MINERAL RICHES o? THE, ; EARTH. CAREFULLY COMPILED FOR THE AMERICAN SUNDAY-SCHOOL UNION, AND PROFUSELY ILLUSTRATED. PHILADELPHIA: AMERICAN SUNDAY-SCHOOL UNION, 1122 CHESTNUT STREET. NEW YORK: 599 BROADWAY. EART'ft SCIENCES LIBRARY Entered according to Act of Congress,, in the year 1861, by the AMERICAN SUNDAY-SCHOOL UNION, in the Clerk's Office of the District Court of the Eastern District of Pennsylvania. h PREFACE. To every intelligent observer, the ground we tread on presents so much variety of sub- stance that the mind naturally craves to know what it is made of and how it came there. The following pages are designed in some degree to meet that desire and afford authen- tic information for popular reading. i* CONTENTS. CHAPTER I. PAGE SALT AND SALTS , , 9 CHAPTER II. METALS 31 CHAPTER III. COAL AND COMBUSTIBLES 73 CHAPTER IV. CLAY AND SLATE 103 CHAPTER V. FLINT AND SAND 130 CHAPTER VI. GRAVEL 146 7 8 CONTENTS. CHAPTER VII. PAGE CHALK CORAL MAGNESIA ASBESTOS MOULD. ... 170 CHAPTER VIII. LIME MARBLE GRANITE 195 CHAPTER IX. VOLCANIC PRODUCTIONS 218 CHAPTER X. GEMS 246 CHAPTER XL FOSSILS 276 EARTH'S RICHES. CHAPTER I. SALT AND SALTS. MR. GOODMAN had a large family of sons and daughters, whose education he delighted to superintend; and young friends in abun- dance joined the social circle from time to time, sharing in their pursuits and partaking of their amusements. As is common among intelligent minds, their attention was sometimes attracted to subjects which, for a season, engrossed all their leisure time; and one summer was very hap- pily spent in constructing what they called "a friendship-grotto," inasmuch as the stones, (minerals and fossils with which it was deco- rated were contributed by various beloved friends and relations, who kindly interested 10 SALT AND SALTS. themselves in juvenile undertakings. Mr. Goodhjaxi .was *as \zealpus as any one; and, as 'his garden was situated among the inequalities of ground near a chain of hills, an appropriate spot was soon selected, where a sudden rising of the surface permitted the hollowing of a cave near a small spring of water. This oave was tastefully lined with specimens of all sorts. Stalactites hung from the roof; spark- ling ores adorned the sides, with fossil woods, zoophytes and shells; and different-coloured pebbles studded the floor. A summer-house was built over the top, to which access was made by a gentle ascent behind the grotto, and here some glazed shelves and partitioned drawers received those fragile materials which could not be exposed to the air, or were so valuable as to be guarded under lock and key. When all was completed, the interior of the grotto was furnished with a rustic table and seats ; and it became the favourite resort for the solitary students in the family, or for the afternoon social gatherings, when in summer weather they loved to read and work together, and often refreshed themselves with fruit or tea, after their labours, in this cool retreat. SALT AND SALTS. 11 At length, when the excitement of building and the novelty of possession had in some measure subsided, and all their friends had duly praised the ingenuity and admired the results of the young people's handiwork, Mr. Goodman proposed that they should take occasion to derive some permanent advantage from the time they had so happily spent, and the presents they had received, not only from friends at home, but in foreign countries, of minerals peculiar to different localities and of widely different composition and use ; for, till the subject is studied, few persons, per- haps, are aware how much their comfort and health depend upon substances composing the very ground they tread upon. This proposition was hailed with general satisfaction ; and Mr. Goodman, who had de- voted much of his own youthful leisure to mineralogy, and had lately been watching for an opportunity of imparting some of his taste to his children, at one of the evening meetings for tea entered upon the subject by asking which of the objects around should be first discussed. Edward Goodman, the eldest son, referred to salt, coals and metals, as certainly very 12 SALT AND SALTS. useful, and his sister Alice to clay, earth and gravel, as necessary for the growth of fruit and vegetables. Mr. Goodman said that it would help their memories to classify the subjects, and that, as they had just been eating salt with their early spring radishes, he would proceed to discuss that first. He accordingly stated that COMMON SALT has some very remarkable qualities. It is a great preservative against the putrefaction and decay of dead animals, yet is so injurious to living worms and snails that it speedily destroys and dissolves them. In moderation, it is needful with food; yet eaten in very large quantities it causes death, as an irritant poison, both to men and animals. It pre- serves plants and fruits when no longer grow- ing, and yet is so mischievous to living vege- tation that the most expressive mode of de- scribing a fertile country abandoned to bar- renness is to say, as the Scriptures often assert, " It is sown with salt." Thus, in the book of Judges (ix. 45) it is related that when Abimelech took the city of Shechem, he de- stroyed it, "and sowed it with salt" to render the ground unfruitful. COVENANT OF SALT. 13 Salt must have been very anciently known to mankind. It was one of the original che- mical deposits made in the ocean, and the ear- liest inhabitants of the East had access to it, in the form of rock-salt. It is mentioned in the earliest books of Scripture; and, in the law given by Moses, it was prescribed to be min- gled with the Jewish sacrifices. A store of salt was kept in the Temple, in an apartment appropriated to that purpose. According to Oriental usages, to partake jointly of salt was a pledge of peace and friendship : so that when once shared, even unwittingly, the bitterest foes were safe from mutual injury. This accounts for the phrase, frequent in Eastern tales, "He has eaten salt with him;" and the same mean- ing belongs to the Scripture expression "a covenant of salt." The bond of friendship and reconciliation was renewed by each fresh sacrifice under the Jewish dispensa- tion. " Neither shalt thou suffer the salt of the covenant of thy God to be lacking from thy meat-offering." (Lev. ii. 13.) "It is a covenant of salt," or friendship, "forever." (Num. xviii. 19.) " The Lord God gave the 14 SALT AND SALTS. kingdom over Israel to David by a covenant of salt. 1 ' 2 Chron. xiii. 5. We now no longer need the symbolic salt in our approaches to God's mercy-seat, be- cause we are told in the New Testament that Jesus has offered himself a sacrifice for all sins, and is now the perfect Intercessor and Mediator for all who by faith come unto God through him. Alice inquired whether the phrase in Eng- lish history, "sitting below the salt/' meant the same thing as the Oriental pledge of friendship. Mr. Goodman answered that that refers to the olden time, when a chief, and all his household, dined at the same table, but he and his family and guests sat at the upper end, above the salt-bowl, which was usually placed in the middle: hence to be above or below the salt indicated the rank of the per- son so seated. It is supposed, from the descriptions of Herodotus, that the ancient Abyssinians used to enclose their dead in masses of rock-salt, which is very common about that part of Africa. It is still employed as money there, and also in Thibet. The slave-caravans SEA-SALT. 15 across the deserts of Northern Africa carry rock-salt in great cubical masses as mer- chandise. Salt is very extensively distributed both in the Old and New Worlds ; in some regions in its fossil state, as rock-salt; in others, in brine lakes or springs, and thin incrustations formed by evaporation through the sun's heat. Wher- ever the sea comes, people may, if they choose, get its salt, by boiling and evaporating its waters. This process, however, yields But a coarse-grained kind, needing much purifica- tion, so that it is generally abandoned as civil- ization advances. The Turk's Island salt is of this kind. Many countries depend entirely upon foreign supplies of salt, and it is then an expensive article : in India fifty cents a pound is no uncommon price. Salt has been sometimes so heavily taxed as to occasion much distress among the poor. Salt became excessively dear during the war of the American Revolution. In a few places the inhabitants procure all their salt from the ashes of vegetables. The annual production of the English mines, from which the Western world is largely supplied, is about five hun- dred thousand tons, most of which comes down 16 SALT AND SALTS. the river Weaver to Liverpool. The annual consumption of salt by an adult man or woman has been estimated at sixteen pounds. Edward here interrupted to ask if all sea- water contained the same quantity of salt. Mr. Goodman told him that it varies con- siderably. The water of the Baltic Sea is reckoned to contain one-sixty-fourth of its weight of salt ; that of the sea between Eng- land and Flanders, one-thirty-second ; and the sea-tvater on the coast of Spain, one-sixteenth of its weight ; and it varies again elsewhere. In the heart of the American continent are extensive deserts and lakes of salt water, the largest of which is Utah Lake. Such exist also in Chinese Tartary. It is a rule in geography that whenever a body of water has no outlet to the sea it must be salt, because its rivers are always bringing down salt from the rocks around. The ocean is salt, because it necessarily retains all the salt that flows into it. Bodies of water like the Dead Sea, which lie low and under a hot sun, are necessarily salter than others. Salt water also being heavier than fresh water, the bottom of the Mediterranean Sea is salter than the top. This has been tested by experi- SALT-LICKS. 17 ment. At a depth of six hundred and seventy fathoms the salt water was found to be four times as heavy as at the surface. Salt seems quite a necessary of life to human beings; for we pat it into all our food, while in nature.it occurs in milk and other substances. Almost all graminivorous ani- mals are fond of it, and a mixture of it in their food seems beneficial. The wild animals of the forest repair regularly to the salt-licks, where salt waters issue from the rocks and form pools or marsh places, and here the hunters lie in wait for them. Some are called deer licks, others bear licks, and others buffalo licks. Eegularly-beaten tracks or paths descend to them, which have been used by the animals from very ancient days, and form the best ways to cross the mountains. In similar licks the mammoths and masto- dons of old were frequently mired and lost, and their skeletons are found at the present day. All animals need salt in some measure. It is, however, said to be injurious to poultry; and if human beings feed too much upon salt food, they suffer from scurvy and similar dis- orders, while the drinking of sea-water has often caused madness and death. The prophet B 2* 18 SALT AND SALTS. Elisha healed waters by casting salt into them ; which seems strange, for salt water is not fit to drink, and does not generally improve the land. But perhaps a remedy apparently so unlikely may have been commanded by God as a clearer exercise of his miraculous power. There is more in the Bible about salt than many might suppose. It is mentioned as a familiar substance in the book of Job, (vi. 6,) one of the earliest known records. "Salt- pits" are named by Zephaniah, (ii. 9,) as well as "the city of salt" by Joshua, (xv. 62.) The " valley of salt," (2 Sam. iii. 13,) " a salt land," (Jer. xvii. 6,) "salt marshes," (Ezek. xlvii. 11,) and a "pillar of salt," (Gen. xix. 26,) are all spoken of in the books of Moses, Samuel and Jeremiah. All the va- rious modes of procuring salt seem thus early to have been in use, while its common abundance is still further shown by Ezra's statement (vii. 22) that King Artaxerxes directed his treasurers to supply for the temple at Jerusalem "salt without prescribing how much." Salt was valuable enough to bear a tax in the time of the Maccabees, as it did also in the reign of Ancus Martius, the fourth king ENGLISH SALT-MINES. 