THE ART OF BLEACHING. \ THE ART OF BLEACHING PIECE-GOODS, COTTONS, and THREADS, OF EVERY DESCRIPTION, Rendered more eafy and general by Means of the Oxygenated, Muriatic Acid ; with the Method of rendering painted or printed Goods perfectly white or colourlefs. To which are added, the moll certain Methods of bleaching Silk and Wool ; and the Discoveries made by the Author in the Art of bleaching Paper. ILLUSTRATED WITH NINE LARGE PLATES, IN QUARTO, REPRESENTING ALL THE UTENSILS AND DIFFERENT MANIPULATIONS OF THE BLEACHING PROCESS. AN ELEMENTARY WORK, COMPOSED FOR THE USE OF MANUFACTURERS, BLEACHERS^ DYERS, CALLICO PRINTERS, AND PAPER-MAKERS, By PAJOT DES CHARMES, EORMERLY INSPECTOR OF MANUFACTURES, MEMBER OF THE LYCEUM OF ARTS, OF THE SOCIETY OF INVENTIONS AND DISCOVERIES OF THE PHILOMATHIC SOCIETY, IN FRANCE. TRANSLATED FROM THE FRENCH, With an Appendix. LONDON: I>RINTS» FOR Q. G. AND J. ROBINSON, PATER-NOSTSR-RO"VV, . 1799- CONTENTS. CHAPTER I* Jr\.N Explanation of the Difficulties which attend the Method of Bleaching, described in rhe fecond Volume of tue Annales de Chimie, when pra£tifed by inexperi- enced Operators - page i CHAP. II. The Methods fubftituted inftead of thofe enumerated in the foregoing Chapter - - -6 CHAP. III. The Composition of Lutes - r « 12 CHAP. IV. The Method of difpofing the Apparatus for Diftillation 19 CHAP. V. Preparation of the Materials - * 43 xlv CONTENTS, CHAP. VI. The Diftillation g 52 CHAP. VII. Concerning the alkaline Lixivium or Lees - 74 CHAP. VIII. Refpe&ing the Preparation to be given to the various Kinds of Goods « - - or CHAP. IX. Concerning the firft Immerfion - - in CHAP. X. Jnftruc"lions with Regard to the Quantity of Lixiviations and Immerfions - - - 126 CHAP. XI. An Account of the Quantity of Linen, and Cotton Thread, bleached at each Immerfion, and the Colours acquired by thofe Subflances - - 134. CHAP. XII. Of the Firft Dreflings - 140 CHAP. XIII. Of the Laft Dreflings - 154 CHAP. XIV. Concerning Proof Liquors - . 17a CHAP. XV. The Methods of remedying fuch Accidents as happen during the Courfe of Bleaching - - 178 CONTENTS. xv CHAP. XVI. The Method of taking out Spots of Ruft or Iron-mould, Tar, Fruit, Wine, Sec. - - - 189 CHAP. XVII. The Expence of Bleaching different Kinds of Goods, of Linen, Hemp, or Cotton, by the oxygenated muriatic Acid, at per Ell, or per Pound - - 193 CHAP. XVIII. The Method of bleaching yellow Wax, nankeen Stock- ings, and other Articles which have acquired a dark Colour by keeping ; Linen flamed by Dampnefs, and the Madder Grounds of printed Goods - 207 CHAP. XIX. The Method of difcharging the Colour of painted or printed Cottons, or Linens, and every Kind of Dye on Cloth or Thread, before or after it is wrought up 21$ CHAP. XX* The Methods of taking out the Dye from Silk and Wool 228 CHAP. XXI. Dying by the oxygenated muriatic Acid - 232 CHAP. XXII. Various Properties of the oxygenated muriatic Acid 236 CHAP. XXIII. On the Podibility of applying the Refidues to Profit 250 CHAP. XX r V. The Method of bleaching Hemp and Flax in the unma- xvi CONTENTS. nufaftured State, as well as Thread and Piece-goods^ by the Afliitance of Water only - 261 CHAP XXV. The Method of Bleaching written or printed Papers and Rags, whether unbleached, dyed, or coloured . 266 CHAP. XXVf. - - * - 271 CHAP. XXVII. Fabrication of crude Alkali (cendres Gravelees) with the Lees of Wine - - - - 276 CHAP. XXVIII. The Method of bleaching Wool - - 280 CHAP. XXIX. The bleaching of Silk - - . 291 Explanation of the Plates - 296 Appendix - » - - 245 PRELIMINARY OBSERVATIONS, BY THE AUTHOR. iHOUGH the illuftrious Swedifh che- inift Scheele was the firft who obferved the property of the oxygenated muriatic acid, which was alfo a difcovery of his own, of difcharging vegetable colours, has acquired the ftrongeft claim to the gratitude of the public, it is equally true, that the celebrated French chemift Berthollet has eftablifhed an equal claim to the acknowledgments of the world, by his active and able exertions on an object of fo much confequence to the com- merce of the linen and cotton manufactures. The different memoirs which he has pub- lifhed on this fubjedt, particularly that which is inferted in the fecond volume of the An- b 2 nales Vlll PRELIMINARY OBSERVATIONS. nales de Chimie — the fcientific application he has made of this acid to difcolour the feve-* ral vegetable fubftances which conftitute the raw materials of 'manufactures — the particu- lar developement, which the profperity of thole manufaclures led him to confider as ne-» cerTary to excite emulation among {peculate ors, foon afforded very promifing remits, as might naturally be expected from the publication of fo ufeful a procefs. Manu- facturers in all parts of the nation were in- duced to confult chemical and philofophical men, in order to obtain information refpecH* ing it : the happy confequences which have rewarded their labours in this refpect, are truly honourable to the zeal of the parties themfelves, and have added to the reputa- tion of their guide in this new department of refearch. The knowledge which I had acquired re- fpecting the inconvenience and delay of the common PRELIMINARY OBSERVATIONS. IX common procefs of bleaching— the incalcula-» ble advantages which I faw mull attend the method propofed by Berthollet — the new life which the manufactures of thread and piece-* goods, and the commercial tranfadtions de- pendent thereon, would certainly receive : — thefe views, added to the defire of knowledge, and a wifh to contribute to the propagation of a difcovery which promifed an increafe of our riches and our enjoyments, engaged me to verify the procefs defcribed in the Annales de Chimie. My intention was, in the firft place, to make myfelf mafter of the procefs, and then to propofe, with confidence, this new method of bleaching to the manufac- turers, merchants, and bleachers, in my de- partment of infpedtion, to whom this fpecies of induftry might prove advantageous, and to give them every information in my power. But I foon found that it would be in vain to defcribe and publifh this method, which would X PRELIMINARY OBSERVATIONS* would be in a fhort time forgotten or confined to a few individuals, if it were not rendered more economical, lefs dangerous, and more amply defcribed with regard to the manipu- lations, or practical part, fo as to be rendered eafy and perfectly adapted to the comprehen- fion even of workmen totally unacquainted with chemical operations. For I knew that mailers have feldom the time, or will take the trouble, to operate themfelves, but moft commonly coafide their work to men upon whom they can depend. I therefore took the utmoft pains to render the difcovery of bleaching with the oxygenated muriatic acid of general ufe. As I had the good fortune to be fuccefsful in my trials, I fhall endeavour in the following work to defcribe the procefTes, by the afiiftance of which I fucceeded. I firft give an account of the principal diffi- culties I experienced in operating, according to, the PRELIMINARY OBSERVATIONS. Xl the directions in the memoir before-men- tioned ; difficulties which the author him- felf would not have failed to remove, if he had himfelf operated in the large way. I then defcribe the methods which I have thought proper to fubftitute, inftead of feve- ral of thofe which are there pointed out : and, laftly, I defcribe, with the greateft precifion and minutenefs, the different operations which are indifpenfably neceffary to give linen, hempen, cotton and mixed goods, a perfect bleaching, equal in colour to the beft which are met with in the market, and are known in France by the names of the white goods of Troyes, Rouen, Senlis, &c. ADVERTISEMENT BT THE TRANSLATOR. X HILOSOPHICAL men, as well as manu- facturers, will, no doubt, receive with fatif- fa&ion the following treatife on a new art of great importance to fociety, and truly honour- able to philofophical chemiftry. It is unne- cessary to enlarge on the value of a procefs, which has been eagerly and univerfally adopted as foon as ever it was known, and its principal difficulties removed. Neither will it require any argument to fhew the advantage which practical men muft receive from a detailed and very faithful account of procefTes, conducted on a fcale of fufficient magnitude for commercial purpofes. a i When VI ADVERTISEMENT. When we reflecl: on the ftate of thofe arts which are mentioned in the title pr.ge, and the numerous applications this new method is ftill capable of, as well as the utility of teach- ing it to all who are in any refpect concerned in bleaching, it will fcarcely be queftioned, but that this elementary treatife muft prove of great public benefit. WILLIAM NICHOLSON. Newman-ftreet, June 13, 1799. THE ART OF BLEACHING COTTONS, THREAD, &c. BY THE OXYGENATED MURIATIC ACID, ' RENDERED OF MORE EASY AND GENERAL USE *. CHAP. I. An Explanation of the Difficulties which attend the Method of Bleaching, defcribed in thejecond Volume of the Annales de Cbimie, when praclifed by inex- perienced Operators. V_>/NE of the firft difficulties, in the operation illuftrated by the plate annexed to the memoir in the Annals of Chemiftry, is to obtain in the depart- * It was intended that this work fhould have been publifh- cd, in 1791, by the General Adminiftration of Commerce (in France) ; but the fuppreflion of that board, in the courfe of the fame year, prevented its appearance. Since that time, other circumftances have been unfavourable to the author's intention of publifhing the refults of his experiments on tha new method of Bleaching. — Ncte of the Jutbar. B A fhort i The Art of Bleaching departments fuch furnaces as are there pre- ferred to be ufed. They can fcarcely be had but by fending to Paris, where they are made : and if it be even fuppofed that thefe furnaces might conveniently be made at a diftance from the capital, they would flill appear to be coftly, fuitable only to a fmgle matrafs, not calculated to fhew the procefs which takes place in the veffel, fubje£r. to be heated too fpeedily, and liable to render part of the lutes difficult to hold ; laftly, they do not always fecure the operation from the confequences of an abforption of the water of the tub into the intermediate vef- fel (notwithstanding the tube of fafety), in fuch cafes where the heat is not kept up and urged particularly towards the end of the diftillatiom or where any negligence has taken place in the agitation which is required for the fpeedy ab- forption of the gas, or where the tubes of com- munication are too fmall. 2. The greatefl addrefs and precaution are required for the proper application of the re- curved tube, which on the one hand communi- A fliort table of fynonimes is added at the end of this work, for the ufe of thofe who may be unacquainted with the new nomenclature. — P. D. C. The method of Bleaching, to which the prefent chapter be:}is reference, is defcrihed in my Chemical Dictionary, ait. Bleaching. — Note of the Ttaiflator. cates Cottons, Thread, &V. $ cates with the matrafs, and on the other with the intermediate veffel. The flighteft agitation, whe- ther in attending the lutes, fupplying the fur- nace with coal, &c. is fufficient to break this tube, and likewife that which communicates to the tub. The difagreeable confequences of fuch an accident, w T hen the apparatus is in a ftate of activity, and the difengagement of the gas muft continue to take place, are too obvious to need defcription. The fame accident may happen whenever the tube is put in its place, or taken out to clear the matrafs. To this we may add, the difengagement and frequent re- newal of fo many ftoppers of cork, which are corroded by the gas and the acid during their paffage, and the adjuftment of the lutes requir- ed to cover and defend them. The care and vi- gilance required to maintain the feveral lutes of the whole communication muft be extreme. 3. The pneumatic tub or veffel having no cover, muft fuffer a large quantity of gas to efcape during the courfe, and particularly to- wards the end of the operation, which is not only attended with lofs, but renders it impoffible to remain for any length of time in the place of diftillation, without being greatly and even in- fufferably incommoded. 4. It is not a flight talk to conftru£t the fides » 2 or 4 The Art of Bleaching or borders of the inverted veffels in the pneu- matic tub, to retain and concentrate the gas in a proper manner. The memoir affords no explanation of the manner of conftructing cr adjufting thefe parts, and, confequently, leaves a degree of uncertainty, which expofes fuch ope- rators as may not be aware of the great import- ance of the perfect clofure of thefe parts, to the probability of making very confiderable mif- takes. 5. The long fucceffion of lixiviations and im- merfions prefcribed in this memoir, which are in- difpenfible according to that procefs, is produc- tive of much Iofs of time and inconvenience. 6. The method of compofing the lutes, parti- cularly thofe which are proper for this diftillation, not being explained, any one who is not ac- quainted with the means of doing this, or can- not conveniently procure them, will be much embarraffed, more particularly if his refidence be in the country, where the practical chemifts of the vicinity, if any, may either be unprovided in this refpe£t, or not difpofed to fupply either the lute, or the initruclions for making it. 7. Laftly, I have found, by my own experience, that, independent of the difficulties here enume- rated, the fingle obttacle of keeping the lutes in a proper ftate during the whole courfe of the diftillation, Cottons, Thread, &c. 5 diftillation, together with the no lefs effential requifite of preventing the danger of immerfions, are quite fufficient to repel the efforts of the moil zealous and obltinate in this kind of ope- ration. Such are the leading impediments to which every one, whether he be a practical chemifl or not, will find himfelf expofed in an attempt to follow in the large way the procefs of bleaching defcribed in the fecond volume of the Annales de Chimie. It was, therefore, of effential con- fequence to diminifh, or rather to remove thefe difficulties, without which this important art might be confidered as of no value to the public. It will be feen in the account of the methods I have employed, whether 1 have fucceeded in rendering the application and practice of this new procefs much more advantageous and prac- ticable, by perfons the leaft acquainted with chemical manipulations. CHAP. The Art of Bleaching CHAP. II. The Methods fubjlimtt J inflcad of thofe enumerated in thefcrcgoir.g Chapter. X SHALL, in the firft place, defcribe the fur- nace I have made ufe of, which I have endea- voured to render of the greateft poffible utility, without increafing the expence of fuel. A fimple calk of the proper height, or four pieces of wood framed together (fee plate I, fig. i and i *), fupport the furnace. The hearth is difpofed upon boards defended by tiles placed on a bed of clay. The walls or fides are formed of bricks, likewife connected with clay. 'J his furnace would be equally ufeful and folid, and perhaps lighter, if it were lined with plaifter, like thofe portable furnaces commonly ufed in Paris,' which it confiderably refembles in its manner of fupport. It is ufually double, and ought in fact to be fo, when the operations are intended to be made on a fcale of fome extent ; and confequently it is divided in the middle by a partition. At the front of the furnace above * The defcriptions of the plates, by literal reference, are found at the end of this work.— N. there Cottons, Thread &c. 7 there are two openings, which may be either round or fquare, adapted each to receive a fquare or cylindric capfule, with a ledge, and flat or rounded at bottom. Behind, and on the fame level as the capfule, there is a vent or pipe which conveys the heat and vapour of the char- coal, which is burned in a chafing-difli, or upon a portable grate, beneath, or round the capfules, into a kind of refervoir, which being difpofed a few inches higher than the capfules, ferves to place along fquare bafon of fheet-iron with pro- jecting edges, which is kept filled with fea fait or muriate of foda to the height of an inch and a half, in order that it may be dried during the diftillation. At the two oppofite extremities are two fmall apertures, which are opened or clofed as may be found expedient for the pailage of the heat or fmoke, and therefore operate like re- gifters. In the empty fpace, at the back part of the furnace, beneath the drying place, there is an opening in the fide, into which troughs or boxes of fheet-iron are put, containing the mix- tures of muriate of foda, and manganefe, ready prepared before hand. In this place they are kept dry, and in readinefs to be poured into the vefiels, the evening before the diftillation. The opening through which the chafing-difli is introduced, which is likewife on the fide of b 4 the 8 The Art of -Bleaching the furnace, is not quite fo much raifed as the bottoms of the capfules, which, though fup- ported by their rims on a level with the top of the furnace, have neverthelefs their bottoms placed on a fmall bar (verguillon). This open- ing may be fliut during the diftillation by a plate of iron, or any regiiler whatever which does not permit the accefs of air from without, except at its lower part. The furnace, it may be perceiv- ed, is portable, and on that account can be placed in any part of the laboratory, as conve- nience or new arrangements may require. If, in order to anfwer any particular purpofe, or without attending to expence, the preference fhould be given to furnaces of baked earth, I would then advife the ufe of fuch as have their chimnies on the fide, without a dome. Many furnaces of this kind have lately been conftrufted at Paris, by Laffineur, rue Mazarine. Their upper part, which is flat, and on a level with the chimney, allows the placing of capfules ; and the chimney, which is at the front, renders it eafy to take out the wood or charcoal which is put into a fire-place, provided with its alb- hole in the fame manner as the other furnaces which have a dome. This furnace is round, portable, lefs coftly, and appears to rne to be, in other refpedls, much more convenient than tha t defcribed Cottons, Thread, &c, 9 defcribed in the Annals : befides which, they may be made of any required fize. 2 = Inftead of the matrafs, the intermediate veflel, and the tubes which communicate from this laft veflel to the diftilhng and the pneu- matic apparatus, I have fubftituted a tubulated retort, to which I have adapted a recurved neck of glafs or lead, the beak of which is placed and luted to a fmall leaden fupport in the form of a funnel j and this laft piece is adjufted to the end of a tube, of the fame metal, within the pneu- matic tub, whofe lower extremity is bended to a right angle, and performs the office of the glafs tube in the apparatus of Berthollet. This tube, as w T ell as the additional neck of the retort, may likewife be made either of pottery, ftone ware, or, which is ftill better, of porcelain. Inftead of the retort, and its neck of glafs or lead, I have ufed, with no lefs but even with more advantage, a body or bottle tubulated at the fhoulder. Above the neck of this body or veflel is applied a pipe, which at the fame time forms the communication and the interior tube. I (hall hereafter fliew the method of difpofing this apparatus. 3. The pneumatic veflel, to which I adjuft a cover, is divided into three parts by two falfe bottoms, fixed in the veflel itfelf by means of its I o The Art of Bleaching its conical figure, or upon a hoop, or mafles of wood, fixed with pins. I (hall alfo, in the pro- per place, give an account of the manner of fixing and difpofing thefe falfe bottoms, as well as of other kinds of veffels, not without their peculiar conveniences. 4. I have considerably diminished the lixivia- tions and immcrfions. In the chapter which treats of thefe fubjecis, it will be feen in what manner I have proceeded in Amplifying thefe important operations. 5. I mail alfo defcribe the method of compo- fing two lutes, which I have found very ufeful ; one made with the cake of linfeed, and the other known in chemiftry by the name of fat lute. The latter, though mere expenfive and difficult to make, appears to me to deferve the prefer- ence. 6. By fuppreffing the intermediate veflel, and by the fubftitution of a retort or tubulated bot- tle inftead of the matrafs, together with the re- curved neck or tubes of lead inftead of the tubes of glafs ; when once the connecting part is well luted, in the manner hereafter to be defcribed, no further trouble or inconvenience follows from the lute?, becaufe there is but one to take care of, namely, that of the beak of the neck placed on the tube which pafles into the pneumatic veflel. Cottons, Thread, &c. II veffel. This lute being renewed, if thought fit, at each diftillation, and a little attention being paid to apply it well, is never found to fail. The operator is, therefore, at liberty to employ his time in the lixiviations and immerfions. It will hereafter be feen in what manner I have fucceeded in removing the danger of thefe im- merfions. In this early ftage of our defcription, it is eafy to perceive how much lefs troublefome our apparatus muft prove, than that to which we have referred in the firft chapter. Neverthelefs, as it is of confequence that the inhabitants of the country, to whom my attention has been principally directed in this work, mould be in no refpect expofed to failure in the fraalleft par- ticular, I (hall proceed to give the molt minute accounts of the ufes and arrangement of the apparatus j and, in the firft place, I mall treat of the 'utes. CHAP, 12 Tie Art of Bleaching CHAP. III. The Compoftlion of lutes. FAT LUTE. JL HE obfervations I (hall offer on this parti- cular lute are partly extracted from Baume's Chemiftry. I have thought it proper to add fome ufeful obfervations for the fake of besrin- ners. Take any quantity of good grey or blue clay : I have always found fullers-earth (iirgile a foulon) excellent for the purpofe. The clays of Gentilly and of Vanvres, near Paris, are Iikewife very good. The clay is to be dried in thin cakes, which may be fpeedily done in an oven after the bread is drawn ; the dried clay is to be pounded finely, and fifted ; a certain quantity of this clay, together with a fufficient dofe of boiled linfeed oil, rauft then be beaten in an iron or bell-metal mortar for a long time, until the fmalleft lumps have difappeared, and the whole mafs ihall form a pafte, of an uniform colour, rather folid and tenacious, but, neverthelefs, not adhering to the hands: this is called fat lute. A large quantity of this lute may be prepared beforehand, more efpecially when the operations are Cottons, Thread, &c. i* are to be performed in the large way, and almoft continually. That which has been made for a twelvemonth is more pliant and better, but it muft be kept in a cellar, in a covered earthen pot. When it has become too dry to be handled, it may be eafily foftened, by firft warming it, and afterwards beating it in the iron mortar, with as much of the boiled linfeed oil as may be found neceffary. The lute, which has ferved for one diftillation, may be ufed again, after the burned or decom- pofed parts have been feparated : thefe parts may be known by the white or yellowifh colour, and the dry or brittle confidence which the lute illumes at thofe places. Lute which is worked up again is fo far from being worfe, that it is more flexible and tenacious. In this manner, the old fat lute, or that which has already been ufed, may be advantageoufly mixed with new lute. It is particularly effential that the burned por- tions mould be rejected from this mixture 5 if this be not done, the lute will not dry as it ought, and, fo far from being foft and flexible, it will be harm, fhort, and continually difpofed to give way, by flicking to the fingers. When the quantity to be mixed, or kneaded up again, is very fmall, the trouble of beating it in the mortar may be avoided, becaufe the ope- ration 14 The Art of Bleaching ration is performed very well, by kneading the matter with the hands. For this purpofe, a portion of the lute already kneaded in the mor- tar, and foaked with oil, may be taken and rolled in the veiTel containing the pounded and fifted earth ; the portion of earth which adheres may then be worked in ; and, by a repetition of this manipulation, the mafs will fpeedily become enlarged, and muft be ftrongly compreffed, rolled out, and doubled again, until it is found that it pofiefTes the requifite foftnefs and tenacity, and does not crack when doubled. If it mould happen that the lute mould become too foft by excefs of oil, and clay is not at hand to correct this fault, the mafs will foon acquire firmnefs by expofing it to the open air upon parchment, or upon a plate. It muft not be laid upon paper, becaufe it is very difficult to feparate this material entirely ; and if any parti- cles mould remain, there would be reafon to fear that, when incorporated in the mixture, they would either prevent the perfect adhefion of the lute, or would allow the paffage through that kind of void, or pore, which the fragments of paper would form. It is, moreover, to be re- marked, that this lute cannot be too fmooth and uniform. It ought not to afford any per- ception of inequality when it is handled, or kneaded> Cottons, Thread, &V. 15 kneaded, nor indicate the prefence of foreign fubftances, fuch as fand, ftraw, earthy particles, &c. which are capable of preventing the inti- mate connection of its parts. I ftrongly infift on the perfection of this lute, becaufe it is the foul of diftillation. Boiled linfeed oil is thus made : two pounds of common linfeed oil being put into a faucepan, or proper vefTel, of copper, iron, or pottery, add three ounces of red litharge, finely powdered and lifted ; after ftirring the whole well together* place the vefTel on the fire, heating it gradually, until the litharge is completely difTolved. It is neceflary to ftir the mixture very frequently with a wooden fpatula, until the whole folution, which at firft acquires a brick-duft colour, is completed : it is then to be removed from the fire, and, when cold, transferred into a ftone or earthen vefTel, and kept well corked. This is the boiled linfeed oil above directed to be ufed in making the fat lute. When this oil, which is blackifh after boiling, is well made, it congeals in the vefTel as foon as it is cold. When it is required to be poured out, it may be rendered fluid by bringing it near the fire. To fave the trouble of heating it, it may be poured, as foon as made, into a plate or fhallow vefTel, or left in the vefTel ufed for boil- ing 1 6 The Art of Bleaching ing it. It is feldom neceflary to heat it for the mere purpofe of mixture ; the quantities re- quired for this purpofe may be taken up with the fingers, or in any other manner. It is proper to obferve, that the veflel in which the oil is boiled muft be fumciently high, to afford a fpace for the fuelling of the fluid ; for, as foon as the heat begins to ael:, it will rife and overflow the veffcl, if particular attention be not paid to it. As foon as this procefs begins, the veffel muft inftantly be taken off the fire, and the mixture ftrongly agitated by plunging the fpatula in it, at the fame time blowing ftrongly at its furface with the mouth ; by which means the ebullition will be checked. After this event lias happened two or three times, it may with certainty be concluded, that the oil will be fufficiently coniiftent to form a good fat lute. By cooling, it immediately con- geals, as has been remarked, to the confiftence of plaifter, of a black colour, inclining to brown. The lute made of linfeed oil cake is thus made : The cake is firft to be broken and pounded in an iron or bell-metal mortar, and afterwards fitted. through a iilken fieve ; ftarch is then to be boiled up, to the confiftence of fize or glue ; a fmall piece of this, being powdered with the flour Cc:U;ts y Thread, &c. 17 flour of the oil-cake, is to be worked in a plate, or with the hands ; more of the flour may then be added, and the kneading continued until the mafs is abfolutelv without any lump, or in- equality, and its confidence has become nearly the fame as that of the fat lute ; after which it is to be kept in a plate, or covered wooden bowl, in the cellar, for ufe. The fame care mud be taken with this, as with the fat lute, not to wrap it in paper, but in parchment, if thought neceftarv. This lute dries and hardens much on its outer furface, which remains uninjured at the place where it is applied; but it is decompofed more fpeedily than the fat lute, on account of its peculiar property to become hard and flirink with a firong heat. In this ftate, in confe- quence of the action of acids, it aflumes a yellow colour, and is then good for nothing: it mull be renewed. A very good lute is likewife made with equal parts of the flour of almonds, of linfeed, and of itarch, kneaded together. It muft be under- ftood, that the latter is to be boiled to the con- fidence of ftarch. To thefe different lutes we may add that which is compofed of lime and white of egg, c which 1 8 The Art cf Bleaching which has the property of acquiring a consider- able degree of hardnefs. Among all thefe lutes, that to which I have conftantly given the preference, and is always kept in fight in the prefent work, is the fat lute. The lute of white of Qgg and lime, retained by a cloth and a bandage, may be advantageoufly ufed as a covering to the fat lute *. The fat lutes adhere very much to the hands, during the kneading, or working ; but it is not difficult to wafli off the remains after the opera- tion : nothing more is neceffary, than to ufe warm water and foap, or foap leys, after having previoufly wiped off the greater part with blot- ting paper. * Faujas de St. Fond, in his Voyage en Ecoue, mentions the following lute, communicated to him by. the celebrated Dr. Black, of Edinburgh. That chemift confrdered it as impermeable to every fpecies of gas. This lute is composed fimply of the pafte of almonds, in the ftate it poffefles after extraction of the oil ; it is foftened with a fmall quantity of water, in which glue ha<, been dif- folved; the glue may even be difpenfed with.— Note of the Author. CHAP Co 1 tons, TBread, &?r. ig CHAP. IV. The Method of dt/pcfing the Apparatus for Dtf- tillation. T IT has already been remarked, that our diftil- ktion may be performed either in a retort, or 9 tubulated body or bottle. There can be no difficulty in properly placing thefe veiTels. The jun£Hon of the neck or tube, communicating; with the pneumatic veflel, is the only obje£t which requires particular care. The manner of joining thefe two parts, by means of lute alone, will be explained below. As the ufe of the retort requires more atten- tion with regard to its form, and the applica- tion of the additional part, the following details will be of ufe to prevent accidents. When the retorts are new, and have not be* ore been luted to any additional part, it is ad- vifable either to rub a fmall quantity of warmed wax on the parts where the lute is to be ap- plied, that is to fay, the neck of the retort, as well as the correfpondent part of the addi- tional piece, or to fuffer a fmall quantity of ftarch or pafte to dry upon thofe parts j without c z this fi 20 The Ait of Bleaching this precaution the lute could not be eafily ap- plied ; it would Aide and roll upon the glafs in- ftead of adhering. Care muft afterwards be taken to fix round the neck of the retort a mafs of lute, fomewhat greater than is fuppofed to be neceffary to fill the additional part to the place where it is to be fixed, in order that by the forcing of that piece upon the neck of the retort, the lute may extend and apply itfelf more intimately. The fame attention muft alfo be paid to the mafs of lute, which is required to fecure the beak of the additional piece in its connection with the pneumatic apparatus. Thefe obfervations are of more importance, in order that the two pieces may, by this compreftion, be made to operate as if they formed one entire vefTel. To apply thefe lutes with eafe and conveni- ence, the retort is to be held in one hand, in fuch a manner as that its belly or lower part may not touch or reft upon any thing whatever, becaufe the flighted blow upon this very thin part will break it. Before the lutes are applied, care muft be taken to introduce the neck of the retort into the additional piece, and mark with lute or wax upon the additional piece the place where the extremity of the retort touches it internally; and Cot 'ens, Thread, &ff. 21 and in like manner, on the retort itfelf, the place where the extremity of the additional piece touches its neck. By means of thefe marks it is eafy to eftimate the thicknefs of the mafles of lute, by placing the two veffels near each other in the refpeftive portions they ought to have when fixed. Laftly, they are united toge- ther by Hiding the recurved additional piece upon the neck of the retort, which is to be held firmly by its neck, refting the hand on the furrounding part, if the retort is (mall; or hold- ing it by the recurved part, if it be large, or the additional piece mould be too long and heavy. The greateft attention muft be paid not to turn the parts round, during this operation, more than is abfolutely neceffary to bring them toge- ther ; and if this can be done without any turn- ing at all, it will be dill better, as the lute will hold more effeaually. The neck of the retort muft be entered into the additional piece as far as it is capable of comprefling the lute, or nearly to the marks made upon the pieces before they were put together. In this fituation the lute } which forms a mafs round the edge of the addi- tional piece, muft be raifed fo as to cover both furfaces, after having firft preffed it as firmly as poffible into the joint; fmoothing it upon the two pieces, fo as to prevent the fmalleft c 3 opening 22 The Art of Bleaching opening or crack. It is advifable after all to fpread a thin coating of the boiled linfeed oil over the lute, which not only renders it fmoother and more perfect, but by the denfity it acquires from evaporation it forms a kind of varnifh or pellicle, which fupports the late, and prevents the fiffures which might be formed during the actual operation. Whenever in the courfe of the work the lute ihould appear too dry, it mull be fupplied with a thin coating of oil. While the lute is thus fpread and applied on the external part of the additional piece and the neck of the retort, the compound apparatus is to be held by the additional piece only, and the retort left to be fupported untouched in the air, by its infertion at the neck only. Inftead of luting the additional piece to the retort, (imply at the extremity of th^ neck of this laft, and at the place where the wider part of that piece touches the retort, we might apply the lute upon the whole furface comprehended between thofe parts. But I have found that it is fufheient if thefe two parts be made fecure. A retort luted in this manner forms one fingle and entire body with its additional neck ; and with very little care and attention, the lute will feldom or ever have occafion to be renewed before one or two months' fervice. The Cot tens, Thread, &u o§ The tube on which the recurved additional piece refts during the diftillation, and through, which the gas is introduced into the pneumatic tube, is, as I have remarked, entirelv of lead. If i be not caft, it ougiu to be carefully joined with ftrong folder ; and, for fear this lair mould fail, it will be prudent to cove/ it with a coating of yellow wax, pitch, or melted pitch. At the beginning o^ my experiments, I made thefe tubes of the fame fize as thofe of the ba- rometer ; I afterwards had them of eight or nine lines (| inch Engliih), and did not find that the diftillation was lefs advantageous. The greater diameter even feemed to be preferable, becaufe the gas was tranfmitted with more facility, and the abforption feemed to be more effectually op- pofed. That part of the tube (if foldered as before mentioned) which pafifes under the lower falfe bottom, ought to be carefully bended with -a round corner, before it is coated with the wax or pitch ; and in the bending it is fafer to caufe the foldered part to lie within the angle. It 's likewife proper to ftop the mouth of the tube with paper, or a cork, during the time of wax- ing or tarring, in order to prevent any introduc- tion of thofe fubltances into its cavity, taking care to withdraw this temporary (topper before c 4 the 24 The Art of Bleaching the apparatus is applied to actual ufe. It is not abfolutely neceflary to coat any other part of the tube, but that which is to be placed within the pneumatic apparatus, becaufe it is eafy to fto.p any other part, out of which the gas might iflue, with foft wax or lute. The extremity of this tube, in which the re- curved neck of the additional piece is to be in- ferted, rauft have the form of a fmall funnel, net only for the purpofe of affording the moft con. venient fupport, and the more ready adaption to the various fizes of thofe necks, but alfo be- caufe it more readily fupports the only kind of Jute which in this work we fuppofe to be ufed. This lute is never deranged, if care be taken to prefs it againft the internal furfaces of this fmall funnel, and of the glafs or lead of the additional piece, fo as to unite them as much as poflible, it being always underltood that the lute is good, and polTdTcs the properties before defcribed in treating of that fubflance. I have remarked that the ufe of the retort with its additional neck might be difpenfed with, by fimply ufmg a body or bottle with a neck (even a wine bottle may be ufed in cafe of neceflity, provided its bottom be either very thin, or very gradually heated). In the orifice of the neck of thefe veflels, is to be adapted a tube of lead. Cottons, Tbread y Cifr. 25 lead, properly bended, and of a due fize. This method is in fact very advantageous and eccmo mical ; but care muft be taken to join the tube, if it be of meet-lead, particularly in the parts below the bottle which are liable to become heated, a fhort time before the end of the diftil- lation ; to join it, I fay, without folder, by fufing the two edges together. For in procefs of time the folder, though ever fo ftrong, yet becaufe it contains tin, is liable to exceflive cor- fofion by the oxygenated muriatic acid, which, notwithstanding its heat, is not found to attack lead in any perceptible degree. But it may, perhaps, be more convenient to caft fuch a tube at one heat, as well as the ad- ditional piece in the apparatus, with the retort; unlefs, indeed, it mould be practicable to have it made of ftoneware or porcelain, the latter of which is the leaft permeable to the gas. Or we might, with more advantage, make ufe of a thick tube of common glafs, which might be eafily bended in a charcoal fire, and might be adapted to the tubulated bottle, as well as the leaden tube. But the danger of its breaking, and the difficulty of procuring others in cafe of need, together with the expence, have led me to reject this, as well as the tubes of pottery or porcelain. In order that the tube adapted to the neck of a 6 The Art of "Bleaching of the bottle may accurately fit, and prevent all cfcape of the oxygenated muriatic acid, it is de- fended by lute in fuch a manner, that it (hall not be thruft into the neck of the bottle, with- out extruding a portion of that fubftance; and a border of luting muft then be applied round the place of junction, which will effectually pre- vent the efcape of any vapour which might ifTue through the firir. luting. Laftly, the whole fur- face of this external luting is to be fmeared with boiled linfeed oil; after which the diftil- latory apparatus may be confidered as perfectly fecure. If a tube of glafs be ufed, it may be fo adapt- ed by grinding with emery as to fit the neck of the glafs body, and require no luting. The lame might be done v%ith a tube of porcelain, if the material were fufriciently fine. With regard to the other neck which I have recommended, as well in the bottle as in the retort, it ferves not only to introduce the mate- rials when the leaden tube is previoufly luted in, but likewife to admit the external air, if by chance an abforption fhould be perceived to take place ; that is to fay, if the water, by a diminution of the heat, which leaves a kind of vacuum, mould rife from the pneumatic appa- ratus into the body: though even in this cafe there Cottons, Thread, &c. 2T there would be no reafon to fear its breaking notwithftanding its being confiderably heated, as at the end of the operation. I have expreftly made the trial feveral times, and always with- out any accident. The fluid becomes gradually heated in its pafiage along the (ides of the tube or neck of the diftiiling apparatus, before it enters and mixes with the matter in the body itfelf; and again, if the tubulated bottle and tube be made ufe of, the water riling through the latter and falling in the middle of that con- tained in the yeffel, cannot directly touch the fides before it becomes mixed. But, at all events, if the fmalleft abforption be feared, it will be fufficient to raife the Hopper and return it to its place the inftant after the introduction of the at- mofpheric air. Inftead of a glafs Hopper, a cork may be ufed, which muft be carefully luted round the neck, if there be any reafon to think that the vapour mould find its way through, in confequence of the neck being not perfectly round. With regard to the pneumatic veflfel, the fol- lowing is the method of placing and fixing the falfe bottoms. (See plate I. and If. and plate IX. figs, i, 2, 3, 4, 5, and 6.) A common wooden hoop is plained flat on the fide which is to bear the falfe bottom, and fixed 28 The Art of Bleaching fixed within the caflc with pegs which do not pafs quite through the ftaves. The falfe bot- tom, fecured together by two dove-tails, is plac- ed upon this hoop, and fixed there by fimilar pegs, which penetrate part of the bottom it- felf, and by that means prevent it from either rifing or turning. The cavities between the falfe bottom and the fides are then to be clofed round with caulker's fluff {brai fa), or melted pitch. It mull' be remembered, that the verti- cal axis with its crofs arms is to be placed be- neath each falfe bottom. The arms are fixed in a mortice by means of two pins, which prevent them from vibrating or getting loofe. The leaden pipe in which the extremity of the addi- tional neck is to be inferted. is not to be put into its place till the firft falfe bottom is immove- ably fixed. A notch is fuppofed to have been cut in this bottom to admit the tube; and when it is duly placed, the vacant fpace is to be made good, firft with tow and then with melted pitch. Inftead of the wooden hoop, which affords