2^5' rilA-^M/-! >fei86t*S-' ^^CL6ft^ LIBRARY OF THE UNIVERSITY OF CALIFORNIA LlBRIRV OF LIBRARY OF THE UNIVERSITY OF CALIFORNIA LIBRARY OF " LIBRARY OF THE UNIVERSITY OF CALIFORNIA LIBRARY OF ^^^^/^ ^ IPMl Y Of CALIFORNIA LIBRARY OF THE UNIVERSITY OF CALIFOR Y OF CALIFORNIA LIBRARY OF THE UNIVERSITY OF CALIFOR! 1 Y OF CALIFORNIA LIBRARY OF THE UNIVERSITY OF CALIFORf fitter CHEMISTRY FOUR SEASONS, Spring, Summer, Autumn, antr Winter: AN ESSAY, PRINCIPALLY CONCERNING NATURAL PHENOMENA ADMITTING OF INTERPRETATION BY CHEMICAL SCIENCE, AND ILLUSTRATING PASSAGES OF SCRIPTURE. BY THOMAS GRIFFITHS, PROFESSOR OF CHEMISTRY IN THE MEDICAL COLLEGE OF ST. BARTHOLOMEW'S HOSPITAL; AUTHOR OF "RECREATIONS IN CHEMISTRY," AND " CHEMISTRY OF THE FOUR ELEMENTS." LONDON; JOHN CHURCHILL, PRINCES STREET, SOHO. MDCCCXLVI. \f\ n. ft 1 \\ A A LONDON J PRINTED BY G. J PALMER, SAVOY STREET, STRAND. el PREFACE. " THE Chemistry of the Four Ancient Elements," an Essay founded upon Lectures that I had the higli and enviable honour of delivering before the Queen,, and by Her most gracious special permission dedi- cated to Her Majesty, had the good fortune to meet with a favourable reception from the Public. I am therefore induced to publish " The Che- mistry of The Four Seasons," an Essay founded upon Lectures that I have recently delivered at Scien- tific Institutions in London and Liverpool, and I hope that it will be found equally worthy of reception. I have written this Essay, not for the proficient but for the uninitiated in Chemistry; and I have endeavoured to bear in mind that in tracing na- tural phenomena, " there is not so much required any strength of imagination, or exactness of method, or depth of contemplation, as a sincere hand and faithful eye to examine, and to record the things themselves as they really appear." It may be safely said, that there is no science more admirably calculated to awaken feelings of interest regarding the wonders of The Creation than that of VI PREFACE. Experimental Chemistry ; the extraordinary disclosures with which it abounds will immediately lead the stu- dent to an acknowledgment of the power and goodness of God. The science of Chemistry will lead the student to ' search the Scriptures,' and thus to imitate the exam- ple of the best and greatest philosophers, for Newton esteemed The Bible " the most authentic of all histo- ries ;" Hale said, " none was like unto it for excellent wisdom, learning, and use ;" Boyle considered it " u matchless volume, impossible to be too much studied or too highly esteemed ;" and Locke pronounced it as " consisting of Truth without any mixture of Error for its matter." I have humbly endeavoured to select a few of the beautiful passages of Holy Writ which refer to Natural Phenomena, and to interpret these through the me- dium of the science that it is my delight to follow, a science to employ the words of Davy " which has its moral and intellectual, as well as its common uses ; its object is not only to apply the different substances in nature for the advantages, comfort, and benefit of man, but likewise to set forth that wonderful his- tory of Wisdom and Intelligence which is written in legible characters both in the heavens and on the earth." To those who have not studied the science of Che- mistry, I may say, in the words of the same philoso- pher, " its beginning is pleasure ;" and when they have mastered its rudiments they will find, that " its pro- rrvPQfi ic; L-r PREFACE. Vll gress is knowledge ;" and lastly, when they have at- tained its higher combinations and laws, and can ven- ture upon the application of these to the interpretation of natural phenomena, they will confess that " its ob- jects are truth and utility," and eminently calculated to inculcate feelings of thankfulness, gratitude, and re- verence, towards The Great Creator, " He that is ex- cellent in power and in judgment." In this Essay it will be found, that in addition to the interpretation of a few of the phenomena of The Four Seasons, through the medium of Chemistry, I have introduced a variety of other miscellaneous, and I hope both interesting and useful information ; all the experimental illustrations are of the simplest cha- racter, and do not involve the necessity of costly appa- ratus ; and I have given explicit directions for their performance, so that the student may be certain of their success. Chemical experiments are often unsuccessful on account of some apparently trifling matters having been neglected ; I have endeavoured to point out all these, and yet I find, that in the experiment at page 343, I have omitted to state, that in pouring the various solutions through the long funnel, care should be taken to pour them so gently, that no bullies of air le car- ried down the pipe of the funnel, as these would dis- turb the levels of the respective liquids ; and in re- Vlll PREFACE. moving the funnel, care should -be also taken to lift its pipe very slowly, to the level of each liquid, holding it at each for two or three seconds. For the arrange- ment of this experiment, I am indebted to my friend Mr. T. S. Dick, who affords me his valuable assist- ance in the Chemical Laboratory at St. Bartholomew's Hospital. At page 104, line 2 from the bottom, I must re- quest the reader to insert the following paragraph, which 1 find has been accidentally omitted. " An equal portion of the clay containing moisture, after being heated to 88 degrees, was exposed in a temperature of 55 degrees ; in less than a quarter of an hour it was found to have gained the temperature of the room." CONTENTS. INTRODUCTORY. The subject proposed, 1 . Chief object of the science of chemistry. Experiments of the laboratory may elucidate natural phenomena. Prominent features of The Four Sea- sons briefly enumerated, 2. Exalting tendency of the study of chemistry. Object of the present work. Com- pound and elementary matters, 3. Ponderable and impon- derable elements enumerated, 4. Exact meaning of the term element, the metal iron an element, 5. Common salt a compound of chlorine and sodium, 6. These are both elements in the modern acceptation of the term, 7. Chalk a compound, ib. Its components also compounds of the elements Carbon and Oxygen, and Calcium and Oxygen ; these constitute carbonic acid and lime, and com- bine to form chalk, 8. Primary and secondary combina- tions. All chemical combinations and decompositions are governed by definite weights, 9. Endeavour of the che- mist to interpret Natural phenomena, and to discover proofs of the power and goodness of God, 10. Chemistry founded upon experiment, ib. Extraordinary facts disco- a 5 X CONTENTS. vered by its practice. The elements Oxygen and Nitro- gen, when combined, produce five poisons ; but when mingled, they constitute the chief volume of the Atmo- sphere throughout all the changes of the Seasons, 11. Rigid examination or analysis of the atmosphere proves it to contain small proportions of the compounds called water and carbonic acid, 12. Total weight of the atmosphere, and of its elementary and compound constituents. No other medium fit for the support of life, 14. Lavish abun- dance of water as presented throughout Nature. Water ne- ver absolutely pure, or solely consistent of the two elements Oxygen and Hydrogen, from whose union it may be formed, 15. The Earths popularly so called, viz. Lime, Clay, Sand, and Magnesia, are truly rusts of metals or metallic oxides, 16. Earthy substances, viz. Limestone, Marble, Gypsum, and Bone-earth, are compounds of the foregoing with various acids, 17. General statement re- garding the constituents of soils, as preparatory to more particular examination, 18. Importance of chemistry to agriculture, ib. Chemical analysis extends to organic bo- dies, and discloses extraordinary facts. Elements of organic bodies are few in number, viz. Oxygen, Nitrogen, Carbon, and Hydrogen, 19. All organic bodies may be submitted to analysis, but synthesis is impossible, 20. Tabular state- ment regarding proximate organic compounds, and the definite weights of their three or four ultimate elements, 21. Solar light necessary for the welfare of the animated creation, 22. The rainbow displays the seven coloured rays of solar light, 23. Colours of terrestrial surfaces, 24. Beneficial agency of heat, 25. Habitudes of various forms of matter with heat, more particularly Earth, Air, and CONTENTS. XI Water, 26. Electricity constantly present throughout Nature ; its occasional display as lightning, ib. The examination of the principal chemical phenomena of The Four Seasons, presents proofs of the power and goodness of The Creator, 28. CHAPTER I. SPRING. Reflections on the beauty of this season, 29. Outline of the plan proposed for examining its principal chemical phe- nomena, 30. The germination of seeds, 31. Changes of their proximate principles induced by the joint agencies of earth, water, air, and heat, 32. Conditions requisite for germination to ensue. Dormant state of seeds, 33. Re- ception and retention' of water, by soils for the excitement of germination and the support of vegetation, ib. Illustra- tions of capillary attraction, 35. Its effects in Nature and Art, 39. The fertility of soils promoted by the absorption of water, 40. Valuable information afforded by the che- mist to the agriculturist, 41. Simple illustrations of the art of analysis, 42. Statement regarding the composition of various soils, and their general characters, 44. Nutri- ment of plants, 46. Formation of springs of water in the earth, 47. The accumulation of water in the form of clouds referred to evaporation, ib. The return of water to the earth in showers, 49. The absorption of watery va- pour from the atmosphere by soils, is much connected with their fertility, 50. Methods of ascertaining the quantity of watery vapour absorbed by different soils, 5 1 . Results Xll CONTENTS. of such experiments, 53. Amount of watery vapour pre- sent in the atmosphere, 55. The effect of heat and cold upon the atmosphere does not alter its nature, ib. Expe- riments in proof of this wonderful and beneficial fact, 58. Actual combustion, and animal respiration, both alter the nature of the atmosphere, and render it mephitic, 59. Ex- traordinary provision made for the escape of the products of respiration, and their diffusion throughout the atmo- sphere, 6 1 . Uniformity in the constitution of the atmo- sphere, 64. Action of the germination of seeds and the growth of plants upon the atmosphere, 65. Evaporation of water from the earth, during the prevalence of March winds, 66. Proverbs concerning the weather at this sea- son, 67. The formation of rain-clouds cannot be satisfac- torily explained, 68. Vesicular vapour of mists, ib. Ab- sorption of heat by the surface of the earth, where it is most needed for the welfare of the animated creation, 69. The earth has no great power of conducting heat ; hence springs of water are not materially affected during the Sea- sons, 70. Earth, Air, and Water, are all imperfect con- ductors of heat, ib. Experiments in illustration of the conduction and non-conduction of heat, 71. Investigation continued regarding the phenomena of germination and growth, 75. Precautions in transplanting, 76. Plants destroyed by various poisons. Natural constitution of soils favourable for the growth of plants, 77. Circulation of the sap, 78. Transpiration and absorption of water, by the leaves of plants, 7880. CONTENTS. Xlll CHAPTER II. SUMMER. Extraordinary increase in the growth of plants during this season, 81. Remarkable experiment regarding the growth of a willow tree, 82. Water is apparently the sole aliment of plants, ib. Accurate examination proves that plants derive the chief if not the whole amount of their constituent carbon, from the Carbonic acid of the atmo- sphere, 83. Enormous amount of Carbonic acid naturally present in the atmosphere, and hourly exhaled into it by animal respiration, 84. Carbonic acid, though a poison to animals, is the food of plants, 85. Growing plants decom- pose carbonic acid, secrete its carbon, and elicit its oxygen, and thus renovate vitiated air, ib. Experiments concern- ing this miraculous phenomenon, 87. Conclusions drawn from them, 89. Vegetation will not proceed without the presence of Carbonic acid, 90. The presence of light is essential to the welfare of plants, 91. The absence of light modifies their natural physical and chemical charac- ters, ib. Solar light is absolutely essential to the health of man, 94. The mountaineer and the miner contrasted, ib. The importance of light is universally manifest, 95. Local impurities in the atmosphere affect the growth of plants, ib. Destruction of plants and modifications of the colours of flowers by acid vapours, 97. Plants may be grown in a confined portion of air, and thus protected from injury in smoky cities, 98. Tremulous motion of objects when xiv CONTENTS. viewed through the air incumbent upon a soil heated by the solar rays, 102. Rate of the heating and cooling of soils differing in their physical and chemical characters, 103. Importance of the thermometer to the agriculturist, 105. The thermometer merely denotes the degree of heat that a medium can impart, and not the actual quantity of heat that such medium contains, ib. Substances of the same tem- perature contain different quantities of heat, ib. Experi- mental illustrations regarding the capacity of bodies for heat, 106 121. Diminution of the density of the atmo- sphere in proportion to its altitude, 122. The " snow line," or " line of perpetual congelation," 123. Miracu- lous adjustment of the density and temperature of the air, to the functions of human beings, 124. Summer heat never gains sufficient intensity to cause the combustion of terrestrial productions, 125. Reflections upon the beauty and harmony of the foregoing phenomena, 126. Coolness of the earth after a summer shower, chiefly referrible to evaporation, 129. Rate of evaporation at different tem- peratures and during different states of the atmosphere, 130. The evaporation of water employed as a means of effecting reduction of temperature, 131. Water frozen in summer by the cold produced during its own evaporation, 134. Hygroscopes for detecting the presence of watery vapour in the atmosphere, 137. The sea and land breezes of tropical islands and coasts, 140. Settled weather essen- tial for the hay harvest, 142. Hay damaged by floods Firing of damp hay, 143. Examination of the ashes of a hay-stack and corn-rick, 144. Silica and potash are essen- tial components of soils for the growth of grasses and corn, 145. Utility of straw for thatching, 147. CONTENTS. XV CHAPTER III. AUTUMN. Radiation of heat from the earth, 150. Experiments concerning radiation 151. Influence of mere alteration of surfaces upon the reception and retention of heat, 152 157. Colour of surfaces affects their absorption of solar radiant heat, 158. The black skin of the Ethiopian a de- fence against the intensity of solar heat, 159. The " sun- stroke," 161. Radiation of heat from different soils, 162. Theory of the wonderful phenomenon of dew, 163. Depo- sition of dew, upon terrestrial objects, does not take place indiscriminately, 165. Experiments concerning dew, 166 170. Ice obtained by the cold induced during radiation, 171. Deposition of dew upon dead organic matters hastens their putrefaction, 171. The phenomenon of a morning mist, 173. Its disappearance, 175. Spherical figure of dew and rain drops, 176 179. Honey dew, 181. Hy- grometer for ascertaining the watery vapour present in the atmosphere, 182 189. Deposition of water from the at- mosphere in Eastern climates, 190. Investigations regard- ing the phenomena of the universe a source of happiness, 191193. Blue colour of the sky, 194. Red appear- ance of the evening and morning sky, 194 196. The phenomenon of the rainbow, 1 97 200. Reliance placed upon experiment, 202. Aeration of water for the respira- tion of fishes, 203 208. Aquatic plants purify water from the results of the respiration of fishes 209 218. Water is incapable of being heated by the solar rays, 219. The solar XVI CONTENTS. rays collected to a burning focus by a globular vessel filled with water, 220. The gas of stagnant pools, 221. The ignis fatuus or Will o' the wisp, ib. Phosphorescent light of vegetable and animal matters, 222. Deleterious mat- ters produced during the putrefaction of organic bodies, 223. The marsh-miasma, and malaria, ib. The nature of contagious and infectious matters has not been discovered, 225. They may be destroyed by chemical means, viz., Nitric acid and Chlorine, 227. Distinction between ancient and modern Nitre, the term being now applied to Saltpetre or Nitrate of Potash, 226. Its decomposition by sulphuric acid for the evolution of Nitric acid vapour, 228. Com- mon salt, by the action of sulphuric acid, produces Hydro- chloric acid, 231. This deprived of Hydrogen evolves Chlorine, the most powerful disinfectant, 232. Method of fumigating an apartment, 233. Experiments regarding the action of Chlorine upon organic and inorganic bodies, 236. Contagious and infectious matters destroyed by a high arti- ficial temperature, 238. Quick-lime an important adjunct in cases of fumigation, 240. The phenomenon of the thun- der-storm, 242. Various forms of lightning, 245. Pre- cautions for personal safety during a thunder-storm, 250. Identity of lightning and electricity, 254. Conductors at- tached to buildings for averting the destructive effects of lightning, 256. Nitric acid produced by the union of the elements of the air during a thunder-storm, 259. Showers of rain and hail during a thunder-storm, 260. The pheno- menon of the water-spout, and its probable cause, 264. "Wonderful phenomena that are constantly proceeding throughout Nature during the changes of the seasons, 267. The vital force displayed by vegetation, ib. The endeavour CONTENTS. XVli of plants to remove obstacles opposed to their growth, 268. The origin of the Corinthian capital, 266. Things of com- mon occurrence present scientific information when properly examined, 271. The corn harvest the grand feature of Autumn, 272. A proper supply of food necessary for the support of life, 273. Examination of the chief proximate principles of wheaten flour, viz., Gluten and Starch, 280. Utility of manuring wheat-lands with recent " bone-dust," 286. Utility of quick lime and stable manure, 288. Gum and Sugar are proximate elements of many vegetables and fruits, 289. Sugar essential in all cases of vinous fermenta- tion, 292. The chief bulk of vegetables consists of Lignin or woody fibre, 295. Various and important forms in which it is presented, 297. Results of its decomposition when absolutely pure or as commonly obtained, 302. The non-conducting power of the bark of trees as regards the heat of Summer or the cold of Winter, 304. Action of flowers and fruits upon the atmosphere, 306. Seeds produced in Autumn similar in all characters with those that were con- signed to the earth in Spring, 308. The varied hues of Autumn and fall of the leaf, 311. The phenomenon of " fairy rings," ib. The frosts at the close of Autumn, 312. CHAPTER IV. WINTER. Transition of water into ice, 315. Action of cold and heat upon solids, liquids, and aeriform substances, 314. Experimental illustrations, ib. Pure water undergoes no decomposition by keeping, 321. The boiling fountains of XV111 CONTENTS. Iceland, 322. Petrifying springs, ib. Contraction and expansion of gases, liquids, and solids, 323. The anoma- lous expansion of water by cold, 324. Slow progress of the congelation of water during Winter, 325. Beneficial effects of this phenomenon, 326. Very deep lakes resist congelation, 327. Sea water does not freeze at the same degree as fresh water, 328. Experiment regarding the superficial formation of ice, 329. Ice lighter than water, and though solid floats upon its surface, 334. Meaning of the term specific gravity, ib. Methods of ascertaining the specific gravity of pure and salt water, 335. The construc- tion of the hydrometer, 338. Experimental illustrations of the specific gravities of liquids, 34 1 . Methods of ascer- taining the specific gravity of solids, 345. The freezing point of water is immutable, 346. The graduation of the Thermometer, 347. The principle upon which the Baro- meter is constructed, 348. The examination of the freezing of water continued, 350. Powerful expansion of water during its transition into ice, ib. Experimental illustration of this curious and important fact, 35 1 . Beneficial effects that result throughout nature from the expansive force of water in freezing, 352. Rupture of water-pipes and bottles by frost, 354. Burning lens formed of a block of transpa- rent ice, 356. The antiseptic power of ice, 357. The preservation of provisions in ice, 358. The collection of ice in the vicinity of London, 359. The construction of an ice-house or ice-well, 362. The sheet of ice upon a pond frequently causes the fishes to perish by preventing the escape of the results of their respiration, 363. Won- derful provision made in Nature for the preservation of the life of fishes during Winter, 364. The " frost-smoke," ib. CONTENTS. XIX The congelation of water contained in foot-prints, hoof- marks, and wagon ruts, 367. The phenomenon of "ground ice," or ice formed at the bottom of rivers, 369. The phe- nomenon of snow, 3/2. Crystalline form of snow flakes, 373. Snow is a great preservative against the effects of cold, ib. Construction of snow-houses by the Esquimaux, 374. Warmth of these dwellings, 377. Red snow of the Arctic regions, 379. The collection of snow by the Neapolitans, 380. The preservation of snow on mount Etna, by the non- conducting power of volcanic sand, 381. The reflection of solar heat by white, and its absorption by black surfaces, illustrated upon snow, ib. The phenomenon of hoar-frost, 383. Imitation of the appearance of hoar-frost upon branches, 334. Beautiful forms of hoar-frost upon various objects, 387. The formation of icicles, 389. Neither cold nor heat alter the chemical constitution of water, 390. Phenomena that ensue during the elevation of water to its boiling-point, experimentally illustrated, 390. Atmospheric pressure affects the temperature at which water enters into ebullition, 397. The vapour of water the motive power of the steam-engine, 404. Experiments concerning the de- composition of water, 407- Enormous volume of Oxygen and Hydrogen gases contained in a drop of water, 415. Separation of Nitrogen from the atmosphere, 416. Exa- amination of the chemical philosophy of an " English fire- side," 419. The ascent of flame, 420. Accidents by dresses catching fire, 421. Reason why flame is applied to the lowest part of the fuel in a fire-grate, 422. Remarks concerning the warming of an apartment by an open fire, 424. Production of gas from coal, for the purpose of ar- tificial illumination, 432. The importance of coal, 437. XX CONTENTS. The fire-damp of coal mines, ib. The miners' safety lamp, 439. Coke a valuable fuel for the reduction of metals, 442. Utility of the metals for the construction of culinary im- plements, 444. Destruction of matter does not ensue during combustion, 445. Ordinary sources of artificial light and heat, 447. Different sensations experienced upon touching different substances having similar temperatures, 448. The terms heat and cold are merely relative, 452. Aeriform substances extremely susceptible of change of volume by change of temperature, 454. The specific gra- vity of air and gases, 455. The winter clothing of animals, 456. The transition of ice into water upon the return of Spring, 458. Experiments concerning latent heat, 461. Latent heat of the vapour of water, 471. Miraculous ad- justments of temperature during the thawing of ice, 474. The magnitude of the earth as compared with the size of man, 476. The study of chemistry and of all the high sciences is well suited to keep down a spirit of arrogance and intellectual pride, 478. Conclusion, 480. APPENDIX, containing the names of the discoverers, historians, and narrators of the principal facts which are embodied in this work, 481. CHEMISTRY OF THE FOUR SEASONS. INTRODUCTORY. THE FOUR SEASONS present many phenomena which admit of interpretation through the Science of Chemistry. Some persons imagine that the science of chemistry consists entirely of experiments with furnaces, cru- cibles, alkalies, acids, salts, and metals, which are all more curious, than useful, and they will ask Can the chemist emerge from the narrow precincts of his labo- ratory, and venture upon the boundless realms of Nature, with explanations concerning the verdure of Spring, the heat of Summer, the harvest of Autumn, and the cold of Winter ? The reply of the chemist is in the affirmative ; he can expound such phenomena to a certain extent, B 2 INTRODUCTORY. for the chief object of chemistry, is to ascertain the composition of things, and to determine the laws by which they are governed. By numerous experiments with furnaces, crucibles, alkalies, acids, salts, and metals, the chemist has ob- tained a key to the vast laboratory of Nature, and although standing merely upon the threshold of its newly-opened portal, if he temper his little knowledge with humility, he may witness and understand many of the gigantic and refined operations therein pro- ceeding, under the guiding and protecting hand of Almighty God, for maintaining the regularity and order of the Four Seasons. The most prominent features of Spring, Summer, Autumn, and Winter, may be thus briefly enumerated: In spring, the earth is covered with verdure, buds and blossoms vary and adorn its surface ; soft showers 3escend, the air is clear, sunshine glads the heavens, and steadily increases in power unto the fervent glow of summer; then, generally speaking, vegetation has attained its fulness, the earth is crowned with foliage and flowers, the fields are becoming ripe for the scythe, and sickle ; and soon the sultry noon- tide heat, the refreshing night dew, and the lowering thunder-cloud, herald the advent of autumn; it comes, laden with purple fruit, and golden grain ; it yields its bounteous store, it passes, and then, sunshine is pale and lan- gdid, winds are bleak and cold, trees become leafless, streams are fast bound with ice, hoar-frost and snow form the winter mantle of the earth. INTRODUCTORY. These Four Seasons, these miraculous changes in the aspect of the globe, these definite periods of Ger- mination, of Growth, of Maturity, and of Repose, familiar to all men, yet unheeded by many, present the votary of chemistry with magnificent illustrations of facts regarding the powers and properties of matter, which he has discovered upon a minor scale by expe- riments in his laboratory. To him, who comes with a mind duly prepared and fitted to the business of the interpretation of Nature, in accordance with the axioms of Inductive Philosophy, the tendency of the science of chemistry is most exalt- ing ; at each step, it implants a firm belief in the Power, and a perfect reliance upon the Goodness of God, who promised that, " While the earth remaineth, seed-time and harvest, and cold and heat, and summer and winter, and day and night, shall not cease." The object of this essay is to adduce a few of the principal phenomena of the four seasons, which admit of explanation and illustration through the medium of chemistry; and as it teaches the composition of things, a general statement regarding natural objects and the powers unto which they are subject, will form the remainder of this introductory chapter. y The chemist, by experimenting upon the various solid, liquid, and aeriform matters, presented through- out the creation, discovers that many of them can be divided into two or more substances of distinct and opposite characters, and that these cannot be again divided into others. B % 4 INTRODUCTORY. Substances that can be divided, analysed, or sim- plified, are called Compounds ; and such as cannot be so treated, are called Elements. Fifty-five of these are known, all Ponderable, and subject to the agencies of Light, Heat, and Electri- city, which are Imponderable. The ponderable ele- ments are distinguished by the following names; those marked * are Combustible and non-metallic ; those marked f are Incombustible and non-metallic ; the others are Metallic. 1, Aluminum ; 2, Antimony; 3, Arsenicum; 4, Ba- rium ; 5, Bismuth ; 6*, Boron ; 7f, Bromine ; 8, Cad- mium ; 9, Calcium ; 10*, Carbon; 11, Cerium; 12f, Chlorine; 13, Chromium; 14, Cobalt; 1 5, Columbium ; 16, Copper; 17f, Fluorine; 18, Glucinum; 19, Gold; 20*, Hydrogen; 21f, Iodine; 22, Indium; 23, Iron, 24, Lantanum ; 25, Lead ; 26, Lithium ; 27, Magne- sium; 28, Manganesium; 29, Mercury; 30, Molybde- num; 31, Nickel; 32f, Nitrogen ; 33, Osmium ; 34f, Oxygen; 35, Palladium; 36*, Phosphorus; 37, Plati- num ; 38, Potassium; 39, Rhodium ; 40*, Selenium; 41, Silicium ; 42, Silver ; 43, Sodium ; 44, Strontium ; 45*, Sulphur; 46, Tellurium ; 47, Thorium; 48, Tin ; 49, Titanium ; 50, Tungstenurn ; 51, Vanadium; 52, Uranium ; 53, Yttrium ; 54, Zinc ; 55, Zirconium. Of these elements, the following are the most abun- dant, and will be most frequently mentioned throughout this inquiry. I. Combustible and non-metallic, Carbon, Hydro- gen, Phosphorus, and Sulphur. INTRODUCTORY. 5 II. Incombustible and non-metallic, Chlorine, Nitrogen, and Oxygen. III. Metallic, Aluminum, Calcium, Iron, Magne- sium, Potassium, Silicium, and Sodium. The ponderable elements are capable of uniting in various ways to form a great number of compounds ; and these compounds in their turn are capable of uniting with each other to form a greater number of complex compounds ; and so far as the knowledge of the chemist extends, it leads him to consider that all natural and artificial objects consist of elements, and their combinations and mixtures, arranged according to definite laws of weight and measure. The term Element will occur very frequently during this examination of the principal chemical phenomena of the Four Seasons, and therefore its exact meaning demands explanation at this early stage. The metal Iron, its tenacity, ductility, and nu- merous uses, are familiar to all persons ; but the che- mist is not satisfied with this mere knowledge of its mechanical properties, he wishes to ascertain the com- position of the metal, the things of which it consists ; he endeavours to do this by making experiments ; he submits iron to every process that -he can devise ; he alters or disguises its ordinary properties in many curious ways ; but at length the metal presents itself in its original state, pure and unharmed by the ordeals through which it has passed, and without yielding the slightest clue regarding its composition. The chemist depends entirely upon the results of INTRODUCTORY. experiments for his knowledge, and in the ahove instance, he has no alternative hut to make a candid confession of his inability to prove of what things Iron consists ; and, in accordance with the principles of inductive philosophy, he is ohliged to call the metal a Pure, Undecompounded, or Simple substance, a Eudi- ment, or an Element. In employing this term he wishes to he distinctly understood, that he does not presume to say that Iron must he absolutely simple or undecomposable, because he is not sufficiently skilful to discover its composi- tion ; he merely wishes to express, that he cannot ex- perimentally prove it to contain two, or more sub- stances, or in other words, that he cannot prove it to be a Compound, and in this sense no objection can be made to the term Element. The substance called Common-salt, and its important uses as a preservative of food, are universally known and appreciated ; but the chemist wishes to know of what things Common-salt consists. " TRY," is the motto of the laboratory ; and ac- cordingly, by trials or experiments, the chemist soon discovers that he can divide Common-salt into two new and distinct substances, one of them a Vapour of a greenish yellow colour, and the other a Solid of a silvery lustre ; he therefore terms Common-salt, a Com- pound. The Vapour, he terms Chlorine, in allusion to its pe- culiar tint ; the Solid, Sodium, to denote its identity with that obtained from a plant called the salsola soda ; INTRODUCTORY. 7 and as these are the only two substances obtained by the analysis of Common-salt, he terms it Chloride of Sodium, to express its constitution with precision. But the chemist is now only half satisfied,, he has another question ready : Of what does Chlorine con- sist, and of what does Sodium consist ? He again appeals to accurate experiment; but finds that neither Chlorine nor Sodium can be ana- lysed or simplified, they remain refractory as the metal Iron, they demand to rank with it as Elements, and this position the chemist is reluctantly com- pelled to grant. Chalk is another well-known substance ; Of what does it consist, is the question of the chemist : is it an Element like Iron, or is it a Compound like Salt ? The chemist discovers that Chalk will immediately relinquish two new substances, one of them an Invisible Vapour, and the other a White Solid ; he therefore terms Chalk, a Compound. But the chemist is not contented with this result; he again puts the ques- tion, Are these new substances elements or com- pounds ? Although one of the substances is an Invisible Vapour, it can be confined, weighed, measured, and experimented upon with the utmost facility ; and when the chemist submits it to his most refined operations, it yields two new substances, the one an Invisible Gas, and the other a Black Solid ; whilst the analysis of White Solid, yields the same Invisible Gas, and a Solid of Silvery splendour. INTRODUCTORY. These new substances now require to be denoted by names ; the chemist finds that the Invisible Gas has the power of producing many Acids, and therefore he calls it Oxygen ; the Black Solid he discovers to be the pure inflammable principle of Coal, and therefore he calls it Carbon ; whilst the Solid of Silvery splendour he discovers to be a constituent of Lime, and therefore he calls it Calcium. He generally draws upon the rich stores of the Greek and Latin languages, for names to denote the various substances that he obtains ; and this will be evident upon reference to the list of elements, at page 4. The Invisible Vapour obtained by the chemist during his first experiments upon Chalk, proves to be an Acid compound of Oxygen and Carbon, and to denote this fact, he calls it Carbonic acid ; whilst the White Solid substance proves to be an Alkaline compound of Oxygen and Calcium, and therefore he calls it Oxide of calcium, or more familiarly, Lime. The composition of Chalk, in refined chemical no- menclature, is accordingly expressed by the term Car- bonate of oxide of calcium ; but the chemist, for bre- vity, generally calls it Carbonate of lime. ^ it is a com- pound of two compounds, and these lie -fimiiliarfy calls its Proximate elements, because they^ immediately come forth, upon the first, or proximate analysis, and they will, under certain conditions, immediately unite and reproduce chalk. On the other hand, Oxygen, Carbon, and Calcium, into which Carbonic acid and Lime are resolvable* do INTRODUCTORY. 9 not admit of further analysis or simplification ; they are refractory like Iron, Chlorine, and Sodium, and therefore the chemist calls them Ultimate elements, meaning by the term, elements elicited when analysis is carried to its utmost possible extent. The union of two or more Ultimate elements, con- stitutes a Primary combination ; and that of two or more Proximate elements, a Secondary combination ; and as the chemist, throughout all his researches, is guided by a constant appeal to a just and delicate ba- lance, he discovers that each kind of combination is governed by a definite weight. For example, if he experiment upon 1000 parts by weight of Chloride of sodium, he will invariably obtain 600 parts of Chlorine and 400 parts of Sodium ; if upon 1000 parts of Carbonate of lime, he will first obtain 440 parts of Carbonic acid, and 560 parts of Lime ; if he pursue the ultimate analysis of these com pounds, he will obtain from this quantity of Carbonic acid 320 parts of Oxygen, and 120 parts of Carbon; and from the Lime, 160 parts of Oxygen, and 400 parts of calcium. If the chemist, by well-known agents, excite the above substances to combine as Primary, or Secondary compounds, they will only do so in such weights, he has no power of forcing them to combine according to his caprice ; a grand and immutable law of Definite weight presides over every analytical and synthetical operation. Chemistry, thus tending to the discovery of the B 5 10 INTRODUCTORY. elements of things, and of the laws by which they are controlled, presents its votary with powerful illustra- tions of the Truth, that " a just weight and measure are the Lord's ;" that " a just weight is His delight ;" that " He comprehended the dust of the earth in a measure, and weighed the mountains in scales, and the hills in a balance." The chemist endeavours to act as the humble and faithful interpreter of the wonders of the Creation, and everywhere discovers proofs of the power and goodness of God : what a glorious contrast does this exalted occupation present, to the sordid pursuits of the darker ages, when the transmutation of metals, and the pro- duction of an elixir of immortality, formed the vain and presumptuous hopes of the experimenter ! Throughout the Four Seasons, it must be obvious that Air, Water, Earth, and Heat, are ever active and important agents, and therefore a general account of their chemical habitudes demands a place in these introductory pages, to facilitate our future proceed- ings. The science of chemistry is founded upon the labo- rious yet certain practice of EXPERIMENT, and by its aid the Air, or Atmosphere, is proved to consist chiefly of two elementary gases, named Oxygen and Nitrogen ; they are strongly opposed in their chemical characters, for the former will support life, and flame, for a time, but the latter will destroy both, instantaneously. The chemist can combine Oxygen and Nitrogen, in INTRODUCTORY. 1 1 definite proportions, by weight, and produce Five com- pounds, as shown in the following statement : I. Oxygen, 3640+Nitrogen, 6360=10000 Nitrous oxide. II. Oxygen, 5333 -[-Nitrogen, 4667=10000 Nitric oxide. III. Oxygen, 6320-f Nitrogen, 3680=10000 Hyponitrous acid. IV. Oxygen, 6960+Nitrogen, 3040=10000 Nitrous acid. V. Oxygen, 7410+Nitrogen, 2590=10000 Nitric acid. I. Is an invisible vapour, called Nitrous oxide, to denote that it is not acid. II. Is an invisible gas, called Nitric oxide, to denote that it is not acid; and by the termination ic, that it contains more oxygen than the former. III. Is an acid liquid, called Hyponitrous acid, to de- note that it is intermediate with Nitric oxide and Nitrous acid, and below the latter in its propor- tion of oxygen. IV. Is an acid vapour called Nitrous acid,- to denote that it contains less oxygen than Nitric acid. V. Is called Nitric acid, to denote its large amount of oxygen ; the chemist has not determined if nitric acid be solid, liquid, gas, or vapour, but he is certain of its composition. These five compounds are deadly poisons to ani- mated beings, and yet they contain the elements of Air, which is the pabulum of life, how can this be ? The chemist replies, that to constitute Air, these elements are not combined, they are only mixed, and very nearly in the following weights : 12 INTRODUCTORY. Oxygen, 2300 + Nitrogen, 7700 = 10000 Air. These elements are rendered incapable of combining under all ordinary circumstances, they remain inti- mately and uniformly mixed to constitute the first, and the last food of life. But when the lightning goes forth, as the terrible display of natural electricity in the thunder-storm, the chemist discovers that the elements of the air in the immediate passage of the flash, are suddenly excited to combine and produce the poison, called nitric acid ; but this effect is miraculously restrained by the Hand of Providence, and not permitted to ensue throughout the entire volume of the air, or inevitable would be the destruction of every living thing ; and the relatively minute portion of poison thus formed during a long protracted discharge of lightning, is soon infinitesi- mally diffused throughout the untainted volume of air, or absorbed by the waters, or neutralized by the earth, and thus deprived of virulence. The animated creation is thus miraculously pre- served amidst the elements of destruction ; true indeed is the solemn warning, that " in the midst of life we are in death." These extraordinary elements, Oxygen and Nitrogen, form the chief volume of the Atmosphere during all the vicissitudes of the Four Seasons; but a rigid analysis likewise proves the simultaneous existence of small quantities of two . compounds, named Carbonic acid, and Water. Reference has been made to the com- INTRODUCTORY. 