GIFT OF Agriculture education THE FIRST YEAR OF SCIENCE BY JOHN C. HESSLER, Ph. D. \ s PROFESSOR Or CHEMISTRY, THE JAMES MILLIKIN UNIVERSITY. LATE INSTRUCTOR IN THE UNIVERSITY OF CHICAGO AND IN THE HYDE PARK HIGH SCHOOL, CHICAGO nblX aUd BENJ. H. SANBORN & CO. 1914 1 144 COPYRIGHT, 1914 BY JOHN C. HESSLER HGRIC, DEPT, Ur" R. R. DONNELLEY & SONS COMPANY CHICAGO PREFACE The chief interest in Secondary School science, which for a long time was concentrated upon the later years of the course, has recently been shifted to the work of the first year. The leading reason for this is the conviction, which is rapidly becoming general, that the first science of the High School should be fundamental to the entire field of science and should not be any one of the special sciences. It is hard to see how Physiography, Physiology, and Biology, the usual subjects of the early High School years, can be taught satisfactorily unless the pupil has previously acquired the elementary physical and chemical conceptions which underlie Physiography, Physiology, and Biology. A proof that this need is felt is the fact that many teachers of first-year science, no matter what their subjects may be called, find themselves obliged, even now, to give a large part of their class time to the presentation of fundamental physical and chemical ideas. The problem involved in the proper preparation of pupils for the study of Physiography and the biological sciences cannot be solved by the transfer of Physics and Chemistry, as formal subjects, to the first year of the High School curriculum. The cause lies both in the difficulty of the subjects themselves and also in the high development which these sciences have reached in Secondary Schools. For Physics and Chemistry are now taught in Secondary Schools in a way and with an iii >* O A iv PREFACE equipment far in advance even of College instruction in these subjects a generation ago. Work of this character requires a certain maturity on the part of the pupil, as well as some knowledge of other High School subjects, and it cannot be maintained unless Physics and Chemistry are kept in the later years of the course. While Physics and Chemistry as such ought not to be put into the early years of the High School, yet instruction in the simpler principles of these sciences can be given in a first-year General Science course. The most im- portant part of this course will be introductory notions of physical and chemical phenomena, but the course should include much more than this. The problems of modern conveniences and of their relation to scientific discovery, the soil as the basis of agriculture, plants and animals and their ascent from simpler forms to those that are more complex, all can find a place in such a course. So can sanitation, the application of science to community life. When we assign to General Science the scope suggested in the foregoing paragraph, the need of it in the first year of the High School course is self-evident. This is true even if we confine ourselves to the staple High School curriculum of a decade ago. But when we remember that this curriculum has been immeasurably enlarged by the introduction of short courses, business courses, do- mestic science courses, agricultural courses, and of voca- tional guidance in all courses, the demand for adequate first-year science instruction becomes imperative, and the argument for its introduction overwhelming. The question that remains is: "Can such a General Science course be given to large, first-year High School classes, PREFACE V with their varied needs, without special teachers par- ticularly prepared for this subject and without expensive equipment for laboratory work?" The answer is certainly "Yes." To give the answer in expanded form is the purpose of this book. The "First Year of Science" is written to meet the need of General Science instruction. It consists of three parts: the text proper, the laboratory manual, and the Teacher's Handbook. The text and laboratory manual may be had either bound together or in separate volumes. If the writer were asked to characterize the book in a phrase or two, he would say that it is intended to stimu- late uncommon thinking about common things, to produce a scientific attitude toward everyday problems, to give scientific knowledge to as large a body of our people as possible in order that modern inventions may be the tools and not merely the toys of the men and women into whose hands they are placed. The text proper consists of descriptive matter, of exercises, and of chapter summaries. There are twenty chapters. As the Table of Contents shows, about half of these consist of elementary Physics and Chemistry. The chapters on Physics contain no formulas and only a few simple calculations; there are no symbols or equations in the chapters on Chemistry. The author's plan is to give only the primary notions of matter, force, and chem- ical action. These are needed for all subsequent work in pure or applied science, as well as for that general knowledge of common things which every person ought to carry away from a High School course. In the latter half of the text are' chapters on "Water, vi PREFACE Heat, Air, and Light in the House," "The Weather," " Rocks and Soil," "Plants," and " Animals." Chapters XVII to XX are given to elementary Physiology and Sanitation. The book therefore contains the material needed by schools that desire to give a short course in Physiology at the end of the first year. Coming, as it does, after the elementary Physics and Chemistry of the earlier half of the book, and immediately after the chapters on " Plants" and "Animate," the work in Physiology ought to mean far more to the pupil than if it were an isolated appendix to the first year's work. The illustrations of the "First Year of Science" are unusually numerous and especially adapted to the text. They have been prepared with great care, for they are intended, by their direct appeal to the eye, to enlarge materially the teaching power of the text. To this end descriptive matter has been added to them and they have been made very simple. The parts of drawings have usually been designated by names rather than by letters. Exercises are given at the end of each chapter and also in the body of each chapter except the first. The exercises are questions taken from the chapter; they en- courage the pupil to apply to common phenomena what he has learned in the text and the laboratory work. Summaries are placed at the end of each chapter to bring together in a bird's-eye view the leading topics of the chapter. An appendix contains useful tables and a reference Glossary of terms used in the book. The laboratory exercises are such as can be per- PREFACE VII formed with simple apparatus, and the directions are specific both as to the form of apparatus and as to the quantity of materials to be used. A special feature is a series of alternative experiments, in which the apparatus used is so simple that it can be made at home. If desired, most of these alternative experiments may be performed by the pupil at home. If the laboratory facilities of the school are limited, none but these simple experiments need necessarily be used. We have become so accus- tomed, in our well-equipped schools, to laboratory ap- paratus which has certain definite forms and requires certain set manipulations that we are likely to forget that the setting up of home-made apparatus is usually far more stimulating to the pupil than even the best of ready- made equipment. Only by linking our science with everyday things can we hope to convince the pupil that science is only common sense applied to daily life. The handbook on the " Teaching of First- Year Science " forms the third part of the book. It contains material intended chiefly for the teacher's use. Here are dis- cussed the topics suitable for recitation and the methods of presenting them, the amount and kind of work to be expected of pupils, answers to exercises, and a list of experiments, carefully planned, to be performed by the teacher before, or, better, with the class. The handbook is designed to assist the teacher in every possible way in making the elementary science course profitable and stimulating. In the preparation of this book the writer has neces- sarily consulted many textbooks of Science, and put himself under deep obligation to their authors. To all of Vlll PREFACE these he desires to express his thanks. He is especially grateful to his friends, Dr. Eugene C. Woodruff, of Penn- sylvania State College, and Miss Marion Sykes, of the Chicago High Schools, for valuable criticisms and sug- gestions. The author desires likewise to thank the many in- dividuals and firms who have so generously assisted him in the procuring of illustrations. Among these are Drs. O. C. Farrington and C. F. Millspaugh, of the Field Museum of Natural History, Chicago; the International Stereograph Co., Decatur 111.; Dr. S. W. Stratton, of the Bureau of Standards, Washington; Dr. Orville Wright, Dayton, Ohio; Mr. William D. Richardson, of Swift and Company; Professor Frederick Starr, of the University of Chicago; Professor Martha Van Rensselaer, of the Department of Home Economics, Cornell University; and many others whose names appear under the figures. The drawings for the illustrations have been made by Messrs. William F. Henderson, Macknet Van Deventer, Otto Roth, Alex. Van Praag, Milford Davis, and Leland Smith, and by Miss Hila Ayres. The drawings for Figs. 88, 206, and some others were made by Miss Ruth Fuller. To all of these the author hereby expresses his apprecia- tion and gratitude. J. C. H. Decatur, Illinois. CONTENTS CHAPTER I. Matter and Its Measurement 1 The Earth and Science. Phenomena. The Scientific Way or Method. Matter. Substances. How We Measure Space and Matter. Common Units of Length. The Metric System. The Standard Meter. Metric Tables of Length, Area, and Volume. Larger Units of Length. Weight. Units of Weight. Metric Units of Weight. Bureau of Standards. Summary. Exercises. CHAPTER II. Force and Energy 17 Gravity. Gravitation. Mass and Weight. Falling Bodies. Exercises. Force. Force of Expanding Gases. Work and Energy. Power. Inertia of Matter. Flying from the Center. Exer- cises. Cohesion and Adhesion. The Surface of a Liquid. Capil- lary Action. Density and Specific Gravity. Buoyant Force of Liquids. Center of Mass or Gravity. Summary. Exercises. CHAPTER III. Air and Fire 38 The Atmosphere. Weight of Air. Atmospheric Pressure; Ba- rometer Changes in Atmospheric Pressure. Pumps. Compressed Air. Exercises. Collection of Gases. Discovery of Oxygen. The Air a Mixture. Burning and Oxidation. Flames. Prepara- tion of Oxygen. Properties of Oxygen. Oxygen and Life. Exer- cises. How Nitrogen is Prepared, Properties of Nitrogen. Nitro- gen and Life. Liquid Air. How the Atmosphere is Purified. Summary. Exercises. CHAPTER IV. Heat 59 Heat and Matter. Thermometers. The Two Thermometer Scales. Heat and Temperature. Ways of Distributing Heat. Radiation. Convection. Exercises. Physical States of Matter; Solids. Liquids. Gases. Kindling Temperature. The Measur- ing of Heat. Heat and Life. Clothing. Sources of Heat. Sum- mary. Exercises. ix X CONTENTS CHAPTER V. Water . 76 How Water Occurs in Nature. Substances Dissolved in Natural Water. Drinking Water. Hardness of Water. Purifying Water. Filtering. Filtering City Water. Exercises. Why Ice Forms j Only at the Surface. Artificial Ice. Steam. The Boiling Point Changes with Pressure. Solutions. Properties of Solutions. Freezing Mixtures. Solubility. Crystals. Summary. Exercises. CHAPTER VI. Elements and Compounds 94 Physical and Cheniical Changes. Composition of Water. Electrolysis of Water. Elements and Compounds. Mixtures. Preparation of Hydrogen. Properties of Hydrogen. Burning of Hydrogen. Diffusion of Gases and Liquids. Exercises. Salt. iSodium. Chlorine. Hydrochloric Acid. Ammonia. Sulphur. <. Number of Elements and Compounds. Summary. Exercises. CHAPTER VII. Carbon and its Compounds . .110 Carbon as an Element. Coal. Uses of the Forms of Carbon. Hydrocarbons. Petroleum. Flashing Point. Other Compounds of Carbon. Dry Distillation of Coal and Wood. Exercises. Carbon Dioxide. Carbon Dioxide in the Air. To Prepare Carbon Dioxide. Carbon Dioxide in Fermentation. Baking Powders. Carbon Dioxide as a Fire Extinguisher. Limestone. Summary. Exercises. CHAPTER VIII. Magnets and Electricity . ( . . .125 Magnets. Poles of a Magnet. Magnetic Substances. The Magnetic Field. The Earth a Magnet. Exercises. Electric Charges from Friction. Conductors and Insulators. Attraction and Repulsion. Induction of Charges. Electric Discharge. Stor- ing a Charge; Leyden Jar. Electricity of the Atmosphere. Light- ning Rods. Exercises. Electric Currents. Kinds of ' Cells. Sal Ammoniac Cell. Currents and Magnetism. Electro-Magnets. The Telegraph. Electric Bell. Changing the Current into Light. Electric Furnaces. Electroplating. The Dynamo. Electric Mo- tor. Electric Power. Summary. Exercises. CONTENTS XL CHAPTER IX. Light and Sound 150 Luminous Bodies. Transparent and Opaque Bodies. Light and Its Properties. Images through Small Openings. Shadows. Brightness or Intensity of Light. Candle Power. Exercises. Division of Light Striking a Body. Reflection of Light. Mirrors. Dispersed or Diffused Light. Refraction of Light. The Lens. Composition of White Light. The Rainbow. Absorption of Light; Color. The Sky and Its Colors. Change of Light into Heat. Light and Life. Exercises. Simple Microscope. Compound Mi- croscope. The Camera. How Sounds are Made and Carried. Sound Waves. Echoes. Noise and Tone. The Telephone. Summary. Exercises. CHAPTER X. Simple Machines 174 Need of Machines. Law of Machines. The Lever. Classes of Levers. Exercises. Pulleys. Wheel and Axle. Inclined Plane. The Wedge. The Screw. Friction. Sailboat. The Kite. The Airship. The Windmill. Summary. Exercises. CHAPTER XI. Acids, Alkalies, and Cleaning 188 Acids. Classes of Acids. Acids and Coloring Matter. Action of Acids with Metals. Action of Acids with Carbonates. Alkalies or Bases. Caustic Soda and Caustic Potash. Neutralization; Salts. Tests for Certain Salts. Exercises. The Washing of Cloth- ing. Soap and Soap Making. Action of Soap. Soap and Hard Water. Materials of Clothing. Dyes. Paints. Removal of Stains. Summary. Exercises. CHAPTER XII. Water, Heat, Air, and Light in the House . 207 Modern Conveniences. Water Supply. Plumbing. Hydrants and Traps. Kindling a Fire; Matches. The Fireplace. Stoves. Gas Stoves. Gasoline Stoves. Electric Stoves and Heaters. Stream and Hot Water Heating. Thermostat. Exercises. Need of Ventilation. Methods of Ventilation. Ventilation without Fans. Need of Moisture in Air. Light in the House. Glass. Artificial Lighting. Gas for Lighting. Incandescent Mantles. Gas Pipes and Fixtures. The Gas Meter. Acetylene for Lighting. Electric Lighting. The Electric Meter. Summary. Exercises. Xll CONTENTS CHAPTER XIII. The Weather . . 232 Causes of Weather. Changes in Density and Pressure of Air. Heating of the Air. Moisture of the Air. Humidity. Dew and Frost. Fogs and Clouds. Forms of Clouds. Rain and Snow. Hail. Rainfall. Exercises. The Winds. Regular Win ds. Storms and Cyclones. Thunderstorms. Tornadoes. Cyclones of the Tropics. Weather Service. Weather Maps. Summary. Exercises. CHAPTER XIV. Rocks and Soil . 258 The Earth's Crust. Some Common Rocks. Classes of Rocks. Origin of Stratified Rocks. Origin of Igneous and Metamorphic Rocks. Weathering of Rocks. Causes of Weathering. Drift. Erosion. Exercises. Soil. Structure of Soil. Tilling the Soil. Irrigation. Fertility. Loss of Fertility. Preserving and Re- storing Fertility. Rotation of Crops. Artificial Fertilizers. Summary. Exercises. CHAPTER XV. Plants . . , . ... . . . . .;, ' ,-, - ..,.. ... . 282 Plants and the Soil. Functions of Plants. Germination of a Bean. Other Seeds. Leaves. Work of Leaves. Modified Leaves. Stems. Structure of Stems; Wood. Sap. Buds. Roots. Underground Storage of Food. Flowers. Formation of Seeds. Dispersal of Seeds. Exercises. Classes of Plants. Algae. Fungi. Mosses. Ferns. Seed Plants. Economic Plants. Distribution of Plants. Summary. Exercises. CHAPTER XVI. Animals . . . . . 312 What is an Animal? One-Celled Animals. Simple Many-Celled Animals. Starfishes. Worms. Mollusks. Crustaceans. In- sects. Exercises. Fishes. Amphibians. Reptiles. Birds. Mammals. Importance of Animals to Man. Summary. Exer- cises. CONTENTS Xlll CHAPTER XVII. The Human Body and Its Food 338 Chief Divisions of the Body. Cells and Tissues of the Body. Structure of Bones. Joints. The Skeleton. Muscles and Tendons. Injuries to Bones and Muscles. Kinds of Food. Organs of Di- gestion; Glands. The Mouth. The Teeth. The Swallowing of Food. Exercises. The Stomach. Gastric Juice. The Intestines. The Liver. The Pancreas. Changes in Food by Digestion. Absorption and Assimilation of Food. Storage of Food. Alcohol and Its Effects. Summary. Exercises. CHAPTER XVIII. Circulation and Respiration 372 Circulation of the Blood. The Heart. Arteries and Veins. Capillaries. Blood. Lymph. Excretion. Respiration. The Lungs. Exchange of Gases in the Lungs. Inspiration. Expira- tion. Exercises. The Nostrils and Pharynx. The Larynx and Trachea. The Voice. Speech. Care of the Organs of Respiration. The Skin. Perspiration. Hair and Nails. Functions of the Skin. Summary. Exercises. CHAPTER XIX. The Nerves and the Sense Organs 395 The Nervous System. Nerve Cells and their Structure. The Brain and its Parts. Spinal Cord. Sympathetic System. Nervous System as a Whole. Voluntary and Involuntary Action. Reflex Action. Habit. Effect of Alcohol and Tobacco on the Nerves. Exercises. The Special Senses. Touch. Taste. Smell. Hear- ing; Structure of the Ear. Sight. Eye Socket and Lids. Parts of the Eye. Accommodaton. Near and Far Sight. Summary. Exercises. CHAPTER XX. Sanitation 425 Bacteria and their Relation to Disease. How the Body Resists Bacteria. Natural Destruction of Germs. Artificial Destruction of Germs; Antiseptics. The Housefly and Mosquito in Relation to Public Health. Exposed Food. Drinking Fountains. Typhoid and Sewage. Exercises. Tuberculosis and its Cure. Spitting in Public. Colds. Diphtheria. Antitoxins. Smallpox. Vaccina- tion. Malaria and Yellow Fever. Quarantine. Disinfection. Summary. Exercises. THE FIRST YEAR OF SCIENCE CHAPTER I MATTER AND ITS MEASUREMENT 1. The Earth and Science. In order that we may get a knowledge of the earth we must study the separate parts that make it up. We have already done this some- what in Geography. Hence we know that the earth con- sists of many different rocks and soils, trees and plants; of bodies and streams of water; of the air; of a multitude of animals that live on or in the soil, the vegetation, and the water. We call any particular rock, tree, lake, or animal an object, or body. The sum of all its objects, large and small, is the earth itself. Nature, or the Uni- verse, includes the earth together with the sun, moon, stars, etc. Science is the study of the truth about the objects of nature. Since the number of objects is very large, one method of studying nature is to find important resem- blances and differences between objects. We can then arrange objects in groups or classes. Thus, we can make a division of all objects into (a) living objects and (6) non-living objects. Living things may then be classified as either animals or plants. Plants in their turn may be i "/ 2 MATTER AND ITS MEASUREMENT grouped as flowering or non-flowering plants, and each of these will have many divisions. To take one illustration : the daisy, the dandelion, and the sunflower belong in one great group of flowering plants because the structure of their flowers is similar, while the rose, the strawberry, and the apple belong in an entirely different group. But the classifying of objects, while very valuable, is only a part of science. By far the greater part is taken up with the study of the objects themselves. We want to know their beginning, or origin, what they do, and what becomes of them. For the objects of nature are always changing. Living things grow, and then decay; rocks are made, and then crumble. Even the "eternal hills" are worn away, and the "fixed" stars appear to be fixed only because, to the eye, they change their positions so slowly. 2. Phenomena. By a "phenomenon" (plural, phe- nomena) we mean simply a happening, a change, that takes place in some object. It is not necessarily a strange occurrence, like the appearing of a comet or an eclipse. We observe a phenomenon when we see a marble roll over the floor, when an apple falls to the ground, when a com- pass needle takes a north and south position, when an electric light is "turned on" or "goes out." Other phe- nomena are such common changes as the burning of wood, the souring of milk, the freezing of water, and the rusting of iron. * 3. The Scientific Way, or Method. Primitive man probably reasoned in a very childish way about objects THE SCIENTIFIC WAY and phenomena. We know that men were once satisfied to explain an eclipse of the sun (cf. 169) by saying that it was caused by a great dragon, or bird, or spirit, passing across the sky. Even in comparatively recent times people have had ideas only a little better, for when Colum- bus asserted that the earth was a sphere the men of his day ridiculed him. They were sure that if the earth were round, the people on the other side of the earth must be standing on their heads. But men interested in finding out about nature have kept on experimenting and reasoning, until they have come to understand something of nature's ways. They have made the most progress when they have used the method of study which we now call the scientific method. This method consists in (a) getting together as many facts as possible regard- ing the object or phenomenon studied; (b) arranging these facts in the order of their impor- tance; (c) drawing some conclusion. Men now use the scientific method to get at every sort of knowledge, even the knowledge needed to conduct a business or to "keep house." We may, therefore, define science a second time and say that it is organized knowledge. We call such knowledge "organized" because, like a plant or animal, it is composed of parts called, in the plant or animal, organs each of which has a particular place and a particular duty. General Science, which we are now to study, takes up many topics also found in the special sciences, such as Physics, Chemistry, Botany, Physiology, etc. A knowledge of these topics is necessary not only to the students who are later to study the special sciences, but to every MATTER AND ITS MEASUREMENT FIG. 1. Flask with a glass-stop- pered tube. one who wants to understand and to use scientific methods and apparatus in the home, in the shop or store, on the farm in short, anywhere in his daily life. 4. Matter. Suppose we examine a number of objects, such as pieces of marble, sulphur, wood, lead, etc. They are certainly unlike in color, size, and shape. Are they alike in any particulars? In the first place, they all take up room, or occupy space. We cannot think of a body that does not. A second way in which objects are alike is that all of them have weight (cf. 20). We accept these statements readily when we think of lead, of marble, of water, of rock. These are solids or liquids, and are readily seen and handled. But even invisible gases, like the air, take up room and have weight, just as solid and liquid objects do. A vessel, such as a flask (Fig. 1), from which the air may be removed, is lighter when empty than when full of air. Again, a vessel full of air cannot be filled with water unless the air is allowed to escape. We see this when we try to pour water rapidly into a narrow-mouth bottle; the water can enter only a little at a time, as bubbles of air come out to make room for it. Another illustration is seen in the construction of a kerosene can (Fig. 2). The can has an opening at the top not only to allow the can to be filled with kerosene, but also to permit air to enter in a steady stream as the kerosene is poured out of the spout. FIG. 2. As kerosene comes out air enters. SUBSTANCES 5 Now, why do all bodies occupy space? We answer by saying that bodies are portions of matter, and that matter occupies space. Matter not only occupies space, but it has weight. When we give the weight of an object we give the weight of the matter in it. 5. Substances. While it is important for us to get the general idea of matter, yet we always observe and study matter in separate portions, or bodies (cf. 1). Each body may be made up of one kind of matter or of several kinds. Thus, we might have chips of marble, each consisting of one kind of matter (marble), or we might have chips consisting of a mixture of marble and clay. The kinds of matter are called substances. The qualities, or characteristics, of a body depend upon the qualities of the substance or substances of which it is composed. The qualities of a substance are called its properties. We learn the properties of any given sub- stance by the use of our senses or by experiment. Some illustrations will make clear the meaning of properties and the difference between bodies and substances. A lake is a body of water; water is not a body but a kind of matter, that is, a substance. A pencil is a body consisting of the substances wood and "black lead," or graphite (cf. 117). We can readily tell the wood from the graphite by the properties of each. Thus, the wood is soft when cut; it is brittle, light in color, and it floats upon water; it burns when heated in the air. Graphite, on the other hand, has different properties. It too is brittle, but its color is black, it sinks in water, burns with great difficulty, and leaves a black mark when rubbed on paper. All these properties dis- tinguish graphite from wood. Sulphur, or "brimstone," is another common substance. It is dis- tinguished from wood and from graphite by the following properties: 6 MATTER AND ITS MEASUREMENT it is yellow, crystalline (Fig. 3), brittle; it sinks in water, and does not dissolve in water; it melts when heated, giving a clear, yellow liquid; it burns readily in the air (cf. 51). Wood tipped with sulphur, phosphorus, and some other substances makes up another body, a match (cf. 72). Now, the properties of the substances FIQ 3 composing a match make the uses of the match A Sulphur Crystal. quite different from the uses of a pencil. General and Special Properties. We must remember that the properties of a body, such as its filling space, hav- ing weight, etc., are the general properties of all matter, and do not belong to one substance more than to another. The special, or specific, properties of a substance belong to that substance alone. No two substances have exactly the same special properties. 6. How We Measure Space and Matter. We know from experience that all bodies have three dimensions; namely, length, breadth, and thickness. We also think of space as having these dimensions. When we say that a body has a definite volume, we mean that it fills a definite amount of space. We do not know what space is, but we distinguish between space and matter, calling that " space" which is not filled with some object. On the earth, a por- tion of space from which matter has been removed is called a vacuum. As already stated (cf. 4), air and other gases are matter, not space. FlG 4 If a body is regular in shape, we can readily calculate its volume. Thus, we obtain the vol- ume of a cube (Fig. 4) from the formula, THE METRIC SYSTEM Volume = length X breadth X thickness. We can get the volume of an irregular solid by im- mersing it in some liquid (Fig. 5). The body displaces its own volume of liquid. The boundaries of a body, by which the mat- ter of the body is separated from other matter, or from space, are called surfaces. A cube has six plane surfaces. A sphere has a uniformly curved surface. A surface has two dimensions, length and breadth. The boundaries of a sur- face are lines, with only the dimension of length. 50 40 ,, FIG. 5. 7. Common Units of Length. The unit of length used in Great Britain and the United States is the yard. Originally the yard was probably the length of the King's arm, but this changeable standard has become fixed, and is now the length of a standard metal bar kept in London, with a copy at Washington. The foot was originally the length of the human foot, but became fixed as ^ of a yard. The inch was fixed as ^ of a foot. 8. The Metric System. The yard and its subdivisions and multiples are still used for ordinary measurements in this country and England, but on the continent of Europe a different system prevails. This is called the metric system, from its standard, the meter. It is a decimal system, and has been adopted by scientific writers the world over. The coinage of this country has long been upon the decimal basis, and the names used for subdivi- sions of the dollar are also used for subdivisions of the 8 MATTER AND ITS MEASUREMENT meter. The name of the smallest money unit, the mill, is derived from the Latin millia, meaning 1000. Cent is from centum, or 100, and dime is from decem, meaning 10. A mill is iffio of a dollar; a cent is 150 ; a dime, A. In the same way 1^5 of a meter is called a millimeter ; n^, a centimeter; and ^, a decimeter. 9. The Standard Meter. Men intended that the meter should be 40,000.000 of the earth's circumference, but we now define it as the distance between two fine lines ruled on a metal bar (Fig. 6). The bar is made of an alloy (mix- united StatefproLype Meter. tui>e ) f tn ^ metals pldtl- num and indium. While the distance between the lines is being measured, the bar is kept at the temperature of melting ice; that is, at Centigrade (cf. 63 and 69). Thirty-one inter- national standard meters were made at Paris and dis- D 1 23456 1 1 ii 1 1 II 1 i M I In 1 1 1 1 II 1 1 1 ii I 1 1 1 1 M 1 1 1 1 M li 1 1 il in i II 1 1 1 1 7 8 C 1 1 1 1 1 II 1 1 1 II II 11 1 .M 1 i ' j ' i ' 1 ' | ' | ' i ' 1 ' i | ' i ' | ' i i i D I 2 FIG. 7. Inches and Centimeters. 1 | ' 1 < | ' 1 ' 3 IN. tributed among the principal governments of the world. Two of them were brought to the United States and are kept at Washington. The length of the meter is 39.37 inches, or 3.28 feet. The exact measurement of the meter is very difficult, because the metal bar changes its length slightly, but in recent years the meter has been made LARGER UNITS OF LENGTH 9 equal to the length of a certain number of light-waves (cf. 179), so that if all the standard meters were destroyed, a new, perfect meter could be obtained. 10. Metric Tables of Length, Area, and Volume. The metric table of length (Fig. 7) is 10 millimeters (mm.) = 1 centimeter. 10 centimeters (cm.) = 1 decimeter. 10 decimeters (dm.) = 1 meter. 1000 meters (m.) = 1 kilometer. 1 kilometer (km.) =0.6214 mile. For surface measure the table is 100 square millimeters = 1 square centimeter. 100 square centimeters = 1 square decimeter. 100 square decimeters = 1 square meter. For cubic measure the table is - 1000 cubic millimeters (c. mm.) = 1 cubic centimeter. 1000 cubic centimeters (c.c. or c.cm.) = 1 cubic decimeter. 1000 cubic decimeters (c. dm.) = 1 cubic meter. One cubic decimeter is called a liter (pronounced leter). It is a little larger than a U. S. liquid quart. As the last table shows, the cubic decimeter, and therefore the liter, contains 1000 cubic centimeters. The relation between metric units and other ordinary units is shown in the Appendix, Table II. 11. Larger Units of Length. For distances on the earth the mile (5,280 feet) and the kilometer (3,281 feet) are convenient units. But when we express, in miles, the distance of the earth from the sun, the 10 MATTER AND ITS MEASUREMENT /* FIG. 8. The Big Dipper and the North Star on September 22, 8 p. m. number about 93,000,000 is so large that it means very little to us. We can get a better idea of the distance by saying that it takes over eight minutes (499 seconds) for the sun's light to reach us, al- , though light travels at the rate of about 186,000 miles (300,000 kilometers) each second. Or we may say that a train traveling a mile a minute would need about 178 years to get to the sun. Yet the earth's distance from the sun is very small as compared with its distance from the stars. The light of the nearest fixed star requires about 4 years to reach the earth; while the light of Polaris, the " North Star" (Fig. 8), that enters our eyes to-night left the star about 47 years ago. In order to avoid the use of the many figures needed to express such enormous distances in miles astronomers use a larger unit for star distances. This unit is the light-year; that is, the distance which light travels in a year. The light-year is about 63,000 times as great as the distance of the earth from the sun, or 63,000X93,000,000 miles. 12. Weight. Just as we might estimate moderate distances by means of our ' ' sense of distance/' or " sense of space," so we might get the weights of many objects by using our " sense of weight." In fact, the experienced cashier and baggageman often develop the sense of weight to a remarkable degree, owing to years of training in the "hefting" of coins and trunks, respectively. However, to get distances accurately we FIG. 9. The Chemical Balance. UNITS OF WEIGHT 11 FIG. 10. Trip Scale. use measuring rods, tapes, chains, etc., and to get accurate weights we use balances and scales. If the balance has two arms of equal length, as in the chemical balance (Fig. 9) and the "trip" balance of the labora- tory (Fig. 10), the weights used as the counterpoise must be exactly as heavy as the object weighed. The object to be weighed on such balances is placed in the left-hand pan, and the weights in the right. In making the spring balance (Fig. 11) the manufac- turers stretch the spring by means of weights placed on the hook, and then mark the successive positions of the pointer on the graduated scale. A body which stretches FIG. 11. the spring to the same extent must be just as heavy as the weights used. Scales for weighing heavy objects, such as cars, or loads of hay or coal, are made by putting together a system of levers (cf. 198), so that the whole apparatus can be kept in a small space under the weighing platform. 13. Units of Weight. Man has used many units of weight. The old English pound (from the Latin pondus, a weight) was originally the weight of 7680 grains of wheat "all taken from the middle of the ear, and well dried." From this origin of the pound came the word "grain," the small division of the pound. Henry VIII, King of England from 1509 to 1547, made the "avoirdupois" pound the unit of weight. It contains 16 ounces, or 7000 grains. In 1758 a piece of brass of suitable size was de- clared by Parliament to be a pound. Later, a piece of 12 MATTER AND ITS MEASUREMENT platinum was substituted for the brass. The English pound weight is still this platinum standard pound. Copies of it, also of platinum, are kept in the United States (Washington) and in other countries. The abbreviation "lb.," for "pound," comes from the Latin libra, or scales. The word "ounce" is probably from unus, "one," and was originally applied to & of a pound, as it still is in "Troy " weight. In the form "inch" it was also applied to 1*3 of a foot. The ton probably received its name from the "tun," a large cask that held about 2,000 pounds of water. 14. Metric Units of Weight- In the metric system the com- mon weight units are the gram and kilogram (1000 grams). A liter of pure water at 4 C. (cf. 87) weighs one kilogram. This is abbreviated to "kilo" or to 1 i kg. ' ' The international stand- ard kilogram is a piece of plati- num, as is the English standard pound. Forty of these were constructed in Paris, and two of them are in the Bureau of Standards, at Wash- ington (Fig. 12). FIG. 12. The Standard Kilogram. One cubic centimeter of water, that is, i^bo of a liter, weighs one gram. Subdivisions of the gram, like those of the meter, are formed from the prefixes "milli," "centi," and "ded." BUREAU OF STANDARDS 13 10 milligrams (ing.) = 1 centigram. 10 centigrams (eg.) = 1 decigram. 10 decigrams (dg.) = 1 gram. 1000 grams (g.) = 1 kilogram. 1 kilogram (kg.) = 2.2046 Ibs. 1000 kilograms = 1 metric ton. Two advantages which the metric system has over the English sys- tem are: (1) It is a decimal system. (2) It is already in use in practically all of Europe, and in Latin America. Just as we can gather together "one dollar, four dimes, and three cents" into the expression "$1.43," so we can write "two grams, five decigrams, three centigrams, and one milligram" as "2.531 g." A weight consisting of several English units, such as two pounds, six ounces, and fifteen grains, cannot be expressed in pounds without much calculation. 15. Bureau of Standards. Since it is important that all apparatus used for measuring shall be correct, several governments have established "Bureaus of Standards/' to which such apparatus may be sent for the purpose of comparing it with the standard apparatus of the govern- ment. The United States Bureau of Standards (Fig. 13) was established at Washington in 1901. Originally the Bureau was only a place for keeping the pound, yard, gallon, bushel, meter, kilogram, etc., up to standard, but it has grown to be much more than this. The many new industries that have arisen in recent years and the application of scientific methods to old industries make new standards necessary. It is also important that both the quantities of the materials that go into manufactured articles, as well as their qualities, or properties (cf. 5), shall be definitely known. Hence the Bureau furnishes standards of measurement for electricity, the unit of light intensity (known as the "candle power"; 14 MATTER AND ITS MEASUREMENT cf. 171), standard thermometers for determining temperature (c/. 63), and standard pyrometers for determining higher temperatures than the thermometer will measure. We can realize the value of this work when we understand that the measurement of high temperatures, for example, is necessary in such important industries as making glass, FIG. 13. The Bureau of Standards. pottery, and illuminating gas, and in the preparation and working of the metals. Besides, the Bureau determines the strength of materials such as wood, steel, and cement, the fuel value of coal, petroleum, etc., as well as many other properties which the modern manufacturer needs to know. 16. Summary. Science is organized knowledge. It arranges ob- jects into groups or classes and studies the changes that objects undergo. SUMMARY 15 The scientific method is necessary in everyday life quite as much as in study and investigation. Phenomena are the changes in objects. Objects are portions of matter. Matter exists in the solid, the liquid, and the gaseous form. Matter occupies space and has weight. Substances are the kinds of matter. Properties are the qualities by which we distinguish one substance from another. Space is that which contains no matter. A space from which the matter has been removed is called a vacuum. Matter has three dimensions: length, breadth, and thickness. The meter is the unit of the metric system. It contains 39.37 inches.. The kilometer is 0.6214 miles. The liter is the unit of volume. It equals 1 cubic decimeter, or 1.0567 U. S. liquid quarts. The standard pound weight contains 16 ounces, or 7000 grains. The gram is the weight of 1 cubic centimeter of pure water at 4 C. The kilogram is 1000 grams. It is the weight of one liter of pure water, and equals 2.2046 pounds. The Bureau of Standards keeps the standard weights and measures, compares common weights and measures with the standard ones, makes new standards as new industries demand them, and determines the properties of materials. 17. Exercises. 1. Name the so-called "five senses." Are there any senses besides these? Explain. 2. Name two substances that you can distinguish from each other by each of the five senses. For ' ' hearing," think of the way we test the genuineness of a coin. * 3. Make a list of ten objects, and write opposite each the substance or substances of which it is made up. 4. Make a list of all the properties you can think of for each of the following substances: iron, water, sugar, wood, and coal. 16 MATTER AND ITS MEASUREMENT 5. Name five phenomena besides those of 2. 6. Compare the way in which water is poured out of an inverted, small-mouth bottle with the way in which it is poured out of a pitcher. Explain. 7. Find the number of cubic feet of air in a room 14 ft. by 14 ft. by 9 ft. high. Find the weight of the air in ounces, if one cubic foot of air weighs 1% ounces. Reduce the weight to pounds. 8. Write down as grams and decimal parts of a gram 6 grams, 5 decigrams, 3 centigrams, and 9 milligrams. Subtract from this number the sum of 2 grams and 8 centigrams. 9. Locate the North Star to-night or the next clear night, note the hour, and draw a diagram to show the position of the "Big Dipper" with reference to the star. What stars of the dipper are the ' ' Pointers' ' ? 10. Look up (in the Glossary at the back of this book) the difference between planets and fixed stars. Name some of the planets. Name some fixed stars besides Polaris. 11. Look up the distance of the moon from the earth. What is the moon's diameter? The earth's? 12. Look in a dictionary for the origin of the words quart, gram, meter, vacuum, and substance. 