rirf AT! .LIBRARY i>r rur. s UNIVERSITY OF CALIFORNIA Accessions No. \3tf & J Shelf No. $ ENERGY IN NATURE ENERGY IN NATURE, 15E1XG, WITH SOME ADDITIONS, THE SUBSTANCE OF A COURSE OF SIX LECTURES UPON THE FORCES OF NATURE AND THEIR MUTUAL RELATIONS, Delivered tinder the auspices of the Gilchrist Educational Trust, in the Autumn of 1881, WM. LAKT CAKPENTEK, B.A., B.Sc., KKI.LOW OF THE CHEMICAL AND PHYSICAL SOCIETIES, AM) OF THE SOCIETY OF CHEMICAL INDUSTBY. CASSELL & COMPANY, LIMITED: LONDON, PARIS $ NEW YORK. [ALL RIGHTS BESF.BVED.] 1883. to* m|i WILLIAM B. CARPENTER, C.B., M.D., LL.D , F.R.S., F.G.S., F.L.S., &c. &c., WHO HAS DEVOTED MUCH OF THE ENERGY OF A LIFETIME TO THE SCIENTIFIC EDUCATION OF THE PEOPLE, 31 DcMtate ti)is f ittlc gook. PREFACE. THE object of the following pages is to give to those who have had little or no opportunity of studying the subject, some idea of the mutual relations existing between the various so-called " Forces of Nature," expressed in the simplest language, but at the same time, it is hoped, with sufficient scientific accuracy. Whenever it is im- possible to avoid the use of technical terms r they will be carefully defined and explained, and the illustrations used will, as far as possible, be matters of common experience. An attempt is made in the earlier pages to lay down clearly the distinction between Force and Eneryy, and to explain how the language of the older books on the so-called Forces of Nature, the Correla- tion of Forces, &c., has been of late modified viii PREFACE. by the development of the doctrine of Energy and its Conservation. The book may be shortly described as an endeavour to expound in popu- lar, yet accurate language, the meaning and consequences of that important principle known as the Conservation of Energy. Considerable pains, however, have been taken, especially in dealing with Electricity, to illustrate and ex- plain the very latest developments of the subjects treated in the text, since the trans- formation of Mechanical into Electrical Energy by the dynamo-machine is a remarkably good example of the general principle. The sub- stance of what is here written was delivered extenrpore by the writer to large audiences of artisans and others, under the auspices of the Gilchrist Educational Trust, in five Lancashire towns during the autumn of 1881, the lectures were abundantly illustrated by ex- periments, and by the projection of photographs upon the screen. It is believed that this was the first occasion on which the attempt was made to bring home to those who were not, in the PREFACE. ix ordinary sense of the term, either educated persons or students of science, the important practical consequences arising out of, as well as some of the glorious thoughts suggested by the consideration of, that grand doctrine of the Conservation of Energy, probably the most sublime generalisation of modern times, since its effects are not confined to our own planet, but pervade the Universe. So much interest was excited on the subject among the audiences to whom the lectures were addressed, and so many enquiries have been made for a book in which the subject is treated in a popular manner, as to create a belief that the publication of the substance of the lectures in book-form will meet a real want; although no one, probably, is more conscious than the writer, of the different impressions produced by essays on a subject, and by the same matter treated orally, with experimental demonstrations and other illustrative aids to the comprehension of what may be to many readers comparatively unfamiliar scientific truths. x PREFACE. I wish to express my obligation to Pro- fessor Balfour Stewart, and to one or two other friends, for valuable suggestions made to me while the book was passing through the press ; and to Messrs. Macmillan, Mr. Stanford, Messrs. Longman, and the publishers of Engineering, for permission to reproduce certain illustra- tions. 3d, Craven Park, Harlesden, London, N.IV. September 1st, 1883. C N T E N T[8 CHAPTER I. PAGE MATTKR AND MOTION FORCE AND ENERGY 1 31 CHAPTER II. HEAT, A FOKM OF ENERGY 32 60 CHAPTER III. CHEMICAL ATTRACTION, ESPECIALLY COMBUSTION ... ... 61 86 CHAPTER IV. ELECTRICITY AND CHEMICAL* ACTION 87126 CHAPTER V. MAGNETISM AND ELECTRICITY ,. 127 172 xii CONTENTS. CHAPTER VI. ENERGY IN ORGANIC NATURE .. 173206 NOTE. The following- outline of the Course of Six Lectures, as arranged with the tlilchrist Trustees, will convey a fair idea of the contents of the six chapters, whose headings are given above. The delivery of the Course was prefaced with an Introductory Lecture by Dr. W. B. CARPENTER (the Secretary of the Trust), on "The Philosophy of a Lucifer Match," illustrating the connection between Mechanical Force, Heat, Light, Chemical Action, Electricity, and Vital Energy, all of them concerned in the simple act of "striking- a light." LECTURE I. MATTER AND MOTION FORCE AND ENERGY. Different states of Matter (solid, liquid, and gaseous), all having weight, and offering Resistance Indestructibility of Matter Changes in its state. Different kinds of Motion Visible Motion of Masses Invisible Motion of Particles, or Molecular Motion. Different Modes of Force Attraction of Gravitation giving Motion to Masses Attraction of Cohesion holding together the particles of Masses. Energy, or the Power of doing work Energy of Motion, and Energy of Position, or Potential Energy Relation of Energy to Mass and Motion Its Disappearance really a change in its mode of mani- festation. CONTENTS. xiii LECTURE II. HEAT, A FORM OF ENKKf;Y. Source of Heat in check to visible Motion, as in Friction and Percussion Mechanical Equivalent of Heat Communication of Heat by Con- duction, Convection, and Radiation Action of Heat in the Change of state of Matter Relation of Heat to Light and to Chemical Action. LECTURE TIL CHEMICAL ATTRACTION, ESPECIALLY COMBUSTION. Chemical Action generally Elementary and Compound bodies Changes of Composition due to Chemical Attraction Ordinary Combustion the union of combustible substances with Oxygen, producing Light and Heat, thereby generating Mechanical Force Influence of Heat in exciting Combustion or other kinds of Chemical action Influence of Light in producing Chemical Change Photography. LECTURE IV. ELECTRICITY AND CHEMICAL ACTION. Production of Electricity : (1) by Friction of dissimilar Substances ; (2) by Heat affecting two metals unequally ; (3) by Chemical Action, as in the galvanic battery Difference between Electricity at rest, xiv CONTENTS. and Electricity in motion Transmission of Electricity by Conduction Electric Currents Heat and Light produced by opposing resist- ance to their passage Mechanical effects of their interruption Induced Currents Ruhmkorff's Coil Production of Chemical Action by Electricity Law of Equivalence Electrotyping and Electro-plating Electrical Storage of Energy in Secondary Bat- teries. LECTURE V. MAGNETISM AND ELECTRICITY. Magnetism originally derived from Lodestone ; now induced in iron and steel bars by Electric Currents Electro-Magnets Mariner's Compass ; its direction due to the Magnetism of the Earth Deflection of Magnetic Needle by Electric Current Induction of Electric Currents by giving Motion to Magnets Magneto - Electricity. Application of these facts in the Electric Telegraph, the Telephone, Microphone, and Photophone, and in the Dynamo-machine for Electric Lighting, and for the Transmission of Power. LECTURE VI. ENERGY IN ORGANIC NATURE. Growth of Plants, and formation of their material, dependent on the Light and Heat of the Sun Reproduction of this Light and Heat CONTENTS. xv in the combustion of Wood, Kf.-sin, &c. Storage of Solar Energy in Coal. Growth of Animals also dependent upon Heat ; but their material derived from plants Animal Energy dependent on Combustion of Food Material Power directed, but not generated, by Human Will Balance of Organic Nature. These mutual relations of the Powers of Nature, and the Uniformities expressed in its Laws, prove a Common Source, and suggest a Designing Mind as their Originator. [UNIVERSITY; ENERGY IN NATURE. CHAPTER I. MATTER AND MOTION; FORCE AND ENERGY. BEFORE studying any of the so-called Forces of Nature, some of which are known under the names of Gravity, Chemical Attraction or Affinity, Electricity, Magnetism, Heat, and so on, it is desirable to say clearly and emphatically that these so-called Forces are not " things" in them- selves, in the sense in which sand, wood, &c., are " things " in themselves, and that they are only known, and can only be investigated, by their effects upon substances, or, to use a more pre- cise phrase, upon what the scientific man calls Matter. We cannot lay hold of some thing and handle it, or deal with it in any way, and say, " this is electricity," or "that is heat," in the sense in which we can say, " this is iron," or " that is clay." The so-called forces of nature have been well and truly spoken of as the moods, or affections, of matter. The relations of an indi- vidual to the objects which surround him, vary B 2 BNEUGY IN NATURE. with the mood in which ho is ; in a similar way, the relations of any object in nature to other objects in its immediate neighbourhood vary with the mood of these objects, or with the way in which they affect each other. Thus, for example, a leaden rifle-bullet weighing exactly one ounce may be held in the hand and will produce the sensation of weight and of metallic coldness, but in other respects it appears to be in a very impassive mood ; if it be melted in an iron spoon its weight will be unchanged, but it can no longer be handled with impunity, and is in a very heated mood ; and again, if it be fired off from a rifle it will still be the same leaden bullet, but in a very destructive mood. Lastly, if it be brought under the influence of a current of electricity it will be found to behave to- wards iron and steel very much as a magnet does, and it may be said to be in an attractive mood. Hitherto we have spoken of Force, and of the forces of nature; and so long as heat, chemical attraction, electricity, magnetism, &c. &c., were regarded as so many distinct and separate forces (called in the older books on natural philosophy the " imponderables," i.e., the un-weigh-ables), this phraseology served its purpose very well. As, however, the idea gradually became developed that these so-called various forces were all diffe- rent manifestations of a power of doing work (i.e., causing change), residing in or acting through FORCE AND ENERGY. 3 matter, the need was felt for some general phrase which should include them all ; accordingly the word Energy was adopted, as expressing more accurately this fundamental idea. Energy, then, is the power of doing work, in the strict scientific sense of the term. The phrase is an expressive one, and the consideration of what is implied in the phrase " an energetic man" will assist the reader in grasping the idea implied in it. We do not exactly know what energy is, but we recognise it, just as we recognise life (about the nature of which we are equally ignorant) in various forms, and, as will presently be seen, we can measure it very exactly. On this view then all the so-called forces of nature, or the various moods that affect matter, are so many kinds of energy, which is capable of assuming various forms, and of being changed from one form to another by apparatus arranged for the purpose by man, but is never created afresh or destroyed en- tirely, by any contrivance of his. This is the idea intended to be conveyed by the modern phrase, " The Conservation of Energy " (in place of that of the " Correlation of Forces"), which is the subject of the following pages, an idea which the diagram, Fig. 2 (p. 13) is designed also to convey to the eye. Let us consider for a moment what is implied exactly by the term Force. A little thought givei? to the subject will show that whenever it is de- B 2 4 ENERGY TN NATURE. sired to set anything in motion, or to bring to rest anything already in motion, the use of force is necessary. The exertion required to bowl, and to catch, a ball at cricket, and the action of the locomotive and the brake in the railway train, are familiar examples of this. Hence, Force may be defined as any cause which alters or tends to alter a body^s natural state of rest, or of uniform motion in a straight line, and it should be borne in mind that the states of rest and of motion here referred to are not merely molar, but also molecular, i.e., not merely motion of the body as a whole, but of the motion among themselves of the very minute particles or molecules (vide pp. 17-20) of which the body is made up. There is very good reason to believe that all the various energies of nature, light, heat, electricity, magnetism, &c., are derived from different kinds of molecular motion. Prof. Tyiidall wrote a book several years ago entitled u Heat considered as a Mode of Motion." Prof. Hughes has quite lately (Feb- ruary, 1883) exhibited to the Royal Society some very curious experiments, which seem to confirm the idea long entertained by Sir W. Thomson and others that magnetism is another form of molecular motion. A wire along which an electric current is made to pass undergoes no change in weight thereby, nor, if it is large enough (Chap. IV.) in any outward appearance, but under certain conditions (in a dynamo- FORCE AND ENERGY. 5 machine, for example, Chap. V.), it can produce not only molecular motion, but even that kind of motion familiar to us as mechanical. It is evident, therefore, that Force also can only be known by its effect upon Matter, and that it is not a " thing' 7 (in the ordinary sense of that word) any more than the bank-rate of interest is a sum of money, or a birth-rate of children is the actual group of children who are born in a year. Force is simply the expression of the rate or speed at which any change takes place in matter ; what its essence, or primordial cause is, is a problem that science does not attempt to solve. The terms Energy and Force do not, therefore, mean exactly the same thing, and, indeed, it is most important to grasp, and to bear in mind, the distinction between them. Energy involves two distinct ideas combined, whereas Force in- volves only one. Energy has been defined as "the power of doing work," and work is force exerted through space, i.e., the idea of motion of some kind is connected with it.* The dis- tinction again between energy and what the * When a weight rests on the ground, the weight pushes the ground down with a certain force, and the ground pushes the weight up with the same force. It is obvious, however, that a weight in this condition is incapable of doing any work, i.e., of producing motion of any kind ; indeed, the very expression " dead- weight " applied to it is a practical admission of its inefficiency in this re- spect. The pressure that this inert weight produces is force and not energy, but the operation of raising tho weight is doing work, 6 ENERGY IN NATURE. artizan and engineer recognise as " power " is essentially difficult, and lies probably in the idea of direction any form of directed energy is power. In some lectures on the Transmission of Energy, recently delivered before the Society of Arts, Prof. Osborne Reynolds compared the difference between undirected and directed energy, to the difference between a mob and a trained army, the individuals in whom the energy re- sided being, in both cases, the molecules (p. 20) or ultimate particles, of matter. Reference has been frequently made to the term " Matter." What is this Matter, in the different moods or affections of which we re- cognise what is now known as Energy? It may be stated in general terms to be " what- ever can affect one or more of our senses;" but there are certain kinds or conditions of it for which we need to increase the sensitiveness of what have been called our u five gateways of knowledge" by suitable apparatus, in order to become aware of this affection of our senses. Thus, for example, the sense of sight may be assisted by magnifying glasses, and those of touch and hearing by certain electrical contri- vances, such as the telephone and the micro- and involves the expenditure of energy. In every case in which force is said to act, what is really observed is a transference (or a tendency to transference) of energy from one portion of matter to anothr:- and the so-called force in any direction is simply the rate of that transference. MATTElt. 7 plionc (Chap. V.), with which it is possible to hear the footsteps of a fly crawling upon a piece of wood, and to converse in spoken language with a friend a thousand miles off.* A little attentive consideration will show that we usually meet with matter in one of three states, known as solid, liquid, and gaseous, f It will presently be shown that, in the majority of instances, the occurrence of any substance in one form or the other depends upon the tem- perature and the pressure to which the matter is subjected. A very familiar example of the three states of matter is to be found in ice, water, and steam, each of which forms of water can be changed into either of the others by regulating the amount of heat to which it is ex- posed, while it still remains through all these changes the same compound of two measures of hydrogen with one measure of oxygen (vide page 68), which the chemist recognises as water bv its behaviour towards other kinds of * matter. It will be desirable now briefly to consider one or two properties which are possessed, with- out any exception, by matter in all its states. A stone left to itself in the air falls until it touches the ground; a round stone or ball rolls * Vide Nature for March 22nd, 1883. f For the purposes of the present enquiry the question of the existence of a fourth state of matter need not be discussed. ENEliQY IN NATVUE. down a sloping surface ; a mass of water, such as a stream or river, flows from a higher to a lower level in the channel in which it is con- fined ; clouds appear to rise in the air, and descend again as rain ; all these occurrences are due to the fact that all matter pos- sesses weight. That this is the case with solids and liquids is a matter of such com- mon experience as to need no more than a reference to it ; but it is not so apparent, although equally and universally true, in the case of gases. It may, however, be readily proved by very simple apparatus (a balloon for example), and may be shown more exactly by weighing differ- ent kinds of gas in a glass-bottle provided with a stopcock, attached to one end of a delicate balance or pair of scales, as in Fig. 1 . If all the air be removed from the bottle by an air- pump, and the bottle be then carefully weighed, it will be found that when the stopcock is opened, and air is admitted into the bottle, weights must be put in the other scale-pan to restore the balance. FIG. 1. FORCE AND ENERGY. 9 In this way it can be shown that five gallons of common air weigh very nearly an ounce, or, in the so-called metrical system in use on the con- tinent, not only by scientific men but also in all the dealings of daily life, that one litre of air weighs 1*29 gramme. Instead of common air other gases may be allowed to enter the bottle, being conveyed there by a pipe, and it can thus be shown that they differ greatly in weight. Thus : 100 cubic inches of air weigh . . .31 grains. 100 ,, of carbonic acid weigh . 47 ,, 100 ,, ,, of hydrogen weigh only . 2 Now here we have an illustration of the fact which is of considerable importance in connection with this property of weight, that substances differ largely in the mass or quantity of matter contained in the same measure thereof. Thus, for example, a gallon of water weighs exactly 10 Ibs. (and in the metrical system a cubic centimetre of water weighs exactly one gramme), while a gallon of oil, or of spirit, weighs only 9 Ibs., or less. If the weight of one-tenth of a gallon of water (or 27*27 cubic inches) which is 1 lb., be taken as a standard, and compared with the weight of the same mea- sure of other substances, we shall find that the weights of equal measures, expressed in Ibs., give us figures like the following : 10 ENERGY IN NATURE. Hammered Copper . 