13 position of Carbonic acid, and when obtained from the air or other sources, in a pure or insulated state, it is fatal to animal and vegetable life, and is materially heavier than either Oxygen or Nitrogen; but as mingled with these elements, and the vapour of water, to con- stitute Air, it has a beneficial influence, and never subsides as a distinct mephitic stratum. The chemist discovers that Water is a compound of Oxygen and Hydrogen, an elementary gas thus named in allusion to its producing that substance ; the following are the weights in which these elements combine : Oxygen, 8890 + Hydrogen, 1110= 10000 Water. It does not exist in the mixture of Oxygen, Ni- trogen, and Carbonic acid, as Liquid water, but as Vapour of water, produced by the all-prevailing agency of solar heat ; thus it is wafted over the surface of the globe, until local changes of temperature cause its condensation, and fall, as rain or snow, and other well- known forms, according to the season. The result obtained by a minute analysis of Air, pre- sents the following weights of its elementary and com- pound constituents. Nitrogen 7555 Oxygen 332 Carbonic acid .... 10 Aqueous vapour . . . . 103 10000 14 INTRODUCTORY. This wondrous medium, or atmosphere, containing the elements of life and of destruction, enfolds the earth, as a mantle ; and although the chemist cannot experimentally determine its limit, he can determine its total weight, and is perfectly astounded at its im- mensity ; it is expressed by the sum of Five quatrillions, two hundred and eighty- seven trillions, three hundred and fifty billions of TONS ! The accompanying statement will show the relative proportions by weight, in which the elementary and compound constituents of Air are blended, to produce this gigantic sum total. Nitrogen . . . 3.994.592.925.000.000 Oxygen .... 1.233.010.020.000.000 Carbonic acid . . 5.287.305.000.000 Aqueous vapour . 54.459.705.000.000 TONS 5.287.350.000.000.000 Both the chemist and the physiologist concur in stating, from the results of numerous experiments, that no elementary gas, no compound gas, no elemen- tary vapour, no compound vapour, no other mixture or combination of elementary or compound gases, or of elementary or compound vapours, can support the respiratory functions of the animated creation, like Atmospheric air; and its ultimate analysis presents Four elements, namely, Oxygen, Nitrogen, Carbon, and Hydrogen. INTRODUCTORY. 1 5 Water is presented, throughout nature in lavish abundance, it occupies more than three-fourths of the superfices of the globe ; but philosophers cannot de- termine the total weight of this enormous bulk of water, as they can that of the atmosphere. The chemist discovers that water, as it falls from the clouds, invariably contains air, and sometimes a com- pound of hydrogen and nitrogen, called ammonia, to which much of its fertilizing power may be referred : he further discovers that the water of springs, brooks, and rivers, always contains portions of earthy and saline compounds, particularly common-salt, although not sufficient to destroy its freshness, and unfit it for the beverage of man and animals. The chemist discovers, that the water of springs in certain localities, is so impregnated with gaseous, earthy, and metallic compounds, as to be unfit for constant use as a beverage, yet occasionally taken, it exerts considerable influence in palliating or remov- ing some forms of disease ; and pursuing his investi- gations regarding the water of the ocean, which, when drank, soon causes delirium and death, he discovers it to derive its strong saline taste from a proportion of common-salt, far exceeding that in ordinary spring brook, or river water; and its bitter taste, from an inferior proportion of compounds of lime and mag- nesia. But during all experiments and researches upon water, the chemist cannot find a solitary instance of its occurring, in nature absolutely pure, or solely 16 INTRODUCTORY. consistent of the elements, Oxygen and Hydrogen ; he can render it so, artificially, and then he finds it is perfectly unfit for the beverage of man and animals ; he has, therefore, reason to admire the wonderful pro- vision of the Creator, in ordaining water to contain principles, in addition to its own elements, which are indispensable to the support of vitality. V The solid parts of the globe, which are popularly called the Earths, as, for example, Lime, Sand, Clay, and Magnesia, are, in fact, compounds of Oxygen, with the metals, Calcium, Silicium, Aluminum, and Magnesium ; they are rusts of these metals, or metallic oxides, and as such they are styled in refined chemical language, but they will be spoken of as Earths in this inquiry, and the following statement will show their composition. I. Oxygen, 286 + Calcium, 714 = 1000 Lime. II. Oxygen, 500 + Silicium, 500 = 1000 Sand or Silica, III. Oxygen, 480 -J- Aluminum, 520 = 1000 Clay or Alumina. IV. Oxygen, 400 + Magnesium, 600 = 1000 Magnesia. These earths are sometimes found very pure, but more frequently mingled together, or combined with other metallic oxides, as, for example, those) of iron and potassium: thus common clay contains^ a large portion of alumina, to which its tenacity and plasticity with water is entirely referrible ; but it also contains portions of silica, and oxide of iron, which cause its grittiness and colour ; and lastly, oxide of potassium INTRODUCTORY. 17 or potash, which renders it fertile for the growth of corn. The chemist discovers that the earths are likewise presented by nature, in combination with Acids con- taining the inflammable elements, Carbon, Sulphur, and Phosphorus. These are respectively called Carbonic, Sulphuric, and Phosphoric acids, and their combina- tions with the earths are called Carbonates, Sulphates, and Phosphates. Thus, for example, Chalk, Limestone, and Marble, are Carbonates of lime ; Gypsum and Alabaster are Sulphates of lime; and Bone-earth contains Phosphate of lime and phosphate of magnesia. The earths, when absolutely pure, are solid, incom- bustible, infusible, excepting in the most intense de- gree of artificial heat that can be commanded ; they are insoluble in water, with the exception of lime v When the earths naturally occur in various states of purity, they have the foregoing characters in a very eminent degree ; their natural and artificial compounds with each other, with several metallic oxides, and with the above acids, in the generality of instances are simi- larly characterized. ' ' A general notion of the manner in which earths, earthy and saline compounds, organic matters, and water, are mingled together to constitute a soil, may be gained from the following statement, which sup- poses that 1000 parts by weight of a soil, have been submitted to proximate analysis. 18 INTRODUCTORY. 1000 Parts of Soil. Parts. Large loose stones and silicious gravel . 143 Fine silicious sand . . . . . . . 572 Aluminous earth 75 Carbonate of Lime 47.5 Carbonate of Magnesia 7.5 Sulphate of Lime 5 Oxide of iron 12.5 Salts of sodium and potassium .... 10 Phosphate of Lime 2.5 Vegetable and animal manure .... 72.5 Water 52.5 1000.0 The more particular examination of soils, as regards their relative fertility, will be given hereafter ; and it is by a correct knowledge of the nature of the pure earths, and their compounds, and various mixtures with organic and inorganic matters, that the chemist is enabled to afford valuable information to the agri- culturist, and thus assist him materially in augment- ing the produce of the autumnal harvest. It is true that every man can cause ground to bear corn, yet it will only grow in abundance, and of the best quality, where sown after rational principles, and the labours of the agriculturist are profitable and useful, in proportion as he is acquainted with the rudi- ments of chemical science. Air, water, and earths, are inorganic substances ; INTRODUCTORY. I 9 they neither grow nor are they reproduced ; they have no period that may be called their perfection ; but Seeds, upon which the hopes of the agriculturist are founded, are Organic bodies, produced by the powers of vitality ; they have periods of growth, ma- turity, death, and decay. Can the chemist extend his analytical researches to seeds, and other organic bodies, and ascertain their elements, as he can those of air, water, earths, and in- organic matters ? He can : all organic bodies admit of analysis, and with reason it might be imagined, that hundreds of elements would be elicited by such an extensive investigation of the diversified array of animated nature. How different is the fact obtained by experiment, for it teaches the chemist that only Four elements enter into the essential constitution of all organic productions ! These Four elements are Oxygen, Nitrogen, Carbon, and Hydrogen, or the ultimate elements of the atmo- sphere. This statement may appear incredible, but it is an experimental fact, and moreover, some vegetable and animal structures do not even contain nitrogen. This discovery presents a magnificent illustration of the power and goodness of God, who created these elements, and controls their arrangement by definite and unerring laws, into countless forms of beauty and utility, for the adornment and enrichment of the earth. It must be remembered that such combinations are under the influence of the incomprehensible agency of vitality, and towards it man can make no approaches. 20 INTRODUCTORY. As a chemist, Le is permitted to analyse the air, the water, the earths, and to recompose nearly all, in the same weights of their constituents, as those in which they were presented for his examination ; he is likewise permitted to analyse all organic bodies, and to obtain their three or four elements, in weights, the sum total of which exactly equals the original weight of the body subjected to experiment; but he is not permitted to exercise synthesis. He may place these elements toge- ther, in every possible manner that human skill can suggest, employ upon them the most powerful exciting agencies at his command, they will neither combine to produce the original body, nor the slightest resem- blance of an organized body. The chemist thus meets with an impassable barrier to synthetical operations, and upon all occasions when he encounters recondite matters, which do not admit of elucidation by his own limited and insignificant ac- quirements, he does not perplex his mind with pre- sumptuous efforts to tear the veil of mystery that he cannot raise, but humbly yields submission to the Truth "that the things which are impossible with man, are possible with God." " There is no part of chemistry which abounds in more extraordinary disclosures than that connected with the composition and properties of organic pro- ducts. It teaches us that, infinitely diversified as they apparently are, none of them seem essentially to con- tain or include more than three or four elementary substances." INTRODUCTORY. " Fifty- five elements are presented to us by nature : of these, only four are employed in the elaboration of all the wonderful creations of living matter." " Flowers and perfumes, leaves and wood, food and poisons, flesh, fat, hair, feathers, when the chemist comes to look at all these, he finds that such wonder- ful diversity is the result, not of the employment of a multiplicity of elements, but of the combination of a very few, in varied proportions, and under the influ- ence of vital agency." To render this extraordinary fact still more impres- sive, a tabular statement is here subjoined of the ana- lysis of ten proximate principles, Gum, Sugar, Starch, Lignin or woody fibre, Wax and Gluten are of vege- table origin ; Gelatin, Albumen, Fibrin, and Fat, are of animal origin. Gum. Carbon 414 Hydrogen 65 Oxygen 521 Sugar. Starch. Lignin. Wax. 421 428 500 806 64 63 56 114 515 509 444 80 1000 1000 1000 1000 1000 Gluten. Gelatin. Albumen. Fibrin. Fat. Carbon 557 Hydrogen 78 Oxygen 220 Nitrogen 145 483 516 520 790 80 75 72 118 276 259 250 92 161 150 158 000 1000 1000 1000 1000 1000 22 INTRODUCTORY. From this statement, we discover that the proximate principles of Vegetables, with the exception of Gluten, contain but Three elements, and that those of Animals, with the exception of Fat, contain Four ; and whilst its composition is closely analogous to that of most vege- table principles, that of gluten approximates to the composition of most animal principles. The important consequences of these discoveries will become apparent at a future stage of our inquiry. All ponderable elements, and the host of natural and artificial compounds in which they exist, are sub- ject to the imponderable agencies of Light, Heat, and Electricity, which modify and control all chemical changes, but more particularly those of organic pro- ductions. The chemist is totally ignorant of the ultimate na- ture of these imponderable or ethereal matters; he, cannot experiment with them as with solids, liquids, gases, or vapours ; he is only acquainted with them when acting upon such ponderable forms. Solar light enters the confines of the atmosphere, permeates its transparent volume with incredible velo- city, and illuminates the solid opaque earth. Such light is absolutely necessary for the welfare of the animal and vegetable creation ; its presence stimu- lates a healthy action of their vital functions, and causes the elaboration of elements that enter into the consti- tution of organized structures ; whilst, in the prolonged absence of light, morbid and fatal changes will gene- rally ensue. 7 ' INTRODUCTORY. 23 The power and goodness of God are magnificently displayed in solar light, it being, not of one colour, but of seven colours, a fact that we behold with ad- miration and gratitude, in the stupendous arch of varied light, which so frequently spans the heavens as the rainbow. "Look upon the rainbow, and praise Him that made it, very beautiful it is in the brightness thereof ; it compasseth the heavens about with a glorious circle, and the hands of the Most High have bended it." .. The very limited extent to which scientific inquirers can reason and experiment upon an element so incon- ceivably attenuated as solar light, leads them to con- sider that the bow may be caused by the coloured re- fraction of light by drops of rain, for it is found that when the solar rays are caused to impinge upon watery spray, similar colours to those of the rainbow appear, although microscopic in comparison with its gigantic span. These colours likewise appear when the solar beam is refracted by the denser solid medium of flint glass, a triangular prism of this invaluable compound, pro- bably elicits the phenomenon in the greatest perfection and beauty attainable by human skill ; hence the term Prismatic colours applied to the Eed, Orange, Yellow, Green, Blue, Indigo, and Violet rays of light which constitute the spectrum. When these Seven coloured rays are collected to a focus, by a glass lens, they coalesce into colourless 24 INTRODUCTORY. light, and are therefore presumed to constitute such ethereal agent. The chemist discovers that the coloured rays are possessed of different chemical powers ; that the red have the highest, and the violet the lowest temperature ; that the former have hut little, and, in some instances, no tendency to promote chemical changes, whilst the latter are most powerful excitants of such phenomena. If solar light were of one colour, or mono- chromatic, all terrestrial objects would appear of such colour, or, if incapable of reflecting it, they would appear black, we should not be charmed with the varied and gorge- ous hues of the creation ; but light being seven- coloured, or chromatic, and the surfaces of objects being differently constituted, both physically and che- mically, they are capable of reflecting, in some cases, all the rays, and thus of appearing white ; and, in other cases, of absorbing them all, and thus of appearing black ; but more generally of reflecting certain simple rays, or mixtures of rays, in preference to others, and of thus impressing the eye with numerous shades of colour. Light, is accompanied by heat during its swift pas- sage from the sun to the earth, but heat is an impon- derable element, and therefore the chemist is obliged to rest content with examining its effects upon terres- trial objects; and although he can artificially elicit heat by various experiments, he is even then ignorant of its nature. INTRODUCTOKY. 25 " In all our excursions over the surface of the globe, innumerable objects excite our admiration, and contri- bute to inspire delight; but whether our gratitude is awakened by the verdure of the earth, the lustre of the waters, or the freshness of the air, it is to the bene- ficial agency of heat, under Providence, that we are indebted for them all. " Without the presence and effects of heat, the earth would be an impenetrable rock, incapable of supporting animal or vegetable life ; the waters would be for ever deprived of their fluidity and motion ; and the air of its elasticity and utility together. " Heat animates, invigorates, and beautifies all na- ture; its influence is absolutely necessary to enable plants to grow, put forth their flowers, and perfect their fruit ; it is closely connected with the powers of life, since animated beings lose their vitality when heat is withdrawn. " Such is the universal influence of this powerful agent in the kingdoms of nature ; nor is this influence diminished in the provinces of art ; it is with the aid of heat that rocks are rent, and the hidden treasures of the earth obtained ; matter is modified in countless ways by its agency, and rendered subservient to the uses of man ; furnishing him with useful and appro- priate implements, warm and ornamental clothing, wholesome and delicious food, needful and effectual shelter." Solar heat, and artificial heat, are indeed pow- erful agents; the 'former most particularly, as con- c 26 INTRODUCTORY. nected with the varied phenomena of the Four Seasons, and with one exception, to he reserved for minute con- sideration hereafter; all substances enlarge in hulk when heated, and contract when cooled. These temporary expansions hy heat, and contrac- tions by cold, are hut small in the generality of closely- compacted solids, great in mobile liquids, and greatest in attenuated gases and vapours. Some substances, especially the metals and their ores, have the power of conducting heat with great facility throughout their entire mass, so that it matters not where heat he applied, they will in due time be equally elevated in temperature. Other substances, especially the earths, and their compounds, generally absorb heat rapidly upon their surfaces, and only conduct it very slowly and imper- fectly throughout their mass, therefore heat chiefly remains upon the part to which it is originally ap- plied. Lastly, some substances, especially air and water, will not admit of being heated by conduction. The chemist accordingly classes the foregoing sub- stances, as conductors, imperfect conductors, and non- conductors of heat ; and he has reason to admire and appreciate the beneficial results that ensue from their several habitudes with this agent. The transparent atmosphere is so wonderfully constituted, as to allow the rays of the sun to pass through it, without absorb- ing their heat ; but upon reaching the opaque surface of the solid earth, it immediately absorbs heat, and INTRODUCTORY. 27 becomes elevated in temperature ; then the air incum- bent upon it obtains heat by contact, and is thus ren- dered lighter, volume for volume, than it was ; it rises, and its place is immediately occupied by another and colder stratum of air ; this becomes heated, and lighter, and in its turn rises, whilst colder air falls, and thus by ascending and descending, or convective cur- rents, the atmosphere becomes heated from the earth, and not by direct conduction from the sun. Thus winds are produced by the continued motion of cold air to supply the place of that which ascends in a heated state. Transparent water is heated by the warm air that blows over its surface, and npt by direct conduction of heat from the sun ; but these matters will be particu- larly explained in their proper season : it may, how- ever, be remarked, that if earth, air, and water, were conductors of heat, the animated creation could not exist ; the sun would immediately heat the earth intensely, the water would wholly disappear ; the air, instead of being a temperate mantle, would become a scorching shroud, or, in the more emphatic language of Scripture, " the heaven would be as iron, and the earth as brass." Electricity is the third imponderable element of whose ultimate nature the chemist is entirely ignorant, but he has every reason to suppose that it is univer- sally present with light and heat ; it is not manifest to the senses unless its equilibrium be disturbed either naturally or artificially, and then in the former case its 02 28 INTRODUCTORY. mysterious power is displayed as flashing lightning, and in the latter as snapping sparks. The chemist can control electricity to a certi.in extent, for he discovers, as in the case of heat, that some substances have the power of conducting, others of retarding it, or of arresting its passage. Air is a non-conductor, water and earth are con- ductors of electricity ; and when it has accumulated in clouds to a certain degree of intensity, the flash of lightning announces its escape by rending asunder the non-conducting air to meet the conducting media of the waters and the earth. Such is a general introductory statement regarding the elements of natural productions, and the agents unto which they are subject; we may now proceed to examine the Principal Chemical Phenomena of the Four Seasons ; and throughout them all, we shall be presented with proofs of the Power and Goodness of God, " who hath created these things, that bringeth out their host by number; He calleth them all by names by the greatness of His might, for that He is strong in Power ; not one faileth." CHAPTER I. SPRING. How beautiful is the Creation ! how full of harmony, order, and proofs of the power and goodness of God ! Abundantly as these are presented throughout the Four Seasons, they are never more obvious than in Spring, when verdure clothes the earth, as the snow of Winter vanishes under the genial influence of solar heat. A.11 things rise in praise of the Creator, and He beneficently ordains them to be as salutary to our bodies, as they are delightful to our senses : our fer- vent emotions of gratitude are called forth by this wondrous change of season; and if we cultivate an acquaintance with its glad attributes, and humbly endeavour to interpret the unerring laws by which they are governed, we gain a valuable fund of knowledge, which is calculated to make us not only wiser, but better, as it leads us to the highest appreciation of the miraculous workings of Providence. The germination of seeds, and the growth of plants, present " the servant and interpreter of nature " with 30 SPRING. several phenomena which admit of elucidation through the science of Experimental Chemistry, and accord- ingly these will first claim our attention ; it will next be directed to an examination of the manner in which the earth receives and retains water, for the welfare and support of vegetation ; and having ascertained this point, we shall proceed to examine the conditions under which water accumulates in the atmosphere, ta form the showers of Spring, and its fertilizing agency even when it does not so descend upon the earth ; the action of heat and cold upon the atmosphere will then claim our notice, and the changes which it sustains by respiration, germination, and combustion; we shall then pass on to examine some of the habitudes of the earth, in retaining heat, and the beneficial results which ensue from these ; lastly, resuming the examina- tion of vegetable growth, a few of the peculiar func- tions of plants will occupy our attention, as prepara- tory to others which will present themselves in the ensuing season of Summer. First, as regards the Chemical phenomena, attendant upon the germination of seeds, and the growth of plants. If we examine a seed, and for our general purpose no better can be selected than a garden bean, we find that its external membrane, or covering, is easily removed, and then it may be divided into two distinct portions, which are called Cotyledons; these enclose the germ, or embryo, whose largest part, or that most embedded in the Cotyledons, is called the plumula, SPRING. 31 and its smallest part, or that almost escaping from them, the radicle. Fig. 1. Upon tasting the cotyledons, we find them amy- laceous, and insipid, for chemical analysis proves them to consist chiefly of a proximate vegetable principle called Starch, a compound of Carbon, Oxygen, and Hy- drogen, wonderfully elaborated by Nature into the form of the seed, and having no tendency to change under ordinary circumstances during the lapse of ages. If we cast a seed of this kind into the earth, no matter in what position, and carefully examine it from day to day, we find that it sustains changes which are not presented by an equal bulk of inorganic matter similarly situated. The seed swells considerably ; its external membrane bursts, an upward and a downward shoot protrude Fig. 2. from the cotyledons, the former being an enlarge ment of the plumula, the latter that of the radicle. SPRING. In a few days the plumula will emerge from the soil, whilst the radicle penetrates much lower than the original position of the seed; and then it will be found, upon tasting the cotyledons, that they are no longer amylaceous or insipid, but sweet and mucilagi- nous, because the proximate element called Starch, has arranged its elements, Carbon, Oxygen, and Hy- drogen, to constitute two new proximate elements? called Sugar, and Gum. At the same time we shall observe, that numerous vessels are disposed throughout the cotyledons, for the purpose, as it is presumed, of conveying these princi- ples as generous nutriment to the newly-born plant, until it has acquired sufficient maturity to procure other support for its welfare from the air and the earth ; and when this happens, the saccharine and mucilaginous principles entirely disappear from the cotyledons ; they decay, and allow the plant to remain entirely dependent upon the leaves which are developed in the plumula, and the fibres of the radicle, for its future sustenance. This silent and miraculous phe- nomenon of Germination, will only ensue under certain conditions ; in the first place darkness is required, ^ejfflbg?- an d it is ensured by the opacity of the soil in which the seed is cast ; yet when the germ has acquired p ig 3 SPRING. 33 sufficient strength to burst, and rise as the plumula from its terrestrial prison, and to meet the air, light immediately becomes essential for its health and growth towards maturity. In the second place, the seed requires a due temperature, which must always exceed 32 degrees, and never exceed 100 degrees of Fahrenheit's thermometric scale; it also demands a liberal supply of water, either in the liquid or the vaporous state, and perfect access of air. These agents, ponderable and imponderable, must be admitted, not singly, but conjointly ; for example, plant the seed in the earth, allow it the free access of water and air, and it will not germinate if the tempera- ture of the earth be reduced to 32 degrees; neither will it germinate between such temperature and 100 de- grees, though liberally supplied with water if the access of the air be prevented. Bury the seed deep in the earth, and so situate, it will neither germinate nor decay, it will remain un- changed or dormant ; but remove it near the surface, so that the porosity of the soil may admit of the just and naturally combined agencies of air, water, and heat, it will quickly start into life, and its emerging plumula become verdant under the influence of solar light. Knowledge of the above fact enables the Chemist to explain why the surface of barren earth newly turned or excavated, so frequently becomes covered with luxu- riant vegetation ; seeds were buried deep in the earth, probably by natural convulsions in past ages, and thus c ft 34 SPRING. rendered incapable of undergoing the changes requisite for their germination to ensue ; but these are imme- diately excited when the combined influence of the foregoing agents is admitted. Common experience teaches us that seeds must be sown at the depth of a few inches in the earth, or they will never put forth shoots above its surface ; the chemical reason of this practice is, that they may gain a requisite supply of air, water, and heat through its pores. Thus loamy and calcareous soils, being porous and light, admit air, water, and heat to seeds, and are generally fertile ; whilst clay-land, being compact and adhesive, opposes the admission of such agents, and frequently is not so productive ; indeed it often retains water in such excess that seeds become rotten and worthless. So far as the Chemist can ascertain by experiment, it appears to be chiefly by the absorption of water in properly tilled soils, that the cotyledons of a seed are enabled to increase in bulk, to put forth a plumula and a radicle, and to transmute their original consti- tuent starch into the new principles of sugar and gum : but of this matter hereafter. Let us now inquire how the genial showers of spring are received by the earth, to promote the germination of seeds and the growth of plants, that clothe its surface with verdure. Water is received by the earth in consequence of an attractive force existing between liquids and porous solids generally ; this force is denoted by the term SPRING. 35 Capillary Attraction ; it is a most important and ever active agent throughout nature. Capillary attraction admits of illustration by the following simple experiments, and after performing them they will be found explanatory of the manner in which water is received and retained by the earth. Take a piece of cane, about an inch and a half long, having its ends cut perfectly flat and smooth, hold it per- pendicularly and place a drop of water upon the upper end, the drop will soon vanish, and so will another, and another, until the lower end of the cane becomes wetted ; the water will not suddenly run through the pores of the cane, which are nearly as fine as hairs ; they retain it in oppo- x*7jv sition to the attraction of gravitation, and ^Ss this retention is called capillary, attraction of Fig. 4. the liquid, from the Latin word capilhis. This capillary attraction of the fine pores of the cane will also raise water in opposition to the attraction of gravitation, which would otherwise cause its fall. Take another piece of cane, similar in dimensions to that employed in the last experiment, place one end just below the surface of water, and, in the course of a few seconds the upper end will become wetted. In this instance capillary attraction is again superior to the attraction of gravitation, or the water would not rise above its ordinary level ; but still it is mere mecha- nical attraction, unaccompanied by chemical change ; the cane and the water are both of the same composi- tion as they were at the outset of the experiment. 36 SPRING. Sponge is a very porous substance, and when thrown into water it does not disappear or dissolve, because the water has no chemical attraction for the particles of which it is composed ; but it will mechanically attract and retain a very large quantity of the liquid, because sponge may be considered as consisting of myriads of small tubes interwoven or interlaced in all directions, and exerting capillary attraction for the water, as energetically as did the perfectly straight tubes or pores of the cane. Take another example, bearing yet more strongly upon the rationale of capillary attraction in nature ; a heap of sand consists of countless solid atoms of silica, not in absolute contact, as its examination by a magnifier will immediately prove, but separated by interstices ; or, in other words, a heap of sand is full of capillary pores, and these will become filled upon the addition of water. To render this more intelligible, or to represent, upon a magnified scale, the grains of sand and their inter- Fig. 5. stices, a large glass-may be filled with marbles ; whilst to denote the water (whose liquid particles, philosophers SPRING. 37 have likewise every reason to believe are not in absolute contact) a small glass may be filled with -tape-seed, this, when poured among the marbles, will fill their interstices, as the water did those of the sand. Place a shell or a piece of tile over the aperture in the lower part of a flower-pot, fill it with dry sand, then pour water upon its surface, and remark the large quantity that may be added before any portion flows from the aperture ; when it does so, the capillary pores of the sand are saturated, and the excess of water passes through, in obedience to the attraction of gra- vitation. When the mould in a flower-pot becomes excessively dry, we know that a great quantity of water may be poured upon its surface before any escapes from the aperture into the saucer beneath : this depends upon the capillary attraction of the pores of the mould, as just exemplified in the case of sand. Suppose the saucer become filled with water, we find it soon vanish if the plant in the flower-pot be in full vigour. Why does the water vanish ? Not by drying away., in the common meaning of the term, but in consequence of being attracted upwards as was the water by the porous cane to supply the roots of the plant, in which capillary vessels exist, and these transfer it to the stem, leaves, and flowers, from whose surfaces it ultimately dries away or evaporates ; therefore, in place of water- ing the surface of the mould, we very frequently pour 88 SPRING. water into the saucer, and depend, as now shown, upon capillary attraction for the rise of the liquid to main- tain the life of the plant. A porous substance has the power of raising water to a very remarkable extent, as may he proved by the following simple experiment. Select a lump of common salt, cut it with a saw into a regular shape, about six inches long, two inches broad, and one inch thick, then set it to dry perfectly before a fire. Fill a shallow plate with water, contain- ing sufficient red ink to impart a deep tint, and when the lump of salt is dry, place it upright in the plate, as here shown. Fig. 6. The salt, though apparently solid, is in fact full of capillary pores ; these will instantly attract the reddened water, and the salt will become powerfully stained to a very considerable height. The red ink is only added to render the result more striking than it would be if water alone were employed. In the course of a few seconds the salt will fall, on SPRING. 39 account of the chemical solvent power of the water un- dermining its lower part, or in other words, on account of the solid particles of the salt heing now received hy the interstices between the individual atoms of the water, which action is regarded as solution ; but it does not necessarily follow that a substance capable of exerting capillary attraction, should thus be soluble. A lump of porous sandstone, for example, similarly placed, will attract water, but will not fall, even when perfectly saturated, because it is an insoluble sub- stance. In nature, it frequently happens that capillary at- traction and chemical solution act simultaneously, and produce highly important results in conveying liquid manure to the roots of plants, by which their growth is wonderfully promoted. Vegetation on the margin of a brook, or pond, is generally more luxuriant than on the soil a few yards distant, because the porous earth of the bank attracts water abundantly, and retains it very forcibly even in time of drought. Whilst upon this subject, it may be stated, that much of the dampness in the walls of buildings depends upon the porous brick or stone-work of the foundations attracting water from the earth, and it frequently causes great damage and inconvenience. Oolite, or Bath-stone, as it is popularly called, is much employed in the decorative architecture of inte- riors, on account of the extreme facility with which it may be sawn and wrought into the most delicate tracery, and in such situations, if protected from damp, it will 40 SPRING. remain unimpaired for ages, as exemplified in many abbeys and cathedrals. Requiring little labour from the masons, and pro- ducing a most beautiful effect, architects have been occasionally tempted to employ oolite for external work ; but it is not durable, because water is rapidly absorbed by capillary attraction, and this extraordinary liquid, by undergoing expansions and contractions during the changes of atmospheric temperature, and more particularly expansion upon freezing ; flakes of the stones are violently detached, and the original sharp outline of the work broken down. This action silently, though certainly, continued for years, the sculptured work becomes undistinguishable. Turning from the works of Art to those of Nature, as more particularly connected with this inquiry re- garding the principal chemical phenomena of the Four Seasons, we discover capillary attraction to be a most active agent in retaining and administering a proper supply of water to the vegetation upon certain soils and rocks. In sandstone and limestone districts, which particu- larly abound in England, the absorption and retention of water for the support of vegetation is very remarka- able; we may see luxuriant plants, nay even forest trees, flourishing upon both rocks, the sandstone being porous, the limestone full of cracks or fissures, all readily imbibing water from the heavens, retaining or yielding it in proportion as it is demanded, for the sustenance of vegetable life. SPRING. 4 1 It is no uncommon thing in such districts to see plants and trees sending forth their roots into such cracks and fissures in search of moisture, and occasion- ally, when these cannot yield sufficient, the root will travel completely down the external -surface of the rocks to draw a supply from the more humid soil at their hase. Different is the case when compact, glassy granite is the prevailing rock of the country ; it is incapable of exerting capillary attraction for water, it cannot pro- vide itself with vegetable clothing, and therefore stands forth in bare and gaunt outline. When the careful agriculturist observes a particular district, in which vegetation naturally thrives, it be- comes a matter of importance with him to ascertain the cause of such fertility ; and upon application to the chemist, the desired information can be obtained. He can determine the average quantity of water ab- sorbed and retained by the soil under ordinary vicissi- tudes of the atmosphere ; he can determine the nature of its components, the exact proportions of sand, clay, calcareous compounds, organic, and other matters, that it contains, and can frequently artificially compose a soil equally fertile with that naturally found, or he can render it still more productive by the judicious and well-timed application of various organic and inorganic matters as manures. Chemistry thus becomes directly applicable to agri- culture, and many agriculturists have embraced its study, and by obtaining a sound knowledge of its 42 SPRING. rudiments, have been enabled to ameliorate the condi- tion of soils upon rational principles. " Plants, being possessed of no locomotive powers, can grow only in places where they are supplied with food ; and the soil is necessary to their existence, both in affording them nourishment, and enabling them to fix themselves in such a manner as to obey those mechanical laws by which their radicles are kept below the surface, and their leaves exposed to the free atmo- sphere." " As the systems of roots, branches, and leaves are very different in different vegetables, so they flourish in most different soils ; the plants that have bulbous roots require a looser and a lighter soil than such as have fibrous roots ; and the plants possessing only short fibrous radicles, demand a firmer soil than such as have tap-roots, or extensive lateral roots." The manner in which the chemist proceeds to analyse soils, cannot be particularly described in this examina- tion of the Chemical Phenomena of the Four Seasons, because it involves several agents whose action would not be readily understood ; it mainly depends upon presenting to the soil some element or compound that will attract away one of its components in preference to another. This may be tangibly illustrated, in the first place, as follows. Mix a heap of iron filings with an equal heap of sand ; let these represent two distinct components of a soil, and suppose that their ready separation is re- quired . SPRING. 