13. What are the proofs that the earth is sphere-like and not flat? 14. Name some scientific methods or apparatus that have recently been brought into our homes. Into factories. Into stores. Name some that are used on the farm. In navigation. CHAPTER II FORCE AND ENERGY 18. Gravity. Many of our most common phenomena are simply changes in the position of bodies. The falling of an apple, the movement of water in waves and tides, the flight of a stone or a bullet through the air, all illustrate this. So do the turning of a magnetic needle toward the poles and the vibrating of a violin string. Now, why does a stone or an apple "fall"? Sir Isaac Newton gave the reason when he said that the earth pulls the apple and all other falling bodies. We do not find it easy to picture to ourselves just how the earth's ' ' pull " is applied. A horse pulling a wagon is attached to the wagon, and the strength of his muscles overcomes the tendency of the wagon to remain at rest. Similarly, an engine is attached to the cars it pulls. But the earth's attraction acts through space, without visible or invisible attachment. We can illustrate the earth's attraction, on a small scale, by the action of a magnet upon an iron nail. The magnet is a piece of steel which has been "magnetized," so that it has the power of drawing to itself bodies consisting of steel, iron, nickel, etc. There is no connection between the magnet and the attracted object, yet we know that there is action between them. It is just as necessary for us to assume that the apple attracts the earth as that the earth attracts the apple. It is also just as reasonable to suppose that the earth falls 17 18 FORCE AND ENERGY toward the apple as that the apple falls toward the earth. But the distance that the earth moves before they meet must, of course, be very small, owing to the much greater size of the earth. This earth-pull we call gravity. 19. Gravitation. The attraction which exists be- tween the earth and bodies near its surface exists also between all bodies of matter on the earth and between the earth and the sun, moon, and other heavenly bodies. It is called gravi- tation. Gravity is merely a particular case of gravitation. The gravitation, or attraction, between two bodies on the earth, as, for example, between two suspended balls (Fig. 14), is not easily observed, because the great attraction of the earth for both of them holds them in a ver- tical position. By means of a celebrated experiment first carried out in the latter part of the 18th century this attraction was made visible. A large ball of lead and a small one of copper were suspended side by side, with the result that the copper ball was drawn aside from a vertical position. 20. Mass and Weight. We need to distinguish be- tween the mass of a body and the weight of a body. New- ton saw that the earth's attraction for a body depends on the quantity of matter in the body, and not upon its kind. A pound of feathers is attracted with the same force as a pound of lead. The quantity of matter in a body is called FIG. 14. The two balls attract each other. MASS AND WEIGHT 19 the mass of the body. The weight of the body is the re- sult of the earth's pull upon the mass of the body. If, in some way, the pull upon a given body is increased, the weight will be in- creased; but if the pull is weakened, the weight will be de- creased. Now, how can we change the effect of gravity, that is, the attraction of the earth for a cer- tain mass? We can do it by changing the distance between the earth and the body. In other words, the attraction between two bodies depends not only on their masses, but also on the distance they are apart. The distance between two bodies is taken to be the distance between their centers. Suppose we have two balls weighing, say, 10 grams each, and 1 inch apart. If we place them 2 inches apart, the force of the attraction be- tween them will be only % as great as at 1 inch. If the distance be- tween them is made ^ an inch, the attraction will be 4 times what it was originally. Now, we have learned that the earth is not a perfect sphere, but is flattened at the poles. An object at the poles is about 13 miles nearer the earth's center than if it were at the equator. As a result of this difference a body weighing 589 pounds at the equator would weigh 590 pounds at the poles. Copyright International Stereograph Co., Decatur, 111. FIG. 15. Leaning Tower of Pisa. 20 FORCE AND ENERGY If we remove a body from the earth at any given place, that is, if we take it ' 'up in the air," or on a mountain top, it will also lose in weight. The mass of the body will, of course, remain the same everywhere. 21. Falling Bodies. We know that if we drop a stone it falls "straight down." We have also seen bricklayers using a string with a weight attached a plumbline to be sure that they were making a wall vertical. The position taken by the plumbline, like the path of the falling ball, shows that gravity pulls ver- tically downward. But objects that are very light, like feathers, seem to fall more slowly than heavy objects. Why is this? Galileo, dropping balls of different sizes and differ- ent materials from the "leaning tower" of Pisa (Fig. 15), insisted that all objects, FIG. 16. heavy and light, if let fall from the same Bodie va^uum gina height, should reach the ground at the same time. A feather and a bullet would fall at the same rate were it not for the air, which resists being pushed out of the way. In a tube free from air, that is, in a vacuum (Fig. 16) they do fall at the same rate. On a very windy day even a heavy body may not fall straight down. Thus an apple blown off the tree by a sudden gust will go in the direc- tion of the wind (horizontally) and also downward. It cannot go in either of these directions alone, so it goes down in a curved path. But it will reach the ground by the longer, curved path in the same time as if it fell vertically to the ground. This fact may be illustrated by two marbles (Fig. 17) one of which is given a horizontal blow, while the other is permitted to fall vertically. FORCE 21 22. Exercises. 1. Name five phenomena, besides those of 18, that are "changes in the position of bodies." 2. Suppose that the moon and the earth were of exactly the same mass, and that a ball weighing a ton were placed half-way between them. What would its weight be? Why? 3. If you dropped wooden, iron, and lead balls from an upper window, which would reach the ground first? 4. Suppose the wind were blowing hard down the street, and you dropped a tennis ball from an upper window. Where would it strike the ground? Why? 5. Draw a diagram to show the kind The Marbleg ^ &t ^ of a path a ball takes if you throw it Same instant. horizontally. If you throw it upward at an angle of 45 degrees (half a right angle). In which case would the ball have the greater range? 6. Who was Sir Isaac Newton? When did he live, and where? What did he add to our knowledge? Answer the same questions regarding Galileo. 23. Force. Let us imagine we are at a baseball game. The pitcher throws a "fair" ball, the batter strikes at it but makes a "foul" hit, and the catcher catches the ball. Three persons were concerned in the flight of that ball: the pitcher, who set it in motion ; the batter, who changed the direction of its motion; and the catcher, who stopped its motion. We say that all three exerted force upon the ball. Besides the players, two other bodies exerted force upon the pitched ball: (1) the air, which resisted being pushed 22 FORCE AND ENERGY out of the way and hence made the ball move more and more slowly; (2) the earth, which by its downward pull made the ball move in a path curving downward instead of in a horizontal one. This illustration shows us the ways in which one body may exert force upon another: (1) it may set the other body in motion; (2) it may change the direction of the motion; (3) it may stop the motion. In addition, (4) one body may change the velocity, or rate of motion, of another and so exert force upon it. Air exerts force, not simply by resisting other bodies as they pass through it, but also as wind air in motion. We use the force of the wind to sail a kite, to run a wind- mill, or to drive a ship through the sea. 24. Force of Expanding Gases. What exerts the force that sets a bullet in motion? The cartridge used in modern firearms is partly filled with powder (Fig. 18), and the open end of the cartridge is closed by the bullet. Besides powder, the cartridge contains a small amount of a white solid called mercury ful- minate, which, when given a blow (percussion), sets the pow- der on fire. The pulling of the trigger releases the hammer of the gun; the blow of the hammer causes the mercury fulminate to ignite the powder, so that it "explodes." By the explosion of the powder a gas is formed that will take up, when released, perhaps 300 times as much space as the original powder. In the cartridge the gas is under FIG. 18. Kinds of Powder: (1) Ordinary Form; (2) Giant Powder. FORCE OF EXPANDING GASES 23 great pressure, because it is crowded into so small a space. As it rushes out of the cartridge it expands, and drives the bullet rapidly before it. The steam engine, like the gun and cannon, is a device for producing motion by means of the expansion of a compressed gas. Steam is pro- duced, under high pressure, in a boiler (Fig. 19), and is allowed to ex- pand in a cylinder, first on one side and then on the other, of a FIG. 19. Principle of the Steam Engine. piston. The piston is thus moved rapidly to and fro. This forward and backward motion is then changed to motion in a circle by means of a shaft. The eccentric turns with the shaft and moves the slide valve. The cause of motion in a gasoline engine is also the force exerted by expanding gases. A mixture of gasoline vapor and air, which is ex- ploded by an electric spark or a hot wire, is used in place of steam. The explosion produces a large volume of hot gases, and the expansion of the gases sets a piston in motion. The force exerted in the examples given may be put in one of the following classes : 24 FORCE AND ENERGY (1) Muscular force, such as that exerted by draught animals and man. (2) Gravity. (3) The force of the wind. (4) Resistance, such as that of air, water, the ground, or the parts of machinery. We commonly call this friction (cf. 206). (5) The force of expanding gases. Of course one body may exert force upon another and yet not move it, as when you try to lift a weight too heavy for you. 25. Work and Energy. When we raise a hammer into the air, we do work upon it, for we lift it against grav- ity. We also do work when we throw a ball, or wind up a watch. In the last case we produce motion against the elastic force of the spring. Because we can do work, we say we have energy. Energy is the capacity for doing work. A body that can do work upon another body possesses energy. The lifted hammer has energy because we have done work upon it, and it, in its turn, can do work upon some other body. If we let it fall, it can break a nutshell or drive a nail into wood. While poised in the air, the hammer has energy because of its position; while it is de- scending it has energy of motion. In the same way, the water of a waterfall has energy of position at the top of the fall, but energy of motion as it descends. A bullet in a gun at the instant of discharge can be said to have energy of position because of the compressed gas behind it. In its flight it has energy of motion. When it strikes a rock or a tree or other INERTIA OF MATTER 25 obstruction, it does work: it breaks the rock, or splits the tree, or flat- tens itself. When a body does work by lifting another body against gravity, the amount of work done is obtained by multiplying the weight lifted by the vertical distance it is lifted: Work = weight X distance. Thus, a workman carrying 50 Ibs. up a ladder 20 ft. high does just as much work as one raising 40 Ibs. 25 ft., or 10 Ibs. 100 ft. 26. Power. In calculating the amount of work done by a force we have not taken account of the time required. Yet if we were choosing a horse or an engine to raise a weight (Fig. 20), we would take the horse or engine that could do the work most rap- idly. The rate of doing work is power. The common unit of power is the horse-power (written H.P.) . James Watt, who de- vised the unit, thought that an average horse could raise 33,000 Ibs. 1 ft. in 1 minute, or 550 Ibs. 1 ft. in 1 second. As a matter of fact, the average American horse can exert only about three- fourths of a horse-power; that is, it can raise about 25,000 Ibs. 1 ft. in 1 minute. FIG. 20. Horse Raising Weight of a Pile-Driver. 27. Inertia of Matter. In Chapter I we learned that matter occupies space and has weight. What we have now learned about force shows us that matter has another 26 FORCE AND ENERGY striking property helplessness. This property is com- monly called inertia. We define inertia when we say that matter cannot move itself, cannot stop itself if moving, and cannot change the direction or rate of its motion. There are many illustrations of inertia : When you played "tag," and your playmate came rushing toward you at full speed, you took advantage of the inertia of his body when you l ' dodged." You knew he could not stop himself at once. When you run around a corner, you go in a wide curve, because the inertia of your body will not let you turn the corner sharply. When you shake a rug, you are able to jerk the rug away from the dirt because of the inertia of the dirt. If you hit a suspended newspaper, you burst a hole in it, because only the part struck moves forward while the rest of the newspaper remains behind. The air also has inertia. If we try to push it away suddenly, as by thrusting forward a paper fastened in a large hoop, the air remains where it was and tears the paper, just as a tree or a rock would. We work against the inertia of air in mo- ;/' N \ against a strong wind, or to "haul in" / \ a sail in a gale. \ \ 28. " Flying from the Cen- / ter." If a stone attached to / a string is whirled about the hand, it moves in a circle (Fig. ^^ x 21). The circular path is the FIG. 21. result of two forces: (1) the The Circular Path is the Result of inertia rvf tVm rnr^nncr c+rmo inertia and the string. uiertia oi me moving stone, which, acting alone, would cause the stone to move off in a straight line; and (2) the re- sistance of the string, which compels the stone to remain EXERCISES 27 always at the same distance from the hand. Because of the inertia of the moving stone we feel a decided pull upon the string. The pull becomes the stronger the more rapidly the stone is whirled. Finally the pull may break the string. If it does, the stone will fly off in a straight line. This tendency of the matter of a revolving body to fly off in a straight line is called centrifugal force. ' ' Cen- trifugal" comes from words meaning "to fly from the center." Centrifugal force is really no new kind of force, but merely a result of the inertia of matter. The flying off of mud from a revolving carriage wheel, and of water from a turning grindstone, and our difficulty in turning a sharp corner when we are running, are familiar illustrations of centrifugal force. The planets continue in their paths around the sun because of inertia together with the attraction between them and the sun. The dairy separator is an apparatus for separating cream from milk by rapid whirling. In this apparatus centrifugal force causes the milk, which is the heavier, to move out farther than the cream, and so divides them. 29. Exercises. 1. Why is it so hard to walk upon a polished floor? Why is it easier to skate on ice than to walk upon it? 2. Why does not gravitation draw the sun and earth together? 3. On which will a marble roll farther, a carpet or a smooth floor? Why? Suppose we could roll the marble on a perfectly smooth, horizontal plane, what force would there be to stop the marble? 4. When you strike the lowest of a pile of blocks a sharp blow, it flies out, leaving the rest of the blocks piled up. Why? 5. What happens to a child sitting on a sled if the sled is suddenly started? If the moving sled is suddenly stopped? In what direction is the child thrown off if the sled turns a sharp corner? Explain. 28 FORCE AND ENERGY 6. What work was done upon the water of a waterfall to give it energy? 7. What device is used to prevent a railway train from leaving the track when rounding a curve? Is any similar device used in a gym- nasium? On an automobile or motorcycle race course? 30. Cohesion and Adhesion. If we hold a sheet of glass face down against the surface of some water, and then pull the glass away from the water, we must use more force than is needed to lift the glass against gravity alone. Another force is being exerted on the glass. The under side of the glass will be wet. This shows that in pulling the glass away we did' not separate glass from water, but water from water. We therefore did work (cf. 25) against the force that holds the water together. The force that is exerted between the particles of matter is called cohesion. We can find the amount of cohesion, in the case of water, by attaching a piece of glass by means of strings to one arm of a balance (Fig. 22), allowing the glass to touch the water, and then adding weights to the other side of the balance until we tear the glass away. Of course we must subtract the weight of the glass from the total weight to get the ''breaking weight" of the water. FIG. 22. Measuring the Force Needed to Tear Water from Water. When cohesion is exerted between different substances, we call it adhesion. Thus cohesion holds water together, and cohesion holds glass together, but adhesion holds THE SURFACE OF A LIQUID 29 water to glass. Since we pull water away from water, we see that the cohesion of water is not as strong as the adhesion of water to glass. Cohesion in solids causes them to be rigid; that is, to resist being strained or broken. 31. The Surface of a Liquid. We know that large liquid surfaces are flat (horizontal) ; this is because grav- ity pulls down equally on all parts of the surface. But when the body of liquid is very small (a drop), the effect of gravity is also small, and cohesion is able to pull the liquid into the shape of a sphere. This is exactly the shape that would be produced if the liquid were enclosed in a tightly stretched, elastic covering, say, of rubber. The shape of a drop of liquid depends on cohesion alone, but a quantity of liquid in a vessel is acted upon by three kinds of force, and the shape of its surface will depend on all three. These are: (1) gravity, (2) cohesion of the liquid, (3) adhe- sion between the liquid and the material of the vessel. FIG. 23. Surfaces of Water (A) and Mercury (B). Let us take the case of mer- cury in a glass vessel (Fig. 23, B). Mercury does not wet glass. This means that the cohesion of mercury is greater than the adhesion between mercury and glass. Hence the surface of the mercury curves outwards, or is convex, like the surface of a drop. The case of water in a glass vessel is different (Fig. 23, A): water wets glass. This means that the adhesion between water and glass is greater than the cohesion of water. In such cases the liquid is drawn 30 FORCE AND ENGERY FIG. 24. A Needle Floating on Water. up at the edges, and the surface curves inwards, or is concave ("hol- lowed out"). In a greased vessel water has a convex upper surface, like that of mercury in a glass vessel. The cohesion of water is evidently stronger than the adhesion between water and grease. The curved surface of a liquid is called a meniscus. In reading the level of water in a graduated cylinder (Fig. 5) we read at the bottom of the meniscus. That the surface of a liquid acts as though it were an elastic covering, and that it can be stretched, is shown by an experiment in which a needle is floated upon water (Fig. 24). The needle must be put down carefully, or it will break the elastic surface of the water. The experiment suc- ceeds better if the needle is slightly greased, so that the water is certain not to wet it. 32. Capillary Action. If you leave one end of a towel in a bowl of water, the water rises, against gravity, into the towel. If you let a wet string, or> bet- ter, a wet strip of cloth, hang over the side of a dish of water (Fig. 25), the water will rise through the string or cloth, and so flow out of the dish. If you touch a drop of ink with a blotter, the whole drop will flow into the blotter. What causes these phenomena? We say that the force exerted in these cases is " capillary " FIG. 25. Water Flowing by Capillary Action Over the Side of a Dish. DENSITY AND SPECIFIC GRAVITY 31 B FIG. 26. A, Capillary Rise of Water; B, Capillary Depression of Mercury. action. "Capillary" means "hairlike." The phenome- non is so called because it is commonly studied in tubes of small diameter (Fig. 26). Capillary action in water is due to adhesion between the water and the capillary tube, and to the cohesion of the water, which produces an elastic surface. If the tube is a large one, the water is raised, but only at its edges, as in the case of water in a dish. The elastic surface cannot exert force enough to lift all the water in the tube. But if the tube is of small diameter a " capillary " tube the weight of the water in the tube is small, and the elastic liquid surface lifts the whole column of water up the tube. Water rises in a capillary tube until the weight of the water is just equal to the force exerted by the elastic surface. The upper surface of the water column in a capillary tube is still concave. If a glass capillary tube is placed in mercury (Fig. 26, B), the effect is the opposite of that in water, and we have a capillary depression instead of elevation. Water rises up between two glass plates held close together just as it does in capillary tubes. In the case of the blotter, cloth, string, etc., the fibers of the material are so near one another that the spaces be- tween them act like a multitude of fine tubes. 33. Density and Specific Gravity. If you were "hefting" a piece of wood and a piece of lead, you would say that wood is a light substance and lead a heavy one. In saying this you would not mean that a large board of 32 FORCE AND ENERGY wood is lighter than a small lump of lead, but you would mean that, taken volume for volume, wood is lighter than lead. This is the same as saying that the density of wood is less than the density of lead (Fig. 27). We have already learned that the mass of a body is the quantity of matter in it (c/. 20). We may now de- Gold. Lead. Copper. Aluminum. Coal. Wood. FIG. 27. Cubes of Different Volumes, but of Equal Weight fine the density of a body as the quantity of matter packed in a given volume of the body. To get the mass of a body we weigh it. To get the density of a body we divide its weight, in grams, by its volume, in cubic centimeters. mass (in g.) Density = volume (in c.c.) Suppose that a piece of marble weighs 5 g. and has a volume of 2 c.c. ; it is plain that 1 c.c. of the marble would weigh 2.5 g. We say that the marble has a density of 2.5 g. for each cubic centimeter. The den- sity of water is 1 g. for each cubic centimeter (c/. 14). In the Eng- lish system the density of water is about 62.5 Ibs. for each cubic foot. We often find the expression specific gravity used in place of density. We get the specific gravity of a body by dividing the weight of the body by the weight of an equal volume of water. Wt. of body Specific gravity = Wt. of equal vol. of water BUOYANT FORCE OF LIQUIDS 33 When the density of a body is given as so many grams for 1 c.c., the number representing the density is the same as the number for the specific gravity. 34. Buoyant Force of Liquids. If we attach a string to a block of wood, and lift the wood by the string, we need to put forth a muscular effort equal to the weight of the wood. But if we let the block rest on water, we do not put forth any effort; the water supports the block. We say that the block floats on the water. If we hold a piece of stone by a string, first in air, and then in water, we find that the stone is lighter (weighs less) in water than in the air. Here the water does not support all of the weight, but it does support part of it. It is well known that a stone can be lifted much more easily when it is under water than when it is out of the water. Suppose that some lead is cut or cast in the form of a cube having a volume of exactly 1 c.c., and is attached to one arm of a balance, as in Fig. 28. If we weigh it in air and then in water we shall find that it weighs 1 gram less in water than in the air. One cubic centimeter of iron, glass, or marble, or of any solid which is more dense than water, would lose the same amount 1 gram when weighed in water. Since the 1 c.c. of water displaced by each of the cubes weighs just what the cube seems to lose, we conclude that a body put under water is pushed, or buoyed, up by just the amount of the water it displaces. A mass of iron, stone, glass, etc., having a volume of a cubic foot would weigh 62.5 pounds less in water than in the air, since this is the weight of a cubic foot of water (cf. 33). FIG. 28. A Solid Immersed in a Liquid is Buoyed up by the Liquid. 34 FORCE AND ENERGY Not only water, but all liquids and gases, have this buoyant power. The more dense the liquid or gas, the greater is its power of buoyancy. Hence we may state the facts regarding buoyant force as a general rule : A body immersed in a liquid or gas is buoyed up with a force just equal to the weight of the liquid or gas it displaces. A floating body sinks into the liquid supporting it until it has pushed aside its own weight of liquid. Thus a piece of cork 34 as dense as water sinks until % of its volume is below water. A piece of ice 0.92 as heavy as water has 0.92 of its volume below water. A needle (cf. 31) has really a much greater density than water, but it can be supported on water because its weight is very small. As a result the elastic surface of the water does not break. If the needle becomes wet, the water surface breaks, and the needle sinks. 35. Center of Mass. Why does a slender stick which has been set upright fall over so easily? Why cannot we stand an egg "on end"? The answer is found in a study of the center of mass of a body. We all know what is meant by the center of a sphere: it is the point around which the volume of the sphere is arranged in a regular way. Let us call this cen- ter the center of volume of the sphere. Now, in a wooden ball or a lead ball the matter , as well as the volume, is all grouped around the center; so we can call the center of volume the center of mass, or center of gravity, of the ball. If we were to mix small fragments of lead and sawdust uniformly together, and pack thejn into a ball, the center of mass of the ball would still be the same as its center of volume. But if we were to make half of the ball of wood and the other half of lead, and were to fasten the two CENTER OF MASS 35 halves together, the center of mass of the ball would not be the same as its center of volume. Lead is so much denser than wood that the center of mass would be somewhere in the lead half of the / ball (Fig. 29). In /Lead wood\ an egg the center \ of mass is nearer \ the larger than the smaller end. A body IS in its The Ball Takeg Pogition (2) The Heavy Knife Handles (3) most ' ' Stable " pOSi- Bring the Center of Mass Below the Tip of the Pencil. tion, that is, is best able to stand, when the center of its mass is lowest, or nearest the earth's center. A ball of wood is at rest in any position, because its center of mass is as low in one position as in another, but a ball half wood and half lead will be in a stable position ' only when the lead half is the lower. An egg lies on its side but not on end because when it is on its side its center of mass is lower. To make it stand on end we would need to keep its center of mass exactly above the point at which it rests upon the table or other support. As we cannot do this, the egg rolls over. We ourselves stand when we keep the center of mass of our bodies above the space bounded by our feet, but we fall when we lean over so far that our center of mass is no longer vertically above this space. When an irregular body, such as a log or tree, lies on the ground, it cannot shift itself so that it can bring its center of mass to the lowest position, but if we float the body upon water, it turns over until it finds this position. 36. Summary. Gravitation is the pull, or attraction, existing be- tween all bodies of matter. Gravity is the earth's pull upon bodies at or near its surface. Grav- ity pulls vertically downward, that is, toward the earth's center. 36 FORCE AND ENERGY The mass of a body is the amount of matter in it. The amount of attraction between bodies depends on the masses of the bodies and on the distance they are apart. The weight of a body represents the earth's attraction, at any given place, for the mass of the body. A body weighs more at the earth's poles than at the equator, and more at the earth's surface than "up in the air." The mass does not change. In a vacuum all bodies fall with the same speed. If a falling body is acted upon by a horizontal force, its path is curved; but the time taken is the same as if gravity acted alone. Force is exerted on a body by the muscles of men and animals, by the earth (gravity), by the wind, by other bodies (as resistance or fric- tion), by expanding gases, etc. A body on which work has been done has energy, or the capacity for doing work on other bodies. There is energy of position and energy of motion. Work (against gravity) = weight X vertical distance. Power is the rate of doing work. Inertia is the helplessness of matter to alter its condition of rest or motion. "Centrifugal force" is the pull of matter, when revolving, against whatever holds it to the center. The force that is exerted between the particles of matter and holds matter together is called cohesion, or adhesion. The cohesion of liquids causes them to form drops, and to have elas- tic surfaces. The upper surface of a liquid that does not adhere to the vessel is like a flattened drop; that is, convex. If the liquid wets the vessel, the surface is concave. The cohesion of liquids and their adhesion to solids (wetting) causes the liquids to rise in narrow spaces or tubes. This is "capillary action." The density of a body or a substance is the quantity of matter in a .given volume. Pure water at 4 C. has a density of 1. Buoyant force is the supporting, or lifting, power of liquids and gases. EXERCISES 37 A floating body is entirely supported. An immersed body is sup r ported with a force equal to the weight of the liquid (or gas) displaced by the body. The center of mass of a body is the point around which the matter of the body is arranged. A body is in a stable position when its center of mass is directly over some part of the base on which the body rests. It is most stable when its center of mass is in the lowest possible posi- tion. 37. Exercises. 1. What is the chief force to be overcome when we drive a nail into wood? 2. Why does a drop of mercury on a table remain almost spherical, while a drop of water does not? 3. Why is it so hard to dry the hands on a new, unlaundered towel? Why is writing paper " filled" or " sized"? 4. Name the following substances in the order of their densities, beginning with the lightest (see Appendix, Table III): iron, cork, kerosene, lead, paraffin, aluminum, marble, zinc, gold, silver, copper, water, alcohol, and milk. 5. If one cubic foot of water weighs 62.5 Ibs., how much does a cubic foot of iron weigh? 6. How does the addition of a life preserver to a person's body alter the weight of matter that must be supported by the water? How does it alter the density? Why? .7. Why does a steel ship float? 8. We can find the volume of a body, such as a stone, if we weigh the body first in air and then in water. Explain how. 9. An iceberg may turn over after the part under water has melted for a time. Why? 10. How do you lean your body when you carry a pail of water? When you run forward? When you climb a hill? Why? CHAPTER III AIR AND FIRE 38. The Atmosphere. As we already know, the earth has a diameter of about 7,900 miles. By means of wells, of cracks in the earth, and of deep mines the solid surface has been studied to a depth of about 6,000 feet. This outer layer is called the crust to distinguish it from the unknown interior, or core. Filling the great hollows of the crust is a layer of water, which, if it were spread evenly over the crust, would cover all the land to a depth of about two miles. Finally, sur- rounding both land and sea is the ocean of gas the atmos- phere (Fig. 30) . The atmosphere extends outward from the crust an unknown distance, but most of it is within 50 miles of the earth's surface. Half of it is within four miles. The substance that makes up the atmosphere is air. Because air is a gas, and therefore difficult to handle, men looked upon it for a long time as a mysterious, un- knowable part of the earth. Only when men became used to the idea that air and other kinds of gaseous matter are not really different from solid and liquid matter was it 38 FIG. 30. Ideal Section of the Earth. Thick- ness of the outer layers greatly exaggerated. ATMOSPHERIC PRESSURE 39 possible for them to get a thorough knowledge of many of our common phenomena. We now know that the atmos- phere contains gases and living forms of great activity, and that these have very important effects upon the sub- stances and the living things of the earth's surface. Thus, the respiration, or breathing, of animals and plants, and the decay of all substances of animal and vegetable origin, are due to the air. So are the rusting, or tarnishing, of metals, and the phenomenon of fire, or burning. 39. Weight of Air. The atmosphere is drawn toward the earth's center as all other bodies are; hence air has weight (cf. 4). One liter of air ordinarily weighs about 1.2 grams. It takes a little over 4 liters (about a gallon) to weigh as much as a nickel five-cent piece; that is, 5 grams. We can get an idea of the weight of air in another way: A room 20 x 20 x 10 feet holds 4,000 cubic feet of air. One cubic foot of air weighs about 1M ounces; hence the air of the room weighs 4,000X1 M, or 5,000 ounces. Dividing this by 16 we get 312.5, the weight in pounds. 40. Atmospheric Pressure ; the Barometer. Because air has weight, it exerts pressure on all bodies in it, and on the earth, which supports it. That the atmosphere has pressure was first proved by Torricelli (pronounced Tor-ri-tchell-y), a pupil of Galileo, in 1643. Finding that no pump could lift water higher than 32 feet above the water of a well, he reasoned that this was probably the greatest height to which the atmospheric pressure could push a water column. If this were so, then a mercury 40 AIR AND FIRE FIG. 31. Filling a Barometer Tube and Inverting It in Mercury. column ought to be raised only about 1 / 13 as high, since mercury is about 13 times as dense as water. The apparatus Torricelli used to test his conclusion (Fig. 31) was a glass tube about a meter long and closed at one end. He filled the tube entirely with mercury, closed the open end with his finger, and inverted the tube in a vessel of mercury. When he removed his fin- ger, some of the mercury in the tube ran out, but it stopped when the level was about 29 inches (that is, */ of 32 ft.) above the mercury in the vessel. It did not fall lower because the pressure of the atmosphere held it up. We can also make a barometer out of a tube open at both ends, if we put one of the ends under mercury, and remove the air of the tube by means of an air pump. The mercury will rise about 30 inches, but not higher. The simple barometer is still made as Torricelli made it. The ver- tical distance between the top of the mercury in the tube and the mercury in the vessel is called the height of the barometer. The barometer height changes as the atmospheric pressure changes. Its average at sea level is about 760 mm. (30 inches) ; hence this is called standard pressure, or a pressure of one atmosphere. The space above ' the mercury is a vacuum. We can readily calculate the atmospheric pressure from the barom- eter height. If the column of mercury in the barometer is 1 square inch in cross section, and 30 inches high, it has a volume of 30 cubic, inches. Now, 30 cubic inches of mercury weigh about 15 Ibs. Hence the atmosphere presses down upon every square inch of matter at the earth's surface with a force of 15 Ibs. PUMPS 41 Height n Miles 35 Baro- meter n&es 41. Changes in Atmospheric Pressure. If you were at the bottom of a haystack, trying to work your way up through it, you would have the hardest time at the bot- tom, and the task would become easier as you approached the top. The reason is that the hay is most compact, or dense, in the lowest layers, since these layers have to bear the weight of all the hay above them. So it is with the atmosphere : its lower layers are crowded together by the weight of the air they support. That this is so is proved by the bwhavior of a barometer as we carry it up a mountain or up in a balloon. The mercury column falls more and more, showing that the density and the pressure of the air grow smaller as we ascend (Fig. 32). At a height of less than 4 miles the barometer height is about 380 millimeters, or 15 inches; hence half of the atmosphere is within four miles of the earth's surface. In a famous balloon ascent the barometer fell to 7 inches. The balloon was then about 7 miles above sea level, and had left more than three fourths of the air behind. When a barometer is carried down into a deep mine, the mercury column rises, because the density and the pressure of the air are greater there than at the surface. FlG - 32 - The density of the atmosphere grows less as we ascend. 42. Pumps. Pumps were used by man at least 2,000 years before Torricelli showed that their action is due to the pressure of the atmosphere. 15 10 42 AIR AND FIRE If we put the open end of a pipe under the water of a well or cistern, and remove the air of the pipe, the atmos- pheric pressure will raise the water into the pipe about 34 feet (cf. 40). In other words, the pipe and the well become a water barometer. The simple lift pump (Fig. 33) not only removes the air from the pipe, but lifts the water to the spout. It consists of a cylin- der in which a tightly fitting piston can be moved up and down by means of a handle. The cylinder is attached to a pipe, which extends into the water. The Lift Pump. I n the bottom of the cylinder there is a cylinder valve, which opens upwards so as to admit water from the pipe. There is also a valve in the piston. This, too, opens upwards, admitting water above the piston. When the piston is forced downwards, the water in the cylinder opens the piston valve and closes the cylinder valve. Some of the water of the cylinder then collects above the piston. When, now, the piston is raised, as in Fig. 33, the water above it closes the piston valve, and the water above the piston is discharged through the spout. At the same time the cylin- der valve is opened by the water below it, and more water is forced into the cylin- der. Thus the up and down strokes of the piston cause a more or less regular discharge of water from the spout. Force Pumps and Rotary Pumps. In the force pump (Fig. 34) the piston has no valve. When the piston is raised, water rises into the pipe and into the cylinder. When the piston descends, the water below it closes the cylinder valve, and water is forced out through the discharge FIG. 34. A Force Pump with Its Air Chamber. COMPRESSED AIR 43 Discharge valve. The pressure of the water in the discharge pipe compresses the air in the air chamber. When, now, the piston is raised once more, the discharge valve is closed by the pressure of the water in the discharge pipe; yet the stream of water does not stop flowing, because of the pressure of the air in the air chamber. The steam fire-engine is a good example of a force pump. A rotary pump (Fig. 35) consists of a wheel with inclined blades. The wheel is turned rapidly by an engine, and removes the air of a pipe dipping into water. The water is then raised by atmos- pheric pressure into the case in which the wheel revolves. The blades of the wheel force the water out through the dis- charge pipe. Since the rotary pump has no valves, it can pump water carrying grit and dirt, mate- rials which would clog a pump with valves. This fact makes it especially valuable for the draining of swamp lands, marshes, etc., and for pumping into canals and ditches the water that is to be used in irrigation, the artificial watering of land. 43. Compressed Air. -While an ordinary pump re- moves air from a given space, a compression pump (cf. 71) packs as much air as possible into a given space. A bicycle or automobile tire pump is such a pump. When compressed air is released, it expands, and, like other expanding gases, it can do work (cf. 24). Thus, a sand blast is a current of air released from pressure, and carrying sharp sand with great speed. If the sand strikes glass, it chips its surface, forming ground glass. If part of the glass is protected with wax, while the rest is exposed take] I 1 I Pulley FIG. 35. This rotary, or centrifugal, pump is driven by a belt placed over the pulley. 44 AIR AND FIRE to the blast, a design will be made on the glass. The blast is used to clean castings, and will even drill holes into steel. The pneumatic hammer is a hammer kept in rapid motion by com- pressed air. It is with this hammer that large pieces of steel, such as those of bridges and of the framework of largeuil bdings, are riveted together. compressed ci.r The air brake, which stops the motion of trains, is worked by compressed air stored in the locomo- tive. In making foundations for bridges and buildings men must often work under water. They can do this by going down in large caissons, or diving bells (Fig. 36). Compressed air is forced into the bell at sufficient pressure to keep the water from rushing in, and to give fresh air to the workmen. The used air bubbles out around the edge of the bell. A submarine boat is supplied with compartments which can be filled with water when the boat is to go under water. The boat also carries compressed air for forcing the water out when the boat is to rise to the surface. 44. Exercises. 1. What is the volume of the air in a room 40 x 25 x 9 ft.? Its weight in ounces? In pounds? 