a folid fupport for the falfe bottom, it may anfwer the purpofe very well, if cleats or blocks of wood, three inches thick, be pinned on, at dif- ferent parr> of the circumference ; or, which is ftill better, if the trouble be taken to fit the falfe Cottons, Thread, &cj iy falfe bottom fo well, that it may bear fimply upon the inclination of the ftaves, which natu- rally oppofe its defcent. This method would certainly be the quickeft, and is not very dif- ficult to be done. When the falfe bottom is thus fixed, it muft be retained in its place by pins placed at certain diftances, and afterwards made tight by caulk- ing. In order that the tube may not be expofed to vary in its pofition, a mark muft be made on the edge of the funnel which terminates one of its extremities, by which it is eafy to afcertain the pofition of the bended part below, and place the fame in the moft favourable fituation. It. will be convenient to fix the pipe in this pro- per fituation, by means of two pegs, which muft be drawn out previous to the laft fixing of the falfe bottoms. When the firft or lowed falfe bottom is fe- cured in its place, the fecond arm of the agita- tor is to be faftened to the axis, and the other falfe bottom is to be placed and made faft in the fame manner as the firft. It is particularly neccffary to place thefe two partitions in fuch a manner, as that the holes of communication may not be in the fame vertical line, but as far as poftible from each other, that is 30 The Art of Bleaching is to fay, diametrically oppofite. This diipofw- tion is neccfTary in order that the gas may have time to concentrate in one part, before it ef- capes to the other. For the fame feafon, it is proper to direct, the lower opening of the leaden tube to that extremity of the diameter which is oppofite the pipe of communication from the firft to the fecond bottom, in cafe one diftilling vefTel only is ufed. If two or more communi- cate with each pneumatic apparatus, the open- ings of the tubes muft be refpecYively difpofed at equal diftances, as far as pofiible from each other, and from the opening in the falfe bottom next above them. If inftead of falfe bottoms the preference fliould be given to inverted tubs [cuvettes), the following method mav be ufed to make the rims or tides, and to fix them immoveable. (See plate IX. fig. i, 2, 3, 4, 5, and 6.) The rim may be made in two ways ; either by fhort ftaves, fixed with wooden hoops as ufual, fcarfed or hooked together at their two extremities, or tKe, by fimply fixing a broad wooden rim. like that of a fieve, round the bot- tom of this inverted vefTel, by means of fmall wooden pins with heads. Eoth thefe methods are good. The fecond has the advantage of taking lefe room and being cheaper. Cottons , Thread* <3c. 3 1 cheaper. If this method be ufed, the points of the pins muft be made a little thicker than the ilem, in order that they may be lefs difpofed to draw out of the holes bored in the bottom. With regard to the joining of the two ends of this kind of broad hoop, it may be effected very firmly by fewing them together with a fiat ftrip of ofier, as is done in the better fort of chip boxes, or it may be very well managed by means of two pins with heads, which may be driven through the overlapping part, and fe- cured at the other fide by driving a fmall wedge into the tail of each pin. With regard to the empty fpaces or openings which may be be- tween the rim and its bottom, they muft be flopped with glaziers' putty (mafiii du vitrier), which may be fmooihed with oil. This putty is of excellent fervice when the muriatic acid is ufed without potafh j but it is foon deftroyed if potafh be put into the pneumatic veffel. \n this cafe the internal part of the places of junc- tion muft be pitched or caulked, as has been already fhewn. The method of making thefe inverted velTels with Haves and hoops, has the advantage of being clofe, and not requiring any particular caulking. Laftly, inftead of thefe inverted veffals, the operation 32 Tic Art of Bleaching operation may be performed merely by flat beards without rims, provided, however, that the upper board be fome inches broader on everv fide than the lower, in order that the bub- bles of the diftilling vefTels duly placed and luted, and the Cottons, Thread, 6fV. $$ the mixture of muriate and manganefe introduced the evening before the day of diftillation, after having cleaned and cleared the fame veflels from their refidues *. By means of this preparatory work, there remains nothing more to be done at the beginning of the day-work, than to pour in the fulphuric acid, which during the night has had time to cool, in the earthen or (tone- ware veflels, in which it was previoufly mixed with water. Not that it would not be advan- tageous to pour it while yet warm, after having diminifhed its temperature, by plunging the veflel in cold water ; but there would be reafon to fear, that the proper degree of heat might not eafily be adjufted, and that the diftilling velTel might be endangered by the fudden applica- tion. It might alfo be practicable to advance the diftillation, by pouring in the fulphuric acid in the evening, immediately after the introduction of the mixture of muriate and of manganefe ; but there would be reafon in this cafe to fear that the greateft part of the gas afforded by the diftil- lation might be loft by derangement of the Jutes, if the operation were not overlooked dur- * A fufiicient number of diftilling velTels ought always to be in readinefs, to be difpofed for the diftillation of the following day. Author, E 4 ing $6 The Art of Bleaching ing the interval. This management would not in fact be fuitable to a manufactory, in which the work was not continued both day and night. With regard to the fulphuric acid, it is to be introduced gently through a glafs or leaden funnel, in order that the air which efcapes may not throw up drops of the acid on the face or hands of the operator. When the acid is pour- ed in, the neck muft be flopped by turning the ftopper with a flight preffure. If the acid has been poured in warm, and the muriate is very dry, and well mixed, the fulphuric acid not more diluted than has been prefcribed> and the manganefe of a good quality, bubbles of air will be heard to pafs into the wooden velTel, through the leaden tube, at the end of two or three minutes'. If the above requifites be wanting, the efcape will not take place till fomewhat more than a quarter of an hour. In either cafe it is necefTary, a few inftants after the pouring of the acid, to place a charing dim with lighted charcoal beneath the vcfTel which holds the retort. About half an hour after the pouring of the acid, a confiderable effervefcence takes place, which fometimes fwells the materials as high as the neck of the retort, if this laft be too fmall for its charge. The bubbles of the froth are /. lar S e > Cottons, Thread, (3c. 57 large and covered with a kind of pellicle, formed by a portion of the mixture carried up during the agitation. This intumefcence lafts about two hours, during which time the bubbles of oxygenated muriatic acid gas are moft abund- antly difengaged in the water. They even fuc- ceed with fuch rapidity, that the intervals are not diftinguifhable, and an inceffant noife is heard in the pneumatic veflel, which very often lafts three or four hours, according to the ma- nagement cf the fire, and the goodnefs and ac- curate mixture of the materials. The agitation produced by this rapid efcape is commonly fuch, that it is fcarcely neceffary to move the agitator. The fire is not to be renewed till the expira- tion of two hours, even though it may have gone out in the mean time. After this, it is not to be renewed till the end of an hour and a half, and after that period at the end of an hour, and fo forth, without any perceptible increafe of its intenfity. It will be fufficient after thefe periods to keep up the fire, excepting that during the laft two hours the fire mufl be maintained with- out fufTering the charcoal to be almoft burned away, as in. the former cafes, before it is re- newed. The chafing dim mull be raifed upon bricks, to bring it nearer the retort, during the laft 5 8 The Art of Bleaching laft hour. Imuftobferve, with regard to this chaf- ing dim, that the grate mud not be too open, left the charcoal mould be too rapidly confumed. After the intumefcence of the mixture has ceafed, the rapid efcape of bubbles does not diminifh for a long time, in confequence of an effervefcence which conftantly proceeds. It is true that this continually diminiihes, and to- wards the end of the diftillation the bubbles which pafs into the tube appear only at inter- vals, notwithstanding the marter k tort mav, by the gradual augmentation of the heat, be brought into the ftate of ebullition. This heat is fuch, that eight or nine hours after the com- mencement of the operation, the hand can fcarely be endured near the aperture, or the neck of the retort, or other diftillatory vefiel, though between the fourth and fixth hours the fame parts are fcarcely warm. The diftillation of one or more retorts or bodies into a fingle veftel, according to the dofes before mentioned, takes ufually eleven or twelve hours, and even lefs ; the time for Hooping the diftillation is known from the efcape of the bubbles being very flow, and the noife lefs perceptible. This flight noife is even a mark to form a judgment of the concentration of the gas, and the degree of faturation of the water. In order to hear the bubbles, Cottons, Thread, t!£c. 59 bubbles, it is often neceflary to apply the ear againft the tub. Moreover, the adopter of the retort begins to be heated, and the lute upon its neck becomes a little foftened. Another in- dication that the procefs is near its termination is had from the Ions: vibrations of the water in the indicatory tube, placed on the outfide of the tub, and like wife in the tube of fafety, when an intermediate veffel is ufed. If a proper regard be not paid to the figns here enumerated, and the diftillation be not Hopped, there will not only be a lofs of time and fuel, and a diftillation of mere water ; but the fleam when an intermediate veffel is ufed, will drive the water through the tube of fafety, and itfelf immediately follow, if not inftantly re- medied by diminifhing or removing the fire, and cooling the neck of the retort and its adopter with a wet cloth, or, which is better, by drawing the ftopper of the retort for an inftant. As foon as the diftillation is flopped, the im- pregnated fluid of the pneumatic veffel is to be drawn ofT into tubs, or other veflels, proper to receive the goods which are previoufly difpofed therein. If it be not convenient to ufe it im- mediately, the liquor may be left in the tub without fear of any perceptible diminution of its virtue, provided the cover and its joinings be well 6o The Art of Bleaching well clofed with lute and ftrips of paper pafled on, and likewife that the fpace between the axis of the agitator and the cover be fimilarly fecured. It may likewife be drawn off in ftone-i ware bottles well clofed with corks, covered With lute at the place of their contact. In this manner the liquid may be preferved till wanted. I have kept it for feveral months without its goodnefs having been impaired. I muft obferve in this place, that if it be wiihed that the liquor at the upper part of the veflel fliould be equal in ftrength to that of the lower, without retarding the diftillation (which may be ufelefsly prolonged for upwards of twenty-four hour?, by an erTecl: ot the concen- tration of the gas in the bottom of the vefieh and the refinance it then oppofes to its intro- duction, which Angularly contributes to inereafe the heat of the retort) ', I have found no better method, than that of drawing off the liquor, either into earthen pitchers or veflels tilled with merchandize ready for immerfion. I have done this after a limited time, and repeated proofs of the good quality of the fluid. At the end of eight hours diftillation, I drew off one fourth of the contents of the veflel ; a fecond fourth two hours afterwards ; a third fourth after ten hours and a half, or eleven hours 5 and the reft after twelve Cottons, Thread, 6fa gi twelve hours diftillation, which formed the con- clufion. * When the liquor is entirely drawn off from the veffel, it mud again be immediately filled with water, or at leaft to the height of five or fix inches above the return of the leaden tube, otherwife the gas, which continues to efcape from the diftilling veffel and then affords no re- finance, might attack the pneumatic veffel it- The fire mufl be taken from beneath the re- tort as foon as the diftillation is fmifhed, not only to prevent the effeft of the gafeous vapours, which (till continue flowly to efcape, from act- ing on the fides of the tub, but likewife to dif- pofe the retorts or bodies to receive a quantity of warm water, which is to be poured in up to the neck. There is no reafon to fear an excefs of quantity, and the hotter the veffels are the better. It is effeniial, however, that it be not poured in cold, for fear of breaking the glafs. The adopter is then to be unluted from the neck of the leaden tube, if the operator chufes ; and in order that no vapour may efcape into the workthop, a bit of lute or a cork may be ap- plied to the beak of the adopter. The fand bath eafily permits the retort to be raifed and returned again to its place ; as well as the ap- plication 6z The Art o/Blsaciririg plication of the lute or ftopper to the neck of the adop'.e , this 'aft baing railed with one hand while the cork is put m with the other. Neverthelefs, as the lutes which connect the adopter with the retort are fomewhat foftened towards the end of the operation, it would be more prudent to leave every thing in its place, for fear of deranging thofe lutes. This danger is greater when the adopter is of lead, becaufe the great length of this additional piece tends to force the luting ftill more on that account. If it be required to proceed immediately to a new diftillation, the retort or bottle with its capfule or pan mull: be immediately taken from the fur- nace, and another fubftituted in its place ready prepared during the former diftillation. This neceflarily requires a double fet of veflels. When the diftilling veflel is cold, or nearly {o, the whole of its contents muft be fhaken, by holding this veflel by the neck with one hand, and applying the other to its bottom. The ftop- per mull then be taken out, and the veflel fpeedily inverted, Ihaking the relidue to facili- tate its efcape. In this laft Situation the retort is to be held by its neck with one hand, and its fide gently refting againft the other. The vef- fels into which the water and refidual matter of the retorts are poured, mould rather be of ftone- ware, Cottons, Thread, &c. 63 ware, pottery, or lead, than of wood, unlefs thefe laft be oil veflels, which are lefs fubje£t to dry in the part above the fluid. If this cir- cumftance be not attended to, there will be danger of lofing great part of the contents. It is moft convenient to difengage the retorts or bodies while they are flill warm, which con- tinues to be the cafe the next morning after diftillation, in confequence of the heat of the fand bath. If they be left to cool entirely, the fulphate of foda will cryftallize, and it will be neceffary to dilTolve in hot water fuch larger portions as cannot pafs through the neck. But this inconvenience is not likely to happen, unlefs the quantity of water laft added be too fmall, and the refidues have been left undif- turbed for feveral days. The fame obferva- tion is applicable to that kind of incruftation which is formed by the muriate, if not properly pulverifed, dried, or mixed ; this cannot be fepa- rated from the bottom of the retort, but by means of hot water poured at different fuccef- five times. It is like wife effential to leave no crufl: or depofition of muriate, or other matter, in the veflels which are emptied, unlefs the fame be moveable, in which cafe the rifk is lefs. But if the urgency of bufinefs mould then re- quire that the fame veflels be ufed without en- tirely 64 The Art of Blenching tirely clearing them, it will be neceffary to range this refidual matter on one fide, where it will be lefs expofed to the heat, and will afford a greater degree of facility for the nitric acid to acl upon it. In order that the vapour which exhales from the diftilling veflels may not prove inconvenient* it is necefiary to pour in a fmall quantity of al- kaline lixivium in the firft place, which inftantly deftroys the fmell. This may be done imme- diately after the end of the diftillation, and the weak alkaline folution may fupply the place of the water ufed for diluting the refidues. At the inftant of pouring this lixivial water, a ftrong effervefcence takes place ; for which rea- son it is proper to pour it in by feveral fucceflive portions, waiting a little between each time. The oxygenated muriatic acid obtained in this manner has a moft keen and penetrating odour. It cannot be breathed even for a few inftants, without the danger of a moft obftinate and violent cough. Its aclion is fometimes fo flrong that the operator will fall down fenfclefs, if he fliould determine to continue his work with his nofe over the veflels. Running of the nofe, afthmatic affecYion of the breaft, headach, tears and fmarting of the eyes, bleeding at the nofe, the fenfation known by the name of the teeth Cottons, Thrtad, &c. $j teeth fet on edge, pains in the fmall of the back, and even fpitting of blood, are the ordinary in- conveniences to be expected, when the pure oxygenated muriatic acid is ufed as is prefcribed in the /Innales de Chimie. It is even impoffible to Tupport for feyeral fucceffive days an em- ployment fo deftru&ive to the health, if the lutes be not carefully attended to, and the vef- fels for immerfion of goods be not covered and placed in a med, through which a ftrong cur- rent of air pafTes. I am moreover perfuaded that there is not, perhaps, any perfon who has fuffered fo much as myfelf in this refpecl, on account of the earneftnefs with which I at. tempted to bring this procefs of bleaching to perfection, or rather to make it more generally ufeful. The ftrong expectoration to which I was expofed, agitated the fyftem fo much, that I found it impoffible to retain any food on my. ftomacb, and was for forty-eight hours, without intermiffion, not only deprived of fleep, but con- tinually emitting faliva, with acid and corrofive humours from the eyes and nofe in fuch abund- ance, particularly from the eyes, that it was fometimes five or fix hours before I could open them to fupport the light. My fituation, at thofe periods, was fo difagreeable, that I could not lie a moment on my back, and a very fhort F tim 66 The Art of Bleaching time on my fide. The ereft pcfition was leafl painful j but I was foon obliged to fit or lie down, in confequence of the pain I felt, at every attack of the cough, in the mufcles of the back and thighs. The difficulty, or rather the impoffibility, of fupporting fuch painful exertions for any length of time, induced me to contrive a mafk of card, with glafs eyes, which allowed me, for a certain fpace, to work with my face over the veffels for the immerfion of goods, to turn, prefs, and wring the pieces without fear of any ferious inconve- nience. I likewife occafionally made ufe of a handkerchief, moiftened with alkaline lixivium, which I bound round my head to defend my nofe and mouth from the effect of the odour, but thefe means were merely palliatives. As it is of great confequence that the opera- tor mould be defended againft fuch accidents, or at leaft be able to diminifh their confequences, it may be of fome advantage to know, that X have had the pleafure to experience, that the black extract of liquorice, which I chewed be- fore I expofed myfelf to refpire this vapour, almoft always pfoduced a good effect, by di- miniming the cough, and in fome inftances pre- ferving me from it. I therefore was particularly careful to ufe this extract, previous to expofing myfelf Cottons, Thread, &c. Cy myfelf to the danger of refpiring the gas, at the fame time taking care not to omit the ufe of my moiftened handkerchief, or mafk. A folution of fugar in warm or cold water, fipped or drank flowly, likewife appeafed the cough very much after a certain time. The warm folution was rather the moft effectual. I likewife occafionally fipped or drank milk for the fame purpofe. Being at length, however, worn out with fuffering, and unable to purfue my experiments on bleaching with the requifite convenience, I endeavoured to make the acid without fmell, avoiding, at the fame time, any confiderable in- creafe of expence. The following procefs fuc- ceeded bell of any that I tried. It confifts fimply in adding to the quantity of water pro- per for each pneumatic veffel, a quarter of a pound, at moft, of carbonate of pot-afh, or of foda, for every pound of muriate of foda which has been taken in the mixture of the matter for diflillation. This quantity is fufficient, abfo- lutely, to prevent the fmell of the acid, and per- mit the operator to work with his face uncover- ed over the neutralized fluid, without rifking the fmalleft inconvenience. The water may be difpofed, for this purpofe, in two different man- ners ; either by previoufly diflblving the clari- F a fied 6S The Art of Bleaching fied pot-alh in the refervoir of water appro- priated to fill the vefTels, or it may be fimply poured into the latter vefTels after it has been difTolved, fettled, and drained by itfelf. This latter method is preferable to the other. For this purpofe, after having difTolved the alkali in a fmall portion of water, it is to be poured in at different times at the commencement, and towards the end of filling the pneumatic vefTels. Thefe precautions muft be more efpecially at- tended to when the vefTel has falfe bottoms, be- caufe the folution of pot-afh, in that cafe, mixes lefs readily with the water. I muft here re- mark, that the falfe bottoms, inftead of being placed horizontally, muft be fomewhat inclined towards that fide, in which the aperture of com- munication, through which the gas pafles, is made. This inclination prevents any of the fluid from remaining in the vefTel at the time of drawing off, which might happen if there were not a decided flope towards the place of com- munication. If it fhould, however, be defired to prepare a folution of pot-afh proper to fill the vefTels, it muft be diluted till it marks no more than one degree beneath zero on the areometer of MofTy already mentioned. But this arrangement is attended with trouble, and requires more vef- Tels, Cottons, Thread, &c. 6f fels, and confequently more room, without pro- ducing any advantage fuperior to that which is derived from pouring the ftrong folution of pot- afh to the water at the time of filling, according to the directions already given. It fometimes happens, that the laft portions of the impregnated fluid, at the time of drawing ofF ; have a flight degree of fmell ; either becaufe the agitators have not been fufficiently attended to, or becaufe the falts are conftantly difpofed to fall to the bottom of the veffel. To avoid this inconvenience, about a fourth or an eighth part of the alkaline folution may be referved, not to be poured into the veffel till half an hour before the diftillation is (topped. The agitator is then to be turned, and the fuperior liquid will be without fmell as well as the reft, be- caufe the combination takes place inftantly. The fame effect will follow, if the folution of pot-afh be put into the bottles or veffels ufed to draw off the liquid : nothing more being re- quired in this cafe, than to pour a few glaffes of the lixivium into the receiving veffel, which, when filled, mult be covered up or corked. In order that the feparate folution of pot-afh, which is poured into the pneumatic veffel at the time of filling it with water, may not be fubject to Remain in part upon the falfe bottoms, to the F 3 prejudice 70 The Art of Bleaching prejudice of the water beneath, it is poured through wooden or leaden pipes, terminating above in a conical part or funnel, and of fuch a length as refpeclively to communicate with the feveral cavities into which the veflel itfelf is divided. By this expedient it is rendered cer- tain, that the pot-afh, which is required to be depofited in the feveral compartments, will be fpecially poured into each. But as the alkaline folutk-n does not immediately and intimately mix with the whole of the water, but is dif- pofed to flow infenfibly from the upper com- partments to the lower, by reafon of its weight, care muft be taken to pour no greater quantity into the loweft compartment than four-fixths of the faline folution, referving the two other fixths for the fecond or firft compartment, and forbearing to pour them in till the whole, or at leaft the greatefl: part of the water has been poured into the veffel. The neceffary attention for diftilling the acid, as well as the dofes of the materials, are the fame whether the odour be prevented or not. The only difference confifb in their effects, as we fhall hereafter fee. The colour of both folutions is abfolutely the fame. That which contains pot-afh feems rather Iefs limpid, par- ticularly the firil portions drawn off, on account of Cottons, Thread, fcfo 7 x of the faline deposition which is ftirred up by the rapid motion of the fluid as it iffues out. A fimilar effeft happens when the veflfel has been newly painted ; in which cafe, the liquor decompofes the paint by feizing the oil, and from this caufe flows out with a foapy, or milky appearance. Inftead of pouring the pot-afh into the veflej, as has been defcribed, I have very often ufed the following method. To prevent the effluvia from rifing from the veflfel in which the goods were to be immerfed, I Amply poured my folu- tion of pot-afh into one or two pots, and after- wards fprinkled it upon the furface of the li- quor contained in the bleaching veffel. This afperfion was fufficient to check the fuffocating exhalation of the muriatic acid gas. I fre- quently ufed powdered chalk for the fame pur- pofe, and with equal efFe£t. I muft obferve, that I did not refolve upon making this new liquor without fmell, until after I had repeatedly afcertained, that it is im- poffible to refift, for any length of time, the dif- ficulties which refult from the method and the jproportions defcribed in the Annates de Chimie. I am even of opinion, that this method of bleach- ing would be renounced altogether, if the ope- rators were literally to follow thofe inftruclions F4 7 2 The Art of pleaching in preference to my method, or fome other me-r thod on fimilar principles. ' I muft particularly remark in this place, that the agitator muft by no means be neglecled. It is necefiary to turn it feveral times together at the end of every half or quarter of an hour, to favour the abforption of the gas in the water, and to deftroy its odour by facilitating its com- bination with the pot-afh. If this be not done, in cither cafe, the gas beneath the firft falfe bot- tom will pafs too fpeedily into the fecond. This pafTage muft be prevented as much as poftible, until it is fuppofed that the water in the lower compartment is nearly faturated. It muft alfo be remarked, that when a pneumatic veflel has once been ufed to make one of thefe liquors, it muft not be changed in its application ; for nothing more fpeedily de- ftroys the veflel and the agitator, than alternate- ly ufing them for both. On the contrary, when the fame veflel- is conftantly ufed for the fame liquor, the action of the muriatic acid is fcarce- ly, in any refpecl, perceptible. Laftly, I muft remark that the ftrength of the liquor may be increafed at pleafure, as Ber- thollet alfo obfervcs, by putting lefs water into tbe veffels. I have feveral times obtained it at fuch a degree of concentration, as to mark be- tween. Cottons, Thread, &c, 73 twcen ten and twelve of the areometer of MofTy. In this (late i*s colour was evidently of a lemon yellow, a little inclining to green. This liquor contained no pot-am, and was de- figned for particular ufes. CHAP 74 The Art of Bleaching CHAF. VII. Concerning the alkaline Lixivium or Lees, ' JL HE method of making the lees is not a matter of indifference, whether we attend to the faving of time, or of alkali. The following is that which I would, from my own experience, advife, and which I have fince learned is the method ufed in Ireland. It is well known, that the white colour of the Irifh linens is highly ef- teemed. The method has always fucceeded perfectly well with me. Upon a kind of iron platform, compofed of two or three concentric rings, connected to- gether by crofs pieces of the fame metal, as may be feen in the figures, i, 2, 3,4, Plate III, which refts on the bottom of a boiler fet in a furnace for the faving of fuel, are placed the piece-goods, thread, &c. in folds or parcels, When thefe different kinds of goods are to be immerfed together in the alkali, the piece-goods muft always be placed at the bottom. When the boiler is thus charged, the alkaline folution, at the ftrength of a degree and a half under zero of Cottons, Thread, &V. 75 of the areometer, muft be poured in till the mafs of goods are foaked, and covered to the depth of at leaft an inch or two without preffing them too much down. Or the alkaline folution may- be poured in, accordingly as the goods are placed in the copper. This lafr. method would be pre- ferable, in my opinion, in all cafes where there was no reafon to fear that the goods might lie too clofe. To prevent thefe from rifing and floating above the furface of the lees, a flat cover is fitted to the boiler, which ferves to re-r tain the heat, and prevent any dirt from falling upon the goods. A judgment is formed that the pieces are in, a ftate to be taken out of the fluid, when this laft under the cover in the middle of the heap is too hot to admit of the hand being held in it, pr when it fimmers round the circumference of the boiler and throws up white bubbles, which circulate towards the centre. It is not neceffary that the lees fhould boil ; the effential conditions are, that it fhould be fufflciently ftrong, abun- dant, and hot ; and that it fhould properly pe- netrate the goods which are fubmitted to its action. I have frequently thought it fufhcienr, between the two immerfions in the bleaching liquor, to plunge the goods (previoufly wafhed and ftraitened out) for a few minutes into the lixivium* 76 The Art of Bleaching lixivium, which was very far from pofleiTing the degree of heat above mentioned. The cloths and piece-goods, which were treated in this manner, bleached perfectly well. In order to obtain a criterion refpecling the time confumed in one boiling of the lixivium, I mult obferve, that 3,600 French pints (or about 900 Englith wine gallons) of the alkaline folu- tion, in a boiler fet in the manner juft defcribed, will be rendered juft boiling hot in three quar- ters of an hour at moft; and if pit-coal be ufed, the quantity of fuel required, for this pur- pofe, will be one-third part lefs than if wood be ufed. When the goods are to be taken out of the copper, the cords or chains which are fixed to the exterior circle of the ftage are to be raifed, and hooked to the fall or rope of a crane placed on one fide of the boiler ; by turning which crane the whole of the goods are raifed out of the copper, and after they have drained for a certain time, the mafs is conveyed and placed upon two crofs-pieces over a tub defigned to re- ceive the fubfequent drainings ; after which, the feveral pieces are prefled or wrung, and after- wards rinfed in a ftream, if the manufacturer poiTeffes that convenience ; or, otherwife, they are warned by means of the revolving cy- linder, Cottons, Threap &c. 77 linder, or other machinery. Thefe operations are to be repeated as often as the goods are taken out of the alkaline lixivium, according to the nature of the merchandize ; for it may eafily be imagined, that piece-goods, hofiery, and thread, will require different kinds of manipu- lation. As it is of effential confequence to lofe as little as poffible of the lixivium in this procefs, it will be proper to wring or prefs the goods before they are rinfed. Piece-goods may be advantageoufly wrung by means of a fixed hook, and a handle or wooden crofs, to which a fimilar hook is adapted that moves with the handle. See Plate IX. fig. 9. Thefe hooks being placed refpe&ively at the two fides of a trough intended to receive the wafte lees, the piece it- felf muft be palled and repaired a number of times over the hooks, as is reprefented in the figure, until either the whole piece is thus wound up, or as much of it as can be con- veniently wrung at a time. With regard to thread, it may be prefTed or wrung with the pin ; and hofiery may be treated in the fame manner. But it is more advifable to wring this laft article feparately by hand, un- lefs the operator poflefTes a prefs fuited to both the laft-mentioned articles. By this engine the goods' 7$ The Art of Bleaching goods may be cleared of the alkaline lee, with more eafe and expedition, and with much lefs injury. In order to economife the fire in the fufion of the alkali made ufe of in new lees, as foon as the old has been drawn out of the boiler, which may be done by means of a fyphon, or a cock, as may be moft convenient, the neceflary quantity of water may be immediately poured in with the pot-afh or crude foda broken in fmall pieces, if the purified fait be not ufed. In this manner the folution may be accomplished for the following day. The heat of the boiler, and its fire-place, fuppofing a fmall quantity of the fire to remain, the regifters of the furnace being fhut, and the boiler covered up, will be fufficient to melt the alkali in the courfe of the night. It is neceflary to break the pot-afh into pieces of the fize of a nut before it is thrown in, particularly that kind which is known in France by the name of pot-afh of York, the pieces of which are as hard as ftones, and can- not eafily be broken but by a mallet upon a ftone pavement. The Spanifh foda is equally hard. The method of pafling the goods through the heated alkaline lixivium, as here defcribed, is particularly fuited for works upon a large fcale. But Cottons, Thread, Sfa, 79 But when the manufacturer intends to confine himfelf to the bleaching of fmall articles, fuch as hofe, night-caps, thread, &c. without med- dling with the larger piece-goods, it will be equally advantageous to uie a fimple boiler, pro- perly difpofed in a common fire-place, with a barrel and winch above it, as is exhibited in Plate II. fig. 4, 5, and 6. For the faving of fuel, this boiler maybe fet in brick- work ; and like the great boiler before defcribed, it may have a fur- rounding cavity for evaporating the old lees, which will be very ufeful if it be no more than four inches in height, and of the fame width. New lees, which have already been ufed for the immerfion of one piece of cloth, are not to be rejected on that account; As the folution lofes fomewhat of its ftrength on account of the matter which it extracts from the cloth, and with which it enters into combination, it muft be reftored by adding one-third or one-fourth of lixivium from the refervoir, which likewife fup- plies that portion which was carried away in the goods, and partly recovered by draining, rinf- ing, or preffure. The firft lixivium, after two boilings, can only be poured on dyed goods, be- caufe it is then loaded with extractive matter, which in a great meafure faturates it, and ren- ders it black and vifcid to fuch a degree, that it fome- 8o The Art cf Bleaching fometimes takes a curdled or gelatinous appear- ance on cooling. The fecond lixivium may commonly be ufed three or four times for the fame objects, taking care to flrengthen it every t m with one-third or one-fourth part of new lees ; after which it is to be thrown, like the others, into the refervoir. The third and fourth lixiviums mav likewife be ufed feveral times, but without adding new lees, be- caufe they take up but little colouring matter; It is eafily afcertained by the tafte, whether they have any remaining active faline parts. Many perfons, particularly laundreffes, afcertain whe- ther their alkaline lees has loft its force, by rub- bing it between their finger and thumb. They eftimate its quality according to the degree of lubricity it exhibits. The quality of the two fTrft lixiviums may be afcertained to a certain point by the ufe of the areometer. When they mark three degrees under zero, they are cer- tainly too much loaded with extractive matter, and w T ill produce no other effect on the goods, than to give them a brown colour, to the abfo- lute lofs of time. It is advi fable to keep the lees at the fame degree of force, either by ad- dition, or by changing them altogether, for the firft two or three immerfions of the fame goods ; diminiftiing the ftrengtbj however, one-third or one- Cottons, Thready &c. 8t one-fourth as foon as the pieces have acquired an uniform colour, which will happen, at fartheft, at the fecond immerfion in the bleaching liquid. When the goods have arrived at this ftate, weaker lixiviums may be advantageoufly ufed, becaufe there remains fcarcely any thing more of impurity to be carried off ; and the fubfe- quent procefs may be confidered merely as a brightning of the colour, by detaching the fmall portion of impurity which may remain fixed in the texture of the thread itfelf. The old faturated lees bein£ taken out of the boilers, are to be added to the other lees of the fame kind, arifing from the drainings into refer- voirs appropriated for that purpofe. This fluid is of ufe to foak piece-goods or thread, in or- der to clear them of their drefTing, or the im- purity attached to the latter during the {pin- ning. With regard to the lees which are ob- tained by preffure or wringing of the goods, if they be not too highly coloured, they may, as well as all the others, be added to the lees in the boiler. As foon as one boiling or immerfion is made, if the lixivium be in a good ftate, whether by the addition of frefh lees or not, the next im- merfion may be immediately proceeded upon in order to take advantage of the heat, in cafe « the Sz The Art of Bleaching the courfe of bufinefs requires it ; but for this purpofe it is neceffary to have another frame or platform ready prepared, with the proper quan- tity of goods for immerfion. But if there only remain a fmall number of pieces which require to be plunged in the alkali, they may be thrown into the fame bath without reftoring it, or even heating it up again. Nothing more will be ne- ceffary than to cover up the boiler, and leave the goods immerfed for a fufficient time, that they may be well penetrated with the alkaline folution. I have often found this manner of proceeding very convenient for piece-goods, hofe, or thread, in fmall quantities, without making ufe of the frame or platform. It muft not be overlooked, that whenever the goods are taken out, the copper muft be exa- mined with a ftaff, in order to difcover and take out any fmall articles which might be forgotten, and would be in danger of burning if they were to remain at the bottom of the copper during the time of the fubfequent procefs or charge. It muft alfo be remarked, that it fcldom hap- pens that any piece which may have been fub- je&ed to two frefli fucceliive lixiviations, even though it may have been a dyed piece, will re- ceive any advantage from a further repetition. The third immerfion, to which it might be fub- jecled, Cottons, Thread, &c. 83 je£ted, with the hope of clearing it of an addi- tional portion of impurity, will be found to pro- duce fcarcely any effect, and the liquid will take up little or no colour. It fometimes happens, that the fecond lixivium, even though of con- iiderable flrength, is equally ineffectual. It is of great importance that the alkaline lees mould be always as clear and limpid as p*f- fible. Their value may be eftimated by ob- serving the readinefs with which they abforb the colouring matter from the goods. The tubs, in which they are kept, ought, therefore, to be made of fir ; becaufe thofe of oak, or chefnut, though very carefully treated with lime water, always become more or lefs coloured in procefs of time. It is true, that the colour of the lees is of, comparatively, little confequence for the firft two or three immerfions of dyed goods [des pieces bifes). But this is not the cafe when the goods have once acquired an even colour, and require only to be brightened. It is then highly effential, for the faving of time and la- bour, that the lees fliould be as clear and limpid as pofiible. The new lixivium, or lees, is good whenever it marks one degree and a half beneath zero j and 1 have obferved, that it is not necefTary it lhould be ftronger. At a higher degree of o 2 firength, 84 The Art of Bleaching ftrength, it would foon become as foul or co- loured as the weaker folution ; and it is ufelefs to confume the alkali to no purpofe, and com- municate a dark colour to the goods, which by that means become more difficult to wafh or rinfe. Care mult alfo be taken to rinfe them after the lees, until the water, if the opera- tion be performed in the warning apparatus, flows off very clear ; or, on the contrary, if the goods be expofed to a dream of water, they muft not be taken out till it has been afcer- tained, in various parts of the pie'ces, that the water, upon wringing, comes out very clear. If this precaution be not attended to, the pieces, thus imperfectly rinfed, would be in danger of becoming yellow inftead of white, by immerfion in the bleaching liquor ; and even to acquire a very tenacious and difagreeable ruddy tinge, either partially, if the rinfing have been partial, * or totally, if it have been entirely neglected. The activity of the fixed alkali, or pot-afh, may be increafed, by throwing into the boiler in which this fait is put for folution, one-third or one-fourth of its weight of well burned and very white lime, of the belt, quality ; which is to be tied up in a bag or cloth. By this management, the calcareous earth is lefs capable of render- ing the lees turbid ; or if it mould efcape, it will fall Cottons, Thread, &c. 85 fall to the bottom when the folution cools. The lime may alfo be feparately diffolved or diffufed, and the pot-afh diffolved in this folution inftead of pure water ; a method which may be prefer- able to the other. It is fcarcely neceflary to add lime to the foreign pot-afh, moil of them contain a certain quantity ; particularly thofe which are imported from the north of Europe, or from America. The ufe of lime has appeared to me to pro- duce a greater effe6t at the commencement, than towards the end of the bleaching. At this latter period, the different operations to which the merchandize has already been fub- je£ted, the caufticity of the lees, and the fmall grains of calcareous earth which they may con- tain in fpite of every precaution, would be likely to impair the ftrength of the goods, particularly during the operations of wringing, or the prefs. But the ufe of lime has appeared to me to be pf advantage at the beginning, becaufe I have found reafon to conclude, that the goods which are thus treated acquire a decided whitenefs in lefs time than the others. As it may happen, that the boilers ufed for the lixiviations may leak at the place of the rivetting, and manufacturers may find them- selves embarraffed at a diflance from proper g 3 work- 86 The Art of Bleaching workmen, I conclude, that the following method of repairing them may be acceptable. It con- fines in beating a certain quantity of lime, flaked by expofure to the air, and fifted with a fmall quantity of the white cheefe called a la pie*. The mixture is to be ftirred or beaten without ceafmg ; and the lime muft be fucceffively added, until the mixture begins to acquire a certain confidence. The damaged part of the copper being then well cleaned and wiped, this cement is to be very firmly applied, fpreading and ex- tending it at the edges as well as poilible. The cement foon hardens, and the copper may be ufed as before. By this means every kind of fmall fra&ure, or opening, may be eafily flopped without difplacing the boiler. The fame kind of lime fifted, and mixed in a fimilar manner with leaven, may be ufed with equal advantage. I have had occafion to ufe both thefe cements, and it appears that the falts exercife no a&ion upon them ; or, if they acl at all, it muft be in a manner fcarcely perceptible. As it may be of advantage, in certain places, inftead of ufing pot-afh, to give the preference * I am not acquainted with this kind of cheefe ; but it may eafily be fuppofed, that experiment will point out, which of the feveral kinds the manufacturer may have at his dif- pofal may be the beft. I fuppofe a very fmall quantity of water is to be added.