43 If a strong magnet be thrust into the mixture, it will only attract the iron filings, and effectually sepa- rate them from the grains of sand; the mixture is thus immediately analysed. Mix common salt and sand ; it would be very diffi- cult, almost impossible, to separate, or to pick out, their individual grains, even if the eye were aided by a magnifier; and, as mechanical means fail, chemical means must be tried. Experience teaches us that salt will dissolve in water, and that sand will not : therefore if water be added to this mixture, and agitated, and poured off", and more water added and agitated, and again poured off, until it has no saline taste, the sand will remain, and by placing the solution of the salt in a warm oven, the water, or the chemical solvent, will dry away, and leave the salt. This is a simple example of analysis. Mix common salt, sand, and sawdust, how are these to be separated ? Add water to dissolve the salt ; the sand will subside, but the sawdust will float, or remain suspended in the solution ; and if this be poured upon a fine sieve, the sawdust will remain, whilst the solution passes through, and the salt can be obtained from it as before. This is another example of analysis. The chemist, therefore, by extensive knowledge of the habitudes of substances with water, and more powerful solvents, is enabled to separate the components of soils ; he adapts the process of analysis and the agents which he employs according to circumstances ; but invariably takes the utmost care to educe, or draw 44 SPRING. forth, the several components as they naturally exist in the matter upon which he operates, and not to disturb or modify the arrangements of their elements to produce new compounds. In illustration of the varied composition of soils fitted for the support of the different kinds of vegeta- tion ahove described, their chemical analysis is here subjoined. " A good turnip soil afforded eight parts out of nine of Silicious sand, and the finely divided matter (that remained suspended, like the sawdust upon the water,) yielded 63 parts of Carbonate of lime, 15 Silica, 11 Alumina, 3 Oxide of iron, 5 Vegetable and Saline matter, and 3 of Moisture. " A soil remarkable for producing flourishing oaks afforded 3 parts of Carbonate of lime, 54 Silica, 28 Alumina, 5 Oxide of iron, 4 Decomposing vegetable matter, and 3 of Moisture. " An excellent wheat soil gave three parts in five of Silicious sand, and the finely divided matter consisted of 28 parts of Carbonate of lime, 32 Silica, 29 Alumina, 1 1 Organic matter and Moisture. " Of these soils the last was by far the most, and the first the least, coherent in texture ; in all cases the constituent parts of the soil which give tenacity and coherence, are the finely divided matters, and they possess the power of giving those qualities in the highest degree when they contain much alumina." " A small quantity of finely divided matter is suffi- cient to fit a soil for the production of turnips and barley ; and a crop of turnips has been grown on SPRING. 45 a soil containing eleven parts out of twelve sand ; a much greater proportion of sand, however, causes sterility." " Vegetable or animal matters, when finely divided, not only give coherence, but likewise softness and penetrability ; but neither they, nor any other part of the soil, must be in too great proportion ; and a soil is unproductive if it consist entirely of impalpable matters. No soil is fertile that contains as much as nineteen parts out of twenty of any of the constituents that have been mentioned." The power that different soils possess of becoming heated by the solar rays, and of retaining heat, will demand future attention ; at the same time it must be evident that the general heat of the soil, particularly in spring, is of the highest importance to the rising plant. f( The moisture in the soil influences its tem- perature, and the manner in which it is distributed through, or combined with, the earthy materials, is of great importance in relation to the nutriment of the plant." " If water be too strongly attracted by the earths and their compounds, it will not be absorbed by the roots of the plants ; if it be in too great quantity, or too loosely held amidst them, it tends to injure or destroy the fibrous parts of the roots." The power of the soil to absorb water by capillary attraction depends in a great measure upon the state of division of its particles the more divided they are, the greater is their capillary power ; thus fine sand will 46 SPRING. absorb and retain more water than coarse sand, but each component of the soil has its particular capillary attraction ; thus vegetable matters seem to be more absorbent than animal matters when employed as ma- nures, and animal substances are more so, than com- pounds of alumina and silica, and these again are more absorbent than carbonate of lime and magnesia ; but the chemist states that these differences may depend to some extent upon their mechanical division, and upon the surface exposed. " Water, and the decomposing animal and vegetable matter existing in the soil, constitute the true nourish- ment of plants ; and as the earthy parts of the soil are useful in retaining water, so as to supply it in the proper proportions to the roots of the vegetables, so they are likewise efficacious in producing the proper distribution of the animal and vegetable matter of manure ; when equally mixed with it they prevent it from decomposing too rapidly, and by their capillary attraction the soluble parts are supplied in due proportions." The foregoing are a few of the facts relating to the philosophy of soils which have been discovered by the chemist ; many others will be presented as we proceed throughout the Four Seasons. Water appears to be the chief agent upon which plants depend for sustenance; and although seeds may be sown in a heap of insoluble sand, or of small lead shot, and will both germinate and flourish for a time, if such materials be kept moistened with water, expe- rience teaches us that they will do so more perfectly, 6 SPRING. 47 if some form of organic matter, in a decomposing state, be applied at the same time. Chemical analysis points out the reason of this ; and when we come to the con- sideration of a plant in its advanced stage of growth, the theory of organic and inorganic manures will be investigated. It is chiefly to the capillary attraction of the pores and fissures of the earth, that we are indebted for our supplies of spring-water ; when rain falls, a great portion is absorbed and retained by the surface for the main- tenance of vegetation ; whilst the excess not so em- ployed percolates or filters through the soil, abstracts various saline and earthy compounds, until it meets with an impermeable stratum of rock ; it then accu- mulates, and ultimately gushes forth at a lower level as a refreshing fountain. A question now presents itself to the chemist, how does water accumulate in the air to form the showers whose influence in promoting germination and growth in the Spring season, has passed into the proverb that " April showers bring forth May flowers ?" Experiment proves that such accumulation of water in the air is dependent upon a natural phenomenon called Evaporation, to denote a property possessed by the air, of causing the gradual wasting away, or the disappearance of the surface of water in the state of vapour ; and such evaporation is proportionate to the temperature of the air, and the rapidity of its move- ment over the surface of the water. Fill a broad shallow vessel with rain-water, collected 48 SPRING. before it has touched the earth, leave it uncovered and exposed to the air, in a situation sheltered from rain, and in the course of a few days of warm weather, the whole of the water will vanish, and leave the vessel perfectly dry. The rationale of this simple experiment may be thus stated ; air contains heat, and this incites the liquid water to change into vapour or steam ; this is lighter than air, but immediately blends with its volume, and is wafted away ; fresh portions of air blow over the surface of the water and convert it into vapour as before, until at length the whole of the liquid is thus consumed. Evaporation is constantly proceeding throughout nature, and the parent source of the fresh water that diversifies and enriches the surface of the earth, is the vast ocean, although this may not be directly evident, as its waters are well known to be saline, bitter, and poisonous. An experiment will elucidate this point ; collect a pint of rain-water, as already described; select two finger-glasses of equal size ; measure half a pint of the water into each of these, and in one of these portions dissolve half an ounce of common salt. Place both glasses in a situation sheltered from rain, but freely exposed to the air, and it will be found in the course of a few days, that the water has evaporated from both, and has left in the one glass no solid deposit, but in the other the original half- ounce of common salt. SPRING. 49 Pure water, solely consistent of Oxygen and Hydro- gen, and rain-water is very nearly pure is totally volatile by natural or artificial heat ; but common salt, and other saline and earthy compounds capable of being held in solution by such water, are not similarly volatile, they are fixed, and accordingly remain when pure water has evaporated. The waters of the ocean are saline and bitter from containing common salt, or chloride of sodium, and chloride of magnesium ; these compounds are fixed at all natural ranges of atmospheric temperature ; and accordingly when currents of air, or winds, blow over the wide expanse of the ocean, its absolutely pure water is incited to change from the liquid state to that of vapour, and thus to mingle with the air, to travel on the wings of the wind far inland, where, meeting with depression of temperature, the vapour chills or con- denses into drops, which the air cannot support, and therefore they fall through it as showers of rain, in obedience to the attraction of gravitation. These showers partly sustain the vegetable produc- tions of the earth, and partly accumulate to form springs ; these gush forth as fountains, as already stated, and soon meander as streams upon its surface, and gradually spread and flow onward as rivers, which ultimately reach the ocean ; from whence, by evapo- ration, the water again travels inland, again condenses as rain, accumulates as springs, rivers, and is again received by the ocean ; thus performing an incessant round of utility, and displaying the power and goodness of God. D 50 SPRING. A similar process of evaporation is constantly pro- ceeding from the surface of streams, rivers, lakes, and from the humid earth itself; the beneficial effects of this grand natural phenomenon are powerfully set forth in the Sacred Writings. " God maketh small the drops of water, they pour down rain according to the vapour thereof, which the clouds do drop and distil upon man abundantly, and the tree of the field shall yield her fruit, and the earth shall yield her increase." Again, " Thou visitest the earth and waterest it, thou greatly enrichest it with the river of God which is full of water, thou preparest them corn when thou hast so provided for it ; thou waterest the ridges thereof abundantly, thou makest it soft with showers ; thou blessest the springing thereof."" How eloquent, how beautiful, are these passages, how calculated to enlighten, adorn, exalt, and purify the mind of the philosopher, and lead him to extol with reverence and gratitude the Giver of every good and perfect gift ! The watery vapour thus present in the air is imbibed or attracted by soils with various degrees of energy, and is as much connected with their fertility as the direct absorption of the waters of the Spring showers. When this power of attracting aerial moisture is great, the plant is supplied with water, even in the absence of rain ; and the effect of the evaporation in the day is counteracted by the absorption of aqueous vapour from the air by the interior parts of the soil during the day, and by both the exterior and interior during night. The compact, tenacious varieties of clay soils which SPRING. 5 1 absorb a great quantity of the water of the shower, do not attract a great quantity of moisture from the air during the absence of rain, they become hard and the vegetation upon them is liable to wither away. Chemical analysis of soils distinguished for their power of attracting aerial moisture, points out that they contain sand, finely-divided clay, carbonate of lime, and organic manure, all so lightly bound together as to admit of the perfect access of air to a considerable depth ; and the great utility of carbonate of lime, or chalk, and manure, consists in their conferring attrac- tive powers upon the soil without rendering it adhesive and compact ; sand likewise will destroy tenacity, but it appears also to impair this attractive power. Soils which attract aerial moisture with the greatest avidity are always the most fertile ; and very simple experiments upon this subject will afford means of judging of the value or productiveness of land. One thousand grains of the soil collected during dry weather, may be placed on a metallic " hot- water plate/' filled with boiling water; then let the soil be stirred with a piece of thick wire, until no dew or steam is deposited upon a cold glass plate or tumbler held about an inch above its surface. This is a test that the soil is dried, and upon carefully removing it from the plate to the scale pan, the number of grain weights required to restore the original balance will indicate the quantity of water that was retained in the soil by capillary attraction, although it might have felt perfectly dry. D 2 52 SPRING. If this dried soil be left in the scale pan exposed to the air, it will gradually increase in weight by attracting aqueous vapour. The temperature of boiling water is directed to be used for the desiccation, because it is a good standard of comparison, viz. 212 degrees; and moreover such temperature will not alter the chemical nature of the soil by decomposing its organic consti- tuents, like the greater heat of an open fire or lamp. If it be required to ascertain the utmost quantity of moisture that the artificially dried soil is capable of attracting from the air, the following arrangement may be made. Place the soil in an earthenware saucer, supported on an egg-cup, in the centre of a large dinner-plate full of water ; place a bell-glass, or a large earthenware jar, over this arrangement, that the rim of the glass or jar may stand in the water contained in the plate. No liquid water can rise to the soil in the saucer, but the vessel with which it is covered contains air ; this will excite the water to rise in vapour, and become SPRING. 53 saturated ; a portion of this 'vapour will be attracted and condensed by the soil ; examine its weight after a few hours, then replace it as before ; and upon future examination, when it has ceased to gain weight, it may be considered to have attracted the greatest amount of water of which it is capable ; again place it upon the plate to dry as before, and the water will evaporate. Accurate experiments of this nature presented the first chemist who devoted his talents to agriculture with the following results. I. One thousand parts of a celebrated soil from Ormiston, in East Lothian, which contained more than half its weight of finely- divided matter, of which 1 1 parts were carbonate of lime, and 9 parts vegetable matter, when dried at 212 degrees, gained by exposure for an hour to air saturated with moisture, at a tem- perature of 62 degrees 18 grains. II. One thousand parts of a very fertile soil from the banks of the river Parret, in Somersetshire, under the same circumstances gained 1 6 grains. III. One thousand parts of a soil from Mersea, in Essex, worth 45 shillings an acre, gained 13 grains. IV. One thousand parts of a fine sand from Essex, worth 28 shillings an acre, gained 1 1 grains. V. One thousand parts of a coarse sand, worth 1 5 shillings an acre, gained only 8 grains. VI. One thousand parts of the soil of Bagshot Heath, gained only 3 grains. A very considerable degree of chemical attraction is 54 SPRING. discovered to exist between the aluminous portion of soils, and the organic matter of manure; thus it is preserved from too rapid decomposition, and from being carried away by water ; or, in other words, the soil remains rich, and capable of yielding nutriment to vegetation, whilst very silicious soils have little or no such chemical attraction, and therefore often remain poor, and incapable of yielding generous support to their produce. When soils are immediately situated upon a stratum of rock or stone, they become dry much sooner than when the sub-stratum is of marie or clay, which are strongly absorbent of water, and accordingly in some cases this is of great advantage to light sandy soils, as a reservoir of moisture upon which they can draw in time of drought for the support of their vegetation ; in other cases, where the external soils are too absorbent, this property is corrected by the sub -stratum being of sand or gravel ; this admits of the percolation of the excess of water. In limestone districts, the actual soil is a kind of marie, generally only a few inches deep, but highly ab- sorbent, and capable of supporting vegetation, because the limestone rock upon which it rests does not allow the water to escape by rapid capillary attraction ; whilst on the other hand, in sandstone districts, where the sandy soil, although absorbent, rests on absorbent sandstone rock, vegetation frequently suffers from the capillary attraction of the latter, withdrawing the water too rapidly ; indeed during the height of summer it is SPRING. 55 no uncommon thing to see the grass on sandstone dis- tricts parched and browned, whilst that on limestone districts is luxuriant and green. The student of Nature must bear in mind, that the enormous amount of fifty-four trillions, four hundred and fifty-nine billions, seven hundred and five millions of tons of watery vapour, is sustained by the atmo- sphere, which is a mechanical mixture of the elements Oxygen and Nitrogen, and the compound Carbonic Acid; and that during all the wonderful vicissitudes of the Four Seasons, the atmosphere is never sensibly altered in the due proportion of its constituents. Even when replete with solar heat, gained indirectly by convection from the warm surface of the earth, the air is simply expanded in volume, not altered in actual constitution ; and when from local causes it has parted with a certain degree of heat, or become cold, it is simply contracted in volume ; the pure abstract effect of artificial heat and cold upon air, is likewise attended by similar phenomena ; this can be experimentally proved by the following arrangement. Fig. 8. A Florence flask is placed with its neck dipping beneath the water contained in a glass ; the flask, 56 SPRING. although empty, in the ordinary acceptation of the term, is actually full of air ; this has no tendency to escape, because it is nearly of the same density and elasticity as the external atmosphere ; neither has the water a tendency to enter but a very little way into the neck of the flask, because it is opposed by the included air. Fig. 9. Apply the flame of a spirit-lamp very gently to the bulb of the flask, its thin glass immediately conducts the heat to the air, which expands in volume, or be- comes too large for the flask to contain, and accord- ingly a portion escapes from the neck, and bubbles through the water. Allow twelve or fourteen bubbles to escape, then remove the lamp, and as the flask cools, water from Fig. 10. the glass will gradually rise into the neck of the flask, and. at last become stationary. SPRING. 57 The explanation of this experiment is as follows : the air was expanded by heat, and a portion escaped, the remainder- then contracted by cooling ; and if the neck of the flask had not been under water, the exter- nal air would have entered to restore the original vo- lume ; but being thus placed, the pressure of the exter- nal air forces water upward, to supply the place of the air that escaped. Again apply the flame of the lamp to the bulb of the flask, until the expansion of the portion of air that it now contains, forces down the water nearly to the neck ; then remove the lamp, and upon cooling the water rises as before; again heat and again cool, to the same degree ; the air will invariably expand in the one case and contract in the other, and cause the water to fall and rise as many times as may be thought pro- per ; the same results will ensue upon alternate expo- sure of the flask to sunshine and shade. When the air has contracted for the last time, lift the flask with one hand, that its mouth may be only half an inch beneath the water, and take a cork be- tween the fingers of the other hand, and dip it beneath the water, to close the mouth of the flask; then it may be placed to stand upon a wooden or pasteboard ring, as shown in the next engraving ; the water that was in the neck of the flask, will now occupy part of its bulb, the air will occupy the remainder. Provide a small wax taper, about one inch and a half long, attach it to the end of a bent wire, rather exceeding the height of the flask ; kindle the taper, D 5 58 SPRING. remove the cork, and gently let the taper down the neck into the bulh of the flask, the flame will be found to continue for a time, with the same brilliancy as in the open air ; at last it is extinguished. Fig. 11. Fig. 12. These experiments are to prove that the pure and abstract effect of heat from the flame of the spirit- lamp conducted through the glass, is merely to cause expansion of the volume of the air, and that of cold, its contraction ; and that no chemical change in the pro- portion or nature of its constituents is effected, or the flame of the taper could not exist for a moment when plunged into air subjected to these ordeals. Whether the air be hot or jcold, it invariably con- tains the relative proportions of nitrogen and oxygen, which have been so frequently named; the latter element supports the flame of the taper for a time, but why does it not continue as it would do in the sur- rounding air ? Because actual combustion in air effects its decomposition, chemical changes are in- stantly summoned into activity, the chief elements of SPRING. 59 the wax taper are Hydrogen and Carbon ; at an elevated temperature both combine with Oxygen, to form in the one case Water, and in the other Carbonic acid ; and the flame or chemical change ceases when the given volume of oxygen is thus abstracted, be- cause these results of combustion, water and carbonic acid, and the liberated nitrogen, can yield it no support. The flame of the spirit-lamp employed for heating the flask, decomposed the free air for its support ; and in every case of the combustion of ordinary fuel, the air is similarly decomposed, the elements of the fuel combining with the oxygen, and producing water and carbonic acid, and liberating nitrogen, for which they have no attraction. Animal respiration effects changes upon atmospheric air, closely analogous to those of combustion ; air that has passed from the lungs is rendered perfectly unfit for the further support of life or flame; the fact as regards flame may be experimentally proved, by a very simple arrangement of apparatus, of which a sketch is given in the following page. Provide a glass vessel, in the form of a quart bottle, having the lower part removed ; withdraw the ground- glass stopper, and then place the glass, to stand in a shallow pan of glass or earthenware, containing about two pints and a half of water; introduce a lighted taper through the neck of the glass, and ascertain that the included air supports flame; then remove the taper, lift the glass perfectly out of the water, and 00 SPRING. move it backwards and forwards in the open air, to allow the products of the flame of the taper to escape ; the glass will thus become filled with fresh air, and is to be placed in the water as first directed. Fig. 13. Fig. 14. Make a deep expiration, or sigh, of air from the lungs, apply the lips closely around the neck of the glass, and draw air from it into the lungs ; as this is done, water will rise from the pan into the glass, and when it nearly reaches the lips, expel air from the lungs, until the water falls to its original level ; again inhale, and again exhale, then remove the lips from the neck of the glass, and immediately insert the stopper. Kindle the taper, remove the stopper, and introduce the flame; it will be extinguished as effectually as though plunged into water, not even a glowing spark will remain; therefore the air must have sustained some most extraordinary change during its brief contact with the lungs ; it is as follows. The chemist has discovered that Carbon is an SPRING. 61 element of the blood, and in that wonderful fluid, it has a powerful affinity for oxygen; therefore, when the blood is exposed to the action of air inhaled by the lungs, carbonic acid is instantaneously produced, whilst nitrogen is liberated, and both compound and element are to be found in the exhaled air, which is perfectly unfit for the further maintenance of life, or the support of flame. The manner in which these mephitic results of re- spiration are prevented from injuring vitality, presents another wonderful example of the Power and Goodness of the Creator. From experiments conducted upon Aqueous vapour. Nitrogen and Carbonic acid, the chemist discovers that the two first are lighter, and the latter heavier, than a similar volume of air of the same temperature ; there- fore, reasoning a priori upon this fact, the most ob- vious inference would be, that when they are con- jointly exhaled from the lungs, the aqueous vapour and nitrogen would ascend, the carbonic acid descend, and thus leave a mid-path for the inhalation of fresh air. How different is the action, induced by the refined and miraculous power of vitality ! The temperature of the living body exceeds that of the surrounding air ; the aqueous vapour ; nitrogen and carbonic acid are all exhaled from the lungs in a heated state ; the action of vital heat is not merely to expand the exhaled mat- ters to more than their original volume, but to render aqueous vapour and nitrogen still lighter than they 62 SPRING. are inherently, and to render inherently heavy car- bonic acid, equally light with them ; accordingly, all conjointly ascend swiftly from the respiratory organs, without vitiating the fresh air that immediately enters the lungs to discharge its functions, and in its turn to undergo similar change and disposal ! This fact admits of experimental illustration, by a very simple arrangement ; provide a cylindrical glass, about eighteen inches long and four inches in diameter, closed at one end, and its rim ground smooth ; also a piece of flat plate-glass, to cover this, and about a pint of lime-water ; this is prepared by adding an ounce of quicklime to a quart of water, contained in a glass bottle, corking it closely, shaking it several times, then allowing it to settle, and carefully decanting a part of the transparent find colorless liquid into a clean bottle, that must be provided with a glass-stopper. These preparations being completed, place the glass jar, with its rim, just below the lower lip, and breathe across it twice or thrice ; then cover the rim with the glass plate, and set the glass jar upon the table. Remove the stopper of the bottle containing the lime- water, then slide the glass plate a little on one side; that sufficient room may be made for pouring about half the lime-water into the glass cylinder ; it is then to be closed with the glass plate, and shaken two or three times, for the lime-water to come into contact with the air that it contains ; no change will be percep- tible in the clearness of the lime-water ; pour it away ; then hold the glass cylinder in an inverted position, SPRING. 63 with its rim just above the upper lip, and breathe be- neath it twice or thrice; close the jar with the glass plate, and place it to stand on the table ; then proceed as before, to pour in the rest of the lime-water ; and upon agitation it will lose transparency, and become milk-white. The chemist presents the following explanation or rationale of these experiments : lime is slightly so- luble in water, and in that state has a strong attrac- tion for carbonic acid, or, in technical terms, it is a test of carbonic acid, forming white carbonate of lime; this it will do slowly, even from the atmo- sphere. The aeriform matters were exhaled from the lungs in a heated state, therefore they did not fall through the air contained in the glass cylinder held with its rim upwards, as in the first experiment, but as- cended, and were lost in the surrounding air; had they fallen, the lime-water would have detected the carbonic acid, by the immediate formation of carbonate of lime or chalk. On the other hand, when the glass cylinder was held with its rim downwards, the heated exhalation from the lungs ascended, and displaced the air that it originally contained, and the lime-water immediately detected the newly-formed Carbonic acid, by combining with it to produce Carbonate of Lime or Chalk. Thus do the results of respiration and of combustion ascend and diffuse themselves throughout the atmo- sphere ; but they are destined to perform a ceaseless 64 SPRING. round of changes, the consideration of which will claim our attention at a future season ; for in the vast and perfect laboratory of Nature, nothing is lost, nothing is destroyed, or rendered worthless. The germination of seeds effects a chemical change upon the air, analogous to that now described ; this may be experimentally proved : place a handful of peas in a quart bottle, moisten them with water ; intro- duce a lighted taper for a moment, to prove that the air is unvitiated, then close the mouth of the bottle with a ground stopper, place it in a warm situation, and in a few days germination will ensue ; the produc- tion of carbonic acid, and the liberation of nitrogen, may then be proved by the extinction of the flame of the taper when introduced into the bottle. From experiments similar in principle to the fore- going, but conducted with the utmost skill and preci- sion, the chemist concludes, that combustion, respira- tion, and germination, are active in producing changes upon the nature of the air, and yet he fails in detect- ing any accumulation of mephitic matters; this is partly on account of the utterly insignificant volume of air only a few gallons upon which he can operate with analytical agents, and partly on account of a dis- covery that he makes regarding plants when in full vigour, and especially when under the direct influence of solar light, having the miraculous property of de- composing carbonic acid, and thus restoring the just balance of the atmosphere : this will demand future consideration. SPUING. 65 It must now be remarked, that the presence of un- combined oxygen is requisite for the phenomenon of germination to proceed ; and the chemist discovers that such condition is wonderfully provided for in the vast atmosphere, in which oxygen is only mingled with, and not combined with, nitrogen. The presence of uncombined oxygen is indispen- sable, that it may exert chemical affinity for a portion of the Carbon of seeds, and convert it into Carbonic acid ; and unless seeds thus lose carbon, they will not germinate. Place seeds in elementary nitrogen, or in compound carbonic acid, supply them with a due temperature and water, but instead of germinating, they will rot, because nitrogen has no affinity for carbon under these circumstances, neither has carbonic acid, as it already contains that element. A vigorous and healthy plant will soon wither and die, if placed in nitrogen or car- bonic acid, a phenomenon analogous to the cessation of animal life, when imprisoned in the same media. On the other hand, place seeds in pure elementary Oxygen, supply them with a due temperature and water, they will germinate with extreme rapidity ; but the action is morbid, for carbonic acid is formed at the expense of their carbon, in great excess, and they soon decay ; so when an animal is imprisoned in the same medium, respiration becomes hurried by the unnatural escape of carbon from the blood, and death quickly ensues, from the intense excitement into which the system is thrown. 66 SPRING. We have therefore reason to admire the power and goodness of God, in preserving the wonderful uni- formity in the constitution of the air in every terres- trial locality, and rendering it alike congenial to the welfare of animal and vegetable life. The negative properties of the large volume of nitrogen, restrain the positive properties of the small volume of oxygen ; this element is therefore slowly received by animals and vegetables, and without mor- bid excitement, because their secretory organs are compelled to perform the preliminary office of seeking and of separating it from a state of admixture with nitrogen. In connexion with this subject it may be remarked, that unless the large volume of negative nitrogen were existent in the atmosphere, all the materials which are now advantageously employed as sources of fire and artificial light, would consume with a degree of rapidity entirely disproportionate to their abundance upon the earth, or to the limited power of mankind to extract them from its strata. Another phenomenon of Spring, upon which the germination of seeds and the growth of plants depend, now demands attention. The thaws and floods of February leave the earth saturated with water, and unfit for the reception of seeds ; but the aerial currents, familiarly called " March winds," which reach the shores of England, cold and almost anhydrous from sweeping over the frozen con- tinent of Europe, are ordained to evaporate the surplus SPRING. 67 of such moisture, and to dry the soil sufficiently for the husbandman to commence his active labours. In the ensuing month, the evaporated water hovers above on the wings of the clouds, and ultimately con- denses into drops, and descends as the showers of April, to fertilize the earth from whence it ascended. Hence the origin of the proverb March comes in like a lion, and goes out like a lamb meaning that the weather at the beginning of the month is generally rough and boisterous, but in the end softened and subdued. Again, a peck of March dust is worth a king's ransom Why ? Because it indicates to the husband- man the probable continuance of dry weather, and upon the proper dryness of the soil, for the reception of the seed, at this season, that it may not rot and decay, depends the produce of the autumnal harvest. A dry and cold March never begs its bread, be- cause it prepares the earth for seed-time ; but a wet March makes a sad August because, urged by ne- cessity, the husbandman is obliged to cast seed into the ground saturated with the waters of February, and much is spoiled, and yields no crop in August. " The late Spring makes the fruitful year ;" for if very mild weather happen in March, nature assumes the aspect which properly belongs to April; buds and blossoms are pinched by the night frosts, and are either killed, or so injured that they produce neither flowers nor fruits in due season ; and hence the expression, ' March flowers make no summer bowers.' 68 SPRING. These proverbs must not be despised for their home- liness; they convey philosophical truths, and prove how accurately our ancestors studied the changes of the Four Seasons, though undirected by refined sci- entific knowledge. The chemist can offer no satisfactory explanation of the formation of clouds or rain ; but so far as his researches have been carried, they tend to the conclu- sion, that clouds and mists consist not of actual drops of water, but of myriads of excessively thin vesicles of water, similar to soap bubbles ; if clouds, mists, and fogs, consisted of drops, their fall would be rapid, - for mathematicians calculate, that a drop whose diameter amounted to a thousandth part of an inch, in obeying attraction of gravitation would acquire a velocity of nine or ten feet per second ; whereas we see clouds hover at a small elevation for hours ; and they are transported from the sea, lake, river, or marsh, from which they are raised, far into the country, or to the tops of mountains, where the requisite supply of mois- ture cannot be had in any other way. A scientific traveller in the Alps was enveloped in a mist which was almost stagnant ; he was greatly sur- prised at the size of the drops as he imagined them to be float slowly along instead of falling ; some of these were larger than the largest peas, and upon close examination proved to be vesicles of water of extreme tenuity. Clouds are probably formed when two vo- lumes of air of different temperatures, and both satu- rated with aqueous vapour, meet, and mix together ; SPRING. 69 but the cause of the production of vesicular vapour, and the fall of rain, remains a mystery. " He causeth the vapours to ascend from the ends of the earth : He hindeth up the waters in the thick clouds, and the cloud is not rent under them. He weigheth out the waters by measure. Canst thou tell the balancings of the clouds, the wondrous works of Him which is perfect in know- ledge ? " Leaving, therefore, these recondite yet beneficial phenomena, let us proceed with such as admit of interpretation through the medium of experiment. The porous surface of the earth has been shown to be peculiarly fitted for the reception of water, and its accumulation as springs; but this beneficial result could not ensue if the earth were a good conductor of heat, because such imponderable agent would then travel beneath the surface, and vaporize or dry up the whole of the water. The Creator, in His power and goodness, has consti- tuted the earth of materials that are incapable of con- ducting heat to any great extent, and therefore it chiefly remains at or near the surface, where it is needed for the welfare of animal and vegetable life. In the height of summer, when the surface of the earth is parching hot, if we excavate only a few feet beneath, it feeJs many degrees colder : and in the depth of winter, when frost is on the surface, if we proceed similarly, it feels several degrees warmer, and 70 SPRING. is always above 32 degrees, or the clods of earth thrown out by the spade would not be soft and moist, they would be hard and dry as ice. Thus, the imperfect, or bad conducting power of the earth as regards heat and cold, the terms being merely relative, is the reason that springs of water do not wholly escape as vapour in summer, and that they do not wholly become solid ice in winter. The coolness of a draught of water, drawn from a deep spring in summer, and its comparative warmth from the same source in winter, is a familiar example of the point in question ; indeed during the intense cold of winter, as the water of a deep spring gushes to the surface of the frosted earth, it actually steams, or in more chemical language, its warm vapour under- goes condensation by the cold air into which it escapes. At the depth of 100 feet from the surface, the temperature of the earth is the average temperature of the climate, and differs with the latitude; thus at Wadso, in Lapland, it is 36, at St. Petersburgh, 40, in England, 52, at Paris, 54, at Kome, 61, and at Cairo, 70. Air and water are non-conductors, and the earth is an extremely imperfect conductor of heat ; good con- ductors of this extraordinary imponderable agent do not, generally speaking, occur abundantly upon the surface of the earth, which they would render sterile, but as metallic treasures deeply hidden in its bosom, where there is no life, and from whence they are arti- SPRING. 