2. If the surface of a man's body is 2,600 square inches, what is the pressure, in pounds, of the atmosphere upon it? Why does not this weight crush the body? Diving Bell. FIG. 36. How men can work under water. COLLECTION OF GASES 45 3. If an elastic balloon holding 1 cu. ft. of gas at the earth's surface were to ascend until the barometer height is 15 in., would the volume of the gas in the balloon grow smaller or larger? Why? 4. Pouring a little water upon the piston of a dry pump is called "priming" the pump. Why does this help the action of the pump? 5. Explain why you can ''suck" lemonade through a straw or other tube. If the lemonade had the density of water, and you had the necessary strength, how high could you suck it? 45. Collection of Gases. When we wish to collect a gas for study, we must remember that so-called " empty 7 ' vessels are filled with air, and that to fill a vessel with another gas we must have some way of removing the air. One way is to " sweep out" the air by passing the other gas through the vessel for some time. Fig. 37 shows how we might fill a bottle with illuminating gas by sweeping out the air. We must use a large excess of the gas to make sure no air remains. FIG. 37. Collecting Gas by Displacement of Air and Air by Dis- placement of Water. A better way to get the air out of the collecting vessel is to fill the vessel with water. Then we close the mouth of the full bottle with the hand, or with a piece of cardboard, and set it, upside down, in a pan of water (Fig. 37). We must have the mouth of the bottle under water before we uncover it, or, as we well know, the water will fall out, and air will take its place. Now, if we wish to collect a bottle full of the air from the lungs, we can "blow" through a tube the end of which is 46 AIR AND FIRE placed under the mouth of the bottle of water. The air, being lighter than water, will displace the water of the bottle. We can fill a bottle exactly full of illuminating gas by attaching a "delivery tube" to the gas outlet, and allowing the gas to displace water in the same way. 46. Discovery of Oxygen. The phenomenon of fire, or burning, has fascinated men for ages, but what the air has to do with it no one understood until 1774. The explanation was given by Lavoisier, a French scientist, and was as important, in its way, as the explanation of gravity by Newton (cf. 18) ; for it was the beginning of modern Chemistry. Priestley, an English experimenter, had just prepared oxygen (Aug. 1, 1774) by heating a red powder which we now call mercuric oxide. Sunlight Mercury Oxide Oxygen Priestley's apparatus (Fig. 38) was a bottle filled completely with mercury, and inverted in a "bath" of the same liquid. He put the mercuric oxide under the mouth of the bottle; the oxide, being lighter, floated to the top of the mercury. He then brought sunlight to a focus (cf. 178) upon the mercuric oxide by means of a burning lens. The heat produced caused the red powder to disappear; but a colorless gas appeared in its place. When Priestley put into the gas a splinter with a glowing tip, the spark burst into flame. He also put a live mouse into the gas, and, to his sur- prise, it continued to live. Priestley called the gas "good air." FIG. 38. Priestley's Way of Getting Oxy- gen from Mercury Oxide. 47. The Air a Mixture. When Lavoisier heard of Priestley's discovery, he reasoned that the gas obtained by Priestley, which supported burning and life so much THE AIR A MIXTURE 47 Mercury better than air, must be present in the air. So he planned an experiment to prove that he was right. Lavoisier set up the apparatus shown in Fig. 39, putting some mercury in the glass retort. The drawn-out tube of the retort was bent so that it dipped into the pan of mercury. Over the end of this tube, and dipping below the mer- cury, was the bell jar. The air of the bell jar and of the retort was thus cut off from the outer air, and nothing but mercury could get into the apparatus. Lavoisier then heated the retort for 12 days. Gradually a red powder collected on the mercury in the retort. At the same time the atmospheric pressure pushed some mercury into the bell jar. This showed that the volume of air in the apparatus became smaller. When no further change took place, Lavoisier let the apparatus become cool, and found that only 4 / 5 of the air remained. The air that was left "put out" a burning candle, and mice could not live in it. So Lavoisier reasoned that the active part of the air was removed by the heated mercury, and that it makes up about 1 / 5 of the air. FIG. 39. Lavoisier's Experiment. Heating Mercury in a Confined Portion of Air. When Lavoisier heated the red powder that had collected in the retort, he obtained all the gas that had been lost by the air. When he applied to this gas the tests which Priestley had used for his "good air/' he obtained the same results as Priestley. Lavoisier had thus proved that the air consists of two substances, one of them active, and able to support burning and life; the other, inactive. The active gas is oxygen; the inactive one, nitrogen (cf. also 54). 48 AIR AND FIRE 48. Burning and Oxidation. Many metals besides mercury unite with the oxygen of the air. Thus, iron rusts at the ordinary temperature. Hot, melted lead, if stirred so that a fresh surface of it is kept exposed to the air, is gradually changed to lead oxide, a yellow powder. Tin is changed in the same way to tin oxide, a white pow- der. Zinc and magnesium burn with bright flames to give their oxides. Powdered magnesium is burned to give the light for "flash light " photographs. If we weigh a quantity of any one of these metals, and then weigh the oxide formed, we always notice a gain in weight; this is due to the oxygen that is taken up (Fig. 40) . The uniting of a substance with oxygen is called the oxidation of the substance, and the substance is said to be oxidized. Burning is also called combustion, and a substance that can burn in the air is called a combustible sub- stance. But burning is not differ- ent from other oxidation : it is oxidation which is so rapid that heat and light are given off. The phenomenon of burning was mysterious for so long a time because the matter of a burning body seems to be destroyed. This is because most of our common combustibles, such as wax, coal, wood, and paper, give invisible gases when they burn (Fig. 41). Of course these escaped unnoticed (cf. 38). FIG. 40. A burning body takes up oxygen from the air, and gains weight. 49. Flames. There is a difference in the way in which substances burn: some have a large, bright flame; TO PREPARE OXYGEN 49 while others, like charcoal, merely glow. The explanation is simple. A flame is a burning gas. Substances that do not give off gases when burning do not have flames. In fact, coke and charcoal are the material that is left when the gaseous part of coal and wood, respec- tively, is driven off by heat (cf. 117 and 124). When a candle burns (Fig. 42), a little of the wick is consumed in melting the wax; then the FIG. 41. melted wax is drawn, by capillary action (cf. 32), Burni s?ov e a al up the wick into the flame. The heat of the burn- ing wick changes the liquid wax into a gas, or vapor, and this burns with a flame, producing heat and light. The flame itself is merely the region in which oxidation is taking place. The materials burning in the flame are constantly changing, but they are constantly renewed; hence the flame has a somewhat definite shape and size. 50. To Prepare Oxygen. Since oxygen is the active element of the air, we cannot pre- pare it by simply removing the nitrogen. We can, however, capture the oxygen by means of some such substance as hqated mercury (cf. 47). By heating the mercury oxide that is formed to a higher temperature we can get the oxygen by itself. Mercury and oxygen (at about 350 C.) give mercury oxide. Mercury oxide (at about 380 C.) gives mercury and oxygen. This is what Lavoisier actually did. In the laboratory, oxygen is generally made by heating potassium chlorate. This is a white solid which melts 50 AIR AND FIRE FIG. 43. The Common Way of Preparing Oxygen. when heated, and foams, or "effervesces," as the oxygen passes off. If a small amount of iron oxide (rust) is mixed with the potassium chlorate when it is heated, it gives off its oxygen more easily. The substance manga- nese dioxide, a black solid, has the same effect. The apparatus required for making oxygen is shown in Fig. 43. A test tube contains the mixture of powdered po- tassium chlorate and manga- nese dioxide. The delivery tube is attached "gas tight" to the test tube by means of a rubber stopper. The test tube is then heated with a very small flame, and the oxygen given off is collected over water in the bottle. When the bottle is full of oxygen, it is stoppered, or covered with a glass plate, and set, right side up, on the table. A still easier method of mak- ing oxygen is to let a solution of hydrogen peroxide drop into a flask (Fig. 44) upon some crys- tals of potassium permanganate just covered with water. 51. Properties of Oxy- gen. With the bottles of oxygen made as directed in 50 we can study the properties of oxygen. Potassium Permanganate and Dilute Sulphuric Acid FIG. 44. Another Way of Preparing Oxygen. (1) In the first place, we can test a bottle with a glowing splinter (the test used by Priestley). (2) Iron does not burn readily in air, but it burns in oxygen. This may be shown as follows (Fig. 45): OXYGEN AND LIFE 51 FIG. 45. Burning Iron Wire in Oxygen. Sand is put into one of the bottles of oxygen, so that the bottom is completely covered. Then a bundle of fine iron wires (picture cord) is tipped with a little sulphur, or with a splinter of wood. The sulphur (or wood) is lighted, and the wire is put into the bottle of oxygen. The burning tip heats the iron to its "kindling temperature," so that it burns brilliantly in the oxygen. Iron oxide is formed, as in rusting. The melted oxide collects as a drop upon the end of the wire, or falls into the bottle. The sand is used to protect the bottle from the hot iron oxide. (3) Sulphur, which burns with an almost invis- ible, blue flame in the air, burns with a brilliant, violet flame in oxygen. The sulphur is held in a "combustion spoon" (Fig. 46), and is melted and lighted in a burner before being put into the oxygen. The product formed is sulphur dioxide, the same choking gas that results when sulphur burns in air. (4) Charcoal burns in air with a faint glow; but in oxygen it burns vigorously, giving off a brilliant light. The charcoal is held by means of a copper wire, or in a combustion spoon, and is ignited in a flame before being put into the oxygen. The product is the color- less gas, carbon dioxide. If we put " lime water " (cf. 127) into the bottle in which charcoal has been burned, the lime water and carbon dioxide unite to form a white, insoluble solid which makes the lime water look "milky." In a bottle of pure oxygen or air, lime water is not changed. Oxygen dissolves slightly in water. Like air, of which it forms a part, oxygen has no color, odor, or taste. 52. Oxygen and Life. Oxygen forms a part of all living things, and an abundant supply is needed to main- tain life. The process of getting oxygen in contact with the tissues of an animal or plant is called respiration. FIG. 46. Burning Sulphur in Oxygen. 52 AIR AND FIRE Respiration consists both of breathing, which is performed for the higher animals by lungs (cf. 343), and also of the actual oxidation that takes place throughout the body. A grown man takes in (" inspires") about 350 cubic feet (10 cubic meters) of air in a day. The purpose of respiration is to get the oxygen of the air to combine with the materials of the body that are constantly wearing out, and to oxidize them (cf. 48) to substances that the body can get rid of. Since this worn- out matter, like the body itself, is largely made up of carbon and hydrogen, it is changed chiefly to carbon dioxide and water when oxidized (cf. 51 and 105). The oxidation within the body is not an actual burning; but it produces heat. This heat keeps the bodies of animals warm. In man the normal temperature is 98.6 Fahren- heit, or 37 Centigrade (cf. 63). In certain diseases the lungs are not able to get oxygen rapidly enough from the air; so pure oxygen is used. Water animals depend upon the oxygen dissolved in natural water. Fishes, clams, etc., take in oxygen through their gills (cf. 337 and 341). In the gills the same ex- change of carbon dioxide for oxygen takes place as in the lungs of higher animals. 53. Exercises. 1. How can you show that the expired breath contains water? Carbon dioxide? 2. Give the dates of the birth and the death of Priestley and of Lavoisier. What did each do for science? (See Glossary.) 3. What substance is used to polish stoves (cf. 119)? How does it prevent rusting? What other materials are used to cover iron to prevent rusting? HOW NITROGEN IS PREPARED 53 4. Why do we use, first, paper, then wood, and then coal in starting a coal fire? 5. Why are oxides used as fire-proofing materials? 6. Compare the composition of the air that enters at the bottom of a stove with that which passes out into the flue. 7. Why does a kerosene lamp need a wick? Why a chimney? 8. Why does a blanket or rug put out a fire? Why does water? 9. When a gas is collected over water, why does the gas force the water out of the bottle? 54. How Nitrogen is Prepared. One method of pre- paring nitrogen is to remove the oxygen from air. We may remove the oxygen, as Lavoisier did, by means of heated mercury; but an easier way is to burn phosphorus in a bottle or jar of air (Fig. 47). A small heap of red phosphorus is placed in the middle of a thin slice cut from a cork about three fourths of an inch in diameter. A wire pushed into tfye cork supports it. To hold the wire upright, we stick it into a rubber stop- per, placed, large end downward, on the bottom of a pan of water. The water is about two inches deep. The phosphorus is lighted, and the jar of air (a fruit jar does very well) is immediately placed over the burning phosphorus, and pressed tightly against the bottom of the pan. After the phosphorus has burned for a moment, the hand may be removed. Water rises into the jar to take the place of the oxygen used up. The white smoke is phosphorus oxide. The jar is left until the smoke has entirely disappeared (it dissolves in the water) ; then a piece of glass or cardboard is slipped under the jar, and the jar is set upright on the table. A burning splinter "goes out" when put into the jar. If too many bubbles did not escape when the jar was put over the FIG. 47. Burning Phosphorus in a Jar of Air Over Water leaves Nitrogen. 54 AIR AND FIRE phosphorus, the volume of water that enters the jar, and, therefore, the volume of the oxygen, will be about one fifth of the volume of air in the jar at first. Nitrogen made in this way contains argon, a gas even more inactive than nitrogen itself. Argon makes up almost one per cent, by volume, of air. Perhaps the most convenient way to get a 250 c.c. bottle of nitrogen is to heat carefully a solution of 5 g. of sodium nitrite and 5 g. of ammonium chloride in 100 c.c. of water. The nitrogen escapes, and is collected over water. 55. Properties of Nitrogen. Unlike oxygen, nitrogen does not unite readily with other substances, and does not support burning and life. It dilutes the active oxygen of the air. Nitrogen is somewhat lighter than the air, and is very slightly dissolved by water. Like oxygen, it is colorless, tasteless, and odorless. Nitrogen finds it hard not only to unite with other substances, but also to hold its place in many substances that contain it. As a result of this property it is made a part of all our common explosives, such as gunpowder, nitroglycerine, guncotton, etc. These are all substances that hold nitrogen loosely. When the explosive is set on fire, or is given a "shock" (cf. 24), the nitrogen is set free as a gas under great pressure, and in expanding does the work required of the explosive. 56. Nitrogen and Life. The properties and uses of nitrogen described in preceding sections are due to the fact that it has little activity, or little power of uniting with other substances. But nitrogen is important also because of certain positive qualities: it forms a necessary NITROGEN AND LIFE 55 part of proteids, or albumins, materials needed by all living cells. Nitrogen is, therefore, a necessary part of all animals and plants. The proteids make up a large part of such food as meat, eggs, cheese, and milk. Animals cannot make their own proteid; they must get it by feeding upon plants. Plants make proteids out of the carbon, hydrogen, oxygen, nitrogen, etc., which they ob- tain from the soil and the air. Now, most plants can take up nitrogen only when it is a part of certain compounds dissolved in the water of the soil. Hence soils must con- tain nitrogen compounds to be fertile. While most plants can make proteids only out of nitrogen com- pounds present in soil, some plants seem to take up nitrogen directly from the air. Such are beans, peas, clover, and alfalfa. It has been found that the plants named have this power because " colonies" of bacteria very small plants (cf. 324) find a home upon their roots. It is the bacteria that take the nitrogen out of the air, and build it into the complex albumins upon which the beans, etc. feed. But the bacteria produce not only enough proteid for the beans, etc., but they produce an excess of it, and leave it in the soil. Be- cause they themselves contain so much proteid, beans, peas, and clover are valu- able as food for man and animals; but they are even more important because they, or, rather, the bacteria growing upon them, are the means of bringing into a soil the nitrogen it needs for other plants. As all farmers know, clover is grown in a field, and " ploughed under," to enrich the soil for crops of grain. Artificial fertilizers, containing nitrogen com- pounds, are often added to the soil for the same purpose. TUBCffCLE FIG. 48. A Clover Plant with its Tubercles. 56 AIR AND FIRE FIG. 49. A Dewar Bulb for Holding Liquid Air. 57. Liquid Air. In the liquid form air is colorless, and has about the same density as water. It is composed of liquid oxygen and nitrogen. Liquid air is constantly evaporating; to prevent explosions we keep it in open vessels called "Dewar bulbs," from the inventor (Fig. 49). They have double walls, and the air is removed from the space between the walls, so that heat from the outside cannot affect the liquid within. The walls of the bulbs are silvered for the same reason. "Thermos" and "Caloris" bottles are made on the principle of Dewar bulbs, to keep a cold liquid from getting warm and a hot liquid from getting cool (cf. Ex. 12, 68). Air is made liquid at a low temperature by great pressure. It boils at about -190 C. (Fig. 50). Alcohol held in liquid air becomes solid, like ice. Mercury is changed to a hard metal, and may be used as a hammer head, to drive nails. A rubber ball put into liquid air be- comes brittle, and flies into fragments when thrown on the floor. A piece of meat be- haves in the same way. Liquid air that actually wets the skin burns it like white- hot iron; yet the hand may be put into the liquid for a moment without injury, because a layer of gaseous air covers the hand like a glove. FIG. 50. Liquid Air Boiling on Ice. 58. How the Atmosphere is Puri- fied. Since the air receives impurities from the breathing of animals and plants, from all burning, and from all decay, why does it not become foul, and unfit to breathe? HOW THE ATMOSPHERE IS PURIFIED 57 The answer is that the impurities are constantly being removed. The wind scatters foul air, and mixes it with fresh air from the country, the mountains; and the sea. The rain washes out impure gases, dust, smoke, and bacteria, or germs. Sunlight destroys many bacteria that produce disease. Other bacteria bring about the oxida- tion of dead organic matter, and so destroy it. Plants use up the carbon dioxide cast off by animals, and give back oxygen in its place (cf. 309). 59. Summary. The atmosphere is the gaseous ocean that forms the outer layer of the earth. Air is the substance that makes up the atmosphere. Air is matter, for it takes up space, and has weight, inertia, etc. The pressure of the atmosphere is due to the weight of the air. It is measured by the barometer, and is equal to about 15 Ibs. for each square inch of surface at sea level. The pressure becomes less as we go up a mountain, and greater as we go down into a mine. The lift pump is a device for removing the air that is over a liquid, so that atmospheric pressure will raise the liquid. Its limit is about 34 feet for water, and 30 inches for mercury. Compressed air, like other compressed gases, can do work when it expands. Gases are " collected " by displacement of air or water. Priestley discovered oxygen in 1774 by heating mercury oxide. Lavoisier proved that air consists of two substances, oxygen and nitrogen. Oxygen makes up about one fifth, by volume, of air. Burning in air is union with oxygen, or oxidation. Oxidation may be slow, as in rusting and decay, or rapid, as in burning. A flame is a burning gas. Oxygen is prepared by heating mercury oxide or a mixture of potassium chlorate and manganese dioxide, or by putting hydrogen peroxide with potassium permanganate. Oxygen is colorless, tasteless, odorless, and slightly soluble in water. 58 AIR AND FIRE Bodies that burn slowly in air burn vigorously in oxygen. Oxygen is a part of all living things. Respiration consists of breathing and of oxidation. The heat pro- duced in the oxidation keeps the body warm. Water animals use the oxygen that is dissolved in water. Nitrogen is made from air by removing the oxygen. It is also made by heating a solution containing ammonium chloride and sodium nitrite. Nitrogen is colorless, tasteless, odorless, lighter than oxygen, and inactive. Nitrogen is held loosely in many substances, and is set free from most explosives. Nitrogen is necessary to life, since it is a part of proteids. Proteids are made by plants. Clover, beans, etc., support colonies of bacteria that make proteids out of nitrogen and other materials. Liquid air is a mixture containing liquid nitrogen and liquid oxygen. Most substances change their properties when exposed to it, owing to its low temperature. The atmosphere as a whole does not become unfit for breathing because of the winds, ram, sunlight, oxidizing bacteria, and plants. 60. Exercises. 1. How can you tell a bottle of air from one of oxygen? One of air from one of nitrogen? One of nitrogen from one of carbon dioxide? 2. What gases do plants take from the air? Animals? What gas does each restore to the air? 3. If the cover of a fruit jar has an area of 5 square inches, and the jar is empty (a vacuum), how great a weight must I lift to get the cover off, not counting friction? 4. Why does the air seem so refreshing after a rain or a snowfall? Why should sunlight and air be admitted into the rooms in which we live? Fio. 51. Metal Ball and Ring. CHAPTER IV HEAT 61. Heat and Matter. It is a familiar fact that most bodies increase in volume as they grow hot, and shrink as they grow cold. Thus, a brass or iron ball (Fig. 51) which just goes through a ring when cold will not go through it when hot. If, however, the ring, as well as the ball, is heated, then the ball will go through it. A liquid, like water or mercury, which just fills a flask at the tem- perature of the room, 'overflows when heated, but does not fill the flask when cooled. A gas behaves in the same way. Thus, if a flask of air is heated (Fig. 52), some of the air escapes; but the volume of the air contracts when the flask is cooled. How can we explain these changes of volume? It is hard to see how the volume of a body can change unless the matter of the body is broken up into particles, with spaces between them. Then, if the volume becomes smaller, as is the case when a body is cooled, we Heating expands air" cooling makes it shrink. Can explain the shrinkage FIG. 52. 60 HEAT by saying that the particles are crowded closer together. Scientists believe that matter really consists of such particles, and call them molecules, or " little masses." The molecules are believed to be in motion. Each molecule needs a portion of space in which to move about; hence the volume of a body is the sum of the spaces needed by all the molecules, in addition to the vol- umes of the molecules themselves. The motion of the molecules is heat. When we add heat to a body, each molecule moves more rapidly, and pushes its neighbors farther away. Because of this the distance between molecules becomes greater, and the volume of the body increases. We assume that when bodies expand and contract the volumes of the molecules remain unchanged. The molecules are very small. Scientists estimate the number of molecules in 1 c.c. of a gas as about 27 million million millions (27,000,- 000,000,000,000,000). 62. Thermometers. We make use of the expansion and contraction of matter in the thermometer, the instru- ment with which we measure temperature. The common thermometer consists of a glass tube having a bulb at one end. The bulb and part of the tube contain mercury. The inside of the tube is of a very small bore, so that if the mercury expands only a very little in the bulb, it will make a great difference in the length of the mercury "thread" inside the tube. Glass expands when heated, as well as mercury, but only y 7 as much; hence the ex- pansion we see in a thermometer is the difference between the expansion of mercury and that of glass. When a thermometer is made, the end of the tube is open, and there is enough mercury to fill the bulb and a little of the tube. The instru- THE TWO THERMOMETER SCALES 61 ment is then heated, so that bulb and tube are completely filled, and the open end is sealed by melting the glass. The thermometer is then graduated, that is, the "degree" marks are put on it. First the bulb is put into melting ice (Fig. 53), and the point at which the mercury comes to rest is marked the freezing point. Then water is made to boil under " standard pressure" (cf. 40), and the bulb is put into the steam that comes off (Fig. 54). The place at which the mercury stops is called the " boiling point" mark of the thermometer. FIG. 53. Getting the Freezing Point of a Ther- mometer. FIG. 54. Getting the Boiling Point of a Ther- mometer. 63. The Two Thermom- eter Scales. The differ- ence between the two common thermom- eters the Fahrenheit and Centigrade thermometers is in the number of de- grees that are put between the freezing point mark and the boiling The maker of the Centigrade He divided the space point mark, instrument was Celsius. between the two marks into 100 degrees (Fig. 55). "Centigrade" means just that: "100 degrees" or "steps." Celsius made the freez- ing point of his thermometer 0, and the boiling point 100. If the thermometer tube is of the same bore throughout, and a new mark is made as far above 100 as is below it, the new mark will be 200. In this way the other marks of the thermometer are fixed. The Fahrenheit thermometer is named from The Fahrenheit its maker, who took for his the temperature lcfi entigrade 62 HEAT produced by a certain "freezing mixture" (cf. 93). The melting point of ice, on the Fahrenheit thermometer, is 32, and the boiling point of water 212. The number of degrees between 32 and 212 is 180; consequently 100 Centigrade degrees equal 180 Fahrenheit degrees. Each Fahren- heit degree is, therefore, 5 / 9 of a Centigrade degree, and each Centi- grade degree is 9 / 5 of a Fahrenheit degree. If we multiply the number of degrees shown by a Centigrade thermometer by 9 / 5 , and then add 32, we get the Fahrenheit reading. Fahr. = (Cent.X 9 A)+32. If we subtract 32 from the Fahrenheit reading, and then multiply the remainder by 8 / 9 , we get the Centigrade reading. Cent. = 5 / 9 (Fahr. 32) . The Centigrade scale is used almost everywhere on the continent of Europe, and practically everywhere, the world over, for scientific work. For temperatures below 39.1 C., such as are found in the Arctics, alcohol is used instead of mercury (cf. 57). 64. Temperature and Heat. We must know the difference between quantity of heat and degree of heat. We know whether a body is hot or cold, generally speak- ing, by its degree of heat, that is, its temperature. The temperature of a body depends upon the rapidity with which its molecules are moving, and not upon whether there are many molecules or few. But the heat which a body possesses depends upon the speed of the molecules and also upon the number of molecules, that is, upon both the temperature of the body and its mass. We shall see later ( 73) that it also depends upon the substance of which the body is composed. The unit of heat quantity is called a calorie, just as the unit of mass is called a gram. A calorie is the amount of heat needed to warm 1 gram of water 1 C. It is also the amount given off by 1 g. of water CONVECTION 63 when its temperature falls 1 C. So 1 g. of water in cooling from 100 C. to C. gives off 100 calories of heat. The same amount is given off when 2 g. of water are cooled from 50 C. to C., and when 10 g. are cooled from 10 C. to C. 65. Ways of Distributing Heat; Conduction. If a flat-iron is placed on a stove, the iron becomes warm, because heat (motion of molecules) from the stove is given to it. If you touch the flat-iron, it gives some of its heat to the hand; hence the iron feels warm. The heat has been conducted, first from the stove to the flat-iron, then from the flat-iron to your skin. But if you hold a piece of ice in your hand, the hand becomes cold, because heat is conducted from your hand to the ice. So the objects you handle are either hot or cold according as they give heat to the hand, or take it from the hand. The handle of a flat-iron can still be held comfortably after the bottom is hot; but in a short time the handle, also, is heated by con- duction from the part nearer the stove. To hold it then, we use a non- conducting handle of cloth or of wood. It would take longer to heat a brick from the bottom to the top, because it is a poorer carrier, or conductor, of heat. Metals are the best heat conductors; air is probably the poorest. Water, wood, and paper are poor conductors. Conduction is only one of the ways in which heat is distributed; other ways are by radiation and by convection. 66. Radiation. If you stand near a stove, you become warm without touching the stove. Heat is radiated to you from the stove. If you are near a block of ice, you become chilled, because your body is radiating heat to the ice. Heat reaches the earth from the sun by radiation through space. 67. Convection. Convection is not really a new way 64 HEAT of distributing heat, but depends on the other two ways. The air near a stove becomes heated by conduction and radiation. As a result it expands, and becomes lighter. While a cubic foot of air at 32 F. (0 C.) weighs about 1.2 oz., at 80 F. (27 C.) it weighs 1.1 oz. The lighter air then rises to make room for the cooler air, which flows in to take its place (Fig. 222, 274) . Thus ' ' convection currents " are set up, and the air rises while it is warm and descends again when it has become cooled. ' ' Hot air " furnaces heat our houses (Fig. 56) because the warmed air flows upward through the "registers " to make room for the cold air taken in at the bottom of the furnace (' ' cold air intake" ;c/. 248). Fio. 56. Convection Currents from a Furnace. When air is cooled, convection currents are also set in motion. Because of its greater density the cold air falls, and warm air flows in to take its place. Hence in ice-boxes (Fig. 57) the waste water is not allowed to drop directly into the air, but is controlled by a "trap" which permits only the waste water, and not the cold air, to flow out at the bottom of the refrigerator. Convection currents can also be seen when a liquid is heated and cooled, if bits of paper or sawdust are put into the liquid. Hot water heating of houses de- pends upon such currents (cf. 243). Convection currents, and the fact that water is most dense at 4 C., prevent the freezing of lakes and rivers except near the surface (cf. 87). FIG. 57. Trap in an Ice-Box, to Pre- vent Cold Air from Falling Out. PHYSICAL STATES OF MATTER 65 68. Exercises. 1. When the glass stopper of a bottle "sticks," we can often loosen it by heating the neck of the bottle. Why? 2. If you heat water in a thick glass bottle over a flame, the bottle usually breaks, while a thin glass flask does not. Why? 3. Why do telephone wires sag in summer and become taut in winter? 4. Alcohol boils at 78 C.; what temperature is this on the Fahren- heit scale? The room temperature is 70 F. ; what is this on the Centigrade scale? 5. How could you make an air thermometer, that is, one using the expansion of air instead of that of mercury? 6. Which feels colder in a room, oilcloth or carpet? Wood or metal? Is there any real difference of temperature? Explain. 7. Why can ice cream be carried in a paper box through heated air, and yet not melt? Would a tin box be better? 8. Which feels hotter, the handle of a silver spoon, or that of an iron spoon, if the bowl of each is in boiling water? Why? 9. Why does air enter a stove at the bottom, and go out at the top? 10. Where should steam pipes be put to heat a room? Where should pipes of cold water be placed in a cold storage room in order to cool the room? 11. Why are houses built with double walls having air spaces be- tween them? 12. How is a "fireless cooker" made? Why is the heat not given off? How is it like a Thermos bottle (cf. 57)? 69. Physical States of Matter; Solids. If we believe that matter is broken up into molecules ( 61), we can understand the differences between solids, liquids, and gases, the three physical states, or forms, of matter. The two causes at work upon the molecules are cohesion and heat. Cohesion represents the attraction of the molecules for one another; heat is the motion of the molecules. Cohesion draws the molecules together; heat causes them to fly apart. 66 HEAT In a solid, like ice or sulphur, the cohesion between the molecules greatly overbalances the motion of the mole- cules; therefore a solid has a definite form. Usually a solid forms crystals (cf. 95). When solids are melted, their temperature does not rise during the melting; but the heat added is used up in overcoming cohesion. Thus, when ice at C. is brought into a room at the ordinary temperature, the ice melts; but its temperature remains C. until all of the ice is melted. If the ice and the water formed by its melting are stirred thoroughly, the temperature of the water also remains C. until the ice disappears. The reason is that the heat which the ice receives from the room is used up in melting the ice instead of in raising the temperature of the water or the ice. To change a gram of ice at G. to water at G. requires as much heat as to warm a gram of water from C. to 80 C., that is, 80 calories of heat. All the heat taken up by ice in melting is given off again when water freezes. The heat that is given off by tubs of freezing water is used to keep vegetables from freezing. The temperature in the vegetable cellar cannot fall much below C. until all the water is frozen. The vegetables themselves do not freeze at C. 70. Liquids. We know that liquids are different from solids in one important way: they have no definite shape, but take the shape of the vessel that holds them. We explain this by saying that the heat, or motion, of the molecules of a liquid is greater than in the case of a solid; so that cohesion cannot keep the liquid molecules in any particular order or arrangement. Most liquids contract, or grow smaller in volume, when GASES 67 they freeze. Water is an exception: 100 c.c. of water at C. become 109 c.c. of ice at C. On this account water pipes often burst in winter, and water that freezes in the cracks of rocks breaks the rocks in pieces (cf. 289). Metals that have about the same volume when solid as when liquid can be used to make castings; for the casting will then fill the mold completely. Cast iron, type metal, and brass are metals of this sort. But gold and silver, which shrink when they become solid, cannot be cast; they must be stamped, or " minted." When a liquid becomes a gas, or vapor, an enormous increase in volume takes place. Thus, 1 c.c. of water at 100 C. becomes about 1,200 c.c. of steam at 100 C. Engineers express this by saying, "A cubic inch of water gives a cubic foot of steam." The heat taken up in changing a gram of water at 100 C. to steam at 100 C. is 536 calories (cf. 64). The same amount of heat is set free when a gram of steam at 100 C. is condensed to water at 100 C. Hence a scalding from steam is much more painful than one from hot water. When a liquid is evaporating rapidly, it is always a little colder than the surrounding air. In tropical countries people take advantage of this fact to cool their drinking water. The water is put into porous jars. A little of the water goes through the jar, and by its evaporation on the outside cools the jar and the water in it. 71. Gases. Gases do not have either a definite shape or a definite volume. The volume of a gas depends upon its temperature (cf. 61) and its pressure (cf. 41). Cohesion between the molecules of a gas is slight, because the molecules are so far apart. Because of the motion of its molecules, a gas placed in a vacuum expands, until it fills the vacuum. If we force the molecules of a gas closer together, we 68 HEAT TO BICYCLE FIG. 58. Bicycle Pump. When the handle is raised, air en- ters around the piston. are working against the energy of the molecules. There- fore the compression of a gas liberates heat. This is illustrated in the compression pumps (Fig. 58) used to fill the tires of bicycles and automo- biles. They become hot. Since compressing a gas heats it, expansion cools it. The air rising from the earth in con- vection currents ( 67) is cooled as it ascends. This is because its volume increases as the atmospheric pressure becomes smaller. The heat needed to increase the volume of the rising air is taken from the air itself. In the balloon ascent described in 41 the temperature at 7 miles height was 60 F. To change a gas into a liquid we can (1) force the molecules together by increasing the pressure; or (2) make the motion of the molecules smaller by lowering the temperature (Fig. 59); or (3) combine both methods. The liquefying of air requires both a very low temperature and a great pressure. The method consists, first, in compressing the air greatly in long tubes; then in re- moving the heat produced by the com- pression; and, finally, in allowing some of the compressed air to expand. The heat needed to produce the expansion comes from the air that is still under pressure. The removal of this heat cools the air until it condenses in drops of liquid. S'ulphur Dioxide VSulphur Dioxide FIG. 59. Liquefying Gaseous Sulphur Dioxide by Cooling It. 72. Kindling Temperature. All of us know that fires must be "started" by some hot or burning body. The temperature at which a substance begins to burn is called its kindling temperature. A piece of iron picture THE MEASURING OF HEAT 69 cord will burn in oxygen (cf. 51), if tipped with burning sulphur to start the action. A match consists of several substances, each of which is used to kindle another sub- stance having a higher kindling temperature. Friction ignites the phosphorus, the burning phosphorus ignites the sulphur, and the burning sulphur sets the wood on fire. A stick burns from one end to the other, each part giving out enough heat to ignite the part next to it. 73. The Measuring of Heat. While the thermometer is the instrument for finding the degree of heat of a body, the calorimeter is the instrument by means of which we get the amount of heat in a body (cf. 64). We measure this amount by finding out how much heat the body can give to a certain weight of water. The simple calorimeter is a metal vessel (Fig. 60) with polished sides. A covering of felt (a non-conductor) prevents the air from taking heat away from the vessel, or FIQ 6Q adding heat to it. Suppose that we wish to A simple eter Surrounded find out which holds more heat at the same by a Non-con- ductor. temperature, lead or iron. We put into the calorimeter a known weight of water, at room temper- ature, let us say. We then put into the water 10 g., say, of lead having a temperature of 100 C. The hot lead gives heat to the water, until the water and the lead have the same temperature. A thermometer, kept in the water, tells us how many degrees the temperature of the water has been raised. We now put into the calorimeter another portion of water of the same weight as before, 70 HEAT get its temperature, and add 10 g. of iron having a temperature of 100 C. In this case the temperature of the water rises more than 3 times as far as when lead was used. This shows us that the iron has more than 3 times as great a heat capacity, or specific heat, as the lead. (See Appendix, Table VII.) The calorimeter has very important, practical uses. A factory using a large amount of coal needs to test different kinds of the fuel (cf. 15), in order to find which one gives the most heat for the least money. The worker in Domestic Science wants to know how much heat the different kinds of food, such as butter, potatoes, beef, and fish, will give out in our bodies (cf. 74). In this way he can get an idea of the values of these foods. The heat that can be obtained from both the coal and the food is found by burning them in a calorimeter. A calorimeter such as is needed to give the heating value, in calories, of a fuel or a food (Fig. 61) is more complicated than the simple calorimeter, but the principle according to which it " works" is the same. Some of the fuel or food is burned in an inclosed space containing com- pressed oxygen, or some oxidizing substance (cf. 48), and the heat given off is imparted to a known weight of water. From the increase in the temperature of the water the calories of heat given off can be calculated. FIG. 61. 