— T. in Cottons, Thread, &c. 87 in France to the alkali, known by the name of /alia, which can now be bought one-third part cheaper than formerly, before the impoft of page was fuppreffed ; I fliall defcribe the manner of calcining it, in order to deprive it of the colouring matter with which it is combined. The common baker's oven may eafily be ufed, at leaft pro- visionally, inftead of a calcining furnace. It is to be heated as if for bread, taking care only to place the wood on one fide, in order that the part of the floor which remains free, may be wcli heated by the circulation of the flame. The crude falin is to be thrown into this vacant part by means of a fliovel or any peel ; for which purpofe, the common peel, belonging to the oven, may anfwer very well. The alkali may, without inconvenience, be difpofed to the height of two or three inches over the whole clear fur- face of the floor of the oven, as far as to the diftance of five or fix inches from the mouth ; and in order that the coal of the finall wood may fall thereon as little as poffible, by fpark- ling, rolling, or bounding, the largeft pieces, or faggots, muft be placed neareft to the fait. At the commencement of the operation it is neceffary to turn up the alkali, and renew its Surfaces from time to time ; for which purpofe, vhe bended part of the poker may be very ufe- g 4 ful. 88 The Art of Bleaching fill. This precaution is the more effentia], be* caufe it prevents the fait from adhering to the bottom of the oven by the aqueous fufion. Some famples of this fait, at the firit impreilion of the fire, decrepitate more or lefs, which arifes from the muriate of foda, or fulphate of pot-aih, which is almoft conftantly found in every kind of incinerated vegetables ; and it is fometime3 the confequence of adulteration, to which that of Lorraine is more particularly fubject. Thq oven is to be more and more heated, and the fait ftirred until it ceafes to emit fumes, and be- gins to lofe its fmoaky or black appearance, and becomes white throughout internally, as well as externally. When the fait is firft put into the oven, the heat ought not to be greater than for baking bread. It may be of advantage to begin the operation immediately after the bread is drawn, becaufe ihe heat which is already in the oven, will render the confamption of fuel lefs than would otherwife have been required for the cal- cination. After the fait has once become white, the fire is to be kept up as fteadily as poffible, with- out increafing it ; and the greater!: care muft be taken, left the fait, by too ftrong heat, fhould form itfelf into clots or malfes. Whenever this happens, Cottons ', Thread, &c. - 89 happens, the pieces mult be broken fmall with the rake or poker ; for the internal part of fuch Jumps, though white on the outride, would very probably retain its dark colour. If the fait be imperfectly, or not at all calcined, it will afford a folution of a yellow-blackiih colour, fimilar to that of old lees highly charged with colouring matter, as is the cafe with that which has been ufcd for the firft immerfion of piece-goods, or thread. The effeft of fuch a folution would be very different from that of the clear and limpid folution, which it is abfolutely neceffary to pre- pare for thefe operations. When the fait appears white throughout, and ignited in certain places, when it is turned oveiy it will be proper to take it out of the oven. The fire is then to be gently diminifhed till no more combuftion remains than is convenient to give light for drawing out the fait. The latter is then to be drawn with an iron rake, or the bended part of the poker, to the mouth of the oven ; where it may be received in troughs of (lone, or plate-iron, or caft-iron pots, of fufficient fize to contain the whole. The fire may be fuf- fered to decay, until the oven mall have ac- quired the proper temperature to begin the fecond calcination, if required ; which is to be managed as before, taking care only, that the fait 90 The Art of Bleaching fait be rather more frequently ftirred at the commencement, becaufe the floor of the oven is always fomewhat hotter than at the commence- ment of the firft calcination. The operator muft alfo endeavour, as much as he can, to pre- ferve his alkali from the fmall pieces of char- coal which fly in fparks from the wood, though thefe are not abfolutely of much confequence, becaufe they fwim on the furface of the water in which the calcined fait is afterwards dif- folved ; in which fltuation they may be taken off" with the fcum which ufually rifes from this fait, though in lefs quantity than from the or- dinary pot-afh ; which laft fait is expofed to a itronger heat, and is ufuallv mixed and calcined with calcareous earth, or other earthy matter, either to increafe its caufticity, or to add to its weight. The coal and the fcum obtained in this folution, are not to be thrown away, but may be difpofed upon a cloth or fieve over the refervoirs containing the new lees. As thefe fubftances retain a fmall quantity of fait, it is advifable to pour water upon them feveral times ; after which, they may be thrown into the oven at the next calcination. If the calcination of this alkali be carefully managed, there will be no incruftation upon the pavement in the oven ; but if that event lhould happen, Co! Ions, Thread, &c. 91 happen, the oven would not be lefs proper for baking bread. The only effect it will have upon this article of food, would be, that the bottoms of the loaves would be rendered more uneven. Thefe incruftations may eafily be removed by ftriking them with a hammer while they are flill hot, or by raking them off after the oven is cold, and the alkali has began to attract the humidity of the air. In this ftate the flighteft blow will detach all the faline incruftations, which may have fixed themfelves to the pavement of the oven *• The Jalin lofes twelve or fifteen per cent when thus converted into pot-alh, accordingly as it is more or lefs humid at the time of calci- nation. The procefs here defcribed, is practicable by women as well as men. The whole was ex- * In the fecond year of the French republic, I had occa- fion to direct my attention particularly to the inquiry after certain fubftances proper to afford alkali by incineration; that of the marc or (talks of grapes appeared tome, among others, to deferve the notice of thofe who are engaged in the manu- facture of pot am. I have, therefore, inierted at the end of this work, the two memoirs which I at that time addretfed to the different committees of the national convention, which were fpeciaily charged to excite the zeal of the citizens to- wards the molt proper means of fupplying the faltpetre works with the requifite quantity of vegetable alkali. ceedingly 92 The Art of B leaching ceedingly well managed by a woman, to whom I gave inftru6tions. In an oven capable of bak- ing two meafures of flour, each weighing twenty- five Paris pounds (or twenty- feven pounds avoir- dupois), an hundred pounds of alkali may be eafily calcined, in three or four hours, at a fingle heat, at no greater expence than twelve or fifteen fols, in fuch wood as is ufed by the bakers. After this defcription of calcining the impure alkali, it mav not be amifs to point out the me- thod of obtaining the alkali from the old lees, which were formerly thrown away. For this purpofe, I prefer the following method. In- ftead of covering with mafonry, or brick-work, that fpace which remains above the nanch or horizontal part of the boiler for lixiviation, an additional piece is to be applied round the cir- cumference, fo as to form a circular cavity or external boiler. The heat which this channel undergoes from the continual action of the flame beneath, very fpeedily evaporates the old lees, with which it is for that purpofe filled. When the lees are thus rendered very thick by evapo- ration, they are conveyed to a boiler, or pot of caft-iron, properly placed upon a calcin- ing furnace; fee Plate III. dcr. j y 8, 9, io, and 11. The lees muft not be fiiffered to become entirely Cottons, Thread, &c. 93 entirely dry in the circular cavity, which fur- rounds the great boiler, left the copper fhould be burned or oxyded. The old lees, when brought to a pellicle in the evaporatory apparatus firft mentioned, are, as already obferved, to be conveyed to the boiler of caft-iron, where they may be heated to dry- nefs without any danger of breaking the veffel ; particularly if it be made of foft grey iron. The refidue muft be ftirred as frequently as polfible, efpecially towards the end of the procefs, in order to prevent the fait from adhering ; which, in that cafe, would render it neceffary to dW it out with a chiflel and mallet, unlefs there were time for it to foften by the humidity of the air ; or the operator might choofe to fprinkle it with water to produce the fame effect. In order to take the utmoft advantage of the heat of the evaporating apparatus, it muft be duly fupplied with lixivium as foon as that which has been evaporated to a pellicle is taken out; and in cafe there fhould be no foul lees to evapo- rate, it will be proper to fill the external channel with water, to prevent the copper from burn- ing. This hot water may be drawn off for ufe, by means of a fyphon or cafk, when required. The heat which is carried up the chimney may alfo be converted to an ufeful purpofe, by placing 94 3Tfe Art of Bleaching placing another fmall copper over the flue, into which the old lees may be put ; where they will obtain a certain degree of concentration previous to conveying them into the circular channel. In this laft veffel they will be (till farther concentrated, previous to the laft evapo- ration in the iron-pot, in which they are reduced to the irate of pot-afh, or JaUn. This feries of veifcls may be ufed with great profit and advan- tage. o CHAP. Cottons, Thread, &c. 05 CHAP. VIII. RefpeSiing the Preparation to be given to the various kinds of Goods. T, HE preparation necefTary tQj.be given to piece goods, before they are immerfed in the oxygenated muriatic acid confiits, firil, in {bak- ing them about twelve hours in water to dif- folve, and clear off the dreffing, which is ufually either common (larch, or thin parte of flour. If the piece be foaked in a trough, it mull be dif- pofed in very open folds, and covered with water. If the foaking be performed in a river, or ilream, it mult be expofed to the current, after having fattened it to a poll fixed for this purpofe. It would be much better to form a kind of refervoir, defended all round by planks, as well as at the bottom, in order that the pieces might fwim therein, without being expofed to damage or dirt ; and the water might pafs in and out by two fluices. When the goods have foaked for a convenient time, they are taken out fold by fold, and then preiTed or wrung by the wring, fig. 9, PI. IX ; or, if time permits, they are fuffered to drain on the horfe. With regard to 96 The Art of Bleaching to the goods foaked in troughs, as the water be- comes very foul, it would not be amifs to foak them again in frefh water till the fluid comes off very clear. In fact, there cannot be too much attention paid to clear the goods perfectly of their dreffing. This previous treatment difpofes them for the fubfequent operations, by render- ing the extractive colouring matter more eafily to be difcharged. A fulling-mill would be very ufeful for thefe workings and rinfings. The fecond operation to which the piece- goods are to be fubje&ed, is that of maceration ; which confifts in foaking them in old lees which has been ufed, and is referved for this purpofe. In the macerating troughs the pieces are like- wife to be difpofcd in folds ; not only becaufe they occupy lefs room, but likewife becaufe they will be lefs preffed together, and the maceration will be more equally effected. The quantity of lees muft be fufficient to cover the goods ; and in order that thefe may not rife above the fluid, they may be preffed down by means of loaded planks, or which is ftili better, by pieces of wood capable of being fixed fo as not to prefs the goods, but Amply to prevent their riling above the furface. In this fituation they muft be left for at leaft forty-eight hours, even in fummer, without any fear of inconvenience. For greater certainty Cottons, Thread, &c. qj certainty, however, this procefs may be managed according to the heat of the atmofphere. It is known that the maceration operates in a proper manner when the lixivium is covered with an infinity of white bubbles, and begins to emit a fetid fmell ; and the piece-goods have aflumed a clear yellowifli ruddy colour, inftead of the grey or dark colour they had before their kn- merfion. This, at leaft, is the cafe with almoft all the linens of Picardy, in confequence of the fpreading of the linens in the field, where the impurities are fo far from being detached, as when the clearing is performed in water, that they become fixed, and acquire more colour. This maceration is accelerated if the lixivium be ufed hot, as it is when rejected from the boilers. It would fcarcely be imagined how much the maceration in the old lees, when thus managed, advances the bleaching of the goods. It anfwers the fame purpofe as two immerfions in the copper ; whence it is evident, how much it faves of time, labour, and expence. Inftead of macerating the goods in the old lees, I have fometimes ufed with advantage a cold bath of lime water, or milk of lime. The grey piece-goods when deprived of their dreffing, or even without that previous preparation, were plunged in this liquid? and after having re- mained therein no longer than five or fix hours, h thev 98 The Art of Bleaching they were taken out, of a ruddy yellow colour, and in a proper ftate for the aclion of the lixi- viums. In order that the pieces fct to macerate may not be too clofely prefled againft the bottoms of the veffels, bundles of white ofier twigs, or merely flicks deprived of their bark and laid acrofs each other, may be difpofed upon the bottom. The fame remark is applicable to the firil foaking, required to clear them of the drefl*- ing. This firft operation is performed merely to fave the lees, for when the operator is preffed for time, the foreign matter contained in piece- goods, that is to fay, the faliva of the fpinners, and the ftarch of the weavers, is cleared off as perfectly as in the old lees when the goods are fubmitted to maceration. When the maceration is carried to the dclired point, the lees are to be drawn off, the goods taken out, and wrung or prefled in the manner already defcribed, and rinfed in the ftream, or in a veflel where it may be worked until the water, which is repeatedly poured on, comes off clears or, in preference to this laft procefs, the goods may be paffed through the fulling appa- ratus, if the manufacturer poffeffes one. See the plans and parts of this mill in the Plates IV. and V. After the fulling or rinfing, the goods are left to drain on a proper ftage, or preffed or wrung Cottons, Thread, &c. 99 wrung to fuch degree that they may remain only moift or humid. For too great a quantity of water if retained would weaken the aftion of the oxygenated muriatic acid. If the operator do not poffefs the advantage of a fulling^ftock, but fimply that of a ftream of water, the warning of thefe piece-goods may be haftened, by beating them on a ftage, level with the furface of water, by means of dyers' fticks or poles, which are very well adapted for this operation. Care mull be taken that the troughs or other wooden veffels in which the goods are foaked or macerated, be clear of every crack or fplinter, otherwife there would be danger of tearing them in taking out, becaufe the fermentative procefs occafions them to expand and prefs againft the fides of the veffels. The obfervations we have made with refpe£i to piece-goods of linen or hemp, are alfo ap- plicable to thofe containing cotton, taking care to proportion the time of foaking and macera T tion to the coarfenefs or fmenefs of their tex- ture. Particular attention muff be paid after the rinfing or clearing of the piece-goods, fubfe- quent to the firft foaking or maceration, and even after the firft lixiviations or boilings, to rub H 2 them ioo The Art of Bleaching them well with black foap, and afterwards to clear them out, particularly along their felvedges; for this part, being always clofer than the reft, requires to be made very fupple, in order to open it to the aclion of the lees and the acid. Without this precaution it might, probably, be neceffary after the feveral operations to rub them feparately by hand, and the bleaching would be retarded by requiring feveral extraor- dinary immerfions to prevent thefe parts from being lefs perfectly white than the reft. If the rinfing and clearing be well performed at the commencement, the beauty and evennefs of the white colour, and likewife its acceleration, will be much promoted. It is alfo highly advan- tageous, particularly to fine goods, that the whole piece fhould be foaped and cleared after the laft lixiviation and rinfing, till the water flows off limpid. I do not hefitate to recom- mend this particular manipulation, as well after the maceration as after the laft immerfion in the lees, becaufe the whitenefs which it affords is proportionally more brilliant and folid. It is proper to add, that it will be likewife very ufeful to proceed with the fame attention and care in rinfing the goods after each lixivia- tion. This part of the work being well per- formed, has more effeel than is ufually fuppofed ©n CotionSy Thread, &V. ior on the folidity of the white colour in many- piece-goods which are efteemed in the market. Out of the various kinds I fhall only mention thofe called De Laval, which, after drefling, ex- hibit the mod beautiful milk white ; but which have the fault of not preferving it when they are brought into the ufual wafh, during the courfe of wear. This fault is particularly attributed to the expofure of the goods in the field, before they are properly cleared of the extractive matter detached by the lees. I forgot to mention, that for numbering and marking the cloths, red ochre {/anguine) may be ufed as well as lamp-black ground with oil ; but the mark traced with red-ochre upon a moiftened place, is more expeditioufly made, and equally tenacious. Linen, thread, hofe, mittens, and gloves, of the fame material, mud undergo the pre- parations of fteeping in water, and in the old lees, with the ' fame care. Sewing thread, hofe, and gloves, only require more time to arrive at the defired point in the lees, on ac- count of the firmnefs of their texture, which fwells confiderably, and acquires a degree of rigidity, that oppofes the extraction of the impurities which this operation is defigned to remove. Hj The 1 o 4 The Art of Bleaching The firft thing to be done in the management of thread, is to make good the faftenings of all the fkeins, large or fmall ; for there are many places in which the loops are either imperfectly or not at all fattened by the fpinners. As thread fwells up more than half its own bulk by wet- ting, it is neceffary to loofen all the faftenings already made, in fuch a manner that the thread may lie very loofe in the loop $ for if it were otherwife, there would be reafon to fear an in- equality in the bleaching. One perfon may loofen, and tie up again, all the fkeins of one hundred pounds of thread in a day, This is work for women rather than men. When the fkeins are made up, a firing is paffed through two or three fkeins, according to their thicknefs ; upon one end of which firing, a certain number of knots may be made to denote the owner of the article, whofe name is fup- pofed to be entered in a book oppofite the fame number. This affemblage of fkeins is called a hank, fee Plate II. fig. 1 1. An account is like- wife taken of the weight of the thread, and the number of hanks, togetherwith its quality,asmay be neceifery. Thefe. different obferyations muft be entered in the day-book as foon as the goods are received, for fear of omiffion or miflake. The fame care mull be taken to regifter the quality, Cottons, Thread, &V. 103 quality, number, and weight, of the piece- goods under the name of the proprietor. The firings for tying up the hanks ought to be previoufly boiled in water, as well for the purpofe of clearing them of the drefling, which the manufacturer may have applied for the pur- pofe of glazing them, as to render them fupple, and prevent their curling up when acled upon by the hot lees. The fame firings may be ufed for a long time. The foaking in water requires a lefs time for thread than for piece-goods, becaufe there is no drefling to be diffolved, but merely the impurity which it may have acquired during the fpin- ning. The thread is to be difpofed in layers in the fleeping veffelsj taking care to place the end of the firing of each hank upon the hank itfelf, in ord.er that there may be no difficulty in taking them out. It is likewife advifable, to place thofe articles together which belong to the fame perfon. Attention muft alfo be paid, to place a kind of bafket-work, as was directed with regard to the piece-goods, in order that the lower parcels while preffed by the upper may continue to be furrounded with water. Fine goods ought always to be placed the laft ; and in order that no part may rife above the furface, they muft be kept down either by a h 4 cover 104 The Art of Bleaching cover perforated with holes, or boards properly difpofed. Thread may Hkewife be foaked as well as piece-goods, by expofure to a current of water ; but for this purpofe it is neceffary to pafs the hanks over poles fixed beneath the water. When the thread has remained feven or eight hours in the water, it is eafily taken out after the water is drawn off. It may then be wrung on the pin, or preffed, after having been rinfed, if convenient, in clear water. It is then to be arranged in the fame manner, one ftratum crofs-wife over the other in the troughs for maceration, as has been directed for the freeping ; or, if the fituation and con- venience of the operator permit, it may be fuf- pended upon flicks. But it will require more time to macerate or heat in this manner, though the goods will by that means acquire a more equal colour. When they are fuppofed to be well cleared, as we have obferved refpefting the piece-goods j they are then to be taken out, wrung or preffed, then rinfed or warned in clear water, and wrung a fecond time, or hung up to drain. When the thread is wrung on the pin, care muft be taken to twift the hanks three times in three different parts of their circum- ference, drawing it out each time with as much ftraitnefs and equality as poffible, to difpofe and arrange Cottons, Thready &c. 105 arrange the threads. This operation is likewife neceffary for the perfect wringing out of the fkeins in every part. The precaution of extend- ing the hanks upon the pin for the due arrange- ment of the threads, is particularly neceffary for double thread, which is apt to curl up by the impreffion of the heat. If they be left in this fituation, there would be reafon to fear, that the bleaching would be lefs perfect in the curled parts. Inftead of wringing the thread on the pin, which requires much time, it would be ftill better to clear it of the water by the beetle, or by the prefs, as by this treatment the thread would be lefs fubjeft to injury. With regard to the time of maceration for thread, it requires in general lefs time than piece-goods, by reafon of the clofe texture of the latter. The time, likewife, depends on the finenefs or quality of the article, the tempera- ture of the air, and the goodnefs of the lees. With regard to ftockings, gloves, and mit- tens, they require at leaft as much time, if not more, than cloths, to be properly macerated. This muit be managed according to the clofe- riefs of their texture, and the other relative cir- cumftances already mentioned. Cotton, as well as linen thread, muftbe made into 1 06 The Art of Bleaching into hanks, then foaked in water, and difpofed irt crofs-layers, if troughs be ufed. Cotton imbibes water with great difficulty, and is lefs difpofed to adhere together than linen thread, which is not fo foft and porous. It therefore always fwims at the top of the fluid in fpite of every precaution which can be taken, unlefs it be kept down by the methods before defcribed. The cotton being difpofed in crofs-layers, and thus loaded, the troughs (which, as well as.thofe for piece-goods, ought to be fquare, for the more convenient difpofition of the feveral ar- ticles) are to be filled with water. On account of the difficulty of imbibing water, which depends on a certain oil, gum, or refin, it is naturally impregnated with, cotton requires at leaft as much foaking as piece-goods. Though it may not appear foul, it never fails to render the water of a darkifh colour by its im- purities. The foaking, likewife, affords a faving of lees, for if the cotton were to be put into the lees, without this previous treatment, the cop- per would hold but a fmall quantity. After twenty-four hours, or lefs time, of im- merfion, the cotton is to be taken out, and wrung or preffed, after rinfing in clear water, if thought ncceffary. It cannot be left to drain of itfelf, unlefs the procefs be conducted very leifurely Cot Ions, Thread, &c. 107 leifurely indeed, for it requires a long time to clear itfelf of water in this manner. The cotton is not to be macerated. After fteeping in water it is boiled in the lees. A good folution of black foap may on fome occa- fions be ufed inflead of the lees ; but the lees are always more effectual, and need not be made ftronger than three quarters of a degree below zero. But the folution of black foap muft not be neglected for thread foiled by the oil of the jennies or fpinning machines ; for fome of the girls who manage that procefs take fo little care in greafing the fpindles, that the bobbins of thread are fpotted with a thick black oil, which it is advifable to rub, previous to lixivia- tion, with a good folution of black foap. If this be not done, it will be very difficult to dif- charge the fpots : in fpite of every care they are fometimes vifible upon the hanks even after the bleaching. I muft here remark, that I re- commend black foap in preference to the white, becaufe it is more active, and does not contain thofe fmall ftones, or grains, which fometimes abound in the white foap, and may injure the goods, or the hands of the operator. Black foap, indeed, has a ftronger fmeJl, but this is diiiipated in the courfe of the fubfequent pro- cefles. Night- 10S The Art of Bleaching Night-caps, ftockings, focks, mittens, and gloves of cotton, are to be tacked together as foon as received, and marked with threads paflf- ing through each pair ; upon which a greater or lefs number of knots is to be tied, and an account taken in the day-book of every circum- ftance relating to their number, quality, &c. which may be neceflary to prevent miftakes, or confufion, in the fubfequent delivery to the re- fpecHve proprietors. Thefe goods, when marked and tacked to- gether, are not to be fteeped in pure water ; but, on the contrary, in a good folution of green or black foap as hot as poffible, in order that the black and oily marks, and the impurities with which they always more or lefs abound, may- be eafily detached by rubbing them with the hands. "When the ftockings, night- caps, &c. are taken out of the fuds, thev mull be rinfed and cleaned in clear water, and afterwards wrung by hand. They cannot be treated in any other manner, excepting by the prefs, without danger of breaking fome of the flitches. After this treatment the feveral pieces may- be conveyed to the troughs for immerfion in the bleaching liquor ; but the work fucceeds much better if they be previoufly boiled in the lees. With Cottons y Thread, &c. 109 With regard to flax and hemp, which it may- be required to bleach in the rough, it will be proper in the firft place to give them a lixivia- tion, on account of the difficulty of macerating them in this ftate, though it is not abfolutely impracticable to do it, by tying them up in fmall feparate parcels. The different knots of flax, muft, therefore, be difpofed on the bottom of the boiler, firft covered with a piece of wicker work, upon which a coarfe cloth is fpread. The different knots are to be mixed as little as poffible, taking care to make a flight fold, or return, at the head of each knot. They are to be preffed by hand the fame as the ftockings. For rinfing and walhing them, it is likewife ne- ceflary that this mould be done by hand, hold- ing each parcel by the head, and repeatedly plunging and moving it about in water. This, at lealt, is the management I have thought it beft to adopt in my trials. It is to be remarked, that the exhaufted and unferviceable folutions of the oxygenated muri- atic acid may be ufcd inftead of water for the lixivium, if it be fufficiently concentrated to mark one degree beneath zero on the areometer. I have fometimes ufed it to advantage for cotton goods, after the laft, and even the fecond, boil- ings. This liquor was not lefs difpofed to be- 1 come no The Art of Bleaching come coloured, by diffolving the extractive parts of thread and piece-goods, notwithftanding the acid with which the pot-afh appeared to be combined. It feems probable, that the acid is but flightly attached to the alkali, and may be driven off by a ftrong heat -, as, in facl, I thought I perceived in feparate evaporations *. * This laft observation feems to apply to fuch bleaching liquor only, as may have been deprived of its fmell by pot-afh> and not to that in which chalk, or lime, may have been ufed; CHAP, Cottons, Thread, &c. gjg CHAP. IX. ' Concerning the fir ft Immerfion. T. HE firft, as well as the laft, immerfions may be made with the acid without fmell, compofed with the proportion of pot-afh already pointed out ; but in cafe this proportion mould be ex- ceeded, it muft not be ufed but for the two firft immerfions. In every cafe thefe ought to be made with the acid without fmell, becaufe this liquid acls with more fpeed and equality. We fhall prefently mention the reafon why, in cafe of a greater proportion of pot-aili, no more than the two firft immerfions ought to be made in this inodorous oxygenated muriatic acid. When the immerfions are to be made, if the apparatus is fo placed, that the trough or back defigned for that purpofe is placed below the ipigot of the pneumatic veiTel (fee Plate I. fig. i, 2), the muriatic acid is to be drawn off to the necelfary height, in order that the goods which are folded in equal folds may be covered at leaft two or three inches. But if the arrangement be not made in this manner, the liquor muft be drawn 112 The Art of Bleaching drawn off in pitchers, or conducted to the vef- fels of immerfion by leaden or wooden tubes, provided thofe vcfTcls be placed on the ground, or low enough for that purpofe. With refpect to what remains in the pneumatic veffel, which is fhewn by the degrees on the external tube or £ase, after the moveable veffel of immerfion is conveyed away on caftors, if the bleaching li- quor be fuppofed to be fufficiently ftrong, and ; is not immediately wanted, it may be drawn off in ftone-ware bottles of that kind which is ufed for nitrous acid ; or, if requifite, the diftillation may proceed to its entire termination. I muft only remark, that when the liquor is thus partly drawn off, the diftillation is renewed though there be no increafe of the fire, becaufe the gas which efcapes from the diftilling veffels under- goes lefs refiftance from the diminished column of water. This is even a method, as I have al- ready remarked, to render the liquor in the fe- cond partition equal in Strength to that in the firft ; for otherwife there will always be a dif- ference between them, which, neverthelefs, fpecdily difappears when the whole, of the fluid contained in the pneumatic veffel is drawn off at once, and poured into the fame veffel for im- merfion. I mall now proceed to defcribe the method of Cottons, Thread, &c. 113 of fubmitting piece-goods to the a&ion of the oxygenated muriatic acid. 1. Above the veffel for immerfion is placed the winch, or reel, ufed by dyers. The piece- goods, if there be many pieces, are fewed to- gether, or fattened with firings in fuch a man- ner, that they form a large loop, or endlefs web, which is pafled over the reel, fo that by turning one part rifes as the other defcends, and the; whole length is fubje&ed to the aaion of the acid. One workman turns the handle gently, while another Handing in front of the cloth, takes it by each felvedge, and conduas it into the liquor. Two round fmooth Haves may be ufed for the fame purpofe. The perfon who manages the immerfion takes care to prevent the piece from folding breadthwife, and guides the cloth in fuch a manner, that it may continue open and expanded as it defcends into the veffel. This procefs of turning muft be continued for half an hour, in which time the liquor, almoft in every cafe, has produced its whole effeft in equalizing the colour. It is then taken off the reel, and left in the acid for another quarter of an hour ; after which it is palled again over the reel, and left in the liquor till the time of tak- ing it out, which may be done immediately, if the * fluid ! 14 The Art of Bleaching fluid no longer acts on the goods, and mould appear (till of value to operate upon other pieces. This may be immediately afcertained, either by the appearance of the fluid, of which experience will render the operator a fufficient judge, or by the proof of indigo or cochineal, pointed out in the Annals of Chemiftry, of which I fhall hereafter fpeak. If the liquor do not retain fufKcient ftrength for new, or dyed pieces, but enough for fuch as are in a more advanced ftate (which circum- ftances, and qualities, will be foon learned by experience) , or if it be proper for cotton itock- ings, or thread only, they may immediately be. immerfed after having wrung the cloths by the wring over the trough, in order to fave the acid they have imbibed, and bring them to a ftate fit for boiling. Every time the piece-goods arc wrung, it is necelTary to arrange them in folds on a clean table, or board, whence they may be carried and arranged in. the fame manner upon the frage of the lixiviating boiler. In cafe there be no particular hafle required to boil the goods, after it has been afcertained that the acid exerts no further action upon them ; and fuppofing, likewife, that no other goods are at hand to be immerfed in the fluid, the yiects may be difengaged from the reel, and left in Cottons, Thread, &c. n r Sn the bleaching liquor until they are wanted for the boiling. This prolonged immerfion can do no harm, and only exhaufts the acid more completely. Laftly, when this liquor is entirely cxhaufted, it is either to be thrown away, or elfe referved for the purpofes hereafter to be men- tioned. This firft folution, it may be remarked, has ufually a ruddy yellow colour. The veflel, or back, for immerfion ought to be fquare, or at leafl, long like a bathing tub, be- caufe the piece-goods are much better flowed in fuch a veflel. It ought to be fomewhat more than five quarters long, and three quarters wide, thefe dimenfions being beft fuited to our piece- goods (in France). The height may be propor- tioned to the quantity or length of the pieces intended to be depofited therein at the fame time, and the mafs of fluid which muft, confe- quently, be poured in. The mixed goods of cotton and thread, or cotton alone, being more fufceptible of the fpeedy aftion of the acid than fuch as are en- tirely of linen ; and among thefe the fine being more fpeedily affeaed than the coarfe, they muft accordingly be taken out as early as expe- rience may have mown to be proper for their effeaual bleaching. The other goods which lie beneath, and require to remain a longer time in 1 2 the 1 1 6 The Art of Bleaching the fluid, will be more advantageoufly a&ed upon, becaufe they will be lefs preffed, and will float in a greater volume of the bleaching liquor. Inftead of paffing the goods over the reel or winch in the manner here defcribed, which re- quires the time and attention of two perfons, the goods might be previoufly difpofed in a frame of one ell in breadth. This frame, fee Plate VIII. fig. i and 2, is provided with a number of pins with heads, over which is pafled the fame number of loops attached to the fel- vedge of the cloth, at the diftance of an ell afunder. By this means the pieces are fuf- pended in a zig-zag form, and not only occupy a fmall fpace in the veffel, but likewife become of a very even colour, in confequence of the free accefs which the acid obtains to the whole of the furface when the apparatus is plunged therein. This operation may be performed by a pulley fattened to lines which fufpend the frame. The latter may thus be eafily taken out with its charge, and be left to drain above the vefTel it- felf, or any other veffel appropriated to that purpofe, in cafe the liquor lhould be found fuf- ficiently ftrong to admit a fecond frame pre- vioufly prepared. If this fhould not, however, b£ the cafe, the fluid is to be difnofed as before J A. directed. With Cottons •> Thread, &V. ny With regard to linen and hempen thread, and knit or woven goods of the fame materials, they may be managed as follows. Over a trough for the immerfion, fee Plate IX. fig. 7 and 8, are placed clean poles or fticks cleared of the bark, upon which the fkeins of thread, {lockings, night-caps, or mittens in pairs, are to be hung. After the acid is introduced, each hank, or pair of ftockings, &c. is to be fucceflively turned, by immerfing that part into the liquor which was before upon the pole. In this manner the operator proceeds from one pole to the other, and returns fucceffively to thofe goods which were flrft turned. Care muft be taken to open them well at the time of turning, in order that they may prefent a greater furface to the fluid. Inftead of turning the poles fingly in this manner, it might be fo ma- naged by a band, or other mechanical contriv- ance, that the whole might turn together upon turning one (ingle piece of the fet. This me- thod would be lefs tedious and fatiguing for the workmen. It is advifable, that the troughs for the im- merfion of threads mould be as nearly as pofli- ble of a fquare figure, in order that they may hold a greater quantity of hanks ; and the diftance between each may be very nearly equal, for the purpofe of exhaufting the bath J 3 with 1 1 8 The Art of Bleaching with uniformity; excepting that the diftance between the fides of the veffel, and the thread may be lefs confiderable. . As the bleaching liquor is liable to lofe its gas more fpeedily in proportion to the extent of its furface, it might, perhaps, be proper to have the troughs rather deep than broad, in order that the gas may be more effectually retained ; and fmce it is effential, that the bleaching liquor fhould act with the utmoft pollible equality upon the threads, inftead of pouring it into the troughs wherein thefe are difpofed and arranged upon poles, it would be more advantageous to caufe it to rife gradually to the height of the hanks or poles ; a condition which may eafily be obtained by means of one or more tubes of lead or wood ; the bended parts of which might be laid under the middle of the bottom of the trough. Thefe tubes being fixed along the in- ternal fides of the trough, may be furnifhed at their upper extremity with a funnel of wood, or of lead, for the reception of the fluid. After the fluid has been poured in, great care muft be. taken to keep the funnels clofed. Thefe are the methods which it is convenient to ufe, to fubject threads to the action of the oxygenated muriatic acid, when the operator is in pofiefiion of a certain quantity; but when, on the contrary, the quantity he poflefles is Qnall, Cottons, Thread, m. I i 9 fmall, or his operations on a fmall fcale, certain pieces of bafket work, with handles, for which fee Plate II. fig. 2 and 3, may be ufed, feveral of which ma v be placed one above the other in a found or fquare trough of oak or fir, it being of 110 oonfequence which of the two kinds of wood be ufed ; upon each bottom a fingle layer of hanks is to be difpofed, taking care that it ftiall be covered with the bleaching liquor at leaft one inch or two in depth, and to turn them upfide down, at firlt every quarter of ari hour, and afterwards every half hour j laftly, after one hour's- immerfion the thread may be taken out, if its colour be equal, and other thread put in, if the- blfeachmg liquor continues ' to pofTei*s ftrength.