71 ficially extracted, and rendered subservient, amongst thousands of other uses, to the formation of the ploughshare, and the sickle, for tilling the ground, and reaping its produce. A few experiments regard- ing the difference between good and bad conductors of heat, can be easily performed. Provide a metallic " hot-water plate," as commonly used at the dinner- table, then spread evenly fine iron filings over one half of its surface, and fine dry sand over tl^e other half, to the depth of three quarters of an inch, and place a lump of tallow about the size of a pea upon each ; lastly, pour boiling water through the hole in the rim of the plate, until it is filled. The iron and the sand are thus exposed to the same degree of heat, but they will not conduct it with the same facility, as will be proved by the tallow melting on the iron in the course of a few seconds, whilst it remains unmelted on the sand for many mi- nutes afterwards. The difference between the conducting power of a metal, an earth, and an earthy compound, may be further illustrated by the following simple and instruc- tive experiment : Provide solid cylinders, of these three materials, viz. iron, sandstone, and chalk ; let them be one inch in diameter, and six inches long, and perfectly flat at each of their ends. Place a cup, containing an ounce of tallow, upon the warm hob of the grate ; and when the tallow is perfectly melted, dip into it for about half an inch one end of the iron cylinder, and then lift it out ; a por- 72 SPRING. tion of tallow will adhere, and quickly become solid, because the iron, by good conducting power, deprives it of the heat of fluidity. Dip one end of each of the other cylinders in the same way ; they will attract, or absorb, a considerable portion of the melted tallow, and some time will be required before it will become equally solid with that on the iron cylinder, because sandstone and chalk have not sufficient conducting power" to deprive it of heat in a similar degree. Dip the end of all three cylinders again, and lift them out, and when the tallow becomes solid, dip them again, and lift them out, until they have all obtained an equal coating of tallow, then allow them to cool. Pour boiling water into a " hot-water plate," and place the three cylinders to stand upon it, at equal dis- tances, with their coated ends uppermost, as shown in the annexed sketch. Fig. 15. In the course of a few minutes, the iron will again prove its good conducting power, by melting the tallow ; but the sandstone and chalk will prove their bad con- SPRING. 73 ducting power by the tallow remaining solid during the whole time that the water is cooling down to com- mon temperatures. When heat is applied to the surface of good con- ductors, their entire mass will eventually become equally elevated in temperature ; whilst, on the other hand, with bad conductors, the heat will chiefly remain upon the point to which it is first applied, and the great part of their mass gains no increase of temperature. If, for example, the iron cylinder be felt when the whole of the tallow has fairly melted from its upper end, this will be found as hot as the lower end ; if the cylinders of sandstone and chalk be felt, their lower ends alone will be found hot, and by moving the finger slowly upwards, the limited extent to which they have conducted heat will become sensible. By reversing the arrangement of the last experi- ment, namely, by applying heat above, instead of beneath the cylinders, it can be proved that neither the conducting power of the iron, nor the non-con- ducting power of the sandstone and chalk, are in the least degree affected or modified. Let the iron cylinder be again coated with tallow, but pare away all from its circular extremity, that it may now stand firmly upon this, and have only a ring of tallow about half an inch wide around its circum- ference ; do the same with the cylinders of sandstone and chalk; then set the three, at equal distances, within a circle, similar in diameter to the bottom of the " hot-water plate," that they may form a tripod E 74 SPRING. for its support ; this arrangement must be made upon a steady table; then remove the plate, without dis- turbing the cylinders ; fill it with boiling water, and carefully replace it to stand upon them, as represented in the annexed sketch. Fig. 16. The three cylinders will now be subjected to heat, applied from above, instead of from below, as in the last experiment ; but this arrangement will cause no difference in their conducting or non-conducting power, as will be proved in the course of a few minutes, by the ring of tallow melting from the iron cylinder, whilst that upon each of the other cylinders remains solid as before. Thus in Nature, solar heat impinges on the surface of the earth, and there chiefly remains, as it cannot escape downwards on account of the bad conducting materials of which the earth is constituted. During a hot day, a sandy district is perfectly dry and dusty; but upon removing the surface for the depth of a few inches, damp sand appears, proving that heat has not been conducted downwards to any great extent. SPRING. 75 The reason that heat does not accumulate to a destructive extent upon the earth, will appear when we are considering the chemical phenomena of another Season. In some countries, Spring and Winter are hardly known, vegetation being constantly luxuriant, but sudden showers, or rather torrents of water, periodi- cally fall, and are absorbed by the capillary structure of the non-conducting soil, and there treasured up for due transmission to vegetation in future seasons of drought. Other countries, from their low level, are subject to periodical inundations, by the rise of large rivers; these saturate the earth with water, and then subside, leaving a sediment or mud, consisting of finely-divided earthy and organic matter, which acts as a powerful stimulus to the germination and growth of seeds This phenomenon is alluded to in the following beau- tiful metaphor " Cast thy bread upon the waters, and thou shalt find it after many days." In oriental countries, bread is synonymous with rice, which is cast upon the soil, saturated by the inunda- tion, and apparently lost, but appears in due season, as a plenteous harvest. We may now resume our investigation concerning the phenomena of germination and growth, which we quitted at the time that the seed had put forth its radicle and plumula. The radicle sends out its fibres amidst the soil, in E 2 76 SPRING. search of moisture and soluble matters, and by an incomprehensible vital power, transfers them into the body of the plant, where they undergo mysterious elaboration to form the fluid called sap. The terminal fibres of the radicle are so minute as almost to defy detection by the aid of a microscope, and if injured, they will not fully exert their proper functions ; therefore, in transplanting, we always en- deavour to avoid wounding them with the spade, by digging some distance around the stem, and thus car- rying away with the plant a large ball of earth, through which the terminal fibres have not penetrated. This precaution protects the radicle, and also the plant, from sustaining the derangement of its functions that would ensue, if it were rudely torn up, and sud- denly transplanted to a soil physically and chemically different to that in which it originally germinated and grew ; the plant continues to draw for food upon its parent clod of earth, until its organs are enabled to pierce beyond such limit, and to become inured to the change of nutriment presented by the neighbouring soil. The chemist is acquainted with numerous substances which act as poisons upon the animal frame ; of these, white-arsenic, corrosive- sublimate, blue-vitriol, prussic acid, and opium, may be cited as examples ; and he discovers that any of these, if dissolved in water, and applied to the roots of a plant, will soon cause it to languish, droop, and die. SPRING. 77 Many experiments have been made upon this destruction of the vitality of plants by poisonous sub- stances ; the following are a few of the most re- markable. Beans were watered with a solution of white-arsenic ; they faded in the course of a few hours, then became yellow, and in three days were dead, A lilac was killed by the introduction of a portion of solid white- arsenic into a cut made in one of its branches ; and a similar effect was produced by corro- sive-sublimate. Beans were killed by prussic acid in the course of a single day, and deadly nightshade in four days ; while spirit of wine killed the plant to which it was applied in a few hours. An experiment can be easily made regarding the poisonous action of a metallic solution upon a plant For example, water a succulent plant with a solution of blue vitriol (sulphate of copper) until it die ; then cut its stem across with a perfectly clean steel knife ; and that the poisonous compound has been transferred to the plant, and caused its death, will be evident by bright metallic copper appearing on the knife-blade. All things are so miraculously adjusted throughout Nature, that the earth seldom or ever presents the roots of plants with poisonous matters, but in their stead, soluble compounds of potash and lime, which, under the influence of vitality, promote the elaboration of healthy sap or vegetable blood. The chemist can throw but very little light upon the composition of 78 SPRING. sap, and no analysis unto which it has been subjected, can be regarded as correct, on account of the difficulty of obtaining it in a normal state, or free from other juices of the plant ; the cause of its motion or circula- tion is also a mystery ; it is observed to travel through the stem' and the branches, and chiefly towards the leaves, it enters their peculiar structure as a compara- tively thin fluid, containing a large amount of water ; and by the combined agencies of heat, air, and light, much of this is evaporated in a pure state, or in other words, the sap becomes thickened, .or concentrated, and excited to form new proximate principles, which increase the growth of the entire plant. Upon close examination, the chemist discovers this evaporation to be enormous ; for example, a large sun- flower was proved to lose one pound four ounces, and a cabbage one pound three ounces, of water during twenty-four hours ; and many plants were proved to lose one hundred times their weight of water during three months. This evaporation of water from plants may be proved very readily, by covering them with a cold, dry, bell- glass, for in the course of a few minutes its interior will become lined with small drops of water resulting from the condensation of the vapour; and that it ensues chiefly from the lower surfaces of the leaves, may be shown by placing them between two cold, dry plates of glass, as represented in the opposite sketch. Drops of water will thus condense most abundantly SPRING. 79 upon the glass plate, which is opposed to the lower surfaces of the leaves ; ({ their organization is such, as to render these surfaces the most apt for the escape of watery vapour ; but in some plants the upper surfaces are said to be most active." Fig. 17. As evaporation thus proceeds from the leaves, they incessantly demand a fresh supply of moisture from the roots ; and if the soil be too dry, or water not abun- dantly furnished to meet the demand, the plant will inevitably sustain derangement of its functions. Plants are frequently "blighted" during early Spring, by dry winds, for when branches and leaves are first put forth, they are extremely succulent, and part with water so readily, that during a dry easterly wind this loss by evaporation cannot be rapidly compensated for, by the capillary attraction of the roots. The drooping of a plant during a hot day, mainly de- pends upon the extreme evaporation of water that has been excited from the leaves, and the inadequacy of the terminal fibres of the roots to collect more with suffi- cient rapidity from the arid earth ; if then water be artificially added to it, the plant revives, sometimes with extraordinary quickness. 80 SPRING. Leaves have not only the power of transpiring the vapour of water, but likewise of absorbing it under certain conditions ; thus a plant, drooping beneath the heat of Summer, will soon revive if placed in a damp cellar ; the leaves absorb the damp, or vapour of water, and through its genial influence the plant speedily regains its wonted strength and beauty. The leaves in their exercise of these functions of evaporation and of absorption are of vital importance to plants ; and upon stripping them away, the plants suffer in health, or suddenly die. The further consideration of the vital functions of plants upon surrounding media, will be presented in the next Chapter ; and in proportion as we extend these researches, so shall we have cause to appreciate, with admiration and gratitude, the power and goodness of the Creator. " He causeth the grass to grow for the cattle, and herb for the service of man : that he may bring forth food out of the earth." 81 CHAPTER II. SUMMER. SUMMER arrives, the sun attains its zenith of splen- dour and heat, and under its influence the buds and blossoms of Spring have transmuted into foliage and flowers ; they adorn and diversify the scenery of the earth; they captivate our senses, by their exquisite structure, and their delicious fragrance ; they all exert specific functions upon surrounding media, for main- taining the harmony and order of the Creation ; let us therefore resume our investigation regarding vegetable growth. The seed weighed only a few grains, when cast into the earth in Spring; it has now produced a plant, weighing many ounces, and the general increase of bulk which has ensued throughout the vegetable king- dom, cannot fail to elicit a remark from the most list- less observer : let us endeavour, if possible, to account for this growth upon chemical principles. 82 SUMMER. If the chemist undertake the ultimate analysis of a vegetable, or the generality of vegetable products, for example, Lignin or woody-fibre, Sugar, and Starch, he finds them to yield nearly half their weight of Oxygen and Hydrogen in the proportions requisite for the constitution of Water ; and nearly half their weight of Carbon ; this will be evident, upon reference to the tabular statement at pages 21 and 22 of the Introduc- tory Chapter. Now the dry timber, or lignin, or woody fibre, of an average sized oak, weighs about Sixty tons, and therefore it contains about Thirty tons of Carbon. Again, Europe alone, annually consumes about Five hundred thousand tons of Sugar, containing about Two hundred and fifty thousand tons of Carbon. It therefore becomes a curious question, as to the source of the enormous quantity of this solid element Carbon ; for the chemist discovers, upon close exami- nation of the earth in which vegetables grow and flourish, that it loses no considerable weight, as the following account of an experiment will prove. Two hundred pounds of earth were dried in an oven, and afterwards put into a large earthenware vessel ; the earth was then moistened with rain-water, and a willow tree, weighing five pounds, was planted therein. During the space of five years, the earth was care- fully watered with rain water, or pure water ; the willow grew and flourished; and to prevent the earth from being mixed with fresh earth, or dust blown upon it by the winds, it was covered with a metal plate, per- SUMMER. 83 forated with a great number of small holes, suitable for the free admission of air only. After growing in the earth for five years, the willow tree was removed, and found to weigh One hundred and sixty-nine pounds, and about three ounces; the leaves which fell from the tree every autumn were not included in this weight. The earth was then removed from the vessel, again dried in the oven, and afterwards weighed ; it was disco- vered to have lost only about two ounces of its original weight ; thus, One hundred and sixty-four pounds of lignin or woody fibre, bark, roots, &c., were certainly produced, but from what source ? Why, the chemist who made this remarkable expe- riment, in very early days of scientific investigation, reasonably concluded the tree to have derived the increase of its structure from water alone, as no other source was obvious ; and the opinion that water was the sole aliment of vegetables, was entertained by many of the greatest philosophers ; but as knowledge regarding the powers and properties of matter through- out the Creation, became gradually extended by expe- riment, the Air was discovered to be the source of the solid element at least, which enters into the structure of the vegetable kingdom. This statement may at first appear incredible, but upon slight reflection, its truth is proved, because the Air, or atmosphere, contains Carbonic acid, and it is a Compound of 714 parts by weight of Oxygen, and 286 parts by weight of Carbon. 84: SUMMER. By means of several inorganic agents, having an intense affinity for Oxygen, the chemist can decompose Carbonic acid, and obtain its solid elementary Carbon ; but he discovers, that the leaves of vegetables under the influence of vitality, effect the decomposition, with a degree of refinement and precision perfectly inimitable, by his utmost skill ; in fact, that they withdraw, and secrete into their structures, Carbon from Carbonic acid, and liberate pure Oxygen. Still the young student may ask, Although this curious compound called Carbonic acid, does exist in the air, is it in sufficient quantity for the supply of Carbon to constitute half the weight of trees, shrubs, plants, herbage, and the endless variety of vegetable clothing that now adorns the earth, and likewise the important proximate principles obtainable from these ? The experienced chemist, in reply, states, that there is abundance of Carbonic acid for this purpose, natu- rally existing in the air, its weight being expressed by the enormous sum of Five trillions, two hundred and eighty- seven billions, three hundred and five millions of TONS. In other words, the number for expressing this quantity of Carbonic acid, vastly exceeds that for ex- pressing the number of SECONDS which have elapsed since the Creation, namely, One hundred and eighty- four billions, four hundred and fifty-four millions, one hundred and fifty thousand, and four hundred ! in addition to the enormous weight of Carbonic acid, just stated, it must be remembered, that the SUMMER. 85 respiration of man and animals, the processes of com- bustion, the phenomena of the germination of seeds, the ripening and the decay of fruits, the putrefaction of organic matters, are hourly sending forth incal- culable quantities of the same compound into the atmosphere. In fact, the chemist can only determine with tolerable accuracy the weight of the quantity of carbonic acid exhaled by human beings ; and when this is done, it strikes the mind with wonder and amazement, at the stupendous scale upon which natural phenomena pro- ceed, under the guidance of Omnipotence. The volume or bulk of Carbonic acid produced by a healthy adult individual in twenty-four hours, amounts to about Fifteen thousand cubic inches, containing about Two thousand six hundred grains of Carbon, or about Six ounces, or to between Thirty-seven and thirty-eight pounds, from every Hundred persons ; so that, assuming thirty- seven pounds as the average, One million of human beings would thus exhale into the surrounding air, a compound containing no less than Three hundred and seventy thousand pounds, or up- wards of One hundred and sixty-five TONS of Carbon! The total population of the globe is estimated at Seven hundred and sixty millions; and accordingly, on the above data, they would exhale Carbonic acid, containing One hundred and twenty-five billions, and four hundred millions of TONS of Carbon ! " If there were not excellent, and adequate adjust- ments, which compensate for, and virtually remove, 86 SUMMER. this poisonous effluvium of Carbonic acid, for poison- ous it must be called in reference to its abstract effect upon the animal system, as mentioned at page 13, it would soon overwhelm us;" and we have indeed occasion to extol the power and goodness of God, when we discover the miraculous workings which He has ordained, for the disposal and uses of the agent we are considering. In the first place, Carbonic acid is a vapour, and escaping from the lungs in a heated state, by which it gains wings, as it were, and is instantly wafted away ; in the next place, it has what is termed " diffusive pro- perty," meaning the power of uniformly blending with the enormous volume of the atmosphere, so as to elude detection in hurtful quantity ; and lastly, as most par- ticularly applicable to the present inquiry, " this car- bonic acid, which is poison to us, is the food of plants, and of the whole vegetable world ; they absorb it into their systems, and whilst they retain the Carbon, they emit the Oxygen, and so feeding themselves, they purify our Atmosphere." " Here, then, the chemist reveals the mutual de- pendence of the animal and vegetable kingdoms," and presents for our admiration and gratitude a magnificent example of the power and goodness of God, " Who hath created nothing in vain ; and Whose tender mer- cies are over all His works." This miraculous process of the analysis, or decom- position of Carbonic acid by the vegetable kingdom, appears to be constantly active, though certainly in the SUMMER. 87 greatest degree, under the direct influence of solar- light ; and it admits of most satisfactory illustration by simple experiments. Provide a quart wide-mouthed stoppered bottle, of flint-glass; remove the stopper, and apply a slight touch of pomade to its ground part, and likewise to that of the neck of the bottle ; replace the stopper, turn it gently round twice or thrice, to distribute the pomade thinly and evenly between the ground sur- faces, to make an air-tight joint; then again remove the stopper, and pour in a few spoonfuls of water. Kindle a wax-taper, attached to the end of a bent wire, as in the experiment described in page 57 ; introduce this into the bottle, and keep it there until the flame ceases ; then withdraw the extinguished taper, and quickly introduce a sprig or two of growing mint ; lastly, insert the stopper, tie it over with string, that it may not be forced out by expansion, and then place the bottle in the sunshine : the arrangement is here represented. Fig. 18. The combustion of the taper in the confined portion of the air, has withdrawn the greater portion of its 88 SUMMER. oxygen, and formed carbonic acid, and liberated nitro- gen ; the rays of the sun will excite the leaves of the mint to decompose the Carbonic acid, to secrete its Carbon and to liberate Oxygen, which blending with the unaltered Nitrogen, will restore the contents of the bottle to their original condition ; this fact is proved by removing the stopper after a few days, and again introducing the lighted taper ; it will then burn, as it did at the outset of the experiment. If a portion of air be vitiated by respiration, as in the experiment described at page 60, upon intro- ducing a few sprigs of mint into the glass, and then exposing the arrangement to sunshine, a similar result will be obtained. Sprigs of mint, are directed to be used in these experiments, as they were the simple means by which this important discovery was originally made, as fol- lows : A chemist found that air was not vitiated by the growth of a sprig of mint, kept in it for some months ; he therefore thought it possible that the pro- cess of vegetation might restore the air injured by burning candles ; accordingly he put a sprig of mint into air in which a wax candle had burned out ; and ten days afterwards he found that another candle burned perfectly well in it; and then to verify the con- clusion, he divided the injured air into two separate portions, putting the plant into one of them, and merely leaving the other; he always found that a candle would burn in the former, but not in the latter. SUMMER. 89 This restoration of the air, the chemist found to depend upon the health and vegetating state of the plant ; for though he kept many fresh leaves of mint, in a small quantity of air, vitiated by combus- tion, and changed them repeatedly for many days, they did not ameliorate the state of the air. This remarkable effect was not dependent upon anything peculiar to mint, because several portions of vitiated air were perfectly restored by sprigs of balm, and then groundsel, spinach, and other plants were used with like effect, to prove that it did not depend upon aromatic principles. The conclusions drawn by the chemist from these experiments he thus stated ; These proofs of a resto- ration of air by plants in a state of vegetation, though in a confined and unnatural situation, cannot but render it highly probable, that the injury which is continually done to the atmosphere by the respiration of such a number of animals, and the putrefaction of such masses of both animal and vegetable matter, is, in part at least, repaired by the vegetable creation ; and notwithstanding the prodigious mass of air that is corrupted daily by the above-mentioned causes, yet, if we consider the immense profusion of vegetables upon the face of the earth, growing in places suited to their nature, and, consequently, at full liberty to exert all their powers, both inhaling and exhaling, it can hardly be thought but that it may be a sufficient counterbalance to it, and that the remedy is adequate to the evil." 90 SUMMER. The experiments now detailed, were made upwards of seventy years since, when refined methods of ope- rating were unknown, but they have received full cor- roboration, from recent researches, conducted with accurate apparatus. Vegetation will not proceed, in a mixture of Oxygen and Nitrogen, in whatever proportions they may be blended together, because there is no compound of Carbon present to yield solid matter, and when the above elements are mingled in the proportions in which analysis proves them to constitute the chief constituents of the air, the addition of eight or ten per cent, of carbonic acid forms a medium, fatal to plants, when in the shade, but not when exposed to solar light. The proportion of carbonic acid naturally present in the air, is certainly essential for the welfare of animal life, although the chemist is unable to ascer- tain the manner in which its influence is exerted. Experiments similar in principle to the foregoing, but conducted with the utmost refinement, and un- wearied patience, lead to the conclusion that the vegetable kingdom, though a silent, is an ever active agent in sustaining the uniform balance of the con- stituents of the atmosphere, and in contributing its share to the maintenance of the harmony and order of the works of God. The phenomena that we have been considering are eloquently set forth in the following words : " From these discoveries we are assured that no SUMMER. 91 vegetable grows in vain ; but that, from the oak of the forest to the grass of the field, every individual plant is serviceable to mankind, if not always dis- tinguished by some private virtue, yet making a part of the whole which cleanses and purifies the atmo- sphere. In this the fragrant rose and deadly night- shade co-operate ; nor is the herbage nor the woods that flourish in the most remote and unpeopled re- gions unprofitable to us, nor we to them, considering how constantly the winds convey to them our vitiated air, for our relief and their nourishment. And if ever these salutary gales rise to storms and hurricanes, let us still trace and revere the ways of a beneficent Being, who not fortuitously, but with design, not in wrath, but in mercy, thus shakes the water and the air together, to bury in the deep those putrid and pestilential effluvise which the vegetables on the face of the earth had been insufficient to consume." The imponderable agency of solar light, though not required in the early stages of germination, becomes, at a more advanced season, of the utmost importance to the welfare of the growing plant. For example ; take a flourishing plant, with leaves full verdant, supply it with a due share of heat, air, and water, but shut it in darkness for a few days ; then withdraw it from such imprisonment and remark its appearance ; the leaves are no longer vigorous and green, they are languid and pale; why this change ? Because the stimulus of light was denied them, and 92 SUMMER. the vessels of the plant could not elaborate those prin- ciples, from the earth, water, and air, which are essen- tial to its welfare j the physical structure of the leaves has also suffered derangement, and they are incapable of reflecting a proper amount of the green rays of light. Now expose the languid and pale plant to the sunlight for a few hours, its functions will be excited to proper action, it will regain health and verdancy. The generality of plants have a predilection for solar light, and if they be either accidentally or inten- tionally placed in gloom, through which penetrates but one ray, their leaves and branches turn and bend towards the spot upon which its effulgence falls, as if eager to exchange their pallor and languor for colour and health. Solar light excites strange chemical affinities in growing plants, the reason of which is not understood ; thus some leaves are acid in the morning, tasteless at noon, and bitter at night ; some flowers are white or blue, according to the intensity of the light; many fruits are more acid in the morning than in the even- ing ; some flowers expand their petals to meet the sunshine, others close them against its power. The influence of light in promoting the colour and ripening of fruits is also remarkable ; select a peach for example ; the portion of it which is fully exposed to light, has a brilliant crimson hue, whilst that in shadow, or merely covered by a leaf, is pale green and yellow ; the taste of the one part is more luscious SUMMER. 93 than that of the other, because, light has there sti- mulated the elaboration of the most sugar ; hence, also, the sweetest fruits are generally found in southern climates. On the other hand, some plants, when grown in the full glow of light, become unfit for food ; this is the case with celery, it grows rank, green, and bitter ; but by banking earth around the stem to exclude the light, it becomes blanched, and pleasantly aromatic to the taste, with the exception of the tuft just above the ground, which remains dark green and hurtful. During the growth of lettuces, they are tied round, that the exterior leaves may exclude light from the interior, or heart ; this becomes white, and eatable, and does not contain a poisonous principle, which is discoverable in the green leaves ; plants of endive and secale are grown under earthen covers, and thus be- come blanched, and fit for food. The shoots of a potato produced in a dark cellar are white, straggling, and differently formed from those which the plant exhibits under its usual circum- stances of growth ; the seeds of mustard and cress, germinating in darkness, put forth a crop of a dingy yellow colour, instead of a brilliant green; a plot of green grass, perfectly excluded from the light, by a board or stone, becomes of a pale yellow colour, and is soon killed ; and even when par- tially excluded from light, by the dense summer foliage of surrounding trees and shrubs, it suffers a similar change of colour, and ultimately dies away. 94 SUMMER. The term etoile, or " star-grown/' is applied to vege- tables, when their colours have been thus modified or prevented by the exclusion of light. The effect of light upon the animal creation is no less remarkable ; beasts and birds of tropical climates have generally brighter skins^ and more vivid- coloured plumage, than those of climates farther distant from the equator, and a difference is even observable in the same climates between such as bask in sunshine, and such as prowl in darkness. Solar light is absolutely essential to the health of man, a strong contrast is presented between the athletic stature and the ruddy cheeks of him who roves on the mountain, and the stunted figure and the pallid features of him who crawls in the mine ; in the one case, by light, conjoined with air, food, and exercise, chemical attractions are promoted between the elements of the secretions, to form principles conducive to health ; whilst in the other, the absence of such stimu- lants in due proportions deranges the vital functions, and disease results. The vigorous mountaineer, if immured in a dark dungeon, even with a proper supply of food, will soon become more pallid, and yet more unhealthy, than the miner, who, between the intervals of his subterranean toil, may have the benefit of ascending for a few hours to enjoy the light of day. The poor inhabitants of gloomy and crowded dis- tricjis are invariably found with blanched and haggard features, partly on account of the absence of sunlight SUMMER, 95 and pure air ; but chiefly, with sorrow be it spoken, on account of their inability, through poverty, to ob- tain a moderate share of wholesome food. If we turn from these natural examples of the in- fluence of solar light, to those artificially presented in the chemical laboratory, it is found to affect the brilliancy of dyes, the deposition of crystals, the de- composition of substances, to an extent unheeded in early days of scientific inquiry, and hence the former uncertainty of many operations that are now conducted with precision. Independently of stimulating the exquisite struc- ture of the eye to the sense of vision, the importance of light is universally manifest, and it displays the wisdom and power of the Creator, who in the be- ginning said : (( Let there be light : and there was light." " And God saw the light that it was good." " Vegetables, in general, are extremely susceptible of impurities in the air that surrounds them, and very slight modifications in the proportions of its consti- tuents are more or less prejudicial to their growth, especially when they are prevented from the access of light." In the free and open air of the country, excepting in a very few instances, no matters hurtful to vegeta- tion can be discovered ; but the air of large cities and towns is subject to many local contaminations, from several causes, such as the combustion of coal, the 96 SUMMER. smoke of furnaces, the gases and vapours that are produced, or elicited, during metallurgical operations and other processes of chemical arts and manufac- tures : " and instead of our heing surprised at the injury which plants sustain in the atmosphere of a city like London, we should rather wonder that they are not more generally affected by it." " There is no doubt, however, that plants, like ani- mals, vary in regard to the delicacy of their constitu- tions, and that some are infinitely more susceptible, not only of changes in the temperature and humidity of the air, than others, but are fatally influenced by the presence of foreign matters which the more hardy tribes resist." In the immediate vicinity of chemical works, where large quantities of poisonous exhalations are hourly sent forth into the atmosphere, the vital functions of vegetables are strangely deranged or altogether de- stroyed ; the grass, for example, is stunted and brown, the trees are leafless and withered, and we need not wonder at delicate organic structures being thus af- fected, when we find even the stone and iron-work of adjacent buildings sustain decay and corrosion from the action of the same agents. An acid vapour called Hydrochloric acid, to denote its consisting of Hydrogen and Chlorine, is probably the most fatal to the life of plants; this is abundantly produced in some chemical manufactories, and causes sterility in the immediate neighbourhood ; a very SUMMER. 79 simple experiment will prove its baneful effects, as follows. Select a small geranium or myrtle, growing in a pot, and tie the stem to an upright iron wire, made perfectly bright ; set the pot to stand in a tea-saucer, and place this in the middle of a large dinner- pi ate, containing about half a fluid ounce of liquid hydro- chloric acid, then cover this arrangement with a bell- glass, the rim of which will rest upon that of the plate. Fig. 19. Liquid hydrochloric acid contains the vapour of the acid dissolved in water, and when exposed to air, it will readily escape, thus in the act of pouring the acid into the plate a dense white fume will be ob- served ; and this will continue to rise and contaminate the air contained in the bell-glass ; its poisonous effect upon the plant is manifested in the course of a very short time by the leaves drooping and shrivelling ; 98 SUMMER. and its corrosive effect upon the iron is shown by the metal losing its polish and becoming tarnished. Upon removing the plant from this noxious atmo- sphere, all attempts at its restoration will be in vain ; it is killed, and so would an animal be if subjected to similar treatment. The colours of flowers are curiously affected by acid vapours, as may be proved in the following man- ner : place a red rose in the centre of a bunch of dark purple pansies, sufficiently large for the stems to fit the neck of the glass employed at page (60) when introduced in an inverted position, so that the flowers may hang in the glass with their petals down- wards. Fig. 20. Place a fragment of sulphur, about the size of a hazel-nut, upon an egg-cup turned bottom upwards, and standing in the middle of a dinner-plate ; kindle the sulphur by touching it with a glowing coal, and then place the glass containing the flowers over this arrangement, as directed in the last experiment. The sulphur will continue to burn for a considerable SUMMER. 99 time, and during this combustion, the oxygen of the confined air combines with it, to produce Sulphurous acid vapour, fumes of which will be observed to ascend, and upon coming into contact with the flowers, the red rose will bleach, and the purple pansies will be more or less deprived of colour. If a similar experiment be made with autumnal dahlias of varied colours, they will present a still more striking example of the destruction or modifica- tion of their colours by the acid vapours. In consequence of the existence of the above acid, and other vapours in the atmosphere of large cities, many plants cannot be grown exposed to its influence, and therefore the following arrangement has been successfully adopted for preventing them from sus- taining injury in such localities. Fig. 21. The engraving represents a circular wooden box, about fifteen inches in diameter, and six inches deep, lined with sheet-lead, or sheet-zinc, so as to be water- tight; a stratum, about two inches thick, of clean F 2 JOO SUMMER. gravel stones, is placed upon the bottom of the lining ; then a stratum, about two inches thick, of turfy loam upon the gravel, and the remaining space filled with well-moistened loam ; in this various small plants and flower-roots are set in the usual manner ; and then covered with a large bell-glass, that rests upon the rim of the box. The arrangement of the earthy materials in the box closely resembles that of a naturally fertile soil, be- cause the water filtrates by capillary attraction, and remains among the gravel, until the wants of the plants above, require it for their support ; the water cannot escape by evaporation into the external air, but it saturates that contained in the bell-glass, con- denses as drops, and trickles down again to the soil, again to rise as vapour, and again to condense, and thus incessantly circulating, the plants are never sub- jected to irregular watering, at the same time they are preserved from cold, dust, soot, smoke, and noxious vapours, and continue to flourish in perfection and beauty. The glass shade merely stands on the rim of the box, and is not perfectly air-tight, so that during changes of temperature the included air undergoes expansions and contractions, by which it becomes re- newed from the external atmosphere ; but experiments have been made with glass shades fitting perfectly close, and even then the plants flourished for a time. A very curious fact was likewise discovered, namely, that the portion of air thus effectually confined and SUMMER. 