or THE UNIVERSITY OF au of Economic Geology and Technology HANDBOOK SERIES NO. 1 AIDS TO IDENTIFICATION OF GEOLOGICAL FORMATIONS BY I, A. UDDEN IRLF 105 l/D in 3) H ublished by Univcr-'.v of :. xa; EXCHANGE THE UNIVERSITY OF TEXAS Bureau of Economic Geology and Technology HANDBOOK SERIES NO. 1 AIDS TO IDENTIFICATION OF GEOLOGICAL FORMATIONS BY J. A. UDDEN Published by The University of Texas Austin CONTENTS Page Introduction 7 Minerals and rocks 9 Minerals 9 Quartz ., 11 Mica 12 Feldspar 12 Hornblende 13 Augite and pyroxene 13 Serpentine and chlorite 13 Glauconite 13 Calcite 14 Dolomite 15 Gypsum and anhydrite 15 Barite 16 Pyrite and marcasite 16 Hematite and limonite 17 Siderite 18 Salt 18 Asphalt, coal, and lignite 18 Rocks 19 Igneous rocks 19 Sedimentary rocks 20 Mechanical sediments 21 Chemical sediments 21 Organic sediments 21 Gravels, conglomerates, and puddingstone. . 23 Sands, sandstones, and quartzites 24 Packsand 24 Micaceous sandstone 24 Ferruginous sandstone 25 Bituminous sandstone 25 Cemented sandstone 25 Quartzite 25 Clay, shale, and slate (Argillites) 25 Marl . . 27 430114 4 Contents Page Fire-clay 27 Fuller's earth 28 Micaceous clay and shale 28 Ferruginous clay and shale 28 Bituminous clay and shale 28 Carbonaceous clay and shale . 29 Soapstone 29 Gumbo 29 Limestone 29 Oolitic limestone 31 Shell breccia . . . : V. 32 Chalk 32 Lithographic limestone 33 Dolomite 33 Caliche 34 Travertine , 34 Bituminous limestone 34 Gypsum and anhydrite rock 35 Rock salt 36 Flint and chert i 36 Clay-iron-stone 37 The principal formations in Texas 39 Introductory 39 Pleistocene and recent formations 41 The Tertiary formations 42 The Upper Tertiary 42 The Middle Tertiary 43 The Dewitt Formation 43 The Fleming clay 43 The Catahoula sandstone 43 The Lower Tertiary 43 The Jackson formation 43 The Yegua clay 44 The Cook Mountain 44 The Mount Selman. 44 The Wilcox 44 The Midway 44 The Upper Cretaceous 45 The Tornillo . .45 Contents 5 Page The San Carlos beds 45 The Rattlesnake beds 45 The Escondido beds 45 The Navarro beds 46 The Anacacho limestone 46 The Taylor marl 46 The Austin chalk 46 The Eagle Ford 47 The Woodbine 48 The Lower or Comanchean Cretaceous formations 48 The Buda limestone 48 The Del Rio clay 48 The Georgetown 49 The Edwards limestone 49 The Paluxy sands 49 The Glen Rose 49 The Trinity 49 The Jurassic formations 50 The Triassic formations 50 The Permian formations. 50 The Pennsylvanian formations 51 m The Bend formation 53 The Mississippian, the Devonian, and the Silurian formations 54 The Ordovician formations 55 The Cambrian formations . 55 Archean and igneous rocks 56 Tables for identifying minerals and rocks 57 1. General appearance under a magnifying glass 60 2. Examination of texture 62 3. Observation of color 63 4. Observation of streak 64 5. Test for hardness 65 6. Acid test 66 . 7. Test for fumes 68 8. Fire test . . 69 INTRODUCTION By long experience many drillers learn to dis- tinguish, generally quite correctly, the three prin- cipal classes of sediments in which most of their work is done, such as shale or clay, sandstone and limestone. The most experienced drillers in any locality have, also, expert knowledge of what we may call the "key rocks" of the field in which they work. They know the rocks that . determine the depth at which casing is to be set, or the depth at which the tests for oil or gas must be made. This knowledge of rocks is mostly taught from mouth to mouth, by the head driller to his helpers, entirely without any other guidance than the limited experience of each driller. No aid, so far as I know, has ever been prepared by geologists to help drillers in procuring the information both are eager- ly seeking. With the extension of drilling operations to re- gions of widely different geological formations and conditions, it has become a matter of some urgency that drillers' logs be made with greater accuracy and uniformity than before. The only way to en- courage improvement in this direction is to place in the hands of the men who make the "logs," what aid they need. By the use of a few very simple devices, available to all, great improvements in re- sults can be attained without the least loss of time.. The