r~ - CO 0) ^ ^ cO o -* - m o a" r 3- 2 3 cx CD m m mfrMs- University of California Berkeley The Joseph M. Bransten Coffee and Tea Collection A TREATISE ' / OJT ADULTERATIONS OF FOOD, AND UotoonOt EXHIBITING FRAUDULENT SOPHISTICATIONS OF BREAD, BEER, WINE, SPIRITUOUS LIQUORS, TEA, COFFEE, Cream, Confectionery, Vinegar, Mustard, Pepper, Cheese, Olive Oil, Pickles, AND OTHER ARTICLES EMPLOYED IN DOMESTIC ECONOMV. of tretetting tfjenu ERE IS DEATH IN THE Kin6s C . IVTT. 77/E SECOND EDITION. BY FREDRICK ACCUM, Operative Chemist, Lecturer on Practical Chemistry, Mineralogy, and on Chemistry applied to the Arts and Manufactures ; Member of the Royal Irish Academy ; Fellow of the Linnaean Society; Member of the Royal Academy of Sciences, and of the Royal Society of Arts of Berlin, &c. &c. 31 outs on : OLD BY LONGMAN, HURST, REES, ORME, AND 'BROWN, PATERNOSTER ROW. 1820. TO HIS GRACE THE DUKE OF NORTHUMBERLAND. MY LORD DUKE, The interest your Grace takes-on all occasions in promoting the application of Chemical Philosophy to the useful pur- poses of life, has emboldened me to lay before you the present Treatise, which ori- ginated in a suggestion of your Grace, while cultivating the study of Experimental Chemistry in my Laboratory., Be pleased, My Lord Duke, to accept this public testimony of profound 11 DEDICATION. respect and veneration for your Grace's exalted moral virtues and high intellectual endowments. That your Grace may retain 9 through a long and happy life, the ardent attachment to the pursuits of Philosophical Chemistry, which has so greatly endeared your renowned name to the votaries of that important and useful branch of knowledge ^ is the sincere wish oj} MY LORD DUKE, Your Grace's most devoted, Humble Servant, FREDRICK Old Compton Street, Soho. January the 19th, 1820. preface TO THE FIRST EDITION. Old Compton Street, Sola. THIS Treatise, as its title expresses, is intended to exhibit easy methods of detecting the fraudu- lent adulterations of food, and of other arti- cles, classed either among the necessaries or luxuries of the table ; and to put the unwary on their guard against the use of such commodities as are contaminated with substances deleterious to health. Every person is aware that bread, beer, wine, lr PREFACE. and other substances employed in domestic econo- my, are frequently met with in an adulterated state : and the late convictions of numerous in- dividuals for counterfeiting and adulterating tea, coffee, bread, beer, pepper, and other articles of diet, are still fresh in the memory of the public. To such perfection of ingenuity has the system of counterfeiting and adulterating various com- modities of life arrived in this country, that spu- rious articles are every where to be found in the market, made up so skilfully, as to elude the dis- crimination of the most experienced judges. But of all possible nefarious traffic and decep- tion, practised by mercenary dealers, that of adul- terating the articles intended for human food with ingredients deleterious to health, is the most cri- minal, and, in the mind of every honet man, must excite feelings of regret and disgust. Numerous PREFACE. V facts are on record, of human food, contaminated with poisonous ingredients, having been vended to the public ; and the annals of medicine record tragical events ensuing from the use of such food. The eagar and insatiable thirst for gain, is proof against prohibitions and penalties ; and the pos- sible sacrifice of a fellow-creature's life, is a secondary consideration among unprincipled dealers. However invidious the office may appear, and however painful the duty may be of exposing the names of individuals, who have been con- victed of adulterating food ; yet it was necessary, for the verification of my statement, that cases should be adduced in their support : and I have carefully avoided citing any, except those which are authenticated in Parliamentary documents and other public records. Tl PREFACE* To render this Treatise still more useful, I have also animadverted on certain material errors, sometimes unconsciously committed through ac- cident or ignorance, in private families, during the preparation of various articles of food, and of delicacies for the table. In stating the experimental proceedings neces- ary for the detection of the frauds which it has been my object to expose, I have confined myself to the task of pointing out such operations only as may be performed by persons unacquainted with chemical science; and it has been my purpose to express all necessary rules and instruc- tions in the plainest language, divested of those recondite terms of science, which would be out of place in a work intended for general peru- sal. The design of the Treatise will be fully an- swered, if the views here given should induce a PREFACE. Vll single reader to pursue the object for which it is published ; or if it should tend to impress on the mind of the Public the magnitude of an evil, which, in many cases, prevails to an extent so alarming, that we may exclaim, with the sons of the Prophet, " TO&m to Heat?) m t&* pot/' For the abolition of such nefarious practices, it is the interest of all classes of the community to co-operate. FREDRICK ACCUM. LONDON, 1820. ADVERTISEMENT TO ISttitfoiu THE sale of one thousand copies of the Treatise on the Adulterations of Food, within one month after its publication, has been a sufficient inducement to reprint the work. Several additions have been made to the edition now presented to the reader; among which will be noticed, the adultera- tion of milk of cinnamon of isinglass of Spanish liquorice juice, and of several other articles employed in housekeeping, with the A 5 X ADVERTISEMENT. methods of detecting the frauds. Some animadversions have also been made on the disgusting practice of inflating butchers' meat and fish ; and on the frauds committed in the coal trade. I embrace this opportunity of offering my public expression of thanks for the flattering compliments which I have received from numerous individuals of high rank and dig- nified station, and from other distinguished persons, whose opinion and judgment I re- spect. To those who have chosen anony- mously to transmit to me their opinion concerning this book, together with their maledictions, I have little to say ; but they may rest assured, that their menaces will in no way prevent me from endeavour- ing to put the unwary on their guard against Ihe frauds of dishonest men, wherever they ADVERTISEMENT. XI may originate ; and those assailants in am- bush are hereby informed, that, in every succeeding edition of the work, I shall con- tinue to hand down to posterity the infamy which justly attaches to the knaves and dishonest dealers, who have been convicted at the bar of Public Justice of rendering human food deleterious to health. FREDRICK ACCUM, Compton-streetj Soho, April 1820. CONTENTS. Page PRELIMINARY REMARKS ON THE ADULTERATIONS OF FOOD 1 ADULTERATIONS OF DRUGS AND MEDICINES, and method of detecting them 15 Adulteration of Peruvian Bark .... 16 Adulteration of Rhubard Powder, Ipecacuanha, $c 17 Adulteration of Spirit of Hartshorn, and method of detecting it 19 Adulteration of Magnesia, and me* thod of detecting it 20 Adulteration of Calcined Magnesia, and method of detecting it 21 XIV CONTENTS. Adulteration of Calomel, and method of detecting it , 22 Adulteration of Syrup of Buckthorn, Worm-Seed, and Arrow Root Pow- der ib. Adulteration of Essential Oils, and methods of detecting it 2 ADULTERATION OF PAINTERS' COLOURS, and methods of detect- ing it 26 Adulteration of Ultramarine, and method of detecting it 27 Adulteration of Carmine, and method of detecting it , . ib. Adulteration of Madder and Carmine Lake, and method of detecting it .. ib. Adulteration of Antwerp Blue, and method of detecting it ib. CONTENTS. XV Page Adulteration of Chrome Yellow, and method of detecting it ib. Adulteration of White Lead, and method of detecting it ib. Adulteration of Vermillion, and me- thod of detecting it ib. ADULTERATION OF VARIOUS ARTICLES USED IN HOUSE- KEEPING 29 Adulteration of Soap, $c ib. FRAUDS PRACTISED IN THE COAL TRADE 31 DISGUSTING PRACTICE OF RENDERING BUTCHERS' MEAT, FISH, AND POULTRY, UNWHOLESOME 36 General Remarks on the Adultera- tion of Food 41 XVI CONTENTS* Page IMPORTANCE OF THE PURITY OF WATER EMPLOYED IN DOMESTIC ECONOMY 43 Characters of Good Water 49 Easy method of curing Hard Water 5"2 Chemical Constitution of the Waters used in Domestic Econony and the Arts 53 Rain Water ib. Snow Water.. 54 Spring Water , , 56 River Water 60 Thames Water 62 Substances usually contained in Com- mon Water, and Tests by which they are detected 66 Deleterious Effects of keeping Water for Domestic Economy, in Leaden Reservoirs r% ; 74 Method of detecting Lead in Water.. 86 CONTENTS. XV11 Page ADULTERATION OF WINE 92 Crusting of Wine Bottles, and other nefarious Artifices committed by fraudulent Wine Merchants 96 Dangerous Adulteration of Wine with poisonous Substances 102 Accidental Impregnation of Wine with Lead. 105 Test for detecting the deleterious Adulterations of Wine 108 Method of detecting extraneous Co- lours in Red Wine.... Ill Specific Differences of various kinds of foreign Wines , 113 Chemical Constitution and Component Parts of Wine. 115 XVJii CONTENTS. Page Method of ascertaining the Quantity of Spirit contained in various sorts of Wine , 117 Per Cent age of Alcohol contained in various kinds of Wine, and other fermented Liquors 120 Chemical Constitution of Home-made Wines 122 ADULTERATION OF BREAD 125 Adulteration of Bread with Alum. , 127 Adulteration of Bread with Potatoes 133 Method of detecting the presence of Alum in Bread. 139 Method of judging of the Goodness of Breads-Corn and Bread- Flour. . 142 ADULTERATION OF BEER 145 Early practice of adulterating Beer with Substances noxious to Health, tind rapid Progress of this Fraud. 148 CONTENTS. Page Druggists and Grocers prosecuted and convictedfor supplying illegal Ingredients to Brewers for adulte- rating Beer 158 Remarks on Porter* 161 Strength and Specific Differences of different kinds of Porter 166 List of Publicans prosecuted and convicted for adulterating Beer with illegal Ingredients, and for mixing Table Beer with their Strong Beer 171 Fraudulent Practice of adulterating Beer with substances not deleteri- ous to health 173 Illegal Ingredients seized at various Breweries and Brewers' Druggists 9 181 Adulteration of Strong Beer with Small Beer.. 185 XX CONTENTS. Pagt List of Brewers prosecuted and con- victed for adulterating Strong Beer with Table Beer 189 Remarks with regard to the Origin of the Beer catted Porter , 191 Composition of Old or EntireBeer. . 194 Fraudulent Practice of converting New Beer into Old or Entire Beer 196 Fraudulent Practice of increasing the intoxicating quality of Beer... 199 Brewers prosecuted and convicted for receiving and using illegal In- gredients in their Brewings 201 Method of detecting the Adulteration of Beer 207 Method of ascertaining the Quantity of Spirit contained in Porter, Ale, or other kinds of Malt Liquors.... 209 CONTENTS. XXi Per Centage of Alcohol contained in Porter, Ale, and other kinds of Malt Liquors 211 COUNTERFEIT TEA-LEAVES ... 213 List of Grocers prosecuted and con- victed for adulterating Tea 230 Method of detecting the Adultera- tions of Tea-Leaves 231 COUNTERFEIT COFFEE 238 List of Grocers prosecuted by the Solicitor of the Excise and con- victed for adulterating Coffee 241 ADULTERATION OF BRANDY, RUM, AND GIN 249 Method of detecting the Adultera- tions of Brandy, Rum, and Malt Spirit 261 Method of detecting the Presence of Lead in Spirituous Liquors 272 XXli CONTENTS. Page Method of ascertaining the Quantity of Alcohol in different kinds of Spirituous Liquors 273 Per Centage of Alcohol contained in various kinds of Spirituous Liquors 275 POISONOUS CHEESE, and method of detecting it 276 COUNTERFEIT PEPPER, and me- thod of detecting it 284 White Pepper^ and method of manu- facturing it 290 POISONOUS CAYENNE PEPPER, and method of detecting it 292 POISONOUS PICKLES, and me- thod of detecting them 295 ADULTERATION OF VINEGAR, and method of detecting it.... 299 Distilled Vinegar 300 CONTENTS. XXlli Page ADULTERATION OF CREAM, and method of detecting it 302 POISONOUS CONFECTIONERY, and method of detecting it 305 POISONOUS CATSUP, and method of detecting it 309 ADULTERATION OF LOZENGES, and method of detecting it 314 POISONOUS OLIVE OIL, and me- thod of detecting it 318 ADULTERATION OF LEMON ACID, and method of detecting it 321 POISONOUS SODA WATER, and method of detecting it..... 324 POISONOUS ANCHOVY SAUCE, and method of detecting it 325 POISONOUS CUSTARD.., 328 xxir CONTENTS. Page POISONOUS MUSHROOMS 332 Mushroom Catsup 338 ADULTERATION OF MILK, and method of detecting it 340 ADULTERATION OF ISINGLASS, and method of detecting it 342 ADULTERATION OF CINNAMON, and method of detecting it 344 ADULTERATION OF MUSTARD 346 ADULTERATION OF SPANISH LIQUORICE 548 FOOD POISONED BY COPPER VESSELS, and method of detect- ing it 350 FOOD POISONED BY LEADEN VESSELS, f HE TESTS FOR DETECTING THEM. 67 soap in alcohol, the water will remain tran* sparent. This test is employed for ascertaining the presence of earthy salts in waters. Hence it produces no change when mingled with distilled or perfectly pure water ; but when added to water containing earthy salts, a white flocculent matter becomes separated, which speedily collects on the surface of the fluid. Now, from the quantity of floc- culent matter produced, in equal quantities of water submitted to the test, a tolerable notion may be formed of the degrees of hardness of different kinds of water, at least 80 far as regards the fitness of the water for the ordinary purposes of domestic economy. This may be rendered obvious in the following manner. 68 SUBSTANCES CONTAINED IN WATER, EXPERIMENT II. Fill a number of wine-glasses with dif- ferent kinds of pump or well water, and let fall into each glass a few drops of the solu- tion of soap in alcohol. A turbidness will instantly ensue, and a flocculent matter collect on the surface of the fluid, if the mixture be left undisturbed. The quantity of flocculent matter will be in the ratio s>f the quantity of earthy salts contained in the water. // -^ It is obvious that the action of this test is not discriminative with regard to the che- mical nature of the earthy salt present in the water. It serves only to indicate the presence or absence of those kinds of sub- stances which occasion that quality in water which is usually called hardness, and which AND THE TESTS FOR DETECTING THEM. 69 is always owing to salts with an earthy base. If we wish to know the nature of the different acids and earths contained in the water, the following tests may be em- ployed. EXPERIMENT III. Add about twenty drops of a solution of oxalate of ammonia, to half a wine-glass of the water ; if a white precipitate ensues, we conclude that the water contains lime. By means of this test, one grain of lime may be detected in 24,250 of water. If this test occasion a white precipitate in water taken fresh from the pump or spring, and not after the water has been boiled and suffered to grow cold, the lime is dissolved in the water by an excess of 70 SUBSTANCES CONTAINED IN WATER, carbonic acid ; and if it continues to pro- duce a precipitate in the water which has been concentrated by boiling, we then are sure that the lime is combined with a fixed acid. EXPERIMENT IV. To detect the presence of iron, add to a wine-glassful of the water a few drops of an infusion of nut-galls ; or better, suffer a nut- gall to be suspended in it for twenty-four hours, which will cause the water to acquire a blueish black colour, if iron be present. EXPERIMENT V. Add a few grains of muriate of barytes, to half a wine-glass of the water to be ex- amined ; if it produces a turbidness which AND THE TESTS FOR DETECTING THEM. 71 does not disappear by the admixture of a few drops of muriatic acid, the presence of sulphuric acid is rendered obvious. EXPERIMENT VI. If a few drops of a solution of nitrate of silver occasion a milkiness with the water, which vanishes again by the copious ad- dition of liquid ammonia, we have reason to believe that the water contains a salt, one of the constituent parts of which is muriatic acid. EXPERIMENT VII. If lime water or barytic water occasions a precipitate which again vanishes by the admixture of muriatic acid, then carbonic acid is present in the water. 72 SUBSTANCES CONTAINED IN WATER, EXPERIMENT VIII. If a solution of phosphate of soda produce a milkiness with the water, after a previous addition to it of a similar quantity of neutral carbonate of ammonia, we may then expect magnesia. The application of this test is best made in the following manner : Concentrate a quantity of the water to be examined to about -fa part of its bulk, and drop into about half a wine-glassful, about five grains of neutral carbonate of am- monia. No magnesia becomes yet preci- pitated if this earth be present; but on adding a like quantity of phosphate of soda, the magnesia falls down, as an insoluble salt. It is essential that the carbonate of ammonia be neutral. AND THE TESTS FOR DETECTING THEM. 73 The presence of oxygen gas loosely com- bined in water may readily be discovered in the following manner. EXPERIMENT IX. Fill a vial with water, and add to it a small quantity of green sulphate of iron. If the water be entirely free of oxygen, and if the vessel be well stopped and completely filled, the solution is transparent; but if otherwise, it soon becomes slightly turbid, from the oxide of iron attracting the oxygen, and a small portion of it, in this more highly oxidated state, leaving the acid and being precipitated. If we examine the different waters which are used for the ordinary purposes of life, 74 DELETERIOUS EFFECTS OF WATER and judge of them by the above tests, we shall find them to differ considerably from each other. Some contain a large quantity of saline and earthy matters, whilst others are nearly pure. The differences are pro- duced by the great solvent power which water exercises upon most substances. Hence wells should never be lined with bricks, which render soft water hard ; or, if bricks be employed, they should be bedded in and covered with cement. DELETERIOUS EFFECTS OF KEEPING WATER IN LEADEN RESERVOIRS. THE deleterious effect of lead, when taken into the stomach, is at present so univer- sally known, that it is quite unnecessary to KEPT IN LEADEN RESERVOIRS. 75 adduce any argument in proof of its dange- rous tendency. The antients were, upwards of 2000 years ago, as well aware of the pernicious quality of this metal as we are at the present day ; and indeed they appeared to have been much more apprehensive of its effects, and scrupulous in the application of it to pur- poses of domestic economy. Their precautions may have been occasi- onally carried to an unnecessary length. This was the natural consequence of the im- perfect state of experimental knowledge at that period. When men were unable to detect the poisonous matters to be over scrupulous in the use of such water, was an error on the right side. The moderns, on the other hand, in part, perhaps, from an ill-founded confidence, and E2 76 DELETERIOUS EFFECTS OF WATER inattention to a careful and continued exa- mination of its effects, have , fallen into an opposite error. There can be no doubt that the mode of pre- serving water intended for food or drink in leaden reservoirs, is exceedingly improper; and although pure water exercises no sen- sible action upon metallic lead, provided air be excluded, the metal is certainly acted on by the water when air is admitted : this effect is so obvious, that it cannot escape the no- tice of the least attentive observer. The white line which may be seen at the surface of the water preserved in leaden cisterns, where the metal touches the water and where the air is admitted, is a carbo- nate of lead, formed at the expense of the metal. This substance, when taken into the stomach, is highly deleterious to health. KEPT IN LEADEN RESERVOIRS. This was the reason which induced the an- tients to condemn leaden pipes for the con- veyance of water ; it having been remarked that persons who swallowed the sediment of such water, became affected with disorders bowels*. ferent potable waters have unequal t powers on this metal. In some s -"^i places the use of leaden pumps has been discontinued, from the expence entailed upon the proprietors by the constant want of repair. Dr. Lambf states an instance where the proprietor of a well ordered his plumber to make the lead of a pump of double the thickness of the metal usually employed for pumps, to save the charge of * Sir G. Baker, Med. Trans, vol. i. p. 280. t Lamb on Spring Water. E 3 78 DELETERIOUS EFFECTS OF WATER repairs ; because he had observed that the water was so hard, as he called it, that it corroded the lead very soon. The following instance is related by Sir George Baker*: " A gentleman was the father of a nume- rous offspring, having had one-and-twenty children, of whom eight died young, and thirteen survived their parents. During their infancy, and indeed until they had quitted the place of their usual residence, they were all remarkably unhealthy ; being particularly subject to disorders of the sto- mach and bowels. The father, during many years, was paralytic ; the mother, for a long time, was subject to colics and bilious ob- structions* * Medical Trans, vol. i. p. 420. KEPT IN LEADEN RESERVOIRS. 79 " After the death of the parents, the fa- mily sold the house which they had so long inhabited. The purchaser found it neces- sary to repair the pump. This was made of lead ; which, upon examination, was found to be so corroded, that several perfo- rations were observed in the cylinder in which the bucket plays ; and the cistern in the upper part was reduced to the thinness of common brown paper, and was full of holes, like a sieve." I have myself seen numerous instances where leaden cisterns have been completely corroded by the action of water with which they were in contact: and there is, perhaps, not a plumber who cannot give testimony of having experienced numerous similar in- stances in the practices of his trade. I have been frequently called upon to E4 80 DELETERIOUS EFFECTS OF WATER examine leaden cisterns, which had become leaky on account of the action of the water which they contained ; and I could adduce an instance of a legal controversy having taken place to settle the disputes between the proprietors of an estate and a plumber, originating from a similar cause the plum- ber being accused of having furnished a faulty reservoir; whereas the case was proved to be owing to the chemical action of the water on the lead. Water containing a large quantity of common air and carbonic acid gas, always acts very sensibly on me- tallic lead. Water which has no sensible action, in its natural state, upon lead, may acquire the capability of acting on it by heteroge- neous matter, which it may accidentally re- ceive. Numerous instances have shewn that KEPT IN LEADEN RESERVOIRS. 81 vegetable matter, such as leaves, falling into leaden cisterns filled with water, imparted to the water a considerable solvent power of action on the lead, which in its natural state it did not possess. Hence the neces- sity of keeping leaden cisterns clean ; and this is the more necessary, as their situations expose them to accidental impurities. The noted saturnine colic of Amsterdam, des- cribed by Tronchen, originated from such a circumstance; as also the case related by Van Swieten*, of a whole family afflicted with the same complaint, from such a cis- tern. And it is highly probable that the case of disease recorded by Dr. Duncanf, * Van Swieten ad Boerhaave, Aphorisms, 1060, Comment. t Medical Comment. Dec. 2, 1794. E5 82 DELETERIOUS EFFECTS OF WATER proceeded more from some foulness in the cistern, than from the solvent power of the water. In this instance the officers of the packet boat used water for their drink and cooking out of a leaden cistern, whilst the sailors used the water taken from the same source, except that theirs was kept in wooden vessels. The consequence was, that all the officers were seized with the colic, and all the men continued healthy. The carelessness of the bulk of mankind, Dr. Lambe very justly observes, to these things, " is so great, that to repeat them again and again cannot be wholly useless." Although the great majority of persons who daily use water kept in leaden cisterns receive no sensible injury, yet the apparent salubrity must be ascribed to the great slow- KEPT IN LEADEN RESERVOIRS. 