8*9 Gold . . . . 19-6 Cast Iron . . . 7'0 Wrought Iron . .7*7 Lead .... 114 Silver . . . . 10'5 Platinum . . . 21 '5 Tin .... 74 Zinc . . . .7-0 Mercury . . .13-6 Brick . Clay . Chalk . Dry Sand Glass . Spruce Fir Oak . Proof Spirit Ether . Oil 2-1 1-9 2-3 1-4 2-7 0-6 0-8 0-9 0-7 0-9 The annexed drawings of spheres (Fig. 2), and figures, also present the same relationship between other substances : Hydrogen Air . Water . Platinum FIG. 2. 1 14-4 11,943 256,764 1 829 17,831 1 21-5 Thus, for equal bulks, the metal platinum is 21 J times as heavy as water, 17,831 times as heavy as air, 256,764 times as heavy as hydrogen, and so on. This relation between the measure (or volume) and the weight of any substance is known as its specific gravity, and is recognised in common life by such phrases as u Oil is lighter than water," " Lead is heavier than iron," &c., the words MATT Eli. 11 " heavier" and "lighter" really implying the addition to them of the phrase " bulk for bulk." Another characteristic of all kinds of matter is that it offers resistance. This, again, so far as our sense of touch is concerned, conies within our common experience, even in the case of gases, for who has not experienced the resis- tance offered to his progress by air in violent motion ? Another mode of expressing the same thing is to say that matter possesses impenetra- bility, which means that no two portions of matter can occupy the same place at the same time. An amusing story illustrating this is told of King Charles II., in whose reign the Royal Society was founded. The king propounded to the philosophers composing it the following query: "Why is it that when two gold-fish are put into a bowl of water full up to the brim, the water does not overflow?" The ques- tion was gravely debated at considerable length, until some one suggested that the question should be put to Nature, or in other words, that the ex- periment should be tried. The result, of course^ showed that the " Merry Monarch " had been amusing himself at their expense. It may be pointed out here that by no process at the command of man can matter be either created or destroyed. It is a most important truth that the utmost man can do in this direction is to change the combinations of matter. For 12 ENEliGY IN NATURE. example, when coal is burnt in the fire it is not destroyed, but in the act of burning (Chap. III.) its carbon and hydrogen unite with the oxygen of the air, forming gases which pass away into the atmosphere. The main object of this little book is to show that the same thing is true of the so-called Forces of Nature, that is to say, of the forms of Energy, which can neither be created nor destroyed by man, whose power over them is limited to changing their form, or mode of manifestation. This doctrine may be looked upon as the outcome of the scientific work done during the last thirty years by such men as Meyer, Helm- holtz, Clausius, and others, in Germany, and as Grove, Joule, Thomson, Balfour Stewart, Tait, Tyndall, and W. B. Carpenter in England. Pro- perly regarded in its various aspects, it is one of the most sublime generalisations of modern times ; the most stupendous phenomena of the universe are seen to happen in accordance with it, while the life and movements of the minutest living being, and the most insignificant natural phe- nomenon occurring in human experience, alike bear witness to its truth. That when Energy seems to be destroyed, or to disappear, it does not really do so, but, like the magician in the " Arabian Nights," only vanishes to reappear under some other form (or mode of manifestation) it will be the object of the follow- ing pages to prove. A careful inspection of the FORCE AND ENERGY^ 1:' accompanying engraving (Fig. 3) im^ $\ reader in grasping this grand idea, to which name " Correlation of the Physical Forces " was first given, but the progress of research has shown (Chap. VI.) that it may be extended also to the so-called Vital Forces, i.e., to the Energy dis- played in the phenomena of Vitality. The circles are intended to represent movable discs, upon which are written the names of some of the forms 14 ENERGY IN NATURE. of energy existing in Nature. It is obvious that any two of these discs may be made to inter- change places, and thus to express graphically the change or transformation of one form of energy into another. A grand thought, which follows from the recognition of the indestructibility of energy, is that the total quantity of it in the universe is unchangeable, and can neither be increased nor diminished ; this is strictly what is meant by the phrase " Conservation of Energy," and it is expressed in the diagram by the ring which surrounds all the smaller discs. One other property of matter remains to be considered that called Inertia, in virtue of which matter can neither start into motion of itself, nor, when it is once in motion, can it stop of itself. It may be objected that although the first part of that sentence is obviously true, daily experience tends to contradict the second. A ball rolled along the ground, for example, speedily comes to rest. True, but if that same ball be rolled along a level surface of ice it will travel very much farther, and the more the resistance of friction is removed from any body in motion, the longer will that motion continue. If a strong mental effort be made to put aside the impressions caused by the familiar facts of the case, it will then be evident to the accurate thinker that a state of motion is just as natural to a body as a state of rest, provided MATTER AND MOTION. 15 that no external cause acts upon it, or, in otlier words, that there is nothing in the inherent nature of a moving body to cause it to cease moving. Here it is desirable that we should pause and reflect upon what is implied by the term Motion, and on the meaning of the phrases used to describe it. Motion means change of place, and it is obvious that in order to have a clear idea of the movement of any body, we must know the direction or line in which it is moving, and also the rate or velocity at which it moves. This velocity is often mea- sured in ordinary life in miles per hour ; thus an express train is said to go at the rate of forty miles an hour, meaning that if it continued moving for a whole hour at an unchanged speed it would rush over forty miles of railroad in that time ; but that if it only travelled at that rate for a fraction of an hour it would move over a proportionate distance two miles in three minutes, for example. It is more usual, in scien- tific language, to speak of velocity as measured in feet per second ; for instance, sound travels through the air at the rate of about 1,100 feet per second. The Laws of Motion were very carefully studied by that great philosopher, Sir Isaac Newton, who reduced them to three. The first one states that " a body at rest will continue at rest, and a body in motion will continue in motion, unless acted on by some external force;" 16 ENERGY IN NATURE. and it has already been discussed in connection with Inertia. The second one states that "when two or more forces act upon a body each pro- duces its full effect, whether the body be at rest or in motion." Simple illustrations of this are seen in the fact that if a stone be dropped from the window of a moving train it falls on, and not behind, the carriage step, or, when let fall from the top of the mast of a ship in motion, it falls at the foot of the mast ; in the feats of circus performers, who, in jumping through hoops, &c., simply jump upwards into the air, and are carried forwards by the motion derived from the horse ; and in a boat which, propelled straight forward by oars, while carried sideways by the tide, moves in a line which is really the result of the action of both these forces. The third law states that "Action and Reaction are equal and opposite ; " but for present purposes it need not be here discussed. It may now be noted, however, with advan- tage, that although a body may be apparently at rest, it may have a very decided tendency to move, actual movement being prevented by some counteracting tendency, a very slight diminution in which may cause a vast movement to take place. The case of heavy weights carefully balanced, and then moved with a very slight addition to them, illustrates this. Before leaving the subject of Motion, it should MATTUli .l\l> MOTION. 17 not be forgotten tl at a body may be affected by motion in two ways ; the first of these, viz., the change of place of the whole mass of the body, has been already considered; the other way is by the movement among themselves of the small particles of which the body is made up. This kind of movement is known as Molecular Motion. There arc the strongest possible grounds for believing that all matter, whether solid, liquid, or gaseous, is made up of exceedingly small particles, in visi- ble even with the aid of the highest powers of the microscope, Which are in a more or less continual state FIG. 4. of movement among each other. When a blow, or impulse of any kind, is sent through a solid or liquid substance, it is passed on, as it were, from particle to particle, somewhat in the manner re- presented on a comparatively gigantic scale in the annexed figures (Fig. 4). A good instance of this molecular motion, or movement of the particles of an apparently 18 ENERGY IN NATURE. solid body amongst themselves, is afforded by that curious alteration in the internal structure of the iron in girders of bridges, &c., in con- sequence of which the iron becomes more brittle, and the bridge therefore unsafe, after the lapse of some years. Illustrations of molecular motion in liquids are afforded by the beautiful forms assumed when they solidify as for example, the crystalline appearance of melted metals that are allowed to cool slowly (as seen in ornamental tin ware, &c.), or of different salts crystallising from their solution in water; a very familiar and a very beautiful instance is seen in the exquisite crystals of snow, a few of the varieties of which are seen in Fig. 5, and the same general plan of structure exists also in ice, and is re- FORCE AND ENERGY. vealed therein by passing a. beam of light through it, and throwing the image on a screen by a lens, as shown in Fig. 6. A very pretty ex- periment illustrating the molecular movement in gases is as follows : A round porous pot (such as is used in voltaic batteries) is closed at the open end with a perforated cork, through which a glass tube about two feet long is inserted, and the lower end of this tube dips into co- loured fluid (Fig. 7). A bell-jar full of hydro- gen gas (p. 70) is in- verted over the porous pot, when bubbles of air will at once issue from the mouth of the tube ; the reason of this is that the molecules of hydro- gen pass into the pot, through its pores, faster than the molecules of air can pass out. If the bell- jar be now re- moved, the hydrogen will pass out faster than c 2 20 ENERGY IN NATURE. the air can pass in again, a partial vacuum will be formed, and the fluid will rise in the tube. Although no one has ever yet seen a single molecule, it is a remarkable fact that four distinct lines of mathematical reasoning, based upon as many different sets of experiments, have led emi- nent men like Sir W. Thomson, Clausius, and others, to the conclusion that in any ordi- nary solid or liquid the mean distance between the centres of contiguous molecules is less than the 1-5, 000, 000th and greater than the 1-1, 000, 000, 000th of a centi- metre (2*5 centimetres = one inch).* To form some idea of what this implies, let the reader imagine a solid sphere the size of a football magnified to the size of the globe of our earth, which is about 8,000 miles in dia- meter ; if the molecules were magnified in the same proportion, the structure would be more coarse-grained than a globe of small shot, but less coarse-grained than a globe of footballs. Since we have been considering the two kinds of motion, molar and molecular, which affect FIG. 7. * For fuller information 011 this subject, the reader may consult with advantage Sir W. Thomson's Jeeture, reported in three num- bers of Nature for July, 1883. FORCE AND ENERGY. 21 matter, it may be convenient here to discuss briefly the two forms of ordinary attraction which affect matter, simply (so far as is at pre- sent known) as matter, i.e., irrespective of such attractions as those due to electricity, magnetism, and chemical agency. The first, or the attrac- tion between whole masses of bodies, is known as Gravitation, while the second, which expresses the attraction of molecules for each other, is called Cohesion. It is a universal physical law that every par- ticle of the universe attracts every other particle with a certain force, the amount of which de- pends on conditions to be presently explained. If a body (such as a stone or a rifle bullet) be projected into the air, experience tells us that it will almost immediately return to the surface of the earth, in consequence of the attractive force exerted by the earth upon it. It is equally true, however, that, in an infinitesimal degree, the earth falls towards the stone. Very delicate experiments have been made in a laboratory with two large masses of lead, accurately balanced and free to move, which proved the fact of the attractive force that they exerted on each other. A good illustration of the attraction of a large for a small mass of matter is seen in the fact that a plumb-line in the neighbourhood of large mountain masses does not hang perfectly vertical, the " bob " being attracted towards the moun- 2-2 ENERGY IN NATURE. tain, as was clearly shown by experiments made near Schehallion, an isolated mountain in Scot- land. Astronomers tell us how gravitation ex- tends its power to the most remote parts of the heavens; how the moon and the earth gravitate towards each other, and both together towards the sun ; how the whole solar system is gravi- tating in a given direction among the stars ; how double stars are systems of suns, revolving round each other under the action of the same force, each of which has probably its own system of planets, all moving in accordance with the same law. If we confine our attention to this earth and its satellite, we shall see that to gravi- tation in great part are due, in one sense the rise and fall of the tides, all the phenomena of wind and rain, all the mechanical energy derivable from falling water (in the form of torrents, so apparently irresistible), and, in fact, the regu- lation of the whole of the existing fabric of the earth's surface. Were it not for the attraction of gravitation, the speed at which the earth is rotating on its axis would send every loose thing upon its surface flying into space ; if we jumped into the air, or went up in a balloon, we should have 110 means of returning to the earth's sur- face. Thoughts like these illustrate the truth of the remark that " gravitation is the force which keeps the universe going." It is by virtue of gravitation that matter possesses weight ; for PORGE AND ENERGY. 23 the weight of any thing is the expression of the force with which it tends towards the earth, and, as we have seen, depends upon the mas,;, or quantity of matter, in the body. Hence it is evident, first, that weight is a particular case of the universal law of gravitation, and, secondly, that the force of gravitation between two bodies depends upon their mass. It remains to enquire what effect distance lias upon the force also. Experiment shows that if the distance between two bodies be doubled, the force of attrac tion between them will only be one-fourth as great ; if the distance be trebled, one-ninth as great ; if quadrupled, one-sixteenth as great, and so on; this is expressed in general terms by saying that the force of gravitation varies in- versely as the square of the distance. Other physical phenomena follow the same rule, e.g., the distribution of light from any light-source. Another illustration of the law of squares is seen in the phenomena of falling bodies ; a stone falls towards the earth 16 feet in the first second, 64 feet (or 16 multiplied by the square of 2) in 2 seconds, 144 feet (or 16 x 3 2 ) in 3 seconds, and so on. If the resistance of the air were removed all bodies would fall towards the earth at the same rate, irrespective of their compara- tive weight. This may be roughly shown by placing upon a penny a flat disc of paper the same size as the coin, and letting both fall to- 24 ENERGY IN NATURE, gether, when they will be found to reach the ground at the same instant. In all bodies there is some point at which its whole weight may be considered as concen- trated, and about which it will balance in all positions ; it is called the centre of gravity. When a body is free to move it takes up such a position that its centre of gravity occupies the lowest possible point, hence by hanging up an irregularly shaped body in two posi- tions (Fig. 8), and noticing where vertical lines from the points of support in- tersect each other, its centre of gravity may bo found. Many remarkable feats of balancing, of re- covery of equilibrium, &c., depend upon the position of the centre of gravity of the performer or of the thing balanced. The general rule governing these cases is that the equilibrium will be maintained as long as a ver- tical line drawn downwards from the centre of gravity of the body, falls within the base-line of the support (Figs. 9 and 10). The celebrated leaning tower of Pisa is a standing instance of this. The attraction of cohesion differs from that of gravitation, inasmuch as it is only exerted FIG. 8. VUUi'K AND ENERGY. 25 FIG. 9. between very minute particles of matter, and at exceedingly small distances ; it is, however, that which binds together the various par- ticles of a body, and resists our attemptsto break it; on the other hand, when the body is once bro- ken, and the particles separated by a measurable distance, it is very difficult to get them to adhere to- gether again.* It is obvious, therefore, that this molecu- lar attraction acts very powerfully through a certain small distance, but disappears * A notable instance to the contrary is afforded by lead ; u bullet may be cut in half, and the two clean surfaces -will adhere strongly if pressed together. >4dhes:on is the name sometimes gi\en to this form of cohesion. 26 ENERGY IN NATURE. entirely when the distance becomes percep- tible. Cohesion is strongest in solids, in liquids it is much diminished, and in gases it may be said to vanish altogether. Reference was made to the conditions of material life with- out gravitation ; a similar line of thought with regard to cohesion shows that if that attraction suddenly ceased to be exerted, our houses, our own bodies, and, in fact, the whole surface of the earth, would be instantly resolved into a heap of dust ! This is well illustrated by the so- called Prince Rupert's drops, formed by allowing drops of melted glass to fall into water, which assume, on cooling, the form of a pear-shaped crescent. If the conditions of equilibrium (i.e., the balancing of the forces) of cohesion are dis- turbed by breaking off the minutest fragment from the small end, the whole mass (the thick part of which will resist severe blows from a hammer) will suddenly fall into fine powder. Having thus disposed of some of the more important properties of Matter, simply as matter, let us proceed to inquire a little more in detail into what we have ventured to term its moods, i.e., to discuss the states and forms of Energy, which forms the special subject of this book. Energy may exist in two states, that of motion, and that of repose. It is obvious that any moving body possesses energy, or the power of doing work, but it is not quite so clear at first FORCE AND ENERGY. 