the tap-hole is opened, and the metal flows out into water, where it is granulated. The slags if not free from metal are again returned to the furnace, when other charges are put in. This granulated metal is usually about one-third copper; it contains sulphur, copper, and iron. This coarse metal is next calcined, just as the ore was first calcined; by which the iron is oxydized. The charge remains in the furnace 24 hours, and is repeatedly stirred and turned. It is then transferred lo the furnace for melting, and there melted along with some slags from the previous fusion. The sulphur reduces any oxyd and the whole fuses down. The slags are skimmed off and the furnace tapped: the metal is again drawn off into water. In this state it contains about 60 per cent. of copper, and it is called fine metal. The fine metal is then calcined like the coarse metal; and next it is melted as before. It results in a coarse copper containing 80 to St per cent. of pure metal. The coarse copper is then roasted in the melting furnace; the air drawing in large quantities over the copper in incipient fusion, oxydizes the iron and the volatile substances are driven off. The metal is fused toward the end of the operation, which is continued from 12 to 24 hours, and is then tapped into sand beds. The pigs formed are covered with black blisters and they are cellular within. The copper is then remelted in a melting furnace; it is heated slowly to allow of any farther oxydizing that may be necessary. The slag is removed and the metal is examined from time to time, by taking out souirs J it, and when it is in the right condition, it is next subjected to the process (f toughening. It is now brittle, of a deep red color inclining to purple with an open grain and a crystalline structure; the copper in this state is what is termed dry. The surface of the melted metal is first covered with charcoal; a pole, commonly of birch, is held in the liquid matter, causing considerable ebullition; and this poling is continued, with occasional additions of charcoal, till it is found in the assays taken What are the several steps in reduction? COPPER ORES. 305 out that the crystalline grain has disappeared, and the copper when cut through has a silky polished appearance, and the color is light red. It is then ladeled out into moulds, usually 12 inches in width by 18 long. Lead is sometimes added in the purification, to aid by its own oxydation in the oxydation of the iron present. The process of melting copper on the continent is done by blast furnaces instead of the reverberatory, and they are said to be more economical in fuel, and produce a less waste of copper in the slags. Tiis mode is used at the works at Boston, while the Swansea mode has been adopted at the Baltimore furnaces, Maryland. At the Ha'ford works, South Wales, a furnace of three tiers of hearths has been introduced, which answers the double purpose of calcination and fusion at the same time. Galvanism has been turned to account in the reduction of copper ores. The ore is converted into a sulphate by roasting with the free access of the atmosphere. From this sulphate the copper is deposited in a pure state by galvanic decomposition. See on this subject American Journal of Science, ii ser., volume iv, p. 276, or Franklin Journal, volume xi, p. 128. Copper Mines. The principal mines of copper in the world are those of Cornwall and Devon, England; of the island of Cuba; of Copiapo, and other places in Chili; Chessy, near Lyons, in France; in the Erzgebirge, Saxony; at Eisleben and Sangerhausen, in Prussia; at Goslar, in the Lower Hartz; at Schemmitz, Kremnitz, Kapnik, and the Bannat, in Hungary; at Fahlun, in Sweden; at Turinsk and Nischni-Tagilsk, and other places in the Urals; also in China and Japan. Lately extensive mines have been opened in Southern Australia. In the United States, considerable quantities have been raised from the mines of New Jersey, and those of Simsbury, Conn. At Bristol, Conn., is a fine vein of vitreous copper, now under profitable exploration. The Hiwassee mine, Tennessee, and the mine at Corinth, Vermont, are at present productive. The most extensive deposits are those of Northern Michigan, near L. Superior. The Michigan mines are vertical veins mostly in the trap rock which intersects a red sandstone, probably identical in age with the red sandstone of Connecticut and New Jersey. The first discoveries of copper ore in this place were made at Copper harbor, where the chrysocolla and carbonate occur. Near Fort Wilkins the black oxyd was afterwards found in a large deposit, and 40,000 pounds of this ore were shipped to Boston. On farther exploration in the trap, the Cliff mine, 25 miles to the westward, was laid open, where the largest masses of native copper have been found, and which still proves to be highly productive. Other veins have since been opened in various parts of the region, at Eagle harbor, Eagle river, Grand Marais, Lac La Belle, Agate Harbor, Torch Lake, on the Ontonagon, in the Porcupine mountains, and elsewhere. At Mineral Point, Wisconsin, a blue siliceous carbonate is found. Other mines are opened in Missouri. The country north of Lakes Superior and Huron, also afford copper ores. What is the process of reduction on the continent of Europe? Where are the principal foreign mines of copper? Where is copper found iA the United States? 306 METALS. In the Lake Superior Region, the four larger mines have afforded, according to Whitney: Cliff Mine. Minnesota. N. American. Northwest 1845, 8-88 tons. 1846, 16-79 1847, 183-38 1848, 444-85 4-00 1849. 572-38 34.00 22.90 15.32 1850, 319-04 66-00 76-20 87-06 1851, 377-89 165-00 76-50 130-89 1852, 370-25 208-50 22-90 120 17 1853, 415 00 480-19 112-32 102 27 The total yield from all the mines in 1853, was 1,296-94 tons. Mr. Whitney observes that various attempts have been made to work the mines associated with the trappean rocks north of Lake Superior and Lake Huron, but as yet with little success. On Spar Island, and also on Michipicoten Island, veins have been opened which are abandoned. The Bruce Mine, on Lake Huron, is the only one in those regions now worked with profit. It is situated about fifty miles below Saut Ste, Marie, and due north of the extremity of St. Joseph's Island. The ore is chiefly copper pyrites, with some variegated copper ore. turing the year 1853, 1650 tons of ore were shipped. The Wallace Mine, 16 miles from La Clocke, a station of the Hudson's Bay Company, is said to furnish copper pyrites, like Bruce's Mine, and also nickel and cobalt ores.* The amount of copper produced by different mining countries in Europe is as follows: Great Britain, 300,000 cwt.t Denmark, 8,500 cwl Russia, 130,000 " Prussia, 30,000 " Austria, 60,000 " France, 2,000 " Germany, 12,000 Spain, 8,000'" Sweden and Norway, 40,000 " Other countries afford in 1853 (Whitney's Met. Wealth): Africa,.. 1,200 cwt. Asia,... 60,000" Australia and New Zealand,. 60,000 " Chili,......280,000 South America, exclusive of Chili, 26,000 Cuba,.... 50,000" United States and Canada,.. 40,000" Making the total for the world of about 1,150,000 cwt., or 55,750 tons. What three countries are most productive in copper? Where are the principal mines in the United States? * Whitney's Metallic Wealth of the United States. t 5-6ths of the whole from Cornwall. COPPER ORES, 307 What will be ultimately the proceeds of the copper region of Lake S-perior, cannot now be fully determined. But there is every prospect h.at the country will prove boundless in its resources. Uses. The metal copper was known in the earliest periods and was used mostly alloyed with tin, forming bronze. The mines of Nubia and Ethiopia are believed to have produced a great part of the copper of the early Egyptians. Eubaa and Cyprus are also mentioned as affording this metal to the Greeks. It was employed for cutting instruments and weapons, as well as for utensils;'and bronze chisels are at this day found at the Egyptian stone-quarries, that were once employed in quarrying. This bronze, (chalkos of the Greeks, and as of the Romans,) consisted of about 5 parts of copper to 1 of tin, a proportion which produces an alloy of maximum hardness. Nearly the same material was used in early times over Europe; and weapons and tools have been found consisting of copper, edged with iron, indicating the scarcity of the latter metal. Similar weapons have also been found in Britain; yet it is certain that iron and steel were well known to the Romans and later Greeks, and to some extent used for warlike weapons and cutlery. Copper at the present day is very various in its applications in the arts. It is largely employed for utensils, for the sheathing of ships, and for coinage. Alloyed with zinc it constitutes brass, and with tin it forms bell-metal as well as bronze. The best brass contains 2 parts of copper to 1 of zinc; the proportion of 4 of copper to 1 of zinc, makes a good brass. Pinchbeck contains 5 of copper to 1 of zinc; and tombac and Dutch gold, are other allied compounds. Bath metal consists of 9 of zinc to 32 of brass. A whitish metal used by the button-makers of Birmingham, and called platina, is made of 5 pounds of zinc to 8 of brass. Bronze is an alloy of copper with 7 to 10 per cent. of tin. This is the material used for cannon. With 8 per cent. of tin, it is the bronze for medals. With 20 of tin, the material for cymbals. With 30 to 33 parts of tin, it forms speculum metal, of which the mirrors for optical Instruments are made. Lord Rosse used for the speculum of his great telescope, 126 parts of copper to 57J parts of tin. The brothers Keller, celebrated for their statue castings, used a metal consisting of 91'4 per cent. of copper, 5-53 of zinc, 1-7 of tin, and 1-37 of lead. in equestrian statue of Louis XIV, 21 feet high, and weigh ing 53,263 French pounds, was cast by them in 1699, at a single jet. Bell-metal is made of copper, with a thiru to a fifth as much tin by weight, the proportion of tin varying according to the size of the bell and sound required. The Chinese gong contains 80 parts of copper to 20 or 25 of tin; to give it its full sonorousness, it must be heated and suddenly cooled in cold water. Sheet copper is made by heating the copper in a furnace and rolling it between iron rollers. Copper is also worked by forging and casting. In casting, it will not bear over a red heat without burning. How did the ancients use copper? What is the proportion of allor in the ancient bronze 7 306 METALS. 2. NOBLE METALS. 1. PLATINUM.-IRIDIUM.-PALLADIUM. NATIVE PLATINUM. In flattened or angular grains or irregular masses, the masses occasionally large. Crystalline form cubic, but seldom observed. Cleavage none Color and streak pale or dark steel-gray. Luster metallic, shining. Ductile and malleable. H=4 —4-5. Gr =1619. Composition. Platinum is usually combined with more or less of the rare metals Iridium, Rhodium, Palladium, and Osmium, besides copper and iron, which give it a darker color than belongs to the pure metal, and increase its hardness. A Russian specimen afforded, platinum 78'9, iridium 5'0, osmium and iridium 1'9, rhodium 0-9, palladium 0'3, copper 0'7, iron 11-0=98'75. Platinum is soluble in heated aqua regia. It is one of the most infusible substances known, being wholly unaltered before the blowpipe. It is very slightly magnetic, and this quality is increased by the iron it may contain. Dif. Platinum is at once distinguished by its malleability and extreme infusibility. Obs. Platinum was first detected in grains in the alluvial deposits of Choco and Barbagoa in South America, where it received the name platina, derived from the word plata, meaning silver. Although before known, an account by Ulloa, a Spanish traveller in America in 1735, directed at. tention in Europe, in 1748, to the metal. It has since been found in the Urals, on Borneo, in the sands of the Rhine, and in those of the river Jocky, St. Domingo; and recently traces have been observed i:n the Uilted States, in North Carolina. The Ural localities of Nischne Tagilsk, and Goroblagodat, have afforded much the larger part of the platinum of commerce. It occurs, as elsewhere, in alluvial beds; but the courses of platiniferous alluvium have been traced to a great extent up Mount La Martiane, which consists of crystalline What is the condition and appearance of native platinum? What I said of its crystallization? What is its specific gravity? With what is it usually combined? Where and when was it first found? Where else does it occur? PLATINUM. 309 rocks, and is the origin of the detritus. One to three pounds are procured from 3700 pounds of sand. Though commonly in small grains, masses of considerable size have occasionally been found. A mass weighing 1088 grains was brought by Humboldt from South America and deposited in the Berlin Museum. Its specific gravity was 18'94. In the year 1822, a mass from Condoto was de. posited in the Madrid museum, measuring 2 inches and 4 lines in diameter, and weighing 11,641 grains. A more remarkable specimen was found in the year 1827 in the Urals, not far from the Demidoff mines, which weighed 11l (more accurately, 11.57) pounds troy; and similar masses are now not uncommon. The largest yet discovered weighed 21 pounds troy; it is in the Demidoff cabinet. Russia affords annually about 80 cwt. of platinum, which is nearly ten times the amount from Brazil, Columbia, St. Domingo, and Borneo. Borneo affords six or eight hundred pounrds per year. The North Carolina platinum was found with gold in Rutherford county. It was a single reniform granule, weigh ing 2'54 grains. Other instances are reported from the southern gold region, and from Point Orfbrd and elsewhere in California. Uses. The infusibility of platinum and its resistance to the action of the air, and moisture and most chemical agents, renders it of great value for the construction of chemical and philosophical apparatus. The large vessels employed in the concentration of sulphuiic acid are now made of platinum, as it is unaffected by this corrosive acid. It is also used for crucibles and capsules in chemical analysis; for galvanic batteries; as foil or worked into cups or forceps for supporting objects before the blowpipe. It alloys readily when heated with iron, lead, and several of the metals, and is also attacked by caustic potash, and phosphoric acid, in contact with carbon; and consequently there should be caution when heat. ing it not to expose it to these agents. It is employed for coating copper and brass; also for painting porcelain and giving it a steel luster, formerly highly prized. It admits of being drawn into wire of extreme teniity: Dr. Wollaston obtained a wire not exceeding a two. housandth of an inch in diameter. Platinum is coined in Russia, but is not a legal tender What are the uses of platinum? 310 MFA rLs. The coins have the value of 11 and 22 tables each. The amount coined from 1826 to 1844 equals 21 millions of dollars. For many years after its discovery, platinum was almost a useless metal on account of the difficulty )f obtaining it in masses. The grains weld when heated, but because ot theil small size, this was interminable labor, and moreover the metal was not pure. Dr. Wollaston introduced the oroces now in use, which consists in dissolving the metal i\ nitro muriatic acid, and throwing down from the solution an orange precipitate by means of muriate of ammonia. This pr'ecipi tate (a double chlorid of platinum and ammonium) i, thea heated and thus reduced to the metallic state; the platil urn is now in an extremely minute state of division. This black powder (" spongy platinum") is next compressed in steel moulds by the aid of heat and strong pressure; and when sufficiently compact, is forged under the hammer and then re. duced at last to solid masses. This metal fuses readily before the ",compound blowpipe;" and Dr. Hare succeeded in 1837 in melting twenty-eight ounces into one mass.* The metal was almost as malle. able and as good for working as that obtained by the other process; it had a specific gravity of 19'8. He afterwards succeeded in obtaining fiom the ore masses which were 90 per cent. platinum, and as malleable as the metal in ordinary use, though somewhat more liable to tarnish, owing to some of its impurities. Platin-iridium. Grains of iridium have been obtained at Nischne Tagilsk, consisting of 76'8 iridium, and 19'64 platinum, with some palladium and copper. A similar platin-iridium has been obtained at Ava in the East Indies. Another from Brazil contained 27'8 iridium, 55'5 platinum, and 6-9 of rhodium. Iridosmine. A compound of iridium and osmium from the platinum mines of Russia, South America, the East Indies and California. The crystals are pale steel-gray hexagonal prisms: occurs usually in flat grains. H=6-7. Gr==19'5-21-1. Malleable with difficulty. The composition varies. One variety contains iridium 46-8, osmium 49'3, rhodium 3'2, iron 0'7. Another, iridium 25-1, osmium 74'9; another, iridium 20, osmium 80. They are distinguished by their superior hardness from the grains of platinum, and also by the peculiar odor of osmium when heated with niter. Iridosmine is common with the gold of California, and injures its quality for jewelry. It is proposed to separate it by keeping the gold melted for a short time, to allow the grains of iridosmine to settle. What is the value of Russian platinum coins? How is platinum worked into masses? * American Jour. Sci.. lxxiii, 195; xxxvlii, 155, 163 and ii ser. iv, 39 PALLADIUM. 31) The metal iridium is extremely hard, ani is used as well as rhodium for nibs to gold pens. Its specific gravity is 21S8. Rhodium (1 to 2 pel cent.) gives great hardness to steel, and would be a useful metal were it more abundant. NATIVE PALLADIUM. In regular octahedrons. Albo in hexagonal iXbles. Occurs mostly in grains, apparently composed of divergent fibers. Color steel-gray, inclining to silver-white. Ductile and malleable. H. above 4-5. Gr=11V8-12-2. Consists of palladium, with some platinum and iridium Fuses with sulphur, but not alone. Obs. Occurs in Brazil with gold, and is distinguished from platinum with which it is associated by the divergent structure of its grains. Selenpalladite is nothing but the native palladium. Uses. This metal is malleable, and when polished has a splendid steel-like luster which does not tarnish. A cup weighing 3* pounds was made by M. Breant in the mint at Paris, and is now in the garde-meuble of the French crown. In hardness it is equal to fine steel. 1 part fused with 6 of gold forms a white alloy; and this compound was employed, at the suggestion of Dr. Wollaston, for the graduated part of the mural circle, constructed by Troughton for the Royal Observatory at Greenwich. Palladium has been employed also for certain surgical intruments. Quite large masses of the metal palladium are brought from Brazil. It is extracted from the auriferous sands by first fusing it with silver, and consequently forming a quaternary alloy of gold, palladium, silver and copper, which is granulated by projecting it into water. By means of nitric acid all but the gold is dissolved; and from the solution, the silver is first precipitated by common salt as an insoluble chlorid, and then, after separating the chlorid, the palladium and copper are precipitated by plates of zinc. This pre. cipitate is redissolved in nitric acid, an excess of ammonia added, and then hydrochloric acid sufficient to saturate; a double chlorid of palladium and ammonia is deposited as a crystalline yellow powder, which on calcination produces spongy palladium. Describe native palladium? Where and how does it occur? Howl it used? 312 31 FT A LxS. 2. GOLD. Gold occurs mostly native, being either pure or alloyed with silver and other metals. It is occasially found miner. alized by tellurium. NATIVE GOLD. Monometric. In cubes, without cleavage. Also in grains, thin lafinna and masses; sometimes filiform or reticulated. Color various shades of gold-yellow; occasionally nearly silver-white, from the silver present. Very ductile and malleable. H =2'5-3. Gr=12-20, varying according to the metals alloyed with the gold. Composition. Native gold usually contains silver, and in very various proportions. The finest native gold from Russia yielded gold 98-96, silver 0-16, copper 0-35, iron 0-05; Gr= 19'099. A gold from Marmato afforded only 73'45 per cent. of gold, with 26'48 per cent. of silver; Gr=-12'666. This last is in the proportion of 3 of gold to 1 of silver. The following proportions also have been observed: 38 to 1; 5 to 1; 6 to 1; 8 to 1, and this is the most common; 12 to 1, also of frequent occurrence. Copper is often found in alloy with gold, and also palladium and rhodium. A rhodium-gold fiom Mexico gave the specific gravity 155 —16-8, and contained 34 to 43 per cent. of rhodium. Dif. Iron and copper pyrites are often mistaken for gold by those inexperienced in ores. Gold is at once distinguished by being easily cut in slices and flattening under a hammer. The pyrites when pounded are reduced to powder; iron pyrites is too hard to yield at all to a knife, and copper pyrites affords a dull greenish powder. Moreover, the pyrites give off sulphur when strongly heated, while gold melts without any such odor. Obs. Native gold is mostly confined to those suocrysalline slaty or schistoae rocks that abound in quartz veins, and more especially to talcose and chloritic slates. It occurs In what condition does gold occur in nature? What is the crystallization of native gold? What are its common forms in the rocks? Mention its characters. With what is it alloyed? How is gold distinguished from iron and copper pyrites? From what rocks is gold o' pi ned? GOLD 313 sparingly in granite, gneiss or mica slate, for the veins of these more highly crystalline rocks are commonly feldspathic or granitic rather than quartzose, and granitic veins seldom afford gold. The quartz veins often intersect the slaty rocks in great numbers, are generally very irregular in size, and often lie as beds conformable to the lamination. The quartz is frequently rather cellular, containing cavities in which it is crystallized. It generally contains more or less pyrites, and sometimes galena and other minerals. The decomposition of the pyrites leaves the quartz very cavernous, and some. what rusty in appearance; and occasionally a little sulphur lines the cavities, derived from the removed pyrites. The rock in this cavernous state, (as it is very liable to be near the surface,) is rather easily quarried out; but deep below, where the minerals are not removed by decomposition, mining is far more difficult. The pyrites itself is nearly as hard as quartz, when unaltered, and readily strikes fire with a steel. This pyrites is often very abundant, and contains throughout it consider. able gold; but the gold is so finely distributed, that little of it can be removed by the ordinary process of crushing and amalgamation, and nature's way of decomposing the pyrites and thereby making it drop its load, is the only effectual one. This is accomplished by exposing the pyrites in hiaps, with moisture and perhaps a little heat, by which it changes to copperas, which may be dissolved and the gold obtained. The galena of a gold region is also usually auriferous. Gold sometimes occurs in the slate rocks adjoining the veins, though mostly confined to the latter. The quartz may contain gold when none is visible to the naked eye. The minerals most common in gold regions are platinum, iridosmine, magnetic or titanic iron, iron pyrites, galena, copper pyrites, blende, tetradymite, zircon, rutile, heavy spar; also in some cases, brookite, monazite and diamond. Pla. tinum and iridosmine accompany the gold of the Urals, Brazil and California; and diamonds are found in the gold region of Brazil, and occasionally in the Urals and Eastern United States. Gold is widely distributed over the globe. It occurs in Brazil (where formerly a greater part of that used was obtained)'along the chain of mountains which runs nearly parallel with the coast, especially near Villa Rica, and in the 314 METALS. province of Minas Geraes; in New Grenada at Antioquia, Choco, and Giron; in Chili; sparingly in Peru and Mexico; in the southern of the United States. In Europe, it is most abundant in Hungary at Konigsberg, Schemnitz and Felso. banya, and in Transylvania at Kapnik, Vorospatak and Of. fenbanya; it occurs also in the sands of the Rhine, the Reuss and the Aar; on the southern slope of the Pennine Alps from the Simplon and Monte Rosa to the valley of Aosta; in Piedmont; in Spain, formerly worked in Asturias; in the,county of Wicklow, Ireland; in Sweden at Edelfors. In the Urals are valuable mines at Beresof, and other places on the eastern or Asiatic flank of this range, and the comparatively level portions of Siberia; also in the Altai mountains. Also in the Cailas mountains in Little Thibet. There are mines in Africa at Kordofan, between Darfour and Abyssinia; also south of Sahara in the western part of Africa, from the Senegal to Cape Palmas; also along the coast opposite Madagascar, between the 22d and 35th degrees south latitude, supposed to have been the Ophir of the time of Solomon. Other regions are China, Japan, Formosa, Ceylon, Java, Sumatra, western coast of Borneo, the Philippines, Australia, Van Diemen's land and New Zealand. The present total yield of the gold mines of the world is not less than 195 tons. Much the larger part of this (about 175 tons) comes from Asiatic Russia, South America, Aus. tralia and Calitbrnia. The Russian mines till recently ranked first in pro. ductiveness. They are principally alluvial washings, and these washings seldom yield more than 65 grains of gold for 4000 pounds of soil; never more than 120 grains. The alluvium is generally most productive where the loose material is most ferruginous. The mines of Ekaterinenberg are in the parent rock-a quartz constituting veins in a halt decomposed granite called " beresite," which is connected with talcose and chloritic schists. The shafts are sunk vertically in the beresite, seldom below 25 feet, and fiom them;atral galleries are run to the veins. These mines afforded betaween the years 1725 and 1841, 679 poods of gold, or about 30,000 pounds troy. The whole of the Russian mines viel led in 1842,970 poods of gold, or 42,000 pounds troy, ha)/ W lat is said of the distribution of gold over the globe? V nat.count'ies afford the greatest part of the gold of comrnm rce? GOLD. 315 of which was from Siberia, cast of the Urals. In 1843, the yield was nearly 60,000 pounds troy, or about $13,000,000; in 1845 it amounted to $13,250,000; and in 1846,to 1722'746 poods, equal to 75,353 troy pounds, and $16,500,000.* At the Transylvania mines of Vorospatak, the gold is ob. tained by mining, and these mines have been worked since the time of the Romans. The annual yield of Europe, exclusive of Russia, is ilot above $1,000,000. Austria afforded in 1844, 6785 mo ks. The sands of the Rhone, Rhine and Danube contain.i in small quantities. The Rhine has been most productive be. tween Bale and Manheim; but at present only $9000 are extracted annually. The sands of the richest quality contain only about 56 parts of gold in a hundred millions; sands containing less than half' this proportion are worked. The whole amount of gold in the auriferous sand of the Rhine is estimated at $30,000,000, but it is mostly covered by soil under cultivation. Africa yields annually at least 4500 pounds troy, ($850,000,) and Southern Asia and the East Indies 25,000 pounds. The mines of South America and Mexico were estimated by Humboldt to yield annually about $11,500,000; but the amount is now not over $10,000,000. Brazil of late has furnished about 6000 pounds troy; New Grenada, etc., 15,000; Peru 1900; Bolivia 1200; Chili 3000; in all for South America 27,100 pounds. Mexico yields about 10,000 pounds annually. It is estimated that between 1790 and 1830, Mexico produced $31,250,000 in gold, Chili $13,450,000, and Buenos Ayres $19,500,000, making an average annual yield of $16,050,000. The whole product of Europe, Asia, Africa and South America, is not far from 125,000 pounds troy, annually; and this is far less than is derived at the present time from either Australia or the United States. The gold mines of Australia afford at this time about What amount was furnished by Russia in 1846? What is the annual yield of the other mines of Europe? * The value of gold, silver and platinum, coined in Russia from 1644 to 1844, at present rates equals 545,360,317 silver-ubles, or 4(0,020,000 dollars, in addition to which, during the same period, the value of 37,500,000 dollars in copper was.coined. 316 METALS 250,000 pounds. These mines occur in eastern and south. eastern Australia, about the mountains called the Australian Alps, and their continuation north beyond the Blue Mountains. They were first made known to the world in 1851. The localities discovered were on Summer Hill Creek and the Lewis Pond River, (near lat. 330 N., long. 149 —150~ E.,) streams which run from the northern flank of the Coriobolas down to the river Macquarie, a river flowing westward and northward. It was afterwards found on the Turon river, which rises in the Blue Mountains; and finally a region of country 1000 miles in length, north and south, was proved to be auriferous. The coantry is a region of metamorphic rocks, granite and slates, and in some parts abounds in quartz veins. The gold has been obtained mainly from alluvial washings. Van Diemen's Land or Tasmania, and New Zealand, also afford the precious metal. The mines of California yield per year about 200,000 pounds troy, or $50,000,000. The first discovery was made early in the spring of 1848, on the American Fork, a tributary to the Sacramento, near the mouth of which Sutter's establishment was situated. Soon Feather river, another affluent, 18 or 20 miles north, was also proved to abound in gold about its upper portions; and it was not long after before each stream in succession, north and south, along the western slope of the Sierra Nevada was found to flow over auriferous sands. The gold as now developed extends along that chain, through the whole length of the great north and south valley which holds the rivers and plains of the Sacramento and San Joaquin. It continues south nearly to the Tejon pass, in latitude 35, and north beyond the Shasty mountains to the Umpqua, and less productively into Oregon and Washington territories. Gold also occurs in some places in the coast range of mountains. Even the very site of San Francisco has been found to contain traces Beyond the Shasty mountains there are important mines on the Klamath and the Umpqua, and some df the best on the sea-shore between Gold Biuff, in 410 30' south of the Klamath (30 miles south if Crescent City) to the Umpqua. What once was Rogue river is now called Gold river. T he gold of the Sierra Nevada occurs mainly about tne upper parts of the tributaries to the Sacramento and other GOLD. 317 rivers, rather high up among the mountains; and not only along the streams where the torrents perform annually the washing process, but also in the gravelly material or drift that covers the country, and over the slopes of the valley. At places along the valley where the descending waters meet an obstacle or a projecting rock, both in the river bed and on the declivities, " pockets " of gold are found. Certain layers of the drift are especially rich in the metal. This dritt material is explored by turning the streams across it by artificial channels, where nature has not prepared the way, and thus the gold is separated and gathered. The gold is mostly in thin scales or grains, usually of quite small size, and sometimes in plates or lumps; occasionally in masses of fifteen or twenty pounds, mixed more or less with quartz. Each region is generally distinguished by some peculiarity in the ji1 form or size of the scales. or their color, / the lighter colored containing the most silver. Some of the plates are bealtiftlly crystallized in dentritic or plumnltise forms made of united crystals. A trw I Af simple crystals of large size have 1eel 1 ^ found. The annexed figure represents one of natural size, figured and described by Mr. Alger, of Boston. The gold of the alluvial washings, as in other cases, has been derived from gold-bearing rocks. By some long action of denudation, those rocks have been extensively worn down to gravel and sand, and the gold is distributed along the water courses or on the slopes. As the metal is se very heavy-seven times heavier than the gravel-it has mostly been dropped by the waters high up the streams.'he smaller scales have been carried farthest away, and no doubt minute traces exist throughout the Sacramento valley. The forms of the scales have arisen partly from the original la. mellar form in the rocks, and partly from the process of wear. Quartz veins, rich in gold, have been found in many parts of the country, aind great efforts have been made to work them, especially'in Nevada, Tuolumne, and Placer counties. For a knowledge of particular localities in California, see an article by W. P. Blake, in the American Journal of Science, volume x, page 72, 1855. 31 METALS. Other gold mines exist in Lower California, the Great Basin and Now Mexico. The gold mines of the Eastern United States have pro. duced of late less than a million of dollars. They are mostly confined to the states of Virginia, North and South Carolina, and Georgia, or along a line from the Rappahannock to the Coosa in Alabama. But the region may be said to extend north to Canada; for gold has been found at Canaan, N. H., Bridgewater, Vt., Dedham, Mass., Albion and Madrid in Maine, and on the Chaudiere river and elsewhere in Canada. Gold also occurs in Arkansas and Texas. In Virginia, the principal deposits are in Spotsylvania county, on the Rappahannock, at the United States mines and at other places to the southwest; in Stafford county, at the Rappahannock gold mines, ten miles from Falmouth; in Culpepper county, at the Culpepper mines, on Rapidan river: in Orange county, at the Orange grove gold mine, and at the Greenwood rold mines; in Goochland county, at Moss and Busby's mines; in Louisa county, at Walton's gold mine; in Buckingham county, at Eldridge's mine. In North Car. olina, the gold region is mostly confined to the counties of Montgomery, Cabarrus, Mecklenberg and Lincoln, which are situated about in a line running N. E. and s. w., parallel nearly with the coast. The mines at Mecklenburg are prin. cipally vein deposits: those of Burke, Lincoln, McDowell and Rutherford, are mostly in alluvial soil. In Georgia, gold mines occur in Habersham county, and at many places in Rabun and Hall counties, and the Cherokee country. In South Carolina, the gold regions are the Fairforest in Union district, and the Lynch's creek and Catawba regions, chiefly in Lancaster and Chesterfield districts; also in Pickens county, adjoining Georgia. The only mine not deserted is the Dorn mine in the Abbeville district. There is gold also in eastern Tennessee. Viewing the gold region of the eastern United States as a whole, it is perceived that it ranges along the Appalachians, particularly the Eastern slope, from Maine to Alabama, having nearly a northeast and southwest course. Masses of gold of considerable size have been found in North Carolina. The largest was discovered in Cabarrus county; it weighed twenty-eight pounds avoirdupois, ("steel. yard weight," equals 37 Ibs. troy,) and was 8 or 9 inches long GOLD. i19 by 4 or 5 broad, and about an inch thick. In Paraguay, pieces from 1 to 50 pounds weight were taken from a mass of rock which fell from one of the highest mountains. Several specimens weighing 16 pounds have been found in the Ural, and one of 27 pounds: and in the valley of TaschkuTarganka, in 1842, a mass was detached weighing very nearly 100 pounds troy. This mass is now in the museum of the Institute of Mining Engineers at St. Petersburg. The largest mass yet discovered in any part of the world, is one from California, weighing 134 pounds 7 ounces, and affording 109 pounds 11 ounces of pure gold: it sold for ~5,532. Another of 27J pounds, here figured, was found at Forest Creek, Mount Alexander, in the colony of Victoria. It was 11 inches long and 5 in breadth at its broadest part. The origin of gold veins, or rather of the gold in the veins, is little understood. The rocks, as has been stated, are metamorphic slates that have been crystallized by heat; and they are the talcose and argillaceous, that have been but imperfectly crystallized, rather than the mica schist and gneiss which are well crystallized: and the veins of quartz which contain the gold, occupy fissures through the slates, and openings among the layers, which must have been made when the metamorphic change or crystallization took place. it was a period, for each gold region, of long continued heat (occupying, probably, a prolonged age,) and also of vast iip What is said of the gold rock of the United States? 320, A ALo. riftings and disturbances of the beds; tor the bleds are tilted at various angles, and the veins show where were the fractures of the layers, or the separations and gapings of the tortured strata. The heat appears not to have been of the intensity required for the better crystallization of the more perfectly crystalline schists. The quartz veins could not have been filled from below, by injection.-a view not now accepted for the generality of mineral veins. They must have been filled either laterally or from above. In all such conditions of continued heat beneath an ocean, the hot water would dissolve silica fieely within the rocks or from them, (as happens at the Geysirs of Iceland and-elsewhere,) so that the region would become one of hot siliceous solutions permeating and overlying the upheaving strata. Thus silica would be fiee to consolidate or metamorphose the strata, and to fill up all rents or openings, whether they were no thicker than a sheet of paper, or rods in width. The waters would work laterally into these fissures, as this would be the tendency of the internal flow or movement, and they would carry mineral material of various kinds with them; besides, the superficial waters might deposit what mineral matter they contained along with the silica; and at the same time vapors might rise from below along the lines of rents, and be still a third source of metallic or mineral material. Between these methods appears to lie the process by which the gold was introduced into the quartz veins, and it remains for further research to ascertain the particular facts in the case. The pyrites formed in the veins is usually aurifeirous, showing that they were crystallized under the same circumstances as the depositing of the gold in strings, crystals and grains. Murchison has stated, that in the Urals the gold diminishes on descending in a vein; but this is not yet regarded as an established truth. The time when the gold veins were formed may differ in different regions. Along our eastern coast it appears to have been after the coal period. An examination of a gold rock for gold is a simple process. The rock is first pounded up fine and sifted; a certain quantity of the sand thus obtained is washed in a shallow iron pan, and as the gold sinks, the material above is allowed to pass off into some receptacle. The largest part of the gold is thus left in the angle of the pan; by a repetition of the procss a further portion is obtained; and when the bulk GOLID 321 the bulk of sand is thus reduced to a manageable quantity the gold is amalgamated with clean mercury; the amalganl is next strained to separate any excess of mercury, and finlal. ly is heated and the mercury expelled, leaving the gold.