83 ness of its operation, and the minuteness of the dose taken, the effects of which become modified by different causes and different constitutions, and according to the predis- positions to diseases inherent in different individuals. The supposed security of the multitude who use the water with impunity amounts to no more than presumption, in favour of any individual, which may or may not be confirmed by experience. Independent of the morbid susceptibility of impressions which distinguish certain ha- bits, there is, besides, much variety in the original constitution of the human frame, of which we are totally ignorant. " The susceptibility or proneness to dis- ease of each individual, must be esteemed peculiar to himself. Confiding to the expe- E 6 84 DELETERIOUS EFFECTS OF WATER. rience of others is a ground of security which may prove fallacious ; and the danger can with certainty be obviated only by avoiding its source. And ^considering the various and complicated changes of the human frame, under different circumstances and at different ages, it is neither impossible nor improbable that the substances taken into the system at one period, and even for a series of years, with apparent impunity, may, notwithstanding, at another period, be eventually the occasion of disease and of death. " The experience of a single person, or of many persons, however numerous, is quite incompetent to the decision of a question of this nature. " The pernicious effects of an intemperate use of spirituous liquors is not less certain KEPT IN LEADEN RESERVOIRS. 85 because we often see habitual drunkards enjoy a good state of health, and arrive at old age : and the same may be said of individuals who indulge in vices of all kinds, evidently destructive to life ; many of whom, in spite of their bad habits, attain to a vigorous old age*." In confirmation of these remarks, we ad- duce the following account of the effect of water contaminated by lead, given by Sir G. Baker: " The most remarkable case on the sub- ject that now occurs to my memory, is that of Lord Ashburnham's family, in Sussex; to which spring water was applied, from a considerable distance, in leaden pipes. In consequence, his Lordship's servants were * Lambe on Spring Water. 86 METHOD OF DETECTING every year tormented with colic, and some of them died. An 'eminent physician, of Battle, who corresponded with me on the subject, sent up some gallons of that water, which were analysed by Dr. Higgins, who reported that the water had contained more than the common quantity of carbonic acid ; and that he found in it lead in solution, which he attributed to the carbonic acid. In consequence of this, Lord Ashburnham substituted wooden for leaden pipes; and from that time his family have had no par- ticular complaints in their bowels," Richmond, Sept. 27, 1802. METHOD OF DETECTING LEAD IN WATER. ONE of the most delicate tests for detect- ing lead, is water impregnated with sulphu- LEAD IN WATER. 87 retted hydrogen gas, which instantly im- parts to the fluid containing the minutest quantity of lead, a brown or blackish tinge. This test is so delicate that distilled water, when condensed by a leaden pipe in a still tub, is effected by it. To shew the action of this test, the following experiments will serve. EXPERIMENT T. Pour into a wine-glass containing distilled water, an equal quantity of water impreg- nated with sulphuretted hydrogen gas: no change will take place ; but if a J of a grain of aeetate of lead (sugar of lead of com- merce,) be added, the mixture will instantly turn brown and dark-coloured. 88 METHOD OF DETECTING To apply this test, one part of the sus- pected water need merely to be mingled with a like quantity of water impregnated with sulphuretted hydrogen. Or better, a larger quantity, a gallon for example, of the water may be concentrated by evaporation to about half a pint, and then submitted to the action of the test. Another and more efficient mode of ap- plying this test, is, to pass a current of sul- phuretted hydrogen gas through the sus- pected water in the following manner. EXPERIMENT II. Take a bottle* (a) or Florence flask, adapt to the mouth of it a cork furnished * See the Figure, page 89. LEAD IN WATER. with a glass tube (6) bent at right angles ; let one leg of the tube be immersed in the vial (c) containing the water to be examined ; as shewn in the following sketch. Then take one part of the sulphuret of antimony of commerce, break it into pieces of half the size of split pease, put it into the flask, and pour upon it four parts of common concen- trated muriatic acid (spirit of salt of com- merce.) Sulphuretted hydrogen gas will become disengaged from the materials in abundance, and pass through the water in the vial (c). Let the extrication of the gas be continued for about five minutes ; and if 90 METHOD OF DETECTING the minutest quantity of lead be present, the water will acquire a dark-brown or blackish tinge. The extrication of the gas is facili- tated by the application of a gentle heat. The action of the sulphuretted hydrogen test, when applied in this manner, is asto- nishingly great ; for one part of acetate of lead may be detected by it, in 20,000 parts of water*. Sulphate of potash, or sulphate of soda, is likewise a very delicate test for detecting 1 * See An Analysis of the Mineral Waters of Tun- bridge Wells, by Dr. Scudamore, p. 55. The application of the sulphuretted hydrogen test requires some precaution in those cases where other metals besides lead may be expected ; because silver, quicksilver, tin, copper, and several other metals, are effected by it, as well as lead ; but there is no chance of these metals being met with in common water. See Chemical Tests, third edition, p. 207. LEAD IN WATER. 91 minute portions of lead. Dr. Thomson* dis- covered, by means of it, one part of lead in in 100,000 parts of water ; and this acute Philosopher considers it as the most une- quivocal test of lead that we possess. Dr. Thomson remarks that " no other precipi- tate can well be confounded with it, except sulphate of barytes ; and there is no proba- bility of the presence of barytes existing in common water." Analysis of Tunbridge Wells Water, by Dr. Scu- damore, p. 5$. 8totUterattott of IT is sufficiently obvious, that few of those commodities, which are the objects of com- merce, are adulterated to a greater extent than wine. All persons moderately conver- sant with the subject, are aware, that a por- tion of alum is added to young and meagre red wines, for the purpose of brightening their colour; that Brazil wood, or the husks of elderberries and bilberries*, are employed to impart a deep rich purple tint to red Port of a pale, faint colour ; that gypsum is used to render cloudy white wines transpa- rent ; that an additional astringency is im- * Dried bilberries are imported from Germany, under the fallacious name of berry 'dye. ADULTERATION OF WINE. 93 parted to immature red wines by means of oak-wood sawdust*, and the busks of fil- berts; and that a mixture of spoiled foreign and home-made wines is converted into the wretched compound frequently sold in this town by the name of* genuine old Port.' Various expedients are resorted to for the purpose of communicating particular fla- vours to insipid wines. Thus a nutty flavour is produced by bitter almonds ; factitious Port wine is flavoured with a tincture drawn from the seeds of raisins ; and the ingre- dients employed to form the bouquet of high-flavoured wines, are sweet-brier, oris- root, clary, cherry laurel water, and elder flowers. * Sawdust for this purpose is chiefly supplied by the ship-builders, and forms a regular article of commerce of the brewers' druggists. 94 ADULTERATION OF WINE. The flavouring ingredients used by ma- nufacturers, may all be purchased by those dealers in wine who are initiated in the mysteries of the trade ; and even a manu- script receipt book for preparing them, and. the whole mystery of managing all sorts of wines, may be obtained on payment of a considerable fee. The sophistication of wine with substances not absolutely noxious to health, is carried to an enormous extent in this metropolis. Many thousand pipes of spoiled cyder are annually brought hither from the country, for the purpose of being converted into fac- titious Port wine. The art of manufacturing spurious wine is a regular trade of great extent in this metropolis. " There is, in this city, a certain frater- nity of chemical operators, who work under- ADULTERATION OF WINE. 95 ground in holes, caverns, and dark retire- ments, to conceal their mysteries from the eyes and observation of mankind. These subterraneous philosophers are daily em- ployed in the transmutation of liquors, and by the power of magical drugs and incan- tations, raising under the streets of London the choicest products of the hills and val- leys of France. They can squeeze Bour- deaux out of the sloe, and draw Champagne from an apple. Virgil, in that remarkable prophecy, Incultisque rubens pendebit sentibus uva. Virg. Eel. iv. 29. The ripening grape shall hang on every thorn. seems to have hinted at this art, which ean turn a plantation of northern hedges into a vineyard. These adepts are known among one another by the name of Wine-brewers ; 96 ADULTERATION OF WINE* and, I am afraid, do great injury, not only to Her Majesty's customs, but to the bodies of many of her good subjects*. " Recipes for manufacturing spurious wines may be seen in Dr. Reece's Gazette of Health, No. 7, and in the Supplement to the Pharmacopoeias, p. 245. CRUSTING OF WINE BOTTLES, AND OTHER NEFARIOUS ARTIFICES COM- MITTED BY FRAUDULENT WINE MERCHANTS. THE particular and separate department in this factitious wine trade, called crusting, consists of lining the interior surface of * Tatler, vol. viii. p. 110, edit. 1797, 8vo. ADULTERATION OF WINE. 97 fempty wine-bottles, in part, with a red crust of super-tartrate of potash , by suffering a saturated hot solution of this salt, coloured red with a decoction of Rrazil-wood, to crys- tallize within them ; and after this simula- tion of maturity is perfected, they are filled with the compound called Port Wine. Other artisans are regularly employed in staining the lower extremities of bottle-corks with a fine red colour, to appear, on being drawn, as if they had been long in contact with the wine. The preparation of an astringent extract, to produce, from spoiled home-made and foreign wines, a " genuine old Port," by mere admixture ; or to impart to a weak wine a rough austere taste, a fine colour, and a peculiar flavour ; forms one branch of the business of particular wine-coopers ; 98 ADULTERATION OF WINE, while the mellowing and restoring of spoiled white wines, is the sole occupation of men who are called refiners of wine. We have stated that a crystalline crust is formed on the interior surface of bottles, for the purpose of misleading the unwary into a belief that the wine contained in them is of a certain age. A correspondent oper- ation is performed on the wooden cask ; the whole interior of which is stained artificially with a crystalline crust of super-tartrate of potash, artfully affixed in a manner pre- cisely similar to that before stated. Thus the wine-merchant, after bottling off a pipe of wine, is enabled to impose on the under- standing of his customers, by taking to pieces the cask, and exhibiting the beautiful dark coloured and fine crystalline crust, as an indubitable proof of the age of the wine ; ADULTERATION OF WINE. 99 a practice by no means uncommon, to flatter the vanity of those who pride themselves in their acute discrimination of wines. These and many other sophistications, which have long been practised with impu- nity, are considered as legitimate by those who pride themselves for their skill in the art of managing, or, according to the fa- miliar phrase, doctoring wines. The plea alledged in exculpation of them, is, that, though deceptive, they are harmless : but even admitting this as a palliation, yet they form only one department of an art which includes other processes of a tendency ab- solutely criminal. _ Several well-authenticated facts have con- vinced me that the adulteration of wine with substances deleterious to health, is cer- tainly practised oftener than is, perhaps, F2 100 ADULTERATION OF WINE* suspected ; and it would be easy to give some instances of very serious effects hav- ing arisen from wines contaminated with deleterious substances, were this a subject on which I meant to speak. The following statement is copied from the Monthly Ma- gazine for March 1811, p. 188. " On the 17th of January, the passengers by the Highflyer coach, from the north, dined, as usual, at Newark. A bottle of Port wine was ordered ; on tasting which, one of the passengers observed that it had an unpleasant flavour, and begged that it might be changed. The waiter took away the bottle, poured into a fresh decanter half the wine which had been objected to, and filled it up from another bottle. This he took into the room, and the greater part was drank by the passengers, who, ADULTERATION OF WINE. 101 after the coach had set out towards Grarv- tham, were seized with extreme sickness ; one gentleman in particular, who had taken more of the wine than the others, it was thought would have died, but has since re- covered. The half of the bottle of wine sent out of the passengers' room, was put aside for the purpose of mixing negus. In the evening, Mr. Bland, of Newark, went into the hotel, and drank a glass or two of wine $nd water. He returned home at his usual hour, and went to bed; in the middle of the night he was taken so ill, as to induce Mrs. Bland to send for his brother, an apothecary in the town ; but before that gentleman ar- rived, he was dead. An inquest was held, and the jury, after the fullest inquiry, and the examination of the surgeons by whom r3 102 ADULTERATION OF WINE. the body was opened, returned a verdict of Died by Poison." DANGEROUS ADULTERATION OF WINE WITH POISONOUS SUBSTANCES. THE most dangerous adulteration of wine is by some preparations of lead, which pos- sess the property of stopping the progress of acescence of wine, and also of rendering white wines, when muddy, transparent. I have good reason to state that lead is cer- tainly employed for this purpose. The effect is very rapid ; and there appears to be no other method known, of rapidly re- covering ropy wines. Wine merchants per- suade themselves that the miniate quantity ADULTERATION OP WINE. 103 of lead employed for that purpose is per- fectly harmless, and that no atom of lead remains in the wine* Chemical analysis proves the contrary; and the practice of clarifying spoiled white wines by means of lead, must be pronounced as highly dele- terious. Lead* in whatever state it be taken into the stomach, occasions terrible diseases ; and wine, adulterated with the minutest quantity of it, becomes a slow poison. The merchant or dealer who practises this dan- gerous sophistication, adds the crime of murder to that of fraud, and deliberately scatters the seeds of disease and death among those consumers who contribute to his emolument. If to debase the current coin of the realm be denounced as a capital offence, what punishment should be awarded 104 ADULTERATION OF WINE* against a practice which converts into poison a liquor used for sacred purposes ? Dr. Watson* relates, that the method of adulterating wine with lead, was at one time a common practice in Paris. Dr. Warren f states an instance of thirty- two persons having become severely ill, after drinking white wine that had been adulterated with lead. One of them died, and one became paralytic. In Graham's Treatise on Wine-Making J, under the article of Secrets, belonging to the mysteries of vintners, p. 31, lead is re- * Chemical Essays, vol. viii. p. 369. t Medical Trans, vol. ii. p. 80. J This book, which has run through many editions, may be supposed to have done some mischief. In the Vintner's Guide, 4th edit. 1770, p. 67, a lump of sugar of lead, of the size of a walnut, and a table-spoonful of sal eni^um, are a*irected to be added to a tierce (forty- $wo gallons) of muddy wine 3 to cure it of its muddiness* ADULTERATION OF WINE, 105 commended to prevent wine from becoming acid. The following lines are copied from Mr. Graham's work : " To hinder Wine from turning. " Put a pound of melted lead, in fair water, into your cask, pretty warm, and stop it close," " To soften Grey Wine. " Put in a little vinegar wherein litharge has been well steeped, and boil some honey, to draw out the wax. Strain it through a cloth, and put a quart of it into a tierce of wine, and this will mend it." ACCIDENTAL IMPREGNATION OF WINE WITH LEAD. IT is well known that bottles in which wine has been kept, are usually cleaned F5 106 ADULTERATION OF WINE. by means of shot, which by its rolling motion detaches the super-tartrite of potash from the sides of the bottles. This practice, which is generally pursued by wine-merchants, may give rise to serious consequences, as will become evident from the following- case*: " A gentleman who had never in his life experienced a day's illness, and who was constantly in the habit of drinking half a bottle of Madeira wine after his dinner, was taken ill, three hours after dinner, with a se- vere pain in the stomach and violent bowel colic, which gradually yielded within twelve hours to the remedies prescribed by his medical adviser. The day following he drank the remainder of the same bottle of * Philosophical Magazine, 1819, No. 257/p. 229. ADULTERATION OF WINE. 107 wine which was left the preceding day, and within two hours afterwards he was again seized with the most violent colliquative pains, headach, shiverings, and great pain over the whole body. His apothecary be- coming suspicious that the wine he had drunk might be the cause of the disease, ordered the bottle from which the wine had been decanted, to be brought to him, with a view that he might examine the dregs, if any were left. The bottle happening to slip out of the hand of the servant, disclosed a row of shot wedged forcibly into the angu- lar bent-up circumference of it. On ex- amining the beads of shot, they crumbled into dust, the outer crust (defended by a coat of black lead with which the shot is glazed) being alone left unacted on, whilst the remainder of the metal was dissolved. F 6 108 ADULTERATION OF WINE, The wine, therefore, had become contami- nated with lead and arsenic, the shot being- a compound of these metals, which no doubt had produced the mischief." TEST FOR DETECTING THE DELETE- RIOUS ADULTERATIONS OF WINE. A READY re-agent for detecting the pre- sence of lead, or any other deleterious metal in wine, is known by the name of the wine test. It consists of water saturated with sulphuretted hydrogen gas, acidulated with muriatic acid. By adding one part of it, to two of wine, or any other liquid suspected to contain lead, a dark coloured or black precipitate will fall down, which does not disappear by an addition of muriatic acid ADULTERATION OP WINE. 109 and this precipitate, dried and fused before the blowpipe on a piece of charcoal, yields a globule of metallic lead. This test does not precipitate iron ; the muriatic acid retains iron in solution when combined with sul- phuretted hydrogen; and any acid in the wine has no effect in precipitating any of the sulphur of the test liquor. Or a still more efficacious method is, to pass a current of sulphuretted hydrogen gas through the wine, in the manner described, p. 89, having previously acidulated the wine with muria- tic acid. The wine test sometimes employed is pre- pared in the following manner : Mix equal parts of finely powdered sulphur and of slaked quick-lime, and expose it to a red heat for twenty minutes. To thirty-six grains of this sulphate of lime, add twenty- 110 ADULTERATION OF WINE. six grains of stiper-tartrate of potassa ; put the mixture into an ounce bottle, and fill up the bottle with water that has been previ- ously boiled, and suffered to cool. The li- quor, after having been repeatedly shaken, and allowed to become clear, by the subsi- dence of the undissolved matter, may then be poured into another phial, into which about twenty drops of muriatic acid have been previously put. It is then ready for use. This test, when mingled with wine containing lead or copper, turns the wine of a dark-brown or black colour. But the mere application of sulphuretted hydrogen gas to wine, acidulated by muriatic acid, is a far more preferable mode of detecting lead in wine. ADULTERATION OF WINE. Ill METHOD OF DETECTING EXTRANEOUS COLOURS IN RED WINE. M. VOGEL* has lately recommended ace- tate of lead as a test for detecting extrane- ous colours in red wine. He remarks, that none of the substances that can be employed for colouring wine, such as the berries of the Vaccinium Martillus (bilberries,) elderber- ries, and Campeach wood, produce with ge- nuine red wine, a greenish grey precipitate, which is the colour that is procured by this test by means of genuine red wines. / Wine coloured with the juice of the bil- berries, or elderberries, or Campeach wood, * Journ. Pharm. iv. 56. (Feb. 1818,) and Thomson's Annals, Sept. 1818, p. 232. 