101 prevented from renewal, in the course of a short time after exposure to sunlight, contained a considerably greater proportion of oxygen than at first ; this some- times amounted to an excess of one and a half, two and a half, and even four per-cent., and apparently depended upon the vital functions of the included plants being excited to decompose the carbonic acid exhaled from the soil. When air is either partially or wholly confined, or rendered stagnant, it forms an exceedingly bad con- ducting medium of heat and cold, therefore the plants growing in it will bear local variations in temperature which would otherwise prove fatal to them. The following is a good illustration of this fact : In New Holland, in the month of February, when the temperature was 94 degrees in the shade, a case of plants was prepared for a voyage to this country ; in rounding Cape Horn, two months subsequently, the temperature was only 20 degrees; a month later, in the harbour of Rio, it rose to 100 degrees ; and upon crossing the line, it even rose to 120 degrees, and fell to 40 degrees upon arrival in the British Channel, in November, eight months after the plants were en- closed; they were in most healthy condition, on ac- count of the confined air having protected them from experiencing these extreme changes of temperature with suddenness or irregularity. The apparatus upon the above principle may be constructed of any size, and if very large, glazed frames are employed for the covering ; costly plants 102 SUMMER. need not be collected, for common ivy, honeysuckle, primroses, anemones, ferns, and mosses, by the luxu- riance and beauty of their growth, will amply reward the little trouble required for this arrangement. During a hot and brilliant summer day, if we look across a tract of dark- coloured land, we frequently observe that all objects upon it, or surrounding it. appear to have a dancing or tremulous motion ; this singular phenomenon admits of the following explana- tion. The land becomes exceedingly hot, by absorbing the solar rays, and imparts heat to the air incumbent on its surface ; the air so heated becomes lighter and ascends, whilst a colder and heavier portion descends, so that the solar light, in traversing a medium of such unequal density, does not pass through with steadi- ness, but is distorted or broken, or refracted, and the rays, coming to the eye of the observer with irregu- larity, the objects consequently appear distorted. This phenomenon may be artificially imitated by heating a bar of iron red-hot, then holding it hori- zontally in the air, at arm's length from the face, and looking at surrounding objects, through the air above the heated surface, they will all appear distorted, be- cause the natural equilibrium of the air is disturbed, convective currents take place, and the light is un- equally refracted. Again ; the same phenomenon is observed when we look at objects beyond the top of a chimney, from which the heated products of a clear burning fire are SUMMER. 103 rising without smoke ; and if the chimney belong to a cottage built in a small hollow, with rocks or trees im- mediately above it, the distortion of their positions is very remarkable. The examination of this refraction of light belongs to the science of Optics, and not to that of Chemistry ; but the reception of heat by the land, which is the cause of the phenomenon, is a legitimate branch of the latter science, and therefore demands our attention. By the aid of the thermometer, the chemist has dis- covered that some soils are more easily heated than others, when equally exposed to the rays of the sun ; and when they eventually acquire the same degree of temperature, some cool faster than others. Soils principally consisting of white, and strongly ad- hesive clay, are not, generally speaking, easily heated, and containing a very considerable amount of water, the heat soon escapes, because it is immediately concerned in producing evaporation ; chalky soils agree with these, as regards heating with difficulty, but as they do not contain a large quantity of water, they do not lose much heat by evaporation. The chemist has farther ascertained, that an exceed- ingly dark, or black soil, containing a large quantity of vegetable matter, becomes the most heated, both by the direct rays of the sun, and by warm air, that wafts over its surface from other localities ; and that soils containing either much carbonaceous or ferru- ginous matter, exposed, under equal circumstances, to 104 SUMMER. natural heat, acquire a much higher temperature than pale-coloured soils. " When soils are perfectly dry, those that most readily become heated by the solar rays, likewise cool most rapidly ;" but it has been determined by accurate experiment, " that the darkest coloured dry soil, (that which contains abundance of animal or vegetable mat- ter, substances which most facilitate the diminution of temperature,) when heated to the same degree, pro- vided it be within the common limits of the effects of solar heat, will cool more slowly than a wet pale soil composed entirely of earthy matter. A specimen of rich black mould, which presented upon analysis nearly one-fourth its weight of vegetable matter, was exposed for an hour to sunshine, during which time its temperature increased from 65 to 88 de- grees : whilst a chalk soil, under the same circum- stances, had its temperature increased only to (39 de- grees; however, upon removing the mould into the shade, where the temperature was 62 degrees, in half an hour it lost 1 5 degrees, whereas the chalk similarly situated lost only 4 degrees. Portions of brown fertile soil, and barren clay, were accurately dried, and then artificially heated to 88 degrees ; they were afterwards placed in a room at 57 degrees; in the course of half an hour the brown soil lost 9 degrees, but the clay lost only 6 degrees of heat. Throughout all these experiments, the temperatures were ascertained by a delicate thermometer, and the SUMMER. 105 soils were placed upon equal-sized shallow trays, made of tin plate. Upon considering the results of these experiments, " nothing can be more evident than that the general heat of the soil, particularly in Spring, must he of the highest importance to the rising plant. And when the leaves are fully developed, the ground is shaded ; and any injurious influence which in Summer might be expected from too great a heat, entirely prevented ; so that the temperature of the surface, when bare, and exposed to the rays of the sun, affords at least one indication of the degrees of its fertility; and the thermometer may be sometimes a useful instrument to the purchaser or improver of lands." The thermometer, although so frequently consulted throughout the Four Seasons, merely denotes the degree of heat that air, water, earth, and other media are capable of imparting, and not the actual quantity of heat therein contained ; several experiments can be made concerning this fact, and they will lead to the elucidation of some curious natural phenomena. Introduce the bulb of a thermometer into one pint of water, and then into four pints of water, drawn at the same time, from the same spring ; the temperature of both portions of water will be found alike, although it is evident, upon the slightest reflection, that four times as much heat must be present in the one case than in the other ; this the thermometer does not indicate. To proceed further in this inquiry ; Provide two F 5 106 SUMMER. glass bottles, of equal size and thickness, and resem- bling each other in every respect as nearly as possible ; pour into one of these a pound of Olive oil, and into the other a pound of Water, of the same tempe- rature, which, for the sake of illustration, may be 40 degrees. Provide two similar mercurial thermometers, one of which place in the water, the other in the olive oil, as shown in the engraving. Fig. 22. Carry the bottles, thus prepared, into a room heated to 70 degrees ; place them side by side upon a table ; allow the air of the room to remain undisturbed by draughts ; and in time the oil and the water will gain its temperature ; this does not appear remarkable, it is what might be expected ; if, however, the thermo- meters be inspected from time to time during this pro- ceeding, we find something to excite our attention ; we find that the temperature of the room is acquired by the Oil, in exactly half the time that it is acquired by the Water. Keverse the conditions of the experiment, by re- SUMMER. 107 moving the bottles to a cold room, at 40 degrees, for example, and it will be found that the Oil will acquire such temperature, or cool, in exactly half the time that the Water will require to cool. What inference is to be drawn from these experi- ments ? Why, in the first place, that the oil requires less heat than the water to raise it to the thermometric temperature of 70 degrees; and in the second place, that it parts with such heat more easily than the water. The chemist denotes these results by a technical term that conveys a direct and concise meaning ; and technical terms facilitate inquiry when they are under- stood, but impede it if employed without explanation ; the Oil required less heat than the Water, and parted from it with the greatest readiness, therefore the che- mist says, that the Capacity of Oil for heat is less than that of Water, exactly as we should say that the capacity of one mind for the reception and retention of knowledge, was less than that of another. In fact, the Oil acquired and lost heat with twice the facility of the Water ; and if, for the sake of ex- ample, the Capacity of the Oil be called Fifty, that of the Water is One Hundred ; or yet more simply, the Capacity of oil is Half that of water. A very simple and decisive experiment will prove, that equal weights of Oil and of Water, although at the same thermometric temperature, do not contain the same amount of heat ; and for the performance of this, the following preparations are required. 108 SUMMER. Two cylindrical canisters, of tin-plate, each of these being six inches in height, two inches and a half in diameter, and having a cover with a knob in its centre, and a perforation near that, about three quarters of an inch in diameter ; these covers must fit very tight, or have small catches, so that upon holding them by their knobs, the canisters will not fall away, but will require considerable force to effect a separation. Two cylinders of tin-plate, in height equal to that of the canisters, but in diameter about an eighth of an inch greater, and open at each of their ends, so that the canisters may easily slide through them. Two earthenware flower-pots, alike in shape and size; in depth equal to the height of the cylinders, but in diameter at bottom about three quarters of an inch greater than them ; two large hyacinth glasses, resem- bling each other in shape and size as nearly as pos- sible ; and lastly, two small mercurial thermometers, similarly graduated, and with bulbs small enough to enter the apertures in the covers of the canisters. Suspend a pair of common scales from any conve- nient and steady support, and in each of its pans place a canister without its cover ; they will probably not balance each other, therefore small shot and sand must be added to the scale-pan containing the lightest of the two, until an equilibrium is effected. Pour olive oil into one canister, until it is filled within half an inch of its rim ; then pour water into the other, until it is sufficient to balance the oil ; thus equal weights of the two liquids are obtained; the SUMMER. 109 canisters are then to be removed from the scale-pans, and firmly closed with their respective covers, and the thermometers introduced through their respective apertures. Place the canisters to stand upright in a saucepan, sufficiently deep and narrow to prevent them falling upon one side or the other ; then pour water into this, until the canisters are rather more than half immersed ; lastly, place the saucepan over a clear glowing fire, that the water may boil. This it will probably do, at or near 212 degrees; but whatever temperature a thermometer may indicate, as the boiling point, of course it will be imparted to the canisters, their contents will become equally heated, and the thermometers will be equally affected : this is the condition to be fulfilled. Whilst it is in progress, a few more arrangements can be made : select two pieces of wood, each of these being two inches in length, and sufficiently square to remain firm, when thrust half way into each of the small circular apertures of the flower-pots ; then place each of these to stand upon a deep cup, or jar. Fold about two pounds of clean ice in a flannel, and beat it with a mallet, until the ice is broken into pieces about the size of ordinary hail-stones, and, if neces- sary, let it drain in a sieve. Thrust a crumpled sheet of thin paper into one end of each cylinder, to form a temporary stopper ; then place each with this end uppermost, to stand in the centre of each flower-pot ; and carefully fill the space 110 SUMMER. between the exterior of each cylinder and the interior of each flower-pot, with the powdered ice ; this is most easily done, by dropping in a small portion at a time from a wooden spoon. The ice is prevented from entering the interiors of the cylinders by the paper stoppers ; these are now to be removed, and each flower-pot lifted, to stand upon the top of each hyacinth glass. If the water boil in the saucepan, remove it from the fire ; protect the hands with thick woollen gloves, and lift out each heated canister at the same time, holding one in the right hand and the other in the left ; then drop each at the same moment into each cylinder, and immediately lift up each cylinder completely away, that the ice may simultaneously come in contact with each canister. In this arrangement, the canisters are supported one inch above the apertures in the flower-pots, by the plugs of wood, and these being square, they prevent the ice from falling through, whilst they readily allow the water resulting from its thawing to pass, and direct it into the respective hyacinth glasses. When removed from the boiling water in the sauce- pan, the Water and the Oil were of the same thermo- metric temperature; and if they contain the same amount of heat, if they have the same Capacity for heat, then, in cooling down to the same degree, they should most certainly thaw equal quantities of ice, and equal quantities of water should flow into the glasses. But the Capacity of Water for heat is Double that SUMMER. Ill of the Oil, as already stated, and as now strikingly proved ; for upon the thermometers indicating the same temperature in both liquids, it will be found that the Water has thawed Twice as much ice as the Oil, and accordingly the hyacinth glass that supports the flower-pot holding the Water- canister, will receive twice as much water as that which supports the flower- pot holding the Oil -canister. The annexed engraving shows this result, and may aid the whole description that has been given of the method of performing this remarkable experiment. Fig. 23. By a similar proceeding with other liquids con- ducted with extreme precision, and accurate apparatus, the chemist arrives at the conclusion that Water pos- sesses the greatest capacity for heat, and the least sen- sibility to heat of any substance with which he is acquainted ; the extraordinary, the important conse- quences of this fact throughout nature, will be appa- rent at a future Season. 112 SUMMER. Solids, liquids, and aeriform substances, though of the same thermometric temperature, have different capacities for heat; and these are most singularly affected by changing their physical state of density. Thus, at common temperatures, if a given bulk of Water weigh 1000 parts, the same bulk of Lead will weigh 11,350 parts ; if this be violently compressed by machinery, the individual particles of the metal are thrust, or packed into less bulk, than they originally occupied, the lead becomes more compact or dense ; and now, if its weight be compared with that of an equal bulk of water, it may be found perhaps increased to 11,360 parts, or, in other words, the lead has increased in density. Lead, in common with other substances, contains a certain amount of heat, or has a certain capacity for heat ; and if a strip of the metal, placed on an anvil, be suddenly and forcibly beaten with a hammer, its density is increased, but its capacity for heat is dimi- nished, the particles of the metal being compacted into a smaller space, have not room for all the original heat ; some, therefore, escapes, and warms the lead, to a degree painful to the hands ; indeed it will imme- diately kindle a small piece of phosphorus. A dextrous blacksmith will place the point of a soft iron horse- shoe nail upon an anvil, and strike it only two violent blows with a hammer, and the point will instantly become red-hot, and inflame a sulphur match ; thus he generally obtained fire, before the introduction of Lucifer matches. SUMMER. 113 In further elucidation of these curious matters, which at first sight may appear to have no connexion with the chemical phenomena of the Four Seasons ; a piece of sponge may represent the metal ; the sponge has a certain capacity for holding water, the same as the metal has a certain capacity for holding heat ; when the sponge is squeezed, its particles are brought closer together, it has less capacity for holding water, and accordingly some will run out ; so the metal, when struck, has its particles more closely compacted, and therefore less capacity for holding heat, and some must escape. Change of density in liquids is also attended with change in their capacities for heat, and the chemist can furnish experimental illustrations of this pheno- menon ; provide an apparatus resembling the annexed engraving. Fig. 24. It is a glass tube, twelve or fourteen inches long, half an inch diameter, closed at one end, and enlarged at the other into two bulbs, about three inches diameter, connected by a neck the same size as the tube ; the bulb farthest from it has a mouth, provided with an accurately-fitted stopper, slightly touched on its ground part with pomatum, for a reason already described. Remove the stopper, and holding the apparatus 114 SUMMER. upright by the bulb to which the stopper belongs, pour in water until the tube and lower bulb are filled ; then pour in alcohol, until the upper bulb and its mouth are filled ; carefully insert the stopper, and wipe away the little quantity of alcohol that will flow over. In this arrangement, the water, being the heaviest liquid, will remain below, and distinct from the lighter alcohol ; the two liquids are prevented from mixing rapidly, by the narrow neck between the bulbs, and they are both of the same thermometric temperature. Place the palm of the hand over the stopper, grasp it and the bulb, and invert the apparatus, that the tube may now stand perpendicularly ; and in this posi- tion the heavy water will fall through the light spirit, or vice versa; the tube will not appear full as it was originally, and the bulbs will become sensibly warm. Why is the tube deficient of its contents, for the ground stopper has prevented any portion of liquid from escaping, and why do the bulbs feel warm ? Because the light alcohol, by combining with the water, has its density increased, it occupies a smaller space than at first, and like the solid lead, has its ca- pacity for heat diminished ; a portion therefore escapes, and affects the hand. These experiments are preliminary to others upon the atmosphere, which most concerns our present inquiry ; and we shall find that changes in its density, by condensation and rarefaction, produce changes in its temperature, elevation in one case, depression in the other. SUMMER. 1 1 f> All aeriform substances admit of more sudden con- densation and rarefaction than either solids or liquids, and therefore experiments, upon such highly atte- nuated, and often invisible forms of matter, are not only extraordinary, but instructive. The annexed sketch represents an apparatus for proving that the condensation of air compels it to part with heat. Fig. 25. It consists of a well-annealed, and perfectly cylin- drical glass-tube, fourteen inches long, a quarter of an inch thick, . and rather more than a quarter of an inch internal diameter, containing air ; one end of this tube is closed with resinous cement, which likewise secures a brass cap, terminating in a ball, about one inch and a half in diameter, whilst the other end of the tube is open, but its circumference bound with a brass band, about two inches broad, to prevent it from being acci- dentally chipped. The other part of the sketch represents a rod of well-tempered steel, about one inch longer than the glass-tube, but rather smaller than the bore, for about twelve inches ; one end of this rod is firmly screwed into a flat brass knob, about one inch in diameter, whilst the other end is enlarged and closely packed with oiled leather, to form a piston, which accurately fits the tube ; the end of the piston has a small hook, 116 SUMMER. or it is slightly cupped, to hold a fragment of perfectly dry German tinder, ahout the size of half a pea. Insert the piston with the tinder into the glass tube, place the brass knob upon a solid table, that the brass ball may be uppermost ; grasp this with the right hand, steady the tube with the left, then with one sudden and powerful jerk, thrust the tube down as far as prac- ticable ; a vivid flash of light will instantaneously ap- pear; and upon quickly withdrawing the piston, the tinder will be found burning as perfectly 'as though it had been kindled at a common flame. Why is this ? Because the sudden compression, condensation, or increase of the density of the air in the tube, diminished its capacity for heat, or in other words, the sudden thrust, beat the heat from the air, as the sudden blow, beat the heat from the lead in the first experiment ; the heat is caught by the tinder with sufficient intensity to cause its combustion. If the experiment do not succeed, the piston must be withdrawn, the tinder examined, and if oily, it must be thrown away, and replaced by a fresh dry piece ; the air in the tube must be renewed by intro- ducing a long straw, applying the lips to its projecting end, and gently drawing, not blowing, fresh air through for three or four seconds ; then the experiment may be tried again, and after a few trials, the proper method of sudden condensation will be discovered, so that success will be certain at any future time. If so much heat be elicited from so small a portion SUMMER. 117 of air as that contained in the glass tube, what an incon- ceivably enormous store must be emitted from the vast atmosphere by natural changes in its density through- out the Four Seasons. Diminution of the density of the air, or, in other words, its sudden rarefaction or expansion, produces the opposite effect of cold ; an experiment in proof of this fact may be performed by the aid of an air-pump, and most persons are now familiar with the construc- tion of this important apparatus. Fig. 26. For simplicity of description, the engraving repre- sents a section of an air-pump, with merely a single barrel ; at the bottom of tin's is a small chamber, con- taining a hemispherical valve, and upon the top of the piston is a similar valve ; these are both arranged to open upwards ; the barrel is unclosed at its mouth, and the two featherless darts indicate the air, that it J 18 SUMMER. of course includes as far as the valve upon the piston. The horizontal tube is connected, on the one hand, with the valve chamher, and on the other, with the central aperture of a flat, smooth, and circular plate of brass, technically called " the pump -plate ;" upon this, and near its edge, is placed a delicate thermo- meter, attached to a standard having a firm base ; then the smooth ground rim of a large bell-glass, technically called " a receiver," is slightly touched with pomatum, and placed over this arrangement, to rest evenly upon the pump-plate. The air contained in the horizontal tube, and that contained in the receiver, now coalesce and form one volume of equal density and temperature ; the degree of this must be noted. Grasp the cross handle of the piston-rod, and thus raise the piston to the mouth of the barrel, both the density and the temperature of the air will be instantly affected as follows. The air contained in the barrel of the pump, as indicated by the featherless darts, is lifted up and expelled from its mouth as the piston is raised ; the space in the barrel, between the bottom of the piston and the valve of the chamber, would therefore be void of air; but this valve being made to open upwards, the air in the receiver, in consequence of its extraor- dinary property of elasticity, or property of self-ad- justment to the circumstances under which it is placed immediately expands, passes in the direction of the SUMMER. 119 perpendicular and horizontal feathered darts, lifts the valve and fills the barrel, as indicated by the two double-barbed darbed darts in the annexed figure. By thus expanding, rarefying, or diminishing, in density, the heat ori- ginally contained in the air is, of course, more weakly diffused throughout such enlarged volume; it is not so concen- trated around the thermometer, and this instrument will indicate a slight depres- sion of temperature. By thrusting down the piston, its Fig. 27. valve will open and permit the air, indi- cated by the two doublebarbed darts, to escape, and fill the barrel as formerly indicated by the two feather- less darts ; whilst the valve in the chamber firmly closes, and prevents its return into the receiver. By raising the piston a second time, a second call is made upon the air in the receiver; it again ex- pands, lifts the valve, and fills the barrel ; its density is now less than before, its heat is more diffused over an equal space, and the thermometer will again de- note cold ; and by thus proceeding, repeated calls are made upon the air in the receiver to supply the re- peated losses of that from the barrel, until at length it is exhausted, and the thermometer will fall several degrees. It will now be impossible to lift the receiver from the plate, because it is firmly held on by the pressure of the external atmosphere, which amounts to about 120 SUMMER. fifteen pounds upon each square inch of surface ; this pressure manifests the endeavour of the external at- mosphere to enter and to restore the equilibrium that has been disturbed. By removing the small screw that is placed under the valve chamber, the external air will immediately enter, the equilibrium will be restored, the density of the air in the receiver will be the same as it was, and the thermometer will slowly rise to its original de- gree. During the ascents and descents of the piston in this experiment, another phenomenon will be observed namely, the interior of the receiver appears as though it were filled with mist ; this is really the case, and for the following reason. Air invariably contains the vapour of water, and to raise such vapour, and to retain it, a certain amount of heat is necessary. The air included by the receiver contained the vapour of water, invisibly maintained throughout its volume by heat, but upon being sud- denly compelled to expand, the heat is as suddenly diffused throughout such expanded volume, the va- pour thus chilled or robbed of heat, is converted into minute drops of water, and forms an artificial mist. This experiment accordingly furnishes the chemist with an explanation of the formation of a natural mist, the invisible heated watery vapour present in the air becoming visible, minute drops of water, when its temperature falls, either by sudden local rarefaction SUMMER. 121 of the air, or by coming in contact with cold surfaces of the earth and waters. To impress these curious and important matters upon the mind of the young student of Nature, take the following example ; suppose a cubic foot of air contain a certain amount of heat, equally diffused throughout its elementary and compound constituents, and capable of affecting the thermometer to a given degree ; if this volume of air be compressed to one-tenth of a cubic foot, of course there will be ten times as much heat concentrated into that tenth as there was, and the thermometer would indicate a rise of temperature. On the other hand, suppose the cubic foot of air to be expanded to ten cubic feet, the heat would be so diffused throughout such volume, that the thermo- meter would indicate depression of temperature, or, in other words, the air would feel cold. These experiments of the laboratory furnish the chemist with a key to the explanation of natural phe- nomena ; an enormous store of heat is contained in the atmosphere, but this medium is not of uniform density from the earth to its own confines, those por- tions that are directly incumbent upon the earth are most dense, because they bear the weight of super- incumbent portions; as, to use a very humble simile, the hay at the lower part of a rick bears the weight of that above, and is therefore more compact and dense ; or it may be conveyed by the accompanying en- graving, the gradual shading of which denotes the 1 22 SUMMER. gradual diminution in the density of the atmosphere in proportion to its altitude. Fig. 28. The compression of the lower, by the upper portion of the atmosphere, alters its capacity for heat, as it was altered by the compression of the piston in the ex- periment so recently described, and accordingly heat escapes from the atmosphere in quantity suited to time and season for the welfare of the animated creation. If we ascend a lofty mountain, and thus approach many hundred feet nearer to the sun than we were in a valley, we might expect to find the temperature con- siderably warmer ; but the contrary is the case, when we left the valley, it was glowing under the heat of the summer sun, we can see it still glowing, and though we are nearer the sun on the mountain sum- mit, the air is intensely cold ; what reason can be assigned for this ? The chemist submits the follow- ing : It has been already stated that the sun does not heat the transparent air ; and at the elevation just mentioned, it is greatly rarefied or comparatively free from pressure ; the heaflbfthat it has derived from con- tact with the warm earth is widely diffused, and in a given volume of air on the mountain summit, there SUMMER. 123 is not the actual heat that exists in a similar volume in the valley. Again ; warm air in ascending from the valley expands, and reinotion of heat, or, in other words, cold is produced, and frequently to such an extent that the watery vapour of the air condenses in clouds, which, when surcharged, deliver rain, or it congeals as snow, and clothes the mountain summit. Air, in rising from the level of the sea, becomes nearly one degree colder for the first two hundred feet of ascent, and altogether about fifty degrees colder in rising fifteen thousand feet, thus, water would freeze at this elevation even near the equator, where the tem- perature of the low plains is at least eighty degrees ; this is the reason why the summits of lofty mountains are covered with perpetual snow, and the height at which it occurs is called the " snow line," or " line of perpetual congelation." The Andes present a magnificent illustration of these phenomena attendant upon the varying capacity of air for heat ; placed nearly under the equator, they tower from parching sands ; about their middle height the climate is temperate ; their summits are crowned with unchanging snow, and these ranges of tempera- ture are always distinct ; the hot winds from below, if they ascend, become gradually cooled by expansion, and if by any force of the blast the cold air be driven downwards, it is condensed, and rendered warmer in its fall. How grand, how beautiful, how harmonious ; are G 2 124 SUMMER. these adjustments and balancings of The Almighty Hand, who " made the weight for the winds, and weighed out the waters by measure !" how eminently calculated they are to inspire us with emotions of admiration and gratitude towards the Author of our being ! He has ordained the level earth to be chief dwell- ing-place of mankind, and commanded the air directly incumbent upon it to be of the just weight or density, and to contain the due amount of heat which vitality requires for the proper maintenance of its manifold recondite functions; whilst on greater elevations, which are but thinly peopled, or on mountain sum- mits, which are but rarely visited, these wondrous agents, air and heat, are rare and feeble, because they are not required in abundance and power for the sup- port of life ! Exploring and investigating throughout the trea- sures of the Creation, we become more and more impressed that it is founded upon the most miraculous scale of beneficence; that bounteous gifts are not in- discriminately scattered where they would be useless to organic beings, but are abundantly presented where required for their manifold wants. Great, inexpressibly great, is the delight in thus b'-jmg permitted to follow the marvellous works of The Creator, to trace the unbounded power and trans- cendent goodness which are displayed alike in the mightiest and the lowliest parts of the terrestrial world. SUMMER. 125 " In the heavens hath He set a tabernacle for the sun, which is as a bridegroom coming out of his chamber, and rejoiceth as a strong man to run a race ; his going forth is from the end of heaven, and his circuit unto the ends of it, and there is nothing hid from the heat thereof." In the splendid poetical images of the above pas- sage, are set forth the beauty, power, glory, and genial effects of solar light and heat during an unclouded day ; let us trace The Hand by which these are all directed to work together for our good. .During the brilliant zenith of summer, even in torrid climes, although the heat of the sun impinges upon the earth, with vast and continued power, its degree is so miraculously adjusted and restrained by Providence, that it never attains sufficient intensity to cause the destruction of organic bodies by combus- tion. Nay more, the chemist, after all his extensive researches throughout the varied objects of the Crea- tion, can find neither a single element nor a single compound in a native state which is capable of in- flaming by solar heat. If the heat of the sun were not thus miraculously adjusted, by the power and goodness of God, to the earth and its productions ; if the earth were capable of receiving and retaining all the heat that is constantly sent forth from the sun ; if the air were capable of being heated by conduction, the increase of the tem- perature of the globe instead of being, as now, pro- 126 SUMMER. bably only one degree in one thousand years, would be upwards of three hundred degrees in a single year ; and, above all, if the whole atmosphere were to sus- tain sudden condensation of its volume, the tem- perature would instantly exceed that of red-hot iron. Thus all living things would perish, the waters would be dried up, and the earth, by the accumulated heat, would ultimately " pass away." Considering the elements and constituent parts of which this terraqueous globe is composed, how slight a disturbance in the present harmony and order of its adjustments would cause its instantaneous destruction! These are facts which become apparent during the pursuit of science, and like all others so discovered by man, they emanate from " The Fountain of All Truth." Pure science, therefore, corroborates the testimony of Scripture, which recounts the first revolutions of The Creation, and which equally foretells the last. Scripture recounts, " That by the word of God, the heavens were of old, and the earth, standing out of the water, and in the water : " Whereby the world that then was, being overflowed with water, perished." Scripture foretells, " But the heavens and the earth, which are now, by the same word are kept in store, reserved unto fire against the day of judgment and perdition of ungodly men. " In the which the heavens shall pass away with a SUMMER. 127 great noise, and the elements shall melt with fervent heat, the earth also, and the works that are therein, shall be burned up.'"' " Wisdom is the breath of the power of God, and a pure influence flowing from the glory of the Almighty," and concerning His manifold, wondrous, and perfect works, it is gradually permitted to man, through the proper and chastened exercise of his noblest faculties, during the short period of his sojourn here upon earth, that he may be led to a sincere and grateful apprecia- tion of the power and goodness of God; and this will blend in perfect harmony with the humble and devout confession of an implicit faith, and constant obedience, as commanded in His Eevealed Will. Unless a firm belief of another and far higher stage of existence be deeply fixed in the mind of man, to uphold him during his present state of progress and trial, his science is vain, his philosophy is false. As intricate derangements of the elements of nutri- tious food, cause its transition into deadly compounds by the refined experiments of the chemist, so do subtle perversions of the elementary truths of pure science yield moral poisons by the cunning of the sophist ; but the first shrinks back with fear and dread, lest his dis- covery should be wilfully or accidentally misapplied, whilst the second stands forth with presumption and arrogance, and prides himself upon the exhibition of his morbid skill in turning good gifts to bad purposes. It is accordingly the duty of the teacher of science, to " put on the whole armour of God ; to stand girt 128 SUMMER. about with Truth ;'' and thus, not only instruct, but guard the mind of the young disciple entrusted to his care, by the Divine admonitions which irradiate the invincible " shield of Faith, wherewith he shall be able to quench all the fiery darts of the wicked." " Prove all things ; hold fast that which is good." " Let no man spoil you through philosophy." " Be not carried about with divers and strange doc- trines." " Perverse disputings of men of corrupt minds, and destitute of the truth, supposing that gain is godliness, from such withdraw thyself." " And this I say, lest any man should beguile you with enticing words." The foregoing remarks were called forth during an early stage of our investigation of the beautiful pheno- mena consequent upon the miraculous adjustment of the temperature of the solar rays to the earth and its productions ; let us now resume this interesting subject. During the most intense heat of Summer, the at- mosphere is never anhydrous, or devoid of watery vapour, though frequently so desiccated, that the animal and vegetable creation droop beneath its parch- ing influence ; then, mark the power and goodness of the Almighty Hand, that is beneficently extended for their relief. The invisible watery vapour is commanded from its wide aerial expanse in other localities, and gathered into opaque clouds ; these float between the sun and SUMMER. 129 the earth, and act as veils in preventing the direct transmission of solar heat. The clouds thus permit the earth to lower in tem- perature, and in so doing, they either gain sufficient heat for their own dispersion as invisible vapour, again to collect, and to perform the same genial .office in other suffering districts, or they fully complete the wondrous work of present relief, by relinquishing their waters in showers. These are eagerly imbibed by the arid earth, and its productions, whose leaves and flowers immediately send forth their delicious fragrance and perfume in grateful return for such miraculous and salutary aid. This phenomenon, upon close examination, appears to depend upon the functions of plants being suddenly excited by water, to the elaboration of aromatic prin- ciples, although its exact theory is still unknown ; but the peculiar odour which is emitted even by barren earth, after a summer shower, is fully proved to depend upon the combination of water with the aluminous and ferruginous matters which are present in the soil. Neither pure alumina, nor oxide of iron, emit odour when separately watered, but it immediately becomes perceptible when they are mingled together, and in such condition they are naturally found in soils. The water of the shower, having yielded refreshment to the earth, is again destined to ascend as vapour into the atmosphere, under the agency of heat derived from the earth. The delightful coolness of the earth, after a summer G 5 130 SUMMER. shower, induces man and animals to venture forth from the dense non-conducting foliage, "beneath which they gladly sought refuge from the scorching sun ; and this coolness depends upon the evaporation which en- sues, and carries away the superfluous heat ; it is very much facilitated if the air be in gentle motion at the same time, and a considerable reduction of temperature is thus effected. It has been already stated, at page 47, that evapo- ration is dependent upon the temperature of the air, and the velocity of its movement over the surface of water; the rate at which it ensues may be judged of by reference to the annexed table, showing the number of grains of water which evaporate per minute from a circular surface six inches in diameter, during different temperatures and states of the atmosphere. Temperature. Calm. Breeze. High Wind. Fahrenheit. Grains. Grains. Grains. 