74. Heat and Life. A healthy man has a temperature of 98.6 F., or 37 C. This does eter. By means , -, . , , . . of it we find the not change, day or night, summer or winter, amount of heat 1 1 .. . _ , given off in burn- although the temperature oi the air may vary 50 F. in a day, and 150 in a season. The body is warmed by the changes (oxidations) of its own cells and of digested food. We have seen (cf. 25) that energy is the capacity for doing work. The body is CLOTHING 71 FIG. 62. Distribution of Heat Obtained from Food. thus a complex engine, using its changes to produce heat, and to enable it to do work. It has been calculated that about 3 / 4 of all the heat produced in the body is used to heat the body (Fig. 62). A day's work requires about 3 /ie, respiration about 1 / 6 o, and the heart about 1 /ie. While the oxidation changes are much greater in some organs than in others, the heat is carried away by the blood as fast as it is produced. Hence the temperature does not vary in any two parts as much as half a degree Fahr. The skin is, of course, cooler than the rest of the body, both because it is exposed to the air, and also because it is cooled by the constant evaporation of the perspiration (cf. 70). The excess heat of the body acts like the heat of a stove in turning perspiration into steam. Ordinarily the perspiration is evaporated as rapidly as it is formed, and we do not notice it. This is insensible perspiration. Sensible perspiring, or sweating, takes place only when water is given off by the perspiration glands more rapidly than it can be evaporated by body heat. 75. Clothing. Man protects his body against sudden loss of heat by clothing. The best clothing for this pur- pose is that which is made of a non-conductor (cf. 65), and permits little heat to escape. Of the common non- conducting materials the best is wool. Wool prevents heat from coming to the body as well as its escape from the body. Hence firemen, who are obliged to work where it is hot, use woolen clothing to keep cool. Linen and cotton are better conductors of heat than wool is, and so are better for summer clothing than for winter clothing. 72 HEAT But whether a material will be a conductor or a non- conductor depends largely upon whether it is woven loose- ly or tightly. For it is the air in the meshes of the cloth that acts as the best non-conductor. Fur and feathers are warm chiefly because they imprison so much air. For the same reason moderately loose winter clothing is warmer than tightly fitting clothing. 76. Sources of Heat. The chief sources of heat are the sun, body heat, the burning of fuels, friction and collision, and electrical resistance. a. The Sun. The earth gets some heat from the moon and stars and its own interior, but the amount is small. Practically all the warmth of the earth's surface and of its atmosphere comes from the sun. The sun is so far away, and our earth is so small, that we get only a very little of the heat sent forth by the sun, perhaps 1 part out of 2,000,000,000, yet this is enough to make the earth fit for living things instead of a frozen, unin- habited sphere. The gain and loss of heat in the temperate and frigid zones cause the seasons of these zones, and the cutting off of the sun's rays from any place brings its night. b. Fuels. Man is the only animal that uses fire. Other animals and the world of plants store up some of the energy received from the sun, and man uses them for food and fuel. In causing a fuel to unite with the oxygen of the air, man is getting back some of the sun's energy. The chief fuels are wood, coal, charcoal, coke, natural gas, petroleum, and alcohol. Petroleum (cf. 121) is the natural product out of which kerosene, gasoline, and par- SUMMARY 73 affin (white wax) are prepared. Coal is the chief source of illuminating and fuel gas (cf. 124). c. Collision and Friction as Sources of Heat. If you slap your hands together briskly, they become warm. When a bullet is stopped by a rock, it becomes hot. What is the source of the heat in these cases? The answer is that the moving bodies (the hands and the bullet) have their motion changed into heat, the motion of the mole- cules. The heat is due to the collision. When you rub your hands together, they become warm, because their motion is partly changed into heat. The loss of motion is due to the friction of one hand against the other. Early man learned to use friction to kindle his fires (Fig. 63), and thus exchanged mus- cular energy for heat. Later he obtained sparks by striking together flint and steel, or flint and iron pyrites ("pi-rl'- tes"; also caUed " fools' gold," from its deceptive color). In the modern match man is still exchanging motion for heat; for he uses friction to kindle the match. d. Electrical Resistance. The energy of the electric current is easily changed into heat, and gives us electric lights, heaters, and furnaces. We can understand these better after we have studied Chapter VIII. FIG. 63. Batua Fire-Drilling, Congo Free State. Copy- right, 1912; Frederick Starr. 77. Summary. Bodies usually expand when heated, and con- tract when cooled. This is explained by the theory that matter is composed of molecules, and that heating separates them further, while cooling causes them to come closer together. 74 HEAT Thermometers measure differences of expansion between mercury and glass. The "freezing point" of a thermometer is the temperature of melting ice. The " boiling point " mark is the temperature of steam given off by water that is boiling under standard pressure. . = (Cent.X 9 A)+32. = 5 /9(Fahr.-32). Degree of heat is temperature. It depends upon the rapidity of molecular motion. Quantity of heat in a body depends upon the temperature and the mass; also upon heat capacity (cf. 73). The calorie is the unit of heat quantity. Heat is distributed by conduction (or contact), by radiation, and by convection. Convection currents are set up in liquids or gases if they are heated from the bottom or cooled from the top. The three physical forms of matter are solids, liquids, and gases. They depend on the cohesion and the energy of the molecules. Heat of melting, or of fusion, is the number of calories of heat needed to melt 1 g. of a solid. Heat of freezing is the number of calories given off in the freezing of 1 g. of a liquid. It is equal to the heat of melting. Water expands when it freezes; most liquids contract. Heat taken up in the change of liquid to vapor is given off in the condensation of the vapor. Compression of a gas liberates heat. Expanding gases take up heat; that is, become cold. Kindling temperature is the temperature at which a substance begins to burn. A calorimeter is an apparatus in which the heat given off in burn- ing, or in some other change, can be given to some water, and so measured. The human body is a complex engine. It uses the changes in its cells and in food to produce heat and the ability to do work. Evaporation of perspiration keeps the body's temperature constant. Wool makes the best clothing for those exposed to extremes of temperature. EXERCISES 75 Sources of heat are the sun, fuels, collision, friction, and electrical resistance. 78. Exercises. 1. If you mix 100 g. of water at 80 C. with 100 g. of water at C., what temperature will the mixture have? 2. How many calories are needed to melt 100 g. of ice? If you mix 100 g. of water at 80 C. with 100 g. of ice at C., what will happen? What will the temperature of the mixture be? 3. If a glass fruit jar is filled completely with water, then sealed, and put outdoors in zero weather, what is likely to happen? Why? 4. If you open the valve of a full bicycle tire, the escaping air feels cold; why? 5. If steam at 100 C. enters the steam coil of a room, and water at 100 C. leaves the coil, how is the roorn heated? 6. Why does sprinkling a lawn in hot weather cool the air? 7. If some liquid air is poured into an open beaker, its temperature does not rise above 182.5 C., no matter how warm the room is. Explain. 8. What do we mean by saying that the specific heat of water is 9 times that of iron? 9. Why does a nail struck repeatedly with a hammer become hot? Why does a bit used to drill holes in a board become hot? What causes a "hot box" on a railway car? Give other illustrations of the same phenomenon. CHAPTER V WATER 79. How Water Occurs in Nature. We commonly think of water as a clear, easily poured liquid; we must also think of it as a solid : snow, frost, and ice, and as a gas or vapor : steam. Water is very abundant, not only in rivers, lakes, and the ocean, but also in the earth's solid crust. No matter where we dig, we find it even in the desert. The atmosphere likewise contains a great deal : as steam. Water makes up a large part of all plants and animals. The following table shows how much of our bodies and our food is water: Human body. .... 70% Watermelon. .'. . . . 92% Milk 87% White bread 35% Potatoes 78% Beef 62% Natural water is never pure. The rain gathers material from the atmosphere (cf. 58) ; the water that flows over or through the earth's crust dissolves substances from the* soil and the rock; and both rain and running water take up living creatures, such as bacteria (cf. 56 and 324). Rivers and lakes become impure because of the sewage, or waste matter, of the cities, factories, and farms upon their banks. The purest natural water is probably obtained by melt- ing some ice obtained from a pure source. 76 DRINKING WATER 77 80. Substances Dissolved in Natural Water. Lakes and rivers are usually fresh because the salty substances brought into them are also carried away; but the ocean becomes more and more loaded with dissolved material. The same is true of such lakes as Great Salt Lake and the Dead Sea. The reason is that while these bodies receive both water and dissolved substances, only the water evaporates. The solids are left behind. Nearly 2.7 per cent of sea water is common salt. Mineral waters contain so much solid material in solution that it is usually perceptible to the taste. The most common substances in mineral waters are salt, soda, potash, limestone, gypsum, and com- pounds of iron and of sulphur. As many as 15 grams of solids are sometimes present in one liter of mineral water. Salt springs and wells furnish most of our table salt (cf. 108 and Fig. 84). COMPOSITION OF SOME NATURAL WATERS Source of Water Grams of Solids in 10GO g. of Water Cubic Centimeters of Gases in 1 1. of Water Nitrogen Oxygen Carbon Dioxide Rain .029 .097 .282 .438 35.25 40.00 228.60 271.40 13.1 15.0 15.8 12.Q 6.4 7.4 8.5 6.'0 1.3 30.0 1.1 i7'6 Rivers and Lakes Springs Deep Wells English Channel Mediterranean Sea. . . . Dead Sea Lake Elton 81. Drinking Water. By "pure water" different classes of people mean different things, for each is thinking of some impurity that is especially objectionable to him. If the water is to be used for drinking, the chief impurities 78 WATER we are troubled about are injurious bacteria, and the de- caying matter upon which they live. Dissolved gases and minerals are not usually considered impurities in a drink- ing water; but if the bacteria of certain diseases, such as typhoid fever, get into the water, we may " catch' 7 the disease by taking the bacteria into the stomach. Hence drinking water should be tested carefully. This is espe- cially true if the source of the water is not well known, or if it is suspicious. Whether a water is pure or impure cannot be told by its appearance: a dirty looking water may be safe to drink, while one clear as crystal may be filled with deadly germs. Shallow wells are always sus- picious ; for filth may be washed in from the surface by the rain, and kitchen drains, outbuildings, or barns may be sufficiently near to pollute the well (Fig. 64). We must re- member that ice made from polluted water is also dan- gerous. The disease germs are not killed by freezing, but live on in an inactive state. They become active again when they find lodging in our bodies, or in favorable food, such as milk. FIG. 64. A well may be polluted by a cesspool or by drainage from a barn. PURIFYING WATER 79 82. Hardness of Water. To the manufacturer ' ' pure " water usually means water that can be used in boilers, to produce steam. The most objectionable impurity from his point of view is the "hardness" of the water. Hard- ness is also harmful in water to be used in the house- hold for bathing and for the washing of clothes. Water is said to be "hard" if it does not wet the skin readily, and if soap put into the water forms, at first, an in- soluble scum. Suds, or lather, is not formed in hard water until the hardness is removed by the soap; hence hardness is defined as the soap-consuming power of a water. Distilled water, water from melting ice, and rain water form a lather almost immediately; hence they are called " soft " waters. Some of the impurities that cause hardness become insoluble, and settle, when the water is boiled. In this case the hardness is said to be temporary. Hardness that cannot be removed by boiling is called permanent hardness (c/.226). If a boiler is filled repeatedly with hard water, it becomes clogged with a deposit "boiler scale" just as a kettle does (Fig. 65). Iron is a conductor of heat (cf. 65) ; hence the walls of a new iron boiler cannot become much The kettle is lined with solids hotter than the water in the boiler. But boiler deposited from boiling scale is so poor a conductor that a boiler con- taining much of it needs to be heated very hot, or the water will not boil. As a result of this over-heating, the "scale" is often broken up into substances that act upon the iron, and weaken it. Boiler scale has caused very serious explosions and loss of life. 83. Purifying Water. Water may be purified (1) by distilling it ; (2) by boiling it ; (3) by filtering it. 80 WATER Overflow Distillation consists in heating a liquid until it bpils, and then passing the vapor through a condensing appara- tus to convert it back into the liquid state. The solid substances, such as salt, limestone, gypsum, etc., do not boil off, but remain behind in the boiler. The form of distilling apparatus much used in laborato- ries is shown in Fig. 66. Fia. 66. Distillation of Water; Liebig's Condenser. The Condenser is known as Liebig's condenser, after the celebrated scientist of that name. It is of glass, and consists of an inner tube for condensing the vapor, and an outer jacket for the cooling liquid, which is usually water. For distillation on a larger scale a boiler and a "worm" condenser are used (Fig. 67). Other liquids may be distilled like water. Thus, while water boils at 100 C., alcohol boils at 79 C. If a mixture of alcohol and water is distilled, the alcohol boils FIG. 67. Off first, and the tWO may thus be Large Still and Worm Condenser. Boiling removes the temporary hardness of water, and kills the germs. Since the taste of natural water is due to the dissolved gases and solids it contains, distilled water tastes very "flat." Boiled FILTERING 81 placed in the funnel, liquid is poured from a beaker, down a glass rod, upon the filter. The filtrate runs through the filter. water is more agreeable, because some dissolved solids are still present; but both kinds of water are better if they are aerated; that is, if they are made to dissolve air. We can add the air to a water by filtering the water through porous stone, or by pouring the water several times from one vessel to another. 84. Filtering. A filter is a screen or sieve with openings so small that only liquids and the substances dis- solved in them can get through. Substances suspended in the Jiquid, which make the liquid roily, or turbid, can not get through. In the laboratory we make a filter by folding a piece of porous paper, as shown in Fig. 68, and placing it in a funnel. If a milky mixture of water and powdered chalk be poured upon the filter, the water goes through, but the chalk does not. In household filters (Fig. 69) por- ous stone and charcoal are used as filtering materials. These strain out the suspended impurities of the water, including the bacteria. However, unless a filter is cared for, it may become so clogged with organic matter that it will serve as a breeding-place for bacteria, in- stead of removing them. Water filters should be cleaned frequently, and exposed to direct sunlight, to keep them fresh and wholesome. This is especially true of filters Charcoel FlG. 69. A Household Filter. 82 WATER attached to faucets, because of the large volume of water that passes through them daily. 85. Filtering City Water. The best natural filter is clean sand. It is loose, and contains much air; hence oxidizing bacteria can penetrate far into it. If the sand is not kept soaked too long at a time, impure water that passes through it will be made fit for drinking. A soil containing much clay does not make a good filter, because clay is too compact. In filtering water for cities (Fig. 70) men run the water of rivers or lakes through beds of sand. After soaking through the sand the water enters reservoirs, from which it is distributed through the water "mains" of the city. But the large filters, like the small ones, need to be emptied often, and allowed to lie idle, so that the sand may be purified by the direct action of sunlight and air. Coagulation Filters. In some cases a coagulating, or clotting, substance, such as alum, is added to the water before it enters the sand filters. The alum causes the clay particles, which of themselves settle only very slowly, to flock together and to come down rapidly, carrying decaying matter and germs with them. Coke dust is often mixed with the sand to improve the quality of the filter. FIG. 70. Filter Beds of a City System; Evanston, 111. WHY ICE FORMS ONLY AT THE SURFACE 83 86. Exercises. 1. Hard cookies placed in a box containing fresh bread become soft and mellow; why? Why do crackers lose their crispness when taken out of their box? 2. Tell why a potato loses weight when baked. 3. Why does candy become sticky, and why does salt "cake," in damp weather? 4. The Jordan River flows into Lake Utah, and Lake Utah empties into Great Salt Lake. Would you expect Lake Utah to have fresh water or salty? Why? 5. Tell how the crew of a ship can prepare fresh water out of sea water? How does nature do it? 6. Name some of the ways in which dirty water thrown into the yard is purified by nature. Why should such water never be thrown near a well or cistern? 7. Why does moisture condense on the windows of the house on a cold wash day? 8. Why should bottles of alcohol, gasoline, and turpentine be stop- pered? 87. Why Ice Forms Only at the Surface. Since ice is lighter than water (cf. 70), it floats, and the ice cover- ing usually prevents the water beneath from freezing. But the chief reason why lakes and streams do not freeze to a great depth is that water is most dense, or heavy (cf. 33), not at C., the freezing temperature, but at 4 C. Let us see the results of this fact : A lake or stream is cooled chiefly from the top, where it touches the cold air. Now, when a lake having water at, let us say, 10 C., is cooled by air at C., or below, the surface layer becomes colder than 10 C., and heavier, and so sinks to the bottom, while a warmer layer takes its place. This movement of water goes on until all the water is cooled to 4 C. But as the upper layer of water, 84 WATER which is now at 4 C., is cooled further, it becomes lighter than the water at 4 C., and floats upon the warmer water. When, finally, the surface of the water freezes, the ice that is formed also floats. Hence the water below the ice is rarely cooled below 4 C. Because of this fact water animals and plants survive the winter, and live even in Arctic waters. 88. Artificial Ice. The supply of natural ice is so un- certain, especially in warm climates, that men have been Hot Gas 130C 17C -15C Co.mpreseion Pump Expansion Coils and Ice Molds FIG. 71. Cooling Brine for Ice Making by the Expansion of Compressed Liquid Ammonia. forced to make ice by artificial freezing. To freeze the water some liquid is used that boils at a low temperature. Usually the liquid is liquid ammonia. This is not "am- monia water," but the gas, ammonia, which has been liquefied by pressure. The liquid ammonia is made to evaporate rapidly by the removal of the pressure. The turning of the liquid into the gas requires heat, just as STEAM 85 the turning of water into steam does. In the ammonia ice apparatus the heat comes from the water to be frozen. The apparatus is shown in Fig. 71. In this apparatus the water is not frozen directly by the evaporation of the liquid ammonia; but a brine is cooled to 15 C. or 20 C., and this cold liquid is used to freeze the water. The brine is a water solution of salt or of calcium chloride, and freezes far below the freezing temperature of water. The cold brine is also used in cold-storage warehouses, and in refriger- ator cars, to produce a low temperature. In this way butter, eggs, meat, fruit, etc., are kept cold, and prevented from spoiling (Fig. 72). FIG. 72. . Rooms for storage of meat are cooled by means of a cold brine distributed through pipes. "Iceless" refrigerators are now being made. They are really refriger- ating machines, and are kept cold by the rapid evaporation of liquid ammonia. 89. Steam. Steam is water in the vapor form. When steam issues briskly from a vessel of boiling water, as 86 WATER from the spout of a tea-kettle, it is invisible until it con- denses to fine drops, some distance away. The fine drops are liquid water, not steam. Clouds are made of similar droplets : ' ' fog," not of steam. While water freezes at a definite temperature (0 C. or 32 F.), it is changed into steam at any temperature. Even ice and snow pass directly into steam (evaporate) on a cold winter's day, without melting. Like air and other gases, steam has pressure. At the ordinary temperature the pressure of the steam given off by water is small (cf. Appendix, Table VIII) ; but as the temperature of the water rises, its steam has a greater and greater pressure, until at 100 C., or 212 F., the steam has the same pressure as the air (760 mm.). The steam then sweeps the air completely out of the vessel in which the water is being heated. We say that the water is boiling, and we call 100 C., or 212 F., the boiling point of water (cf. 62). 90. The Boiling Point Changes with Pressure. If water is boiled in a closed vessel, more and more steam is packed into the space above the liquid water, and the pressure of the steam increases accordingly. Under the increased pressure of the steam, the water now boils above 100 C. When the steam has twice the atmos- pheric pressure (2X760 mm.), water boils at 121 C. In a locomotive boiler producing steam at 13 " atmospheres " pressure (191 pounds to the square inch) water boils at 192 C., or 378 F. When steam at high pressure is allowed to escape, it expands greatly. This is the source of motion in a steam engine (cf. 24). SOLUTIONS 87 Condenser When the pressure under which water boils is less than 760 mm., the boiling point is less than 100 C. (cf. Appendix, Table VIII). Sugar refiners make use of this fact in boiling off the water from dilute syrup. If the water were removed at the ordinary pressure, the syrup would boil so high that the sugar would be spoiled. By the use of evaporating vessels called "vacuum pans," which are covered with tight hoods (Fig. 73), this is avoided. If the air is removed from the pans until its pressure is only 233 mm., the water boils off at 70 C. without injuring the sugar. Salt is ob- tained from salt brines in the same way. The boiling point of water falls about 1C. for every 960 feet we ascend above sea level. Thus, at the city of Mexico, 7,500 ft. above the sea, water boils at 92.3 C., while at Denver, 5,000 ft. high, it boils at about 95 C. 91. Solutions. If we put salt or sugar into water, the solids disappear. We say they dissolve in the water. They have not really disappeared, however, for they give their taste and other properties to the water. We call the water the solvent, and the dissolved substance the solute. The mixture of solute and solvent is called a solution. Solutions in which alcohol is the solvent are called tinc- tures. If the solute is of some other color than white, its water solution will usually be colored. A minute FIG. 73. Vacuum Pan. Water is being distilled at "reduced pressure." 88 WATER . amount of potassium permanganate, or of aniline violet, shows a remarkable power of coloring water. But whether colorless or colored, true solutions are clear, not roily (cf. 84). Milk is a mixture of water, sugar, etc., with suspended particles of fat. The fat is very finely divided, and the casein of the milk (cf. 357) prevents the water and fat from separating at once into two distinct layers. After a while, however, the fat (cream) rises to the top. Such a mixture is called an emulsion. 92. Properties of Solutions. A solute not only im- parts its taste and color to a solution, but it makes the boiling point, freezing point, and density of the solution differ from those of the solvent. A solution of a solid boils at a higher temperature, and freezes at a lower temperature, than the pure solvent. Thus, a solution of 40 g. of salt in 100 g. of water boils at about 108 C. A saturated salt brine does not freeze until the temperature is about 22 C. Because of its dissolved solids, ocean water rarely freezes in temperate latitudes. When a dilute salt brine freezes partly, but not wholly, most of the salt remains in the solution, and the ice is nearly fresh. A solution of a solid has a greater density than the solvent. Thus, while a liter of pure water weighs about 1000 g., the same volume of sea water weighs about 1026 g. (qf. 80). 93. Freezing Mixtures. When most solids dissolve in water, they lower the temperature of the water. Thus, if equal parts, by weight, of ammonium nitrate and water are mixed at C., the temperature falls to 15 C. CRYSTALS 89 We have learned (c/. 69) that when ice is placed in water, the heat needed to melt the ice (80 calories for each gram) comes from the water; hence the water is cooled to its freezing point, C. Now, when ice is mixed with salt, the salt dissolves in the water formed by the melting of the ice. We thus get a salt brine. The heat needed to melt the ice comes from the brine, and cools it to its freezing point, 22 C. If cream or ' ' ices " are placed in this brine, heat is taken out of them until they are frozen. 94. Solubility. By the solubility of a solid we mean the weight of it that will dissolve in a definite amount, say, 100 grams, of the solvent. We know that if we add too much sugar to our tea or coffee, some of it will not dissolve, even though we stir the liquid vigorously. The tea or coffee is then said to be " saturated " with sugar. If a liquid is hot, it can usually dissolve more solid than when cold. A solid that is soluble in water may be insoluble in another solvent. Thus, salt does not dissolve in alcohol. Camphor and shellac dissolve in alcohol, but not in water. The accompanying table shows that substances differ greatly in solubility, and also that the solubility of solids generally increases as the temperature rises. Substance Grams Soluble in 100 g. Water at oc. 20 50 70 100 Potassium nitrate (saltpeter) Sodium chloride (salt) 13 35 3 15 6 32 36 7 22 13 85 37 20 32 140 38 32 iis 246 39 59 73 Potassium chlorate Copper sulphate (blue vitriol) Alum 95. Crystals. The table of solubility shows us that water at 100 C. can dissolve more of the substances 90 WATER FIG. 74. Crystals of Salt (A), Alum (B), and Blue Vitriol (C7). named than water at 20 C. (the ordinary temperature). Suppose we were to saturate some water at 100 C. with common salt, and were then to let the solution cool to 20; what might we expect to happen? We might expect part of the salt to be deposited as a solid. If we examined the deposited salt, we would find that it consisted of small cubes (Fig. 74, A). We would also get cubes of salt if we were to let some salt solution evaporate slowly at the ordinary temperature. The cubes are crystals of salt. If we make a hot, saturated solution of alum, and let it cool slowly, we shall get crystals like Fig. 74, B; while crystals of blue vitriol are like I ig. 74, C. All of these crystals have flat (plane) faces and straight edges arranged in a definite way. Each substance has its own crystalline form, but the crystals may be imperfect if they are deposited on the sides of the vessel. The more slowly the crystals separate from solution, the larger they will be. Sugar crystallized upon a string which is sus- pended in the sugar solution is called "rock candy" (Fig. FIG. 75. Crystals of Sugar (A), Quartz (B), and 75, A). Sulphur crystallizes (Fig. 3) from a liquid called Diamond (co carbon disulphide. Crystals may be formed notonly from solution, but also by the freezing of a liquid; as ice is made by the freezing of water. Ice is SUMMARY 91 composed of small crystals packed closely together. The separate crystals can be seen when freezing begins, and in the form of snow and Fio. 76. Crystals of Snow. frost. Snowflakes take on many forms (Fig. 76), but all are six-sided or six-pointed. Substances that do not crystallize are said to be amorphous, that is, "without form." Glass and many gums are examples. 96. Summary. Water exists as solid, liquid, and vapor. It is very abundant in nature, but natural water is rarely pure. Mineral waters contain so much material that it can be tasted. The sea contains even more dissolved material than mineral waters. Drinking water is considered pure if it does not contain too much mineral matter, and if it is free from injurious "germs." Hardness of water is its soap-consuming power. It may be tem- porary or permanent. Boiler scale is a deposit left in steam boilers and kettles that use hard water. Water is purified by distillation, boiling, filtration, and ' 'softening/' Distillation is changing a liquid into its vapor, and then condensing the vapor. The impurities are left behind. The "flat" taste of distilled and boiled water is due to the absence of dissolved substances, including air. Filters "strain out" the suspended impurities of water and give a large surface for the oxidizing bacteria of the air. Water freezes at C. (32 F.). It expands as it freezes; hence ice floats. Artificial ice is made by the use of the principle that evaporation requires heat. The heat needed to vaporize liquid ammonia is taken from the water to be frozen. 92 WATER Steam is the gaseous form of water. Water and ice change to steam at all temperatures. At 100 C. the steam from boiling water has a pressure equal to the pressure of the atmosphere. A solution consists of solvent and solute. An emulsion is a mixture in which the suspended substance is so finely divided that it separates itself from the solvent very slowly. Solubility of a solid is the weight of it that will dissolve in a definite weight, usually 100 g., of water or other solvent. Crystals are solid bodies that take regular shapes when they sep- arate from solution or from the liquid state. Non-crystalline sub- stances are amorphous. 97. Exercises. 1. If water were most dense at C., what effect would this fact have upon the depth of ice in winter? 2. If a test tube of water is placed in a cup of ether, and a rapid current of air is forced through the ether, the water may be frozen. Why? 3. Which should be kept in the colder room of a storage warehouse, eggs or meat? 4. The sharp edges of a piece fo ice become rounded off even in very cold weather; why? 5. In making " fudges," or the filling of French candies, why is the candy first cooled without being disturbed, and afterwards stirred rapidly? 6. Can you dissolve salt in water, and then recover the salt un- changed by boiling off the water? Can you do the same with sugar? Why? 7. At Quito, in Ecuador, water boils at 90 C., too low for the cook- ing of potatoes; why? Can you suggest how you could make water boil at 100 C. in Quito? 8. How is salt commonly obtained from salt water? In Northern Russia the salt makers remove much of the water by partly freezing the salt solution, and so save fuel. How is this possible? EXERCISES 93 9. Why is it easier to swim in the ocean than in fresh water? 10. If sugar is dissolved in a cup of tea, does its dissolving affect the temperature of the tea in any way? Explain. 11. If you had some powdered alum, how would you make good- sized alum crystals out of it? CHAPTER VI ELEMENTS AND COMPOUNDS 98. Physical and Chemical Changes. If we heat a flat-iron on a stove, it becomes hot. It may even become red hot, so that it gives off heat and light. But if it is taken from the stove, it becomes cold again, and looks just as it did before the heating. A lump of coal thrown into the air comes down again, still a lump of coal. The water of the ocean is changed into steam, then carried away by air currents, and finally falls again as rain or snow. The iron is changed in temperature, the coal and water are changed in position, and the water is changed in physical state (cf. 69); but the changes do not really alter the iron, coal, and water. We call such changes physical changes. But if a piece of iron is left in moist air, it rusts (cf. 48) . If water is added to quicklime , it combines with the lime, forming "slaked" lime; it is no longer water. If coal is burned, it disappears, as carbon dioxide and steam (cf. 52). Such changes do alter the nature of substances. They are called chemical changes, because they are stud- ied in the science of Chemistry. Chemical changes are also called reactions. Digestion consists of the physical and chemical changes that take place in food, in order that it may be taken up by the blood for the use of the body. 94 ELECTROLYSIS OF WATER 95 99. Composition of Water. By the " composition/ ' or " make-up," of water we do not mean a list of the materials present in a particular sample of water, such as the carbon dioxide, limestone, salt, etc., that are dissolved in a natural water (cf. 80). What we mean is that pure water, which we obtain by purifying natural water, is still made up of two different substances : hydrogen and oxygen. We say that water is "composed of," or "is a compound of," hydrogen and oxygen. Water is formed when hydrogen is burned (cf. 52 and 105). Can we reverse the action that takes place in burning, and break up water into hydrogen and oxygen, just as we "decomposed" mercury oxide into mercury and oxygen (cf. 50)? Water, like mercury oxide, can be broken up by heat; but the temperature required is very high, and the method is hard to carry out. The decom- position of water is easy, if we use the electric current. The operation is called the electro- lysis of water. Electrolysis means "loosing," or "breaking apart," by the use of electricity. 100. Electrolysis of Water. The "breaking apart" of water by the electric current may be carried out as follows (Fig. 77) : FIG. 77. Electrolysis of Water. The electric current breaks up water, containing a little of an acid, into hydrogen and oxygen. Two wires from a battery or other source of the current (cf. 150 and 160) pass into a vessel. The vessel contains water and a very little sulphuric acid. The liquid to be changed by the electric current is thus a very dilute sulphuric acid. The wires inside the vessel are 96 ELEMENTS AND COMPOUNDS of the metal platinum (c/. 9), and they have tips of platinum foil. We call the ends of the wires the poles of the battery. If we were to put the two platinum poles together, the current would have a com- plete passageway, or circuit, without going through the dilute acid. But if we keep the poles apart, the current is compelled to pass through the dilute acid. In the language of the electrician, the dilute acid makes, or doses, the circuit. While it is carrying the current from one pole to the other, the dilute acid is changed chemically (cf. 98). What we see is that bubbles of gas arise from the poles. We can collect the gas by placing over each pole a test tube filled with some of the dilute acid. We then see that one test tube collects gas about twice as rapidly as the other. If we put a burning splinter into the gas that is collected the more slowly, the splinter burns more brightly than in air, and if the splinter is merely glowing, it will burst into flame. The gas collected in this tube is oxygen. If we bring a flame near the other gas, the gas takes fire with a slight "pop," or explosion, and then burns with an almost invisible blue flame. This gas is hydrogen. It is so called because it is -a part of water. The Greek word for water ' ' hydor " appears in many other English words, such as hydra, hydrant, hydraulic, etc. 101. Elements and Compounds. Water is so hard to decompose by heat that men were unable to learn its real nature until 1781. In that year Cavendish, who had prepared hydrogen in 1766, burned hydrogen, and ob- tained water. The decomposition of water by the electric current was first carried out in 1800. The question now arises : ' ' Can the hydrogen and the oxygen obtained from water be divided up into other substances?' 7 The answer is that they have never been divided by any method used for the purpose. A substance like water, which is not a single kind of matter, but has at least two kinds of matter in it, is called a compound. A kind of matter which we have never been able to break up is called a simple MIXTURES 97 substance, or element. Hydrogen, oxygen, nitrogen, carbon, iron, tin, mercury, etc., are elements (see Appen- dix, Table IX). How complete the change is, when substances unite chemically, is seen when we compare water, the compound, with the two elements that make it up. The formation of carbon dioxide by the burning of carbon is another common illustration of the same thing. No one would suspect that this colorless gas (cj. 51), which puts out fire, which is exhaled from our lungs, and is taken up by plants (cf. 58), is really the black carbon of coal and charcoal, and of the "black lead" of our pencils, combined with the active gas oxygen. Yet this is the case. 102. Mixtures. If, in the electrolysis of water, we were to collect two test tubes of hydrogen and one of oxygen, and were to mix them in a bottle over mercury (Fig. 78), would they unite at once to produce water? They would not. They would remain in each other's presence for a long time without any noticeable change. It is neces- sary for the temperature to be raised to about 620 C. before the two gases unite rapidly. When they are mixed at the ordinary temperature, they form only a physical, or mechanical, mixture. No heat is set free; no new substance is formed. If we shake the mixture with water, the hydrogen dissolves as if no oxygen were present, and the oxygen dissolves as if no hydrogen were present. FIG. 78. A gas can be transferred from one vessel to another under a liquid. 98 ELEMENTS AND COMPOUNDS The air is a physical mixture of nitrogen, oxygen, steam, carbon dioxide, and small amounts of other gases. Of course we have mixtures of compounds, as well as of elements. Natural water is always a mixture (cf. 80). All soils, and most rocks, are mixtures (cf. 285 and 294). The forms in which the solid elements and compounds are found in nature are called minerals. 103. Preparation of Hydrogen. The most common way to prepare hydrogen is to bring certain metals and certain acids together. All acids are compounds con- taining hydrogen (cf. 214) ; but all do not give it off with the same ease. The best acids to use are dilute sulphuric acid and dilute hydrochloric acid; the best metals are zinc and iron. The apparatus needed (Fig. 79) is a bottle provided with a stopper having two holes, a " thistle tube," and a delivery tube reaching to a O FIG. 79. (A) Making Hydrogen and Collecting It over Water. (B) Collecting It over Air. water-pan. The thistle tube is the opening through which fresh supplies of acid are put into the bottle; it also allows the hydrogen to escape if the delivery tube becomes stopped up. Hydrogen is not very BURNING OF HYDROGEN 99 FIG. 80. Soap Bubbles Filled with Hydrogen. soluble in water (cf. 100), and is collected "over water," just as oxygen and nitrogen are. 104. Properties of Hydrogen. Like oxygen and nitro- gen, hydrogen has no odor, taste, or color. It is the light- est substance known. Oxygen is 16 times as heavy as hydrogen, and nitrogen is 14 times as heavy. At the ordinary temperature and pressure 1 gram of hydrogen has a volume of about 12 liters, i. e., about 3 gal- lons (cf. Appendix, Table IV). Because of its lightness, hydrogen may be collected ' ' over air " (Fig. 79, B), and may be used to fill balloons. Soap bubbles filled with the gas rise in air (Fig. 80). 105. Burning of Hydrogen. If we wish to burn hydro* gen in a jet (Fig. 81), we must light it with great care. When we begin the prep- aration of hydrogen, the bottle is full of air; hence the first portions of gas that come off are a mix- ture of hydrogen and air. If we light this mixture, there will be a violent ex- plosion, which may break the bottle, and blow the FIG. 81. . Hydrogen burns in air to form water. glaSS into OUr laCCS. 100 ELEMENTS AND COMPOUNDS Before we bring a flame near a jet of hydrogen, we hold a test tube -over the outlet tube (Fig. 79, B) for a minute, and then carry the test tube, with its mouth downward, to a flame at least 3 feet away. The gas in the test tu*be burns rapidly, if it still contains air; but if it con- sists of fairly pure hydrogen, it burns slowly. When we have lighted the gas in the test tube, we carry the tube, with its mouth downward, back to the jet of hydrogen. We do this until the test tube of burn- ing hydrogen sets the jet of hydrogen on fire. Hydrogen burns with a colorless flame when pure. The flame is very hot. When 1 gram of hydrogen is burned in oxygen, the heat given off is sufficient to heat 342 grams of water from C. to 100 C. Water is formed not only when hydrogen itself burns, but also when compounds of hydrogen burn (cf. 52). Thus it happens that when a kettle of cold water is placed over a gas flame, water drops are deposited on the outside of the kettle. When the kettle becomes hot enough, the steam formed in the burning escapes without being condensed. 