present paper is an attempt to present some information, in compact form, that will aid prac- tical and intelligent men to correctly identify ma- terials explored in drilling for oil, gas, or water. It will be found that much of the information here set forth consists of elementary methods 'and facts drawn from mineralogy and geology. Most drillers are eager to acquire all knowledge they can in these sciences. They have exceptional opportunities in 8 Handbook of Aids to their occupation to return to the geological profes- sion manyfold any little help that can be offered them of the kind here attempted. Identification of Geological Formations MINERALS AND ROCKS Minerals, when pure, have a more or less constant chemical composition, and with some exceptions they have definite crystalline form. In these respects they differ from rock which may or may not be constant in its chemical composition. By rock we mean any considerable quantity or large body of material which has been brought together into a deposit by some natural process. A mass of ice resulting from the accumulation of snow, is a rock. Salt or calcareous mud precipitated from the wa- ters of the sea and laid down in beds, forms rock. Sand and gravel are rock. When indurated, or hardened, we call these two latter deposits sand- stone and conglomerate, respectively. Many rocks consist of mixtures of different kinds of minerals. Many sandstones are mixtures of grains of quartz sand and scales of mica, and many limestones are mixtures of calcite and dolomite. Minerals are classified according to their chemical composition, while rocks are classified according to the processes by which they have been formed, or the manner in which the materials of which they consist have been brought together. MINERALS The number of minerals which occur in sufficient frequency to be of interest in formations that are extensively drilled are quite few. Though more than a thousand different mineral species are known-, less than a score ar$ Commonly found in the forma- tions which aue encountered by drillers in this state, may be enumerated and classified as follows; 10 Handbook of Aids to Siliceous minerals: Quartz. Mica. Feldspar. Hornblende. Serpentine and Chlorite. Augite and Pyroxene. Glauconite. Calcareous, lime-bearing, minerals: Calcite. Dolomite. Gypsum and Anhydrite. Iron-bearing minerals : Pyrite and Marcasite. Hematite and Limonite. Siderite, or clay-iron-stone. Sodium chloride: Salt. Carbon compounds: Asphalt. Coal. Lignite. Barium compound: Barite. If these minerals are classified on the basis of the acid elements entering into their composition they arrange themselves in the following groups: Oxides : Quartz. Hematite. Limonite. Sulphides : Pyrite. Marcasite. Chloride: Salt. Silicates : Mica. Hornblende. Identification of Geological Formations 11 Feldspar. Pyroxene. Serpentine. Glaucdnite. Carbonates : Calcite. Dolomite. Siderite. Sulphates : Gypsum. Anhydrite. Barite. Hydrocarbons : Asphalt. Coal. Lignite. QUARTZ Quartz is the oxide of an element called silicon. It is the most common of all minerals and occurs in many varities, such as rock crystal, which is its purest but not its most common form; chert and flint; agate; jasper; chalcedony; and a number of other forms. It is a little harder than glass, which it easily scratches. It may have, like most other minerals, any color. The purest varieties are either colorless and transparent, or white. Crystals of quartz are usually six-sided like a pencil, and term- inate in six-sided pyramids, or points, at one or both ends. Quartz is not affected by ordinary acids, and is not much changed by heating. To drillers the most familiar form of quartz is that seen in quartz sand and in layers of flint and chert. The latter occur in some limestones and greatly retard drilling on account of the hardness of this mineral. The chert layers in the Edwards limestone are from a few inches to two and three feet in thickness. There are also some chert layers in the Pennsylvanian limestones and in the so called Ellenburger lime- 12 Handbook of Aids to stone. Small quartz crystals of perfect shape are characteristic of the Redbeds of the Permian in the northwest