- In this way by successive trials with the rock, the proportion of gold is quite accurately ascertained. It is the same pro. cess used with the larger washings, though on a small scale. Mercury unites readily with gold, and thus separates it from any associated rock or sand; and it is employed in all exten sive gold minings, though much gold may be often obtained by simple washing without amalgamation. The operation of hand washing is called in Virginia pan. ning. With a small iron pan, they wash the earth in a tub or in some brook, and thus extract much gold from the gravel or soil, which is said to pan well or pan poorly according to the result. Masses of quartz, with no external indications of gold, examined in the above way at a Virginia mine, afforded an average of more than eight dollars to the bushel of gold rock. When gold is alloyed with copper or silver, the mode of assay for separating the copper depends on the process of cupellation; and that for separating the silver, on the power of nitric acid to dissolve silver without acting on the gold. The process of cupellation consists in heating the assay in a small cup (called a cupel,) made of bone ashes, (or in a cavity containing bone ashes,) while the atmosphere has Jree access. The heated metal is oxydated by the air pass. ing over it, and the oxyd formed sinks into the porous cup, 1 leaving the precious metal 2 behind. The shape of the i ^~^g cupel is shown in fig. 1. In order to fuse the alloy and 11111 still have the atmosphere circulating over it, the cupel is placed in a small oven-shalped vessel, called a muffle (fig. 2:) it is of infasilie stone ware, and has a number of oblong holes, through which to admit the flame from the fire, and give exit to the atmosphere which passes into it. The muffle is inserted in a hole fitting it in the side of a vertical furnace, with the open mouth out How is a rock examined for gold? What are the processes for sepa rating gold from silver or copper? Describe the process of cuDellation 27* 3'2' METALS. ward and even nearly with the exterior surface of the fur nace. The fire is made within the furnace, below, around. and above; and after heating up, the cupel is put in the muffle with.the assay in its shallow cup-shaped cavity. It thus has the heat of the furnace to fuse the assay, and the air at the same time is drawn in over it through the large opening of the rmuffle. The oxygen of the atmosphere unites with the lead of the assay, and produces an oxyd, which oxyd sinks into the cupel, leaving the silver or gold behind. The completion of the process is at once known by the change of the assay suddenly to a bright shining globule. In the cupellation of gold containing copper, lead is melted with the assay. The lead on being fused in a draft of air oxydizes, and also promotes the oxydation of the copper, and both oxyds lisappear in the pores of the cupel leaving the gold behind, and the silver alloyed with it. In this process the gold is melted with three times its weight of silver, (a. quartation as it is termed, the gold being one part out of four of the alloy,) in order by its diffusion to effect a more com. plete removal of the silver as well as the contained copper. The cupel is placed in the heated furnace, and the gold, silver, and lead, on the cupel; the heat is continued until the surface of the metal is quiet and.bright, when the cupellation is finished; the metal then is slowly cooled and removed. The button obtained, after annealing it by bringing it to a red heat, is rolled out into a thin plate and boiled in strong nitric acid. This process is repeated two or three times with a change of the acid each time, and the silver is thus finally removed. At the United States mint, half a gramme of the gold is submitted to assay. The assay-gold and quartation-silver are wrapped in a sheet of lead weighing about ten times as much as the gold under assay. After cupellation, the plate of gold and silver, loosely rolled into a coil, is boiled for 20 minutes in 4~ oz. of nitric acid, of 20 to 22 Beaume; the acid is then poured off and another portion of stronger acid is added, about half the former quantity, and boiled 10 minutes; then the same again. The gold thus purified is washed and exposed to a red heat, for the purpose of drying and annealing it, and then weighed. Uses. The uses of gold are well known; and also that it owes a great part of its value to its extreme malleability, and the fact of its not tarnishing on exposure. Alth -ugh a costly metal, it is one of the cheapest means of ornament, SILVER ORES. 3 2 on account of the thinness of the leaves into which it is beaten. A grain of the metal may be made to cover 56* square inches of surface, and the thinnest leaf is but 1-280,000th of an inch thick. Perfectly pure gold is denominated gold of 24 carats, or fine gold. If it contains 22 parts of pure gold to 2 of silver, ior to I of copper and 1 of silver, it is said to be 22 carats fine; so also for 20 carats fine, it contains 20 parts of pure gold, The carat is divided into ~, 8, s, - parts, for a more min. ute specification of the quality of gold. The standard gold of the United States consists of 900 parts of gold to 100 of atl alloy of copper and silver. The eagle (10 dollars) contains 232 grains of fine gold. Aurotellurite, called also Sylvanite, is a grayish or silver-white mineral, containing gold combined with lellurium. 3. SILVER. Silver occurs native and alloyed; also mineralized with sulphur, selenium, arsenic, chlorine, bromine, or iodine, and in combination with different acids. The ores of silver fuse easily and decompose before the blowpipe, affording a globule of silver either alone or with soda; the globule is known to be silver by its flattening out readily under a hammer, and also by its sectility. The species vary in specific gravity from 5-5 to 10-5. NATIVE SILVER. Monometric. In octahedrons. No cleavage apparent. Occurs often in filiform and arborescent shapes, the threads having a crystalline character; also in lamina. Color and streak silver-white and shining. Sectile. Mal. leable. H=2-5-3. Gr —-103-105. Composition: native silver is usually an alloy of silver and copper, the latter ingredient often amounting to 10 per cent. [t is also alloyed with gold, as mentioned under that metal. A bismuth silver from Copiapo, S. A., contained 16 per cent. of bismuth. What surface may a grain of gold be made to cover? How much ure gold is there in the American eagle? What is the use of the ern carat? What is the condition of silver in nature? Describe native silver. 324 METALS. Before the blowpipe it fuses easily and affords a globule which becomes angular on cooling. Dissolves in nitric acid, from which it is precipitated by putting in a clean piece of copper. Dij. Distinguished by being malleable; from bismuth and other white native metals by affording no fumes before the blowpipe; by affording a solution with muriatic acid, which becomes black on exposure. Obs. Native silver occurs in masses and string-like ar borescences, penetrating rocks, and is found in igneous rock and in sedimentary strata, in the vicinity of dikes of trap and porphyry. The mines of Norway, at Kongsberg, formerly afforded magnificent specimens of native silver, but they are now mostly under water. One specimen from this locality, at Copenhagen, weighs five hundred pounds. Other European localities are in Saxony, Bohemia, the Hartz, Hungary, Dauphiny. Peru and Mexico also afford native silver. A Mexican specimen from Batopilas, weighed when obtained, 400 pounds; and one from Southern Peru, (mines of Huan. tajaya,) weighed over 8 cwt. In the United States, elegant specimens are associated with the native copper of Lake Superior. The silver generally penetrates the copper in masses and strings, and is very nearly pure, notwithstanding the copper about it. Much of the galena of the west contains a very small per centage of silver, and that of Monroe, Conn., yields nearly 3 per cent. Native silver has also been observed near the Sing Sing state prison; at the Bridgewater copper mines, N. J.; and in handsome specimens at King's mine, Davidson county, North Carolina. Uses. The uses of silver are, for the manufacture of va rious articles of luxury, for plating other metals, for philo. sophical instruments, for coinage, and also various purposes in the arts. For coins, it is alloyed in this country with copper, and is thus rendered harder and more durable; 1000 parts of the coin contains 100 parts of copper. When thi alloy is boiled with a solution of cream of tartar and sea salt, or scrubbed with water of ammonia, the superficia. How is native silver distinguished? How does it occur and in wha rocks? Where does silver occur in the U. States, and how? Wha are the uses of silver? SILVER ORES. 3'25 particles of copper are removed, and: surface of fine silvel is left. Silver is much less malleable than gold, and can. not be beaten into unbroken leaves less than 160,00(th part of an inch thick. In expressing in the arts the purity of silver, if absolutely pure, it is said to be silver of 12 peinyweights; it it con tain At of its weight of alloy it is called silver of 11 penny weights; if 2-12ths be alloy, it is called silver of 10 penny weights, and so on. rlVXK OGLAINCE.-Sulphvret ojf'lver. Monometric. In dodecahearons nore or less modirfec Fig. 22a, page 30, and also other modifications. Cleavage sometimes apparent parallel to the faces of the dodecahedron. Also reticulated and mas- sive. Luster metallic. Color and streak black- j' ) ish lead-gray; streak shining. lte, H= \ / 2- 25. Gr=7-19 7-4. Composition: when pure, silver 87-04, sulphur 12-96. Before the blowpipe it intumesces, gives off an odor of sulphur, and finally affords a globule of silver. Soluble in dilute nitric acid. Dif. Resembles some ores of copper and lead, and other ores of silver, but is distinguished as a sulphuret by giving the odor of sulphur before the blowpipe, and as an ore of silver by affording a globule of this metal, by heat alone. Its specific gravity is much higher than any copper ores, and it is sectile. Obs. This important ore of silver occurs in Europe, principally at Annaberg, Joachimstahl, and other mines of the Erzgebirge; at Schlemnitz, and Kremnitz, in Hungary, and at Freiberg in Saxony. It is a common ore at the Mex ican silver mines, and also in the mines of South America. A mass of sulphuret of silver, is stated by Troost, to have oeen found in Sparta, Tennessee. It also occurs with naive silver and copper in Northern Michigan. Uses. This is a common and highly valuable ore of sil ver. Besides this sulphuret of silver there are two others, which contain also sulphuret of iron or copper. What is the appearance of vitreous silver? What isits composition i What is its value' How is it distinguished? 326 METALS. Stromeyerite This is a steel-gray sulphuret of silver and copret containing 52 per cent. of silver. Gr=6'26. Before the blowpipe i, fuses and gives an odor of sulphur; but a silver globule is not obtained except by cupellation with lead. A solution in nitric acid covers a plate of iron with copper, and a plate of copper with silver indicating the copper and silver present. From Peru, Siberia, and Europe. Sternbergite. A sulphuret of silver and iron containing 33 per cent. of silver. It is a highly foliated ore resembling graphite, and like it leaving a tracing on paper; the thin laminae are flexible and may be smoothed out by the nail. Luster metallic, color pinchbeck brown. Streak black. It affords the odor of sulphur and a globule covered with silver on charcoal, before the blowipe. With borax a globule of silver is obtained. From Joachimstahl, in Bohemia. BRITTLE SILVER ORE.-Slulphuret of Silver and Antimony. Trimetric. In modified right rhombic prisms. M: M 115' 39. No perfect cleavage. Often in compound crystals. Also massive. Luster metallic; streak and color iron-black. H = 2 —25. Gr=6*27. Composition: Sulphur 16-4, antimony 14-7, silver 68'5, copper 0'6. Before the blowpipe it gives an odor of sulphur and also fumes of antimony, and yields a dark metallic glob. ule from which silver may be obtained by the addition of soda. Soluble in dilute nitric acid, and the solution indi. cates the presence of silver by silvering a plate of copper. Dif. The black color of this ore distinguishes it from the preceding; and more decidedly the fumes of antimony given off before the blowpipe. By the trial with nitric acid as well as by soda and the blowpipe, it is ascertained to be an ore of silver. Obs. It occurs with other silver ores at Freiberg, Schnee. berg, and Johanngeorgenstadt, in Saxony; also in Bohe. mia, and Hungary. It is an abundant ore in Chili, Peru, and Mexico. It is sometimes called black silver. An antimonial sulphuret of silver is said to occur with native silver and native copper, at the copper mines in Michigan. Uses. This is a very important ore for obtaining silver especially at the South American mines. Besides this there are other antimonial, and also arsenical and scleiferous ores of silver. What is the composition of brittle silver ore? its color and appear ice? For what is it valued I SILVER ORES. 327 Antimonial Silver, consists simply of silver and antimony (77 parts to 23,) and has nearly a tin-white color. Gr=9 4-9-8. Before the olowpipe gray fumes of antimony pass off, leaving finally a globule of silver. Called also Discrasite. Polybasite is near brittle silver ore in color, specific gravity, and composition, but contains some arsenic and copper, with 75'2 per cent. of silver. The crystals are usually in tabular hexagonal prisms, without cleavage. From Mexico and Peru. Miargyrite is an antimonial sulphuret of silver, containing but 36-5 per cent. of silver, and having a dark cherry-red streak, though ironblack in color. Before the blowpipe gives off fumes of antimony and an odor of sulphur; and with soda, a globule is left which finally yields a button of pure silver. Dark Red Silver Ore, and Light Red Silver Ore, are two allied ores rhombohedral in their crystals. The former contains silver (59 per cent.,) antimony, and sulphur, and has a color varying from black to cochineal red, a metallic adamantine luster, and a red streak. H-=25. Gr=5-7-5-9. The latterfeoifsists of silver, (654 per cent.) arsenic, and sulphur. [ts color and streak are cochineal red. H=2-2 -5. Gr=-545'6. Before the blowpipe these species fuse easily, give off fumes, one of antimony, the other of arsenic; and finally a globule of silver is obtained. They are abundant ores in Mexico, and occur also in Saxony, Hungary, and Bohemia. These ores have been called ruby silver. Eucairite is a seleniferous ore of silver and copper occurring in black metallic films. It gives before the blowpipe fumes of selenium, having an odor like that of decaying horse-radish. From Sweden. Another seleniferous ore, from the Hartz, called selensilver, contains silver and selenium, with a little lead, and crystallizes in cubes. Telluric Silver is a Russian ore, of a steel-gray color, containing silver 62-8, and tellurium 37'2. Another variety contains 18 per cent. of gold. Gr=83 —8-8. With soda, silver is obtained. Xanthocone is another silver ore, containing silver (66-2 per cent.) combined wih sulphur a'nd arsenic. Color dull red to clove-brown; powder yellow. HORN SILVER.-Chlorid of Silver. Monometric. In cubes, with no distinct cleavage. Also massive, and rarely columnar; often incrusting. Color gray, passing into green and blue, and looking somewhat like horn or wax. Luster resinous, passing into adamantine. Streak shining. Translucent to nearly opaque. Cuts like wax or horn. Composition: when pure, silver 75'3, chlorine 24'7. Fuses in the flame of a candle, and emits acrid fumes. Af. ords silver easily on charcoal. The surface of a plate of ron rubbed with it is silvered. Describe horn silver. Of what does it corsrst t 326 MrETArS. Obs. 4 very common ore and extensively worked in the mines of South America and Mexico, where it occurs with native silver. It also occurs at the mines of Sa'xony, Sibe ria, Norway, the Hartz, and in Cornwall. lodic Silver. Bromic Silver. Silver also occurs in nature united with iodine and bromine. These rare ores occur with the preceding in Mexico, and the latter in Chile, and at Huelgoet, in Brittany. Embolite. A chlorobromid of silver, resembling the chlorid or horn silver. Color asparagus to olive green. Contains 51 of chlorid of silver to 49 of bromid. This ore is not less common in Chili than the chlorid It has also been found in Chihuahua, Mexico. REMARKS ON SILVER AND ITS ORES. The ores from which the silver of commerce is mostly obtained are the vitreous silver, brittle or black silver ore, red silver ore and horn silver, in addition to native silver. Besides these, silver is obtained in large quantities from galena, (lead ore,) and from different ores of copper: and some galenas are so rich in silver that the lead is neglected for the more precious metal. This metal occurs in rocks of various ages, in gneiss, and allied rocks, in porphyry, trap, sandstone, limestone, and shales; and the sandstone and shales may be as recent as the middle secondary, as is the case in Prussia, and probably also in our own Michigan mining region. The silver ores are associated often with. ores of lead, zinc, copper, cobalt, and antimony, and the usual gangue is calc spar or quartz, with frequently fluor spar, pearl spar, or heavy spar. The silver of South America is derived principally from the horn silver, brittle silver ores, including arseniuretted silver ore, vitreous silver ore, and native silver. Those of Mexico are of nearly the same character. Besides, there are earthy ores called colorados, and in Perupacos, which are mostly earthy oxyd of iron, with a little disseminated silver; they are found near the surface where the rock has undergone partial decomposition. The sulphurets of lead, iron, and copper, of the mining regions, generally contain silver, and are also worked. The mines of Mexico are most abundant between 18~ and 24~ north latitude, on the back or sides of the Cordilleras and especially the west side; and the principal are those of the districts of Guanaxuato, Zacatecas, Fresnillo, Sombrerete, Catorce, Oaxaca, Pachuca, Real del Monte, Moran, and Pasco. The veins traverse very different rocks in these regions. The vein of Guanaxuato, the most productive in Mexico, intersects argillaceous and chloritic shale, and porphyry; it affords onefourth of aH the Mexican silver. The Valencian mine is the richest in Guanaxuato, and has yielded for many years, from one to two millions of dollars annually. In the district of Zacatecas the veins are in grayWhere is horn silver a common ore? From what ores is the silver it commerce mostly obtained? How do they occur? What are the onlmmon ores of South America? SILVER ORES. 329 wacke. In Sombrerete they occur in limestone, and there are extensive veins of the antimonial sulphuret, one of which ga; e in six months 700,000 marcs, (418,000 lbs. troy) of silver. The Pachrca, Real del Monte, and Moran districts, are near one another. Four great parallel veins transverse these districts, through a decomposed porphyry. From the vein Biscaina, in Real del Monte, $5,000,000 were realized by the Count de Regla, in twelve years. In South America the Chilian mines are on the western slope of the Cordilleras,. and are connected mostly with stratified deposits, of a shaly, sandstone, or conglomerate, character, or with their intersections with porphyries. The chlorids and native amalgams are found in regions more towards the coast, while the sulphurets and antimonial ores abound nearer the Cordilleras. The mountains north of the valley of Huasco contain the richest silver mines of Chili. The mines of Mt. Chanarcillo produces at the present time more than 80,000 marcs of silver per year. The veins abound in horn silver, and begin to yield arsenio-sulphurets at a depth of about 500 feet. The mines of Punta Brava, in Copiapo, which are nearer the Cordilleras, afford the arseniuretted ores. In Peru, the principal mines are in the districts of Pasco, Chota, and Huantaya. Those of Pasco are 15,700 feet above the sea, while those of Huantaya are in a low desert plain, near the port of Yquique, in the southern part of Peru. The ores afforded are the same as in Chili. The mines of Huantaya are noted for the large masses of native silver they have afforded. The Potosi mines in Buenos Ayres, occur in a mountain of argillaceous shale, whose summit is covered by a bed of argillaceous porphyry. The ore is the red silver, the vitreous ore along with native silver. It has been estimated that they have afforded since their discovery $1,300,000,000. These mines have diminished in value, though they still rank next to those of Guanaxuato. In Europe the principal mines are those of Spain, of Kongsberg in Norway, of Saxony, the Hartz, Austria, and Russia. The mines of Kongsberg occur in gneiss and hornblende slate, in a gangue of calc spar. They were especially rich in native silver, but are now nearly exhausted. The silver of Spain is obtained mostly from galena, and principally in the Sierra Almagrera in Grenada. The mines of Saxony occur mostly in gneiss, in the vicinity of Freyberg, Ehrenfriedensdorf, Johangeorgenstadt, Annaberg and Schneeberg. The ores of the Hartz are mostly argentiferous copper pyrites and galena, yet the red silver, vitreous silver ore, brittle silver ore, and arsenical silver, occur, especially at Andreaskreutz, and the mines of that vicinity. The rock intersected by the deposits is mostly an argillaceous shale. Carbonate of lime is the usual gangue, though it is sometimes quartz In the Tyol, Austria, sulphuret of silver, argentiferous gray copper, and mispickel occur in a gangue of quartz, in argillaceous schist. The Hungarian mines at Schemmitz and Kremnitz, occur in syenite and hornblende porphyry, in a gangue of quartz, often with calc spar or heavy spar, and sometimes fluor. The ores are sulphuret of silver Where are the principal mines in Europe? 28 3130 METALS. gray copper, galena, blende, pyritous copper and iron; and tne galena and copper ores are argentiferous. The Russian mines of Kolyvan in the Altai, and of Nertchinsk in the Daouria mountains, Siberia, (east of Lake Baikal,) are increasing in value, and yield annually at this time, 58,000 troy pounds of silver. The Daouria mines afford an argentiferous galena which is worked foi its silver. It occurs in a crystalline limestone. The silver ores of the Altai occur in silurian schists in the vicinity of porphyry, which contain besides silver ores, gold, copper, and lead ores. In England argentiferous galena is worked for its silver. 40,000 tons of the ore were reduced in 1837, one half of which contained 8 to 83 oz. of silver to the ton of lead, and the other half only 4 to 5 oz. ot ilver. In the United States, the Washington silver mine, in Davidson coun ty, N. Carolina, had afforded up to 1845,30,000 dollars of silver. The native silver of Michigan is associated with copper in trap and sandstone. These mines promise to be highly productive. The silver mines of the world have been estimated to yield at the present time $50,000,000 annually. The annual product of the several countries of Europe is nearly as follows: Pounds troy. Pounds troy British Isles, 70,000 Saxony, the Hartz, and 120000 France, 5,000 other parts of Germany, Austria, 90,500 Belgium, 440 Sweden a!;d Norway, 20,000 Piedmont, Switzerland and ) 00 Spain, 130,000 Russia, 5,00 making in all nearly 500,000 troy pounds, or about 7,750,000 dollars annually. This is small compared with the amount from America, which at the beginning of the present century equaled 2,100,000 pounds, or 311 millions of dollars, nearly six times the above sum; and it is probable that these mines will again yield this amount when properly worked. The annual amount from Mexico is set down at 1,750,000 pounds, and from Chili, Peru and Bolivia, near 700,000 pounds. The whole sum from Russia, Europe and America, makes nearly 3,000,000 pounds troy. The common modes of reducing silver ores in the large way arc two; by amalgamation, and by smelting. Both mercury and lead have a strong affinity for silver, and these reducing processes are based on this fact. In amalgamation, the silver ore is brought to the state of a chlorid by a mixture of the powdered ore (or " schlich,") with about ten per cent. of common salt; the chlorid is reduced by means of salts or sulphurets of iron, or metallic iron in filings, and at the same time mercury which has been added, combines with the liberated silver, and thus separates it in the condition of an amalgam, (a compound of mercury and silver.) The mixture of salt and "schlich" requires several days to become complete. Heat is employed at the Saxon mines, but not at hose of Mexico, where the climate is tropical. After the mercury is ut in, (6 or 8 parts to 1 of silver,) the mixture is kept in constant agiWhere are the Russian mines? What is the yield of the silvel nines of the world? What was afforded by South America at the beirsning of this century? Describe the process of almalgamation. SILVER ORES. 38 1 tation until the process is finished. In the best arrangements, at ix Saxony, this agitation is performed in revolving barrels, and the resul s accomplished in a few hours; but in Mexico it is effected by the reading of mules or oxen, and requires two or three weeks or more. The amalgam, separated from the muddy mass, by a current of water or washing, is then filtered of the excess of mercury; as a last step it is subjected to heat in a distilling furnace, by which the silver is left behind, the mercury passing off in a state of vapor to be condensed in a condensing chamber or receptacle. The loss of mercury by the process is often large. In case of the ordinary sulphurets and arseniurets of silver, or the chlorid, in Mexico and South America, the poorer ores are first fuseu with a flux, and the result, (called the " matt") is then roasted to expel the sulphur; afterwards it is mixed with better ores, again fused, and on cooling, again roasted. This fusion and roasting is again repeated with the best ores. The result from this fusion is next mixed thoroughly with melted lead; the lead separates the silver; and the impurities which float on the surface, are removed in plates as a crust cools, to be again melted with new ores, as the slag is apt to contain some of the Silver. When the argentiferous galena is the ore, it is reduced by roasting in a reverberatory furnace in the ordinary way for lead ore; the resulting lead contains also the silver. The accompanying sketch represents the essential characters of a reverberatory furnace. It is a transverse section. a is the grate on which the fire is made, and from which the flame proceeds through the hor- e izontal chamber or gen- eral cavity of the furnace, (usually very low,) to the flue at e. b is the sole of the hearth, for rereceiving the ore or assay, having an elliptical or circular form according to the shape of the furnace; c is the fire bridge, separating the fire from the sole; d is the arched roof. The flame plays horizontally over the charge of ore, and as the air may be made to pass freely with it, we may have in such a furnace a combined effect derived from the heat and the presence of the atmosphere; the ore, or its metal, if capable of uniting with the oxygen of the atmosphere, may be oxydated by the process, precisely as in the outer or oxydating flame of the blowpipe. In an ordinary blast furnace, (page 233,) the ore and its flux are confined from the atmosphere, (except the air that enters with the blast,) and the resuit is the reduction of an ore or its deoxydation, as in the inner or reducing flame of the blowpipe. This latter effect may in many cases be obtained also with a reverberatory furnace, when the atmosphere is excluded except what is essential to feeding the fire. In the reverberatory furnace, there is a small door near the fire-grate, a, for putting in fuel. There is also an opening either at top, or on the Describe a reverberatory furnace. :^3'.'-], METALS. sild,,1lor wr: d luiilg the charge; also there may be tne cr nore doors on each slde for working the charge while exposed to the heat. There may also be a tap hole for drawing off the reduced metal into one or more pots attached for the purpose; another in some cases for the es cape of slag as in cupellation, and where there is a vaporizable ingredient to be condensed, one or two flues leading to a condensing chamber. In large establishments several of these reverberatory furnaces connect with a single chimney. They are actually like -arge elliptica or circular ovens, of brick or stone, communicating with a common flue. In reverberatory furnaces adapted for melting metals, the hearth is a gently inclined plane, sloping to a spot towards one end, in order thai the fused metal may flow down together and be convenient for drawing off. For many other purposes, the sole is flat, and the depth is greater than in the above figure. To separate the silver from the lead, the lead is heated in a reverberatory furnace, the hearth of which is covered with wood ashes ant clay, so as to give it the nature of a cupel. The air received through an aperture on one side, passes over the metal in fusion, in a constant current, oxydizing it and changing it to litharge, which is from time to time drawn out; finally the lead is thus removed, and the silver remains nearly pure. The completion of the process is known by the metal becoming brilliant. It is again subjected to another similar operation, and thus rendered quite pure. The litharge from the latter part of the process is also subjected to another operation for the silver it usually conrains. According to Pattinson's new process, adopted in England, the silver is separated by melting the lead, and, as it begins to cool, straining oun the crystals with an iron strainer. The portion left behind contains nearly all the silver. This is several times repeated, each time the remaining lead becoming richer in silver. This is then cupelled. Ar ore containing only 3 ounces of silver to the ton of lead, (or but 110,000th part,) may thus be profitably worked, and with little loss of lead. When the ore containing silver is a copper ore, as is often the case with gray copper ore, the calcined ore is mixed with lead or lead ore, and fused and calcined, and the resulting products are either liquated to sweat out the silver or cupelled. In liquation, the copper is run into )igs, (called liquation cakes,) and kept above a red heat for two or three days; the lead first melts and flows in drops into cast iron troughs, carrying with it the silver, which is afterwards obtained by cupelling. The copper still contains some of the lead. In trials by cupellation, a piece of lead of known weight is placed in a cup of bone-ashes, and this is subjected to heat in a small air chamber or oven, and placed in a furnace so that the air shall have free access. The lead is oxydized, and the oxyd sinks into the cupel, leaving a globule of silver behind. The globule being then weighed, and compared with the weight of lead, the proportion of silver is ascertained Silver may thus be found in almost any specimen of the lead of corn What is the process of amalgamation with an argentiferous lead ore What is the mode of trial by. cunellation? si LVER ORE. 333 merce, however small the proportion. The weight of the globule, especially when quite minute, may be also ascertained by measurement, according to a scale given by Prof. W. W. Mather, in the American Journal of Science, volume iii, second series, page 414. Much that has been mentioned in the preceding pages on the American mines oi silver, has been derived from an article by Prof. Mather, in volume xxiv of the same Journal. Other modes of reducing silver ores without quicksilver, have been proposed. According to one, the ore is calcined with common salt, as in Mexico, and converted thus to a chlorid. It is then removed to some proper vessel, and a hot solution of salt poured over it; this takes up the chlorid of silver and holds it in solution. The liquid is transferred to another vessel, and by means of metallic copper the silver is deposited.. Another process consists in roasting the sulphurets and converting them in a reverberatory furnace to sulphates; then by boiling water, dissolving the sulphates in a proper vessel, and finally precipitating as above by copper. This process requires tile presence of a good deal ot sulphur, and is the best when there is much iron and copper pyrites present. In the assay to separate copper from silver, the alloy is dissolved in nitric acid, and the silver precipitated ill the state of a chlorid by common salt. The amount of silver may then be ascertained by weighing the precipitated chlorid, and observing that 75-33 per cent. of the chlorid is pure silver. SUPPLEMENT. Forms of Gems.-Gems are cut either by cleaving, by sawing with a wire armed with diamond dust, or by grinding. Some remarks on the cutting of the diamond are given on page 83. The harder stones, as the sapphire and topaz, are cut on a copper wheel with diamond powder soaked with olive oil, and are afterwards polished with tripoli. For other gems, less hard, a lead wheel with emery and water is first used, and then a tin or zinc wheel with putty of tin or rotten stone and water. The following are some of the common forms. It will be remembered that the upper truncated pyramid is called the table, the lower part or pyramid, the collet, and the line of junction between the two pairts, the girdle. Figures 1 and 2 represent the brilliant, the best form of the diamond, used also for other stones, as well as pastes. Figs. 3 and 4 are views of a variety of the rose diamond. Figs. 5 and 6 the same of an emerald. The cut in steps is called the pavilion cut. Fig. 7 is an upper view of a mode of cutting the sapphire. A side view would be nearly like figure 6, except that the collet is more like that of igure 8. Fig. 8 represents a side view ot an oriental topaz. The table has the brilliant cut, like figs. 1 and 2. Figure 9 represents a Bohemian garnet, which is made thin because its color is deep. The common topaz is cut like figure 8; often also like figure 9, but much thicker, and frequently having the table bordered by two or more rows af triangular facets. Figure 10 is a very simple table. Figures 11 and 12 represen!t the form "en cabochon" given the opal; and figures 12 *.1d 13, " en cabochon" with facets, a mode of cutting the chrysobcrul ~ 3 4 ~ SVPPLEMENT. The following are some of the common forms. It will be remem. bered that the upper truncated pyramid is called the table, the l]wer part or pyramid, the collet, and the line of junction between the two parts, the girdle. Figures 1 and 2 represent the brilliant, the best form of the diamond, used also for other stones, as well as pastes. Figs. 3 and 4 are liews of a variety of the rose diamond. Figs. 5 and 6 the same of an emerald. The cut in steps is called the pavilion cut. Fig. 7 is an I 2 3 <, t7_ \l 14 upper view of a mode of cutting the sapphire. A side view would be nearly like figure 6, except that the collet is more like that of figure 8. Fig. 8 represents a side view of an oriental topaz. The table has the brilliant cut, like figs. 1 and 2. Figure 9 represents a Bohemian garnet, which is made thin because its color is deep. The common topaz is cut like figure 8; often also like figure 9 but much thicker, and frequentl having the table bordered by two or more rows of triangular facets. Figure 10 is a very simple table. Figures 11 and 12 represent the form " en cabochon" given the opal; and figures 12 and 13, " en cabochon" with facets, a mode of cutting the chrysoberyl. SUPPLEMENT. 335 The form of the diamond after being cut anew, is represented in the following figures, which are of natural size: This re-cutting has diminished the weight of the diamond o. -; one third, a sacrifice of magnificence to mere ornamental brilliancy CHAPTER VII. CHEMICAL COMPOSITION AND FORMULAS OF MINERALS. On a former page a brief explanation is given of the constitution of minerals. The following table contains the names of all the elements thus far discovered by Chemistry, together with the abbreviations or symbols by which they are indicated in chemical formulas, and the combining or atomic weights. Thus Al stands for the element Aluminium, Sb for Antimony (derived from Stibium, the Latin name for Antimony). As all the elements combine with oxygen, and oxyds (as such compounds are called), are the most common of all compounds, Berzelius proposed to use a dot over a letter for oxygen, that is, one dot for one proportion of oxygen, two for two proportions, three for three proportions, &c. In this way, Ba means that one part of oxygen is combined with one of Baryum; the compound is protoxyd of baryum. So P signifies that five parts of oxygen are combined with one of phosphorus; the compound is phosphoric acid. Again to express two of Aluminium, a bar crosses the letter A, so that X;l means a compound of three of oxygen and two of aluminium; Pe means three of oxygen and two of iron, or a sesquioxyd of iron. Besides the atomic weights of the dlements, the principal occurring oxyds are given, with their atomic weights, and also the percentage of oxygen in each. Table of Atomic Weights. ALUMINIUM, Al, 171 25 Alumina, &1, 642-5 (0, 46'7) &NTIMONY (Stibium), Sb, 1612-5 ARSENIC, As, 937'5 BARYUM, Ba, 856-25 Baryta, Ba, 956-25 (0, 10'46) BISMUTH, Bi, 2600 BORON, B, 136-2 Boracic acid, B3, 436-2 (0, 68-8) BROMINIE, Br, 1000 TABLE OF ATOMIC WEIGHTS. 33*7 CADM, M, Cd, 696'8 CALCIUM, Ca, 250 Lime, Oa, 360 (0, 28'57) CARBON, C, 75 Carbonic acid, C, 275 CERIUM, Ce, 687-5 Protoxyd of C., Oe, 687-5 (0, 14'55) CHLORINE, Cl, 443-3 Hydrochloric acid, HC1, 455-8 CHROMIUM, Cr, 333-75 Oxyd of Ch., Jr, 967-5 (0, 3-0) Chromic acid, Or, 633-75 (0, 47'8) COBALT, Co, 368-65 COLUMBIUM, Cb, 2300? Columbic acid, Ob, 2600 (0, 11-5) COPPER (Cuprum), Cu, 396-25 Oxyd of Copper, Ou, 892-5 (0, 11-2) Oxyd of Copper, Ou, 496-25 (0, 20-16) DIDYMIUM, D. ERBIUM, Eb. FLUORINE, F, 237'6 Hydrofl. acid, HF, 250-0 GLUCINUM (Beryllium), Be, 58-75 Glucina, 3e, 476-25 (0, 63) GOLD (Aurum), Au, 231-26 HYDROGEN, H, 12'Water, f[, 112-5 (0, 88-89) IODINE, I, 1587-5 IRIDIUM, Ir, 1237'5 IRON (Ferrum), Fe, 350 Protoxyd of I., Fe, 450 (0, 22-22) Sesquioxyd of I., 3Pe, 1000 (0, 30) LANTHANUM, La, 687'6 Protoxyd of L., ta, 687-6 (0, 14'6) LEAD (Plumbum), Pb, 1294'6 Protoxyd of Lead, Pb, 1394-6 (0, 7-17) rITHIUM, Li, 81-6 Lithia, Li, 181-6 (0, 556) MAGNESIUM, Mg, 150 Magnesia, Mg, 260 (0, 40) 338 CHEMICAL COMPOSITTON OF MINERALS. MANGANESE, Mn, 344'7 Protoxyd of M., An, 444-7 (0, 22'5) Sesquioxyd of M., Mtn, 989-4 (0, 30-3) MOLYBDENUM, Mo, 575 Molybdic acid, Mo, 875 NICKEL, Ni, 369'3 Protoxyd of Ni., Si, 469-3 (0, 213) NITROGEN, N, 175 Nitric acid, S, 675 (0, 74) OSMIUM, Os, 1243-6 OXYGEN, 0, 100 PALLADIUM, Pd, 665-5 PHOSPHaRUS, P, 387-5 Phosphoric acid, ~, 887-5 (0, 56-84) PLATINUM, Pt, 1237-5 POTASSIUM (Kalium), K, 488-9 Potassa, K, 588-9 (0, 16-98) QUICKSILVER (Hydrargyrum), Hg, 1250 RHODIUM, Rd, 652 RUTHENIUM, Ru, 652 SELENIUM, Se, 493-75 SILICIUM, Si, 266-25 Silica, Si, 566-25 (0, 52-98) SILVER (Argentum), Ag, 1350 SOlIUM (Natrium), Na, 287-5 Soda, Na, 387-5 (0, 25-8) S'rUONTIUM, Sr, 547-5 Strontia, Sr, 6475 (0,15-44) SULPHUR, S 200 Sulphurous acid, S, 400 Sulphuric acid,, 500 (0, 60) TANTALUM, Ta, 2300 Tantalic acid, ta, 2600 TELLURITM, Te, 801-8 ERB.RIUM, Tb. THORIUM, Th, 743-9 TvlN (Stannum), Sn, 725 Oxyd of Tin, Sn, 925 (0, 21-6 TirANIUM, Ti, 312-5 Oxyd of Titanium, Si 925 (0, 32-4J Titanic acid, Ti, 512-5 (0, 8'; CHEMICAL COMPOSITION OF MINERALS. 339 TUNGSTEN (Wolfram), W, 1150 Tungstic acid, W', 1450 URANIUM, U, 650 Protoxyd of U., At, 850 Peroxyd of U., 4, 1800 VANADIUM, V, 856-9 YTTRIUM, Y, 402'5 Yttria, y, 502'5 (0, 19-9) ZINC, ZU, 406-6 Oxyd of Zinc, 2n, 506-6 (0, 19-74) ZIRCONIUM, Zr, 419'7 Zirconia, Zr, 1139-5 (0, 26-3) By atomic weights is understood the combining prop rtions of the elements. For example, when iron and oxygen combine, they unite in the proportions of 350 parts by weight of iron to 100 of oxygen, or in some simple multiple of these numbers. The protoxyd contains one part or atom of each, and has therefore the atomic weight 450; the peroxyd (more precisely sesquioxyd) contains 2 of iron (2X350=700) to 3 of oxygen (3 X 100=300), and therefore has the atomic weighs 1000 (700-300= 1000). To ascertain the per-centage of oxygen in this oxyd, we have 300 of oxygen in 1000 parts; hence the ratio,-1000 are to 300 as 100 to the number of parts in 100; therefore dividing 300X100 by 1000 give the oxygen per-centage. Hence too if we multiply the percentage of oxygen by the atomic weight of the oxyd, we obtain as a result, after dividing by 100, the oxygen amount in the compound. For alumina, 46'7X642'5 -100=300, the amount of oxygen; and in this way the correctness of the oxygen per-centage may be verified. The mode of deducing chemical formulas may be illustrated by two or three examples. 