106. Diffusion of. Gases and of Liquids. If we attach a porous cup (Fig. 82) tightly to a tube ending under water, and place a jar of hydrogen over the cup, an interesting Hydrogen 2 'pas- phenomenon takes place : bubbles of gas escape P e o r l n us cup from the bottom of the tube. The bottom of the S.a r n S^wS jar containing hydrogen is open; so the only reason why gas escapes through the water must be that hydrogen enters the porous cup. It can be proved that air passes outward through the porous materi- al; but it does this so much more slowly than the hydrogen goes inward that there is a sudden increase in the volume EXERCISES roi Hydrogen of gas inside the cup and tube. Hence some of it es- capes through the tube. This experiment shows that gases have the ability to mix when placed together. We call this mixing diffusion, and we explain it by saying that the energy of the molecules (cf. 61) causes the molecules of the one gas to move rapidly into the spaces between the molecules of the other gas, until the mixing is complete. If we place a bottle of hydrogen, with its mouth downward (Fig. 83), over a bottle of air, the hydrogen diffuses downward, and the air upward, in spite of the fact that air is 14.4 times as dense as hydrogen. When the gases are separated by a wall through which they can pass, as in the porous cup ex- periment, they still diffuse into each other; but we can see that they move at different rates: the lighter gas diffuses more rapidly than the heavier one. Liquids and solutions diffuse, in spite of gravity, just as gases do. Thus, if some blue vitriol (cf. 95) is put into the bottom of a tall jar, under a deep layer of water, the blue vitriol solution that is formed at the bottom rises gradually to the top, coloring all the water. Also, if some alcohol is put upon water, it descends into the water, even though the water is the heavier; and water ascends into the alcohol, until the mixture is complete. The diffusion of oxygen inward, through the walls of the blood-vessels, into the blood, and of carbon dioxide outward causes the exchange of gases necessary for the life of the higher animals (cf. 52). 107. Exercises. 1. Are the following changes physical or chemical? Souring of milk, freezing of water, decomposition of mercury oxide by heat, dis- solving of sugar in water, incandescence (" getting white hot") of an electric light, burning of candy on a stove, heating a penny by striking FIG. 83. Hydrogen passes down- ward into the air, and air upward into the hy- drogen,. 102 ELEMENTS AND COMPOUNDS it with a hammer, changing of the starch of a cracker to sugar by means of the saliva in the mouth. 2. Compare the properties of hydrogen with those of oxygen. Compare hydrogen with water. 3. What properties of hydrogen and of oxygen can you show only by changing these elements chemically? 4. In what proportions by volume would you expect hydrogen and oxygen to unite in forming water? 5. Coal, wood, and kerosene contain carbon and hydrogen. What products are formed when they burn? 6. How would you prove that wood ashes are a mixture of soluble and insoluble substances? 7. If you were making the hydrogen for filling a balloon, which would be the cheaper to use as the metal, zinc or iron ( 103)? For what reason would illuminating gas be better than hydrogen? In what way would hydrogen be better? 8. How many calories of heat are given off when 1 g. of hydrogen burns ( 105)? 9. Carbon dioxide is 1.5 times as dense as air. If, in the porous cup experiment (106), you were to surround the cup with a jar of carbon dioxide, which would pass through the porous wall more rapidly, the air or the carbon dioxide? Would air be forced out of the tube, or would water be forced in? 108. Salt. Salt is found in large amount in sea water; it is also mined as rock salt. To purify rock salt we add water to it, so that the salt dissolves, while the impuri- ties do not. The water is then boiled off, either at ordinary FIG. 84. pressure or in "vacuum pans" Hopper-shapjd t Massof Salt fa QQ). ^dlt Wells form an- other source of salt. Salt crystallizes in cubes (95); masses of the crystals are "hopper shaped" (Fig. 84). Because the crystals do SODIUM 103 not fit exactly together, some of the brine is caught be- tween them. When the salt crystals are heated, some of the water is changed to steam, and bursts the crystal mass. Hence small salt crystals " crackle " when heated; while large ones "snap" vigorously, and fly out of the dish. Salt is not changed, even when heated to fed heat. At white heat it melts. Like water, it can be broken up by the electric current. When the current is passed through melted salt, its elements, sodium and chlorine, are formed, one at each pole. The chemical name of salt is sodium chloride. 109. Sodium. Sodium is a metal, like silver, gold, copper, etc.; but it is so soft that it can be cut with a knife. When it is freshly cut, its surface is white as silver ; but it is soon tarnished by the moisture, the oxygen, and the carbon dioxide of the air. Sodium is kept under gasoline, or some other liquid containing no oxygen. When heated in air or oxygen, sodium burns, forming sodium oxide (cf. 48 and 51). Sodium acts vigorously with water (Fig. 85) . The action produces so much heat that the sodium melts, forming a round ball which floats upon the water. A gas escapes with a hissing noise, and the sodium finally disappears. The gas produced is hydrogen. FlQ . 85 . When the water is rubbed between the fin- ^p^wlte^ gers, it feels soapy, or slimy. It contains sodium hydroxide, also called caustic (i. e., burning) soda (cf. 218). Sodium + water give sodium hydroxide + hydrogen. 104 ELEMENTS AND COMPOUNDS Owing to the danger that sodium may be spattered into our eyes, we never put more than a very small piece at a time upon water, and we add it at arm's length, holding a piece of glass between our eyes and the dish. An excellent way is to use a small wide-mouth bottle 3 / 4 full of water (Fig. 85). The bottle is provided with a glass cover, which is drawn aside when the sodium is added, and replaced during the action. Several pieces of sodium may be added, one at a time. The hands and tongs used must be dry. If, after each piece of sodium has disappeared, we apply a match to the mouth of the bottle, the hy- drogen will burn. All sodium compounds make a colorless flame yellow. 110. Chlorine. While the element sodium is a solid at the ordinary temperature, chlorine, the other element present in salt, is a gas. The gases we have studied up to this time are colorless, odorless, and tasteless; but chlorine has a green color, a suffocating odor, and a dis- agreeable action on the lining of the nose and throat. It produces the effects of a bad cold. Its name comes from chloros, the Greek word for " green." We have the same word in "chlorophyll," the green coloring matter of plants (cf. 309). Chlorine has the power of bleaching; that is, of removing the color of grass, straw, and other plant products. It also bleaches cloth or paper dyed with indigo, litmus, cochineal, etc. Large quantities of chlorine are used in mak- ing bleaching powder FIG. so. ("chloride of lime")' an( l The Bleaching of Cotton Goods. ,, ,. , .. -m bleaching solutions. These are used for the whitening of cotton goods (Fig. 86) and, as "disinfectants," for destroying disease germs. Bleaching solutions are also used to remove ink and other stains from fabrics (cf. 230). AMMONIA 105 When a burning splinter is put into chlorine, it does not continue to burn. Many metals, however, burn vigorously in chlorine. Thus, warm copper foil takes fire, and burns to form copper chloride. If thin shavings of sodium are put into chlorine, the sodium becomes covered with a white deposit of common salt, and is soon used up. We thus prove, both by breaking up salt, and by forming it again, that it is a compound of sodium and chlorine. 111. Hydrochloric Acid. When a jet of burning hydro- gen (cf. 105) is put into a bottle of chlorine (Fig. 87), the hydrogen continues to burn, and the chlorine disappears. Instead of chlorine, the bottle now contains hydrogen chlo- ride. This is a colorless gas. It fumes, or "smokes," when exposed to moist air, and forms a dense fog when you blow your breath over it. Hydrogen chloride is very soluble in water; the solution is hydrochloric acid (c/. 214). Hydrogen bums in i ~i f . . . j chlorine to give hy- An old name for it is muriatic acid. drogen chloride. 112. Ammonia. The two elements nitrogen and hy- drogen form a compound called ammonia. This is a colorless gas, which dissolves readily in water, forming "ammonia water" or "aqua ammonice." Ammonia water has the sharp odor of ammonia itself. Ammonia water is one of the bases (cf. 218). When a bottle of "strong" ammonia water and one of "strong" hydrochloric acid are brought together, the gases that arise from the solutions unite to form a white cloud of ammonium chloride, or "sal ammoniac" (Fig. 88). This is the white solid used in making the solutions 106 ELEMENTS AND COMPOUNDS for the batteries that ring electric door-bells, etc. (cf. 152). The same substance is formed in solution, when ammonia water and hy- drochloric acid are put together. Here we have an illustration* of the uniting of two com- pounds to form a more complex compound. FIG. 88. Gaseous ammonia and hydrogen chloride give white fumes of sal ammoniac. After Mellor's Chemistry. Courtesy of the publishers, Messrs. Longmans, Green & Co. 113. Sulphur. Sul- phur, or "brimstone/' is another element. It does not dissolve in water ; but it dissolves in carbon di- sulphide (cf. 95). When the solution is allowed to evaporate slowly, crystals of sulphur are obtained (Fig. 3). Carbon disulphide must be evaporated away from a fire, as it is very inflammable. Sulphur is found chiefly in volcanic regions such as in Sicily, Mexico, and Japan. Louisiana now produces more than any other state, and as much as Sicily. Sulphur burns in air or oxygen to give the colorless, suffocating gas, sulphur dioxide (cf. 51). This is used to bleach straw, silk, lace, wool, etc., which would be in- jured by chlorine (cf. 110). It is also used to destroy the germs of disease, and vermin, such as fleas. We make the gas for this purpose by burning sulphur "candles," or by pouring liquid sulphur dioxide (cf. 71) into saucers, and allowing it to evaporate. Hydrogen and sulphur form the compound hydrogen sulphide. This is a gas having the disgusting odor of rotten eggs. When eggs NUMBER OF ELEMENTS AND COMPOUNDS 107 decay, part of the hydrogen and sulphur they contain is given off as hydrogen sulphide. The gas burns in air, giving water and sulphur dioxide (cf. 105). It is present in the mineral waters known as "sulphur" waters. 114. Number of Elements and Compounds. The total number of compounds known is very large : probably several hundred thousand. All of these are made out of 80 or 90 elements. Most com- pounds contain only 2, 3, or 4 of these elements, and only about 30 elements are at all common (Fig. 89). We may compare the formation of com- pounds out of elements with the making of the many words of our language out of its 26 let- ters. In the following table Abundance of Eements in the we have the names of some compounds formed out of the elements we have been studying. Combined with Oxygen Nitrogen Carbon Chlorine Sulphur Hydrogen Water Ammonia Marsh gas Hydrogen chloride Hydrogen sulphide Oxygen Nitrogen oxide Carbon dioxide Chlorine oxide Sulphur oxide Nitrogen Nitrogen oxide Cyanogen Nitrogen chloride Carbon Carbon dioxide Cyanogen Carbon chloride Carbon disulphide Chlorine Chlorine oxide Nitrogen chloride Carbon chloride Sulphur chloride Sodium Sodium oxide Sodium nitride Sodium carbide Sodium chloride Sodium sulphide 108 ELEMENTS AND COMPOUNDS 115. Summary. Physical changes do not alter the nature of a substance; chemical changes do. Water is composed of hydrogen and oxygen. The electrolysis of water gives two volumes of hydrogen for one of oxygen. Elements are substances that have never been divided. Compounds are made up of elements that are united as the result of a chemical change. Mixtures are made up of elements or compounds not united chemi- cally. Hydrogen is prepared by the action of certain metals upon certain acids. It is the lightest substance known. Hydrogen burns with a very hot flame, forming water. Water is also formed in the burning of compounds of hydrogen, such as wood and coal. Diffusion is the mixing of substances because of molecular motion. Salt is sodium chloride. It is broken up by electrolysis into sodium and chlorine. Sodium is a metal, which burns, and which acts upon water. It reunites with chlorine, giving salt. Chlorine is a green gas, which has the power of bleaching and dis- infecting. Ordinary combustibles do not burn in it. Hydrogen burns in chlorine, giving hydrogen chloride. In solution this is hydrochloric acid. Ammonia is a compound of nitrogen and hydrogen. It unites with hydrogen chloride to give ammonium chloride, or "sal ammoniac." Sulphur burns to give sulphur dioxide. Hydrogen sulphide is formed by the decay of organic materials containing sulphur, such as eggs. The number of compounds is very large ; but most of them are made out of only 2, 3, or 4 elements. 116. Exercises. 1. What are the melting points of the following metals : sodium, tin, lead, copper, silver, gold, cast iron, steel? (See Appendix, Table V.) EXERCISES 109 2. Look up the densities of the following metals: sodium, alu- minum, iron, lead, gold. Is sodium heavier than water? 3. Bromine is an element similar to chlorine. Give the name of the compound it forms with sodium, with hydrogen, with carbon, and with sulphur. 4. When a jet of hydrogen issuing from a glass tube is first lighted, its flame is colorless and invisible; but when the glass becomes hot, the flame is yellow. What element forms a part of glass? 5. When common salt is treated with concentrated sulphuric acid, hydrogen chloride is formed. Where does its hydrogen come from? Its chlorine? 6. What compounds are formed when carbon disulphide burns? 7. When a ton of soft coal is heated, it gives off about 6 Ibs. of ammonia. What elements must coal contain? CHAPTER VII CARBON AND ITS COMPOUNDS 117. Carbon as an Element. We all know carbon as it exists in soot, coal, charcoal, and in the " black lead" of our pencils. It is a black solid; it does not dissolve in water; and even powerful chemicals, such as acids and bases (cf. 214), do not change it to any great extent. When it is heated to the right temperature, it burns, forming carbon dioxide (cf. 51). It is hard to believe that the bright, hard, and lustrous diamond (Fig. 75, 95) is a form of the same element as the black graphite (' ' black lead") and charcoal, yet it is true. If a pure sample of each of these substances is completely burned in oxygen, it gives nothing but carbon dioxide. If a diamond is heated in a tube containing no oxygen, it is changed to graphite. Carbon is of great importance for all life upon the earth. Living things are made up of wonderfully constructed compounds containing carbon. Proteids, sugar, starch, and fats are such compounds. When compounds of car- bon are heated, and can get plenty of oxygen, they usually burn. But when they are heated without sufficient air, or too rapidly, nearly all of them char, or "turn to car- bon." We have all seen this happen when sugar or milk have been spilled upon a hot stove, and when toast or meat have been "burned" by overheating. 118. Coal. All of the many different kinds of coal 110 USES OF THE FORMS OF CARBON 111 (Fig. 90) were probably formed from vegetable matter, such as leaves, boughs, trunks, and roots, that collected FIG. 90. Parallel Seams of Coal Outcropping on a Hillside. Clay beds lie under the coal. Here the other rock is sandstone; often it is limestone as well. After Hopkins. under water in past ages. This material was prevented from decaying by deposits of sand and mud, which kept out the air (cf. 38) while the change to coal was going on. In some imperfect coals the markings of the original wood can still be seen. In "soft," or bituminous, coals the change is usually more complete, but many carbon compounds still remain; while in anthracite, or "hard," coal the change of vegetable matter to coal is so complete that very little is present besides car- bon. See Fig. 91. ' 119. Uses of the Forms of Carbon. The element carbon is put to a multitude YEAR SHORT TONS TOO, 000, 000 200,000,000 300,000,000 400,000,000 1814-1820 424 1821-18*0 140,331 1891-18*0 1.031.642 1841-1850 14,534 58 itself becomes a magnet (Fig. 113), and A n ^ n h d el d f attracts iron filings or another nail. But ^f becomes a mag ~ when the nail is removed from the mag- net, its magnetic properties disappear. Thus, while steel can be permanently magnetized, soft iron forms only a temporary magnet. THE MAGNETIC FIELD 127 It is not necessary for the magnet to touch the nail in order that the nail may become a magnet. If the two are simply brought near each other, the nail takes on magnetic qualities. We say it is mag- netized by induction. Before a bit of iron is drawn to a magnet, it is magnetized by induction, and its N-seeking pole is attracted by the S-seeking pole of the magnet, while its S-seeking pole is repelled by the S-seeking pole of the magnet. The metals cobalt and nickel are also attracted by a magnet, but less than iron. One oxide of iron, the magnetic oxide, is also attracted, but rust is not. 138. The Magnetic Field. That a magnet can affect a magnetic needle, or a piece of nickel or iron, without touching it, shows that a magnet affects surrounding space; that it has about it a " region of influence. " This region is called the magnetic field (Fig. 114). It extends in all direc- tions from the magnet, but the strength of mag- netic attraction, like that of gravitation (cf. 20), becomes less as the dis- tance from the magnet increases. The magnetic needle may be enclosed in glass, but this does not cut off the magnetic field. Air is not necessary, for the magnetic influence is felt in a vacuum. We can readily trace the magnetic field, in cross section (Fig. 114), by placing the magnet under a sheet of glass or cardboard, and sprin- kling iron filings upon the glass or cardboard cover. When the cover is tapped gently, the filings arrange themselves end to end in the magnetic FIG. 114. The filings arrange themselves parallel with the magnet's "lines of force. " 128 MAGNETS AND ELECTRICITY field. If we use a cover of fresh blue print paper, and expose it to light with the filings in place, the position of the filings will be printed on the paper. 139. The Earth a Magnet. The earth itself is a great magnet, having its north and south poles. It is to these magnetic poles, not to the geographical poles, that the compass needle points. The north mag- netic pole is now in Northern Canada, inside the Arctic Circle. It is slowly moving westward. 30W FIG. 115. The North Magnetic Pole, the " Line of No Vari- ation," and the "Declination" in Different Parts of North America. The latest determination of the position of the north magnetic pole was made by Amundsen, the Norwegian explorer, in 1905; he found it to be in latitude 70 5' N., and in longitude 96 46' W. (Fig. 115). This is the same Amundsen who discovered the earth's south geographical pole in 1912. Since the earth's north magnetic pole is not the same as its north geographical pole, a compass will point due north only at certain places. The "line of no variation" is shown, for North America, in Fig. 115. For all places east and west of this line the compass shows a variation, or declination, from true north, and the amount of variation must be known if the com- pass is to be used accurately. In the eastern part of the EXERCISES 129 United States and Canada the compass points west of north ; in the western part, east of north. Columbus knew of the declination of the needle, and kept a record of its amount for many places in the Atlantic ; but to his sailors it was a source of great uneasiness, for they thought that the very laws of nature were changed in the new regions they passed through on their long voyage. Dipping Needle. If a magnetized needle is supported so that it will swing in a vertical plane (Fig. 116), instead of horizontally, it is called a dipping needle. Its north- seeking end will then dip noticeably in the northern hemi- sphere. Over the north magnetic pole it will stand verti- cal, the north-seeking end being downward. At the south magnetic pole the north-seeking end of the compass points upward. It is plain that the compass cannot tell north and south directions at the earth's magnetic poles, because there the magnetic force is all vertical. 140. Exercises. l.-If you had a compass and a bar magnet, how could you tell, without suspending the bar magnet, which of its ends was north- seeking? 2. How would a dipping needle behave at the "magnetic equator"; that is, on a line half-way between the earth's magnetic poles? 3. How would a dipping needle behave if brought near a large deposit of iron? How would a compass behave? 4. We believe that in a magnet the iron molecules are themselves magnets, set end to end. Draw a sketch of such an arrangement, marking the poles of each small magnet N and S respectively. 5. When a steel bar is held in the direction taken by a dipping needle, that is, pointing to the earth's magnetic pole, sharp blows on one end of the bar cause it to become a magnet. Suggest the reason. 130 MAGNETS AND ELECTRICITY 6. How could ships be steered in the right direction, out of sight of land, without the use of a compass? 7. Why are some magnets made in horseshoe form? 141. Electric Charges from Friction. If a glass rod is rubbed with silk, the rod will attract light bodies, such as paper, pith balls, cork, etc. (Fig. 117). If a pane of glass is placed upon two books, and rubbed with silk (Fig. 118), bits of paper or cork that are placed under the glass will be set in motion. A stick of sealing wax, or a hard-rubber ruler or comb, has the same power after it has been rubbed with fur or flannel or hair. The silk, flannel, and hair FIG. 117. become electrified, as well The charged . , -, 11 rod first at- as the glass, wax, and rub- tracts and * ' ber. In fact, any two unlike substances are FIG. us. "charged" by rubbing; a part of the ^JjJk^Lifetft muscular energy used up in the rub- ^ e n ath move up and bing is changed into electric charges. The ancient Greeks knew that amber, a fossil gum, would attract bodies after being rubbed. Amber was called "electron"; hence our words, electric, electricity, etc. 142. Conductors and Insulators. Dr. Gilbert, the physician of Queen Elizabeth, found that some bodies could be electrified by rubbing, and that others could not. So he divided bodies into "electrics" and "non -electrics." Because metal rods, held in his bare hand while being rubbed, were not charged, he called metals "non-electrics." If he had held the metal in a dry wooden or silk handle, ATTRACTION AND REPULSION 131 he could have electrified the metal as well as the glass. His own body acted as a conductor, and the charge passed through it to the earth. We now call bodies conductors, or non-conductors. Non-conductors are also called insulators, from the Latin, insula, an island. A charge formed on one end of a glass rod remains where it. was produced; but if one end of a metal rod is rubbed, the whole rod is charged. The glass is an insulator, the metal a conductor; but both are "electrics." Some of the best conductors are: metals, charcoal, water vapor, and wet substances generally. Some of the best insula- tors are: dry cotton, wool, wood, silk, glass, wax, rubber, and shellac. Since the earth is a good conductor, a charged conductor will lose its charge if it is not insulated from the earth. 143. Attraction and Repulsion. If an electrified body is brought near bits of paper, they are first attracted, and then repelled. This phenomenon is studied most easily if an "electric pendulum" is used. One is shown in Fig. 119. It is sim- ply a ball of pith, or of cork, suspended by a thread which insulates it. If a glass rod, charged by rubbing it with silk, is held near the ball, the ball is attracted to the rod. After it has obtained a charge from the rod, it is repelled. If a stick of sealing wax, charged by rubbing it with flannel, is now brought near the charged ball, the ball is attracted. .Since the charged sealing wax attracts what the charged glass repels, we say that the glass and wax are oppositely charged. If we call the charge on the glass positive (+), that on the wax is negative ( ). It will be found that the silk has received a negative FIG. 119. Like charges repel each other. 132 MAGNETS AND ELECTRICITY charge by being rubbed with glass, while the flannel rubbed with wax or rubber receives a positive charge. The laws of charged bodies are like those of magnets (cf. 136) : 1. Charged bodies attract uncharged bodies. 2. Bodies having unlike charges attract each other. 3. Bodies having like charges repel each other. The space sur- rounding a charged body is called an " electric field" (cf. 138). 144. Induction of Charges. We have learned ( 143) that an uncharged body is charged by contact with a charged body. It may also be charged by induction, without contact. A simple apparatus for showing this is an egg shell covered with_tin foil (Fig. 120). If a posi- tively (+) charged glass rod is brought near the shell without touching it, the shell will be electrified by induction. An uncharged cork ball will be attracted by either end of the shell. If the glass rod is removed, the charges disappear. We say they neutralize each other. We FIG. 120. can charge the shell permanently if we Egg tnd 1 un gedby remove one of the charges induced by the glass rod. To do this we hold the rod near the shell, as before, and then touch with the finger the end of the shell farther away from the rod. The repelled positive charge passes through the hand and body to the earth. If the glass rod is now removed, the shell will have a negative ( ) charge. 145. Electric Discharge. If the finger is held near a charged glass rod, sparks pass between the two. The sparks are larger if the finger is held near a charged ELECTRICITY OF THE ATMOSPHERE 133 conductor, for the whole conductor is discharged at once. The strain in the electric field is greatest around the points of an object; hence a discharge takes place very easily from points, but less readily from blunt portions. When the spark passes, the air is heated, and its rapid expansion and contraction produce a sharp explosion." 146. Storing a Charge; the Leyden Jar. Apparatus for storing frictional electricity (Fig. 121) is made of two conductors (metal foil) separated by a non-conductor, such as glass. If one conductor is connected with a source of positive charges, while the other conductor is connected with the earth, the negative charge of the second con- ductor is held on the side of the metal next to the glass, but the positive charge of the second conductor is repelled to the earth. If the earth connection is then removed, we have a large positive charge on one side of the glass, and a correspondingly large negative charge on the other side. Earth FIG. 121. An Electric Condenser. Ear FIG. 122. The Leyden Jar; an Electric Condenser and Storing Appa- ratus. The most common form of the apparatus is the Leyden jar (Fig. 122); this consists of a glass bottle, partly covered, both inside and outside, with metal foil. If we charge the j ar with frictional electricity, and then almost connect the two foils by some conductor, a strong spark discharge takes place. 147. Electricity of the Atmosphere. Benjamin Frank- lin showed that a lightning discharge was only a large 134 MAGNETS AND ELECTRICITY spark of electricity. One day in June, 1752, when a thunderstorm was coming on, he sent up a kite having at its top a pointed wire. On the lower part of the string he had a key, and the kite-string was insulated from the earth (Fig. 123). When the kite-string became wet, so that it could con- duct electricity, Franklin obtained sparks from it. The sparks were ex- actly like those obtained by fric- tion. When two charged clouds approach each other, the strain in the "electric field" between them becomes so great that, finally, the charge bursts through. This is lightning (Fig. 124). If the charge passes be- tween a cloud and the earth, we say that the lightning strikes. The two clouds, or a cloud and the earth, with the non-conduct- ing air between them, thus form a huge Ley den jar. Thunder is due to the rapid expansion and contraction of the air heated by the lightning. 148. Lightning Rods. The electric charge " induced" on the earth Insulator FIG. 123. Franklin's kite was "charged by induction" from a charged thundercloud. Note the spark. EXERCISES 135 by a passing thundercloud is greatest in projecting objects, such as trees, spires, and hilltops (cf. 145). Commonly the leaves of trees conduct the charge from the earth quietly, as a "silent discharge," and prevent the striking of lightning. Franklin reasoned that a pointed conductor a lightning rod would perform the same ser- vice for a house. To be a real protection a lightning rod should have a large diameter, should have a large number of points, and should extend far enough into the ground so that it will always end in moist earth. 149. Exercises. 1. When hair is combed or brushed vigorously in cold, dry weather, it often ' ' fluffs out," showing that the individual hairs are repelling one another. Ex- plain. 2. If, in cold, dry weather, you ' ' skate " in your slip- pers across a woolen carpet or rug, and then bring the tip of your finger near a gas jet or other metal object, a spark often passes between your finger and the object. Explain why. 3. If you rub a stick of sealing wax with flannel, the wax receives a negative ( ) charge. If the charged wax is brought near an un- charged "electric pendulum," what happens? When the pendulum is repelled, what kind of a charge does it have? If, now, you bring near the charged pendulum a rubber comb which has been rubbed with flannel, and you find that the comb repels the pendulum, what kind of a charge is there on the comb? A Lightning Discharge. FIG. 124. Field Museum of Natural History. 136 MAGNETS AND ELECTRICITY 4. Why is it dangerous to stand under a tree in a thunderstorm? 5. Read about the life of Benjamin Franklin. What did he do for science, for business, and for the American Colonies? 150. Electric Currents. Magnetism and frictional electricity, the two kinds of electrical phenomena already studied, are closely related to the third form, electric currents. The study of currents begins with the electric, or "voltaic," cell, a contrivance by which the energy set free in certain chemical reactions appears in the form of electricity, instead of as heat or light (cf. 51, 105, and 109). Methods of producing currents were first studied by Galvani, in 1786, and by Volta, in 1792. We have already learned (cf. 103) that zinc and dilute sulphuric acid give hydrogen. The chemical change also produces a substance called zinc sulphate. Besides both of those the reaction produces heat. But when both zinc and copper are put into dilute sulphuric acid (Fig. 125), and the ends of the metals outside of the liquid are joined, a current flows through the wire, the metals, and the liquid. The metals may be joined by simply allowing them to touch each other. The zinc wastes away, just as when it is used alone; but in exchange we get the current. A simple way to find out whether or not a current is passing through the wire connecting the metals is to " taste" the current. We do this by touching the tongue with the ends of the wires a little distance apart. The current produces a sharp sensation. Copper Cop- Zinc per FIG. 125. Two Forms of the Simple Cell. The current flows in the di- rection of the arrows. KINDS OF CELLS 137 In making a cell we may use other metals instead of zinc and copper. We choose one metal that acts readily with the acid, arid one that does not. Carbon plates are often used instead of copper ones. Both plates must be conductors. Solutions of other acids, of bases, or of certain salts (cf. 214, 218, and 220) may be used instead of the dilute sulphuric acid. To bring the free ends of the metals into connection, so that there can be a current, is called ''making," or "closing, the circuit"; the re- verse is called "breaking," or "opening, the circuit" (cf. 100). A number of properly connected cells is called a battery. 151. Kinds of Cells. The voltaic cell is of little prac- tical use in its simplest form, because it is soon weakened, or stopped entirely (we say it is " polarized "), by the bubbles of hydrogen that collect upon the copper plate. The hydrogen is formed by the action between the zinc and the acid. A description of DanielFs cell also called the gravity cell will show one way in which polarization is avoided. In Darnell's cell (Fig. 126) the two plates, zinc and copper, are given a "crowfoot" shape to increase their surfaces. The cop- per is placed at the bottom of the jar in a saturated solution of copper sulphate (blue vitriol), while the zinc, which is in the upper A Gravity, or part of the jar, is surrounded by dilute sul- Daniell> G ' eU * phuric acid. The copper sulphate solution is the heavier, and remains at the bottom; hence the name ' t gravity " cell. The action of the cell is as follows: The zinc reacts with the dilute sulphuric acid, giving zinc sulphate and hydrogen. The hydrogen moves toward the copper plate; but in passing through the layer of copper sulphate the hydrogen is used up, and copper is deposited in its 138 MAGNETS AND ELECTRICITY FIG. 127. Sal Ammoniac Liquid and Dry Cells. place. Thus polarization is prevented. Daniell's cell is much used for the operating of telegraph instruments (cf. 155). 152. Sal Ammoniac Cells. Sal ammoniac cells (Fig. 127) are used where a strong current is needed for a short time, as for ringing telephone and house bells. The liquid used is a water solution of sal ammoniac, or am- monium chloride (cf. 112). The conduc- tors are a rod of zinc and a plate consisting of carbon and manganese dioxide. Dry Cell. A "dry" cell is enclosed in a zinc jar, which serves as the zinc plate. The space between the zinc and the carbon is filled with a paste consisting of sal am- moniac, manganese dioxide, charcoal, and water. The cell is closed so that the water cannot evaporate. 153. Currents and Magnetism. As we learned in 150, we can test a circuit for the presence of a current by bringing the free ends of the conducting wires in con- tact with the tongue. Of course this will not do for very weak or very strong currents. A second way of testing for a current is to bring the wire of a closed circuit near a magnetic needle or compass. The needle will be turned from its N-S position. If the current is sufficiently strong, and the bare conducting wire is dipped into iron filings, some of the filings will cling to the wire. Both of the last two tests show that a wire carrying a current is surrounded by a magnetic field: that it is a magnet. 154. Electromagnets. Since a conductor that is carrying a current is surrounded by a magnetic field, we THE TELEGRAPH 139 should expect that a piece of soft iron placed inside a coil of the wire would become a temporary magnet, just as when it is in the field of a bar magnet (cf. 137). Such magnets are called electromagnets. The coil must be made of insulated wire, so that the successive turns may not touch one an- other. If they do touch, the current will not pass through all the wire, but will be " short circuited. " The greater the number of turns in the coil the stronger the magnetic field will be, and the stronger the electromagnet. But as soon as the circuit is broken, the electromagnet is demagnetized. The coil of wire is called the helix; the iron is called the core. A core made up of a bundle of small iron wires makes a much stronger electromagnet than one in a single piece. Telegraph instruments, telephone bells, electric doorbells, fire alarms, and many other de- vices are operated by electromagnets. Earth_ j_ _ FIG. 129. A Simple Telegraph Instrument. When the key is pressed, the circuit is made complete, and the sound- er is drawn down by its electromagnet. 155. The Tele- graph. The tele- graph instrument (Fig. 129) consists essentially of a' key for making and breaking the circuit in an electromagnet, and thus pro- ducing "clicks" in the sounder. The sounder is a small lever (cf. 198) which is held by a spring against its upper stop. Opposite the core of the electromagnet is a piece of soft iron called the armature. When the key is pressed 140 MAGNETS AND ELECTRICITY down, and the circuit is thus closed, the core is magnetized, and draws the sounder to the lower stop. This produces a " click." When the key is released, the sounder springs back. The current is usually supplied by a " gravity" battery. Only one wire is needed, for the return circuit is through the earth (cf. 146). There is no interference between these earth circuits, in spite of the large number of messages passing at the same time. In the original telegraph, as made by Morse in 1832, a moving strip of paper was placed under the sounder. If the circuit was kept closed a very short time, a dot was made upon the paper; if for a longer time, a dash was the result. Combinations of dots and dashes made up the alphabet. The " printing telegraph" is rarely used now, for messages are taken much more rapidly by ear. The telegraph code is as follows: I - ---- 2 -- --- m w -- 3 ---- -- n -- x - - - 4 ----- o - - y - - - - 5 ~ p ----- z --- - 6 ...... q ---- & ---- r - -- , - --- 8 ----- s --- ? ------ 9 ---- - t - . ------ 156. The Electric Bell. The electric bell (Fig. 130) has a push-button for closing the circuit and thus operat- ing the electromagnet. The hammer of the bell and the armature are attached to a spring. When the electro- magnet attracts the armature, the hammer strikes the bell. But at the same instant the circuit is broken, and the spring throws the armature back against the stop. The circuit is thus closed once more, and the armature is again attracted. In this way the hammer is made to give the bell a rapid succession of blows. ELECTRIC FURNACES 141 157. Changes Produced by the Current. The difficulty which a current meets in passing through a conductor is called resistance. Some substances are much better conductors than others. Thus, a silver wire is a better conductor, that is, has a smaller resistance, than a platinum wire of the same diameter. For any given ma- terial, the smaller the diameter of the wire the greater the resistance. The heating effect of German silver wire of high resist- ance is used in the electric heater, electric pad, electric flat-iron, and electric stove. In passing through a fine wire of platinum or carbon, the current finds so much resistance that it heats the wire white hot, forming the incandes- cent- electric light. If carbon wire is used, it must be placed in a bulb free from air, or the carbon will burn up (c/. 51). The "arc" electric light (Fig. 131) consists of two pencils of gas carbon (cf. 119) placed such a distance apart that there is great resistance at the gap between them. The heat produced changes some of the carbon to the vapor state, and makes the vapor white hot. The temper- ature produced is about 3,800 C. 158. Electric Furnaces. An electric arc furnace (Fig. 132) is an arc lamp enclosed in a box made of high-melting materials, such as fire clay, lime, or magnesia (magnesium oxide; cf. 48). 142 MAGNETS AND ELECTRICITY The resistance furnace (Fig. 133) has two poles able to deliver a powerful current. We "close the circuit" by packing between the poles the materials that are to be heated. The resistance due to the materials changes the energy of the current into heat. In the intense heat of electric furnaces man has been able to turn metals like gold and platinum into vapors, and to prepare many substances of great commercial importance. Among these are graphite (cf. 119), carborundum, a very hard abrasive (scouring and polishing material), and calcium carbide, a gray solid that reacts with water to give acetylene, the gas used in acetylene lamps (cf. 257). FIG. 132. Electric Arc Furnace. 159. Electroplating. We have learned that when the electric current is passed through dilute sulphuric acid, hydrogen collects at one pole, and oxygen at the other (cf. 100). If the current is passed through a solu- tion of copper sulphate, copper is formed at one pole, and oxygen and sul- phuric acid at the other. FIG 133 In this Case the COpper Resistance Furnace. The materials to be sulphate is used up. But if the pole at which the current enters the solution is of copper, the copper sul- phate is not used up. What happens is that copper wastes away at one pole, and is deposited at the other. An object placed at the receiving pole will be electroplated with copper. . heated are poured through the hoppers A, A, and the current is passed between B and B. DYNAMO 143 Battery FIG. 134. The copper plate forming the + electrode (pole) wears away, but an equal amount of copper is de- posited on the impression of the type (the elec- trode). In this way a copper film is formed which is the exact image of the type. This is the way in which electrotype plates of the pages of books are made (Fig. 134). An impression of the type is prepared in wax, this is covered with graphite (cf. 119) to make it a conductor, and the wax mould is then made the receiving pole in a cop- per sulphate "electrolytic bath." The copper de- posit is an exact copy of the type. It is, however, very thin; hence it is strengthened, at the back, by a filling of melted metal. The original type is free to be used over and over again in the setting up of other pages of the book. Silver-plating (Fig. 135) is carried out in a similar way. The solu- tion contains a silver compound, the pole that wastes away is of silver,, and the object to be plated is made the receiving pole. 160. Dynamo. On a small scale, currents may be produced by batteries (cf. 150) ; but for larger uses men need more economical and more powerful generators. These are commonly known as dynamos. We have learned that when a bar of soft iron, or a bun- dle of soft-iron wires, is put into the field of a coil carry- ing a current, the soft iron becomes magnetized (cf. 154) . Equally important is the fact that when a magnet is introduced into, or removed from, a coil of insulated wire, a current is produced Fia. 135. Silver-plating. 