19 of Borne, B.C. 640; and the Eomans took tribute from the Droitwich mines, in England, from their first settlement, paying their sol- diers partly with salt. Hence, it is said, we derive our word salary (from sal, salt) for the payment of work. These Droitwich springs are mentioned in Doomsday Book, and are yet inexhaustible, rising from beds of solid rock-salt through strata of gypsum from one hundred and twenty to one hundred and fifty feet thick. The salt-mines at Northwich, in England, are two hundred and twenty feet deep, lying in two beds, alternating with gypsum and marl. The salt-rock is red, and so hard as to need gunpowder. In the eastern part of France beds of rock-salt have been discovered, lying in regular order over one another, like beds of coal, to a- great depth in the ground. The borings through these beds, by which the salt water is allowed to ascend to the surface, are one thousand feet deep. The salt-wells of Syracuse, in the State of New York, sink to masses of rock-salt in a very ancient forma- tion, which contains also gypsum; and gypsum and salt usually go together in geology. At Saltzburg, in Southwestern Virginia, there is 20 SALT AND SALTS. a deep valley filled to the depth of five hun- dred or one thousand feet with red clay, gyp- sum and rock-salt ; and all that part of the country is now supplied with salt from thence. The hundreds of salt-wells sunk during the last fifty years along the valleys of the Mo- nongahela, Youghiogheny, Conemaugh, Alle- ghany, Beaver, Muskingum, and Mahoning Kivers in Western Pennsylvania and Ohio, and along the Big and Little Kanawha and Sandy Kivers in Virginia and Kentucky, descend through the rocks of the coal-measures and obtain their salt water from the formations immediately underneath, where lakes or sheets of it exist in the bottoms of the basins. When this salt water ascends to the surface, through natural crevices or through artificial auger- holes, it is often accompanied with coal oil and coal gas ; and these valuable natural pro- ducts of the earth are sometimes used to boil the salt water at the mouth of the well. It does not follow that all salt springs must be at the level of the ocean, although they must be in the bottoms of valleys ; for the salt lakes of Utah are in valleys elevated many thousand feet above sea-level. The central parts of the continent consist of elevated plains, covered PILLAR OF SALT. 21 with gravel and a scanty shrubby vegetation. "Where much rain falls, salts are washed out of the soil, and vegetation is abundant. Many parts of the world are barren for want of rain, and are very salt. The Isle 'of Ormus, in the Persian Gulf, consists almost entirely of rock- salt. There is no sweet water, nor grass; and, though once a place of trade for the Portu- guese and Persians, it is now almost deserted, as it produces nothing but fine white salt. This sometimes lies two inches thick upon the ground. Perhaps the largest salt-mines in the world are those of Cracow, in Poland, extending nearly a league under ground. Many of the workmen and horses live there entirely. There are cottages and chapels, statues and crucifixes, before which lamps are kept con- tinually burning. When well lighted up, these lamps look very glittering and beautiful, as the crystals reflect the light in splendid coloured rays. Sacred history informs us that, as the family of Lot were fleeing from the doomed cities of the plain, his wife " looked back" and "became a pillar of salt." That an object has been seen which was said to be the .pillar into which Lot's 22 SALT AND SALTS. wife was turned, and which the beholders be- lieved to be such, there is little doubt. In one of the Apocryphal books allusion is made to the destruction of the five cities: "Whose land, for a testimony of their wickedness, is desolate and smoketh to this day, and the trees bear fruits that ripen not ; and a stand- ing pillar of salt is a monument of an incredu- lous soul." This passage might be sufficient for the faith of Eoman Catholics, but would have no weight with Protestants. That a column of solid salt should be found in a region where there are " precipices of pure crystallized fossil salt forty or fifty feet high and several hundred feet in length,"* is by no means incredible ; but there is no satisfactory evidence of the existence of any visible memorial of the judgment which came upon Lot's wife. Indeed, it is remarkable that the scenes and events which the sacred history records should be so rarely marked by permanent visible monu- ments. To those who receive the Sacred Scrip- tures as of divine authority, their testimony is conclusive. "If they hear not Moses and the prophets, neither will they be persuaded though one rose from the dead." *Dr. Robinson, edit. 1841, vol. ii. p. 482. MAKING OF SALT. 23 Rock-salt is generally either of a pale red, green, blue, gray, or yellow color, and requires purifying to assume the delicate hue suited for domestic use. Only small cubes here and there are white. It is purified by dissolving the rock-salt in water, or by boiling the brine from the salt springs over and over -again, and evaporating, or suffering the water to fly off in vapour. The salt liquor is generally boiled in large shallow vessels, and the salt continually stirred, to prevent it from crystal- lizing as it granulates. It is afterwards dried, and sold in cakes of convenient size. Salt could be made in the chemist's labora- tory if it were worth while to do so ; but it is too abundant in nature to need artificial pro- duction. Chemically, it is a chloride of sodium. It used to be termed muriate of soda, but ac- cording to more accurate modern nomenclature its proper name is, as stated, chloride of sodium. There is generally a sediment, or residue of insoluble matter, from most brine. Salt pre- pared from sea- water leaves a mixture of car- bonate of lime and carbonate of magnesia, with fine flinty sand. Rock-salt generally leaves sulphate of lime, (gypsum,) or some sort of marly earth. 24 SALT AND SALTS. Salt water does not generally freeze so soon as fresh water : it requires a greater degree of cold to produce ice. Yet the arctic regions afford abundant proof that it freezes very completely under severe cold; and salt is added to snow and ice by confectioners to quicken the process of freezing their creams. In the salt steppes of Orenburg there is a remarkable cave, called the Freezing Cave, from the fact that during the summer months the surrounding region of salt renders its atmosphere so cold that snow and icicles line it at that season, though in the winter the same cave is so much warmer than the ex- ternal air that the Eussians state they could sleep iu it without their sheepskin cloaks. There is a coarse-grained salt that fisher- men use for salting fish, known also to most housekeepers by the name of bay salt, which is merely salt less carefully stirred in boiling and purifying than the finer sort. Both that and the finer kinds equally preserve fish or meat; but for packing and exporting such provisions the larger grains are best, as they do not soon dissolve, and therefore melt only as the juices of the meat absorb them. Bay salt is thus exceedingly useful for long voy- SALT AN ANTISEPTIC. 25 ages, and, moreover, is used for preserving foreign skins during their travels to the tanner. Great quantities of salted hides are brought from South America. Damask roses, too, are. imported for the chemist and perfumer, mixed with salt, which does not affect their sweet scent in the least : indeed, much of their colour is retained, as may be noticed when making rose tea from the chemist's stores. From the earliest periods, salt was used for preserving the bodies of animals; and even the corpses of men, were placed in salt or brine when removed to any distance for funeral rites. Pharnaces, the unnatural son of Mithri- dates, King of Pontus, not only joined the Konians against his father, but, after procur- ing his death, sent the body packed in salt to Pompey at Rome. In the fifth century, the monks were accustomed to preserve the heads of martyrs in salt ; and animals for zoological collections were successfully kept in brine for a long period. Of course, butterflies and birds would lose the beauty of their down and feathers in brine : they would recover their proper looks after being wet. Soda and muriatic acid are both extracted from this useful mineral. Salt thrown into 26 SALT AND SALTS. the oven where common pottery is baked produces a glaze upon it. It improves the whiteness and clearness of glass, gives hard- ness to soap, and is used both in melting metals and dyeing calicoes and stuffs. It quenches flame, and is therefore useful to stop a chimney on fire; while wood thoroughly steeped in salt water is very slow to burn. Nor is this all. Salt-water baths are often recommended to strengthen weak limbs ; for salt purifies the skin, and, by producing a gentle irritation, increases its healthy action. Some of the salt may also penetrate the pores, so as to mix with the blood and supply any deficiency there. The young people looked so surprised at this statement that Mr. Goodman explained that salt should be in the blood of most healthy animals, mankind included. Dr. Livingstone perceived the salt taste .even of fresh animal food, after he had long been de- prived of it ; and the absence of salt, which it was sometimes difficult to procure in the in- terior of Africa, created an intense longing for meat or milk, the salt in either of which seemed to supply the want in a great measure. Most people can remember noticing a very BORAX. 27 salt taste when the mouth bleeds at all copi- ously, and are surprised when the doctor says that it is all right. Salt, though rather painful when applied to a wound, does not really do mischief, but fre- quently promotes its healthy healing. The writers of the New Testament often use salt as an emblem of wisdom: "Let your speech be always with grace, seasoned with salt;" and of purification, " Ye are the salt of the earth," while consistently spreading a useful influence; "but if the salt have lost its sa- vour," if professed Christians yield to the cor- ruptions of the world, they lead others astray, and thus diffuse evil instead of good; and our Lord adds the fearful doom, " it is thence- forth good for nothing but to be cast out." Many other substances are called salts, such as alum, borax, soda, nitre and saltpetre, which, however, are seldom found in a native pure state, but are obtained from various clays and earths in which they largely mingle. Borax is found in the East and in South America, and is much used as a flux for melt- ing and purifying various substances, and in soldering metals. Saltpetre is obtained from 28 SALT AND SALTS. Bengal, and is used in making gunpowder, signal-lights, dyeing, purifying metals and curing meat. Nitric and sulphuric acids are both procured from it, which, together with nitre itself, are largely used in medicine, though they are both poisonous, and, applied outwardly, rapidly corrode and consume the flesh. Chloride of lime is a salt of rather recent discovery, and, in solution, is particularly valuable for its disinfecting properties, ren- dering a foul atmosphere speedily pure. Hence it is much used in hospitals, and in cleansing drains and places which generate unwhole- some and disagreeable effluvia. It was dis- covered by Sir Humphry Davy during his researches upon gases. Chlorite, the mineral from which the salt is extracted, is composed of multitudes of little shining spangles which fall to powder under the pressure of the fingers. It is of a greenish colour, and occurs in Ger- many, Switzerland, Sweden, Norway and Java, mingled with other substances, such as clay-slate and sulphates of iron and arsenic. Chloride of lime is much used as a bleaching- powder. The paper-makers boil their rags in CHLORIDE. 29 it to render them perfectly colourless : " there- fore/' said Mr. Goodman, "your pretty new print dress was spoiled by some being spilled on it, as well as the damask curtains." He further remarked that all through the works of God in nature "one thing seems set over another :" there are antidotes to poisons, correctives of disagreeables, and promoters of all that is pure and pleasant, reminding us of the power of God's grace to change the vilest hearts and the most unholy tempers by the purifying influences of the Holy Spirit, as the Apostle Paul teaches us in his Epistle to the Corinthians. After describing some of the worst of sinners, he exclaims, " Such were some of you; but ye are washed, but ye are sanctified, but ye are justified, in the name of the Lord Jesus, and by the Spirit of our God/' 1 Cor. vi. 11. The young people seemed so much interested in these observations upon salt, that Mr. Goodman determined, while sharing in their occupations, to avail himself of any circum- stance which would introduce the study of kindred topics, knowing that formal lectures at set times are often forgotten, while the 3* 30 SALT AND SALTS. mind eagerly seizes and easily retains inform- ation upon the materials which employ the labour of the hands. His own mental stores and still lively taste rendered him a fountain of wisdom, which could be readily drawn upon at pleasure. TINKERING. 31 CHAPTER II. METALS. EDWARD considered himself "fond of ex- perimental philosophy." Alice used to laugh at him for possessing what she called "a genius for tinkering ;" and now and then she laughed with good reason, for, in his great zeal for experiments, he did not always prove himself a prudent philosopher. He had visited some metal- works; and, interested with the various processes he had witnessed of casting, welding and hammering, he be- thought himself of some lead he possessed, and fancied he could cast it into shape and im- press upon it sundry devices, which would look much prettier than a plain mass of dull metal. To work he went, and was busily occupied all one holiday morning, moulding, casting and stamping to his heart's content. But, alas ! when he came to exhibit the result of 32 METALS. his skill, his father looked grave, for the young metallurgist had used a silver half- dollar and some foreign silver coins for his dies, and they were much injured by the pro- cess. Edward could not tell why the real coins looked black, and asked the reason. " Because/' replied Mr. Goodman, "the sur- faces of your silver coins have amalgamated, that is, united with the lead. You should not venture on such an experiment as this with- out knowing a little about the chemistry of such combinations. That black tint is actually the lead, which has mixed with the silver and alloyed all the surface. No common rubbing with plate-powder or leather will restore them. You cannot get rid of the lead till you grind down to a new surface, and the coins will then have lost some of their silver and be so much less valuable. Lead and silver are almost always found together in mines; and it is always a troublesome business to separate them." "Well," sighed Edward, "I must keep my half-dollar, then, as a monument of my foolish ignorance." "If you preserve it as a reminder to con- sider before you act, it will purchase you COMPOUND METALS. 