part of Texas. Sand grains of chalce- dony are characteristic of some of the middle Ter- tiary formations, and have come to be spoken of as "rice sand," from a resemblance of the larger grains to polished rice. MICA Mica is a silicate of magnesia. It splits into ex- ceedingly thin transparent flakes, which are elas- tic, and will spring back when bent. It will not crumble when heated in a flame, as gypsum will. It is not affected by acid. Some mica is black and some has a golden color. It is generally present in several different kinds of crystalline rocks, from which it has been washed and mingled with sand and silt, afterward often hardened into sandstone and shale. Sandstones in the Cretaceous, and also in the Pennsylvanian and the Permian, seldom have much mica; while the sandstones in the Triassic of West Texas and the sands and silts in the Eocene Tertiary are usually very rich in this mineral. FELDSPAR Feldspar is a silicate of potash, soda and lime. There are several kinds of feldspar. It has straight cleavage planes that often show a pearly lustre. Orthoclase feldspar has a pinkish color. It is not quite as hard as quartz, but decidedly harder than calcite. It can be scratched by hard steel, and does not slack after heating to redness in fire. This mineral is the principal ingredient in granite and some other igneous rocks. In sedimentary rocks it is sometimes found as pebbles in some conglomer- ates, such as those occurring in the Pennsylvanian in north Texas and in the Trinity formation in central Texas, around the Llano uplift. Identification of Geological Formations 13 HORNBLENDE This is a very dark greenish or almost black min- eral with crystalline cleavage. .It is a silicate of magnesium, iron, manganese, soda, and potash, and has about the same hardness as feldspar. It occurs in some intrusives, schists and gneisses, underlying the sedimentary rocks in central Texas, and in the Trans-Pecos country. AUGITE (AND PYROXENE) Augite is a greenish black mineral. It is a sili- cate of lime, magnesia and iron. It has straight cleavage in two directions, and is of a hardness very slightly below that of feldspar. This mineral is found in igneous rocks at a few points along the Balcones Escarpment and in the mountainous coun- try west of the Pecos. It does not occur in sedi- mentary rocks. SERPENTINE AND CHLORITE Serpentine is a silicate of magnesia and iron containing moisture. It has an oil green color and a hardness varying from below to above that of limestone. Chlorite is closely related to serpentine but contains more iron and alumina. These miner-r als are the hydrated decomposition products of such minerals as augite and hornblende. They consti- tuted the principal oil-bearing rock in the Thrall oil field and are known to occur as altered intru- sives at other points along the Balcones Escarp- ment and in the Trans-Pecos country. GLAUCONITE This mineral is also known as greensand. It is a silicate of iron and potassium, and is from light green to very dark green in color. It will turn 14 Handbook of Aids to black on being heated to redness, and is then at- tracted by a magnet. This mineral is always found in small rounded grains usually mingled with sand and clay. It occurs in some of the Cambrian rocks, in the Taylor and the Navarro formations of the Upper Cretaceous, and in the Eocene of the Ter- tiary beds. A well-marked bed of glauconitic green- sand is a good horizon marker in the oil fields south of San Antonio. CALCITE Calcite, or spar, is identical in composition with pure limestone. In most limestones this main ingre- dient is mixed with some clayey material, and con- sists of crystals of such small size as to be entirely invisible to the unaided eye. The rock appears to be a structureless mass. The mineral is carbonate of lime, and hence consists of calcium in chemical combination with oxygen and carbon. When burned in a kiln it loses its carbon and forms quicklime. Its hardness is less than that of soft iron and it is easily scratched by a knife. Limestones in which the calcite crystals are large enough to be readily made out by the naked eye are often described as "crystalline lime" by drillers. Most marble is of this