144 MAGNETS AND ELECTRICITY in the wire, kept moving. The current flows as long as the magnet is This is illustrated by Fig. 136. The moving of the magnet causes the wire constantly to pass through new portions of the magnet's field. Instead of moving the magnet within a fixed coil, we can keep the coil in mo- tion, while we leave the magnet stationary. This is the principle of the dynamo (Fig. 137). A revolving frame, called the armature, is wound with many separate coils of wire. As each coil ap- proaches and leaves the magnetic field, currents are pro- duced in the wires. These are drawn off, as rapidly as they FIG. 136. A magnet moved into or out of a coil produces a current in the coil. FIG. 137. A Direct Current Dynamo, Directly Connected with an Automatic Engine. Courtesy of the Ridgway (Pa.) Dynamo and Engine Co. are produced, through wires attached to the poles of the dynamo. The dynamo current may be used for the pro- duction of heat or light, or it may be run into the motors of trolley cars, etc., and used to produce motion. ELECTRIC POWER 145 161. Electric Motors. The motor has practically the same construction as the dynamo, but its action is that of the dynamo reversed. That is to say, while in the dynamo we cause the coils of the armature to revolve in the field of the magnet, and thus produce a current, in the motor we run a current into the armature, and cause it to revolve, producing motion. The motion of the arma- ture can be passed on, by gear wheels or by belts, to the wheels of a street car, or of whatever is to be set in mo- tion. In other words, in the dynamo we exchange mechan- ical motion for an electric current; but in the motor we exchange the current for mechanical motion. Electric motors are used not only for the moving of vehicles, but also for running the machinery of factories, sewing machines, washing machines (cf. Fig. 194), electric fans, vacuum cleaners, etc. e Electric Street Cars. In the trolley car the motor is generally under the car, and the current is supplied by the generators (dynamos) of a power house (Fig. 138). The current is carried by a "feed wire" to the trolley wire, or third rail, from which it passes to the motor of the car. The return circuit for the current is through the car track. 162. Electric Power. Electric power may be generated in dynamos by engines using coal, gasoline, petroleum, etc., as sources of energy, or the power may come from the wind, waterfalls, rapids, or dams. Niagara furnishes power not only for many electric furnaces and for processes of electrolysis, but for lighting cities like Buffalo and Roches- 146 MAGNETS AND ELECTRICITY ter, and for propelling, lighting, and heating trolley cars within a considerable distance. The control of water power is everywhere giving the energy needed for electric power (Fig. 139). This is true of the great dam at As- souan, in Egypt, the Gatun dam of the Panama Canal, and the dam across the Mississippi, at Keokuk, Iowa (Fig. 140). 163. Summary. Magnets are natural or artificial. Natural magnets are lodestones. All magnets, when freely suspen- ded, point toward the earth's magnetic poles, unless they are interfered with by large masses of iron, or by local magnetic fields. Two magnetic poles of the same kind repel each other; those of opposite kind attract each other. Soft iron forms temporary magnets; steel forms permanent magnets. Iron, steel, magnetic cobalt, nickel, etc., are magnetic; that is, attracted by FIG. 139. Water from a higher level falls through a penstock against the guides of the turbine. The guides direct the rushing water upon the blades, causing them to revolve rapidly. The whirling turbine turns the shaft and the generator attached to it. iron oxide, a magnet. A magnet attracts a magnetic body by first inducing it to become a magnet. The earth is a magnet, with two magnetic poles. These are found by the dipping needle, as well as by the compass. The compass has been of the greatest use in the development of navigation and civilization. Frictional electricity is commonly developed by rubbing two sub- SUMMARY 147 stances together. Conductors can be electrified only if held by means of an insulator. An electrified body attracts one not electrified, then charges it with its own kind of electric charge, and then repels it. The space around a charged body is an electric field. An insulated body brought into the field is electrified by induction. FIG. 140. Generator Room of the Mississippi River Power Co. at Keokuk. A dam 4,649 feet long extends across the river, and raises the water behind the dam. Some of the water rushes through turbines, generating 200,000 horse power (cf. 26) of electricity. About a third of this is carried to St. Louis, 137 miles away. When the strain in the electric field between two oppositely charged bodies becomes sufficiently great, a discharge takes place, usually as a spark. Discharge takes place most easily from points. An electric condenser consists of two conductors, such ^s metal foil, separated by a non-conductor, such as glass. The common form is the Leyden jar. Franklin proved that lightning is a huge electric spark. His kite was electrified by induction from the charged cloud. Electric currents are usually generated in cells or by dynamos. The simple cell consists of zinc, copper (or carbon), and dilute sulphuric acid. The current flows from zinc to copper inside the 148 MAGNETS AND ELECTRICITY liquid, and from copper to zinc outside of the liquid. A group of con- nected cells is a battery. The simple cell is easily polarized by the hydrogen which collects upon the copper (or carbon) plate. Polarization is prevented, in Daniell's cell, by a layer of copper sulphate solution between the zinc and the copper. In other cells oxidizing materials are put into the solution, or mixed with the carbon. These convert the hydrogen into water. Wires carrying currents are magnets. Electromagnets are formed when soft iron is put into coils carrying currents. The telegraph is essentially an electromagnet, with a key for making and breaking the circuit. The electric bell is an electromagnet in which the armature carrying the hammer continually breaks the circuit, causing the hammer to vibrate back and forth. The resistance which the current meets in passing through con- ductors appears as heat. This is the principle of electric lighting and heating devices. Electroplating is due to the electrolysis of solutions of the com- pounds of certain metals, such as copper, silver, gold, nickel, etc. A dynamo is a device in which coils of wire, moving rapidly through the fields of powerful magnets, produce a current. A motor is a dynamo reversed. In it an electric current is changed into mechanical motion. Men get electric power on an enormous scale by changing the mechanical energy of falling water into electric currents. 164. Exercises. 1. If piece of steel is held near a dynamo, it is pulled strongly toward the dynamo. If held there for a short time, it becomes a magnet. Explain both facts. 2. Write in the Morse code: Will visit your school Tuesday, April 9. Leave short spaces between letters and longer ones between words. 3. Read an account of the life of Morse, the inventor of the tele- graph. EXERCISES 149 4. What is meant by the terms " triple plate, quadruple plate," etc., as applied to silver utensils? 5. How could a slab of impure copper be purified by the electric current? 6. How could coal be converted into energy at the mine, and this energy distributed without the shipping of the coal? 7. When the lighting system of a trolley car is on the same circuit as the power, the lights often burn low while the car is being started, but burn brightly when the car is in motion. What does this show as to the power required to start the car as compared with that needed to keep it moving? 8. What advantages has electric power over steam power for factory use? For the home? CHAPTER IX LIGHT AND SOUND 165. Luminous Bodies. Every object that we see " is seen/' or " is visible/ ' because light from the object enters the eye. When the visible body itself produces the light, the body is said to be self-luminous. Self-luminous bodies are usually very hot. This is the case with the sun, a lamp flame, an arc electric light. However, most visible bodies are not self-luminous; but they shine, or are seen, by light which they receive, and then reflect to the eye. We say that non-luminous bodies are illuminated by luminous bodies. The moon is a non-luminous body. Moonshine is sunshine reflected to us from the moon's surface. An object seen by moonlight is thus seen by sunlight that has been reflected twice: first from the moon to the object, and then from the object to the eye. When we take a lamp into a dark room, we see the objects in the room, because they reflect lamplight to the eye. 166. Transparent and Opaque Bodies. Substances through which objects are seen clearly are said to be transparent. Such are water, glass, and air. A substance that does not permit light to pass through it is said to be opaque. Wood and iron are opaque. Certain substances allow some of the light to pass, but objects cannot be seen distinctly through them; such substances are said to be 150 IMAGES THROUGH SMALL OPENINGS 151 translucent. Examples of translucent substances are fog, ground glass, oiled paper, and thin china. Very thin plates of all bodies, even metals, are translucent. Thus, gold foil transmits a green light. 167. Light and Its Properties. Light is the cause outside of us that produces the sensation of sight. Sun- light produces other effects besides the lighting of objects. Thus, if the skin is exposed to sunlight, it is not only illuminated, but also warmed. In addition, chemical changes are brought about in the skin, and it is tanned. The energy of the sun thus appears as heat, light, and chemical energy. The velocity of light is very great: about 186,000 miles a second (cf. 11). Sound waves travel through air at the rate of about 1,100 feet a second; but this is a snail's pace as compared with light. Be- cause of the greater speed of light we see the flash of a gun before we hear its report, and we see the lightning long before we hear the thunder that accompanies it. Light travels in straight lines through a transparent substance, if the density of the substance is the same throughout. A single line of light is called a ray, and a number of parallel rays make up a beam. A sunbeam is an example. If a sunbeam enters a dark, dusty room, its straight path is shown by the illuminated dust particles. On a foggy night a street lamp sends out straight lines of light in all directions. These observations show that light travels in straight lines. The same thing is shown by the formation of images and shadows. 168. Images Through Small Openings. An easy way to learn how images are formed is to let light pass through the small opening of a " pin-hole camera." The camera (Fig. 141) consists of a box with both ends removed. A hole is cut in one of the remaining four sides of the box, 152 LIGHT AND SOUND and over this is pasted a strip of tin foil. A smooth pin- hole is made in the foil. The inside of the box is black, except for a white space just opposite ,- : -_-n the tin foil. If the room is darkened, - Jw> and a small, lighted candle is placed FIG 141 before the pin-hole, an image of the when light from an object candle is seen inside the box, on the passes through a pin-hole into a darkened box, the white screen: but the image is corn- image is inverted. ' pletely turned about. The explanation is as follows: The candle flame is sending out rays of light from a large number of points on its surface. Each of these points sends a small beam through the pin-hole, and the beam, when it strikes the white screen, makes an image of the part of the candle flame from which it came. But all the beams cross at the pin-hole. Hence the light from the top of the flame will form the bottom of the image, and the light from the right side will form the left side of the image, and the image is completely inverted. A landscape seen through a very small point is also turned about. 169. Shadows. That light travels in straight lines is shown, also, by the forming of shadows. When an opaque body is put in the way of light rays, it cuts off the light from the space behind it, producing a shadow. If the source of light is very small (S, Fig. 142), the shadow is very distinct. But if the luminous body has a consider- able surface, and sends out n FIG. 142. The shadow cast by an object that is light from many points, the jJ^j^^arkSess point f light is f shadow will have two parts: one receiving no light at all, and the other getting light from part of the luminous surface, but not from all of it. BRIGHTNESS, OR INTENSITY, OF LIGHT 153 We call the distinct shadow, which receives no light at all, the umbra; the indistinct part surrounding the umbra is called the penumbra. Fig. 143 gives the illustration : FIG. 143. The shadow cast b y an object that is illuminated by the sun's surface consists of umbra and penumbra. Let us suppose that the moon, in the cone- hnrPrl crmpp to tVP rio-Vit rigm of the earth, is entirely cut off from sunlight. To an observer on that side of the earth the moon would be entirely eclipsed by the earth's shadow (cf. 3). To an observer on the moon the sun would be entirely eclipsed by the earth. But if the moon were in the penumbra of the earth's shadow, an observer on the moon would see the earth as a black body covering part of the sun's disc, but not all. If an observer could stand just at the tip of the umbra, and facing the earth, the sun's face would be just exactly covered by the earth. 170. Brightness, or Intensity, of Light. We all know that the distance of an object from a source of light affects the amount of light received by the object, or the intensity of the light. Now, if one boy holds his book twice as far away from a reading lamp as another boy does, he receives, not % as much light, but M as much light as the other. A third boy, sitting three times as far away as the first, receives only l / 9 as much light, and so on. The reason for this is shown by Fig. 144. Two square cards, 1 inch and 2 inches on each edge, respectively, are placed in vertical positions on the same PIG 144 side of the lamp. The lamp should be An object twice as far from the lamp Very Small, SO that its light shall COHie as another gets only M as < , n A. / / e i nr\\ much light. from practically one point (cf. 169). 154 LIGHT AND SOUND The area of the smaller card will be 1 square inch; of the larger, 4 square inches. If we place the smaller card 4 inches from the lamp, and the larger card 8 inches (twice as far) from the lamp, then the shadow cast by the first card will just cover the second card. This means that the light which falls on 1 square inch at distance 1 is spread out over 4 square inches at distance 2. Therefore the intensity, or brightness, of the light on the more distant card is not H of the brightness on the nearer card, but H X H, or 3^ as great. 171. Candle Power. The intensity of the light given off by lamps is always stated as so many " candle power." This is because the unit of intensity is the illuminating power of a standard candle. The standard candle is of sperm fat, weighs Ye of a pound, and burns at the rate of 120 grains (7.78 grams) an hour. We get the candle power of a lamp by using a photometer (Fig. 145). This consists of a piece of oiled paper or cardboard, supported in a frame, and a pencil that can be set upright near the frame. The work must be done in a room that is dark, except for the lamp and candle to be compared. These two are lighted, and placed so that the two shadows of the pencil shall fall on the oiled screen side by side. The distance of the lamp or candle is then altered, so that the shadows are equally dark. Suppose that the distance between the candle and its shadow is 1 foot, and that between the lamp and its shadow, 4 feet. We square each of these numbers; that is, we multiply each by itself. The square of 1 is 1, and that of 4 is 16. So the lamp has an illuminat- ing power 16 times as great as that of the candle. We say it is a " 16 candle-power " lamp. 172. Exercises. 1. At about 525 C. iron becomes red hot. Is iron illuminated FIG. 145. How to get the "candle power" of an electric light. DIVISION OF THE LIGHT STRIKING A BODY 155 or self-luminous when we see it below this temperature? When we see it above this temperature? 2. What reasons have we for believing that the moon is not self- luminous? 3. Classify the following substances as transparent, translucent, or opaque: ice, snow, alcohol, milk, iron, the material of our finger nails, skin, tissue paper, carbon dioxide, a solution of blue vitriol. 4. I see a carpenter, down the street, driving nails; but the sound of each blow comes to me just as I see the hammer raised for the next blow. Why? 5. A flash of lightning is seen 10 seconds before the thunder is heard. How far away is the thunder cloud? 6. Sirius, the brightest of the fixed stars, is about 8 light-years distant (c/ 11). How many miles is this, if we call the speed of light 200,000 miles a second? 7. What are the positions of the sun, the moon, and the earth when we have " new moon "? When we have " full moon "? At which of these times may we have an eclipse of the moon? At which an eclipse of the sun? 8. Why is the shadow cast by a light of small diameter, such as an electric bulb, so distinct? 9. I sit 5 feet from a lamp, while my brother is 1 foot from the lamp. How much more light does he get than I? 10. In a photometer (Fig. 145) a candle at a distance of 1 foot casts a shadow just as dark as one cast by a lamp 6 feet away. What is the lamp's candle power? 173. Division of the Light Striking a Body. When light meets a body, several things may happen : (1) The light may be thrown back reflected in a regular way and in certain definite directions. (2) It may be reflected irregularly dispersed in all directions. (3) It may pass through the body it meets. (4) It may be absorbed by the body. 156 LIGHT AND SOUND FIG. 146. The angle of incidence is equal to the angle of reflection. Usually two or more of these results take place at the same time. 174. Reflection of Light. If you throw an elastic ball, such as a tennis or golf ball, vertically downward against a horizontal sidewalk, you expect it to bound back vertically upward. But if you throw the ball downward in an inclined direction, as A C of Fig. 146, it bounds off in another inclined direc- tion CB. Except for the effect of gravity on the ball (cf. 21) the angle made by AC with CD (angle A CD) is of the same size as the angle made by CB with CD (angle BCD). The first angle (A CD) is called the angle of incidence (i. e., falling upon); BCD is the angle of reflection (i.e., bending back). The rule is: The angle of incidence equals the angle of reflection. Light and sound are reflected in the same way as the ball. If A of Fig. 146 represents a small opening through which a beam of light is admitted into a dark room, and if the reflecting surface at C is a smooth plane mirror, you will see the reflected beam only when your eye is placed somewhere on the line CB. 175. Mirrors. 'A mirror, or looking-glass, is a good reflector of light, because at its back there is a thin layer of a metal, usually silver. You have noticed that when you look at any object, including yourself, in a mirror, the right- hand side of the object becomes the left-hand side of the MIRRORS 157 R FIG. 147. image of the object. If an open book is held toward a mirror, the image has the printed matter backward. A watch showing 9 A. M. forms an image in N which the hands are where we expect ~ them to be at 3 p. M. Let us see how the regular reflection of light produces images. Suppose that MR of Fig. 147 represents a The eye sees an object in ... ,. the direction from which vertical mirror, and that a point or some object the light of the object is at 0. Rays of light from strike the surface of the mirror everywhere; but only the ray that meets the mirror at F passes to the eye, according to the rule of reflection (174). But the eye sees only in the direction from which the light ray comes as it enters the eye; so appears to be in the imaginary position O f (read this: prime). 0' is just as far back of the mirror as is in front of it. Now suppose that the object is not one point, but many points. An The image of arrow is a convenient form of object (Fig. 148). The fna J p C ia e ne image of the arrow is of the same shape as the arrow skuTup "but itself, but reversed sidewise. Ibt^ieft A piece of polished plate glass (Fig. 149), if looked at at the right angle, will be a mirror, and yet be a transparent body at the same time. If a bottle of water is placed behind the glass, and a burning candle in front of it, we see both objects in the direction from which their light comes to the eye. Hence the candle and the bottle appear to be in the same place, behind the plate glass, Athickgl asspiat 9 e acts both and the candle seems to be burning in transmitter^ fight ; a thl . -i candle seems to be burn- tne Water. ing in the water. FIG. 148. 158 LIGHT AND SOUND 176. Diffused Light. When a reflecting surface is rough, the light striking it is dispersed in all directions. It is by diffused light that we see most objects. Daylight is sunlight dispersed by reflection from the ground, trees, houses, dust, clouds, etc. Moonlight is uniformly diffused sunlight from the moon's surface. We see the " old moon in the new moon's arms " by earthshine; that is, by sunlight that has been re- flected by the earth to the moon, and has then come back to the earth. FIG. 150. 177> Refraction of Light. Let us If an object under water is ^ looked at obliquely, it suppose that in Fig. 150 we have a seems to be at one side of and vessel partly filled with water, and that we drop a stone (S) into it. To the eye the stone does not appear to be S, but a little to one side, and nearer the surface; that is, at S'. The explanation is that water is denser than air (cf. 33), and that the light which comes from the stone to the eye is bent at B, where it passes from water into air. It is bent away from the direction of the line SB. Since we see an object in the direction which its light has as it enters the eye, the stone appears to be at S'. Because light is refracted in passing from water into air, the water of a pond or stream seems to be more shallow than it really is, and a reed or an oar seems to be bent where it enters the water. For a similar reason a star near the horizon appears to be higher up than it really is (Fig. 151). Its light is bent as it enters the earth's atmosphere (cf. 38) from A ^Jj^ hori . outside space. The amount of bending increases as zon appears to be ,, higher up than it the star's light approaches the earth, because the really is. COMPOSITION OF WHITE LIGHT 159 FIG. 152. Forms of lenses. air becomes more and more dense (cf. 41). A heavenly body is, therefore, never where it seems to be, except when it is at the zenith; that is, directly overhead. 178. The Lens. A lens is a piece of transparent mate- rial, usually glass, having two curved surfaces, or a curved and a plane surface. Six forms of lenses are shown in Fig. 152. When rays of light pass through a lens, they are bent toward the thickest part of the lens. This is shown in Fig. 153. Parallel rays coming from the left would thus be brought together, or " brought to a focus/ 7 at F, on the opposite side of the lens. If, on the other hand, light were produced at the point F, and its rays went through the lens, they would be made parallel. Focus is from the Latin, and means " hearth." Burning Glass. The double-convex lens of Fig. 153 would bring parallel heat rays, as well as sunlight, to a focus at F. It would then be called a " burning glass." Paper, or a match, at F could be set on fire. Refraction of Sound. If a lens were constructed of the right mate- rial, it could refract sound waves (cf. 190), and bring them to a focus. The ticking of a watch might then be heard at this focus, although not at places much nearer the watch (Fig. 154). 179. Composition of White Light. At first thought it may seem likely that white light, such as that of the sun, is simpler in FIG. 153. The lens brings the par- allel rays to a focus. FIG. 154. Sound waves can be brought to a focus like light waves. 160 LIGHT AND SOUND Fia. 155. A glass prism breaks up white sunlight into light of seven well-marked colors. its composition than colored light; but this is not so. If a beam of sunlight is admitted through a narrow slit (A) into a dark room (Fig. 155), an image of the opening will be made upon the screen at B. But if a glass prism (P) is put in the path of the sunbeam, the image of the slit will not be a simple line, but a series of lines side by side; that is to say, a band. The image will not be white, but will consist of bands of different colors. As the prism is placed in Fig. 155, the violet band is highest, while the red band is lowest. The reason is that violet light is bent mosfc by the prism, and red, least. The order of the colors will be: violet, indigo, blue, green, yellow, orange, and red. The initial letters make the fanciful word VIBGYOR. When platinum, iron, etc., are heated, they first become red hot, and last of all white hot. This suggests that we get the red rays first because they have the slowest rate of motion. Only when the temperature has risen are the violet rays added which are necessary to give pure-white light. The red rays have the longest waves; the violet waves are shorter, but move much more rapidly. APPROXIMATE LENGTH OF LIGHT WAVES, IN MILLIMETERS Violet. 000397 Yellow 000589 Indigo 000431 Orange 000656 Blue 000480 Red 000688 Green 000527 If a reversed prism is placed so as to catch the colored bands produced by the first prism (Fig. 156), the colors THE RAINBOW 161 will be brought together again, and the rays produced will be white, as they were before refraction. So we can prove, both by breaking up white sunlight and by putting its colored parts together, that it is composed of many rays of different colors. The colored band produced by the single prism is called the solar (i. e., the sun's) spectrum. It was first studied with great care by Isaac Newton, in 1672. FIG. 156. i or\ TO. T> * l TU ~ Reversed Prism. Sunlight that has been loll, ine KainDOW. ine broken up can be recombined to ,, , give white light. finest solar spectrum we see in Nature is the rainbow. In order to see a rainbow we must look at falling rain, and the sun must be behind us, and 42 degrees, or less, from the horizon. Half the dis- tance from the zenith (c/. 177) to the horizon is 45 de- grees. On a small scale a rainbow may often be seen in the spray of a waterfall or of a lawn sprinkler. In Nature two bows are often seen together: a primary one, red on the outside of the arch and violet on the inside, and a secon- dary one, outside the primary one, and with the colors of the primary rainbow in reversed order. In forming a rainbow each drop of water acts both as a lens and as a mirror. It refracts the sun's rays as they enter the drop, reflects them from side to side within the drop, and then refracts them as they re-enter the air. From the outside of the rainbow arch only red rays reach our eyes. The drops inside the arch send to us, in order, orange, yellow, green, blue, and indigo rays. The lowest drops send the violet rays. A halo, or ring of light, around the moon or the sun is probably due to a similar bending of light rays by the thin, icy clouds of the upper part of the atmosphere. 162 LIGHT AND SOUND heat (cf. 183) 181. Absorption of Light; Color. Certain substances do not allow light to pass through them, and do not reflect it; what, then, becomes of the light? We say it is absorbed (173). It is really changed almost entirely into Lampblack, or soot, is a good absorber of light; silver is an almost perfect re- flector (cf. 57 and 175; also Fig. 157). We see most objects by the light they reflect (cf. 165 and 174). The color of an object thus depends upon the color of the reflected rays, or, in the case of a transparent body, upon the color of the light that passes through the body. A red body sends red rays to the eye, and absorbs all other rays. If it reflects nearly all rays, it is light gray. If it absorbs all, it is black. Two colors that yield white light when mixed are called comple- mentary colors. Such are red and blue-green, yellow and blue-indigo, orange and light blue, green-yellow and violet. Color is not really a property of bodies, but a sensation which they produce upon ourselves. What we call color is the sensation that a body produces when we see it in ordinary daylight. We all know how different the same colors ap- pear in daylight, gas light, and the electric arc light. A blue ribbon will not appear blue unless the light by which it is illuminated contains blue rays. Daylight contains blue rays. But the light of sodium vapor (cf. 109) contains only yellow rays. In such light all objects are either yellow or black. For the same reason a blue object held in the red light of a photographer's " dark room " appears black. 182. The Sky and Its Colors. The normal color of the sky is blue, except when the atmosphere contains too FIG. 157. Two Air Thermometers. The air in the black- ened bulb becomes warmer than that in the colorless, or sil- vered, one; the black bulb absorbs the more light and heat. CHANGE OF LIGHT INTO HEAT much dust. Atmospheric dust may be ordinary, solid dust, or fine particles (mist) of water or ice (cf. 268). Sunlight dispersed by this dust is " white' ' daylight (cf. 173 and 176). Near the sun and near the horizon the sky is ordinarily light gray. Sunrise and sunset colors are due to the rays that are refracted least (cf. 179) ; hence the indigo and blue of the zenith shade into yellow, orange, and red near the horizon. Sky coloring is caused not only by reflection and refraction, but also by an effect which thin clouds of fine particles have in breaking up sun- light into its spectrum. The same effect is produced by a glass plate ruled with many parallel lines, say 15,000 to the inch. The phenome- non is called diffraction. As with the prism, violet rays are bent most and red rays least. In 1883 the volcano of Krakatoa, Java, suffered a violent explosion, and so much dust was driven into the upper air that it spread around the whole globe. It produced brilliant sunset effects for 3 years. 183. Change of Light into Heat. From the study of the spectrum we learned that the violet rays move most rapidly and the red least rapidly. Below the red rays there are rays moving too slowly to give out light of any color, yet having a great deal of energy. These long waves can be changed into heat just as light waves can. Glass will not cut off the light waves, but it will cut off the longer heat waves. We can prove this easily by holding a pane of glass between the hand and a hot stove. Now, when sunlight has been absorbed, and is then radiated again (cf. 66), it no longer consists of the short light waves, but of the long heat waves. The glass of green- houses or hot-beds thus acts as a trap for the sun's energy; for it permits the light waves to pass into the soil; but 164 LIGHT AND SOUND when the light waves have been changed into heat they cannot escape. The water vapor and impurities of the air act like glass in making prisoners of the light waves and thus raising the temperature of the earth. Without this the chill that would follow the rapid radiation of heat from the earth would quickly put an end to all animal and vegetable life. 184. Light and Life. The energy of the sun is stored up not only by the earth's atmosphere, but also by the action of plants. Plants containing chlorophyll, the green coloring matter of our common vegetation, are able by the aid of sunlight to build up complex organic sub- stances, such as sugar, starch, cellulose, etc. (c/. 310). Plants build up these substances out of carbon dioxide and water. Oxygen is set free (cf. 52). Energy is re- quired, for this is chemical work, and the sun supplies it. When the material produced by the plant is afterwards used as fuel or food, it reunites with the oxygen; the energy reappears as body heat, muscular force, etc. In a very real sense, therefore, plants store up the sun's energy for their own use and for the use of animals. 185. Exercises. 1. Stand before a vertical mirror, and look at the image of your hand while you write your name. What is the result? Explain it. 2. A mirror on a dresser is 30 inches above the floor. How do you tilt the mirror if you want a full length view of yourself? Why do you step back from the dresser? 3. Why is the broken top of a wave white (" white cap "), while the unbroken wave is blue, green, etc.? 4. If you lay a small piece of thick glass over the middle part of a COMPOUND MICROSCOPE 165 piece of wire, and then look at the wire obliquely, the wire seems to be broken at the edges of the glass. Try it, and give the reason. 5. If you look obliquely downward at a fish on the bottom of a pond, is the fish where it seems to be? Is it nearer you or farther away? Draw a figure to show why. 6. Why do we see the sun after it has really set, and before it has really risen? 7. Investigation has shown that forest fires are sometimes caused by glass bottles left by campers; explain. 8. Do we ever see a rainbow at midday? Explain why. 9. A mercury vapor electric lamp contains almost no red rays. What effect has this upon the color of objects? 10. For what reasons can vegetables be raised so much earlier in a, box covered with glass (a " cold frame ") than in the open air? 186. Simple Microscope, or Magnifying Lens. The simple microscope (Fig. 158) consists of a convex lens that will bring light to a focus. The object to be magni- fied (here the arrow a b) is placed between this focus and the lens. The figure shows that the image (a' b') will appear to be farther from the lens than the object is, and that it The lens e*he object ap _ will be right side up and enlarged. pear ""tSSSSt " not 187. Compound Microscope. The compound micro- scope (Fig. 159) consists of (1) a concave, i. e., hollowed out, mirror to collect and direct light rays; (2) an object lens, or objective ; and (3) an eye-piece. The inside of the microscope tube is black, to prevent light from being re- flected back and forth. The object to be magnified (a b} is fastened in a glass " slide," and is lighted up by rays directed by the mirror. The rays from the object 166 LIGHT AND SOUND then pass through the object lens, and produce a reversed and inverted image near the eye-piece. Just as the simple magnifying lens enlarges an object placed near it, so the eye-piece enlarges the image a b' , and it appears to be further magnified to the size a" b" (read this: a second, b second). Eye ,PTece 188. The Camera. The camera (Fig. 160) consists of a dark box having a movable screen of ground glass (S). The tube con- tains a convex lens. The image of the object appears upon the screen, and may be looked at through 0. When the image has been " focused " on the screen, a " sensitized " film or glass plate is put in place of the screen. The chemical action of light " prints " a picture of the object upon the film or plate. The sensitive film or plate is made by completely 8 . image covering B> sheet of gelatine or of glass with some compounds that are easily decom- posed by light. Usually these are silver chloride or silver bromide. After the film or plate has been exposed to light from the object, the image is still invisible. It must be " developed" by means of a solution of pyrogallic acid, or some other " developer." Finally the image is " fixed." Fixing consists in removing the unchanged silver salt. The material used is generally o sodium thiosulphate, known | popularly as Objective FIG. 159. The compound microscope makes an object appear much larger, but hypo. 3 The result of these operations is FIG. 160. The camera is a device for focusing the clear image of an object upon a sensi- tive plate or film. HOW SOUNDS ARE MADE AND CARRIED 167 the negative (Fig. 161). In it the light parts of the object are dark (opaque), and the dark parts are light. The photographer " prints " the positive picture by placing the negative over sensitive paper con- taining silver chloride, and exposing the two for some time to sunlight. The paper will then be changed as the negative was. But as the dark parts of the negative cut off the light, while the lighter parts permit FIG. 161. Negative and Positive Photograph. Negative by H. L. Schall. it to pass through, the positive "print" contains light and shade in the same relation as the object photographed. 189. How Sounds are Made and Carried. Just as light is the cause that affects the optic nerve and gives us sight, so sound is the cause that affects the nerve of the ear and causes hearing. All sound is due to the motion of some portion of matter. When a violin string is producing a note, it is moving rapidly back and forth. We can prove this by touching the string lightly with the finger. We can prove the same thing in the case of a sounding tele- phone or door bell. When we speak or sing, we force air through the slit between the vocal cords (cf. 389), and set them into rapid motion. When a vibrating tuning 168 LIGHT AND SOUND fork is put into water, it throws the water into sprays; this shows that its sounding is due to its motion (Fig. 162). Sounds are ordinarily carried by the air. If an electric bell is placed inside a vessel of air (Fig. 163), and the air is nearly all removed by an air pump, the sound given out by the bell is feeble; but it becomes stronger again when air is admitted. This shows that a vacuum would not carry sound. But other kinds of matter besides air carry sound. Thus the tap of a pencil or the scratch of a pin against a long steam pipe is heard readily, if we put the ear close to the pipe. Iron conducts sound better than air. Water is also a better sound conductor than air: the clashing together of two stones under water produces a louder sound than in air. In air at C. Fia. 162. A sounding body is in rapid vibra- tion. sound travels about 1,100 feet in a second; in water, about 4,600 feet, and in iron, about 17,000 feet. -f- Fia. 163. A bell ringing in a vacuum would give forth no sound. 190. Sound Waves. When a sound is produced (Fig. 164), it is heard in all directions. This sug- gests to us that sound waves start as small spheres which get larger and larger as they move outward from the sounding body. But as the sphere grows larger, more and more air must be set in motion. Naturally the motion of a given volume of the air must become smaller and smaller. Fi- nally the motion of the air is too small to affect the ear. We say the sound " dies out " with distance. FIG. 164. How does the air move when it s ?n g nd 8 p w h a e v rf,; 8p th e elr a8 is e aSe g r : carries sound? It caimot go as in a na^compressed and e*- ECHOES 169 movement of a body of air; for we do not feel any motion of the air from a sounding body. To understand the for- mation of sound waves we must remember that air is elastic; that is, it can be compressed, but will expand again when released. The sudden jar given the air by a bell (Fig. 164) pushes the air particles near the bell forward, producing a layer of compressed air. This layer then expands, and in doing so gives a rapid push to the next layer of air. The sound wave thus proceeds outward as a series of short, rapid compressions and ex- pansions of air. With a row of elastic balls (Fig. 165) we can illustrate the way in which air particles can give up their motion without going forward. If we draw aside one of the balls, and let it fall against the row, it gives its motion to its neighbor. This gives its f ow . of balls : onlv the last ball actually moves forward. motion to the next ball, and so on down the line. Only the last ball, which has no ball to which it can give its motion, actually moves forward. 191. Echoes. Sound waves are reflected as light waves are (cf. 174). If, on a quiet day, we shout toward some wall, or barn, or cliff, our shout may be returned to us as an echo. To succeed we must be far enough away to per- mit the shout to cease before the reflected sound can come back. In a small room the echo blends with the original sound, and we do not notice it; but in a large room or hall the echo of one word or sentence may come back just as another is being spoken. The result is a confused mix- ture of sounds. Echoes are often prevented by the hang- ing of curtains or wires across the room. These break up the disturbing sound waves. 170 LIGHT AND SOUND 192. Noise and Tone. We distinguish clearly between noises, which come from the confused mingling of sound waves, and tones, which are the result of a rapid succession of waves, all of the same sort, and coming at regular in- tervals. It is this regularity that makes musical sounds pleasant to the ear. By striking hard bodies, such as dishes, stones, wires, car wheels, etc., we find that each has its own definite tone. By the pitch of a tone we mean whether it is high or low. Pitch is caused by the frequency of the vibrations of what- ever causes the sound. " Middle C " of a piano is brought about by a wire that vibrates 256 times in a second. The range of the human voice is from about 80 vibrations (lowest bass) to about 1000 vibrations (high soprano) in a second. We can hear sounds due to a much greater frequency than we can produce. Thus, the high notes of a violin, the noise of a cricket, and the whistle of a locomotive are due to thousands of vibrations in a second. When a sound comes from more than 40,000 vibrations per second, the human ear can no longer hear it. 193. The Telephone. The principle according to which the telephone " works " is shown in Fig. 166. M and TV are two permanent magnets placed inside the wire coils B and C. The circuit is through the coils, the wire connecting them, and the earth. Before each magnet there is a thin, iron disk (D and E) . If we make a sound in front of D, the sound waves in the air make the disk vibrate. As D moves back and forth in the " lines of force " (cf. 138) of its magnet (M), it induces currents (cf. 160) in the coil B. These currents are carried along the wire, and appear in the coil C. Here they cause move- SUMMARY 171 FIG. 166. The Simple Telephone. ments of the lines of force of the magnet A 7 , and produce vibrations in the disk E. The vibrations of E are just like those of Z), and reproduce the sound we made at the other end of the line. In the modern telephone the " return circuit" is through a second wire instead of through the earth. The receiver is like the simple disk of the figure, but the speak- ing instrument ("trans- mitter") is more complex. The telephone was in- vented in 1875 by Alexander Graham Bell, of Washington, and Elisha Gray, of Chicago. 