33 many a half-dollar's worth of wisdom, both in intellectual pursuits and moral actions : so you need not sigh too heavily over the loss of your money." " But, father, will you tell me a little about metals ? I never thought of silver and lead mixing together, as I found this morning they will do." " You forget, then, the preparation of the metallic compounds you saw at Chicopee, when they were mixing bell-metal, queen's metal, pewter, pinchbeck, brass and bronze?" Alice and the rest of the family here joined them, and, as they had watched Edward's ex- periments, they were curious to know the reason of the failure he lamented ; and their father led them to the grotto, that he might be able to illustrate his remarks on metals by reference to the numerous ores they had there interspersed about the walls. Mr. Goodman, looking more particularly at Edward, remarked that all METALS cannot be mixed together ; but new compounds of metal are frequently invented, consisting sometimes of two only, and sometimes of several, in various proportions, according to the quality desired. Thus, copper and tin form not only c 34 METALS. bronze, but bell-metal ; tin and lead make pew- ter ; and small quantities of bismuth, zinc ; or other metals added to these will produce con- siderable change either in appearance or quality. Fusibility, or the capacity to melt, is a very important and* useful quality common to all metals in different degrees, as well as malle- ability and ductility, or their capacity for being beaten or drawn out, rolled into plates, bars and wire. All metals, too, have some degree of shining hue, termed the metallic lustre. They are not generally transparent, though, as leaf gold when held up to the sun transmits a green light through it, and silver a white light, it is probable that other metals might, if equally thin, also be thus partially transparent ; but few of the other metals will bear being so much beaten out. No metals have ever yet been decomposed, or divided into simpler substances, but are already what chemists call elements in their simplest state. There are several theories of their formation, each of which presents part of the truth. One theory supposes that metals have been deposited from above, by earthy or metallic salts held in solution by water, just as the mineral waters of the present day ORIGIN OF METALS. 35 contain iron, copper, lead, &c. This is un- doubtedly true of many mineral veins, as may be shown by their being composed of regu- larly-deposited linings of ore and spar on their walls. Other persons have fancied that the metals were the result of sublimed vapours or exhalations, as the mercury seems to be in the mines of Austria ; and some again prefer to consider spars and metallic ores as injected, while melted by heat, into these veins. Elec- tricity or magnetism seems to have contri- buted to the formation of metals, either the general magnetism and electricity of the earth, or local currents of such forces, pro- duced by surrounding influences. All metals crystallize into definite forms, and some into more than one form. This question, as to how the metallic ores were formed, or, more properly, how they were de- posited, is one which naturally rises in every thinking mind, and is frequently asked by those who examine collections of ores; for metals are scarcely ever found in a native or pure state, but are mixed with a great va- riety of mineral substances. Inquiring minds are trying to ascertain the cause of the metal- lic deposits, and the mode of their accumula- 36 METALS. tion ; but, though many interesting and inge- nious theories have been devised and many curious facts discovered in the course of in- quiry, no entirely satisfactory answer has yet been found. It is most probable that the metals were made with all the other chemical elements of matter when the world was cre- ated; for tin, iron, copper, chrome, cobalt, manganese, titanium, arsenic and one or two other metals have been detected in the oldest rock formations with which we are ac- quainted. Yet there are many metallic veins or streams of ore, which have evidently been deposited during convulsions of nature of a much more recent date than the geological age of the rocks in which they are found. Such are the copper veins of Lake Superior, and the tin and copper veins of Cornwall. They vary greatly in width, the Cornish veins from one inch to thirty feet. In other countries much wider veins occur ; but even the narrow veins are often rich enough to be quite worth working, especially as they are so very deep that they have never yet been fathomed, or exhausted of their contents, even three thou- sand feet below the surface. The lately-dis- covered Washoe silver vein, on the west coast METALS OF SCRIPTURE. 37 of North America, worth from three thousand dollars to nine thousand dollars a ton, is only eight inches wide. The great iron-ore bed of Marquette, in Michig'an, is one thousand feet wide. In following the course of veins, they are generally observed to slant downwards from the commencement. Sometimes they widen as they are explored, and a large deposit is reached, whence several veins seem to have started. Other veins become narrower, descending, and stop altogether; or spar, or some other mate- rial, is substituted for the metallic deposit. In the earliest records of man, frequent mention has been made of metals. Even in the description of the garden of Eden, gold good gold is particularized ; while Job says, " Surely there is a vein for silver, and a place for gold in the earth. Iron and brass are dug out of stones," (Job xxviii. 1,) suggesting the idea that mining-operations were known from the first. Indeed, Tubal-cain, the instructor of workers in brass and iron, lived before the flood. Gen. iv. 22. These metallic veins are generally enclosed between hard, dark-coloured crusts, which miners term the walls of the vein. There is mostly, too, a small vein of a whitish clayey 4 38 METALS. substance running down one or other of the walls. Besides this, most metallic veins con- tain a good deal of spar and quartz, either loose or crystallized against the sides. Occa- sionally large empty spaces occur, lined with beautiful crystals. Experience, of course, in some degree enables miners to learn from appearances whether the veins are likely to continue to bear metal or not ; but these ap- pearances are often so fallacious that mining is at all times an uncertain experiment. It is also hazardous and costly, from the great depth under ground at which the work must often be carried on. In Cornwall, copper and tin are seldom found nearer to the surface than eighty feet. If tin is discovered then, perhaps, in descending eighty or one hundred feet lower, copper alone exhibits itself; but tin is sel- dom found below copper. In Tennessee, the black copper-ore is at the base of the hills, and under it the veins are a poorer mixture of sulphur, copper and iron. Another diffi- culty arises from a second system of veins of a totally different metal often crossing the first and altering the direction of the east and west veins, " heaving them out of their course/' CHANGE OF VEINS. 39 as the miners say, sometimes one hundred or even five hundred feet north or south of their true place ; so that they can be found again only after long, laborious and expensive search : in one case forty years have been thus occu- pied. In many districts these heaving s happen several times to the same veins, to the exceed- ing perplexity of the workmen, especially when numerous veins thus cross each other. At the point of crossing there is generally a considerable change of composition in the contents of veins, so as to excite some expecta- SECTION OF TIN-CROFT MINE. tion of a crossing vein. Indeed, the same mine- ral vein varies so much in passing through different sorts of strata, or layers of rock, that the miner looks for a change of metal with every marked change of ground or " country." 40 METALS. In Cornwall, the copper-ore of a vein passing through clay slate becomes richer on entering granite, or, what is more remarkable, produces copper-ore differently mineralized. In the Lake-Superior region, the veins which all cross the rocks nearly at right angles show an abundance of copper only while they are passing through sandstone, but become bar- ren when they enter the trap. All metals are not found in these curious veins ; for some are in large horizontal layers or beds ; but these are generally the ores of iron, lead, zinc and manganese combined with other sub- stances. Some few metals are found in the sources or beds of old rivers : gold especially is thus discovered. Metals do not often show themselves on the surface of the ground, though occasionally the earth is sufficiently stained or coloured with the rust produced by the damp of the atmosphere to suggest that iron or copper may lie beneath. The show which iron makes for itself and its allied metals is called its " gossan." The beds of metal worked as mines are generally rather low ; but all the best known silver-mines are situated in high table-land, which would not be inhabited but for the GOLD AND SILVER. 41 mineral treasures to be obtained. Thus, at Pasco, in Peru, there are silver-mines with some thousand mouths opening into the very houses of the owners. A complete network of silver veins appears to spread there beneath the surface of the earth, one of which is nine thousand six hundred feet long and four hun- dred and twelve feet broad. Gold is frequently found near the surface of the ground. The Gold Coast of Africa is so named from its abundance in the sands. The gold-fields of Peru, California and Australia occasionally yield large nuggets, or lumps, of the precious metal, weighing several ounces and even many pounds ; but they are remarkable and rare. Gold occurs in every quarter of the globe, and nearly in every country, though not always so plenteously as to be worth the expense of dig- ging for it. "What! Is there gold in Vermont and Massachusetts ?" exclaimed Edward and Alice both together, in amazement. " Yes ; and in Virginia and North and South Carolina and Georgia also," said Mr. Good- man. The United States Government has an assay-office in North Carolina for the native gold. The Dahlonega and other mines there 42 METALS. are very rich, and the new hydraulic process of washing out the gold and gravel by tearing the hills to pieces with tremendous jets of water brought in canals and pipes for many miles, which has revolutionized gold-mining in California, is 'now being introduced into the Carolina gold-fields with great profit. Almost every river which flows into the Atlantic brings down small quantities of gold. But the Ptocky Mountains seem to be the home of gold, from which, in the future, the world is to be supplied. It is a proof of God's superin- tending care that the most useful metals gold, silver, iron and copper are freely distributed all over the world, and generally in situations that can be got at without much difficulty: hence, throughout history they are continually named as substances of common use. Lead and tin are abundant in certain localities, where they were discovered in very early times and imported to other countries. Both were known to the ancient Egyptians. The Cornish tin-mines, in all probability, supplied the luxurious city of Tyre, (Ezek. xxvii. 12 ;) but the tin found among the six varieties of metal in the spoils of the Midianites by Moses may have come from the East Indies. (Num. NUMBER OF METALS. 43 xxxi. 22.) The lead-mines of Derbyshire (England) were worked long before the Eoman invasion ; but lead was used as a writing ma- terial in the time of Job, (xix. 24,) and its great weight was remarked by Moses, when he sang at the Exodus, " They sank as lead in the mighty waters." Exod. xv. 10. Quicksilver or mercury, antimony, zinc and platinum, are seldom found in their metallic state, but are extracted from their ores by various laborious processes ; while the metals forming the bases of several metalloids alu- minum, silicum, sodium, &c. are never pro- cured except by artificial means, and then some of these are so quickly changed by the influence of the atmosphere that they are only slowly coming into use in the arts, and chiefly in the form of alloys. You are familiar with gold and silver money, silver spoons, copper tea-kettles and coal-scuttles, steel pens, tin saucepans and dish-covers ; but perhaps you have ' not thought of many other metals and their uses. There are at present known about fifty-one distinct metals, which cannot be decomposed. Some of these have been only discovered so lately that we may suppose other unknown 44 METALS. ones still to exist; and they are separated from their ores in so many different ways that I cannot describe all very particularly. Native gold is procured by simply washing and picking out the glittering particles from the earth or sand amidst which it lies, or the quartz rock in which it lies is picked and blasted, broken up and crushed with hammers and wheels, and mixed with mercury in pans* full of water. The water flows off and leaves the amalgam of mercury and gold. After- wards the mercury is driven off in vapour by heat, and the gold remains pure behind, only containing here and there small, sharp and exceedingly hard crystals of osmium, iridium and rhodium, which are picked out at the mint and sold to make the diamond points for gold pens. The amalgamation of silver with mercury in South America is effected by the trampling of horses, but the quicksilver soon destroys their hoofs, and in a very few years they are unfitted for work. Gold and silver are too soft for use as money without an alloy of cop- per ; they are not only used for money and for ornament, but, as ordinary acids do not injure them, they are employed for spoons, QUICKSILVER. 