35 0.95 1.22 1.49 45 1.36 1.75 2,13 55 1.90 2.43 2.98 65 2.62 3.37 4.12 75 3.65 - 4.68 5.72 85 4.92 6.49 8.04 The amounts of the evaporation of water in this table are rather above those of the natural phenome- non, since they refer to air Artificially dried, and it is never perfectly dry throughout the Four Seasons. SUMMER. 131 For the conversion of water into vapour, heat is in all cases required, and the surfaces which impart it become cold ; advantage is taken of this fact, for ob- taining artificial reduction of temperature, even during the summer of tropical climates ; thus in India, apart- ments are often separated from the courts, by curtains instead of walls, and these being continually sprinkled with water, its rapid evaporation occasions a reduction of temperature from ten to fifteen degrees below that of the atmosphere ; this is also done in Sicily and Malta during the prevalence of hot winds, and is faci- litated by putting the air into motion by fans. The door-ways of apartments or tents in India are often fitted with light frames of bamboo, enclosing the dried roots of a fragrant grass sparingly distributed in vertical lines all over them ; on these water is occa- sionally thrown, which, gently trickling down and eva- porating, reduces the temperature of the air which passes through the frame-work from the external atmosphere to the interior of the apartments or tents. Even in England, during the height of summer, we very frequently sprinkle water upon the ground or pave- ment in front of our houses, and experience relief by the reduction of temperature that ensues. The Egyptians availed themselves of this produc- tion of cold by evaporation for the purpose of cooling- water : pitchers were filled with the coldest water that could be obtained, and servants were employed through- out the night, to keep the outsides of these constantly 132 SUMMER. wetted with water ; as it evaporated, it abstracted heat from the pitchers and their contents, and when the utmost depression of temperature was gained, the pitchers were hound round with bands of straw, which, being a very imperfect conductor, prevented the water from immediately gaining the heat of the surrounding atmosphere. The porous vessels of earthenware which are used for wine-coolers act upon the same principle; being dipped into water, they imbibe a large portion by ca- pillary attraction ; this gradually evaporates upon their removal into the air ; and as part of the heat requisite for the production of vapour will be taken from a bottle of wine placed in the vessel, a considerable diminution of temperature is obtained. To remain in wet clothes, is proverbially dangerous, especially when exposed to a draught of air, for evapo- ration immediately takes place with such rapidity, that the animal heat of the body is lowered below its natural standard, and rendered injurious to vitality ; if, how- ever, exercise be taken, there is less danger, because the action of the muscles incites the evolution of animal heat, in proportion as it is demanded by evaporation. The natural temperature of the human body is be- tween 96 and 98 degrees; but when we take very active exercise, or when we are exposed to a great degree of heat, there is a tendency to a rise of tem- perature, which is conducive to health ; and the most SUMMER. 133 injurious effects would ensue, if it were not for perspi- ration, which withdraws heat from the body, and cools it down to the healthy standard ; if this perspiration be checked in its escape, by air-tight, or water-proof clothing, the most serious and occasionally fatal con- sequences may ensue. By merely placing the hand on a cold, dry plate of glass, or in a bell-glass, the watery vapour which escapes as perspiration will condense, and immediately become perceptible, as it was found to do from the surfaces of leaves in the experiment at page 79. Upon applying a cambric handkerchief to the per- spiring brow, great relief and coolness are immediately experienced, because the fine fibres of the cambric have an extremely strong capillary attraction for mois- ture, and a good conducting power as regards heat; thus by rapidly abstracting both moisture and heat from the skin, the refreshing sensation of coldness is produced. The case is different with a cotton handkerchief, be- cause its coarse fibres have neither strong capillary attraction nor good conducting power ; and its appli- cation to the skin produces a sensation of heat. The cold produced by evaporation can be imme- diately detected by several simple experiments; for example, let the bulb of a thermometer be smoothly covered with a piece of fine cambric ; and by keeping this constantly wetted during the time that the ther- mometer is suspended in a draught of air, or by blow- ing upon it from a pair of bellows, the thermometric 134 SUMMER- liquid, be it either mercury or spirit, will descend, and indicate cold. Fig. 29. The above engraving represents a glass tube, about one quarter of an inch internal diameter, and ten inches long, having at one extremity a bulb one inch and a half diameter, and at the other, which is bent like a shepherd's crook, another similar bulb, with a small short neck; pure water is introduced through this, until the plain bulb is about half filled ; and then, by cautiously holding it over the flame of a spirit-lamp, the water will soon boil ; its steam will expel all the air originally contained in the instrument ; and when this happens, the orifice of the neck is suddenly melted by the flame of another lamp. The instrument is thus finished, and by shaking it, the water will fall through the tube from one bulb to the other, not with a gurgling sound, but with a sharp clicking noise, because there is no air to resist its rapid fall, or to act as a spring against its immediate contact with the glass ; or in other terms, the water is in vacuo, as regards the absence of air, and only subject to the pressure of its own vapour. If the instrument be now held slightly inclined, as shown in the engraving, with the hand grasping the SUMMER. 135 plain bulb, the expansion of tbe vapour will force nearly all tbe water into the other ; the moment after this has ensued, it will be succeeded by a rapid bub- bling, and the hand will then experience a sensation of cold, because heat is suddenly withdrawn from it to enable the small portion of water adhering to the bulb to assume the state of vapour. The empty bulb of the instrument may be now placed in a mixture of equal parts of finely-powdered ice and salt, contained in a pint finger-glass, and covered with a glass shade, for the performance of another expe- riment, the rationale of which is as follows. Fig. 30. The mixture of ice and salt produces a very low temperature, (for a reason to be explained hereafter,) it immediately condenses* the vapour in the bulb into water, and afterwards solidifies it into ice ; but the water contained in the upper bulb immediately emits a portion of vapour to supply the loss below ; this in turn is condensed and solidified, fresh vapour is again 136 SUMMER. emitted from above, and so on, until the water by these successive calls has lost so much heat that it can no longer remain liquid, but is forced to become solid or to freeze, although at so great a distance from the source of cold. Hence the instrument is known to the chemist by the name of " Cryophorus, or Ice-bearer ;" and when the phenomenon has ensued, the bell-glass should be lifted off, and the instrument immediately removed, (for a reason to be given hereafter,) that the ice may slowly thaw; and it will present the same pheno- menon, upon immersion in a freezing mixture at any future time, even in the height of summer, if covered with the bell-glass to prevent the direct access of warm air to the upper bulb. It illustrates the curious fact, that water may be frozen by the cold produced during its own evapora- tion; but the more particular consideration of the wonderful natural law which presides over the tran- sition of water into ice, will demand our attention, during our examination of the chemical phenomena of Winter. From this experiment, and from the Table at page 1 30, it is evident that water is capable of evaporating at very low temperatures ; and on account of the im- mense quantity which is spread over the globe, many extraordinary and important changes in the atmo- sphere are doubtless caused by this phenomenon. Accurate experiments appear to justify the conclu- sion, that the annual evaporation of water averages SUMMER. 137 thirty inches, meaning, that the vapour, if re- con- verted into water, would cover the surface from which it ascended, to a depth of thirty inches ; then the sur- face of all the waters of the globe being assumed at One hundred and twenty-eight millions of geographical miles, nearly Sixty thousand cubic miles of water would be annually changed into vapour. The presence of watery vapour in the air is indicated by its condensation upon a cold surface; as for ex- ample, on that of a decanter, containing water drawn from a deep spring ; and yet more satisfactorily, by the action of certain substances which have a powerful che- mical attraction for water, Pearl-ash, or Carbonate of potash, is one of these ; if an ounce of it be carefully weighed, and left in the scale for a few hours, even during the driest weather, it will be observed to pre- ponderate, on account of attracting water, and in the course of some days, although thoroughly protected from rain, the solid pearl-ash will change into a thick oily liquid ; this is only an extremely strong solution of the substance in water attracted from the atmo- sphere ; Pearl-ash is accordingly called a Hygrometric, and Deliquescent compound. It is popularly known, that clothes wetted with sea- water will seldom become perfectly dry ; this is be- cause sea-water contains chloride of sodium and chlo- ride of magnesium, the former being hygrometric, and the latter deliquescent, so that in place of the clothes drying perfectly, they absorb water from the air, with greater or less avidity according to the temperature. 138 SUMMER. In very hot and dry weather, a white crust appears on clothes that have been wetted with sea-water ; this is the saline matter, deposited by the evaporation, but it will soon disappear or dissolve upon the approach of damp weather. Hence a sea- weed forms a natural hygroscope, the alternate appearance and disappearance of its saline matter, its crispness, and softness, indicating changes in the dryness and dampness of the weather. If a large sponge be dipped in sea-water, and then squeezed almost dry, upon being accurately balanced in a pair of scales suspended from a steady support, it will be found to preponderate, or to ascend, according to the relative dampness or dryness of the weather. f Fig. 31, It by no means follows that hygrometric substances should contain deliquescent salts, for many do not, yet their physical, fibrous, or capillary structure is such as to enable them to absorb water mechanically, and thus become affected in form ; this is the case with the beard of the wild oat, it is commonly placed in a small SUMMER. 139 circular frame at the top of the household u weather- glass," and by twisting and untwisting, during atmo- spherical changes in the local quantity of watery vapour, carries round a piece of straw as an index to " Dry " and " Moist." " The weather-house" is a very ingenious and accu- rate hygroscope, well known to most husbandmen; it consists of a small model of a building, having two archways, separated by an intervening pier, or column, which does not quite touch the floor ; one end of a piece of harp, or violin string, is secured to the roof; and passing down the pier, carries at the other end a cross-wire, an extremity of which proceeds into the centre of each of the archways, supporting on the one hand a male, and on the other a female figure. The harp, or violin string, is then gently turned, that the figures may be parallel with the archways ; and as it is a hygrornetric substance like the beard of the wild oat, it will twist or untwist according to the dryness or dampness of the air, and cause in the former case the cross wire to turn, that the female figure may come beyond its arch, whilst in the latter case, the male figure will advance. This " weather-house," and another similar con- trivance equally well known, as " the .monk and cowl," to indicate changes in the humidity and dryness of the air, should be kept in a hall or passage, where the natural temperature is unaffected by the artificial heat of a fire ; if they be placed in a warm dry room, the female figure will be always beyond its arch, and the 140 SUMMER. cowl always thrown back from the head of the figure of the monk. Although the foregoing, and many other, sub- stances are commonly called " Hygrometric," they are more correctly denoted by the term " Hygroscopic," since they do not measure, they only show, the pre- sence of watery vapour in the air, the true " Hygro- meter " will engage our attention when considering the chemical phenomena of Autumn. The atmosphere being continually in motion from the disturbance of its equilibrium by heat, performs a most important part in the economy of Nature, the tropical regions are refreshed, and their temperature prevented from attaining a degree insupportable to the human frame by the cool currents that arrive from the polar regions ; and, on the other hand, these have the severity of their cold modified by the arrival of warmer gales. Tropical islands and coasts are subject to the re- freshing agency of sea and land breezes ; these result from the motion of the atmosphere in seeking to re- store the disturbance of equilibrium that it has sus- tained by heat. The chemist offers the following explanation of these phenomena : the solar beams are incapable of eleva- ting the temperature of the transparent water of the ocean, or the transparent volume of the atmosphere, but they heat the surface of the opaque earth, as already stated, with great facility ; therefore an island exposed to the tropical sun, has its soil greatly SUMMER. 141 elevated in temperature, and communicating heat to the air, a strong ascending current is produced, whilst other portions of air from the cooler surface of the ocean, immediately glide inland to restore the equili- brium, and this constitutes the sea-breeze. During the night, the surface of the island, no longer subject to the direct influence of the sun, becomes much cooler than the super-incumbent air, and causes it to contract in volume, to become heavier, therefore it sinks down, and spreads on all sides, producing the land breeze; this is frequently loaded with unhealthy exhalations from decomposing vegetation, whilst the sea breeze is salubrious and fresh. Although water is so essential to the growth of ve- getables, if it remain in them after they are removed from the soil, or deprived of vitality, it is the most active agent in causing their decay and corruption ; and in order to preserve them, they must be dried to a very great extent, but always short of that which would cause a new arrangement of their elements or decomposition. The atmosphere, on account of its strong attraction for water, and its miraculous adjustment of tempera- ture, is a grand natural agent for effecting this de- siccation generally, and of the hay and corn harvest particularly. The long green grass, as it falls beneath the scythe of the mower, is extremely succulent or abundant in water, and if collected into heaps, it would soon pu- trify and become worthless. 142 SUMMER. The careful and provident husbandman, knowing this fact from experience, not only chooses the most settled weather for the commencement of the hay- harvest, but engages a troop of active work-people, to follow directly in the track of the mowers, and to shake and turn the green swathes about, that all may be quickly and effectually dried in the warm air; and when this is properly done, the hay may be stacked without danger, it is no longer prone to rot, but re- mains a fragrant nutritious store of provender against the " time of need." The very best sun-dried hay generally contains upon the average from fourteen to fifteen per cent, of water ; but this quantity does not interfere with its preser- vation. In this country, the weather is not always propi- tious during the hay-harvest ; heavy showers are very frequent, these saturate the newly-mown grass, and dissolve out a considerable portion of nutritious mat- ter, and load the air with so much vapour, that no drying can ensue until the return of fine days. It is an old saying, that " hills draw the wet," or " hills draw the clouds," but they have no inherent or particular attraction in this respect, they are only surfaces of the earth, projecting above its common level, and thus being nearest to the clouds, they soonest receive the rain, and often in such abundance, that it swells into floods, which descending on the re- cently-mown low lands, suddenly inundate them, and carry off the hay. SUMMER. 143 This disaster is not only confined to the immediate districts in which it first occurred, hut is very fre- quently extended to others many miles remote, as the flood rolls onward, to seek its level; every possible means are therefore taken by the husbandman, for preventing the total loss of the valued crops, upon which his hopes of future prosperity were anxiously founded ; hurdles and tall stakes are thickly set upright in the course of the flood, ropes and chains drawn across it wherever practicable; all hands are active with rakes, and these contrivances, aided by fences, hedgerows, and plantations, are sometimes effectual in arresting or collecting a portion of the hay ; it then requires fair weather for drying, but is found to be greatly damaged, not only by the solvent power of the water, but by the sandy and earthy matters deposited from the mud. During the anxiety and hurry consequent upon un- propitious weather, the husbandman is often compelled to stack the hay whilst it is damp ; but he generally takes the precaution of leaving one or more vacant spaces, reaching from the bottom to the top of the stack, to admit air, and to allow of moisture evapo- rating from the hay ; and thus the chance of its heat- ing or firing is greatly if not effectually prevented. When a stack consisting of many tons of hay is burned, either by natural causes, or by the accidental contact of household fire, or by the wilful application of the torch of an incendiary, the only remaining traces of the originally valuable property, are a few pounds of 144 SUMMER. apparently worthless vitrified ashes, How are we to account for this ? On chemical principles: the chemist, during his manifold researches, examines the elements and com- pounds which are required for the growth of " the grass of the field ; " and he proves, that unless the earth Silica, and the alkali Potash, be duly present in the soil, it will not yield a full crop ; he discovers that the minute terminal fibres of the roots of every kind of grass, during vitality, have the extraordinary power of withdrawing these two inorganic compounds from the soil, and of elaborating them as clothing for their own organic structures ; and that when the vitality of the grass is destroyed by the scythe of the mower, the silica and the potash still remain in the dead and withered hay. The chemist prepares a mixture, containing certain weights of Silica and Potash ; he heats this in a fierce fire, he finds these two substances combine, and melt into a liquid, which upon cooling becomes solid Glass. This curious experimental fact enables the chemist to explain, that during the combustion of the hay- stack, the elements, Oxygen, Hydrogen, and Carbon, constituting its actual organic matter, escaped as flame and smoke, whilst the compounds Silica and Potash, being inorganic and fixed, were incited by the intense heat to combine and produce Glass, similar to that obtained in the operations of the laboratory. The destruction of the valuable stack by fire, may at SUMMER. 145 first sight be regarded as a loss, for which no compen- sation is made by the curious discovery concerning its vitrified ashes ; but after the grief of the moment has passed, and the husbandman can reason calmly, he finds that the catastrophe teaches him an important lesson. In plain terms, it places before him, directly and palpably, the inorganic substances which every kind of grass requires for its clothing ; it leads him to rea- son upon this, and to mingle silica and potash with soils in which they are not naturally abundant ; and thus, under Providence, the next consignment of seed to the earth, may germinate and flourish in greater perfection and luxuriance, and yield at the season of maturity a greater and more valuable harvest than even that of which a portion was destroyed. The chemist proves the same facts to be even more importantly applicable, as regards the growth of corn, for he discovers the beautifully smooth and polished clothing of its straw, consists of silica naturally with- drawn from the soil, in company with potash, and elaborated by the wonderful vital functions of the plant. This silica, by its flinty hardness, and its insolubility in water, shields the soft organic tissue of the straw from the depredations of insects, and protects it from the solvent action of rain ; it likewise confers strength and elasticity upon the tissue which alone would form a weak and fragile stem, enables it to support the weight of the full ear, permits it to bend beneath the H 146 SUMMER. passing blast, and causes"! t to recover an erect position in the tranquil air, that its maturity may be promoted by the rays of the glowing sun. Silica is nearly absent from the ear of corn, but the earthy compounds already mentioned as phosphate of lime and phosphate of magnesia, are invariably pre- sent in considerable proportion ; and if these sub- stances, together with potash, do not naturally occur in soils intended for the growth of corn, they must be artificially added by the agriculturist, or a full harvest can never be obtained. " Sandy and calcareous soils are generally deficient in potash, and are unfruitful in grasses and corn ; but turnips, and other plants which require but little of such compound, will thrive exceedingly well ; on the other hand, clayey, or argillaceous soils, are very abun- dant in potash, and accordingly are fruitful in grasses and corn." The agriculturist is aware that successive crops of wheat cannot be advantageously grown upon the same soil ; the chemist points out the reason of this, namely, that the potash of the soil becomes exhausted ; and he proves that wheat crops, of all others, are the most ex- hausting ; for example, one hundred pounds of wheat- straw, when burned, will generally yield fifteen pounds of ash or cinder; whilst the same weight of barley straw will yield but nine pounds, and of oat straw only four pounds. The growth of beans and of beet de- mands none of the earthy compounds which are so imperatively requisite for that of wheat and other grain. SUMMEK. 147 The insolubility and permanence of the silicious clothing of straw, point it out to the husbandman as the best natural material for covering hay- stacks and corn-ricks in the form of thatch. Long unbroken straw is selected for this purpose, as it is water-proof, and allows the rain to trickle freely from its surface ; but broken straw will not answer, because its silicious clothing is full of fissures or ca- pillary channels, which would receive and retain a con- siderable portion of the rains of Autumn, or the snow waters of early Spring, and soon become rotten and useless as a protection against further inclemency of weather. A thick layer of good thatch is a covering not only water-proof, but of exceedingly imperfect conducting power, equally preventing the sudden penetration of heat and cold ; thus in Summer, ice may be prevented from thawing by overing it thickly with straw ; and in Winter, fruits may be preserved from frost by similar means. The " bungalows " of India are built with baked or unbaked bricks, and they are generally thickly thatched, to prevent the transmission of heat ; so are tents like- wise protected from sun and rain by a straw thatch laid on frames of bamboo. The limit prescribed for this general investigation concerning the phenomena of the Four Seasons, which admit of elucidation through the science of Chemistry, now demands the conclusion of this Chapter relating to a few only, of those which are presented during the H 2 148 SUMMER. beautiful season of Summer, and throughout it, whilst humbly considering, and endeavouring to explain the manifold and " wondrous works " by which we are surrounded, we have been inevitably led to extol the power and goodness of " The Great Workmaster." " He that created the heavens and stretched them out; He that spread forth the earth, and that which cometh out of it ; He that giveth breath unto the people upon it, and spirit to them that walk therein." Numberless phenomena remain veiled in impene- trable mystery to all men, and regarding such the lowly- minded and true " lovers of wisdom" make a full con- fession of their ignorance ; but, unhappily, examples are numerous, of men proudly assuming the title of " philosophers," and so greatly estimating their own abilities, as to be ready, not only to explain everything, but dogmatically to state what MUST be the physical cause of everything, in the vast and perfect laboratory of Nature, as if they were explaining the machinery, and demonstrating the motive power, of a work made with hands. These are not " philosophers ; " nor have they the remotest claim to the title, as they are deficient in its leading attribute of humility, for " Hardly do we guess aright at things that are upon earth ; and with labour do we find the things that are before us." CHAPTER III. AUTUMN. *' HE changeth the times and the seasons ;" He now ordains the reign of Autumn to commence, accompa- nied by the glorious sun, still shedding brilliancy and heat, for the advancement of the productions of the earth to the mature and bounteous harvest, the hope of which has so long cheered the husbandman through- out his anxious toils. Many extraordinary and beneficial natural pheno- mena, several of which may be elucidated through the science of chemistry, are frequently presented in an equal degree during the end of Summer and the be- ginning of Autumn; these will accordingly now demand our attention ; and in the first place, let us direct it in continuance of the investigation concerning the mira- 150 AUTUMN. culous provision that is made to prevent the earth from the accumulation of a withering and destructive inten- sity of heat. We have already found that the earth is capable of absorbing heat, though incapable of conducting it to any considerable extent ; we shall now discover that the earth has likewise the power of parting with an excess of heat by radiation towards the unclouded Summer and Autumnal skies. The meaning of the term " radiation " may be thus explained : suppose the circle in the centre of the annexed engraving to represent a heated body, the star-like lines emanating from it may denote that heat is escaping, or radiating from it in all directions, quite independent of conduction or of convection. Fig. 32. A few simple experiments of the chemical laboratory will serve as an introduction to the grand natural phe- nomenon of radiation. A plate of metal, either dull or bright, is an excel- ACJTUMN. 151 lent conductor of heat ; if, for example, a lighted coal be placed upon any part of its surface, this will soon become equally warm throughout its whole extent. At the distance of four or five feet in front of a clear glowing fire, hold a large bright tin-plate, in any posi- tion, and it will not become warm ; turn it about, pre- sent its surface at different angles to the fire, and at last a certain angle will be found, at which, although the plate remain cold, heat will instantly dart from its surface, and may be sensibly felt upon the face or hands. Thus, in chemical language, heat is said to radiate from the glowing fire, through the intervening non- conducting air, to impinge upon the metal plate, and although it is an excellent conductor, of mere heat of contact, as that of the lighted coal in the first experi- ment it is not a conductor of this radiant heat which reaches it from the distant fire, it is not even a re- tainer of this radiant heat, but it is an admirable reflector of this imponderable element, and accordingly it instantly darts upon surrounding objects, whilst the metal plate or reflecting surface remains perfectly cold. Place the bright tin-plate flat upon a table, fold half a sheet of fine emery-paper smoothly around a small book, or a flat piece of cork, and with this rub the surface of the tin-plate all over, in the direction of its length ; then do the same in that of its breadth ; and thus effectually destroy all brightness or polish, Now hold the tin-plate in front of the fire, as at first ; 152 AUTUMN. it will soon become hot, and it will reflect but little heat; thus, by mere mechanical alteration of its surface, the metal is instantly rendered a retainer of radiant heat, and depnved of its power of reflecting such agent. Select another tin-plate, brush one of its bright sur- faces over with weak glue ; then sift fine sand over this, and allow it to dry ; thus the bright polish is covered, and not destroyed; and upon holding this sanded side in front of the fire, as already directed, the tin-plate will become hot, but no heat will be reflected. Similar will be the result, if the tin-plate be painted with a mixture of weak glue and lamp-black, whiting, yellow ochre, Venetian red, Brunswick green, or any pigment that may be chosen. In like manner, if a large flat surface of paving- stone, or an unglazed earthen paving-tile, be held in front of the fire, no heat will be reflected from them ; but they will absorb heat, and soon become warm. The following striking experiments will afford far- ther illustrations concerning the extraordinary manner in which the mere alteration of the lustre of a metallic surface affects its habitudes with radiant heat. Select a large tin-plate, equally bright and polished on both sides, and with a strong pair of scissors, or small shears, cut it across to form two pieces similar in size, leave one of these without any farther prepara- tion, but blacken one side of the other with lamp- black, mixed with thin glue, and allow it to dry. AUTUMN. J53 Provide a strip of wood, one foot long, one inch thick, and four inches wide, and with a saw, make two cuts or grooves across this, each of these being an inch from each of the ends of the wood, and each suffi- ciently deep to hold a tin-plate firm and upright when inserted on its shortest edge. Place each plate in its groove, the black surface of the one being opposed to the bright surface of the other ; attach a marble to the centre of the exterior surface of each with a lump of pomatum, then hold a red-hot heater of an " Italian iron" exactly between the plates, as shown in the annexed engraving. Fig. 33. The plates are thus exposed to the same degree of heat that is radiating from the red-hot iron ; but they have different habitudes with it, the bright surface will reflect nearly all, and will not become sufficiently hot to melt the pomatum, and so cause the marble to drop ; whilst the black surface will absorb nearly all, H 5 154 AUTUMN. and will soon become sufficiently hot for such pur- pose. By experimenting with great accuracy, the chemist has discovered, that as the unmetallic surface will absorb heat with the most facility, so will it part with such heat, or cool, or radiate such heat with the most faci- lity ; the following experiment will prove this fact sufficiently well for our present purpose. Fig. 34. Take the tin canisters that were used in the expe- riment at page 111, cleanse the adhering oil from the one by washing it thoroughly with a strong solution of pearlash, then rinse it with water, and polish its exterior as bright as possible ; paint the exterior of the other with the black mixture already described, and allow it to dry. Pour an equal quantity of cold water into each, place on their respective covers, and insert the ther- mometers, that the bulbs may dip beneath the water, the bulb of the oily thermometer having been cleansed as above directed. Lay a soft brick flat upon the table, and in its AUTUMN. 155 centre, with a knife or chisel make a hole about three- quarters of an inch deep, and sufficiently large to admit the end of the iron-heater of a tea-urn ; make the heater red-hot, and then drop it into the hole, and place a canister to stand at each end of the brick. They will be equally distant from the radiant heat of the iron indeed , more accurately so than the tin- plates were in the last experiment but still the black surface will heat the water the fastest, as an inspection of the thermometers will prove. Let it heat to 100 degrees; using a fresh heater, if necessary ; then remove the canister from the brick, and place it upon the table ; remove the bright canister also, throw away its almost cold water, and fill it with water heated to the same degree as that contained in the black canister, and place it likewise upon the table; watch the thermometers, and they will indicate that the water in the black canister is cooling, or radiating heat, more rapidly than that in the bright canister, which will remain sensibly warm when the other is cold. These results are directly contrary to those which might be anticipated to ensue, we might think that by coating a metal-plate with black paint, a bad con- ductor, that it would prevent the heat from coming into contact with the metal beneath, and so keep it cold ; and, on the other hand, the bad conductor would keep in the heat of the water ; but the chemist proves that unmetallic, or earthy substances, though 156 AUTUMN. extremely bad conductors, are most excellent absorbers and radiators of heat. Another curious and instructive experiment con- cerning this power of surfaces in radiating heat may be made by covering one of the sides of a cubical tin- plate canister with lamp-black, another with thin jelly, a third with writing-paper, and leaving the fourth bright and polished : then upon filling the canister with boiling water, and approaching the sides in suc- cession with the hands, or a thermometer with a blackened bulb, the different radiating powers of the various coatings will be immediately detected. The greatest heat will be found radiating from the lamp-black, the least from the polished surface, and if for the sake of illustration, the heat from the lamp- black be supposed equal to one hundred, that from the writing-paper is ninety-eight, from the jelly eighty, and from the polished surface only twelve. " During all these experiments, it will be remarked how singularly these effects of radiation are opposed to the conducting powers of the respective surfaces, if we touch the clean part of the canister it burns us ; but we may place the finger with impunity upon the lamp-black, the paper, or the jelly, which, though good radiators, are bad conductors of heat." Kadiation not only proceeds from the immediate particles which form the surface of a body, but like- wise from those at some distance beneath, and this curious fact may be easily determined ; for example. AUTUMN. 157 take a cylindrical tin canister, and cover one half of its surface with a coating of extremely thin jelly, and the other half with four or five coatings of the same, letting one coat dry before another is applied ; when all are dry, fill the canister with boiling water. In this arrangement, although the nature of the two surfaces is precisely the same as regards material and smoothness, they will radiate very differently ; the hand held at some little distance from the thin coat- ing will not feel so hot as when held at the same distance from the thick coating, and if a thermometer, with a blackened bulb, be similarly held, it will indicate a small elevation of temperature in the one case, but great in the other. " In this experiment the increase of radiating power must be attributed to the increased quantity of radiat- ing material, and it is discovered to continue until the coating amounts to the thickness of about one hun- dredth part of an inch ; after which no further in- crease takes place ; it is inferred, therefore, that the particles constituting the jelly have the power of radiating, from a thickness below the actual surface, equal to the above amount." As regards terrestrial radiant heat, meaning by the term that of a fire, or any other artificial source, the chemist discovers that surfaces, if similar in me- chanical texture, may differ in colour, without having their receptive or radiating power either increased or diminished ; whilst, on the other hand, with solar radi- ant heat, he discovers that the colours of such surfaces 158 AUTUMN. do certainly affect both these powers most strangely ; for dark-coloured, or black, surfaces absorb and ra- diate more rapidly than such as are light- coloured, or white. Paint the bulb of one thermometer with the black mixture already mentioned, and the bulb of another, similar in size and graduation, with a mixture of whitening and glue, of equal thickness with the black ; let these bulbs dry, and then expose the thermometers simultaneously to bright sunshine, it will be imme- diately found that the black bulb absorbs heat quicker than the white bulb, by the greater rise of the mercury in its tube ; and upon removing the two thermometers into the shade, probably the black bulb will indicate that it radiates heat quicker than the white bulb, by the more rapid descent of the mercury in its tube. Again, nine pieces of equally fine kerseymere cloth, seven of them having the prismatic colours, and of the others, one black, and the other white, upon expo- sure to sunshine for the same time, will heat very differently, and of the colours, probably in the follow- ing order, the first being the hottest ; violet, indigo, blue, green, red, orange, and yellow; but the black cloth will surpass even the violet in temperature, whilst the white cloth will not even attain that of the yellow, as the application of the bulb of a thermometer will immediately prove. From an experiment of this kind, we discover that " the warmth or coolness of clothing depends as well on its colour as its quality ; a ' white dress, or one AUTUMN. 159 of a light colour, will always be cooler than one of the same quality, hlaok, or of a dark colour,, and espe- cially so in clear weather, where there is much sun- shine; white, or presence of colour, and very light hues, reflect heat copiously ; hut black, or absence of colour, and very dark hues, reflect little." " Experience has long supplied the place of science in directing the choice of clothing ; the use of light colours always prevails in summer, and that of dark colours in winter/' Eeasoning upon this property of black and dark surfaces in absorbing heat, a natural conclusion is drawn that the black skin or " rete mucosum" of the Ethiopian, would cause him to undergo severe suffer- ing under the intensity of the tropical solar rays ; but our experiments, be it remembered, have been made either upon inorganic matters, or matters deprived of vitality, and they do not hold good with bodies under the influence of the recondite agencies of life, an extra- ordinary fact or anomaly, so called by the finite wis- dom of man, is then presented. The Creator, in His power and goodness, has mer- cifully ordained, that the skin of the Ethiopian shall absorb heat powerfully, but, at the same time, that it shall not sustain the slightest injury. This extraordinary fact was originally investigated by a physiologist in a series of extremely simple yet decisive experiments, of which the following are selected. 