- In a word, this procefs is to be ma- naged like the other already defcribed ; it mull, however, be remarked, that the bleaching liquor may appear to poffefs fome ftrength by the tell of cochineal or indigo, though it may not have fufficient for the bleaching procefs ; thefe nearly exhaufted folutions are to be referved either for the kind of preparation hereafter to be pre- fcribed, or thrown away if no immediate ufe prefents itfelf 3 'or otherwife they may be kept for ufes which I {hall defcribe when I fpeak of piece-goods. The colour of the bleaching li- quor which has been ufed for the firft immer* 1 4 fion no The Art of Bleaching fion of linen or hempen thread or flockings is or* a ruddy yellow, the fame as that which has been ufed for piece-goods. Brown or white cotton threads are to be fteeped and turned in the oxygenated muriatic acid, in the •fame manner as thread of flax or hemp ; namely, upon poles, or in bafkets ; with this difference, neverthelefs, that they require to be turned only haif as often. A good half-hour is fufficient for the firfl: immerfion, after which time they are to be taken out, and other thread put in, if the bleaching liquor continues ftrong enough for ufe, for it very felplom . happens that the new, "bleaching liquor is incapable of ferving more than once for cotton. .This, liquor does not un» dergo any remarkable change of colour. ^Stockings,, night-caps, gloves, mittens, and focks of cotton, may be very well managed with regard to the immerfion, in the fame manner as linen or cotton thread ; but as this fort of bulky articles occupy a coniiderable fpace, and cannot conveniently be laid on the other, it is adyifable to arrange them fcparately in layers in the troughs,, which may be of any form, either round or fquare, though the latter form is moil con- venient, and, upon the whole, to be preferred. Thefe articles are to be difpofed in layers upon platforms of clear ofier work, provided, as has already Cottons, Thread, &V. iai already been obferved, with four handles, upon which the other platforms are to be placed. No more than three can be put into one trough. As the articles placed upon the uppermoft plat- form might rife to the furface, which would ex- pofe. them to an inequality of colour, another platform, or piece of bafket-work, with a rim, may be placed above them, which muft be fo managed as to prefs the goods in a Tmall degree, and -prevent their rifing. Two or three ranges of night-caps, ftockings, Sec. are fufficient upon each platform. . It is eafily known: when the cotton ftockings, or night-caps, have .remained a fufficient time in the firft bleaching liquor. Nothing more is ne- ceflary for this purpofe than to hold them up to the light i in which pofition they ought not to fhew thofe opaque fpots, which are of a more or lefs ruddy colour, according to the nature of the goods, or' at leaft very few of thofe fpots ihould appear. Cotton ftockings^. with .clocks, are more diffi- cult to bleach in that part, and muft be care- fully pulled open every time they are immerfed in the liquor, becaufe they are very fubje£t tq ihrink up. It is advantageous to turn them in- iide-out previous to the fecond immerfion. The prefent remark with refpeel to cotton ftockings f $ l The Art of Bleaching (lockings is Hill more flrongly applicable to ribbed thread (lockings. The fingers of gloves are likewife more difficult to bleach at their ex*. tremities, becaufe the texture is clofeft at that part. It is even prudent to turn ribbed (lock- ings infide-out feveral times during the courfe of the immerfion, for which reafon it will be moft convenient to place them always near the top of the veffei. Common cotton (lockings, and other goods, may remain in the fluid without being turned during their immerfion, becaufe they are more loofe and fpongy. They may be left in the liquor about half an hour. Cotton manu- factured into goods is more difficult to be pene- trated than the fimple thread. By means of cords paffing through the handles of the lowef platform, upon which all the others reft, the whole fyftem may be very eafily raifed by a pulley. In this fituation they mud be left to drain above the trough -, after which, the pieces arc to be preflfed feparately by the hand, or all at once by mechanical means, if the operator be provided with an apparatus. If the acid be dill good, other (lockings are to be immerfed in it, either in their firft (late, or in different itages of the procefs j the raw ar- ticles mufl be immerfed in lefs quantity than thofe which are partly bleached : if the liquor be Cottons, Thread, fcfr. 2 be nearly exhaufted, it is to be referved pur- suant to the recommendation alrcadv given. The obfervation which we have made with regard to night-caps, ftockings, &c. made of cotton, in which the greater or lefs effecT: ma 7 be feeu by holding them up to the light, is alfo applicable to gloves and ftockings of linen thread : but, as it has already been remarked, thefe goods are much more difficult to bring to an equal colou ; for however loofe the texture may be. the linen thread always fvvells confider- ably, fo as to render ftockings ft iff and inflex- ible. The texture in this fituation is fo difficult to be penetrated, that the bleaching is as it were entirely fuperfkial. It is better, therefore, when ftockings are required to be well bleach- ed, that the thread mould have been cleanfed at leaft before the knitting or weaving, by which means it becomes more difpofed to open and imbibe the acid. Stockings, of linen thread entirely in the raw ftate, without having been cleared of their firft impurities, are very un- pleafant for the bleaching liquor to operate upon, and ftill more when they are ribbed or have clocks. Thefe goods are liable to a very unequal colour. In general, all kinds of looped or flocking ^ork of flax or hemp, muft be fuffered to ret main 124 The Art of Bleaching main in the liquor at lead half as much longer than other goods ; that is to fay, from two to three hours, for the acid does not penetrate them and give them an equal colour, unlefs it be'fuffered to operate for a confiderable time. They muft not even be lixiviated until their co- lour is nearly equal. If it mould happen that they do not acquire an uniform colour during the firft immerfion, they mult have a fecond, which muft, in both cafes, be of confiderable ftrength, and in which they muft be kept a fuf- ficient time to undergo the effect without the intermediate action of the lees. This obferva- tion is equally applicable to all other piece- goods of linen, or ftockings of cotton. With regard to knots of flax or hemp, they are to be bleached in the fame manner as the ftockings and night-caps, by difpofing them as much as poflible in thin ftrata ; be caufe fila- ments are naturally much difpofed to become entangled, and form a clofe mafs. Knots of flax are bleached very fpeedily, that is to fav, by one or two immerfions lefs than are required for thread of middling finenefs. It muft, neverthelefs, be obferved, that they muft not be bleached until after having been beaten and combed, becaufe they muft always be foaped after the bleaching, on account of their adher- Cottons t Thread, Z3c. X25 adhering together while drying, a circumftance which can hardly be prevented. If this be not attended to, there will be confiderable lofs. Knots of flax bleached in this manner, and afterwards combed, appear to the eye as beauti- ful and mining as white filk. It muft be remarked, that if the (loop of flax or hemp obtained from this bleaching, or bleached feparately, be cut, in cafe the ftaple be too long, and afterwards carded, it has a lingular reiemblance to the cotton of Siam, which is very plentiful in the market, and known to have the fhorteft ftaple. When it is well carded, no difference can be perceived between the two articles ; neither is it poffible to diftinguifli them in fpinning. I have had an opportunity to weave fome of this thread at the end of a web : of cloth, where it might have been taken for real cotton. I have likewife had an oppor- tunity of ufing it in candle wicks, in which there was no perceptible difference between it and cotton, either with regard to the colour, or clearnefs of the light. It will, no doubt, be a very interefting object to afcertain all the advan- tages which the commercial world may derive from this application of the oxygenated mu- riatic acid. CHAP. tafi The Art of Bleaching CHAP. X. Inftrufticns with regard to the Quantity of Lixivi~ at i ens and Immerfions. JL HE number of immerfions for hempen or linen goods is commonly three for fine goods, fiich as hollands, cloths, lawns, &c. &c. five for common cloths, and feven for the coarfeft. It may alfo happen, that an immerfion extraordi- nary may be required for each of thefe kind of goods, according to the accidents they have met with, the greater or lefs degree of clofenefs in their texture, and the dark colour of threads here and there paffing through the cloths, par- ticularly in thofe known at Laval under the name of toiles brindellees. This name is ^iven to them on account of threads paffing through them, which are faid to be dyed by the manu- facturer for the exprefs purpofe of rendering it heavier, and on this account more advantageous in the fale. The dark threads of thefe cloths can never be bleached by the common method j whence a judgment may be formed of the ad- vantage of the new method ia bringing thefe goods Cottons, Thread, &c. f 2 -i goods into the market, which, though fine and equal in beauty and general whitenefs to thofe of Flanders, Ireland, and Silefia, are neverthe- lefs greatly deprefled in price, on account of the fmgularity In the colour, which renders them at leaft twenty per cent lefs valuable. From the number of immerfions here pre- fcribed, it will follow that the lixiviations may- be reduced to two for fine cloths, four for mid- ling cloths, and fix for the coarfeft kind, fuppof- ing the moft perfeft white to be required 5 for if a commoner colour fhould be thought fuffi- cient, one lixiviation, and one immerfion, may be deduaed from each kind of goods ; whence it follows, that for a middling white no more will be required than to give one or two immerfions to the fine goods, two or three for thofe of me- dium finenefs, and three or four for goods of the moil inferior quality. With regard to piece-goods of cotton, the coarfeft will not require more than four immer- fions, and three lixiviations. For fuch as confift of linen and cotton mixed, no regard mult be paid to the cotton, but to the thread, which al- ways, during the procefs, remains behind in its degree of perfeaion. Neverthelefs thefe are bleached more fpeedily than if they were en- tirely of linen, becaufe the cotton, which is in- termixed, 128 The Art of Bleaching termixed, renders the goods more penetrable by the acid. In general no more than five immer- sions and lixiviations are required for ihe coarfeft goods of this kind. The fame advantage of fpeed is alfo obtained in other open-worked goods, which admit the acid more readily into their texture. Linen and hempen threads are affected nearly in the fame manner as piece-goods ; that is to fay, the fine thread requires no more the three immerfions, and two lixiviations, the middling four or five, and the double or fewing thread, or threads of coarfe quality, fix or feven immer- fions ; whence it follows, that three or four lixi- viations are fuflicient for fine thread, five or fix for clofe coarfe thread, and fix and a half for fewing thread of the fame quality. The latter threads requiring more care and attention, are likewife more difficultly penetrated by the acid. Gloves and flockings of hemp or linen follow nearly the fame proportions, with the addition of half a lixiviation and one immerfion more, according to their quality, the clofenefs of their texture, and the inequality of the thread. Ribbed flockings, or fuch as have woven clocks, will, likewife, in fome cafes require an additional immerfion. The fame proportion is to be ob- ferved in thefe goods wheji they are mixed, as was Cottons, Thread, &c. 129 was (hewn with regard to mixed cotton goods, excepting that an extraordinary immerfion, or half immerfion, is given on account of the linen thread, which fvvells up by moifture, and al- ways becomes white fomewhat more (lowly. But, on the whole, fingle threads bleach more quickly than piece-goods, becaufe the threads are more difengaged and feparate from each other, and being lefs compreiTed admit the fluid into contact with greater facility, with the ex- ception only of dyed or fewing thread. But this facility in the bleaching is fully counter- balanced by the care which thread requires tQ prevent its becoming entangled or broken. Three immerfions are fufficient to bleach the coarfeft cotton thread, fuch as that which is in- tended for cotton wicks ; and accordingly no more than two are required for common threads with the appropriate lixiviations, it being al- ways understood that the fineit white colour is here meant. It is of no confequence whether the cotton be of a dark colour, or inclined to white : the latter, which is naturally more foul or impure, might be expected to bleach more fpeedily, but it frequently acquires the pro- per degree of whitenefs more flowly than the other. Gloves, mittens, focks, night- caps, and ftock- K ings, 1 30 The Art of Bleaching iflgs, of cotton, require no more than three im« mcrfions, and fometimes two are fuflicient, ac- cording to the quality and clofenefs of their tex- ture. Hence it may be obferved, that the number of lixiviations cannot exceed two for the molt common goods, and it is, therefore, eafy to regulate the procefs for an imperfect white. This colour, however, is feldom required on cotton. I mud obferve, that by the words half lixivia- tion, I underftand that the lees poflefs no greater ftrength than one degree at molt for thread and piece-goods, and half a degree, or three-fourths, for cotton, if the lees be new ; but other wife the operator may ufe fuch as have already been applied, and have not been reftored to their original ftrength. When the fame term is ap- plied to immerfions, I mean to fpeak of the bleaching liquor, diluted with one-fourth of its weight of water, or fuch as has already been ufed for the firft white, and ftill retains ftrength enough for the immerfion of pieces already ad- vanced in their bleaching. When the muriatic acid without fmell is well made, the operator fees with pleafure that one quarter of an hour after the immerfion of thread, a white, and, as it were, foapy lather comes up to the top. This is a good fign, for it very feldom Cottons, Thread, &V. i«i feldom happens, that pieces immerfed in a bleaching liquor which produces fuch an effect, do not obtain an even colour. I muft, moreover, remark, that it is not neceffary to dry the goods before their immerfion in the lees, or the bleach- ing liquor. It is fufficient that they be well wrung, or cleared of their water to fuch a de* gree, as only to remain moift. We might even plunge them into the bleaching liquor immedi- ately after their rinfing, or wringing out of the lees, if it were not that this management di- minifhes its ftrength in fome degree. On the fame principle we may plunge the goods;, when taken out of the bleaching liquor, into the lees without rinfing, but merely after ftrong preffure, though the rinfing appears to deferve the preference. To fave time and trou- ble, however, I would advife the operator to omit the rinfing when he is defirous of haftening his work ; the only rifk which this omifTion af- fords, is that of weakening or neutralizing the lixivium to a greater degree, which by this means will not ferve for fo many boilings. It is proper alfo to remark, that if a lixivium thus neutralized, but not loaded, with colouring matter (which may be productive of deception if the ftrength be not afcertained by the tafte) be ufed, the goods will come out dyed of a k z nankeen 132 The Art of Bleaching nankeen colour, and the operator will be af- tonifhed that they do not bleach though fleeped in a new and ftrong bleaching liquor. This laft, on the contrary, ferves only to deepen the nankeen tinge ; but, as I have before remarked, this accident does not happen, excepting when the lixivium is entirely exhaufted, and neutral- ized by frequent immerfions of goods therein. This effect does not ufually happen, until after the lees having been ufed five or fix times with- out being renewed. The remedy for this acci- dent will be siven hereafter. I (hall conclude the prefent chapter by ob- ferving how ufeful it is to rinfe, and cleanfe the ld thread for fine goods, fuch as cloths, cambrics, muflins, or of filk of different colours for more common goods. With regard to coarfe goods, it is ufual to knot the ftrings together in the front part of the fold. I muft here obfefve, that piece-goods lofe in their length by bleaching about one ell, or an ell and a quarter in twenty-five, according t© their quality; and this lofs is reftored to them again by the laft dreffings here defcribed. With regard to the lofs of weight which threads undergo, it depends much on the rot- ting of the flax, according as it has been more or kfs perfect. The linen threads of Flanders and Artois, for example, which are rotted in water, do not lofe more than 2c per cent j whereas thofe of Picardv, of which the rotting in water is fo far from fufficiently warning the thread, that it acquires, on the contrary, a degree of im- purity from the earth on which it repofes, in ad- dition to that which is detached in the courfe of time by the maceration, which its external part has undergone, lofe more than one fourth of their weight, generally ipeaking. Coarfe threads na- turally Cottons y Thread, &c. 165 turally -k>fe more than others. In general the lofs may be eftimated at twenty-five. or thirty per cent, and eighteen or twenty-five for thofe of middling quality. With regard to cotton threads, the lofs is fcarcely three or four per cent. Cotton piece-goods may lofe more in proportion, on account of the dreiTing which was added to their weight, and which mult firft be diflbl.ved, and taken out of the cloth, before it can be prepared for the difcolouring or bleaching procefs. Having treated of the ordinary dreffings ufed in France, I think that the reader will receive, with pleafure, fome account of the fingeing, particularly ufed by the Englilh for light cotton goods. Every one knows that muflinets are ftriped, plain, and fpotted : muflins are more beautiful in proportion as they are lefs downy, or covered with fibres of the cotton wool. On this account the Engliiri, who are like wife at- tentive to ufe cotton of long ftaple for thefe goods, take the greateft care to render them as fmooth as pollible ; this may be obferved, par- ticularly in their frame-work, and other cotton goods, of which the beauty of the bleaching is the more confpicuous, in proportion as the fur- face of the article is fmoother, or lefs covered with the light down, which is ohfervahle on m 3 aU 1 6 6 The Art of B leaching all the articles of cotton when firft manu* factured. I have, therefore, prefumed, that my country- men will learn with pleafure how the Englifti manufacturers contrive to take off all this down, which on a beautiful and fine piece of cloth is fmgularly hurtful to the reflection and bright- nefs of the white colour it has received. With this view I have given a drawing of the machine -ufed for this dreffing. See Plate VIII. figs. 5 to 10, and the defcription. It will be fufficient to obferve in this place, that after having fewed the muflins to the coarfe cloths, which are nailed upon two rollers, with handles to ftretch them, they are rubbed with a brufh to raife the down. The brufh is pafled once or twice over the face of the piece, after which a bended bar of iron, more or lefs ignited, is fpeedily and Jightly pafled over the upper furface. This bar, according to its degree of heat, is pafled two or three times over the fame place, and after it has been repeatedly moved along one border, it is infenfibly moved towards the other. When the down of this firft length is well cleared off, which is obferved by looking aflant upon the furface of the piece, a new portion is ftretched, by rolling another part of the piece, which is to be treated as before. Piece- Cot tens, Thread, &c, 167 Piece-goods which are intended to produce an effect on both fides, are fmged on the back as well as the face, but more flightly on the former than the latter. It is neceflary to have at leaft two or three irons, one of which is to be heated, while the other is in ufe ; and the greateft precaution mull be had to make them very clean previous to each time of ufing; this is done upon a rag, or a fine grained fand-ftone, when they are taken out of the furnace in which they were heated- This attention is neceffary, for fear fome greafy fubftance, or tallow, might attach itfelf to the face of the iron, and burn, or penetrate the piece. The irons may be heated indifferently with turf or pit-coal, as well as. with wood. Cotton cloths, or muilin, which are rendered even and fmooth by this method, immediately acquire by this treatment, which is always per- formed at the commencement of the bleaching, a brown tinge fimilar to that exhibited by linen burned in ironing, but this colour moftly difap- pears at the firft or fecond immerfion, without any intermediate lixiviation. This management with regard to cotton goods, or mujflins, is equally applicable to li- nens, though thefe are lefs fubjecl to the downy m 4 covering, J 6 8 The Art of Bleaching covering, on account of the length of the ftaplc of which they are compofed. It is very poflible to life the fame procefs with ftockings, night-caps, and other fine knit works in cotton, capable of being rendered more valuable by their clear white colour, which always feduce the confumer, who is, for the moft part, lefs attentive to the quality of the merchandize than its external appearance But I have already remarked, that the mechanifm to . difpofe knit, or frame-worked goods, to re- ceive the fingeing, ought to be different from that of piece-goods, and appropriated to the form of the object. There is another method alfo of fingeing cot- ton goods and muflins, namely, by fpirit of wine ; but this method never operates with the fame fmoothnefs and equality as the red-hot iron, and is alfo much lefs expeditious. Never- thelefs, as it may be ufeful and applicable to certain goods, the reader may confult Plate VI. fig. i and 2, where I have defcribed the ma- chine which may be ufed for this purpofe. I need only remark, that inftead of the box which contains the hot embers, another muft be placed, containing a row of wicks for burn- ing fpirit of wine. One man is fufficient to at- tend Cot ton s t Thready Z3c. iSg tend and direct this method, as well as the former j and the fpirit of wine made ufe of may be mixed with a certain proportion of brandy, or otherwife it may be lowered in its ftrength, as the operator may find beft fitted to his pur- pofe T CHAP. 170 The Art of Bleaching B CHAP. XIV. Concerning Proof Liquors, 'Y proof liquors, I underltand all thofe co- loured fluids, which are extracted from vege- tables by deco£Uon or fermentation, and which, when mixed with the oxygenated muriatic acid, are more or lefs changed, according as the one or the other liquors is more or lefs concentrated : thefe vegetable fluids, accord- ing to the degree of alteration which they undergo, are of ufe to afcertain the ftrength, and more particularly to afford a judgment of the ufe to which the muriatic acid may be ap- plied, when after having been prepared accord- ing to the directions already pointed out, it has been applied to one or more immerfions. It is true, indeed, that this acid might be more concentrated by putting lefs water into the pneumatic veffel, or by increafmg the dofes of the ingredients ; but this would afford no ad- vantage excepting for the purpofe of carrying it from place to place, or for the more fpeedy bleaching of coarfe goods, or other objecls of the fame quality 5 fuch as towel pieces, coarfe thread, Cottons, Thread, &c, jji thread, twifts, and the like, of which there is no reafon to fear an alteration in their texture. For every other merchandize of a fine quality, it is always prudent to dilute the acid in a cer- tain proportion for its mpft advantageous appli- cation. A folution of one part of indigo in eight parts of fulphuric acid, is particularly pointed out by Berthollet as having been ufed by De Croifille at Rouen. This preparation differs from a folution of Saxon blue in no other re- fpect than that this laft is made with one part of indigo to four parts of the fulphuric acid. Either of thefe compofitions may be digefted in a matras, or fimply in an apothecary's phial, placed on a water or fand bath, or in hot afhes : at the expiration of feveral hours part of the indigo, previoufly pounded and fifted through (ilk, becomes diffolved. This folution, which js of a very deep and denfe blue, is to be gently poured by inclination into an appropriate veflel, after which it is to be diluted with water, until it marks one degree below zero on the areo- meter of Mo fly. In this ftate it forms a proof liquor, of which three parts will be rendered cplourlefs by one feventh or eighth part of oxy- genated muriatic acid, compofed in the manner before defcribed. This liquor may be meafured in 1 7 a The Art of Bleaching in the cap of the cafe of the areometer, and then poured into a glafs cylinder, which is gra- duated and {lands upon a foot. See Plate IX. fig. 10 and n. •I have thought proper in this place to men- tion the kind of meafure which is made ufe ot in this proof, becaufe the degree of itrength in- dicated by the fluid is very frequently different when the oxygenated muriatic, acid is poured into a veifel of a different diameter. It is there- fore efiential to ufe the fame meafure conftantly. It muff, be obferved, that the oxygenated acid may be ufed to advantage, as a fecond bath for linen goods, already in the progrefs of bleaching, or as a fir ft bath for cotton goods, from the time its itrength is fuch, that one iingle half part of the acid is required to render three parts of the blue fluid colourlefs, until that ftate in which it requires one entire part of the latter to difcolour three of the blue. When the bath is weakened to this degree, it is no longer applicable but to the preparation. Neverthelcfs, if there be a certain quantity on hand, it may be ufed for fteeping and prepa- ration, in cafe there is time for fuch goods as are either cleared or uncleared ; for though the acid be fo weak that it does not feem capable of bleaching., neverthelefs it will act. in process o Cottons, Thread, &fo 173 of time!, as long as it is capable of difcolouring the proof liquor. For I have many times re- marked, that however weak the preparation may be in which the piece is thus immerfed* the white colour of this laft does not fail to be very perceptibly forwarded, when it comes to be again fubjected to the aclidn of a newly-pre- pared and ftrong bleaching liquor. This ex- haufted fluid muft not, therefore, be rejected^ even though one whole meafure mould be re- quired to difcolour one meafure of the blue fo- lution of indigo, with which it may be mixed. In this manner trials may be made to afcertain its ftrength, as foon as it is weakened to that degree that three parts of the blue liquor are difcoloured by one of the acid. The operator cannot pay too much attention to the total ex- haufling of the power of the bleaching liquor, fince, upon the whole, thofe weak folutions may be very profitably applied in a well-regulated manufactory. When the liquor of the bath no- longer acls upon the proof liquor, it is entirely exhaufted of the oxygenated muriatic acid, though it (till preferves a peculiar odour, which is not difagreeable ; it then confilts of the com- mon muriatic acid diluted with water, if it be the refidue of a bath of the odorant muriatic acid ; but, if, on the contrary, the fluid be the refidue j 74 Tbe Art of Bleaching refidue of the oxygenated muriatic acid without finell, it contains likewife a combination of that acid with pot-am. In either cafe the fluid may be thrown away,, if the operator is not aware of any peculiar purpofe to which it may be ap- plied ; if he has fuch a purpofe in view, he may referve it either for that obje£t, or for rinfing fuch goods as are already bleached, and have paired through the laft lees, as has before been remarked, for which laft purpofe it appears preferable to common water. The tincture of cochineal may be ufed as a proof liquor, according to the information given in the annals of chemiftry. It is equally valuable with the Saxon blue, and even made with lefs trouble ; nothing more being required than to boil a finall quantity of the cochineal, firft cru flied in a marble or glafs mortar, or (Irongly rubbed between the fingers; the decoction mult then be filtered through cloth, or blotting-paper, upon which it muit be poured (lightly by inclin- ing the veflel, in order that the remains of the infed may be feparated from the fluid. Two parts of the tinclure of cochineal diluted with water to half a degree below zero, require two parts of the muriatic acid without fmell, at the fame degree as that which is neceflary to render the blue proof liquor colourlefs. The tincture Cot tons y Thread y &V. 17 c tincture of cochineal becomes converted to a yellow colour. It may here be remarked, that the violet li- quor of Javelle concentrated to four degrees of pot-afti below zero, requires no more parts to difcolour three parts of the blue before de- scribed, than are required of oxygenated muri- atic acid to difcolour the fame quantity of blue ; but the liquor of Javelle bleaches more fpeedily and uniformly. The tincture of turnfole may alfo be ufed with no lefs advantage than cochineal, and is prepared in the fame manner ; and, laftly, the tincture of beet-root, and even wine itfelf r may be ufed with equal convenience, if other vegetable tinctures and decoctions be not at hand. The juice of acacia and currants are alfo fufceptible of affording the fame indications. With regard to the colours which the differ- ent tinctures affume, they are as follows : The Saxon blue, or folution of indigo in the fulphuric acid, becomes a yellow, more or lefs inclining to fawn colour, whether it be mixed with the oxygenated muriatic acid with fmell or without. Its tint becomes deeper in pro- portion as the blue is more intenfe. The tincture of cochineal aflumes an orange colour. Red jy$ The Art of Bleaching Red wine of Macon acquires an opal colour ; the infufion of turnfole becomes of a light amber colour with either of the acids, prepared in the manner recommended in this treatife ; I have, neverthelefs, obferved, that it does not change with the fluid called the lixivium of Javelle (leffive de Javellc), which neverthelefs caufes a flight efTervefcence with vinegar. It is very eafy for the operator to regulate his procefs with regard to every kind of tincture or irtfufion, which he may find it mod convenient to ufe, whether of woods or roots, according to the preparations I have laid down for cochineal and indigo. The latter folution may be pre- pared without the afliftance of heat, as follows. After having poured the proper quantity of ful- phuric acid into an earthen or ftonc ware bottle, the pounded and lifted indigo is poured in, and ftrongly agitated by the hand for an hour, which is a fufheient time for the clots of indigo, which are formed either at the furface of the acid, or on the fides of the bottle, entirely to difappear: during this agitation a ftrong efTervefcence takes place in the fluid. The in- digo, when well fhaken, and penetrated by the acid, is foon difiblved, but it ufually require? half an hour for that purpofe. This portion of time is applicable to two ources of indigo in one Cottons, Thread 3 &c. ijj pound of the fulphuric acid. To this quantity of acid half a glafs of water may be added. I am convinced by experience, that this addition renders the a£tion of the acid upon the blue more fpeedy. W CHAP. 178 T. j Art of Bleaching CHAP. XV. The Methods of remedying fuch Accidents as happen during the Courje of Bleaching. T H E accidents likely to happen in the courfe of bleaching, may be diftinguifhed into accidents of the diftillation, accidents of the immer- fion in the alkaline or acid liquor, and accidents of the dreffing. I fhall give a fhort account of thefe three claufes of accidents, and at the fame time point out their remedies. Accidents in the diftillation. The principal ac- cident which is capable of interrupting the dif- tillation, is when the lutes of the adopter fuffer the gas to efcape. The moft fpeedy remedy, in this cafe, to prevent the exhalation of the acid, which cannot be retained but with great diffi- culty, feldom for any length of time, and then very imperfectly, in confequence of its great expanfion ; the fhorteit method, I fay, at lead if the diftillation be not near its conclufion, is to remove the fire immediately from beneath the capfule of the retort, and to furTer this laft to cool for a certain time, by railing it a little in its Cottons, Thread, &c. 179 its fand-bath. If it be not poflible to take it out of the furnace, together with its capfule, on account of the heat, or its (ticking too faft, the adopter muft be unluted from the funnel of the ]eaden tube, and the aperture of this tube clofed with a cork, or lute, to prevent the gas of the pneumatic veflel from evaporating ; after which the retort muft be raifed, and placed gently upon a bag of ftraw, or on coarfe cloths folded together; and then holding the retort by its neck, near the flexure, the adopter muft be en* tirely unluted, by twifting it round and drawing it off. The orifice of the neck of the retort is then to be clofed with a cork ftopper, but not fo clofely but that a very fmall portion of gas may be fufFered to efcape, for fear of an ex- plofion. The ftopper of the neck may, for greater fafety, be flightly raifed. This precau- tion is neceflary, on account of the great ex- panfion of the muriatic acid gas. The old lute muft then be taken off, as well from the adopter as the retort, and the places to which they were applied muft be well cleaned, in order to receive frefh lute, after having carefully wiped off the moifture with a cloth or a fponge. If. the lute which comes off be ftiU good, it may be kneaded again, adding, if required) a fmall N a quantity 1 8o The Art of Bleaching quantity of boiled oil, or it may be mixed with new lute> if it be burned or decompof- ed. This decomposition in the fat lute may be known by the white or reddifh colour which it acquires, and the facility with which it breaks, on account of its having loll the glu- ten which afforded it that toughnefs and tena- city, on which its goodnefs chiefly depends. With regard to the lute of linfeed cake, it muft, in almoft every cafe, be totally renewed, particularly when internally applied, becaufe the heat hardens it too much to admit of its being kneaded again, with any moderate degree of facility ; the decompofition of this lute is known by the yellow colour it acquires, and the con- traction it undergoes from the e fife ft of the heat. The lutes being kneaded to a proper conliftence, and duly placed according to the directions laid down in Chap. IV. the adopter is to be fixed, previoufly removing the Hopper from the mouth of the retort, and placing another in that of the fmall end of the adopter, to prevent any inconvenience from the vapour which might iffue out during the time of fixing it. This vapour is likewife condenfed within the adopter, in confequence of its coldnefs. The retort is then to be placed, as before, on the furnace, Cottons, Thread, &c. i8t furnace, the adopter uncorked, and its beak luted into the tube of lead ; after which, the iire is to be replaced beneath the capfule, and the diftillation very fpeedily recommences, and proceeds as ufual. This operation is a work of fome delicacy; it requires to be performed with fpeed, and great care muft be taken while plac- ing the lutes and the adopter in their proper fituations, to ftand always in fuch a pofition, that the current of the external air may drive the vapour from the operator himfelf. If the accident here defcribed mould take place towards the end of the diftillation, as it may fometimes happen, in confequence of the ftrong heat which, at that time, may foften the lutes, it will be fufficient if the fire be taken from beneath the capfule. The diftillation foon ceafes when this is done, particularly if care be taken to condenfe the gas, by the pru- dent application of wet cloths on the neck of the retort, as well as the adopter. This inconvenience would not take place, if the workmen in th.ofe glafs-houfes which are principally employed in the fabrication of chy- mical veflels could make retorts with necks re- curved in the form of the adopter. Thefe kind of yeffels maybe affiduoufly fupplied by making n 3 ufe 182 The Art of Bleaching * life of a tube of lead, fo formed as to ferve inftead of the adopter, as I have already obferved, with regard to the tubulated bottles or bodies *. If, by accident, the lute which is adapted mould fail, or fuffer the gas to pafs through, it may eafily be flopped, by applying new lute to the place of junction. Inftead of the leaden tube, we may fubftitute, with flill greater convent ence (the danger of breaking excepted), a tube of glafs, of which the end neareft the bottle, or tubulated body, ihould be ground with emery. Bv thefe means there would be no application of lute, and confequently no danger to be feared with regard to the filtration of the gas, the efcape of which is eafily perceived by the fmell which diffufes itfelf through the work> fhop, and is more particularly perceived when the nofe is applied near the veflels, or the lute. But as this laft method of difcovering the place where the lute has failed may be attended with the moft ferious confequences, if the greateft precaution be not ufed, it is more prudent to apply an open bottle of ammoniac near the * This laft method appears to me preferable to every other ; becaufe it requires only a flight attention to the lute, and can never produce thole dangers which arifc from the ufe of retorts. — C. fufpected Cottons , Thread, &c. 1 83 fufpe£red place ; at the inftant that it is pre- ferred, a white fume is formed, which immedi- ately points out the defective fpot. The bottle muft be prefented above the current of air$ which takes place near the lute, or in the w r ork- fhop. If this precaution be not attended to, the operator might be induced to remove a good lute, inftead of one which was really defective. On the other hand, if in the courfe of the dif- tillation, and for want of keeping up the heat, the fluid in the pneumatic veffel mould be abforbed and rife into the diftilling apparatus, it is necef- fary the inftant it is perceived to withdraw for a moment the (topper out of the neck of the retort, where, as I have already had occafion to obferve, the abforption inftantly ceafes. Neverthelefs, if for want of being obferved in time, the water mould rife fo far as partly to fill the retort, or body (for it never entirely fills it), the diftillation will be ftopped, from the coldnefs of the water, and its too great quantity. The ihorteft remedy is to draw out the excefs of water, which is thus introduced into the diftilling veffel, by the aiiift- ance of a glafs pump, or fyphon, and afterwards to heat the fame veflel, firft returning the water into the pneumatic veiTel, if thought expedient : but if the diftillation be properly attended to, *fris accident can sever happen, n 4 Accidents 184 The Art of Bleaching Accidents in the lixiviations and immcrfions. I place the accidents arifing from thefe two opera- tions in the fame clafs, becaufe they can fcarcely take place, but by the joint operation of both. Any article which is badly cleared of the lixi- vium, and afterwards immerfed in the oxygenat- ed muriatic acid, becomes almoft immediately of a nankeen colour, particularly in the folds, either in fpots where certain parts have not been fufficiently rinfed, or ele the colour is general, if the whole has not been well rinfed. The fame accident happens if foot has fallen on the linen or thread. The difference is fim- ply in the colour, which approaches more to brown. Thefe colours are capable of becoming more and more deep if the mifmanagement be not remedied as foon as perceived, and that be- fore the goods are fubje£ted to other immerfions in the alkaline lees, or of the oxygenated muria- tic acid. The fame acident is to be expected, if the goods, though white at the time of their immerfion, arefuffered to remain too long in the bleaching liquor. I his does not fail to happen, particularly if r he articles which are fuffered to remain even in a weak folution, are kept in that fhte the whole night. The next day they are found to be yellow, or charged with lix- ivium. The Cottons, Thread, Z3c\ 185 The remark which has here been made, con- cerning the nankeen colour, takes place alfo with regard to thofe articles which, though white, have been immerfed in an exhaufted lixivium or lees which have been ufed feveral fucceflive times for the immerfion of goods taken out of a ftrong muriatic acid, without previous rinfing. Thefe articles, when taken out of fuch exhaufted lees, and plunged into a new acid folution, un- dergo a change even though they may have been properly rinfed. I muft in this place remark, that a lixivium may be exhaufted in confequence of its combination with the muriatic acid from the goods which are plunged in it, though they may have been prefTed or wrung at the time of taking them out of the acid. Such exhaufted lees may, neverthelefs, indicate a certain degree of ftrength by the areometer, though in fact they do not poffefs it. The only method of remedying thefe acci- dents confifts in the ufe of water, flightly acidulat- ed with fulphuric acid, no matter whether cold or hot, but the hot folution operates more fpeed- ily. The fpotted or tinged goods are to be foak- ed in this water for a few minutes, or a quarter of an hour, accordingly as the colour may be more or lefs deep, in confequence of a feries of lixiviations 1 86 The Art of Bleaching lixiviations or immerfions, more or lefs repeated. In this fituation the offenfive colour is feen aU mofi: immediately to difappear. ■ % Inftead of making a fulphuric foliition ex- prefsly for that purpofe, that which has ferved for the drefling may anfwer very well : neither of thefe reed be ftronger than has been there directed, uniefc the goods be confiderably charg- ed with colour, and there be a great quantity to immerfe at once. The acidulated water is tried by the areometer, and if, in confequence of having been ufed, it mould not be fufficiently ftrong, it may be reftored by adding the requifite quantity of acid for that purpofe. It is necef- fary when any new acid is poured in, to mix it well with the water before any goods are immerfed therein. It muft, in this place, be obferved, that though the thread and piece-goods may become charg- ed with a foreign colour, in confequence of the accidents here pointed out, both thefe arti- cles are frequently very