1. We have an analysis of Red Silver Ore as follows: Silver 59'02, antimony 23-49, and sulphur 17'49 per cent It is desired to ascertain the relative number of atoms of each element in the compound. This number must depend on the weights of the atoms, as compared with the quantity of each, for the less the weight, the greater the number of atoms. The rule consequently is,-Divide the per-centage of each element by the atomic weight of the same; as, 5'02 by 340 CHEMICAL COMPOSITION OF MINERALS. 1350, the atomic weight of silver, and so on. (See preced ing table.) This process gives the relation, 0'0437: O0146: 00875, and dividing each by the smallest, to simplify it, it becomes 3 1:6, which is therefore the number of atoms of each, silver, antimony, and sulphur. The formula 3Ag+lSb+6S, or Ag3 Sb S6, expresses this relation. As chemistry makes known a sulphuret of silver consisting of 1 of sulphur to 1 of silver, and also a sulphuret of antimony containing 3 of sulphur to 1 of antimony, the ingredients are regarded as thus combined in the compound. The 3Ag take 3S, making 3AgS, and leave 3S for the ISb to form I(SbS3); so that Red Silver Ore is supposed to be represented by the formula 3AgS+SbS3 or Ag3Sb, if the mark (') be used, as is common, for sulphur. 2. An analysis of Feldspar gives in 100 parts, Silica 64'78, Alumina 18-38, Potash 16-84. Now if we ascertain the proportion of oxygen in these constituents we learn the ratio of the constituents, since we know that silica contains 3 of oxygen, alumina 3, and potash 1. From the above table we find that 100 of silica contain 52'98 of oxygen; consequently if 100 give 59'98, the amount in 64-78 parts will be found by multiplying 52-98 by 64'78, and dividing by 100; or what is equivalent, multiplying 0'5298 by 64'78. So in 100 parts of alumina the oxygen is 46-7; hence the oxygen in 18-38 parts of alumina will equal 18'38X46'7.-100. In this way we ascertain that 64'78 of silica contain 34-32 oxygen, or dividing 12 18-38 of alumina " 8-58 ". each by the 3 16'84 of potash " 2-86 " mallest, 1 Hence the amount of oxygen in the potash, alumina, and silica, is as 1:3: 12. Now as each atom of silica contains 3 of oxygen, 12 atoms of oxygen correspond to 4 of silica: so also 3 of oxygen for the alumina correspond for a like reason to I of alumina; and 1 of oxygen for the potash to 1 atom of potash. The compound therefore contains 4 parts of silica to 1 of alumina and 1 of potash. CHEMICAL FORMULAS OF MINERALS. 341 The next step in the usual method, is to determine how these constituents are combined; how much of the silica with the potash, and how much with the alumina. Reference is made to the possibility or probability of certain compounds, which Chemistry alone can teach; but aid is found in the principle, that the number of atoms of oxygen in each acid and base is usually some simple multiple, the one of the other. If in the above compound, 1 of silica be united with 1 of potash, the ratio alluded to is 1 to 3; and if the alumina be combined with the remaining 3 atoms of silica, the same ratio holds. This is the mode of combination commonly adopted; it is expressed in the following formula, the dots as explained, indicating the oxygen:' Si+;l Si. The index 3 expresses the number of atoms of silica: had the 3 been written as a prefix, thus, s;1 Si, it would have meant 3 atoms of a compound of silica and alumina. The formula might also be written with equal precision, and without dividing the silica between the bases, as follows: (KR+^l) gi4. In a similar manner, an analysis of Garnet affords the ratio of ingredients as follows: 3 of lime (30a), 1 of alumina (11), 2 of silica (2Si), corresponding to the oxygen ratio 3: 3: 6 or 1:1: 2. Apportioning the silica to the bases, we have the formula Ca3Si+ASli, in which the oxygen ratio for each member is I: 1. Idocrase and Meionite afford other simple examples. 3. In Feldspar, above cited, the protoxyd portion is often not potash alone, but part soda or lime. Again, in Garnet, the protoxyds, instead of being all lime, may be part magnesia, protoxyd of iron, &c. In each case, however, all the protoxyds added together, make up the same specific number of atoms as if there were but one alone. So the peroxyd portion may not be all of it alumina, but part peroxyd of iron, the amount of this peroxyd of iron being just equivalent to the deficiency in the alumina; that is, an equivalent not in actual weight, but in atomic weight. In Garnet, as stated above, the oxygen ratio is 1: 1: 2; and whatever the 342 CHEMICAL COMPOSITION OF MINERALS. peroxyds or protoxyds, the ratio still holds. Suppose an analysis of Garnet affords the per-centage, Silica 39-6, alumina 22'5, lime 32'6, protoxyd of iron 5'3: we ascertain the oxygen in each constituent in the manner explained, (in the Silica, by multiplying 0-5298 by 39-6,-in the alumina, by multiplying 0-467 by 22-5,-in the lime by multiplying 0-2857 by 32-6,-in the protoxyd of iron by multiplying 0-2222 by 5'3); then on adding the oxygen of the protoxyd of iron to that of the lime, the amount just equals that of the alumina, as the oxygen ratio requires. Moreover the oxygen of all the protoxyds and peroxyds together equals the oxygen of the silica. As different protoxyds may thus replace one another, and as different peroxyds likewise admit of mutual replacement, it is common to write R as a general symbol for the protoxyds of a compound, and f for the peroxyds. It is also common to write the special symbols of the protoxyds which replace one another, in parentheses, with a comma between them. Thus in the Garnet referred to, in which lime and protoxyd of iron replace one another, the general formula may be either R3Si+SldSi; or (a, le)3Si+;lgi. The proportions of the lime and protoxyd of iron are not here stated, but may be; if I: 2, the formula becomes (~0a+IFe)3Si+l'Si. Again, the formula (Oa, lg)O, signifies that the compound is a carbonate of lime and magnesia, in definite or indefinite proportions; (JCa+lSIg)C that the proportion is 1:; (aOa+ lMg)C that the proportion is 2: 3, 2 and 3 having this ratio, and together equaling a unit. RA is a general expression for a carbonate of any protoxyd. 4. The formula for Garnet, 3i'i+;iISi, may also be written with equal precision as follows: (qk+AA1)Si, the ratio 1:1: 2 being still retained, and the fact being also presented to the eye that the oxygen of all the oxyds is to that of the silica as: 1. In Gehlenite, another silicate of alumina and lime, the oxygen ratio is 3: 3: 4, which gives 6: 4 or 3: 2 for the ratio of the oxyds and silica (that is, the oxygen of the silica is two-thirds that of all the oxyds), while CHEMICAL FORMULAS OF MINERALS. 3 3 that of the protoxyds and peroxyds is 1:1, The formula may hence be Si q+- Sif; or (R3-+H)io. In the first of these formulas each of the two members has the same oxygen ratio 3: 2; in the second this ratio is also retained, and is more briefly expressed, without the hypothetical idea that the silica in the compound is divided off between the protoxyd and peroxyd bases. 5. To deduce the per-centage atomic relations from a formula, the process above described is reversed. For example: for Feldspar we have 4 of silica, 1 of alumina, 1 of potash. In the preceding table the atomic weight of silica is 566'25, and four times this is 2265. Setting this down and the atomic weights of alumina and potash below it, and adding, we have 4 of silica, -.. 2265 1 of alumina, - - - - 642-6 1 of potash, - - - - 588-9 Total atomic weight of the feldspar, 3496'4 Now if this amount (3496'4) of feldspar contains 2265 of silica, what will 100 parts contain? Hence, to obtain the per-centage, we divide the atomic weight of each constituent in succession by the sum of the whole, and this gives the percentage relation for each; viz. silica 64-78, alumina 18'38, potash 16-84. The following are the formulas of the more comnon mineral species following the order of the book. Table of Chemical Formulas of Minerals. Sal Ammoniac (100), NH4C1 Niter (101), ~S Glauber Salt (102), Na S+10o[ Nitratine (Nit. Soda, 103), Sa S Natron (103), Na 0+10o[ Trona (103), Na2 8+4A1 Common Salt (104), Na C1 Borax (107) aaB2-10Ol Barytes (Heavy Spar, 108), Ba ~itherite (109), Ba 344 CHEMICAL COMPOSITION OF M1IERAL!. Celestine (110), Sr Strontianite (111), Sr C Gypsum (112), OaS+2]1 Anhydrite (114), Cag Calcite (115), Oae Aragonite (118), OaO Dolomite (119), (Ca, S:g)0 Apatite (120), Ca3P+iCa(Cl, F) Fluor spar (121), CaF Epsomite (Epsom salt, 124), MlgS+7li Magnesite (124), iMg Brucite (125), gIgA Boracite (126), lI:g3'B4 Potash alum (127), KS+- S1 +2-24H Soda alum (128), aS+-;-i1 93+24I Alunite (129), KS'+3iS+6H Wavellite (130), (;14 3- +18A)+-AlFa Gibbsite (131), Al13 Quartz (132), gi Opal (139), Si(+Aq.) Wollastonite (141), ca3s i2 Datholite (142). (Ca3, H3, ]B)Si Talc (143), Mg6sis 5 -+2 Chlorite (145), (f3, 1)Si+_IlI Ripidolite (145), (fR3, l)S'i+1l Serpentine (145), Mg3'Si2 +- ] MgHI Meerschaum (148), MgSi+-l Clintonite (148), (R8, ) (Si, il) ftiPyroxene (l15i), (Mg, Ca, Fe, MIn)'Sis Hornblende (152), (Mg, Ca, Fe, Mn)4Si Spodumene (156), (ti, Na)'Si2+4Al' is Chrysolite (157), (Mg, Fe, Ca)3Si Chondrodite (157), (Mg, Fe)Si Corundum (158), A1 Spinel (160), (Mg, I1) Automolite (var. of Spinel, 161), Zn1l Hercinite, " Fetl Ceylanite, " (Mg, Fe)A Dysluite, " (Zn, n (Al, e}) CHEMICAL FORMULAS OF MINERALS. 315 Kreittonite, (var. of Spinel), (2n, Pe) (xl, Pe) Halloysite (161), A18i+-3f (in part) Heulandite (164). Cagi+- lSiS+ 5 Stilbite (165), CaSi+-lSi3+6A1 Apophyllite (165), Ca, K, Si, A, F. Laumontite (166), Ca3 Si2+341'Si 1 -. I2H Natrolite (166), Na'Si+-lSi;i+211 Scolecite (167), CaSi+AiSi+1-s Thomsonite (167), RaSi+3;lSi+7fi Harmotome (168), ]aSi+-l'Si2 +5ft Analcime (168), Na3Si23;lSi2 + 651 Chabazite (169), R3Si2 + 3l'i2 +1 8H Prehnite (170), 2Ca3'Si+3 lSi+H3Si Sillimanite (172), AlSii; (partly AlgSi ) Kyanite (173),;lgiQ Andalusite (174),'g Staurotide (174), Si Leucite (175), K3Si2+3Ali 2 Orthoclase (176), (K-+;l)S-i4=K'Si+-lSiS Albite (177), (Na+I l)Si4NaSi+lSiJ Labradorite (178), (Ca+;4l)Si2=CaSi +AlSi Nepheline (179), (na+il)Si- =Na2 Si-i-2'lSi Scapolite (180), (iRa-+1)'Si —RA=3'Si+-I!2S3 Meionite (181), (Iaa3+-:l)Si-=- C=a3'Si+ 2ll'Si Petalite (182), (3 1)i4= Si44 i Epidote (182), (if3+ A-l)Si=fR3Si+ 2A1Si Allaulte (183, 207), (~3+-)l)' i=-f3Si+l'Si Idocrase (184), (-IR 3 - dl)Si=3 i3 ii+ 2li Garnet (184), (iR3+~il)1Si==R3Si +ISi Tourmaline (187), (R3, X1,'B)~i Axinite (190), (R3,, B)Si [olite (190), (5.. 5i.3.Si Si Muscovite (191), ( rl3+2)Sir=R3Si+ 12 Sit Biotite (193), (3+ ~r1)Si-ISi Phlog)pite (193), (-q3+ -l)' Si=SR3i+2 3'1Si Topaz (194), l1Sif with F replacing part of O Beryl (197), (Be+-.1)S12=:-I Si?. 346 CHEMICAL COMPOSITION OF MINERALS. Euclase (199), ( e-I)i — eS. Chrysoberyl (199), Be+;-3 Zircon (200), VrIi Yttrocerite (206), (Ca, Ce, Y)F Monazite (206), (0e, La, Th)3P Allawite (see above). Rutile (210), Ti Sphene (211), (al+Ti)Sii=(~)Sit Tin Pyrites (213), 31uS(Sn2S3, Fe2S) Tin Ore (214), Sn Molybdenite (217), MoS8 Molybdic ocher (218), Mo Tungstic ocher (218), w Scheelite (Tungstate of lime, 219), Caw Gray Antimony (222), Sb2Ss White Antimony (224), Sb2O0 White Arsenic (226), As203 Oroiment (226), As2S8 Realgar (226), AsS Uranite (228), Ca-2 t-4+ 161 Chalcolite (229), 6u2P+ — P+-16l Pyrites (231), FeS2 Pyrrhotine (233), Fe7S; FeS. Mispickel (234), Fe(As, S)2 Magnetite (235), Pete Specular Iron (237), Pe Limonite (239), Pe2]3 Gothite (240), Ve[ Franklinite (240), Zn(Ve, Rn) Ilmenite (241), (Fe, Ti) Chromic Iron (241), Fe(jr) Columbite (243), FeS3b~ Tantalite (ferrotantalite, 244), FeTa Wolfram (244), (Fe, Mn)w Copperas (246), Fe-+7f Spathic Iron (247), PeO Vivianite (248), Pe8l+ 8f Rhodonite (268), MIn3Si Pyrolusite (259! Sn CHEMICAL FORMULAS OF MINERALS. 847 Psilomelane (259), ISn2+t I Wad (260), tln+A I Triplite (260), (f^ te)4T Copper Nickel (268), NiAs Chloanthite (268), (Ni, Co)As2 Safflorite (263), (Ni, Co, Fe)ASa Nickel Glance (268), Ni(S, As)2 Capillary Pyrites or Millrite (264), NiS Emerald Nickel (264), Ni- +2Ril~1 Smaltine (266), (Co, Ni)As2 Erythrine (267), 00oss1+8[ Blende (269), ZnS Zincite (270), Zn Sulphate of Zinc (271), 2n-+7t Smithsonite (272), Ane Calamine (272), ZnsSi+I - Galena (277), PbS Minium (280), PbO4 Anglesite (281), PbS Cerusite (281), PbO Pyromorphite (283), 1Pbs +rPDcl Crocoisite (284), Pbar Cinnabar (287), HgS Copper Glance (292), OuS Copper Pyrites (292), euS+Fe2S* Erubescite (294), (Fe, Cu)S Tetrahedrite (296), euS+K(Sb, As)'St Red Copper (296), Ou Blue Vitriol (297), tu~-+bMalachite (298), 0Oue2+53 Azurite (800), 20u0+0ul Chrysocolla (800), oCuSi2-+-6 Dioptase (801), OuSi2+8s Silver Glance (825), AgS Brittle Silver Ore (826), AgS+*SbS* Dark Red Silver Ore (827), AgS-+-Sb2S Light Red Silver Ore (827), AgS+-AssSS Horn Silver (827), AgOl Bromic Silver (327), AgBr Embolite (827, Ag(C1, Br) ROCKS. CHAP. VII.- ROCKS OR MINERAL AGGREGATES General Nature of Rocks. In the early part of this vol. ume it is stated that the rocks of the globe are mineral in their nature, and consist either of a single mineral in a mas sive state, or of intimate combinations of different minerals Limestone, when pure, is a single mineral,-it is the spe cies calcite or carbonate of lime; common granite is a com. pound or aggregate of three minerals, quartz, feldspar, and mica. Sandstones may consist of grains of quartz alone, like the sands of many sea-coasts, being such a rock as these sands would make if agglutinated; it is common to find along with the quartz, grains of feldspar, and sometimes mica. Clay slates consist of quartz and feldspar or clay, with sometimes mica, all so finely comminuted, that often the grains can. not be observed. Conglomerates or puddingstones. may be aggregates of pebbles of any kind: of granite pebbles, of quartz pebbles, of limestone pebbles, or of mixtures of different kinds, cemented together by some cementing material, such as silica, oxyd of iron, or carbonate of lime. Texture or structure of Rocks.-Rocks differ also in tex. ture. In some, as granite, or syenite, the texture is crystalline: that is, the grains are more or less angular, and show faces of cleavage; the aggregation was the result of a cotemporaneous crystallization of the several ingredients. Common statuary or white building marble, consists of angular grains, and is crystalline in the same manner. But a pudding-stone is evidently not a result of crystallization; it consists only of adhering pebbles of other rocks with a cementing material which is often not apparent. Sand. stones also are an agglutination of grains of sand,-just such rocks as would be made from ordinary sand by compacting it together; and clay slates are often just what would result from solidifying a bed of clay. There are therefore crystalline and uncrystalline rocks. It should be remembered, however, that in each kind of rock the grains themselves are crystalline, as all solid matter becomes solid by crystal. lization. But the former kind is a crystalline aggregation of grains, the latter a mechanical aggregation. In crystalline rocks it is not always possible t( distinguish the grains, as they may be so minute, or the rock so corn ROCKS. 349 pact, that they are not visible. Much of the crystalline rock called basalt is thus compact. Positions, or modes of occurrence of Rocks. A great part of the rocks of the earth's surface constitute extensive beds or layers, lying one above the other, and varying in thickness from a fraction of an inch to many scores of yards. There are compact limestones, beds of sandstone and shales or clay slates, in many and very various alternations. Il some regions, certain of these rocks, or certain parts of the series, may extend over large areas or underlie a wholp country, while others are wholly wanting or present only ii, thin beds. The irregularities in their geographical ar. rangement and in the order of superposition are very numerous, and it is one object of geology to discover order amid the apparent want of system. Thus in Pennsylvania, over a considerable part of the state, there are sandstones, shales, and limestones, connected with beds of coal. In New York there are other sandstones, shales, and limestones, without coal; and the geologist ascertains at once by his investigations, (as was observed in the remarks on ooal,) that no coal can be expected to be found in New York. These rocks contain each its own peculiar organic remains, and these are one source of the confident decision of the geologist. The stratified rocks bear evidence in every part-in their regular layers, their worn sand or pebbles, and their fossils,that they are the result of gradual accumulations beneath water, marine or fresh, or on the shores of seas, lakes or rivers. Besides the stratified rocks alluded to, there are others which, like the ejections from a volcano, or an igneous vent, form beds, or break through other strata and fill fissures often many miles in length. The rock filling such fissures, is called a dike. Such are the trap dikes of New England and elsewhere; they are fissures filled by trap. Porphyry dikes, and many of the veins in rocks, are of the same kind. Similar rocks may also occur as extensive layers; for the lavas of a single volcanic eruption are sometimes con. tinuous for 40 miles. They may appear underlying a wide region of country, like gr,-a'ito. The stratified rocks, or such as consist of material in reg. ular layers, are of two kinds. The worn grains of which they are made are sometimes distinct, and the remains of shells farther indicate that they are the result of gradual accu. 35)0 ROCKS. mulation. But others, or even certain parts of beds that elsewhere contain these indications, have a crystalline texture. A limestone bed may be compact in one part, and granular or crystalline, like statuary marble, in another. Here is an effect of heat on a portion of the bed; heat, which has acted since the rock was deposited. Other rocks, such as mica slate, gneiss, and probably some granites, have thus been crystallized. They are called metamorphic rocks. In these few general remarks on the structure of the globe, we have distinguished the following general facts: 1. The great variety of alternations of sandstone, conglo. merates, clay shale, and limestones. 2. The existence of igneous rocks in beds and intersect. ing dikes or veins. 3. The mechanical structure of sandstone, conglomerate, and shales. 4. The crystalline character of igneous rocks. 5. The crystalline character of many stratified or sedimentary rocks, arising from the action of heat upon the beds of rock themselves, after they were first formed. We follow this comprehensive survey of the arrangement and general nature of rocks, with descriptions of the more prominent varieties and a mention of their applications in the arts.* * One of the most important uses of stone is for architectural purposes. The character of the material depends not only upon its durability, but also its contraction or expansion from changes of temperature. This latter cause occasions fractures or the opening of seams, and produces in cold climates serious injuries to structures. The following table, by Mr. A. J. Adie, gives the rate of expansion in length tor different materials, for a change of temperature of 180~ F. —Proc. Roy. Soc. Edinb., i, 95, 1835. Granite, ~0008968 —0007894 Sicilian white marble, 00110411 Carrara marble, -0006539 Black marble, from Galway, Ireland, -00044519 Sandstone, (Craigleith quarry, Scotland, -0011743 Slate, Penryhn quarry, Wales, -0010376 Greenstone, -0008089 Best brick, -0005502 Fire brick, -0004928 Cast iron,'00114676 —001102166 Rod of wedgewood ware,'00045294 GRANITE. 351 GRANITE. SYENITE. Granite consists of the three minerals, quartz, feldspar, and mica. It has a crystalline granular structure, and usual. ly a grayish-white, gray, or flesh-red color, the shade vary. ing with the color of the constituent minerals. When it contains hornblende in place of mica, it is called syenite, hornblende resembles mica in these rocks but the laminae separate much less easily and are brittle. Granite is said to be micaceous, feldspathic, or quartzose, according as the mica, feldspar, or quartz, predominates. It is called porphyritic granite, when the feldspar is in large crystals, and appears over a worn surface like thickly scattered white blotches, often rectangular in shape. Graphic granite has an appearance of small oriental cha. racters over the surface, owing to the anrlllar arrangement of the quartz in the feldspar, or of the feldspar in V the quartz. When the mica of the granite is wanting, it is^ then a granular mixture, ) / of feldspar and quartz, called granulite or lepty- rnt*. Graphic Granite. When the feldspar is replaced by aibite, it is called albite granite. The albite is usually white, but otherwise resem. bles feldspar. When replaced by talc, it is called protogine. Granite is the usual rock for veins of tin ore. It con. tains also workable veins of pyritous, vitreous, and gray copper ore, of galena or lead ore, of zinc blende, of specular and magnetic iron ore, besides ores of antimony, cobalt, nickel, uranium, arsenic, titanium, bismuth, tungsten, and silver, with rarely a trace of mercury. The rare cerium and yttria minerals are found in granite, and mostly frequently in The experiments of W. H. C. Bartlett, Lieut. U. S. Engineers, led o the following results.-Amer. J. Sci., xxii, 136, 1832. For 1~ F. For 1800 F. Granite, ~000004825 -00086904 Marble, -000005668 -00102024 Sandstone, -000009532 -00171596 Hamnmered copper, -000009440.00169920 35'2 -ROCKRS. albitic granite. It also contains emerald, topaz, corundum zircon, fluor spar, garnet, tourmaline, pyroxene, hornblende, epidote, and many other species. Diorite is a rock of the granitic series, consisting of hornblende and feldspar. Color dark green or greenish-black Cry t';,'inl texture distinct. Granite is one of the most valuable materials for build. ing. The rock selected for this purpose, should be fine and even in texture, as the coarser varieties are less dura. ble; it should especially be pure from pyrites or any ore of iron, which on exposure to the weather will rust and destroy, as well as deface, the stone. The only certain evidence of durability, must be learned from examining the rock in its native beds; for some handsome granites which have every appearance of durability, decompose rapidly from some cause not fully understood. The more feldspathic are less en. during than the quartzose, and the sycnitic (or hornblendic) variety more durable than proper granite itself. The rock, after removal fiom the quarry, hardens somewhat, and is less easily worked than when first quarried out. Massachusetts is properly the granite state of the union. New Hampshire and Maine also afford a good material. The Quincy quarries in Massachusetts, south of Boston, have for many years been celebrated. Besides this locality, there are others in the eastern part of this state, between cape Ann and Salem, in Gloucester, at Fall River, in Troy, in Danvers; also south between Quincy and Rhode Island, where it is wrought in many places, as well as in Rhode Island, even to Providence. The so-called Chelrnsford granite comet fiom Westford and Tyngsborough, beyond Lowell, and an ex. cellent variety is obtained at Pelham, a short distance north in New Hampshire. Masses 60 feet in length are obtained at several of the quarries. They are worked into columns for buildings, many fine examples of which are common in Boston, New York, and other cities. Good granite is also quarried in Waterford, Greenwich, and elsewhere, in Connecticut. The granite is detached in blocks by drilling a series of holes, one every few inches, to a depth of three inches, and then driving in wedges of iron between steel cheeks. In this manner masses of any size are split out. There is a choice of direction, as the granite has certain directions of easiest fracture. Masses are often got out in long narrow strips, a foot wide, for fence posts. GNEISS-MICA SLATE. 353 Granite is also used for paving, in small rectangular blocks neatly fitted together, as in London and in some parts of New York and other cities. The feldspathic granite is of great value in the manufacture of porcelain, as remarked upon under Feldspar. Granite was much used by the ancients, especially the Egyptians, where are obelisks that have stood the weather for 8000 years. GNEISS. Gneiss has the same constitution as granite, but the mica is more in layers, and the rock has therefore a stratified appearance. It generally breaks out in slabs a few inches to a foot thick. It is hence much used both as a building material and for flagging walks. The quarries in the vicinity of Haddam, Conn., on the Connecticut river, are very extensively opened, and a large amount of stone is annually taken out and exported to the Atlantic cities, even as far as New Orleans. There are also quarries at Lebanon and other places, in Connecticut; at Wilbraham, Millbury, Monson and many other places in Massachusetts. XICA SLATE. Mica slate has the constituents of gneiss, but is thin slaty,.and breaks with a glistening or shining surface, owing to the large proportion of mica, upon which its foliated structure depends. It contains less feldspar and much more mica than gneiss. The thin even slabs of the more compact varieties of mica slate are much used for flagging, and for door and hearth stones; also for lining furnaces. The finer arenaceous varieties make good scythe stones. It is quarried extensively of fine quality, in large even slabs, at Bolton in Connecticut; also in the range passing through Goshen and Chesterfield, Mass. It is worked into whetstones in Enfield, Norwich, and Bellingham, Mass., and extensively at Woonsocket Hill, Smithfield, R. I. The south part of Chester, Vt., affords a slate like that of Bolton. Mica slate is used at Salisbury, Conn., for the inner wall of the iron furnace. Hornblende slate resembles mica slate, but has not as glistening a luster, and seldom breaks into as thin slabs. It is more tough than mica slate, and is an excellent material for flagging. 29 354 ROCKS. TALCOSE SLATE.-TA.LCOSE ROCK. Talcose slate resembles mica slate, but has a more greasy feel, owing to its containing talc instead of mica. It is usually light gray or dark grayish.brown. It breaks into thin slabs, but is generally rather brittle, yet it often makes good fire-stones. A talcose slate in Stockbridge, Vt., is worked for scythe stones and hones, and is of excellent quality for this purpose Talcose rock is a hard and tough compact rock, containing more or less talc, and often quite compact. It is usually very much intersected by veins of white quartz. Much of it contains chlorite (an olive-green mineral) in place of talc, here and there disseminated. Chlorite slate has a dark green color, and is similar in general characters to talcose slate. These slaty rocks are to a great extent the gold rocks of the world, especially the quartzose veins, as mentioned under Gold. Platinum, iri. dosmine, pyrites and many other minerals, occur in them, or in associated beds. STEATITE, OR SOAPSTONE. Steatite is a soft stone, easily cut by the knife and greasy in its feel. Its color is usually grayish-green; but when smoothed and varnished it becomes dark olive-green. It occurs in beds, associated generally with talcose slate. Owing to the facility with which soapstone is worked, and its refractory nature, it is cut into slabs for fire stones and other purposes, as stated on page 144. The powder is employed for diminishing friction, and for mixing with blacklead in the manufacture of crucibles. It is also used, as observed by Dr. C. T. Jackson, for the sizing rollers in cotton factories, one of which is 4~ feet long and.5 to 6 inches in diameter. The most valuable quarries in Massachusetts are at Middle. field, Windsor, Blanford, Andover, and Chester; in Vermont, at Windham and Grafton; in New Hampshire, at Frances. town and Oxford; in Orange county, North Carolina. The Francestown soapstone sells at Boston at from 36 to 42 dol. lars the ton, or from. to 83 dollars the cubic foot.* Steatite often contains disseminated crystals of magnesian carbonate of lime, (dolomite,) and brown spar; also crys. tals of pyrites and actinolite. * Geol. N. H., by C. T. Jackson, 1844; p. 168. SERPENTINI',.-TRAP. 355 Pots~fne is a compact steatite. Rensselaerite is another comp, t variety, (page 144,) found in Jefferson and St. Law. renc counties, N. Y., and used for inkstands. SERPENTINE.'his dark green rock is usually associated with talcose rcv ks, and often also with granular limestones. It has been described on page 145, where its uses are alluded to. It often contains disseminated a foliated green variety of hornalende called diallage. A compound rock consisting ofdial(age and feldspar, has been called diallage rock or euphotide TRAP.-BASALT. Trap is a dark greenish or brownish black rock, heavy and tough. Specific gravity 2*8 —32. It has sometimes a granular crystalline structure, and at other times it is very compact without apparent grains. It is an intimate mixture of feldspar and augite. It is often called dolerite. The feldspar in this rock is usually the kind called labraborite. (p. 113.) Amygdalta, (from the Latin amygdalum, an almond,) is a trap containing small almond-shaped cavities, which are filled with some mineral: usually a zeolite, quartz or chlorite. Porphyrztlt trap is a trap containing, like porphyritic granite, disseminated crystals of feldspar. Basalt resemblies trap, but consists of augite, olivine and feldspar. It varies in color from grayish to black. In the lighter colored, which are sometimes denominated graystone, feldspar predonlia.ies: and in the darker, iron, or a ferruginous augite. Xne chrysolite (or olivine) it contains is in small grains ot a bottle-glass appearance. Magnetic or titanic iron are also frequently present in the rock. When feldspar crystals are coarsely disseminated, it is called por. phyritic basalt; aid when containing minerals in small nodules, it is amygaaloidal basalt. Basalt is a common product of volcanic action. Wacke or toadstone is an earthy basalt, or a sedimentary rock of trap or basaltic material. Both trap and basalt occur in columnar forms, as at the Giant's Causeway and other similar places. Trap and basalt are excellent materials for macadamizing roads, on account of their toughness. Trap is also used for buildings. It breaks into irregular angular blocks, and is b56 OC(KS. employed in this condition. For a Gothic building it is w, fitted, on account of an appearance of age which it has. PORPHYRY.-CLINKSTONE.-TRACHYTE. Pophyry consists mainly of compact feldspar, with dis. seminated crystals of feldspar. Red or brownish-red and green, are common colors; but gray and black are met with. The feldspar crystals are from a very small size to half or three quarters of an inch in length, and have a much lighter shade of color than the base, or are quite white. It breaks with a smooth surhfce and conchoidal fracture. The specific gravity and other characters of the rock are the same nearly as for the mineral feldspar; the hardness is usually a little higher than in that mineral. Porphyry receives a fine polish, and has been used for columns, vases, mortars, and other purposes. Green por. phyry is the oriental verd antique of the ancients, and was held in high esteem. The red porphyry of Egypt is also a beautiful rock. It has a clear brownish red color, and is sprinkled with small spots of white feldspar. Clinkstone or Phonolite is a grayish-blue rock, consisting, like porphyry, ma;nly of feldspar. It passes into gray basalt, and is distinguished by its less specific gravity. It rings like iron when struck with a hammer, and hence its name. Trachyte is another feldspathic rock, distinguished by breaking with a rough surface, and showing less compactness than clinkstone. It sometimes contains crystals of hornblende, mica, or some glassy feldspar mineral. It occurs in volcanic regions. LAVA.-OBSIDIAN.-PUMICE. The term lava is applied to any rock material which has. flowed in igneous fusion from a volcano. Basalt is one kind of lava; and when containg cellules, it is called basaltic lava. Trachyte is also a lava. There are thus both feld. spathic and basaltic lavas. The feldspathic are light colored, and of low specific gravity, (not exceeding 2'8); the basaltic vary from grayish-blue to black, and are above 2'8 in specific gravity. The general term basaltic sometimes includes doleritic lava, which is closely allied. Chrysolite is present in basaltic lavas; and such lavas are not unfrequently por phyritic, or contain disseminated crystals of feldspar. SII.ALl 357 The light cellular ejections of a volcano are called scorla or pumice. Pumice io ftldspathic in constitution; it is very porous, and the fine pores lying in one direction make the rock ap. pear to be fibrous. It is so light as to float on water. It is much used for polishing wood, ivory, marble, metal, glass, etc., and also parchment and skins. The principal localities are the islands of Lipari, Ponza, Ischia, and Vulcano, in the Mediterranean between Sicily and Naples. Both scoria and pumice are properly the scum of a volcano. Volcanic ashes are the light cinders, or minute particles of rock, ejected from a volcano in the course of an eruption. Obsidian is a volcanic glass. It resembles ordinary glass. Black and smoky tints are the common colors. In Mexico, it was formerly used both for mirrors, knives and razors. Pitchstone is less perfectly glassy in its character, and has a pitch-like luster. Otherwise it resembles obsidian. Pearl. stone has a grayish color and pearly luster. Spherulite is a kind of pearlstone, occurring in small globules in massive pearlstone. Marekanite is a pearl-gray translucent obsidian fiom Marekan in Kamschatka. ARGILLACEOUS SHALE, OR CLAY SLATE.-ARGILLITE. Slate is an argillaceous rock, breaking into thin lamine; shale a similar rock, with the same structure usually less perfect and often more brittle; schist includes the same varieties of rock, but is extended also to those of a much coarser laminated structure. The ordinary clay slate has the same constitution as mica slate; but the material is so fine that the ingredients cannot be distinguished. The two pass into one another insensibly. The colors are very various, and always dull or but slightly glistening. Roofing slate is a fine grained argillaceous variety, commonly of a dark dull blue or bluish-black color, or some. what purplish. To be a good material for roofing, it should split easily into even slates, and admit of being pierced for nails without fracturing. Moreover, it should not be ab. sorbent of water, either by the surface or edges, which may be tested by weighing, after immersion for a while in water. It should also be pure from pyrites and every thing that can undergo decomposition on exposure. Roofing slates occur in England, in Cornwall and Devon, Cilmberland, Westmoreland..29* 358 ROCKS. In the United States, a good material is obtained in Maine at Barnard, Piscataquies, Kennebec, Bingham and elsewhere also in Massachusetts, in Worcester county, in Boylston, Lancaster, Harvard, Shirley, and Peperell; in Vermont, at Guilford, Brattleborough, Fairhaven, and Dummerston; in Hoosic, New York; on Bush creek and near Unionville, Maryland; at the Cove of Wachitta, Arkansas. At Rutland Vt., is a manufactory of slate pencils, from a greenish slate. These slate rocks are also used for gravestones; and we cannot go through New England cemetries without frequent regret that a material which is sure to fall to pieces in a few years, should have been selected for such records. Drawing slate is a finer and more compact variety, of bluish and purplish shades of color. The best slates come from Spain, Italy, and France. A good quality is quarried in Maine and Vermont. Novaculite, hone-slate, or whet-stone, is a fine grained slate, containing considerable quartz, though the grains of this mineral are not perceptible. It occurs of light and dark shades of color, and compact texture. It is found in North Carolina, 7 miles west of Chapel Hill, and elsewhere; in Lincoln and Oglethorpe counties, Georgia; on Bush creek, and near Unionville, Maryland; at the Cove of Wachitta Arkansas. Argillite is a general term given to argillaceous or clay slate rocks. Many shales or argillites crumble easily, and are unfit for any purpose in the arts, except to furnish a clayey soil. Alum shale is any slaty rock which contains decomposing pyrites, and thus will afford alum or sulphate ot alumina on lixiviation. (See under Alum, page 128.) Bituminous shale is a dark colored'slaty rock containing some bitumen, and giving off a bituminous odor. Plumbaginous schist is a clay slate containing plumbago or graphite, and leaving traces like black lead. The Pipestone of the North American Indians was in part a red claystone or compacted clay from the Coteau de Prairies. It has been named catlinite. A similar material, now accumulating, occurs on the north shore ot'Lake Supe. rior, at Nepigon bay. Another variety of pipestone is a dark grayish compact argillite; it is used by the lalians of the north west coast of America. Agalmatolife is a soft mineral, impressible:i tb,,-i.i QIARiTZ ROCK. 35)9 and waxy in luster when polished, presenting grayish and greenish colors and other shades. Gr=-2'8 -29. It has a greasy feel. It consists of silica 55'0, alumina 30'0, potash 7'0, water 3 to 5 per cent., with a trace of oxyd of iron. It is carved into images, and is hence calledJigure-stone. QUARTZ ROCK. Quartz rock is a compact rock consisting of quartz, and often appearing granular. Its colors are light gray, reddish or dull bluish; also sometimes brown. When the granular quartz contains a little mica, it often breaks in slabs like gneiss or mica slate. The itacolumite of Brazil, with which gold and topaz are associated, is a micaceous granular quartz rock of this kind. Flexible sandstone is an allied rock of finer texture. It owes its flexibility to the mica present, and its looseness of aggre. gation. Granular quartz graduates into the proper sandstones, which are treated of for convenience on a following page. Granular quartz is one of the most refractory of rocks. It is consequently used extensively for hearthstones, for the lining of furnaces, and for lime kilns. At Stafford, Conn., a loose grained micaceous quartz rock is highly valued for furnaces; it sells at the quarry for 16 dollars a ton.* Granular quartz is also used for flagging, and a fine quarry is openec in Washington, near Pittsfield, Mass.; it also occurs of good quality at Tyringham and Lee, Mass. In the shape of cobble stones, it is a common paving material. A highly important use of this rock is in the manufacture of glass and sandpaper,' and for sawing marble. In many places it occurs crumbled to a fine sand, and is highly con. venient for these purposes. In Cheshire, Berkshire county, Mass., and in Lanesboro', Mass., it occurs of superior qual. ity, and in great abundance. It is also in demand for the manufacture of glass and pottery. In Unity, N. H., a gran. ular quartz is ground for sandpaper and for polishing powder; the latter is a good material for many purposes. A fine variety of granular quartz is a material much valued for whet-stones. BUHRSTONE. Buhrstone is a quartz rock containing cellules. It is as hard and firm as quartz crystal, and owes its peculiar value Rep. on Connecticut, by C. U. Shepard-p. 78. 360 ROCKS. to this quality and the cellules, which give it a very rough surface. In the best stones for wheat or corn the cavities about equal in space the solid part. The finest quality comes from France, in the basin of Paris and some adjoining districts. The stones are cut into wedge-shaped parallelopipeds called panes, which are bound together by iron hoops into large millstones. The Paris buhrstone is from the tertiary formation, and is therefore of much more recent origin than the quartz rock above described. Buhrstone of good quality is abundant in Ohio, and others of the western states. It is associated there with proper sandstones, as more particularly mentioned on page 346. The quartz rock of Washington, near Pittsfield, Mass., is in some parts cellular, and makes good millstones. A buhrstone occurs in Georgia, about 40 miles from the sea, near the Carolina line; also in Arkansas, near the Cove of Wachitta. SANDSTONES.