160 AUTUMN. During an intensely hot day, he exposed the back of each hand to the sunshine for ten minutes, one hand being bare, and having a thermometer attached to it, the other being covered with black cloth, and having the bulb of a thermometer beneath this. At the expiration of the above time, the exposed thermometer indicated eighty-five degrees, whilst the covered thermometer indicated ninety-one degrees ; in a second trial, the former indicated ninety-one degrees, the latter ninety-four degrees ; and in a third trial, the first thermometer indicated ninety-eight degrees, whilst the second indicated one hundred and six. de-; grees. In these three trials, the bare skin was powerfully scorched and raised in blisters, but the covered skin, though so much hotter, was not in the slightest degree injured. Upon covering one hand with white cloth, and the other with black cloth, and exposing them for a simi- lar time to sunshine, the former was invariably scorched, but the latter never afiected. The power of the solar rays to scorch the skin of man and animals is destroyed when these surfaces are black, although the absolute heat in consequence of the absorption of the rays is greater. " The same wise Providence which has given so extraordinary a provision to the Negro for the defence of his skin, while living within the tropics, has extended it to the bottom of the eye, which otherwise would AUTUMN. 16 f suffer in a greater or less degree when exposed to strong light ; the retina from its transparency allowing it to pass through without injury." The black or dark matter of the " retina" is techni- cally called the " nigrum pigmentum," and is probably not absolutely necessary for vision, but only provided as a defence against strong light, since it is found to be much darker in the Ethiopian than in the European, and is of a lighter colour in fair people than in dark, and therefore lightest in those countries farthest re- moved from the effects of the sun. The scorching power of the solar rays being de- stroyed when received by black surfaces is an incon- trovertible fact, and the only explanation that the chemist can offer regarding it is that the mixture of heat and light in the solar rays is absorbed by black surfaces, and converted into sensible heat. The sudden and fatal infliction called " the sun- stroke" that frequently seizes reapers and labourers, in the intense heat of harvest time, is referred to the scorching effect of the solar rays, upon the scalp of the head, producing inflammation of the brain, and probably the first record of this is in th& following Scripture passage. " And when the child was grown, it fell on a day that he went out to his father to the reapers. And he said unto his father, My head, my head ! And he said to a lad, Carry him to his mother. And when he had taken him, and brought him to his mother, he sat on her knees till noon, and then died." 162 AUTUMN. In extremely Lot climates the traveller is often " sun-stricken," and dies ; and in allusion to the watchful care of Providence over His chosen people, it is said, " They shall not hunger nor thirst ; neither shall the heat, nor sun smite them : for He that hath mercy on them, shall lead them, even by the springs of water shall he guide them." The difference between the heating of dark and light-coloured soils, when equally exposed to solar heat, and their difference in cooling when equally placed in the shade, as mentioned at page 104, may be now stated in technical terms, viz., that dark soils absorb heat more powerfully, and radiate heat more energetically than light- coloured soils, which reflect a great portion of heat; we have now to examine how these facts, and others concerning the mere alter- ation of surfaces in affecting both absorption and ra- diation of heat, are applicable to the explanation of a beautiful phenomenon of Summer and Autumn. The night has been serene, the moon and stars have shed their brilliant light, no clouds have obscured the heavens, no rain has fallen, and yet when we step forth at daybreak, we find the grass and the flowers of the field loaded with myriads of drops of water, sparkling like gems in the golden rays of the rising sun. We recognize this beautiful phenomenon as Dew ; but from whence has it silently journeyed and ar- rived during the hours of night? can the chemist- reply ? AUTUMN. J63 He can ; and the reply will furnish another example of the power and goodness of God, for " His favour is as dew upon the grass ;" another proof of the ever- watchful care of Him with Whom " the darkness and the light are both alike/' Whose Hand is equally extended for the protection of the animated creation during its noontide activity and its midnight repose. Throughout the fervent glow of a Summer or Au- tumnal day, the solid opaque earth absorbs heat ; this abides upon its mere surface, and is not conducted beneath ; but at sunset, if the sky be cloudless and calm, the earth immediately radiates part of the heat upward, and soon becomes many degrees colder than the air directly incumbent upon its surface ; accord- ingly the watery vapour that is present in the yet warm air, is chilled or condensed into drops of water, and these " distil as the dew" upon the earth, for the refreshment of its productions. This phenomenon cannot fail of appearing remark- able, even to the most careless observer, and it be- comes yet more so, when accurately investigated by the chemist. Examine a garden immediately after sunrise at this season ; probably the grass-plat is saturated with dew ; the gravel walk is nearly dry ; the leaves of the hollyhock are dripping with water ; the leaves of the laurel are free from moisture ; but all these objects were similarly exposed to the night air, and if dew were a fine rain, as some persons ima- gine it to be, all should be equally covered with- its drops ; why is this difference observed ? 164 AUTUMN. Because the surfaces of the various objects differ in their radiating power ; the grass-plat and the leaves of the hollyhock are excellent radiators; they throw off heat with great energy, and so becoming cold, they induce a more copious deposition of water from the air than the gravel -walk and the laurel leaves, which, being bad radiators, retain heat, and remain so warm that the watery vapour in the air wafts over their surfaces without being chilled or condensed, and therefore they are free from dew. Hough or woolly leaves, like the painted or sanded surface of the tin-plate, radiate heat most rapidly, whilst smooth or varnished leaves, like the polished or bright surface of the tin-plate, do not radiate with such energy, and as a consequence of this, the former leaves, ensure a more plentiful deposition of dew than the latter. From the limits of the garden, let us carry forth these observations and facts into the boundless fields of Nature, and discover the miraculous workings of Providence. Barren rocks and soils, by reason of their peculiar hard and compact structure, have neither the power of absorbing nor of radiating heat with great energy, they do not speedily acquire a low temperature during the clear nights of Summer and Autumn, and as a consequence, dew is scarcely, certainly not abundantly, deposited upon them ; it is not required for their sup- port, and they have no vegetable life, or but little of the lowest grade to maintain. AUTUMN. 165 Like every treasure from the bountiful Hand of God, the precious (f dew of Heaven" is not lavished and scattered upon objects that are unfitted for its reception, and therefore can derive no benefit from its genial influence, but only abundantly upon such as are properly prepared, and accordingly these obtain whole- some nurture, and bring forth good fruit, whilst the former remain as barren stones. Naturally fertile soils, and such as are artificially ren- dered productive, are generally of a loose porous struc- ture ; this physical peculiarity enables them to absorb heat abundantly during the day, and to radiate it so power- fully at night, or, in other words, to become so many degrees colder than the -ambient air, that its watery vapour condenses upon them and their productions as dew in abundance. It is indeed a subject well calculated to arrest our attention, and excite our admiration and gratitude, when we thus find every soil, plant, shrub, and tree, has, by its own physical peculiarity of structure, in- duced the deposition of dew in proportion to its wants ; and when we reflect that not a single dew- drop is created in vain, but each is measured by The Hand of Infinite Wisdom, and appointed to fulfil some useful end. Some tracts of land, when clothed with vegetation, radiate heat with such vast energy that their low tem- perature not only causes the plentiful deposition of dew, but subsequently changes it into frost ; but this extreme of cold, if continued, would be equally fatal 166 AUTUMN. to vegetable life as an extreme of beat, and as upon a former occasion, we discovered The Hand of Provi- dence extending clouds for protecting the earth from the heat of noon, so upon this, do we discover the same Hand, extending them for preventing the undue escape of heat from the earth during the cold of night ; "for His mercy is great above the heavens, and His truth reacheth unto the clouds." These recondite accumulations of vapour, or clouds, intervening between the earth and the confines of the air, act as screens in arresting radiation from the earth to the sky, and also being warmer than the earth, they now radiate part of their own heat to it, and thus restore a due temperature to its chilled pro- ductions. Moderate tranquillity of the air, and a serene sky, are essential requisites for the perfect deposition of dew, for very little takes place during the prevalence of winds, and none during that of clouds, unless they are exceedingly high in the air, because the former disturb, and the latter arrest, the radiation of heat from the earth. During a fine Summer or Autumnal night, the following curious and instructive experiments can be made regarding this beautiful phenomenon of dew. Weigh some dry wool into two portions of twenty grains each, for example ; then bend a large sheet of pasteboard in half, to form a kind of pent-house, place this with its ridge uppermost on a closely mown grass-plat, and lay one of the portions of wool on the AUTUMN. 167 middle of the grass beneath the pent-house ; and the other portion on the adjacent grass fully exposed to the sky. Fig. 35. Examine this arrangement at sunrise, and the sheltered wool will he found to have increased only about four grains in weight, whilst the exposed por- tion will probably have increased about thirty-two grains ; the slight pent-house, although open at both ends, and admitting the free access of air, yet pre- venting, in a remarkable degree, the direct radiation of heat from the wool, and accordingly opposing any great deposition of dew; in fact, throughout the night it has been warmer beneath the pent-house than in the open air. The foregoing experiment admits of variation to prove that even more partial shelter from direct radia- tion causes the deposition of dew in smaller quantity to that which appears upon objects fully exposed, and it will entirely remove the notion that dew is a kind of fine rain, falling from the atmosphere. Place a few bricks upon a grass-plat, to form a small wall, about three feet in height ; at the foot of this, spread twenty grains of dry wool, and some feet distant place a similar weight of the same sub- 108 AUTUMN. stance ; let this arrangement remain during the night, and upon examining it at sunrise next morning, (always providing no rain have fallen,) the partially sheltered wool will be found to have increased only a few grains in weight, whilst the exposed portion eight or ten times as many grains in weight. Fig. 36. Gravel walks, and stone pavements, radiate heat and acquire dew, less readily than grass-plats, hence, wool placed on the former has its temperature less de- pressed than on the latter, and therefore obtains less dew ; and this effect is by no means referrible to the capillary attraction of the fibres of the wool, for it ensues equally well if the wool be placed in a clean saucer ; nor is it referrible to hygrometric attraction of water from the air, because wool, placed upon a board, elevated at some feet from the earth, during a cloudy night, will acquire only a very minute increase of weight ; the effect is entirely dependent upon ra- diating power. Before the cause of dew was discovered, scientific inquirers were at a loss to account for the principle AUTUMN. 169 upon which a thin mat, employed by gardeners, pro- tected tender plants from cold ; it appeared scarcely possible, that such a slight covering could have any effect in preventing them from attaining the tempera- ture of the external air, and yet common experience proved its utility. When the discovery was made, that bodies on the surface of the earth become much colder than the atmosphere, by radiating heat during -a still and serene night, the true reason of the gardener's homely prac- tice of covering plants with matting, was fully evident ; it prevented radiation from taking place. Fig. 37. In order to acquire precise information upon this subject, the following simple arrangement was made : the experimenter " fixed perpendicularly in the earth of a grass-plat, four small sticks, and over their upper extremities, which were six inches above the grass, and formed the corners of a square, whose sides were two feet long, a very thin cambric handkerchief was tightly drawn. 170 AUTUMN. " Therefore nothing existed to prevent the free pas- sage of air from the exposed grass, to that which was sheltered, except the four small sticks, and there was no suhstance to radiate downwards to the latter grass, except the cambric handkerchief." ' The sheltered grass, however, was found nearly of the same temperature as the air, while the unsheltered was 5 degrees or more colder; one night the fully ex- posed grass was 1 1 degrees colder than the air, hut the sheltered grass was only 3 degrees colder." Hence we see the power of an awning, infinitely more slight in texture than that of matting, in averting or lessening the coldness of the ground that would otherwise occur, and be injurious to plants. It is for this reason that a tent, or marquee, although merely constructed of thin canvass, and by no meaas air-tight, becomes a comparatively warm shelter during a cold night ; no dew will be found upon the plot of grass shielded by the tent, but abundance upon that exposed to the open air around. A piece of matting, that has covered a plant during an autumnal night, will be found copiously bedewed, whilst the plant remains dry ; the matting having pre- sented its radiating surface, and parted with heat, which otherwise the plant would have done ; nay, even the matting occasionally performs this office with such energy, that its surface becomes covered with hoar- frost, from which it suffers no injury, as it has no vitality, whilst it shields the living plant, that other- AUTUMN. 171 wise would be compelled to radiate, and perish, by the degree of cold induced by its own power. In some countries, the temperature never falls to the freezing point of water, and yet ice may be pro- cured by taking advantage of the radiation of heat from surfaces, in the following manner. A layer of dry straw, or stubble, is spread in an open situation during a calm and cloudless night, and upon this surface are placed shallow earthen pans, filled with water; radiation immediately commences from the straw and the water ; both lose heat so rapidly and so effectually, that the water can no longer remain liquid, and therefore becomes covered with a thin crust of ice. It has been already stated, that water hastens the putrefaction of dead vegetable substances ; the same remark is applicable to those of animal origin ; in warm climates, more especially, the deposition of water, in the form of dew upon these, induces putrefaction with great rapidity; and as this generally happens only during clear bright nights, it was anciently sup- posed that moonlight favoured animal corruption. The moon, when at full, reflects upon the earth only about one three hundred thousandth part of the light of the sun ; and the lunar rays, even when concen- trated by a powerful lens, and the focus directed upon the bulb of a delicate thermometer, do not affect it in the slightest degree ; hence the phrase, " the pale, cold moon," is not only poetically beautiful, but phi- losophically correct ; and as the light alone will not I 2 172 AUTUMN. induce putrefaction, and as there is no heat, the phe- nomenon appears to be solely referrible to the radiating power of animal substances inducing a copious deposi- tion of dew upon their surfaces, for water is essentially requisite in all cases of putrefactive changes. If a thermometer be placed upon a grass-plat, it will very frequently indicate a temperature of fifteen or twenty degrees colder than one suspended over the grass, at the height of three or four feet, thus prov- ing that radiation is proceeding with extreme rapi- dity in the one case, from the comparatively solid vegetable matter and the soil, but not from the am- bient air. Accordingly, the portions of air in immediate con- tact with the grass, become much colder than those far above, and are compelled to deposit dew ; and if the air over a given locality remain tranquil for some hours, this phenomenon will solely ensue from the lower and colder portions. Small valleys, and hollow-ways, permit the air to repose undisturbed ; and although they are apparently situations sheltered from cold, yet they are frequently more subject to reduction of temperature than higher situations ; and accordingly, much to our surprise, we find delicate plants chilled, or even frost-bitten, in hollows, whilst others suffer no injury upon the adja- cent slopes. ' In the close and sheltered streets of cities, the deposition of dew is very rarely observed, because there the objects are necessarily exposed to each other's AUTUMN. 173 radiation, and an interchange of heat takes place, which maintains them at a temperature uniform with that of the air ; a deposition of dew in this case can only take place when the natural temperature of the air falls below its point of saturation." At sunrise during Summer or Autumn, we may fre- quently see a dense white mist, only a few feet in height, directly incumbent upon a grass or corn-field, whilst the air above is clear and bright with the rays of the sun ; and we may even walk along the foot- path across the field, with the lower part of our body enveloped in this mist, whilst the upper, is perfectly free from its humidity. This phenomenon of mist, is consequent upon the calm of the previous night having admitted rapid ra- diation to ensue from the earth, which then became so much colder than the great volume of the atmosphere above, that the portion in immediate contact with the earth was suddenly deprived of a large amount of its aqueous vapour, and then the mist, or " earth-cloud," thus formed, prevented any farther radiation from en- suing towards the clear sky, and therefore remained until dawn. Let us now remark another beautiful phenomenon in connexion with our present subject of inquiry : although at sunrise the dense mist reposes upon the surface of such tracts of land, and although innu- merable dew-drops bespangle the trees, plants, herbs, and flowers of others, yet as the sun mounts higher in 174 AUTUMN. the heavens to run its appointed course, both mist and dew vanish, and the earth and its productions become dry ; how is this ? Because the water of the mist and dew gains suffi- cient heat, to change from the state of visible liquid, to that of invisible vapour; this the air immediately re- ceives, and treasures in its capacious volume, through- out the glowing day ; and then at its close, if the sky be calm and cloudless, the earth and its productions again radiate the stores of heat which they had with- drawn from the noontide intensity ; they again be- come cooled, and the air commences its wonderful work of relinquishing its aqueous store as mist and dew, in just proportion for the relief of all. Thus, in the sublime and all-powerful language of Scripture, " Dew after heat refresheth : to every thing there is a season : -and shall not the dew assuage the heat ? " Or, in the imperfect and limited terms of science, thus the earth, by its peculiar habitudes as regards the reception and retention of solar heat, resists an exces- sive or destructive accumulation of this powerful, im- ponderable agent, and maintains a temperature condu- cive to the well-being of the animated creation. These are the pleasures and advantages of the pro- per pursuit of science, to examine, and if possible, interpret the varied phenomena around us, which pre- serve the order and harmony of the Creation ; they all unfold volumes of wonders, and prove, as in the case AUTUMN. 175 that we have been considering, " who seeketh Wisdom early, shall have no great travail, for he shall find her sitting at his doors." It is only of late years that man has been permitted to interpret and understand the cause of dew, but from the earliest ages he has experienced and acknowledged its wonderful and beneficial effects, and more particu- larly in those countries where rain seldom or ever falls ; hence the Sacred Writings so abound in eloquent passages, and splendid metaphors, concerning the blessings which emanated from the presence of dew, and the miseries entailed by its absence, of which the following have been selected: " For the seed shall be prosperous ; the vine shall give her fruit, and the ground shall give her increase, and the heavens shall give their dew." " God give thee of the dew of heaven, the fatness of the earth, and plenty of corn and wine." " The heaven over you is stayed from dew, and the earth is stayed from her fruit." " I will make your heaven as iron, and your earth as brass." The metaphor of the last passage is thus humbly interpreted : that the intense power of the sun should directly heat the air, and render it so arid, that neither dew nor rain should descend, and that the earth should consequently be so parched and hardened, as to be rendered incapable of being ploughed into furrows for the reception of seed. Knowledge concerning the phenomena and laws of 176 AUTUMN. the Creation, is not revealed to man, and he must attain it by the proper use of his noblest faculties ; and the subjects which he now classes into the form of a science, when mentioned in Scripture, are always couched in language accommodated to sensible ap- pearances, and popular notions, as in the foregoing, and many other passages that have been, and yet remain to be adduced. In Egypt, the wind that traverses extensive tracts of sandy deserts, is so dried as to deposit no dew ; whilst that which crosses the Mediterranean, is so saturated as to deposit it in abundance. In this country, the deposition of dew from the atmosphere is generally less during the continuance of easterly, than of westerly winds, a phenomenon attri- butable to the different nature of the surfaces over which these winds travel, the former crossing the con- tinent of Europe, and thus becoming comparatively dry or arid, the latter sweeping across the vast expanse of the Atlantic ocean, and therefore becoming moist or hydrated, requiring but little reduction of their tem- perature for the copious deposition of dew to ensue upon terrestrial objects. The mere form of a drop of rain or of dew, presents matter of inquiry to the philosophic mind ; why is it either a perfect sphere, or some modification of a sphere, and not cubical, or octohedral, or other an- gular figure; and why does it equally adhere to the upper and under surfaces of the blades of grass ? AUTUMN. 177 Because the impress of perfection is set upon every work of the Creator, and He permits man to discover that a sphere is a perfect and simple figure, the consti- tuent particles of which are equally distant from one common centre of attraction, and thus being equally and simultaneously attracted, no other figure can pos- sibly result, unless some superior external attractive force be presented. Fig. 38. A sphere, is the figure assumed by liquid water, when a portion of it is either perfectly unsupported, or sup- ported upon a surface having little attraction for it ; but it becomes more or less spheroidal, or ultimately disappears, in proportion to the extraneous attraction of the surfaces upon which it is received. Thus a drop of rain or of dew, in descending from the air is a sphere, and will so continue when received only at a minute point of contact by the upper surface of a dry blade of grass, and even gently roll unto its extremity, and pass to the under surface, and there remain pendent in opposition to the attraction of gra- vitation which is soliciting its return to the earth, the attractive force of the minute point of contact with i 5 178 AUTUMN. the blade of grass, being superior for a time to that of gravitation. If several drops coalesce into one large drop, the point of solid contact likewise increases, and then becomes far superior to the attractive force between the mobile liquid particles, and thus drawing them away from each other, produces a spheroid ; but this will remain well defined upon the upper surface of the blade of grass, or even continue pendent from the lower. By successive additions, its size becomes so great, that the surfaces can no longer oppose the attraction of gravitation, and therefore the spheroidal drop becomes more and more oblate, until it rolls or falls away, and immediately loses its form amidst the capillary chan- nels of the earth, from whence it is destined to ascend as vapour, to mingle with the air, and again to descend as rain or dew, or other forms suited alike to time and season, for not even a drop of water is lost or anni- hilated in the laboratory of Nature. When drops of water fall heavily upon the generality of vegetable productions, the abrupt shock forces them into such extensive contact with these surfaces, and also with each other, that in place of remaining as beautifully defined spheres and spheroids, they rapidly coalesce as a slender stream of water, and thus flow away into the soil, with the exception of a compara- tively few drops, which sometimes escaping this sud- den attraction, remain yet clinging to that of the ter- minal points of the leaves. The surfaces of many leaves are covered with an AUTUMN. 179 extremely fine powder, which, like fine dust upon the floor of an apartment, is repulsive of gently-sprinkled water ; thus, upon the leaves of the cabbage and the garden poppy, brilliant globules repose, and if shaken by the wind, or by the hand, they rapidly glide about without wetting the surface ; and although they may divide into many more globules, the most minute, always having the most perfect spherical form, they immediately exert attraction for each other when allowed to come into mutual contact, and coalesce into one or two large spheroidal forms of silvery radiance. The chemist proves that the petals of many beautiful and delicate flowers contain a minute portion of essen- tial oil, yet amply sufficient to render them incapable of the rapid absorption of either drops of rain or dew, by which their structures might be injured. Fig. 39. A drop of pellucid water, thus reposing within the crimson petals of a rose, and sparkling like a diamond in the morning light, must certainly present more 180 AUTUMN. attraction to the experimenter or investigator of its cause, than to the mere admirer or delineator of its beauty. In connexion with this inquiry relative to the sphe rical figures of drops of water when supported upon surfaces for which they have little or no attraction, it may be remarked, that the feathers of aquatic birds are imbued with an oily secretion, which renders them eminently repulsive of water ; thus the majestic swan, after diving its graceful neck beneath the stream, proudly raises it in the air, perfectly free from humi- dity ; or if the spray of a light wave dash over its plu- mage, the sparkling drops coalesce into one large and brilliant globule, which reposes on the snow-white feathers of its back, without wetting or disturbing their beautifully soft and regular arrangement. Water-fowl swim about boldly, dive deeply, remain for a considerable time beneath the water, and then rise buoyantly to its rippling surface with unwetted and unruffled plumage. Even the loose feathers that escape when birds are pluming on the banks of the water, are wafted by the wind upon its surface, and as they gently sail along, they afford matter of reflection to a philosophic mind ; for the slightest occurrence in Nature surely cannot be unworthy the attention of man. Again, during a summer or autumnal evening, it is both interesting and instructive to stand on the bank of a calm sheet of water, and watch the swarms of ex- quisitely-formed insects, with delicate and slender limbs so perfectly repellent of water, that are running, or AUTUMN. 181 rather darting, upon its actual surface, and scarcely depressing or disturbing its smooth and glassy tran- quillity. The foregoing, and many similar phenomena, must have been remarked by the most indifferent observer ; they are popularly called instances of the " repulsions of water, by pulverulent or oily substances ;" but the correct philosophical expression is, that such surfaces have not so great an attraction for the drops of water as their constituent particles have for each other, and therefore they preserve as much as possible the sphe- rical form which they had when entirely deprived of support. The dew that we have been considering, consists of water very nearly pure, and is therefore perfectly dif- ferent to a thick sweet liquid that is frequently ob- served to collect on the leaves of trees during Autumn, and is popularly called " honey-dew." This liquid is shed by a species of insect, known to the Entomologist under the name of the " Aphis ; " it dwells upon the under side of the leaves, and when this " honey- dew" escapes from its body, it is received upon the upper surface of the leaves below ; this liquid is very deleterious to vegetation, it fills the pores of the leaves, and disturbs their proper functions of transpiration and absorption ; they soon become dis- eased, and from being originally of a brilliant green, they turn of a dingy yellow colour. But this " honey-dew" is a favourite food witli ants, and they may very frequently be observed crawl- 182 AUTUMN. ing up exceedingly lofty trees, in order to gain a sup- ply of it from the leaves. Several contrivances for denoting the existence of watery vapour in the atmosphere, or in other words, its relative dampness and dryness, have been already noticed at page 140, under the name of " Hygro- scopes," the principle of an instrument for denoting, or actually measuring, the quantity of aqueous vapour in the atmosphere, now demands our attention, and it properly bears the name of a " Hygrometer ; " its form is shown in the annexed engraving. Fig. 40. It consists of a small and delicately -constructed " Cryophorus," (page 134,) but containing the liquid called Ether, instead of Water; the two thin glass bulbs are about one inch and a quarter in diameter, and are connected by a glass tube, the horizontal part of which is about the eighth of an inch, and the per- AUTUMN. 183 pendicular, about a quarter of an inch internal diameter; the horizontal part is only thus made of thicker glass, that it may be stronger, and not so liable to break when inserted into the small spring clip, on the top of the brass standard or column, to the shaft of which is attached a small and delicate mercurial thermometer. The horizontal part of the tube is about four inches, and the perpendicular part, six inches in length ; this latter includes another and equally delicate thermo- meter, but having an elongated, or pear-shaped bulb, merely to facilitate its introduction into a tube so small ; and this bulb dips fairly into the ether, with which one of the glass bulbs already described is three- quarters filled. The other bulb, attached to the upper and shorter part of the tube, is smoothly covered with a piece of fine cambric, secured around the tube by thread ; a small capillary neck, closed by melting the glass, pro- jects about a quarter of an inch beyond this covering. This is the appearance of the instrument, but its con- struction is as follows: the perpendicular tube, with its bulb, is first made, and the small thermometer in- troduced ; then the horizontal tube and its bulb, with the capillary neck open, are made ; the left hand extremity of this tube is then melted, or welded, to the perpendicular tube ; after this is done, ether is intro- duced through the capillary neck, until the bulb unto which it belongs is nearly filled ; and then, by invert- ing the instrument thus far constructed, the ether is 184 AUTUMN. caused to flow into the bulb attached to the tube con- taining the thermometer. The gentle heat of a lamp is then applied to this bulb, that the ether may boil ; this it will do at 96 de- grees ; its vapour perfectly expels all the air from the interior of the instrument, through the capillary neck ; and when the vapour itself, fully and fairly issues forth, the opening of the neck is suddenly closed by melting it in the flame of a lamp. Thus the greater portion of the ether still remains in a vacuum, as far as the absence of air is concerned, and only subject to the pressure of its own vapour, as was the water in the " Cryophorus ;" the bulb is then enveloped in cambric, and the instrument is com- pleted. Now as regards the method of using it, or of causing it to act as a Hygrometer : should any ether enter the covered bulb, this must be grasped in the hand, and by holding it as directed for the " Cryophorus/' the heat of the hand will expand the vapour, and force the liquid ether into the other bulb ; at the same time a sensation of cold will be felt, because ether, although more volatile than water, still requires heat for its eva- poration; and this it takes from the hand, which, losing heat, feels cold. When all the ether has entered its proper bulb, the instrument is placed upon the standard, and then set at an open window, or still better, in the free atmo- sphere on some steady support, level with the eye, AUTUMN. 1 85 taking care, if possible, that a dark tree or wall, or a black hat, at some few feet distant, will throw it out into strong relief. An examination of the thermometer attached to the brass standard, and of that enclosed in the glass tube, with its pear-shaped bulb dipping into the ether, will prove that they both indicate the same temperature : tbis must be noted; and then from a small bottle, provided with a conical tube stopper, as shown in the next engraving, a few drops of ether are let fall upon the cambric envelope. Fig. 41. Ether being exceedingly volatile, infinitely more so than water, will immediately gain heat from the bulb, for its conversion into vapour, or its evaporation ; the bulb will be reduced in temperature, and the va- pour of ether that it contains will be condensed therein into liquid ether, as was the vapour of the water, first condensed into liquid water in the experiment with the " Cryophorus." As in that case, a call or demand is now imme- diately made upon the bulb containing the thermo- meter and the liquid ether, for a portion of vapour to 186 AUTUMN. supply the place of that which has heen condensed; and there "being no air in the instrument to oppose this demand, it is instantly supplied by gaining heat from the bulb in which the ether is contained. This vapour in its turn is instantly condensed ; but as the ether evaporates from the capillary attraction of the cambric, another, and another, and many calls, are so quickly made, that the bulb containing the ether, by yielding heat, becomes extremely cold, as its in- cluded thermometer will indicate, and at length be- comes so cold, that the watery vapour contained in the atmosphere coming into contact with it, is condensed, as a fine ring of dew upon its surface at the level of the remaining ether. This is instantly detected, by the strong relief into which the transparent bulb is thrown by the dark object, and the included thermometer shows the degree of temperature at which this phenomenon ensues ; it must be immediately noted, and it is technically called " The dew-point." Suppose the external thermometer indicate 60 de- grees, and the internal thermometer indicate 48 de- grees, the difference between the two is 12 degrees, and therefore the atmosphere does not contain a very large amount of watery vapour, since a reduction of temperature so considerable, is required for the depo- sition of dew ; but suppose the one thermometer indi- cate 66 degrees, and the other 64 degrees, the dif- ference between the two is only 2 degrees, and there- fore the atmosphere does contain a very considerable AUTUMN. 187 amount of watery vapour, since it is immediately prone to deposit dew by such a slight reduction of tempera- ture ; therefore, in the first example, the degree of its dryness may be denoted by 12, and in the second by 2 degrees. Or, the fact may be stated in the following terms, namely ; the more widely that the thermometers differ in their indications, the smaller is the quantity of the vapour in the atmosphere ; and the more closely that they agree, the greater is the quantity of the vapour contained in the atmosphere. For example ; in exceedingly dry weather, the cam- bric will require to be well saturated with ether more than once, before it can produce sufficient cold to sum- mon the small quantity of atmospheric vapour to chill and deposit as dew ; whilst on the other hand, in ex- ceedingly damp weather, the addition of a very few drops of ether to the cambric, will quickly summon the large quantity of vapour with which the atmosphere is almost saturated, and can hardly retain, to con- dense and deposit as dew upon the plain bulb. Experimental proof of these facts may be gained, by first employing the " hygrometer " in a hot dry room, when great difference will be observed between the thermometers at the moment of the " dew point ;" and next in a cold damp cellar, when little difference will be found between them at th^ moment of the " dew point ; " indeed, if the air of the cellar be already na- turally saturated with vapour, or the air of a small 188 AUTUMN. apartment be artificially saturated with vapour, by a large wet cloth or blanket hung within it, the two ther- mometers will almost coincide at the moment of the deposition of the ring of dew, or the " dew-point." In England, the degree of atmospheric dryness, or freedom from watery vapour, as measured by the ther- mometers of the " hygrometer," seldom amounts to 30 degrees; that is to say, the " dew-point" is seldom 30 degrees below the temperature of the air ; but in the Deccan Shabarpore, an island which is situated near the eastern mouth of the river Ganges, at a temperature of 90 degrees, the " dew point " has been seen as low as 29 degrees, thus marking the dryness or aridness of that unwholesome atmosphere at 61 degrees. In deeply scientific investigations, accurate experi- ments have been made with the "hygrometer," and elaborate tables have been constructed, to show the actual weight of aqueous vapour locally contained in the atmosphere, at the time that the " dew point" is ascertained ; but these tables or calculations, although highly interesting and important to professed meteoro- logists and chemists, would scarcely be intelligible to general readers and juvenile students, therefore no reference is made to them during this slight inquiry regarding the phenomena of the Four Seasons. What has been stated concerning the construction and method of employing the " hygrometer/' the man- ner in which it may be caused to act as " a weather- AUTUMN. 