112 ADULTERATION OF WINE, produces, with acetate of lead, a deep blue precipitate ; and Brazil-wood, red saunders, and the red beet, produce a colour which is precipitated red by acetate of lead. Wine coloured by beet root is also rendered co- lourless by lime water ; but the weakest acid brings back the colour. As the colour- ing matter of red wines resides in the skin of the grape, M. Vogel prepared a quantity of skins, and reduced them to powder. In this state he found that they communicated to alcohol a deep red colour : a paper stained with this colour was rendered red by acids and green by alkalies. M. Vogel made a quantity of red wine from black grapes, for the purpose of his ex- periments ; and this produced the genuine greyish green precipitate with acetate of lead. He also found the same coloured ANALYSIS OF WINE. 113 precipitate in two specimens of red wine, the genuineness of which could not be sus* pected; the one from Chateau-Margeaux, and the other from the neighbourhood of Coblentz. SPECIFIC DIFFERENCES OF VARIOUS KINDS OF FOREIGN WINES. EVERY body knows that no product of the arts varies so much as wine ; that dif- ferent countries, and sometimes the different provinces of the same country, produce dif- ferent wines. These differences, no doubt, must be attributed chiefly to the climate in which the vineyard is situated to its cul- ture the quantity of sugar contained in the grape juice the manufacture of the wine, 114 ANALYSIS OP WINE. or tbe mode of suffering its fermentation to be accomplished. If the grapes be ga- thered unripe, the wine abounds with acid ;\ but if the fruit be gathered ripe, the wine will be rich. When the proportion of sugar in the grape is sufficient, and the fermenta- tion complete, the wine is perfect and ge- nerous. If the quantity of sugar be too large, part of it remains undecomposed, as the fermentation is languid, and the wine is sweet and luscious ; if, on the contrary, it contains, even when full ripe, only a small portion of sugar, the wine is thin and weak ; and if it be bottled before the fermentation be completed, part of the sugar remains un- decomposed, the fermentation will go on slowly in the bottle, and on drawing the cork, the wine sparkles in the glass ; as, for example, Champagne. Such wines are not ANALYSIS OF WINE. 115 sufficiently mature. When the must is separated from the husk of the red grape before it is fermented, the wine has little or no colour : these are called white wines. I on the contrary, the husks are allowed to remain in the must while the fermentation is going on, the alcohol dissolves the colour- ing matter of the husks, and the wine is co- loured : such are called red wines. Hence white wines are often prepared from red grapes, the liquor being drawn off before it has acquired the red colour; for the skin of the grape only gives the colour. Besides in these principal circumstances, wines vary much in flavour. CHEMICAJL CONSTITUTION AND COM- PONENT PARTS OF WINE. ALL wines contain one common and iden- tical principle, from which their similar 116 ANALYSIS OF WINE. effects are produced : namely, brandy or alcohol. It is especially by the different proportions of brandy contained in wines, that they differ most from one another. When wine is distilled, the alcohol readily separates* The spirit thus obtained is well known under the name of brandy. All wines contain also a free acid; hence they turn blue tincture of cabbage, red. The acid found in the greatest abundance in grape wines, is tartaric acid. Every wine contains likewise a portion of super- tartrate of potash, and extractive matter, de- rived from the juice of the grape. These substances deposit slowly in the vessel in which they are kept. To this is owing the improvement of wine from age. Those wines which effervesce or froth, when poured into a glass, contain also carbonic acid, to which their briskness is owing. ANALYSIS OF WINE. 117 The peculiar flavour and odour of different kinds of wine probably depend upon the presence of a volatile oi7, so small in quan- tity that it cannot be separated. METHOD OF ASCERTAINING THE QUAN- TITY OF SPIRIT CONTAINED IN VA- RIOUS SORTS OF WINE. THE strength of all wines depends upon the quantity of alcohol or brandy which they contain, Mr. Brande, and Gay Lussac, have proved, by very decisive experiments, that all wines contain brandy or alcohol ready formed. The following is the process discovered by Mr. Brande, for ascertaining the quantity of spirit, or brandy, contained in different sorts of wine. 118 ANALYSIS OF WINE. Experiment. Add to eight parts, by measure, of the wine to be examined, one part of a concen- trated solution of sub-acetate of lead: a dense insoluble precipitate will ensue; which is a combination of the test liquor with the colouring, extractive, and acid matter of the wine. Shake the mixture for a few mi- nutes, pour the whole upon a filtre, and collect the filtered fluid. It contains the brandy or spirit, and water of the wine, together with a portion of the sub-acetate of lead. Add, in small quantities at a time, to this fluid, warm, dry, and pure sub-carbo- nate of potash (not salt of tartar, or sub- carbonate of potash of commerce), which has previously been freed from water by heat, till the last portion added remains un- ANALYSIS OF WINE, 119 dissolved. The brandy or spirit contained in the fluid will become separated ; for the sub-carbonate of potash abstracts from it the whole of the water with which it was com- bined ; the brandy or spirit of wine forming a distinct stratum, which floats upon the aqueous solution of the alkaline salt. If the experiment be made in a glass tube, from one half inch to two inches in diameter, and graduated into 100 equal parts, the per cen- tage of spirit, in a given quantity of wine, may be read off by mere inspection. In this manner the strength of any wine may be examined. 120 QUANTITY OF BRANDY Per Centage of Alcohol* contained in various kinds of Wine and other fer- mented Liquors'f. Proportion of Spirit per cent. Proportion of Spirit per cent. by measure. by measure* Lissa 26,47 Port .. 25,83 Ditto 24,35 Ditto ,. 24,29 Average 25,41 Ditto ,. 23,71 Raisin Wine 26,40 Ditto . 23,39 Ditto , 25,77 Ditto . 22,30 Ditto 23,30 Ditto . 2^40 Average 25,12 Ditto . 19,96 26,03 Average ,. 22,96 Ditto 25,05 Sherry . 19,81 Average 25,09 Ditto . 19,83 Madeira 24,42 Ditto . 18,79 Ditto 23,93 Ditto . 18,25 Ditto (Sercial} 21,40 Average . 19,17 Ditto 19,24 Teneriffe . 19,79 Average 22,27 Golares . 19,75 * Of a Specific Gravity, 825.^- t Philosophical Trans. 1811, p. 345; 1813, p. 87; Journal of Science and the Arts, No viii. p. 290. CONTAINED IN WINE. 121 Lachryma Christi... 19,70 Claret 16,32 Constantia (White) 19,75 Ditto , 14,08 Ditto (Red) 18,92 Ditto 12,91 Lisbon 18,94 Average 15,10 Malaga (1666) 18,94 Malmsey Madeira.. 16,40 Bucellas 18,49 Lunel 15,52 Red Madeira 22,30 Sheraaz 15,52 Ditto 18,40 Syracuse 15,28 Average 20,35 Sauterne 14,22 Cape Muschat 18,25 Burgundy 16,60 Cape Madeira 22,94 Ditto 15,22 Ditto 20,50 Ditto 14,53 Ditto 18,11 Ditto 11,95 Average 20,51 Average 14,57 Grape Wine 18,11 Hock. 14,37 Calcavella 19,20 Ditto 13,00 Ditto 18,10 Ditto (old iu cask). 8,68 Average 18,65 Average 12,08 Vidonia 19,25 Nice 14,62 Alba Flora 17,26 Barsac 13,86 Malaga 17,26 Tent 13,30 Hermitage (White) 17,43 Champagne (Still).. 13,80 Roussillon 19,00 Ditto (Sparkling)... 12,80 Ditto 17,20 Ditto (Red) 12,56 Average 18,13 Ditto (ditto) 11,30 Claret... 17,11 Average 12,61 122 ADULTERATION OF WINE. Red Hermitage 12,32 Mead 7,32 Vin de Grave 13,94 Ale (Burton) 8,88 Ditto 12,80 Ditto (Edinburgh). 6,20 Average 13,37 Ditto (Dorchester). 5,50 Frontignac 12,79 Average 6,87 Cote Rotie 12,32 Brown Stout 6,80 Gooseberry Wine... 11,84 LondonPorteraverage4,20 Currant Wine 20,55 Do. SmaUBeer, do. 1,28 Orange Wine average 11, 26 Brandy 53,39 Tokay 9,88 Rum 53,68 Elder Wine 9,87 Gin 51,60 Cyder highest average 9,87 Scotch Whiskey 54,32 Ditto lowest ditto... 5,21 Irish ditto 53,90 Perry average 7,26 CHEMICAL CONSTITUTION OF HOME- MADE WINES. BESIDES grapes, the most valuable of the articles of which wine is made, there are a considerable number of fruits from which a vinous liquor is obtained. Of such, we have in this country the gooseberry, the currant, ADULTERATION OF WINE. 123 the elderberry, the cherry, &c. which fer- ment well, and afford what are called home- made wines. They differ chiefly from foreign wines in containing a much larger quantity of acid. Dr. Macculloch* has remarked that the acid in home-made wines is principally the malic acid ; while in grape wines it is the tartaric acid. The great deficiency in these wines, inde- pendent of the flavour, which chiefly origi- nates, not from the juice, but from the seeds and husks of the fruits, is the excess of acid, Which is but imperfectly concealed by the addition of sugar. This is owing, chiefly, as Dr. Macculloch remarks, to the tartaric acid * Macculloch on Wine. This is by far the best Treatise published in this country on the Manufacture of Home-made Wines. G 2 124 ADULTERATION OP WINE. existing in the grape juice in the state of super-tartrate of potash, which is in part de- composed during the fermentation, and the rest becomes gradually precipitated ; whilst the malic acid exists in the currant and gooseberry juice in the form of malate of potash; which salt does not appear to suffer a decomposition during the fermentation of the wine ; and, by its greater solubility, is retained in the wine. Hence Dr. Maccul- loch recommends the addition of super-tar- trate of potash, in the manufacture of Bri- tish wines. They also contain a much larger proportion of mucilage than wines made from grapes. The juice of the goose- berry contains some portion of the tartaric acid ; hence it is better suited for the pro- duction of what is called English Cham- pagne, than any other fruit of this country. of THIS is one of the sophistications of the articles of food most commonly practised in this metropolis, where the goodness of bread is estimated entirely by its whiteness. It is therefore usual to add a certain quantity of alum to the dough ; this improves the look of the bread very much, and renders it whiter and firmer. Good, white, and porous bread may certainly be manufactured from good wheaten flour alone; but to produce the degree of whiteness rendered indispensable by the caprice of the consumers in London, it is necessary (unless the very best flour is employed,) that the dough should be bleached; and no substance has hitherto o 3 126 ADULTERATION OF BREAD. been found to answer this purpose better than alum. Without this 'salt, it is impossible to make bread, from the kind of flour usually em- ployed by the London bakers, so white as that which is commonly sold in the metro- polis. If the alum be omitted, the bread has a slight yellowish grey hue as may be seen in the instance of what is called home-made bread, of private families. The quantity of alum requisite to produce the required whiteness and porosity, depends entirely upon the genuineness of the flour, and the quality of the grain from which the flour is obtained. The mealman makes dif- ferent sorts of flour from the same kind of grain, The best flour is mostly used by the biscuit bakers and pastry cooks, and the in- ADULTERATION OF BREAD. 127 ferior sorts in the making* of bread. The bakers' flour is very often made of the worst kinds of foreign damaged wheat, and other cereal grains mixed with them in grinding* the wheat into flour. In this capital, no fewer than six distinct kinds of wheaten flour are brought into market. They are called line flour, seconds, middlings, fine middlings, coarse middlings, and twenty- penny flour. Common garden beans, and pease, are also frequently ground up among the London bread flour. ADULTERATION OF BREAD WITH ALUM. I have been assured by several bakers^on whose testimony I can rely, that the small profit attached to the bakers' trade, and the o 4 128 ADULTERATION OF BREAD. bad quality of the flour, induce the genera- lity of the London bakers to use alum in the making 1 of their bread. The smallest quantity of alum that can be employed with effect to produce awhite,1ight, and porous bread, from an inferior kind of flour,I have my own baker's authority to state, is from three to four ounces to a sack of flour, weighing 240 pounds. The alum is either mixed well in the form of powder, with a quantity of flour previously made into a liquid paste with water, and then incorpo- rated with the dough ; or the alum is dis- solved in the water employed for mixing up the whole quantity of the flour for making the dough. Let us suppose that the baker intends to convert five bushels, or a sack of flour into loaves with the least adulteration practised. ADULTERATION OP BREAD. 129 He pours the flour into the kneading trough, and sifts it through a fine wire sieve, which makes it lie very light, and serves to sepa- rate any impurities with which the flour may be mixed. Two ounces of alum are then dissolved in about a quart of boiling water, and the solution poured into the seasoning- tub. Four or five pounds of salt are like- wise put into the tub, and a pailful of hot-, water. When this mixture has cooled down to the temperature of about 84, three or four pints of yeast are added ; the whole is mixed, strained through the seasoning sieve, emp- tied into a hole in the flour, and mixed up with the requisite portion of it to the consis- tence of a thick batter. Some dry flour is then sprinkled over the top, and it is covered up with cloths. In this situation it is left about three o 5 130 ADULTERATION OF BREAD. hours. It gradually swells and breaks through the dry flour scattered on its sur- face. An additional quantity of warm water, in which one ounce of alum is dissolved, is now added, and the dough is made up into a paste as before ; the whole is then covered up. In this situation it is left for a few hours. The whole is then intimately kneaded with more water for upwards of an hour. The dough is cut into pieces with a knife, and penned to one side of the trough ; some dry flour is sprinkled over it, and it is left in this state for about four hours. It is then kneaded again for half an hour. The dough is now cut into pieces and weighed, in order to furnish the requisite quantity for each loaf. The loaves are left in the oven about two ours and a half. When taken out, they ADULTERATION OF BREAD. 131 are carefully covered up, to prevent as much as possible the loss of weight. The following account of making a sack, or five bushels of flour, into bread, is taken from Dr. P. Markhatn's Considerations ou the Ingredients used in the Adulteration of Bread Flour and Bread, p. 21 : Five bushels of flour, eight ounces of alum*, four pounds of salt, half a gallon of yeast, mixed with about three gallons of water. The theory of the bleaching property of alum, as manifested in the panification of an * Whilst correcting this sheet for the press,, the prin- ter transmits to me the following lines : ec On Saturday last,, Mr. Wood, a baker, was con- victed before T. Evance, Esq. Union Hall, of having in his possession a quantity of alum for the adulteration of bread, and fined in the penalty of 5. and costs, under 55 Geo. III. c. 99." The Times, Oct. 1819, G 6 132 ADULTERATION OF BREAD. inferior kind of flour, is by no means well understood ; and indeed it is really surpris- ing that the effect should be produced by so small a quantity of that substance ; two or three ounces of alum being sufficient for a sack of flour. From experiments in which I have been employed, with the assistance of skilful bakers, I am authorised to state, that with- out the addition of alum, it does not appear possible to make white, light, and porous bread, such as is used in this metropolis, unless the flour be of the very best quality. Another substance employed by fraudu- lent bakers, is subcarbonate of ammonia. With this salt, they realize the important consideration of producing light and porous bread, from spoiled, or what is technically called sour flour. This salt, which becomes ADULTERATION OF BREAD. 133 wholly converted into a gaseous state dur- ing the operation of baking, causes the dough to swell up into air bubbles, which carry before them the stiff dough, and thus it renders the dough porous ; the salt itself is, at the same time, totally volatilised dur- ing the operation of baking. Thus not a vestige of carbonate of ammonia remains in the bread. This salt is also largely em- ployed by the biscuit and ginger-bread bakers. ADULTERATION OF BREAD WITH POTATOES. POTATOES are likewise largely, and per- haps constantly, used by fraudulent bakers, as a cheap ingredient, to enhance their pro- fit. The potatoes being boiled, are tritu- 134 ADULTERATION OF BREAD, rated, passed through a sieve, and incorpo- rated with the dough by kneading. This adulteration does not materially injure the bread. The bakers assert, that the bad quality of the flour renders the addition of potatoes advantageous as well to the baker as to the purchaser, and that without this admixture in the manufacture of bread, it would be impossible to carry on the trade of a baker. But the grievance is, that the same price is taken for a potatoe loaf, as for a loaf of genuine bread, though it must cost the baker less. I have witnessed, that five bushels of flour, three ounces of alum, six pounds of salt, one bushel of potatoes boiled into a stiff paste, and three quarts of yeast, with the requisite quantity of water, produce a white, light, and highly palatable bread. ADULTERATION OF BREAD. 135 Such are the artifices practised in the preparation of bread* ; and it must be al- lowed, on contrasting them with those so- phistications practised by manufacturers of other articles of food, that they are compa- ratively unimportant. However, some me- dical men have no hesitation in attributing many diseases incidental to children to the use of eating adulterated bread ; others again will not admit these allegations: they persuade themselves that the small quantity of alum added to the bread (perhaps, upon an average, from eight to ten grains to a quartern loaf,) is absolutely harmless. * There are instances of convictions on record, of bakers having used gypsum, chalk, and pipe clay, in the manufacture of bread. 136 ADULTERATION OF BREAD. Mr. Edmund Davy, Professor of Chemis- try, at the Cork Institution, has communi- cated the following important facts to the public concerning the manufacture of bread. " The carbonate of magnesia of the shops, when well mixed with flour, in the propor- tion of from twenty to forty grains to a pound of flour, materially improves it for the purpose of making bread. " Loaves made with the addition of car- bonate of magnesia, rise well in the oven ; and after being baked, the bread is light and spongy, has a good taste, and keeps well. In cases when the new flour is of an indifferent quality, from twenty to thirty grains of carbonate of magnesia to a pound of the flour will considerably improve the ADULTERATION OF BREAD. 137 bread. When the flour is of the worst qua- lity, forty grains to a pound of flour seem necessary to produce the same effect. " As the improvement in the bread from new flour depends upon the carbonate of magnesia, it is necessary that care should be taken to mix it intimately with the flour, previous to making the dough. " Mr. Davy made a great number of com- parative experiments with other substances, mixed in different proportions with new bread flour. The fixed alkalies, both in their pure and carbonated state, when used in small quantity, to a certain extent were found to improve the bread made from new flour ; but no substance was so efficacious in this respect as carbonate of magnesia. " The greater number of his experiments were performed on the worst new seconds 138 ADULTERATION OF BREAD. flour Mr. Davy could procure. He also made some trials on seconds and firsts of different quality. lu some cases the results were more striking and satisfactory than in others ; but in every instance the improve- ment of the bread, by carbonate of magnesia, was obvious. " Mr. Davy observes, that a pound of carbonate of magnesia would be sufficient to mix with two hundred and fifty-six pounds of new flour, or at the rate of thirty grains to the pound. And supposing a pound of carbonate of magnesia to cost half-a-crown, the additional expence w r ould be only half a farthing in the pound of flour. " Mr. Davy conceives that not the slight- est danger can be apprehended from the use of such an innocent substance as the METHOD OF DETECTING ALUM IN BREAD. 139 * carbonate of magnesia, in such small propor- tions as are necessary to improve bread from new flour." METHOD OF DETECTING THE PRE- SENCE OF ALUM IN BREAD. POUR upon two ounces of the suspected bread, half a pint of boiling distilled water ; boil the mixture for a few minutes, and filter it through unsized paper. Evaporate the fluid to about one fourth of its original bulk, and let gradually fall into the clear fluid a solution of muriate of barytes. If a co+ pious white precipitate ensue, which does not disappear by the addition of pure nitrie acid, the presence of alum may be suspected. Bread, made without alum, produces, when assayed in this manner, merely a very slight 140 METHOD OP DETECTING ALUM IN BREAD. precipitate, which originates from a minute portion of sulphate of magnesia contained in all common salt of commerce ; and bread made with salt freed from sulphate of mag- nesia, produces an infusion with water, which does not become disturbed by the barytic test. Other means of detecting all the consti- tuent parts of alum, namely, the alumine, sulphuric acid, and potash, so as to render the presence of the alum unequivocal, will readily suggest itself to those who are fa- miliar with analytical chemistry; namely: one of the readiest means is, to decompose the vegetable matter of the bread, by the action of chlorate of potash, in a platina crucible, at a red heat, and then to assay the residuary mass, by means of muriate of barytes for sulphuric acid ; by ammonia, METHOD OF DETECTING ALUM IN BREAD. 141 for alumine ; and by muriate of platina, for potash*. The above method of detecting the presence of alum, must therefore be taken with some limitation. There is no unequivocal test for detect- ing in a ready manner the presence of alum in bread, on account of the impurity of the common salt used in the making of bread. If we could, in the ordinary way of bread making, employ common salt, absolutely free from foreign saline substances, the mode of detecting the presence of alum would be very easy. Some conjecture may, nevertheless, be formed of the pre- sence, or absence, of alum, by assaying the * See a Practical Treatise on the Use and Applica- tion of Chemical Tests, illustrated by experiments, 3d edition, p. 270, 231, 177, and 196. 142 METHOD OF JUDGING OF THE GOODNESS infusion of bread in the manner stated, p. 139, and comparing the assay with the results afforded by an infusion of home- made or household bread, known to be genuine, and actually assayed in a similar manner. METHOD OF JUDGING OF THE GOODNESS OF BREAD-CORN AND BREAD-FLOUR. MILLERS judge of the goodness of bread corn by the quantity of bran which the grain produces. Such grains as are full and plump, that have a bright and shining appearance, without any shrivelling and shrinking in the covering* of the skin, are the best; for wrinkled grains have a greater quantity of OF BREAD-CORN AND FLOUR. 143 skin, or bran, than such as are sound or plump. Pastry-cooks and bakers judge of the goodness of flour in the manner in which it comports itself in kneading. The best kind of wheaten flour assumes, at the instant it is formed into paste by the addition of water,* a very gluey, ductile, and elastic paste, easy to be kneaded, and which may be elongated, flattened, and drawn in every direction, without breaking. For the following fact we are indebted to Mr. Hatchet : " Grain, which has been heated or burnt in the stack, may in the following man- ner be rendered fit for being made into bread. " The wheat must be put into a vessel capable of holding at l^ast three times the 144 METHOD OF CURING MUSTY WHEAT. quantity, and the vessel filled with boiling- water; the grain should then be occa- sionally stirred, and the hollow decayed grains, which float, may be removed. When the water has become cold, or in about half an hour, it is drawn off. Then rince the corn with cold water, and, having com- pletely drained it, spread it thinly on the floor of a kiln, and thus thoroughly dry it, stirring and turning it frequently during this part of the process.