well bleached at the under furface. It is even a proof that the muri- atic acid has operated effectually, in caufing the lixivium to produce fuch an effecl : but thefe acidents are difficult to be obferved on objects &mply cleared, or in the crude ftate. In the latter -Cottons, Thread, "r. 187 latter cafe, a permanency of the original colour may alone (hew the neceffity of ofing the ful- phuric acid, particularly when the lees and the muriatic acid which have been ufed are not at all exhaufted. Accidents at. fending the •preparation or drying, When the piece-goods are immerfed in a folution of foap, after having been taken out of the fulphu* ric acid, while they are (till too ftrongly acidulated, or if inftead of rinfing them they be immediately conveyed from the acid into the folution of foap, this laft folution is fubject to curdle, or become immediately decompofed; whence the operator has the mortification to obferve the whole furface of the goods covered with an infinite number of fmall fpots of oil, in the form of clots, of a yellowifh colour, and very tenacious, particularly on (lockings or cotton goods, be- caufe they incorporate as it were with the nap or texture of the goods : they difappear in eon- fequence of much warning or rinfing. I muft particularly mention an accident which may happen to any one, namely, that of placing by miftake (lockings or other bleached objects, which have received their fir ft: treatment in the folution of foap, upon articles which have been expofed to the vapour of fulphur. I have placed (tockV.L ;s upon gauze, which had been whitened by i S 8 Tie Art of Bleaching by fulphur, and found that after they had re- mained in this fituation for the courfe of a night, they became entirely of a brown-red at the place of contact. They appeared as if burnt or marked with an hot iron. This colour, which, no doubt, was produced by the combination of the volatile fulphuric acid, with the alkali of the foap, with which the (lockings were ftill impregnated to a certain degree, immediately difappeared upon expofing them, firft, to the action of a bath of the odorant oxygenated mu- riatic acid, and afterwards to another of water, Hightly acidulated with the fulphuric acid. Every fait with excefs of acid, fuch as the fait of forrel, removes the ruddy fpots here men- tioned with equal eafe. It is true, that this fait cannot with convenience be ufed, on account of its dearnefs, but the refidue of the diftilling veflels, that is to fay, the water which holds in folution the refidue of the diilillation of the oxygenated muriatic acid, is very ferviceable in this procefs, and may be advantageoufly ufed either hot or cold, to remove thofe very tena- cious fpots, which are not at all capable of being removed by foap or alkaline lees. CHAP. Cottons, Thread, &c. 1JJ0 CHAP. XVI. The Method cf taking cut Spots of Rujl or Ironmould, Tar, Fruit, Wine, &c. W HEN the fpots of oxyde of iron, com- > monly diftinguifhed by the name of ironmould, are fmall, they may eafily be taken out with fait of forrel in powder, laid upon the fpot itfelf, which is afterwards to be moiftened with a fmall quantity of water; or the part which is fpotted may be fleeped in a folution of the fame fait. It foon becomes fainter, and at length difappears, after which the place mufl be very well rinfed. The fulphuric acid may be ufe- fully applied inftead of the fait of forrel, as Bertholet feems to affirm in his memoir ; and I have proved with fuccefs, that, though the fpots may penetrate quite through the cloth, and be very broad, yet if they be foaked in a bath of fulphuric acid, either warm or cold, when the goods are taken out of the bath of muriatic acid, the x 9<^> 5f2e Art of Bleaching the effect will be that the fpots infenfibly dif- appear. If the goods be of clofe texture, the operation of the acid is flower *. With regard to the fpots of ruft which are frequently feen on thread or cotton ftockings, they are produced by the needles of the engine, and commonly disappear during the dreffing, that is to fay, in the bath of fulphuric acid. The fame obfervation is true of the fpots of ruft which fometimes appear on the piece-goods, in confequence of their having been in contact with iron. In general, the older any ironmould may be, the more tenacious it is, and the more difficult to be effaced ; but every fpot may be made to difappear in time. It frequently happens that piece-goods are fpotted with tar, during their carriage by water, in boats, where they are liable to be placed upon the pitchy parts of the veffels, or in con- tact with tarred ropes. Thefe fpots may be foon taken out, by rubbing them with oil of olive, which diffolves the tar j or ftill better, by holding the part id fpirit of wine, if this procefs fhould be thought more convenient. The latter * The fait of forrel is fold in London, in fmall bo:tles, by the perfumers and apothecaries, under the name of fait of lemon. The fulphuric acid, as prefcribed above, muft, of couife. be diluted. — T. method Cottons, Thread, &c. 191 method operates by the complete folution of the tar. With regard to fpots of wine, cyder, or anjr kind of fruit, they may be effaced by drop- ping a few drops of the oxygenated muriatic acid upon them, which caufes them almoft in- ftantly to difappear. But there are certain fruits, fuch as plumbs, of which the fpots are more difficult to efface ; they requiring one or two lixiviations- Thofe that are grey, or reddifh, at firft, affume a fine yellow colour in the muri- atic acid, which does not difappear during a fubfequent lixiviation, but requires a fecond immerfion in the bleaching liquor. I muft not omit a fecond very fimple and economical method to rake out every kind of fpot occafioned by fruits, fuch as ftrawberries, goofeberries, &c. It confifts in caufing the fpotted part to imbibe water, and afterwards to burn one or two common brimftone matches over the place : the fulphureous gas which is dif- charged foon caufes the fpot to difappear. There is a kind of indelible fpot which is produced from red ochre and the charcoal black, with which the weavers mark the turns of the beam, in order to afcertain the length of the chain of piece goods. This kind of mark, whi£b 192 The Art of Bleaching which is impreffed on the goods at equal diftances, is fo far from being effaced, that it feems, in fome meafure, to receive ftrength from the oxvgenated muriatic acid, notvvith- ftanding the intermediate action of the lees. CHAP. Cottons, Thready &c. 193 CHAP. XVII. The Expence of Bkaching different Kinds of Goods, of Linen, Hemp, or Cotton, by the oxygenated muriatic Acid, at per Ell, or per Pound. B EFORE I proceed to give an account of the expence of bleaching any quantity of ells or pounds of goods, by the muriatic acid, I mall, in the firft place, mention the prices of the materials required to make the liquor, either with or without fmell, of which I have before defcribed the compofition. The prices are cal- culated according to thofe of the articles to be delivered at Abbeville, in 1791 *. The fulphuric acid of Rouen, rectified for * I have not reduced the numbers in this chapter to their values in Englifh money, becaufe the difference of locality would, even in that cafe, have rendered them of little im- mediate utility. As tranflator, I am obvioufly not at liberty to omit the chapter, even if I were fo difpoGd. The Englifli pi ices of the materials are given in the Appendix. — T. o the 194 ?7 , made according to the pro- portions prefcribed in this Work. Lit), s. d. Sulphuric acid, five pounds and a half ---306 Manganefe, two pounds and a half - - - - 100 Grey muriate of foda, eight pounds ----080 One bufhel of charcoal of wood ------ o 3 o Workman, one day -------«-ioo Potalh, two pounds and a half ------ 1100 Total 7 1 6 Expence of two pneumatic vejfels of the odor ant muriatic acid, made according to the proportions prefcribed in this work. Sulphuric acid, five pounds and a half Manganefe, two pounds and a half - Grey muriate of foda, eight pounds One bufhel of charcoal of wood Workman, one day - Potafh Liv , s. Turf, two marines, or halt a fack, 4fbls J It remains to be fhewn, what may be the expence of bleaching the above feventy-two pounds of fingle thread, or feventy-two ells of cloth. I have before obferved, that cloth of middling finenefs requires nearly four immer- fions, two of which may be made in the muri- atic acid without fmell, and two, if it be thought Cottons, Thread, &c. 197 thought better, in the odorant acid, befides four iixiviations ; and again, that one pneuma- tic veflel is fufficient for (ixty pounds of thread, at the firft immerfion, and from feventy-two to eighty at the fecond. I (hall take feventy-two pounds as the middle term, between the firft and the Iaft immerfions, which, as well as the Iixiviations, I will fuppofe to be made with freih folutions. Liv. j. Two pneumatic veflels, for the two firft new im- merfions in muriatic acid without fmell - 1* x Two pneumatic vefTeJs, for the two other immerfions, in the odorant muriatic acid - - n 3 Four new Iixiviations, or the quantity of potafh necef- fary for that purpofe - Two facks of turf One day's work - Total Hence, the pound of thread of Picardy, con- taining fixteen ounces, will coft 10 fols 10 de- niers. With regard to Flanders thread, which is cleared in water, the price will not, at molt, exceed 8 fols, becaufe this article requires only one immerlion, and a lixiviation lefs. Flanders thread, likewife, as has been remarked, is fub- jecl to a lofs of no more than twenty per cent. If this calculation be, therefore, applied to the bleaching of common coarfe cloth, two elk 03 of 1 9 3 The Art of Bleaching of which weigh a pound, the ell will not ex- ceed 5 fols 5 deniers for the bleaching. If it be, therefore, fettled to charge for the thread of Picardy, or any other which is cleared on the grafs, 12 fous the pound, or livre de Marc ; for Flanders thread, or any other, which is rotted or cleared in water, at 10 fols, upon an average ; and for linen piece-goods, 8 fols the ell, of fine or middling quality, the manufacturer will find himfelf reafonably paid for his trouble. Thefe are the ufual prices at the moft celebrat- ed bleaching works of Lifle, Beauvais, Saint Quentin, Senlis, Rouen, Rheims, &c. I mud, however, take notice, that the dreffings are not reckoned in thefe charges, which, with regard to the piece-goods, amount to about 2 liards per ell for cold calendering, and 1 fol for hot calendering, including the folding, &c. There are feme articles of which the price of the dreffing amounts to half that of the bleaching : thefe are fuch as require a degree of firmnefs, by means of flarch, gum, or other fimilar mate- rial, with blue, which, in certain markets, and with regard to goods of a certain description, is favourable to the fale. The proper dreffing for thread amounts to about 1 fol the pound, but is the objeti of a particular agreement between the bleacher and the Cottons, Thread, &c. 199 the owner. With refpe£t to the price of bleach- ing double, or fewing, threads, my advice is to charge 1 fols extra per pound, on account of the greater difficulties they prefent, and the atten- tions they require, as may be gathered from what has been before faid on this fubjecl Piece-goods, in general, require more care, and are attended with more difficulty, than threads, on account of their volume, their weight, their texture, and the even white co- lour required to be given, on both fides, as well as towards the felvedges. It mult alfo be remarked, that the felvedges having their tex- ture clofed by the action of the temple, when the cloth is in the loom, fometimes require, in the middle of the bleaching procefs, to be rubbed with foap, by hand, for which purpofe black foap is to be ufed in preference. If they be not opened to the action of the acid by this treatment, there will be danger of the white being lefs advanced towards the edge than on the reft of the furface. This management may, however, be avoided, if, at the time of fteeping and macerating the cloth, as well as in the firft lixiviation, the operator is careful to rub or clear thefe parts, on account of the rirmnefs of their texture. From thefe feveral data, it will be eafy to o 4 eftimate ceo The Art of Bleaching eftimate the expence of bleaching finer thread, for linens and lawns, as well as that of the ell of thefe articles refpectively. For nothing more will be neceffary, for that purpofe, than to con- lider the account of the number of immerfions and lixiviations which I have ftated to be necef- fary for thofe goods. The thread of lawns, of the ordinary finenefs, will run fix ells in the piece to the pound, on a breadth of one ell. Having thus fhewn the coft of bleaching thread or linen goods, by the pound or ell, I (hall proceed to examine that of the fame articles in cotton ; for which purpofe I fhall choofe the thread proper to make the commoneft wrappers, which run two ells to the pound, on a width of one ell. I have before ftated, that each pneu- matic veffel is fufficient for the immerfion of eighty or ninety pounds of thread, for the firft working, and ioo for the fecond. I will, there- fore, take only ninety for the middle term. I have alfo ftated, that no more than three im- merfions, at moft, were required to bleach cotton, one of which mould be in the muriatic acid without fmell, and the others in the odo- rant acid, befides three lixiviations. I will fuppofe that neither the acid nor the lees have been ufed before. My piece of cloth mall be ailumed at 180 ells, or two pieces of ninety ells I 4 I e 32 8 6 Cot Ions, Thread, &c% 201 ells each, and the quantity of thread equiva- lent to this {hall be ftated at oo"pounds \ whence it will follow : LlV. S. d, Firft immerfion in new muriatic acid, without fmell 716 Two other new immerfions in the odorant mu- riatic acid - - - - - -1130 Three new lixiviations in one of double propor- tion with regard to the mafs to be lixiviated - 12 o o Three facks of turf, on account of the double lixiviations - - One day's work _----. Total This computation fettles the pound of cotton thread at about 7 fols 6 deniers, and confe- quently the cloth at 3 fols 9 deniers the ell. It is to be obferved, that cotton, being more loofe and fpongy, and more fubjeel: to rife up in the boiler by the aftion of heat, requires near double the quantity of lees than for thread, and confequently more fire in the fame proportion to heat it, fuppofing the fame boiler to be ufed. The fame remark is, in part, applicable to the muriatic acid ; but as this may be ufed rather weaker for cotton than for thread, the liberty of diluting it with water may be taken. If the bleacher, according to this new me- thod 202 The Art of Bleaching thod, {hall therefore fix the price of bleaching cotton thread at 8 fols 6 deniers the pound, and of cloth entirely of cotton at 6 fols the fquare ell, of every kind coarfe or fine, he may derive confiderable advantage, and the public will have no reafon to complain, fince cotton threads in genera], and likewife muflins, require much care and attention, on account of the delicacy of their texture and the flight tenacity of the fibres, the fhort ftaple of which, as is very well known, will fcarcely permit it to be turned on the reel without great care. It now remains to be fhewn what price ought to be fixed for the bleaching of ftockings of linen or cotton per pair. 1 fliall begin with plain thread ftockings of men's fize, from which an eftimate may be made for fmaller articles of the fame kind, as well as all other knit or ftocking-wove goods. I fliall likewife aflume that one pair of men's ftockings contains half a pound of thread, and confequently 6 pounds will be contained in one dozen pair. My calculation will be for :2 dozen or 72 pounds of thread. I fliall likewife aflume that one pound of green foap will be re- quired for the firft wafliing of fix dozen pair of men's ftockings, and one pound of white foap for the fecond and laft wafliing of the fame fix dozen. And accordingly I fliall add to the fum before s. d. Co/tons, Thread, £3c. 203 before deduced, for the mere and fimple bleach- ing of 72 pounds of linen, of which the detail has been given, the furplus in lixiviations, im- merfions, and wafliing with foap, which (lock- ings require. This amounts to two lixiviations, and the fame number of immerfions as I have fhewn at chapter X. Therefore firft fet down the fimple price of bleaching 70 pounds of thread, namely - To which add two additional lixiviations Two immerfions in the odorant muriatic acid Two pounds of green foap for the firft warning Two pounds of white foap for the fecond wafiiing Half a fack of turf to heat the folutions of foap A woman one day for the warning Total This account gives 8 fols 3 deniers for each pair of men's dockings ; and if 12 fols be taken for this article, I am of opinion that there will not be many bleachers envious of the advantage of rendering them milk-white at this price, on account of the difficulties they prefent, which require them to be turned from time to time to open the texture, which would otherwife become clofe and impenetrable to the muriatic acid: and if the ftockings be ribbed, or have clocks, it will not be too much to charge 14 fols the pair, on account 39 2 6 8 11 3 16 1 4 4 IS 59 12 204 The Art of Bleaching account of the particular care required for thefe kind of goods, the ribs of which being difpofed to fhrink up, are very apt to prevent the intire action of the acid. With regard to women's and boys' (lockings, 10 fols per pair may be charged, and for fmaller articles 8 fols; at which laft price gloves ought to be charged, becaufe the fingers being clofer than the other parts, require to be turned from time to time to produce an even colour. Mittens may be charged at 5 fols the pair. Articles of the fame kind of thread and cotton, mixed, de- ferve nearly the fame price on account of the thread which retards the bleaching. We muft now inquire the price of bleaching the fame articles in cotton. Here likewife I mall ground my comparifon on plain ftockings for men, admitting that 6 ounces of cotton will make one pair of this fize, which will amount to 41 pounds the dozen pair, or 90 pounds of thread for 22 dozen pair. To this laft quantity we fhall direct our inquiries, in which I fhall con- fine myfelf to add to the former determination with regard to 90 pounds of cotton thread of like quality, the extraordinary lixiviations and immersions which knit or itocking-wove articles require. This excefs, as fhown at chapter X. is half Cottons, Thread, &c. 205 half a lixiviation and one immerfion in the odo- rant muriatic acid. Liv. s. d. I (hall therefore reckon for the mere bleaching of 90 pounds of cotton thread as before ftated - 32 8 6 To which add half a lixiviation in a double dofe 340 One immerfion in the odorant muriatic acid - 5 ix 6 One fack of turf for heating the double quantity of lees - - - 080 Four pounds of green foap for the fin! warning 112 o Four pounds of white foap for the fecond and laft wafhing - -- - - 280 One fack of turf for heating the folutions of foap 080 Two days' work of a woman to wafh - 1 10 o Total 47 10 o Whence we fee that the coft for 1 pair of men's plain cotton (lockings is about 4 fols, and if the charge be fettled at 5 fols for men and 4 for women, or 4 fols 6 deniers one with another, there can be no caufe of complaint. Ribbed ftockings mull:, however, be excepted. Thefe deferve at lead an addition of 1 fol per pair for the extra attentions, which have been before mentioned. Nightcaps may be charged, one with another, at 2 fols 6 deniers : gloves, on account of the fingers, mull: be charged at 3 fols the pair, and mittens, and children's ftockings, at 2' fols. Xh< " icS The Art of Bleaching The foregoing are, in general, the articles which are ufually bleached at the proper works for that purpofe. With regard to the prices I have affi^ncd for bleaching; each article without any kind of dreiiing, they are fuch as I have, from my own experience, thought fit to advife to thofe perfons to whom 1 have had the pleafure of teaching this new and important art of bleach- ing. They are capable of being confiderably diminiihed bv turning to advantage the lees and acid which have been ufed as I have advifed in the proper place. But I have chofen in my eftimates to confider them as new, in order that I might be fubjeft to no reproach for diminifhing the charges which I have, on the contrary, ftated at the higheft, as every operator may convince himfelf. If to thefe firft favings of lees of mu- riatic acid, and of the other collateral and de- pendent objects, we add the advantage which may be derived from the old lees, as I have fhewn, as well as from the exhaufted bleaching liquor, the refidues of the retorts, &c. there can be no doubt but that all thefe different prices may be confiderably abated ; even though we might not venture to affirm that the expence would be entirely compenfated by the profit arifing from an intelligent application of thefe matters, which have heretofore been thrown away as ufelefs. CHAP. Cottons, Thread, &c. 207 CHAP. XVIII. The Method of bleaching yellow Wax, Nankeen Stockings, and other Articles which have acquired a dark Colour by keeping ; Linen Jlained by Damp- nefsy and the Madder Grounds of printed Gcods. JL HE bleaching of yellow wax may be ef- fected by means of the bleaching liquor, with fmell, as well as with that which has no fmell. For which purpofe a fingle immerfion, or, at mod, two, with the fame number of intermedi- ate fufions, are necefTary. The operation, never- theless, fucceeds more fpeedjly with the odorant muriatic acid, becaufe the wax bleaches as well above as below; which facility it acquires by its property of fwimming, and prefenting a greater furface, as well to the gas which rifes in the liquor, and bleaches in its paffage, as to that which efcapes above the ribbons of wax, which, being retained by the covers of the vef- fels, is forced to a£t upon the furface expofed to its a£lion by falling in a kind of dew. Thefe ribbons of wax mull be very thin. It is more convenient, however, to ufe only the vapour of the oxygenated muriatic acid, as 2oS Tie Art of Bleaching 3.s Berthollet informs us from the experiment of T-andriani. This laft method is, as I likewife find by experiment, much more effectual. To prove this truth, nothing more is neceflary to be done than to expofe wax rafped or fcraped into very thin leaves, under the cover of a pneumatic veffel, above the furface of the liquor. I am even difpofed to think that this experiment may point out the invention of a bleaching procefs in appropriate veffels furnifhed with different ftages of frame-work covered with coarfe cloths. The goods being fufpended through the whole height of the veffel thus conftrucled, or elfe in a chamber difpofed and appropriated to the fame effect, that is to fay, that it fhall be provided \rith fhelves, or poles, fo difpofed all round within its capacity, upon which the acid va- pour, directly conveyed from the neck of the retort, or admitted through the fides of the chamber, may thus act with great freedom and promptnefs, in the fame manner as the volatile fulphureous acid a£ts upon goods which are re- quired to be bleached by its means. I have alfo remarked, that the mafs of wax, with which the ends of 'the leaden tubes, plunged in the intermediate veffel when I ufed this apparatus, was rendered of a beautiful white through its. whole thicknefs, which was nearly half a line, and CottonSy Thread, &V. 209 and this by no more than two hours expofure to the action of the vapour. 1 The true nankeen is bleached or deprived of its colour with fome difficulty. It is firft to be wetted and wrung ; after which it i9 fubjee~red to a firft immerfion in the bleaching liquor, which deprives it of a large portion of its colour. It is then to be properly rinfed, and agitated in a good folution of lbap, which is preferable to lees, becaufe it caufes the colour, which had merely difappeared, to (hew itfelf again more effectually. The piece of nankeen is then to be well rinfed, and fubjected to a new immer- fion. The number of immerfions varies accord- ing to the ihade of the colour ; but this article feldom requires more than three immerfions, with intermediate warnings with foap< The finifh is given in a bath of fulphuric acid, after which it is to be rinfed in a large quantity of water, and then wrung and dried. This pro- cefs may be performed indifferently with either of the two acids, the odorant, or that without fmell ; neverthelefs the latter ought always to be preferred, particularly for the firft immer- fion, becaufe it more fpeedily and equally de- ftroys that kind of flefh colour which is peculiar to the true nankeen. Neverthelefs, though the oxygenated muriatic acid acts fo ftrongly on this f colour, a I o The Art of Bleaching colour, I never have been able to bring nan- keens to a white of the fame beauty as is ac- quired by cotton, thread, and piece goods bleached by this procefs. Stockings and other goods bleached by the old procefs, but which have acquired a ruddy co- lour, at the extremity of the folds, by remaining in the fhop or warehoufe, partly uncovered either from want of care or for fliew, require only a fingle immerfion without preliminary foaping or lixiviation. The ink marks which retailers are in the habit of making to afcertain either the number, price, or quality of their goods, partly difappear in this immerfion, and totally in the bath of fulphuric acid, in which they are afterwards plunged. Thefe goods are to have all the fubfequent dreflings, of which I have given an account, if the proprietor expects or re- quires it. It is a peculiar property of the oxygenated muriatic acid, to difcharge thofe black fpots which are feen on foul linen, particularly when they rife from perfpiration or moifture. The places moft fubjec~t to thefe flains, are where the linen is applied to the back or beneath the arm pits. This procefs is to be commenced with a lixiviation or boiling, which is to be fucceeded by^n immerfion, and afterwards by a bath Cottons, Thread, &c. m bath of fulpburic acid. However ftrong the fpots may be, they never refill thefe feveral operations. Spots of brandy likewife difappear by the fame procefs. With regard to the madder ground of paint- ed or printed goods, it is eafily difcharged by either of the oxygenated muriatic acids, a fingle bath ufually being fufficient for that pur. pofe. For greater convenience, it is advifeable to ufe the acid without fmel], becaufe the operator may, with more eafe, follow and conclude at a proper time the immerfion of the piece as foon as, while paffing it over the reel, he obferves that the ground is fufficiently white and clear. The bleaching liquor, which is partly exhaufted, may be ufed to advantage in this procefs. Be- fore the immerfion is made, care muft be taken to plunge the piece in water and wring it out fo far as to leave it merely humid or moift. After the immerfion it muft be well rince4 and dried either in the fun or in the fhade, turn- ing the coloured furface from the fun. It may be remarked that the deep reds are capa- ble of being again brought out, or rendered flightly red, by the fun's light, and the other (hades ad- vanced in proportion 5 this would happen in the eommon method of bleaching, if the printed * 2 part 2t2 The Art of Bleaching part were not always turned to the grafs. I fhall proceed to mention fome circumftances with refpecl to this method of difcolouring or bleaching, which may be of ufe to thofe who are interefted in applying it to practice. Goods printed in fait colours (bon tei?itj t for thofe with chemical colours (-petit teint) are too difficult to be treated by this method, intended to be bleached by the oxygenated muriatic acid, inftead of the ufual expofure in the field, ought to have their den^iis much more charged with colour, than fuch as are intended limply to be fubje&ed to the action of the air ; in order that while the acid exercifes its action on that part of the ground which is maddered without mor- dant, the fame action which is alfo exerted on the part where the madder is combined with the mor- dant, may not deftroy in the laft part any more of the colour than that quantity in excefs, be- yond what the piece ought to preferve to pro- duce the intended e fleet, and, confequently, that it fliould not, after the procefs, appear more fenfibly altered than it would have been after the ufual expofure in the field : this pre- caution ought to be attended to more particu- larly with regard to the ordinary violets, blacks, and browns. They are much more eafily de- graded than the red, or rofe-colours, and the deep browns. One Cottons, Thread, Z3c. 912 One leading objecl, which is effential to the prefervation of the colour, and contributes in- finitely to the unmaddering, is to give the pieces pne or two boilings in bran and water, which may follow a boiling in a folution of foap. If thefe three boilings are properly managed, the ground of the piece goods will be brightened at lead three quarters. One or two immer- iions in the bleaching liquor will remove the fmall portion of colour which remains. Be- tween the two immerfions attention muft be paid to plunge the goods in bran and water. This ought to be done after the laft immeriioi), for it raifes and relieves trje tone of the colours which may have been flightly weakened. I have feveral times found, that when the preparatory baths have been well proportioned to the grounds intended to be coloured, it is unnecefTary to apply the bleaching liquor. &. few days expofure in the field are fufficient afterwards to complete the bleaching. The proportions which I followed for the bath of bran and water, were three ounces and an half of wheat bran, and three pounds and an half of river water. Thofe for the folution of foap were two ounces of foap to four or five pounds of water; the weight of the goods to which thefe dofes were adopted were 10 gros. ? $ More, 214 Me Art of Bleaching Moreover, it is practicable, according to the depth of the tints, and the experience the ope- rator may have acquired, to diminifh the force of the oxygenated liquor to that point which may infure him againft a too perceptible de- struction of thofe parts which ought to pre- ferve their brightnefs. But, in this practice, the procefs is too flow, and the great advantage of ufing this method with regard to fuch kind of goods would thus be loft. In a confiderable manufactory, where the operations of printing and bleaching fucceed each other with rapidity, it might, perhaps, be more advantageous to clear off no more than three-fourths of the ground of the cloth which has received the madder without mordant, by fubjecting it to the boilings with bran, wa- ter, foap, and a flight immerfion in the liquor, as has been prefcribed, and afterwards to ex- pofe it to the action of the air in the fieid. This method of operating feems preferable, and would be no lefs expeditious, whether in fummer or in winter. And in the cafe only of the goods being in great hafte, the complete bleaching with the oxygenated acid might be advifcable, taking care to ufe all the precau- tions which have already been pointed out. In order to avoid expofing the goods to too con- Cottons 3 Thread, &c. 215 confiderable alteration, it is more convenient to pafs only one or two pieces through at a time, with the attention that they fhould be of the fame degree of intenfity in their colours, in order that if it mould be neceffary to ftop fud- denly the effea of the liquor, it may, in fome meafure, be done inftantly. This could not be eafily accomplifhed, if eight or ten pieces were fewed together as foon as foaped. For it is eafy to imagine, that while one piece was drawn out, the others remaining in the liquor too long a time, would be expofed to have their colours weakened, at lead in the propor- tion of the longer time they remained in the liquor. If it were thought an objea of fuf- ficient importance, this laft inconvenience, however, might be removed, by placing at the bottom of the veflel for immerfion a platform of ftrong balket work, which might be fpeedily raifed by means of a pulley, or other me- chanifm, to remove the goods out of the bath at the inftant it might be found neceffary, and they might afterwards be thrown into a refer- voir of water, or conveyed to the river. It would be a very delirable objeft, if the oxygenated muriatic acid could aa only upon the furface oppofite to the printed fide ot the piece. In this way it would operate like the P ^ atuio- 2i6 The Art of Blading atmofpheric air, without giving caufe to fear the deftru&ion or perceptible alteration of the fbades, whatever might be their depth. The difficulty of fucceeding, and the length of time required for bleaching, may, perhaps, fooner or later, give rife to a method of fixing the co- lour by particular mordants, without the aflift- ance of madder. It would alfo be a dcfirable object to difcorer a procefs to prevent too much degradation of the tranfverfal red or blue ftripes, and other or- naments of coloured thread, which are ufually made at each extremity or angle of cotton co- verlids. This procefs might alfo be applicable to the defence of thofe tranfverfal blue or red ftripes which are made in pieces intended for napkins, between one napkin and another, and at the ends of pieces of muflins and the like. The beft method, no doubt, would confift in manufacturing thefe goods entirely of one co- lour, and afterwards making the terminations with coloured thread. As thefe kind of jroods ate capable of being foiled, either by the dref- fing given to their chain, or by the different operations which fucceed or are previous to the weaving, they may be eafily cleanfed by a proper wafhing or foaping. The following is the expedient which I have thought Cottons, Thread, &c. 217 thought proper to ufe to preferve the ftripes in queftion from every action which might be too perceptible. After two good baths in the lixivium, each of the ftripes was covered, on both fides, with one or more coatings of chalk and oil, which was left to dry until the pieces could be handled without fear of fpotting the neighbouring parts. I then fubjecled them to the bleaching liquor, afterwards to a flight lixi- viation, and a folution of foap, &c. and fo on, fuccefhvely, till the ground was as clear as re- quired. After each lixiviation I took care to repair or renew the covering, if neceflary. I afterwards cleared off this covering of chalk and oil, either with a good foaping, or with a flight bath of fulphuric acid, according to the nature of the colour of the bar, and the degree of te- nacity of the paint. If by accident the colour of the bar was fomewhat weakened, it did not fail to be raifed again, by palling it through bran-water at the conclufion of the procefs. I apprehend that this expedient, which I have always ufed with a certain degree of fuccefs, will be acceptable to the'manufacturer. CHAP. 2i8 The Art of Bleaching CHAP. XIX. The Method of df charging the Colour of fainted or fritted Cottons, or Linens, and every Kind of Dye on Cloth cr Thread, before or after it is wrought up, -/jLLL the colours of callicocs, or printed goods in fail colours, are deftroyed by either of the oxygenated muriatic acids, without having recourfe to the lixiviations or other previous or intermediate operations before defcribed. The blues, yellows, and blacks, afford an excep- tion with refpect to the bath of fulphuric acid, which muft be fubftituted inftead of the lixi- viation. A fmgle immerfion in the muriatic acid is fufficient to deftroy all other colours, fuch as reds, yellows, auroras, green, &:c. ; but the yellows, properly fo called, and the lemon colour, with which greens are produced, and the blues and blacks, fometimes require, accord- ing to their (hade, three immerlions, and two or three intermediate baths of fulphuric acid. It Cottons, Threads , &c. 219 It muft not, however, be fuppofed, that the Adrianople reds, when difcharged by the oxy- genated muriatic acid, become perfectly white. There always remains a flight ruddy appear- ance, which arifes from the oily matter which enters into the preparation for this dye.. This tinge of rednefs does not difappear, however numerous the lixiviations and immerfions and baths of fulphuric acid may be. There is another thing no lefs worthy of remark with regard to the black colour, which, forms the outline or border of defigns, namely, that if the muflin, or cleared fine piece, upon which the different flowers were deligned which have been difcharged, be folded toge- ther in feveral folds, or placed upon a dark- coloured ground, the effaced outline becomes vifible according to the expofure of the piece under a certain obliquity of the light exhibiting the appearance of a flight trace. The kind of outline which, under thefe circumftances, be- comes vifible, cannot be compared to any thing better than the embroidery of muflins placed on a coloured ground. This trace feen at a cer- tain diftance has the fame effect, and even when clofely obferved, it is impoffible to determine what it is, becaufe it is not vifible, except under a certain reflection of the light ; never- thelefs 22* The Art of Bleaching thelefs the whole piece appears white, and or a very fuperior quality. I have remarked that this effect does not take place excepting with regard to the old prints of flowered defigns of the true India callicoes imported from that part of the globe. For in the .printed goods of our manufactures, fuch as thofe of Paris, Joly, St. Denis, and Beauvais, all the traces of the defigns completely difappeared, to my great furprize. It mult, therefore, necelTarily be admitted, that the difference in thefe refult* depend on the qualities of the mordants, which are more or lefs oily, or the manner of ftriking the blocks in the aft of printing. If this effect were produced by the mordant with the outlines of the defigns in the pieces of printed goods, it might, perhaps, be of advan- tage to take the fame method of obtaining a fubftitute, inftead of the rich expenfive em- broideries with which the fine muffins of India and Switzerland a^e covered. Thcfe defigns Jikewife do not appear in their full effect, but when they are placed upon a tranfparent fluff of a deep colour, which exhibits all the out- line. This method of producing fo rich an effett would be extremely fimple, fingularly permanent, and highly economical. I think, however, that I may add, that, after many trials I I Cottons, Thread, &c. 22 S I Lave at laft fucceeded in difcbarging this mordant, fometimes by a bath of fulphuric acid, rather ftronger than ufual, and at other times by foaping the goods before and after the bath. This management is very eflential to be known, in order that the operator may not be cxpofed to the mortification of feeing the fame defigns return again by the fecond action of the madder applied to the fame bleached piece in a fubfequent printing procefs. To obviate every accident of this kind, it will be proper to in- form the owner which of the methods have been ufed to bleach their goods, and in cafe the new method may have been ufed, it would then be prudent to pafs them previoufly through a good Bath of fulphuric acid. With regard to chemical colours, as they are called, which are applied on callicoes or other goods, they difappear immediately, and much more fpecdily, than fa ft colours. A fingle im- merlion in the weakeft oxygenated muriatic acid, without any other preparation, is Sufficient to deftroy them, excepting only the outline of the flowers, which, as has already been re- marked, requires particular precautions. Among the yellow colours of this defcription there is one, however, in the compofition of which fulphate of copper, fulphate of iron, and 222 ¥he Art of Bleaching and acetate of lead, are ufed, which is fo far from being deftroyed by the oxygenated mu- riatic acid, that, on the contrary, it is nxed by that means. This colour cannot be difcharged, unlefs the piece be previoufly well rubbed in a good bath of foap, which difpofes it fo far to detach itfelf from the goods, that the immer- fion it afterwards undergoes in the muriatic acid completes its difcharge. It is very remarkable, that, after the difco- louring of the printed goods, particularly brown or black, and when the oxygenated muriatic acid has combined with the merchandize, there arifes from the trough a certain gas, which acts upon and irritates the organ of fight only, to fuch a degree, that it is very difficult to fup- port its action for any confiderable time with- out a difcharge of tears *. This effeft, how- ever, is not very perceptible in a trough over which the workman has operated for the whole day, until towards the evening, whence it fol- * The effect of this gas upon the human body is very fimi- lar to that which was produced on the 22d Brumaire in the evening, the prefent year, 6th of the republic, by a thick mift, of which the influence was felt, more or lefs, through- out Paris. This action was exerted principally by an irrita 7 tion of the throat, a pricking fenfation in the eyes and nofe, and a difcharge from the head. The oxygenated muriatic gas produces the fame effects when it is breathed for any length of time, on which fubject lee chap. vi. of the prefent work. lows Cottons, Thread, &c. 11% lows that the acid does not a£t till after a confi- derable time upon the mordants, (o as to pro- duce this peculiar gafeous combination, which is then capable, by its quantity, of irritating the organs of fight. Thefe inconveniences may be avoided, by taking care to work thefe pieces under a glafs cover, exprefsly difpofed for that purpofe, nearly as is reprefented in fig. 1 and 2. in plate 1 ; or by making ufe of the covered verTel reprefented in fig. 1 and 2. plate 9. It would be an important acquifition to know the nature of the gas here fpoken of. With regard to piece goods dyed before or after the weaving, whether of thread or cotton, all the falfe dyes,-fuch as red, blue, green, flefli- color, orange, grey, black, &c. difappear in an inftant, and almoft conftantly, by a fingle im- merfion, and certainly by one immerfion and one lixiviation ; but it is moft ufual to omit the lixi- viation. The fame remark does not apply to the true dyes, or fair, colors, fuch as blues, Indian red, ftrawberry colour, deep brown, &:c. the yellow colour and lemon colour either applied to linen or cotton : thefe are much more difficultly effaced. They fometimes require one lixiviaticn between two immerfions, according to the force of the made. The blue in particular is the molt tena- cious 224 the Art of Bleaching cious colour ; it muft be obferved, that a bath of fulphuric acid muft always be given at the con- clufion, particularly with refpeft to the yellows, of the colour of ruft of iron, which does not to- tally difappear but in this laft fluid. With regard to goods which have not been maddered, and of which the defigns have been printed in oil, the firft preparation is that of the lees, in which they muft be heated, without rinf- ing or clearing off. After this, while they are yet hot from the lees, they mull be flrongly rub- bed in a good folution of fo?p. Moll of the colours are, by this means, partly difcharged, and their definition may be completed, either by. the oxygenated muriatic acid, or by the fulphuric acid. It is feldom Decenary to repeat this courfe of operations, many of thefe colours being ufu- ally difcharged by the foap. It is certainly proper to remark, in this place, that the effect of the oxygenated muriatic acid in deftroying all colours whatever, as well on printed goods, as in fuch as have undergone the procefs of dying, whether in the thread, or in the web, muft afford many perfons the advantage of multiplying, in fome meafure, the changes of their clothes, without going to the expence of new : for if the old or unlafhionable colours of a garment be difcharged, and it be afterwards font to Cottons, Thread, &c. 11$ to the printer's to receive a new defign, this fun- pie procefs would enable the wearers to change the faftiion every feafon, if they thought proper. The only expence would be that of difcharging the old colours and printing new, at fo much an ell, for the feveral colours, according to their re- fpe&ive value. It is equally obvious, that dealers in printed goods * might, by this means, vary or enlarge their fpeculations. I muft like wife add, it might be poffible to take advantage of the faid property of the oxygenated muriatic acid, to de- stroy the colours of dyed goods, or to trace any re- quired defign with the pencil, the pen, fimply in the way of outline, and in the manner of goods printed a la referve. I have feveral times attempted to iketch different flight defigns on fuch goods, principally in the muriatic acid without fmell, and I fucceeded perfectly in ob- taining very neat and fine traces. It might be, perhaps, an object of (till greater intereft, to give a rofe or other colour to piece-goods dyed d la referve, becaufe this method has not hitherto been applied but with refpecl to blues, and * It feems probable that the wholefale method of operating in England, and the effe£t of the excife laws, would render the practice here dsfcribed not very convenient in the English market, — T. €L fometimes 226 I'be Art of Bleaching fometimos to orange or olive colour, or a few other light colours of this kind. The fame thing might be done with regard to the. particular defigns or things which might be imitated on ftriped goods, the threads of which were dyed before the weaving ; from which it might be poffible, either to take away part of the colour, or to add at pleafure a ftripe of another kind. I have fometimes ac- complished this purpofe on blue and white ftockings, as well as, ftriped and chequed piece- goods, by lightly fprinkling the oxygenated muriatic acid upon them : the different drops of the acid produced a lingular effect by fpot- ting thofe ftockings and ftriped goods. All the goods thus treated may be warned with foap or lees, without danger of effacing the different lingular marks or defigns which have been traced upon them. The obfervation I have made, with refpect to dyed goods, is like- wife applicable with regard to certain patterns of one uniform colour ; it is probable that the prints might be made from a block impregnated with the muriatic acid, combined or amalga- mated in fuch a manner as to work with the fame accuracy as in the common practice of callico printing. 