189 glass," in the popular acceptation of the term, to indicate the dryness and dampness of the atmosphere, and therefore the lesser or greater probability of rain, may be sufficiently intelligible. Watery vapour, although invariably present in the whole atmosphere, and its mean quantity expressed by the enormous sum at page 14, is liable to local varia- tions of its quantity, according to the local tempera- ture of any particular volume of the atmosphere ; for instance, it is shown at page 130, that warm air, either calm, or moving as a breeze, or as a high wind, is capable of evaporating and sustaining in its invisible volume more water than cold air, under similar condi- tions of repose and motion. It has been ascertained during most refined, accu- rate, and laborious experiments, conducted both by the meteorologist and the chemist, that a cubic foot of absolutely dry or anhydrous air, i. e. air consisting of Nitrogen, Oxygen, and Carbonic acid, when at the temperature of 33 degrees, or near the " freezing point " of water, does not absorb or sustain more than two grains and one-third of a grain of watery vapour ; whilst at the temperature of 60 degrees, by such in- crease of heat, it will sustain five grains and three quarters of a grain ; and at the temperature of 70 de- grees, by such further increase of heat, it will sustain eight grains. This experimental fact immediately accounts for the greater rapidity with which a pool, or other accu- 190 AUTUMN. mulation of stagnant water, is " dried away " even by the naturally hydrated atmosphere in warm weather than in cold weather ; and it also, in a great measure, accounts for the more copious deposition of dew from the atmosphere in the one season than in the other. In some cases, a parched volume of the atmosphere in motion, as " wind " travelling from one clime to another, over the wide expanse of sea or ocean, incites the rise, and accumulates the burthen of so large a pro- portion of pure watery vapour upon its (< wings," as to be at length unable to sustain the whole ; and then, during its flight or transit, a portion is slowly and gently re- linquished in the mysterious form of clouds. These eventually descend as rain upon the earth ; but in other cases, a parched volume or blast of wind, is ordained to sweep over arid sands or deserts, and in place of refreshing these with a copious supply of water, it actually deprives them of their very scanty store of this invaluable fluid for its own hydration, and thus often causes a most intense and almost in- supportable sensation of heat. These phenomena are most particularly evident in Eastern climates, and being familiar to the most ig- norant observers, they were chosen by The Saviour of mankind as a medium for conveying a just and powerful reproof to the captious malevolence of be- nighted minds, concerning the utter vanity of physical observation and knowledge, if not combined with full perception, and confession of the transcendent excellency of Faith. AUTUMN. 191 " When ye see a cloud rise out of the west, straight- way ye say, There cometh a shower ; and so it is." " And when ye see the south wind blow, ye say, there will be heat ; and it cometh to pass." " Ye hypocrites, ye can discern the face of the sky and of the earth ; but how is it that ye cannot discern this time ?" " Yea, and why even of yourselves judge ye not what is right ?" The physical explanation of the phenomena to which this powerful allusion is made, may be thus rendered ; the Mediterranean Sea is situated imme- diately to the west of Judea, and during the preva- lence of a westerly wind, yields sufficient vapour to form a cloud of rain, for the refreshment of the land ; whilst the hot countries of Egypt, Ethiopia, and Arabia, situated immediately to the south of Judea, during the prevalence of a southerly wind, so greatly deprive it of moisture as to parch the land on which it ultimately arrives. To minds duly prepared, the observation and study of the " magnificent history of Wisdom and Intel- ligence, which is written in legible characters both in the heavens and on the earth," is an inexhaustible source of happiness ; which can never prove incom- patible with the exalting influence of The Scriptures, since both, emanate from One Omnipotent Being, as faithful messengers, to direct the humble approach of man towards The Throne of His Mercy and of His Power. 192 AUTUMN. The Scriptures do not contain a single prohibition regarding the acquisition of wisdom and understanding concerning the phenomena of The Universe ; on the contrary, they first, set forth the rudiments of such philosophy in the circumstantial language of history ; and subsequently, enjoin its search in the sublimest strains of poetry, and extol the pleasures and advan- tages of its discovery in the attractive charms of pro- verb and of song. First, as regards the rudiments and goodness of philosophical knowledge; secondly, as enjoining its search ; and, thirdly, as extolling its discovery. The Scriptures thus testify : I. " In the beginning God created the heaven and the earth," et seq. " And God saw everything that He had made, and behold it was very good." II. " The works of the Lord are great, sought out of all them that have pleasure therein." Worthy, that is, of being inquired into, and studied by all that delight in obedience to His will, and such only, can appreciate His power. III. " Happy is the man that findeth wisdom, and the man that getteth understanding." The refined joy and happiness of the man that finds pure knowledge, is here to suit human comprehen- sion likened to the ordinary elation and gladness of the man that either directly finds a pure vein of pre- cious metal, or indirectly succeeds in getting or draw- ing it out in purity and value from an ore by his own AUTUMN. 1 93 application and labour ; the terms " finding " and getting," as in remote ages, are even now employed for denoting such discoveries. The inestimable worth of pure knowledge is then placed in direct and powerful contrast with the insig- nificant value of metallic riches. " For the merchandize of it is better than the mer- chandize of silver, and the gain thereof than fine gold." Truly inestimable are the varied phenomena presented in the wide realm of Nature throughout the revolving year ; and such as we cannot comprehend, still awaken our minds in the most glowing feelings of gratitude and admiration. Thus the physical cause of the blue colour of the sky cannot be satisfactorily explained through the medium of science; and yet at all seasons, we acknowledge its surpassing beauty, more especially perhaps in Autumn. The atmosphere immediately incumbent upon the earth, has probably the power of absorbing and retain- ing more of the blue rays of light than that at greater altitudes ; and thus, when we cast our eyes on high, we look through a volume of the densest air, replete with blue light; and so likewise, if we look abroad over an extensive tract of country, the horizon of which is formed by distant hills, they appear blue, or in other words, they partake of the colour of the medium through which they are viewed ; if we journey to them, their K 194 AUTUMN. blue colour gradually vanishes, and at length their or- dinary colours appear, and now, looking from the hill;* towards the spot from whence we journeyed, it in turn appears hlue. " The ridge called ' The Blue Mountains/ in Aus- tralia, another of the same name in America, and many others elsewhere, are not really hlue, for they possess all the diversity of scenery which their climates can give; but to the eye which first discovered them, bent on them generally from a distance, they all at first appeared blue, and they have retained the name." The air contained in a spacious hall or room is too small in volume to affect the eye with an impression of blue colour, and all objects appear of their natural tint ; the same as an alabaster figure will appear beau- tifully white when viewed through a thin glass shade, but will gradually appear green, upon being covered with three or four additional shades, although they are of equal thickness and transparency ; and if several more be employed, the vase will at length become invisible. The red appearance of the evening and morning sky, so popularly known as indicative of fair and foul weather, was chosen by the Saviour of Mankind, as the medium of a reproof, similar in its force and tendency to that which has already engaged our attention, in humbly endeavouring to present its philosophical inter- pretation. :e When it is evening ye say, it will be fair weather, for the sky is red." AUTUMN. 1 95 " And in the morning, it will be foul weather to-day, for the sky is red and lowering." The astronomer proves, that in consequence of the refractive or light-bending power of the atmosphere, the sun is visible for a considerable time after actual sunset, and also before actual sunrise ; the chemist ascertains the fact, that at actual sunset, the surface of the earth radiates heat, and the watery vapour present throughout a vast height of the atmosphere, imme- diately enters into a state of incipient condensation ; he therefore presumes the glow of light that so often blushes in the sky during a summer or autumnal sun- set, may depend upon the vesicular vapour reflecting the red rays more powerfully than the others, for he discovers, that if light be transmitted through steam mingled with air, and therefore on the verge of con- densation, that it assumes a deep orange or red colour. " The red colour of the sky at sunset, is indicative of fine weather ; for although watery vapour is present in the air, it is probably only on the verge of incipient condensation, and not sufficiently condensed to form rain-clouds ; and this slowly progressive transition of vast volumes of the air through the temperature of the dew-point, can only occur in serene weather at sunset, and not at sunrise." " The red and lowering appearance of the morning sky, which indicates foul weather, probably depends upon such an excess of vapour being present in the whole atmosphere, that clouds are actually forming in 196 AUTUMN. the higher regions, contrary to the direct tendency of the rising sun to dissipate them, they accordingly reflect the red rays of light abundantly, and are consi- dered as announcing a speedy precipitation of rain." " In the morning, in fine weather, the strata of the air near the surface of the earth alone, and in the lowest and most sheltered spots, are in a state of abso- lute dampness, the more elevated regions are compa- ratively free from humidity, and the morning light is grey ; the vapours which, during the reversion of the process, might probably reflect the red rays, are not elevated until the action of the sun upon the surface of the earth has continued long enough to impart a sen- sible warmth, by which time the moment of sunrise is past, and the sun has risen above the horizontal vapours." The close observance of natural phenomena by our ancestors, gave rise to many sayings and proverbs, of which several have been presented ; and we find another concerning the appearance of the skies that we have just considered. " An evening red, and morning gray, Will set the traveller on his way ; But an evening gray, and a morning red, Will pour down rain on the traveller's head." The " rainbow," that so frequently adorns and glads the clouded watery heavens, in full display of gorgeous- coloured zones of first-created light, as " the token of the covenant between God and man, that the waters AUTUMN. 197 shall no more become a flood to destroy all flesh/' must be esteemed as the most beautiful and magnificent atmospheric phenomenon that we behold throughout the Four Seasons of the revolving year. This phenomenon, however, does not admit of ex- planation through the medium of Chemistry, its inter- pretation belongs to the very highest departments of the science of Optics, and there probably we only know it in part : but even such part, if it could be here ad- mitted, would more than occupy the remaining limits that are assigned for the actual chemical phenomena of Autumn and Winter. But we are inevitably led for a few moments to quit the direct province of Chemistry, and trespass upon that of Optics, for unfolding the probable physical cause of the rainbow, in concise and intelligible terms. The rainbow invariably appears in that part of the heavens which during the day is directly opposite to the sun, and whilst rain is falling between" the dark clouds in the one quarter, and the solar beams in the other ; these, under most circumstances, impinging upon pellucid drops of water, will either directly pass through them in right lines, or if refracted from such course, they will, upon emerging from the drops, immediately resume it, and pass onward as colourless light. Under certain natural conditions, which merely to facilitate our inquiry may for the moment be called extraordinary, the solar rays impinging upon drops of water, will not only pass through them, or be simply 198 AUTUMN. refracted, as above, but upon emerging from the drops, a portion of the rays will continue to pass onward as colourless light after ordinary refraction ; whilst ano- ther portion deviates from such path, and is further refracted, or broken, into seven extraordinary-coloured rays, or prismatic rays, as mentioned at page 23 of the Introductory Chapter. This extraordinary or coloured refraction or analysis of solar light, is frequently presented by drops of morning dew, but in greater perfection by drops of rain, in falling through the atmosphere, between a dark cloud and the brilliant sun, the rays of which entering and emerging from successive drops, are re- fracted into Violet light, which departs farthest from the path that the unaltered rays would have pursued, and into Bed light, which keeps nearest the path that the unaltered rays would have pursued ; thus the external and the internal fringes of the rainbow are formed., and they Include within their zones the remaining co- loured rays in the order of their inherent refrangibility, the Indigo, Blue, and Green, being nearest the Violet, whilst the Yellow, and Orange, are nearest the Red ; thus presenting a perfect rainbow of the seven colours of analysed light. Or in more technical terms, the Violet, Indigo, Blue, and Green, rays, are the most refrangible, whilst the Yellow, Orange, and Bed, are the least refrangible rays of solar light ; the rainbow, therefore, is said to pre- sent a magnificent natural example of its analysis ; for the coloured rays cannot be divided into others. AUTUMN. 199 When a single and perfect rainbow appears, its inte- rior fringe is Red, and its exterior fringe is Violet ; but a " double rainbow" is most frequent ; a pheno- menon that is, of one bow within another ; and then not only are the colours of the inner and smaller, or Primary bow, more vivid than those of the outer and larger, or Secondary bow, but they are exactly in the reverse order, the interior fringe of the inner bow being Violet, and its exterior fringe being Bed. Fig. 42. The form of the " double rainbow" the artist has successfully represented in the above engraving, the dark shading of the bows denoting their respective fringes of violet light, as the employment of surfaces to reflect individual colours is impracticable in this department of art ; indeed, when we consider that the effect of an engraving depends upon the total reflec- tion of one portion of colourless light, by the surface 200 AUTUMN. of the paper, and the total absorption of another portion by the surface of the ink, it becomes extra- ordinary that simple engravings should convey to the eye any correct notion of the appearances of surround- ing objects. The following ancient and popular proverb concern- ing the " rainbow," affords one more example of a refined physical truth appearing in plain homely guise : " A rainbow in the morning, is the shepherd's warning, A rainbow at night, is the shepherd's delight." " This old proverb is generally correct, as a rainbow can only occur when the clouds containing or depositing the rain are opposite to the sun ; and in the evening the rainbow is in the East ; and in the morning in the West ; and as our heavy rains in this climate are usually brought by the westerly wind, a rainbow in the West indicates that the bad weather is on the road by the wind to us ; whereas the rainbow in the East proves that the rain in the clouds is passing from us." " As an indication of wet weather approaching, nothing is more certain than a halo round the moon, which is produced by the precipitated water, and the larger the circle, the nearer the clouds, and conse- quently the more ready to fall." All things demand equal attention from him who truly loves and desires knowledge ; thus the foregoing- explanation of the homely proverb emanated from the AUTUMN. 201 most enlightened philosopher that ever devoted his talents to the fascinating science of Chemistry. Educated in strict accordance with, the inflexible doctrines of " Inductive Philosophy," constantly in- ferring and collecting general results, general facts, and laws, from a number of particular instances care- fully established on actual Experimental evidence, this philosopher proved the utility of Chemistry when judi- ciously applied towards increasing the resources, and adding to the welfare of man ; demonstrated its im- portance as a medium for interpreting the wonders of natural phenomena ; concentrated all its varied rays, by the mirror of truth, into one effulgent star of light, for the moral and intellectual guidance of man, towards " The First Author of Beauty who hath cre- ated them all." God, for the fulfilment of His inscrutable purposes, has been pleased to take the spirit of this true philo- sopher to a better and more elevated sphere than the world that it was permitted for a few years to en- lighten and adorn ; the voice that once poured forth fervid eloquence regarding the wonders of the Crea- tion, is hushed, and the hand that demonstrated them, is closed in the silent, cold grave. But those words of fervour, and works of skill, are faithfully remembered, and zealously guarded by his disciples who are yet permitted to remain ; and as they follow at a vast distance the footsteps of their master, they endeavour, as he did, to keep the laborious yet certain path that is permanently illuminated by true 202 AUTUMN. experiment, and to shun the seductive uncertain mazes that are capriciously lighted by the false fires of theory and hypothesis. In cases of doubt and indecision, reliance may always be placed upon the light of experiment, because its rays emanate from the rock of truth; theory and hypothesis " impose upon the imagination like the ' mirage ' of the Egyptian sands, but like this illusion they must pass away ; they may present to the eye, a magnifi- cence as seducing as the ' fata morgana ' oftentimes witnessed on the coast of Calabria, in which the most beautiful landscapes, crowned with picturesque villages, superb palaces, and massy towers, seem to possess a real existence ; all is but an aerial phantom ; the en- chanted scene changes with the least shifting of the light or the ruffling of the sea ; melting away like a dream of the night ; so, ultimately vanish all systems of Philosophy and Science that are not founded on the solid basis of Induction." The fleeting form of clouds has been attentively studied by the meteorologist, and the refined instru- ments that are employed in such researches enable him to predict with considerable accuracy the probable state of the coming weather ; although he yet remains in ignorance concerning the manner in which vesicular vapour is formed, or in which rain is relinquished from the clouds. In the absence of accurate scientific knowledge, and refined meteorological apparatus, the husbandman in- variably consults the appearance of the evening and AUTUMN. 203 morning sky, the actions of animals, the forms of flowers, and is thus enahled to foretell if the weather will be fair, or foul. The sky guides him according to the proverbs ; and if, in the morning, cattle low more than usual, and stretch forth their necks, and snuff the air with ex- tended nostrils, he expects rain ; if the chickweed be quite open, and if the trefoil and bindweed stand out boldly, no rain will fall : many flowers besides these, close their petals against the approach of rain, but these are most common, and most easily observed. The presence of watery vapour in the air, or more technically the " hydration " of the atmosphere, is imperatively requisite for the welfare of the animal and vegetable creation ; animals cannot breathe, neither can plants grow, in dry or anhydrous air : their exqui- site functions are immediately deranged, suspended, and ultimately destroyed. The chemist has now to direct attention to the fact that absolutely pure water is a direct poison to aquatic beings, and for their respiration, the water they inhabit requires mixture with air, or aeration ; precisely the same as the air in which we are placed, for our respira- tion, requires mixture with the vapour of water, or " hydration." It has been already stated that pure water evaporates, and collects in the atmosphere as clouds ; these by a recondite power, not understood, yield it back to the earth as showers. For the sake of illustration let us imagine that rain falls into a hollow or basin, near 204 AUTUMN. the summit of a mountain, and accumulates as an Alpine lake ; we ascend the mountain, and reach the lake, and then experience something more than mere bodily fatigue ; our breathing becomes difficult, per- haps painful. If we examine the water of the lake we find it either very scantily supplied with fishes, or entirely free from them. What is the reason of the oppression in breath- ing that we feel, and the fact regarding the lake that we discover ? As follows : the air is not so abundant upon the mountain summit as it is in the valley ; it is more rare, more attenuated at this elevation, and there- fore our lungs do not receive the supply to which they have been commonly accustomed, either in the valley, or on the level earth : the water of the lake, thus ex- posed to an atmosphere so rare, cannot exert attraction for it, or become sufficiently aerated to support the respiration of fishes. Suppose even that aerated water were exposed at this great elevation, it would immediately part with its air, to supply the rarity of the surrounding atmosphere, as it would to supply a vacuum : the following experiment can be made in illustration of this fact. Place a large glass, filled with clear river -or spring water, beneath the receiver of the air pump, (page 117;) then exhaust the air from it as already directed ; and it will be found that myriads of small bubbles will rise from all depths of the water ; these were originally dissolved in it, and had no' tendency to escape under the ordinary pressure of the atmosphere, but as the air AUTUMN. 205 is exhausted from the receiver, they are freed from pressure, and therefore expand and rise, and ultimately escape to supply the vacuum. In place of allowing all the bubbles to escape, re- move the screw, and admit the external air ; its pres- sure will immediately force back those that remain into union again with the water, which will appear pellucid and clear as it did at first. A portion of aerated water popularly so called, either natural, as Pyrmont- water, or artificial, as soda- water, after exposure to the air for half an hour, if similarly experimented upon, will evolve more numerous bubbles, than river or spring water ; but such bubbles are not pure air, they are carbonic acid, formerly called " fixed air," in the one case, combined with water naturally by an unknown process, in the other artifi- cially, by the force of machinery ; but in both cases the sudden escape of the greater part of such carbonic acid when the corks of the bottles are drawn, causes the well-known effervescence ; all does not escape, for at the end of half an hour sufficient remains dissolved in the water to present an effervescence when in a vacuum, and thus illustrates the point that we are considering. If rain water be boiled, the air that it contained will be nearly expelled, and after allowing the water to cool down to atmospheric temperature in a tightly corked bottle, if we pour it from this, without guggling, into a finger-glass, and then introduce a small fish, it will show signs of distress by raising its head and gasping 206 AUTUMN. at the surface, and it would soon die if kept immersed ; if it be removed, and the water poured from the height of two or three feet, from one vessel to another, for a few minutes, upon then immersing the fish it will not show such signs of distress as at first. The water, on the one hand, contained no air for exciting the action of the respiratory organs of the fish, it therefore gasped to obtain a supply from the external atmosphere ; but, on the other hand, by pouring the water for a time from one vessel to another, it became aerated, and fitted to yield a supply to the fish when introduced. Fishes breathe in consequence of their respiratory organs being fitted to withdraw oxygen, not from the water itself, but from the air, that it is capable of dis- solving and of holding in solution under ordinary circumstances. The chemist applies these facts to the explanation of a natural phenomenon ; let us suppose that the unaerated, unproductive water of the lake overflows its bounds, and under the influence of gravitation dashes as a cataract over the mountain side ; each moment that it increases in velocity, it passes into denser and denser regions of the atmosphere, and in the hurry and turbulence of its fall, dissolves air, foams with bubbles, and then flows onwards and throughout the vallies and plains, as a stream or river, sufficiently aerated for supporting the respiration of aquatic beings, and accordingly we now find them in abundance. AUTUMN. 207 The description of this beautiful phenomenon may be aided by reference to the engraving, in which the horizontal shading being strong below, faint in the centre, and faintest at the top, may denote as at page 122, that the atmosphere is heavy upon the level sur- face of the earth, light at some height above, and lightest at the elevation of the mountain summit. Fig. 43. Upon this, the unaerated water of the lake is sup- posed to be ; and as it overflows and falls through the successive strata of the atmosphere, as indicated by the successive increase of the shading, it gains more and more air, until upon its arrival in the heaviest air, as indicated by the strongest shading, at the base of the mountain it becomes turbulent with foam. 208 AUTUMN. The grandeur of a mountain torrent, cataract, or waterfall, is chiefly referrible to the tremendous velocity of its fall in the denser regions of the air, and the powerful shock with which the water and air incorporate, producing an enormous foam, As such water traverses the surface of the earth in its return to the parent ocean, it widens its course and thus exposing a larger surface to the atmosphere, be- comes more powerfully aerated, and likewise by the rippling, the agitation, into which it is thrown by breezes and winds. If we fill a vessel with water, thus naturally and wonderfully aerated, and place a fish in it, and then secure the mouth of the vessel with an air-tight cover, the creature will die when its respiration has consumed the certain amount of oxygen that the air contained ; it will die though immersed in water that contains oxygen as an element, bat this is combined with hydrogen, be it remembered, and the respiratory organs of the fish have not the power of separating it from such chemical combination, as they have from its mechanical mixture with nitrogen, which constitutes the chief volume of atmospheric air. Fishes demand a constant supply of fresh aerated water, the same as animals demand a constant supply of fresh hydrated air, for both classes of beings are soon destroyed by the mephitic products of their own respiration. The lavish abundance of air and water presented throughout Nature, would alone probably ensure the AUTUMN. 209 fulfilment of these demands for oxygen, and ages might elapse hefore either of these extraordinary media would become vitiated, or unfitted for the maintenance of life ; but the Creator has made the same beneficent pro- vision for purifying water from the results of the respi- ration of aquatic beings, as He has made for purifying air from those of man and the higher order of animals. Everything is miraculously balanced and adjusted throughout the Creation, and displays the power and goodness of God ; and above all branches of science, that of chemistry is particularly favoured in being permitted to become the medium of interpreting so many wonders. During the bright weather of Summer and Autumn most plants that grow in ponds, pools, and streams, and particularly those slender green filaments known to the botanist as " conferva rivularis," are covered with myriads of small air globules ; this is a common " observation ;" the chemist devises means of col- lecting thousands of these globules in a glass, and finds that such aeriform volume will cause a lighted taper to burn with far greater brilliancy than it burns in the surrounding atmosphere : this is a simple " experiment ;" he next reasons upon this, and guided by " analogy" tries if all plants of a similar character, when exposed to light, will present the same pheno- menon ; he finds them to do so, and thus establishes a " scientific truth." These three essential requisites enabled us to recog- 210 AUTUMN. nize the plants of the earth, combining their agencies for purifying the atmosphere from the mephitic results of combustion, and the respiration of man, and the higher order of animals ; they will now enable us to recognize the plants of the water, combining their agencies for purifying it from the mephitic results of the respiration of fishes, and other aquatic beings. When under the direct influence of solar light, the slender green filaments of " confervse " have the power of decomposing the carbonic acid, produced by the respiration of fishes, and of eliciting oxygen nearly pure; thus globules of this element, ascending and collecting in the glass, will support the flame of a taper with greater brilliancy than the surrounding atmosphere containing nitrogen. Two or three handfuls of " conferva rivularis " col- lected carefully without injuring their fragile structure, may be introduced into a large globular glass " carafe," or " water-flagon," having a long and narrow neck the narrower the better ; then fill the " carafe " witli water from the pool, pond, or stream, in which the plant grew, place one hand over the mouth of the " carafe " to close it firmly, and with the other holding the globular part, invert it ; pass the first hand beneath the surface of three or four pints of water contained in a shallow pan or glass, then withdraw it from the neck of the " carafe ;" no water will escape from this, be- cause the weight of such water is inferior to that of the surrounding atmosphere ; thus the " carafe " will AUTUMN. 211 remain perfectly full, with its globular part containing the " conferva " uppermost. As on account of the weight being so much above the narrow support of the mouth, the " carafe" would be liable to fall from this upright position, carry the arrangement to an open window where the sun is shining with its greatest splendour, set the pan upon the window-sill, place a heavy brick against the side of the pan to prevent it from slipping, and then gently move the " carafe" from its upright position still keeping its mouth under water that its globular part may securely rest against the corner of the window- frame, as shown in the annexed engraving. Fig. 44. This simple arrangement is precisely similar in principle, though upon a larger scale, to the well-known " globe bird-fountain," that is placed in a " breeding- cage," or the " conical bird- fountain " that is placed AUTUMN. outside, with its horizontal neck passing through a hole to the inside of a small bird-cage, and the " carafe" will act similarly to both of these contri- vances. For example, the water in each " fountain " is pre- vented from running out by atmospheric pressure ; but as the birds gradually sip away the water from the " cistern" of the one, or the neck of the other, air will gradually bubble up into the globe or cone, and cause the fall of an equal portion of water : as this is gra- dually drank, air will again gradually ascend, water will again descend ; so that, at length, each fountain will be exhausted of water, or " dry," and will only contain air. The great utility of each contrivance is that only a very small surface of water is presented to the surrounding air, and therefore it cannot " dry away," or evaporate with the rapidity that it does from a wide shallow glass, or even from a common i( bird- glass ; " it remains as a refreshing store for the birds for many days without requiring replenishing. These " bird-fountains," simple as they may appear, and unworthy of attention as they may be thought, involve the principle upon which all the refined and accurate apparatus is constructed by the chemist for extending his researches regarding the nature of aeriform matters or gases, be they either invisible as Oxygen, or coloured as Chlorine. From facts, and contrivances the most simple, have emanated some of the most important and invaluable discoveries and inventions which adorn not only che- AUTUMN. SI 3 mislay, but every other experimental science ; but tbe pursuit of chemistry more particularly does not ne- cessarily involve the possession of costly and compli- cated apparatus ; SIMPLICITY, not mystery, is its aim, and by endeavouring to keep this steadily during our inquiry, we have been enabled, and shall yet be ena- bled to conduct many curious and instructive experi- ments with materials of common occurrence. The splendid show of costly and beautiful apparatus that appears on the well- arranged table of the public lecturer, is imperatively demanded,, because he has to demonstrate the facts of science to assembled hundreds ; experiments therefore require to be made upon a large scale, with the greatest promptitude, and as far as possible with success, that all the audience may see, and may be simultaneously convinced of the facts under discussion, for the lecture-room is not the arena for individual instruction. But in the quiet of the laboratory, much of the appa- ratus of the lecture-table may be dispensed with, and important facts discovered by simple means : thus the grand discovery of the element Oxygen, which, about seventy years since, completely changed the whole aspect of the science of chemistry, was made by em- ploying a globular glass, or flask, about the size of that of the " bird-fountain," and inverted like it into a small " cistern," but instead of containing water, both vessels contained mercury, and in that of the globular glass was placed a portion of a compound from which, when heated by the rays of the sun in August, drawn to a 214 AUTUMN. focus in a powerful burning lens, Oxygen was at length evolved, and collected, as the air may be collected, in the " bird-fountain." But in the arrangement with the " carafe," water, and " conferva," the artificial concentration of the heat of the sun is not required, its natural splendour alone is necessary ; and after it has beamed upon the " con- ferva" for an hour, the slender filaments of the plant will be studded with beautiful globules of Oxygen ; these gradually increase in size, and then either spon- taneously quit the attraction of the filaments, or will do so upon slight agitation of the " carafe," and as- cending to its upper part, there, after a few hours, by the addition of other globules which continue to rise, all will coalesce into one large bubble, a portion of water of corresponding volume having descended into the glass pan, this water being expelled by the oxygen evolved within, exactly as in the " bird-fountain " it is expelled by air ascending from without. Allow the arrangement to remain exposed to the sun throughout the whole summer or autumnal day, to obtain as much oxygen as possible ; kindle a very small wax taper attached to the end of a wire, as at page 57 ; then pass one hand beneath the water to close the mouth of the " carafe," and with the other lift it ; and place it to stand upon the table, as the flask at page 58, and as in that the air ascended, so in this, the oxy- gen evolved by the " conferva" will ascend and occupy the neck of the ;< carafe ;" slide away the hand from its mouth, quickly introduce the lighted taper, and its AUTUMN. 21 5 flame will burn with far greater brilliancy than it did previously in the surrounding atmosphere. Why ? Because the carbon which first was an element of the living bodies of fishes, was converted into carbonic acid by their respiration, and so exhaled as a poison to them, but under the influence of light, the growing plants were enabled to convert it into nutriment for themselves by secreting the Carbon, and thus eliciting pure Oxygen ; and there being no diluent Nitrogen present as in the atmosphere, there is no barrier or impediment to the intensely rapid combination of such Oxygen with the Carbon and Hydrogen of the taper, consequently its flame is greatly enhanced in brilliancy and swiftness of combustion. The researches of the chemist warrant the conclu- sion that fresh-water plants, and likewise marine plants, derive the chief, if not the whole portion of their con- stituent carbon from carbonic acid, either absorbed directly by the waters from the atmosphere, or produced by the respiration of fishes; and thus both the vege- tation of the earth and of the waters, may be equally active in keeping the just balance of the atmosphere for the life of man and animals, as for preserving their own proper degree of aeration for the support of aquatic beings. The vesicles of the sea- weed called " fucus vesicu- losus," or more commonly " bladder-wrack," when recent, contain air more highly oxygenated than the atmosphere, and after having filled the " carafe " with 210 AUTUMN. water, and inverted it as directed, if several of these vesi- cles be punctured with a pin when immersed just below the mouth of the " carafe," and then gently pressed, air may be collected from them, which will support the flame of a taper with greater brilliancy than the external atmosphere. Such, then, are the simple experimental illustrations of the miraculous provision that is made in Nature for decomposing the mephitic results of the respiration of fishes, by the vital functions of plants ; and it reveals to us another instance of the mutual dependencies of the two organic kingdoms. Fishes produce and exhale carbonic acid, growing plants stimulated by solar light, decompose such compound, and increase their own structures by absorbing and combining with its car- bon, emitting the oxygen, ready to dissolve again in the water, or to ascend to its surface, and there min- gle in due proportion with nitrogen. This mixture the water again absorbs, again its oxygen supports respiration, again carbonic acid is produced by the fishes, again this is decomposed by the plants, and from being mephitic it becomes a pabulum of life : thus incessantly does this wonderful action continue, and furnish a proof of the wisdom and power of the Almighty in providing for the welfare of His creatures. It is necessary in the foregoing experiment to have the glass " carafe " as large as possible ; indeed one of the globular " show-bottles of a druggist's shop- AUTUMN. 217 window is preferable, if it can be obtained ; plenty of " conferva " also is required ; and if this cannot be easily procured, several bunches of fresh water- cresses," or of " chick-weed," may be substituted ; and thus probably sufficient oxygen will be at length collected for proving its power of enhancing the bril- liancy of the flame of the taper ; but should there not be sufficient for this purpose, the fact of the glo- bules of the element appearing on the leaves of the several plants, will always be manifest in the bright sunshine. We now discover the reason that fishes placed in marble basins or glass globes, filled with river water, so frequently become languid and sickly ; they were taken from a pond or stream of water fully and power- fully aerated, and fitted for their respiration by the vital action of growing plants ; they are suddenly trans- ferred into a confined portion of the same water, and in proportion as they consume the oxygen of its aeration, they load it with carbonic acid, and no growing plants being present to decompose this, they must inevitably suffer in health, and will ultimately die if the water be not repeatedly changed. It therefore becomes necessary for the life of fishes, in marble basins and glass globes, either to change the water repeatedly, or what is much better, as se- lected from the perfect example of Nature, to intro- duce some aquatic plants, not only to decompose the results of the respiration of the fishes, but to afford them L 218 AUTUMN. shelter from the solar rays ; for these beautiful crea- tures demand such protection as imperatively as we ourselves ; strange as it may appear, it is nevertheless a fact, that light- coloured or silvery- white fishes espe- cially, although in clear water, are sometimes scorched by solar heat. A " silver fish " had long been the brilliant and spotless inhabitant of the clear water of a pond sur- rounded by lofty trees, casting shadows in which it could occasionally derive shelter from the direct rays of the sun; when these trees were ultimately cut down, and the waters thus exposed to the full unmitigated glow of light, the fish shortly appeared with a brown spot upon its back, like a scorch ; this increased in colour and size, and according to the examination of a na- turalist and physiologist, it was certainly a f