27 sight how there can be energy in repose. In order to understand it, let us recur again to the analogy of the energetic man ; lie may be very quiet, and yet be able to do a great deal of work when he chooses to se!: about it. Energy in repose is in many case j due to its position, as may be seen from tliij example : Imagine a mill or factory driven by a water-wheel, and near this mill two ponds of water of equal capacity, one below the level of the wheel, the other at a considerable elevalion above it. It is obvious that, as far as the mill is concerned, there is no work at all to bj got out of the lower pond, while the fall of water from the upper pond will drive t:ie wheel. It should be carefully noted tluit the work is done by the passage of the water from a higher to a lower level, and this will help us to understand later on, how, in dor.ig work, energy passes from a higher to a lov.-er grade. Examples, then, of energy due to position, or, as it is called, potential energy, are to be found (mechanically) in a raised weight, a stretched spring, and a "head" of water; chemically, in coal, gunpowder, corn, and other foods, &c. (Chaps. III. and VI.) ; electrically, in voltaic batteries, and in accumulators or storage batteries (Chap. IV.). A little consideration will show that all poten- tial energy must ultimately be converted into energy of motion (called scientifically kinetic 28 ENERGY IN NATURE. energy), whether that motion be molar (i.e., of the mass), as in the case of mechanical motion, or one of the various forms of molecular motion. The following table gives the various supplies of natural energy and their sources, it being borne in mind that the words are used in a wide sense fuel and chemical affinity, for example, being intended to include the burning of zinc in a voltaic battery (pp. 102, 119) as well as of fuel in the air. Supplies of Natural Energy. Potential. Kinetic. (1) Fuel. (1) Winds. (2) Food of animals. (2) Water and ocean currents. (3) Ordinary water-power. (3) Volcanoes and hot-springs. (4) Tidal water-power. The sources of these supplies are : (1) Chemical affinity. (2) Solar Energy. (3) Energy of the earth's rotation on its axis. (4) Internal heat of the earth. These energies may be conveniently distri- buted into three groups, as follows : (1) Visible energies, including all cases of visible motion, such as those produced by gravitation, &c ; (2) heat energies, in which the motion is molecular (Chap. II.) ; and (3) chemical and electrical energies, in which the motion is rather that of atoms than of molecules (see Chaps. III. and IV.) It must not be imagined, however, that each of these groups or systems is complete in itself and 29 lias no sort of connection with its neighbours, for the various forms of energy are inseparably inter- mingled with each other. Energy, then, being the power of doing work, let us next enquire how that work is measured, a point of the utmost importance, as to which clear ideas are essential. When a man raises a weight from the ground, against the action of gravity, he does a certain amount of work ; if the number of pounds in the weight raised be multiplied by the number of feet through which it is raised, a number will be obtained which expresses the measure of that work ; these numbers are called foot-pounds, and foot-pounds are the standard in which all work is measured scientifically. One foot-pound, then, is 1 Ib. raised 1 foot ; 100 foot-pounds is either 1 Ib. raised 100 feet, or 100 Ibs. raised 1 foot, or 10 Ibs. raised 10 feet, and so on. The " horse-power" is the measure of the rate of work most commonly used, but it is obviously an unscientific one, because the strength of horses varies so much. What is now recognised as one horse-power is 550 foot-pounds of work per second, or 33,000 foot-pounds per minute. In the metrical system, to which reference has been made, the standards taken are the kilogramme (or 1,000 grammes, about 1-1 Ib.) and the metre (39*37 inches), and hence the unit-measure of work on the continent, and among 30 ENERGY IN NATURE. many English scientists, is the kilogram-metre, which is equal to about 7^ foot-pounds. Since the various forms of energy are inter- changeable, this work-measure can be applied to any one of them, whether it be heat, or electricity, or any other form, and so it comes to pass, for example, that when electrical energy is applied to produce mechanical motion (Chap. V.), and is distributed over our towns for this purpose^ the amount supplied will be measured, and can be expressed in foot-pounds, by meters con- structed for the purpose. It is a matter of common experience that the energy of a moving body depends upon, or varies with, its mass. The relation that the velocity of a body bears ta its energy is expressed by the law of squares (p. 23) ; i.e., if the velocity be doubled, the energy is quadrupled, three times the velocity gives nine times the energy, and so on. Having now cleared the ground somewhat, and gained some exact ideas on the subject of matter and its moods, let us enquire into the truth of the statement so often insisted on, that energy is never destroyed, but only transmuted, or changed in form ; and, to begin with, let us try to find an answer to the enquiry, What becomes of the energy of mechanical motion when it is retarded, or altogether arrested ? It is a matter within the common experience of FORCE AND ENERGY. 31 almost every one, that any attempt to stop such motion, to "put the brake on," results in the production of heat, and it will be the object of the next chapter to point out the relations between mechanical energy and heat energy. CHAPTER II. HEAT, A FORM OF ENERGY. LET us now consider some instances of the state- ment that whenever mechanical energy is re- tarded or destroyed, heat makes its appearance. All who have anything to do with machinery are familiar with the fact in the form of hot bearings, which need to be lubricated with oil (or water) in order to diminish the friction ; in the absence of that appliance of civilised life, the lucifer match (which is itself ignited by the heat produced when it is forcibly drawn over a rough surface) ; the untutored savage spends a great deal of energy in producing fire by rubbing together two pieces of wood ; a clever blacksmith can heat a large nail red-hot by simply hammering it upon his anvil ; when a cannon-shot strikes a target, its energy of motion is at once destroyed, but both shot and target become very hot, and fragments of the metal are often heated sufficiently to glow perceptibly in diffused daylight. The annexed engraving (Fig. 11) represents a Shoe- buryness target struck with an amount of energy expressed by about 2,200 foot-tons. The first person to whom science was in- HEAT, A FORM OF ENERGY. 33 debted for proving clearly the relationship be- tween mechanical and heat energy, was Count Rumford, who, on January 25th, 1798, read an elaborate paper to the Royal Society, entitled " An Enquiry concerning the Source of Heat which is" ex cited by Friction." In it lie detailed FIG. 11. experiments showing the large amount of heat produced in boring brass guns by horse-power in the military arsenal at Munich, during which the gun itself became hot enough to boil large quantities of water, and the metallic chips were intensely heated. These experiments, taken in connection with the very obvious fact that a hot body does not weigh more (or less) than the same body when cold, effectually disposed of D 34 ENERGY IN NATURE. the notion that heat was a material substance. " What is heat ? " he asked. " Is there any such thing as an igneous fluid? Is there anything that, with propriety, can be called caloric ? " and, after reviewing the whole series of experi- ments, he concluded, "It appears to me ex- tremely difficult, if not impossible, to form any distinct idea of anything capable of being ex- cited and communicated in these experiments, except it be MOTION." There is, as will be seen in the sequel, good reason to FIG. 12. believe that when motion disappears in this way, it is changed from the motion of the whole mass of the body into the motion of its particles, or, in other words, that the molar motion becomes molecular. Count Rumford's experiment may be illustrated on a small scale by the apparatus represented in Fig. 12, where a tube four inches long, and three- quarters of an inch in diameter, containing water, and corked, is rapidly rotated, while it is gently squeezed with a broad pair of wooden tongs. The heat thus developed speedily boils the water and blows the cork out. HEAT, A FORM OF ENERGY. 35 To Dr. Joule, of Manchester, belongs the credit of first expressing in numbers this relation- ship between heat and work, by a long series of laborious researches, extending from 1843 to 1849, and his experiments were of this kind. He took a closed vessel B, Fig. 13, contain- ing water, in which a paddle fixed on an axis was caused to rotate by gearing connected FIG. 13. with falling weights E, F; and as the amount of this weight was known, and also the dis- tance through which it fell, the work done could be calculated in foot-pounds; the fric- tion of the paddles against the water heated the whole contents of the box, and thus Dr. Joule established the fact that the mechanical work represented by 772 foot-pounds would, when converted into heat, raise the temperature of one pound of water by one degree of Fahreii- D 2 36 ENERGY IN NATURE. Kelt's thermometer (the ordinary scale in use in England). This number, then, is known as the mechanical equivalent of heat. Conversely, the amount of heat necessary to raise 1 Ib. of water 1 Fahr. would, if all applied mechanically, raise 772 Ibs. 1 foot high, nearly equal to 1J horse- power for 1 second. The heat generated by the collision of a fall- ing body with the earth depends on the height from which it falls, and as that height is pro- portional to the square of the velocity (p. 23), it follows that the heat generated increases as the square of the velocity; hence, if we double the velocity of a projectile, we increase four- fold the heat generated when that motion is destroyed, and so on. A velocity of about 1,400 feet per second in a rifle bullet would, when it struck the target, raise its own temperature nearly 1,100 Fahr. (if no heat were absorbed by the target), which would melt a portion of the lead. Calculating on this principle it has been shown that if the earth were suddenly stopped in her motion through space, as much heat would be generated as would be developed by the combustion of fourteen globes of solid carbon, each as large as the earth; and that if the earth fell into the sun the heat thus produced would be equal to that of the combustion of 5,600 such worlds. Specula- tions upon how the vast amount of the sun's HEAT, A FORM OF ENERGY. 87 energy* is maintained have led to the suggestion that it may be kept up, in part at any rate, by the constant showering down of solid meteoric o matter upon its surface ! It is a very curious fact, and one that has an important bearing upon the economy of na- ture, that equal weights of various bodies require different quantities of heat to bring them to the same temperature, or, in other words, that bodies vary very much in their capacity for heat. If 1 Ib. of water at 60 Fahr. be mixed with 1 Ib. of water at 212 Fahr. (its boiling-point) the temperature of the mixture will be found to be half-way between the two, or 136 ; but if 1 Ib. of mercury at 212 be used instead, the tempera- ture of the mixture will only be about 65. Water has a very great capacity for heat; the same amount of heat that will raise the tem- perature of 1 Ib. of water 1 Fahr. will raise 9 Ibs. of iron, 11 Ibs. of zinc, and 30 Ibs. of mercury by the same amount. This difference in capacity for heat may be also thus shown experimentally ; balls of different metals, iron, lead, bismuth, tin, and copper, are heated in oil * It is difficult to convey any idea of this. The amount of heat received by the earth from the sun in one year would liquefy a layer of ice 100 feet thick all over it, and yet this is only the l-2,138,000,000th part of the total heat emitted. Sir W. Thom- son has lately put it in another form (Nature for January 18, 1883), and expresses the radiant energy of the sun as equal to 7,000 horse- power per square foot, or 50 horse-power per square inch, every second of time, from the whole of his vast surface. 38 ENERGY IN NATURE. to about 350 Fahr. and laid upon a cake of wax (Fig. 14). The iron and copper balls will work themselves through first, the tin will follow, while the lead and bismuth scarcely sink more than half the depth of the wax. The following table in- dicates in figures the rela- tive capacity for heat, or specific heat, of various substances : FIG, 14. Substances. Water . Turpentine Air Glass . Iron Copper . Tin -'. Mercury Lead Specific Heat. , i-ooo , 0426 , 0-237 0-198 0-114 , 0-095 , 0-056 . 0-033 0-031 The specific heat of water is nearly the greatest of all known substances, hydrogen, and a certain mixture of alcohol and water, being the only exceptions. Comparing equal weights the relation of the specific heat of water to that of air is as 1 to 0'237, or 4-2 to 1; but as water is 770 times as heavy as air, if HEAT, A FORM OF ENERGY. 39 equal measures are compared it will be seen that the proportion is as 770 x 4*2, or 3,234 to 1. Hence a cubic foot of water in cooling 1 will warm by the same amount 3,234 cubic feet of air. A little reflection will show the - bearing of this fact upon the influences of the sea on climate, and the reason of the comparative ab- sence of extremes of heat and cold in an island climate ; it will presently be shown also how the system of circulation of the waters of the great oceans, from the equator to the poles, and from the lowest depths to the surface, demonstrated by such researches as those of H.M.S. Challenger, assists in moderating the severity of the land climate in various parts of the earth, and notably in the western shores of Europe. We have now to inquire into the mode in which heat passes through bodies. Experiment shows us that substances vary very much in their power of allowing this kind of molecular motion to pass through them, or, in other words, of conducting heat. A simple illustration will show this : place two spoons, one of pure silver, the other of German silver, in the same vessel of hot water; in a few moments the free end of the silver one will be much hotter than its neigh- bour, and if the experiment be repeated, and fragments of phosphorus placed on the ends, that on the end of the silver spoon will fuse and catch ^ while the other piece will be unaffected. 40 ENERGY IN NATURE. Of all solid bodies, metals (except bismuth) conduct heat best; next in order come stone, glass, and marble, wood-charcoal, and animal and vegetable tissues. The following table shows the relative conducting powers of metals for heat and for electricity (pp. 106-7), both of which we have good reason to believe are dif- ferent kinds of molecular motion. It will be noticed how alike they are : Substance. Silver Copper . ".."'" 1- Gold. | .-'.. .. Brass . .. . Tin . Iron . . Lead . Platinum . German Silver . Bismuth . . . Advantage is taken of the unequal conductivity of solids in many ways. Tools and metal uten- sils are furnished with non-conducting handles of wood or ivory : a wooden house is cooler in summer and warmer in winter than a stone one ; ice is packed in sawdust or flannel to prevent its melting ; steam boilers and pipes are (or should be) covered with felt. The natural clothing of the animal creation, and its application to the needs of human life, depend upon the same circumstance ; and the effect is heightened in this case by the fact that the air entangled among the Conductivity for Heat, 100 ' Conductivity for Electricity. 100 74 ''": . 73 53 59 24 22 15 23 12 13 9 11 8 10 6 6 2 2 HEAT, A FORM OF ENERGY. 41 fibres, feathers, &c., is an almost perfect non- conductor, so long as it is at rest. It should be noticed in this connection that the sensation of cold is really due to an abstrac- tion of heat from our own bodies. The tem- perature of the blood is about 98 Fahr., and when the hand is laid upon any substance at the air-temperature, it feels more or less cold, ac- cording to the rate at which heat passes from the hand to it, i.e., according to the conductivity of the substance. In the severe winter of the Northern United States it is absolutely necessary for all who have to handle metals in the open air to wear gloves ; the metal is not colder than the surrounding air, but, being a good conductor, it robs the human body of heat very rapidly, and will produce blisters upon the naked skin. The experiments which have been made to measure the conductivity of liquids 'and gases, prove that it is very slight indeed. Heat is, however, rapidly transmitted through these media by actual transport of the heated parts, a process to which the term convection (i.e., con- veyance, carrying,) is given ; it depends 011 the fact that (as will be immediately shown) the heated portions of the liquid expand, and thus become specifically lighter, when the balance is therefore disturbed, and motion throughout the mass ensues. The annexed cut (Fig. 15) shows the convection currents set up in water when 42 ENERGY IN NATURE. heated from below. Numerous examples of con- vection on a grand scale in nature will readily occur to the thoughtful mind: the cooling of large masses of fresh water in winter, the move- ments of air in all systems of ventilation, the trade- winds, produced by the sun heating the air at the equator, and, indeed, all winds. The investigations into the temperature of the sea at various depths, made on board H.M.S. Porcupine, Challenger, &c., show that in the great oceanic basins there is a constant cir- culation of their waters, both vertical and horizontal ; that the upper layers are moving from the equator towards the poles, while the lower layers are gradually creeping along the floor of the oceans from the poles towards the equator ; both upper and lower currents, however, being in- fluenced in their direction, just as the trade- winds are, by the rotation of the earth upon its axis, the northerly and upper current in the northern hemisphere being turned in an easterly direction, and the southerly and lower current in the same hemisphere taking a westerly set. There is good reason to believe that the maintain- ing cause of this grand circulatory system is to be sought rather in polar cold than in equatorial heat. FIG. 15. HEAT, A FORM OF ENERGY. 43 The interchange of heat between bodies not in contact, takes place by the process known as radiation. It is in this way that any heated body cools in the air that we are sensible of heat when we approach a fire that the heat of the sun reaches the earth and the various planets. Eadiant heat passes through space in straight lines at the same speed as light, and can be re- flected by mirrors and refracted by lenses in pre- cisely the same manner, a familiar illustration of which is seen in the so-called burning-glass. The nature of the surface of a body has a very great influence upon the rate at which it loses heat by radiation, and since those surfaces which radiate heat best, also absorb it most readily, these differences have very important bearings upon natural phenomena, and, there- fore, indirectly upon human life. Moreover, the power of a surface to reflect heat is the com- plement of its power to radiate or absorb it, as is seen by the following table, the totals of the two numbers opposite any substance being 100 in all cases : Eadiating powers. . 100 90 17 17 7 7 5 3 Lamp black Glass . Steel . Platinum Polished brass Red copper Gold . Polished silver Reflecting powers. 