45 ladles and other domestic articles. Silver, especially, is common for such purposes, and it was thought that aluminum, or clay metal, which is as white as silver but only half as heavy, would be used for the same purposes; but it rusts too easily, and is Very hard to work, so that it is only used as an alloy. Gold and silver make beautiful colours also, and are therefore used in colouring glass and china- ware. Silver combined with nitric acid produces the caustic of the surgeon ; while the addition of sap green, or Indian ink, forms marking- ink : when alcohol is added, fulminating pow- der is the result, an exceedingly dangerous compound, which explodes with a very little heat or friction. This powder is used in making lucifer matches, percussion-caps, Con- greve rockets, and such things. A little silver is occasionally found in quick- silver-mines, but mercury seldom lies in silver- mines. It occurs mostly in chalk or clay rocks, sometimes in pure globules, but more commonly as an ore with sulphur, called cin- nabar, from which it is driven off as a vapour by heat. It derives its name of "quick" or living silver from its usual fluid state, the 46 METALS. movable globules continually eluding the touch, as if it were alive. It is usually carried either in iron or glass jars, leather bags, or bamboo canes. Pliny mentions that the Greeks ob- tained cinnabar from Almaden, in Spain, 700 B.C., and that the same mines in his own time yielded annually seven hundred thousand pounds. Quicksilver is still derived from them, and their present annual product is nearly three millions of pounds : so that during the last three thousand years they must have yielded an immense quantity. There are some quicksilver-mines also in Peru and in China. Mercury was discovered at Idria, in Austria, about 1497, in rather a singular manner, which shows the importance of noticing facts occurring in daily life, and thinking over any unusual circumstance. The district at that time abounded in wood, and was chiefly inhabited by coopers. One even- ing a cooper placed a new tub under a drop- ping spring, to try if it would hold water, and the next morning he found it so heavy that he could scarcely move it. At first his super- stition led him to think it was bewitched ; but, perceiving a shining substance at the bottom, he collected and carried it to the town, where QUICKSILVER. 47 it was soon ascertained to be valuable mercury. His profits from the sale of his treasure re- sulted in a successful search further for the metal. Quicksilver-mines are unhealthy for the work-people, not only from their heated atmo- sphere, but from the danger of imbibing the poisonous mercury itself into the system through any little scratch, or with food. The Austrian mines are used as a place of punish- ment for state criminals. In 1810, some ships were bringing home a cargo of mercury from Cadiz, when some of the bags burst and the contents were spilled. All the copper articles on board speedily became amalgamated: rats, mice, cockroaches, a canary-bird, fowls, dogs, cats, sheep and goats were destroyed, and the whole of the crew were seriously ill : indeed, two of them died. Quicksilver is a difficult metal to use in the arts on this account, and, even with great care, our mirror-makers are liable to a disease called " the shaking palsy." It loosens the teeth, causes the hair to fall off, and produces great pain and softness in the bones, which is greatly aggravated by damp weather. As calomel, it is used in medicine, but great cau- 48 METALS. tion and medical advice are requisite in taking it. The brilliant red paint called vermilion as produced from mercury. Corrosive sub- limate is another exceedingly dangerous pre- paration from it, used for preventing dry-rot in timber and mildew in sail-cloth. Mercury is never seen in a solid state, ex- cept when frozen solid in the coldest arctic regions, when, of course, the philosophical instruments depending upon it are rendered useless. In these regions, the philosophers themselves have, for curiosity sake, shot bul- lets of quicksilver from their muskets. "They told me," said Edward, "when I was travelling last summer up the Lehigh Kiver, in Pennsylvania, that they made iron out of stone. What does that mean ?" Mr. Goodman then described the iron-manu- facture, and began by saying that iron is never found in a pure state, like gold or copper, but only as ore, of which there are six princi- pal useful varieties, wanting a great deal of preparation before you could make out of them a spade or a needle. The ore, or iron-stone, as it is called, is first roasted, to drive off the water, sulphur and arsenic with which it is often combined ; then smelted in a high stack- AN IRON-FURNACE. 49 furnace with coal or charcoal, when the melted iron runs out from the bottom into moulds of sand or clay, where it is allowed to cool. The rough bars of cast iron are called "pigs," because they lie side by side along the casting- floor in the sand, all attached at one end to the great stream of metal down the centre, called the sow, which is broken up and smelted over again, while the pigs are heated and ham- mered into blooms or balls of wrought iron and then rolled into bars and sheets for use. Some of the pig-metal is re-melted and run into moulds of various shapes, to make cast- ings of all kinds, pots and skillets, railings, columns -for buildings, the bed-plates of en- gines, cannon and cannon-balls, car-wheels, and a thousand other things, both great and small. An iron-furnace is a grand object. The largest sort are sixty feet in height, built up of solid masonry, like a square tower, with sloping sides, in every one of which is a great archway, and under each are pipes through which hot air is blown through holes into the raging fire within. Sometimes a single fur- nace-stack will have twelve of these nozzles blowing air into it at once. The nozzles, or D 5 50 METALS. " tuyeres/' as they are called, are surrounded by cool running water, to keep them from melting. The air is heated in furnaces at the top of the stack, and driven forward by power- ful steam-engines and great air-pumps of cast iron. The coal, ore and limestone are car- ried over high bridges from the hill-side to the furnace-stack top, to be thrown in at the "tunnel-head" or mouth of the furnace; or else are hoisted up in movable stages by the weight of water ; or else are drawn up on long inclined planes by steam-engines from the banks of the canal or the platform of the rail- road. Sometimes three, four or five of these great furnace-stacks are built close together in a row, and have one great top for all, on which the hot-air ovens stand, and along which the " stock" of ore, &c. is drawn on wheelbarrows. Tall chimneys rise from this high place still higher into the air, and per- petual flames and noxious gases pour from the tunnel-heads. At night the glare of the fires above, and of the molten metal below, the laborious sighing of the blast-pipes, the clank- ing of the hoisting-apparatus, and the rolling of the trains of cars bringing ore or carrying off the metal, make a scene which when once COMBINED ORES. 51 seen can never be forgotten, and is perhaps the best symbol of the energy and productive- ness, the skill and the power, of the Christian civilization of the present day. The ores used by furnace-men are very dif- ferent, and are always mixed together, so that their hurtful qualities may neutralize each other and their admirable qualities may be combined in the cast iron which is made from them. Thus, for instance, on the Lehigh River, the heavy black magnetic and zincy ores of the New Jersey veins are mixed with the light, porous brown hematite or "limonite" ores dug from the pits around Allentown. On the Schuylkill and Susquehanna, this brown hematite ore is mixed with the gray magnetic coppery ore of the Cornwall mine near Lebanon. On the North Branch of the Susquehanna, both these varieties are mixed with the blood-red " fossil ore" of the Mon- tour's Ridge, at Danville and Bloomsburg. At the head-waters of the Juniata, this fossil ore, again, is mixed not only with the pipe ore of the interior limestone valleys, but also with the carbonate ores or clay iron-stone of the coal-measures. At Pittsburg, and in Northern Ohio, these carbonate ores are mixed with the 52 METALS. magnetic ore which comes in lake boats from Lake Superior and in steamboats from Mis- souri; and both these varieties are mixed, again, with " black band" ore ; and soft out- crop brown hematite ore, found also in the coal-measures. Finally, the mixture is carried still further at some furnaces which stand in the neighbourhood of rolling mills, by adding what is called rolling-mill cinder, which con- tains a large percentage of iron. Cast iron was unknown, but casting -in brass was common, in the days of Solomon, when vessels for the temple were "cast in the clay ground between Succoth and Zarthan," (1 Kings vii. 46,) and no doubt suggested the preacher's simile, "If thine enemy hunger, feed him ; if he thirst, give him drink ; for in so doiDg thou shalt heap coals of fire upon his head" (Prov. xxv. 22,) or melt him with thy kindness, repeated also by the Apostle Paul. (Eom. xii. 20.) Perhaps Solomon used to watch the workmen smelting, and then God put the thought into his mind. Iron is refined by being strongly blown into while in a melted state. This is called the Kelly process, and is in use in the Western States. When re-melted and blown into, IRON. 53 according to Bessemer's process, it becomes excessively hot, and loses all its impurities, but is not so useful as when it has a small percentage of foreign matter left in it, which seems to give it fibre and strength. Small quantities of other metals, such as tungsten, are found to be beneficial also to its strength ; but a small quantity of sulphur left in iron makes it very brittle when it is hot, so that it cannot be worked by the machinist or black- smith ; and small portions of phosphorus or silicon make it very brittle when it is cold. A small quantity of carbon or pure coal is mixed with iron at a slow heat to make steel, which is much harder than iron. Pure iron, however, can be somewhat hardened by plunging it into cold water. The uses of iron have been thus well described: "It can be cast into moulds of any form, drawn into wire of any desired strength or fineness, extended into plates, or beaten in every direc- tion, and can be sharpened, hardened and softened at pleasure. Iron is equally ser- viceable to the arts, sciences, agriculture and war; furnishes the sword, the plough- share and prun ing-hook, the needle and graver, the spring of a watch or a carriage, 5* 54 METALS. chisels, chains, anchors, compasses, cannons and pens. It is a medicine of much virtue, the only metal friendly to the human frame." Indeed, I do not know what we should do without iron, it seems a metal of such every-day importance. Steam-engines, bridges, ships, houses and churches are now made of iron, as well as innumerable articles of domestic use. Swedish iron is generally esteemed the best. It is a singular circumstance that the only pure native iron which we are sure has ever been found has come from the sky, in the form of meteorolites, or stones which were wandering in space until they met the earth upon its way. Some of this iron has a mix- ture of nickel with it, and w*hen polished shows a fine grain and shining hue nearly resembling steel, with curious markings called the Widmanstatian figures. The Esquimaux use this meteoric iron for their spears, and, indeed, possess no other metal. How this iron could drop from the skies has never yet been explained, and various theories are proposed, some supposing it to be ejected from volcanoes, others from distant planets, while some imagine it may be produced by THE LOADSTONE. 