*" Phil. Trans, for 1817, part 1. ^alteration of MALT LIQUORS, and particularly porter, the favourite beverage of the inhabitants of London, and of other large towns, is amongst those articles, in the manufacture of which the greatest frauds are frequently committed. The statute prohibits the brewer from using any ingredients in his brewings, ex- cept malt and hops ; but it too often happens that those who suppose they are drinking a nutritious beverage, made of these ingre- dients only, are entirely deceived. The beverage may, in fact, be neither more nor H 146 ADULTERATION OF BEER. less than a compound of the most delete- rious substances ; and it is also clear that all ranks of society are alike exposed to the nefarious fraud. The proofs of this state- ment will be shown hereafter*. The author f of a Practical Treatise on Brewing, which has run through eleven editions, after having stated the various ingredients for brewing porter, observes, " that however much they may surprise, " however pernicious or disagreeable they " may appear, he has always found them " requisite in the brewing of porter, and " he thinks they must invariably be used " by those who wish to continue the taste, * See pages 158, 171, 181. t Child, on Brewing Porter,, p. 7. ADULTERATION OF BEER. 147 " flavour, and appearance of the beer*. " And though several Acts of Parliament " have been passed to prevent porter brew- " ers from using many of them, yet the " author can affirm, from experience, he ** could never produce the present flavoured " porter without them -f. The intoxicating " qualities of porter are to be ascribed to " the various drugs intermixed with it. It u is evident some porter is more heady than " other, and it arises from the grea(er or i4 less quantity of stupifying ingredients. " Malt, to produce intoxication, must be " used in such large quantities as would " very much diminish, if not totally ex- " elude, the brewer's profit." * Child, on Brewing Porter, p. 16. t Ibid, p. 16. H2 148 ADULTERATION OP BEER. EARLY PRACTICE OF ADULTERATING BEER WITH SUBSTANCES NOXIOUS TO HEALTH, AND RAPID PROGRESS OF THIS FRAUD. THE practice of adulterating beer appears to be of early date. By an Act so long ago as Queen Anne, the brewers are pro- hibited from mixing cocculus indicus, or any unwholesome ingredients, in their beer, under severe penalties : but few instances of convictions under this Act are to be met with in the public records for nearly a century. To shew that they have augmented in our own days, we shall exhibit an abstract from documents laid lately before Parliament*. * " Minutes of the Committee of the House of Com- mons, to whom the petition of several inhabitant* of ADULTERATION OF BEER. 149 These will not only amply prove, that unwholesome ingredients are used by frau- dulent brewers, and that very deleterious substances are also vended both to brewers and publicans for adulterating beer, but that the ingredients mixed up in the brew- er's enchanting cauldron are placed above all competition, even with the potent charms of Macbeth's witches : " Root of hemlock, digg'd i' the dark, " For a charm of pow'rful trouble, " Like a hell-broth boil and bubble." London and its vicinity, complaining of the high price and inferior quality of beer, was referred, to examine the matter thereof, and to report the same, with their observations thereupon, to the House. Printed by order of the House of Commons, April 1819." H3 150 ADULTERATION OF BEER. Mr. Morris* recommends the following Receipt for brewing Porter : Cwt. Qrs. Ib. Malt, 25 Quarters. Hops. 1 2 Cocculus Indicus Berry 6 Xeghorn Juice 30 Porter Extract Cwt. Qrs. Ibs, Malt, 20 Quarters. Hops 2 Cocculus Indicus Berry 00 4 Sugar .0 28 Fabia Amara 6 To make up a Vat of 150 Barrels* Use half a barrel of colouring, cwt of cream of tarter, \ cwt. of ground alum, * Morris on Brewing- Malt Liquors, p. 38, and H6. ADULTERATION OF BEER. 151 1 pound of salt of steel, and two barrels of strong finings. Mix these well together, and put them in a vat, rousing it thoroughly at the same time. Let the vat remain open three days ; then close it and sand it over* In a fortnight it will be fit for use. Your own good sense will inform you how, to advantage. The following are some of the Articles used by fraudulent Brewers, and recom- mended by Mr. Morris. Colouring. " I should recommend to every brewer to provide himself with a sufficient quantity, as it gives a good face to the beer, and enables you to gratify the sight of your different customers. Cocculus Indicus. " Cocculus Indicus is used as a substitute for malt and hops, and is a great preservative of malt liquor ; it H 4 152 ADULTERATION OF BEER, prevents second fermentation in bottled beer,, and consequently the bursting of the bottles in warm climates. Its effect is of an inebri- ating nature. " Calamus Ar omaticus is used in the brew- ery as a succedaneum for hops and strength, by slicing it thin, and boiling it a short time with the hops ; one pound of which is equal to six pounds of hops. " Quassia leaves so severe a bitter on the palate, long after the liquor is drank, that it requires much judgment in using it. " Coriander is much used by brewers, to give a flavour to ales. " Capsicum, or guinea pepper, is used in ales and amber. " Caraway Seed is put into ales, for the flavour ; and is used in the tun. " Grams of Paradise are of a warm na- ttire also, and are used in ales. ADULTERATION OF BEER, 153 ** Ginger. This article, when used in the brewery, is always ground fine ; and made use of in the tun at the time of cleansing, " Beans tend to mellow malt liquor ; and, from their properties, add much to its inebri- ating qualities ; but they must not be used in too large a quantity. " Oyster Shells are very good to recover sour beer : but when used, you must leave the bung out. " Alum is generally put into the vat, as it gives the beer a smack of age." Such are the articles recommended by Mr. Morris. The fraud of imparting to porter and ale an intoxicating quality by narcotic sub- stances, appears to have flourished during the period of the late French war: for, if ii 5 154 ADULTERATION OF BEER. we examine the importation lists of drugs, it will be noticed that the quantities of coc- culus indicus imported in a given time prior to that period, will bear no comparison with the quantity imported in the same space of time during the war, although an additional duty was laid upon this commodity. Such has been the amount brought into this country in five years, that it far exceeds the quantity imported during twelve years an- terior to the above epoch. The price of this drug has risen within these ten years from two shillings to seven shillings the pound. It was at the period to which we have alluded, that the preparation of an extract of cocculus indicus first appeared, as a new saleable commodity* in the price-currents of br eivers* -drug gist s* It was at the same time, also, that a Mr. Jackson, of notorious ADULTERATlbN OF BEER. 155 memory, fell upon the idea of brewing beer from various drugs, without any malt and hops. This chemist did not turn brewer himself; but he struck out the more pro- fitable trade of teaching his mystery to the brewers for a handsome fee. From that time forwards, written directions, and re- ceipt-books for using the chemical prepa- rations to be substituted for malt and hops, were respectively sold; and many adepts soon afterwards appeared every where, to instruct brewers in the nefarious practice, first pointed out by Mr. Jackson. From that time, also, the fraternity of brewers' chemists took its rise. They made it their chief business to send travellers a!! over the country with lists and samples exhibiting the price and quality of the articles manu- factured by them for the use of brewers H6 156 ADULTERATION Of BEER* only. Their trade spread far and wide, but it was amongst the country brewers chiefly that they found the most customers; and it is amongst them, up to the present day y as I am assured by some of these opera- tors, on whose veracity I can rely, that the greatest quantities of unlawful ingredients are sold. The Act of Parliament* prohibits che- mists, grocers, and druggists, from supply- ing illegal ingredients to brewers under a heavy penalty, as is obvious from the fol- lowing abstract of the Act. " No druggist, vender of or dealer in " drugs, or chemist, or other person, shall " sell or deliver to any licensed brewer, " dealer in or retailer of beer, knowing him * 56 Geo. III. c. 2. ADULTERATION OF BEER. 157 " to be such, or shall sell or deliver to any " person on account of or in trust for any * such brewer, dealer or retailer, any liquor " called by the name of or sold as colouring, " from whatever material the same may be " made, or any material or preparation other " than unground brown malt for darkening " the colour of worts, or beer, or any liquor " or preparation made use of for darkening " the colour of worts or beer, or any mo- " lasses, honey, vitriol, quassia, cocculus " Indian, grains of paradise, Guinea pepper " or opium, or any extract or preparation of " molasses, or any article or preparation to " be used in worts or beer for or as a sub- " stitute for malt or hops ; and if any drug- " gist shall offend in any of these particu- " lars, such liquor preparation, molasses, &c. " shall be forfeited and may be seized by 158 ADULTERATION OF BEER. " any officer of Excise, and the person so ' offending shall for each offence forfeit " 500." The following is a list of druggists and grocers, prosecuted by the Court of Excise, and convicted of supplying unlawful ingre- dients to brewers. Druggists and Grocers prosecuted and convicted from 1812 to 1819, for sup- plying illegal Ingredients to Brewers for adulterating Seer*, Messrs. Dunn and Co, druggists, for selling aduk terating ingredients to brewers, verdict 500/. Messrs. Rugg and others, druggists, for selling adul- terating ingredients to brewers, verdict 500/. * Copied from the Minutes of the Committee of the House of Commons, appointed for examining the price and quality of beer. See page 18, 29, 30, 31, 36, 43. ADULTERATION OP BEER. 159 Messrs. Hodgkinson and others, for selling" adulterat- ing ingredients to brewers, 1001. and costs. Messrs. Hiscocks and others, for selling adulterating ingredients to a brewer, 200/. and costs. Mr. Hornby, for selling adulterating ingredients to a brewer, 2001. Mr. Wilson, for selling adulterating ingredients to a brewer, 2001. Mr. Andrews, grocer, for selling adulterating ingre- dients to a brewer, 25/. and costs. Air. Knowles, for selling substitute for hops, costs. Messrs. Kernot and Alsop, for selling cocculus india, c. 25/. Messrs. Brandram and Co.* for selling various drugs, WOL Mr. Moss, for selling various drugs, 300/. Mr. Whitcombe, Mr. Dunn, and Mr. Waller, drug- gists, for having liquor for darkening the colour of beer, hid and concealed. Mr. Hebberd, for having liquor for darkening the colour of beer, hid and concealed. Mr. Whitcombe, Mr. Dunn, and Mr. Waller, drug- gists, for making liquor for darkening the colour of Beer. * Not Messrs. Brandram, of Size-lane, Cannon-st. 160 ADULTERATION OF BEER. Mr. Lord, grocer, for selling molasses to a brewer, 20/. and costs. Mr. Smith Carr, grocer, for selling molasses to a brewer, 20/. and costs. Mr. Fox, grocer, for selling molasses to a brewer, %bL and costs. Mr. Cooper, grocer, for selling molasses to a brewer, 40/. and costs. Mr. Bickering, grocer, for selling molasses to a brewer, 40/. and costs. Mr. Howard, grocer, for selling molasses to a brewer, 2l. and costs. Mr. Reynolds, grocer, for selling molasses to a brewer, costs. Mr. Hammond, grocer, for selling molasses to a brewer, 20/. and costs. Mr. Mackway, grocer, for selling molasses to a brewer, 20/. Mr. Renton, grocer, for selling molasses to a brewer, costs, and taking out a licence. Mr. Adam son, grocer, for selling molasses to a brewer, costs, and taking out a licence. Mr. Weaver, for selling Spanish liquorice to a brewer, 200/. Mr. Moss, for selling Spanish liquorice to a brewer. Mr. Braden, for selling liquorice, 20/. Mr, Draper, for selling molasses to a brewer, 20/. ADULTERATION OF BEER. 161 REMARKS ON PORTER. THE method of brewing- porter has not been the same at all times as it is at pre- sent. At first, the only essential difference in the methods of brewing this liquor and that of other kinds of beer, was, that porter was brewed from brown malt only ; and this gave to it both the colour and flavour required. Of late years it has been brewed from mix- tures of pale and brown malt. These, at some establishments, are mashed separately, and the worts from each are af- terwards mixed together. The proportion of pale and brown malt, used for brewing por- ter, varies in different breweries ; some em- ploy nearly two parts of pale malt and one part of brown malt ; but each brewer ap- 162 ADULTERATION OF BEER. pears to have his own proportion ; which the intelligent manufacturer varies, according to the nature and qualities of the malt. Three pounds of hops are, upon an average, allowed to every barrel (thirty-six gallons) of porter. When the price of malt, on account of the great increase in the price of barley during 1 the late war, was very high, the London brewers discovered that a larger quantity of wort of a given strength could be obtained from pale malt than from brown malt. They therefore increased the quantity of the former, and diminished that of the latter. This produced beer of a paler colour, and of a less bitter flavour. To remedy these disadvantages, they invented an artificial colouring substance, prepared by boiling- brown sugar till it acquired a very dark ADULTERATION OF BEER. 163 brown colour ; a solution of which was em- ployed to darken the colour of the beer. Some brewers made use of the infusion of malt instead of sugar colouring*. To impart to the beer a bitter taste, the fraudulent brewer employed quassia wood and worm- wood as a substitute for hops. But as the colouring of beer by means of sugar became in many instances a pretext for using illegal ingredients, the Legisla- ture, apprehensive from the mischief that might, and actually did, result from it, passed an Act prohibiting the use of burnt sugar in July 1817; and nothing but malt and hops is now allowed to enter into the composition of beer : even the use of isin- glass for clarifying beer, is contrary to law. 164 ADULTERATION OF BEER. No sooner had the beer-colouring Act been repealed, than other persons obtained a patent for effecting' the purpose of impart- ing an artificial colour to porter, by means of brown malt, specifically prepared for that purpose only. The beer, coloured by the new method, is more liable to become spoiled, than when coloured by the process formerly practised. The colouring malt does not contain any saccharine matter. The grain is by mere torrefaction converted into a gum-like substance, wholly soluble in water, which renders the beer more liable to pass into the acetous fermentation than the com- mon brown malt is capable of doing ; be- cause the latter, if prepared from good bar- ley, contains a portion of saccharine matter, of which the patent malt is destitute. ADULTERATION OF BEER. 165 But as brown malt is generally prepared from the worst kind of barley, and as the patent malt can only be made from good grain, it may become, on that account, an useful article to the brewer (at least, it gives colour and body to the beer) ; but it cannot materially economise the quantity of malt necessary to produce good porter. Some brewers of eminence in this town have as- sured me, that the vise of this mode of co- louring beer is wholly unnecessary; and that porter of the requisite colour may be brewed better without it ; hence this kind of malt is not used in their establishments. The quantity of gum-like matter which it contains, gives too much ferment to the beer, and render it liable to spoil. Repeated experiments, made on a large scale, have settled this fact, 166 ADULTERATION OF BEEfc. STRENGTH AND SPECIFIC DIFFERED CE& OF DIFFERENT KINDS OF PORTER. \ THE strength of all kinds of beer, like that of wine, depends on the quantity of spirit contained in a given bulk of the li- quor. The reader need scarcely be told, that of no article there are more varities than of porter. This, no doubt, arises from the dif- ferent mode of manufacturing the beer, al- though the ingredients are the same. This difference is more striking in the porter manufactured among country brewers, than it is in the beer brewed by the eminent London porter brewers. The totality of the London porter exhibits but very slight dif- ferences, both with respect to strength or the quantity of spirit, and solid extractive mat- ADULTERATION OF BEER. 167 ter, contained in a given bulk of it. The spirit may be stated, upon an average, to be 4,50 per cent, in porter retailed at the pub- licans : the solid matter is from twenty-one to twenty-three pounds per barrel of thirty- six gallons. The country-brewed porter is seldom well fermented, and seldom con- tains so large a quantity of spirit ; it usually abounds in mucilage; hence it becomes turbid when mixed with alcohol. Such beer cannot keep, without becoming sour. It has been matter of frequent complaint, that ALL the porter now brewed, is not what porter was formerly. This idea may be true, with some exceptions. My profes- sional occupations have, during these twenty-eight years, repeatedly obliged me to examine the strength of London por- ter, brewed by different brewers ; and, from the minutes made on that subject, I am au- 168 4^ULTERATION OF BEEU. thorized to state, that the porter now brewed by the eminent London brewers, is unques- tionably stronger than that which was brewed at different periods during the late French war. Samples of brown stout with which I have been obligingly favoured, whilst writing this Treatise, by Messrs. Barclay, Perkins,and Co. Messrs. Truman, Hanbury, and Co. Messrs. Henry Meux and Co. and other eminent brewers of this capital afforded, upon an average, 725 per cent. of alcohol, of 0,833 specific gravity; and porter, from the same houses, yielded upon an average 5,25 per cent, of alcohol, of the same specific gravity*; this beer re- * The average specific gravity of different samples of brown stout, obtained direct from the breweries of Messrs. Barcley, Perkins, and Co. Messrs. Truman, Hanbury, and Co. Messrs. Henry Meux and Co. and from several other eminent London brewers, amounted to 1,022; and the average specific gravity of porter, from the same breweries, 1,01 8. ADULTERATION OF BEER. 169 ceived from the brewers was taken from the same store from which the publicans are supplied. It is nevertheless singular to observe, that from fifteen samples of beer of the same denominations, procured from different re- tailers, the proportions of spirit fell conside- rably short of the above quantities. Sam- ples of brown stout, procured from the retailers, afforded, upon an average,* 6,50 per cent, of alcohol; and the average strength of the porter was 4,50 per cent. Whence can this difference between the beer furnished by the brewer, and that re- tailed by the publican, arise ? We shall not be at a loss to answer this question, when we find that so many retailers of porter have been prosecuted and convicted for mixing table beer with their strong beer ; this is 170 ADULTERATION OF BEER. prohibited by law, as becomes obvious by the following words of the Act*. " If any common or other brewer, inn- keeper, victualler, or retailer of beer or ale, shall mix or suffer to be mixed any strong 1 beer, ale, or worts, with table beer, worts, or water, in any tub or measure, he shall forfeit 50." The difference between strong and table beer, is thus settled by Parlia- ment. " All beer or ale f above the price of eighteen shillings per barrel, exclusive of ale duties now payable (viz. ten shillings per barrel,) or that may be hereafter paya- ble in respect thereof, shall be deemed strong beer or ale ; and all beer of the price * 2 Geo. III. c. 11, sec. 2. 1 59 Geo. III. c. 53, sec. 25. ADULTERATION OF BKER. 171 of eighteen shillings the barrel or under, exclusive of the duty payable (viz. two shillings per barrel) in respect thereof, shall be deemed table beer within the meaning of this and all other Acts now in force, or that may hereafter be passed in relation to beer or ale or any duties thereon." Publicans prosecuted and convicted from 1815 to 1818, for adulterating Beer with illegal Ingredients, andfor mixing Table Beer with their Strong Beer*. Mr. Atterbury, for using salt of steel, salt, molasses, &c. and for mixing table beer with strong beer, 401. Mr. Dean, for using salt of steel, salt, molasses, &c. and for mixing table beer with strong beer, 50/. * Copied from the Minutes of the Committee of the House of Commons, appointed for examining the price and quality of beer, p. 19, 29, 36, 37, 43. i2 172 ADULTERATION OF BEER. Mr. Jay, for using salt of steel, salt, molasses, &c. and for mixing table beer with strong beer 50/. Mr. Atkinson, for using salt of steel, salt, molasses, &c. and for mixing table beer with strong beer, 201. Mr. Langworth, for using salt of steel, salt, molasses, &c. and for mixing table beer with strong beer, 50/. Mrs. Spencer, for using salt of steel, salt, molasses, &c. and for mixing table beer with strong beer, 1 50/. Mr. Hogg, for using salt of steel, salt, molasses, &c. and for mixing table beer with strong beer, 51. Mr. Craddock, for using salt of steel, salt, molasses, &c. and for mixing table beer with strong beer, 1001. Mr. Harris, for using salt of steel, salt, molasses, &c. and for receiving stale beer, and mixing it with strong beer, 42/. and costs. Mr. Scoons, for using salt of steel, salt, molasses, &c. and for mixing stale beer with strong beer, verdict 200/. Mr. Geer and another, for using salt of steel, salt, molasses, &c. and for mixing strong and .table beer, verdict 400/. Mr. Coleman, for using salt of steel, salt, molasses, &c. and for mixing strong and table beer, 33/. and costs. Mr. Orr, for using salt of steel, salt, molasses, &c. and for mixing strong and table beer, 50/. Mr. Gardiner, for using salt of steel, salt, molasses, &c. and for mixing strong and table beer, 10Q/. ADULTERATION OF BEER. 173 Mr. Morris, for using salt of steel, salt, molasses, &c. and for mixing strong and table beer, 201. Mr. Harbur, for using salt of steel, salt, molasses, &c. and for mixing strong and table beer, 501. Mr. Corrie, for mixing strong beer with table beer. Mr. Cape, for mixing strong beer with table beer. Mr. Gudge, for mixing strong beer with small beer. FRAUDULENT PRACTICE OF ADULTE- RATING BEER WITH SUBSTANCES NOT DELETERIOUS TO HEALTH. WE have stated already (p. 145) that no- thing is allowed by law to enter into the composition of beer, but malt and hops. The substances used by fraudulent brew- ers for adulterating beer, are chiefly the fol- lowing : Quassia, which gives to beer a bitter taste, is substituted for hops ; but hops possess a i 3 174 ADULTERATION OF BEER. more agreeable aromatic flavour, and there is also reason to believe that they render beer less liable to spoil by keeping ; a pro- perty which does not belong to quassia. It requires but little discrimination to distin- guish very clearly the peculiar bitterness of quassia in adulterated porter. Vast quan- tities of the shavings of this wood are sold in 3 half-torrefied and ground state to dis- guise its obvious character, and to prevent its being recognized among the waste mate- rials of the brewers. Wormwood* has like- wise been used by fraudulent brewers. The adulterating of hops is prohibited by the Legislature f. * See Minutes of the Committee of the House of Commons for Reporting on the Price and Quality of 1819. p. 29. 