10 83 -83 93 93 95 97 44 ENERGY IN NATURE. The properties of radiant heat have been made a special subject of experimental study by Prof. Tyndall, who has shown how closely allied they are to those of the other form of energy which we recognise as light. The term radiant energy may, perhaps, be used to include them both, and a very pretty illustration of its effects is seen in the Kadio- meter of Mr. Crookes, in which four small mica vanes, blackened on one side, are mounted upon a pivot, and the whole arrangement is placed in a globe from which air is then almost completely ex- hausted (Fig. 16). When radiant energy, as the light of a candle, is allowed to fall on the globe, it is absorbed by the black sides FIG 16 ^ ^ e vanes > an ^ the molecular motion thus set up among the particles of gas still left inside the globe is at once transformed into visible motion, and the vanes rotate rapidly, with a speed varying partly with the intensity of the light. It must not be hastily concluded, however, that radiant heat and light are identical, although they are propagated in the same way, viz., by wave-motion in that ether, which, according' to the " undulatory theory" now generally accepted, pervades all space. The length of these waves HEAT, A FORM OF ENERGY. 45 can be measured, and those which affect the sense of touch as heat are much longer than those which affect the eye as light. Further, many substances, glass for example, are quite transparent to light, but opaque to radiant heat ; while others, such as iodine in solution, are abso- lutely opaque to light, but permit radiant heat to pass with the greatest ease. The presence of more or less moisture in the air has a most im- portant influence on the passage through it of radiant heat. Moreover, it must be borne in mind that the passage of radiant heat, as such, through any medium does not heat it at all; radiant heat only becomes sensible heat when the waves by which it is propagated are ab- sorbed, instead of being either reflected or trans- mitted. We now pass to the consideration of the effects of heat upon Matter, one of the first and most obvious of which is that, with one or two exceptions, all bodies expand when heated, and contract when cooled. In the case of solids this expansion takes place in the three directions of length, breadth and thickness. The linear ex- pansion of a rod by heat has been used in an instrument called a pyrometer to measure very high temperatures, in which an expanding rod presses against the short end of a bent lever, the long end of which moves a pointer upon a scale. Solids vary much in the amount of 46 ENERGY IN NATURE. their expansion under the same rise of tempera- ture, and the mechanical energy of this mole- cular motion under changes of temperature, is very great; an iron bar, for example, one inch square, cooled through 80 Fahr., contracts with a pull of fifty tons. Advantage has been some- times taken of this fact to restore to the per- pendicular the bulging walls of a building, iron tie-rods being placed across, and while they were red-hot the nuts on the ends of the rods outside the walls were screwed up tight; on cooling, the contraction of the rods drew the walls together. The practice of " shrinking" tyres on wheels is an example of the force of contraction. As a general rule liquids expand more than solids, but also vary much among themselves. The indications of the thermometer depend upon the expansion of liquids by heat. A glass bulb, from which projects a long fine tube, is filled with either mercury or alcohol ; in order to graduate it, it is plunged first into melting ice, arid a mark is made on the stem where the column of fluid becomes stationary ; the same process is then repeated with boiling water. The interval between these two points is variously divided ; the scientific division, also very largely used on the continent, is into 100 parts, the lowest mark (melting ice) being called 0, and the highest (boiling water) 100. This is called the centi- HEAT, A FORM OF ENERGY. 47 grade, or " hundred steps" scale, and ought to be universally adopted. In Northern Europe the interval is divided into 80, melting ice being 0, a scale known as Reaumur's. In English- speaking countries the scale is that of Fahrenheit, in which the interval is divided into 180 parts; in this case, however, the 0, or zero- point, is not the tempera- ture of melt- ing ice, but a point as much below that as cor- responds in distance on the scale to 32 of these 180 parts. Hence, on Water 4) _M "c S Reaumur rf o boils Water 90 80 70 60 50 40 30 20 io c _^o 70 60 60 40 30 20 10 freezes C ; FIG. I 7 . 1 I d " o -212 32- Fahrenheit's scale, the " freezing-point," which is the zero of the two other scales, is marked 32, and the boiling-point of water is 32 + 180, or 212. Since, therefore, the same in- terval, i.e., that between the temperatures of melting ice and of boiling water, is variously divided (Fig. 17) into 100, 80, and 180, the proportions of degrees on the Centigrade, Reau- 48 ENERGY IN NATURE. mur, and Fahrenheit scales are as 100 to 80 to 180, or as 5 to 4 to 9, or in other words, 5 C. = 4 R. = 9 Fahr. The temperatures of melting ice and of boiling water being the two fixed points, all degrees above and below those are obtained by simply prolonging the scale in either direction. The most notable exception to the law of expansion of liquids by heat is the case of fresh water, which is at its greatest density (i.e., is heaviest in proportion to its bulk) at 4 C. (39 Fahr.). Heated above, or cooled below, this point, it expands, and when it is converted into ice the expansion is sudden and consider- able, the ice, as is well known, floating on the surface. Were it not for this remarkable excep- tion to the general law, fresh- water lakes would become solid masses of ice in severe winters, all animal life therein would probably perish, and the climate in their neighbourhood would be- come quite rigorous. It is a somewhat remarkable fact that, in the absence of experiments, physicists somewhat hastily assumed that sea- water followed the same rule, and hence predicted that "in all deep seas a temperature of 4 C. (39 Fahr.) would be found to prevail."* Experiment shows, however, that sea- water continues to contract down to its freezing-point, and the deep-sea temperature * Sir J. Herschel's "Physical Geography," 1861. HEAT, A FORM OF EXfl&C&.j 4i> i^JY^ observations before referred to confinf and demonstrate the important consequences that follow from it. The linear expansion of metals heated be- tween the freezing and boiling points of water, varies from about one to three parts in 1,000. Water similarly treated undergoes a total in- crease in volume of 43-15, i.e., 1,000 gallons would become 1,043*. Three cubic feet of air, or of almost any gas, heated under the same circumstances, would become four, or, more exactly, 1,000 cubic feet would become 1,807, provided that the pres- sure were unaltered. The expansion of gases by heat may be readily shown by heating some in a vessel (Fig. 1) provided with a tube, the open end of which dips under a vessel previously closed at one end, filled with water, and inverted. The ascent of a fire-balloon, the ventilation of mines, the as- cending' currents of air which produce winds (and which under various conditions of moisture (ause clouds also), are all illustrations of the effects of alterations in the density or specific E FIG. 18. 50 ENERGY IN NATURE. gravity (p. 10) of air, produced by the expan- sion caused by heat. Having now considered the alterations in the mass of a body produced by heat, let us consider more closely its effect upon the molecules of which that body is composed. It was pointed out in the last chapter, water being taken as an illustration, that whether any substance was in the solid, liquid, or gaseous form depended in great measure upon the temperature and pressure to which it was exposed. By the use of intense eold and severe pressure, even the so-called per- manent gases such as oxygen and hydrogen have recently been condensed to liquids. On the other hand, the intense heat of the arc between the carbon points of the electric light (Chap. V.) is sufficient not only to melt, but to turn into vapour, the most infusible metals. Heat-energy, therefore, changes the molecular state of matter. If, however, the change be more closely examined, it will be found that in the passage of any substance from the solid to the liquid, or from the liquid to the gaseous state, an enormous quantity of heat disappears ; and that any change in the reverse direction is always accompanied by the apparent production of heat. For example, if 1 Ib. of water at C. (32 Fahr.), and 1 Ib. of water at 77-8 C. (172 Fahr.) be mixed together, the result will be 2 Ibs. of water at 39 C. (102 Fahr.). On the other hand, the temperature of a HEAT, A FORM OF ENERGY. 51 mixture of 1 Ib. of ice at C. and 1 Ib. of water at 77-8 C., will be found to be only C. What lias become of this heat ? The only dif- ference between the two experiments is, that in the first case liquid water was used, and in the second ice, or solid water. In the older books the phenomena was said to be explained by say- ing that the heat which thus disappeared " became latent," and the phrase is still in use to express the fact, but it does not explain it. Why does the heat become latent ? The true explanation, upon the principle of the conservation of energy, is that it is used up in overcoming the cohesive force of the molecules of water, and is thus trans- formed into a kind of energy of position. Again, it can be shown experimentally that 1 Ib. of water at 100 C. in being turned into steam, absorbs enough heat to raise 537 Ibs. one degree in temperature, and yet the steam is no hotter. In this case also the heat has " conferred potential energy upon the atoms," as any attempt to make the experiment in a confined space will immediately render evident ! A cubic inch of water produces nearly a cubic foot of steam. It may be stated generally, then, that change of state in the direction of solid to gas is accom- panied by the absorption of heat, or, in other words, the production of cold. Freezing mix- tures, in which certain substances snow and salt, for example rapidly liquefy when brought E 2 52 ENERGY IN NATURE. into contact, depend upon this principle, as well as all those freezing machines which owe their action to the rapid vaporisation of some volatile liquid, as ether, liquid sulphurous acid, or solution of ammonia. In all these cases the heat which is thus abstracted, reappears in that part of the machine devoted to the condensation of the vapour. In a similar way, whenever work is spent upon a gas, as it is when air (or gas) is com- pressed by mechanical means, heat is evolved, and when that gas is allowed to expand again by the removal of the pressure, heat is absorbed, or, in other words, cold is produced. The heat pro- duced by the compression of air may be shown experimentally by placing a piece of dry tinder under the piston of an air-syringe, closing the mouth of the cylinder, and smartly driving the piston to the bottom of it ; the heat thus evolved will ignite the tinder, as may be seen when the piston is withdrawn. During the last few years several very success- ful attempts have been made by various practical inventors, such as Bell-Col email, Hargreaves, and others, to take advantage of the production of cold when compressed air is allowed to expand, and to construct cooling machines upon this prin- ciple. Such machines (Fig. 19) are now exten- sively used for freezing meat, and for maintain- ing so low a temperature in the chambers in tttiAT, A FORM OF ENERGY. 53 which it is stored, that several cargoes of fresh meat have lately been brought to England from Australia and New Zealand in such good con- dition as to be indistinguishable from home- grown meat. The air is compressed by pumps, operated by a small steam-engine, and confined in strong reservoirs, round which sea-water is allowed to flow, in order to cool the compressed air to the surface-temperature of the ocean, after which it is allowed to expand into the frozen meat-chamber, which is of course kept closed (except as to the air entrances and exits) and surrounded with non-conducting material. The temperature of this chamber is controlled by regulating the volume of air passing into it, the quantity required being naturally dependent 54 ENERGY IN N upon its temperature, and this again upon the pressure from which it is allowed to expand. A very obvious advantage of this process is that no " chemicals " are employed in it by which the flavour of the meat can possibly be affected. Let us now consider that machine which effects the transformation of heat into work for practical purposes the Steam-engine. It is well known that the work, or motion, is produced by the expansive force of steam, which is ad- mitted alternately on either side of a piston fitted tightly in a closed cylinder in which it moves to and fro, and that when it has done its work the steam passes either into the air (as in locomotives and other " high-pressure " en- gines), or into a cold chamber or condenser (as in the ordinary marine and stationary engine). It will probably surprise many, however, to be told how very imperfect a machine even the most modern type of engine is, not more than eighteen per cent., or less than one-fifth, of the energy generated by the combustion of the fuel being given back as mechanical work. In fact, a no less eminent authority than Sir W. Arm- strong has stated that, for practical purposes, if the whole potential energy of the coat be divided into ten parts we should find that two went up the chimney, one was lost by radia- tion and friction, only one was turned into work, and the remaining six were wasted ! If it were HEAT, A FORM OF ENERGY. 55 not that coal is so cheap, and every other form of potential energy that we can buy is so dear, we should find the steam-engine very expensive to use. An attempt will now be made to show how this comes about, and why no very great improvement in the steam-engine is to be ex- pected. There is one condition which must be rigidly fulfilled in order to get mechanical work out of heat there must be a difference of temperature, and the heat must pass from a body of high temperature to one of low. An analogy may here be drawn with the case of water, out of which no work can be got unless it flows from a higher to a lower level (p. 27). What difference in temperature, then, is it possible to maintain in practice between the boiler and the condenser of the steam-engine ? In giving an answer to this question we must take into account not merely the thermometric differences, but the absolute quantity of heat, or of heat-units, in each, and to do this we must enquire what is the absolute zero of temperature. The law of expansion of gases by heat tells us that gases expand 373 of their volume for every increment of 1 C. in temperature between and 100 C., so that at 4- 273 C., the elastic force of a gas is double what it is at Q C. Supposing the same law to hold good in the other direction, at -273, i.e., 273 below zero, the gas would have no 53 ENERGY IN NATURE. elastic force at all. This point, then, -273 Q C., or -4()1 Falir., may be considered as probably the absolute zero of temperature, although it has never been actually readied. This number of degrees, therefore, must be added to the thermo- metric degrees in any such calculation. Let us assume the case of an ordinary engine with steam at three and a half atmospheres pressure, or 53 Ibs. per square inch. The temperature of this is 300 Fahr. The condenser cannot prac- tically be kept below 110 Fahr. Hence we have : Heat in boiler . . 300 + 461 = 761 units of heat. Heat in condenser . 110 +461 = 571 Difference, available for work . 190 ,, ,, Or only one-fourth of the total energy (100 parts out of 761) is available for the production of motion, even supposing that there were no other sources of loss, such as friction, radiation, &c. How much more perfect a machine in this respect is nature's engine, i.e., the human body, in which energy is derived from the combustion of food, will be seen in Chap. VI. (p. 189). It has been pointed out by Thomson, that although work can be transformed into heat with the greatest ease, there is no process known by which all the heat can be changed back again into work ; that, in fact, the process is not a reversible one. The consequence is that the mechanical HEAT, A FORM OF ENERGY. 57 energy of the universe is daily becoming more and more changed into heat, that heat being of a low grade, and (as we have seen in the case of the steam-engine) inconvertible. Hence it is conceivable that a time may ultimately arrive when " the universe will become an equally heated mass, utterly worthless as far as the pro- duction of work is concerned, since such produc- tion depends upon difference of temperature. Although therefore, in a strictly mechanical sense, there is a conservation of energy, yet, as regards usefulness or fitness for living beings, the energy of the universe is in process of deterioration. Universally diffused heat forms what we may call the great waste-heap of the universe, and this is growing larger year by year. . . . We are led to look to a beginning in which the particles of matter were in a diffuse chaotic state, but endowed with the power of gravitation, and we are led to look to an end in which the whole universe will be one equally-heated inert mass, and from which everything like life, or motion, or beauty, will have utterly gone away."* This is the doctrine known under the name of the " Dissipation of Energy," and, although very suggestive, its consideration should bo entered upon with the recollection that it applies solely to the physical universe, or rather to such portions of it as our senses can appreciate. * " Conservation of Energy," by Bulfour Stowurt, p. 153. 58 ENERGY IN NATURE. Reference has already been made to the in- timate association of heat and light, and it may be well here to point out that all bodies when heated sufficiently give out light, and that the colour of the light in the case of solids and liquids (melted metals, for example) depends upon the temperature to which the body is heated. The phrases in common use, such as red- hot, white- hot, & c . , applied to metals, re- cognise this f act. A very re- fined me- t h o d of examining; FIG. 20. -, or analy- sing the colour of light, is to pass a beam of it through a triangular piece of glass, called a prism. A coloured band is then seen, in which the various tints are separated from each other (Fig. 20), and to this coloured band the name spectrum is given. In the case of the rainbow, we see the spectrum of the sun's light apparently projected in the air. The examination of vari- ous kinds of light with an instrument called a spectroscope (the essential parts of which are a prism, a slit to narrow the beam of light, lenses, HEAT, A FORM OF ENERGY. 