kind. The Edwards limestone in the Coman- chean series of rocks is characterized by such a coarse crystalline texture. In nearly all limestones places are apt to be found where the original fine- grained rock has been replaced by crystals of cal- cite of large size which are spoken of as spar. Such spar is nearly always present where underground water courses traverse the formations, and quite frequently they are associated with openings or fissures and cavities in limestone. In the lower part of the Comanchean limestones there are, especially in the southwest part of the state, one or two layers, some two feet thick, in which the crystalline cleavage is continuous through the entire thickness of these Identification of Geological Formations 15 layers and cuttings made by the drill from these lay- ers seem to be crushed crystalline calcite. DOLOMITE Dolomite is a mineral slightly harder than cal- cite. It is a carbonate of lime and magnesia, and is not as readily affected by acid as limestone, which is a carbonate of lime. Dolomite is rare except as it occurs in dolomitic rocks which are particularly common in the Ordovician and the Permian series of formations in Texas. GYPSUM AND ANHYDRITE Gysum and anhydrite both consist of sulphate of lime. Gypsum contains in addition some water, while anhydrite is free from combined water. When gypsum is heated it loses its water and is said to be calcined. In this state it has the same chemical composition as anhydrite. "Neither one of these two minerals effervesces when subjected to the action of acids. Both are softer than calcite or limestone and can be carved and cut with a knife. The crystals of clear gypsum, known as selenite, have acute and obtuse angles, and they have good cleavage in the direction of their length and breadth. They will split into thin leaves, which can readily be bent, but which will not spring back to shape, as the thin leaves of mica do. On account of its resem- blance to mica, crystalline gypsum is often incor- rectly called "isinglass." Anhydrite differs from gypsum in its cleavage. It breaks straight in three directions which are at right angles to each other. Hence cuttings of anhydrite often have sharp, square angles. Gypsum occurs in many clays and shales as sep- arate crystals. It frequently has formed from the disintegration of pyrite in marls and other calca- reous material. It is usually rare at depths below 16 Handbook of Aids to four or five hundred feet. Below this depth anhy- drite mostly takes its place. This mineral occurs in extensive beds in association with the cap rock in our oil fields of the coast, and it underlies ex- tensively the redbeds of northwest Texas. BARITE Barite is barium sulphate. It is white or color- less and has about the same hardness as calcite, be- ing easily scratched with soft iron. It is much heavier than calcite. If some cuttings of barite be thrown on the fire of a forge, they give a pale yellowish-green color to the flame. Barite has been found in considerable abundance in some of the salt dome oil and sulphur fields on the Gulf Coast, and it is occasionally encountered in the Permian redbeds and in the Comanchean limestones. PYRITE AND MARCASITE Pyrite is an easily recognized mineral. It has a yellow, metallic color*, frequently confused with that of gold, is hard enough to scratch glass, and gives sparks when hit with steel. It crystallizes mostly in cubes and octahedrons. Frequently also its crys- tals present five-sided flat surfaces. Consisting of iron and sulphur, it is natural that this mineral should give a sulphur odor when heated or when violently struck with some substance of sufficient hardness. One variety of pyrite often found in dark clays is known as marcasite. This is usually almost silver white. Pyrite and marcasite are very common in clays, shales, and slates of all colors except red and yel- low. In fact, many red clays- have originally had a dark color and they have become red by the ox- idation of disseminated pyrite. Pyrite also fre- quently occurs in limestone and in sandstone. When evenly disseminated in such rocks and in micro- Identification of Geological Formations 17 scopic particles, and when present