7 Geo. II. c. 19, sec. 2- ADULTERATION OF BEER. 175 " If any person shall put any drug or in- gredient whatever into hops to alter the colour or scent thereof, every person so of- fending, convicted by the oath of one wit- ness before one justice of the peace for the county or place where the offence was com- mitted, shall forfeit 5 for every hundred weight." Beer rendered bitter by quassia never keeps well, unless it be kept in a place pos- sessing a temperature considerably lower than the temperature of the surrounding at- mosphere : and this is not well practicable in large establishments. The use of boiling the wort of beer with hops, is partly to communicate a peculiar aromatic flavour which the hop contains, partly to cover the sweetness of undecom- posed saccharine matter, and also to separate, i 4 176 ADULTERATION OF BEER. by virtue of the gallic acid and tannin it contains, a portion of peculiar vegetable mu- cilage somewhat resembling gluten, which is still diffused through the beer. The com- pound thus produced, separates in small flakes like those of curdled soap ; and by these means the beer is rendered less liable to spoiK For nothing contributes more to the conver- sion of beer, or any other vinous fluid, into vinegar, than mucilage. Hence, also, all full-bodied and clammy ales, abounding in mucilage, and which are generally ill fer- mented, do not keep as perfect ale ought to do. Quassia is, therefore, unfit as a substi- tute for hops ; and even English hops are preferable to those imported from the Conti- nent ; for nitrate of silver and acetate of lead produce a more abundant precipitate from an infusion of English hops, that can be oh- ADULTERATION OF BEER. 177 tained from a like infusion by the same agents from foreign hops. One of the qualities of good porter, is, that it should bear a fine frothy head, as it is technically termed : because professed judges of this beverage would not pro- nounce the liquor excellent, although it possessed all other good qualities of porter, without this requisite. To impart to porter this property of froth- ing when poured from one vessel into ano- ther, or to produce what is also termed a cauliflower head, the mixture called beer- heading, composed of common green vitriol (sulphate of iron), alum, and salt, is added. This addition to the beer is generally made by the publicans*. It is unnecessary to ge- * See List of Publicans prosecuted and convicted for mixing table beer with strong beer, &c. p. 171. " Alum gives likewise a smack of age to beer, and is penetrating to the palate." S. Child,on Breiving,p.lS. i 5 178 ADULTERATION OF BEER. nuine beer, which of itself possesses the pro- perty of bearing a strong white froth, witis- out these additions ; and it is only in conse- quence of table beer being mixed with strong beer that the frothing property of the porter is lost. From experiments I have tried on this subject, I have reason to believe that the sulphate of iron, added for that purpose, does not possess the power ascribed to it. But the publicans frequently, when they fine a butt of beer, by means of isinglass, adulterate the porter at the same time with table beer, together with a quantity of mo- lasses and a small portion of extract of gen- tian root, to keep up the peculiar flavour of the porter ; and it is to the molasses chiefly, which gives a spissitude to the beer, that the frothing property must be ascribed; for, without it, the sulphate of iron does not pro- duce the property of frothing in diluted beer. ADULTERATION OF BEER. 179 The following lines on the application of Beer Heading, are copied from Morris's Treatise on brewing Malt Liquors, p. 108. Heading. " On this part of our subject it may be necessary to observe, that here are various modes of making it. Some make use of ground copperas and ground alum, in about equal proportions ; some resort to salt of steel, of which as much as will lie on a shilling is sufficient for a barrel of beer. But, as the duties of a brewhouse sufficiently employ every person engaged in it, I recom- mend it to be purchased of those who make it their business to have it ready prepared. " Observe, that porter should not be sent out without it, as it causes the head so much admired in that liquor, and is agree- able to its flavour." Capsicum and grains of paradise, two i 6 180 ADULTERATION OP BEER. highly acrid substances, are employed to give a pungent taste to weak insipid beer. Of late, a concentrated tincture of these ar- ticles, to be used for a similar purpose, and possessing a powerful effect, has appeared in the price-currents of brewers' druggists. Ginger root, coriander seed, and orange peels, are employed as flavouring substances chiefly by the ale brewers. From these statements, and the seizures that have been made of illegal ingredients at various breweries, it is obvious that the adulterations of beer are not imaginary. It will be noticed, however, that some of the sophistications are comparatively harmless, whilst others are effected by substances de- leterious to health. The following list exhi- bits some of the unlawful substances seized at different breweries and at chemical labo- ratories* ADULTERATION OF BEER. 181 Illegal Ingredients, seized from 1812 to 1818, at various Breweries and Brewers 9 Druggists*. 1812, July. Mr. Nibbs. Multum 84lb. Cocculus indicus 12 Colouring 4 Galls. Honey 180 Ibs. Hartshorn Shavings... 14 Spanish Juice 46 Orange Powder 17 Ginger 56 Penalty 300, 1813, June 13. Mrs. Willis. Cocculus indicus lib. Spanish Juice 12 Hartshorn Shavings... 6 Orange Powder 1 Penalty 200. * Copied from the Minutes of the Committee of the House of Commons, appointed for examining the price and! quality of beer, p. 38. 182 ADULTERATION OF BEER. August 3. Mr. Whiffing. Grains of Paradise ... 441 b . Quassia 10 Liquorice 64 Ginger 80 Caraway Seeds 40 Orange Powder 14 Copperas 4 Penalty 200. Nov. 25. Mrs. Hasler. Cocculus indicus 12lbs. Multum 26 Grains of Paradise ... 12 Spanish Juice 30 Orange Powder 3 Penalty 200. Dec. 14. Mr. Abbott. Copperas, &c 14lbs. Orange Powder ..... 2 Penalty 500. and Crown's costs. Proof of using drugs at various times. ADULTERATION OF BEER. 1815, Feb. 15. Messrs. Mantell and Cook. Proof of mixing strong beer with table beer, and using colouring with other things. Compromised for 300. 1817. From Mr. Stevenson, an old Servant to Dunn and Waller, brewers' druggists. Cocculus indicus Extract 6lbs. Multum 560 Capsicum >... 88 Copperas 310 Quassia 150 Colouring & Drugs 84 Mixed Drugs 240 Spanish Liquorice ... 420 Hartshorn Shavings... 77 Liquorice Powder ... 177 Orange Powder 126 Caraway Seeds 100 Ginger , 110 Ginger Root 176 Condemned, not being claimed. 184 ADULTERATION OF BEER. July 30. Mr. Lyons. Capsicum lib. Liquorice Root Powder 2 Coriander Seed 2 Copperas 1 Orange Powder 8 Spanish Liquorice \ Beer C olouring 24 galls. Not tried (7th May, 1818.) Aug. 6. Mr. Gray. Multum 4lbs. Spanish Liquorice 21 Liquorice Root Powder 113 Ginger 116 Honey , 11 Penalty, ^300, and costs ; including mixing strong beer with table, and paying table-beer duty for strong beer, &c. Numerous other seizures of illegal sub- stances, made at breweries, might be ad- vanced, were it necessary to enlarge this subject to a greater extent. ADULTERATION OF BEER. 185 ADULTERATION OF STRONG BEER WITH SMALL BEER. ANOTHER fraud frequently committed, both by brewers and publicans, (as is evi- dent from the Excise Report,) is the prac- tice of adulterating strong beer with small beer. This fraud is prohibited by law ; since both the revenue and the public suffer by it*, "The duty upon strong beer is tea shillings a barrel ; and upon table beer it is two shillings. The revenue suffers, be- cause a larger quantity of beer is sold as * See Mr. Marr's evidence in the Minutes of the House of Commons, p. 32. 186 ADULTERATION OF BEER. strong beer ; that is, at a price exceeding the price of table beer, without the strong beer duty being paid. In the next place, the brewer suffers, because the retailer gets table or mild beer, and retails it as strong beer." The following are the words of the Act, prohibiting the brewers mixing table beer with strong beer : " If any common brewer shall mix or suf- fer to be mixed any strong beer, or strong* worts with table beer or table worts, or with water in any guile or fermenting tun after the declaration of the quantity of such guile shall have been made ; or if he shall at any time mix or suffer to be mixed strong beer or strong worts with table beer worts or with water, in any vat, cask, tub, measures or utensil, not being an entered ADULTERATION OF BEER. 187 guile or fermented tun, he shall forfeit 200/V With respect to the persons who commit this offence, Mr. Carr*, the Solicitor of the Excise, observes, that " they are generally brewers who carry on the double trade of brewing both strong and table beer. It is almost impossible to prevent them from mixing one with the other ; and frauds of very great extent have been detected, and the parties punished for that offence. One brewer at Plymouth evaded duties to the amount of 32,000/ ; and other brewers, who brew party guiles of beer carrying on the two trades of ale and table beer brewers, where * 42 George III, c. 38, section 12. t See Minutes of the House of Commons, p. 32. 188 ADULTERATION OF BEER* the trade is a victualling brewer, which is different from the common brewer, he being a person who sells only wholesale ; the vic- tualling brewer being a brewer and also a seller by retail. " In the neighbourhood of London," Mr. Carr continues," more particularly, I speak from having had great experience, from the informations and evidence which I have re- ceived, that the retailers carry on a most extensive fraud upon the public, in pur- chasing stale table beer, or the bottoms of casks. There are a class of men who go about and sell such beer at table-beer price to public victuallers, who mix it in their cellars. If they receive beer from their brewers which is mild, they purchase stale beer; and if they receive stale beer, they purchase common table beer for that ADULTERATION OF BEER. 189 purpose; and many of the prosecutions are against retailers for that offence." The fol- lowing may serve in proof of this state- ment. Brewers prosecuted and convicted from 1813 to 1819, for adulterating Strong Beer with Table Beer*. Mr. Manton and another, brewers, for mixing strong and table beer, verdict 300/. Mr. Morrell and another, brewers., for mixing strong and table beer, 20/. and costs. Mr. Jones and another, brewers, for mixing strong and table beer, verdict 125/. Mr. Stroad, brewer, for mixing strong and table beer, 200/. and costs. Mr. Cobbett, brewer, for mixing strong and table beer, 100?. and costs. Mr. Withers, brewer, for mixing strong and table beer, 7o/. and costs. * Copied from the Minutes of the Committee of the House of Commons, appointed for examining the price and quality of Beer, 1819, p. 29, 36, 43. 190 ADULTERATION OF BEER* Mr. Cowel, brewer, for mixing table beer with strong 1 , 50/. and costs. Mr. Mitchell, brewer, for mixing table beer with strong, absconded. Messrs. Lloyd and another, brewers, for mixing table beer with strong, 25/. and costs. Messrs. Edmunds and another, brewers,? for mixing table beer with strong, for a long period, verdict 600Z. Mr. Hoffman, brewer, for mixing strong and table beer, and using molasses, 130/. and costs. Mr. Langworth, brewer, for mixing strong with stale table beer, 10/. and costs. Mrs. Spencer, brewer, for mixing strong with stale table beer, verdict 150/. Messrs. Smith and others, brewers, for mixing strong and table beer. Mr. George, brewer, for mixing strong and table beer, verdict 200/. Mr. Row, brewer, for mixing strong and table beer, verdict 400/. Messrs. Drew, jun. and another, for mixing strong beer with table, 50/. and costs. Mr. Cape, brewer, for mixing strong and table beer, 250Z. and costs. Messrs. Williams and another, brewers, for mixing strong and table beer, verdict 200/. ADULTERATION OF BEER. 191 REMARKS WITH REGARD TO THE ORI- GIN OF THE BEER CALLED PORTER. IT is necessary to state, that every pub- lican has two sorts of beer sent to him from the brewer ; the one is called mild, which is beer sent out fresh as it is brewed ; the other is called old ; that is, such as is brewed on purpose for keeping, and which has been kept in store a twelve-month or eighteen months. The origin of the beer called entire, is thus related by the editor of the Picture of London: "Before the year 1730, the malt liquors in general use in London were ale beer and two-penny; and it was customary to call for a pint, or tankard, of half-and-half, i. e. half of ale and half of beer, half of ale and half of 192 ADULTERATION OF BEER. t\vo-penny. In course of time it also be- came the practice to call for a pint or tankard of three-threads, meaning a third of ale, beer, and two-penny ; and thus the publican had the trouble to go to three casks, and turn three cocks, for a pint of liquor. To avoid this inconvenience and waste, a brewer the name of Harwood conceived the idea of making a liquor, which should partake of the same united flavours of ale, beer, and two-penny ; he did so, and succeeded, call- ing it entire, OY entire butt, meaning that it was drawn entirely from one cask or butt ; and as it was a very hearty and nourishing* liquor, and supposed to be very suitable for porters and other working people, it obtained the name of porter*" The system is now altered, and porter is very generally com- pounded of two kinds, or rather the same ADVLTERATIOH OF BEER. 193 liquor in two different states, the due ad- mixture of which is palatable, though nei- ther is good alone. One is mild porter, and the other stale porter ; the former is that which has a slightly bitter flavour; the latter has been kept longer. This mixture the publican adapts to the palates of his several customers, and effects the mixture very readily, by means of a machine, containing small pumps worked by handles. In these are four pumps, but only three spouts, be- cause two of the pumps throw out at the same spout : one of these two pumps draws the mild, and the other the stale porter, from the casks down in the cellar ; and the pub- lican, by dexterously changing his hold works either pump, and draws both kinds of beer at the same spout. An indifferent ob- server supposes, that since it all comes from K 194 ADULTERATION OF BEER. one spout, it is entire butt beer, as the pub- lican professes over his door, and which has been decided by vulgar prejudice to be only good porter, though the difference is not easily distinguished. I have been informed by several eminent brewers, that, of late, a far greater quantity is consumed of mild than of stale beer. COPMOSITION OF OLD OR ENTIRE BEER. THE entire beer of the modern brewer, ac- cording to the statement of C. Barclay*, Esq. consists of some beer brewed ex- pressly for the purpose of keeping : it like- wise contains a portion of returns from pub- * See the Parliamentary Minutes* p. 94>. ADULTERATION OF BEER. 195 I leans ; a portion of beer from the bottoms of vats ; the beer that is drawn of from the pipes, which convey the beer from one vat to another, and from one part of the pre- mises to another. This beer is collected and put into vats. Mr. Barclay also states that it contains a certain portion of brown stout, which is twenty shillings a barrel dearer than common beer ; and some bot- tling beer which is ten shillings a barrel dearer* ; and that all these beers, united, are put into vats, and that it depends upon various circumstances, how long they may remain in those vats before they become per- fectly bright. When bright, this beer ig * Mr. Barclay has not specified the relative propor- tions of brown stout and of bottling beer, which are introduced at such an augmentation of expence. K2 196 ADULTERATION OF BEER* sent out to the publicans, for their entire beer, and there is sometimes a small quan- tity of mild beer mixed with it." The present entire beer, therefore, is a very heterogeneous mixture, composed of all the waste and spoiled beer of the pub* licans the bottoms of butts the leavings of the pots the drippings of the machines for drawing the beer the remnants of beer that lay in the leaden pipes of the brewery, with a portion of brown stout, bottling beer, and mild beer. FRAUDULENT PRACTICE OF CONVERT- ING NEW BEER INTO OLD OR EN- TIRE BEER. THE old or entire beer we have examined, as obtained from Messrs. Barclay's, and ADULTERATION OF BEER. 197 other eminent London brewers, is unques- tionably a good compound ; but it does no longer appear to be necessary, among frau- dulent brewers, to brew beer on purpose for keeping, or to keep it twelve or eighteen months. A more easy, expeditious, and economical method has been discovered to convert any sort of beer into entire beer, merely by the admixture of a portion of sulphuric acid. An imitation of the age of eighteen months is thus produced in an in- stant. This process is technically called to bring beer forward, or to make it hard. The practice is a bad one. The genuine, old, or entire beer, of the honest brewer, is quite a different compound ; it has a rich, generous, fullrbodied taste, without being acid, and a vinous odour: but it may, per- haps, not be generally known that this kind K3 198 ADULTERATION OF BEER. of beer always affords a less proportion of alcohol than is produced from mild beer. The practice of bringing beer forward, it is to be understood, is resorted to only by fraudulent brewers*. If, on the contrary, the brewer has too large a stock of old beer on his hands, recourse is had to an opposite practice of converting stale, half-spoiled, or sour beer, into mild beer, by the simple ad>- mixture of an alkali, or an alkaline earth. Oyster-shell powder and subcarbonate of potash, or soda, are usually employed for that purpose. These substances neutralise the excess of acid, and render sour beer somewhat palatable. By this process the beer becomes very liable to spoil. * Mr. Child, in Ms Treatise on Brewing, p. 23, directs, to make neiv faer older, use oil of vitriol. ADULTERATION OF BEER, 199 It is the worst expedient that the brewer can practise : the beer thus rendered mild, soon loses its vinous taste; it becomes va- pid; and speedily assumes a muddy grey colour, and an exceedingly disagreeable taste. These sophistications may be considered, at first, as minor crimes practised by fraudu- lent brewers, when compared with the me- thods employed by them for rendering beer noxious to health by substances absolutely injurious* FRAUDULENT PRACTICE OF INCREAS- ING THE INTOXICATING QUALITY OF BEER. To increase the intoxicating quality of beer, the deleterious vegetable substance, K4 200 ADULTERATION OF BEER. called cocculus indicus, and the extract of thifc poisonous berry, technically called black extract, or, by some, hard multum, are employed. Opium, tobacco, nux vomica, and extract of poppies, have also been used. This fraud constitutes by far the most censurable offence committed by unprinci- pled brewers; and it is a lamentable re- flection to behold so great a number of brewers prosecufed and convicted of this crime ; nor is it less deplorable to find the names of drug-gists, eminent in trade, im- plicated in the fraud, by selling the unlaw- ful ingredients to brewers for fraudulent purposes. ADULTERATION OF BEER. 201 prosecuted and convicted from 1813 to 1819,. ybr receiving and using illegal Ingredients in their Brewings*. Mr. Gardner, brewer, for using adulterating ingre- dients, 100/., judgment by default. Messrs. Webb and another, brewers, for using adulterating ingredients, and mixing strong and table beer, verdict 500^. Mr. Wyatt, brewer, . for using adulterating ingre- dients, verdict 40 O/. Mr. Harbart, retailer, for receiving adulterating ingredients, verdict 150/. Messrs. Blake and others, brewers, for using adul- terating ingredients, and mixing strong and table beer, verdict 250k Mr. Sneed, for receiving adulterating ingredients, 25/. and costs. Messrs. Rewell and another, brewers, ditto, verdict 1DO/. * Copied from the Minutes of the Committee of the House of Commons appointed for examining the price and quality of beer, p. 29, 36. K5 202 ADULTERATION OP BEER. Messrs. Swain and another, brewers, for using adul- terating ingredients, verdict 200/. Mr. Ing, brewer, ditto, stayed on defendant's death. Mr. Hall, ditto, for receiving adulterating ingre- dients^ 5/. and costs. Mr. Webb, retailer, for vising adulterating ingre- dients. Messrs. Fogg and another, brewers, for receiving and using adulterating ingredients. Mr. Gray, brewer, for using adulterating ingre- dients, 300/. and costs. Mr. Bowman, for using liquid in bladder, supposed to be extract of cocculus, 100/. Mr. Bowman, brewer, for ditto, 100Z. and costs. Mr. Stephens, brewer, for ditto, verdict 50/. Messrs. Rogers and another, brewers, for ditto, 220 /, and costs. Mr. Moore, brewer, for using colouring, 300/. and costs. Mr. Morris, for using adulterating ingredients. Messrs. Webb and Ball, for using ginger, Guinea pepper, and brown powder (name unknown), 1st. 100/. 2nd. 500/. Mr. Clarke, for using molasses, 150Z. Messrs. Kewell and Burrows, for using cocculus india, multum, &c. 100/. Messrs. Allatson and Abraham, for using eocculus india, multum, and porter flavour, 630/. ADULTERATION OF BEER. 203 Messrs. Swain and Sewell, for using cocculus india, Guinea opium. &c. 200/. Mr. Ing, for using cocculus india, hard colouring, and honey, dead. Mr. Dean, for using molasses, 50/. Mr. Cowell, for using Spanish liquorice, and mixing table beer *vith strong beer, 50/^ Mr. Mitchell, for using cocculus india, vitriol, and Guinea pepper, left the country. Messrs. Lloyd and Man, for using extract of coc- culus, 251. Mr. Gray, for using ginger, hartshorn shavings, and molasses, 300/. Mr. Hoffman, for using molasses, Spanish juice, and mixing table with strong beer, ISO/. Messrs. Rogers and Boon, for using extract of coc- culus, multum, porter flavour, &c. 220/. Mr. Betteley, for using wormwood, coriander seed, and Spanish juice, 200/. Mr. Lane, brewer, for using wormwood instead of hops, 5/. and costs. That a minute portion of an unwholesome ingredient, daily taken in beer, cannot fail to be productive of mischief, admits of no doubt ; and there is reason to believe that K6 204 ADULTERATION OF BEER. a small quantity of a narcotic substance (and cocculus indicus is a powerful narcotic*), daily taken into the stomach, together with an intoxicating liquor, is highly more effi- cacious than it would be without the liquor. The effect may be gradual; and a strong constitution, especially if it be assisted with constant and hard labour, may counteract the destructive consequences perhaps for many years ; but it never fails to shew its baneful effects at last. Independent of this, it is a well-established fact, that porter drinkers are very liable to apoplexy and palsy, without taking this narcotic poison. * The deleterious effect of Cocculus Indicus (the fruit of the memispermum cocculus} is owing to a pe- culiar bitter principle contained in it; which, when, swallowed in minute quantities, intoxicates and acts as poison. It may be obtained from cocculus indicus ber- ries in a detached state : chemists call it picrotoxin^ from 7r*x/?ofc bitter ; and TO&KOV, poison. ADULTERATION OF BEER. 205 If we judge from the preceding lists of prosecutions and convictions furnished by the Solicitor of the Excise*, it will be evident that many wholesale brewers, as well as retail dealers, stand very conspicuous among those offenders. But the reader will like- wise notice, that there are no convictions, in any instance, against either of the eleven great London porter brewersf for any illegal practice. It has been asserted, that it is more dif- ficult J for the officers of the Excise to detect * See Minutes of the House of Commons, p. 28, 36. t Messrs. Barclay, Perkins, and Co. Truman, Han- bury and Co. Reid arid Co. Whitbread and Co. Combe, Delafield, and Co. Henry Meux and Co. Calvert and Co. Goodwin and Co. Elliot and Co.-<- Taylor and Co. Cox, and Camble and Co. See the Minutes, before quoted, p. 32* t Ibid. p. 22. 206 ADULTERATION OF BEER. fraudulent practices in large breweries than in small ones; this may be true to a certain extent: but what eminent London porter brewer would stake his reputation on the chance of so paltry a gain, in which he would inevitably be at the mercy of his own man? The eleven great brewers of this metropolis are persons of such high respecta- bility, that there is no ground for the slight- est suspicion that they would attempt any illegal practices, which they were aware could not possibly escape detection in their extensive establishments. And let it be remembered, that none of them have been detected in any unlawful practice* in the processes of their manufacture, or in the adulteration of their beer. * Minutes of the House of Commons, p. 32. ADULTERATION OF BEER, 207 METHOD OF DETECTING THE ADUL- TERATION OF BEER. THE detection of the adulteration of beer with deleterious vegetable substances is beyond the reach of chemical analysis. The presence of sulphate of iron may be detected by evaporating the beer to perfect dryness, and burning away the ve- getable matter obtained, by the action of chlorate of potash, in a red-hot crucible. The sulphate of iron will be left behind among the residue in the crucible, which, when dissolved in water, may be assayed, for the constituent parts of the salt, namely, iron and sulphuric acid : for the former, by tincture of galls, ammonia, and prussiate of 208 ADULTERATION OF BEER. potash ; and for the latter, by muriate of barytes*. Beer, which has been rendered fraudu- lently hard or stale, by the admixture of sulphuric acid, affords a white precipitate (sulphate of barytes), by dropping into it a solution of acetate or muriate of barytes; and this precipitate, when collected by fil- tering the mass, and after having been dried, and heated red-hot for a few minutes in a platina crucible, does not disappear by the addition of nitric or muriatic acid. Ge- nuine old beer may produce a precipitate ; but the precipitate which it affords, after having been made red-hot in a platina cru- cible, instantly becomes re-dissolved with * See a Treatise on the Use and Application of Che- mical Tests, 3d edition ; Tests for Sulphuric Acid^ &c<. ADULTERATION OF BEER. 209 effervescence by pouring on it some pure nitric or muriatic acid ; in that case the pre- cipitate is malate (not sulphate) ofbarytes, and is owing to a portion of malic acid having been formed in the beer. But with regard to the vegetable mate- rials deleterious to health, it is extremely difficult, in any instance, to detect them by chemical agencies ; and in most cases it is quite impossible, as in that of coeculus in- dicus in beer. METHOD OF ASCERTAINING THE QUAN- TITY OF SPIRIT CONTAINED IN PORTER, ALE, OP^ OTHER KINDS OF MALT LIQUORS. TAKE any quantity of the beer, put it into a glass retort, furnished with a receiver, 210 ADULTERATION OF BEER. and distil, with a gentle heat, as long as any spirit passes over into the receiver ; which may be known by heating from time to time a small quantity of the obtained fluid in a tea-spoon over a candle, and bringing into contact with the vapour of it, the flame of a piece of paper. If the vapour of the dis- tilled fluid catches fire, the distillation must be continued until the vapour ceases to be set on fire by the contact of a flaming body* To the distilled liquid thus obtained, which is the spirit of the beer, combined with water, add, in small quantities at a time, pure subcarbonate of potash (previously freed from water by having been exposed to a red heat), till the last portion of this salt added, remahis iiddissolved in the fluid. The spirit will thus become separated from the water, because the subcarbonate of pot- ADULTERATION OF BEER. 211 ash abstracts from it the whole of the water which it contained; and this combination sinks to the bottom, and the spirit alone floats on the top. If this experiment be made in a glass tube, about half or three- quarters of an inch in diameter, and gra- duated into 50 or 100 equal parts, the rela- tive per centage of spirit in a given quantity of beer may be seen by mere inspection. Quantity of Alcohol contained in Porter, Ale, and other kinds of Malt Liquors*. One hundred parts, by Measure, Parts of Alcohol^ 'by contained Measure. Ale, home-brewed 8,30 Ale, Burton, three samples -. 