1 fliall hereafter relate an ex- periment Cottons, Thread, &V. S27 periment which I have made in fupport of this obfervation . I muft not omit the remark, that the oxyge- nated acid is very ufeful to brighten up the white defigns referved in piece-goods printed a la referve. It is well known that thefe white fpaces are feldom clear; .either becaufe the compofition being ill applied, or ill made, fuffers a fmall quantity of the colour to pafs through j or from the effect of the fulphuric acid in which they are fteeped to clear off the compofition, when it is made of tobacco-pipe clay, &c. If the piece, when taken out of the boiler, is not well cleared of its colour, this laft will flightly extend itfelf towards the blue, which is uncovered ; con- sequently, by fteeping the piece in a bath of oxygenated muriatic acid, after its immerfion in the fulphuric acid, the colour is not only brightened, but the referved white, in confe- quence of the neat finifh in its outline, is ren- dered much more linking in its effect. a. * * CHAP. 228 The Art of Bleaching CHAP. XX. The Methods of taking cut the Dye from Silk and. Wool. J^ILKS dyed in a fimple colour, fuch as indigo- blue, lilac, crimfon, and grey, are capable of lofing their colour, and acquiring a yellow cha- mois colour, by fteeping in a bath of oxygenated muriatic acid, without any previous or inter- mediate lixiviation or preparation. White filk receives the fame yellow colour, if expofed to this acid. But it is poffible to convert this yel- low colour to white, by expofing the filk to the vapour of fulphur or the fulphureous volatile acid. For this purpofe, it is neceffary that they fhould be yet in a moift ftate, to facilitate the equal a£tion of the fulphureous gas. It rauft be obferved alfo, that the goods ought not be ex- pofed too near the flame of the fulphur, becaufe the heat dries them, and retards the aclion of the Cottons, Thready &c. S29 the volatile acid, and may likewife give them a fcorched or brown colour. Compound colours, fuch as browns, violets, greens, and blacks, likewife lofe their colour, and acquire a fimilar tinge of chamois yellow ; but this difcolouring commonly requires two immerfions. The blue of brown violet and puce colours commonly difappears firft, leaving the fhade of red more or leis weakened. The fame gradation takes place with regard to the green and orange colo jrs, of which the yellow gives way firfl:. The blue of the former, and the red of the latter, only remains. It is neceffary that the oxygenated muriatic acid mould be weak (legcre) otherwife it would ac- quire an aurora colour inftead of a rofe colour, when it afterwards came to be fteeped in ful- phuric acid ; for it is to be noted, that it is pro- per to ufe a bath of fulphuric acid, and rinfe off with much water previous to each of the faid immerfions. With regard to black filks, the brown difappears firft, and leaves the blue ground, if this may have been ufed ; or the root ground, fuppofing this lafl: to have been the bafis of the black. Thefe obfervations, refpecting filk, hold good alfo with regard to wool dyed grey, orange, green, Q. 3 Saxon a 30 The At of Bleaching Saxon blue, apple green, root or fawn colour, brown lemon, and dipped blue. All thefe co- lours difappear more or lefs readily, and become of a chamois yellow, like the filk ; but this laft tint is eafily brought to the original white, by expofure to the volatile fulphureous acid. Two immerfions in the oxygenated muriatic acid are fometimes required, according to the depth of the colour ; and the expofures to fulphuric acid will like wife require to be occasionally repeated. For if the cbamoi.s colour ioes not totally difap- pear at the fir ft expofure, it will at the fecond. If we attend, for a moment, to the alterations which woollen and filken goods undergo by ex- pofure to the air, we lhall immediately fee, that the oxygen of the atmofphere is the principle which acls on the colouring matters with which the goods are impregnated, particularly the falfe dyes ; and that the change is of the fame nature as that which is produced by immerfmg thefe goods in a liquid which is, in fome meafure, faturated with that principle. The difference confifts only in the fpeed with which this effect is brought about in the latter cafe. The yellowifh colour produced by the oxygen of the air is particularly obfervable in grey woollen with a raifed nap, and loofe hofiery of the Cottons, Thread, Be- 0.3 i the fame colour. This mode of fabrication and opennefs of texture probably affords a ftronger hold to the oxygen, from the more extended furface it prefents. With regard to dyed filks, thofe of a rofe co- lour, and Saxon blue, as well as the falie blacks, are moft fubjeft to alteration by fimple expofure to the air. d 4 CHAP. 2$l The Art of Bleaching CHAP. XXL Dying by the oxygenated muriatic Acid. I HAVE little to fay, with regard to the dyes, in which the concurrence of the oxygenated muriatic acid is of advantage, after thofe of the nankeen and lemon yellow, of which I had oc- cafion to fpeak in the fifteenth chapter. I fhall here fpeak only of the different tinges of grey, which are obtained by plunging white wool or iilk in a folution of fulphate of copper, and after- wards taking them out and immerfing them in a bath of the oxygenated muriatic acid, either with or without fmell. By this treatment the operator will obferve the gradual appearance of a fine grey colour, more or lefs dark, and varying in its tinge, accordingly as the folution of the fulplate, or of the oxygenated acid, may have been concentrated. This dye appeared to me to be folid > for I perceived no alteration in its fhade after expofing it for feveral days to the fun, and to a ftrong folution of foap. It may be proper, in this place, to fpeak of a black or grey dye varying in its fhade, which I have feveral times feen fuccefsfully made, in thofe Cottons, Thread, &c. 233 thofe glafs-houfes where the mineral alcali, with the crude foda, or the purified fait, is ufed. I here fpeak only of the Spanim foda, which is well known to contain a certain quantity of the mu- riate of foda, the prefence of which is indicated at the moment of the fufion of the glafs : for at this period more efpecially, as well as during the whitening of the frit, there exhales from the pots, for about half an hour, a thick white fume of muriatic acid, which afts on the nofes and mouths of the workmen, and caufes them to cough and fneeze : its prefence is likewife ma- nifested by the ruft which immediately covers the pipes and other iron implements, placed within its reach, which the workmen are obliged to brighten, whenever they ufe them. I have con- cluded that the dye, of which I mail here give a concife account, was the more evidently pro- duced by the action of the oxygenated muriatic acid, becaufe a confiderable quantity of man- ganefe is ufed in the glafs-works in which it is praclifed. The quantity ufed is fuch that the cadmia fornicorum of thefe works are of a perfeft violet colour. The following is the procefs I have feen in pra£iice, at the glafs-works of St. Gobin, in the department of Aifne, as well as in that of Tour- la-ville, in the department oflaManche. The former 234 The Art of Bleaching former of thefe eftablifhments ufe wood for fue], and the purified fait of the foda of Alicant; the other burns pit-coal, and ufes the fame foda in the crude ftate. The fkems of thread being previoufly warned in lees, or cleaned and afterwards rinfed and dried, are fteeped in a folution of alum, in river- water. When they are well foaked in this fo- lution, they are dallied ftrongly upon a kind of blackiih foot, which is fixed along with the fa- line vapours by the internal projection of the fur- nace above the glafs pot or crucible. After having repeated this a number of times, in order that the thread may become more or lefs loaded with the foot, it is agitated or rinfed in the fame alum water, and again dafhed againft the foot, until it is thought to have acquired a colour fufficiently equal and deep. Laft of all, they are rinfed in the fame water, in which they become deprived of the excefs of faline and colouring matter ; after which they are flightly rung out, and dried, either in the fun, or in the made. This black or grey colour, which the thread has thus acquired, is fingularly tenacious. I have neck- ings of thread, thus dyed ten or twelve years ago, which have been warned in lees upwards of forty times, and have loft not the leaft portion of the intenfity of their colour. It is to be remarked, that Cottons, Thread, &c. 235 that linen and cotton piece-goods are dyed by the fame procefs. There is no doubt but it would be poffible to imitate this dye, with pro- fit and advantage, by fome direct manufacturing procefs. I have made fome trials which have fucceeded, to a certain degree, by putting the foot of pit-coal into alum-water, in which I fteeped thread, which acquired a fhade, and was afterwards put into a bath of oxygenated muriatic acid. I repeated this alternation feve- ral times, which appeared to communicate an equal dye, and this dye was very flightly altered by foap. I We may likewife give the fame grey or black fhade to cotton, by boiling it for fome time in a certain quantity of the faline foot of the glafs- works, ufually difFufed in water, in which mix- ture the thread is (imply turned and worked for a number of times, without any previous or fubfequent operation, excepting that of wafhing or rinfing, which is always indifpenfable. I have, in this manner, dyed white thread (lockings of a violet grey colour (grifdelin). This (hade be- came fome what pale after repeated warnings. CHAP. i$6 The Art of Bleaching CHAP. XXII. Various Properties cf the oxygenated muriatic Acid. Ti HE power of difcharging every kind of co- lour from painted or printed goods, mud render the difcovery of the oxygenated muriatic acid of the higheft value to manufacturers of paper, who may very profitably avail them- felves of the acid to form white paper out of coloured rags. It, in fome meafure, affords them an additional refource to fupply their manu- factories with raw materials, and to avoid any particular forting. They may, even in this re- fpett, extend their fpeculations to cordage, oakum, old fails, and other articles, which they may bleach as fpeedily, and in as large a quantity, as they pleafe, without giving them- felves any concern about the fcarcity of rags. It may alfo be queftioned, why the bleaching property of the oxygenated muriatic acid mould not be ufed to whiten paper which has been written Cottons, Thread, &c. 237 Written upon, and is become wafte. This paper may afterwards be fized again, like any other fort, by which means the product and activity of this manufactory may be inftanta- neoufly augmented. This laft object is fo much the more eafy to be attained, becaufe the leaves of paper, containing writing, require to be fteeped only one fmgle time in the oxygenated muriatic acid without fmell. The work is, therefore, of the greateft facility. This firft operation may be made on a number of leaves together, difpofed in fuch a manner that the oxygenated muriatic acid may furround and pe- netrate each leaf fufpended in the fluid. It mull be followed by a bath of fulphuric acid, of the fame ftrength as has already been prefcribed for the dreffings. This bath is effentially ne- ceflary, however clearly the ink may appear to have been discharged when the paper comes out of the muriatic acid. The fulphuric acid is required to take up the iron, which, as is well known, compofes a great part of every writing ink. Care mult be taken to wafh the paper, when it comes out of this laft bath, in clean and limpid water, in order to carry off the fulphuric acid, after which the paper may be fized, if ne- ceflary, and then left to dry. Such paper as has been lized before it has undergone this ope- ration. 2j 3 The Art cf Bleaching ration, will not require fizing again, or at leaft this is very fcklom the cafe, unlefs it has re- mained too Jong in the rinfing water. The paper, when dried, muft be afterwards treated exactly in the fame manner as if it had been newly manufactured. This method of bleach- ing written paper may alfo be of the greateft ufe to men of bufinefs of every defcription, merchants, and others, who ufe many books. When thefe have become ufelefs, and out of date, they may, by the method here directed, be eafily cleared of their writing, and ren- dered ufeful a fecond time *. When we re- flect on the property of the oxygenated muriatic acid to difcharge ink from paper, we obferve, in the action of this liquor, a kind of analogy with that action which takes place, in the courfe of time, with refpeft to ancient writings. There is reafon to think, that, in this lair cafe, the air, by virtue of the oxygen which it contains, is acted upon in the fame manner as the oxygenated muriatic acid ; for old writings * Since thefe experiments I have had occafioa to make others, as well on the bleaching of the pafte of paper, as on dif charging the colour of written or printed papers. I have, therefore, thought it ufeful to infert, at the end of this work, the feries of particular proceffes which I have made ufe of* and which I addrefled to the different committees of the .Na- tional Convention, in the year Ii. of the republic. are Colt ens y Thread, &c. j^o are fo confiderably altered, that a fingk flirht bath of fulphuric acid is often fufficient to dif- charge them entirely, and in cafe this bath fhould not have been fufficient, they do not refill a very flight immerfion in the muriatic acid. The fame obfervation may be made with re- gard to fnow and dew; both thefe fubftances difcolour and foon render the foles of fhoes yellow when expofed to their a&ion. This ob- fervation may very eafily be made after walking out on the fnow or grafs embibed with dew. On the fame principle it is in the mountainous country, in the department of La Somme, the country people clear their linens limply by ex- pofmg them in the winter to the a&iori of the fnow, the dew, and the mills, without giving them any other preparation; except that they are careful to turn them from time to time on the ground, for about fifteen or twenty days, dur- ing which time this vegetable fubftance is expofed to the influence of the air and the a'tmofphere. A folution of fulphate of foda, and the re- fidue of the dialling veflels, is fometimes fuf„ fkient to difcharge thefe ancient writings, which are already in part effaced by the oxygen of the atmofpheric air in the courfe of time. I muft here mention an obfervation I have had 240 The Art of Bleaching had occafion to make in the courfe of my ope* rations on the bleaching of threads and cloths. The waters which had ferved to rinfe the fingle, double, and twilled threads, when taken out of the lees, were very foon covered in the veffels, where this rinfing was then performed with a kind of lather, more or lefs white, accordingly as the thread was more or lefs advanced in its bleaching. This froth, which rofe to the top of the water, wasfometimes more than an inch in thicknefs, according to the quantity of thread or cloth which was rinfed or cleared, and forms* an excellent parte for the immediate manufacture of paper. It may, in fact, be . eafily underftood that this fubftance is of the fame -nature to that which is ufually formed by the decompofed rags in the paper-mills, and is, in the prefenf cafe, form- ed of an affemblage of the filaments of thread or cloth detached by the lees or the acid, but more particularly by the former, and more fpeedily and effectually feparated by the rinfing. I can alfo affert, that the famples of paper which I- have attempted to make with this material, were very beautiful and fine. The bleachers may, there- fore, referve this produce, and fell it to the paper manufacturer at a price which muft necef- farily vary according to its colour and quality." The fame remark is applicable to the inner part Cottons ', Thread, &V. 94 1 part of the fides of the veffels or tubes which is direclly bleached by the action of the oxyge- nated acid, which, in procefs of time, renders it of a very fine white colour. This ligneous fubftance, when collected, is alfo very proper to form paper, after it has undergone the pre • vious action of the mallets or cylinders of the paper-mill, and is afterwards properly diluted with water, according to the practice of the paper-makers ; a very confiderable quantity of this pafte may even be collected in a fliort time. Nothing is more neceflary for this object than to difpofe the wood in the veffels defiined for this purpofe in fuch a manner, that it may pre- fent alternately to the acid and the fait of the intermediate lees the greateft quantity of furface poffible. Two lixiviations, and two immerfions, are fufHcient to alter the wood fo far that it may be rafped off with advantage. This very eco- nomical method may, with much profit, be ufed to fupply certain paftes, which will afford very fine and good paper, according to its beauty* its whitenefs, and the proportionate mixture of other paftes formed from rags. I have in this manner fabricated fmall famples of paper, which I mewed, at the beginning of 1789, to the adminiftration of commerce, announcing this particular method, as well as that of mak* mg $4 2 The Art of Bleaching ing a kind of grey paper with the tufts of the typha paluftris. Thefe paftes are not to be re- jected, even fuppofing they could only be ufed for the white-brown or common paper, or for pafleboard ; as they would always contribute to render the fine rags more abundant for the ma- nufacture of white papers, to which ufe they might be entirely referved, if it fhould not be found advantageous to mix them with the other materials to produce the intermediate kinds of paper. Olive oil, expofed in the uppermoft falfe bottom of the pneumatic veffel to the gas or vapour of the oxygenated muriatic acid, pall- ed through water loaded with potafh in the proportion I have pointed out, became changed to the confidence of foft foap, or very white greafe, without tafte, nearly mifcible with wa- ter, not foluble in the fpirit of wine, nor fub- je£f. to any perceptible change by the ordinary muriatic or nitric acids. Rectified fulphuric acid alone decompofes it almoft as foon as poured on. The muriatic acid, with which the oil was combined, flies off, and the fulphuric acid changes the white and foapy colour of the oil into a brown mafs, which very foon after- wards became blackiih. Does not this expe- riment lead to a prefumption that it might be poffible Cottons, Thread, &V. 243 foflible to form a kind of muriatic foap in the foft or hard form, which mould have the pro- perty of bleaching ? Thus much is certain, that from this notion I have attempted to com- bine olive oil with potafh, partly neutralized by the oxygenated acid ; and a fample of thread, which I bleached and foaped with this kind of foap, appeared to me to become white to a higher degree, and much more fpeedily, than by the method above defcribed. This new method would be of infinite utility in every refpe£t. Copper or brafs expofed in the fame manner as the oil above mentioned to the a£tion of the oxygenated acid gas, became, at firft, blackilh, after which it was covered with a firm, dry, pellicle of verdigreafe, as well above as be- neath : this verdigreafe was of a very fine colour. When warned and ground, it is abfolutely equal in colour to that fine Englifh green fo highly efteemed, with which the fafhionable papery hangings are printed. It might be poflible to obtain this matter, in great quantities of it, at a low price, by conftru&ing an apparatus for this purpofe. I have obtained this kind of verdi- greafe by putting copperplates into the waters obtained from the refidue of the diitilling veffels. I have had occafion to remark on this fubjecr, r 2 that 244 "ft* 6 drt of Bleaching that the fluid was, in the courfe of time, covered with a pellicle fimilar to that which rifes upon milk when fet to boil, but of a green colour. Water, impregnated with the gas, has no action upon the copper, except in the courfe of a long time ; but the gas itfelf acts inftantly either upon copper or brafs. This kind of verdigreafe may alfo be ufefully employed in dying, and, in many inftances, fup- ply the place of that which is made with the refufe of grapes in the fouthern provinces. Tin vefTels (pewter) are totally diffolved or corroded by the oxygenated muriatic gas, and aflume a grey colour. Malacca tin is corroded in like manner, but it affumes a whitifh colour. From this experi- ment it is that we have thought proper to con- clude, that the folder of leaden tubes cannot long refift the aftion of the gas or liquor which is impregnated with our acid, and that it is par- ticularly neceflary, when tubes of this metal are to be ufed, that they mould be caft entire, or without folder *. * As the muriatic acid, whether oxygenated or not, when in the expanded or vapourous ftate, attacks, and fpeedily f ults copper, iron, and tin, it is improper to have in the, place of diftillation, any vtflel or inftrument made of thofe metals, becaufe they would fpeedily be deftroyed. Sheet Cottons, Thready &c. 84$ Sheet lead did not all, or fcarcely at all, change its colour or properties by this expofure. It merely acquired a flight brown tinge. It was in confequence of this experiment that I de- termined to fubftitute tubes and adopters of lead inftead of thofe of glafs, and to recom- mend that the pneumatic veffels to be made of common wood, and that thefe, as well as the veffels for immerfion, mould be defended with meet lead. Litharge of gold, or yellow litharge, remains dry, and undergoes no other effect than to ac- quire a violet colour. The directions or addrefs on the outfide of letters difappear entirely, without leaving any trace or alteration in the paper. This experi- ment, added to that of taking out the ink- marks made by the proprietors of (lockings, gave me the firft hint to apply this method of bleaching to written paper, which I have men- tioned in this chapter. Red fealing-wax became of a pale rofe- colour, and was reduced into a kind of moid or foft wax. Indigo, in fmall fragments expofed in the fame manner to the oxygenated muriatic acid o-as, changed its colour from a deep blue to the yellow colour of dead leaves. Black pitch merely became red at its furface. Hair, and feathers r 3 cf 246 The Art cf Bleaching of a black colour, were changed, the firft grey, and the latter to an aurora colour. Green oil- cloth (tcih die.'), fpotted with black, became very white, and fpotted with brown fpots. Fluid vegetable alkali, being the foluio^ of blue potafh expofed to the fimple contact of the oxygenated muriatic acid, acquired the property of bleaching like the true water of Javelle, but, inftead of the clear yellow colour it at firft poflefTed, it became white and limpid, The bottom of the faucer made ufe of was lined with an infinite variety of very white cryftals, in thin brilliant plates, of a dry appearance, like talc or mica -, having the appearance of fo many factions of the cryftals of fulphate of potafh, through the whole length of the prifms, termi- nating in their pyramids. Thefe cryftals might be one line and an half in length, one in breadth, and near a quarter of a line thick. This expe- riment, and another mentioned in the following chapter, feemed to prove that the violet colour of the lees, diitinguiihed by . the name of ja- velle, is, as Berthollet has obferved, more par- ticularly owing to manganefe, of which the co- louring matter is carried off with the gas that efcapes. The folution of mineral alkali, extracted from the foda of Alicant, and of an amber colour, being Cottons, Thread 3 &c. 247 being expofed in the fame manner as that of the vegetable alkali, acquired the fame property of bleaching, without, however, entirely lofing its own colour, or prefenting any cryftalization. Pure water, expofed in the fame manner, ob- tained the fame property of bleaching, preferv- ing its natural colour, without exhibiting any obfervable peculiarity. Thefe three different fluids, by becoming thus impregnated by the muriatic acid gas, feem to prove that it is not abfolutely neceffary to agi- tate the water of the veffels to concentrate the gas. An experiment with the intermediate tubulated veffels of the old apparatus, in which I have obtained pure folutions of this gas, co- loured yellow or greenifh, and marked from ten to twelve degrees of concentration, appear like- wife to fliew that agitation of the water is not, in ftrictnefs, abfolutely neceffary. Thread, which had been fubjecled to the lees, and was merely moift, or (lightly humid, with the lixivial folution, being limply expofed to the vapour or oxygenated acid gas, acquired a ruddy white colour fimilar to that of the third immerfion, and without any kind of altera- tion. Coarfe thread, macerated feveral days in a \veak folution of fulphate of potafh, became r 4 three- %±3 "The Art of Bleaching three fourths bleached, and with much uni- formity or evennefs of colour. Flax macerated in the fame manner likewife obtained a very fine white. Flax, macerated for feveral days in the folu- tion of potafh, one degree below zero, and ex- pofed, like the objects above mentioned, to the oxygenated muriatic acid gas, became of th moft beautiful white. All thefe different articles were fubjeft to no alteration. It is true, that, being apprehenfive left the gas, with which they were impregnated, mould alter their texture in confequence of its concentration when they ihould become dry, J was careful to wafli them out in a large quan* tity of water. May we not infer from thefe various trials, which were all made during the winter of 1790, that it is highly probable that threads and piece- goods might be advantageoufly bleached by fimple expofure to the vapour of the oxyge- nated muriatic acid. For this purpofe it ap- pears to me, that the various articles, flightly moiftened with water or with lees, would re- quire to be hung up in a very clofe chamber, like that which is ufed for expofmg goods to the vapour of fulphur, into which room the extre- mity of the diftilling veffels mull be introduced, to Cottons, Thread, &c. 249 to convey the gas in proportion as it mould bo difengaged. An experiment of this nature would require peculiar management, and its fuccefs would be of the greateft importance to the manufacturer. CHAP. 2 50 The Art of Bleaching CHAP. XXIII. On the Pojjibility of applying the Refidues to Profit, T JL HE refidues to which the attention of the operator may be directed, in order to derive advantage, are : 1. Thofe of the retorts, bottles, or other diftillinar veflfels : 2. Thofe of the im- merfions, or bleaching liquors: 3. Thofe of the alkaline lees, or foap : and, 4. Thofe of the baths of fulphuric acid. The refidues of the retorts, bottles, or other diftilling veflels, are reducible to the following : 1. Manganefe not difcoloured, and the common muriatic acid coloured by manganefe, if the muriatic acid has been ufed inilead of the mu- riate of foda : 2. Sulphate of foda, and a fmall portion of muriate of foda not decompofed, if this laft has been made ufe of: 3. Sulphate of potafh, if lees have been ufed to extinguish the fuffocating odour of the refidue of the folution, which is always more or lefs impregnated with oxvjrenated muriatic acid. Though Cottons, Thread, &?£ z$t Though I have reduced the proportions o£ manganefe to one-fixth lefs than directed by Berthollet, it is not,neverthelefs, difcoloured after the operation, or rather, it is only difcoloured very flightly, and in few places. In this ftate it ftill prefer ves fufficient virtue, that is to fay, enough of vital air to be mixed with about one-third of new manganefe of the fame quality. This pro- perty, or ftrength, cannot, however, be afcribed to manganefe in lumps, or interfperfed with quartz, though well cleared of foreign matter. The manganefe cryftallifed in needles, fuch as is fold by Lapelletier, has alone afforded me this. very perceptible difference *. Every other man- ganefe, on the contrary, that is to fay, the fpe- cimens in lumps, afford a much lefs quantity of gas, and render the bleaching liquor lefs ftrong. This laft kind of manganefe is alfo harder and more troublefome to pulverife. The manganefe taken out of the retort, after the firft diftillation, preferves almoft the whole of its metallic brilliancy, and foils the hands as before, and may be ufed to purify glafs. It is true, that in this ftate it feems to have increafed in bulk. Manganefe entirely decompofed is known by the whitifh or pale * This manganefe is brought from Hambourn;, in the duchy of Deuxponts. purple 25ft The Art of Bleaching purple colour, which the ftrong impreffion of the fire has given it. The fbmrion of the refidue of the diftilling veffels diluted with water, the evening after the dilliilation, is found on the following day, if the veffels have been clofed, to be of a fine red, in- clining to violet or purple, accordingly as the foiutionhas been more oi' lefs diluted; but this colour does not fail to disappear by expefure to the open air, or by the heat employed to eva- porate it. In either cafe, the violet colour of the foluticn is changed for a iliade inclining to apple-green. It feldom happens that the water which holds the refidue of the retort or bottle in folution, is not fufficiently concentrated to afford, after re- maining for a day or two in the receiving vef- fels, cryllals of the fulphate of foda ; but thefe cryftals, which are of different fizes, are covered with manganefe, from which it is neceiTary to clear them. This is eafily done, by putting a fmall quantity of thefe refidues into a veffeJ, and pouring a little clean water upon them, which, after brifo agitation, mull be imme- diately poured off, before the manganefe fub- fktes, into a proper veffel intended to receive this laft fubftance. This manoeuvre is to be re- peated Cottons, Thread, trie 2$$ peated four or five times as quic^'y as poflible, in order that lefs of the fait may be diflblved. This trouble of warning may be avoided, if the violet-coloured water, which covers the re- fidue of the diftilling veflels, be carefully de- canted off into wooden or leaden receptacles appropriated to this purpofe. The cryftals, which are foon afterwards formed in this water, are neat and clear as they ought to be. But it is neceflary, after having decanted this violet- coloured fluid, that common water mould be poured into the retorts or bottles, for the pur- pofe of facilitating the extraction of what re- mains. This, together with the water, muft be referved by itfelf. If it be propofed to fepa- rate the manganefe, for the purpofe of ufing it again, as I have before mentioned, the follow- ing method mull be recurred to. The refidue muft be warned repeatedly with a large quan- tity of water till it gives no perceptible faline or acid indication. The refidue muft then be dried, and afterwards mixed with new manga- nefe, in the proportions before directed. If the waters of the wafhing be fufficiently impreg- nated to render it proper to mix them with the violet water, in order to increafe the producl of cryftals, whether by infeniible evaporation, or by the affiftance of heat, this muft be done, taking £54 &>* Art of Bleaching taking care only, that in the latter procefs leaden veffels mud be ufed, becaufe copper, iron, and mod other metals would be fpeedily corroded and deftroyed. The fulphates of foda and of potafh, which are obtained from the wafhings of the refidue of the diftilling veffels, have not hitherto been ap- plied to any ufe in the arts. It is poffible, as I have before remarked, to employ them for dif- colouring certain ribbands, and effacing writing from paper or parchment, as well as for fcour- ing copper and iron for braziers, &c. Both thefe falts are likewife ufed in medicine when puri- fied -, but it may be doubted whether the apo- thecaries would purchafe them, becaufe the very fmall quantity they confume is afforded very cheap from the falt-works of Lorraine and other places. It would, therefore, be much more interefting to decompofe thefe falts, and obtain the alkalis, in a difengaged ftate, which might, in that cafe, be ufed, to make the lees in the fubfe- quent operations. Berthollet, in the firft vo- lume of the Annales de Chimie, informs us, that feveral perfons have communicated different recipes to him for effecting this purpofe ; it were much to be wifhed that the authors would benefit the public by a more liberal communi- cation. Cottons, Thread, cjrV; ac; .? Cation. In the mean time I mail here remark, that it is very poffible to decompofe thefe neu- tral falts by means of liberal fulphur and the muriate of foda, by the fulphuric acid, and more efpecially by certain metallic oxydes, par- ticularly that of lead. I have fuccefsfully tried this 1 alt method in 1784, which was indicated by Scheele. The alkali which is obtained by thefe different proceffes is of the pureft kind, and I have had reafon to be affured, that, with proper treatment, it affords glafs equal in beauty to flint or cryftal glafs * The fecond refidue, which may be applied to ufe, is that of the exhaufted liquor of im- merfion. After the vital air, or oxygen, has been exhaufted, the odorant liquor contains nothing but muriatic acid and water; the liquor without fmell likewife contains muriate of pot- afh. This fait, as well as the neutral falts, w r ith * The Committee of Public Safety published, in the fe- cond republican year, the various procefTes for decompofing muriate of foda, which it had received from the different au- thors or inventors. Eftablifhments may, therefore, be made for fupplying the national commerce with the alkaline fait of foda, the ufe of which is indifpenlible in different works, fuch as thofe of glafs, foap, dyeing, bleaching, &c. for the fupply of which feveral millions are annually expended among foreigners. Note of the Slather, A copy of this report may be feen in the Annales de Chimie.— 7*. a fixed 2 $6 fhe Art of Bleaching a fixed alkaline bafe, is of fome ufe in medi-> cine, but it is not worth while to extract any thing but the fulphate of foda. This may be decompofed for the fake of the alkali, if the refulf mould be attended with fufncient profit, I mall fimply remark in this place, that thefe exhaufted bleaching liquors may be effectually ufed in making fill ammoniac. The different trials I have made on this fubjecl, by combining them with the volatile alkali of putrified urine or rotten vegetables, have conftantly tended to confirm my opinion. Laftly, if it fhould be found advantageous to reduce the pure bleach- ing liquor without potaih to the merchantable ftrength, it may be ufed for the fubfequent diftillations, in the fame manner as other mu- riatic acid, inftead of the muriate of foda and fulphuric acid j unlcfs, indeed, it ihould be thought more advantageous to ufe it for making white lead or verdigris, both which combi- nations I have made and ufed in painting with fuccefs. The verdigris might alfo be ufed in dyeing. I have alfo occafionally ufed thefe waters of immerfion of the muriatic acid without fmell, to make the fecond lees for piece-goods and threads. This fluid becomes as highly charged as if the lees had been pure. The exhaufted bleaclr Cottons, Thread, &c. 257 bleaching liquor may likewife be ufefully em- ployed in the firft maceration of goods ; for which purpofe, when it is not highly charged with colouring matter, it is no lefs valuable than the new liquor from the pneumatic veffels. There is another property of the exhaufted bleaching liquor, which is, perhaps, of conlider- able importance, namely, that of accelerating the vegetation of plants ; from repeated trials I can affirm that it pofleffes peculiar properties in this refpecl. I have at different times ufed it, inftead of common water, on cauliflowers, chervil, peas, cabbages, leeks, &c : and thefe various plants have not only grown more quickly than others of the fame kind planted in the fame bed, and watered with river water, but have likewife acquired double the fize. Befides the property of accelerating vegeta- tion, thefe waters have likewife the property to drive away, at the inftant of pouring on the ground, the fpiders, ants, worms, fnails, and other reptiles of this kind, which are noxious to plants and feeds. A gardener, near the la- boratory where I made the muriatic acid for bleaching, was fo fully convinced of the advan- tage of thefe waters, from his own experience, that he requefted, as a favour, that I would re- serve them for his ufe; and was continually s fpeak- 258 The Art of Bleaching fpeaking in praife of the good effects it produced on the plants in his garden. But in proportion as the fmall quantity of oxygenated muriatic acid, diffufed through' the exhaufted water, is of advantage to vegetation, fo much more noxious it is to plants when in the form of gas or vapour. Plants expofed to this elaftic fluid infrantly fade and perifli. I have frequently feen this effect on the plant monk's-hood, and even on vines, the leaves of which foon became vellow, and the ftems, after having languished for a certain time, partly died. With regard to the third refidue, of which the waters of lixiviation form a part, I think I have faid all that is neceffary in the chapter upon lixiviums. I (hall here only add, that if there were an opportunity of difpofing of them to advantage to a faltpetre-work, it would pro- bably be more advantageous than to reduce them by evaporation. There is, however, rea- fon to think, that the old lees might be re- stored to a certain point by boiling them a long time with lime j this earth, having the property ct dcftroying the vegetable parts which cover and weaken the alkalis, might, perhaps, produce the fame effect as reducing the folution to the iblid confidence. The following is likewife an economical me- thod Cottons, Thread, &c. 259 thod of constantly applying the fame lees to ufe, which I have often employed with the greateft fuccefs. It confifts fimply in throwing the afbes, from which they have been extracted, into the fires ufed for domeftic purpofes in the houfe, fufFering them to dry, and afterwards wetting them with the exhaufted lees from time to time, which are to be referved for this purpofe. The flame of the wood, burned in the chimney (for thefe obfervations are only applicable to a wood fire), and the heat of the hearth, foon burn the impurities, which coloured the alkali, and the afhes fpeedily become proper for lixi- viation as before. This operation, which de- mands very little care, may be of great ufe, ^even in the domeftic concerns of a houfe where alkaline lees are ufed. The foap-waters likewife are not to be neglected. It would be poffible to decompofe them, either by means of the waters which have ferved for the baths of fulphuric acid, or with thofe of the exhaufted bleaching liquor ; but the beft ufe would be for the manufacture of falt- petre, for which purpofe the alkali mult be ex- tracted by calcination. In the laft cafe the procefs is nearly the fame as with the lees - 3 that is to fay, when the foap-water is reduced to the con- fidence of extract, and nearly dry, the oil mutt s 2 be 260 The Art of Bleaching be burned off in an open fire, which will leave the alkali foluble in water, and ready for ufe, in the diftillations and lixiviations, in the fame manner as new potafh. I have pra&ifed this method, and muft here remark, that new foap- water rifes in froth above the veffel when it boils, whereas that which has been ufed does not exhibit the fame propertv. With regard to the baths of fulphuric acid, which compofe the fqurth refidue, when they are too much diluted with water, from the im- merfion of wet articles, the fhorteft method is to add more acid, or elfe to concentrate the fluid in the fame manner as I have obferved with regard to the fulphate of foda, and other falts. For this purpofe it may be concentrated to fuch a degree as to be ufed again infread of common fulphuric acid, or it may be ufed tor making alum or fulphate of ammoniac, by com- bination with the alkali of urine or putrefying vegetables. CHAP. Cottons, Thread, (3 c. 261 CHAP. XXIV. 