55 some process in the atmosphere. Professor Shephard, at Amherst, in Massachusetts, has the largest collection of these meteorites ever made. Plumbago has been considered a carburet of iron ; but repeated analyses have proved that it contains so small a proportion of the metal that it must be looked upon as a sort of anthracite coal with iron occasionally pre- sent. It has never yet been either dissolved by acid or melted by heat, and therefore has not the true characteristics of a metal. Loadstone, or magnetic iron ore, is a va- riety found in Norway, Cornwall and Scot- land, China, Bengal, Arabia, Asia Minor and the United States, especially at Lake Supe- rior, in Missouri, Northern New York, in the Highlands of the Hudson and New Jersey, and along the Blue Bidge of Virginia and the Carolinas. It is the richest and most valuable of all the ores of iron. It was known to the ancients, who ascribed medicinal vir- tues to it, using it for the cure of burns and weak eyes. The Chinese seem to have disco- vered its polarity and turned it to use as a com- pass long before the Europeans, and by them it was termed "the sailing stone." The ancient 56 METALS. Greeks called it the " Herculean stone, because it commands iron, which subdues every thing else." The loadstone not only attracts pure iron itself, but communicates its magnetic power to pure iron and steel when rubbed upon it : hence the magnetic needles used in the mariner's compass. Arctic explorers have observed that the needle dips its north end more and more towards the earth as it is carried into higher and higher latitudes, until at last, at a cer- tain point called the North Magnetic Pole, it stands vertical, and beyond that it points towards the south. The attraction of the surveyor's compass-needle for the masses of iron which are in the earth, renders it almost useless in surveying certain portions of the earth's surface, especially in primary re- gions. It is used, however, for discovering the existence and locality of veins of iron-ore. The loadstone enables those who understand its use to astonish the ignorant by many amusing feats, which used to pass for magical wonders, such as " the enchanted swan, the mysterious watch," &c., by which a waxen bird appears to obey its master, or a watch to stop or go on at the command of its owner. COPPER. 57 Among your toys you used to have some fishes that would have come to a magnetic hook. Copper is generally found in brilliant ores, some of which are called Peacock copper. Copper pyrites look so glittering and attract- ive as to be called " fool's gold/' because it has beguiled the inexperienced into fancy- ing that a mine of that precious metal must exist in its neighbourhood. Copper is almost as useful as iron, not only in furnishing boilers, kettles and wire, but for sheathing the bottoms of ships, to protect them from the action of water and the attacks of sea- worms : it is also used to furnish green and blue colours to the printer. It combines readily with some other metals, with zinc, forming brass and pinchbeck ; with tin, in different proportions, forming bell-metal of varied sound, and also bronze. With tin and silver it makes a speculum metal, ca- pable of receiving the highest polish, and used as mirrors for large telescopes ; and, with tin and nickel, it forms German silver and other compounds of white metal for spoons, forks, teapots and other articles of domestic use. The oxide or rust of copper, 58 METALS. however, is highly poisonous : therefore the old-fashioned custom of boiling a penny with greens, pickles and preserves, is dangerous. A copper-mine was discovered in Wicklow by a stream of blue water flowing from it, of so injurious a quality as to destroy all the fish in the river Arklow; and a work- man having left an iron shovel in this stream for a few days found it encrusted with copper, the copper thus obtained being of a purer quality than that produced by smelting, and the process a much less trou- blesome one. The largest known copper-mines are in Sweden, one of which is twelve hundred feet deep, and its mouth so extensive, from having once or twice fallen in, that the visitor is a full hour reaching the bottom. Fires have broken out in it, and many passages are filled up to prevent their spreading; but the hot and sulphurous vapours are still excessively oppressive. This mine was anciently used as a State prison, in which criminals, slaves and prisoners of war toiled during their miserable lives ; and here, too, Gustavus Vasa, disguised as a peasant, worked for his daily bread during a long concealment, after having been robbed MUNDIC. 59 by his guide ; and it was well, perhaps, that he experienced some of the sufferings of his state prisoners. Much of our copper-ore comes from Chili, in South America, and a good deal from Eastern Tennessee ; but the richest mines in this country are those of Keweenaw Point, on Lake Superior. Two millions of dollars' worth of copper-ore was sent from that region in 1859. The famous malachite is an ore of copper found in the copper-mines of Russia, Norway, Wales, England and the Shetland Isles. Its beautiful colour, and the soft lustre which exhibits all its streaks, render it a pretty material for ornaments. Mundic is another ore of copper, most abundant in Cornwall, where it was long considered of no use except to nourish the copper, a curious miner's notion, which of course had no foundation. You have some cubes of mundic there ; and the grain seems to be different on every side, so that if you were to cut through the cube you would cross the grain on its opposite side. The reason of this has never been explained, but it is one of its peculiarities. " Was my lump of lead just as it came out 60 METALS. of the mine, father?" asked Edward, looking ruefully at his workmanship. " No," said Mr. Goodman ; for lead also is almost always found as an ore, commonly mixed with sulphur; but there are fourteen or fifteen varieties occurring commonly in limestone. The most common and productive is galena, or sulphuret of lead. The carbon- ate of lead, a heavy white clay, is also greatly valued as an ore, and usually accompanies the sulphuret. The ores of zinc are almost always found in company with these ores of lead, especially in the limestone fissures of Wisconsin, Iowa and Missouri. The ore is roasted and smelted in small open furnaces. Small cubes of pure lead are occasionally seen among crystals of lime in the Derbyshire mines. It is a soft metal, and easily spread into sheets for roofing, flooring, or for cis- terns. River and spring water may be stored in these safely; but pure distilled water soon corrodes the lead, and dissolves sufficiently to render the water unwholesome. Bullets and shot are made of lead, but it is mixed with arsenic to make it hard enough. Joined with tin, it forms pewter and solder- ing metal. With antimony and. tin, it makes LEAD PIPE. 61 type and stereotype metal. Litharge, red lead, white lead and sugar of lead are all oxides, or rusts, of lead, employed as paints, or for making coloured glass, or for glazing pot- tery and enamelled vases. Lead pipe is now made by passing half-melted lead through a hole in the bottom of a reservoir, in which is a plug of iron of the size of the pipe-bore. The pipe as it forms is wound upon an im- mense drum, and afterwards cut into required lengths. It is a pretty experiment to hang a small lump of zinc in a bottle, and then dissolve sugar of lead in water for making zinc trees. Little branches speedily show themselves all over the lump of zinc hung in the solution. Lecturers on chemistry often make this experi- ment, to prove the chemical affinity the zinc has for the lead ; for those little branches are really the lead attracted from the water by the zinc, and thus deposited, perhaps in some degree explaining how metals are accumulated in veins in company. Interesting changes are remarked upon coins that have been long buried in the earth, and in the metal utensils discovered in Assyria. There are no true mines of zinc, but it is 6 62 METALS. found in two ores, calamine and zinc-blende, in England, Germany, China and the United States. It requires all the processes of roast- ing, washing and smelting, and then rises as vapour to the top of large furnaces like glass- houses, and is conducted by tubes passing through water in small globules, which are afterwards melted together and cast into ingots for sale. It is, as you may suppose, a light metal, but, notwithstanding all this preparation, it is comparatively cheap, so as to permit its use for chimney-pots, water-spouts, roofing and flooring.' It is quickly affected by acids, and is, therefore, not suited for use in the kitchen or dairy. Zinc plates are used for the transfer of printing, under the name of zincography. Joined with copper, zinc forms brass, as I mentioned before ; and when plunged into sulphuric acid it is the powerful generator of electricity in the Voltaic pile battery. Zinc forms the other ingredient of the celebrated Franklinite iron-ore of New Jersey, and, by clogging the furnace-stacks and the burden of ore and coal, has proved a formidable obstacle to the use of that valuable ore in the iron-manufacture. And yet a small TIN. 63 mixture of zinc in iron adds greatly to the toughness and strength of the latter. Tin was one of the metals known to the ancients. You have some pretty specimens of tin-ore here, and minute grains of it. are found in granite. It is mentioned by Moses (Num. xxxi. 22) among the six metals found in the spoils of the Midianites, which were to be purified from heathen idolatry by fire. 'As these Midianites were " merchantmen" trading with "pieces of silver" in Joseph's time, they doubtless traded also with " the strong city of Tyre" (Josh. xix. 28) of that period ; and it is known that British tin was brought to Phoenicia, of which Tyre was one of the principal cities, in very early times. ' Tin is by no means universally diffused, and in fact is a very rare metal. A small vein of it was discovered in the White Moun- tains of New Hampshire ; but it has never been wrought. A valuable vein of tin-ore is reported as lately discovered on the western borders of Utah. There is a little tin-ore in Chili, Mexico and the East Indies, but it is abundant in Cornwall and Devonshire, Eng- land, in two sorts of ore only, though occa- sionally it appears quite pure in small crys- 64 METALS. tals. Indeed, block- tin is a collection of minute crystals intercepting one another in every possible direction, so as to leave tiny spaces between. Hence it is a light metal, and produces a peculiar crackling noise in bending, which the French call "le cri de l'etain," or " the cry of tin." Attention to the shape and direction of the crystals greatly assists the polishing of metals. Tin is broken into small pieces and melted over and over again, till it looks as bright as silver, and is then cooled, and ladled gradually into moulds, because, if quickly poured into them while hot, the tin becomes brittle. It is too soft and too valuable to be used alone, but is con- stantly employed for lining and coating iron utensils. It will bear beating into leaves only the thousandth part of an inch thick, and therefore, as tin-foil or tin-leaf, is much used for the lining of tea-caddies and the packing of articles that must be kept dry. Mixed with lead, tin forms pewter. It is also used with mercury for silvering the back of mirrors and looking-glasses, and, when dis- solved in muriatic acid, it furnishes colours for dyers and calico-printers. Edward now showed his father a piece of PLATINA. 65 ore labelled "needles of antimony," and asked if that were the same mineral used for anti- monial wine. Mr. Goodman told him that oxide of antimony was used for that purpose. The metal itself is found nearly pure in veins amidst the mountains of Dauphins' and Sweden, as well as the Hartz Mountains. It is, as may be seen from that specimen, ex- tremely brittle and easily corroded. It is very useful in the arts for the white metal often used instead of silver for music-plates. Its sulphuret forms the black powder with which the ladies of ancient times used to stain their eyebrows and eyelids. Oxide of anti- mony gives colour to the artificial imitations of beryls, topazes and yellow diamonds. .Anti- mony and bismuth usually go together, but their power of conducting heat is so different that when two pieces are soldered together and a stream of galvanism is sent through them in one direction, a drop of water laid in the crease between them will boil ; but when the current is reversed the drop of water will freeze. Platina must be added to this list of metals. The term is a diminutive of "plata," the Spanish for silver. It is so scarce as to be E 6* 66 METALS. almost as costly as gold, and is really nearly as valuable, as it is heavier and more difficult to melt, yet ntill more ductile and flexible. It is also very malleable, that is, it can, when hot, be easily beaten out and welded to iron and steel. Neither air, water nor any simple acids injure it, though it can be converted into a chloride by nitro-muriatic acid. It is, therefore, exceedingly useful to the chemist for his crucibles, and is sometimes employed for the mirrors of reflecting telescopes. There are no platina-mines. It is generally found combined with palladium, rhodium, titanium, gold, iron and other metals, but in very small, heavy grains, seldom larger than a pea or a nut. The last-named substances are some of the new metals which have been discovered during the past century, but not in sufficient quantities to make them very available for use. Cobalt, manganese, arsenic and nickel are the principal of these ; though manganese was known in Pliny's time, being then deemed an earth. It is much used by potters and glass-makers for colouring, and yields brown to the calico-printer. The ore of manganese, called black wad, is remarkable for its spon- BISMUTH. 