6,25 * Repository of Arts, No. 2, p. 74. 1316. 212 ADULTERATION OF BEER. One hundred parts, by Measure, Parts of Alcohol, contained by Measure. Ale, Burton* 8,88 i Ale, Edinburgh* 6,20 Ale, Dorchester* , 5,50 Ale, common London-brewed^ six samples.... 5,82 Ale, Scotch, three samples ..... ....5,75 Porter, London, eight samples 4,00 Ditto, Dittot 4,20 Ditto, Dittot 4,45 Ditto, Ditto, bottled V& Brown Stout, 4 samples.... 5 Ditto, Dittot 6,80 Small Beer, six samples 0,75 Ditto, DittoJ 1,28 * Copied from Professor Branded Paper in the Phi- losophical Transactions, 1811, p. 345. t Result of our own Experiments, see p. 16D, $ Professor Brande's Experiments. Counterfeit f CHINA and PORTO, now farewell; ** Let others buy what you've to sell. " Your Port, and your Bohea ; " For we've our native Sloe divine, " Whose fruit yields all our Porto Wine, " Whose leaves make all our Tea." Literary Journal, vol. i. p. 14?. THE heavy duties payable to Government upon tea, hold out a strong- temptation to those who scruple not to enrich themselves by fraud, although at the expence of the health, and even the lives of the community. The application of leaves poisonous to health for the purpose of imitating tea, is not 214 COUNTERFEIT TEA. a new invention, detected for the first time within these few years : as is obvious from the Acts of Parliament passed at differ- ent periods to prevent and punish the of- fence. The first legislative enactment on the subject is in 2d. Geo. I. cap. 30, sec. 4, whereby it is declared " That the dealer in tea, or manufacturer or dyer thereof, who shall counterfeit or adulterate tea, or shall alter, fabricate, or manufacture it with terra japonic a, or with any other drug or drugs whatsoever, or shall mix with tea any leaves other than leaves of tea, or other ingredients whatsoever, shall forfeit the sum of one hundred pounds." The 4th Geo. II. cap. 14, sec. 11, recites, " That several persons do frequently dye, fabricate, or manufacture very great quanti- COUNTERFEIT TEA. 215 ties of sloe-leaves, and the leaves of tea that have been before used, or the leaves of other trees, shrubs, or plants, in imitation of tea, and do likewise mix, colour, stain, and dye such leaves with terra japonica, logwood, and other ingredients, and do sell and vend the same as true and real tea, to the preju- dice of the health of his Majesty's subjects, the diminution of the revenue, and to the ruin of the fair trader." The Act then de- clares, that the dealer in or seller of such " sophisticated" teas, shall forfeit the sum of ten pounds for every pound weight. The latest statute on this subject is 17th Geo. III. cap. 29, which states, that this trade had increased to a very great degree, and by the same Act, the seller or manufac- turer of such tea is to forfeit five pounds per pound weight of tea; or, upon non pay- 216 COUNTERFEIT TEA. ment of that sum, be committed to prison for any time not exceeding twelve months; and, if the party so selling is a tea-dealer, he is subject to the provisions of the Act of Geo. II. and the penalty is ten pounds sterling, per pound weight. The extent to which this most iniquitous traffic has been carried, appears to have been as great formerly as now, and there- fore it is necessary for the public to be al- ways on their guard, and not to suppose that the late convictions will deter others from continuing the practice. In 1778 there was a printed circular, signed by the headsman and secretary of a company of grocers in Norwich, stating, that they had been shown a small quantity of green tea, one-fourth part of which was avowedly sloe-leaves, yet so well manufactured as almost to pre- COUNTERFEIT TEA. 217 vent detection ; and there is another coun- terfeit of hyson tea, which is a strong decep- tion. So much for the closeness of the imi- tation. Of the extent to which this illicit traffic of defrauding the revenue was carried, we have very satisfactory evidence. In a report of the Committee of the House of Commons, dated December 24, 1783, wherein it is stated, that " the quantity of fictitious tea, which is annually manufactured from sloe and ash-tree leaves, in different parts of England, to be mixed with genuine teas, is computed at more than FOUR MILLIONS OF POUNDS:" and this too at a time when the whole quantity of genuine teas sold by the East India Company did not amount to more than six millions of pounds annually. In Scotland, and in Ireland, the fraud of L 218 COUNTERFEIT TEA. counterfeiting tea* has been carried on to an equal extent, and with greater ingenuity ; in the latter country, the penalties imposed for this offence, have, during a few months, amounted to more than 15,000 ! In the defence set up by some fraudulent grocers convicted of adulterating tea, it is stated that the spurious leaves made use of were perfectly harmless ; and that they were only mixed with tea to cheapen it to the lower classes of the community, who could not afford to pay the high price at which genuine tea was sold. But sloe-leaves are rendered poisonous by the process they un- dergo in being manufactured as a substitute for tea. We have the authority of the most eminent botanist of his day, to prove this * The History of the Tea Plant, p. 4,9. COUNTERFEIT TEA. 219 statement. The following is from the twelfth volume of English Botany, page 842; by Sir James Smith, M.D. President of the Linnoean Society. " The recent fruit of the sloe* is one of the many articles used to adulterate Port wine in England. The dried leaves are said to be a substitute for tea ; and are, perhaps, often mixed with it in this country. They may be one cause of its proving sometimes pernicious ; for the green parts of the plumf and cherry tribe are highly poisonous ; and it is fortunate if they act merely as a purga- tive." * Prunos Spinosa, sloe or blackthorn, t The genus, Primus, or plum, includes the sloe, plum, cherry, peach, bay, laurel, &c. L 2 220 COUNTERFEIT TEA. It is not to be expected that the recent convictions will suppress a crime which has existed for a century, and to the committal of which the temptation is stronger than ever; while the duties remain unrepealed, the opinion may be fairly hazarded, that im- position will still continue to be practised on the public. This opinion must be strengthened when it is stated that a profit of from 300 to 600 per cent, can be ob- tained by this species of fraud ; and though some of our punishments are represented to be too severe, yet there are many more much too mild, and wholly inadequate to the purpose of deterring offenders from a repetition of the crime. It is probable, that not a single individual, of those lately fined, will desist from his nefarious practices ; the profits of which have long since enabled him COUNTERFEIT TEA. 221 to meet the trivial loss which attends a conviction, and will speedily reimburse him the penalty in which he has been convicted. The late detections that have been made respecting the illicit establishments for the manufacture of imitation tea leaves, arrested, not long ago, the attention of the public ; and the parties by whom these manufacto- ries were conducted, together with the nu- merous venders of the factitious tea, did not escape the hand of justice. In proof of this statement, it is only necessary to consult the London newspapers (the Times and Courier) from March to July 1818; which show to what extent this nefarious traffic has been carried on in this metropolis ; and they re- port the prosecutions and convictions of numerous individuals who have been guilty L 3 222 COUNTERFEIT TEA. of the fraud. The following are some of those prosecutions and convictions. HATTON GARDEN*. On Saturday an in- formation came to be heard at this office, before Thomas Leach, Esq. the sitting- ma- gistrate, against Edmund Rhodes, charged with having, on the 12th of August last, dyed, fabricated, and manufactured, divers large quantities, viz. one hundred weight of sloe leaves, one hundred weight of ash leaves, oiie hundred weight of elder leaves, and one hundred weight of the leaves of a certain other tree, in imitation of tea, con- trary to the statute of the 17th of Geo. Ill, also, 2 Geo. I. c. 30, sec. 5 ; and 4 Geo. II. c. 14, sec. 11. whereby the said Edmund Rhodes had, for every pound of such leaves so manufactured, forfeited the sum of 5/. * Courier, Jime 22, 1818, COUNTERFEIT TEA. 223 making the total of the penalties amount to 2,0007. The second count in the informa- tion charged the said Rhodes with having in his possession the above quantity of leaves, under the like penalty of 2,000/. The third count charged him with having, on the said 12th of August last, in his possession, divers quantities, exceeding six pounds weight; of each respective kind of leaves ; viz. fifty pounds weight of green sloe leaves, fifty pounds weight of green leaves of ash, fifty pounds weight of green leaves of elder, and fifty pounds weight of the green leaves of a certain other tree ; not having proved that such leaves were gathered with the consent of the owners of the trees and shrubs from which they were taken, and that such leaves were gathered for some other use, and not for the purpose of manufacturing the same L 4 224 COUNTERFEIT TEA. in imitation of tea; whereby he had forfeited for each pound weight, the sum of 5/. amounting in the whole to 1,000/,; and, in default of payment, in each case, subjected himself to be committed to the House of Correction for not more than twelve months, nor less than six months* Mr. Denton, who appeared for the defen- dant, who was absent, said, that he was a very poor man, with a family of five chil- dren, and was only the servant of the real manufacturer, and an ignorant man from the country, put into the premises to carry on the business, without knowing what the leaves were intended for. By direction of Mr. Mayo, who conducted the prosecution, several barrels and bags, filled with the imi- tation tea, were then brought into the office, and a sample from each handed round. To COUNTERFEIT TEA. 225 the eye they seemed a good imitation of tea. The defendant was convicted in the pe- nalty of 500 on the second count. The Attorney-General against Palmer. (The Times, May 18, 1818.) This was an action by the Attorney-General against the defendant Palmer, charging him with hav- ing in his possession a quantity of sloe- leaves and white-thorn leaves, fabricated into an imitation of tea. Mr. Dauncey stated the case to the Jury, and observed that the defendant, Mr. Palmer, was a grocer. It would-appear that a regu- lar manufactory was established in Gold- stone-street. The parties by whom the manufactory was conducted, was a person of the name of Proctor, and another person named J. Malins. They engaged others to L 5 226 COUNTERFEIT TEA. furnish them with leaves. The leaves, in order to be converted into an article resem- bling black tea, were first boiled, then baked upon an iron plate; and, when dry, rubbed with the hand, to produce that curl which the genuine tea had : the colour, which was yet to be given to it, was produced by logwood. The green tea was manufactured in a manner more destructive to the consti- tution of those by whom it was drank. The leaves, being pressed and dried, were laid upon sheets of copper, where they received their colour from an article known by the name of Dutch pink. The article used in producing the appearance of the fine green bloom, observable on the China tea, was, however, decidedly a dead poison ! He al- luded to verdigrise, which was added to complete the operation. This was the case COUNTERFEIT TEA. 227 which he had to bring before the jury; and hence it would appear, that, at the moment they were supposing they were drinking a pleasant and nutritious beverage, they were, in fact, in all probability, drinking the pro* duce of the hedges round the metropolis, prepared for the purposes of deception in the most noxious manner. T. Jones deposed, that he knew Proctor, and was employed by him at the latter end of April, 1817, to gather black and white thorn leaves. Sloe leaves were the black thorn. Witness also knew John Malins, the son of William Malins, a coffee-roaster; he did not at first know the purpose for which the leaves were gathered, but afterwards learnt they were to make imitation tea. Witness did not gather more than one hun- dred and a half weight of these leaves ; but L6 228 COUNTERFEIT TEA. he employed another person, of the name of Bagster, to gather them. He had two- pence per pound for them. They were first boiled, and the water squeezed from them in a press. They were afterwards placed over a slow fire upon sheets of copper to dry ; while on the copper they were rubbed with the hand to curl them. At the time of boiling there was a little verdiyrise put into the water (this applied to green tea only). After the leaves were dried, they were sifted, to separate the thorns and stalks. More verdigrise and some Dutch pink were then added . The verdigrise gave the leaves that green bloom observable on genuine tea. The black tea went through a similar course as the green, except the application of Dutch pink: a little verdigrise was put in COUNTERFEIT TEA. 229 the boiling-, and to this was added a small quantity of logwood to dye it, and thus the manufacture was complete. John Bagster proved that he had been employed by Malins and Proctor to gather sloe and white-thorn leaves : they were taken to Jones's house, and from thence to Malin's coffee-roasting premises* witness received two-pence per pound for them; he saw the manufacturing going on, but did not know much about it: witness saw the leaves on sheets of copper, in Goldstone-street. This was the case for the Crown. Ver- dict for the Crown, 840. 230 COUNTERFEIT TEA. List of Grocers prosecuted and convicted in the year 1818, for adulterating Tea. Mr. Rhodes the defendant was convicted in the penalty of 600. Mr. Palmer the defendant was convicted in the penalty of 840. Mr. Prentice the defendant submitted to a verdict for the Crown. Mr. Holmes the defendant submitted to a verdict for the Crown. Mr. Orkney verdict for the Crown. Mr. Grey verdict for the Crown Penalties 120. Messrs. Gilbert and Powel verdict for the Crown Penalties 140. Mr. Clarke verdict for the Crown. Mr. Horner verdict for the Crown Penal- ties 210. Mr. Dowling verdict for the Crown. Penal- ties 70. Mr. Bellis verdict for the Crown Penalties 70. COUNTERFEIT TEA. 231 METHOD OF DETECTING THE ADUL- TERATIONS OF TEA. THE adulterations of tea may be evinced by comparing the botanical characters of the leaves of the two respective trees, arid by submitting- them to the action of a few che- mical tests. The shape of the tea-Jeaf is slender and narrow, as shown in this sketch, the edges arc deeply serrated, and the end or extre- mity is acutely pointed. The texture of the 232 COUNTERFEIT TEA. leaf is very delicate, its surface smooth and glossy, and its colour is a lively pale green. The sloe-leaf (and also the white-thorn leaf,) as shewn in this sketch, is more rounded, and the leaf is obtusely pointed. The serratures or jags on the edges are not so deep, the surface of the leaf is more un- even, the texture not so delicate, and the colour is a dark olive green. These characters of course can be ob- served only after the dried leaves have been suffered to macerate in water for about twenty-four hours. The leaves of some sorts of tea may differ in size, but the shape is the same in all of COUNTERFEIT TEA. 233 them ; because all the different kinds of tea imported from China are the produce of one species of plant, and the difference between the green and souchong, or black tea, de- pends chiefly upon the climate, soil, culture, age, and mode of drying the leaves. Our ladies are our tea-makers ; let them study the leaf as well as the liquor ; let them become familiar with both vegetables, with their forms, colours, flavours, and scents; let us drink our tea upon the responsibility of our wives, daughters, and sisters, and not upon that of our grocers. Let every female distinguish tea-leaves from sloe-leaves, as well as if she had served an apprenticeship in the ware-house in Leadenhall-street. Let them wet and spread out the leaves which come from their grocers, and let them be compared with our figures. 234 COUNTERFEIT TEA. The examination of twenty-seven sam- ples of imitation tea of different qualities, from the most costly, to the most common, which it fell to my lot to undertake, induces me to point out the following chemical marks of sophistications, as the most simple and expeditious. Spurious black tea, slightly moistened, when rubbed on a sheet of white paper, immediately produces ablueish-black stain; and speedily affords, when thrown into cold water, a blueish black tincture, which instantly becomes reddened by letting fall into it a drop or two of sulphuric acid. Two ounces of the suspected leaves should be infused in half-a-pint of cold, soft water, and suffered to stand for about three hours. Genuine tea produces an amber-coloured in- fusion, which does not become reddened by sulphuric acid. COUNTERFEIT TEA, 235 All the samples of spurious green tea (nineteen in number) which I have examined, were coloured with carbonate of copper (a poisonous substance), and not by means of verdigrise or copperas*. The latter sub- stances would instantly turn the tea black ; because both these metallic salts being soluble in water, are acted on by the astringent matter of the leaves, whether ge- nuine or spurious, and convert the infusion into ink. Tea, rendered poisonous by carbonate of copper, speedily imparts to liquid ammonia a fine sapphire blue tinge. It is only ne- * Mr. Twining, an eminent tea-merchant, asserts, that " the leaves of spurious tea are boiled in a copper,, with copperas and sheep's dung." See Encyclop. Britan. vol. xviii. p. 331, 1797. See alo the History of the Tea Plant, p. 48. ; and p. 22 and 228 of this Treatise. 236 COUNTERFEIT TEA. cessary to shake up in a stopped vial, for a few minutes, a tea-spoonful of the suspected leaves, with about two table-spoonsful of li- quid ammonia, diluted with half its bulk of water. The supernatant liquid will exhibit a fine blue colour, if the minutest quantity of copper be present. Green tea, coloured with carbonate of cop- per, when thrown into water impregnated with sulphuretted hydrogen gas, immedi- ately acquires a black colour. Genuine green tea suffers no change from the action of these tests. The presence of copper may be further rendered obvious, by mixing one part of the suspected tea-leaves, reduced to powder, with two or three parts of nitrate of potash, (or with two parts of chlorate of potash,) and projecting this mixture by small portions a,t COUNTERFEIT TEA. 2-37 a time, into a platina, or porcelain-ware cru- cible, kept red-hot in a coal fire ; the whole vegetable matter of the tea leaves will thus become destroyed, and the oxid of copper left behind, in combination with the potash, of the nitrate of potash (or salt petre), or with the muriate of potash, if chlorate of potash has been employed. If water, acidulated with nitric acid, be then poured into the crucible to dissolve the mass, the presence of the copper may be rendered manifest by adding to the solution, liquid ammonia, in such quantity that the pungent odour of it predominates- <0ttttterfett Coffee. THE fraud of counterfeiting ground cof- fee by means of pigeons' beans and pease, is another subject which, ^not long ago, ar- rested the attention of the public : and from the numerous convictions of grocers prosecuted for the offence, it is evident that this practice has been carried on for a long time, and to a considerable extent. The following statement exhibits some of the prosecutions, instituted by the Solicitor of the Excise, against persons convicted of the fraud of manufacturing spurious, and adulterating genuine, coffee* COUNTERFEIT COFFEE. 239 Alexander Brady, a grocer, prosecuted and convicted of selling sham-coffee, said, " I have sold it for twenty years." Some of the persons prosecuted by the solicitor of the Excise for this fraud, we might, at first sight, be inclined to be- lieve, were inconscious that the adulterating of genuine coffee with spurious substances w r as illegal ; but this ignorance affords no excuse, as the Act of the 43 Geo. III. cap. 129, explicitly states : " If after the first day of September, 1803, any burnt, scorched, or roasted pease, beans, or other grain, or vegetable substance or substances prepared or manufactured for the purpose of being in imitation of or in any respect to resemble coffee or cocoa, or to serve as a substitute for coffee or cocoa, or alledged or pretended by the possessor or vender 240 COUNTERFEIT COFFEE. thereof so to be, shall be made or kept for sale, or shall be offered or expesed to sale, or shall be found in the custody or posses- sion of any dealer or dealers in or seller or sellers of coffee, or if any burnt, scorched, or roasted pease, beans, or other grain, or vegetable substance or substances, not being coffee, shall be called by the preparer, manufacturer, possessor, or vender thereof, by the name of English or British coffee, or any other name of coffee, or by the name of American cocoa, or English or British cocoa, or any other name of cocoa, the same respectively shall be forfeited, together with the packages containing the same, and shall and may be seized by any officer or officers of Excise; and the person or persons pre- paring, manufacturing, or selling the same* or having the same in his, her, or their cus* COUNTERFEIT COFFEE. 241 tody or possession, or the dealer or dealers in or seller or sellers of coffee or cocoa, in whose custody the same shall be found, shall forfeit and lose the sum of one hun- dred pounds." List of Grocers prosecuted and convicted by the Solicitor of the Excise (I8l8) t for adulterating Coffee. The Jlttorney-General against Malins, This was an information filed by the At- torney-General against the defendant, charg- ing him, he being a dealer in coffee, with having in his possession a large quantity of imitation coffee, made from scorched pease and beans, resembling coffee, and intended to be sold as such, contrary to the statute of 31 242 COUNTERFEIT COFFEE, the 43d of the King, whereby he became liable to pay a fine of 100. J.Lawes deposed that he had lived servant with the defendant; he constantly roasted pease and beans, and ground them into powder. When so ground, the powder very much resembled coffee. Sometimes the sweepings of the coffee were thrown in among the pease and beans. Witness carried out this powder to several grocers in differ- ent parts of the town. Thomas Jones lived with the defendant. His occupation was roasting and grinding pease and beans. They looked, when ground, the same as coffee. Witness had seen Mr. John Malins sweep up the refuse coffee, and mix it with the pease and beans. He had taken out this mixture to grocers. J. Richardson, an excise-officer, deposed, COUNTERFEIT COFFEE. 