59 and an eye-piece) has shown (1) that all solid and liquid bodies when heated sufficiently give out all the various kinds of light, or, in other words, that their spectra are all the same, whatever their substance is, and are continuous bands of colour ; and (2) that when gases or vapours are heated sufficiently to give out light they only give out a few kinds, and that no two elementary substances give out the same kind. In other words, the spectra of glowing gases (i.e., of the vapours of metals, for example) are isolated bands of various colours, in groups characteristic of each gas. These facts are at the base of the whole science of spectrum analysis, whether applied to the detection of minute quantities of terrestrial sub- stances on the earth, or to the recognition of their presence in the atmospheres of the sun, stars, comets, nebulae, &c., since the mere examination of any light enables the trained observer to say with certainty whether the light- source is a glowing solid or liquid on the one hand, or glowing gas on the other, and if it be a gas, to form an accurate notion of its nature. He is also able to watch the constant changes going on in the atmosphere of that source of nearly all terrestrial energy, the sun, to say approximately the temperatures and pressures to which the glowing gases are subjected, and, more wonderful still, to estimate with tolerable accuracy the rate at which some of the heavenly bodies are moving 60 ENERGY IN NATURE. towards and from the earth in the direct line of sight ! Hitherto we have only considered the phy- sical effects of heat upon matter, in which no change takes place in the nature of the substance itself, but only in its mood or condition. One of the most important of the effects of heat, how- ever, is that of promoting in matter those changes which are known as chemical, in which more than one kind of matter, or one substance, takes part, and which result in the production of a third substance different from either. For ex- ample, in every coal-cellar containing coal there is in the fuel a large amount of potential energy ultimately derived from the sun (Chap. VI.), and the oxygen necessary for the combustion of that fuel is present also ; the fire, however, does not barn. In order to bring into play the energy of chemical attraction, the application of heat to a portion of the coal is necessary, and when this has once been done the chemical action continues, a large amount of heat is produced, and at the same time the coal disappears, being converted into carbonic acid gas. In this conversion of chemical energy into heat energy, which will be specially considered in the next chapter, the heat may be regarded as the mechanical result of the collision of the atoms of the carbon and oxygen. CHAPTER III. CHEMICAL ATTRACTION, ESPECIALLY COMBUSTION. THUS far we have been considering the effect of heat- energy upon one kind of matter or one sub- stance at a time, changes in which the body undergoes no alteration in its kind, but only in its mood or condition. To changes of this nature the term physical is frequently given, in contrast to the term chemical, which implies the fact that two or more different kinds of matter are con- cerned in producing the effect observed, and result in the formation of a third substance dif- fering in properties from either of the two with which the experiment is made. The present chapters deals with the relations between heat and chemical attraction, while the next one will deal, in part, with the relations between chemical attraction and electrical energy. We shall pre- sently see evidence of the broad fact that when- ever different substances combine under the in- fluence of chemical attraction, heat is produced or evolved ; and it will also be shown that, when it is desired to reverse this change, when it is wished to undo that work and to separate the two substances again, the application of heat to them 62 ENERGY IN NATURE. will in many instances effect that as well. In short, we shall see how much "potential energy" is stored up in substances between which there is a strong chemical attraction , and how great an in- fluence heat has upon the question whether these different substances shall be attracted to, or re- pelled from, each other. Although a strongly-marked distinction has been drawn between physical and chemical changes, it must be taken in the same sense, for example, as when the difference between plants and animals is exemplified by the instances of an oak-tree and a cow. The tendency of all scientific research is to obliterate these strongly-marked lines of demarcation and classification, just as among the lower forms of life it is frequently a matter of doubt whether a given organism is an animal or a vegetable (and, indeed, there is the best reason to believe, in one instance at least, that the same organism may be both animal and vegetable at different periods of its life history), so also are there actions, partly physical, partly chemical, which it is difficult to assign to either one class or the other. Let us consider now a couple of simple illus- trations of chemical action between two different bodies, and the influence of heat upon them. If a mixture be made of iron filings and flowers of sulphur, a grey powder is produced, in which the particles of iron and of sulphur each have CHEMICAL ATTRACTION. 63 the properties that characterise larger masses of iron and sulphur ; for example, a magnet applied to the mass will draw out of it all the iron filings. If, however, heat be applied to one part of it, enough to melt a very small portion of the sulphur, the whole mass will speedily glow with a bright red heat, and when it is cold it will be a dense compact mass, utterly unlike either iron or sulphur, and unacted upon by a magnet. If the experiment be made out of contact of air, the mass will be found to weigh exactly the same as the powder did before it was heated. Again, powdered charcoal and sulphur mixed together give another grey powder ; if, however, the sulphur be (not melted this time but) turned into vapour in a closed vessel, and bits of hot charcoal be dropped into it, the charcoal and sul- phur will unite chemically, and if the closed vessel be connected with a condenser, the result of the experiment will be found to be a clear bright liquid, as white as water, but very much heavier, known as carbon bisulphide, which is highly inflammable, and will dissolve many things which water will not. In order, then, that chemical attraction may take place between the (atoms or) molecules of two substances, it is necessary to bring them into very close and intimate contact. This is very conveniently done by heat, which, as we have seen, tends to separate molecules from each other, 64 ENERGY IN NATURE. and thus to make easier the passage of two sets of molecules between each other. * Any very fine extension of their surface, or severe pressure, however, will often bring two bodies within the sphere of chemical attraction without any heat whatever, a subject which has formed the basis of some curious recent investigations. Instances of some of these points will come before us in this chapter. Since we have now to deal with different Jdnds of matter, it may be well to state here that all kinds of matter known to the chemist are either simple, i.e., of one kind of substance only, or compound, made up of two or more of the simple ones. These simple substances, which cannot by any known process be separated into two others, are called elements. About seventy elements are at present known, and of these about sixty are the pure metals, iron, copper, silver, &c. Of the remaining ten or twelve, which are not metals, some are solid, such as charcoal, sulphur, and iodine ; one is liquid (bro- mine), while others are gases at the ordinary pres- sure and temperature, such as oxygen, nitrogen, hydrogen, and chlorine. As examples of chemical compounds we may cite chalk, made up of carbon, * A rough illustration of this effect of heat was afforded by the speaker presenting his right and left hands to each other, with the fingers closed, when they could not interlace. Supposing heat to expand the interval between the molecules i.e., the fingers the hands could then be interlocked. CHEMICAL ATTRACTION. 65 oxygen, and the metal calcium ; common salt, made up of sodium and chlorine ; water, made up of oxygen and hydrogen ; and bread, meat, and most foods, made up of the four simple ele- ments carbon, hydrogen, oxygen, and nitrogen. (The amount of energy to be got out of different kinds of food when we eat them, and the chemi- cal changes which they undergo in our bodies, will be considered in Chap. VI.) Having now a clear idea as to the difference between an element and a compound, let us consider some instances of the general statement that when two or more elements combine and produce a compound, their atoms rush together with great force, and the amount of heat developed by their collision is proportional to the mutual attraction of their respective atoms. The most familiar example is presented by all cases of combustion, whether that be carried on merely for the domestic uses of warming and cooking, or for metallurgical purposes, as in the smelting of metals, or for the production of mechanical power by the aid of the steam-engine, or for the projection of missiles of war and the blasting of rocks, as in the combustion of gun powder. In all these instances, then, the heat- energy is developed from the chemical attraction between the fuel that is burnt and the element oxygen, which, in all cases except the last (to be F 66 ENERGY IN NATURE. considered later), is supplied by the air around us, of which it forms one-fifth, and as a result com- pounds are produced which are neither fuel nor oxygen, but which contain both, and from which, by undoing the work done in combustion by reversing the process, by unburning them, as it were the oxygen and the constituents of the fuel may be recovered again. Speaking broadly, all the substances that are used as fuel, or for the production of light (ex- cept electric lighting, which will be dealt with in Chap. V.) are made up of very little else than the two elements carbon and hydrogen, in different proportions. Charcoal, and that peculiar hard shiny coal called anthracite, are nearly pure carbon. Paraffin oil arid coal-gas are almost entirely composed of carbon and hydrogen. Wood and bituminous coal, i.e., the ordinary caking coal that we use, contain small quanti- ties of oxygen, in addition to the carbon and hydrogen, as do also the animal and vegetable oils, and that elegant but expensive form of fuel, spirits of wine. The difference in properties of these various substances, and the various ways in which they behave when burnt, are largely due to the great differences in the relative pro- portions of hydrogen and carbon which they contain. Paraffin oil and spirits of wine, when burnt in similar lamps, behave very differently, the former giving a dull and very smoky CHEMICAL ATTRACTION. 67 flame, the latter a clear non-luminous blue one; and chemical analysis shows that the propor- tion by weight of carbon to hydrogen is as 4 to 1 in the first, and as 6 to 1 in the second. Smoke, as is well known, arises from the imperfect combustion of the fuel, due to a deficiency in the supply of air, or oxygen, and it is almost entirely composed of a mix- ture of other compounds of hydrogen and carbon, and of almost pure carbon. The formation of these products is due to the fact that in so many of our fire-places the coal frequently undergoes a sort of rough distillation (before it is actually burnt) without any attempt being made to con- dense the products. Before going farther into this question, however, it will be well to be- come acquainted with the chemical properties of oxygen, hydrogen, &c., and with the laws according to which these substances combine together. One of the most important laws in chemistry is known as the law of combining proportions ; it is the general expression of the fact that when two (or more) substances combine together to produce a third, they do so in certain definite quantities, or multiples of those quantities, which never vary. It is upon this invariability that the whole science of chemistry depends ; but for it exact chemical analysis would be impossible. Each element has its own combining proportion, F 2 68 ENERGY IN NATURE. and the numbers in the case of the three ele- ments we are considering- are- Carbon . . . * . ..12 Oxygen . , . . .16 Hydrogen . . . . . . 1 Hence 12 parts of carbon combine with 16 parts (or a multiple of 16) of oxygen, and so on. In this particular case the compound of 12 parts of carbon and 16 of oxygen is a colour- less, poisonous, inflammable gas, called carbonic oxide, which we often see burning with a pale blue or yellowish flame on the top of a clear coal fire; while the compound of 12 carbon to (twice 16 or) 32 oxygen is the gas usually known as carbonic acid, Avith which we shall shortly be concerned. No other compounds of carbon and oxygen only, are known, and should such be dis- covered they will be found to contain carbon and oxygen, in the proportion of multiples of 12 and 16. The application of this law in the present instance is that when fuel is completely burnt 12 parts (by weight) of carbon take 32 parts oxygen, forming 44 parts carbonic acid. 2 parts (by weight) of hydrogen take 16 parts oxygen, forming 18 parts water. Or, in this case by measure, oxygen being six- teen times as heavy as hydrogen 2 volumes of hydrogen take 1 volume of oxygen, form- ing 2 volumes of steam. CHEMICAL ATTRACTION. 69 It is a very practical point, and one which cannot be too strongly or too clearly brought home to those in charge of furnaces, steam-boilers, &c., that (assuming for a moment that coal is nearly pure carbon, as it actually is in some instances) every 12 tons of coal require 32 tons of oxygen for their complete combustion, and as oxygen is only one-fifth of the air, they require 1GO tons of air, or practically a ton of coal re- , quires 14 tons of air (or nearly 410,000 cubic feet] to be passed over it in order to burn it completely. To move this mass of air requires the expen- diture of considerable energy, and here we see one source of that loss of available energy pointed out in connection with the steam-engine. Oxygen may be readily obtained in the pure state by heating some of its compounds in a closed vessel provi- ded with an exit tube, the end of which dips under water, and the gas as it bubbles up (Fig. 21) is collected in a jar pre- viously filled with water and inverted over the end of the pipe. Chlo- rate of potash, and oxide of manganese are the two compounds generally FIG. 21. 70 ENERGY IN NATURE. employed for this purpose. Oxygen is the most abundant of all the elements, forming eight-ninths of the water, nearly one-fourth the air. and about j one-half of sand, chalk or limestone, and clay, the three most abundant minerals on the earth's sur- face, as well as entering largely into the composi- tion of most substances. Under ordinary conditions it is a transparent colourless gas, but it has been liquefied by cold and pressure. It is not inflam- mable itself, but substances burn in it with much greater brilliancy than in air, evolving a large amount of heat energy. A steel watch-spring, for example, one end of which is heated white hot in air, if plunged into a jar of oxygen, begins to burn with brilliant scintillations. Hydrogen is usually obtained from water by decomposing it (i.e., pulling it asunder), either by the energy of the electric current (p. 116) or by some metal which unites with the oxygen of the water, and turns out the hydrogen. Zinc */ put into water, to which a little acid has been added, effects this easily ; heat is not required in this case, and the mode of doing it is shown in Fig. 22. Hydrogen is the lightest substance in nature, being about one-fourteenth as heavy as air ; soap- bubbles blown with it easily ascend in the atmos- phere. It has also the greatest capacity for heat, or specific heat (p. 38), of any known sub- stance. It is usually a transparent colourless gas, CHEMICAL ATTRACTION. but, like oxygen, it has been liquefied, and probably also solidified, by cold and pressure. Unlike oxygen, it will not allow substances to burn in it, but it is itself inflammable, burning in air with a pale blue flame, and producing water by its combination with oxygen.* The chemical attraction between hydrogen and oxygen is greater than between any other two known substances, and hence their combination pro- duces the most powerful artifi- cial heat which can be produced by purely chemi- cal means. If the two gases be mixed together in the propor- tions by measure necessary to form water (p. 68), and a flame, or red-hot wire, be brought in contact with them, they unite with great explosive violence. In the oxy -hydrogen blow-pipe, the gases are brought to the jet by two separate tubes which unite, like a A, each provided with a cock for regulating the gas supply. The heat * The formation of water from the hydrogen of fuel or of gas when burnt, may be readily shown by holding a cold tumbler or bell-glass momentarily over a flame, and is also seen in the water which on a cold night trickles down the inside of a shop window where many lamps are burning. FIG. 22. 72 ENERGY IN NATURE. of this jet melts some of the most infusible metals, and heats lime to intense whiteness, pro- ducing the lime-light. For this latter purpose coal-gas is frequently employed in place of pure hydrogen, with but little diminution in the effect. The properties of the other element in fuel, carbon, in its usual form are familiar to most persons a dense black solid, devoid of taste or smell.* When it unites with oxygen, the pro- duct is a heavy poisonous gas known as carbonic acid. This gas is exhaled naturally from various parts of the earth, as a result of the energies that are at work in its interior. It may be readily prepared in the gas-bottle (Fig. 22) by acting on chalk or limestone, which contain nearly half their weight of carbonic acid, by another acid, such as hydrochloric acid (spirits of salt). When limestone is " burnt" in a kiln, the heat expels the carbonic acid and leaves pure lime. Carbonic acid is also a transparent colourless gas, much more soluble in water than oxygen or hydrogen ; it will neither burn itself nor allow anything else to burn in it, and it is poisonous to animal life. It forms the chief part of the fatal choke-damp or after-damp found in coal mines after an explosion. It is given off by all animals when breathing, and is one of the * It occurs pure in nature, however, in a crystalline form, and is then known as the diamond. Jet, lampblack, charcoal, &c., as well as the diamond, are other forms of carbon, and they all produce carbonic acid when burnt. CHEMICAL ATTRACTION. 73 results of fermentation and of the decay of ani- mal and vegetable matter. A portion of Chap. VI. will be devoted to explaining the source of the physical energy of the human body, which is closely associated with the production therein of carbonic acid resulting from the union of the carbon in our food with the oxygen of the air. The frequent formation and occurrence of this gas render it very desirable that a knowledge of its properties, and of some simple tests for its presence, should be widely spread. It is an ex- ceedingly heavy gas, being about half as heavy again as air, with which it does not readily mix ; this can be shown by actually pouring the gas from a vessel full of it into a vessel full of air, when the test of a burning taper will show that it has actually displaced the air, although there was no visible passage of matter from the first vessel to the second.* It cannot be too carefully re- membered that air containing so much car- bonic acid gas that a candle will not burn therein, is unfit also to support human life. A very simple test for it is afforded by clear lime- water (lime stirred up with water, and allowed to settle clear), which becomes milky directly it is shaken up in a bottle with air containing carbonic acid. The production of it in the * One practical consequence of this is that it has a great ten- dency to remain at the bottom of old wells, mines, brewers' vats,' &c. 74 ENERGY IN NATURE. human body may be shown by drawing air into the lungs through lime-water, which remains clear, and then breathing the same air out again into the lime-water, which at once becomes milky. The amount of carbonic acid in the breath is about 5 per cent (five parts in 100), and since pure air in the open country contains only about three parts in 10,000, and in towns seldom more than four or five in 10,000, while air with only six parts of carbonic acid in 10,000 is felt at once to be close and disagreeable, the need of the ventilation of confined spaces is very evident. It has been shown by very careful ex- periments and calculations that in ordinary dwel- ling-rooms of moderate size, the amount of fresh air necessary to be passed through the room in order to keep the proportion of carbonic acid below 6 in 10,000 is about 3,000 cubic feet per hour for each human being, for each lamp or gas-burner, and for each pair of candles.* It will now be desirable to consider a little more in detail the conditions under which fuel is burnt for the production of light, or, in other words, the structure of flame. It may be stated broadly at the outset that, under the ordinary practical conditions of daily life, no flame is luminous in which there are not some solid par- * It is beyond the scope of this little be ok to go more fully iiito this important question of respiration and ventilation, but the reader will find it fully and yet popularly treated in Professor Hartley's " Air and its Relations to Life" (Longman's). CHEMICAL ATTRACTION. 