-GRIT ROCKS.-CONGLOMERATES. Sandstones consist of small grains, aggregated into a compact rock. They have a harsh feel, and every dull shade of color from white through yellow, red and brown to black. Many sandstones are very compact and hard, while others break or rub to pieces in the fingers. They usually consist of siliceous sand; but grains of feldspar are often present. In many compact sandstones there is much clay, and the rock is then an argillaceous sandstone. Sandstones are of all geological ages, from the lower Silurian to the most recent period. The older rocks are in general the most firm and compact. The " old red" sandstone is a sandstone below the coal in age; while the so called "new red" is more recent than the coal. But these terms are of indefinite application out ot' Great Britain, and are not now used in this country. R,.d sandstone, when used as a building material, is often called freestone. Grit rock. When the sandstone is very hard and harsh, and contains occasional siliceous pebbles, it is called a grit rock, or millstone grit. Conglomerates. Conglomerates consist mostly of pebbles compacted together. They are called pudding stone when the pebbles are rounded, and breccia when they are angular. They may consist of pebbles of any kinds, as of granite. SANDSTONES. 36] quartz, limestone, etc., and they are named accordingl) gran itic, quartzose, calcareous, conglomerates. The use of sandstone as a building material is well known. For this purpose it should be free, like granite, from pyrites or iron sand, as these rust and disfigure the structure. It should be firm in texture, and not liable to peel off on exposure. Some sandstones, especially certain argillaceous varieties, which appear well in the quarry, when exposed for a season where they will be left to dry, gradually fall te pieces. The same rock answers well for structures beneath water, that is worth nothing for buildings Other sandstones which are so soft as to be easily cut from their bed without blasting, harden on exposure, (owing to the hardening of silica in the contained moisture,) and are quite durable. These are qualities which must be tested before a stone is used. Moreover it should be considered that in frosty climates, a weak absorbent stone is liable to be destroyed in a comparatively short time, while in a climate like that of Peru, even sunburnt bricks will last for centuries. Mr. Ure observes, that " such was the care of the ancients to provide strong and durable materials for their public edifices, that but for the desolating hands of modern barbarians, in peace and in war, most of the temples and other public monuments of Greece and Rome would have remained perfect at the present day, uninjured by the elements during 2000 years. The contrast in this respect of the works of modern architects, especially in Great Britain, [much more true of the United States,] is very humiliating to those who boast so loudly of social advancement; for there is scarcely a publicibuilding of recent date which will be in existence a thousand years hence." Many splendid structures are monuments (not endless) of folly in this respect. He ob. berves also that the stone intended for a durable edifice ought to be tested as to its durability by immersion in a saturated solution of sulphate of soda, and exposure to the air for some days the crystallization within the stone will cause the same disintegration that would result in time from frost. The dark red sandstone (freestone) of New Jersey and Connecticut, when of fine gritty texture and compact, is generally an excellent building material. Trinity Church in New York is built of the stone from Belville, New Jersey. At Chatham, on the Connecticut, is a large quarry, which supplies great quantities of stone to the cities of the coast; 362 ROCKS. and there are numerous others in the Connecticut valley, both in Connecticut and Massachusetts. A variety in North Haven, at the east end of Mount Carmel, has been spoken of as excellent for ornamental architecture. That of Longmeadow and Wilbraham, in Massachusetts, is a very fine and beautiful variety and is much used. A freestone occurs also at the mouth of Seneca creek, Maryland, convenient for transportation by the Chesapeake and Ohio canal; white and colored sandstones occur also at Sugarloaf mountain, Maryland. The sandstone of the Capitol at Washington, is from the Potomac; it is a poor material. Sandstones when splitting into thin layers, form excellent flagging stones, and are in common use. Hard, gritty sandstones and the grit rocks are used for the hearths of furnaces, on account of their resistance to heat. They are also much used for millstones, and when of firm texture, make a good substitute for the buhrstone. The true buhrstone has been described as a cellular siliceous rock, without an apparent granular texture. The buhrstone of Ohio approaches this character; it is in part a true sandstone containing fossils in some places, and overlying the coal. Much of it contains lime; and it is possible that the removal of the lime by solution, since its deposition, may have occasioned its cellular character. It has an open cellular structure where quarried for millstones. It occurs in Ohio, in the county of Muskingum, and the counties south and west of south, on the Raccoon river and elsewhere. The manufacture commenced in this region in 1807, and ip Richland, Elk, and Clinton, and in Hopewell, the manufacture is now carried on extensively. Stones 4 feet in dian e. ter bring $150.* The "green sand" of the cretaceous formation contains grains of silicate of iron and potash, to which it owes its greenish tint. It occurs abundantly in New Jersey as a soft rock, and is much used for improving lands: a value it owes mostly to the alkali it contains. Pudding stones and breccias are fitted, in general, only for the coarser uses of stone, as for foundations, butments of bridges. Occasionally when of limestone, they make hand. some marbles, as the "Potomac breccia marble" on the * S. P. Hildreth, Geol. Report, Ohio. LIMESTONES. 363 Monocacey, of which the columns in the Hall of Represen. tatives at Washington. Porphyry couglomerates, basaltic conglomerates, pumiceous conglomerates, consist respectively of pebbles or fragments of porphyry, basalt, pumice. Tufa is a sandrock consisting of volcanic material, eithei cinders or the comminuted lavas. Pozzuolana is a kind of tufa found in the vicinity of Rome, Italy. It consists of silica 34-5, alumina 15, lime 8'8, magnesia 4'7, potash 1'4, soda 4'1, oxyds of iron and titanium 12, water 9'2. Pepe. rino is a coarse sandrock, made up of volcanic cinders or fine fiagments of scoria, partially agglutinated. LIMESTONES. Limestones consist essentially of carbonate of lime, and belong to the species calcite, (p. 115,) or of the carbonates of lime and magnesia. They are distinguished by being easily scratched with a knife, and by effervescing with an acid. They are either compact or granular in texture: the com. pact break with a smooth surface, often conchoidal; the granular have a crystalline granular surface, and the fine varieties resemble loaf sugar. Granular limestone. The finest and purest white crystal line limestones are used for statuary and the best carving, and are called statuary marble. A variety less fine in texture is employed as a building material. Its colors are white, and clouded of various shades. It often contains scales of mica disseminated, and occasionally other impurities, from which the cloudings arise. The finest statuary marble comes from the Italian quarry at Carrara; from the Island of Paros, whence the name Parian; from Athens, Greece; from Ornofrio, Corsica, of a quality equal to that of Carrara. The Medicean Venus and most of the fine Grecian statues are made of the Parian marble. These quarries, and also those of the Islands of Scio, Samos and Lesbos, afforded marble for the ancient temples of Greece and Rome. The Parthenon at Athens was con structed of marble from Pentelicus. Statuary marble has been obtained in the United Sates, but not of a quality equal to the foreign. Good building material is abundant along the Western part of Vermont, and south through Massachusetts to Western Connecticut and Eastern New York. In Berkshire county, Mass., mar. 364 ROCKS. ble is quarried annually to the value of $200,000; the pi, cipal quarries are at Sheffield, West Stockbridge, New Ashford, New Marlborough, Great Barrington, and Lanes. borough.* The columns of the Girard College are from Sheffield, where blocks 50 feet long are sometimes blasted out; the material of the City Hall, New York, came from West Stockbridge; that of the Capitol at Albany, from Lanesboro'. At Stoneham is a fine statuary marble; but it is difficult to obtain large blocks. The variety from Great Barrington is a handsome clouded marble. Some of the West Stockbridge marble is flexible in thin pieces when first taken out. There are Vermont localities at Dorset, Rutland, Brandon, and Pittsford. In New York extensive quarries are opened not far fiom New York, at Sing Sing; also at Pat. terson,-Putnani county; at Dover in Dutchess county, N. Y.; in Connecticut there are marble quarries at New Preston; in Maine at Thomaston: in Rhode Island at Smithfield, a fine statuary; in Maryland, a few miles east of Hagerstown; in Pennsylvania, a fine clouded variety, 20 miles from Philadelphia. A fine dun colored marble is obtained at New Ashford and Sheffield, Mass., and at Pittsford, Vt. The granular limestone when coarse usually crumbles easily, and is not a good material for building. But the best varieties are not exceeded in durability by any other architectural rock, not even by granite. The impurities are sometimes so abundant as to iender it useless. For statuary, it is essential that it should be uniform in tint and without seams or fissures; the liability of finding cloudings within the large blocks makes them useless for statuary. The pres. ence of pyrites or manganese unfits the stone for buildings. The common minerals in this rock are tremolite, asbestus, scapolite, chondrodite, pyroxene, apatite, besides sphene, spinel, graphite, idocrase, mica. Verd antique marble-verde antico-is a clouded green marble, consisting of a mixture of serpentine and limestone, as mentioned under Serpentine, page 147. It occurs at Milford, near New Haven, Connecticut, of fine ouality; and also in Essex county, N. Y., at Moria and near Port Henry n Lake Champlain. A marble of this kind occurs at Genoa and in Tuscany, and is much valued for its beauty A variety is called polzivera di Genoa and vert d'Egypte. Hitchcock's Geol. Rep., p..62. LIMESrTOiES. 365 The Cipolin marbles of Italy are while, or nearly so, with shadings or zones of green talc. The bardiglio is a gray variety from Corsica. Compact limestone usually breaks out easily in'o thick slabs, and are a convenient and durable stone for building and all kinds of stone work. It is not possessed of much beauty in the rough state. When polished it constitutes a variety of marbles according to the color; the shades are very numerous, from white, cream and yellow shades, through gray, dove-colored, slate blue or brown, to black. The Ner'o-antico marble of the Italians is an ancient deep black marble; the paragone is a modern one, of a fine black color, from Bergamo; and panno di morte is another black marble with a few white fossil shells. The rosso.antico is deep blood-red, sprinkled with minute white dots. The giallo anlico, or yellow antique marble, is deep yellow with black or yellow rings. A beautiful marble fiom Sienna, brocatello di Siena, has a yellow color, with large irregular splots and veins of bluish-red or purplish. The nmandelalo of the Italians is a light red marble, with yellowish-white spots; it is found at Luggezzana. At Verona, there is at red marble, inclining to yellow, and another with large whtle sjots in a reddlish and greenish paste. The black marble usted in the Ulnited States comes mostly from Shoreham, Vt., and! other )lltces in that state near Lake Champlain. The Bristol marble of England is a black marble containing a few white shells, and the Kilkenny is another similar. There are several quarries at Isle La Motte. It is quarried also near Plattsburgh and Glenn's Falls, N. Y. The portor is a Genoese marble very highly esteemed. It is deep black, with elegant veinings of yellow. The most beautiful comes from Porto-Venese, and under Louis XIV a great deal of it was worked up for the decoration of Versailles. Gray and dove-colored compact marbles are common through New York and the states West. The bird's.eye marble of Western New York is a compact limestone, with crystalline points scattered through it. Ruin marble is a yellowish marble, with brownish sha dings or lines arranged so as to represent castles, towers or cities in ruins. These markings proceed from infiltrated iron. It is an indurated calcareous marl. Oolitic marble has usually a grayish tint, and is speckled with rounded dots, looking much like the roe of a fish n30 366 ROCKS. Shell marble contains scattered fossils, and may be of dif. ferent colors. It is abundant through the United States. Crnoidal or encrinital marble differs only in the fossils being mostly remains of encrinites, resembling thin disks. Large quarries are opened in Onondaga and Madison counties, N. Y., and the polished slabs are much used. Madreporic marble consists largely of corals, and the surface consists of delicate stars: it is the pietra stellaria of the Italians. It is common in some of the states on the Ohio. Fire marble, or lumachelle, is a dark brown shell marble, having brilliant fire or chatoyant reflections from within. Breccia marbles and pudding stone marbles are the pol ished calcareous breccia or pudding stone, alluded to on page 346. Stalagmites and stalactites (page 116) are frequently polished, and the variety of banded shades is often highly beautiful. The Gibraltar stone, so well known, is of this kind. It comes fiom a cavern in the Gibraltar rock, where it was deposited from dripping water. It is made into inkstands, letter-holders, and various small articles. Wood is often petrified by carbonate of lime, and occasionally whole trunks are changed to stone. The specimens show well the grain of the wood, and some are quite handsome when polished. Marble is sawn by means of a thin iron plate and sand, either by hand or machinery. In polishing, the slabs are first worn down by the sharpest sand, either by rubbing two slabs together or by means of a plate of iron. Finer sand is afterwards used, and then a still finer. Next emery is applied of increasing fineness by means of a plate of lead; and finally the last polish is given with tin-putty, rubbed on with coarse linen cloths or baggings, wedged tight into an iron planing tool. More or less water is used throughout the process. Quicklime. Limestone when burnt produces quicklime, owing to the expulsion of the carbonic acid by the heat. The purest limestone affords the purest lime, (what is called fat lime.) But some impurities are no detriment to it for making mortar, unless they are in excess. Hydraulic lime, which is so called because it will set under water, is made from limestone containing some clay, silica, and often magnesia. The French varieties contain 2 or 3 per cent. of magnesia, and 10 to 20 of silica and alumina or clay. The LIMESTONES. 367 varieties in the United Sfates contain 20 to 40 per cent. of magnesia, and 12 to 30 per cent. of silica and alumina. A variety worked extensively at Rondout, N. Y., afforded Prof. Beck, carbonic acid 34'20, lime 25*50, magnesia 12-35, silica 15'37, alumina 9-13, peroxyd of iron 2*25.* Oxyd of iron is rather prejudicial than otherwise. In making mortar, the lime is mixed with water and siliceous sand. The final strength of the mortar depends principally on the formation of a compound between water, the silica (or sand) and the lime; of course therefore the finer the sand, the more thorough the combination. In hydraulic lime, there is silica and alumina present in a thor. oughly disseminated and finely divided state, which is favorable for the combination alluded to; and to this fact appears to be mainly owing its hydraulic character. Much less sand is added in making mortar from this lime than from that of ordinary limestone. Pozzuolana (page 347) forms a hydraulic cement when mixed with a little lime and water. Similar cements may be made with tufa, pumice stone, and slate clay, by varying the proportions of lime; these materials consist essentially of silica and alumina or magnesia with alkalies, and often some lime, and therefore produce the same result as with hydraulic limestone. In the burning of lime, the most common mode is to erect a square or circular furnace of stone, with a door for managing the fire below. An arched cavity for the fire is first made of large pieces of limestone, and then the furnace is filled with the stone placed loosely so as to admit of the passage of the flame throughout: the carbonic acid is ex. pelled by the heat, and when the fires are out, the lime now in the state of quicklime, or in other words, pure lime, is taken out. Great economy of fuel is secured by means of what is called a perpetual kiln. The cavity within is oest made nearly of the shape of an egg with the narrow end uppermost. The inner walls are of quartz rock, mica slate, or some refractory stone or fire brick, and between the inner and outer there is a layer of cinders or ashes, as in the iron furnace, page 233. Below are three or more openings for furnaces which lead into the main cavity, a few feet from the bottom; and alternate with these are other openings at a * Mineralogy of New York, page 78. 368; OCE:s. lower level tor withdrawing the lime. The lime is taken out below and the stone thrown in above, and this may be kept up without intermission as long as the kiln lasts. Be. neath the furnaces there are also ash pits. Such a kiln is most convenient for being filled and emptied when situated on a side hill. The localities of limestone in the United States are too common to need enumeration. Hydraulic limestone is also abundant. Quicklime is much used for inrr;ioving lands; also for clarifying the juice of the sugar cane and beet root; for puri fying coal gas; for clearing hides of their hair in tanneries and for various other purposes. SAND.-CLAY. The loose or soft material of the surface of the earth consists of sand, clay, gravel or stones, and what we call in general terms, soil or earth. These materials are either in layers or irregular beds. Most clay beds, and many of gravel, when cut through vertically, show indications of horizonta) layers, a result of deposition, or distribution, by water. The ordinary constituents of earth are quartz, feldspar or clay, oxyd of iron and lime; but these vary with the source from whence they are derived When the rock that has afforded the soil is granite, mica slate, or the allied rocks, mica is usually present, as well as feldspar and quartz; so a quartzose rock will furnish siliceous gravel; a magnesian, will give magnesia to the soil; calcareous, lime; trap, the ingredients of decomposed feldspar or hornblende. The material will be coarse or gravelly, or fine earthy, according to the nature of the rock, or the condition under which it is worn down, or its subsequent distribution by flowing waters. Besides the prominent constituents mentioned, there are small proportions of phosphates, nitrates, chlorids, etc., together with the results of vegetable decomposition; and these comparatively rare ingredients are of great importance to growing vegetation. The pebbles of a soil are commonly siliceous, as this kind resists wear most effectually. Sand is usually pulverized quartz, often with some feldspar. Clay is a plastic earth, consisting mainly of pulverized or altered aluminous minerals (largely feldspar) and quartz, the latter about two-thirds the whole. The alumina is often SAND. 36 b partly in the state of a hydrous silicate like Raolin or Hal. loysite. It owes its plasticity to the alumina, and ceases to be called clay when the proportion of silica is too great for plasticity. It is afforded by the decomposition of feldjpai and all argillaceous rocks. Oxyd of iron, carbonate of lime, and magnesia, are often present in clays. Sand for glass manufacture should be pure silica, fiee from a taint of iron. This purity is apparent in the clear. ness of the grains, under a lens, or their white color. The sand of Cheshire and Lanesboro', in Massachusetts, is a beautiful material. In the manufacture of glass, the object is to form a trans. parent fusible compound, and not an opaque infusible one as in pottery. This result is secured by heating together to fusion, silica (quartz sand or flint powder) and the alkali pot. ash or soda. The ingredients combine and produce a silicate of potash or soda-in other words, glass. Besides these ingredients, lime or oxyd of lead are added for glass of different kinds. A small proportion of lime increases the density, hardness, and luster of glass, producing a specific gravity between 2-5 and 2*6; while with lead a still denser material is formed-called crystal orflint glasswhose specific gravity is fiom 3 to 3-6. From 7 to 20 parts of lime are added for 100 of silica, and 25 to 50 of calcined sulphate or carbonate of soda; common salt (chlorid of sodium) may also be employed. A good colorless glass has been found by analysis to consist of silica 76-0, potash 13*6, and lime 10*4 parts, in a hundred. For coarse bottle-glass, wood-ashes and coarse sea-weed soda, called kelp, or else pearlashes, are used along with siliceous sand and broken glass. For a hard glass, the proportion of alkali is small. The best English crystal glass analyzed by Berthier, afforded 59 parts of silica, 9 of potash, 28 of oxyd of lead, and 1-4 of oxyd of manganese. Crown glass contains, in general, less alkali than crystal glass, and is superior in hardness. The alkali, moreover, in England, is soda instead of potash. Plate glwss also contains soda, and this soda (the carbonate) is prepared with great care. The proportions are 7 parts of sand, 1 of quicklime, 2j of dry carbonate of soda, besides cullet or broken plate. The materials are first well pounded and sifted, and mixed into a. fine pas e; they are then heated together in pots made 30)* 3 () ROCKS. of a pure refractory clay, until fusion has taken place and the material has settled. The glass is afterwards worked by blowing, or moulded, into the various forms it has in market; and it is finally annealed-or in other words, is very slowly cooled-to render it tough. A little oxyd of manganese is usually employed to correct the green color which glass is apt to derive from any oxyd of iron present. But if the manganese is in excess, it gives a violet tinge to it. The following chemical distribution of glasses has been proposed: Soluble glass. A simple silicate of potash or soda, or of toth of these alkalies. Bohemian or crown glass. Silicate of potash and lime. Common window and mirror glass. Silicate of soda and lime; sometimes also of potash. Bottle glass. Silicate of soda, lime, alumina, and iron. Ordinary crystal glass. Silicate of potash and lead. Flint glass. Silicate of potash and lead; more lead than in the preceding. Strass. Silicate of potash and lead-still more lead. Enamel. Silicate and stannate, or antimonate of potash or soda and lead. Glass was manufactured by the Phoenicians, and the later Egyptians. According to Pliny and Strabo, the glass works of Sidon and Alexandria were famous in their times, and produced beautiful articles. The Romans employed glass to some extent in their windows, and remains of this glass are found in Herculaneum. Window glass manufacture was first commenced in England in 1557. Sand for casting is a fine siliceous sand, containing a little clay to make it adhere somewhat and retain the forms into which it may be moulded. It must be quite free from lime. Tripoli is a fine grained earthy deposit, having a dry, harsh feel and a white or grayish color. It contains 80 per cent. of silica, mostly derived from the casts of animalcules. It is valuable as a polishing material. Marl. Marl is a clay containing carbonate of lime. The material is valuable as manure. The term is also impropery applied to any clayey earth used in fertilizing land. The green sand in New Jersey is sometimes called marl. Fuller's earth is a white, grayish, or greenish-white earth, having a soapy feel, which was formerly used for removing oil or grease from woolen cloth. It falls to pieces in water, CL AY. 371 and forms a paste which is not plastic. A variety consists of silica 44-0, alumina 23-1, lime 4-1, magnesia 2-0, pro toxyd of iron 2-0. Gr = 245. Lithomarge is a compact clay of a fine smooth texture, and very sectile. Its colors are white, grayish, bluish-white, reddish-white, or ocher-yellow, with a shining streak. Gr= 2'4-2*5. The tuesite of Thomson, a white lithomarge from the banks of the Tweed, is said to make good slate pencils. Clay for bricks is the most ordinary kind; it should have slight plasticity when moistened, and a fine' even character without pebbles. It ordinarily contains some hydrated oxyd of iron, which when heated turns red by the escape of the water in its composition, which reduces it to the red oxyd of iron, and gives the usual red color to the brick. It also frequently contains lime; but much lime is injurious, as it renders the brick fusible. A clay is extensively employed at Milwaukie, in Michigan, which contains no iron, and produces a very handsome cream-colored brick. About 9,000,000 of this kind of brick were made at that place in 1847. In making bricks, the clay is first well worked by the tread. ing of cattle or by machinery: after this, it is moulded in moulds of the requisite size, (91 inches, by 41 and 2*,) and then taken out and laid on the ground. A,od workman will make by hand 5000 in a day, and the best 10,000. After drying till stiff enough to bear handling, the bricks are trimmed off with a knife when requiring it, and piled up in long walls for farther drying. They are then made into a kiln by piling them in an open manner, (so that the flame and heated draft may have passage among them,) and leaving places beneath for the fires. The heat is continued 48 hours or more. The best brick are pressed in moulds. They have a smooth, hard surface. Near Baltimore, Md., bricks are thus made by a machine, worked by a single horse, which will mould 30,000 bricks in 12 hours; the bricks are dry enough when first taken from the mould for immediate burning. Burnt bricks were not used in England before the elqventh century, when they were employed in the construction of the abbey of St. Albans. But they date historically ]as far back as the city of Babylon. Unburnt bricks have also been used in all ages. Those of Egyptian and Babylonish times were made of worked clay mixed with chopped straw, 372 SAND-CLAY. to prevent it from falling to pieces. The adobies of Peru. are large sun-baked bricks or blocks of clay; and in that dry climate they are very durable. Clay for Fire-bricks should contain no lime, magnesia, or iron, as its value depends on its being very refractory There is a large manufactory in the United States, at Balti more, from the tertiary clays of eastern Maryland. In Eng land a slate clay from the coal series is employed. Potter's clay and pipe clay are pure plastic clays, free from iron, and consequently burning white. The clay of Mil waukie, from which the cream-colored bricks are made is much used also for pottery. In the manufacture of coarse pottery, the clay is worked with water and tempered; and then the required form of a pot or pan is given on a wheel. The ware is dried under cover for a while, and next receives the glaze in a creamlike state. The glaze for the most common ware consists of very finely pulverized galena, mixed with clay and water. The ware after drying again is next placed in the kiln, which is very gradually heated; the heat causes the baking of the clay, and drives off the sulphur of the galena, thus producing an oxyd of lead, which forms a kind of glass (or glaze,) with the alumina. For a better stone ware, common ialt is used, and it is put on after the baking has begun. For the finer earthenware, a mixture of red and white ad, feldspar, silica and flint-glass, is used for a glaze, the proportions differing according to the ware. The clay foi this ware is mixed with flint powder (ground flints or sand,) to render it less liable to contract or break, and it is worked with great care, and through various processes to prepare it lor moulding. The ware is usually baked to a biscuit, be. fore the glazing is put on, as in the manufacture of porcelain. Kaolin or porcelain clay, is derived from the decomposi. ion of feldspar, as stated on page 117. The foreign kaolin occurs in Saxony; in France at St. Yrieux-la-Perche, near Limoges; in Cornwall, England; also in China and Japan The kaolin used at the Philadelphia porcelain works comes mostly from the neighborhood of Wilmington, Delaware. The name kaolin is a corruption of the Chinese Kau. ling, meaning high-ridge, the name of a hill near Jauchau Fu, where this material is obtained. In the manufacture of porcelain, the kaolin, and also the other ingredients, are first ground up separately to an im SAND-CLAY. 37? palpable powder The kaolin is mixed with a certain pro. portion of feldspar, flint and lime. The whole are worked up together in water, by mallets and spades, and well knead. ed by the hands and sometimes the feet of the workmen, The plastic material is then laid aside in masses of the size of a man's head, and kept damp till required; ihe dough, as it is called, is now ready for the potter's lathe, (or other means,' by which it is moulded into the arious forms of china ware. After moulding, they are slowly and thoroughly dried, and then taken to the kiln, for a preliminary baking. They come out in the state'of biscuit, and are ready for painting and glazing. The colors are metallic oxyds, which are put on either from a wet copper-plate impression on bibulous paper, or by means of a brush. The former is used for flat surfaces; the paper is rubbed on carefully to transfer the impression to the porcelain, and is then wet and washed off. It is then carefully heated to evaporate any oil or grease employed in the printing. The glaze is made of a quartzose feldspar; it is ground to a very fine powder and worked into a paste with water, and a little vinegar. The articles are dipped for an instant into this milky fluid, and as they absorb the water they come out with a delicate layer of feldspar in a dry state. They are touched with a brush wherever not well covered. They are then ready to be finally baked in the kiln, for which purpose each vessel is placed in a separate baked clay case or receptacle, called a sagger. In this process the material undergoes a softening, amounting almost to a partial fusion, and thus receives the translucency which distinguishes porcelain from earthen or stone ware. The blue color of common china is produced by means of oxyd of cobalt; carmine, purple and violet, by means of chlorid of gold; red of all shades by oxyd of iron; yellow by oxyd of lead, or white oxyd of antimony and sand; green by oxyd of copper or carbonate of lead; brown by oxyd of iron, manganese, or copper. A steel luster is produced from chlorid of platinum. The best Sevres ware is made from 63 to 70 parts of kaolin, 22 to 15 of feldspar, nearly 10 of flint, and 5 or 6 of chalk. In China the kaolin is mixed with a quartzose feldspar rock, consisting mainly of quartz, called peh-tun-tsz. Soapstone is sometimes used in this manufacture; and ai it substitutes magnesia for a part of the potash, it makes r harder ware; but it is also more brittle. 374 L('OAI.ITIES OiF MINERALS. CHAPTER IX. CATALOGUE OF AMERICAN LOCALITIES OF MINERALS. The following catalogue may aid the mineralogical tourist in selecting his routes and arranging the plan of a journey. Only important localities, affording cabinet specimens, are in general included. The names of those minerals which are obtained in good specimens at the several localities, are distinguished by italics. When the specimens are remarkably good, an exclamation mark (!) has been added, or two of these marks (!!) when the specimens are quite unique. MAINE. MT. ABRAHAM.-Andalusite, staurotide. ALBANY.-Beryl! green and black tourmnaline, feldspar, rose quartz. ALBION.-Iron pyrites. AROOSTOOK.-Red Hematite. BINGIAM.-Massive pyrites, galena, blende, andalusite. BLUE HILL BAY.-Arsenical iron, molybdenite! galena, apatite! fluor spar! black tourmaline, (Long Cove,) black oxyd of manganese, (Osgood's Farm,) rhodonite, bog manganese, wolfram. BOWDOINHAM.-Beryl, molybdenite. BRUNSWICK.-Green mica, garnet! black tourmaline! molybdenite. BUCKFIELD.-Garnet, (estates of Waterman and Lowe,) iron ore. CAMDAGE FARM.-(Near the tide mills,) molybdenite, (wolfram.) CAMDEN.-Macle. CARMEL, (Penobscot Co.)-Gray Antimony. CORINNA.-Iron pyrites, arsenical pyrites. DEER IsLE.-Serpentine, verd antique, abestus, diallage. DExTER.-Galena, pyrites, blende, copper pyrites, green talc. DIXFIELD.-Native copperas, graphite. FARMINGTON.-(Norton's ledge,) pyrites, graphite, bog ore. GEoRGETOWN.-(Parker's island,) beryl! black tourmaline. GREENWOOD.-Graphite, black manganese. HARTWELL.-Staurotide. LENox.-Galena, pyromorphite. LEWISTON.-Garnet. LITCHFIELD.-Sodalite, cancrinite, nepheline, zircon. LUBEC LEAD MINES.-Galena, copperpyrites, blende, pyromorphite, an ore of bismuth. MADRID.-Gold. NEWFIELI), (Boid's Mt.)-Mispickel, olive phosphate of iron in boti-oidal n.asses. PARS. —Green! red! black and blue tourmaline! mica! lepidolite I feldspar, all ite, quartz crystals! rose quartz, blende. AMERICAN 1,CALITIES. 375 PARSONSFrIE.D.-Idocrase! yellow garnet, pargasste, adularia, scapolite, galena, blende, copper pyrites. PERRY.-Prehnite and calc spar, (above Loring's cove,) quarta crystal, calc apar. analcime, apophyllite, agate, (Gin Cove.) PERU.- Crystallized p,. rites. PRIPSBURG.- Yellow garnet! manganesian garnet, idocrase, pat gasite, axinite, lauizonite! chabazite. POLAND.'-Idocrase. RAYMOND.-AMagnetic iron, scapolite, pyroxene, lepidolite, tremolite bornblende. RUMFORLt. — Yellow garnet, idocrase, pyroxene, apatite, scapolite, graphite. SANFORD, York Co.-Idocrase! albite, calcite, molybdenite, epidote. SEARSMONT.-A ndalusite. STREAKED MOUNTAIN.-Beryl! black tourmaline, mica, garnet. THOMASTON.-Calcite, tremolite, hornblende, sphene, arsenical iron, (Owl's head,) black manganese, (Dodge's mountain.) WARREN. —Galena, blende. WATERVILLE.- Crystallized pyrites. WINDHAM, (near the bridge.)-Staurotide, spodumene, garnet. WOODSTOCK, (New Brunswick.)-Graphite, specular iron. NEW HAMPSHIRE. ACWORTH.-Beryl I I mica I tourmaline, feldspar, albite, rose quartz, columbite! ALTEAD. —Mica! I albite, black tourmaline. AMHERST.-Idocrase I yellow garnet, pargasite, cale spar. BARTLrE. — Magnetic iron, specular iron, brown iron ore in large veins near Jackson, (on "Bald face mountain,") quartz crystals, smoky quartz. BATH.-Galena, copper pyrites. BELLOWS FALLS.-Kyanite, wavellite, near Saxton's river BENTON.-Quart crystals. CAMPTON.-Beryl I CANAAN.-Gold in pyrites. CHARLESTOWN.-Staurotide made, andalusite made, bog iron ore. CORNISH.-Gray antimony, antimonial argentiferous gray copper, rutile in quartz I (rare.) EATON, (3 m. S. of.)-Galena, blende I copper pyrites, limonite, (Six Mile Pond.) FRANCESTON.-Soapstone, arsenical pyrites. FRANCONIA.-Hornblende, staurotide! epidote! zoisite, specular iron, ozagnetic iron, black and red manganesian garnets: mispickel I (Danaite,) copper pyrites, molybdenite, prehnite; specimens now hardly obtainable. GILFORD.-(Gunstock Mt. )-Magnetic iron ore, native "lodestone." GosHEN.-Graphite, black tourmaline. GRAFTON.-Mica! (extensively quarried at Glass Hill, 2 m. S. of Orange Summit,) albite! asparagus stone, blue, green and yellow icryls' (1 m. S. of 0. Summit,) to-urmaline, garnets. 376 LOCALITIES OF MINERALS. GRANTHAM. — Gray staurotide I HANOVER.-Garnet, a boulder of quartz containing rutile! blacA tourmaline, quartz. HAVERHILL.-Garnet! arsenical pyrites, native arsenic, galena, blende, iron and copper pyrites, magnetic and white iron pyrites. HILLSBORO', (Campbell's Mountain.) —Graphite. HILLsDALE.-Rhodonite, black oxyd of manganese. JACKSON.-Drusy quartz, tin ore, arsenical pyrites, native arsenic, fluor spar, apatite, magnetic iron ore, molybdenite, wolfram, copper pyrites, arsenate of iron. JAFFREY.-(Monadnock Mt.) —Kyanite. KEENE.-Graphite, soapstone, milky quartz. LANDAFF.-Molybdenite, lead and iron ores. LEBANON.-Bog iron ore. LISBON.-Staurotide, black and red garnets, granular nagneticiron ore, hornblende, epidote, zoisite, specular iron. LYME.-Kyanite, (N. W. part,) black tourmaline, rutile, iron pyrites, copper pyrites, (E. of E. village,) sulphuret of antimony. MERRIMACK.-Rutile I (in gneiss nodules in granite vein.) MOULTONBOROUGH, (Red Hill.)-Hornblende, bog ore, pyrites, tourmaline. NEwPORT.-Molybdenite. ORANGE.-Blue beryls! Orange Summit, chrysoberyl, mica, (w. side of mountain.) ORFORD.-Brown tourmaline, (now obtained with difficulty,) steatite, rutile, kyanite, brown iron ore, native copper, green malachite, galena. PELHAM.-Steatite. PIERMONT.~-JMicaceous iron, heavy spar, green, white and brown mica, apatite. PLYMouTH.-Columbite, beryl. RICHMOND.-Iolite! rutile, steatite, iron pyrites. SADDLEBACK MT.-Black tourmaline, garnet, spinel. SHELBURNE.-Argentiferous galena, black blende, copper pyrites, iron pyrites, manganese. SPRINGFIELD.-Beryls, (very large, eight inches diameter,) manganesian garnets! in mica slate, albite mica. SULLIVAN.-Tourmalines, (black,) in quartz, beryl? SuRREY.-Amethyst, calcite. SWANZEY, (near Keene.)-Magnetic iron, (in masses in granite.) TAMWORTH, (near White Pond.)-Galena. UNITY, (estate of James Neal.)-Copper and iron pyrites, chlorophyllite, green mica, magnetic iron, radiated actinolite, garnet, titaniferous iron ore, magnetic iron ore. WALPOLE, (near Bellows Falls.)-Macle. WARREN.-Copper pyrites, blende, epidote, quartz, iron pyrites, tre molite, galena, rutile, talc, molybdenite. WESTMORELAND, (South part.)-Molybdenite! apatite! blue feldspar, bog manganese, (north village,) quartz, fluor spar, copper pyrites, oxyd of molybdenum and uranium. WHITE MTS., (notch behind " old Crawford's house.")-Green ocs tahedral fluor, quartz crystals, black tourmaline. chiastolite. AMERICAN LOCALtTIES 37; WVLMOT.-Beryl. WmCHESTER.-Pyrolusite, diallogite, psilomelane, magnetic iron ore. granular quartz. VERMONT ADDISON.-Iron sand. ALBURGH.-Quartz crystals on calc spar, iron pyrites. ATHEN.-Sttteatite, homb spar, actinolite. BARNET.-Graphite. BELVIDEE. —Steatite, chlorite. BENNINGToN.-Pyrolusite, brown iron ore, pipe clay, yellow ochre. BETrHEL.-Actinolite! talc, chlorite, octahedral iron, rutile, brov n spar in steatite. BRANDON.-Braunite, pyrolusite, psilomelane, limonite, lignite, white clay, statuary marble; fossil fruits in the lignite. BRATTLEBOROUGH.-Black tourmaline in quartz. BRIDGEWATER —Talc, dolomite, magnetic iron, steatite, chlorite, gold, native copper, blende, galena, blue spinel, copper pyrites. BRISTOL —Rutile, brown hematite, manganese ores. BROOxFIELD.-Mispickel, iron pyrites. CABOT.-Garnets, staurotide, hornblende, albite. CASTLETON.-Roofing slate. CAVENDIsH.-Garnet, serpentine. CHESTER. —Asbestus. CHITTENDEN.-Psilomelane, pyrolusite, brown iron ore, speculaf and magnetic iron, galena. CoLCHEsTER.-Brown iron ore, iron sand, jasper, alum. CORINTH.-Copper pyrites, (has been mined;) magnetic iron pyrites. CovENTRY.-Magaganese spar. CRAFTSBURY.-Mica in concentric balls. DUMMERSTON.-Rutile. FLETCHER —Pyrites, octahedral iron, acicular tourmaline. GRAFTON.-The steatite quarry referred to Grafton is properly in Athens. GUILFORD. -Scapolite. HARTFORD.-Calcite, pyrites! kyanite in mica slate. IRASBURGH.-Rhodonite, psilomelane. JAY.-Chromic iron, serpentine, picrosmine, amianthus. LOWELL.-Picrosmine, amianthus. MARLBORO'.-Rhomb spar, steatite, garnet, magnetic iron. MENDON.-Octahedral iron ore. MIDDLEBURY.-Zircon. MIDDLEsEX. —Rutile I (exhausted.) MoNKTON.-Pyrolusite, brown iron ore. MORETOWN.-Smoky quartz! steatite, talc, wad, rutile. MIORRISTOWN.-Argentiferous galena. MOUNT HOLL. —Asbestus, chlorite. NEW FANE.