in sufficient quan- tity, it gives them a dark color, or may cause them to become even black. Water obtained from such strata usually has the odor of hydrogen sulphide, or of "rotten eggs." This mineral has a very general distribution in nearly all formations. It occurs in grains too small to be seen with the naked eye and in grains and crystals up to masses several feet in diameter. It is even known to occur in extensive irregular lay- ers several feet in thickness. It is especially apt to occur at contacts between different formations. Lay- ers of this kind have been reported from the base of the Tertiary formations in south and east Texas. They are very har t d and exceedingly resistant to the drill. In coal-bearing and lignite-bearing beds, pyrite frequently occurs in concretions or loaf-like bodies, which lie flat with the strata. In the Aus- tin Chalk this mineral often forms round balls from one to two inches in diameter; the outer surface of which everywhere exhibits crystalline faces. In the Del Rio clay and in the Eagle Ford shale, pyrite mostly occurs in irregular clusters of cubic crystals. HEMATITE AND LIMONITE Red and yellow ochre (hematite and limonite) bear somewhat the same relation to each other* as do gypsum and anhydrite. Both are oxides of iron. In yellow ochre this oxide is combined with water; while red ochre contains no water in combination. Both are usually soft and are mostly found only in the upper few hundred feet or more of deep ex- plorations. They are for the most part derived either from siderite or- from pyrite by oxidation. A test which these minerals have in common with pyrite and siderite is that they become magnetic after being heated to redness. They form the col- oring matter in most red and yellow rocks. In east Texas extensive beds of hematite and limonite 18 Handbook of Aids to occur in the Tertiary sediments. Like pyrite these minerals sometimes characterize zones of contact be- tween formations of different ages. SIDERITE Siderite is a carbonate of iron. In the impure state in which it mostly occurs it is called clay-iron- stone. In hardness it slightly exceeds limestone. It is also heavier than limestone. It effervesces slowly in acid and becomes magnetic after ignition. Clay-iron-stone has the texture and color of a dark fine-grained limestone. It is the most easily smelted iron ore. This mineral occurs mostly in so called concre- tions, which are loaf-like and range in size from the smallest up to several feet in diameter. These concretions are known as turtle-stones, and are most frequent in association with beds of coal and lignite. They are frequently found in marly formations such as the Taylor Marl and the marls in the Midway formation of the Eocene Tertiary. Drillers very generally call them "boulders" when they are en- countered in borings. SALT Salt is so generally known that it needs hardly to be mentioned here. It crystallizes in cubes and readily dissolves in water. Dissolved in the ground water it occurs generally in the Pennsylvanian and the Permian strata. On the Gulf Coast, it occurs in enormous masses in association with the coastal oil fields, and in the Permian of the west it under- lies in several extensive beds the Panhandle and the Llano Estacado. ASPHALT, COAL AND LIGNITE All these minerals are compounds of carbon and are always black. They all burn. Asphalt readily Identification of Geological Formations 19 fuses when heated and gives off an easily recognized odor. Coal and lignite burn, but do not fuse as readily as asphalt. Particles of coal or lignite may be identified by roasting them on a red hot tin plate in a flame, when they glow for a while. Asphalt occurs impregnating many limestones and filling cav- ities and veins in limestones and shales. In some sandstones asphalt occurs as an impregnation which holds the grains together. Coal and lignite occur in thin layers or thick seams and some kinds of lignite are parts of trunks of trees imbedded in shales and sandstones. ROCKS Rocks are classified into two principal groups: igneous and sedimentary. Igneous rocks are formed by the cooling and congelation of molten materials. These may have welled out on the earth's