75 tides. The flame of burning hydrogen, for ex- ample, or of the mixture of coal-gas and air in a gauze burner or Bunsen lamp (Fig. 23), gives out scarcely any light ; but if some iron-filings are sprinkled into it, or a metallic wire be held in it, these solid particles will be intensely heated, and will glow, or become incandescent, enough to give out light. Solids may be thus made to glow by the energy of the electric current, as will be seen when the " incandescence electric lamps " are explained (Chaps. IV. and V.). It has been shown above that all our fuel is essentially some compound or other of carbon and hydrogen, and also that the energy of chemical attraction between hy- drogen and oxygen is much greater FIG. 23. than that between carbon and oxy- gen. When, therefore, the combustion is so ar- ranged that there is not enough oxygen present to burn both completely, the hydrogen is burnt first, and either pure carbon, or, as is more probable, certain other compounds of carbon and hydrogen containing a greater proportion of carbon than the original fuel, is left in the flame, to be raised to glowing point by the heat resulting from the collision of the atoms of hydrogen and oxygen. A careful study of a candle-flame (Fig. 24) will show that it consists in the main of three parts : (1) the exterior ENERGY IN NATURE. shell, very faintly luminous, where the combustion of both carbon and hydrogen is complete ; (2) the luminous part of the flame, containing the glow- ing and unburnt carbon compounds ; and (3) the inner, non-luminous portion, where no oxygen penetrates, which consists chiefly of the gaseous fuel. If a cold plate, or even a piece of thick white paper, be suddenly depressed upon a flame, so as to cut it across the middle, a ring of black carbon (or hy- drocarbon) will be deposited on it from the unburnt por- tions in the flame; and if the broken stem of a tobacco-pipe be inserted into the inner non-luminous part of the flame and steadily held in it (Fig. 24), inflammable vapours will issue from the other end, and can be igni- ted there. When a candle is blown out these vapours rise from the wick, and the candle can, with care, be rekindled by holding a light in these vapours several inches from it.* It appears, then, that the production of arti- ficial light from fuel depends upon a proper * These and many other interesting points are fully dealt [with in Faraday's "Chemical History of a Candle" (Chatto and Wmdus). FIG. 24. CHEMICAL ATTRACTION. 77 adjustment of the supply of oxygen, i.e., of air, which varies with the nature of the fuel em- ployed, and must be so arranged as to prevent the escape into the air of unburnt particles of fuel (i.e., smoke), and yet to leave enough uncon- sumed in the flame to give out light by their incan- descence. The various arrangements of chim- neys, globes, &c., around our lamps all have this object in view. It is, moreover, a curious fact that if the gaseous fuel be heated before it is burnt, it produces much more light ; this has recently been taken advantage of by Sir W. Siemens in the construction of large gas-lamps of enormous power, rivalling the electric light. We have seen that if hydrogen and oxygen are mixed and heated to a given point, they combine with explosive violence ; the same thing happens with a proportionately less development of energy, when coal-gas or other inflammable vapours are mixed with air, and more or less heated. To this cause are due the lamentable explosions in our coal mines ; fire- damp, a mix- ture of gases, chiefly hydrocarbons, is pent up in the coal, and is sometimes released, either by the mechanical process of mining, or by a diminution in the pressure of the air, owing to atmospheric changes indicated by the barometer, a sudden fall of which at certain periods of the year is frequently followed in a few hours by a colliery explosion. The fire-damp thus set free mixes 78 ENERGY IN NATURE. with the air, and when it comes in contact with a naked flame, or even with red -hot iron (heat, not actual combustion, being all that is necessary to kindle it), a, very rapid explosive combustion takes place. Moreover, recent experiments have con- clusively shown that the presence of finely- divided coal-dust in the air of the mine will communicate this rapid combustion, either alone or assisted by gas ; and further, that any inflammable substance, if sufficiently finely-divided and suspended in the air, will communicate an explosive flame over a large area. Many fires in flour-mills, &c., have been traced to this cause. In fact, the rate at which a flame spreads is largely determined by the extent of surface available for contact be- tween the combustible substance and the oxygen, and also by the heat-conducting power of the substance. Lead-foil, for ^example, cannot be made to burn in the air, but it is possible chemi- cally to obtain lead in such a very fine state of division, that when air has access to it, it begins to burn of itself. The lead pyrophorus, or fire- bearer, is made by heating tartrate of lead in a glass tube till vapours cease to come off, and then sealing the tube. This action, due to in- crease of surface, is the explanation of most cases of spontaneous combustion. Oily rags and greasy sawdust, for example, present large sur- faces of oil to the action of the air they begin to absorb oxygen therefrom, the energy of chemi- CHEMICAL ATTRACTION. 79 cal attraction is exerted, and presently the whole mass bursts into flame. The same process goes on in hay-ricks, and it is not the least of the re- commendations of the new process of preserving green fodder, called ensilage, that the exclusion of oxygen is an essential feature in it, fire-risks being thus avoided.* Allusion has been made to the important influence of the heat- conducting power of metals on the spread of flame, and it is upon this that the principle of the safety- lamp (Fig. 25) used in coal mines is based. Such lamps consist es- sentially of an ordinary oil lamp, the flame of which is completely surrounded with fine wire gauze, through the meshes of which only has air any access to the burning oil. When the lighted lamp is placed in an explosive mixture of gas and air, the mixture is kindled and con- tinues to burn inside the gauze cylinder, but the metal wire conducts away the heat so rapidly from the flame thus produced, that the gas on the outside of the cylinder is not kindled, since * The introduction of this process from America into this country was recently advocated at the Society of Arts by Prof. Thorold Rogers, M.P.,in a paper which has since been extended and published. 80 ENERGY IN NATURE. it is not heated to the necessary point of igni- tion. From what has been said about the theory of combustion, it is evident that when it is desired to obtain the greatest possible amount of heat-energy out of fuel, that fuel must be com- pletely burnt, so as to get the energy developed by the burning of the carbon as well as of the hydrogen. On a large scale this is far more prac- ticable when the fuel is gaseous than when it is either solid or liquid, since the supply both of fuel and of air can be regulated to. a nicety by valves, and hence it is that many furnaces now con- structed for large metallurgical and other manu- facturing operations are built in two or more parts, one of which is known as the gas-producer, the object of which is to roughly distil the coal, i.e., turn it into gas before it is burnt. Great economy and many advantages result from this method. The cleanliness and convenience of coal-gas as a fuel for domestic use are now coming to be more generally recognised, o wing- to the perfection of the combustion causing no smoke, and to the absence of dust, &c., arising from the ash, or unburnt (and unburnable) mineral constituents of the coal ; nor must the difference in the mode of delivery into houses of solid and gaseous fuel be overlooked. In the increased use of gas - stoves, gas - fires, and gas - cooking ranges, is unquestionably to be found the remedy CHEMICAL ATTRACTION. 81 for the smoke and smoke-fogs of our large towns, and proposals have been made by Sir W. Siemens and others to separate the gaseous products of the distillation of coal into two portions, collecting the first and last portions in one gasometer, and the middle portions in another, in order thus to supply lighting gas of higher illuminating power than at present (the middle portions), and, by a second set of pipes, gas of low illuminating, but great heating, power, for use in stoves, fires, &c. In addition to the energy obtained indirectly through heat from chemical attraction, mechanical energy is often obtained directly, in the shape of an explosion. A simple case of this is the gas- engine (Fig. 26), which has been developed during the last few years, and marks an entirely new departure in the artificial development of mechanical energy. In these engines the piston is driven backwards and forwards in the cylinder by the explosion, either in the cylinder itself or in an adjoining chamber, of a mixture of coal- gas and air. The explosion in the early forms was very sudden and rapid, but latterly, by means of automatic valves regulating the supply of air and gas, it has been made more gradual, so as to produce a tolerably uniform motion. The chemical changes that occur in the action of this engine are somewhat complicated, and there is no doubt that the heat produced by the com- G 82 ENERGY IN NATURE. bination ) which expands the gases, largely in- creases the mechanical effect. Directly connected with this subject is the transmission of energy from one place to another by the flow of gas. The use of the gas-engine Fio. 26. is probably at present the largest example of transmitting power, and according to recent cal- culations power can be transmitted by gas at one-twenty-fifth the cost of its transmission by compressed air. In most cases where explosive energy is exerted for mechanical purposes, however, matters are so CHEMICAL ATTRACTION. 83 arranged by the admixture of various solid or liquid chemical substances, that under the influ- ence of heat and of the chemical action induced by heat, these various substances suddenly re- arrange themselves in different combinations, some of which in all cases are gaseous at the temperature of their production, and it is to this sudden production of gas, whose expansive force is enormous, in a very confined space, that the destructive action of explosives is due. Grun- cotton, for example, cannot be distinguished by the eye from ordinary cotton, but the influence of a comparatively low degree of heat (whether applied directly or derived from percussion) will cause the atoms of which it is composed to change their grouping instantly, and to form fresh com- pounds, all of which in this case are gaseous. This is owing to the fact that, in making this explosive, ordinary cotton (which contains carbon, hydrogen, and oxygen) is soaked in nitric acid, whereby it loses some of its hydrogen, and takes up some nitrogen and a great deal of oxygen, and this oxygen eventually helps to burn the carbon and hydrogen. A similar change is made in glycerine, during the preparation of nitro-gly- cerine, from which dynamite, litho-fracteur, &c., are manufactured by taking up the liquid explo- sive with some absorbent powder. In Ms annual address as President of the Society of Chemical Industry, Sir F. Abel stated that the manufacture G 2 84 ENERGY IN NATURE. of dynamite had now (1883) reached the astonish- ing total of 9,000 tons per annum. Blasting gelatine, the " king of explosives," as it has been termed by Sir F. Abel, is a solution of gun-cotton, or nitro-cellulose, in nitre-glycerine. In the case of gunpowder, the charcoal and sulphur which it contains are burnt at the expense of the oxygen in the nitre, a salt which contains nearly half its weight of that gas. When powder explodes, the gases produced by it, when measured at the stan- dard temperature and pressure of C. and 760 mm. (i.e., 32 Fahr. and nearly 3 Gin. barometer) are 270 times the original volume of the powder, but so much heat is produced by the chemical action that if the explosion takes place in a space confined to the original volume of the powder, a pressure of 42 tons per square inch is exerted on the walls of that space. The energy imparted to a shot depends upon the rapidity with which the powder disengages its gases, and slow burning powder is, for artillery purposes, much better than quick. If the energy were developed too rapidly, it would be spent upon the powder-chamber, instead of upon the propulsion of the shot, and the gun would burst. The larger the " grain" of the powder the more slowly does it burn, other things being equal, and for very heavy guns the ." grain" is so large as to cause the term " pebble- powder " to be employed. In the case of some experiments in 1881 with the 100-ton gun, a CHEMICAL ATTRACTION, 85 projectile of 2,000 Ibs. weight was fired with a charge of 448 Ibs. of pebble-powder, each pebble being about one inch in diameter. The striking energy of this shot as it left the muzzle was 33,500 toot- tons. Hitherto we have been concerned chiefly with the production of heat when atoms collide, and chemical combination take place, although, in passing, instances have been mentioned where the decomposition or separation of substances was also effected by heat, as, for example, the "burning" of lime, when 50 parts of limestone lose 22 of carbonic acid, leaving 28 of lime. When a compound of two (or more) elements is resolved by great heat into its constituent elements, the process is called dissociation. Thus water may, if the steam be heated hot enough, be dissociated into hydrogen and oxygen; car- bonic acid into carbonic oxide and oxygen, and so on. It is a remarkable fact that the other form of radiant energy which excites in our eyes the sensation of light, also effects both these kinds of chemical change. If a mixture of hydrogen gas and chlorine gas (which is best prepared by decomposing hydrochloric acid by electric energy, Chap. IV.) be exposed to light in a glass vessel, they will unite with explosive violence. On the other hand, a familiar example of the decomposition of compounds by light is found in the beautiful art of photography, where 86 ENERGY IN NATURE. colourless substances containing silver are so affected by light that the image or picture pro- duced by a lens is painted by the silver thus set free from its compounds. Another instance, which will be developed at some length in Chap. VI., is the decomposition, or dissociation, of car- bonic acid by growing plants, under the influ- ence of light, when the oxygen is set free, and the carbon enters into the substance of the plant, forming therein a store of potential energy. CHAPTER IV. ELECTRICITY. THE first observation recorded with regard to this form of Energy in Nature was made by Thales of Miletus about 2,400 years ago, who observed that the curious substance amber, when rubbed, became temporarily endowed with the property FIG. 27. (which it had not previously) of attracting to itself light particles in its neighbourhood (Fig. 27). It is from the Greek name for amber yXetcrpov, Electron, that the term Electricity takes its name. The next step was made by 88 ENERGY IN NATURE. Dr. Gilbert , in the reign of Queen Elizabeth, who, repeating the experiment of Thales, ex- tended it to other bodies, such as diamond, rock- crystal, glass, sulphur, resin, &c., and showed that the same energy of attraction could be similarly excited in them, and he termed such bodies electrics. Otto Gaiericke, Sir Isaac Newton, and Dr. Franklin made further experiments ; but many years elapsed before the various isolated observations were systematised, and brought into that condition of exact knowledge which we re- cognise as scientific. The science of electricity may be said to have been established by the labours of Franklin, Volta, Galvani, Davy, and above all, of Faraday, during the latter half of the last, and the earlier part of the present cen- tury. It may be stated broadly that in every case of friction between (and probably even of contact of) two different bodies, there is a de- velopment of electricity. This is sometimes ex- pressed in another way ; it is said that ' i different bodies are at different potentials with regard to electricity;" the word "potential," in an electric sense, being used merely to express the degree in which a body is electrified. In the majority of instances, however, the effect is not percep- tible, since the electricity passes away instan- taneously by conduction, a process analogous to the conduction of heat (p. 40). Further ELECTRICITY. 89 researches have shown that the phenomena ob- served are best explained (or, at any rate, best described) by assuming the existence of two kinds of electricity, of opposite properties, to which the terms positive and negative, or vitreous and resinous, are given ; the production of elec- tricity by friction ap- pears to be due to the separation of the two kinds of electricity, one Yin. 28. accumulating on the rubber, the other upon the thing rubbed. If a pith-ball suspended by a silk thread (which being a non-conductor pre- vents the electric influence from passing away from the ball) be touched with a piece of glass that has been rubbed with silk, and the glass be then withdrawn, the ball will no longer be attracted by it, but repelled (Fig. 28). If then 90 ENERGY IN NATURE. a piece of shell-lac, resin, or sealing-wax, be rubbed with flannel and presented to the pith-ball, the ball will be attracted by it. From this we learn that bodies charged with the same kind of electricity repel one another, and that if charged with opposite kinds of electricity they attract one another. This repulsion is felt by many persons in electrical states of the air, their hair having a tendency to stand out from the head owing to the mutual repulsion between the fibres charged with the same kind of electricity. There are many mechanical operations, especially in the textile industries, in which these phenomena of electrical attraction and repulsion play an im- portant part. When one excited body is brought near an unexcited one, which is a conductor, the first attracts towards itself the opposite kind of electricity existing in the second, and as these two opposite kinds have a tendency to rush to- gether, they do so if the distance between them be not too great, and an electric spark passes across the interval ; the duration of this spark is not longer than the twenty-four-thousandth part of a second, and yet considerable heat, light, and noise are developed, and hence the energetic nature of electrified bodies is apparent. This apparent production of an opposite electrical state in bodies brought near to a substance previously electrified is known as induction. When it is desired to obtain larger supplies of ELECTRICITY. 91 electric energy than are produced by rubbing rods of glass, shell-lac, &c., electrical machines are em- ployed, all of which consist of two parts, one for producing, the other for col- lecting, the electricity (Fig. 29). The producing part con- sists usually of one or more FIG. 29. plates of glass, to which a rapid movement of rota- tion can be given, during which it is rubbed ; the collecting part comprises metal points and conduc- tors, placed near the rotating plate, and mounted upon some non-conductor, as a stem of glass or ebo- 92 ENERGY TN NATURE. nite. A description of the details of their construc- tion and mode of action would occupy more space than is here available, but it may be found in any elementary treatise on electricity.