-Glassy and abestiform actinolite,.teatite, greein farf. (called chrysoprase at the locality,) chalcedony, drusy Iilta^z garnet, chromic iron, rh;mb spar. NoRwci(H.-Actinoi'te, feldspar, brown spar in talc. 13 l78 LOCALITIES OF MINERALS, P'TrrsFoulp.-Brow iron ore, manganese ores. ILYMOUTH.-Spathic iron, magnetic and specular iron, both is octahedral crystals. PLYMPTON. Massive hornblende. PUTNEY.-Fluor, brown iron ore, rutile, and zoisite il boulders. READING.-Glassy actinolite in talc. READSBORO'. —(lassy actinolite, steatite. R1PTON.-Brown iron ore, augite in boulders, octahedral iron pyrites. ROCHESTER.-Rutile, specular iron cryst., magnetic iron, in chlorite atate. ROXBURY.-Dolomite, talc, serpentine, asbestus. SALISBURY.-Brown iron ore. SHARON.-Quartz crystals, kyanite. SHOREHAM.-Iron pyrites. SHREWSBURY.-Magnetic iron and copper pyrites. SoMERSET.-Magnetic iron, native gold. STAFFORD.-Magnetic iron and copper pyrites, (has been worked,) native copper, hornblende. STARKSBORO'.-Brown iron ore. STIRLING.-Copper pyrites, talc, serpentine. STOCKBRIDGE.-Mispickel, magnetic iron ore. THETFrRD.-Blende, galena, kyanite; chrysolite in basalt. TRoY.-Jagnetic iron, talc, serpentine, picrosmine, amianthus, steatite, one mile southeast of village of South Troy, on the farm of Mr. Pierce, east side of Missisco, chromic iron. WARREN.-Actinolite, magnetic iron ore, wad. WATERBURY.-Mispickel, copper pyrites, rutile, quartz. WATERVILLE.-Steatite, actinolite, talc. WELLS RIVER.-Graohite. WESTFIELD.-Steatite, chromic iron, serpentine. WESTMINSTER.-Zoisite in boulders. WARDSBORO'.-Zoisite. WINDIIAM.-Glassy actinolite, steatite. WooDBURY.-Massive pyrites. WOODSTOCK. — Quartz crystals. MASSACHUSETTS ALFORD.-Galena, iron pyrites. ATIHOL.-Allanite, fibrolite (?) epidote I babingtonite AUBURN.-Ifasonite. BARRE.-lRutile I mica, pyrites, beryl, feldspar, garnet. GREAT BARRINGTON.-Tremolite. BEDFORD.-Garnet. BELCHERTOWN.-Allanite. BERNARDSTON.-Magnetic oxyd of iron. BEVERLY.-Polymignite, columbite, green feldspar, tin ore. BLANFORD. — Marmolite, schiller spar, serpentine, anthophyllite, actinolite! chromic iron, kyanite, rose quartz in boulders. BOLTON.-Scapolite! petalite, sphene, pyroxene, nuttalite, diopside, boltonite (chrysolite), petalite, apatit', magnesite, rhomb spar, al lanite, yttrocerite, cerium ochre (on the scapolite), spinel. AMERICAN LOCALITIES. 379 BOXBOROUGH.-Scapolite, spinel, garnet, augit, atinolite, ati patite. BRIGHTON.-Asbestus. BRIMFIELD, (road leading to Warren.) —Iolite, adularia, molybdenite, mica, garnet. CARLISLE.-Tourmaline, garnet! scapolite, actinolite. CHARLESTOWN.-Preknite, laumonite, stilbite, chabazite, quartz crystals. CHELMSFORD.-Scapolite, chondrodite, blue spinel, amianthus I rose quartz. CHEsTER.-Hornblende, scapolite, zoi.site, spodumene, indicolite, apatite-magnetic iron and chromic iron, (west part,)-stilbite, heulandite, analcime and chabazite. CHESTERFIELD.-Blue, green, and red tourmaline, cleavelandite (albite), lithia mica, smoky quartz, microlite, spodumene, kyanite, apatite, rose beryl, garnet, quartz crystals, staurotide, tin ore, columbite, erubescite, zoisite, uranite, brookite (eumanite). CoNWAY.-Pyrolusite, fluor spar, zoisite, rutile!!native alum, galena. CUAHMINGTON.-Rhodonite f cummingtonite (hornblende), white iron pyrites, garnet. DEDsHAM.-Asbestus, galena. DEERFISLD.-Chabazite, heulandite, stilbite, amethyst, carnelian, chalcedony, agate. FIT( BURG, (Pearl Hill.)-Beryl, staurotide! garnets, molybdenite. FOXBOROUGH.-Iron pyrites, anthracite. FRANKLIN.-Amethyst. GOSHEN. —Mica, albite, spodumene blue and green tourmaline, beryl, zoisite, smoky quartz, columbite, tin ore, galena. GREENFIELD, (in sandstone quarry, half mile east of village.)Allophane, white and greenish. HATFIELD.-Heavy Spar, yellow quartz crystals, galena, blende, copper pyrites. HAWLEY. —Micaceous iron, massive pyrites, magnetic iron, zoisite. HEATH. —Pyrites, zoisite. HI'3DALE.-Brown iron ore, apatite, zoisite. HUBBARDSTON.-Massive pyrites. LANCASTER.-Kyanite, chiastolite I apatite, staurotide, pinite, andalusite. LEE.-Tremolite sphene! (east part.) LENOx.- Brown hematite, gibbsite, (?) LEVERETT.-Heavy spar, galena, blende, copper pyrites LEYDEN.-Zoisite, rutile. LITTLETON.-Spinel, scapolite, apatite. LYNNFIELD.-Magnesite on serpentine. MARTHA'S VINEYARD.-Brown iron ore amber, selenite, radiated pyrites. MENDON.-Mica I chlorite. MIDDLEFIELD.-Glassy actiiolite, rhomb spar, steatite, serpentine, feldspar, drusy quartz, apatite, zoisite, nacrite, chalcedony, talc I MILBURY.- Vermiculite. MoNTAaUE. —Specular iron. 380 LOCALITIES OF MINERALS. NEWBURY.-Serpentine, chrysolite, epidote, massive garnet, car bonate of iron. NEWBURYPORT.-Serpentine, nemalite, uranite. NEW BRAINTREE. -Black' tourmaline. NORWICH.-Apatite I black tourmaline, beryl, spodumene I triphy line (altered), blende, quartz crystals. PALMER, (Three Rivers.)-Feldspar, prehnite, calc spar. PELHAM.-Asbestus, serpentine, quartz crystals, beryl, molybdenite green hornstone. PLAINFIELD.-Cummingtonite, pyrolusite, rhodonite. RICHMOND.-Brown iron ore, gibbsite I RowE.-EFpidote, talc. SOUTH RoYALSTON.-Beryl l / (now obtained with great difficulty,) mica! feldspar ilmenite, allanite. Four miles beyond old loc., on farm of Solomon Heywood, mica! beryl I feldspar I RUssEL.-Schiller spar, (diallage 1) mica, serpentine, beryl, galena, copper pyrites. SAUGUS. —Porphyry. SHEFFIELD.-Asbestus, pyrites, native alum, pyrolusite. SHELBURNE.-Rutile. SHUTESBURY, (east of Locke's Pond.)-Molybdenite. SOUTIIAMPTON.-Galena, white lead ore, anglesite, molybdate of lead, fluor, heavy spar% copper and iron pyrites, blende, corneous lead, pyromorphite. STERLING.-Spodumene, chiastolite, spathic iron, mispickel, blende, galena, iron and copper pyrites. STONEHAM. —Nephrite. STURBRIDGE.-Graphite, garnet, apatite, bog ore. TAUNTON, (one mile south.)-Paracolumbite. TURNER'S FALLS, (Conn. River.)-Copper pyrites, prehnite, chlorite, chlorophaeite, spathic iron, green malachite, magnetic iron sand, anthracite. TYRINGHAM.-Pyroxene, scapolite. UXBRIDGE.-Argentiferous galena. WARWICK. —a assive garnet, black tourmaline, magnetic iron, beryl,.epidote. WASInNGTON. Graphite. WESTFIELD.-Schiller spar, (diallage,) serpentine, steatite, kyanite, scapolite, actinolite. WESTFORD.-Andalusite I WEST HAMPToN.-Galena, argentine, pseudomorphous quartz. WEST SPRINGFIELD.-Prehnite, ankerite, satin spar, celestine, bituminous coal. WEST STOCKBRIDGE.-Hematite, fibrous pyrolusite, spathic iron. WHATELY.-Native copper, galena. WILLIAMSBURG.-Zoisite, pseudomorphous quartz, apatite, rose and smoky quartz, galena, pyrolusite, copper pyrites. WILLIAAISTOWN.-Cryst. quartz. WINDSOR.-Zoisite, actinolite, rutile! WORCESTER.-Mispickel, idocrase, pyroxene garnet, amianthns, bucholzite, spathic iron, galena. WoRTHINGTON.-Kyanite. Z&oA. —Bitter spar, talc. AMERICAN LOCALITIES. 381 RHODE ISLAND. BRISToL.-Amethyst. CRANSToN.-Actinolite in talc. CUMBERLAND.-Manganese, epidote, actinolite, garnet, titaniferoua iron, magnetic iron, red hematite, copper pyrites. FOSTER.-Kyanite. JOHNSON.-Talc, brown spar. NEWPORT. Serpentine. PoRTSMOUTH.-Anthracite, graphite, asbestus, iron pyrites. SMITHFIELD.-Dolomite, calc spar, bitter spar, nacrite, serpentine (bowenite), tremolite, asbestus, quartz, magnetic iron in chlorite slate, talc!! WARWICK, (Natic village.) —Masonite, garnets, graphite. WESTERLY.-llmenite. CONNECTICUT. BERLIN.-Heavy spar, datholite, blende, quartz crystals. BoLToN.-Staurotide, copper pyrites. BRADLEYVILLE, (Litchfield.)-Laumonite. BRISTOL.-Copper glance, copper pyrites, heavy spar, erubescite, talc, allophane, pyromorphite. BROOKFIELD. —Galena, calamine, blende, spodumene, magnetic pyrites. CANAAN.-Tremolite and augite I in dolomite. CHATHAM.-Mispickel, smaltine, chloanthite (chathamite), scorodite, copper nickel, beryl. CHESHIRE.-Heavy spar! copper glance cryst., erubescite, green malachite, kaolin, natrolite, prehnite, chabazite, datholite. CHESTER.-Sillimanite! zircon, epidote. CORNWALL, near the Housatonic.-Graphite, pyroxene. DANBURY. —Danburite, oligoclase, moonstone, brown tourmaline. FARMINGTON.-Prehnite, chabazite! agate, native copper. GRANBY.-Green malachite. GREENWICH.-Black tourmaline. HADDAM.-Chrysoberyl! beryl! epidote! tourmalise I feldspar, anthophyllite, garnet! iolite! oligoclase, chlorophyllite! automolite, magnetic iron, adularia, apatite, columbite! zircon (calyptolite), mica, white and yellow iron pyrites, molybdenite, allanite., bismuth, bismuth ochre. HADLYME.-Chabazite and stilbite in gneiss, with epidote and garnet. HARTFORD.-Datholite, (Rocky Hill quarry.) KENT.-Brown iron ore, pyrolusite, ochrey iron ore. LITCHFErLD.-Kyanite with corundum, apatite and andalusite, ilmenite, (washingtonite,) copper pyrites. LYME.-Garnet, sunstone. MERIDEN.-Datholite. MIDDLEFIELD FALLs.-Datholite, chlorite, &c., in amygdaloid. MIDDLErOWN.-Mica, lepidolite with green and red tourmaline, albite, feldspar, columbite! prehnite, garnet, beryl, topaz, uranite 18* 382 LOCALITIES OF MINERALS. apatite, pitchblende; at lead mine, galena, copper pyrites, bleude, quartz, calcite, fluor, iron pyrites, sometimes capillary. MILFORD. - Sahlite, pyroxene, asbestus, zoisite, verd-antique marble, pyrites. NEW HAvEN.-Serpentine, asbestus, chromic iron, sahlite, stilbite, prehnite. NoRWICH.-Sillimanite, monazite! zircon, iolite, corundum, feld. spar. OXFORD, near Humphreysville.-Kyanite, copper pyrites. PLYMOUTH.-Galena, heulandite, fluor. ROARING BROOK, (Cheshire.)-lAtholite! calc spar, prehnite, 0aponite. READING, (near the line of Danbury.)-Pyroxene, garnet. RoBURY. —Massive spathic iron, blende. SALISBURY.-Brown iron ore, ochery iron, pyrolusite, triplite. SAYBRooK.-Molybdenite, stilbite, plumbago. SIMSBURY.-Copper glance, green malachite. SOUTHBURY.-Rose quartz, laumontite, prehnite, calc spar, heavy spar. SOUTIINGTON. —Heavy spar, datholite, asteriated quartz cystals. STAFFO D). —Massive pyrites. SToNINGToN.-Stilbite and chabazite on gneiss. THATCHERSVILLE, (near Bridgeport.) —Stilbite on gneiss, babingtonite e TOLLAND.-Staurotide,. massive pyrites. TRUMBULL and MoNRoE. Chlorophane, topaz, beryl, diaspore, magnetic pyrites, iron pyrites, tungstate of lime, wolfram, (pseudomorph of tungsten,) rutile, native bismuth, tungstic acid, spathic iron, mispickel, argentiferous galena, blende, scapolite, tourmaline, garnet, albite, augite, graphic tellurium, (?) margarodite. WASHINGTON.-Triplite, ilmenite! (washingtonite of Shepard,) diallogite, natrolite, andalusite, (New Preston,) kyanite. WATERTOWN, near the Naugatuck.-White sahlite, monazite. WEST FARMS.-Asbestus. WINCHESTER and WILTON.-Asbestus, garnet. NEW YORK. ALBANY CO.-COEYMAN's LANDING.-Epsom salt. GUILDERLAND.-Petroleum. WATERVLIET.-Quartz crystals. ALLEGANY CO.-CUBA.-Petroleum. CATTARAUGUS CO.-FrFEEVoM3.-Petroleum. CAYUGA CO.-AUBURN..-Fluor, epsom salt. CAYUGA LAKE.-Sulphur. LrUDLowVILLE.-Epsom salt. SPRINGVILLE.-Nitrogen springs. CHATAUQUE CO.-FREDONIA. —Petroleum, carbaretted hydrogfe LAoNA.-Petroleum. AMERICAN LOCALITIES. tS COLUMBIA CO.-ANCRAM LEAD MINE.-Galena, blende, coppet pyrites, heavy spar. AUSTERLITZ.-Earthy manganese, molybdate of lead, copper mica. HUDSON.-Selenite I LEBANON. —~Nitrogen spring. DUCHESS CO.-DovER.-Garnet (Foss ore bed.) FISHKILI.-Graphite, green actinolite I talc, hydrous anthophyllite. RHINEBECK.-Granular epidote. UNION VALE.-Gibbsite, (at Clove mine.) AMENIA.-Brown hematite. ESSEX CO.-ALEXANDRIA.-Kirby's graphite mine, graphite, pyroxene, scapolite, sphene. CROWN POINT.-Apatite, (eupyrchroite of Emmons,) brown toutrmaline I in the apatite, chlorite, quartz crystals, pink anld bluti calcite, pyrites; a short distance south of J. C. Ianimontr d's house, garnet, scapolite, copper pyrites, aventurine feldspar, zircon; magnetic iron (Peru). LEwIS.-Tabular spar, colophonite, garnet, labradorite. LONG POND.-Apatite, garnet, p,yroxene, idoci-ase, coccolite!! scapolite, magnetic iron ore, blue calc spar. McINTYRE.-Labradorite, garnet, magnetic iron ore. MORIAH, at Sandford Ore Bed.-Magnctic iron, apatite, allanitel actinolite, and feldspar; at Fisher Ore Bed, magnettic iron, feldspar. quartz; at Hall Ore Bed, or " New Ore Bed," magnetite, zircons. NEWCOMB.-Labradorite, feldspar. PORT HENRY.-Brown tourmaline, msica, rose quartz, serpentine, green and black pyroxene, hornblende, cryst. pyrites, magntlic pyrites, ddularia. Phlogopite! at Cheever Ore Bed, with Inagnetite and serpentine. ROGER'S RocK.-Graphite, tabular spar, garnet, colophonite, feldspar, adularia, pyroxene, sphene, coccolite. SCHRooN.-Calc spar, pyroxene, chondrodite. TICONDEROGA.-Graphite, pyroxene, sahlite, sphene, black tourmaline. WEsTPORT.-Labradorite, prehnite. WILLSBORO'.-Tabular spar, colophonite, garnet, green co(colite, hornblende. FRANKLIN CO.-CHATEAUGAY.-Nitrogen springs. MALONE.-Massive pyrites, magnetic iron ore. GENESEE CO.-Acid springs containing sulphuric acid. GREENE CO.-CATsKILL.- Calc spar. DIAMOND HILL.-Quartz crystals. HERKIMER CO.-LTILE FALLS.-Quartz crystals heavy spat cale spar, anthracite. MIDDLEVILLE. — Qartz crystals! cale spar, brown and pearl spar SALISBURY.-Quartz crystals! blende, galena, iron and cappei pyrites. STARK.-Fibrous celestine, gypsmn. 384 LOCALITIES OF MINERALS. JEFFERSON CO.-ALEXANDRIA.-Hornblende, orthoclase, tour mnaline, celestine. ADAMS,-Fluor, cale tufa, barytes. ANTwERP.-Stirling iron mine, specular iron, chalcodite, spathit iron, millerite, nickeliferous iron pyrites, quartz crystals, pyrites at Oxbow, calc spar porous coralloidal heavy spar; near Vrooman's lake, calc spar I idocrase, phlogopite! pyroxene, sphene, fluor, calcite, pyrites, copper pyrites; alsofeldspar, bog iron ore, scapolite, (farm of Da id Eggleson,) serpentine, tourmaline (yellow, rare). HIlG; ISLAND, (in the St. Lawrence.) —Tourmaline. PAMrELIA.-Agaric mineral, calc tufa. PILLAR POINT.-Massive heavy spar (exhausted). THIERESA.-Fluor, calcite, specular iron ore, hornblende, quartz crustals. serpentine, (associated with the specular iron,) celestine strontianite: the Muscolonge lake locality of fluor is exhausted. WATERTOWN.-Tremolite, agaric mineral, calc tufa, celestine. [This county adjoins St. Lawrence Co., and the localities of Rossie, Hammond and Gouverneur, near Oxbow, are in the latter county.] LEWIS CO.-DIANA, (localities mostly near junction of crystalline and sedimentary rocks, and within two miles of Natural Bridge.) Scapolite! tabular spar, green coccolite, feldspar, tremolite, black pyroxene, sphene, mica, quartz crystals, drusy quartz, cryst. pyrites, magnetic pyrites, blue calc spar, serpentine, rensselaerite, zircon, graphite, chlorite, specular iron, bog iron ore, iron sand. GREIG. —Magnetic iron ore, pyrites. LOWVILLE.-Calc spar, fluor spar, pyrites, galena, blende, calc tufa. MARTINSBURGH.-Wad, galena, etc., but mine not now opened. WATSON, BREMEN.-Bog iron ore. MONROE CO.-ROCHESTER.-Pearl spar, calc spar, snowy gyp sum, fluor, celestine, galena, blende. MONTGOMERY CO.-ROoT.-Pearl spar, drusy quartz, blende. PALATINE.-Quartz crystals, drusy quartz. NEW YORK CO.-CORLAER's Hoo. —Apatite. KINGSBRIDGE.-Tremolite, pyroxene, mica, tourmaline, pyrites, rutile. HARLEM.-Epidote, apophyllite, stilbite, tourmaline, vviianite, lamellar feldspar, mica. NEW YORK.-Serpentine, amianthus, actinolite, talc, pyroxene, hydrous anthophyllite, garnet, staurotide, molybdenite, graphite NIAGARA CO.-LEwIsTON.-Epsom salt. LOCKPORT.-Celestine, cale spar, selenite, anhydrite, fluor, pearl spar, blende. NIAGARA FALLS.-Calc spar, fluor, blende. ONEIDA CO.-BOONVILLr.-Calc spar, tabular spar, coccolite. CLINToN.-Blende, lenticular argillaceous iron ore; in rocks of the Clinton Group, strontianite, celestine, the former covering the latter. ONONDAGA CO.-CAMILLUS.-Selenite and fibrous gypsum. MANL.TUS.-Gypsum and fluor. Svi LA vsruE.-Serpentine. celestine. AMERIC.rr LOCALITIES. 38i ORANGE CO. —CoRNwALL.-Zircon, chondrodite, ho, rnolende, spinel, massive feldspar, fibrous epidote, hudsonite, ilmenite, serpentine, boltonite. DEEzR PARK. —Cryst. pyrites, galena. MONROE. — ica! sphene I garnet, colophonite, epidote, chondrodile. allanite, bucholzite, brown spar, boltoAite, spinel, hornblende, tale, ilmenite, magnetic pyrites, common pyrites, chromic iron, graphite. At WILKS and O'NEIL Mine in Monroe.-Aragonite, magnetite, di magnetite (pseud f), jenkinsite. At Two PONDS in Monroe.-Pyroxen I chondrodite, hornblende,;capolite! zircon, sphene, apatite. At GREENWOOD FURNACE in Monroe.-Chondrodite, pyroxene I mica kornblende, spinel, scapolite, biotite I ilmenite. At FOREST OF DEAN.-Pyroxene, spinel, zircon, scapolite, horn. olende, boltonite. Town of WARWICK. WARWICK VILLAGE.-Spinel, zircon, serpentine! brown spar, pM roxene! hornblende! pseudomorphous steatite, feldspar! (Rock Hill,) ".'menite, clintonite, tourmaline, (R. H.,) rutile, sphene, molybdenite, mispickel, white iron pyrites, common pyrites, yellow iron sinter. AMITY.-Spinel, garnet, scapolite, hornblende, idocrase, epidote I clintonite! magnetic iron l tourmaline, warwickite, apatite, chondrodite, ilmenite, talc I pyroxene! rutile, zircon, corundum, feldspar, sphene, calc spar, serpentine, schiller spar.(?) EDENVILLE.-Apatite, chondrodite! hair brown hornblende! tre molite, spinel, tourmaline, warwickite, pyroxene, sphene, mica, feld. spar, mispickel, orpiment, rutile, ilmenite, scorodite, copper pyrites WEST POINT.-Feldspar, mica, scapolite, sphene, hornblende, al lanite. PUTNAM CO. —CARMEL, (Brown's quarry.) —Anthophyllitc. schiller spar, (?) orpiment, mispickel. COLD SPRING.-Chabazite, mica, sphene. PArrEnRSON. —White pyroxene! calc spar, asbestus, tremolite, do. lomite, massive pyrites. PHILLIPSTOWN.-Tremolite, amianthus, serpentine, sphene, diopside, green crocolite, hornblende, scapolite, stilbite, mica, laumontite, gurhofite, calc spar, magnetic iron, chromic iron. PinLLIPS Ore Bed.-Hyalite, actinolite, massive pyrites. RENSSELAER CO.-Hoosic.-Nitrogen springs. LANSINGBURGH.-Epsom salt, quartz crystals, iron pyrites. TROY. —Quartz crystals, iron pyrites, selenite. RICHMOND CO. —RossVILLE.-Lignite, cryst. pyrites. QUARAsNTsu.-Asbestus, amianthus, aragonite, dolomite, gurhofite, brucite, serpentine, talc. ROCKLAND CO.-CALDWELt.-Calc spar I GRASSY PoINT.-Serpentine, actinolite. HAVERSTRAw.-Hornblende. LADENTOWN.-Zircon, red copper ore, green malachite. PIERMONT.-Datholite, stilbite, apophyllite, stellite, pr yhnite, thomonite, calc spar. 386 LOCALITIES OF MINERALS. STONY POINT.-Kerolite, lamellar hornblende, asbestu& ST. LAWRENCE CO. —CANTON.-Massive pyrites, calc spar, browa tourmaline, sphene, serpentine, talc, rensselaerite, pyroxene, specular iron, copper pyrites. DEKALB.-Hornblende, heavy spar, fluor, tremolite, tourmaline. blende, graphite, pyroxene, quartz (spongy), serpentine. EDWARDS. —Bron and silvery mica! scapolite, apatite, quartz crystals, actinolite, tremolite, specular iron, serpentine, magnetite. FINE.-Black mica, hornblende. FOWLER.-Heavy spar, quartz crystals! specular iron, blende, galena, tremolite, chalcedony, bog ore, satin spar, (assoc. with serpentine,) iron and copper pyrites, actinolite, rensselaerite, (near Somerville.) GoUvERNEUR. -Calc spar! serpentine! hornblende! scapolite! orthoclase, tourmaline! idocrase, (one mile south of G.,) pyroxene, apatite, rensselaerite, serpentine, sphene, fluor, heavy spar (farm of Judge Dodge,) black mica, phlogopite, tremolite! asbestus, specular iron, graphite, idocrase; (near Somerville in serpentine), spinel, houghite, scapolite, phlogopite, dolomite; three quarters of a mile west of Somerville, chondrodite, spinel; two miles north of Somerville, apatite, pyrites. HAMMOND.-Apatite zircon! (farm of Mr. Hardy), orthoclase, pargasite, heavy spar, pyrites, purple fluor, dolomite. HERMoN.-Quartz crystals, specular iron, spathic iron, pargasite pyroxene, serpentine, tourmaline, bog iron ore. MACOMB.-Blende, mica, galena (on land of James Averil), sphene MINERAL POINT, Morristown.-~Fluor, blenlde, galena, phlogopite (Pope's Mills,) heavy spar. OGDENSBURG.-Labradorite. PITCAIRN.-Satin spar, associated with serpentine. POTSDAM.-Hornblende!-eight miles from Potsdam on road to'ierrepont, feldspar, tourmaline, black mica, hornblende. ROSSIE, (Iron Mines.) —Heavy spar, specular iron, corralloidal aragonite in mines near Somerville, limonite, quartz, (sometimes stalac+'iti3 at Parish iron mine,) pyrites, pearl spar. ROSSIE Lead Mine.-Calc spar, galena, pyrites, celestine, coppel pyrites, spathic iron! white lead ore, anglesite. Elsewhere in RossIE.-(- alc spar, heavy spar, quartz crystals, choz drodite (near Yellow Lake), feldspar! pargasite! apatite, pyroxene hornblende, sphene, zircon, mica, fluor, serpentine. automolite, pearl spar, graphite. RUssEL.-Pargasite, specular iron, quartz (dodec.), calcite, serpentine, rensselaerite, magnetite. SARATOGA CO. —GREENFIELD.- Chrysoberyl! garnet, tourmnaline,iica, feldspar, apatite, graphite, aragonite, (in iron mines.) SCHOHARIE CO.-BALL'S CAVE, and others.-Calc spar, stalac tites. CARLISLE.-Fibrous sulphate of baryta, cryst. and fib. carbonate (re ScoHO ARIE. —Fibrous celestino, strontiaRife! cryst. pyrites AMERICAN LOCALITIES. 387 SENECA CO.-CANOGA.-Nitrogen springs. SULLIVAN CO.-WuRTZBORO'.-Galena, blende, pyrites, ceppc pyrites. ULSTER CO.-ELLENVILLE.-Galena, blende, copper pyrites quartz, brookite. MARBLETOWN.-Pyrites. WARREN CO.-CALDWELL.-f-assive feldspar. CHESTER.-Pyrites, tourmaline, rutile, copper pyrites. DIAMOND ISLE, (Lake George.)-Calc spar, quartz crystals. GLENN'S FALLS. —Rhomb spar. JoHNsBURG.-Fluor! zircon I I graphite, serpentine, pyrites. WASHINGTON CO.-FORT ANN.-Graphite. GRANVILLE.-Lamellar pyroxene, massive feldspar, epidote. WAYNE Co.-WOLCOTT.-Heavy spar. WESTCHESTER CO.-ANTHONY'S NosE.-Apatite, pyrites, calcite! in very large tabular crystals, grouped and sometimes incrusted with drusy quartz. DAVENPORT'S NECK.-Serpentine, garnet, sphene. EASTCHESTER.-Blende, copper and iron pyrites, dolomite. HAsTING. —Tremolite, white pyroxene. NEW ROCHELLE.-Serpentine, brucite, quartz, mica, tremolite garnet. PEEKSKILL.-Mica, feldspar, hornblende, stilbite. RYE.-Serpentine, chlorite, black tourmaline, tremolite. kerolite. SINGsING.-Pyroxene, tremolite, iron pyrites, copper pyrites, beryl azurite, green malachite, white lead ore, pyromorphite, anglesite: vauquelinite, galena, native silver. WEST FARMs.-Apatite, tremolite, garnet, stilbite, heulandite, chabazite, epidote, sphene. YONKERSr.-Tremolite, apatite, calc spar, analcime, pyrites, tourmaline. YoRxTowN.-Sillimanite, monazite, magnetic iron. NEW JERSEY. ABBOTTsvILLB —Serpentine, chrysotil. ANDOVER IRON MINE, (Sussex Co.)-Willemite, brown garnet, marg netite. calcite, blende, fluor, galena, copper pyrites, talc. ALLENTOWN, (Monmouth Co.) —Vivianite. BELVrLLE — Copper mines. BERGEN.-Calc spar, datholite, thomsonite, pectolite (called stellite), analcime, apophyllite, prehnite, sphene, stilbite, natrolite, heulandite, laumontite, chabazite, pyrites, pseudomorphous steatite imitative of apophyllite. BRUNSWICK.-C' pper mines; native copper, malachite, mountain leather. BRYAM.-Chondrodite. CANTWwELLS BRIDGE, Newcastle Co., three miles west.-Vivianite DANVLL. —(Jemmy Jump Ridge.)-Graphite, chondrodite, augita mica. 388 LOCALITIES OF MINERALS. FLEMINGTON.-Copper Mines. FRANKFORT.-Serpentine. FRANKLIN and STERLING.-Spinel! garnet I rhodonite i willemite l franklinite I red zinc ore I dysluite I hornblende, tremnolite, chondrodite, white scapolite, black tourmaline, epidote, pink calc spar, mica, actinolite, augite, sahlite, coccolite, asbestus, jeffersonite (augite), calamine, graphite, fluor, beryl, galena, serpentine, honey- colored sphene, quartz, chalcedony, amethyst, zircon, molybdenite, vivianite. Also algerite in gran. limestone. The zinc ores and franklinite, especially at Sterling Hill in Sterling, the jeffersonite at Mine Hill, in Franklin. FRANKLIN and WARWICK MTS.-Pyrites. GREENBRooK. —Copper mines. GRIGGSTOWN.-~Copper mines. HAMBURGRH.-One mile north, spinel I tourmaline! phlogopste, hornblende, &c., limonite, specular iron. HoBOKEN.-Serpentine, brucite! nemalite (or fibrous brucite), aragonite, dolomite. HURDTOWN.-Apatite, magnetic pyrites, magnetite, chalcedony, feldspar, hornblende. IMLEYTOWN.-Vivianite. LOCKWOOD.-Graphite, chondrodite, talc, augite, quartz, green spinel. MONTVILLE., Morris Co..-Serpentine, chrysotile. MOUNT HOPE. —Three miles N. W. of Rockaway, iron mines, mag netite, pyrites, hornblende, apatite; Mt. Tabo mines, spathic iron, pyrites; at Mt. Pleasant, apatite, hornblende, feldspar. MULLICA HILL, Gloucester Co.- Vivianite lining belemnites and others fossils. NEWTON.-Spinel, blue and white corundum, (exhausted,) mica, idocrase, hornblende, tourmaline, scapolite, rutile, pyrites, talc, cale spar, heavy spar, pseudomorphous steatite. PATTERSON. —Datholite. ROSEVILLE, (Bryan Township, Sussex Co.)-Magnetite, calcite epidote, garnet, mica. SCRUYLER'S MINES.-Green malachite, red copper ore, native cop per, chrysocolla. SOMERVILLE.-Red copper ore, native copper, chrysocolla, green malachite, bitumen, (two miles to the northeast.) SPARTA.-Chondrodite! spinel, sapphire, green talc, graphite, epidote, augite. STANnOPE.-Few miles south, several iron mines. SUCKASUNNY, on the Morris canal.-Brown apatite in magnetic pyrites. TRENTON.-Zircon, amber, lignite. VERNoN.-Green spinel, chondrodite, red sapphire, hornblende, pyrites, phlogopite, graphite, limon'te, rutile, sphene, ilmenite, zircon, fluor, margarite. WOODBRIDGE.-Copper mine. NOTE.-From Amity, N. Y., to Andover, N. J., a distance of about shirty miles, the outcropping limestone, at different points, affords more or less of the minerals enumerated as occurring at Franklin'See Geol. Rep. on N. J., by H. D. Rogers) AMERICAN LOCALITIES. 3S9 PENNSYLVANIA. ADAMS CO.-READING.-Molybdenite in quartz zircoL, magnetic iron ore. BERKS CO.-At JONES'S MiINES, near MORGANTOWN, green mal. achite I -chrysocolla! oct. and dodec. magnetic iron, iron pyrites, copper pyrites;-two miles to the northeast, graphite, sphene; at Steel's mines, octahedral and micaceous iron ore, coccolite; Eckhardt's furnace, allanite. BUCK'S CO.-Opposite New Hope, tourmaline! near Attleboro', at Vanarsdale's limestone quarry, sahlite, scapolite, sphene, green coccolite, graphite, green mica. CARBON CO.-At Mauch Chunk, cryst. iron pyrites, selenite. CHESTER CO.-BIRMINGHAM.-Kerolite, amethyst, quartz cryst., serpentine. E. BRADFORD.-On Minorcus Hill, green, blue and gray kyanite, apatite, allanite; on A. Tayfor's farm, sphene, cryst. smoky quartz; on the farms of B. Jones, B. Price, L. Sharpless, and S. Entrikin, amethyst; near Strode's mill, asbestus, magnesite, marmolite, garnet; near T. Hoope's saw mill, epidote, asbestus; on Osborn's Hill, sphene, manganesian garnet, wad, tourmaline, actinolite, anthophyllite, feldspar, fetid calcite; near the Black Horse Inn, rutile. W. BRADFORD.-Near A. Jackson's limestone quarry, green kyanite, rutile, scapolite, iron pyrites; near Marshall's mill, chromic iron, serpentine; at Poor House (limestone) quarry, (called also Baldwin's,) four miles north of Unionville, and six west of Westchester, rutile I in brilliant acicular crystals; cryst. cale spar, cryst. dolomite, zoisite in quartz, talc in implanted crystals on dolomite, orthoclase I (in fine crystals implanted on dolomite,) quartz crystals. CHESTER SPRINGS.-Gibbsite, in an iron mine; near Coventryville, in Chrisman's limestone quarry, augite, sphene, graphite, zircon I in iron ore about half a mile from the village on French Creek. WEST GosHEN.-Amianthus, asbestus, precious serpentine, cellular quartz, jasper, chalcedony, drusy quartz, chlorite, marmolite, dolomite, cryst. carb. magnesia! chromic iron I magnetic iron; near Westchester Water Works, zoisite, (rare, not found now.) KEIM'S IRON MINE near Knauertown.-Flos-ferri, pyroxene, metaxite, micaceous iron ore, aplome! actinolite, yellow octahedral pyrites, copper pyrites in tetrahedrons, red garnet I malachite, hornblende (var. byssolite.) KENNET TOWNSHIP.-Actinolite I (rare on Gregg's farm,) brown *ourmaline, brown mica, epidote, tremolite, scapolite, aragonite; at Pearce's paper mill, zoisite, epidote, sunstone; on R. Lamborne's farm, chabazite in small brownish yellow crystals, (rare,) zeolite; at Gause's corner, epidote. KNAuERTOWN.-North of Pughtown, graphite, sphene, cryst. magnetic iron; in Chrismard's Iron Mine, zircon. LONDON GRovE.-In Jackson's limestone quarry, yellow tourmaline I (rare,) fib. tremolite; at Pusey's quarry, rutile, tremolite. 13 390 LOCALITIES OF MINERALS. NEW GARDEN TOWNSHIP.-At Nevin's limestone quarry, brown tourmaline scapolite, brown and green mica, rutile, aragonite, kaolin. NEWLIN.-See Unionville, below. EAST MARLBORO.-Epidote, and nearly white tourmaline, (rare). OXFORD.-Iron pyrites, garnets. NOTTINGHAM.-At Scott's chrome mine, chromic iron, foliated talc marmolite, serpentine, chalcedony; at the Magnesian Quarry, magnesite, marmolite, serpentine. PARKSBURG, (in township of Sadsbury.)-In the soil for seven miles along the valley, rutile I; northeast of the village, amethyst, tourmaline, epidote, (in a boulder.) PENN.-Garnets, figure stone. PENNSBURY TOWNSHIP.-On Cephas Cloud's farm, brown garnets!; J. Dilsworth's farm, near Pennsville, mica!! (in six-sided prisms from one quarter to seven inches across); at Harvey's lime quarry, on the Brandywine, chondrodite; quarter of a mile above the last, at Wm. Burnett's lime quarry, sphene, diopside, augite, coccolite. PHENIXVILLE.-In Railroad Tunnel, pearl spar (exhausted), dolomite, yellow blende, iron pyrites; at Wheatley's Mine, pyronworphite. cerusite! cryst. quartz, galena, anglesite! copper pyrites, heavy spar, fluor, wulfenite I calamine, cerasine vanadinite? phosphate of copper, chromate of lead, calcite? POTTSTOWN, near French Cr.-(Elizabeth Mine.)-Iron pyrites! (in octahedrons), copper pyrites, magnetite, dark brown garnet, molybdenite. UNIONVILLE.-One and a half miles northeast, on Serpentine Bar rens, corundum! massive and cryst. (often in loose crystals and also in albite, the loose crystals mostly covered with a thin coating of steatite, sometimes with gibbsite), talc, green tourmaline (with flat or pyramidal terminations), ligniform asbestus, yellow beryl (rare), serpentine, brucite, chromic iron, quartz crystals, green quartz, actinolite, clinochlore in cryst., diallage, granular albite (H=7), adularia, oligoclase, halloysite, margarite, euphyllite, allanite, hematite, chalcedony; half a mile southwest, on T. Webb's farm, serpentine, chromie iron, (mas.); two and a half miles southwest, in R. Bailey's lime quarry, fib. tremolite, mussite; kyanite, margarodite; two miles southwest, at Pusey's saw mill, zircon (cryst. small, loose in the soil, rare), rutile; one mile south, on the farm of Baily and Brothers, bright yellow and nearly white tourmaline! (rare), orthoclase (chesterlite), albite (inaccessible); two miles east, near Marlborough meeting house, epidote (rare), serpentine, acicular black tourmaline in white quartz; one mile west, near Logan's quarry, staurotide, kyanite, yellow tourmaline (rare); at Edward's lime quarry, near the last, purple fluor, rutile; four miles west, in limestone quarries of West Marlborough, near Doe River Village, scapolite, rutile, tremolite. At STEAMBOAT, Wavellite with limonite. WESTCHESTER.-One and a half mile north, hydromagnesite, clino. chlore, brucite, in serpentine, zircon, two miles west; one and a half mile northwest, pitch-black allanite; B.B. intumesces very readily G. 2'5); three miles south, chlinoclore, phlogopite. WILLIsTOWN.-Magnetic iron, chromic iron, actinolite. AMERICAN LOCALITIES. 391 COLUMBIA CO.-At Webb's mine, yellow blende in cale spar near Bloomburg, cryst. magnetic iron. DAUPHIN CO.-Near Hummerstown, green garnets, cryst. smok. quartz, cryst. feldspar. DELAWARE CO.-AsToN.-Near Village Green, amethyst, corundum, emterylite, staurotide, sillimanite, black tourmaline, pearl mica, asbestus, anthophyllite; near Tyson's Mill, garnet, staurotide; at head of Peter's Mill Dam, in a brook, garnet resembling pyrope. BIRMINGH.AM.-At Bullock's quarry, zircon, bucholzite, fibrolite, nacrite. ClHESTER.-Amethyst, black tourmaline; in Burk's quarry, beryl!! black tourmaline! I feldspar! manganesian garnet, cryst. pyrites; on Chester Creek, at Carter's, molybdenite, molybdic ochre, copper pyrites, tournaline, kaolin; at Little's quarry, brown garnets, tourmaline; near Henvi's quarries, amethyst in geodes; six miles northwest'of Chester, chromic iron, in sand, consisting of crystals. CHrICHESTER.-Near Trainer's Mill Dam, beryl, tourmaline, cryst. feldspar, kaolin; on W. Eyre's farm, tourmaline!! CO.NCORD.-On Green's Creek, garnets resembling pyrope, buchol. zite, mica! in hexagonal prisms, beryl, actinolite, anthophyllite, fibrolite, rutile! in capillary crystals in the cavities of cellular rose quartz. DARBY. — Kanite, zoisite, (in a boulder); near Gibbon's, garnets, staurotide. EDGEMONT.-One mile east of Edgemont Hall, near the road, rutile in quartz, amethyst, oxyd of manganese, cryst. feldspar. LEIPERVILLE.-Beryl I in granite; in Judge Leiper's Quarries, beryl, tourmaline, apatite, garnet, cryst. feldspar, mica; at Morris's Ferry, kyanite, sillimanite, apatite, red garnet, mica; at Hill's Quarries, chabazite, stilbite, zeolite, epidote, sphene, albite, calcite, cryst. pyrites; near Leiper's Church, on the edge of a wood, andalusite, apatite, tourmaline, mica, gray kyanite. MARPLE. — ourmaline!; on A. Worrall's farm, andalusite, tour maline; near C. Palmer's Mills, beryl, tourmaline, actinolite, amethyst. MINERAL HILL.-CorundumI aventurine feldspar (sunstone), chatoyant feldspar (moonstone), actinolite, green coccolite, green feldspar! chromic iron, cryst. green quartz, ferruginous quartz, asbestus, hydrous anthophyllite, brown garnet! magnesite, marmolite, bronzite, chalcedony, limonite, labradorite, float stone, red garnet, beryl, serpentine. PROVIDENCE.-At Blue Hill, serpentine, cryst. green quartz in green talc, asbestus, talc, anthophyllite, actinolite, hydrous anthophyllite; on M. Hunter's farm, amethyst! (one finely colored cryetal found weighing over 7 lbs.), andalusite. RADNER.-Garnets, marmolite, deweylite, serpentine, chromic iron, asbestus, magnesite. SPRINGFIELD.-Andalusite; on Abby Worral's farm, tour maline, beryl, ilmenite? garnets; on Fell's Laurel Hill, beryl, garnet; ne.'t 392 LOCALITIES OF MINERALS. Beattie's Mill, staurotide, apatite; near Lewis's Parer Mill, tour maline, mica. HUNTINGTON CO.-Near Frankstown, in the bed of a stream, and on the side of a hill, fibrous celestine, abundant. LANCASTER CO.-Near Texas, in the south part of the county. at Wood's Chrome Mine, emerald nickel, pennite, kcemmererite, millerite, baltimorite, chromic iron, marmolite, picrolite, hydromagnesite, brucite, dolomite, cryst. magnesite, calcite, serpentine; at Lowe's Mine, hydromagnesite, brucite, picrolite! magnesite, chromic iron, talc, emerald nickel, serpentine, baltimorite; on M. Boice's farm, N. of the village in the soil, cryst. pyrites I anthophyllite, marmolite, magnesite; near the Rock Spring, chalcedony, carnelian, moss agate, green tourmaline in talc, titanic iron, cryst. magnetic iron in chlorite; at Reynold's Mine, calcite, talc, picrolite; at Gap Mine, magnetic pyrites (containing nickel), copper pyrites, actinolite; at Safe Harbor, iron ores; Pequea Valley, 8 m. S. of Lancaster, argentiferous galena (250 to 300 oz. of silver to the ton); 4 m. N. W. of Lancaster, on L. and H. Railroad, calamine, galena, blende, buratite. LITTLE BRITAIN.-Anthophyllite. LEBANON'CO.-CORNWALL, adjoining Lancaster Co.-Pyrites! in cubo-octahedrons, brilliant steel tarnish, magnetite, native copper, red copper, azurite, chrysocolla. LEHIGH CO.-Near Friedensville in the Saucon Valley, calamine (valuable mine), lanthanite, cryst. quartz, malachite, pyrolusite, wad; near Allentown, magnetic iron, pipe iron ore; near Bethlehem, in S. Mountain, allanite in syenite, zircon. MONROE CO.-In Cherry Valley, cale spar, chalcedony, cryst. quartz; in Poconoe Valley, near Judge Mervine's, cryst. quartz. MONTGOMERY CO.-At Perkiomen Copper Mine, azurite, blende, galena, pyromorphite, cerwsite, molybdate of lead, anglesite, heavy spar, calamine, copper pyrites, green malachite, chrysocolla; at Henderson's Marble Quarry, calc spar; about one mile N. of Henderson's, in the bank of railroad, cryst. quartz in geodes; at Spring Mills, cacoxene, lepidokrokite, sphthic iron: near the Gulf Mills, limonite, garnets, chromic iron; in Franconia Township, (? gold. NORTHUMBERLAND CO.-Opposite Selim's grove, calamine. NORTHAMPTON CO. —Near Easton, zircon! (exhausted), nephrite, serpentine in pseudomorphs, coccolite, tremolite, calamite, pyroxene, sahlite, limonite, magnetic iron, purple calc spar; near Bethlehem, at the South Mountain, on Mr. Weaver's farm, allanite, magnetite, epidote, zircon, sphene, brown garnet, black spinel and tourmaline in syenitic gneiss. PHILADELPHIA CO.-On the Schuylkill, near foot of inclined plane, garnet, tourmaline, mica; on the Schuylkill, a fourth of a mile from the Suspension Bridge, yellow uranite; one hundred yards above bridge, on east side, laumontite in hornt lende slate. AMERICAN LOCALITIES. 3~; CHESNUT HILL —Mica, serpentine, dolomite, asbestus, nephrite, tale, tourmaline, sphene, apatite, tremolite. GERMANTOWN.-Mica, apatite, feldspar, beryl, garnet. BANKS OF WISSAHICCON.-Actinolite garnet, staurotide. FRANKFORD.-Garnet, staurotide, iron pyrites. CoNCHIKOCEN.-Staurotide, garnet, argillaceous iron ore; near Manyunk Tunnell, stilbite, chabazite (rare in small brownish-yellow crystals). YORK CO.-Calc spar (transparent), cryst. smoky quartz, cryst pyrites; in Slate Quarries near the Susquehannah, wavellite. DELAWARE. NEWCASTLE CO.-Brandywine Springs, bucholzite, fibrolit& abundant, sahlite, pyroxene; near Middletown, vivianite in green sand. Dixon's Feldspar Quarries, 6 miles N. W. of Wilmington, (these quarries have been worked for the manufacture of porcelain), adularia, albite, beryl, apatite, cinnamon stone! (both granular, like that from Ceylon, and crystallized, rare), magnesite, serpentine, asbestus, black tourmaline (rare), indicolite! (rare), sphene in pyroxene, kyanite. Dupont's Powder Mills, " hyperstlene." Eastburn's Limestone Quarries, near the Pennsylvania line, tremolite, bronzite. QUARRYVILLE.-Garnet, spodumene, fibrolite, sillimanite. Near Newark on the railroad, sphmerosiderite on drusy quartz. jasper tferruginous opal), cryst. spathic iron in the cavities of cellular quartz. WILMINGTON.-In Christiana quarries, metalloidal diallage. Kennett turnpike, near Centreville, kyanite and garnet. KENT CO.-Near Middletown in Wm. Polk's marl pits, vivianit&! On Chesapeake and Delaware Canal, retinasphalt, iron pyrites, amber. SUSSEX CO.-Near Cape Henlopen, vivianite. MARYLAND. BALTIMORE, (Jones's Falls, 1I miles from B.)-Chabazite (haydenite), heulandite (beaumontite of Levy), pyrites, lenticular carbonate of iron, mica, stilbite. Sixteen miles from Baltimore, on the Gunpowder.-Graphite. Twenty-three miles from B., on the Gunpowder.-Talc. Twenty-five miles from B., on the Gunpowder.-Magnetic iron, sphene, pyenite. Thirty miles from B., in Montgomery Co., on farm of S. Eliot.Gold in quartz. Eight to twenty miles north of B., in limestone.- Tremolite, asgite, pyrites, brown and yellow tournraline. Fifteen miles north of B.-Sky-blue chalcedony in granular'ime ston a. 394 LOCALITIES OF MINERALS. Eighteen miles north of B., at Scott's Mills.-Magnetic iron kyanite. BARE HILLS. —Chromic iron, asbestus, tremolite, talc, hornblende, serpentine, chalcedony, meerschaum, baltimorite, copper pyrites, magnetite. CAPE SABLE, near Magothy R.-Amber, pyrites, alum slate. CARROLL Co. —Near Sykesville, Liberty Mines, gold, magnetic iron, pyrites (octahedrons), copper pyrites, linnaeite (carrollite), an ore of nickel (not analyzed); at Patapsco Mines, near Finksburg, erubescite, malachite, linnceite, reminqtonite, magnetic iron, copper pyrites; at Mineral Hill Mine, erubescite, copper pyrites, ore of nickel (sieginite), gold, magnetic iron. CECIL Co., north part.-Chromic iron in serpentine. COOPTOWN, Harford Co.-Olive colored tourmaline, diallage, tale of green, blue and rose colors, ligniform asbestus, chromic iron, serpentine. DEER CREEK. —agnetic iron! in chlorite slate. FREDERICK Co.-Old Liberty Mine, near Liberty Town, black copper, malachite, copper glance, specular iron; at Dollyhyde Mine, erubescite, copper pyrites, iron pyrites, argentiferous galena in dolomite. MONTGOMERY Co.-Oxyd of manganese. SOMERSET AND WORCESTER Cos., north part.