194. Summary. A visible body is either self-luminous or illuminated. Bodies may be transparent, translucent, or opaque. Light is the cause that produces sight. It moves in straight lines at a speed of 186,000 miles a second. An image formed through a small opening is inverted. A shadow formed from a point of light is distinct, and composed of an umbra alone. A shadow from a luminous surface has both umbra and penumbra. An eclipse of the sun occurs when the earth is within the moon's shadow. An eclipse of the moon occurs when the moon is in the earth's shadow. Intensity of light is given in candle power. A photometer is an in- strument for finding when the intensity of light from two luminous bodies is the same. Light striking a body may be reflected, dispersed, or absorbed; or it may pass through the body. Light is reflected at the same angle as that at which it strikes the reflecting surface, but in a different direction. 172 LIGHT AND SOUND A plane mirror gives an image that is right side up, but has the right and left sides reversed. We see an object in the direction which its light has as it enters the eye. Daylight is dispersed sunlight. Light that passes from one substance to another of a different density is refracted. Because of refraction, objects in water are not seen in their correct positions, and the heavenly bodies seem higher above the horizon than they really are. A lens with convex faces brings light rays, heat rays, and sound waves to a point, or focus. White light is a mixture of many colors. It is broken up into its primary colors by a prism. The band of colors produced by sunlight is called the solar spectrum. A rainbow is a spectrum on a large scale. The color of a body is due to the rays it reflects. It absorbs rays of all other colors. Light rays are changed into heat rays when they are absorbed by the earth and then given off. Plants having chlorophyll use sunlight to prepare sugar, starch, etc., out of carbon dioxide and water. The simple microscope gives an enlarged, natural image. The compound microscope consists of a mirror, an objective, an eye-piece, and a tube. It gives an enlarged image which is completely reversed. The camera consists of a dark box, a screen, and a lens. It gives an inverted, reversed image of reduced size. Sounds are ordinarily carried by the air, but they may be carried by water, metals, wood, etc. Sound waves extend outward from the sounding body as enlarging, spherical layers in which air is alternately compressed and expanded. Echoes are reflected sound waves. Noises are sound waves coming at irregular intervals. Tones are waves, all of the same kind, and coming at regular intervals. Pitch depends upon the frequency of vibration. The telephone is constructed on the principle that vibrations of an iron disk in the field of one magnet will produce corresponding vibra- tions in an iron disk placed in the field of another magnet far away. EXERCISES 173 195. Exercises. 1 . Why does the photographer use red light in his dark room? 2. If you were to hold a suspended pith or cork ball near a sounding tuning fork, what would happen? 3. Suggest why it is so much harder for a speaker to be heard in the open air than in a hall. 4. A circular saw has a certain note when revolving rapidly. Why does the pitch of the sound fall when the saw cuts into a board? 5. Why is the ringing of a bell so much clearer when the sound comes " with " the wind than when it comes " against " the wind? How does the wind affect the shape of the sound waves? 6. When is a room more likely to have echoes, when full of people, or when empty? Why? 7. How are the marks upon a graphophone " record " changed into sound? How are the records made? 8. How can sound waves be carried through a speaking tube? 9. Of what are " chimes " constructed? How are the different notes secured? 10. Why can you hear a distant carriage better by putting your ear to the ground? 11. What is the principle of the yell leader's megaphone? CHAPTER X SIMPLE MACHINES 196. Need of Machines. Man uses a multitude of devices, or tools, to enable him to do his work to better advantage. Thus, he pries a stone or a log instead of lifting it. If he needs to raise stones or bricks to the top of a building, he employs a pulley with a rope over it ; by pulling downward on the rope, he pulls the weight upward. He splits logs with wedge and axe, and ploughs with a slop- ing knife, or ploughshare. If he has to raise barrels into a wagon, he rolls them up a sloping board instead of lifting them. Wherever possible, he puts a wheel or roller under a heavy object, so that he can move it without lifting it. Finally, in order to fasten pieces of cloth or skin together, he uses a needle or an awl. Since the thickness of this tool increases very gradually, a little pushing forces the fabric apart, and makes a hole for the thread. The forms of tools have become more ingenious and complicated with man's progress in civilization, but the simple principles have been known for ages. These principles are repre- sented by six simple contrivances, or machines : (1) The Lever. (4) The Inclined Plane. (2) The Pulley. (5) The Wedge. (3) The Wheel and Axle. (6) The Screw. 197. Law of Machines. None of these machines nor any of their improved forms can originate, or create,. 174 LAW OF MACHINES 175 any energy. They simply make it possible for us to apply force in a convenient direction, or at a convenient place. Or they make it possible for us to exchange a small force exerted through a considerable distance for a much larger force exerted through a correspondingly shorter distance. Thus, we give the head of a screw driver one complete turn in order to get the screw to move forward only the distance between two successive threads; but the force we exert in overcoming the cohesion of the wood is enor- mously greater than that which we ap- ply to the head of the screw driver. Again, we probably could not draw a nail out of a board by pulling with all our might, yet by the use of a claw hammer (Fig. 167) we need to put forth FIG. 167. only a small effort to do the work. But A claw hammer is a machine. we must remember that in using ma- chines we are making an exchange, not getting something for nothing. The exchange we make in using a sewing machine is the opposite of that which we make in the screw and the hammer. Sewing by hand is hard, not because it requires much strength, but because it is slow. With a sewing machine the seamstress can exchange her strength for greater speed. The law of machines is merely the statement of the exchange we make in every machine. If we multiply the power exerted (stated in weight units) by the dis- tance through which the source of the power moves, the product is just equal to the product obtained when we multiply the resistance overcome, or the weight 176 SIMPLE MACHINES lifted, by the distance through which the resisting object, or weight, moves. Power X power distance = weight X weight distance. 198. The Lever. The claw hammer, pitchfork, and crowbar are common forms of the lever. The fixed support on which the lever rests is called the fulcrum. If, in Fig. 168, the distance from the fulcrum (F) to the point at which the weight (R) is attached is 1 foot, and the distance from F to the point (P), where the power is applied, is 2 feet, then the weight that can be lifted at R is twice the power applied: 40 pounds at P can support 80 pounds at R. If the distance from F to R is 3 inches, and that from F to P is 51 inches, then 40 pounds at P can sup- port 680 pounds at R. FIG. 168. A Lever of the First Class- The fulcrum is between the force exerted and the resistance to be overcome. FIG. 169. Fish Scales: a Lever of the First Class. The balances (Fig. 9) are a lever. If the two arms are of equal length, equal weights in the two pans will just support each other. In fish scales (Fig. 169) the arm holding the pan is the shorter, hence a heavy object on this pan can be supported ' ' weighed " by a small weight on the longer arm. The weighted gate (Fig. 170) and the well sweep (Fig. 171) are other examples of the lever. FIG. 170. Weighted Gate. The stone nearly balances the gate, so that very little effort is required to lift the gate. 199. Classes of Levers. We divide levers into three classes according to the way in which the fulcrum, the CLASSES OF LEVERS 177 FIG. 171. Well Sweep : a Lever Used in Raising Water from a Well. Courtesy of the Ansco Co. power, and the resistance are placed with regard to one an- other. In the crowbar and balance the fulcrum is between the other two. Such a lever is of the first class. In the nut-cracker (Fig. 172) the resistance (the nut) is be- tween the other two : the fulcrum is at one end. This is a lever of the second class (Fig. 173). A wheelbarrow is also of the second class. The fulcrum is the axle of the wheel, the power is applied to the handles, and the weight is between them. The rule of machines applies here, just as in levers of the first class. In making the calculation we will not count the weight of the wheel- barrow. If you place a piece of ice, weighing 100 pounds, 1 foot from the axle of the wheel, and grasp the handles 5 feet from the axle, you need exert a force of only 20 pounds to lift the ice. Levers of the third class have the fulcrum at one end, just as those of the second class nave > but the power is applied be- tween the resistance and the fulcrum FIG. 173. Lever of Second Class. The resistance is between the fulcrum and the power. Lever of 'the' Third class. ' 18 at P 178 SIMPLE MACHINES (Fig. 174). The tread of a grindstone and of a weaving loom are examples of third class levers. So is the human forearm (Fig. 277, 355). 200. Exercises. 1. To what class of levers do scissors belong? In cutting thick cloth, or a wire, with shears, do you put the cloth, or wire, at the tips of the shears or near the rivet? Why? 2. What kind of a lever is a pair of sugar tongs? The oar of a boat? The handle of a hoe? A pitchfork? A pump handle? 3. If you were using a crowbar to roll a log along the ground, how would you use the bar as a lever of the first class? How as a lever of the second class? 4. If you support a 5 Ib. weight at one end of a bar 3 ft. long by means of a 10 Ib. weight at the other end, where must the fulcrum be placed? 5. An oar is 7 ft. long, and the handle is 1 ft. from the oarlock. How far is the end of the blade from the oarlock? A boy pulls on the handle with a force of 25 Ibs.; what force does the oar blade exert on the water? Would there be any advantage in having the oar handle 2 ft. from the oarlock? 6. Why is an oar blade made so broad? Upon what property of water does the blade's usefulness depend? 7. When a woman is pushing with her toes against the treadle of a .sewing machine, where is the power as regards fulcrum and weight? What kind of a lever is the treadle in this case? What kind is it when she uses her heel? In which case does she have to do more work? How is the treadle attached to the driving wheel? 201. Pulleys. In the simplest form of the pulley (Fig. 175) we cannot lift more than FIG. 175. the power we put forth; but we can raise the weight by pulling downward. Such a pulley is used for hoisting the sails of a ship, or for THE WHEEL AND AXLE 179 raising a flag on a flagstaff. By means of a second pulley a horse pulling in a horizontal direction can raise a weight vertically upward (cf. Fig. 20, 26). If we arrange two pulleys as in Fig. 176, two cords support the weight, while only one is supported by the power; hence a power of 1 pound can support a weight of 2 pounds. We get this and One Fixed advantage because the cord on which we pull must descend twice as far as the weight rises. If there^ are three cords (Fig. 177) supporting the weight, and one supported by the power, 1 pound can lift 3. FIG. 177. 202. The Wheel and Axle. In the wheel and axle (Fig. 178) the power applied on the wheel must move a distance equal to the circumference of the wheel, while the weight attached to the axle moves only the circumference of the axle. The wheel in the figure has a circum- ference 3 times that of the axle; therefore 1 pound on the wheel will support 3 pounds on the axle. The winch, or windlass (Fig. 179), is a form of the wheel and axle in which the power is applied to a crank. To raise the weight a distance equal to winch used for Raising of water. the circumference of the axle, FIG. 178. Wheel and Axle. 180 SIMPLE MACHINES the power must be exerted through one complete turn of the crank. A derrick (Fig. 180) consists of a winch and a system of cog wheels and pulleys. 203. The Inclined Plane. In climbing a hill or mountain we pre- fer to go up gradual slopes instead of steep ones, because in this way we can raise the weight of our bodies with much less effort. But in doing so we make an exchange: we travel a much greater actual distance than if we go " straight up." So, if we wished to raise a 200 pound barrel from the ground to a wagon, we might lift it up directly; but an easier way would be to roll it up an inclined plane (Fig. 181). If the plane were 10 feet long and 3^ feet from the ground at the higher end, the force required to push the barrel up the plane would be 1 A of 200, or 66% pounds. We roll the barrel 3 times as far as we wish to raise it, but we need exert only J^ of the force. This is the effort required if we exert force parallel with the plane. FIG. 182. 204. The Wedge. The wedge (Fig. 182) is of im-iinedplane? 1 really two inclined planes with their bases placed FIG. 181. Inclined Plane. THE SCREW 181 together. It is made of hard wood or of iron, and is used to split logs and stones, or sometimes to raise a heavy weight. If the length of the wedge is 5 times its thickness, we drive it into the log 5 inches in order to force the wood apart 1 inch. The axe is a wedge; so are the pin and the needle (cf. 196). 205. The Screw. If we were going to the top of a lighthouse 100 feet high, we might climb a vertical ladder or rope, 01 we might go up gradually, on a long inclined plane, rising, say, 1 foot in every 10. In the ascent by the inclined plane we would walk 1000 feet in order to rise 100 feet. The most compact way of arranging an inclined plane is in a spiral. This is done in the spiral staircases of many lighthouses and towers. Now, the screw (Fig. 183) is really a long inclined plane with the ascent arranged in a spiral instead of in a straight T A 11 f i , line. A small force can produce a large - 'IT n enect with the screw; for the power must go a long distance in order to make the screw itself ad- vance a very short distance. The distance between threads is called the " pitch " of the screw. Suppose that a screw having 12 threads to the inch is driven by a screw driver having a handle 2 inches in diameter. The handle has a circumference of 2X3 1 /?, or 6 2 /7 inches. The handle is thus turned through 6 2 /7 inches while the screw advances l /iz of an inch. Hence the power moves about 75 times (6 2 /7 divided by Vi 2 ) as far as the resistance or weight; a force of 3 pounds applied on the handle will exert a force of about 225 pounds on the threads of the screw. The screw is used not only for holding pieces of great weights, such as wagons or houses, ^ or short distances. 182 SIMPLE MACHINES wood or metal together, and for lifting weights, but also for producing great pressure. The letter-copying press (Fig. 184) and the vise are screws used for this purpose. 206. Friction. The law of machines (cf. 197) does not turn out to be exactly true in the actual use of a machine, because some of the power exerted is used in overcoming friction (cf. 24). But while friction repre- sents lost effort, some friction is usually necessary in order that a machine may " work." Thus, a barrel must "stick " slightly to an inclined plane, or we cannot roll it up; a rope passed over a pulley must adhere to the rim of the pulley, or the pulley wheel will not turn when the rope is drawn in. We all know how difficult it is to walk upon a highly polished floor, owing to the lack of friction between our shoes and the floor. Also, heavy objects that are to be moved horizontally are placed on rollers or wheels, if possible, because rolling friction is much less than sliding friction. The wheelbarrow illustrates this admirably, also the use of castors on bedsteads, tables, etc. 207. The Sailboat. Few discoveries of man have helped him more in his rise to civilization than his ability to travel long distances by water; this was made possible largely by his discovery of the use of sails. We can readily understand how a boat can sail " before the wind": the sail merely provides a large area for re- ceiving the pressure of the moving air. The sailboat not only permits us to sail in the direction of the wind, but it permits us to exchange rapid motion in this direction for slower motion in some other direction. No sailboat, of course, can go directly against the wind. THE SAILBOAT 183 Use of Keel. A wind blowing against a boat causes it to move in the direction of the wind; that is, to " drift." To prevent drifting we provide a boat with a "keel" or a " centerboard." A keel is a strip projecting from bow to stern on the bottom of a boat. A centerboard is a movable keel. The centerboard can be lowered into the water when the boat is in deep water, and drawn up within the boat when the boat is in shallow water. We can illustrate the action of the keel by pushing a vertical board side- wise under water. The water re- sists being pushed out of the way, just as air does (cf. 27). Use of Wind by the Sail. The sail (Fig. 186) is attached so that it can be let out at right angles to the keel, or " hauled in " until it is almost parallel with the keel. Let Fig. 187 represent a boat moving in the direc- tion of the keel; that is, forward. The wind is coming from the side, at right angles with the keel. Such a wind is called a " beam wind." It is plain that if the sail were let out competely, no part of the wind would be FIG. 185. Course of a boat "beating to wind- ward." FIG. 186. A Sloop under Full Way. Courtesy of Dr. C. F. Millspaugh. caught, and there could be no forward motion of the keel. If the sail were drawn in completely, the whole pressure of the wind would be against the keel, and there would be only a sidewise motion, provided the boat was not capsized. But if the sail is set obliquely with the keel, as in Fig. 187, part of the force of the wind is used in push- ing the boat sidewise (a motion resisted by the FIG. 187. Diagram of a Sailboat. 184 SIMPLE MACHINES Kite _ String FIG. 188. keel), while another part pushes the boat forward. The more efficient the keel is, the less does the boat drift; the " closer " does it sail "to the wind." 208. The Kite. While in the sailboat the force of a horizontal wind is changed partly to a force acting di- rectly forward, in the kite a part of the wind's force is made to act vertically upward. If the kite (Fig. 188) is held i Raising vertical, it gets all the force of the wind that strikes it,. and moves off in a hori- zontal direction. This takes place when why the wind Makes a the kite string breaks while the kite is in Kite Rise. the air. The kite is then only a falling body (cf. 21), acted upon by the wind and by gravity. If the kite were held horizontal, it would catch no part of the wind, like a boat with its sail parallel with the wind. But if the kite is inclined to the wind, the force of the wind is divided into two parts, one of which presses against the kite, and is resisted by the string; while the other part acts vertically upward, and raises the kite into the air. 209. The Airship. Airships may be of the balloon type (Fig. 189), which rise because they are filled with heated air or other light gases; or they may be aeroplanes monoplanes, biplanes, hydroplanes, etc. FIG. 189. One of the first Dirigible Airships to Fly in America. Note the whirling propellor in front. Copyright, The International Stereograph Co., Decatur, 111. THE WINDMILL 185 which rise, as the kite does, because of the resistance (inertia) of the air (Fig. 190). Only, while the kite uses the inertia of air in motion (wind), the plane airship uses air as matter which resists being pushed out of the way. The explanation of the action of the air upon the aeroplane is prac- tically the same as if the aeroplane were still, and the air were in rapid FIG. 190. A Modern Wright Flyer. Courtesy of Dr. Orville Wright. motion. When the engine forces the planes rapidly forward, the force (resistance) of the air acts in two parts, as with the kite. One of these parts opposes the forward movement of the planes, and must be over- come by the engine. The other portion of the air's resisting force acts vertically upward, and raises the planes, against gravity, into the air. 210. The Windmill. One of the reasons why farming has developed so rapidly in recent years is that windmills 186 SIMPLE MACHINES have come into such general use in pumping water for the uses of the farm. The windmill relieves the farmer and his family from the drudgery of pumping water, and leaves them free for other labor. The windmill, like the sailboat, kite, and aeroplane, works upon the principle that if wind strikes a plane obliquely, part of the force of the wind is exerted in producing forward (or upward) motion. In the windmill the planes (sails) are attached to a hub (Fig. 191) ; as the planes move forward, the hub, or wheel, revolves. The " pin-wheel " we used when children is a miniature windmill. For the pumping of water, the re- FIQ volving wheel is attached to a piston A Dutch Windmill. Copyright The which moves up and down in a pump JatTrrimn n ot StereographC -' De - fcf- 42); water is thus raised out of a well or cistern. On windy days the windmill pumps the water into a raised tank, from which it can be drawn when there is no wind, and the mill is quiet. A recent article states that a village in Alaska, far within the Arctic Circle, is to have its long night, of six months, illuminated by electri- city. The average wind velocity at the village is 20 miles an hour, and a large windmill will operate the dynamo that gives the current for the light (cf. 162). 211. Summary. The complicated machines used by man are forms of six simple machines: the lever, pulley, wheel and axle, inclined plane, wedge, and screw. A machine enables man to exert force more advantageously, but it does not create any energy. Power x distance power moves equals weight x distance weight moves. EXERCISES 187 Levers are of three classes: (1) The fulcrum is between the weight and the power. (2) The weight is between the fulcrum and the power. (3) The power is between the fulcrum and the weight. Pulleys are wheels over which ropes can be pulled. The wheel and axle is a form of the lever used for circular motion. The wedge and the screw are really forms of the inclined plane. Friction prevents us from getting the full amount of work out of a machine; but some is necessary in order that machines may work at all. A sailboat is a device for getting some forward motion out of any wind except one that is " dead ahead." The kite gets upward motion out of a horizontal wind. The aeroplane gets upward motion by the pushing of its obliquely- set planes horizontally against the air. The windmill converts a horizontal wind into circular motion. 212. Exercises. 1. What kind of a machine is used for lifting window awnings? A door transom? A weighted window sash? 2. How could you arrange a system of pulleys so that by pulling downward with a force of 20 Ibs. you could raise 40 Ibs.? 3. If the crank of a winch (Fig. 179) makes a circle of 36 in. while the rope is wound up 6 in. for each complete revolution of the crank, how much force must I exert on the crank to lift a pail of water weigh- ing 100 Ibs.? 4. What kind of a machine is a nail, a coffee-grinder, a carpenter's brace and bit, a pendulum bob, a snow plow, a pin-wheel, a door knob, a spoon, a spade, a chisel? 5. How do you hold your knife and your fork when cutting a tough piece of meat? What kind of machine are these implements then? What machine are the tines of the fork and the blade of the knife? 6. A man who can exert a force of 100 Ibs. wishes to raise a 300 Ib. barrel into a wagon 3 ft. above the ground. He uses an inclined board; how long must it be? 7. In loading a wheelbarrow, where should you put the load in order to make the force needed for lifting as small as possible? CHAPTER XI (Term^nTed Fruit Juice) ACIDS, ALKALIES, AND CLEANING 213. Acids. We learned in 5 that no two sub- stances have exactly the same special, or specific, prop- erties. There are, however, many substances that are alike in some particular property or properties. This is true of the substances that make up the class we call " acids," as well as of those we call " bases," or " alkalies." The word " acid " means sour; sourness is a character- istic property of most acids. The juices of ripe fruits are sweet because they contain sugar; but when they are ex- posed to the air, the juices " fer- ment": their sugar is changed to alcohol and carbon dioxide. This particular fermentation is due to yeast (cf. 129). The change does not, however, stop here. When the fermented juices, which now contain alcohol, stand longer in the air, they be- come sour, and we have cider vinegar, currant vinegar, wine vinegar, etc. (Fig. 192). The cause of this second fermentation is another plant, known as the " vinegar mould," or " mother of vinegar." The sourness of vinegar is due to acetic acid (cf. 124). In a pure form this is a -colorless, sharp-smelling liquid, which freezes at 16 C., 188 FIG. 192. Quick Vinegar Process. CLASSES OF ACIDS 189 and blisters the skin. Vinegar usually has only 3% or 4% of it. The materials present in plants undergo other fermenta- tions besides the one that gives acetic acid. Thus, "Dill " pickles are small cucumbers fermented so as to give lactic add; " sauer kraut " contains the same acid. Sweet milk becomes sour because the milk sugar in it is changed to lactic acid. Pure lactic acid is a thick liquid of very sour taste. 214. Classes of Acids. It is not only by fermentation of fruit juices that acids are formed. The fruits them- selves, as well as other parts of plants, contain acids. Tomatoes, cherries, rhubarb, etc., are strongly acid. Lem- ons and oranges contain much citric acid; grape juice, much tartaric acid; apples contain malic acid. All of the acids already named in this chapter are compounds of carbon with hydrogen and oxygen (cf. 123). These acids are called organic acids (cf. 3). There are many acids that contain no carbon at all, but have some other element in place of the carbon. These belong to the class of inorganic, or mineral, acids. Thus, nitric acid contains nitrogen, combined with hydrogen and oxygen; sulphuric acid consists of sulphur, hydrogen, and oxygen; phos- phoric acid contains phosphorus, hydrogen, and oxygen. These three acids are all thick, colorless liquids. They are commonly " diluted " with much water. All acids contain hydrogen, but not all have oxygen. Thus, hydro- chloric acid (cf. 111) contains only hydrogen and chlorine. This is the acid of the gastric juice (cf. 364). The gastric juice of man con- tains about 0.22 of 1% of it; the adult dog has several times as much. 190 ACIDS, ALKALIES, AND CLEANING 215. Acids and Coloring Matter. Besides having the property of sourness, acids have a definite action on cer- tain coloring matters, such as purple cabbage solution and litmus. Acids often change the color of the dyes in our clothing. Thus, " navy blue " fabrics are colored red by the common acids of the laboratory. Litmus is the coloring matter we generally use in testing for acids. It is a blue substance obtained from certain plants called lichens (cf. 324). Either the solution, or filter paper that has been soaked in the solution, may be used. The prepared paper is called litmus paper. Blue litmus is changed to red litmus by sour plant juices and by other acids. A substance which is able to change blue litmus to red is said to have an " acid reaction." 216. Action of Acids with Metals. A third important property of acids is that they corrode, or " eat," metals. We have learned that hydrogen is made by the action of some of the acids upon zinc, iron, etc. (cf. 103). When the metals are so used, they are " eaten up," and disap- pear. Some metals, such as copper, do not act with dilute acids to give hydrogen (cf. 150) ; but if the metal and the dilute acid are kept in contact with air, the metal is gradually corroded. Here the oxygen of the air acts with the metal to give the oxide of the metal (cf . 48) ; the oxide then reacts with the acid. Copper and lead cannot be used for cooking utensils, because they act with the air and the acids of fruits and other food, producing poisonous compounds. Copper is " eaten " very readily by dilute nitric acid. If a design is ACTION OF ACIDS WITH CARBONATES 191 painted upon copper with asphalt paint (Fig. 193), and the copper is put into nitric acid, the part not covered by the asphalt is " etched " by the acid. When the asphalt is removed, the design stands out "in relief." 217. Action of Acids with Carbon- ates. -The action of acids with car- bonates may also be used as a test for acids. Marble (cf. 132) and hydrochloric acid react with much FIG. 193. i T i T ^ 13 design may be etched effervescence j because carbon dioxide on copper by dilute nitric escapes as a gas (cf. 126). The other product is calcium chloride. It may be obtained as a white solid by the evaporation of its solution. The limestone of bones, oyster and clam shells, and of coral is rapidly eaten out by acids, and only the animal material is left. As a result, bones that are treated with acids lose their stiffening. The large amount of acid in a dog's stomach enables him to digest bone. Other carbonates react with acids as marble and limestone do. Washing soda is sodium carbonate, which is made up of sodium, carbon, and oxygen. Baking soda is sodium hydrogen carbonate, or sodium bicarbonate (cf. 130). Both washing soda and baking soda effervesce rapidly when an acid is added. The acid used may be tomato juice, sour milk, or lemon juice, as well as a mineral acid (cf. 214). When either of the two " sodas " is treated with hydrochloric acid, there is formed, besides water and carbon dioxide, sodium chloride, or common salt (cf. 108). Soda was formerly rare and expensive; but it is now made, on an enormous scale, from common salt. Wood ashes contain potassium carbonate, or " potash." The potash is obtained from the ashes by the use of water. Potash reacts with hydrochloric acid as soda does; but it gives potassium chloride instead of sodium chloride. 192 ACIDS. ALKALIES, AND CLEANING 218. Alkalies, or Bases. Bases are substances having properties quite different from those of acids. They turn litmus which has been colored red by acids back to the blue color. All substances that do this are said to have a " basic " reaction. The strongest (most active) bases are called alkalies; hence a basic reaction is also called an alkaline reaction. The two strongest bases are commonly known as lye. Better names are sodium hydroxide (caustic soda) and potassium hydroxide (caustic potash). As the chemical names show, these substances are composed of hydrogen and oxygen, combined in the one case with the metal sodium, and in the other with the metal potassium (cf. 109). Other common bases are ammonium hydroxide ("ammonia water' 7 ; cf. 112) and calcium hydroxide (slaked lime). Calcium hydroxide is the cheapest base. It is made by adding water to calcium oxide (quicklime). Quicklime is made by heating limestone (cf. 132). Bases cannot be kept ;f exposed to the air; for they unite with its carbon dioxide (carbonic acid; cf 126) to form the carbonates. Lime that is " air slaked " is largely calcium carbonate. Solutions of potas- sium and sodium carbonates have an alkaline reaction, and behave like weak alkalies in other respects, because they react with water to form small amounts of the hydroxides. 219. Caustic Soda and Caustic Potash. When sodium carbonate (soda) solution is mixed with " milk of lime," which is slaked lime " suspended " in lime water (cf. 132), a chemical change occurs, and calcium carbonate is formed as an insoluble powder. The sodium hydroxide (caustic soda) remains in solution. NEUTRALIZATION; SALTS 193 Sodium carbonate -f calcium hydroxide give (soluble) (soluble) Sodium hydroxide + calcium carbonate. (soluble) (insoluble) The insoluble calcium carbonate settles, and the solu- tion of sodium hydroxide can be poured off. When the solution is evaporated, the sodium hydroxide remains as a white solid. Potassium hydroxide is made in a similar way. Both of these solids are very soluble in water; they even attract water from the air, becoming wet, like some candies. They are changed back to carbonates by the carbon dioxide of the air (cf. 218). Their water solutions are " slimy " to the touch (cf. 109), and act vigorously upon the skin, the fats, and other organic matter. The taste of a very dilute solution of these " caustic alkalies " is bitter. Strong solutions destroy the mucous membrane of the mouth (cf. 359) as a hot body would. Hence the name " caustic," meaning burning. 220. Neutralization; Salts. If caustic soda solution is added drop by drop to hydrochloric acid containing lit- mus, a point is found at which the litmus is neither red nor blue, but has a lavender color. If blue or red litmus is put into the solution, it is either not changed at all, or it be- comes lavender. We say that the caustic soda has neu- tralized the acid. We can neutralize the hydrochloric acid by sodium carbonate also; but in this case there is carbon dioxide given off. If the neutral solutions are now evaporated, each will give a residue of cubical, white crystals. The 194 ACIDS, ALKALIES, AND CLEANING taste and other properties of the residue show that it is common salt. It is " neutral to litmus," .as we should ex- pect from the method by which it was made. If dilute nitric acid is neutralized with soda or with caustic soda, the solid obtained is sodium nitrate; with dilute sulphuric acid the product is sodium sulphate. If potassium carbonate or potassium hydroxide were used with each of these acids, the products would be potassium chloride, potassium nitrate, and potassium sulphate, respectively. Since all of these substances are formed by the neutralization of an acid by a basic substance, just as sodium chloride is, they are all called salts. They have, in general, a salty taste, although there are decided dif- ferences between the tastes. .Calcium hydroxide, or carbonate, if neutralized with these acids, gives calcium chloride, calcium nitrate, and calcium sulphate, respectively. 221. Tests for Certain Salts. To test for a substance, as we use the word " test " in this section, is to find out whether the substance in question is present or not. We find this by the behavior of whatever is being tested. Thus we can show that a solution contains an acid by using the litmus test, and by the behavior of the solution with metals, carbonates, etc. (cf. 214 to 217). Still, these tests will not distinguish sulphuric acid from many other acids. But if we apply the test for sulphates, in addi- tion to the other tests, then there can be no doubt. Tests " work " because no two 'substances behave exactly alike, or have exactly the same properties (cf. 5). In testing for a salt we ask ourselves two distinct ques- tions : (1) What metal does it contain? (2) To what acid is it related; that is, is it a sulphate, a chloride, or what? TESTS FOR CERTAIN SALTS 195 If a salt turns, out to be a calcium salt and also a car- bonate, it must be calcium carbonate. If we get a test for a sodium salt, and also for a chloride, the substance tested must be sodium chloride. 1. Chlorides. We test for a chloride (including hydrochloric acid) by dissolving the substance in distilled water, adding enough dilute nitric acid to give the solution an acid reaction (cf. 215), and by then adding a drop or two of silver nitrate solution. If a chloride is present, there will be a white precipitate of silver chloride, an insoluble solid. If we shake up the precipitate, it will clot together. If we pour some of it upon filter paper, and expose it to sunlight, it becomes dark. This last fact is the basis of modern photography (cf. 188). 2. Sulphates. We test for sulphates (including sulphuric acid) by adding to the solution of the substance some dilute nitric acid, and then a few drops of a solution of barium chloride or barium nitrate. If a sulphate is present, there will be a, white precipitate of barium sul- phate. 3. Nitrates. To test for a nitrate we first make a saturated solution of ferrous sulphate. To about 5 c.c. of this solution, in a test tube, we add a few drops of the solution to be tested, and mix it, by shaking, with the ferrous sulphate solution. We then tilt the test tube, and pour down its side about 5 c.c. of concentrated sulphuric acid. The heavy acid slides underneath the solution, and when we hold the tube up-. right, we find a brown layer or ring between the solution and the acid, provided a nitrate is present. 4. Carbonates (either the solids or their solutions) are tested for by means of dilute hydrochloric or nitric acid. Effervescence takes place, and we prove that the escaping gas is carbon dioxide by passing it into lime water. A white precipitate of calcium carbonate is formed (cf. 126). 5. Phosphates. We test for phosphates in solution by adding to the solution, first, a few drops of concentrated nitric acid, and then a solution of ammonium molybdate. A yellow solid is precipitated, if phosphates are present. 6. Iron Salts. Solutions suspected of containing iron are treated 196 ACIDS, ALKALIES, AND CLEANING ivith a few drops of concentrated nitric acid, and boiled for a few minutes. Then a few drops of a solution of potassium thiocyanate or .ammonium thiocyanate are added. A blood-red solution results; this is pink if only a little iron is present. 7. Sodium Salts are tested for by the bright, yellow flame they give when they are held, on a platinum wire, in the colorless gas flame (cf. 240). 8. Potassium Salts give a violet color to the colorless gas flame. The color is seen best when it is viewed through blue glass; this cuts off the yellow rays of sodium. 9. Calcium Salts. We test for a calcium salt by treating its solu- tion with ammonia water and a solution of ammonium oxalate (the ammonium salt of oxalic acid). A white precipitate of calcium oxalate is formed. We pour off the liquid portion from the precipitate, and .add dilute acetic acid to the precipitate. If the precipitate is really calcium oxalate, it will not be dissolved. 10. Ammonium Salts. We test for ammonium salts by adding them, in solution, to a small lump of quicklime, or about 5 c.c. of sodium hydroxide solution, and warming the mixture gently. Ammonia is ;given off, and can be known by its odor. 222. Exercises. 1. Why do we add soda to tomatoes in making " cream tomato " ;soup? How do sour milk and soda " raise " biscuits? Why do straw- berries curdle milk? 2. How could you tell whether a soil was " sour " or not? 3. Lime water is often added to milk before the milk is given to a child or an invalid; why? 4. " Galvanized iron " is iron covered with zinc. Is it a safe material for utensils in which fruits are cooked? Why? Is " tinned " iron .safer? Why? 5. What base would you use if you wished to make some potassium nitrate by neutralization? What acid would you use? How would you tell when you had used just the right amount of each? 6. In moist weather, laboratory bottles sometimes lose their labels. If this occurred, how could you tell whether a certain solid was, or was THE WASHING OF CLOTHING 197 not, calcium carbonate? Ammonium sulphate? Sodium nitrate? Iron chloride? 223. The Washing of Clothing. We must now apply what we have learned about acids, bases, and salts to some FIG. 194. Modern Laundry. The illustration shows an electric-power tub for washing ; one for rinsing ; a hot mangle, or ironer; a cold mangle; electric irons, and laundry tub. Courtesy of the Department of Home Economics, Cornell University. common household practices. We begin with the washing of clothing (Fig. 194). Clothing that has been worn too long has a damp, sticky feeling. It has this feeling because its pores are clogged with the materials given off by the skin. These consist of perspiration, of organic waste which the body casts off through the skin, and of dead skin itself. When these fill the pores of clothing, it is unfit to wear, whether it looks dirty or not. The evaporation of the perspiration regulates the temperature of the body (cf. 74), and the clothing should aid, not hinder, this evaporation. The reason why clean garments feel so comfortable is largely because they have a fresh absorbing surface. 198 ACIDS, ALKALIES, AND CLEANING We should have clean bodies for the same reason that we should wear clean clothing, if for no other; viz., in order that the pores of the skin may be permitted to act freely in removing waste, and in evaporat- ing the perspiration. The washing of clothing thus has three objects: (1) To remove dirt, and to open the pores of the clothing. (2) To dry the washed clothing, and to give it a new absorbing surface. (3) To destroy the bacteria which are sure to accumulate in the dirt of the skin and clothing. 