surface or may have been forced up into strata that form the bedrock overlying the region where the fusion occurred. Sedimentary rocks have been formed by the natural and slow accumulation of sediments of any and all kinds, either in the sea or on land. Rocks of this latter kind underlie by far the larger part of the State of Texas, and they are of chief interest to drillers in the southwest. IGNEOUS ROCKS The only places where igneous rocks have been encountered by drillers in this state are in the Cen- tral Mineral Region in Llano, Burnet, Mason, Gil- lespie, and Blanco counties; along the structure called the Balcones Escarpment, in Kinney, Uvalde, Medina, Travis, and Williamson counties; and in the mountainous country west of the Pecos. No igneous rocks are likely to be encountered by drill- ing in any other part of the state. It has recently been claimed that some igneous rock has been found 20 Handbook of Aids to in a deep boring on the Gulf Coast, but the full evi- dence of this has not yet been furnished. The in- trusives in the Balcones belt are practically all of one and the same kind, a very tough, hard black basalt, consisting mostly of augite or hornblende. In many places this rock has been altered, so that it is a very easily drilled green chlorite or serpentine rock, softer than limestone. Such was the main oil-bearing rock in the Thrall oil field. In the Cen- tral Mineral Region, the chief igneous rock is gran- ite. This consists of pink feldspar, with some quartz and mica. There are here also extensive areas un- derlain by gneiss and schist. Originally this gneiss and schist was sedimentary rock, but this has been changed by heat and pressure. It is now crystalline and in part resembles granite. It usually contains more mica than the granite and also contains horn- blende. The igneous rocks of the mountainous coun- try west of the Pecos are of many kinds, and can not be briefly described. They belong for the most part to the siliceous types, and range in texture from granite through porphyries, basalts, and lavas to obsidian, or natural glass. SEDIMENTARY ROCKS The sedimentary rocks may be classified into three main groups: (1) mechanical sediments, which are by far the most common; (2) chemical sediments, which have been precipitated from solutions in the ocean and in lakes; and (3) accumulations of the remains of animals arid plants, usually called or- ganic sediments, as animals and plants both are organisms. The following tables give a general view of the classification of sedimentary rocks. Identification of Geological Formations 21 .- PH w o II 2 60 V) CO S ^ EH 5? 03 38 4-> ^ 03 O 0) fl o -*-> H T3 0> C o -4-3 1 H c in m S .- OJ J3 s 0) k/J ^U rt") ' I iiiijsiij v-' r> cl^n-i-j-icl ^g!s|||ti| PQ Identification of Geological Formations 61 'g-BE ||1 a-ga III! Ui ifc -g C si a a I s I'lifill w rz3 *|*?l r^3 O >H O 04^00 l Glauconjte Serpentine Hornblende. Identification of Geological Formations 65 us.!!!! 66 Handbook of Aids to S 8.5:3 g -^^&8 -g ,JQ O H OQ EH Q hH O *o c8rS;^ e w J a H ^5 ililiiliji Identification of Geological Formations 67 eg is 111-! gif H 1* T, a li a gi ss* ii di 8 l IHIII 8 g p, nil 68 Handbook of Aids to w W S t) PH O PH W EH PQ EH *f|fllililli ' 3 C o> Pyrite Marcasite Clay-iron-stoi Hematite Limonite IS,- 2 -- uSae 3'C g-e Limestone Dolomite. 14 DAY USE RETURN TO DESK FROM WHICH BORROWED EARTH SCIENCES Li This book is due on the last date stamped below, or on the date to which renewed. Renewed books are subject to immediate recall. *H97r General Library tiH NOTICE Headers of this text, interested in the geology of Texas, will find it advantageous to have at hand for reference Bulletin 44 of the University of Texas* This has been prepared by the Bureau of Economic Geology, and Is a review of the geology of the state as far as it has been made out to the present time. It contains- maps and sections for ready reference and clear pre- sentation of the known surflcial distribution and the thickness and nature of the forma- tions described on]; briefly in this .text. Bulletin 44 will be mailed promptly on the receipt of the price ($1.00) r Address J e A. Udden, Bureau of Eco- nomic Geology, Austin, Texas*