-Bog iron ore, vivianite ST. MARY'S RIVER. —Gypsum! in clay. VIRGINIA AND DISTRICT OF COLUMBIA. ALBEMARLE Co., a little west of the Green Mts.-Steatite, graphite; galena. AMHERST Co., along the west base of Buffalo ridge.-Copper ores, etc. AUGUSTA Co.-At Wever's (or Weir's) cave, sixteen miles northeast of Staunton, and eighty-one miles northwest of Richmond, calc spar and stalactites. BUCKINGHAM Co. —Gold at Garnett and Moseley Mines, largely worked, also pyrites, pyrrhotine, calcite, garnet; at the Eldridge Mine (now London and Virginia Mines) near by, and the Buckingham Mines near Maysville, gold, auriferous pyrites, copper py rites, tennantite, heavy spar; kyanite, tourmaline, uctinolite. CHESTERFIELD Co.-Near this and Richmond Co., bituminous coal, native coke. CULPEPPER Co., on Rapidan river.-Gold, pyrites. FRANKLIN Co.-Grayish steatite. -FAUQUIER Co., Barnet's Mills.-Asbestus; gold mines, barytes, calcite. FLUVANNA Co.-Gold at Stockton's Mine also tetradymite at "Tellurium Mine." PHENIX Copper Mines.-Copper pyrites, etc GEORGETOWN, D. C.-Rutile. GOOCHLAND Co.-Gold Mines, (Moss and Busby's.) HARPER'S FERRY, on both sides' of the Potomac.-Thurlngite (owenite), with quartz. JEFFERSON Co., at Sheperdstown.-Fluor. AMERICAN LOCALIrIES. 395 KENAWHA Co.-At Kenawha, petroleum, brine springs, cannel coal. LOUDON Co.-Tabular quartz, prase, pyrites, talc, chlorite, soapstone, asbestus, chromic iron, actinolite, quartz crystals; micaceous iron, erubescite, malachite, epidote, near Leesburg, (Potomac, Mine.) LOUISA Co.-Walton gold mine, gold, pyrites, copper pyrites, argentiferous galena, spathic iron, blende, anglesite; boulangerite, blende (at Tinder's Mine). NELSON Co.-Galena, copper pyrites, malachite. ORANGE Co.-Western part, Blue Ridge, specular iron; gold at the Orange Grovet and Vaucluse gold mines, worked by the "Freehold" and "Liberty" Mining Companies. ROCKBRIDGE Co., three miles southwest of Lexington.-Heavy spar SHENANDOAH Co., near Woodstock. —Fluor spar. MT. ALTO, Blue Ridge.-Argillaceous iron ore. SPOTSYLVANIA Co., two miles northeast of Chancellorville. —Kyanite; Gold mines at the junction of the Rappahannock and Rapidan ("Gardiner" Co.): on the Rappahannock (Marshall Mine); Whitehall Mine, affording also tetradymite. STAFFORD CO., eight or ten miles from Falmouth.-Micaceous iron, gold, tetradymite, silver, galena, vivianite. WASHINGTON Co., eighteen miles from Abingdon. —Rock salt with gypsum. WYTHE Co., (Austin's mines).-Cerusite, minium, plumbic ochre, blende, calamine, galena. On the Potomac, twenty-five miles north of Washington City. — Native sulphur in gray compact limestone. NORTH CAROLINA. ASHE Co.-Malachite, copper pyrites. BUNCOMBE Co.-Corundum (from a boulder), margarite, corundophilite, garnet, chromic iron, barytes, fluor, rutile, iron ores, oxyd of manganese. BURKE Co.-Gold, monazite, zircon, beryl, corundum, garnet, sphene, graphite, iron ores. CABARRAS Co.-Phenix mine, gold, barytes, copper pyrites, auriferous pyrites, quartz pseudomorph after barytes, tetradymite; Pioneer Mines, gold, limonite, pyrolusite, barnhardite, wolfram, scheelite, tungstate of copper, wolframine, diamond, chrysocolla, copper glance, molybdenite, copper pyrites, iron pyrites; White Mine, needle ore, copper pyrites, barytes; Long and Muse's Mine, argentiferous galena, iron pyrites, copper pyrites, limonite; Boger Mine, tetradymite; Fink Mine, valuable copper ores; Mt. Makins, tetrahedrite magnetite, talc, blende, pyrites, gale.na; Geo. Luderick's farm, scorodite, limonite, gray copper, copper pyrites, iron pyrites. CALDWELL Co.-Chromic iron. CHATHAM Co.-Mineral coal, pyrites. CHEROKEE Co -Iron ores, gold, galena, corundum, rutile. DAVIDSON Co.-King's, now Washington Mine, native silver, ce rusite, anglesite, scheelite, pyromorphite, galena, blende, malachite black copper, wavellite, garnet, stilbite. Five miles from Wash ington Mine, on Faust's Farm, gold, tetradymite, oxyd of bismulth 396 LOCALITIES OF MINERALS. and tellurium, copper pyrites, limonite, spathic iron, epidote; neai Squire Ward's, gold in crystals, electrum. GASTON Co.-Iron vres, corundum, margarite. Near Crowder'k Mountain (in what was formerly Lincoln Co.), lazulite, kyanite, garnet, graphite; also twenty miles northeast, near south end of Clubb's Mountain, lazulite, kyanite, talc. GUILFORD Co.-McCullock copper and gold mine, twelve inile? from Greensboro', gold, pyrites, copper pyrites (worked for copper), quartz, spathic iron. The Worth Carolina Copper Co. are working the copper ore at the old Fentress mine. I ENDERSON Co.-Zircon. JACKSON Co.-Smoky Mountain, alunogen. LINCOLN Co. —Diamond; at Randleman's, amethyst I rose quartz. MACON Co.-Chromic iron. MCDOWELL Co.-Brookite, monazite, corundum in small crystals red and white, zircons, garnet, beryl, sphene, xenotire, rutile, elastic sandstone, iron ores. MECKLENBURG Co.-Near Charlotte (Rhea and Cathay Mines) and elsewhere, copper pyrites, gold; chalcotrichite at McGinn's Mine; barnhardite near Charlotte; pyrophyllite in Cotton Stone Mountain, diamond. - ROWAN Co.-Gold Hill Mines, thirty eight miles northeast of Charlotte, and fourteen from Salisbury, gold, auriferous pyrites; ten miles from Salisbury, feldspar in crystals. RUTHERFORD Co.- Gold, graphite, bismuthic gold, diamond, euclase, pseudomorphous quartz, chalcedony, corundum in small crystals, epidote, pyrope, brookite, zircon, monazite, rutherfordite, samarskite, quartz crystals, itacolumite; on the road to Ccoper's gap, kyanite. STOKES AND SURREY Cos.-Iron ores, graphite. UNION Co —Lemmond Gold Mine, eighteen miles from Concord, (at Stewart's and Moore's Mine), gold, quartz, blende, argentiferous galena (containing 29'4 oz. of gold, and 86-5 oz. silver to the ton, Genth), pyrites, some copper pyrites. YANCEY Co.-Iron ores, amianthus, chromic iron. SOUTH CAROLINA. ABBEVILiE DIST.-Oakland Grove, Gold (I)orn Mine), galena. pyro morphite, amethyst, garnet. ANDERSON DIST.-At Pendleton, actinolite, galena, kaolin, touw. maline. CHARLESTON.-Selenite. CHEOWEE VALLEY.-Galena, tourmaline, gold. CHESTERFIELD DIST.-Gold (Brewer's mine), talc, chlorite, pyrophyllite, pyrites, native bismuth, carbonate f bismuth, red and yellow ochre, whetstone. DARLINGTON. -Kaolin. EDGEFIELD DIST.-Psilomelane. GREENVILE DIST.-Galena, phosphate of lead, kaolin, chalcedony in burhstone, beryl, plumbago, epidote, tourmaline. KERSHAW DIST.-Rutile. * LANCASTER DIsT.-Gold (Hale's mine), talc, chlorite, kyanite, elastle AMERICAN LOCALITIES. 39? sandstone, pyrites; gold also at Blackman's mine, Massey's mine, Ezell's mine. NEWBERRY DIST.-Leadhillite (I). PICKEN'S DIST.-Gold, manganese ores, kaolin. RICHLAND DIST.-Chiastolite, novaculite. SPARTANBURG DIST. —Magnetic iron ore, chalcedony, hematite; at the Cowpeiis, brown henmatite, graphite, limestone copperas. SUMTER DIST. — Agate. UNION D:ST. —Fairforest gold mines, pyrites, copper pyrites. YORK DIST.- -Limestones, whetstones, witherite, heavy spar. GEORGIA. BURKE AND SCRIVEN Cos.-Hyalite. CLARK Co., near Clarksville.-Gold, xenotime, zircon, rutile, kya nite, specular iron, garnet, quartz. HABERSIIAM Co.-Gold, iron and copper pyrites, galena, horn. blende, garnet, quartz, kaolin, soapstone, chlorite, rutile, iron ores, galena, tourmaline, staurotide, zircon. HALL Co. —Gold, quartz, kaolin, diamond. HANCOCK Co.-Agate, chalcedony. IHEARD Co.-Molybdote of iron. LUMPKIN Co.-Gold, quartz crystals. RABUN Co.-Gold, copper pyrites. WASHINGTON CO., near Saundersville.- Wavellite, fire opal. CANTON Mine.-Harrisite, copper pyrites, melaconite, galena, pyromorphite, pyrites, marcasite, erubescite, blende, native copper, automolite, staurotide, kyanite, ilmenite, Hitchcockite, covelline. ALABAMA. BIBB Co., CENTREVILLE. —Iron ores, marble, heavy spar, coal, cobalt. TUSCALOOSA Co. —Coal, galena, pyrites, vivianite, limonite, calcite, dolomite, kyanite, steatite, quartz crystals, manganese ores. FLORIDA. NEAR TAMPA BAY.-Limestone, sulphur springs, chalcedony, car. nelian, agate, silicified shells and corals. KENTUCKY. MAMMOTH CAvE. —Gypsum, in imitative forms, stalactites, nitre, epsom salt. Near the line between Livingston and Union Cos., galena, coppel pyrites. TENNESSEE. BRowN's CREEE.-Galena, blende, heavy spar, celestine. CARTER'S Co., foot of Roan Mt.-Sahlite, magnetic iron. CLAIBORNE Co.-Calamine, galena, smithsonite, chlorite steatite and magnetic iron. 3Z4 398 LOCALITIES OF MINERALS. COCKE Co., near Brush Creek.-Cacoxene, kraurite, iron siLter, stilpnosiderite, brown hematite. DAVIDSON Co.-Selenite, with granular and snowy gypsum, or alabaster, crystallized and compact anhydrite, fluor in crystals t calc spar in crystals. Near Nashville, blue celestine (crystallized, fibrous and radiated), with heavy spar in limestone. Haysboro', galena, blende, with heavy spar as the gangue of the ore. DICKsoN Co.-Manganite. JEFFERSON Co.-Calamine, galena, fetid heavy spar. KNOX Co.-Magnesian limestone. MAURY Co.-Wavellite in limestone. MORGAN Co.-Epsom salt, nitrate of lime. POLK Co., Hiwassee mine, southeast corner of state, near Ocoee river. Black copper copper pyrites, iron pyrites (mines valuable), allophane. ROAN Co., eastern declivity of Cumberland Mts.-Wavellite in limestone. SEVERN CO., in caverns.-Epsom salt, soda alum, saltpetre, nitrate of lime. SMITH Co.-Fluor. SMOKY MT., on declivity.-Hornblende, garnet, staurotide UNAKA MTS., Eastern Tennessee, at Sevier, etc., in caverns.-Alum. OHIO. BRAINBRIDGE, (Copperas Mt., a few miles east of B.)-Calc spar, heavy spar, iron pyrites, copperas, alum. CANFIEID.-Gypsum! DUCK CREEK, Monroe Co.-Petroleum. LIVERPOOL.-Petroleum. MARIETrA.-Argillaceous iron ore; iron ore abundant also in Sciotc and Lawrence Counties. POLAND.-Gypsum I MICHIGAN. LAKE SUPERIOR MINING REGION.-The four principal regions are Keweenaw Point, Isle Royale, the Ontonagon, and Portage Lake. The mines of Keweenaw Point are along two ranges of elevation, one known as the Greenstone Range and the other as the Southern or Bohemian Range, (Whitney.) The copper occurs in the trap or amygdaloid, and in the associated conglomerate. Native copper! native silver I copper pyrites, horn silver, gray copper, manganese ores, epidote, prehnite, laumontite, datholite, heulandite, stilbite, analcime, chabazite, mesotype, (Copper Falls mine), leonhardite, (ib.), analcime, (ib.), apophyllite, (at Cliff Mine), wollastonite, (ib.), cale spar, quartz (in crystals, at Minesota mine), saponite, black oxyd of copper, (near Copper Harbor, but exhausted), chrysocolla; on Cho. colate river, galena and sulphuret of copper; copper pyrites and native copper at Presq' Isle. At Albion mine, domeykite; at Prince Vein, amethyst; at Michipicoten Ids., copper nickel, stilbite, anaeime. AMERICAN LOCALITIES 399 ISLE ROYALE, 48~ N., 89~ W. —Nstive copper, epidote, harmotome e() datholite, wollastonite (exhausted,, pectolite, chlorastrolite. ILLINOIS. GALLATIN Co., on a branch of Grand Pierre Creek, sixteen to thirty miles from Shawneetown, down the Ohio, and from half to eight miles fiom this river.- Violet fluor spar! in carboniferous lilncstone, heavy spar, galena, blende, brown iron ore; near Rosiclare, calcite, galena, blende; five miles back from Elizabethtown, bog iron; one mile north of the river, between Elizabethtown and lHo siclare, nitre. In NORTHERN ILLINOIS, townships 27, 28, 29, several im portant mines of galena. POPE Co.-Pyromorphite. INDIANA. LIMESTONE CAVERNS; Corydon Caves, &c.-Epsom salt. In most of the southwest counties, pyrites, sulphate of iron, and feather alum; on Slgar Creek, pyrites and sulphate of iron; in sandstone of Lloyd Co., near the Ohio, gypsum; at the top of the blue limestone formation, brown spar, caic spar. MINESOTA. NORTH SHORE OF LAKE SUPERIOR, (range of hills running nearly northeast and southwest, extending from Fond du Lac Superieure to the Kamanistiqueia river in Upper Canada.)-Scolecite, apophyllite, prehnite, stilbite, laumontite, heulandite, harmotome, thomsonite, Jfuor spar, sulphate of baryta, tourmaline, epidote, hornblende, calcareous spar, quartz crystals, iron pyrites, magnetic iron ore, steatite, blende, black oxyd of copper, malachite, native copper, copper pyrites, amethystine quartz, ferruginous quartz, chalcedony, carnelian, agate, drusy quartz, hyalite? fibrous quartz, jasper, prase (in the debris of the lake shore), dogtooth spar, augite, native silver, spodumene I arsenite I of cobalt, chlorite; between Pigeon Point and Fond du Lac, near Baptism river, saponite (thalite), in amygdaloid. KETTLE RIVER TRAP RANGE.-Epidote, nail-head calc spar, ame thystine quartz, calcareous spar, undetermined zeolites, saponite. STILLWATER. Blende. FALLS OF THE ST. CRoIX.-Green carbonate of copper, native copper, epidote, nail-head spar. RAINY LAKE.-Actinolite, tremolite, fibrous hornblende garnet, iron pyrites, magnetic iron, steatite. WISCONSIN. At MINERAL POINT and elsewhere, coppel and lead ores, principally silicate and carbonate of copper, copper pyrites and galena, (only the last abundant.) Also pyrites, capillary pyrites, blende, white lead ore, leadhillite (i), smithsonite (carbonate f zinc), angle site, heavy spar, and cale spar. 400 LOCALITIES OF MINERALS. SANK Co.-Specuiar iron I malachite, copper pyrites. MONTREAL RIVER PORTAGE —Galena in gneissoid granite LAC DU FLAMBEAU R.-Garnet, kyanite. BIG BULL FALLS, (near.)-Bog iron. LEFT HAND R., (near small tributary.)-Malacl ite, copper glance, native copper, red copper ore, earthy malachite epidote, chlorite i quartz crystals. IOWA. Du BUQUE LEAD MINES, and elsewhere.-Galena! cale spar, black oxyd of manganese; at Ewing's and Sherard's diggings, calamine! or smithsonite; at Des Moines, quartz crystals, selenite; Mahoqueta R., brown iron ore. CEDAR RIVER, a branch of the Des Moines.-Selenite in crystals, in the bituminous shale of the coal measures; also elsewhere on the Des Moines, gypsum abundant; argillaceous iron ore, spathic iron, copperas in crystals on the Des Moines, above the mouth of Saap and elsewhere, iron pyrites, blende. MISSOURI. BIRMINGHAM.-Limonite. JEFFERSON Co., at Valle's Diggings.-Galena, whtte lead ore, anglesite, calamine, pyritous copper, blue and green malachite, carbonate of baryta. MINE A BuRTON.-Galena, white lead ore, anglesite, heavy spar, calc spar. DEEP DIGGINGS.-Carbonate of copper, white lead ore in crystals, and manganese ore. MINE LA MOTTE.-Galena! malachite, earthy cobalt and nickel, bog manganese, sulphuret of iron and nickel, white lead ore in crystals, caledonite, plumboresinite, wolfram. PERRY'S DIGGINGS, and elsewhere.-Galena, &c. Forty miles west of the Mississippi and ninety south of St. Louis, the iron mountains, specular ilron, limonite. ARKANSAS. BATESVILLE.-In bed of white R., some miles above Batesville, Gold. OUACHITA SPRINGS.-Quartz I whetstones. MAGNET CovE.-Brookite! schorlomite, elceolite, magnetic iron, quartz, green coccolite, garnet, apatite. CALIFORNIA. Along the Sierra Nevada, gold, platinum (rare), iridosmine, molybdenite, molybdine, zircon, magnetic iron; near bay of San Francisco, actinolite, talc, serpentine, jasper, salt, gypsum (island in the Caquines Straits); ridges of Sierra Azul, south of San Jose. cinnabar. Gold also found in the Umpqua region, Oregon and the.hasty Mountains. Pt. Orford, gold, platinum, iridosmine. AMERICAN LOCALITIES. 401 CANADA CANADA EAST. ABERCROMBIE.-Labradorite. AUBERT, Gallion.-Gold, iridosmi, e, platinum. BAY ST. PAUL.-Ilmenite I apatite, allanite, rutile, (cr brookitel) BOLTON.-Chromic iron, magnesite, serpentine, picrolite, steatite. bitter spar, wad. BOUCHERVILLE MOUNTAIN.-Augite in trap. BRoME. — Magnetic iron, copper pyrites, sphene, ilmenite, phy llit, sodalite, cancrinite, galena. CHAMBLY.-Analcime, chabazite and calcite in trachite. CHATEAU RICHER.-Labradorite, ilmenite, hypersthene. DAILLEBOUT.-Blue spinel, with clintonite. GRENVILLE.-lTbular spar, sphene, idocrase, calcite, pyroxene, garnet (cinnamon stone), zircon, graphite, scapolite. HAM.-Chromic iron in serpentine. INVERNESS.- Variegated copper. LAKE ST. FRANCIS.-Andalusite in mica slate. LANDSDOWNE.-Barytes. MILLE ISLEs.-Labradorite! ilmenite, hypersthene, andesine, zircon. MONTREAL.-Calcite, augite, sphene in trap MoRIN.-Sphene, apatite, labradorite. POLTON.-Chromic iron, steatite, serpentine, amianthus. ROUGEMONT MTs.-Augite in trap. ST. ARMAND.-Micaceous iron ore with quartz, epidote. ST. FRANgOIS BEAUCE. —Gold, platinum, iridosmine, ilmenite, magnetite, serpentine, chromic iron, soapstone, magnetite, heavy spar. ST. JEROME.-Sphene, apatite, chondrodite, phlogopite, tourmaline, zircon, molybdenite, magnetic pyrites. ST. NoRBERT.-Apatite in greenstone. ST. RocH.-On the Achigan, two miles below St. Roch, apatite in trappean rocks. STUKELY.-Serpentine, verde antique! schiller spar. SUTToN.-Magnetic iron in fine crystals, specular iron, rutile, dolomite, magnesite, chromiferous talc, bitter spar, steatite. UPTON.-Copper pyrites, malachite, calcite. VAUDREUIL.-Limonite, vivianite. YAMAsKA.-Sphene in trap. CANADA WEST. BALSAM LAKE.-Mfolybdenite, scapolite, quartz. BRANTFoRD.-Sulphuric acid spring, (4'2 parts of pure sulphuric jcid in 1000). BATHURST.-Heavy spar, black tourmaline, perthite (orthoclase), peristerite (albite), bytownite. BROME. — Magnetite. BURGESS.-Pyroxene, albite, mica, sapphire, sphene, copper pyrites apatite, black spinel! spodumene (in a boulder). 34* 402 LOCALITIES OF MINERALS. BYTOWN.-Calcite, bytownite, chondrodite, spinel. CAPE IPPERWASH, Lake Huron.-Oxalite in shales. CLARENDON.-Idocrase. DALIOUSIE.-Hornblende, dolomite. DRVMMOND.-Labradorite. ELMSLEY.-Pyroxene, sphene, feldspar, tourmaline. FITZROY.-Amber, brown tourmaline, in quartz. G(ETINEAU RIVER, Blasdell's Mills.-Calcite, apatite, tourmaline, ornblende, pyroxene. GRAND CALUMET ISLAND.-Apatite, phlogopite! pyroxene I sphene. idocrase I! serpentine, tremolite, scapolce, brown and black tour. nmaine I pyrites, loganite. HIGH FALLS OF THE MADAWASKA.-Pyroxene! hornblende. HULL.-Magnetite, garnet, graphite. HUNTERSTOWN.-Scapolite, sphene, idocrase, garnet, brown tout maline I INNISKILLEN.-Petroleum. LAC DES CHATS, Island Portage. —Brown tourmaline! pyrites, calcite, quartz. LANARK.-Raphilite (hornblende), serpentine, asbestus. LANDSDOWN.-Barytes I vein 27 in. wide, and fine crystals. MADOC.-Magnetite. MARMoRA.-Magnetite, chalcolite, garnet, epsomite, specular iron. McNAB.-Specular iron. SOUTH CRoSBY.-Chondrodite in limestone, magnetite ST. ADELE.-Chondrodite in limestone. SYDENHAM. —Celestine. TERRACE COVE, Lake Superior.-Molybdenite. WALLACE MINE, Lake Huron.-Specular iron, arsenical nickel, sulphuret of nickel, nickel vitriol BRUCE MINES.-Copper pyrites, copper glance, erubescite. NEW BRUNSWICK, St. John.-Graphite. NoTE.-The rock of the Mississippi valley containing the remarkable deposits of galena, (sometimes regarded as the equivalent of the "Cliff" or'Upper Mag. nesian " Limestone,) is considered by James Hall as between the Hudson River and Trenton Groups of New York in age, and as having no representative in the eastern part of the United States. The sandstones and conglomerates of the Lake Superior copper region in Michigan are referred by Foster and Whitney, Hall, Owen and Logan. to the age of the Potsdam sandstone, or the lowest Silurian; while the copper bearing red sandstone of Connecticut and New Jersey, is s)vwn Vy Re^field, Rogers and Hall, to be as recent as the Liasaic Period. FOREIGN MINING Ik''N. 40O BRIEF NOTICE OF FOREIGN MINING REGIONS. The geographical positions of the different mining regions are learned with difficulty from the scattered notices in the course of a mineralogical treatise. A general review of the more important is therefore here given, to be used in connection with a good map. A course across Europe from southeast to northwest, passes over a large part of the mining regions, and it will be found most convenient to the memory to mention Ihem in this or. der, commencing with the borders of Turkey. 1. The mines of the Bannat in southern Hungary, near the borders of Turkey, (about latitude 45 ) situated principally at Orawitza, Saszka, Dognaszka, and Moldawa. Ores. Argentiferous copper ores, vitreous copper, malachite, copper pyrites, red copper ore, galena, ores of zinc, cobalt, native gold, yielding silver, gold, copper, and lead. Rock. Syenite and granular limestone. 2. The mines of western Transylvania, about latitude 46, situated between the rivers Maros and Aranyos, at Nagyag, Offenbanya, Salathna, and V0orspatak. Ores. Na. tive gold, telluric gold, telluric silver, white tellurium, with galena, blende, orpiment, realgar, gray antimony, fahlerz, carbonate of manganese, manganblende; especially valuable in gold and silver. 3. In the mountain range, bounding Transylvania on the north, about latitude 47~ 40, at Nagy-banya, Felso-ban ya, and Kapnik. Ores. Native gold, red silver, argentife. rous gray copper, pyritous copper, blende, realgar, gray antimony. Rock. Porphyry. 4. In the Konigsberg mountains, northern Hungary, about latitude 48 45, at Schemnitz and Kremnitz. Ores. Argentiferous galena and copper pyrites, native gold, red silver ore, gray antimony, some cobalt ores and bismuth, mispickel; particularly valuable for gold, silver, and antimony. Rock. Diorite and porphyry. 5. To the east of the Konigsberg mountains, at Schmol-.itz and Retzbanya. Ores. Pyritous copper, gray copper re, blende, gray antimony, particularly valuable for copper. Rock. Clay slate. 6. Illyria, west of Hungary, at Bleiberg and Raibel, (in'arinthia.) Ores. Argentiferous galena, calamine, with 404 FOREIGiN MINING REGIONS. some copper pyrites and other ores, affording silver and zinc abundantly. Rock. Mountain limestone.-Also at Idria, native mercury and cinnabar, in argillaceous schist. 7. In Western Styria, at Schladming. Ores. Arsenical nickel, copper nickel, native arsenic, arsenical iron, largely worked for nickel. Rock. Argillaceous slate. Illyria and Styria are noted also for their iron ores, especially spathic iron. 8. In the Tyrol, at Zell. Ores. Argentiferous copper and iron ores, auriferous pyrites, native gold. Rock. Ar. gillaceous slate. 9. In the Erzgebirge separating Bohemia from Saxony, and consisting principally of gneiss. A. Bohemian or southern slope, at Joachimstahl, Mies, Schlackenwald, Zinnwald, Bleistadt, Przibram, Katherinen. berg. Ores. Tin ores, argentiferous galena, (worked prin. cipally for silver,) arsenical cobalt ores, copper nickel, af. fording tin, silver, cobalt, nickel, and arsenic. B. Saxon or northern slope, at Altenberg, Geyer, Marien.'berg, Annaberg, Schneeberg, Ehrenfiiedersdorf, Johann. georgenstadt, Freiberg. Ores. Argentiferous galena, (worked only for silver,) tin ore, various cobalt and nickel ores, vi. treous and pyritous copper, affording silver, tin, cobalt, nickel bismuth, and copper. 10. In Silesia, in the Riesen-gebirge, an eastern extension of the Erz-gebirge, at Kupferberg, Jauer, Reichenstein. Ores of copper, cobalt, affording copper, cobalt, arsenic and sulphur. 11. In Silesia, in the low country east of the Riesen-ge. birge, near the boundary of Poland, at'Tarnowitz. Ores. Calamine, electric calamine, blende, argentifelous galena, affording zinc, silver and lead. Rock. Mountain limestone. 12. Northwest of Saxony, near latitude 51 30', at Eisle. ben, Gerlstadt, Sangerhausen, and Mansfeld. Ores. Gray copper, somewhat argentiferous, variegated copper ore, af. fording copper. Rock. A marly bituminous schist (kupfer. schiefer) more recent than the coal strata. 13. In the Harz-gebirge, (Hartz mountains,) north of west from Eisleben, about latitude 51~ 50', at Clausthal, Zeller. feld, Lauthenthal, Wildemann, Grund, Andreasberg, Goslar, Lauterberg. Ores. Vitreous copper, gray copper, pyritous copper, cobalt ores, copper nickel, ruby silver ore, argentif. erous galena, blende, antirnory ores, affording silver lead. copper, and some gold. FOREIGN MINING REGIONS. 405 14. In Hesse-Cassel to the southwest of the Hartz, at Riechelsdorf. Ores. Arsenical cobalt, arsenical nickel, nickel ocher, native bismuth, bismuth glance, galena, af. fording cobalt. Rock. Red sandstone. Also at Bieber, cobalt ores in mica slate. 15. In the Bavarian or Upper Rhine, (Palatinate,) near latitude 49' 45', at Landsberg near Moschel, Wolfstein, and Morsfeld. Ores. Cinnabar, native mercury, amalgam, horn quicksilver, pyrites, brown iron ore, some gray copper ore, and copper pyrites. Rocks. Coal formation. 16. Province of the Lower Rhine, at Altenberg, near Aix la Chapelle (or Aachen.) Ores. Calamine, electric calamine, galena, affording zinc. Rock. Limestone. The same, just south in Netherlands, at Limburg, and also to the west at Vedrin, near Namur. 17. There are also copper mines at Saalfeld, west of Sax. ony, in Saxon-Meiningen, in Southern Westphalia near Siegen, in Nassau at Dillenberg, and elsewhere. 18. In Switzerland, Canton du Valais. Ores. Argentiferous lead, and valuable nickel and cobalt ores. 19. The range of the Vosges, in France, parallel with che Rhine, about St. Marie-aux-Mines. Ores. Argentiferous galena, (affording 1-1000 of silver,) with phosphate of lead, gray copper, antimonial sulphuret of silver, native silver, arsenical cobalt, native arsenic, and pyrites, occasion. ally auriferous; affording silver and lead. Rocks. Argil. laceous schist, syenite, and porphyry. 20. In France there are also the mining districts of the Alps, Auvergne or'the Plateau of Central France, Brittany, and the Pyrenees, but none are very productive, except in iron ores. Brittany resembles Cornwall, and for. merly yielded some tin and copper. The valley of Oisans in the Alps, at Allemont, contains argentiferous galena, arsenical cobalt and nickel, gray copper, native mercury, and other ores, in talcose, micaceous, and syenitic schists, but they are not now explored. The region of Central France is worked at this time only at Pont-Gibaud, in the department of Puy-de-Dome, and at Vialas and Villefort in the Gard. The former is a region of schistose and granite rocks, inter. sected by porphyry, affording some copper, antimony, lead, and silver; the latter of gneiss, affording lead and silver from igentiferous galena. The French Pyrenees are worked at he present time only for iron. 4')6 FOREIGN MINING REGIONS. 21. In England there are two great metalliferous dls. tricts. A. On the southwest, in Cornwall, and the adjoining county of Devonshire. Ores. Pyritous copper and various other copper ores, tin ore, galena, with some bismuth, co. bait, nickel, and antimony ores, affording principally copper in, and lead. Rocks. Granite, gneiss, micaceous and ar gillaceous schist. - B. On the North, in Cumberland, the adjoining parts'i Durham, with Yorkshire and Derbyshire, just south. Ores Galena, and other lead ores, blende, copper ores, calamine (the last especially at Alstonmoor in Cumberland, anl Castleton and Matlock, in Derbyshire,) affording largely of zinc, and three-fifths of the lead of Great Britain, and some copper. Rock. Carboniferous limestone. C. There is also a rich vein of calamine, blende, and galena, in the same limestone at Holywell, in Flintshire, on the north of Wales; another of calamine at Mendip Hills, in Southern England, south of the Bristol channell in Sor-. ersetshire, occurring in magnesian limestone; mines of copper on the isle of Anglesey, in North Wales, in Westmoreland and the adjacent parts of Cunberland and Lancashire, in the southwest of Scotland, the Isle of Man, and at Ecton in Staffordshire, &c. 22. In Spain, there are minesA. On the south, in the mountains near the Mediterranean coast, in New Grenada, and east to Carthagena, in Murcia; situated in New Grenada, in the Sierra Nevada, or the moun. tains of Alpujarras, the Sierra Almagrera, the Sierra de Gador, just back of Almeria, and at Almazarron near Carthagena. Ore. Galena, which is argentiferous at the Sierra Almagrera, and at Almazarron, affording full 1 per cent. of silver. Rock. Limestone, associated with schist and crystalline rocks. B. The vicinity of the range of mountains running west. ward from Alcaraz, (in the district of La Mancha.) to Por. tugal. 1. On the south, near the center of the district of Jaen, at Linares, latitude 38' 5', longitude 3' 40. Ores. Galena, carbonate of lead, red copper ore, malachite, in granite and schists; affording lead and copper. 2. In La Mancha, at Alcaraz, northeast of Linares, latitude 38~ 45' Ores. Calamine affording abundantly zinc. 3. In the west extremity of La Mancha, near latitude 38~ 38 ai FOREIGN MINING REGIONS. 4ot Alniaden. Ores. Cinnabar, native mercury, born quicksil. ver, pyrites, in clay slate. 4. Southwest of Almaden, in Southern Estremadura, and Northwestern Sevilla, at Guadalcanal, Cazalla, Rio Tinto. Ores. Gray copper, copper vitriol, malachite, with some red silver ore, and native silver, in ancient schists or limestones. There are also mines of lead and copper at Falsete in Catalonia; in Galicia, a little tin ore; in the Asturias at Cabrales, copper ores. 23. 1 k Sweden:-1. At Fahlun, in Dalecarlia. Ores Copper pyrites, variegated copper. Rock. Syenite and schists.-At Finbo and Broddbo. Ores. Columbium ores, tin ore. —At Sala. Ore. Argentiferous galena, affbrding lead and silver. Rock. Crystalline limestone.-At Vena, (or Wehna,) and at Tunaberg. Ores. Arsenical cobalt, arsenate of cobalt. Rock. Mica slate and gneiss.-At Dan. nemora and elsewhere. Ore. Magnetic iron. 24. In Norway, at Kongsberg, vitreous silver, native sil. ver, horn silver, native gold, galena, native arsenic, blende. Rock. Mica slate.-At Modum and Skutterud. Ores. Co. balt ores, native silver. Rock. Mica slate.-At Arendal, magnetic iron. 25. In Russia: —. In the Urals, (mostly on the Asiatic side,) at Ekatherinenberg, Beresof, Nischne Tagilsk, &c. Ores. Native gold, platinum, iridium, native copper, red oxyd of coppe, malachite. 2. The Altai, (southern Siberia,) at Kolyvan and Zmeof. Ores. Native gold, native silver, argentiferous galena, carbonate of lead, native copper, oxyds of copper, malachite, pyritous copper, calamine. Rocks. Metamorphic beds, and porphyry. 3. In the Daouria moun. tains, east of Lake Baikal, at Nertchinsk. Ores. Argentiferous galena, carbonate of lead, arsenate of lead, gray an. timony, arsenical iron, electric calamine, cinnabar. Rocks. Ancient compact limestone and schists. Other important foreign mines, are the copper mines of Cuba, South America, Southern Australia; the silver mines of South America and Mexico; the gold mines of South America, Africa, and the East Indies; the quicksilver mines of Huanca Velica, Peru, and those of China; the tin of Malacca, (principally on the island of Junck Ceylon,) of Banca; of zinc, in China; of platinum, in Brazil, Colun bia, St. Domingo, and Borneo; of palladium, in Brazil; of 4 )H MINERALOGICAL INSTRUMENTS. arsenic in Khoordistan, China. Copper mines are also re. ported from New Zealand.' N ERRALOGICAL IMPLEMENTS. For tht exxinilnation and collection of minerals, the min eralogist should be provided with a few simple implements. 1. A three-cornered or small flat file, for testing hardness. 2. A knili with a pointed blade, of good steel, for trying hardness. Berzelius suggests that it may be magnetized, to be used as a magnet. 3. The series of crystallized minerals, constituting the scale of hardness (see page 64.) The diamond and talc are least essential. 4. Small glass-stoppered bottles (one-ounce) of each of the acids muriatic, sulphuric, and nitric, in a dilute state, (page 66.) 5. A blowpipe, (page 67.) 6. The common fluxes, (page 69.) 7. Pieces of charcoal for blowpipe purposes, (page 69.) Also strips of mica for holding the assay when platinum is not at hand. 8. A candle or lamp for blowpipe trials, (page 68.) 9. Platinum foil, wire, and forceps, (page 69.) 10. Also a pair of small steel spring forceps, for holding fragments of minerals in the blowpipe flame, and for man. aging the assay. 11. A piece of glass tube, j inch bore; and two or three test tubes (of hard glass,) or small mattresses, for trying the action of acids, and testing the presence of water by the blowpipe. 12. A pair of cutting pliers, for removing chips of a min. eral for blowpipe or chemical assay. 13. A common goniometer; or a pair of arms pivoted to. gether to use with a scale, as explained on pages 47, 48. The reflecting goniometer(page 50) is also a desirable instrument. 14. Models of the common crystalline forms; they may be made by the student, out of chalk, or wood; and when finished, a coat of varnish or gum will give great hardness o the chalk. 15. A pair of balances for specific gravity, (page 63.) 16. A hammer weighing about two pounds, resembling a MINERALOGICAL IM1PLEMENTS. 409 stone cutter's hammer, having a slightly rounded face, and at the opposite end, an edge hav-I ing the same direction as the handle. The handle should be made of the best hickory, and the mortice to receive it should be as large as the handle. A similar hammer, having the upper part prolonged to a blunt point, to be used like a pick. 17. Another hammer of half a pound weight, similar to the preceding, except that the face should be flat; to be used in trimming specimens. 18. A small jeweller's hammer, for trying the malleability of globules obtained by the blowpipe, and for other pur. poses. 19. A piece of steel, say ~ inch thick, 1 or 2 wide, and 2 or 3 long, to be used as an anvil. A fragment may be broken or pulverized upon it, by first folding it in a piece of thin paper, to prevent its flying off when struck. A half inch circular cavity on one side, and a pestle to correspond, will be found very convenient. 20. Two steel chisels of the form of a wedge, as in the annexed figure; one 6 inches long, and the other 3. When it is desired to pry open seams in rocks with the larger chisel, two pieces of steel plate should be provided to place on opposite sides of the'hisel, after an opening is obtained; this protects the chisel and diminishes friction while driving it. \ 21. Bone ashes, to be used upon mica, or in a small cavity in charcoal, in cupelling for silver, with the blowpipe. A rounded cavity should be made in the charcoal, as large as the end of the little finger, and the bone ashes (slightly moistened, and mixed with a little soda,) should be pressed into it firmly with the head of a small pestle, after tho roughly drying, it is in a condition to receive the assay. 22. A pocket microscope. 23. A small agate mortar and pestle. 24. A magnetic needle. 25. A pair of scissors. 26. A box of matches. For blasting and other heavy work, the following tools and appliances are necessary:1. Three hand-drills, 18, 24, and 36 inches long, an inch in diameter. The best form is a square b':r of steel, with a diagonal edge at one end. The three are designed to fol..ow one another. 110 WEIGHTS, MEASURES, AND COINS. 2. A sledge hammer of 6 or 8 pounds weight, to use in driving the drill. 3. A sledge hammer of 10 or 12 pounds weight, for break. ing up the blasted rock. 4. A round iron spoon, at the end of a wire 15 or 18 inches long, for removing the pulverized rock from the drill. hole. 5. A crowbar, a pickaxe, and a hoe, for removing stone and earth before or after blasting. 6. Cartridges of blasting powder, to use in wet holes. They should one-third fill the drill-hole. After the charge is put in, the hole should be filled with sand and gravel alone without ramming. If any ramming material is used plaster of Paris is the best, which has been wet and after. wards scraped to a powder. 7. Patent fuse for slow match, to be inserted in the car tridge, and to lead out of the drill-hole. WEIGHTS, MEASURES, AND COINS. For the convenience of the student, the following infor. mation is here inserted, of such weights, measures, and coins, of different countries, as are likely to be met with in the course of his ordinary reading on minerals and mining. 24 grains, Troy, = 1 pennyweight (dwt.) 20 dwt. " = 1 ounce (oz.) 12 oz. " = 1 pound (lb.) 16 drams Avoirdupois, = 1 oz. 16 oz. " = 1 pound. 112 lbs. " = 1 hundred (cwt.) 20 cwt. " = 1 ton. 1 lb. troy = 5760 grs. troy = 13 oz. 2-65143 drams av. 1 lb. av. = 7000 grs. troy =1 lb. 2 oz. 1 dwt. 16 gr. troy. To reduce pounds troy, to pounds avoirdupois, multiply by the decimal.822857; or, approximately, diminish by 3-17. To reduce pounds avoirdupois, to pounds troy multiply by 1-215. 100 lbs. av. is now the usual 1 cwt., and 25 lbs. the quar ter cwt. 112 pounds, formerly = 1 quintal. 100 pounds, now usually = 1 quintal. 1 French gramme = 15-433159 grs. troy. WEIGHTS, MEASURES, AND COINS. 411 I French kilogramme = 1000 grammes = 2*21 lbs. av. nearly = 2-68 lbs. trov = 2'0429 French livres. To reduce Approximately Fr. kilograms to Eng. av. pounds, mult. by 2'2055 or add 6-5. Prussian, (including Hanoverian, Brunswick, and Hessian,) pounds, to Eng. avoir. pounds, " " 1031114 " " 1-32. Fr.livre,(poids de marc) to Eng. av. lbs." " 1-079642 " " 2-25. 5ng av. lb. to French kilogram, " " 0453414 "sb. 11-20 Eng. av. lb. to French livre, " " 0-9262 " " 1-13 Eng. cwt. (112 Ibs.) to a metric quintal, (= 100 kilog. French,) " " 0-5078 Eng. cwt. to a Prus. centner, (==101bs.) " " 0-9875 " " 1-80 Eng. cwt to a quintal, (old measure= 100 livres,) " 1 1-0385 "add 2-53 A metric quintal to an English cwt. " " 1-971 A quintal, old meas. to an Eng. cwt. " " 0-963 "sub.1-27. A Prussian centner to an Eng. cwt. " " 1.0127 "add 1-80. The old French livre contained 2 marcs, or 16 ounces; a marc = 3778 Eng. grs. A marc at Cologne, (Hamburgh, etc.,) = 8 oz. = 3608 Eng. grs. The Russian pood (or pad) = 40 Russian pounds = 36 English pounds avoirdupois. 12 inches English, 1 foot. 3 feet, 1 yard. 40 rods, 1 furlong. 8 furlongs, 1 mile. 3 miles, 1 league. 6 feet, 1 fathom. 60 geographical miles, 1 degree. 69j statute miles (nearly,) 1 degree. A French meter=3 feet, 3-371 inches English, or more correctly, 39-37079 inches English=3 feet, 0 inches, 11*296 line Frleich. A ^tiliu,.v. =3z80'9 English teet, or -4-gths,t a -tatite mile. A French toise=63946 English feet=6 old French feet. English. French. Prussian, Danish and Rhenish Foot: -= 9382928 = -9711361.'To raJuce Approximately French feet to English, multiply by 1-065765 or add 1-15 English feet to French, " " 09382928 or subt. 1-16 French meters to English feet, " " 3-280899 or add 23-7 French meters to English yards, " " 1-093633 or add 1-11 English feet to French meters, " " 03047945 or subt. 7-10 The French foot according to an act in 1812, is a ~ of A.j 41'2 WEIGHTS, MEASURES, AND COINS. meter, but this measure has not been adopted, the old Fiench foot, (==1066 English feet) continuing to be used. A. German geographical mile=4 English geographical miles, or about 4'633 Eng. statute miles - 7407*40 meters, French stere, (cubic measure) = 35'34384 cubic ft. U. S. French litre (liquid and dry measure,) = 61'07416 cubic inches, or 1'05756 quarts wine measure. Value of different weights, in English avoirdupois pounds, of measures in English feet and inches, and of coins in American dollars. Amsterdam. —1 centner lOObs.) = 108'923 av. lbs. Batavia.-1 picul = nearly 136 av. lbs. Bremen.-1 centner - 116 av. lbs.; 1 lb. = 1'1 av. lbs.; I foot = 11 lin; 1 rix dollar, (silver) = $0'787; 72 grotes = rix dollar. Calcutta.-1 rupee, (gold) ==$6.75; 1 rupee (silver,)= $0.45,6; 1 candy = 20 maunds, = 500 lbs. av. Canton.-1 picul = 1331 av. lbs.; 1 catty = 1 av. lbs.; I tael = 1 oz.; 1 tael = $1'48; 10 mace = 1 tael. Denmark. —1 centner (100 lbs.) = 110~ av. lbs.; 1 foot c121 inches; 1 rix dollar, (silver) $0-52; 6 marcs = 1 rix dollar; 16 skillings = 1 marc. Florence and Leghorn. —1 cantaro, (100 lbs.) = 74'86 av. lbs.; 1 palmo = 9] inches. France.-1 franc - $0 186; 10 decimes = 1 franc; 10 centimes - 1 decime. Genoa. —1 peso grosso (100 lbs.) = 761 av. lbs; 1 peso sottile = 69'89 av. lbs; 1 palmo = 9j in. Great Britain. —1 = 20 shillings sterling = $4-84; 1 guinea = 21 shillings sterling = $5'081. Hamburg. —1 foot = 11'3 inches; 1 mile = 4'68 miles; 1 marc banco = $0'35; current marc = $0*28; 3 mares = 1 rix dollar. Malta.-1 foot, 10 inches; 1 cantaro, (100 lbs.) - L74'5 av. lbs.; 1 pezza = $1. Manilla.-1 arroba = 26 av. lbs.; 1 picul = 143 av. lbs.; I palmo = 10'38 in.; 8 rials = $1; 34 maravedis = 1 ial. Naples.-1 cantaro grosso = 196*5 av. lbs.; 1 cantaro iccolo = 106 av. lbs.; 1 palmo = 10# in.; 1 ducat, (sil. er) = $0'80; 10 carlini - 1 ducat; 10 grani= 1 carlino. Portugal. —100 lbs. == 101'19 av. lbs.; 1 arroba - 22'26 WEIGHTS, MEASURES, AND COINS. 413 av. lbs.; 1 quinta. = 89-05 av. lbs.; 1 pe or foot, - 12j in.; 1 mile = 1 mile; 1 milree, or crown = $1'12 1000 rees; 400 rees = 1 cruzado. Prussia.