67 taneous combustion with oil. It is used also for obtaining chlorine for bleaching-purposes. Cobalt and its oxide, smalt, give a beautiful blue tint to glass, china-ware and paper. Nickel is susceptible of magnetism, and is therefore sometimes used for the mariner's compass. Arsenic is employed for hardening candles, making flint-glass, and dyes of green, red, and yellow, as well as for tinting fireworks. It is much used in medicine, and yet is so deadly a poison that it destroys human and animal life very rapidly. Even its fumes are inju- rious to health. Bismuth is a pretty-looking metal, not very common, and of little use, as it melts even before it is red-hot. This, however, adapts it for a soft, soldering material. Sir Isaac Newton composed a fusible metal con- sisting of eight parts of bismuth, five of tin and three of lead, which, though hard enough to polish when cold, ,would melt so readily in hot fluid that spoons made of it will dis- appear in stirring a cup of tea, to the no small dismay of an ignorant person. These are n'ot all the new metals. The following is a list of the whole; though of many of them little else is known than the 68 METALS. name, suggested by the odour, colour, or some such circumstance; and they are not yet much used either in art or medicine. 1. Gold. 2. Silver. 3. Copper. 4. Iron. 5. Tin. 6. Lead. 7. Mercury, or Quicksilver. 8. Zinc. 9. Antimony, 10. Bismuth. 11. Cobalt. 12. Nickel. 13. Manganese. 14. Arsenic. 15. Platinum. 16. Palladium. 17. Rhodium. 18. Osmium, so called from osme, odour. 19. Iridium, from its iris or rainbow hue. 20. Tungsten. 21. Tellurium, from tellus, 22. Molybdenum, from molybdos, lead. 23. Uranium. 24. Titanium. 25. Columbium. 26. Cerium. 27. Cadmium. 28. Chromium. 29. Vanadium. 30. Zirconium. 31. Sodium. 32. Potassium. 33. Calcium. 34. Silicon. 35. Aluminum. 36. Silenium. 37. Lithium. 38. Barium. 39. Strontium. 40. Magnesium. 41. Yttrium. 42. Glucinum. t 43. Thorinium.* J the earth. The metals bracketed together are never * Some others have been named recently, but have scarcely been sufficiently proved to be classed with the above. ALCHEMY. 69 found separate in nature, and are of little use by themselves; but their oxides form the substances known as earths and alkalies, clay, sand, soda, potash, lime, magnesia, &c. At some other time these may be considered by themselves; but they come in here because they really have " a metallic basis," that is, their simplest and purest form is that of metals. Edward asked his father if he thought it possible to change metals into gold, as the old alchemists fancied. He replied that there is no evidence that it is possible. The history of the few imagined successes is so doubtful, and the circumstances described are so improbable, that we must think the alchemists were deceived, by the weight or colour, as to the value of the compounds they produced. Moreover, as the Scriptures say, '" Thou canst not make one hair white or black," it is not likely that the greater change of lead to gold should be within human power. In reply to this, Mr. Goodman remarked that it is very difficult to form a just opinion of their character or views. It is strange that they could have been willing to lend themselves to 70 METALS. the impostures to which they certainly gave currency. Many of them were men of great learning and of irreproachable character. Roger Bacon (commonly called Friar Bacon, being an English monk of the order of the Francis- cans, born in the year 1214,) exposed the absurdity of magic, necromancy and charms, yet professed his belief in alchemy. Doubtless many persons were deceived and deluded by plausible pretenders, and others were induced to embrace and propagate the belief from sordid and corrupt motives. If they had access to the sacred writings, they certainly did not take heed to them, or they would have learned to distrust the principles of their (so-called) science. They could not fail to notice how the lead, iron and silver, which the alchemists were most anxious to transmute into gold, are continually mentioned as " abiding the fire," as being only " tried/' " purified," by its action, but always retaining their own characteristics. Indeed, these pro- perties rendered metals a frequent type of God's dealings with his servants. " I will refine them as silver is refined, and try them as gold is tried," says God by his prophet Zechariah. (xiii. 9.) "When he hath tried me," says Job, (xxiii. SCRIPTURAL ILLUSTRATIONS. 71 10,) " I shall come forth as gold." " He shall sit as a refiner and purifier of silver," (Mai. iii. 3;) an image which is peculiarly apt, as the silver is perfected only when the refiner can see his own image reflected in it, remind- ing us of the purpose of all affliction to assimi- late our characters to that of the Lord Jesus Christ, the Great Eefiner. (Ezek. xxii. 19, 22.) Then, again, iron and brass denote obstinacy on the part of man. "Thou art obstinate," says Isaiah, (xlyiii. 4,) " thy neck is an iron sinew, and thy brow brass," and needed the threatened punishment, to be broken by a rod of iron. The Apostle Paul stigmatizes pro- fession without practice as being but " as sounding brass." (1 Cor. xiii. 1.) God's ene- mies were said to sink " as lead in the mighty waters," (Exod. xv. 10,) or to be consumed in the fire, "cast away like refuse silver," (Jer. vi. 29, 30,) because the Lord had rejected them. Mr. Goodman concluded his remarks on metals by urging his children to remember these illustrations of sin and of duty, and especially the warning given against covetous- ness; for the Bible says that "he that loveth silver shall not be satisfied with silver." (Ec- 72 METALS. cles. v. 10.) The apostle adds, Your silver and gold, ye rich men, is corrupted ; the rust of them if suffered to lie by useless shall be a witness against you. Ye have heaped up treasure for the last day, (James v. 3,) when an account of your property will be re- quired. Such riches are for the earth only, and must be relinquished at the threshold of eternity. Those only who are rich in faith in our Saviour Jesus Christ will carry their wealth beyond the grave. May you, my children, be well furnished with the only true riches ! SPHENOPHYLLUM TRANSVERSE SECTION OF STIGMARIA FICOTDES ; net. SCHLOTHEIMI ; M. Adolphc Brongniart. nat. size. This specimen shows that the cylinder (a in Lign. 36) is formed of bundles of vascular tissue, disposed in rays. FOSSIL FRUITS, OR SEED- VESSELS; nat. FIG. 2 CARPOLITHES BCCKI.AN- DII. Coralline Oolite, Malt on. 3. TRIOONOCARPITM OLIVER- FORME. Snibstone Col- liery. L1= See page 91. LEPIDOSTROBT, THE FRUIT OF LEPIDOPEN- DRA ; nat. tCoalbrook Dale. Fio. 2. The upper part of a cone, display- ing the imbiicated surface. 3. A young specimen attached to the extremity of a branch. ODD. T>. 72. TREASURES. 73 CHAPTEE III. COAL AND COMBUSTIBLES. As summer advanced, the grotto became a favourite retreat with the whole family. Alice enjoyed counting up the names of the various contributions to its beauty as memorials of friendship, while Edward found in them ample food for his philosophical research, Mr. Goodman being the referee and instructor, whenever he could spare time for the pur- pose. / Among the treasures thus gathered were some remarkable pieces of coal and coke, which Edward had obtained from various colliers ; some sulphurs his father had brought from abroad; bitumen from an Egyptian mummy; and one beautiful specimen of amber, enclosing an insect and part of a de- cayed leaf. The young people were admiring these one morning, when Mr. Goodman joined them, and, 74 COAL AND COMBUSTIBLES. pointing out the coal and bitumen, said that they might both be classed with amber in. some respects. " Indeed, father ?" exclaimed Alice. " They seem very dissimilar. " Mr. Goodman replied that they are all com- bustibles, and have very similar origin; for it is now fully ascertained that they are the remains of ancient vegetation, coal being the moss, ferns and leaves, amber the gum, and bitumen the turpentine, sap and juices of whole forests, which, by the arrangements of God's wisdom, have been buried under ground, where they have gradually been changed into these useful minerals. Asphaltum, petroleum, naphtha, and some other compounds of hydro- gen and carbon may be considered as varieties of coal, though they are not always found together, for coal often occurs without bitumen or amber, but bitumen and amber are never found excepting in the neighbourhood of coal- formations. Amber has been found from time imme- morial on the sea-shore in Prussia, thrown up by the waves ; but there are mines of it near Dantzic about one hundred feet deep, where there is a thick stratum of half-decomposed AMBER. 75 trees, yielding bitumen and amber, which sometimes hangs in stalactites from the branches. When burnt in the open air, it gives out a thick, pungent, fragrant smoke, leaving a light-shining black coke as its re- sidue. When distilled, it yields succinic acid, so called from the Latin name of amber, sue- cinum; and the ash or residue is used for making fine black varnish. Alice said she should never have supposed the pretty transparent amber could make coal, it looked so very different. Mr. Goodman remarked that the difference, after all, was great. It will bear a brilliant polish for beads and boxes. It may be boiled in water without softening or altering its ap- pearance ; but, when melted by heat, it yields oil, which is at first colourless, but, if exposed to light or to much greater heat, it becomes brown, and afterward a thick, black mass, almost like bitumen. It can be dissolved in sulphuric acid and some powerful oils, but, when once melted, cannot be restored to its natural transparency. It is of various colours, but most commonly either white or yellow, and is used very much for oil-varnishes. It was known to the ancient Arabs, Greeks and 76 COAL AND COMBUSTIBLES. Romans ; indeed, the Arabs called it ambra. All these nations used it as a medicine, and the Eomans valued it as a gem, importing it largely for ornamental purposes. It was sup- posed to have magical virtues, and was hung about the necks of children to preserve them from sickness, a superstition which still con- tinues in force in some countries. Thales, of Miletus, who lived six hundred years before Christ, noticed its electric property of attract- ing light bodies, when heated by rubbing; and the prophet Ezekiel, (i. 4; viii. 2,) who lived about the same time, mentions it as a substance familiar to the Jews in Chaldea. Most animals seem fond of amber, and eat it when they find it, without injurious effects. Jet, also, is a sort of coal, but very hard and used for ornament : it is known as pitch- coal, and in Prussia it is called black amber. It takes its name from the river Gaya, in Asia Minor, where it was first noticed; it will bear a brilliant polish, and is cut into rosaries, boxes, brooches, inkstands, &c. The Isles of Skye and Feroe yield it, and large quantities are found in Mexico and other volcanic coun- tries. "What is bitumen, father?" asked Edward. BITUMEN. 77 " Our specimen looks like a lump of very dry old resin." Mr. Goodman, taking up the specimen, re- plied that bitumen is rather the general name for several sorts of mineral oil, pitch, mineral hatchetine, tallow and caoutchouc, which are found in the earth, seeming to have been origin- ally vegetable juices, and are now in various stages of mineralization. The remains of ancient fish in some formations such as the Old Red Sandstone are converted into animal bitumen ; and many rocks which give a fetid odour when broken are supposed to owe this pro- perty to animal bitumen from the decom- position of creatures now no longer existing. Naphtha, petroleum and Barbadoes tar are highly inflammable mineral liquids, found issuing from the earth or dropping from the rocks in some parts of Europe and Asia. Naphtha is often collected into wells, and, when lighted, will burn for a long time. It is frequently used for lamps, and in Italy whole cities are lighted by it. Its odour is strong, but not unpleasant, and its power of dissolving oils and resins renders it very use- ful in the arts, especially in dissolving caout- chouc for water-proof clothing. 7* 78 COAL AND COMBUSTIBLES. Petroleum is found in small quantities in England/ but very abundantly in the East and West Indies. Near the town of Rainan- ghong, in the Birman Empire, there are no less than five hundred and twenty wells into which petroleum flows from adjacent coal- beds. No water ever penetrates into these wells ; but more than four hundred thousand hogsheads of petroleum are annually procured, which is extensively used for lamps, and, when mixed with earth, furnishes an important sup- ply of fuel. With us, in America, it is known as Seneca-oil, from the town of Seneca, in the State of New York, where it was first ob- tained. But it is abundant in many places in the coal-regions, especially around their edges, as on Oil Creek, in Northwestern Pennsylvania. At one time, a large quantity of it took fire on the surface of a small river in Ohio, and for half a mile the stream was one sheet of flame. It ascends with the salt water from the salt-borings, and is not only sold for burning-fluid and machine-oil, but is used for boiling the salt water, making salt, and even for lighting houses and villages with gas. There are so many natural gas-vents in India, Persia, China and various parts of the ASPHALTE. 