'The Method of bleaching Hemp and Flax in the unmanufactured State, as well as Thread and Piece-goods, by the Affifiance of Water only. I HAVE long remarked, that the rags or pieces of unbleached cloth, which have been fet to ferment in order to make blotting-paper, became white to a certain point, in confequence of being wafhed or foaked, either in heaps or under the mallets, for the purpofe of deftroying their texture. The wafhing, in thefe circum- ftances, becomes more eafy on account of the fermentation, which opens the threads of the cloth, and the mechanical procefs of the cy- linder, or mallet, which renders the colouring parts more eafily detached, and in a certain degree diflblved. I attempted to imitate this fermentation, and folution of the colouring part of the thread, by warning in a large quan- tity of water. I made my experiment in pre- ference upon flax. - I firft. macerated it in pure fiver water, in a veifel, where I fufFered it to s 3 remain 262 The Art of Bleachir,? remain till the furface of the fluid was covered with numerous bubbles. In this ftage I turned it, and faw, with pleafure, that its grey colour was changed to a light yellow. I then changed the water, firft warning out the flax, and left it till other bubbles appeared, when I warned it again. At the fecond wafhing, I obferved fe- veral parts which were whiter than the reft, and at the fame time obferved a confiderable quantity of fmall portions of grey and yellowifla impurities, which detached themfelves from the filaments of the flax. I then warned it with rub- bing, and was not a little furprifed to obferve the quantity of impurity increafe, and the flax become whiter in proportion. Encouraged by the fuccefs of this wafhing, I then plunged the fame flax into warm water, to haften the folution of the other colouring parts, which had immediately fixed themfelves on the flax, as foon as it had dried, after taking out of the vefTel. I then prefTed it in the water, which difengaged an additional quantity of colouring parts, and the flax appear- ed much more beautiful. I did not carry this experiment further, becaufe the flax appeared clear and white, to as great a degree as 1 fup- pofed it would arrive at by this method, for no more impurities were detached. Though it ap- peared to be white, when in the ftate oi divi- sion. Cottons, ttrecd, (3c. 2.63 (ion, yet in the mafs it dill preferved a flight (hade of yellow, which with a fimple bath of oxygenated muriatic acid totally difappeared, without the ufe of lees, or any other particular preparation. This experiment perfectly agrees with an ob- fervation which may be daily made upon pieces of cloth which are fubje£ted to the fulling-flock. Some of thefe pieces have holes in them ; and jn order that thefe damaged parts may not be enlarged by the procefs of fulling, it is ufual to fecure them by fewing on a piece of brown linen cloth. I have remarked, not without aftonilhment, that thefe pieces of unbleached linen, after having remained in the water for two or three days, with the cloths to which they were fixed, and which were thus expofed in order to clear them, either from the folution of foap, the urine, or the fullers' earth, became as white as if they had been palled through the lees, and expofed alternately in -the field foj feveral months, or the ufual time employed in bleaching. This refult likewife agrees with the method in ufe in India, where, according to the rela* tion of travellers, the natives bleach their fine cottons, which we receive from them, in no other way than by wetting and evaporation by s 4 the. 264 The Art cf Bleaching the fun, and expofure to the dew, without the ufe of lees, or any other preparation. All thefe experiments prove, therefore, that it would be very poffible to bleach with water alone, if not piece-goods, at leaft flax, in as ex- peditious a manner as can be defired. This has, to a certain extent, been put in practice by a certain induftrious individual in the town of Amiens, named Bade. Without any know- ledge of this man, or his method, but from the fimple recital of his difcovery, that he had bleached hemp in the ftalk by water alone, I was tempted to make the trial. In confequence I fet to macerate in water, during for about a fortnight, a certain quantity of hemp ftalks, which had been gathered about five or fix months, and afterwards dried in a barn, without undergoing the procefs of rotting. At the end of fifteen days the hemp had recovered its original ver- dure, that is to fay, the appearance it had when rirft gathered. I rubbed them much under water, which difperfed the green matter which appeared on the bark, and difcovered the fibrous part, which had a pretty good appearance. I feparated this, and left it to fteep for feveral fucceflive days in frefn water, after which I gave it another rubbing, and immerfed it for a fecond time. It then appeared of a very beautiful white, Cottons, Thread, &c, 265 white, nearly the fame as thread acquires by the old method of bleaching in the field, or the new procefs with the oxygenated muriatic acid. This flax retained only a very flight tinge of a pale ruddy colour. Thefe various experiments evince how import- ant it would be to bring the fteeping of hemp and flax to perfe£tion, particularly of the latter article, which in the department of La Somme, whence it is watered only on the grafs ; but the deiire of gain, which attends to the weight only, and not the quality, will fcarcely permit the old method to be laid afide. On the other hand, the bleacher, who is accuftomed to ufe lime in folution, and even in fubftance — an in- gredient which is, in fome refpecls,, rendered neceflary by his intereft, and the black tenacious colour of flax thus watered — might alfo, per- haps, be unwilling to abandon this praclice. For the cheap price, which the ufe of this me- thod enables him to offer, namely, 3 fols an ell, without regard to the breadth, may fecure employ, which would, perhaps, leave him, if he were to ufe another method, fomewhat more coftly, though at the fame time in every refpect beneficial for the merchandize and the pro- prietor. CHAP, a 6 6 The Art ef Bleaebin* CHAP. XXV. The Method cf Bleaching written or print e J paper} and Rags, whether unbleached, dyed, or cc loured. HE following proceffes are extracted from different memoirs addreffed to the Committee of Commerce of the French National Convention ; alfo to the Commiflion of Sublicences and Pro- yifions, on the 24th Frimaire, the 15th Plu- viofe, and the 9th, 14th, and 21ft of Germinal, an the fecond year of the French republic. Bleaching cf old pointed Papers, to be "jxrked up again. 1. Boil your printed paper for an inftant in folution of foda rendered cauftic by potaih. The foda of varech is good. 2. Steep them in foap-water, and then wafh them, after which the material may be decom- pofed, or reduced to apulp, by the machinery of the paper-mill. The wafhing with foap may be omitted without any great inconvenience. Bleaching Cottons, Thread, tsfo 267 Bleaching of old written Papers, to be worked up. again. Steep your paper in a cold folution of ful- phuric acid in water, after which waih them before they are taken to the mill. If the acidu- lated water be heated, it will be fo much the more effe&ual. Bleaching of printed Papers without deflroying the 'Texture of the Leaves. i. Steep the leaves in a cauftic folution of foda, either hot or cold. 2. And in a folution offoap. 3. Arrange the meets alternately be* tween cloths, in the fame manner as the paper- makers difpof e thin meets of paper when deli- vered from the form. 4. Subje£t the leaves to the prefs, and they will become whiter, unlefs they were originally loaded with fize and prin- ters' ink. If the leaves mould not be entirely white by this firft operation, repeat the pro- cefs a fecond, and, if neceffary, a third time. The bleached leaves, when dried and preffed, may be ufed again for the fame purpofes as before. Bleaching 268 The Art of Bleaching Bleaching of old written Tapers without deft r eying the Texture of the Leaves. i. Steep the paper in water acidulated with fulphuric acid, either hot or cold. 2. And in the folution of oxygenated muriatic acid. Thefe papers, when preffed and dyed, will be fit for ufe as before. The Method of bleaching Rags of the natural brown Colour for the Manufaclory of white Paper. 1. Let the rags be opened or feparated from each other, after previous foaking or macera- tion for a longer or a fhorter time, according to their texture and quantity. 2. Give a lixivia- tion in cauftic, vegetable, or muriatic alkali. 3. P2fs them through the oxv more advifable. to refrefti than to renew the hatl^ becaufe the greafy impurity of the wool, which is dilengaged by warning, becomes a leaven which dilengages the greale from the other wool, plunged in the bath. white. Cottons, Thread, &c. £83 white, foft, elaftic, and open, dilating or fwelr ling when touched, inftead of being hard, greafy, and clofe, as it was at firft. The qualities it acquires in the bath do, therefore, fufficiently ihew the neceffity and utility of this fecond cleanfmg, by which it lofes 10 or 12 per cent more. This laft lofs, added to the former, gives a total of about 60 or 70 per cent; that is to fay, 100 pounds of raw wool produce fcarcely more than 30 or 40 pounds in a very clear date, fit for the manufacturer. Wool fir combing for the manufafture of Stuffs. This wool, in the market, is broken or Ported by the clothier, and fent before or after the dying (if this be intended) to the combers in parcels of about fix pounds and a half each. '1 he quantity is fir ft warned in a velTel filled with hot water, taken out of a fmall boiler in which two or two and a half pounds of green or black foap has been diflblved, for the faid quantity of wool, which accordingly as it is thought to be more or lefs foul, is well preffed and after- wards wrung on the hook, and then dried in the fun, or in the open air. Before it is combed, it is again fubjeded to a fecond bath of the fame kind. Thefe two clearings are fufficient to deprive it of all the natural greafe which remains, and 1 84 The Art of Bleachm* and of fuch impurities as might be an impedi- ment to the combing procefs. It muft be remarked, that thefe fix pounds and a half of wool are wafhed in fuccefiive fmalJ portions at a time. The water of the wafhing-tub is renewed as the work goes on, in order to detach the greafe and other impurities from the wool - 3 there are two hooks fixed within the vefTel, one at each end, one of which can be turned round by a handle. The workman, after having well wafhed and preffed with his hands the feveral parts of the w r ool, wraps them round the tw r o hooks, and by wringing it out, he ex- prefles the dirty water, which carries with it ali the greafe detached by virtue of this ftrong preffure. After this fecond warning, the wool is dried carefully to prevent its being accident- ally foiled. In this ftate it is, that the wool is combed. It muft be rather moift for this operation, in order to facilitate the prolongation of its fila- ments, of which, when the wool is well cleanfed, the comber ought always to form lengths of three or four feet each. It is, therefore, eflenti- ally neceflary, that this operation mould be well managed, not only for the good effect it pro- duces in the opening, but, likewife, becaufe the colour Cot tens, Thread, &c. 1%$ co our and clearnefs of the fluff depends much more upon this firft operation, than it is generally- imagined. In many manufactories, after the wools are combed, and according to the kind of ftuff in- tended to be made, it is ufual, in order to difpofe them to fpin well, to give them a third wafliing in the fame veiTel with hot water and foap* The wool is afterwards carefully dried, and in this (late delivered to the fpinner, if it be intend- ed for the chain or weft ; but that which is intended for weft is returned to the comber, and after coming out of his hands it is warned a fourth time as before. But this fourth and laft warning is not given except to wools of the firft quality, manufactured of a white colour, or intended to receive any clear and brilliant dyes. Wool, which is well cleared of the greafe, ought to have its filaments flender, long, even, and not connected with each other, hefides which it ought to be tenacious, white, and difengaged from every foreign fubftance. The wool from Holland is remarkable for this laft quality. That of England, is harfher and much fouler. The German wool is ftill harfher, but equal to this in length. It approaches the French wool, which 1 8 6 The Art of Bleaching which is the word kind of any, with regard to its length and fitnefs for combing;. The lofs fuflained by cleanfing, is fomewhat lefs than one-fourth in the Dutch wools, and about a fourth in thoie of England. The Ger- man wools, and fchofe of France, undergo a iliil more confiderable lofs, on account of their infe- rior quality. Some of the latter lofe more than one-third. Sulphuring. Wool, fluffs, (lockings, and other articles of the fame nature which are foiled by dreffing or ufe, are expofed to the vapours of fulphur. By this procefs thefe goods receive a clearer white than that which is natural to the wool after the ufual warning and cleanfing. This operation is ufually commenced by wafh- ing or fulling the piece, For this purpofe it is re- quifite that the fulling rammers mould be made lighter than ufual. When the convenience of a ftream is not to be had for moving them, it will be fufRcient if a frame of 15 or 20 inches wide be made with two beams three or four inches thick, fupportcd by crofs-pieces, and terminat- ing below in a crofs-piece fomewhat longer, ftronger, and vertically fufpended to a plank or poles placed between the timbers of the loof, and forming a fpring. A wooden trough ft Cottons, Thread, &f& 287 is placed underneath, in which a workman may move the fpringing peflle up and down with his hand with great facility, and by inclining the trough the fame effect of turning the (luff may be produced as in the common fulling apparatus. Inflead of a machine of this kind, the ma- nufacturer may ufe the mallet, or which is ft 111 better, the goods may be worked with the feet, in a place properly difpofed for this effect, as has been recommended for piece-goods and (lockings. When the piece is well cieanfed and rinfed in a dream, it is dried and fmged, or fent to the dye-houfe ; if, on the contrary, it is intended for a clear white, it muft be finged before the fcouring ?. For the fine white, a fecand (light warning is given in a folution of foap, in which the (luff is left for a certain time, then vvaflied well, rinfed in running water, and left to drain tor an hour on the horfe, after which it is ex- pofed to the vapours of fulphur for five or fix hours, or longer, as far as 24 hours, according to the bulk of the piece. After this operation, it is again waihed, and * The method of tinging muflins. i? equally applicable to Woollen goods which require this treatment. its 28B The Art of 'Bleaching its colour heightened with fine whiting and blue, which are difFufed in clear water j it is then fulphured a fecond time, waflied in a flight folution of foap, dried, patted through the flretching machine, calendered, or prelTed, ac- cording to its nature. The following is the method of treating a piece of cloth of 40 or 4c ells, with the whiting and blue. Seven or eight pounds of fine whit- ing (blanc d'FJpagne) are pounded and mixed up with water in a pail. This mixture, except the coarfe particles at the bottom, is poured into a fmall trough of- clear water. The bath being well mixed, the piece is patted rapidly through it upon the reel for a quarter of an hour, after which it is raifed out of the bath upon the reel, and a pail of water is added, in which an ounce and a half of the finell indigo, or Pruiiian blue, has been dittufed by the ufual method of pounding, lifting, and wrapping it in a bag. The bath being again well ftirred, the piece is immediately returned through the fluid again by means of the reel. After this treatment, it is laid on a packing-cloth, and carried to the workfhop, where the nap is laid by the fullers' thiftle, during which the furface is wetted with the fluid of the bath, and when the piece is dry, it Cottons, Thread, &c. 289 it is beaten with twigs to clear it of the white powder it received in the foregoing procefs. It is proper to obferve, that bad fmells, and even the offenfive breath of individuals, will fome- tiiries produce a change in the bath of blue and white, in which woollen goods are deeped ; or, at lead, this is what very refpe£table manufac- turers affirm to be the cafe. When this happens, the operator is obliged to plunge his piece in a bath of hot water, to warn out the white and the blue, which have fixed themfelves irregularly in a kind of vegetation, after which the opera- tion muft be repeated. With regard to woollen fliirts, flannels, and other articles intended to be worn next the (kin, neither fulphur nor foap are in any refpecl fuitable to them. It is fuffici- ent if thefe be well fcoured in bran and water, and afterwards well warned in clear water. The colour is of no particular confequence, as the main objeft is to render it as abforbent as poili- ble, to which quality the foap itfelf is a great impediment. The preference is often given to leave dock- ings on the leg with waihing or fulphuring them. The place in which the operation of fulphur- ing is performed, is merely a very clofe chamber, in which the goods are fufpended on poles of v white 290 Tbt Art of Bleaching white deal, fo as to hang down in folds, which neither touch each other, nor the floor or wall. It is ftill more particularly neceflary, that they fhould not touch any iron, which becomes oxyded by the muriatic and the volatile fulphureous acid afforded by the fulphur which burns in a veffel on the floor, and would certainly fpot it, Inftead of pafling thefe pieces over the poles, it might, per- haps, be more advifeable to faflen them beneath the fame poles, by means of hooks pafling either through the lifts themfelves, or through loops of twine attached to the lifts. It is neceflary to be aware, that a cloth which has undergone the operation of fulphuring, fhould not be immediately laid upon wood before it is purged of the fulphureous acid, which would diflblve the refinous or gummy parts, and fpot the goods. The fulphuring not only communicates a dif- . agreeable fmell to the cloth, but likewife gives it a harfh feel. A bath of foap which is given after this operation reftores its foftnefs, and that in a degree which is more effe&ual the longer the cloth is worked in it. CHAP. Cottons, Thread, (2c. *9 X CHAP. XXIX. The Bleaching of Silk. Th E fame reafons which have led me to in- fer! the procefs of bleaching wool in the forego- in. chapter, with the account of the goods which are wholly or in part made of that material, in- duced me likewife to infert the proceffes for bleaching filk. . There are two methods of performing thi?, either by ungummhg it, or leaving the gum m its texture. I mall treat of both, beginning with that in which the filk is ungummed and boiled*. „ _._. , ? This procefs is managed as follows: D.ffolve, in a fufficient quantity of water, in a bo.le. -over the fire, JO pounds of white foap of Marseilles for every 100 pounds of filk. After the fo luhon has boiled, lower its heat by an addition of cold water. Extinguilh or flacken the fire, but take . Here, as in the foregoing chapter, I recur to the Memoirs of Roland Laplatiere. o 2 care, 2 2 2 The Art of Bleaching care, neverthelefs, to keep the bath at a confi- derable heat. Steep therein the filks, hung on rods, in which ftate. leave them till their white- nefs and flexibility fhevvs that the gum is diffolv- ed and feparated. Spread out the filk on the rods, and turn them, in order that the parts out of the bath may be ftet-ped in their turn, and when each hank is perfectly ungummed, wring them on the pin to exprefs the foap ; make them, and put them in bags of coarfe cloth, containing 20 or 30 pounds each. Make a new bath in the fame proportion, and in the fame manner, as the former. Throw the bajjs therein, and boil them for an hour and a half, ftirring them from time to time in the boiler. The ungumming and boiling of filk deprives it of 25 per cent of its weight. If the filk be intended to be dyed, the ungum- ming and boiling are performed in the fame bath, which is boiled for 3 or 4 hours, making ufe of a quantity of foap proportioned to the finenefsof the colour, or rather the white ground which it requires j 25 or 30 pounds are fufficient: for common colours, and as much as 50 for thofe with faffranum, and poppy red, cherry colour, &c. But when it is intended that the filk mould be white, and, confequently, to bleach it, the basrs a Cottons, Thread, erV. 293 bags are carried to the river, when they are taken out of the boiler, and the filk being taken out, is extended upon cords floating on the water and well wafhed. A new bath, containing a pound and a half of foap to 30 pails of water (of about three Englifli gallons each), in which a fmall quantity of litmus, with a portion of powder-blue or in- digo, isdiffufed, according to the nature of the made intended to be given. The boiler is filled, the bath heated, but never to boiling, and the filk is paffed through it over the rods, until it has uniformly acquired the requifite made. It is then wrung dry, and hung out, or elfe carried to the fulphuring room. All the filks made ufe of in the white, in any manufacture whatever, require to be fulphured in order to bleach them more perfectly. One pound and a half or two pounds of fulphur are fufficient for one hundred pounds of filk. At the expiration of 24 hours, the room is ven- tilated, and muff, not be entered until the vapour of the fulphur is ditfipated. The air which enters in Cummer is fufficient to complete the drying of the filk, but in winter this is performed by a chafing-dim or ffove put into the room. If the white or fulphured filk fhould not prove blue enough, a new (hade is given with clear u 3 watery 194 The Art of Bleaching water ; the hardeft water is beft, after which it is fulphured a fecond time. With regard to filks intended for gauzes and blonds (one of the principal qualities of which is derived from the natural rigidity of the filk), they ought not to be either ungummed or boiled. The whiteft natural filks are chofen in prefe- ence, which are fteeped and opened in a bath of clear hot water, or foap and water In the firft cafe, they are wrung, and afterwards fulphur- ed. The fine filks of Nankin, which are of a beautiful white, have no need of this operation. The following is the method publifhed by Rigaud in 1778, for bleaching filks without ungumming them *. The filk, intended to be bleached, is put into a glafs veffel containing a mixture of fpirit of wine and muriatic acid, in the proportion of a pound of the former to half an ounce of the * This method differs a little from that publifhed in 1793, by Baume. See this laft, Journal de Phyfique of the fame year may be confulted, and for that of Rigaud, the Gazette du Commerce of the 7 Ncvembre, 1778. Kate of the Author. This method requires many precautions, and would be much too expenfive if the materials were not afterwards re- covered. An abridgement of Baumt's paper, which contains a detail of thefe obje«£b, may be feen in Nicholfon's Philoso- phical Journal, I. », 32. — N. latter, Cottons, Thread, fcfa 295 latter, and, in quantity, fufficient to float the filk. The veffel is then clofed with wet parch- ment, and expofed for 12 hours to the fun, or othervvife it may be left 24 hours in the (hade, at a temperature between 15 and 20 degrees of Reaumur. The filk is then taken out and preffed, and again macerated for the fame time, and un- der the fame circumftances, in frefh acidulated fpirit of wine, in another fimilar veffel clofed as before. The filk is then taken out, preffed, and walhed for four or five minutes in pure fpirit of wine. In the next place, it is kept for 24 hours in the fun, or 36 in the fhade, in a third veffel, containing pure fpirit of wine, which is to be renewed at intervals, after which the filk is trbed; they are fupported on one fide by the regular in- clination Explanation of tfot Plates. 299 clination of the ftaves of the veffel, and on the other by the pegs of wood Y : thefe falfe bottoms divide the pneumatic veflel into a number of fe- parate receptacles. Z. The pipe through which the gas pafTes from one cavity to the other ; its prolongation pre- vents the gas from immediately efcaping into the upper-chamber; the gas being by this means forced to remain for a time in the inferior cham- ber, where it is frequently agitated by the arms of the apparatus, becomes abforbed in the water to a certain degree. &, a funnel of wood to facilitate the pouring of water into the pneumatic veffel, when its cover is fixed on, pinned faft, and the places fecured by paper palled on. a. Spigot, or cock, to draw off the acidulat- ed water for trial of its ftrength, by the known re-agents, indigo or cochineal, as mentioned in chap. 14. This cock may be formed of glafs, or lead, or even copper ; but this laft metal muft be covered with a coating or two of white lead paint, to prevent its being rutted, or oxyded by the vapour of the gas, and its confequent fpotting the various goods which may come into contact with it, or may be foiled by the falling of parti- cles of verdigreafe with which it would become covered. b. The cocks, for emptj ing the bleaching li- quor 300 Explanation of the Plates. quor into the veffels of immerfion : they ought to be of wood, clofed either with a cork, or with a turned pin, fecured with flax ; they mud like- wife be firmly fixed in the pneumatic veffel, and well defended with fat lute, within and without. c. A tube of glafs, of the fize of barometer tubes ; that is to fay, 2 or 3 lines in diameter : it ferves to fhew the height of the liquor which re- mains in the veffd, when a portion has been drawn off for particular immerfions; and it likewife in- dicates the greater or lefs a£tion of the diftilla- tion, by the frequency with which the liquor ofcillates up and down without. This laft indi- cation is particularly ufeful toward the end of the operation, when the flownefs and weaknefs with which the bubbles efcape, produce fcarcely the leaft found in the veffel, even though the car be applied to its fides. This tube is fixed at the diftance of about an inch from the bottom of the pneumatic veffel ; its place of junction is well fecured with fat lute, within and without ; its upper extremity is fe- cured in its place, by a fmall piece of wood, d t pinned to the pneumatic veffel. e. A fhort tube, of about the length of two inches, below each inferior falfe bottom ; it does not fuffer any gas to efcape from one cavity to the other, excepting that portion which cannot in- corporate Explanation of the Plates. 301 corporate with the water, either becaufe it may already be nearly faturated, or becaufe too large a quantity may be collected in the upper part of each cavity, refpectively, for want of the agitator being worked with fufficient frequency. /. Pipes of lead, or ftone-ware ; they may likewife be made of wood ; one of them paffes through all the falfe bottoms, the other paffes only through the uppermoft ; they ferve to intro- duce, upon the bottom of each cavity, either the quantity of potafh neceffary to fix the odour of the muriatic acid, or that which may be necef- fary to form the liquor, known under the deno- mination of the oxygenated muriate of potafh. Thefe two pipes are clofed during the distil- lation, with a ftopper of cork ; their upper extre-, mity, being formed fomewhat in the fhape of a funnel, facilitates their fufpenfion and fupport ; they mud be well fecured with fat lute, at the place of contact, with the partition through which they pafs. g. The cover of the pneumatic veffel. It muft be kept in its place by good pins of oak formed with heads, and its joints all round muft be clofed with ftrips of paper patted on The joints of the feveral pieces or planks which compofe it, though tongued together, are likewife covered with pa- per: by means of thefe precautions, no fmell of the 302 Explanation of the Pla'i;. the oxygenated acid exhales. In order likewife that this vapour ihould not efcape through the fmall fpace between the cover and the arbour of the agitator, this laft is furrounded with a fmall quantity of flax, or piece of rag, wetted, either with common water, or a folution of pot-afh. When the diftillation is begun, the opening of the aperture of the funnel / muft be clofed with a cork. h. Supports of the adopter of the retort : they reft on the cover of the pneumatic vef. fel, and receive the upper extremity of the tube, communicating with the internal part near the bottomof the veflel ; this extremity is difpof- ed in the form of a funnel ; i. To receive the beak of the ad. pter; 2. To facilitate the applica r tion of the lute. The two parts which compofe the fupport are connected together, either with Iron-wires, or pack-thread, or elfe by means of hooks, i a hole to fuffer the air to efcape out of the pneumatic velfcl when the water is pour- ed in. /. The veffel for immerfions, mounted on its rollers J. m the reel to move the piece-goods in the liquor, n its handle. the piece, or good . pafiing over the reel, p the dotted lines, reprefenting the cover. It may confifl either of a cloth, thrown over the veflel after the liquor has been poured in, or it may be much more Explanation of the Plates. Tp$ more fuitably and conveniently formed, by means of two frames of light wood, with panes of glafs, which open on the oppofite faces, and clofe to- wards the upper part of the triangle, which they form by their junction. In order that the odour of the liquor may not be inconvenient to the workman, at the time it is poured into the vefTels, in thofe cafes, where it is not thought proper to extinguish it; either by a certain dofe of fifted chalk, or a proper addition of folution of pot-afh in water,one of thefe frames has a proper opening to fuffer the difcharging cocks to pafs through; and thofe parts of this opening, which are not ac- curately clofed, are afterwards fecured by means of cloths tied round the cock itfelf. In order, moreover, to avoid all fmell from the pipes, communicating from the bottom of the pneumatic vefTels to the veffels of immerfion, thefe may be fo difpofed, as to convey the bleaching liquor to the bottom of this laft, and caufe it to rife gra- dually, inftead of pouring it in with agitation. Fig. 3. — Perpendicular view of the grate, or chafing-difh, upon which the coal and charcoal a, which heats the capfules and retorts, is placed. They may be raifed higher or lower by placing them on one or more bricks. It is likev, ife very eafy to take them out of the furnace by means of the handle B, when it is required, from any caufi whatever. 304 Explanation of the Plates. whatever, that the diftillation fliould fpeedily be checked. Fig. 4. — The elevation in pcrfpective of this grate. Fig. 5. — Plate of iron, which ferves as a door to the furnaces. Fig. 6. — The fame plate, or door, feen in pro- file; a t a projection which ferves to raife it, or place it ; b y borders, by means of which it refts on the joints, formed by the upper bricks of the furnace, which, at the time of its construction, are left open for this purpofe. Fig. 7. — Supports which furround the upper extremity of the tube of lead, which receives the beak of the adopter of the retort, or the retort only, if the glafsman have made it all of one piece. Fig. 3. — Elevation, in perfpeclive,of the iron- trough, which contains the mixture of muriate of foda and manganefe, which is fet to dry, as before defcribed, between the furnaces, under the drying place, during the time of diftillation, in order that it may be ready for the fubfequent procefs. Fig. 9. — Plan of the fame trough. Plate the second. Fig. 1. — A machine for grinding the glafs (toppers of veffels and bottles, which are requir- ed to be clofed, as it were, hermetically. Explanation of tie Plates, 30c A^. A bottle with three necks. B, The ftopper fitted to clofe the middle neck. C. A kind of brace, one extremity of which has its centre of motion in the wooden Aider E, and the other extremity F receives in its focket G, the ftem H, of the prefs I, the two jaws of which, I, K, hold faft the knob of the ftopper, re- quired to be ground in. The Aider of wood E is not fixed, but muft rife or fall according to the wear of the ftopper in the neck of the bottle, in which it is intended to be fitted. Fig. 2 and 3.— Plan and profile of a veflel, for immerfing thread ftockings, or other pieces of frame-work knitting ; if, inftead of the round figure, this veflel had been made fquare, the goods might have been ftowed in a more advan- tageous manner. Three bafoets of white wicker- work may be placed one upon the other, as is fhewn in figure 2, each upper bafket reding on the handles of that beneath. B, a bundle, or hank, of flcains of thread fpread out in the bath : there muft not be more than three or four ofthefe con- nected together in the fame bundle, as,other- wife, they would be lefs conveniently expofed to the action of the bleaching liquor, and lefs eafily wrung orcleared out. In order that no dirt may fall into the veflel, and to prevent any oppreflive x vapour 306 Explanation of the Plates, vapour from incommoding the workmen, the> whole is covered with a piece of cloth, deftgned for this purpofe; or, rather, with a light cover- ing of wood, cut into two pieces, to facilitate the management. Fig. 4 and 5. — Plan and elevation of a fmal] portable boiler for the purpofe of immediately Doiling the thread in. alkaline lees, or any other fmall articles, which either cannot with conveni- ence, in point of time, or otherwife, be put into the large boiler with piece-goods, or other articles, whether on account of their finenefs, their fmall quantity, the fpeed required, or their being the obje£t of fome particular experiments. a. The boiler, placed on its tripod, £, under the mantle of the chimney ; c its cover, which muft never be neglected to be put on, not only becaufe the heat is more fpeedily produced, but likewife for the purpofe of defending goods from foot, which may fall down the chimney, and would produce fpots not eafily discharged, as has been mentioned in chap. 15. This boiler may be heated by means of wood, or turf, or pit-coal, if a proper grate may be made ufe of. Fig. 6. — The method of fufpending, by means of an arbor D, the bafket, containing the articles taken out of the boiler, and draining over it. In order that no impurities may fall either into the lees, Explanation cf the Plates. 307 lees, or upon the goods, during this operation, it will be proper that a clofe cloth, or frame of light wood, fhould be fupported in that part of the pipe of the chimney which is immediately over them. e. The bafket, or plat form, of ofier, fupporting the goods ; this plat-form may likewife be made of iron, covered with linen rags : if a bafket be ufed, it muft be perfectly cleared of its bark, for fear of fpotting the goods. The four cords f t which fupport the bafket, are united in pairs, on each fide, at the knot g t to the cord h, which winds on the arbor. j. Supports, between which the arbor turns. - k y a clump fattened on the arbor, to prevent its recoiling from the fupport i, in confequence of the fri&ion upon m. n> the handle of the arbor. Fig. *j. — Rollers, for the purpofe of folding piece-goods into lengths, after they have received the dreflings. a. Cords, one extremity of which is attached to the ring b> fixed to the cieling, and the other extremity bears the two gudgeons of the wooden roller d. e. Part of the piece of cloth, to be folded in two. /. Part pf the cloth already folded. In this x 2 operation, 3^8 Explanation of the Plates. operation, which is very fpeedy, the cloth is fupported by holding one part, /, in one hand, and the other part, e, in the other, taking care to bring the edges together by raiting this part of the cloth thus joined a little, the weight of the folded part, foon draws over that part to the other fide of the roller, a new portion is fuccef- iively folded, and is thus fubjected to the fame manipulation. Fig. 8, 9. — Plan and profile of a machine for folding cloths in equal folds, whether it be re- quired that the folds mould be in the whole length, or that they mould be folded in two, as has al- ready been obferved. a. Uprights of iron, placed oppofite each other, in the holes b, in the brafs c, fixed on each fide of the table d. e. Reds of iron, or wood, placed in each fold of the cloth behind the two uprights. /. Another rod, which raifes from the heap of cloth, g, that part which is to be carried be- hind the upright, over the rods. In proportion as the folding advances, the lower rods are drawn out to be ufed in the progrefs of the work. By this means the operation may be performed with a dozen rods. The ufe of thefe rods, and the regularity which they afford in this method of folding, which is very expeditious, has caufed it to • Explanation of the Plates: 309 to be named folding by the rod, in the fame manner as that defcribed in figure 7 is named folding by the roller. Fie. 10. — End view of the manner in which the pieces are folded together after they are taken from the machine, fig. 9 : the round fold, which is given to the piece, is fecured by means of firings, more or lefs fine, a a t according to the quality of the merchandize. Thefe cords, firings, or twift of filk, or flax, pafs from the up- per felvedge to the lower ; they are faftened to- gether with a knot, which is, la ft of all, covered with a taffel, b, of coloured thread, of filk, or linen, or thread, according to the beauty and flnenefs of the piece. Coarfe goods are likewife faftened in front, as is (hewn by the letter C. ' Fig. 11.— Hanks of linen or cotton thread; the union of feveral fkains, that is to fay, frve or fix by a fingle firing, a, forms what is called a hank : by the number of knots, b, made in one or other of the two ends of the firing, the bleacher diftinguiihes the merchant to whom the article belongs. For this purpofe the diftinclive figns are entered in a book, oppo- fite the name of the proprietor. With regard to other articles, fuch as piece-goods, ftockings, &c. they may be diftinguiflied by one or more coarfe threads fewed to them, upon which any x 3 number 3 » o Explanation of the Plates. number of knots at pleafure maybe made. This method of marking goods appears to be much pre- ferable to the different marks with crayons, red oaker, &c. which always, more or lefs, fpot and foil the goods. Fig. 12. — Shews the method of rinfing the fkairt on the pin to clear it of water, lees, or any other fluid it may contain. As the part which is near- eft the pin is not fo effectually wrung as that which lies near the middle, care mud be taken in opening the fkain, c, to icpkce it in fuch a manner that the part which was upon the pin, a, fhall be near the middle at the time of the fecond wringing. After this fecond wringing, the thread is, for the mofl part, dry enough, and may be ftraitened out -, which is done by palling it over the hand, and ftrongly jirking or mak- ing it by drawing out ; or the operation may be performed with the wringing-pin inftead of the hand. Fig. 13.— The method of difpofing the fkains, fo that they may not intermingle too much with each other, particularly thofe of fewing thread, which, inftead of being wrung on the pin, are worked under the lower part of a kind of rammer or ftirrer. The four faftenings, a, pre- vent the fkains from becoming intermingled dur- ing this kind of fulling procefs. A tub or pail may- be Explanation of the Plates. % 1 * be ufed for this operation, according to the quan- tity of the article, intended to be cleared in this manner. A man or woman may work them with the inftrument, fig. 14, without much dif- ficulty : a certain degree of (kill and intelligence is required to do the bufinefs in the molt effec- tual manner. a. Reprefents the handle of this inftrument, and b, the lower part, which is made of beech cut into fteps or notches, c, on each fide, in order that it may take a flight hold of the goods, and afford a facility in turning them. Thefe indenta- tions muft be rounded at the edges and corners. Fig. 15, 16. — Plan and elevation of a warn- ing implement, with which {lockings, thread, and other fmall and fine articles, may be cleaned or rinfed in a tub or pail, a, exhibit the teeth or feet, between which the different goods dif- pofe themfelves, and are agitated againft each other, for the purpofe of clearing them of the different liquids, with which they are fucceffive- ]y penetrated during the courfe of the bleaching. b, is a double handle, by the affiftance of which this fmall inftrument is moved. Plate 3. Fig. 1. — a* Birds-eye view of the great boiler, in which piece-goods are heated in the alkaline folution or lees. % 4 Fi a* 312 Explanation of the Plates. Fig. 2. — Se&ion of the fame boiler through the line A, B. a. Floor of the (hop. b. The mafonry, in which, the copper C is fet' d, the wooden cover, formed of two or more part?. e, crofs pieces which pafs under the cramps/, fix- ed to the boiler itfelf, which keep down the co- vering and prevent it from rifing by the force of the ftream, which lad is, by thefe means, com- pelled to re-aft on the pieces of cloth, or other articles placed in the boiler. g. A cavity or gutter furrounding the copper, and ufed for evaporating without any other heat than that which it receives from the boiler itfelf, the old lees, which are referved after they have been applied to every ufe, which can be made of them, in order to recover the alkali. h. A fmall boiler, heated by the heat which efcapes from the great boiler, before it pafles into the chimney. In this fmall boiler is kept a quantity of lees, ready prepared, of the proper flrensth. It here receives an increafe of tern- perature, which prevents its fenfibly retarding the boiling of the great boiler, when it is ne- cefTary to convey a certain quantity into this laft velfel. i. A cock, by which the pure folution of al- kali is drawn off, and may be conducted to the Explanation of the Plates. 