243 that, in December 1817, he went to the pre- mises of the defendant, and there seized four sacks, five tubs, and nine pounds in paper, of a powder made to resemble coffee. The quantity ground was 1,567 pounds; it had all the appearance of coffee; and a little coffee being mixed with it, any com- mon person might be deceived. He also seized two sacks containing 279 pounds of whole pease and beans roasted. Among" the latter were some grains of coffee. The witness here produced samples of the arti- cles seized. John Lawes deposed, that the articles exhibited were such as he was in the habit of manufacturing while in Mr. Mai ins' em- ployment. The jury found a verdict for the Crown. Penalty 100. M2 244 COUNTERFEIT COFFEE. The Kiny against Chaloner. -Mr. Cha- loner, a dealer in tea and coffee, was charged on the oaths of Charles Henry Lord and John Pearson, both Excise officers, with having in his possession, on the 17th of March, nine pounds of spurious coffee, consisting' of burnt pease, beans, and gravel or sand, and a portion of coffee, and with selling some of the same ; also with having in his possession seventeen pounds of vegetable powder, and an article imitating coffee, which contained not a particle of genuine coffee. The defendant was convicted in the pe- nalty of 90. The Kiny against Peether. This was an action similar to the last.- Verdict for the Crown, penalty of 50. The Kiny ayainst Toppiny. Verdict for the Crown, penalty of 50. COUNTERFEIT COFFEE. 245 The King against Hallett. Verdict for the Crown, penalty of 50. The King against Pox. This defendant, in his defence, said, he had sold sham coffee for years ; he did it as a matter of accom- modation to the poor, who could not give a higher price \ he did not sell it for ge- nuine coffee. Commissioner of the Excise. " Then you have been defrauding the public for .many years, and injuring the revenue by your illicit practices : the poor have an equal right to be supplied with as genuine an ar- ticle as the rich," He -wag convicted in the penalty of 50. The King against Brady. One of the commissioners tasted some of the sham coffee produced by the officers, and declared M 3 246 COUNTERFEIT COFFEE. tLat it was a most infamous stuff, and unfit for human food. Defendant. " Why, I have sold it for twenty years." Commissioner. " Then you have been for twenty years acting most dishonestly, defrauding the revenue ; and the health of the poor must have suffered very much by taking such an unwholesome article. Your having dealt in this article so long aggra- vates your case ; you have for twenty years been selling burnt beans and pease for ge- nuine coffee. You are convicted in the pe- nalty of 50." ' \ The King against Bowser. This de- fendant pleaded guilty to the charge, and prayed the court to mitigate the penalty. He was convicted in the penalty of 50* COUNTERFEIT COFFEE. 247 The King against Owen*. Mr. Lawes addressed the commissioners on behalf of the defendant, in mitigation of punishment ; for he did not mean to deny the offence. His client was a very young man, and had been most unfortunate in business. He was not aware until lately of the existence of any law by which it could be punished. He was convicted in the penalty of 50 for each quantity of sham coffee. . Mr. Greely and Mr. Dando were fined 20 each ; and Mr. Hirling and Mr. Terry were fined 90 each, for selling spurious coffee f. The adulteration of ground coffee, with pease and beans, is beyond the reach of * Times, July 10, 1818. t Times, June 6, 1818. M4 248 COUNTERFEIT COFFEE. chemical analysis ; but it may, perhaps, not be amiss on this occasion to give to our readers a piece of advice given by a retired grocer to a friend, at no distant period : " Never, my good fellow," he said, " pur- chase from a grocer any thing which passes through his mill. You know not what you g*et instead of the article yon expect to receive coffee, pepper, and all-spice, are all mixed with substances which de- tract from their own natural qualities." Persons keeping mills of their own can at all times prevent these impositions. ADULTERATION , ana BY the Excise laws at present existing in this country, the various degrees of strength of brandy, rum, arrack, gin, whis- key, and other spirituous liquors, chiefly composed of little else than spirit of wine, are determined by the quantity of alcohol of a given specific gravity contained in the spirituous liquor of a supposed unknown strength. The great public importance of this subject in this country, where the con- sumption of spirituous liquors adds a vast M 5 250 ADULTERATION OF sum to the public revenue, has been the means of instituting 1 many very interesting- series of experiments on this subject. The instrument used for that purpose by the Customs and officers of Excise, is called Sikes' s hydrometer*, which has now su- perseded the instrument called Clark's hydrometer, heretofore in use. The specific gravity or strength of the legal standard spirit of the Excise, is tech- nically called proof, or proof spirit. " This liquor (not being spirit sweetened, or having any ingredient dissolved in it, to defeat the strength thereof), at the temperature of * George III. c. xxviii, May 1818. " An Act for establishing the use of Sikes's hydrometer in ascer- taining the strength of spirit, instead of Clark's hy- drometer/' first established by 56 Geo. III. c. 3, 110, and amended by Geo, III. c. 28. SPIRITUOUS LIQUORS. 251 51 Faht. weighs exactly fth parts of an equal measure of distilled water ;" and with this spirit the strength of all other spiritu- ous liquors are compared according to law. The strength of brandy, rum, arrack, gin, or other spirituous liquors, weaker than proof, or below proof, is estimated by the quantity of water which would be necessary to bring the spirit up to proof. The hydrometer is calculated to shew the percentage of strength above or below proof, as the case may be, of the spirit submitted to trial. The stern of the instrument is graduated, and so sub-divided, as to meet every variety in the strength of the liquor to be examined, which may fall between the weights (nine in number), used with the in- strument; the divisions and sub-divisions on the hydrometer, which remain above the sur- M 6 252 ADULTERATION OF face of the liquor in which the instrument is made to swim, being added to the number upon the weight used, and together forming the indication. But as the difference of temperature af- fects materially the specific gravity of spi- rituous liquors, a thermometer, and tables of the concentration of strength as denoted by the hydrometer, are used in the appli- cation of the instrument. The officer of the Excise has therefore only to turn to the tables opposite the indication, and imme- diately under the temperature he finds the percentage of the strength of the liquor. The quantity of proof spirit in any quan- tity of spirituous liquor of any other strength, is found by multiplying the quantity of spirit by its percentage of strength, the decimal point in the percentage being first renloved two places to the left hand, and deducting SPIRITUOUS LIQUORS. 253 the product, if the spirit be below proof, from ; or adding it, if above proof, to the cjuantity of liquor. For Example, 125 gallons. Weight used.. 50. Subdivision shewn by the hydrometer... 1.2 51.2 Temperature by the thermometer 68 Opposite 51.2 on the column of indica- tions, and under the 68th degree of tem- perature, is 8.4 per cent, above proof; had it been below proof, the 10.500 must have been deducted, and would have left 1142 of proof spirit, contained in the 125 gallons of the liquor. Brandy and rum is seizable^if sold by> or found in the possession of, the dealer, un- less it possesses a certain strength*. The following are the words of the Act : * Seventeen per cent below proof, according to Sikes's hydrometer* 254 ADULTERATION OF " No distiller, rectifier*, compounder or dealer, shall serve or send out any foreign spirits, of a lower strength than that of 1 in 6 under hydrometer prooff, nor have in his possession any foreign spirits mixed to- gether, except shrub, cherry or raspberry brandy, of lower strength than as aforesaid, upon pain of such spirits being forfeited ; and such spirits, with the casks and vessels containing the same, may be seized by any officer of Excise.' 5 We have, therefore, a ready check against the frauds of the dishonest dealers in spi- rituous liquors. If the spirit merchant engage to deliver a liquor of a certain * 30 Geo. III. c. 37, sec. 31. t According to Clarke's hydrometer, or 17 per cent, below proof, according to Sikes's hydrometer. SPIRITUOUS LIQUORS. 255 strength, the hydrometer is by far the most easy and expeditious check that can be adopted to guard against frauds of receiving a weaker liquor for a stronger one ; and to those individuals who are in the habit of purchasing 1 large quantities of brandy, rum, or other spirituous liquors, the hydrometer renders the greatest service. For it is by no means an uncommon occurren^, to meet with brandy, rum, and other spirituous li- quors, of a specific gravity very much below the pretended strength which the liquor ought to possess. The following advice given to his read- ers*, by the author of a Treatise on Brewing * The Distillers' Guide, by P. Jonas, 1818, p. 3; also Observations on Malted and Unmalted Corn, connected with Brewing and Distilling, p. 167 ; and Shannon on Brewing and Distilling, p. 232, 233. 256 ADULTERATION OF and Distilling-, may serve to put the unwary on their guard against some of the frauds practised by mercenary dealers. " It is a custom among retailing- distillers, which I have not taken notice of in this di- rectory, to put one third or one fourth part of proof molasses brandy, proportionably, to what rum they dispose of; which cannot be distinguished, but by an extraordinary palate, and does not at all lessen the body or proof of the goods ; but makes them about two shillings a gallon cheaper; and must be well mixed and incorporated together in your retailing- cask ; but you should keep some of the best rum, not adulterated, to please some customers, whose judgment and palate must be humoured. " When you are to draw a sample of goods to shew a person that has judgment in the SPIRITUOUS LIQUORS. 257 proof, do not draw your goods into a phial to be tasted, or make experiment of the strength thereof that way, because the proof will not hold except the goods be exceed- ingly strong; but draw the pattern of goods either into a p;lass from the cock, to run very small, or rather draw off a small quantity into a little pewter pot and pour it into your glass, extending your pot as high above the glass as you can without wasting it, which makes the goods carry a better head abundantly, than if the same goods were to be put and tried in a phial. " You must be so prudent as to make a distinction of the persons you have to deal with ; what goods you sell to gentlemen for their own use who require a great deal of attendance, and as much for time of pay- ment, you must take a considerably greater 258 ADULTERATION OF price than of others ; what goods you sell to persons where you believe there is a manifest, or at least some hazard of your money, you may safely sell for more than common profit ; what goods you sell to the poor, especially medicinally, (as many of your goods are sanative), be as compas- sionate as the cases require. " All brandies, whether French, Spanish, or English, being proof goods, will admit of one pint of liquor (water) to each gallon, to be made up and incorporated therewith in your cask, for retail, or selling smaller quantities ; and all persons that insist upon having proof goods, which not one in twenty understands, you must supply out of what goods are not so reduced, though at a higher price." Such is the advice given by Mr. Shannon. SPIRITUOUS LIQUORS. 259 The mode of judging by the taste of spi- rituous liquors is deceitful. A false strength is given to a weak liquor, by infusing in it acrid vegetable substances, or by adding to it a tincture of grains of paradise and Guinea pepper. These substances impart to weak brandy or rum, an extremely hot and pungent taste. Brandy and rum is also frequently so- phisticated with British molasses, or sugar- spirit, coloured with burnt sugar. The flavour which characterises French brandy, and which is owing to a small portion of a peculiar essential oil contained in k, is imitated by distilling- British mo- lasses spirit over wine lees ; but the spirit, prior to being distilled over wine lees, is previously deprived, in part, of its peculiar disagi-eeable flavour, by rectification over 260 ADULTERATION OF fresh-burnt charcoal and quicklime. Other brandy-merchants employ a spirit obtained from raisin wine, which is suffered to pass into an incipient acescency. The spirit thus procured partakes strongly of the flavour which is characteristic of foreign brandy. Oak saw-dust, and a spirituous tincture of raisin stones, are likewise used to impart to new brandy and rum a ripe taste, resem- bling brandy or rum long kept in oaken casks, and a somewhat oily consistence, so as to form a double froth at its surface, when strongly agitated in a vial. The co- louring substances are burnt sugar, or mo- lasses; the latter gives to imitative brandy a luscious taste, and fulness in the mouth. These properties are said to render it parti- cularly fit for the retail London customers. SPIRITUOUS LIQUOflS. 261 The following- is the method of com- pounding or making up 9 as it is technically called, brandy* for retail: Gallons. " To ten puncheons of brandy . 1081 Add flavoured raisin spirit... 118 Tincture of grains of paradise 4 Cherry laurel water 2 Spirit of Almond cakes 2 1207 " Add also 10 handfuls of oak saw-dust; and give it complexion with burnt sugar." METHOD OF DETECTING THE ADUL- TERATIONS OF BRANDY, RUM, AND MALT SPIRIT. THE false strength of brandy or rum is rendered obvious by diluting the suspected * Observations on Malted and Unmalted Corn, con- nected with Brewing and Distilling-, p, 167. 262 ADULTERATION OF liquor with water ; the acrimony of the cap- sicum, and grains of paradise, or pepper, may then be readily discovered by the taste. The adulteration of brandy with British molasses, or sugar-spirit, becomes evident by rubbing a portion of the suspectetl brandy between the palm of the hands; the spirit, as it evaporates, leaves the disagree- able flavour which is peculiar to all British spirits. Or the liqour may be deprived of its alcohol, by heating a portion in a spoon over a candle, till the vapour ceases to catch fire on the approach of a lighted taper. The residue thus obtained, of genuine French brandy, possesses a vinous odour, still resembling* the original flavour of the brandy, whilst the residue, produced from sophisticated brandy, has a peculiar disa- SPIRITUOUS LIQUORS, 263 greeable smell, resembling gin, or the breath of habitual drunkards. Arrack is coarsely imitated by adding to rum a small quantity of 'pyroligneous acid and some flowers (acid) of benzoe. The compound thus produced, however, must be pronounced a bad one. The author of a very popular Cookery Book, (the Cook's Oracle, 2d edition, p. 480,) directs two scru- ples of benzoic acid to be dissolved in one quart of rum, to make " mock arrack." MALT SPIRIT. MALT spirit, or gin, the favourite liquor of the lower order of people, which is cha- racterized by the peculiar flavour of juniper berries, over which the raw spirit is distilled, 204 ADULTERATION OF is usually obtained from a mixture of malt and barley : sometimes both molasses and corn are employed, particularly if there be a scarcity of grain. But the flavour of whis- key, which is made from barley and oats, is owing to the malted grain being dried with peat, the smoke of which gives it the charac- teristic taste. The malt distiller is not allowed to fur- nish, under a heavy penalty, any crude or raw spirit to the rectiiier or manufacturer of gin, of a greater strength than seven per cent over proof. The rectifier who receives the spirit from the inalt distiller is not al- lowed, under a certain penalty, to send out the spirit to his customers greater than of a certain strength, as is obvious from the fol- lowing words of the Act : " No rectifier or compounder shall sell or SPIRITUOUS LIQUORS. 265 send out any British brandy, British rectified spirits, British compounds, or other British spirits, of greater strength than that of one in five under hydrometer proof (Clark's hy- drometer, equal to 22 per cent, below proof by Sikes's hydrometer) : and if he shall sell and send out any such spirits of a greater strength than that of one in five under hy- drometer proof, such spirits, with the casks or vessels containing the same, shall be for- feited, and may be seized by any officer of Excise ; and he shall forfeit treble the value of such spirit, or 50 at the election of the King's Attorney-General, or the person who shall sue for the same ; the single value of such spirits to be estimated at the highest London price." (30 Geo. III. c. 37, sec. 6.) If we examine gin, as retailed, we shall soon be convinced that it is a custom, pretty N 266 ADULTERATION OF prevalent amongst dealers, to weaken this li- quor considerably with water, and to sweet- en it with sugar. This fraud may readily be detected by evaporating a quantity of the liquor in a table-spoon over a candle, to dryness ; the sugar will thus be rendered obvious, in the form of a gum-like substance, when the spirit is volatilised. One hundred and twenty gallons of ge- nuine gin, as obtained from the wholesale manufactories, are usually made up by frau- dulent retailers into a saleable commodity, with fourteen gallons of water and twenty- six pounds of sugar. Now this dilution of the liquor produces a turbidness; because the oil of juniper and other flavouring sub- stances which the spirit holds in solution, become precipitated by virtue of the water, and thus cause the liquor to assume an opa- SPIRITUOUS LIQUORS, 267 line colour: and the spirit thus weakened cannot readily be rendered clear again by subsidence. Several expedients are had recourse to, to clarify the liquor in an expe- ditious manner ; some of which are hatm- less; others are criminal, because they ren- der the liquor poisonous. One of the methods, which is innocent, consists in adding to the weakened liquor, first, a port ion of alum dissolved in water, and then a solution of sub-carbonate of pot- ash. The whole is stirred together, and left undisturbed for twenty-four hours. The precipitated alumine thus produced from the alum, by virtue of the sub-carbonate of potash, acts as a strainer upon the milky liquor, and carries down with it the finely divided oily matter which produces the blue colour of the diluted liquor. Roach, or Ro- N2 268 ADULTERATION OF man alum, is also employed, without any other addition for clarifying- spirituous li- quors. " To reduce unsweetened Gin*. " A tun of fine gin 352 gallons " Water... 36 Ditto, Bourdeaux, ditto ditto 54,50 Ditto, Cette 53,00 Ditto, Naples, average of three samples... 53,25 Ditto, Spanish, average of 6 samples 52,28 Rum 53,68 Ditto, Leeward, average of 9 samples ... 53,00 Scotch Whiskey, average of 6 samples.... 53,50 Irish Ditto, average of 4 samples 54,25 Arrack, Batavia 49,50 Dutch Geneva 52,25 Gin, Hodges's (own experiment), 3 sam- 7 pies, procured from retail dealers S Ditto, (ditto) procured from the maim- j facturer ? * Repository of Arts, p. 350, Dec. 1819. N 6 SEVERAL instances have come under my notice in which Gloucester cheese has been contaminated with red lead, and has pro- duced serious consequences on being taken into the stomach* In one poisonous sample which it fell to my lot to investigate, the evil had been caused by the sophistication of the anotto, employed for colouring cheese. This substance was found to contain a por- tion of red lead ; a method of sophistication which has lately been confirmed by the fol- lowing fact, communicated to the public by Mr. J. W. Wright> of Cambridge, and co- POISONOUS CHEESE. 277 pied from the Repository of Arts, vol. viiu No. 47, p. 262. " Your readers ought here to be told, that several instances are on record, that Glou- cester and other cheeses have been found contaminated with red lead, and that this contamination has produced serious conse- quences. In the instance now alluded to, rnd probably in all other cases, the delete- rious mixture had been caused ignorantly, by the adulteration of the anotto employed for colouring- the cheese. This substance, in the instance I shall relate, was found to contain a portion of red lead ; a species of adulteration which subsequent experiments have shewn to be by no means uncommon. Before I proceed further to trace this fraud to its source, I shall briefly relate the cir- 278 POISONOUS CHEESE. cumstknce which gave rise to its detec- tion. " A gentleman, who had occasion to re- side for some time in a city in the West of England, was one night seized with a dis- tressing butindescribeable pain in the region of the abdomen and of the stomach, accom- panied with a feeling of tension, which oc- casioned much restlessness, anxiety, and re- pugnance to food. He began to apprehend the access of an inflammatory disorder ; but in twenty-four hours the symptoms entirely subsided. In four days afterwards he ex- perienced an attack precisely similar i and he then recollected* that having, on both oc- casions, arrived from the country late in the evening, he had ordered a plate of toasted Gloucester cheese, of which he had partaken POISONOUS CHEESE. 279 heartily ; a dish which, when at home, re- gularly served him for supper. He attri- buted his illness to the cheese. The cir- cumstance was mentioned to the mistress of the inn, who expressed great surprise, as the cheese in question was not purchased from a country dealer, but from a highly respectable shop in London. He, therefore, ascribed the before-mentioned effects to some peculiarity in his constitution, A few days afterwards he partook of the same cheese ; and he had scarcely retired to rest, when a most violent colic seized him, which lasted the whole night and part of the en- suing day. The cook was now directed henceforth not to serve up any toasted cheese, and he never again experienced these distressing symptoms. Whilst this POISONOUS CHEESE. matter was a subject of conversation in the house, a servant-maid mentioned that a kitten had been violently sick after having eaten the rind cut off from the cheese pre- pared for the gentleman's supper. The landlady, in consequence of this statement, ordered the cheese to be examined by a chemist in the vicinity^ who returned for answer, that the cheese was contaminated with lead ! So unexpected an answer ar- rested general attention, and more particu- larly as the suspected cheese had been served up for several other customers. " Application was therefore made by the London dealer to the farmer who manufac- tured the cheese : he declared that he had bought the anotto of a mercantile traveller, who had supplied him and his neighbours POISONOUS CHEESE. 