79 world, some of which have been burning for centuries, that it is astonishing gas was not sooner turned to account in the arts. The salt-works of Thsee Lieon Teing, indeed, were long heated and lighted by these fiery foun- tains, which rose sometimes twenty or thirty feet high. Bamboo pipes carried the gas from the springs wherever needed, tubes of pipe- clay being fixed at the burning points. At these works, a single gas-well heats more than three hundred kettles; and the fire thus kindled is said to be so exceedingly brisk that the cauldrons are useless in a few months. Three columns of flame carry off the super- fluous gas. The village of Fredonia, in the State of New York, is lighted in a similar manner from natural gas. In both these cases the gas is ascertained to ascend from beds of bituminous coal. Asphalte is so similar to petroleum as to be apparently the same thing in a more solid form. It occurs abundantly on the shores of the Dead Sea, which was anciently called Lacus Asphaltites in consequence. It was largely employed by the ancients in building. All writers agree that the bricks in the walls of Babylon were cemented with hot asphalte, 80 COAL AND COMBUSTIBLES. which rendered them very solid. The Egyp- tians used it in embalming the dead. The lump of bitumen you have here was taken from the head of a mummy. Much of the asphalte used in England is furnished by the Pitch Lake of Trinidad, which is three miles in circumference, of un- known thickness, and sometimes hard enough for men and cattle to walk upon it. Melted and mixed with sand, gravel or iron-slag, it forms a cheap and durable pavement; but very hot weather softens it so that it cannot very well be used for streets. There is a sort of black or brown limestone found near Bris- tol, and in Galway and Dalmatia, so full of bitumen that it is soft enough to be cut like soap. In Dalmatia this stone is used for building, and, when the walls are reared, fire is applied to them, and they burn white. Coal-tar is a product of the distillation of gas-coal in the retorts of gas-houses. The re- siduum is coke, which is also produced in stacks and ovens for the purpose of being used in iron-furnaces, because the uncoked fat coal cakes and stops the draught. Coke weighs only one-half as much as the coal out of which it is made. It is a porous, lava-like, MINERAL TALLOW. 81 shining, ringing, brittle substance, somewhat resembling pumice-stone, but making an in- tense heat when burned. Mineral tallow is scarcely soft enough to be made into candles, though it looks white and feels greasy. That and elastic bitumen, or mineral caoutchouc, are both varieties of bitumen, greatly resembling the substances whose names they bear. There is also a ma- terial found in the iron-mines of Merthyr- Tydvil, in South Wales, of a soft, whitish or greenish hue, looking something like sperma- ceti, or bees '-wax, from which oil can be dis- tilled at a low heat, leaving behind a coaly matter. It is wonderful that from so black a substance as cannel-coal and carbonaceous shale there is obtained, by simple distillation, a pure, white brilliant substance called paraf- fine, much used now for candles in the place of spermaceti, especially when hardened with a little arsenic. Mellite, or honey-stone, so named from its colour and consistency, is another mineral, oc- curring at Thuringia, in Saxony, and in Swit- zerland, on bituminous wood and earthy coal, which has so many similar characteristics as to place it among combustible substances. In F 82 COAL AND COMBUSTIBLES. the blue clay of which Highgate Hill, in Eng- land, consists, small lumps of fossil gum copal are often found, and so like the copal gum of American trees now growing that it is called Highgate resin; and there can be no doubt, from its mode of burning, that it is of vege- table origin. Edward here expressed wonder as to what different vegetables would come to, if they were left to themselves. Mr. Goodman answered that the peat moss of Ireland would help to satisfy this curiosity, as it can be found in all stages between its early green growth and the black substance used for fuel. Peat is not known to occur in tropical regions, where vegetation decays too rapidly for its production. Bog-wood carries us another step on towards the coal-measures, its condition is so evidently a medium between vegetable wood and mineral coal. " Uncle Joe, "said Alice, "when he came back from Ireland, brought some bog-wood with him; but it was not hard enough for the wall of our grotto : so Edward put it into the table-drawer with the crumbling things." So saying, she produced two or three varieties. But bog-wood, said her father, exhibits BOG-WOOD. 83 various degrees of hardness as well as of black- ness. Some specimens will bear carving into brooches and boxes, and are as black as coal ; but all have the lightness of wood, and are liable to split in the same manner. It seems to have been produced by the slow burning action of the oxygen of the water in the bog where it is found, a process well known to chemists, and called eremacausis. The Ca- tholic inhabitants of Ireland make fragrant rosaries of bog-wood, and, when they are blessed by the Pope, they are highly prized by their superstitious owners, and are sent to all parts of the world as the most valuable presents. Edward said that it would be interesting to find coal-mines where the coals did not seem yet completely formed. Mr. Goodman said, laughingly, that they could hardly be called coal-mines till their contents were fully formed ; but, in fact, the later coal-formations, called tertiary, exhibited the coal in the state of lignite, which is really a half-way condition between modern wood and the compacted coal of the secondary and primary formations. Moreover, ancient trees are seen in the rocks; and on the west coast 84 COAL AND COMBUSTIBLES. of France, near Morlaix and Quimper, there are whole modern forests now standing under water, so that their condition can be easily examined and any changes watched. In a report* from these districts, dated 1856, on this very subject, the writer, . Monsieur Du- ^rocher, stated that between Redon and Renai, places which can readily be found on the map, a marsh still exists, which is covered with water at high tides, but at low water the peasants procure large quantities of wood from it for their fires. At St. Nazaire, at the mouth of the river Loire, trunks of trees are still visible, in serried ranks; a re- markable fact, for the whole of that coast is now for the most part destitute of trees. M. Durocher considers that they were over- whelmed within a comparatively recent period by the encroachments of the sea. Documents exist proving that the destruction of the forests on the St. Malo coast took place be- tween the eighth and twelfth centuries. That of Dol, near Mount St. Michael, is principally composed of oaks, which have become quite black and extremely hard. The neighbour- * See "Athenaeum," Dec. 27, 1856. FOSSIL TEEES. 85 ing peasants have long used this wood for carving, as it is capable of receiving a very high polish. They call it " coeron," a word derived from the Celtic language. In Den- mark there are deep wells, sunk through suc- cessive layers of rocks and submerged peat- bogs, with overthrown trunks of trees in such a state of preservation that they are quarried out and used for building and burning. What is most remarkable is the fact that each layer or bed of peat contains trunks of trees of a different kind, one having been an oak forest, another a beech, another a pine, and so on. Mr. Lesquereux, who studied all the bogs of Europe, has shown that the American coal-beds were made from such Great Dismal Swamps as now exist along the coasts of Vir- ginia and the Carolinas. And Mr. Lyell and Mr. Dawson have described the ancient forests standing in the rocks of Nova Scotia, with their roots buried in the ancient coal-beds of that country. Similar forests are seen in all the coal-regions of the world. In Parkfield Colliery, near Wolverhampton, there was a fossil forest so thickly studded that seventy-three stumps of trees were counted on a quarter of an acre. Here is a plan of the 86 COAL AND COMBUSTIBLES. Ground-plan of a fossil forest, Parkfield Colliery, near Wolverhampton, showing the position of 73 trees in a quarter of an acre. spot. All the trees have been removed to different geological collections, and may be examined by the curious student of nature. This fossil forest was discovered where the loose rubbish is seen lying in the foreground of the following sketch, which shows what is rarely to be met with now in England; that is, coal and ironstone beds lying so near the surface of the ground as to be excavated in the open light of day, in the same way as a railway-cutting ; for in that country most of the beds lie so deep under ground that wells have to be sunk to reach them, sometimes FOSSIL FOREST. 87 hundreds of yards in depth, at the mouths of which steam-engines, pumps for raising water, fans for blowing down air into the galleries, and machinery for hoisting the baskets or car- loads of coal to the surface, are placed at great expense. Sliding stages are also made to ascend and descend the sides of these well- shafts, on which the miners go up or down with speed and safety, instead of climbing dangerous, long, steep ladders, or being let up and down in baskets at the end of ropes, as in old times. Mining is much safer and cheaper now than it used to be. The lowest bed of coal adjoining the little tram-road in the sketch above is eleven feet thick, and is known as the bottom-coal. Al- though here only about seven or eight yards below the surface, at another part of the col- liery this bed is one hundred and fifty yards deep. Above the coal on the left-hand side, shown by the streaky lines, lies the white clay ironstone, in beds varying from two to six inches in thickness, and at this point eleven or twelve in number. The measures, lying all so regularly on the left-hand side of the sketch, are brought to a sudden termination by the slip or fault shown in the middle, the whole 88 COAL AND COMBUSTIBLES. being thus thrown down twenty or thirty yards. Such an open cut, but on a much grander scale, was one of the first coal-mines opened in America, the Summit Mine, at Mauch Chunk, where various layers of coal lie hori- zontally so close together that the whole makes up a thickness of sixty feet. At first people thought that the whole mountain was a solid mass of coal ; but by-and-by, after they had opened a vast quarry, in steps all round, like an ancient Eoman amphitheatre, they came to the bottom, and then discovered that this group of coal-beds rolls over and down both sides of the mountain. Many hundred thousand tons a year are taken out of these mines, which present a grand appearance. In other parts of the anthracite-coal region the gangways are driven in at the edges of streams, and little railroads branch off into them from the main railroads coming up from the cities. Inside, there are rooms or breasts, rising with the coal from the level gangway to the outcrop at the summits or on the high hill-sides; and the coal, as it is mined, is al- lowed to slide down these breasts or shoots to where the cars stand ready in the gangway to COAL-! EDS. 89 receive it. In other parts of the region the mining is done on the English plan, by deep shafts, or more frequently by slopes at various angles, with great s team-engines at the mouth, letting down cars upon inclined railroads to the gangways at the bottom. The different coal-beds are distinguished from each other by characteristic qualities : one is harder, and another softer ; one is divided into several layers, and another is more solid; one has an abundance of sulphur and iron in it, and another is quite free from these inju- rious substances ; one has a straight fracture, and another yields coal which looks gnarled and curly when broken to pieces ; one will have many leaves and stems of certain kinds of plants, and another will show very few, or leaves and stems of quite another sort. In this way a bed is traced from one mining property to another. The vegetables which are found in ancient coal-beds are of various species, none of which now live upon this planet. Some are like the horse-tail plants of the present day. In the following cut (No. 1) is seen a stem with two sheaths and a bud. 8* 90 COAL AND COMBUSTIBLES. EQUISETUM LTELLH. CALAMITES APPROXIMATUS. Wealden. Ponceford. natural size. ig. 1. A stem, having two sheaths, and a bud at the lowermost joint. 2. Stem, with remains of roots. % not. 3. CALAMITES APPROXIMATUS, showing the curved lower end of the plant.f % not. Others belong to the order of ferns, and are named commonly from the number of the nerves upon their leaves, or the shape of their teeth-like edges. Others are the remains of gigantic trees, with extensive roots stretching out in all direc- tions, covered with rootlets, which fill the " under clay" of every coal-bed. The bark of these tree-stems turned into coal or cast in FIG. 1. PKCOPTERIS MCRRAYANA ; a pinnule with the fructification; mag- nified. Inf. Oolite, Scarborough. 