* They may be regarded generally as contrivances to develop elec- trical energy of a peculiar kind at the expense of mechanical energy. The most recent types of these machines depend very largely for their effects upon the influence of induction above alluded to, and are known as " induction" and also as " influence" machines. In consequence of the fact that damp air is a very much better conductor of electricity than dry air, or, in other words, is a much worse insulator than dry air, all experiments with such machines succeed best in a warm dry room. The electrical effect of these machines may be stored or accumulated in a Ley- den jar (Fig. 30), which is simply a wide-mouthed glass jar coated with tinfoil inside and outside for about three-fourths of its height from the bottom, and provided with a wooden cover, through which a metal rod passes, having a knob on its outer end, and a chain on the lower end which lies on the inner tinfoil coating. When a charge of one kind of electricity is driven into the jar, by connecting the rod with an electrical machine, * "Elementary Lessons in Electricity and Magnetism," by Silvanus P. Thomson (Macmillan, 18S2), Ferguson's "Electricity" (Chambers, 1882), Balfour Stewart's " Primer of Physics " (Mac- millan), and Worinell's "Electricity and Magnetism" (Murray, 1882), may be consulted with advantage for further information on the subjects of this and the following chapter, ELECTRICITY. 93 it spreads over the inner surface, and drives the whole of the other kind away on to the outer surface, whence it passes into the earth in contact with it. The jar may be retained in this con- dition for some hours, or even days ; but when- ever a path is provided by which the two kinds of electricity can re- unite, they will flow to one another, and the jar will be dis- J FIG. 30. charged. If this path is through the human body a shock will be felt ; if it is through a metal rod and across a space of air (Fig. 30) the discharge will be sudden, and accompanied by sound, light, and heat (from the transformation of electrical energy) ; if it is through a fine wire or a wet strino-, the discharge will be slower and more 94 ENERGY IN NATURE. quiet. It is important to remember that, as was iirst shown by Dr. Franklin, who constructed a jar with movable coatings, the charges of the jar really reside in the glass itself, and not in the metallic coatings. These effects may be largely increased by employing a number of Leyden jars in a " battery," when energetic mechanical and heating effects may be accom- plished by the discharge, such as the perfora- tion of cards, and of plates of glass, the fusion of metallic-foil and wire, the combination of mixed gases, the ignition of combustibles, explo- sives, &c. By far the grandest exhibition of these, however, is seen in the lightning-flash, the destructive energy of which is well known, and with good reason feared. This flash, which is a discharge either between a cloud and the earth, or between two clouds, at the point where the air offers the least resistance, may some- times be a mile in length, and its duration is not really more than the l-100,000th part of a second, although the impression on the retina of the eye lasts much longer. Its electrical energy is sometimes changed into mechanical, as when buildings are destroyed ; and sometimes into heat, as when metallic wires and rods in its path are melted. Dr. Franklin, who first established the identity of atmospheric electricity and that of the machine, suggested in 1749 the use of pointed metallic rods to protect property from ELECTRICITY. 95 destruction by lightning thus affording a path by which the discharge should take place quietly. Care should be taken in fixing these rods that their tips are of some metal which does not tar- nish in air, that the points project well above the highest part of the building, that metal work about the roofs be connected with them by stout wires, and, most of all, that their lower ends lead into damp ground ; the neglect of this last precaution, which is frequently unattended to, will make the best-laid conductor practically use- less , while the owner sleeps in fancied security. A rough practical rule for the height of a con- ductor is, that it will protect a circular area at its base whose radius is equal to its own height, so that a rod 50 feet high will protect a circle on the ground round it whose diameter is 100 feet. Electrical energy may be developed in many other ways than by friction ; a violent blow, and even steady pressure, produces opposite electrical states on the two opposing surfaces the tearing of paper or linen, the crushing of sugar, the cleaving of a sheet of mica, all produce it. Many bodies in passing from the liquid to the solid state become electrical, the phenomena of com- bustion and evaporation are attended by it, and in the evaporation of water over the surface of the oceans is seen one source of atmo- spheric electricity. Certain crystals (e.g., tour- maline) when heated are found to develop 96 ENERGY IN NATURE. opposite electrical charges at opposite poles. Many animals (notably the electric eel), and some plants, produce electrification, and Volta showed that the mere contact of certain metals caused them to assume opposite electrical states. Hence, as has been pointed out by Fleeming Jenkin,* " a sense enabling us to perceive elec- tricity would frequently disclose a scene as varied as a gorgeous sunset . . . Every movement of our body, each touch of our hand, and the very friction of our clothes would cause a play of effects analogous to those of light and shadow on the eye. . . . Without eyes we might never have discovered the existence of light. By direct perception we have become aware of the vast importance of light, and it is probably owing to the absence of direct perception that we do not yet know the part which electricity plays in the economy of nature." Thus far we have been considering chiefly the production of opposite electrical states in bodies, of static electricity, i.e., of electricity at rest ; the only instance of electricity in motion being afforded by the spark, or discharge, passing between two oppositely electrified substances, as in the Ley den jar or the lightning-flash. It will be desirable now to study a little more in detail some of the other modes of producing electricity * S.P.C.K. Manuals of Elementary Science : " Electricity " (pp. 51-53). ELECTRICITY. 97 111 motion, i.e., electric currents, since they afford remarkable instances of the general doctrine of the conservation of energy/ The transformation of mechanical into electrical energy will form the chief subject of the next chapter, the remainder of the present one being devoted to the connec- tion between heat and moving electricity, and between chemical attraction and moving elec- tricity. It has been already pointed out that the mere contact of two different metals gives rise to opposite electrical states in them, but so long as there is no difference in temperature between various parts of their junction there is no dis- charge, or movement of electricity no current is produced. If, however, heat be applied to the point of contact of any two dissimilar metals, and their free ends be united by a wire, a current of electricity will be found to flow through the wire and through the point of junction, in a direction varying with the pair of metals employed. This phenomenon is known as thermo-electricity, and it was first observed in 1822 by Seebeck. The best mode of detecting the existence of the cur- rent is by its action upon a magnetic needle (to be fully explained in Chap. V.), which is turned to one side or the other of its normal* position when an electric current circulates near to it. An instrument for subjecting a magnetic needle to the influence of a current is called a galvano- H 98 ENERGY IN NATURE. meter, and such an arrangement is shown in Fig. 31. The intensity of the effect depends upon the metals employed, and upon the tem- perature ; the pair that produce the greatest effect are bis- muth and anti- mony. If a series of these bars be solder- ed together in such a way that all the odd-numbered joints are on one side and all the even- numbered Oil the other, a thermo-elec- tric battery is formed, and the electrical energy of the arrangement depends upon the dif- ference in temperature which can be maintained between the two sets of joints. Such batteries have been constructed in a form powerful enough to produce the electric light, and other familiar effects of strong currents. When made on a very small scale the arrangement is known as a thermo- electric pile (Fig. 32), and in combination with a FIG. 31. ELECTRICITY. 99 delicate galvanometer is an exceedingly sensitive instrument for detecting minute changes in tem- perature, being largely used in researches upon radiant heat. It should be noted here, as another FIG. 32. illustration of the conservation of energy, that when an electric current is passed through a junction of dissimilar metals, the junction is cither heated or cooled, according to the direction of the current. We have now to consider the connection between chemical attraction and electricity, or, as it is often called, the production of electricity H 2 100 ENERGY IN NATURE. by chemical action. This was due, in the first instance, to two Italian men of science, Galvani and Volta, who early in the present century in- vestigated this subject, which we now recognise as one of the transmutations of energy, and whose names are perpetuated in the terms Voltaic and Galvanic batteries. Volta showed that when any two dissimilar metals are brought into contact, each of them is found to be in an opposite elec- trical state to the other, one becoming positively (+), and the other negatively ( ), electrified. The amount of difference between these states, and whether any given metal was in a + or condition depended upon the pairs of metals em- ployed iron, for example, being positive towards copper, silver, and gold, and negative towards tin, lead, and zinc. The reality of the existence of this "contact force," as it is often called, was doubted for a long time, but such doubts have recently been set at rest by some very delicate experiments of Sir W. Thomson's. It will be noticed, however, that this effect is a mere state, or condition ; in order to produce a flow, continuous discharge, or current of electricity, something more is necessary, and this is found in the arrangement known as the voltaic cell (Fig. 33). To construct it take a vessel of water, to which a few drops of sul- phuric acid, or a few crystals of common salt or of sal-ammoniac, may be added with advantage, and place therein two plates, z, c, of dissimilar metals, ELECTRICITY. 101 taking care to keep them apart. A very usual and effective pair is copper and zinc, with sul- phuric acid and water. As long as the two plates are kept apart scarcely any effect is observable, and none if the zinc be quite pure or be previously rubbed over with mercury, i.e., amalgamated. If, however, a wire, M, be attached to each plate, and examined as to its electrical condition, the two wires are found to be in opposite electrical states, and as soon as they are joined the two electricities rush together, and continue to flow or circulate along the wire. In the case of zinc and copper, the wire attached to the copper is called the positive pole, but, as in Volta's contact experi- ments, the intensity of the effect produced, and whether any given metal is + or , depends on the particular pair of metals employed. It will presently be seen that a wire joining two plates under these conditions, is in a very different state or mood from an ordinary wire. It does not weigh any more while in this state, but it has many curious properties chemical, magnetic, and physiological and these are ex- pressed by saying that a current of electricity circulates or flows in the wire. It is, however, important to remember that this is merely a FIG. 33. 102 ENERGY IN NATURE. convenient phrase to express a set of facts. We do not Jcnoiv that anytJiing actually flows along the wire, although there are some reasons for believing that these observed effects are due to a peculiar condition of vibration, or motion, set up in the wire, different from those accompanying the manifestations of heat-energy. One remarkable fact, however, in connection with this production of electrical energy by a voltaic cell, is invariably noticed, viz., that it is always accompanied by chemical action going on in the cell. One of the two metals must have a considerable chemical attraction for oxygen, and the liquid must be one capable of acting on the metal ; there is, however, no proof that their electrical behaviour is due to their chemical be- haviour, nor vice versa ; but the two sets of phenomena invariably occur together. When zinc foil is burnt in the air, or a mass of zinc in a crucible is heated by fire, the zinc is oxidised at the expense of the oxygen of the air, and heat energy is produced. When, however, zinc is oxidised at the expense of the oxygen of water (and hydrogen is given off), which is the chemical change that occurs in the voltaic cell, electrical energy is produced. Volta increased these effects by arranging a number of the cells in a series, in the manner indicated in Fig. 34, to which the name of " crown of cups " was first given, and this is the ELECTRIC principle of the arrangement of the same kind in a Voltaic battery. It was soon found that the bubbles of hy- drogen gas evolved stuck to the plates (especially to the copper one, from the sur- face of which they chiefly rose, although produced at that of the zinc plate), and that the energy of the cells rapid- ly became less. Numerous plans have been de- vised to over- come this diffi- culty, usually by the adoption of two fluids, separated by a diaphragm of porous earthenware, as well as two metals. DanielPs constant battery (Fig. 35) has the copper-plate immersed in a solution of copper 104 ENERGY IN NATURE. coming as gas, sulphate (blue vitriol), the zinc plate and dilute sulphuric acid being contained in a porous vessel, t h r o u g h which the hydrogen passes, and instead of off , de- posits cop- per on the copper- P late ; kec P- iiig its sur- face always clean and bright. Nearly 88,000 cells of this type are employed in the British postal telegraph service. In the Leclanche battery (Fig. 36) the only exciting liquid is a solu- tion of sal-ammoniac, and the por- ous vessel, M M, contains a carbon rod, c, surrounded by a mixture of carbon and oxide of manganese : 56,000 of these are used in the same service. In the so-called bichromate cell, the plates are zinc and FIG. gas- ELECTRICITY. 105 carbon, surrounded by a mixture of bichromate of potash and sulphuric acid (Fig. 37). More than 20,000 of a modification of these are used in the post-office telegraphs. Many other forms have been devised, the most energetic for a short period being Grove's nitric acid battery, in which the two metals are zinc and platinum, and the two liquids are weak sulphuric acid and strong nitric acid. Each arrangement has advantages of its own, and is best suited for particular kinds of work. It will be convenient here to define certain terms that are frequently employed in con- nection with electrical energy. In a single cell or battery, the path of the positive current from the zinc through the liquid, copper-plate, and wire back to the zinc again, is spoken of as the electric circuit, consisting of the liquid part and the metallic part. When the metallic circuit is not continuous, it is said to be broken, and unless the current has enormous energy it will not leap over the smallest break of continuity ; when two surfaces touch so closely that the current passes from one to the other, they are said to be in contact, A con- ductor is a substance along which the current flows more or less freely, such as most metals ; and it 106 ENERGY IN NATURE. is a curious fact that those metals which conduct heat best (p. 40) also conduct electricity best : the order of conducting power is the same for both. An insulator is a substance through which the current will not pass, such as silk, glass, earthenware, gutta-percha, &c., and insulators are used for preventing the electric energy from leak- ing out of the conductors. The phrase electro- motive force (for brevity often written E.M.F.) denotes that which moves, or tends to move (p. 4) electricity from one place to another, just as the pressure in a system of water-pipes sets, or tends to set, the water in motion along it ; and the phrase " potential" is used to express the degree to which a body is electrified, a great difference of potential between any two bodies corresponding to considerable E.M.F. between them. For further information on these subjects, the reader should consult the various text-books on Electricity before referred to. It will be well now to consider some of the effects of electricity in motion, or current elec- tricity, and to observe how they differ from those of electricity at rest, or the static electricity of bodies in opposite electrical conditions. In the discharge of the Leyden jar, we noticed some of the work that was done by moving electricity, but the discharge and its immediate conse- quences were of excessively short duration. In the case of current electricity, however, the ELECTRICITY. 107 effects produced by it last as long as the current continues to flow, or, in the case now being con- sidered, as long as the chemical changes go on in the cells of the battery, provided also that the circuit is maintained untouched, and that contact is nowhere broken. It should be carefully borne in mind, however, that the phrase " current of electricity" is purely a conventional one, for there is no proof that any- thing " flows " along the wire. Our actual know- ledge is confined to the fact that a wire under these conditions possesses certain remarkable pro- perties, and that this change, whatever it be, is communicated along the wire at a speed closely approaching the velocity at which light travels, con- siderably exceeding 150,000 miles in one second. We have seen what occurred when resistance was offered to the energy of mechanical motion viz., that it was converted into heat-energy. The same thing happens when resistance is opposed to electricity in motion. This resistance is offered by bad and small conductors, and accordingly we find that when a current of elec- tricity meets a high resistance in its path, the place where that occurs is more or less heated. The experiment may be effectively made by in- troducing into a circuit along which a strong current is flowing, a short fine wire, too small to convey the whole of the current, when it will be seen that the wire will get intensely 108 ENERGY IN NATURE. hot, and if the energy of the current is sufficient it will melt, and the circuit will be broken. This power of exciting heat- energy at will by means of electricity is, as is well known, extensively used for firing mines at a safe distance, thus avoiding the possible accidents from time-fuses ; for discharging heavy artillery, either singly or simultaneously, in a broadside on a man-of-war, and, as will shortly be seen, it is at the basis of all applications of electricity to lighting purposes, and more especially to that form known as incan- descence lighting. The resistance offered by a conductor depends upon its size, and also upon the material of which it is made. A very pretty experiment illustrative of this latter point is to construct a chain of alternate links of the same gauge and lengths of silver and of platinum wire. When a strong current is sent through this, the platinum links become red-hot, while the silver links, being better conductors i.e., offering less resistance remain comparatively cool. The principles of electric-lighting will be explained in the next chapter, since, as practi- cally carried out at present, they involve those questions of the relations between magnetism and electricity which will there be specially con- sidered. It will be sufficient to remark here that there are, broadly, two systems [1], the Arc system, in which the light is produced when the resistance opposed by two pieces of carbon ELECTRICITY. 