-100 lbs. = 103'11 av. Ibs.; 1 quintal, (110 lbs.) = 113-42 av. lbs.; 1 foot= 1'03 feet; 1 mile = 4-68 miles; 1 thaler, $0'69 = 30 groschen; 12 pfennig = grosch. Rome.-100 libras = 74-77 av. lbs.; I foot 11 i.. 1 canna = 61 feet; 1 mile 7s fur. Russia.-100 lbs. = 90-26 av. lbs.; 1 pood, (40 lbs.)= 36 lbs.; 1 Russian pound = 32 loths = 96 zolotniks; 1 verst, (mile) 3500 Eng. feet = 5-3 fur.; 1 inch = 1 English inch; 1 foot (in general) = Eng. foot; 1 ruble, (silver) = $0-78 = 100 copecks. Bank ruble= -$0-223, or nearly 22~ cents. Sicily.-100 libras = 70 av. lbs; 1 cantaro grosso192'5 av. lbs.; 1 cantaro sottile = 175 av. lbs.; 1 palmo 91 in.; 1 canna=_ 6 feet; 1 oncia, (gold) = $2-40 = 30 tari; 20 grani = 1 taro. Spain. —1 quintal = 101'44 av. lbs.; 1 arroba = 25-36 av. lbs.; 1 fanega = 1'6 bu.; 1 foot - 11*128 in.; 1 league = 4-3 m. nearly; 1 vara 2'78 feet; 20 rials $11; 16 quintos 1 rial; 2 maravedis 1 quinto. Sweden.-100 lbs. (victualie) = 73*76 av. lbs.; 1 foot 11*69 in.; 1 mile = 6-64 m.; 1 ell = 1-95 feet. Smyrna.-100 lbs. (1 quintal) = 129-48 av. lbs. Trieste.-100 lbs. = 123-6 av. lbs.; 1 foot Austrian 1*037 feet; 1 mile Austrian = 4-6 miles; 1 florin, (silver) - $0485; 60 kreutzers = 1 florin. Venice.-1 peso grosso, (100 Ibs.) = 105-18 av. lbs; I peso sottile = 64-42 av. lbs.; 1 foot = 1-14 feet; 1 li. ra -= franc French = $0*186; 100 centesimi = 1 lira. A troy pound of fine silver is worth at the mint, $15-51,515. A troy pound of standard silver, (American) $13-86.615. A troy pound of fine gold, $248'27,586. A troy pound of standard gold, (American) $223-25.581. 1 dwt. of fine gold, $1-034. I dwt. of American native gold, usually, $095) to 101. troy pound of platinum in bars, $90 to $100 A pound av. of copper, about $0-2.5 to 027 A pound av. of tin, about $0')20 A carat, see page 82. TABLES FOR THE DETERMINATION OF MINERALS. In the following tables, the more common mineral species (comprising all the American) are arranged in subdivisions, to afford aid in ascertaining the names of species. These ables will be found valuble as a means of instruction; the ise of them fixes the attention on distinctive characters, and hereby impresses the peculiarities of species on the mind. A general view of the arrangement in Table I. is here annexed. I.-SOLUBLE MINERALS. A. No effervescence with muriatic acid. a. No deflagration on burning coals. b. Deflagration on burning coals. B Effervesce with muriatic acid when heated, if not without. II.-INSOLUBLE MINERAL. Luster unmetallic. A. Streak uncololred. a. No odorous or colored fumes before the blowpipe on charcoal. 1. Wholly soluble in one or more of the three acids. * Infusible.* t Fusible with more or less difficulty.'2. Soluble, except the silica which separates as a jelly * Infisible. t Fusible with more or less difficulty. 3. Not acted on by acids, or partially sol. uble without forming a jelly. * Infisible. t Fusible with more or less difficulty. b. Colored or odorous fumes before the blow. pipe. alone or on charcoal. B. Streak colored. a. N,, fumes before the blowpipe. r ltfii-ible is meant, not capable of b,'ng melted alone or on char oal by the flame of the conmmon blowpipe. TABLE 1. FOR DETERMINATION OF MINERALS. 415 * Fusible. t Infusible. b. Fumes before the blowpipe. U. Luster metallic. A. Streak unmetallic. * No fumes before the blowpipe on charcoal t Fumes before the blowpipe. B. Streak metallic. * Malleable. t Not malleable; no fumes when heated. t Not malleable; fumes when heated. The abbreviations used in these tables are as follows: Ad. Adamantine. Limest. Limestone. Amyg. Amygdaloidal. Mag. Magnetic. Antim. Antimony. Mam. Mammillary. Arsen. Arsenical. Mas. Massive. B, bh. Blue, bluish. Met. Metallic. BL. Blowpipe. Mur. Muriatic acid. Bn,bnh. Brown, brownish. Nit. Nitric acid. Bk, bkh. Black, blackish. Op. Opaque. Bor. Borax.* Phos. Salt of phosphorus.* Bot. Botryoidal. P'ly. Pearly. Cleav. Cleavable. Pma. Prisms. Char. Charcoal. Prim. Primary rocks.t Col. Columnar. R, rdh Red, reddish. Cryst. Crystals, crystalline. Rad. Radiated. Decrep. Decrepitate. Ren. Reniform. Deliq. Deliquescent. Res. Resinous. Dif. Difficult, difficultly. Soda, Carbonate of soda.* Div. Divergent. Sol. Soluble. Efferv. Effervescence. St. Streak. Exfol. Exfoliate. Stalact. Stalactitic. Fib. Fibrous. Stel. Stellate. Flex. Flexible. Strl. Translucent on edges omy Fol. Foliated. Strp. Semitransparent. Fus. Fusible. Sulph. Sulphureous Gelat. Gelatinize. Submet. Submetallic. Glob. Globule. Sul. Sulphuric acid. Gn, gnh. Green, greenish. Trl. Translucent. rann. Granular. Trp. Transparent..ryh. Gray, grayish Vit. Vitreous Infus. Infusible. Vol. Volatile. Insol. Insoluble. Volc. Volcanic rocks. Intum. Intumesce. W, wh. White, whitish. Lam. Laminae. Yw,ywh. Yellow, yellowish. * Blowpipe flux. t This term as here used means simply, granite and the allied crys. talline locks, syenite, gneiss, mica slate, talcose slate, hornblende rock, withov., ference to age. 33* 416 TABLE I. FOR DETERMINATION OF MINERALS. The Roman numerals refer to the systems of crystalliza. tion, (page 32.) I. Monometric. IV. Monoclinic. II. Dimetric. V. Triclinic. III. Trimetric. VI. Hexagonal or Rhombohedral. The page on which each species is described is mentioned, that the student may conveniently turn to the fuller descrip. tions for a farther, examination of a mineral. The kinds of rock in which the species occur is often addec, after the description. I.-SOLUBLE MINERALS. A. NO EFFERVESCENCE WITH MULIATIC ACID. EVEN IF HIEA'rED. a. Not deflagrating on burning coals. Sal ammoniac, 100. I; crusts; G 1 5-1'6; wh, ywh; taste acute and pungent; not deliquescent; Sul, effervesce; mixed in powder with quicklime ammoniacal odor; volatile. Alum, 127. I; wh; very soluble, sweetish astringent: Bl, fus I intumesces. Common salt, 104. I; G 2-2 —23; w, rdh, gyh; saline; crystals cubic: Bl, decrepitates. Epsom salt, 124. III; G 1-7-1'8; w; bitter saline: Bl, deliq. White vitriol, 271. Ill; G 2-2-1; wh: astringent-met: Bl, w coating on charcoal. Borax, 107. IV; G 1-7-1-8; wh; slow efflor; sweetish alkaline: Bl, swells up and becomes w and opaque. Glauber salt, 102. IV; G 1-4-1-5; wh, gyh; cooling and bitter: Bl, watery fusion. Copperas, 246. IV; G 2; gn, ywh, wh; astringent-met: Bl, red; Bor gn glass. Blue vitriol, 297. V; G 2'2-2'3; sky-blue; nauseous met: Bl, copper reaction. White arsenic, 226. Capillary cryst; hot, mas; Gr 3-7; w; taste astringent, sweetish: Bl, volatile, alliaceous fumes. b. Deflagrate on burning coals. Niter, 101. III; G 1'9-2; w, not deliquescent or efflorescent. Nit. of soda, 103. VI; G 2-3; wh; deliq; burns with a deep yellow light. Nitrate of lime, 123. Cryst efflorescences; G 1-62; w, gy; very deliquescent: BL watery fusion, scarcely detonates. B. EFFERVESCING WITH MURIATIC ACCI Matron, 103. IV; G 1-4-i-5; w, gyh; efflorescent. II.-INSOLUBLE MINERALS. 1. LUSTER UNMETALLIC. A. STREAK UNCOLORED.. No fumes before the blowpipe on charcoaL L WAolly soluble in one or more of the acids, (cold or hot), uually with eferwetace * Infusible. Hardness. Hydromagnesite, 125. 1.0-2-0 Whitish crusts; G 2-8; adheres to the tongue, Serpentine. Brucite, 125. 1-5-2-0 VI; fol. lamine flexible-: G 2'3-2-4, w, gnh: p'ly trl; no effcrvcsccrT e. Serpentine. TABLE I. FOR DETERMINATION OF MINERALS. 417 Hardness. Websterite, 1;9. 1-5-2'0 Ren, mas; G 16-1'-7; dull; w, op; adheres to the tongue: sul, sol, no effervescence. Nemalite, 125. 2 Siiky fib; G 2-3-2-5; gyh, bh-w; fibres separable, brittle on exposure. Serpentine. Calc spar, 115. 3;0-2-0 VI; cleavI fib, mas; G 2'3 —25; vit, p'ly, w, gy, bnh, bk; trp-op.; sometimes soft and earthy Bl, intense light. Aragonite, 118. 3-5 III; mas, fib; G 2-8-3; vit; w, gyh, bnh; trpop; effervesce; Bl. intense light, crumbles. Diallogite, 261. 3-5 VI; cleav; mas; G 3-5-3-6; vit, p'ly; rdh; tri op; nit, effervesces: BI, bor, violet glass. Magnesite, 124. 3-0-4-0 VI; cleav I fib, mas; G 2-9-3; vit, silky; w, ywh, bn; trp, op; little effervescence. Blende, 269. 3'5 —40 I; dodec cleav; mas; G 4-4-1; resin-yw, rdh, w; trp, strl; nit sol, emitting sul. hydrogen: Bl, bor infus. Dolomite, 118. 3-5-4-0 VI; cleav I mas; G 2-8-2'9; vit, p'ly; w, gy, bn; no effervescence unless heated. Mesitine spar, 249. 4-6 VI; clear I mas; G 3-3-3'65; vit; ywh, bn on exposure; mur slow solution. Oligon spar, 218. " VI; cleav; mas; G 3-73-88; vit; bn on exposure: Bl, bor amethystine glob. Yttrocerite, 206. 4'5-50 III; cleav; mas; violet b, gyh, rdh-bn; vit, p'ly; strl, op; hot mur, sol; Bl. whitens. Prim. t Fusible with more or less difficulty. Witherite, 109. 30 —3.5 HI; mas, fib; G 4-2-4.4 w, ywh, gyh; trl-op, nit efferv: B1 fus I op. glob. White lead ore, 281. 3-03-5 III; mas; G 6'1 —65; w, gyh, bnh; ad, res; trp trl; brittle; mur eff: Bl, fus I on char, lead. Strontianite, 111 3-5 III; cleav; fib, mas; G 36-.3-7; res, vit; gnh, ywh, gyh; effervescence: Bi, fus difl colors flame reddish. Pyromorphite, 283. 35-4-0 VI; hexag pms; hot, fib; G 6-5-7-1; bright gn, iw, bn; res; strl, strp; brittle; hot nit so: B, fus With lead ores. Spathic iron, 247. 3-4'0 VI, cl, mas; G 37.~3-9; ply; ywh, bnh, gyh; darkens on exposure; trl, op; pulverized, some eff: Bl, fus dif!; blackens; iron reaction. Wavellite, 130. " III; fib, glob; G 2-3-2-4; p'ly, vit; w, ywh, bnh, gyh; trl; hot nit, sol, vapors corrode glass: Bl, fus, intum, colorless glass. tacoxene, 249. " J)iv, rad, fib, silky; G 3-3-3'4; ywh-bn, ywh; bn on exposure: Bl, infus. luor spar, 121. 40 - I; cl mas; G 3'.-3-2; vit; w, yw, b, violet, gn, r, often lively; trp, trl; sul, affords fumes that cor. rode glass: Bl, fus, decrep; phosphoreaces when heated. Apatite, 120. 4-5 -50 VI; hexag; mas; G 33-33; vit, res; gn, bh. w rh. bn; trp, op; brittle; nit sol slowly;n powder 418 TABLE I. FOR DETERMINATION OF MINERALS. Hardness. without efferv: Bl, fus dif I bor fus I Prim. Gran limestone, vole. lriplite, 260. 5-0 Lam, mas; G 34 —38; bkh-bn; res, ad; nit sol, nc ef: Bl, tue I bk scoria; bor violet glass. Triphyline, 249. 55 IV; mas; G 3-3.6; gnh, yw, gy, rdh-br; vit. res trp, trl; mur, sol; Bl, fus bor, green glass, soda manganese reaction. Boracite, 126. 7-0 1; hemihed cubes; G 29 —3; w, gyh; vit, ad; strp, trl; pyro-electric; mur, sol: Bl, fus. Gypsum. 2. Soluble, ewcepting the silica, which separates as ajelly. * Inlusible. Halloylite, 161. 10 —2-0 Mas, earthy or waxy; G 1'8 —21; w, bh; adheres to the tongue; sul, gelat I Bl, infus. Allophane, 162. 3-0 Mas, ren; G 18-1-9; vit, res; bh, gnh, ywh, trl; very brittle; gelat I Bl, intum. t Fusible. Mesole, 167. 3-5 III; fib rad; G 2-3-24; p'ly; gyh-w, ywh; trl: Bl, fue I Amyg. Laumontite, 166. IV; mas; G 2'2-24; vit, p'ly; w, gyh; trl; w and friable on exposure; gelat I Bl, fus w, frothy. Amyg. prim. Phillipsite, 168. 4-0 —45 III; rad, cryst often crossed; G 2-2-2; w, rdh; vit; trp, op; mur gelat: Bl, fus. Amyg. Tabular spar, 141. 4-0 —50 V; cl, subfib; G 2-7 —29; p'ly, vit; w, gyh; trl: mur gelat: Bl, fus dif, pearl semiop. Prim. anyg. Thomsonite, 167. 45 —50 III; cl, fib, rad; G 2-3-2-4; w, bnh; trp-trl; brittle; gelat: B1, fus I intum, w, op. Amyg. prim. Dyaclasite, 142. 4-5-5-0 fib, div; G 2 —2-4; p'ly, vit; w, bh; trl, strp; very tough under the hammer; tmur gelat; Bl, fus op. Amyg. Pectolite, 142. fib, div; G 2-69; vit, p'ly; w, gyh; after heating gelat in mur: Bl, fus trp glass. Amyg. Calamine, 272. " III; cl; mas, bot, fib; G 3-2-35; w,b, gn,yw, bn; trp-trl; hot nit gelat: Bl, fus dif II intum; phosphoresces. Stratified rocks. Natrolite, 166. 4-5 —55 III; acic, cryst; div fib; G 2-1-2-3; vit; w, ywh; trp, trl; gelat Bt, fus I op glass. Amyg. vole. Analcime, 168. 50-5-5 I; trapezohed; mas; G 2-2-3; vit; w, rhd, gyh, trp-op; brittle; mtur gelat: Bl fus I intum, glassy glob. Amyg. vole. Scolecite, 167. * III; div, fib, rad; G 22 —2-3; vit, p'ly; w; trp, trl; nit and mur; gelat I Bl fus I op, curls up in outer flame. Amyg. vole. Datholite, 142. " IV; glassy crystals; fib, bot, mas; G 2-2-3; w gnh, rdh; trp, trl; nit gelat I Bl, fus Amyg. prim. godalite, 197. 5-5-6-0 I; dodec cryst; mas; G2'22-45; vit; gyh, bn, b trp-strl; nit gelat: Bl, fus, colorless glass. iepheline, 180. 5-5-6-0 VI; hexag; coarse massive, subfib; G 2-4-2-6; vit greasy; w, ywh, gnh, bnh, rdh; trp-op; gelat. RI, lus ditf blebby glass. Volc. prim. TABLE 1. FOR DETERMINATION OF MINERALS. 419 3. Not acted on by acids or partially soluble without forming ajelly. t Infusible. Hardness. Talc, 143. i-1-1'5 VI; foil mas; G 2-7-2-9 light gn, gnh-w gyh. p'ly, unctuous; laminas texible, inelastic. Prim Iyrophylli te Foll gran; apple-gn, w, bnh-gn, ywh; ply; strp, trl: Bl, swells up I Prim. Mica, 191. " Fol 1 lam. thin elastic, tough; G 2'~ —3; colors various, often bright; p'ly; trp, strl: Bl. fus dif I Prim, etc. Chrysocolla, 300. 2-3-0 mas, hot; G 2 —23; bluish-gn; smooth vit, or ear. thy; strl, op; nit sol, except silica. Gibbsite, 131. 30-3-5 Stalact, crusts; G 2-3-2-4; gyh-w, gnn-w; null. Emerald nickel, 264. 30-3-5 minute globular, crust; G 3-05; emerald-gn; St paler; vit; trp, trl; Bl, loses its color. Blende, 269. 3.5-4-0 I; dodec cleav, mae; G 4 —41; resin-yw, on, bh, w rdh; trp-op: Bl, bor inf. Plumbo-resinite, 285. 40 —4-5 reniform; G 6-3-6-4; ywh, bnh, rdh; resinous, or like gum arabic; til; Bl, decrep; enam on char. Clintonite,. 148. 4-0-5-0 IV; fol I lam brittle; G 3 —-1; rdh-bn; met-p'ly strl: B!, bor trp pearl. Alum stone, 129. 5'0 III; acic, stel, mas; G 26 —2-8; vit, p'ly, earthy; w, rh, gyh; sul, mostly sol: Bl, decrep; soda infus. Momnzito. 206. 5'0 IV; imbedded, cryst, cleavl in one direction; G 4'8-i5'1; bn, bnh-r; vit, res; strp, op; brittle; mur, decomposed. Prim. Leucite, 175. 5-5-6-0 I; trapezohedrons; G 2-4-2-5; w, gyh; vit; strp tri: Bl, bor, fus dif Volc. Anatase, 211. " II; in cryst; G 3-8-3-9; fine bn, b; met-ad, res; strp, trl: Bl, loses col; bor fus dif. Prim. Turquois, 130. 6-0 Reniform; G 28 —3; b, bh-gn; waxy, dull; tr, op: Bl, flame green; bor, fus. Opal, 139. 5-5-6-5 Massive, uncleav; w, yw, r, bn, gn, gy, pale; in some a play of colors; vit, p'ly; trp, strl: Bl, decrep, op. Kyanite. 173. 5-0-7-0 V; in prisms or bladed cryst; G 3-5-3-7; b, w, bnh; p'ly, vit; trp, strl: Bl, bor fus dif, trp. Prim. Nephrite. 147. 6-0-7~0 Mas, subgran; G 29 -3-1; leek-gn, bh, wh; vit; trl, strl: Bl, whitens; bor clear glass. Prim. Bucholzite 172. " Col, fib; G 3-2 —36; w, gyh, bnh; p'ly; trl, str)brittle. Prim. Tin ore, 214. " II; mas, fib; G 6-5- 7-1; bn, bk, w, gy, r, yw; ad, res, cryst often brilliant; strp, op: Bl, bor on char with soda affords tin. Prim. Cbrysolite, 156. 65-7'0 III; imbeded grains or masses of a glassy appear. ance; G 33-3-6; gn, bottle glass gn: Bl, darkens bor gn glass; [rarely fusible.] Basalt. etc. aIlimanite, 172. 6-5-7-5 V; col, fib; G 3'0 —4 bn, gyh; p'ly, vit; trl, strl brittle: Bl, bor infus. Prim. Andalusite, 174. " III; stout prisms; mas; G 2-9 —3-2; vit, p'ly; gyb, 420 TABLE 1. FOR DETERMINATION OF MINERALS. Hardness. rdh; tough; structure sometimes tesselated Bl, bor fus dif, trp glass. Prim. Quartz, 132. 7-0 VI; mas; G 2-6-2-8; colors various; vit; trp op: Bi, soda fus I trp glass, efferv. Staurotide, 174. 7-0-7-5 III; stout prisms; G 3-5 —38; bn, rdh-bn, bk; vit res; strp, op. Prim. Zircon, 200. 7-5 II; cryst, seldom mas; G 4-4-48; bn, r, yw, gy, gn w, some bright; subad; trp, trl: Bl, bor, clea glass. Prim; gran limest. Topaz, 194. 7-5-8-0 III; prisms with basal cleavage I mas, col; G 3-4 36; pale yw, gn, b, w; vit; trl, strl: Bl, bor slowl trp glass. Prim. Spinel, 160. 8-0 I; octahedrons, etc; G 3.5-4-6; r, bh, gnh, yh, bn bk; vit; trp, strl, (some impure crystals soft): Bl, bor fus dif. Prim; gran limest, etc. Chrysoberyl, 199. 8-5 III; cryst; G 3-5-3-8; bright gn, ywh, gyh; vit, trp, trl: B1, bor fus dif I Prim. Sapphire, 158. 9'0 VI; mas; in grains; G 3-9 —42; b, r, yw, bn, gyh-b gy, w; vit; trp, trl: Bl, bor fus dif. Prim; gran limest. Diamond, 80. 10'0 I; G 3-4-3-7; w, b,r, yw, gn, bn, gy, bk; adaman. tine; trp; strl. t Fusible with more or less difficulty. Talc, 143. 1-0-1'5 III; fol mas; G 27 —2-9; light gn, gnh-w, gyh; p'ly, unctuous; lamina flexible, not elastic: Bl, infus, or fus dif l Prim; gran limest. Chlorite, 145. 1-5 Fol; mas gran; G 2'6-2-9; olive green; p'ly; su decomp: Bl. fus dif I sometimes to a black glassy bead. Prim. Gypsum, 112. 1-5-2-0 IV; fol I gran, stel; G 2-2-24; w, gyh,bnh, rh, bk; trp, trl; lam flexible, inelastic: Bl, fus dif; whi. tens, exf, and becomes friable; Strat. prim. volc. Mica, 191. 2-0-2-5 Fol! lam thin elastic, tough; G 2-8-3; colors various, often bright; p'ly; trl, strl: Bl, fus dif I Prim, etc. Cryolite, 132. " Mas, fol; G 2-9-3; w; vit, p'ly; fusible in a candle. Prim. Serpentine 145. 2-0-3-5 III; mas; sometimes thin fol, fol brittle; fib; 0 2-4-2-6; dark or light gn, gnh-w, bh-w; trl-opfeel often greasy: Bl, fus dif! Chlorophyllite, 162. 2-0 —40 VI; fol prisms; fol brittle; G 2-7-2-8; dull green. gyh, bnh; p'ly, vit: Bl, fus dif I Prim with iolite. Anglesite, 281. 25 —3-0 III; mas; lam; Gr 6-2-6-3; w, ywh, gyh; gnh, ad, vit, res; trp, trl: Bl, fus 11 decrep; on char, lead globule. Anhydrite, 114. 25,-35 III; rectang cleav I mas; G 2-8-3; w, rh, bh, gyb p'ly, vit: Bl, fus dif; whitens; not exf. *This tesselated variety is often quite soft, owing to impurities. TABLE I. FOR DETERMINATION OF MINERALS. 421 Hardncss. Celestine, 110. 3-0-3-5 III; mas, fib, lam; G 3-8 —4; w, bh, rh; vit, res; trp, strl: Bl, fus, decrep; phosphoresces. Heavy spar, 108. " II; mas, fib, lam, G 4-3 —48; w, gyh, ywh, bn; vit, p'ly, res; trp, strl: Bl, fus, decrep. Slrat, prim. Heulandite, 164. 3-5 —40 IV; fol fol brittle; G 2-2; w, rdh, gy, bnh; p"y vit; trp, strl; acids sol, except silica: Bl,fus, intum, phosphorescent. Amyg, prim. Btilbite, 165 3'5-4'0 III; fol I rad, div; G 2-1-2-2; w, ywh, rh, bn; p'ly trl, strp; nit, silica deposited: Bl, fus I intum colorless glass. Amyg, prim, &c. Schiller spar, 148. " Mas, fol; fol brittle; G 25 —2-7.; dark gn, or sub met: Bl, fus dif!! gives off water. Chabazite,* 169. 4'0-4-5 VI; in rbdns, nearly cubes, and complex smai crystals; G 2-22; w, rdh, ywh; vit; strp, trl mur, silica deposited: Bl, fus I blebby enameL Amyg, vole, prim. Harmotome, 168. III; crystals often crossed; G 2-3-2-5; w, rdh; vit; strp, op; mur, silica deposited: Bl, fus, clear w glass; phosphoresces. Amyg, prim, etc. Nungstate of lime, 219. " II; mas; G 6-61; vit, res; ywh, w; strp-op; nit, becomes yw, but is not dissolved: Bl, fus dif l decrepitates. Prim. Apophyllite, 165. 4-5 —50 II; glassy cryst; transverse cleav; G 23 —2-4; w; gnh, ywh, rdh; p'ly, vit; trp, op; nit, sol, but hardly gelat: Bl, fus, exfoliates. Amyg. Monazite, 206. 5-0 IV; imbedded cryst, one cleavage I G 4-8-51; bn, bnh-r; vit, res; strp, op; brittle; mur, decomposed: Bl, fus difll Prim. Pyrochlore, 208. 50 IV; imbedded oct cryst; G 3-8-4-3; yw, ywh; res, vit; St slightly colored; trl: Bl, fus difl Sphene, 211. 5-0 IV; usually in acute, thin crystals; G 3.2-3-5; bn, yw, gy, bk; res, ad; strl, op: Bl, fus dift bor yw glass. Prim, gran limestone, etc. Scapolite, 180. 5-0 —60 II; mas; subcol; G 2-6-2-8; w, gyh, rh; vit, p'ly, trp-op: Bl, fus. Prim, gran limestone. Hornblende,t 15. IV; fib, rad; mas; (some var fib like flax G 2-93-4; gn to bk and w; vit, p'ly; trp, op: Bl, fs, or dif! fus. Prim, trap, trachyte, etc. Pyroxenej 150. " IV; fib; mas; cleav; G 3-1 —3-5; gn to bk and w, vit, p'ly; trp-op: B1, fus; glassy globule. Prim. basalt, vole, etc. Lazulite. 131. 55 —6'0 IV; mas; G 3 —31; pure b, gnh-b; vit; strp-op; Bl, fus, bor clear glob. * The var. Gmelinite gelatinizes in acids. t Some fitrous varieties (asbestus) of hornblende and pyrexene are quite sol, and resemble those of serpentine ~ and others are like flax, or have nearly the texture of felt 4t23' TABLE I. FOR DETERMINATION OF MINERALS. Hardness. Lapis Lazuli. 196. 5-5-6-0 I; dodec; maa; G 2-5-2'9; rich b; vit; trl —op Bl, fus, trl or op glass. Feldspar, 176. 60 IV; cleav, mas; G 2-3-2-6; wh, gyh, rh, bh, gnh, p'ly, vit; trp, strl; mur, no action: Bl, fus dif, bor trp glass. Albite,'.77. 6-0 V; cleav, mas; G 2-62-7; w, gyh, gnh, rh, bh; p'ly, vit; trp, strl; mur, no action: Bl, fus dif; flame yellow; may generally be distinguished from feldspar by its purer white color. Labradorite, 178. 6-0 V; cleav, mas; G 2-6-2-8; chatoyant, gy, gnh, bn rdh-bn: p'ly, vit; strl; hot mur decomp: B, fus easily, colorless glass. Prim. Chondrodite, 157. 5-5-6.5 IV; granmas; G 31 —3-2; ywh, bnh-yw, rh, gnh vit, res; trp, strl; brittle: Bl, fus difl! bor fust ywh-gn. Gran limestone. Obsidian, 341. 5-5-6-5 Mas, like glass; G 22-2-8; bk, gy, gn; vit, p'ly Bl, fus. Manganese spar, 239. 5-5 —70 V; mas; G 3-4-3-7; flesh-r, dark bn on exposure vit; trp, strl: Bl, fus bkh glass; bor violet. Prim Petalite, 182. 6'0-6-5 Cleav mas, gran; G 2-4-2'5; w, bh, rh, gnh; vit, p'ly; trl; phosphoresces. Bl, fus; bor trp glass. Prim. Idocrase, 184. 6-5 II; mas; G 3-3-3-4; bn, gn, w; vit, res, cryst often brilliant; trp, strl: Bl, fus trl glob. Prim; eol; gran limest. Prehnite, 170. 6-0 —65 III; bot, mas; G 2-8-3; light gn, w; vit, p'ly; trl, strl; tough; mur sol, exc't silica: Bl, fus. Amyg, prim. Epidote, 182. 6'0-7-0 IV; mas, gran, col; G 3-2-35; ywh-gn, gy, bn, bh, rh; vit, p'ly; trp, op: Bl, fus. Prim, etc. Spodumene, 156. 6-5-7-0 Cleav mas, gran; G 3-1-3-2; gyh-w, gnh; p'ly: Bl fus, intum, exf, colorless glass. Prim. Ainite, 190. V; cryst acute-edged; Gr 3-23-3; deep bn; vit, brilliant; trp, strl: Bl, fns I intum dark gn glass; Prim, etc. Garnet, 184. 6'5-7.5 I; cryst, mas, gran; G 3-5-4'3; r, bn, w, gn, bk often bright; vit, res; trp, trl: Bl, fus, no efferr bk glob. Prim, etc. Boracite, 126. 7-0 I; hemihed cubes; G 2-9 —3; w, gyh; vit, ad; strp trl; pyro-electric: Bl, fus, intum. Gypsum. [olite, 190. 70 III; mas, glassy; G 2-6-28; b, gyh-b, bnh; trp trl: Bl, fus dif bor trp, glass. Prim. T.urmaline, 187. 70 —8-0 VI; col, mas: G 3 —31; bk, bn, gn, r, b, w, oftes bright; vit, res; trp, op; pyro-electric: Bl, fus intum. Prim, etc. Euclase, 199. 7-5 IV; in crystals, cleav; G 29 —3'1; pale-gn, b, w vit, brilliant; trp, strl: Bl, fus dif I intum. Prim <<~ryL 197. 7'5-8-0 VI; hexag pms, mas; G 26-2'8; gn, bright oi dull, bh, ywh; trp, strl: Bl, fus dif; bor trp glass Prim. TABLE I. FOR DETERMINATION OF MINERALS. 423 b. Colored or odorous fumes before the blowpipe on charcoal. Hardness. Horn silver, 327. 1-0 —1.5 I; mas, like wax; G 53-5-56; gy, bh, gnh; trl, strl sectile; fus. in candle, yielding odorous fumes Silver ores. Miimetene, 284. 27 —3-5 VI; mas; G 64-6-5; pale yw, bnh, bnh-r; strp, trl; hot nit sol: Bl. fus l on char alliaceous fumes.-Lead ores. Scorodite, 249. 3'5-4-0 III; mas; G 3-1 —33; leek-gn, gnh w, bh, bnh; ad, vit; strp, strl: Bl fus I alliaceous fumes. Blende, 269. " I; dodec cleavl mas; G 4-4'1; resin-yw, rdh. wh; trp, strl; nit sol, emitting sulph hydrogen Bl. on char at a high heat fumes of zinc. Bismuth blende, 221. 3-5 —45 I; mas, col; G 5-9-6-1; bn, gyh, ywh; res, ad B, fus, w fumes. Prim. Bmithsonite, 272. 5-0 VI; mas, ren, bot; G 4-2-4-5; gyh.w, gnh, bnh vit, p'ly; strp, trl; nit efferv: B, infus; on cam w fumes. Usually with lead ore B. STREAK COLORED. a. No fumes before the blowpipe * Fusible. Minlum, 280. soft Mas, pulv; G 4'6; bright red: Bl, fus; on chu glob lead. Lead ores. Vivianite 248. 1-5-2'0 IV; fol Ilam. flex; mas; 0 2'6-27; bkh-gn dark b; St, bh-w, b; nit or sul sol: Bl, fus I decrep, dark bn scoria, magnetic. Uranite, 228. 2-02-5 II; fol I mas; G 3 —6; bright gn, yw; St, paler; p'ly, ad; trp, strp; nit sos, no efferv: Bl, fus, bk glob. Prim. Cup. anglesite, 281. 2'5-3-0 IV; cleav I G 5-3-5-5; fine azure blue; St, paler; ad, vit; trl, strl: Bt, reaction of copper and lead. Lead ores. Chromate of lead, 284. 2-5-.30 IV; mas, col; G 6; bright r; St orange; ad; trl; sectile; nit sol, no efferv: Bl, blackens, decrep, shining slag. Lead ores. Green malachite, 298. 35-4-0 IV; mam, bot, crust; G 4-4-1; gn; 8t, paler, vit, silky, earthy; trl, op; nit sol, efferv: Bl, fus I bk: bor gn. Copper ores. Red cupper ore, 296. " I; mas, fib; G 5-9-6; deep red; St, bnh-r; ad submet; strp, strl; nit sol, efferv: Bl fus I on char metallic copper Copper ores. Pyromorphite, 283. VI; mas; G 6-8-7-1; gn, bn, gy; St yw; res; strp, str]; hot nit sol, no efferv: Bl fus Lead ores. Azurite l300., IV; mas, earthy; G 3-5 —39 azure b, dark b; St paler; vit, ad: trp. strl; nit efferv: Bl, fus! copper' action. Copper ores. 34 424 TABLE I. FOR DETERMINAT[ON OF MINERALS. Hardness. Pyrochlore, 208. 5-0 I; octahed cryst; G 4-2-4-3; rdh-bn, yw, ywh St paler; res, vit; strl, op: B1 ywh-bn, fus dif bor yw glob in outer flame. Prim. Triplite, 260. 50-5-5 Mas, cleav; G 3'4-3-8; bkh-bn; St ywh-gy; res, ad; strp, op; nit sol, no efferv: Bl fus I bk scoria; bor, violet Monazite, 206. " IV; cryst; G 48 —'1; bn, rdh-bn, gyh; Strdh-w bnh-w; vit, res; strp, op: Bl fus dif I yw, op Prim. Chondrodite, 157. 6'0-6-5 IV; gran mas; G 3-1-3-3; light yw, bn, rdh; S paler; res, vit; trp, strl; very brittle: Bl fu dif ll loses color. Gran limest. Prim. Allanite, 207. * V; acic cryst; mas; G 32-4-1; bnh-bk, gnh submet, res; St gnh-gy; op, strl: Bl fus, froths, bk scoria. Prim. t Infusible. Wad, 260. 1-0 Mas, often earthy; G 3-7; bn, bk, soils: Bl, man ganese reaction. Black copper, 296. Mas, or earthy; bk, bnh-bk; St bk; soils: Bl, copper reaction. Copper ores. Earthy cobalt, 267. " Earthy, mas; bk: B1, bor, blue from cobalt. Cacoxene, 249. 3-0-4'0 Fib, rad; G 3.3-3-4; ywh-bn, yw; St ywh; silky. Bl, bor dark red bead. Iron ores. Blende, 269. " I; dodec cleav; mas; fib; G 4 —41; resin yw, bn, bk, red; St pale; strp, op; nit sol, emitting sulph hydrogen: B1, bor infus; on char, at high heat, fumes of zinc. Warwickite, 3-0 —40 Prismatic cryst; G 3-3-3; bnh, tarnished bh, or wh; St bnh; met-p'ly; res. Gran limest. Red zinc ore. 270. 4-0-Lr111; fol! mas; G 5-4 —5-6; bright r; St. orange; subad; strl, op; nit sol, no efferv: Bl, bor yw glass; soda a zinc slag. Dioptase, 301. 50 VI; cryst; G 3-23-3; emerald-gn; St. gn; vit, res; trp, trl; mur, sol, no efferv: Bl, decrep, ywh-gn flame; copper ores. Limonite. 239. 5-0-5-5 Mas, mam, stalact, bot; earthy; G 3'9-4-1; dull bn, bk, ywh; res, submet; strp, op: Bl, bk, mag netic, iron reaction. Chromic iron, 241. 5-5 I; mas, uncleav; G 43 —4'5; iron bk, St bn; nearly dull, submet; op: Bl, bor fine gn glob. Serpentine. Pitchblende, 228. 5.5 Mas, bot; G 6-47; bnh-bk, velvet bk; St bk; sub metallic or dull; nit slow sol BR, bor a gray scoria. Prim. Psilomelane, 259. 5 —6'0 Mas, bot; G 4-4; bk, dark steel gy; St bkh submet; op; mur sol, odorous fumes: Bl, man ganese reaction.. Rutile, 210. b —6-5 II; rarely mas; G 4-2-4-3; rdh-bn, ywh. gy; S paler; ad, met-ad; trl, op: Bi, bor ywh r glass crystals ften acicular. prim, etc. TABLE I. FOR DETERMINATION OF MINERALS. 4225 Hardness. Tin ore, 214. 6-0 —70 II; mas, fib; G 6-5-7-1; bn, bk, yw, r; St paler; ad, strp, op: Bl, on char, with soda, tin glob. Prim. b. Fumes before the blowpipe. Red antimony, 224. 1-0-1-5 IV; capil tufts and div; G 4-4 —46; cherry-r; St bnh-r; ad, met; strl; nit w coating: Bl, fus!I or char, volat. Prim. Cobalt-bloom, 267. 15 —2-0 IV; foll fib, stel, earthy; 2-9-3; crimson and peach-blossom r, gyh, gnh; St paler; dry pow der lavender b; lam flex: Bl, fus I on char allia. ceous, bor fine blue glob. Prim, cobalt ores. Orpiment, 226, III; fol Ilam flex; mas; G 3-4-.35; lemon yw; St paler; p'ly, res; strp, strl; sectile: Bl, sul. phur and arsenical fumes. (Realgar, p. 305, differs in its red color and orange streak.) Copper mica. 301. 2-0 VI; fol I mas; G 2-55; emerald gn, grass gn; S paler; ply, vit; trp, trl; sectile: Bl, alliaceous fumes, rdh-bn scoria. Sulphur, 98. 1-5-2-5 III; mas; G 2-07; yw; rdh, gnh; res; trp, strl, burns, b flame. Red silver, 327. 20-2-5 VI; mas; G 5'4-5-9, light r, to bk; St r; ad, met; strp, op: Bl, fus I! sulph and arsen fumes; silver ores. Cinnabar, 287. " VI; cleav; mas; G 8 —81; bright r, bnh-r, bn; st r, bnh; ad, sub-met; strp, op; nit, sol, r fumes: Bl, wholly vol. Strat, prim. Atacamite, 302. 2-5-3-0 III; cleav; mas; G 4-4 —45; bright gn, olive-gn; St gnh; ad, vit; strl: Bl,fus I muriatic fumes; copper reaction; copper ores. 11. LUSTER METALLIC. A. STREAK UNMITALLIC. No fumes before the blowpipe on charcoal Wad, 260. 1-0 Mas, often earthy; G 3-7; bn, bh; soils; submet. Bl, manganese reaction. Earthy cobalt, 267. " Mas, earthy, hot; G 2-2-23; bh-bk, bnh-bk; St bh bk; sectile: Bl, arsen fumes; bor blue glass. Pyrolusite, 259. 2-0-25 III; col, rad; mas; G 4-8-5; iron-bk, St bk; mur, odor of chlorine: Bl, infus; bor amethyst, glob. Cinnabar, 287. " VI; cleav; mas: ( 8-8I; r, bnh-r, gyh, dark bn; St r; strp, op; nit sol, r fumes: Bl, volatile. Strat, prim. Blende, 269. 3.'5-40 I; dodec cl I mas; G 4-4-1; bn, bk; St yw, bnh op; submet, bright: Bl, fus. Prim, strat, etc. Manganite, 261. 4'0 —45 III; mas; G 4.3-4'4; dark steel-gy, iron-bk; SI rdh-bn. bkh: Bl, infus; bor, amethystine glob. 1'd6 T. RLE I. FOR DETERMINATION OF MINERALS. Lin 1lii1;'SaS. Limonite, 239 5-0;-55 mam, bot, stalact, mas; G 3-9-4; bn, bkh; St ywh bn; strp, op; no action on magnet: Bl, infus bk and magnetic. Wolfram, 244. 50 —55 II; mas; col, lam, G 7-1 —74; gyh-bk, bnh-bk; St dark rdh-bn; submet: Bl fusl decrep, bol gn bead. Prim. Chromic iron, 241. * I; mas; G 43 —4-5; iron bk, rather dull, brittle, St bn; often slightly magnetic: Bl, infus; bor fine gn, fus dif. Serpentine. litchblende, 228. 5-5 Mas, bot; G 6-47; bnh-bk, velvet-bk; St, bk; submet; nit slow sol: Bl, bor gray scoria. Prim. Tsilomelane, 259. 50 —60 Mas, bot; G 4 —4 4; bh, gyh to dark steel gy; St bnh-bk, shining; brittle: Bl, infus, bor violet. Manganese ores. Columbite, 243. " I; mas; G 5-9-6-1; bnh-bk, bk, often with a steel blue tarnish; St dark rdh-bn, bnh-bk; submet: Bl. infus, bor fus dif. Prim. VYenite, 245. 55-6-0 III; mas, col; G 38-4-1; iron bk, bnh; St gnh, bnh; submet; brittle: Bl, fus; bor bk mag glob. Prim. Specular iron, 218. 5-5 —65 VI; mas; G 4-5-53; iron-bk and cryst brilliant St r, rdh-bn: Bl infus, bor iron reaction, glob finally mag. Prim, strat, vole. Magnetic iron, 235. " I; mas; G 5-5'1; iron-bk; St bk; strongly magnetic: Bl, infus, bor iron reaction. Prim, strat. Franklinite, 240. "; mas; G 4-8-5-1; iron-bk; St dark rdh bn; slightly magnetic: Bl, infus; at high heat zinc fumes. Prim. t Fumes before the blowpipe. Dark red silver, 327. 2'5 VI; mas; G 5-7-5-9; iron-bk, lead-gy; St red; met-ad: Bl, fus I b flame, sulph and antimony fumes. Silver ores. Erubescite, 294. 3-0 I; mas; G 55-1; pinchbeck-bn, copper-r, bh tarnish; St pale gyh-bk; brittle: Bl, fus; on char sulph odor, glob mag. Prim, strat, with copper ores. Copper pyrites, 292. 35 —4-0 II; mas; G 4 —4-2; brass yw; St gnh-bk; brittle. nit sol, gn: Bl, fus; on char, sulph odor. Prim strat, with copper ores. Magnetic pyrites, 233. 35 —4-5 VI; mas; G 4-5-4-7; bronze-yw, copper-r; St gyh-bk; magnetic; brittle; dilute nit sol: BL fus, sulph odor. [,eucopyrite, 23b. 5-0 —i5 II; mas; G 7.2-7-4; silver-w, steel-gy; St gyh bk; brittle: Bl, fus; on char, arsen fumes. Copper nicke,, 263. " VI; mas; G 7-3-7-7; copper-r; St pale bnh-hk brittle: Bl, fus I on char. arsen fumes. Prim usual with cobalt ore. TABLE I. FOR DETERMINATION DF MINERALS. 4'27 Hardness. Mtckel glance, 263. 5-0 —0,~ I; mas; G 6-6-2, silver w steel-gy; St gyh-bk Bl, fus I decrep; sulph and arsen fumes in glass tube. Cobaltine, 266. " I; mas; G 6-2-64; silver-w, rdh; St gyh-bk; brittle: Bl, fus; on char, arsen fumes, bh, glob, mag; bor blue. Prim. maltine, 266. I; mas; G 64-7'2; tin-w, steel-gy; St gyh-bk brittle: B1, fus I arsen odor, gyh bk mag pearl, bor blue. Prim. Jhite irn pyrites, 233. " III; mas; crests; G 4-6 —4'9; pale bronze yw; St gyh, bnh-bk; brittle: Bl, fus; on char, sulph fumes. tpickel, 234. 5-5-6-C III; mas; G 6-1; silver-w; St dark gyh-bk; brittle: Bl, on char, arsen fumes, and leaves a magnetic globule. Iron pyrites, 231 6-0-6.5 I; mas; G 4-8-5-1; light bronze.yw; St bnh-bk: Bl, fus; on char, sulph odor. Prim, rtrat, vol, etc. B. STREAK METALLIC. * Malleable. Native mercury, 287. fluid G 13-14; tin-w: Bl, volatilizes. Strat, prm. Native lead, 277. 1-0-1-5 I; in membranes and glob; G 11-12; lead gray; soils: B, fus I i volatilizes and colors charcoal yellow. Native copper, 290. 2-5 —3-0 I; mas, in strings; G 8-5-8-6; c pper-r; uit sol I r fumes; Bl, fus, colors flame green. Native silver, 323. I; mas, capil; G 10-11; silver-w; nit sol: Bl, fus. Native gold, 312. " I; mas, capil; G 12-20, pale to deep yw, according to the proportion of silver present; nit not sol: Bl, fus. Native platinum, 308. 4-0-4-5 In grains and lumps; Gr 16-19; pale steel gy; hot nit-mur sol: Bl, infus. Native iron. 230. 4-0-5-0 I; mas; G 7-3-7-8; iron-gy, magnetic. Native palladium, 311 5-0 —55 In grains, structure rad; G 10-12; steel-gy, silver-w: Bl, infus. t Not malleable: no fumes when heated. Graphite, 91. 1-0 —20 Mas, fol I gran; G 2-2-1; iron-bk, dark steel-gy; sectile; soils; nit, no action: Bl, infus. Prim strat. Imenite 241. 5'0 —6-0 VI; mas; G 4-4 —48; dark iron-bk; slightly mag netic; strong mur sol: B, infus. Prim, vaoc. Not malleable: fumes when heated. bolyudenite. 217. 1-0-15 VI; mas, fol I lam flex; G 4-5- 4-8; pure lead gy sectile; nit, partly sol: Bl, infus, on char sulph odor. Prim. 34* 428 TADLE I. FOR DETERMINATION OF MINERALS. Hardness. Fol. Tellurium, 280. 1-0-1-5 II; fol I gran: G 7-7-1; bkh lead-gy, lam flex sectile; nit sol I Bl, on char, w fumes, flame h Prim. Gray antimony, 222. 2-0 III; cleav; col, div; G 45 —4-7; lead-gy, steel-gy; tarnishes; lam subflex: Bl, fus I I on char sulpo odor and wholly volat. Prim. Vitreous silver, 325. 2'0-2-5 I; mas, retic; G 7-1-7-4; bkh lead-gy; nit sol: Bl, fus I I intum, glob of silver. Silver ores. Native tellurium, 219. " VI; mas; G 5-7-61; tin-w, rather brittle: Bl fus 1on char gnh flame, w inodorous fumes wholly volat. Przm. Brittle silver, 326 # Ill; mas; G 6-2-6-3; iron-bk; sectile; hot nit sol: Bl, fus I I sulph and antim fumes; on char, glob of silver. Silver ores. native bismuth, 220. " I; mas, cleav I G 9-7 —98; silver-w rdh; nit sol, and solution w if diluted: Bl, fus I I volat, inod, yw on char. Prim. Vitreous copper, 292. 2'5-3-0 III; mas; G 5-5 —58; bkh, lead-gy; nit sol, and polished iron put in the solution covered with copper: Bl, fus I on char sulph fumes. Prim, strat. Galena, 277. 25-3-0 I; cleav mas; G 7-5-7-7; pure lead-gy; rather sectile: Bl, fus! decrep; on char sulph fumes and glob of lead. Prim, strat. Amalgam, 287. 2-0-3-5 I; mas; G 10'5-14; silver-w; nit sol: Bl, fumes of mercury, and silver glob. Native antimony, 222 3-0-35 VI; cleav; lam, mas; G 6-6-6-8; tin-w: Bl, fus I volat; on char w fumes. Prim. Native arsenic, 225. 3-5 VI; mas; G 5-6 —5-8; tin-w, lead-gy, darker from tarnish; brittle: B1, wholly volat, garlic odol. Prim. Gray copper, 295. 3-0-4-0 I; tetrahed; mas; G 4-7 —5-1; steel-gy to iron-bk. Bl, fus I I arsen and antim fumes; copper reaction. Prim, copper ores. White nickel, 263. 5-0-5-5 I; mas; G 7.1-7-2; tin-w: Bl, arsen fumes; also nickel reaction. Prim. In determining the name of a mineral by the preceding table, trials should be made of the hardness and of the other characters upon which the arrangement is based, as shown in the general view on page 188. The particular subdi. vision containing the species is thus arrived at, and also, bymeans of the hardness, the place of the species in the sub. division. Afterwards, by a comparison of the other charac. ters, (specific gravity, color, etc.,) with the brief descriptions given in the table, the name of the mineral will be ascer. tained. If any doubt still remains, the fuller descriptions in the body of the work may be referred to, for the convenience of which reference, the page is added for each species. TABLE I. FOR DETERMINATION OF MINERALS. 429 The following hints may be of service to the beginner in the science, by enabling him to overcome a difficulty in the outset, arising from the various forms and appearance of the minerals quartz and limestone. Quartz occurs of nearly every color, and of various degrees of glassy luster to a dull stone without the slightest glistening. The common grayish cobble stones of the fields are usually quartz, and others are dull red and brown; from these there are gradual transitions to the pellucid quartz crystal that looks like glass itself. Sandstones and freestones are often wholly quartz, and the seashore sands are mostly of the same material. It is therefore probable that this mineral will be often encountered in mineralogical rambles. Let the first trial of specimens obtained be made with a file or the point of a knife, or some other means of trying the hardness; if the file makes no impression, there is reason to suspect the mineral to be quartz; and if on breaking it, no regular structure or cleavage plane is observed, but it breaks in all directions with a similar surface and a more or less vitreous luster, the probability is much strengthened that this conclusion is correct. The blowpipe may next be used; and if there is no fusion pro. duced by it, when carefully used on a thin splinter, there can be little doubt that the specimen is in fact quartz. Carbonate of lime (calc spar, including limestone,) is another very common species. If the mineral collected is rather easily impressible with a file, it may be of this species: if it effervesces freely when placed in a test-tube containing dilute muriatic acid, and is finally dissolved, the probability of its being carbonate of lime is increased: if the blowpipe produces no trace of fusion, but a brilliant light from the fragment before it, but little doubt remains on this point. Crystalline fragments break with three equal oblique cleavages. -Familiarized with these two Protean minerals by the trials nere alluded to, the student has already surmounted the principal difficulties in the way of future progress. Frequently the young beginner, who has devoted some time to collecting all the different colored stones in his neighborhood, on pre. senting them for names to some practised mineralogist, is a little disappointed to learn that, with two or three exceptions, his large variety includes nothing but limestone and quartz. He is perhaps gratified, however, at being told that he may call this specimen yellow jasper, that red jasper, another 430 TABLE II. FOR DETERMINATION OF MINERAL8. flint, and another hornstone, others chert, granular quartz, ferruginous quartz, chalcedony, prase, smoky quartz, greasy quartz, milky quartz, agate, plasma, hyaline quartz, quartz crystal, basanite, radiated quartz, tabular quartz, etc. etc.; and it is often the case, in this state of his knowledge, that he is best pleased with some treatise on the science in which all these various stones are treated of with as much prominence as if actually distinct species; being loth to receive the unwelcome truth, that his whole extensive cabinet contains only one mineral. But the mineralogical student has already made good progress when this truth is freely admit. ted, and quartz and limestone, in all their varieties, have become known to him. To facilitate still farther the study of minerals, the follow ing tables are added. TABLE II. FOR THE DETERMINATION OF MINERALS. The general arrangement in this table is the same as in the preceding: but the order of the species, instead of being that of their hardness, is that of their specific gravity. I.-SOLUBLE MINERALS. A. No EFFERVESCENCE WITH MIULATIC ACID a. Not deflagrating on burning coao Sp. gr. 8p. gr Glauber salt 1-4 —15 Copperas, 2-0 Sal ammoniac, 1-5-1-6 White vitriol, 2'0 —21 Epsom salt, 17 —1-8 Blue vitriol, 22 —2'3 Borax, " Common salt, " Alum, " White arsenic, 8-7 b Dflagrate on burning coa". Nit. of lime, 1-62 Nit. of soda, 2-0 —30 Niter. 1"9 2-00 TABLE II. FOI DETERMINATION OF MINERALS. 431 B. EFFERVESCING WITH MURIATIC ACID. Natron, 1'4-1*5 II.-INSOLUBLE MINERALS. 1. LUSTER UNMETALLIC. A. STREAK UNCOLORED. a. No fumes before the blowpipe on charcoal. I Wolly soluble in one or more of the acids, (cold or hot), usually with ifferveseeLnct * Infusible. Sp. gr. Sp. gr. Websterite, 1-6 —1 7 Magnesite, 2-9 —30 Brucite, 2-3-2-4 Mesitine spar. 3'3 —37 Nemalite, 2'3 —2-5 Diallogite, 3'5-3-6 Calc spar, " O;igon spar, 37 —3'8 Hydromagnesite, 2*8 Yttrocerite, A ragonite, 2'8 —30 Blende, 4'0 —41 Dolomite, 2-8-2-9 t Fusible with more or less difficulty. Wavellite, 2'3 —2-4 Triphyline, 3-4-3'6 Boracite. 