313 the great boiler, by a channel of tin or wood, &c. &c. j. The fire-place under the boiler. Inftead of the iron-bars, or a grate, which, on account of this diftance between them, fuffer too much air to pafs, for the confumption of wood, and by thefe means wafte much of that fuel, I have preferred an arch of brick-work, with openings of a fufficient fize. This arch, w T hile it faves the wood, likewife preferves the heat, on ac- count of the fpace between the vents, upon which the burning fuel remains for a longer time. It might perhaps be poffible to diminiOi the expence ftill further, by having no apertures at all through the arch. Thefe apertures are alfo liable to be worn or broken, and require to be defended at their edges with iron. k. The afh-hole. /. The chimney, proceeding from the fire- place, immediately beneath the fmall boiler. n. Stairs afcending from the floor, to the brick- work of the floor. 0. Another fet of (lairs, leading to the plat- form p. q. A regifter for regulating the heat of both boilers. r. Flue of the chimnev. 514 Explanation of the Plates, Fig. 2' — Se&ion of figure 1, along the line c d. a, the floor. b> the mafonry in which the copper is fct. c t mouth of the fire-place of the great boiler, d, lower part of the chimney, e, afh-hole. /, regifter, to regulate the heat of the fmall boiler, g, the flairs from the platform of the mafonry to the floor of the work-fhop. b, ftairs leading to the upper part of the ma-» fonry. Fig. 4. — A crane, moveable on its axis, pro- vided with tooth and pinion-work, by means of which the charge of the boiler, confifting of piece-goods, or other articles, may be raifed. a, the (haft, b, the pivot, c, the arm. d, bracket, or fupport. e, a ratchet wheel, worked by a pinion with a double lever: round the barrel of this wheel is wound the chain, at the other end of which are three or four hooks, in which the chains h are held. Thefe laft are covered with cloth or cord, to prevent the ef- fect of ruft. The intermediate part between the two concentric circles, which form the veflel, or fufpended apparatus, is likewife de- fended by fmall cords, in order that the various articles difpofed therein may not efcape ; this (lage, charged with the different articles which have undergone lixiviation, is, by means of the crane, Explanation of the Plates. 315 crane, conveyed over other veffels, where it is lowered down upon crofs pieces, in order that the drainage may be completed. Fig. 5, 6, 7. — Plan, feclion, and elevation, of an oven for calcining crude alkali, in order to convert it into potafh. a 9 flairs, which lead to the back part of the oven, where there arc placed two boilers of caft-iron, b b, in which the alkali is dried, after having been concen- trated to a certain degree in the cavity furround- ing the great boiler. See Fig. 1, 2. Thefe two boilers may be appropriated alternately to dry the alkali entirely, whence it is to be con- veyed into the calcining oven ; and afterwards to complete the reduction of the concentrated alkalies to the confidence of extract ; and may Jikewife be difpofed in fuch a manner that the flame which they receive from the fire- place of the oven, before it palTes into the Jower part of the chimney, may heat a third boiler of caft-iron, -of copper, or even of lead, which may be ufed to evaporate the old lees, or folutions of foap: for thefe lad: require the fame management in order to obtain their at- knli. This concentrated alkaline folution from the tipper boiler, may be fuffered to fall, drop by drop, into the lower, in order that the evapora- tion, 3 1 6 Explanation of the Plates. tion, or complete drying, may not be impeded by too much water being fuddenly poured in. c. Paflage from the fire-place to the fpace beneath the caft-iron boilers. It conveys a ftream of flame, which is more than fufficient, and may be governed by means of regifters. As this paflage is conftructed on a flope, which, for that reafon, is not eafy to be made in the mafonry, a contrivance was ufed during the building of the roof of the fire-place, to fix in the proper place a roller of wood, upon which the bricks in part refted which were intended to form this paflage ; it may eafily be imagined that this wooden roller could not be taken out after the conftruction was fini fried ; it was, therefore, intended that it mould be burnt out. To accelerate the combuflion at that time, and during the heating of the oven, a hole of two or three inches in diameter was bored through it. This piece of wood may be of white deal, or any other material which is mod readily confumed. The heat conveyed by this paflage, of which I have afcertained the good effect by experiment, is very well regulated by means of a regifter made at the bottom of the fpace immediately beneath the boiler. This regifter is entirely fhut when the boilers are not intended to be ufed. When Explanation of the Plates. 317 When the calcining oven is not ufed, but the boilers are wanted to dry alkaline folutions, thefe laft may be feparately heated by a fire between both. d. An aperture in the roof of the oven, through which the dried alkali is conveyed into the oven. e. The calcining oven. In order that the alkali may be eafily difengaged from the edges or angles of the floor where the walls take their rife, at which place it readily fixes itfelf by the aqueous fufion, it is advifeable that this part fhould be defended by a plate of iron, four or five inches high, and about half an inch thick. By this means the fait is more eafily feparated by the rake. /. The ftoke-hole for fupplying the fuel. It is conftru£ted in the fame manner, and for the fame ufes, as that of the boiler for lixiviation. g. A flight piece of brick-work, between the fire-place and the hearth of the oven, which prevents the fuel and the faline matter from communicating or mixing with each other. h. A done or cafl-iron trough, into which the red hot calcined alkali is thrown when taken out of the oven. In this veflel it is left to cool before it is packed up in calks, in which laft veflels it mud be prefled as clofely as poffible, in order 3 1 8 Explanation cf the Plates. order that it may be lefs liable to attract moiflure from the air. /. The mouth of the oven. It has two iron uprights, j j, forked at top, in which the ends of a racked bar k are placed. The handle of the rake, with which the alkali is ftirred, is refted between the notches of this bar. The mouth of the oven is alfo provided with an iron plate, to be ufed either for clofing it entirely, or more or lefs, as occafion may demand. Inftead of fufFering the heat, which ifiues from the mouth of the furnace, to be loft, it may be very advantageoufly directed by a pipe rifing under the boilers of call-iron, or thofe which are placed above, for preparatory eva- poration. None of thefe means ought to be neglected of employing the heat, which in al- mod every conilruclion of this kind has been hitherto loft, for want of a proper degree of fkill in the proprietors, or thofe who undertake to erecl them. Fig. 8. — Reprefentspart of the chain, which is wound upon the drum of the ratchet-wheel of Fig. 4. It may be obferved, that it is con- ftrucled on the fame principles as the chains of pocket watches. Fig. 9, 10, and n.— Details relative to the racked Explanation of the Plates, 3T9 tacked bar placed acrofs the mouth of the cal- cining oven. a. The teeth, between which the handle of the rake is moved, b, an elbow, which pre- vents the rake from moving the bar fide-ways when once duly placed, r, crampons, or iron fixed pieces, whieh receive and {ready the up- rights, d, the mafonry of the oven in which they are placed, c, the rake feen fide-ways, /, its claw placed on the floor of the oven, g, its iron handle, h, the external part of its handle, which is made of wood, becaufe the iron would communicate the heat too readily to the hand of the workman. Fig. 11. the claw of the rake feen in face. Fig. 12. an hook, by means of which the rake is lifted up or changed for an- other, either on account of its being too hot to be touched, or in danger of bending, a, the hook, b 3 its handle. In order that the iron handle of the rake may Hide more readily be- tween the teeth of the crofs-bar, it is occafion- ally rubbed with a piece of bacon nailed to a fmall piece of wood. PLATE THE FOURTH, Fig. 1.— Elevation of a miH proper to cleanfe piece-goods and other articles, which are more or 3 20 Explanation of the Plates. or lefs bulky. It is moved by a horfe ; or its mechanifm may be fet in motion by wind, wa- ter, or other powers, by making fuitable ar- rangements for that purpofe. A, the principal thaft. B, the bar, to which the horfe is attached. C, the wheel. D, lan- tern. E, the arbor, which gives motion to the flocks or peftles E, by means of certain tripping pieces. See Fig. i. and 2, Plate V. F, mortices, in which the tripping pieces move to raife the peftles. It is advifeable that the part which is a£ted upon by the tripping piece ihould be defended, either by a plate or roller of copper. G, crofs-pieces, between which the peftles rife and fall. H, the box or recep- tacle, in which the goods are placed. The figure reprefents the internal part, in confe- quence of a portion of the wood-work in front being removed. One of the fpaces is larger than the other, for the purpofe of fubdividing the different kinds of work. The receptacle is commonly made of elm, and the rammers of beech. I, holes made at different heights, to draw off the water. J, a door, which may be taken down or put up at pleafure by means of buttons. It mult always be up during the time of work. K, a pipe, which fupplies the work with water. Out of this proceed a number of fliort Explanation of the Plates. 321 jhort pipes anfwerable to the refpective cham- bers. L, a ftop, to prevent the peftle from defcending too low, and injuring itfelf. M, a lever fixed to a crofs-piece, N, behind the four uprights, O. By means of the pin P, and the firing Q, the fulling rammer may be raifed fo high, that the tripping pieces cannot reach it. While it remains thus fixed, the goods may be examined or taken out, as occafion may require. Fig. 1 and 3 A fucking-pump, which fur- nilhes the water to the work. Fig. 2, fhews the fame in profile, and Fig. 3, the front view. A is the extremity of the arbor which works the fulling apparatus. B, prolongation of the axis or pivot of this arbor. It turns on the brafs bed C ; and its extreme part D is bended into a handle, which gives motion to the pump, rods E F. The latter is attached to the ftem of the pifton which moves in the body of the pump. H. I, the pipe, which fupplies the refervoir J with water. K, the pipe which conveys the water to the fulling works. PLATE THE FIFTH, Plan and elevation of the fame machine for wafhing and cleanfing piece-goods. A, the y turning 322 Explanation of the Plates. turning arbor, with its tripping pieces B. C, the mortices, in which the tripping pieces enter to raife the hammers. D, holes, through which the rammers traverfe. E, bolts, which hold together the lateral partitions, and connect them with the uprights F. G, the fulling rammer, refting on its ftop H. I, the lever, to throw the fulling rammers in or out of work. The dotted lines J denote the pofition of the levers when the work is flopped. The cord K being fattened to the hook L, keeps the lever in this pofition; but when M is fixed to the fame hook, it keeps the lever clear of the working bar. N, the infide of the receptacle for the goods. O, holes for drawing off the water. F, the door. Q, the pipe which brings water to the work. R, a table, on which the goods are laid before or after they have been put into the engine. T, a board to defend the work- man frOm being wetted. Fig- 1. — A, the principal arbor, with its tripping pieces B. This figure fhews in what manner they are difpofed in order to produce their alternate effects on the rammers. Fig. 3«— Plan of the wheel fixed on the up- right (haft, which ferves to fhew the manner of its conftruclion. Fig. 4. — The lantern which moves the arbor. A, reprc- Explanation of the Plates. 323 A, reprefents the arbor itfelf, upon which the lantern it folidly fixed. The bolts B connect the two drum-heads. Fig. 5, (hews the method of difpofing the goods in the trough of Fig. 1, when it is more particularly intended to work them acrofs their length. Fig. 6. The method of difpofing them when, on the contrary, it is intended to work them in the direction of their length. PLATE THE SIXTH. Fig. 1, 2. — Plan and profile of the machine for fquaring and rolling out the pieces after they have received the dreffings. a, the flage on which the goods are placed, b, the piece folded back and forwards. c } the ftretcher, through the mortice of which the cloth pafles. At one of its extremities there is a ratchet-wheel, a 7 , by means of which the neceffary tenfion is given, that the cloth may undergo a flight degree of fricVion againft its rounded edges during its courfe. the fquare, into which the fquare end of the cylinder is lodged. », wheel of the arbor, which carries the fquare. c. the lantern or pinion, hlch gives. motion to the wheel, and is itlelf carried Explanation of the Plates. 325 carried round by the handle p, worked by one or two men, according to the force or velocity required to be exerted, q, a fly, armed with balls or plates of lead, which ferves as a refer - voir of force, and greatly affifts the workman, j, a trough of plate-iron, in which hot embers are put for the purpofe of drying, or giving a proper degree of firmnefs to certain goods be- fore they are rolled on the cylinder, upon which they preferve the ftate and appearance it is in- tended they mould receive. Fig. 3 and 4. — Plan, fection, and profile, of the earthen furnace, made au rue Mazarin, of which mention is made in Chapter II. a, the furnace. I/, the am-hole. c, the door of the afh-hole. d, the fire-place, e, door of the fire- place. /, grate of earthen-ware ; inftead of which, if preferred, a grate of iron may be fubftituted. g, the chimney. h, a protuberance for more ealily removing the furnace, i, the pot. /, fand- bath. m, tubulated bottle, containing the mix- ture for diftillation. Inffcead of the bottle, a tubulated retort may be ufed, which, in that cafe, may be placed in a bath fuited to its figure. n, the neck, to which the tube of lead is to be adapted, for the purpofe of conveying the gas into the pneumatic veflels. 0, the aperture, into which the fulphuric or muriatic acid is to be y 3 poured, 326 Explanation of the Plates. poured, accordingly as the diftillation is per- formed with or without the muriate of foda. f y a ftand or bafe of ftone, upon which the fur- nace may be raifed, either for the purpofe of giving it a proper elevation, or to prefervc the floor from the danger of fire. This kind of furnace is ufually compofed of one fingle piece , but for the facility of remov- ing and fixing them, when conftructed of a cer- tain fize, they ought to be formed of fevcral pieces which may be eafily fixed together by means of indentations made in them before they are baked. plate the seventh. Fig. t, 2, and 3. — Bird's-eye view, elevation, and profile, of the machine for calendering piece- goods with or without heat. A, a double handle which gives motion to the pinion B. This ma- chine, as well as the one juft defcribed, may eafily be moved by connecting it with the ful- ling mill, in the fame manner as the pump re- ceives its motion, namely, by a branch or tum- bler, which on the one hand is applied to the arbor of the mill, and on the other to the leading axis of th« machine. It is neceflary of colirfe to arrange the workfhops accordingly. The pinion Explanation of the Plates. 327 pinion drives the toothed wheel C ; on the axis of which is fixed the lantern or pinion P, which moves the great wheel E, to which is adapted the brafs cylinder F, and this in its turn communicates its motion to two cylinders of walnut-tree G. H, the ftage upon which the piece I is placed ready for calendering, having previoufly receiv- ed all the other dreffings ; it is folded, as the figure mews, in alternate folds, in order that it may be more eafily delivered. It firft paries between the crofs-pieces J, thence through the mortice K, of the ftretcher L, which is provided with a wheel and click, M, to flretch the piece more or lefs and regulate its courfe. It after- wards paffes back under the brafs cylinder N, over that of walnut-tree, and returns in front under the upper wooden cylinder, which it en- velopes as it paffes over and falls behind O of the machine on the roller P, and againft Q, where it is ranged in alternate folds on the ftage R, whence it is taken to be regularly made up for fale. S. The prefling fcrew, by means of which the upper wooden cylinder may be urged more flrongly againft that of brafs, accordingly as it js required that the face of the cloth iliould be niore or lefs acted upon. \ r 4 T. Piece 328 Explanation of the Plata. T. Piece of caft-iron, which Aides in grooves made in the uprights U, and bears upon the pivot V of the upper cylinder, accordingly as the fcrews prefs upon the crofs- piece X, to which this piece of call-iron is fixed. Fig. 4. — The brafs cylinder feen at one end, where it is open to receive the bars of red-hot iron which heat it. A. The cylinders of wood to which the brafs cylinder communicates its motion. Inftead of wooden cylinders, others may be fubftituted of card-paper, compofed of the quantity of leaves necefTary to fill the fpace which is determined between the plates of brafs adjufted at the ex- tremity of their axis. They are ftrongly preffed by thefe plates, which are retained in their pofi- tion by powerful fcrews. Cylinders of paper, properly turned, give to fine goods a glaze which they cannot acquire by the wooden cylinders. They have likewife the advantage of retaining their figure, which is not the cafe with wooden cylinders. Thefe lafi: require to be occafionally rectified in the lathe, and at laft become too fmall for ufe. The lathe ufed for turning any of thefe cylin- ders ought to be conftru£ted in fuch a manner, as to render it a matter of certainty that the diameter Explanation of tbe Plates. 329 diameter fhould continue equal from one end to the other. B. The cylinder of brafs. C. The neck on which it turns in the manner of a pivot. D. The aperture through which the bars of red-hot iron are introduced with tongs. The aperture is then clofed with a cover to keep in the heat. U. The uprights between which the brafs cylinder moves againft the plates V. Fig. 5. — The form of the pieces of caft-iron with which the cylinder is heated. Two are commonly put in, and they are ufually changed every hour, or oftener, according to the nature of the work. PLATE THE EIGHTH. Fijf. 1 and 2 Plan and fection of a veffel particularly defigned for fubmitting fine piece- goods, fuch as muflins, linens, &c. to the ac- tion of the oxygenated muriatic acid. a. A frame armed on each fide with fmall leaden points or pins, b, the central parts of which are iron ; they may be altogether of iron, painted with white lead, and well wrapped with ftrips of linen or itring. Thefe points are of ufe 33° . Explanation of the Plates. ufe to fufpend the piece-goods in a zigzag form, as is fhewn by thefe figures, either immediately by the felvedge of the piece, or by loops of tape fewed to the pieces themfelves. c. Rings of lead cad upon rings of iron, which they cover; otherwife rings of iron alone, paint- ed with white lead, and wrapped with cloth or twine to defend them from the mil. The cords e> w T hich are faftened to thefe rings, pafs over hooks at d, fixed to the cord/, which, by means of the pulley £, is ufed to raife or lower the frame. When the latter is entirely plunged in the bleaching liquor, the cords are detached from the hook g, and the veilel is covered to prevent the introduclion of any impurities, as- well as to defend the workmen from any dif- agreeable odour. An apparatus of this kind may be ufed, not only for immerfmg of the goods in the oxvge- nated muriatic acid, but likewife for the lees, as well as the bath oi" fulphuric acid, 8cc. Fig. 3 and 4. — Elevation and profile of the frame for ftrctching the fkains of thread when taken out of the bleaching veflels. A, upright pieces, in which a number of holes, B, are pierced for the purpofe of fupporting C, the crofs-pieces, over which the fkains of thread, D, pafs fingly. Thefe crofs-pieces have th< ir angles Explanation of the Pla'es. 331 angles well rounded, and are fet at a greater or lefs diftance, according to the degree of ten- fion to be produced, by means of the iron pins inferted in the holes of the uprights. The thread is firft well wrung upon the pin, or with the hand, after which ii is fh-etched upon the pannel, and left to dry. Care muft be taken that thofe Ikains which are put on at any one time fhall all be of the fame length, in order that the tenfion may be equal throughout. If thefe threads, when taken out of the bleaching veflels, fhould be fo entangled or mixed as to feem incapable of being cleared without breaking, they may eafily be brought to their original ftate by plunging them in water, and gently finking them with the edge of the hand. This operation may, if thought fit, be repeated at each immerfion, in cafe it fhould be fuppofed that the thread would be too dif- ficult to clear after the entire bleaching-. The fkains of thread, thus adjufted and dried, are afterwards twifted together in dozens or fcores, or any other count, according to the cuftom of the market ; or they may be packed in fmall parcels in coloured paper, according to their quality, and the orders of the vender. Fig. 5, 6, 9, 10.— Plan, profile, and parts of the machine for fcorching or fingeing muflins, and 332 Explanation of the Plates. and other piece-goods, which are particularly required to have an even face fimiJar to goods of the fame kind imported from England. A, ports fixed in a cavity, B, in the pave- ment y or floor of the workfhop. They are con- nected by the crofs-pieces, C, fixed at their up- per extremities by the bolts or fcrews D. Thefe pofls may be taken up at pleafure, in order to leave more fpace in the workfhop. E, axis of a roller placed between each poll, the pro- longation of which is bended into a handle, F, for regulating the tenfion of the piece by the ratchet-wheel G. A fhort piece of cloth or can- vas, H, is nailed to each of thefe rollers, and to thefe the extremities or ends of the piece to be finged are fixed with the needle or rod of iron, K. One of thefe rollers takes up that part of the piece which is finged, while the other gives off or unfolds a new length to be fubje&ed to the fame operation. L, the bended iron, with which the fingeing is performed by palling it over the furface, from one edge to the other, in a light, fpeedy, and dextrous manner. The flat part M being firft made very hot, is well wiped on a cloth or pad, in order that it may not foil or greafe the piece, which laft action would endanger its being burned. This iron is to be pafled two or three times Explanation of the Plates. 333 times over the extended part of the cloth, in order that it may produce its effect more uni- formly. If the piece require to be finged on both fides, it muft be afterwards turned, by chang- ing the rollers M for N. The brown fcorched colour which the piece acquires by this treat- ment fpeedily disappears in the bleaching. Fig. 7 and 8 A plate of call-iron, viewed in face and edgewife, which is advantageoufly ufed to fmooth or lay the nap of certain piece- goods, fuch as velverets, fuftians, coverlets, &:c. This plate is heated to the proper degree ; and one or two men, according to the weight and dimenfions of the plate, and the nature of the fluff, pafs it along, more or lefs fpeedily, over the piece intended to be thus ironed or fmoothed. The fame care mult be taken to wipe the plate when it comes out of the furnace as was de- fcribed for the fingeing. The handles, B, of the plate, are wrapped round with cloth, in order to defend the hands of the workman. Fig. 14. — -A bru(h,with ihort hair, ufed to raife the fibres or nap of the piece-goods intended to be fubje£ted to either of the operations here defcribed. Fig. 11,12 and 13. — Plan, elevation, and fec"H- on of a prefs proper for drying or expreffing the Water 334 Explanation of the Plates. water from piece goods, whether in the courfe of the f veral operations, or at the end of the bleaching procefs. This prefs may like wife be employed to advantage, to give a neat appear- ance to folding goods, or for the clofe packing of bales. A. The platform or table of the prefs upon which the goods are placed. This table is hol- lowed out to the depth of one inch, and is in- clined towards the gutter or beak, B, in order that the waters which flow from the goods may be received in a pail placed underneath for that purpofe. C. The preffing fcrews which rife and fall be- tween the uprights, D, in order that the whole furface of the table may be left clear. PLATE THE NINTH. Fig. i and i. — Plan and fecrion of the dif- tilling apparatus mentioned at the commence- ment of this work. A. The double furnace with its fixed grate. B a cover of plate-iron of a fquare or round figure with Bat edges, which may be raifed or placed in contact with the furnace. C the fand bath whieh furroands the capfule ; it ought to be verydry> fine and uniform. D, the cylindrical bottle Explanation of the Plates. 335 bottle with two necks ; one in the middle, E, to receive the ftem, F, of the communication of the pneumatic veffel, and the other for pouring in the fulphuric acid, when muriate of foda is ufed, or the common muriatic acid, if that fait be not applied. Inftead of the cylindrical bottle, a balloon, or globular veffel with a neck on one iide, may be ufed, as is (hewn in figure 2. The choice of thefe veffels will, in a great meafure, depend on the fkill of the workmen, at fuch glafs manufactories as may be in the neighbour- hood of the bleaching works. In ftrictnefs, the neck or tube on one fide may be difpenfed with, and it is here mentioned only becaufe it adds a convenience to the operation. From thefe obfervations on balloons, it is eafily feen, that thofe who, in purfuance of the dire£ti- onsin the memoir upon bleaching, in the fecond volume of the Annals of Chemiitry, may have ufed the mattras, the neck of which fooner or later muft break at the termination of the chimney of the dome of the furnace there re- commended, may afterwards ufe thefe globu- lar veffels with advantage. J. The door or opening to the fire-place. Inftead of glafs bodies, it might probably be of advantage to ufe leaden veffels heated by a water-bath, or in any other manner which would. not 336 Explanation of the Plates. not endanger the fufion of thofe vefTels. This danger would be lefs to be feared when manga- nefe and the muriatic acid were ufed alone ; but vefTels of this kind would always have the difadvantage of not allowing the operator to fee what paffed within them, as he may with glafs, nor whether the vefTels were well cleaned. Thefe two inconveniences, which can hardly admit of any remedy, unlefs a glafs could be fixed in the upper part, have hitherto prevented me from ufing them, though they might, probably, be at- tended with very confiderable advantages. K. The afh-hole ; this is clofed in the fame manner as the aperture of the furnace, by Aiding doors ; or more limply as has been defcribed in the explanation of the furnace exhibited in plate I. G. A tube of lead formed all of one piece, without folder, and caft at one Tingle pouring, or feveral fucceffive pourings like water pipes in copper moulds. It may alfo be caft very fhort at one (ingle pouring, provided it be made thick enough to be afterwards drawn out. TheTe fucceffive drawings reduce its thicknefs to a An- gle line, while its internal diameter is kept at feven or eight lines, which proportions are very convenient. This pipe is fixed in the pneumatic veflel in fuch a manner that it may be freely raifed Explanation of the Plates. 337 raifed and lowered in the groove L, made for this purpofe in the piece which fecures it on each fide in its place, by means of the wooden pins M. N. Another tube for a fecond diftilling appa- ratus, if it be thought fit to place one befide that already formed, whether for the purpofe of obtaining a high degree of concentration in the oxygenated acid, or great fpeed in the compofi- tion of the gas, on account of the hafte required in the work. O. Arms of the agitator, which may be floped off on both fides. This form agitates the liquor, and facilitates the abforption of the gas more effectually than any other. P. A focket applied to the arbor 'Q of the agitator. If the pneumatic veffel be conftrucled according to the reprefentation in the figure, and the explanation given in the chapter IV. the fockets, R, here expreffed become unneceffary, as well as the inverted ftages, whether they be made with hoops, as at S, or conftru£ted of thin wood-like fieves, as at T. They are placed in this drawing only to fhew the manner of difpofing them in cafe they fhould be preferred. The crofs-pieces, U, of the bottoms of thefe kind of veffels, placed upon cleats fixed to the flaves of the veffel,, fhew the manner in which they are z to 33 5 Explanation g/ the Plates. to be fixed, with wooden pins, that they may not be fubje£t to rife, nor become loofe in any refpect. X. The cover of the pneumatic veffel. Y. A ftool upon which the veflel itfelf is fupported. Fig. 3. — Exhibits the manner in which the hoops of thin wood are joined for the purpofe of forming the inverted veffels, as well at their terminations, where one part overlaps the other, as upon the circumference attached to the bot- tom itfelf. a. Wooden nails with heads. Oak is the befl material. The extremities of the hoop of thin wood overlapping each other, and fecured on each fide in the joint of their ligature with wooden wedges. b. The extremities of the circle of thin wood lying over each other, and confined on each fide in the joint of their ligature with wooden wedges. Fig. 4. — The manner in which the hoops are put on which hold the fmall ftaves of thefecond conftruftion together. The circles a are kept together without binding, merely by a fcarf or notch made in each end. Thefe hoops are {tripped of their bark. Cr The Explanation of the Plates. 339 c. The flaves. Thefe, as well as the bottoms themfelves, may be made of yellow deal. a. The fcarfed ends of the hoops, which are turned inwards. Fig. 5. — The method of difpofing the tranf- verfal bars to which the bottoms of the inverted veflels are fixed, a the crofs-bars. b the bottom of the inverted vefTel. c the ftaves. d the fcarfed hoops, e wooden pins which fix the bottom of the inverted veflfcl to the crofs bar. They are rivetted beneath, by fplitting the lower point of the pin, and driving a wedge into the notch. / a fmall block or cleat, fixed to the ftaves of the cafk with wooden pins, g, driven flan t ways above the crofs-bar to keep it fteady in its place. Ffsn 6. — The method of fixing the inverted veflels, which have a border of thin wood like a fieve. a the hoop or circle of thin wood pinned to the circumference of the bottom, b heads of the pins which fix the circular part, c boards making part of the bottom, but left of a greater length, in order that they may be fixed down to the fupport d. As thefe circles of thin wood are not likely to join exactly to the circumference of the bottom of the vefTel, they mult be made good with putty, after previoufly flopping the larger vacuities with tow driven firmly in. Pitch may be ufed z 2 inftcad 34-o Explanation cf the Plates. inftead of putty, if it fhould be found more con- venient. Fig. 7 and 8. — Section and plan of the veffel for immerfing linen, hempen or cotton thread. It is placed on rollers or trucks, a, for the con- venience of removal. A. Ears with the corners rounded off, which are fupported at each end in a notch or mortice, B, in the-crofs piece c. d. Skains of thread, feparate or ranged in bundles of two or three only. The pofition ot thefe muft be changed once or twice during the immerfion, in order that the part which refts on the bar may be fubjected in its turn to the action of the oxygenated muriatic acid. E. A pipe of lead or wood, through which the veffel is filled from beneath. If the acid were to be poured upon the thread, it would bleach, more fpeedily at the upper part than elfewhere. Inftead of one pipe there may be more, or the diameter may be fufficiently large for the fpeedy filing of this veffel. F. A funnel through which the bleaching liquor flows from the pneumatic veffel. In ftricl- nefs it may be fuppreffed, and the apparatus fa difpofed that the cocks from that veffel may difcharge themfelves immediately into the upper part of the pipe, which muft be fixed withinfide the Explanation of the Plates. 341 the vefTel, in order that it may not impede the covering and uncovering. The cover ought to be corapofed of feveral portions or frames of glafs, as was directed with regard to the vefTel for immerfing piece-goods 3 as by this means facility of management, and fpeed in the procefs, are infured. G. A fmall door or Aiding piece, in which a plate of glafs is fet, through which it is eafy to obfer-ve the progrefs of the work. This may be opened from time to time to examine the goods without railing the covers. This method of difpofing the fkains of thread in the oxygenated muriatic acid, is likewife ap- plicable to their immerfion in the fulphuric acid 5 when either of thefe liquors is exhaufted, it may eafily be drawn off, either by means of fyphons or of a cock placed near the bottom. Fig. 9.— Seaion of a vefTel for immerfing piece-goods, to which a pair of hooks is ahixed to wring out the pieces in parts at a time, particu- larly if of considerable magnitude. A. uprights, which may be eafily adapted to the two oppofite fides of the vefTel by means of the two clamps, B, which are fixed to the vefTel with a hinge on one fide and a ftaple and pin on the other or by ftaple and pin on each fide, if z 3 intended 542 Explanation- of the Plate t. ' intended to be applied to other vefTels. The lower ends of thefe uprights are inferted into holes in the floor or pavement of the workihop. The hook D is fixed and unmoveable. The hook E is capable of revolving upon its fhank, the outer end of which is fixed by plate3 of iron and fcrews to the levers I. The ufe of this aparatus for wringing is equal- \y applicable to the bath of oxygenated muriatic acid, or fulphuric acid or lees, or the macera- tions, &c. Fig. 10. — A tube of glafs divided into feveral equal parts called degrees, it is of ufe to afeer- tain the ftrength of the oxygenated acid. This tube is eafily made out of any cylindrical bottle or piece of tube, the lower end of which may be (imply flopped with a cork. White glafs is to preferred, and it is convenient that it mould be about an inch in diameter. Fig. 1 1 .—A fmall meaiure of glafs, tin, lead, or pottery, which when full contains the quantity of liquor neceffary to form one of the degrees traced on the external furface of the tube with a flint or the edge of a file. The trial is made by pouring one of thefe meafures of the oxyge- nated muriatic acid intended to be proved into the vellel ? fig. 10, and afterwards oblervirig how many Explanation of the Plates* 343 many of the fame veffels filled with indigo blue, or tincture of cochineal, &c. prepared as direct- ed in Chapter IX — XIV, it will difcolour. .From the refult of the experiment, the liquor is judged to be more or lefs adapted to the bleaching procefs , * 4 APPENDIX } R, SUPPLEMENTARY CHAPTER. i. Nomenclature. J\t the end of the original work, the author has given a fhort table of fynonimous terms, to which the following is equivalent : Scientific Names. Marine or muriatic acid Oxygenated muriatic acid Nitric acid — Sulphuric acid — « Ammoniac — Carbonate of ammoniac Aluminc — Potato — . Carbonate of potalh Names in the Market, or common isames. Spirit of fait. Dephlogifticated marine acid of Scbecle. Spirit of nitre; aqua fortis. O'l of vitriol. Spirit of fal ammoniac with lime. Sal volatile. Pure clay. Pearl afti (which is im- pure). Salt of tartar. Soda 346 'Appendix, Scientific Names. Soda — Carbonate of Soda Sulphate of ; otafh of foda ■ of alumine . of iron - of copper -^— — of zinc Acetite of copper Muriate of foda Oxide — Namtt in the Market, Of common Names, Barilla. Salt of foda. Vitriolated tartar, Glauber's fait. Alum. Copperas ; green vitriol. Vitriol ; blue vitriol. White vitriol, or cop- peras. Verdigris, or diftilled ver- digris (if in cryftak). Common fea fait. The ruft or calx of a metaL 2. Meafures and Weights* I have not been able to difcover the Jaws of graduation of the areometer of MofTy, which is mentioned in this work. If is much to be re- gretted that all meafures, and inftruments for fpecific gravity, are not reduced to the. ufual numbers, of the tables in which that of water is taken as unity. Meafures of Temperature, according to Reaumur's fc ale, are reduced to that of Fahrenheit by this Rule : Multiply the degrees by 9 - y divide thepro- du£t by 4, and to the quotient add 32, if the temperature •dfpendiw 347 temperature be above the freezing water point ; or otherwife, if below freezing, take the quo- tient from 32. The fum or remainder will be the degree fought. Meafures of Length. The old French meafures of length are ufed throughout this treatife. The Paris foot, compared with the Englifh (Philof. Tranf. 1768), is as 1.06575 to t, which anfwers to fomewhat more than 12 inches and three quarters Engliih. The Paris ell (aune) being 44 French inches, will therefore meafure 46.89 Englifh inches, or rather more than 46 inches and feven eighths. Whence 5 Paris ells are very nearly equal to 6§ Englifh yards, the latter quantity being lefs than half an inch morter. Meafures of Capacity. The Paris pint is 2.017 Engliih wine pints, or a little more than a quart ; and the muid of wine 280 pints, or very nearlv 707 gallons. The feptier or chopine is half a pint. In corn meafure of Paris, 3 buihels make 1 minot j 2 minots, 1 mine j 2 mines, 1 fep- tier ; and 12 feptiers, 1 muid. The muid is not quite 52 Winchefter bufhcls. Weights. The Paris pound is 7561 Englifh grains, or one pound, one ounce, and 24I grains avoirdupois. Money. The livre is commonly reckoned at" ten 34^ Appendix, ten pence Englifh, and is divided into 20 fob, each confifting of 12 deniers*. With regard to the articles made ufe of, the od of vitriol, or fulphuric acid, may be rated at c|d per lb.; fait, at if per lb. ; manga- nefe, about one penny per pound ; pearlafh, 6d. per lb. ; foap, 4 1. per cwt. ; coals and other fuel very different in price, according to the fituation of the manufactory. 3. Obfervations en the Procefs, The new method of bleaching, for which wc" are undoubtedly indebted to Berthollet, in his application of the oxygenated acid, firft dif- covered by Scheele, to this ufeful purpofe, was very fpeedily introduced into our manufactories at Glafgow and Manchefter, and has fince been" very generally adopted in Ireland, Germany, and France. Some of our bleachers in Ireland im- merfe one thoufand pieces daily. The obftacles which at firft impeded the progrefs of this new aft arofe from the prejudices of bleachers, their ignorance in chemrftry, and the real difficulties * For the new weights, meafures, and money of France, which, however, are not ufed in the foregoing treatife, fee Nicholfon's Fhilof. Journal, I. 199. of Appendix. 349 of the procefs *, the chief of which, as is very ftrikingly (hewn by our author, confifted in the intolerable exhalations of the oxygenated acid, which rendered it nearly impoffible and highly dangerous for any workman to handle the goods during the immerfion, while it feemed no lefs impracticable to contrive a clofe apparatus, in which the goods ihould be expofed through all their parts to an equal a&ion of the bleaching liquor. Various contrivances were tried with little fuccefs, till it was difcovered that an ad- dition of alkali deprived the liquor of its pun- gent effluvia, but left it in poffeffion of its bleaching power. It feems to have been gene- rally thought that the only inconvenience of this addition was the expence of the alkali ; but Mr. Rupp f, in a lace excellent memoir, has fhewn that the ufual addition of one pound of pearlafli to the liquor for every three pounds of fulphuric acid in the mattras, renders the bleaching upon an average * $ per cent, lefs ef- fectual, which, with the coil of the alkali adds 40 per cent, to the coft of the unfaturated liquor. * Mr. Watt at Glafgovv, and Mr. Henry and Mr. Cooper at Manchefter, were among the firft by whofe exertions .his art was introduced. ) Manchefter Memoirs, v. Parti.; or Nicholibn's Jour- nal, II. s68. The 35° Appendix. The fame ingenious chemift has propofed a machine for the gradual and regular expofure ofthefurtace of piece-goods to the bleaching liquor in a clofed veffel. It confifts of two rol- lers, upon one of which the cotton is wound, and from which another roller draws it by- means of a winch. Daring this action, the evolved face is expofed to the liquor, and when all the cloth is thus wound off, it is rolled baek again upon the original cylinder, to which the handle is for that purpofe fhifted. It does not, however, appear that the inventor has ever ufed his apparatus, and I very much fear that the piece would run endways upon the cylinders fo as to defeat the operation *. Mr. Rupp found the bleaching liquor to be always ftrongeft when the diftillation was car- ried on very flowly, and that this ftrength is much increafed by diluting the fulphuric acid more than is ufually done. The following pro- portions afforded the ftrongeft liquor : three parts manganefe, or more or lefs, according to its quality; eight parts common fait; fix parts oil of vitriol; and twelve parts water. The author of the prefent treatife mentions * On this fubjecl:, which is the chief difficulty in cylinder printed, fee the Journal kft quoted, I. 33. lime appendix. 25 l lime as a fubftitute for alkali in the bleaching liquor, but without particularly infilling upon it as pofTefling fuperior advantages. Our bleach- ers, however, doubtlefs from experience, at leaft in point of cheapnefs, fet'a confiderable value upon it. Mr. Turner, of Darnly, near Glafgow, obtained a patent * in January, 1798, for the fole ufe of this earth in a 11 ate of me- chanical fufpenfion in the bleaching liquor, and has even received premiums or rents from other bleachers for permiihon to ufe his method. But I understand that the validity of this grant is likely to be contefted. * See Repertory of Arts, ix. 303. 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