2. PECOPTERIS LONCHITICA. Coal-shale, France. LONCHOPTEKIS MANTELLI. Wealdtn, Tilgate Forest. Fia. 1 and 2. Leaflets magnified, to show the reticulated venation. 3 A fragment of a frond ; nat. Opp. p. 90. SriGMARiA PICOIDES. Carboniferous. Derbyshire. % not. Fio. 1. Portion of a stem, with some of the rootlets (formerly con- sidered as leaves) extending into the surrounding clay. The internal axis is seen at a ; and the corresponding groove on the portion of external surface that remains. 2. An outline of one of the rootlets, with a tubercle to show the mode of its attachment by a ball and socket joint to the root. ERECT STEM OF A SIGILLARTA, WITH ROOTS. Coal Mine, near Liverpool. a. The trunk of the tree, traversing a bed of Coal. It. The roots (Stigmarice) spreading out in the Under-clay. Opp. p. 91. FOSSILS. 91 stone moulds is commonly seen in the rocks which overlie the coal-beds. Sometimes the fruit is found, as if it had been shaken down by the earthquake-con- vulsions which buried up the trees. Among the most common of all the fossils of the coal is a star-shaped flower-like plant, called therefore the aster ophyllites, of which the following is a picture : ASTEROPHYLLITES EQUISETIFORMIS : Coal-shale. (Foss Flor.) 92 COAL AND COMBUSTIBLES. Palm-trees, or something like them, called Zamias and Cycades, with short stems and a plumy head of long and graceful leaves, grew in the ancient days of the secondary coal. FOLIAGE AND UPPER PART OF THE STEM OF CTCAS REVOLUTA. ^ noi. In Kew Conservatory. The fir and pine tribe was also represented, and much of the bituminous character of some coal-beds is thought to be due to the resinous nature of this family of trees. Amber exuded from the bark ; and when the coal is studied with a microscope, small yellow spots are seen scattered through it, which seem to be the amber substance in the solid wood : from this, no doubt, comes the principal part of the gas we get from coal. COAL IN CHINA. 93 It seems generally agreed by the learned that the first mention of coal, as we under- stand that name, occurs about two thousand years ago, in the writings of Theophrastus, a pupil of Aristotle. He devoted the long period of one hundred and six years to scien- tific inquiry, and died lamenting that the shortness of life prevented any great attain- ments. About twenty of his works have been preserved ; and in his book on stones he re- marks, " Those fossil substances called coals, and broken for use, are earthy. They kindle, however, and burn like wood-coal. They are found in Liguria, where there is also amber and ore used by smiths." Liguria was the ancient name for that part of Italy of which Leghorn and Genoa are now the principal towns. Coal seems to have been known to the Chinese before it was known in Europe ; for the earliest traveller to that country whose journal we possess reported that that inge- nious people " burnt a black stone which was as good fuel as wood." Their borings are done with a rope, and their mines are some of them deep. The Bible mentions coals of fire earlier 94 COAL AND COMBUSTIBLES. than Theophrastus ; for they are spoken of by the prophets, and even in the time of Moses ; but at that period the word was used to signify any sort of fuel. The Saxon word col, the German kohl and the Danish kul are all names in those languages for mineral coal t which seems to have been an old British word, now represented in Irish by the word guel, and in the Cornish dialect by kolon to this day. Indeed, some antiquaries zeal- ously contend that a flint axe found stuck in a vein of coal in Monmouthshire proves that the early natives of England were acquainted with this useful substance. But one would think that, if the early Britons had been acquainted with mineral coal, it would have continued in use : therefore, the fact that it has not, must be considered a serious objec- tion to the supposition. Charters still exist, showing that coal was known and used in England during the ninth and tenth centu- ries, although the Newcastle pits were not taken under royal protection till 1239. In 1245, we find a regular system of collieries and coal-vessels arranged for the conveyance of " sea-coal/' as it was long called, because it was taken by sea along the coasts to London COAL IN ENGLAND. 95 and other ports. But at that period it was not plentiful in London; for in 1306 King Edward I. forbade, by proclamation the burning of coal in the city, on account of its sulphurous smoke and smell. As wood became scarce in England from neglect of planting new forests, mineral coal gradually came into use ; yet, as late as 1600, Stowe relates that " the nice dames of London would not come into any house or room where sea- coals were burned, nor willingly eat of the meat that was either sod or roasted with sea- coal fires." It has not been long ago that many of the French had so great a prejudice against the use of coals that landlords ejected tenants for using them, and drawing-rooms were almost emptied of guests when warmed with a coal-fire. In America, where we burn anthracite coal chiefly, all this sounds strange enough; but a visit to Pittsburg, where the bituminous coal is altogether used, will rea- dily explain it. By-and-by coals found their way into the palace of royalty ; and so large a tax was raised from coals imported into London that it aided considerably in the rebuilding St. Paul's Cathedral and the fifty- two parish churches destroyed by the great 96 COAL AND COMBUSTIBLES. fire of 1666. The British coal-trade has now reached thirty millions of tons. Coals with seventy different names are in the English markets, names derived from the localities whence they are procured, as Wallsend, Newcastle, Welsh, &c. ; but many of these are so much alike that the coal-mer- chants themselves find it difficult to state a difference between them. The American market is quite as full of names, such as Diamond, Peach Orchard, Buck Mountain, Lykin's Valley, Lehigh, Cumberland, Broad- top, Alleghany, Westmoreland, Blossburg, &c. &c. Many 01 these are the names of coal- regions or single basins ; and many others are the names of single mines or beds of coal. The geologist recognises only three great kinds, bituminous, semi-bituminous and an- thracite. The English geologist has sub- divided these into fourteen sorts of coal, according as some yield white and others red or black ashes ; some burn quickly, and others slowly; some produce much smoke, and others little ; some cake together as they burn, and others crumble into fine pieces. All have dis- tinct values for these different qualities, accord- ing to the kind of use to be made of them. ANTHEACITE. 97 The principal varieties of bituminous coal are the caking, cubic, splint and cannel coals, all very bituminous, yielding smoke and gas. Anthracite, or " blind coal," is not bitumi- nous, and does not smoke or soil the fingers. It is a natural coke, found in South Wales, in Belgium and in Eastern Pennsylvania so plentifully that whole cities use it and are entirely free from smoke, which is a great advantage ; for in London, Liverpool, Pitts- burg and other cities which use bituminous or smoking coals, the new buildings soon become dark and dingy with soot. The an- thracite coal-beds were originally, however, as bituminous as the rest, and in fact can be traced along so as to be proved to be the very same deposits. How the bitumen or oily and gaseous parts have been separated and driven off, so as to leave hard, crystalline anthracite, it would be hard to tell. The effect has been produced in Wales by the intrusion of trap dikes or ancient lava currents ; but nothing of that kind is visible in the anthracite regions of America. It is possible that warm gases or steam from below have penetrated the cracked crust of the earth and turned the bituminous coal-beds into anthracite; and this Q 9 98 COAL AND COMBUSTIBLES. is the more probable, seeing that the bitumi- nous coal-beds lie very flat and undisturbed, whereas the anthracite coal-beds are tossed and crumpled, and even sometimes turned quite over on their backs, forming long, pointed, narrow troughs or basins, with wrinkled sides ; while the rocks which enclose the coal-beds are baked as if by heat and broken into millions of fragments b) the movements to which they have been sub- jected : so that it would have been an easy thing for hot vapours from below to find their way to the surface through innumerable cracks. It is a curious fact that at the eastern end of all the anthracite basins the coal is hardest and heaviest of all ; while at the western ends of the same basins it con- tains from ten to fourteen per cent, of volatile matter. Going still farther west, to Broad Top, Cumberland and the Alleghany Moun- tains, we find the semi-bituminous coal-beds containing from fifteen to twenty per cent. ; while the Ohio River coals contain from thirty-five to fifty per cent. In Arkansas, the anthracite coal appears again; but in California and Central America all the coal yet discovered belongs to the tertiary forma- COAL IN GERMANY. 99 tion, and is very soft and smoky and full of ashes. Such, also, is the coal of Texas and of the head- waters of the Missouri and Judith Rivers. The age of the Richmond, Dan River and Deep River coal-basins, in Eastern Vir- ginia and North Carolina, is midway between the old coal-measures of Pennsylvania and the West and these modern tertiary coal-mea- sures of the Pacific coast. In Germany there is a kind of soft, earthy " brown coal" much in use, which is made into bricks and fed into great china-ware stoves with hinged tin gloves. It is a dirty, crumbly fuel, but the best the poor people can get. In Wales there is a variety called by the cot- tagers stone-coal. It is found generally in very small pieces, which are mixed with clay into " coal balls." They are difficult to light at first, but, when once ignited, will burn so long, and so slowly, that the fire is not extinguished for years. The good housewives vie with each other in the taste with which these balls are piled into the grate, at the top of the fire, to supply the destruction below. It is considered quite a calamity if the fire goes out. There was a company once formed in New York to mix the broken and fine refuse coal of Potts- 100 COAL AND COMBUSTIBLES. ville and Mauch Chunk with clay, to make into similar bricks or balls for the Philadelphia market ; but it was found to be too costly at the present price of coal. Hills of this refuse coal are annually washed down the rivers by the rains into the sea. At some future day so great a waste will be prevented. The coal comes out of the mine in great lumps, and is crushed between iron rollers set with teeth, and shot down long inclined planes into the cars, which take it to the cities. In England, great cranes let down the cars, full of soft coal which will not bear much handling, into the holds of vessels lying far below. That coal has been so long made ready in the earth for men to use it, we may regard as an eminent and admirable result of the Creator's wise use of the past and seemingly useless exuberance of vegetable nature; for thus the decay of the earth's ancient beauty is made subservient to the comfort and pros- perity of the future generations of its inhabi- tants. Moreover, nothing is more remarkable than this " gathering up of fragments, that nothing be lost," to be observed in all God's works; and so strikingly is this perceived in every deeper discovery of scientific truth LESSONS. 101 that men of science are prepared to assert that no new matter has been added to our world, but that the whole record of natural history is simply the history of oh.a.nges, won- derful and varied, and perhaps; still inex-' haustible. "Well, now," said Edward, "vlien I look at the spring buds and blossoms, I like to think they are all God's new work just fin- ished : as David says, ' Thou renewest the face of the earth/ ' "You may enjoy that pleasure still, my boy," said his father; "for are not the skill and benevolence of our heavenly Father more wonderful still, when new and beautiful fruits and flowers are created from the old soil and gases, so disagreeable to our senses?" " Oh, yes ; but I should like to find out something really fresh created,' actually lately formed by God." " We must leave the world of matter, then, my dear Edward, and use the eyes of our minds ; and then we may discern that every infant possesses a newly-created spirit, one sent into this world to be educated and trained for immortality through the redemption by Jesus Christ. Thus, infancy and childhood 9* 102 COAL AND COMBUSTIBLES. in a family are a precious trust. How care- ful we should all be of the lessons we teach their new souls, which, though only now com- mencing their existence, are nevertheless des- tined to'- live < forever either in happiness or PECOPTERIS SILLIMAXI ; nat. Coal Shale. Ohio a. The Stern. b. Leaf-stalk, or petiole. c. Leaf, or frond, which is bipinnate. d. Leaflets, or pinnae; the upper, d, are entire; the lower, e. are pinnatifid /. The pinnules, lobes, or segments. y. The midrib, or median vein. /. The veins The veins are introduced in the leaflets, d; but in the lower ones, 0 >- CC ^ S _ CO LU O ; o z S < Q. O CO DC LU O CC h- Z IX g < u -^ B 6 E ID D O LU CO o UJ CO < UJ -D 0) c J2 o o CD 363 U.C. BERKELEY LIBRARIES LU . cc LU 2 5 00 Q Q DC O Id,