2'9-3't) Strontianite, 36- 3-7 Apatite.:30 — 33 Spathic iron, 3-7-3*9 Fluor spar, 3'1- -32 WiLhe rite, 4'2 —44 Cacoxene, 3'3 —3'4 White lead ore, 61 —6*5 Triplite, 3-4 —38 Pyromorphite, 6'5 —71 2. Solube in acids, excepting the silica, which separtC ajU 4dy. * Inhlsible. Allophane, 1-8 —19 I Halloylite, 18 —2*1 t Fusible. Philippsite, 2'0-2'2 Mesole, 2-3-2'4 Analcime, 20 —2'3 Thomsonite, Datholite, " Sodalite, 2-2-2'5 Natrolite, 2'1 —23 Pectolite, 2'69 coolecite, 2'2 —2*3 Tabular spar, 2'7-2*9 Laumonite, 2'2-24 Calamine, 32 —3'5 Dysclasite, " 3. Not mtd on by acids, or partially soluble without forming fjelly. * Infusible. Chrysocolla, 2'3 —24 1 Yenite, 2-4-5.2 432 TABLE II. FOR DETERMINATION OF MINERALS Sp. gr. Sp. gr Opal, " Topaz, 3'4-3-6 Quartz, 2-6 —28 Dianond, 3'4-3-7 Alum-stone, " Kyanite, 3 5-3-7 Talc, 2-7 —29 Staurotide, 35 —3- 8 Pyrophyllite, " Chrysoberyl, 3-5F-3-8 Mica, 28 —3-0 Anatase, 38 —3 9 Turquois, " Sapphire, 3-9 —4-2 Nephrite, 2-9 —31 Blende, 40 —4 1 Andalusite, 29 —3-2 Spinel, 35 —4-6 Emerald nickel, 3*05 Zircon, 4*4 —48 Clintonite, 30 —3-1 Monazite, 4-8 —5'1 Sillimanite, 30 —3-4 Plumbo-resinite, 6-3 —64 Bucholzite, 3*2 —36 Tin ore, 6-5-7*1 Chrysolite, 83-33-6 t Fusible with more or less difficulty. Chabazite, 2 —2-22 Prehnite, 28 —3'0 Stilbite, 2-1-2'2 Boracite, 2-9 —30 Heulandite, 2'2 Chrysolite, " Gypsum, 2 —2-4 Euclase, 2-9 —31 Apophyllite, 23 —2-4 Hornblende, 2-9-3-4 Feldspar, 23 —2-6 Lazulite, 30 —3-1 Serpentine, 2'4 —26 Tourmaline, Obsidian, 2'2-2-8 Spodumene, 3-1-3-2 Harmotome, 2'3 —25 Chondrodite, " Petalite, 2'4-2-5 Axinite, 3'2 —33 Schiller spar, 2*5 —27 Pyroxene, 31 —3-5 Lapis Lazuli, 2'5-2*9 Sphene, 3-2 —35 Albite, 2*6 —2*7 Epidote, Labradorite, 2'6-2-8 Idocrase, 3*3-3'4 Scapolite, " Manganese spar, 3'4-3'7 lolite, " Garnet, 35 —4-3 Beryl, " Celestine, 38 —4-0 Chlorite, 2*6 —29 Pyrochlore, 3'8 —4-3 Chlorophyllite, 2*7-2*8 Heavy spar, 43 —4*8 Talc, 2'7 —29 Monazite, 4-8-5i1 Mica, 28 —3'0 Tungstate of lime, 6-0 —6* 1 Anhydrite, " Anglesite, 6'2-6'3 b. Colored or odorous fumes before the blowpipe. Scorodite, 3-1 —33 Horn silver, 55 —5'6 Blende, 4'0 —4-1 Bismuth blende, 5-9-6-1 Calamine, 4-2 —45 Mimetene, 6 4 —6'5 TABLE II. FOR DETERMINATION OF MINERALS. -1t4 B. STRBAK COLONBD. a. No fumes befor thc blovp. * Fusible. sp. Br. Sp. gr. Vivianite, 26 —2-7 Pyrochlore, 42 —4*3 Uranite, 3'0 —3'6 Minium, 4-6.hondrodite, 3'1 —33 Monazite, 4-8 —51 Allanite, 3'2 —41 Cupreous anglesite, 5-3 —5 rriplite, 34 —3*8 Red copper ore, 5'9-6*0 Azurite, 3*5-3'9 Chromate of lead, 6*0 Green malachite, 40 —4-1 Pyromorphite, 68 —7*1 t Infusible. Sulphur, 2'07 Blende, 40 —4-1 Copper mica, 2'55 Psilomelane, 40 —4'4 Earthy cobalt, 2'2 —23 Rutile, 42 —4*3 Cobalt bloom, 2*9 —30 Chromic iron, 43 —4-5 Warwickite, 3'0 —33 Atacamite, 4*4-4*5 Dioptase, 3*2 —33 Red antimony, 4'4 —46 Cacoxene, 3'3 —34 Red zinc ore, 54 —5'6 Orpiment, 34 —3-5 Red silver ore, 5*4 —59 Realgar, 3'3 —37 Pitchblende, 6'47 Wad, 3*7 Tin ore, 65 —7*1 Black copper, Cinnabar, 8*0-8*1 Limonite, 39 —4*1 LUSTER METALLIC. A. STREAK UNCOLOBXD No fumes before the blowpipe on charcoaL Earthy cobalt, 2'2 —23 Specular iron, 4*5-5*3 Wad, 3*7 Pyrolusite, 4*8-5.0 Yenite, 3'8-4*1 Franklinite, 4*8-5*1 Arkansite, 3*85 Magnetic iron ore, 50 —5'1 Brown hematite, 3*9 —40 Columbite, 5'9 —61 Blende, 40 —4'1 Pitchblende, 6-47 Psilomelane, 4'0 —44 Wolfram, 71 —7'4 Manganite, 4'3 —44 Cinnabar, 810 —81 Chromic iron, 4*3-4-5 434 TABLE III. FOR DETERMINATIONOF MINERALlS t Fumes before the blowpipe. Copper pyrites, 40 —4-2 Nickel glance, 60 —62 Magnetic pyrites, 4-5 —47 Mispickel, 6'1 White iron pyrites, " Cobaltine, 6*2-6*4 Iron pyrites, 4*8-5*1 Smaltine, 6*4-7*2 Variegated copper, 5'0-5*1 Leucopyrite, 7-2-7*4 Dark red silver, 5*7 —59 Copper nickel, 73 —7'7 B. STRBAK METALLIC. * Malleable. Sp. gr. Sp gr. Native iron, 7'3 —7*8 Native lead, 11-12 Native copper, 85 —8'6 Native mercury, 13-14 Native silver, 10-11 Native platinum, 16-19 Native palladium, 10-12 Native gold, 12-20 t Not malleable: no fumes when heated. Graphite, 2-21 l Ilmenite, 444-48 I Not malleable: fumes when heated on charcoal. Gray antimony, 45 —4'7 Native antimony, 66 —6*8 Molybdenite, 4-5-4-8 Fol. tellurium, 7 0-7*1 Gray copper, 4*7 —51 White nickel, 71 —7*2 Vitreous copper, 55 —5*8 Vitreous silver, 7 1 —74 Native arsenic, 5-6 —58 Galena, 75 —7-7 Native tellurium, 5'7 —61 Native bismuth, 97 —9-8 Brittle silver, 6'2 —63 Amalgam, 10*5-11 TABLE III.-MINERALS ARRANGED ACCORDING TO THEIR CRYSTALLIZATION. 1.-CRYSTALS MONOMETRIC. A. Luster unmetallic. * Infsible. Hardness. Sp. gr. Cleavage. Blende, 269 20 —3-0 4'0 —42 Dodecahedral. Chromic iron, 241 5'5 4'3-4*5 Octahed. imperf Leucite, 175 5'5-6-0 2-4 —25 Ncne. Dysluite, 161 7,5 —8*0 4-5-4*6 Oct. imp. Spinel, 160 8-0 3*5 —36 Oct. imp. Diamond, 80 10'0 Oct. perfect. TABLE III. FOR DETERMINATION OF MINERALS. 435 t Fusible. Hardness. Sp. gr. Cleavage.. A.m, 127 1'5-2-0 1'7 —1'8 Oct. Common salt, 104 2'0 2-2 —23 Cubic. Red copper ore, 296 3'5 —40 5-8 —61 Oct. imperf. Fluor spar, 121 4'0 3-0 —33 Oct. perf. Pyrochlore, 208 5-0 —55 3-8 —45 None. Analcime, 168 " 2-0 —23 Imperfect. Lapis Lazuli, 196 55 —6-0 2-5 —29 Dodec. imperf. Sodalite, 197 5*5 —60 2-2 —24 podec. imp. Garnet, 184 6-5 —75 3-5-4-3 Dod. oft. distinct Boracite, 126 7'0 2-9 —30 Oct. indistinct. 2.-Luster metallic. * No fumes before the blowpipe on charcoal. Native copper, 290 2'5 —30 84 — 8-8 None. Native silver, 323 " 103 —10'5 None. Native gold, 312 " 12'0-20'0 None. Blende, 269 3'5 —40 4'0- 4'2 Dodec. perf! Native platinum, 308 4'0 —45 16'0-19'0 Cubic, indist. Native iron, 230 4-5 5 1- 5-2 Oct. perfect. Chromic iron, 241 5*0-5-5 4'3- 4.5 Oct. imp. Franklinite, 240 5-5 —65 48 — 5*1 Oct. imp. Magnetite, 235 " 5'0- 5*1 Oct. imp. t Fumes before the blowpipe on charcoal Vitreous silver, 325 2-0 —25 7'1 —74 Dodec. imperf. Native bismuth, 220 " 9-7- 98 Oct. perf! Native amalgam, 287 2'0- 35 10*5-14 Dodec. imp. Erubescite 294 2'5 —30 50 —5*1 Oct. imp. Galena, 277 " 75 —7-7 Cubic perf! Gray copper ore, 295 3-0 —40 4'7 —52 Indistinct. Nickel glance, 253 50 —5-5 60- 6-2 Cubic perf! Cobaltine, 266 " 6'1 —63 Cubic perf. Smaltine, 266 " 6'3 —64 Oct. imp. White nickel, 263 5'5 7'1-7-2 Pyritea, 231 6-0 —65 48 —5*1 Cubic inp. II-CRYSTALS DIMETRIC. 1. Luster unmetallic. * Infusible. &natase, 211 55- 6-0 38 —3-9 Oct. and basal..q5 436 TABLE III. FOR DETERMINATION OF MINERALS. Hardness. Sp. gr. Cleavage Tin ore, 214 6'0-7-0 6-5 —71 Indistinct. Zircon, 200 7*5 4-4 —48 Imperfect. t Fusible. Uranite, 228 2-0 —25 3-0 —36 Basal, perf!! Apophyllite, 165 4-5 —50 2-2 —24 Basal, perf! Scapolite, 180 5-0-6'0 25 —2-8 Lat. distinct. Idocrase, 184 6-0 —65 33 —3*5 Lat. indistinct! Rutile, 210 " 4-1 —43 Lat. imp. 2. Luster metallic. Foliated tellurium, 280 1'0 —15 70 —7*2 Foliated! Copper pyrites, 292 3*5 —40 4'1 —42 Indistinct. Hausmannite, 261 50- 5-5 4-7 —48 Basal, distinct Braunite, 261 6*0 —65 48 —4-9 Oct. distinct. MI. CRYSTALS TRIMETRIC. 1. Luster unmetallic. * Infusible. Talc, 143 1-0 —15 2'7 —29 Basal, foll! Aragonite, 118 3'5 —40 2'9 —30 Lat. imp. Red Zinc ore, 270 4'0- 45 54 —5*6 Basal, fol I! Chrysolite, 156 6-5 —70 33 —3'5 Lat. imp. Staurotide, 174 7'0-7-5 3-6-3-8 Indistinct. Andalusite, 174 7.5 3'1 —34 Indistinct. Topaz, 194 8'0 3-4 —36 Basal, perfectl Chrysoberyl, 199 8'5 3*5-3*8 Imperfect. Fusible: gelatinize in acids. Mesole, 167 3'5 2'3 —24 One perfect. Thomsonite, 167 4'5 2'2 —24 Two rect. perC Phillipsite, 168 4'0 —45 20 —2*2 Imperfect. Calamine, 272 4'5 —50 3'3 —35 Lat. perfect. Natrolite, 166 45 —5*5 21 —2*3 Lat. perf. Scole(ite, 167 5*0 —55 2*2-2*3 Imperfect. Fusible: not gelatizing; giving no odorous or colored fumes before st blowpipe. ralc, (some var.,) 143 1'0 —15 2*7 —29 Foliated!! Niter, 101 2'0 1'9 —20 Imperfect. Epsom salt, 124 20 —2-5 17 —1*8 One perfect. Cryolite, 132 " 2'9 —30 One prf;two TABLE III. FOR DETERMINATION OF MINERALS. 437 Hardness. Sp. gr. Cleavage. Mica, 193 " 2'8 —31 Foliated!! Anglesite, 281 2-5 —30 6*2-6-3 Imperfect. Heavy spar, 108 2-5-3-5 4-3 —48 Imperfect. Celestine, 110 " 3 —-4-0 Lat. distinct. Anhydrite, 114 3'0 —35 2-8 —30 Three rect.dist. White lead ore, 281 " 61 —6-5 Lat. perf. Witherite, 109 " 42 —4-4 Imperfect. Serpentine, 145 3'0 —40 2*5 —26 Sometimes fol, Strontianite, 111 3'5 —40 36 —3'8 Lat. distinct. Wavellite, 130 " 2'2 —2'4 Two distinct. Stilbite, 165 " 2*1-2*2 One perfect! Harmotome, 168 4*0-4'5 2'*4-25 Imperfect. Wolfram, 244 5'0 —55 7*1 —7'4 One perfect. Lazulite, 131 50 —6-0 3-0 — 31 Indistinct. Yenite, 245 5'5 —60 3-8-4*1 Indistinct. Prehnite, 170 6*0 —70 2*8 —30 Basal, distinct. Iolite, 190 7'0 —75 2*5-2'7 Indistinct. ~ Giving fumes before the blowpipe on charcoal Orpiment, 226 1'5 —20 3*4-3*6 Foliated! Sulphur, 98 1*5 —25 2*0 —21 Indistinct. White vitriol, 271 2-0 —25 2-0-2-1 One perfect. White antimony, 224 2*5 —30 5'5 —56 Lat. perfect!! Atacamite, 302 3'0 —35 4-0 —44 Basal, perfect. Scorodite, 249 3'5 —40 3'1 —33 Imperfect. 2. Luster metallic. * No fumes before the blowpipe on charcoaL Pyrolusite, 259 20 —2*5 4*8 —50 Three imperfect Manganite, 261 4'0-4*5 4*3 —44 One imperfect. Wolfram, 244 5'0 —55 71 —7*4 One perfect. Yenite, 245 5-5-6-0 3-8 —41 Indistinct. Columbite. 243 5-0-6*0 5'9- 61 Indistinct. Tantalite, 244 " 7'2 —80 Imperfect. t Fumes before the blowpipe on charcoal. Gray antimony, 222 2'0 4'5 —47 One perfect! Brittle silver ore, 326 2'0 —25 6*2 —63 Imperfect. Vitreous copper, 292 2'5 —30 5-5 —58 Lat. indistinct. Leucopyrite, 235 5'0 —5*5 7'2-7*4 One distinct. Mispickel, 234 5'0 —60 6'1 —62 Lat Imperfect. White iron pyrites, 233 6'0 —65 4'6 —49 Lat imperfect. 438 TABLE III. FOR DETERMINATION OF MINERALS. IV.-CRYSTALS MONOCLINIC. 1. Luster unmetallic. * Soluble. Hardness. Sp. gr. Cleavage. Natron, 103 1-0 —15 14 —1-5 Glauber salt, 102 1-5 —20 1-5 —20 Copperas, 246 2'0 1-8-1-9 One perfect. Borax, 107 2x0 —2-5 1-7 Lat. perfect. t Insoluble: no fumes before the blowpipe on charcoal Vivianite, 248 1'5 —20 26 —2-7 Basal, perfect Gypsum, 112 2*0 2*3 —24 Foliated! Mica, 191 2'0-2*5 2-8 —30 Foliated!! Heulandite, 164 3'5 —40 2'1-2-2 Foliated. Laumonite, 166 3'5 —40 2'3 One distinct. Green malachite, 298 " 4-0-4*1 Basal, perfect Azurite, 300 35 —4-5 35 —3*9 Lateral. Clintonite, 148 4-0 —50 3'0 —31 Foliated. Monazite, 206 5*0 4'8 —51 Basalt, perfect! Datholite, 142 55 —6'0 2-9 —30 Indistinct. Sphene, 211 " 3'2 —35 Indistinct. Hornblende, 152 50 —6*0 2'9 —34 Lat. perfect. Pyroxene, 150 " 3*2-3'5 Lat. distinct. Allanite, 207 " 3*3 —38 Indistinct. Feldspar, 176 6*0 2'3 —26 One prf; one imp Chondrodite, 157 6-0-6*5 3'1 —32 Indistinct. Epidote, 182 6'0-7-0 3'2 —35 Lat. imperf. Spodumene, 156 6'5 —70 3-1 —32 Lat. perfect. Euclase, 199 7*5 2*9 —31 Basal, perfect. t Fumes before the blowpipe. Cobalt bloom, 267-1 5- 20 2-9-3-0 Basal, perfect Realgar, 226 " 33 —3*6 Imperfect. Pharmacolite, 226 2'0-2'5 2-6-2*8 Basal, perfect!l Miargyrite, 327 " 5'2- 5'4 Lat. imperfect. 2. Luster metallic. Miargyrlte, 327 2'0-2'5 5'2 —54 Lat. imperfect. Wolfram, 244 5-0 —55 7'1-7-4 One perfect. Warwickite, 5'5 —60- 3'0 —33 One perfect. Allanite, 207 " 3*3-3'8 Imperfect. V.-CRYSTALS TRICLINIC. * Soluble. 97 2'5 2-2 —2*3 Imperfect. TABLE III. FOR DETERMINATION OF MINERALS. 43f t Insoluble: fusible. Hardness. Sp. gr. Cleavage. Albite, 177 6-0 2'6 —27 One perf.; two imperfect. Labradorite, 178 " 2'6 —28 One perf.; one imperfect. Manganese spar, 258 6'0 —70 3-4 —37 One perfect. Axinite, 190 6'5-7'0 3-2 —33 Imperfect. t Infusible. Kyanite, 173 5'0 —70 3'5- 37 Lat. distinct. Sillimanite, 172 7'0 —75 3'2- 33 Diagonalperf.!! 6. CRYSTALS HEXAGONAL OR RHOMBOHEDRAL. 1. Luster unmetallic. * Soluble. Nitrate of soda, 103 1'5 —20 2-0 —21 Rhomb. perf. Coquimbite, 256 " Hexag. imperf. t Insoluble: infusible. Brucite, 126 1'5 2'35 Foliated! Mica, (hexagonal) 193 20 —2'5 2'8 —31 Foliated!! Calc spar, 115 2-5-3-5 2'5 —28 Rhomb. perf! Diallogite, 261 3'5 3'5 —36 Rhombohedral. Magnesite, 124 3'0- 4'0 2-8-3-0 Rhomb. perf. Ankerite, 120 " 2'9 —32 Rhomb. perf. Dolomite, 118 3-5 —40:35 —40 Rhomb. perf. Spathic iron, 247 " 3'7 —39 Rhomb. perf. Alum stone, 129 5'0 2'6-2*8 Basal, near perf. Dioptase, 301 " 3*2-3'3 Rhombohedral. Quartz, 132 7'0 2'6-2'7 Imperfect. Sapphire, 158 9'0 3-9 Basal, perf. f Insoluble: fusible, without fumes. Chlorite, 145 1'5 —20 2-6-2'9 Foliated! Chabazite, 169 4'0 —45 2-0-2*2 Rhombohed.ma. Apatite, 120 5'0 3'0-3*3 Indistinct. Nepheline, 179 5'5 —60 2'4 —27 Imperfect. Tourmaline, 187 7'0 —80 3'0 —31 Indistinct. Peryl, 197 7'5-8-0 2 6-2-8 Basal, indistinct 35* 440 TABLE III. FOR DETERMINATION OF XINERALo. ~ Insoluble: mnmes before the blowpipe on charcoal. Hardness. Sp. gr. Cleavage. Red silver ore, 327 2-0-3-0 54- -59 Imperfect. Cinnabar, 287 2-0-2-5 7-8 —81 Hexag. perfeec Smithsonite, 272 5-0 4*3 —45 Rhomb. perf. 2. Luster metallic. * NO unes b, -'e the blowpipe on charcoal Graphite, 91 1-0 —20 20 —2-1 Foliated! Iimenite, 241 50 —6-0 4-4 —50 Indistinct. Specular iron, 237 5*5 —65 5'0 —53 Indistinct. t Fumes before the blowpipe on charcoal. Molybdenite, 217 1'0 —15 45 —4'8 Foliated!! Native tellurium, 219 2'0 —25 5'7 —61 Imperfect. Dark red silver, 327 2*5 57 —5'9 Imperfect. Cinnabar, 287 " 7'8 —81 Hexag. perfct. Native antimony, 222 3'0 —35 6'6 —6*8 Basal perficlt rhombohed. dist. Native arsenic, 225 3'5 5*6-6*0 Imperfect. Magnetic pyrites, 233 3'5 —4'5 4'6 —47 Basa) aexag. prf Copper nickel, 263 560 —55 7'3-7-7 INl)EX. A. Alunite, 129. Amalgam, Native, 28t. ACADIOLITE, 170. Amber, 93. Achmite, 156, (Acmite.) Amblygonite, 132. Acid, Arsenous, 226. Amethyst, 134. Boracic, 107. Oriental, 168. Carbonic, 93. Amianthus, 154, 146. Hydrochloric, 77. Ammonia, Salts of, 100. Muriatic, 77. Carbonate of 101. Sulphuric, 99. Muriate of, 100. Sulphurous, 99. Phosphate of, 101. Tungstic, 218. Sulphate of, 101. Acmite, 156. Ammoniac, Sal, 100. Actinolite, 153. Amphibole, 154. Adamant, 80, (Diamond.) Amygdaloid, 355. Adamantine spar, 158. Analcime, 168. Adularia, 176. Anatase, 211. LEschynite, 209. Ancramite, 276. Agalmatolite, 358. Andalusite, 174. Agaric mineral, 116, (Calc Tufa.) Andesin, 178. Agate, 136. Anglarite, 249. Alabandine, 261. Anglesite, 281. Alabaster, 113. Cupreous, 281. Alalite, 151. Anhydrite, 114. Albite, 176. Anhydrous sulphate of lime, 11 Alexandrite, 199. Ankerite, 120. Allagite, 258. Anorthite, 178. Allanite, 207, 183. Anthophyllite, 156. Allophane, 162. Anthosiderite, 245. Alluaudite, 249. Anthracite, 85. Almandine, 185. Anthraconite, 117. Alum, 127. Antigorite, 149. Manufacture of, 128, 129. Antirnonate of lime, 224. ALUMINA, 127, 158. Antimonial copper, 295. Alumina, Fluate of, 132. nickel, 263. Hydrate of, 131, 132. silver, 326, 327. Mellate of, 132. ANTIMONY, 222. Phosphate of, 130. Antimony, Native, 222. Sulphates of, 127, 128, 129. Arsenical, 223. Alum stone, 129. Feather ore of, 223. Alum slate, 128. Gray, 222. Aluminite, 129. Red, 224. Aluminium, Fluorid of, 132. Sulphuret of, 222. 442 INDEX. Antimony, White, 224. Aventurine feldspar, 17l Antimony and lead, sulphurets Axinite, 190. of, 223. Azure, 269. Antimli! olres, general remarks Azurite, 300. on,, 2 24. B. Antrimolite, 171. Apatelite, 247. Babintgtonite, 156. Apatite, 120. Balas i'tbly, 160. Aphanesite, 301. Baltimorite, 146. Aphrodite, 148. BARYTA, 108. Aplome, 186. Baryta, Carbonate of, 109. Apophyllite, 165. Sulphate of, 108. Aquamarine, 198. Sulphato-carbonate of, 110. Aragonite, 118. Baryt-Harmotome, 168, (Hlrz Arendalite, 182, (Epidote.) tome.) Argent, French for silver. Barytocalcite, 110. Argentine, 116. Basalt, 355. Argillaceous shale, 357 Basanite, 137. Argillite, 357. Bell metal, 307. Arkansite, 211. Bell metal ore, 213. Arquerite, 287. Beraunite, 249. &rsenate of iron, 249. Berengelite, 97. of nickel, 264. Beryl, 197. of cobalt, 267. Berthierite, 223. of copper, 301. Biddery ware, 276. of lime, 226. Biotite, 193. ARSENIC, 225. BISMUTH, 220. Arsenic, Native, 225. Bismuth, alloys of, 221. Sulphurets of, 226. Native, 220. White, 226. Acicular, 221. Arsenic ores, general remarks on; Carbonate of, 221. 227. Cupreous, 221. Arsenical cobalt, 266. Silicate of, 221. iron pyrites, 234. Sulphuret of, 220. lead, 280. Telluric, 221. manganese, 261. Bismuth blende, 221. nickel, 263. nickel, 264. silver, 327. ocher, 221. Arsenous acid, 226. Bismutite, 221. Asbestus, 151, 154. Bitter spar, 119, (Brown L29'k Asparagus stone, 120. Bitumen, 95. Aspasiolite, 163. Elastic, 94. Asphaltum, 95. Bituminous coal, 86. Asteria, 158. Black copper, 298. Atacamite, 302. cobalt, 267. Atmospheric air, 76. lead, 91. Augite, 150, 151. Black jack, 270. Aurichalcite, 273. Blei, German for lead. Auriferous pyrites, 232, 313. Blende, 269. Aurotellurite, 323. Bloodstone, 137. Automolite, 161. Blue asbestus, 246. Aventurine quartz, 134. copper ore, 300, 292. INDEX. 443 Blue iron earth, 249. C. malachite, 300, (azurite.) spar, 131, (Lazulite.) Cacholong, 139. vitriol, 297. Cacoxene, 249. Bodenite, 208. Cadmia, 276. Bog iron ore, 239. CADMIUM, 276. manganese, 260. Cairngorum stone, 134. Bole, 162. Calaite, 130, (Turquois.) Boltonite, 157. Calamine, 272. Bones, composition of, 120 Electric, 272. Boracic acid, 107. (Calcareous spar, 115. Boracite, 126. tufa, 116. Borate of lime, 123. Calcedony, 135. of soda, 107. Calcite, 115. of magnesia, 126. Caledonite, 283. Borax, 107. Callais, 131. Borosilicate of lime, 142. Canaanite, 180, (Scapolite.) Botryolite, 142. Caoutchouc, mineral, 94. Boulangerite, 223. Capillary pyrites, 264. Bournonite, 295. CARBON and compounds of car. Branchite, 97. bon, 80. Brass, 275, 307. Carbonic acid, 93. Braunite, 261. Carbuncle, 187. Breccia, 360. Carburetted hydrogen, 77. Breccia marble, 366. Carburet of iron, 91. Breislakite, 157. Carnelian, 135. Breunnerite, 248. Carpholite, 171. Brevicite, 167. Carphosiderite, 249. Brewsterite, 164. Castor, 182. Britannia metal, 225. Catlinite, 358. Brittle silver ore, 326. Cat's eye, 136. Brocatello di Siena, 365. Celestine, 110. Brochantite, 298. Cerasite, 285. Bromic silver, 828. Cerine, 207. Bromlite, 110. Cerite, 207. Bronze, 307. CERIUM, ores of, 206. Bronzite, 151 Cerium, Carbonate of, 206 Brookite, 211. Phosphate of, 207. Brown iron ore, 239. Silicate of 207. hematite, 239. Cerium ocher, 206. ocher, 239. Cerusite, 281. spar, 119, 248 Chabazite, 169. Brucite, 126. Chalcedony, 135 see Chondrodite, 157. Chalcolite, 229. Bucholzite, 172. Chalk, 116. Bucklandite, 183. Red, 237. Buhrstone, 359, 360. Chalybeate waters, Building stone, 352, 353, 355, Chalybite, 247. 361. Chamoisite, 245. Buratite, 273, 302, (Aurichalcite.) Chathamite, 263. Bustamite, 258. Chessy copper, 300, (Azurite. Bytownite, 178. Chiastolite. 174. 444 INDEX. Childrenite, 132. Cobalt, Arsenite of, 268. Chiolite, 132. Black oxyd of, 267. Chlorite, 1-5. Earthy, 267. Chlorite slate, 354. Red, 268. Chlorite rock, 354. Sulphate of, 268. Chloritoid, 172. Sulphuret of, 267. Chloropal, 245. Tin-white, 266. Cilorophane, 122. White, 266. Chlorophyllite, 162. Cobalt bloom, 267. Chlorospinel, 160. mica, 267, (Cobalt bloom.) Chondrodite, 157. ocher, 268. Chromate of lead, 284. pyrites, 267. of lead and copper, 285. Cobalt Ores, gen. remarks on, 26& Chrome salts, manufacture of, 242. Cobaltic lead ore, 280. Chrome yellow, 242. Cobaltine, 266. Chromic iron, 241. Coccolite, 151. ocher, 262. Colcothar, 233, 246. CHROMIUM, 262. Colophonite, 186. Chrysoberyl, 199. Columbite, 243. Chrysocolla, 300. Comptonite, 167. Chrysolite, 157, 245. Condurrite, 302. Iron, 245. Conglomerate, 360. Chrysoprase, 135. Copal, Fossil, 97. Cimolite, 162. COPPER, 290. Cinnabar, 287. Copper, Alloys of, 306 Cinnamon stone, 185. Antimonial, 295. Cipolin marbles, 365. Arsenates of, 301. Clausthalite, 280. Arsenical, 295. Clay, 368. Carbonates of 298, 300. for bricks, 371. Chlorid of, 302. for pottery, 372. Muriate of, 302, (Chlorid.) Clay slate, 357. Native, 290. Clay Iron Stone, 237, 239, 247 Oxvds of, 296. Cleavelandite, 178. Phosphates of, 302. Clinkstone, 356. Pyritous, 292. Clintonite, 148. Selenid of, 296. Cloanthite, 263. Silicate of, 300, 301. Coal, mineral, 85. Sulphate of, 297. Anthracite, 85. Sulphato-chlorid of, 302. Bituminous, 85. Sulphurets of, 292. Brown, 86. Copper froth, 301. Caking, 85. glance, 292. Cannel, 86. mica, 301. Cherry, 85. nickel, 263. Glance, 85. pyrites, 292, 294. Splint, 86. uranite, 228. Stone, 85. Copper ore, Black, 296. Wood, 86. Blue, 292. Coal measures, 86. Gray, 295. COBALT, 266. Octahedral, 296, (Red cop Cobalt, Arsenate of, 269 per.) Arsenical, 266. Red, 296. INDEX. 4 Copper ote, Variegated, 294. Dioxylite, 28H. Velvet, 302. Diphanite, 171. Vitreous, 292. Dipyre, 181. Copper ores, gen. remarks on, 302 Disthene, 173. Assay of, 302. Dog tooth spar, 115. Reduction of, 303. Dolerite, 355. Copperas, 246. Dolomite, 118. Manufacture of, 232. Domeykite, 296. Coquimbite, 246. Dreelite, 110. (Cracite, 228. Dufrenoysite, 280. Cordierite, 190. Dysclasite, 142. Cork, Mountain, 154. Dysluite, 161. Corneous lead, 285 Dysodile, 97. Corundum, 158. Cotunnite, 285. Couzeranite, 179. Earthy cobalt, 267. Covelline, 292. manganese, 260. Crichtonite, 241. Edelforsite, 143. Crocidolite, 246. Edingtonite, 171. Crocoisite, 284. Edwardsite, 206, (Monazite.) Cronstedtite, 245. Egeran, 184. Cross stone, 174, (Staurotide.) Eisen, German for Iron. Cryolite, 132. Elaeolite, 180. Cryptolite, 207 Elastic bitumen, 94. Cuban, 294. Electric calamine, 272. Cube ore, 249. Eliasite, 228. Cube spar, 114, (Anhydrite.) Embolite, 328. Cuivre, French for Copper. Emerald, 197. Cummingtonite, 156. Oriental, 158. Cupreous anglesite, 281. Emerald Nickel, 264. Cyanite, (Kyanite,) 173. Emery, 158. Cymophane, 200. Enceladite, (Warwickite,) 212. Cyprine, 184. Epidote, 182. D. Epistilbite, 171. Epsom salt, 124. Damourite, 172. Manufacture of, 119,124,121 Danaite, 234. Eremite, 206, (Monazite) Danburite, 143. Erinite, 301. Datholite, 142. Erubescite, 294. Davyne, 179, (Nepheline.) Erythrine, 267. Derbyshire spar, 122. Erz, German for ore. Dermatine, 149. Esmarkite, 191. Deweylite, 145, (Serpentine.) Essonite, 185. Diallage, 151. Etain, Fr. for tin. Diallage rock, 355. Eucairite, 327. Diallogite, 261. Euchroite, 301. Diamond, 80. Euclase, 199. Diaspore, 132. Eudialyte, 202. Dichroite, 190. Euphotide, 355. Diopside, 150. Euphyllite, 171. Dioptase, 301. Eupyrchroite, 120. Diorite, 355. Euxenite, 208. 38 446 INDEX. F. I Gibraltar rock, 366. Gieseckite, 180. Fahlerz, 295, (gray copper.) Gigantolite, 163. Fahlunite, 162 Girasol, 139. Fassaite, 151. Gismondine, 168. Faujasite, 171. Glance cobalt, 266, (Cobalt.x.) Feather alum, 128 Glauberite, 108. Feather ore, 223. Glauber salt, 102. Feldspar, 176. Glaucolite, 181. Feldspar, Glassy, 176, 177. Glimmer, G(erm. for mica. Labrador, 178. Glottalite, 171. Fer, French for iron. GLUCINA, 197. Fergusonite, 208. Gneiss, 353. Ferrotantalite, 244. GOLD, 313. Fettbol, 162. Gold, cupellation of, 322. Fibro-ferrite, 246. Gong, Chinese, 307. Fibrolite, 172, (Bucholzite.) Gothite, 240. Fichtelite, 97. Gouttes d'eau, 195. Figure stone, 359. Grammatite, 153. Flagging stone, 353, 362. Granite, 351. Flint, 136. Granulite, 351. Float stone, 137. Graphic granite, 351. Flos Ferri, 118. tellurium, 323, (Aurntellu Flucerine, 206. rite.) Fluellite, 132. Graphite, 91. Fluor spar, 121. Gray antimony, 222. Foliated tellurium, 280. copper ore, 295. Fontainebleau limestone, 116. Graystone, 355. Forsterite, 157. Green diallage, 151. Fossil copal, 97. earth, 245. wood, 138, 366. iron stone, 249 Franklinite, 240. malachite, 298. Freestone, 361. sand, 245. Fuchsite, 193. vitriol, 246. Fuller's earth, 360. Greenockite, 276. Fusible metal, 221. Greenovite, 212. ^~G. ~ Greenstone, 355. Grengesite, 245. Gadolinite, 208. Grit rock, 360. Gahnite, 161, (Automolite.) Groppite, 162. Galena, 277. Grossularite, 185. Galmey, 272, (Calamine.) Grtanauite, 264. Garnet, 184. Guanite, 101, (Struvite. Tetrahedral, 187, (Helvin) Gurhofite, 119. White, 175, (Leucite.) Guyaquillite, 97. Gay Lussite, 108. Gypsum, 112. Gehlenite, 181. Anhydrous, 114. Genesee oil, 96. Gyrasol, 139. German silver, 265. Gersdorffite, 263. Geocronite, 223. Haematite, 237, 239. Gibbsite, 131. Haidingerite, 226. INDEX. 447 Hair salt, 124. L Halloysite, 160. Iberite, 163. Harmotome, 168. Ice, 78. Harringtonite, 167. Ice spar, 176, 178. Harrisite, 292. Iceland spar, 116. Hartite, 97. Ichthyophthalmite, 165, (Apo Hatchetine, 97. phyllite.) Hauerite, 261. Idocrase, 184. Hausmannite, 261. Ildialin, 97. Hauyne, i96. Ilmenite, 241. Haydenite, 170. Ilvaite, 245. Hayesine, 123. Indicolite, 188. Heavy spar, 108. lodic silver, 328. Hedenbargite, 151, 245. mercury, 289. Hedyphane, 284. Iolite, 190. Heliotrope, 137. Hydrous, 163. Helvin, 200. Iridium, 310. Hematite, Brown, 239. Iridosmine, 310. Red, 237. IRON, 229. Hercinite, 161. History of, 250. Herschelite, 170. Manufacture of, 251 Heteroclin, 260. Iron, Arsenates of, 249. Heterosite, 261. Arsenical, 234. Heulandite, 164. Carbonate of, 247. Hisingerite, 245. Carburet of, 9i. Hone slate, 353, 354, 358. Chromate of, 241. Honey stone, 132. Columbate of, 243. Hopeite, 273. Hematitic, 237, 239. Horn quicksilver, 288. Hydrous oxyd of, 239. silver, 327. Meteoric, 230. Hornblende, 152. Native, 230. Hornblende slate, 353. Oligiste, 237. Hornstone, 136. Oxalate of, 249. Houille, Fr. for coal Oxyds of, 235, 237, 239. Hudsonite, 151. Phosphate of, 248. Humboldtilite, 181. Silicates of, 245. Humite, 158. Sparry or spathic, 247. Huraulite, 261. Specular, 237. Hyacinth, 201, 189. Sulphate of, 246. Hyalite, 140. Sulphurets of, 231. Hydraulic limestone, 366 Titanic, 241. Hydroboracite, 123. Tungstate, 244. Hydrochloric acid, 77. Iron chrysolite, 245. Hydrogen, Iron earth, Green, 249. Carburetted, 77. Blue, 249. Phosphuretted, 77 Iron furnace, 252. Sulphuretted, 77. Iron mica, 248, (Vivianite.) Hydromagnesite, 125 Iron ores, general notice of, 250 Hydrophane, 139. Assay of, 251. Hydrotalcite, 329. Reduction of, 251. Hypersthene, 151. Iron ore, Argillaceous, 237 23S Hystatite, 241. 247. 448 INDEX. Iron ore, Axotomous, 241, (II- Kerolite, 146. menite.) Kiesel, Germ. for silica Bog, 239. Kilbrickenite, 223. Brown, 239. Kirwanite, 245. Chromic, 241. Knebelite, 245, 259. Green, 249. Kobalt, see Cobalt. Jaspery, 237. Kobellite, 223. Lenticular, 237. Kollyrite, 162. Magnetic, 235. Konigite, 298. Micaceous, 237. Konlite, 97. Ochreous, 237, 239. Kraurite, 249. Octahedral, 235. Krisuvigite, 298. Pitchy, 260, (Triplite.) Kupfer, Germ. for copper. Red, 237. Kyanite, 173. Rhombohedral, 237, (Specu- L. lar.) Labradorite, 178. Spathic, 247. Labrador feldspar, 178. Specular, 237. hornblende, 151. Titanic, 241. Lanthanite, 206. Iron pyrites, 231. Lapis Lazuli, 196. Arsenical, 234. Latrobite, 179. Auriferous, 232. Laumonite, 166. Hepatic, 233. Lava, 356. Magnetic, 233. Lazulite, 131. White, 233. LEAD, 276. Iron sinter, 249. Lead, Arsenate of, 284. Iron stone, Clay, 237, 239, 247. Arsenids of, 280. Blue, 230. Carbonate of, 281. Iron zeolite, 246. Chlorid of, 285. Iserine, 241. Chromate of, 284. Isopyre, 245. Molybdate of, 285. Itacolumite, 359. Muriate of, 285. Ixolyte, 97. Native, 277. J. Oxyd of, 280. Jade, 147. Phosphate of, 283. Jamesonite, 223. Selenate of, 285. Jargon, 201. Selenids of, 280. Jasper, 137. Sulphate of, 281. Jaspery iron ore, 237. Sulphato-carbonates of, 288 Jeffersonite, 154. Sulphuret of, 277. Jet, 86. Tellurids of, 280. Johannite, 229. Tungstate of, 285. Junkerite, 248. Vanadate of, 285. K.Z~ ~ Lead glance, 277, (Galena.) Leadhillite, 283. Kakoxene, 249. Lead ore, Argentiferous, 277. Kalk, Germ. for lime. Cobaltic, 280. Kammererite, 149. Red, 280. Kaolin, 177, 372. White, 281. Karpholite, 171. Yellow, 285, (Molybdate.) Karphosiderite, 249. Lead ores, general remarks en, Keilhauite, 212. 285 INDEX. 449 Ledererite, 169. Magnesia, Borate of, 12o. Lederite, 212. Carbonate of, 124, 125. Leonhardite, 166. Fluophosphate of, 127. Lepidokrokite, 240. Fluosilicate of, 157, (Chon Lepidolite, 192. drodite.) Lepidomelane, 193. Hydrate of, 126. Leptynite, 351. Hydro-carbonate of, 125. Leucite, 175. Native, 126, (Brucite.) Leucophane, 200. Nitrate of, 126. Leucopyrite, 234. Silicates of, 143. Levyne, 169. Sulphate of, 124. Libethenite, 302. Magnesia alum, 128. Lievrite, 245. Magnesian limestone, 118. Lignite, 86. Magnesite, 124. LIME, 112, 141. Magnet, Native, 236. Lime, Arsenate of, 305. Magnetic iron, (Magnetite,) 235 Borate of, 123. pyrites, 233. Borosilicate of, 142. Malachite, Blue, 300, (Azurite.) Carbonate of, 115, 118. Green, 298. Fluate of, 121. Malacolite, 150. Fluorid of, 121. Malacone, 202. Magnesian carbonate of, 118. Maltha, 95. Nitrate of, 123. Malthacite, 162. Oxalate of, 123. Manganblende, 261. Phosphate of, 120. MANGANESE, 258. Silicates of, 141, 142. Manganese, Arseniuret of, 261. Sulphate of, 112, 114. Bog or Earthy, 260. Tungstate of, 219. Carbonate of, 261. Vanadate of, 219. Oxyds of, 259, 261. Limestone, 116, 363. Phosphate of, 260. Hydraulic, 117, 366. Silicate of, 258. Magnesian, 118. Sulphuret of, 261. Fontainebleau, 116. Manganese ores, general remarks Limestone, burning of, 367. on, 261. Limekilns, 367. Manganese spar, 258. Limonite, 239. Manganite, 261. Lincolnite, 164. Marble, 363, 364, 365, 36 Linnseite, 267. Marcasite, 231, (Pyrites.) Liroconite, 301. Marceline, 260. Lithia mica, 192. Marekanite, 357. Lithographic stone, 10. Margarite, 171. Lithomarge, 371. Margarodite, 193. Liver ore of mercury, 288. Marl, 370. Lodestone, 236. Marmatite, 269, (Blende.) Loxoclase, 176. Marmolite, 146. Lumachelle, 366. Martinsite, 107. Lydian stone, 137. Mascagnine, 101. Masonite, 172. M. Meerschaum, 148. Made, 174. Meionite, 181. Maclurite, 157, (Chondrodite.) Melanchlor, 249. MAGNESIA, 123, 143. Melanite, 185. 38* 4I) INDEX. Melanochroite, 284. Mountain green, 298, (Green Mal Mellate of alumine, 132. achite.) Mellilite, 181. cork, 154. Mellite, 132. leather, 154. Menaccanite, 241. Mowenite, 167. Mendipite, 285. Mullers glass, 140. Menilite, 140. Mullicite, 249. MERCURY, 287. Mundic, 233. Mercury, Chlorid of, 288. Muriacite, 114. Mercury, Iodic, 289. Muriatic acid, 77. Muriate of, 288, (Chlorid.) Murchisonite, 176, (Feldspar.) Native, 287. Muscovite, 191. Selenid of, 289. N Sulphuret of, 287. Mercury ores, general remarks on, Nacrite, 193. 289. Naphtha, 95. Mesitine spar, 248. Natrolite, 166. Mesole, 167. Natron, 103. Mesotype, 167. Necronite, 177. METALS, 202. Needle ore, 221, (Acicular Bi, Meteoric iron, 230 muth. Miargyrite, 323. Needlestone, 167, (Scolecite.) Mica, 191. Nemalite, 125. Mica slate, 353. Nepheline, 179. Micaceous iron ore, 237. Nephrite, 147. Microlite, 208. NICKEL, 262. Middletonite, 97. Nickel, Antimonial, 263. Miemite, 119. Alloys of, 265. Millerite, 264. Arsenate of, 264. Millstone grit, 360. Arsenical, 263. Miloschine, 262. Bismuth, 264. Mimetene, 284. Copper, 263. Mineral caoutchouc, 94. Oxyd of, 2'64. oil, 95. White, 263. pitch, 95. Nickel glance, 263. tallow, 97. green, 264. tar, 95. ocher, 264. waters, 80. pyrites, 264. Minium, 280. stibine, 263. Mispickel, 234. Nickel ores, general remarks, Mocha stone, 135. 264. Molybdate of lead, 285. Nigrine, 210. Molybdenum, Sulphuret of, 217. Nitrate of lime, 123. Molybdenite, 217. magnesia, 126. MOLYBDENUM, 217. potash, 101. Molybdic ocher, 218. soda, 103. Monazite, 206. Niter, 101. Monradite, 149. Nitrogen, 76. Moonstone, 176. Nontronite, 246. Moroxite, 120. Nosean, 196. Mosaic gold, 217. Novaculite, 358. Mosandrite, 207. Nuttallite, 181. MNDEX. 461 O. Phenacite, 200. Phillipsite, 168. Obsidian, 857. Phlogopite, 193. Ocher, Red, 237. Pholerite, 162. Brown or yellow, 239. Phonolite, 356. Cerium, 206. Phosphorite, 120. Plumbic, 280. Phosphuretted hydroger., 77. Uranic, 228. Photizite, 258. Chromic, 262. Phyllite, 193. Octahedrite, 211, (Anatase.) Physalite, 194. CErstedite, 202. Piauzite, 97. Oil, Genesee or Seneca, 96. Pickeringite, 129. Mineral, 95. Picrolite, 146. Okenite, 142. Picrophyll, 331. Oligiste iron ore, 237. Picrosmine, 149. Oligoclase, 179. Pimelite, 264. Oligon spar, 248. Pinchbeck, 307 Olivenite, 301. Pinguite, 245. Olivine, 156. Pinite, 162. Onyx, 136. Pipe clay, 372. Oolite, 116. Pipestone, 358. Opal, 139. Pisolite, 116. Ophite, 145, (Serpentine.) Pistacite, 183. Ores, general remarks on, 202. Pitchblende, 228. Orpiment, 226. Pitchstone, 357. Orthite, 207. Pitchy iron ore, 260, (Triplit.,) Orthoclase, 176. Pittizite, 246. Ottrelite, 193. Plagionite, 302. Ouvarovite, 185. Plasma, 136. Oxalate of iron, 249. Plaster of Paris, 114. Ozarkite, 167. Platin-iridium, 310. Ozocerite, 97. PLATINUM, 308. ~~P. ~ Pleonaste, 160 Plumbago, 91. Packfong, 265. Plumbic ocher, 280. Paisbergite, 259. Plumbo-calcite, 117. PALLADIUM, 311. Plumbo-resinite, 285. Pargasite, 154. Polybasite, 327. Parisite, 206. Polycrase, 209. Peastone, 116, (Pisolite.) Polyhalite, 127. Pearl spar, 119. Polyhydrite, 245. Pearlstone, 357. Polylite, 151. Pectolite, 142. Polymignite, 209. Peloconite, 261. Poonahlite, 167. Pennine, 149. Porcelain, manufacture of, 872 Periclase, 149. Porcelain clay, 372. Peridot, 156, (Chrysolite.) Porcelain jasper, 137. Perofskite, 212, Porphyry, 356. Petalite, 182. Porphyritic granite, 351. Petroleum, 95. Potash, Nitrate of, 101. Phacolite, 170. Potash, Salts of, 101. Dharmacolite, 226. Potassium, Chlorid of 102. 452 INDEX. Potstone, 143, 355. Quartz, Tabular, 137 Potter's clay, 372. Quartz rock, 359. Pottery, manufacture of, 372. Quicklime, 117, 366. Pozzuolana, 355, 367. Quicksilver, 287. Prase, 134. Chlorid of, 288. Prehnite, 170. Horn, 288. Proustite 327, (Red silver.) Quincite, 148. Pseudomalachite, 302. R Pseudomorphs, Steatitic, 149. Psilomelane, 259. Realgar, 226. Pudding stone, 360. Red antimony, 224. Pumice, 357. chalk, 237 Purple or variegated copper, 294. cobalt, 267. Pycnite, 194. copper ore, 296. Pyrenaite, 185. hematite, 235. Pyrites, Arsenical Iron, 234. iron ore, 235. Auriferous, 232. lead, 280. Capillary, 264. silver ore, 327. Cockscomb, 233. zinc ore, 270. Copper, 292. Reddle, 237, (Red chalk. Hepatic, 233. Rensselaerite, 144, 149. Iron, 231. Retinalite, 149. Magnetic, 233 Retinasphalt, 95. Nickel, 264. Retinite, 95. Radiated, 233. Rhoetizite, 173. Spear, 233. Rhodium gold, 311. Tin, 213 Rhodizite, 127. Variegated copper, 294. Rhodonite, 258. White iron, 233. Rhomb spar, 119, 248. Pyrochlore, 208. Ripidolite, 145. Pyrodmalite, 246, (Pyrosmalite.) Rock or mountain cork, 154 Pyrolusite, 259. crystal, 133. Pyromorphite, 283. milk, 116. Pyrope, 187. salt, 104. Pyrophyllite, 149. soap, 162. Pyrophysalite, 194. ROCKS, general remarks on, 840 Pyrorthite, 207. Expansion of, 350. Pyrosclerite, 149. Roofing slate, 357. Pyrosmalite, 246. Rose quartz, 134. Pyroxene, 150. Roselite, 268. Pyrrhite, 212. Rosite, 162. Rubellite, 188. Q^~& ~ Rubicelle, 160. Quartz, 132. Ruby, Spinel, 160. Amethystine, 134. Almandine, 160. Aventurine, 134. Balas, 160. Ferruginous, 135. Oriental, 158. Granular, 137, 359. Ruby silver ore, 327. Greasy, 134. Rutherfordite, 209. Milky, 134. Rutile, 210. Rose, 134. Ryacolite, 176. Smoky, 134. INDEX. 453 aS~. ~ Senarmontite, 224 Seneca oil, 96. haccharite, 175. Serbian, 262. Safflorite, 263. Serpentine, 145, 855. Sahlite, 150. Seybertite, 149. Sal ammoniac, 100. Shale, 357. Saline springs, 106. Sicilian oil, 96. Salt, Common, 104. Sideroschisolite, 245. Epsom, 124. Sienite, 351. Glauber, 102. SILICA, 132. Saltpeter, 101. Siliceous sinter, 140. Samarskite, 209, 229 Silicified wood, 138. Sand, 368. Sillimanite, 172. for glass, 369. SILVER, 323. for casting, 370. Silver, Antimonial, 323 Sandstone, 360. Antimonial sulphuiet, Flexible, 359. Bismuthic, 323. Saponite, 145. Bromic, 328. Sappar, 173. Chlorid of, 327. Sapphire, 158. Horn, 327. Sarcolite, 181. Iodic, 328. Surd, 135. Muriate of, 327, (Chlorid.) Sardonyx, 135. Native, 323. Sassolin, 107. Red or ruby, 327. Satin spar, 113, 116. Selenids of, 327. Scapolite, 180. Sulphurets of, 326, 826. Scheelite, 219, (Tungsten.) Telluric, 327. Scheererite, 97. Silver glance, 325. Schiller asbestus, 146. Silver ore, Black, 326. spar, 148. Brittle, 326. Schist, 357. Red or ruby, 327. Schorl, 188. Vitreous, 325. Schorlomite, 213. Silver ores, general remarks am% Schreibersite, 231. 328. Schrotterite, 162. Reduction of, 830. Schwefel, Germ. for sulphur. Sinter, Siliceous, 140. Scolecite, 167. Iron, 249. Scoria, 357. Skapolith, 180, (Scapolite.) Scorodite, 249. Skolecite, 167. Scythe stones, 363, 354. Skorodite, 249. Sea froth, 148. Slate, 353, 354, 357. Sea water, 79. Smalt, 269. Dead, 79. Smaltine, 266. Selenate of lead, 285. Smelite, 162. Selenite, 113. Smithsonite, 272. Selenpalladite, 311. Soapstone, 143, 354. Selenid of copper, 296. Soda, Salts of, 102. of lead, 280. Carbonate of, 103. of mercury, 289. Nitrate of, 103. of silver, 32'. Sulphate of, 102, 108. Selensilver, 327. Sodalite, 197. Semiopal, 139 Sodium, Chlorid of, 104. 454 INDEX. Somervillite, 181. Talcose slate, 354. Spadaite, 149. rock, 354. Spar, Calcareous, 116. Tallow, Mineral, 97. Derbyshire, 122. Tantalite, 244. Heavy, 108. Telluric Silver, 327. Tabular, 141. Bismuth, 221. Sparry or spathic iron, 247. Lead, 280. Spear pyrites, 233. TELLURIUM, 219. Specular iron, 237. Tellurium ores, 219, 280. Speculum metal, 307. Tennantite, 296. Speiss, 245. Tenorite, 296. Sphene, 210. Tephroite, 259. Spherosiderite, 247. Tesselite, 165, (Apophyllite.) Spherulite, 357. Tetradymite, 221. Spinel, 160. Tetrahedrite, 295. Spinel ruby. 160. Thenardite, 108. Spinel, zinciferous, 161. Thomaite, 248. Spinellane, 196. Thomsonite, 167. Spodumene, 156. Thorite, 202. Stalactite, 116. Thrombolite, 302. Stalagmite, 116. Thulite, 183. Staurotide, 174. Thumite, 190. Steatite, 143, 354. Thuringite, 245. Steatitic pseudomorphs 149. Tile ore, 296. Steinmannite, 223. TIN, 213. Stellite, 142. Tin, Alloys of, 215. Sternbergite, 326. Native, 213. Stiblite, 224. Oxyd of, 214. Stilbite, 165. Stream, 214. Stilpnomelane, 245. Sulphuret of, 213. Stilpnosiderite, 240, (GOthite.) Wood, 214. Stinkstone, 117. Tin ore, 214. Stromeyerite, 326. Tin ores, general remarks on 215 STRONTIA, 110. Tin pyrites, 213. Strontia, Carbonate of, 111. Tincal, 107. Sulphate of, 110. Titanic acid, 210. Strontianite, 111. iton, 241. Struvite, 101. Titanite, 211. Sulphur, 97, 98. TITANIUM, 209. Sulphuric acid, 99. Titanium ores, 210. Sulphurous acid, 99. Toadstone, 355. Sulphuretted hydrogen, 77. Topaz, 194. Sunstone, 176. False, 134. Syepoorite, 267. Oriental, 158. Syenite, 351. Topazolite, 185. Symplesite, 249. Touchstone, 157. T. Tourmaline, 187. Trachyte, 356. Tabasheer, 140. Trap, 355. Tabular spar, 141. Tremolite, 153. quartz, 137. Triphane, 156. Talc, 143. Triphyline, 249. INDEX. Triplite, 249, 260. Vitriol, Green, 246 Tripoli, 370. White, 271. Trona, 103. Vivianite, 248. Troostite, 273. Volcanic ashes, 357. Tschefkinite, 209. glass, 357. Tuesite, 371. scoria, 357. Tufa, 363. Voltaite, 247 Calcareous, 116. Voltzite, 271. Tungstate of iron, 244. Vulpinite, 114. lead, 285. W. ilme, 219. Wacke, 355. rUNGSTEN, 218. Wad, 260. rungsten, Calcareous, 219. Wagnerite, 127. Ferruginous, 244, (Wolfram.) Washingtonite, 241. rungstic ocher, 218. Warwickite, 212. rurquois, 130. Water, 78. fype metal, 304. Mineral, 80. ^U.~~~ ^Sea, 7 9. Dead Sea. 79 Ultramarine, 196. Wavellite, 15u. Uranite, 228. Websterite, 129. Uran-mica, 228, (Uranite.) Weissite, 182. Uranium ores, 228. Wernerite, 181. Uran ocher, 228. Whetstone, 358, 359. Uranium, Phosphate of, 229. White antimony, 224. Oxyd of, 228. arsenic, 226. Sulphate of, 229. iron pyrites, 233. Uranium ore, Pitchy, 228. lead ore, 281. Urano-tantalite, 229. tellurium, 323, (Aurotellu UJran-vitriol, 229. rite.) Jrao, 103, (Trona.) vitriol, 271 Wichtine, 182. Willemite, 273. Vanadate of lead, 285. Wisnlutll, German for Bismutn. of lime, 219. Witlhamite, 182, (Epidote.) of copper, 302. Witherite, 109. Vanadinite. 285. Woerthite. 173. VANADIUM, 219. Wohlerite, 202. Variegated copper ore, 294. Wolchonskoite, 262. Vauquelinite, 285. Wolfraam, 244. Velvet copper ore, 302. Wollastonite, 141, (Tabular spar.) Verd antique, 146. Wood, Silicified, 138. Oriental, 356. Wood opal, 140. Vermiculite, 149. Wood tin, 214. Vermillion, 288. X Vesuvian, 184. Villarsite, 149. Xanthite, 184. Violan, 182. Xanthocone, 327. Vitreous copper ore, 292. Xanthophyllite, 149. silver ore, 325. Xenotime, 208. Vitriol, Blue, 297.'-ylite, 245 Cobalt, 268. INDEX. Y Zinc, alloys of, 275, 27a. Carbonate of, 272. Yenite, 246. Red oxyd of, 270. Yttria, Phosphate of, 208. Silicate of, 272. Yttrium ores, 206, 208. Sulphate of, 271. Yttro-cerite, 206. Sulphuret of, 269. Yttro-tantalite, 208. Zinc blende, 269. Yttro-ilmenite, 229. Zinc bloom, 272. Yttro-titanite, 212. Zinc ores, general remarks on, 278 Reduction of, 274. Zincite, 270. Zaffre, 268. Zinkenite, 223. Zeagonite, 168 ZIRCONIA, 200. Zeolites, 163. Zircon, 200. Iron, 246. Zirconite, 201. Zeuxite, 172. Zoisite, 183. ZINC, 269. Zygadite, i82. ISfATVuI —On page 166, 1Sth line from the bottom, real "blt mina 29'8," inu oad of " almina, 2a."