281 for years with that commodity, without giv- ing occasion to a single complaint. On sub- sequent inquiries, through a circuitous chan- nel, unnecessary to be detailed here at length, on the part of the manufacturer of the cheese, it was found, that as the sup- plies of anotto had been defective and of inferior quality, recourse had been had to the expedient of colouring the commodity with vermillion. Even this admixture could **~t be Considered dlt^ r * nn - s - But on fur* ther application being made to the druggist who sold the article, the answer was, that the vermillion had been mixed with a por- tion of red lead; and the deception was held to be perfectly innocent, as frequently prac- tised on the supposition, that the vermillion would be used only as a pigment for house-* 282 POISONOUS CHEESE. painting. Thus the druggist sold his ver- rnillion, in the regular way of trade, adulte- rated with red lead, to increase his profit, without any suspicion of the use to which it would be applied ; and the purchaser who adulterated the anotto, presuming that the vermillion was genuine, had no hesitation in heightening the colour of his spurious anotto with so harmless an adjunct. Thus, through the circuitous and diversified operations of Commerce, a portion of deadly poison ma^ find admission into the necessaries of life, in a way which can attach no criminality to the parties through whose hands it has suc- cessively passed." This dangerous sophistication may be de- tected by macerating a portion of the sus- pected cheese in water impregnated with POISONOUS CHEESE, 283 sulphuretted hydrogen, acidulated with muriatic acid ; which will instantly cause the cheese to assume a brown or black co- lour, if the minutest portion of lead be pre- sent. Counterfeit BLACK PEPPER is the fruit of a shrubby, creeping plant, which grows wild in the East Indies, and is cultivated, with much advan- tage, for the sake of its berries, in Java and Malabar. The berries are gathered before they are ripe, and are dried in the sun. They becoire black and corrugated on the surface. That factitious pepper-corns have of late been detected mixed with genuine pepper, is a fact sufficiently known*. Such an * Thompson's Annals of Chemistry, 1816 ; a^o Re- pository of Arts, vol. i.1816, p. 11. COUNTERFEIT PEPPER. 285 adulteration may prove, in many instances of household economy, exceedingly vexa- tious and prejudicial to those who ignorantly make use of the spurious article. I have examined large packages of both black and white pepper, by order of the Excise, and have found them to contain about 16 per cent, of this artificial compound. The spu- rious pepper is made of oil cakes (the resi- due of lintseed, from which the oil has been pressed), common clay, and a portion of Cayenne pepper, formed in a mass, and gra- nulated by being first pressed through a sieve, and then rolled in a cask. The mode of detecting the fraud is easy. It is only necessary to throw a sample of the sus- pected pepper into a bowl of water ; the ar- tificial pepper- corns fall to powder, whilst the true pepper remains whole. 286 COUNTERFEIT PEPPER. Ground pepper is very often sophisticated by adding to a portion of genuine pepper a quantity of pepper dust, or the sweepings from the pepper warehouses, mixed with a little Cayenne pepper. The sweepings are known, and purchased in the market, under the name of P. D. signifying pepper dust. An inferior sort of this vile refuse, or the sweepings of P. D. is distinguished among venders by the abbreviation of D. P. D. de- noting, dust (dirt) of pepper dust. This adulteration of pepper, and the mak- ing and selling commodities in imitation of pepper, are prohibited, under a severe pe- nalty. The following are the words of the Act. (Geo. III. c. 53, sec. 21, 1819.) " And whereas commodities made in imi- tation of pepper have of late been sold and found in the possession of various dealers COUNTERFEIT PEPPER. 287 in pepper, and other persons in Great Bri- tain ; be it therefore enacted, that from and after the said 5th day of July 1819, if any commodity or substance shall be prepared by any person in imitation of pepper, shall be mixed with pepper, or sold or delivered as and for, or as a substitute for pepper, or if any such commodity or substance alone or mixed, shall be kept for sale, sold, or deli- vered, or shall be offered or exposed to sale, or shall be in custody or possession of any dealer or seller of pepper, the same, toge- ther with all pepper with which the same shall be mixed, shall be forfeited, with the packages containing the same, and shall and may be seized by any officer of excise ; and the person preparing, manufacturing, mixing as aforesaid, selling, exposing to sale, or delivering the same, or having the 288 COUNTERFEIT PEPPER- same in his, her, or their custody or posses- sion, shall forfeit the sum of one hundred pounds." The following prosecutions and convic- tions have lately come before the public : Mr, Baker* was charged with selling an injurious mixture of rape and mustard seed, called P. D. for pepper. The defendant pleaded ignorance, and he was ordered to pay a fine of 40s. James Hemmett, a grocer, in Kent-street, in the Borough, was charged with a similar offence. Skinner, an officer, deposed, that on the 13th of July last he bought a quarter of a pound of pepper at the shop of the defen- dant ; he afterwards examined it, and found it to contain an injurious mixture. * Morning Chronicle, January 6th and 19th, 1820. COUNTERFEIT PEPPER. 289 James Story, the Examining Officer, said, that there might be a little pepper in it, but the greatest part was P. D. and that of the most deleterious quality. The defendant pleaded ignorance of hav- ing it in his possession, but did not produce any witnesses. He was sentenced to pay a fine of 45s. Mr. Bowling, a grocer, was charged with a similar offence. The defendant pleaded that he had before been convicted by the Court, and trusted that would be a sufficient punishment. The Court thought this rather an aggra- vation, and again convicted him in the sum of 10. Mr. Powey* was charged with selling * Times, January 5th, 1820. O 290 COUNTERFEIT PEPPER. pepper, containing an injurious mixture, with intent to defraud the revenue. As this ap- peared to be part of an oiien^e for which the defendant had been fined 5, the penalty was mitigated to 10s, James Beard w,as charged with selling" pepper containing a mixture called, in the trade, P. D which was nothing more than mustard and rape seed ground to- gether, and sold for peppejr dust. The Court expressed its determination to pro- tect the public from such frauds, and fined the defendant .5. WHITE PEPPER. THE common white pepper is factitious, being prepared from the black pepper in the following manner : - -The pepper is first COUNTERFEIT PEPPER 291 steeped in sea water and urine, and ex- posed to the heat of the sun for several days, till the rind or outer bark loosens ; it is then taken out of the steep, and, when dry, it is rubbed with the hand till the rind falls off. The white fruit is then dried, and the remains of the rind blown away like chaff. A great deal of the peculiar flavour and pungent hot taste of the pepper is taken off by this process. White pepper is al- ways inferior in flavour and quality to black pepper. However, there is a sort of native white pepper, produced on a species of the pepper plant, which is much better than the facti- tious, and indeed little inferior to the com- mon black, pepper. o 2 CAYENNE PEPPER is an indiscriminate mixture of the powder of the dried pods of many species of capsicum, but especially of the capsicum frutescens* or bird pepper, which is the hottest of all. This annual plant, a native of South Ame- rica, is cultivated in large quantities in our West India islands, and even frequently in our gardenSj for the beauty of its pods, which are long, pointed and pendulous, at first of a green colour, and, when ripe, of a bright orange red. They are filled with a dry loose pulp, and contain many small, flat, kidney- COUNTERFEIT PEPPER. 293 shaped seeds. The taste of capsicum is extremely pungent and acrimonious, setting the mouth, as it were, on fire. The principle on which its pungency de- pends, is soluble in water and in alcohol. It is sometimes adulterated with red lead, to prevent its becoming bleached on expo- sure to light. This fraud may be readily de- tected by shaking up part of it in a stopped vial containing water impregnated with sul- phuretted hydrogen gas, which will cause it speedily to assume a dark muddy black colour. Or the vegetable matter of the pepper may be destroyed, by throwing a mixture of one part of the suspected pepper and three of nitrate of potash (or two of chlorate of potash) into a red-hot crucible, in small quantities at a time. The mass left behind may then be digested in weak nitric o 3 294 COUNTERFEIT PEPPER. acid, and the solution assayed for lead by water impregnated with sulphuretted hy- drogen. " We advise those who are fond of Cay- enne not to think it too much trouble to make it of English Chillies there is no other way of being sure it is genuine. They will obtain a pepper of much finer fla- vour, without half the heat of the foreign ; and a hundred chillies will produce two 6unces. The flavour of the chillies is very superior to that of the capsicums. Put them in a warm place to dry; then rub them in a mortar, as fin as possible, and keep them in a well stopped bottle*." * The Cook's Oracle, 12mo. 1S19. poisonous VEGETABLE substances, preserved in tlfe state called pickles, by means of the anti- septic power of vinegar, whose sale fre- quently depends greatly upon a fine lively green colour] knd the consumption of ^vhich, by sea-faring people in particular, is prodigious, are sometimes intentionally coloured by means of copper. Gerkins, French beans, samphires, the green pods of capsicum, and many other pickled vege- table substances, oftener than is perhaps expected, are met with impregnated with this metal* Numerous fatal consequences o 4 296 POISONOUS PICKLES. are known to have ensued from the use of these stimulants of the palate, to which the fresh and pleasing hue has been imparted according to the deadly formula laid down in some modern cookery books ; such as boiling the pickles with half-pence, or suf- fering them to stand for a considerable period in brazen vessels. Dr. Percival [Medical Transactions, vol. iv. p. 80] has given an account of " a young lady who amused herself, while her hair was dressing, with eating samphire pickles impregnated with copper. She soon complained of pain in the stomach; and, in five days, vomiting commenced, which was incessant for two days. After this, her sto- mach became prodigiously distended ; and, in nine days after eating the pickle, death relieved her from her suffering." POISONOUS PICKLES. 297 Among many recipes which modern au- thors of cookery books have given for imparting a green colour to pickles, the following are particularly deserving of censure; and it is to be Loped that they will be suppressed in future editions of the works. " To Pickle Gerkins.* Boil the vinegar in a bell-metal or copper pot ; pour it boil- ing hot on your cucumbers." " To make greening '[.-'Take a bit of verdigrise, the bigness of ahazle-nut, finely powdered; half-a-pint of distilled vinegar, and a bit of alum powder, with a little bay salt. Put all in a bottle, shake it, and let * The Ladies' Library, vol. ii. p. 203. t Modern Cookery, or the English Housewife^ 2d edition, p. 94. OQ 298 POISONOUS PICKLES* it stand till clear. Put a small tea-spoon- ful into codlings, or whatever you wish to green." Mr. E. Raffeld* directs, " to render pickles green, boil them with halfpence, or allow them to stand for twenty-four hours in copper or brass pans." To detect the presence of copper, it is only necessary to mince the pickles, and to pour liquid ammonia, diluted with an equal bulk of water, over them in a stopped phial : if the pickles contain the minutest quantity of copper, the ammonia assumes a blue colour. * The English Housekeeper, p. 352, 354-. This book has run through 18 editions. gGrotttvatfdtt of VINEGAR, as prepared in this country, from malt, should be of a pale brown co- lour, perfectly transparent, of a pleasant, somewhat pungent, acid taste, and fragrant odour, but without any acrimony. From the mucilaginous impurities which malt vinegar always contains, it is apt, on ex- posure to air, to become turbid arid ropy, and at last vapid. The inconvenience is best obviated by keeping the vinegar; in bottles completely filled arid well corked ; and it is of advantage to boil it in the bottles a few minutes before they are corked. 06 300 ADULTERATION OF VINEGAR. Vinegar is sometimes largely adulterated with sulphuric acid, to give it more acidity. The presence of this acid is detected, if, on the addition of a solution of acetate of ba- ry tes, a white precipitate is formed, which is insoluble in nitric acid, after having been made red-hot in the fire. (See p. 208.) With the same intention, of making the vinegar appear stronger, different acrid vegetable- substances are infused in it. This fraud is difficult of detection ; but when tasted with attention, the pungency of such vinegar will be found to depend rather on acrimony than acidity. Distilled vinegar, which is employed for various purposes of domestic economy, is frequently distilled, not in glass, as it ought to be, but in common stills with a ADULTERATION OF VINEGAR. 301 pewter pipe, whence it cannot fail to ac- quire a metallic impregnation, One ounce, by measure, should dissolve at least thirteen grains of white marble. It should not form a precipitate on the addition of a solution of acetate of barytes, or of water saturated with sulphuretted hydrogen. The former circumstance shews that it is adulterated with sulphuric acid ; and the latter indicates a metal. The metallic impregnation is best ren- dered obvious by sulphuretted hydrogen, in the manner stated, page 87. The distilled vinegar of commerce usually contains tin, and not lead, as has been asserted* fttoutterotion of CREAM is often adulterated with rice pow- der or arrow-root. The former is frequently employed for that purpose by pastry-cooks, in fabricating creams and custards, for tarts, and other kinds of pastry. The latter is often used in the London dairies. Arrow- root is preferable to rice powder ; for, when converted with milk into a thick mucilage by a gentle ebullition, it imparts to cream, previously diluted with milk, a consistence and apparent richness, by no means unpa- ADULTERATION OF CREAM. 303 latable, without materially impairing the taste of the cream. The arrow-root powder is mixed up with a small quantity of cold skimmed milk into a perfect, smooth, uniform mixture ; more milk is then added, and the whole boiled for a few minutes, to effect the solution of the arrow-root : this compound, when per- fectly cold, is mixed up with the cream. From 220 to 230 grains (or three large tea- spoonsful) of arrow-root are added to one pint of milk ; and one part of this solution is mixed with three of cream. It is scarcely necessary to state, that this sophistication is innocuous. The fraud may be detected by adding to a teaspoonful of the sophisticated cream a few drops of a solution of jodine in spirit 304 ADULTERATION OP CREAM. of wine, which instantly produces with it a dark blue colour. Genuine cream acquires^ by the addition of this test, a faint yellow tinge. The common notion, of milk being adul- terated with chalk, or whiting, is unfounded. Such an adulteration is not practicable, without being immediately detected ; be- cause the smallest quantity of whiting, or chalk, speedily separates, and falls to the bottom. I have been frequently called upon to examine samples of milk, supposed to be sophisticated with whiting-, but a chemical examination of the milk always proved the contrary. That a liberal quantity of water is often added to the London milk, admits of no doubt. ' IN the preparation of sugar plums, com- fits, and other kinds of confectionery, espe- cially those sweetmeats of inferior qua- lity frequently exposed to sale in the open streets, for the allurement of children, the grossest abuses are committed. The white comfits, called sugar pease, are chiefly composed of a mixture of sugar^ starch, and Cornish clay (a species of very white pipe-clay); and the red sugar drops are usually coloured with the inferior kind of vermillion. This pigment is generally adul- terated with red lead. Other kinds of sweet- 306 POISONOUS CONFECTIONERY. meats are sometimes rendered poisonous by being coloured with preparations of copper. The following account of Mr. Miles* may be advanced in proof of this statement: " Some time ago, while residing in the house of a confectioner, I noticed the co- louring of the green fancy sweetmeats being done by dissolving sap-green in brandy. Now sap-green itself, as prepared from the juice of the buckthorn berries, is no doubt a harmless substance; but the manufactu- rers of ; this colour have for many years past produced various tints, some extremely bright, -which there can be no doubt are effected by adding preparations of copper. " The sweetmeats which accompany these lines you will find exhibit vestiges * Philosoph. Mag. No. 25$, vol. M. 1819. p. 317. POISONOUS CONFECTIONERY. 307 of being contaminated with copper. The practice of colouring these articles of con- fectionery should, therefore, be banished: the proprietors of which are not aware of the deleterious quality of the substances employed by them*" , The foreign conserves, such as small green limes, citrons, hop-tops, plums, an* gelica roots, &c. imported into this country, and usually sold in round chip boxes, are frequently impregnated with copper. The adulteration of confitures by means of clay, may be detected by simply dis- solving the comfits in a large quantity of boiling water. The clay, after suffering the mixture to stand undisturbed for a few days, will fall to the bottom of the vessel ; and on decanting the clear fluid, and suffer- ing the sediment to become dry gradually, it 308 POISONOUS CONFECTIONERY. may be obtained in a separate state. If the adulteration has been effected by means of clay, the obtained precipitate, on exposure to a red heat in the bowl of a common tobacco-pipe, acquires a brick hardness. The presence of copper may be detected by pouring over the comfits liquid ammonia, which speedily acquires a blue colour, if this metal be present. The presence of lead is rendered obvious by water impreg- nated with sulphuretted hydrogen, acidu- lated with muriatic acid (see p. 87), which assumes a dark brown or black colour, if lead be present. , - miting was at length produced. After the operation of the emetic, he expressed him- self generally better, but still continued drowsy. In the evening Mr. Glen found him doing well." The following case is recorded in the Me- dical Transactions, vol. ii. " A middle-aged man having gathered what he called champignons, they were stewed, and eaten by himself and his wife ; their child also, about four years old, ate a little of them, and the sippets of bread which POISONOUS MUSHROOMS. were put into the liquor. Within five mi- nutes after eating them, the man began to stare in an unusual manner, and was unable to shut his eyes. All objects appeared to him coloured with a variety of colours. He felt a palpitation in what he called his sto- mach ; and was so giddy that he could hardly stand. He seemed to himself swelled all over his body. He hardly knew what he did or said ; and sometimes was unable to speak at all. These symptoms continued in a greater or less degree for twenty-four hours; after which, he felt little or no dis- order. Soon after he perceived himself ill, one scruple of white vitriol was given him, and repeated two or three times, with which he vomited plentifully. " The woman, aged thirty-nine, felt all the same symptoms, but in a higher degree. She totally lost her voice and her senses, POISONOUS MUSHROOMS. 337 and was either stupid, or so furious that it was necessary she should be held. The white vitriol was offered to her, of which she was capable of taking but very little; how- ever, after four or five hours, she was much recovered: but she continued many days far from being well, and from enjoying her former health and strength. She frequently fainted for the first week after; and there was, during a month longer, an uneasy sense of heat and weight in her breast, stomach, and bowels, with great flatulence. Her head was, at first waking, much confused ; and she often experienced palpitations, tremblings, and other hysteric affections; to $11 which she had ever before been a stranger, " The child tMf some convulsive agita- tions of his arms, but was otherwise little Q 338 POISONOUS MUSHROOMS. affected. He was capable of taking half a scruple of ipecacuanha, with which he vo- mited, and was soon perfectly recovered." MUSHROOM CATSUP. THE edible mushroom is the basis of the sauce called mushroom catsup ; a great pro- portion of which is prepared by gardeners who grow the fungi. The mushrooms em- ployed for preparing this sauce are gene- rally those which have not found a ready sale in the market, and are in a putrified state ; for no vegetable substance is liable to so rapid a spontaneous decomposition as mushrooms. In a few days after they have been gathered from the dung-bed on which they grow, they become the habitation of myriads of in&rcts ; and, if even the fresh mushroom be attentively examined, it will frequently be found to swarm with life. of ALTHOUGH we have already made some remarks on the sophistication of milk (page 302), the following additional statement may not be deemed superfluous. The most correct method of ascertaining the different qualities of milk, or the rela- tive richness of different kinds of milk, is by means of a simple instrument, lately constructed at the suggestions of Sir Joseph Banks. It consists of any number of cylindrical glass tubes of the same internal diameter, which is generally about half an inch, or J Q2 340 ADULTERATION OF MILK. of an inch ; and about 10 or 12 inches long. They are closed at one end, and open, and a little flanched at the other, like the test tubes used by chemists, and are mounted on a stand in the same manner. At the distance of about 10 inches from the bottom of each tube is a line or mark, with 0, or zero, placed opposite it, and from this point the tube is graduated into tenths of an inch, and num- bered downwards for 2 or 3 inches, so that each division is iJo^ 1 of the capacity of the tube. If several of the tubes are filled with milk at the same time, and placed at the same temperature, the cake of cream will form at the top, and its quantity or percentage will be read off by mere inspection. In this way experiments may be made on the relative quantities of cream produced ADULTERATION OP MILK. 341 by different systems of feeding, or by dif- ferent animals' feed, and placed under dif- ferent circumstances. A standard milk, with which all other samples are to be compared, may readily be fixed by saying what lactometer strength it shall possess. From experiments we have made with several samples of genuine skimmed coun- try milk, we are authorised to state, that the London milk was found by no means to be so very much inferior to the country skimmed milk, as might perhaps be ex- pected. The tests by the lactometer never indicate more than from 8 to 10 per cent, of water. of ISINGLASS may be considered as an ali- mentary substance employed in dometie economy. By boiling isinglass in water, it becomes dissolved, and furnishes a mild tremulous jelly, which, when seasoned with cream, bitter almonds, and sugar, is called blanc-mange; and when seasoned with lemon juice, sugar, and aromatics, forms the basis of many delicacies for the table. It is also employed in domestic use in the clarification of various liquors ; and if small shreds are thrown into boiling coffee, it renders it clear in a few minutes. ADULTERATION OF ISINGLASS. 343 This substance is frequently adulterated with shreds of the skins of the dried blad- der of horses, and with other animal mem- branes. This fraud may be detected by the shreds not dissolving when boiled in water. Genuine isinglass should be totally soluble without leaving any filaments. The best isinglass is perfectly transpa- rent ; it occurs in commerce twisted in the form of a lyre or a heart ; and the worst is formed into the shape of pancakes. Q4