224. Soap. To remove dirt we need not only water, but soap. Soap is a salt, or a mixture of salts. The metal (cf. 221) present in hard soaps is sodium; in the old- fashioned soft soaps (Fig. 195) it was potassium. The acids to which the soaps are related (cf. 221) belong to the class of "fatty" acids, so called because they are ob- tained from the fats. Ex- amples of the natural fats are beef suet, mutton tallow, and lard. Oils are liquid fats. Strictly speaking, we cannot call petroleum products or coal-tar products, such as kerosene or benzene, oils at all. Palm oil, olive oil, and cotton-seed oil are true oils. Soaps are made by the boiling of fats and oils with alkalies. When fat is heated with sodium hydroxide, it is " cut," or "saponified." Saponify is from the Latin sapo (soap), and means " to make into soap." As a result of the boil- FIG. 195. Old Way of Mnking Soap from Grease and Potash L., e. Negative by T. B. Magath. SOAP 199 ing with alkali, the fat disappears into solution ; it is changed into the sodium salt (soap) and glycerine. Both of these are soluble; but when salt is added to the solution the soap is "salted out/' and floats on top of the solution. It is then skimmed off, pressed, and cut into cakes. FIG. 196. Modern Way of Making Soap. The kettle is three stories high, and holds perhaps 275,000 Ibs. : enough to make, say, 700,000 bars of soap. Courtesy of Swift and Company. In many modern soap factories (Fig. 196) the fat is first heated with steam. The products are then glycerine and the fatty acids. The soap is made from the fatty acids and sodium carbonate (instead of the hydroxide). Gly- cerine is a very valuable " by-product " of the soap fac- tory. Until a few decades ago soap was made in the home. In the spring the winter's accumulation of wood ashes was pounded down into a barrel, and set on a platform to be " leached," or extracted by water. A hole was made in the ashes, water was poured into it, and the solu- 200 ACIDS, ALKALIES, AND CLEANING tion of potash that was formed trickled out into little troughs in the platform. The solution was collected in kettles, and boiled down to form the home-made lye. A kettle of fat was melted over an open fire, the lye was added to this, and the two were cooked together, often for two or three days. The resulting " soft soap " was put away in barrels for the next year's use. 225. Action of Soap. When a sodium soap is dis- solved, it is partly broken up, by the action of the water, into sodium hydroxide and the fatty acids (cf. 218). The sodium hydroxide acts upon the fats and oils of the skin and clothing, and partly converts them into soaps, so that they also are dissolved by the water. In using soap we are using lye in a most convenient form, for its caustic properties are so altered that it can cleanse fabrics and the skin without injuring them. Toilet soaps are " neutral to litmus," because an excess of fat is used, so that the amount of free alkali is small. Laundry soaps have more free alkali. Soap has not only this chemical action, but the lather, or suds, acts mechanically, entangling the undissolved fat, dead skin, and dirt, and removing them. 226. Soap and Hard Water. We have already learned (cf. 82) that the hardness of water is its soap-consuming power. Hardness is due to dissolved salts, especially calcium carbonate (limestone) and calcium sulphate (gypsum). When soap is put into a hard water, it acts with these salts, forming the calcium salts of the fatty acids. These are insoluble, and separate as a scum, called lime soap. If soap is used in sufficient amount, it will soften such a water; but soap is too expensive. Besides, MATERIALS OF CLOTHING 201 the lime soap gets into the pores of the fabric, and in- jures it. If a soft water cannot be obtained in any other way, a method of " softening " should be used. To remove permanent hardness from a laundry water we often use soda or borax. Borax is sodium borate. Sodium carbonate (or borate) + calcium sulphate give (soluble) (soluble) sodium sulphate + calcium carbonate (or borate). (soluble) (insoluble) The sodium sulphate left in the solution has no action with the soap. Both temporary and permanent hardness may be removed at one opera- tion by the correct amount of ammonia water or caustic soda. Washing powders also precipitate hardness. They are usually soda or potash, or dried soap containing an excess of alkali. 227. Materials of Clothing. Two common vegetable fibers used for clothing and in the household are cotton and linen. Cotton is the covering of the seed of the cotton plant; while linen is found in the stalks of flax. Both are chiefly cellulose (cf. 123). Although cotton and linen are much alike chemically, they are very different physically. Both consist of hollow tubes (Fig. 197); but the fibers of cotton are flat and twisted, while those of linen are nearly straight, and have thick walls with a central opening. Linen cloth is stronger than cotton, but cotton is lighter and more elastic. Cotton and linen are easily de- stroyed by mineral acids (cf. 214), Woo( - if these are strong or are allowed to Fiberg /'^ Linen dry upon the fabric. They are not ering ol of thewooi! scaly 202 ACIDS, ALKALIES, AND CLEANING so easily harmed by alkalies. In fact, if cotton is treated with strong alkali for a short time, and is then washed thoroughly, it is actually made stronger, and has a glossy, silky appearance. Cotton so treated is called mercer- ized cotton. Wool and silk (Fig. 198) are of animal origin, and con- sist not only of carbon, hydrogen, and oxygen, as cellulose does, but contain nitrogen also (cf. 123). They are the opposites of cotton and linen in chemical behavior; for they are not readily acted upon by acids, but are easily destroyed by FIG. IDS. alkalies. The fibers of wool are entirely Co t c he siik"orm. ibers f different from those of linen and cotton. Instead of consisting of long cells, wool is made up of short, thick cells, with the projecting edges of each lapping over part of the one next to it (Fig. 197). The surface thus appears to be covered with horny scales all lying in one direction. No method of washing wool should be used that will force the cells closer together, or the wool will shrink, and finally become stiff and board-like. 228. Dyes. Dyes are colored compounds that are either absorbed by the pores of a fiber, or combine chemi- cally with the fiber to form a colored, insoluble compound. Silk and wool are much more active chemically than cotton and linen. Hence silk and wool can combine directly with many more dyes. We can think of the process of dyeing cloth as a reaction much like that which occurs when an acid and a base unite to form a salt (cf. 220). PAINTS 203 Since cellulose combines with very few dyes directly, it and the dye must be held together by a third substance, which can unite with the cellulose on the one hand, and with the dye on the other. Such a substance is called a mordant. Here, also, we can look upon the dyeing process as a reaction between acids and bases; only there are three substances in the reaction instead of two. The final, complex salt is the dyed fabric itself. Aluminum hydroxide is a common mordant. It is insoluble, and it is sticky, like boiled starch. It is formed in the fibers of cloth when we soak the cloth in aluminum acetate, and then in ammonia water. In the making of calico the pattern is first printed on cotton cloth with a mordant, and the cloth is then soaked in a dissolved dye. Tne dye com- bines with the mordant, but not with the cloth alone. The uncom- bined dye is washed out. If different parts of a pattern are printed with different mordants, a number of colors can be made from the same dye. 229. Paints. Common paint consists of linseed (flax seed) oil and turpentine, mixed with " white lead," or " zinc white/' and a pigment to give color. White lead, etc., are compounds used to give the paint " body " or "covering power." The turpentine not only thins the paint, but assists in drying the oil. When paint dries, its linseed oil is oxidized by the air to a hard gum. Considerable heat is given off in the process; hence heaps of cloths containing paint or linseed oil often take fire without an apparent cause (" spontaneous com- bustion "). Such cloths should never be left about a building except in covered metal boxes. To remove a paint stain from a fabric we need usually remove only the linseed oil. This is soluble in benzine, gasoline, etc. When we have removed the oil, we can generally remove the white lead by brushing or rubbing. 204 ACIDS, ALKALIES, AND CLEANING When we use gasoline as a cleaning agent, we should take great care to remain away from a fire. Especially should we use care in rubbing silk that is wet with gaso- line, lest the gasoline may be set on fire. 230. Removal of Stains. When we wish to remove a stain from a fabric, we should consider whether the substance causing the stain must be changed chemically, or whether it can be removed by physical means. Thus, paraffin (" white wax "), the material of many candles, especially of colored candles, is not a fat, and cannot be saponified by lye and soap. It is, however, readily dissolved by benzine, gasoline, or ether, and can thus be removed. An excellent way is to wet the paraffin spot with benzine, and then to press it, by means of a flat iron, between blotters. Milk and cream stains, if fresh, are washed out with cold water. If, however, they are old stains, the water of the milk will have evaporated, leaving the fat in the fiber. To remove them we use soap and water, or ammonia water, or we moisten the spot with benzine and press it between blotters. Ammonia water, like soap and lye, saponifies the fat and makes it soluble. Iron rust must be removed by chemical means. It is a base (ferric oxide or hydroxide) ; hence we use an acid to remove it. Dilute hydro- chloric acid (cf. 111), lemon juice and salt, etc., are commonly used. The acid must then be rinsed out and neutralized. Ink stains are often hard to remove, because we cannot be sure of what the ink is made. Fresh ink stains are usually taken out by fresh milk. Old stains are soaked in water, and treated with oxalic acid (10% solution). The acid is a poison. It should finally be rinsed out with water, and neutralized by a mild base like borax or ammonia water. Old-fashioned inks contained iron compounds; hence stains caused by them are treated like iron rust. We must remember that most active chemicals, such as acids and bases, affect dyes (cf. 215); hence they can rarely be used to remove stains from colored fabrics. The cleaning agent should be used with a piece of the goods, before it is applied to the garment. Acids spilled EXERCISES 205 on cloth should be washed out at once with water, and the spots treated with a solution of baking soda, borax, etc. Ammonia should rarely be used to neutralize acid spots on colored goods; it may react with the dye, as well as with the acid we wish to neutralize. 231. Summary. Acids are the sour substances present in fruit, vinegar, pickles, etc. They are either organic or inorganic. Inorganic acids are also called mineral acids. Acids act upon coloring matter, metals, carbonates of metals, bases, and fabrics, especially upon cotton and linen. Alkalies are the strongest bases. They turn litmus blue, destroy skin and flesh, saponify fats, neutralize acids, and destroy fabrics, especially wool and silk. Neutralization is the chemical action between an acid and a base. After neutralization the solution contains a salt. Testing for salts consists in finding the metal present in them, and the acid to which they are related. Washing of clothing is for the purpose of removing dirt, opening the pores of the cloth, and destroying bacteria. Soap is the sodium salt of certain fatty acids; it is made by the boil- ing of alkalies with fat, and is soluble in water. Soft water and soap give alkali and organic acid in mild form. Hard water first gives a lime-soap scum. Hard water is " softened " by soap, soda, borax, ammonia water, etc. Cotton and linen consist of long hollow fibers of cellulose. Wool consists of short, thick cells having overlapping scales. Silk and wool can be dyed directly more easily than cotton and linen. Mordants are substances used to unite the dye to the fabric. Paint generally consists of linseed oil, turpentine, a pigment, and lead white, or some other substance with "covering" power. Stains are removed sometimes by physical, and sometimes by chemical means. 232. Exercises. 1. If you have spilled dilute hydrochloric acid upon woolen cloth- ing, what should you use to neutralize the acid and to restore the color? Would caustic soda do? Why? 206 ACIDS, ALKALIES, AND CLEANING 2. Why is it not enough to wash clothing in cold water, even with soap? Why is not enough to use hot water, without soap? 3. Commercial laundries sometimes use acids, such as hydrochloric acid, for the washing of clothing; why is this not a good practice? What fabrics especially are injured? 4. Why should wool be washed with mild soaps, and in warm, but not hot, water? 5. How could you test a soap for an excess of alkali? 6. Why does not a soap give a lather as quickly in well water as in rain water? 7. Why is " blueing" used in the laundering of white goods? 8. Why do not men make soap out of petroleum and lye? 9. Why should oily cloths piled in a heap take fire spontaneously, while if outspread they do not? 10. What causes the "scum" that forms on the surface of an open can of paint? Gasoline and benzine are cheaper than turpentine; are they good substitutes for it? Why? CHAPTER XII WATER, HEAT, AIR, AND LIGHT IN THE HOUSE 233. Modern Conveniences. In no respect does modern life differ more greatly from that of the past than in home comforts and conveniences. Ancient and medieval peoples built larger monuments, and more enduring tombs and temples, than we are building; but the homes of the people were cheerless indeed when compared with those of American cities to-day. Even the wealthy could not always have heat, light, and water in abundance; consequently the winter was full of dis- comfort, houses were insanitary and dark, and filth and dirt were everywhere the rule. The cleanliness, light, and warmth of our houses, schools, and public buildings are due to modern scientific discoveries and their appli- cation. 234. Water in House and Town. We have already considered the need of pure water (cf. 81 to 85, and 226) ; we must also remember that modern man needs an abundance of water. In our houses we need it for drink- ing, for cooking, and, as ice, for preserving food ; for bath- ing the body, washing dishes and clothing, spraying lawns and gardens, and carrying waste matter into the sewage system. The industries of the city need it for producing steam, for washing and rinsing on a large scale, 207 208 WATER, HEAT, AIR, AND LIGHT IN THE HOUSE as in laundries, tanneries, slaughter houses, starch fac- tories, sugar refineries, gas works, petroleum refineries, dye works, paper mills, etc. The community as a whole needs it for protection against fire, and to carry away its sewage. Some cities pump water into "standpipes," or elevated reservoirs, from which it flows, under pressure, into the street " mains," and then into the houses; others use force pumps of large capacity (cf. 42) ; others, still, have a combination of both systems, using the reservoirs to assist the pumps when there is the greatest demand for water, as at meal-cooking time, or when there is a serious fire. In order to get enough water, great cities go to enormous expense. The Romans built great aqueducts (Fig. 199) to bring water from the lakes of the Apennines to Rome. New York City now gets its water, through an aqueduct, from the Catskills, 90 miles away. Denver is fortunate enough to be sur- rounded by mountains having many streams of pure water; this is allowed to flow through pipes, by gravity, to the city. Los Angeles gets its water , from mountains many miles How water may be carried under a river. away. The cities on or near the Great Lakes use lake water; but they take great care to prevent the sewage from the city from polluting the water intended for the city. Chicago has built an expensive " Drainage Canal" to carry water from Lake Michigan into the Illinois River, and thus to empty the city's sewage into the Mississippi instead of into the lake system. Inland cities usually get their water supply from a near-by stream; but such water needs careful filtration. 199 HYDRANTS AND TRAPS 209* 235. Plumbing. In some cities water is sold to con- sumers at a "flat rate/ 7 without regard to the amount used. Other cities use a meter, or measuring device,, which records the amount that actually flows from the street mains into the house. The pipes, faucets, traps, etc., through which water is carried to the different parts of the house, or away from it, make up the plumbing of the house. The word "plumbing" is from plumbum, Latin for "lead." To make lead pipes, men force hot lead, under great pressure, through steel dies having ring-shaped openings. Nowadays iron pipes, as well as lead ones, are used for plumbing. The iron is " gal- vanized" to prevent rusting (cf. 222, Ex. 4). Lead is used for pipes, sink linings, etc., because it is not rusted readily (cf. 216). Lead pipes .are also easy to bend around corners and into special shapes. Then, too, they can be cut readily where necessary, and the pieces joined by solder. But the use of lead has one disadvantage, in that the fresh surface of the metal is acted upon, and dissolved, by water. When lead is taken regularly into the body, as in drinking water, it accumulates until it causes sickness. Painters often have "painters' colic" because of the lead compounds in paint (cf. 229) . Lead is not acted upon greatly by pure water; but air and soft water, especially if carbon dioxide is present (cf. 80, table), gradually " dissolve" it. Hard water acts. upon the inside of the pipe after a time, and produces a coating that does not dissolve. This protects the lead and the water. We should always let water run for a moment from a new lead pipe, so as to make sure that the water we drink is free from lead compounds. 236. Hydrants and Traps. Faucets, or hydrants, are usually of brass, sometimes plated with nickel. They are generally of two kinds: (1) Those having a movable, tapered plug with a hole in it. 210 WATER, HEAT, AIR, AND LIGHT IN THE HOUSE (2) Those in which the opening is closed by a rubber " plunger," or "gasket." Waste water, like that from a sink or bowl, is discharged into the sewer pipe through a trap (Fig. 200). This is a bend in the pipe, which remains full of water, and cuts off connection between the air of the room and that of the sewer. Water should be -From sink run every few days into sinks and floor drains that are little used, so that the traps may always be full. 237. Kindling a Fire. The discovery Drain Plug of fire came long before the dawn of history. To Waste Pipe j. ... , Fig 200. Many primitive peoples still start their A Trap. fij. es ^y ru kk m g one pi ece of wood against another. The friction gives the temperature needed to set on fire the bits of bark, pitch, dry fungus, etc., that serve as tinder (cf. Fig. 63, 76). A century ago the kindling method used in Europe and America was to strike steel or iron pyrites (a compound of iron and sul- phur) against flint. In the flintlock musket this method was used to kindle gunpowder. The first practical friction matches were made about 1827. They consisted of wooden splints partly coated with sulphur, and tipped with potassium chlorate, anti- mony sulphide, and gum. Friction against a rough sur- face produced heat enough to make the sulphur unite with the oxygen of the potassium chlorate, and the heat of the burning sulphur set the wooden splint on fire. The "parlor" match has a tip containing paraffin or sulphur, yellow phosphorus, and some oxidizing substance like potassium chlorate or "red lead." Glue is used to make all the substances adhere to the wood. Parlor matches are ignited much more easily than THE FIREPLACE 211 sulphur matches; in fact, they often cause accidental fires. Another serious trouble with the parlor match is that it is deadly to the workmen (and these are largely women and children) who handle it. They are frequently at- tacked by a dreadful disease called "phossy jaw." For these reasons many governments forbid the use of parlor matches. Safety matches are less convenient to use than other forms, because they must be struck against the surface of the box; but they are not so likely to take fire, and are much less dangerous to make. The reason for this is that safety matches use red phosphorus, instead of the more active yellow form, and that the phosphorus is on the striking surface instead of on the splint itself. The striking surface is red phosphorus and sand; the tip contains antimony sulphide, some oxidizing substance, and glue. A " strike anywhere" match is now being made with phos- phorus sulphide, a substance that does not cause the evil effects of yellow phosphorus. 238. The Fireplace. It is hard for us to realize that modern methods of heating are of such recent origin that our grandparents, or certainly our great-grandparents, lived at a time when all of these methods were little known, and when the heating and much of the lighting of the house was done by the open fireplace (Fig. 201). No modern method of heating brings into the house the cheer and sentiment that belonged to the fireplace; hence men try, whenever possible, to use it as an ornament, no matter what system they use for the actual heating. But the fireplace is more than an ornament, for it is one of the best means of ventilation (cf. 248), carrying out the foul, cooled, lower air, and making room for the warmed, fresh air that is so much needed for health and comfort. The accessories of the fireplace were numerous. The necessary 212 WATER, HEAT, AIR, AND LIGHT IN THE HOUSE ones were the crane, a swinging frame from which the cooking utensils were hung, and the andirons, or "dogs," used to hold the fuel up from the hearth, so that the air might have better access. In large fireplaces a huge "backlog" was used. This was placed at the back of the fire, while smaller pieces of fuel were laid on the andirons, before it. The Fig. 201. The Fireplace of a Modern Living Room. backlog often lasted for days, and from it the new fire was built in the morning. 239. Stoves. In a stove the heat produced by burn- ing fuel can be used in a more economical and convenient way than in the fireplace. Stoves are usually of cast iron or steel. The best surfaces for absorbing and radiating heat are not highly polished and plated, but roughened and black (cf. 181). In a cooking stove both the top and the oven must be heated. To heat the oven evenly, we rieed specially constructed flues, or outlets. If the h'ot gases formed in burning are allowed to escape at once, GASOLINE AND KEROSENE STOVES 213 there is great waste of fuel; for only the top of the stove is heated. But the cook stove has a "back damper" which compels these gases to travel in a roundabout way, heating a large surface of the oven before they enter the pipe leading to the chimney. Wood and coal stoves have a slightly different construction. 240. Gas Stoves. Gas stoves are rapidly taking the place of wood and coal stoves, wherever gas can be ob- tained. The gas used for lighting has a smoky flame, and deposits soot. To avoid the soot, and to secure a hot flame, we use the principle of the Bunsen burner (Fig. 202). In this burner the gas escapes through a pin-hole into a mixing tube. The tube has air holes near the gas inlet. The small, rapid current of gas draws the air into these air holes, and the mixture of air and gas burns at the top of the burner. The flame is Fi g . 202. smaller than if the gas were burned directly; but it is also hotter. Since the gas is mixed thoroughly with air, the flame is smokeless. Smoke, or soot, repre- sents wasted fuel. If the supply of air taken in by the Bunsen burner is too great for the amount of gas, there is a slight explosion in the mixing tube, and the flame "strikes back" to the narrow opening inside the burner. If we regulate the gas supply and the size of the air holes, this will rarely take place. In gas stoves the air holes are at the front, near the openings through which gas enters. 241. Gasoline and Kerosene Stoves. The gasoline burner is essentially a Bunsen burner. To light the 214 WATER, HEAT, AIR, AND LIGHT IN THE HOUSE gasoline stove we run some of the gasoline into a "cup," and there burn it to heat the vaporizer. When the vaporizer is hot, we allow the liquid gasoline to enter it very slowly ; it is there changed to the gaseous form. Air is drawn into the burner by the current of gasoline vapor, and the mixture burns at the top of the burner with a very hot flame, as in the case of gas. The use of gasoline is attended with some danger unless the stove is of good construction, and unless great care is taken in handling it. People think of gasoline as a liquid. They should rather think of it as a gas. It boils very low (60 to 70 C.), and what seems to be only a little of the liquid may give a great deal of the vapor. The vapor forms a very explosive mixture with air. Reservoirs should not be filled when fires are anywhere about, and if any gasoline is spilled, the room should be thoroughly aired before a burning body is brought into it. Kerosene burns with a smoky flame, and has a high boiling point (150-250C.; cf. 121); hence burners using it must have hotter vaporizers and a greater air supply than gasoline burners. 242. Electric Stoves and Heaters. The great advan- tage of electric heating is leading to its use on a con- stantly larger .scale (cf. 157). The electric flat-iron (Fig. 194, 223) requires no hot range to heat it, nor any particular room for its use, but may be used wherever there is an electric "outlet." The electric stove needs no flue, and heats without fuel or odor. The electric heating pad is far superior to the hot-water bag, for it does not grow cold. But electric heating appliances, like all others, require care; if overheating occurs in the circuit, there is serious danger of fire (cf. 258). 243. Hot Water and Steam Heating. The hot-air furnace has been described already (cf. 67). It brings THERMOSTAT 215 Overflow Pipe- warm air into the house, because it sets up convection currents. Hot-water heating systems (Fig. 203) depend upon the convection currents set up in cold water when one part of the water is heated. The heating is done in a furnace, and the water heated, being lighter than the colder water in the pipes and radiators, rises to take its place. The cooler water flows back to the furnace, to be heated. A "standpipe" in the attic keeps the radiators full of water. In steam heating, a furnace is used to convert water into steam, and the heat given off by the steam, as it cools and condenses (cf. 89), warms the house. The hot water remaining after condensation returns to the boiler to be reconverted into steam. 244. Thermostat. We have already learned that a thermometer tells us temperature by registering the difference in expansion between mercury and glass (cf. 62). We could also make a thermometer out of two metals that expand different amounts when heated through the same degrees of temperature. Thus, we can rivet together a small bar of iron and one of brass so that the resulting compound bar is straight when cold ; but when Fig. 203. Hot Water Heating System. 216 WATER, HEAT, AIR, AND LIGHT IN THE HOUSE the bar is heated, the unequal expansion of the two metals will produce a curved bar. If we fasten one end of the compound bar, leaving the other end free, the free end will be able to push against a pointer, and so to record the temperature. In the thermostat (Fig. 204), an instrument used to regulate the temperature of a room, the bar is made a part of two electric circuits; it will permit the current to flow in one circuit when the room becomes too warm, and through the other circuit when the room becomes too cold. Electromagnets in the two circuits control the supply of steam, hot water, etc., turning it on or off as needed. 245. Exercises. 1. What is the source of the water in the city in which you live? Is the water hard or soft? Is it purified in any way before it enters the mains? How large are the mains? Is your city water ever tested for impurities? What have been the results of the tests for the last two months? How much does your family pay for water? How many cubic feet of water does your family use in a month or in a quarter? 2. What is the form of the plumbing " traps " in your house? Are they like the trap shown in Fig. 200? If your basement or barn has a floor drain, find out the form of the trap, and describe it. 3. How are the outside faucets of your house emptied to prevent the water in them from freezing in winter? Why not let the water freeze in them? 4. Suggest some ways of kindling fire without the use of friction. 5. Show that the wood and coal cook stove is really an improved form of fireplace. Show that the fireplace fire is an improved form of the open fire built against a rock. Fig. 204. Thermostat. I f the room be- comes too warm, the brass ex- pands more than the iron, and turns the rod to the right; so that it makes a circuit which cuts off the heat. NEED OF VENTILATION 217 6. In what way are gasoline cans commonly distinguished from cans for kerosene? Why? 7. What is the cause of the " pounding" often. heard when steam is first turned on in a cold radiator? 246. Need of Ventilation. The changes that take place in air during breathing have been given in 52. Ventilation means the supplying of fresh air and the removing of foul air. Our houses give us shelter, warmth, and a host of comforts; but they usually rob us of air. When the open fireplace was used, ventilation required little thought; for the large volume of air that passed out through the chimney was constantly replaced by fresh air drawn in through cracks around doors and windows, and even through chinks in the walls. But as men have built tight-walled houses, used weather strips and storm windows in winter, and replaced the fireplace by stoves, furnaces, and steam and hot water heaters, this natural ventilation has largely disappeared. It is a common experience of doctors that many people who are healthy enough in warm weather, when doors and windows are open, have ' ' colds " and throat diseases when cold weather comes on. One reason for this is that they seal up most of the openings through which fresh air can enter and foul air be removed. We must have good air in our houses, or we, as a race, are doomed. The way in which tuberculosis, or consumption, is now treated shows the importance of fresh air. Instead of being protected from the outer air the patient is now told to live in a tent, in the open air, winter and summer, day and night. Pure air, with nourishing food, has been found to be an almost certain cure for the disease in its early stages. If the patient will do his part, it seems as though nothing can 218 WATER, HEAT, AIR, AND LIGHT IN THE HOUSE prevent our getting control of the " Great White Plague," as consump- tion is called, in civilized communities. Many healthy persons, realizing that their daily work gives them too little time in the open air, sleep out-of-doors, even in winter. They do this, not only without injury, but with great gain in health and vigor. 247. Methods of Ventilation. It has been calculated that during one hour a healthy man will make about 4,000 cubic feet of air unfit for breathing. This is the volume of a room 20 x 20 x 10 feet. Of course rooms are not air-tight; hence all this air need not be forced into a room artificially. The Massachusetts law provides that at least 1,800 cubic feet of fresh air shall be furnished each pupil each hour he is in school. If the amount of air furnished to a schoolroom is below this, somebody ought to take steps to get better ventilation. Recent experiments show that the air of houses becomes unfit to breathe, not so much because it contains im- purities, as because it is stagnant. Slightly impure air, if in motion, is better than highly pure air that is not moving. In other words, the greatest need is circulation of air. Where steam or electric power can be obtained, as in city build- ings, and in factories, heating and ventilation are often carried out together. One method of such forced ventilation is to drive warm, fresh air into the building by means of rotary fans, while the im- pure air escapes through openings made in the walls and ceilings. Another method is to remove the impure air by fans, and to admit fresh, warm air through many small openings near the floor. Drafts are thus prevented. The air is usually warmed by steam coils in the basement. The means of ventilation may also be used to cool buildings in sum- mer, if the fresh air is first passed over ice. VENTILATION WITHOUT FANS 219 248. Ventilation without Fans. If there is no system of ventilation in the house, each person owes it to himself to provide fresh air for his breathing. Natural ventilation depends upon the simple fact that heating air makes it lighter, so that it rises, while cooling it makes it heavier, so that it falls (cf. 67). We must remember also that in winter the air of the house is warmer than the air out- side; hence fresh air naturally enters through the cracks at the bottoms of doors and windows, while the warm air of the house leaves at their tops. Bedrooms. The windows of bedrooms should be left open, unless storms make this actually impossible. An excellent plan, in stormy weather, is to lower the upper sash a few inches. The outside air then enters between the sashes, while the air of the room leaves at the top of the window. If a board having partly boxed holes (Fig. 205) is placed under the lower sash, the same result is reached. Bedrooms should be aired thoroughly during the day. The fact that a bedroom is kept cold does not mean that its air is pure; cold air may be just as foul as warm air, if it is not renewed often enough. Gas stoves or kerosene stoves not connected with a chimney are dangerous in closed rooms, since they produce carbon dioxide and use up oxygen (cf. 127). Schoolrooms. Schoolrooms that are not ventilated artificially should have each of several windows open a little, rather than one open wide. In this way strong air currents (" drafts") are avoided. If the Fig. 205. How to Ventilate a Bed- room in Stormy Weather. 220 WATER, HEAT, AIR, AND LIGHT IN THE HOUSE wind is blowing strongly, the openings should be on the side opposite the wind. When a large room is heated by a*stove, the stove should be sur- rounded by a "drum," open at the top and bottom, and reaching from near the floor to a point some distance above the stove-top. The drum should be in two parts, hinged together, so that the stove may be easily reached. The circulation of air in the room is then not left to chance; for the drum not only protects those nearest the stove from excessive heat, but it also sets up useful convection currents. These bring cold air from the farthest parts of the room to the stove, heat it, and then carry it away along the ceiling. The room is thus heated evenly, and ventilated at the same time. Healing Systems and Ventilation. The hot-air furnace brings in fresh, warm air; but the removal of the cooled, foul air is left to the cracks of the room. The fireplace, since its opening is near the floor, is an excellent aid to the hot-air furnace. Stoves provide some ven- tilation; since fresh air from outside must come in to take the place of the air that goes through the stove. Hot water and steam heating systems of themselves give no ventilation. 249. Need of Moisture in Air. One very important constituent of fresh air must not be forgotten : its mois- ture. We find air very comfortable, at any given tempera- ture, if it has between 2 /5 and 2 /s of the water it can hold at that temperature. Such air takes up the perspiration at a moderate rate, and so regulates the heat of the body. But if the moisture is more than 2 /s of what the air can hold, we are uncomfortable; the perspiration does not evaporate rapidly enough, and the air feels "sticky." When too little moisture is present, the perspiration evapo- rates too rapidly. The skin then becomes parched and dry. As a result of artificial heating and ventilation the amount of air moisture in a house is almost sure to be too small. The reason for this is that the cold air entering a GLASS 221 house has its power of holding water increased by warm- ing. The actual amount of water is not changed; but the amount that the air holds as compared with what it is able to hold is decidedly smaller. Hence it takes too much moisture from our bodies. A well-known authority says that the moisture in the air of a room should be such that dew and frost are deposited on the inside of windows in cold weather. If steam or hot water are used for heat- ing, a shallow dish of water should be kept in the room. In the hot-air furnace a water pan is provided inside the air box. This should be kept full. 250. Light in the House. The problem of lighting the house properly is a very serious one. Primitive peoples, and even our own ancestors of a few generations ago, could afford but little sunlight in their houses, free as it is out of doors. This was because they had no cheap transparent substance like our modern glass. They had only oiled paper, or thin sheets of horn, isin-glass (the mineral mica; cf. 285), etc. But the common people could not afford, or get, much -of these materials; so their houses were dark. The problem of sunlight is so impor- tant to the general health, as well as to sight, that the men who made cheap glass possible must be ranked among the greatest benefactors of the race. Darkness in the house means dirt and filth, and where these exist disease and pestilence are sure to get a foothold. 251. Glass. Glass is made out of a mixture of sand, limestone, and soda (or sodium sulphate instead of soda). The mixture is melted in fire-clay pots about 4 feet high 222 WATER, HEAT, AIR, AND LIGHT IN THE HOUSE and 4 feet in diameter, and forms a clear, transparent liquid. When this is cooled, it forms, before it hardens, a pasty mass. While the glass is pasty, vessels and other objects can be made from it, and it can be "blown" into many shapes. Window glass is made by work- men who blow the pasty glass (Fig. 206) into the form of a cylinder, and then cut the cylinder open lengthwise, so that it forms a sheet. In a new process, glass is also drawn out by a machine into sheets Fig. 206. Blowing Window Glass. Fig. 207. Casting Plate Glass at the Saint Gobain Manufactory, France. Scientific American Supplement. From the ARTIFICIAL LIGHTING 223 of any desired width and of varying thickness (Scientific American Supplement, No. 1689). Plate glass is made by the pouring of melted glass upon hot iron plates; heated rollers flatten it out (Fig. 207). 252. Artificial Lighting. Until about 1860 the only common means of lighting were the fireplace, candles, and oils. Among the oils used were lard, olive, and whale (sperm) oils. The oils burn with a smoky flame; but by the use of a wick they are drawn up (cf. 32), a little at a time, and converted into vapor. It is this vapor that burns. The oils have a very high boiling point; hence there is little danger that the body of the oil will be set on fire (cf. 122). Candles. The materials used for candles are waxes, fats, and paraffin. Waxes are high-melting fats, just as oils are low-melting fats (cf. 224). The making of Fig. 208. Modern Way of Making Candles, In some of the candle-moulding machines more than 500 candles can be made at once. Courtesy of Roman and Company, Cincinnati, Ohio. 224 WATER, HEAT, AIR, AND LIGHT IN THE HOUSE candles originally took place in the household, and in- volved much painstaking work. A wick was dipped into the melted fat, allowed to cool, and then dipped again, until the desired thickness was obtained. In modern candle-making (Fig. 208) the wick is set in a mould, and the melted fatty material or paraffin (cf. 121) is poured around it in the mould. In former times "snuffers" were required to remove the charred wick inside the flame; nowadays, snuffers are not needed. The reason for this is that in the modern candle one of the threads of the wick is pulled more tightly than the others. As a result the tip of the wick curves outward to the edge of the flame (Fig. 42, 49), where the air oxidizes it completely. Kerosene Lamps. The discovery of petroleum in Pennsylvania in 1859 (cf. Fig. 98, 121) had a decided effect upon the world's lighting and heating problems; for it furnished gasoline, kero- sene, paraffin, etc. Gasoline has too low a flash- ing point (cf. 122) to permit its use with a wick, in lamps. Kerosene cannot be burned with a wick alone, as the true oils can (cf. 224) , because it smokes. To increase the air supply, and so to prevent smoking, kerosene lamps have chimneys. The heated air and gases carried upward by convection create a draft; thus fresh portions of air are drawn into the burner below the flame. To increase the amount of kerosene that can burn in a given time, and, therefore, to get a more intense light, men use central draft burners. These have circular wicks (Fig. 209), and air is drawn to the inside of the circular flame as well as to the outside of it. 253. Gas for Lighting. Illuminating gas is formed when soft coal is heated in closed retorts (cf. 124), and Fig. 209. Central Draft Burner. Air gets at the wick both inside and out- side. GAS PIPES AND FIXTURES 225 when steam is passed through a bed of hot hard coal or coke. The second method gives water gas. At present nearly all illuminating gas is water gas il enriched" with gases obtained by the charring of petroleum; these make it light-producing. As illuminating gas comes to the consumer, it burns with a brilliant, yellow flame. If burned from a circular opening, it is smoky; but if we force it through a narrow slit (a "tip"), it is almost smokeless, because the gas has a large surface in contact with the air. 254. Incandescent Mantles. To get a brighter light than that of the ordinary gas flame, we may burn the gas in a Bunsen burner, and put a "mantle" in its hot, colorless flame. This is the principle of the Welsbach Fig - 21 ; and other " mantle" lamps. The light comes from the A gas stream incandescent (white hot) mantle (Fig. 210). The best mantles contain the oxides of the two rare metals cerium and thorium. The mantle is first knitted xi