109 (with a thin stratum of air between them) is introduced into the circuit; and [2], the Incan- descence, or glow, system, in which the necessary resistance is given by a continuous thin filament of carbon interposed in the circuit. It may be remarked here that neither system is as new as is generally supposed, the arc-light having been produced by Sir H. Davy three-quarters of a century ago,* and an incandescent carbon lamp having been publicly exhibited in Birmingham by Mr. W. Mattieu Williams more than thirty years ago ; in all such cases, however, the electrical energy was developed by chemical means, which were so costly as to prohibit the use of the light except for scientific experiments, and on occa- sions when expense was no object. The reason why so much has been heard during the last few years of the application of electricity to lighting, and to various other purposes of prac- tical life (such as motive power, &c.) is, that only recently have the means been discovered of transforming the cheapest source of energy known to us, viz., mechanical, into electrical, and also of effecting the reverse change. The apparatus which effects this is called a dynamo- machine, and will be fully explained in the next chapter. It may be interesting here to note the * The first production of an arc-light is probably due to Etienne Gaspard Robertson, and is recorded in the Journal de Paris, for the date 22 Yentose, An X (March 12, 1802). Yide Nature, June 7, 1883 110 ENERGY IN NATURE. comparative cost of electrical energy developed chemically and mechanically ; the following table gives the number of foot-pounds of energy which can be got out of one ounce weight of different substances : Gunpowder 100,000 Coal 695,000 Zinc 113,000 Copper 69,000 Hydrogen 2,925,000 From this it appears that coal is capable of giving out six times as much energy as zinc, so that even if coal and zinc were the same price per ton, the (electrical) energy produced by zinc would be six times as costly as the (mechanical) energy produced by coal. As is well known, the price of a ton of zir.c is many times that of a ton of coal, and hence, even under the most favourable circumstances, the cost of electrical energy developed chemically compares most unfavourably with the cost of that developed mechanically, in the manner to be described in the next chapter. We have seen that the mere approach of an electrified body towards a conductor in a neutral condition promotes, or induces, an opposite elec- trical state in that other body ; a phenomenon of a similar kind in current electricity was observed by Faraday in 1831, and the fundamental fact of current induction may be thus stated. If two ELECTRICITY. Ill wires are laid parallel to, but insulated from, each other, and a current be sent along one of them, it is found that at the very instant when the current commences to flow in it, a momen- tary current passes along, or is induced in, the second wire. This induced current is in the opposite direction to the current in the first wire, and it ceases immediately, no change occurring in the second wire until the current in the first wire ceases to flow; at this instant another in- duced current makes its appearance in it, but in the reverse direction to the first induced cur- rent, and therefore in the same direction as that of the continuous current in the first wire. The same effects are observed when a wire along which a continuous current is flowing is brought near to, and removed away from, another sepa- rate wire. The experiment is best shown by insulating both wires with silk or gutta percha, and winding them in coils on thin wooden bob- bins (Fig. 38); the ends of the first, or " pri- mary " wire, are connected to a battery, and the ends of the second to a testing instrument called a galvanometer (Chap. V.). When the primary coil is put inside the secondary, and when it is removed from it, evidence is obtained of the development of the induced currents above described. The same effect may be produced in a more perfect way by allowing the primary coil to remain inside the secondary, and fitting to the former a little mechanical arrangement 112 ENERGY IN NATURE. which makes and breaks contact rapidly with the battery, and consequently produces a very rapid succession of these induced currents. The primary coil is a short length of comparatively thick wire, of low resistance, and the secondary coil is composed of many turns of very fine and well-insulated wire. Such an arrangement FIG. 38. is known as an Induction coil, and sometimes as a Ruhmkorffs coil, from the name of a very celebrated maker of them (Fig. 39). Induced currents always possess great electro -motive force, and their sparks will strike across intervals that no battery will reach ; their physiological effects are very strong, even comparatively small medi- cal coils giving most unpleasant shocks, while the discharge from some large coils is sufficient to kill a man. The largest coil yet constructed ELECTRICITY. 113 belonged to the late Mr. Spottiswoode, President of the Royal Society (1883) ; it is 4 feet long and 20 inches in diameter, weighing altogether 15 cwt. ; its primary coil is 660 yards of wire nearly yVth inch in diameter, and the secondary coil contains 280 miles of wire, nearly yiroth inch FIG. 39. in diameter ; when excited by a Grove's battery of 30 cells it gives a spark 42 J inches long, a veritable miniature flash of lightning! Many of the effects of the ordinary " electrical machines" (p. 91) can be produced by these coils, but their chief use is for the study of the electric discharge under various conditions either in air or in a partial vacuum, some of the experiments upon which last are probably the most beautiful in the whole range of experimental physics. The 114 ENERGY IN NATURE. character of the luminous discharge is subject to almost innumerable variations, depending upon the degree of exhaustion of the glass tube or vessel (Figs. 40, 41), and upon the kind of gas or f gases contained in it at these exceedingly minute pres- sures, but it is a remarkable fact that when the exhaus- tion has reached the stage of a nearly perfect vacuum, the discharge will not take place at all. The study of these discharges has thrown considerable light upon that wonderful natural phenome- non, the . Aurora Borealis, and also upon the molecular theory of matter referred to in Chap. I. The very re- cently published investiga- tions of Prof. Selim Lein- strom (vide Nature , Xos. 709, 710, &c.) into auroral phenomena, have thrown considerable light upon that subject. In the last chapter we saw several instances of the heat-energy developed by the force of chemical attraction, and it was also pointed out that under certain conditions the process could ELECTRICITY. 115 be reversed, i.e., that if heat-energy were allowed to act on the compounds thus produced, the work could be undone, and the compounds separated or decomposed. Now it is found that electrical energy is one of the most powerful agents with which we are acquainted for decomposing chemical compounds, especially when they are Fro. 41. in the liquid state. No liquid (except melted metal) which conducts electricity at all, conducts it without being thus decomposed, and when this occurs the electrical energy is spent in overcoming the resistance of the chemical attrac- tion for each other of the two substances forming the compound. The most familiar ex- ample of this is the electrical analysis, or the electrolysis, as it was called by Faraday, of water. Pure water belongs, like turpentine, petroleum, and many oils, to the class of non- conductors, but if a few drops of sulphuric acid be added, it may readily be decomposed by the i 2 116 ENERGY IN NATURE. current from a few cells of a battery. The arrangement is shown in Fig. 42 ; the wires from the battery are attached to two platinum plates, over each of which is inverted a tube closed at one end, and filled with water. When the con- nections are made, bubbles of gas rise from each plate to the top of the tube, displacing the water, and in a short time it will be evident that twice as much gas is Fia. 42. collected in the tube which is connected with the zinc end of the battery, as in that con- nected with the copper end. If the tubes be then removed and their contents examined by chemical tests, the larger volume of gas will be found to be hydrogen, and the smaller, oxygen, thus demonstrating the statement of the compo- sition of water given on p. 68. If, instead of water alone, a solution of any metallic salt be similarly treated, as, for example, sulphate of ELECTRICITY. 117 copper (blue vitriol), sulphate of nickel, acetate of lead (sugar of lead), &c., oxygen will still be given off in one tube, but in the place where hy- drogen before appeared no gas will be given off ; instead of it the platinum plate will be covered with a deposit of the metal itself, copper, nickel, or lead, according to the salt employed. These facts form the foundation upon which the whole art of electrotyping and electro-plating has been reared, to which industry the phrase electro-metal- lurgy is often given. The articles .to be plated are connected with the zinc end of the battery, or with the corresponding end of some other source of electricity, and are suspended in a tank containing a solution of the metal to be deposited on them. In the case of silver-plating, a double cyanide of silver and potassium is used, and for gilding, a similar salt of gold in a hot solution. The other end of 'the battery (or dynamo-machine, Chap. V.) is attached, not to a platinum plate, but to a sheet of the metal whose salt is in solution, which is also hung in the tank. When the circuit is completed, the electrical energy tears asunder the metal from the acid in the salt, depositing it upon the substance to be plated, and the acid and oxygen thus set free at once exercise their attraction for the metallic plate, which is gradually dissolved away, and thus the strength of the solution is kept up. Electrotyping is the name given to the art of copying seals, 118 ENERGY IN NATURE. medals, engraved plates, &c., in copper, and may be readily practised by the amateur. A sharp mould must first be taken of the object to be copied, in fusible metal, sealing-wax, gutta-percha, or plaster of paris, and if it be made of any except the first named, it must be rubbed over with plumbago (black-lead) to make the surface conduct electricity. The mould is then hung in a tank as above de- scribed, containing a solution of sulphate of copper and a sheet of copper, connected with a battery, and left until a sufficient thickness of metal has been deposited, when the electrotype and the mould are pulled asunder. A large number of the cuts in this book have been printed from electrotypes thus produced. For small objects a simpler arrangement suffices, known as the single cell apparatus (Fig. 43). It consists of an earthenware vessel half filled with a strong solution of sulphate of copper, in which also stands a porous earthenware pot containing dilute sul- phuric acid and a plate or rod of zinc, which is connected by a wire to the mould hung in the solution, and the strength of this is kept up by FIG. 43. ELECTRICITY, 119 suspending some crystals of sulphate of copper in it. We have seen that whenever chemical com- bination takes place some form of energy is developed, and also that energy is absorbed in undoing that work. Now, since the amount of energy produced in the first of these processes varies with the quantity and with the kind of the materials employed, but is always the same when the same quantity of similar materials are used, we should naturally expect to find that the amount of electric energy necessary to undo this work varied in the same way, and this is actually found to be the case. In other words, the ivork done is proportional to the electricity generated, and to the amount of zinc " burnt" in the battery. When water is thus decomposed, the amount of gas evolved depends upon the strength of the current employed, and upon the time for which it acts, and Faraday constructed an instrument called a Voltameter, in which the mixed gases are measured in a graduated tube, and from the quan- tity collected in a given time, the strength of the current can be calculated. Mr. Edison has re- cently proposed to apply the same principle to a meter intended to measure the amount of elec- tricity drawn from the town -supply by any pri- vate house, whether for lighting or as motive- power (Chap. V.). In this ingenious instrument the weight of copper deposited by a known 120 ENERGY IN NATURE. fraction of the current upon a plate of metal gives the necessary data for the calculation, and by a curious mechanical contrivance the instru- ment is provided with a set of dials, to be read off just like a gas-meter. But further, if the same strength of current, i.e., the same quantity of electric energy produced by the consumption of the same amount of zinc, is used to decompose salts of various metals, it is found that the amount of metal deposited differs in each case, and, in fact, that these different weights stand to each other in the same relation as the numbers which express (pp. 67, 68) the combining proportion or equivalent of each element. Thus, for every 32 J parts of zinc consumed in the battery (or de- posited by a given strength of current) 31^ parts of copper, 108 parts of silver, 29 J parts of nickel, and 65 J parts of gold would be deposited. More- over, as hydrogen develops the greatest amount of energy in its combinations, it is not surprising to find that the greatest amount of energy is necessary to decompose its compounds; accord- ingly only one part (by weight) of hydrogen is produced by the consumption of 32 J parts of zinc. Recently, the electro-chemical decomposition of water, or rather of weak sulphuric acid, has assumed exceptional importance in connection with the so-called " storage of electricity," or " storage of force/' erroneous expressions, as will ELECTRICITY. 121 be seen in the sequel, for which should be substi- tuted the phrase u electrical storage of energy." The first observation on the subject is due to Sir W. Grove, who, in 1842, noticed that if he decomposed water in a voltameter, and then, having disconnected the bat- tery, joined the two plati- num plates by a wire (Fig. 44), a current of electricity passed along the wire, and at the same time some of the gas disappeared. More- over, the current was from the oxygen to the hydrogen, or in the reverse direction to that which separated them. A battery made up of fifty of these cells possessed suffi- cient energy to decompose water, and even to produce the electric light, and their energy appears to be due to, at any rate it is always accompanied ly, chemical action between the hydrogen and oxygen, just as in the simple voltaic cell, chemical action between the zinc and oxygen (p. 102) always accompanies the produc- tion of current electricity there. The first person to apply this fact upon an industrial scale was M. Gaston Plante*, who in I860 constructed his storage -battery, or accu- FIG. 44. 122 ENERGY IN NATURE. mulator, in the following simple manner : Two long- wide slips of lead are laid upon each other, separated by narrow strips of gutta-percha ; the whole is then rolled up in a spiral form and im- mersed in a (glass) jar containing weak sulphuric acid ; a connecting strip is at- tached to each plate, and'car- ried outside the cell (Fig. 45). When the current from a bat- tery (or a dynamo-machine) is sent through the cell, water is decomposed, and the plate by which the current enters (i.e., that attached to the " copper," or positive, end of the battery) is covered with a thin film of oxide of lead, while the hydro- gen is absorbed by the other lead plate. When the battery - is disconnected the cell may be kept some time in the same condition, but as soon as the two lead-plates are joined by a wire a current passes between them, and at the same time some of the hydrogen combines with the oxygen of the oxide of lead on the other plate. If the cell be now charged again, but in the reverse direction, more gas will be absorbed by eacli .plate, and if this process of charging and discharging alter- nately in opposite directions be repeated several FIG. 45. ELECTRICITY. 123 times, the surface layers of both lead-plates will get into such a porous condition that they will absorb very large quantities of gas. This pro- cess is known as " forming " the cell, and is somewhat tedious. To obviate this M. Camille Faure in 1880 coated both plates with red-lead, and thus obtained the neces- sary porous condition of me- tallic lead with a much less number of charges and dis- charges of the cell than was necessary in Planters form. A plan of the arrangement of the plates in a Faure cell is given in Fig. 46. In the Faure-Sellon-Volckmar accu- mulators probably the most efficient yet (June, 1883) produced on a commercial scale, thick leaden gratings are cast, the perforations in which are then filled with oxides of lead; and, indeed, nearly all the modifications pro- posed have for their object the increase of surface of the lead employed, upon a support which is not acted on by the liquid contents of the cell. Opinions are somewhat divided as to the exact nature of the chemical changes that occur in these cells, but there can be no question that J ~N L ^ r -N 1 ,j ( -\ -i j ] \ 3. 46 124 ENERGY IN NATURE. sulphuric acid, sulphate of lead, peroxide of lead and water play an important part therein, and that they are continually undergoing decomposition and ^-composition. The main points, however, to be remembered in connection with them are that when the cell is being charged the electric energy does chemical work in the cell, and in so doing ceases to be electricity ; that the work which is done is the overcoming of the chemical attraction of certain substances for each other ; that the cell in the charged condition resembles an ordinary voltaic cell, from which electric energy can be drawn at pleasure by completing the circuit outside it ; and that when the cell is discharged, and the electric energy is drawn off, the electricity is produced at the time, and is always accompanied by, and probably caused by, the re-union of the substances previously separated. Hence these accumulators do not contain electricity as such, but only the means of producing it when wanted energy, not electricity, is stored in them. A precisely parallel case to this will be found in Chap. VI., where the storage of solar energy in wood and coal (through the medium of growing plants), and its reproduction as heat and light when the carbon and oxygen thus separated are brought together again, are de- scribed at some length. In fact, in almost all cases a store of energy arises from the separa- ELECTRICITY. 125 tion of two bodies which desire to come to- gether. Nearly all the practical uses of these accu- mulators, or secondary batteries, are dependent upon the employment of dynamo-machines for charging them, the electric energy being thus produced cheaply. Their use in this connec- tion will be alluded to in the next chapter, but it may be convenient to state here the amount of energy that can be thus stored electro-chemi- cally. The numerical relations between mecha- nical and electrical energy will be explained in the next chapter, and hence, without giving the intermediate steps, it may suffice to say that a fully-charged Plante cell can store about 11,000 foot-pounds of energy per pound of lead in the cell, and that a Faure cell can store nearly 13,000 foot-pounds in the same weight of lead. According to Sir W. Thomson a single Faure cell of the spiral form, weighing 165 Ibs., can store 2,000,000 foot-pounds of energy. Prof. Henry Morton, of the Stevens Institute of Technology, New York, in a report (dated February 17, 1883) upon the Faure-Selloii-Volckmar accumu- lators, states that this same quantity of 2,000,000 foot-pounds of energy, or one horse-power work- ing for one hour, can be stored in a cell of that kind which weighs only 80 Ibs., and that three cells, while standing fully charged for six- teen days, only lost by leakage 7 per cent, of 126 ENERGY TN NATURE. the energy contained in them. The latter part of this result the author can corroborate from his own experience of the working of these cells, under very trying conditions. CHAPTER V. MAGNETISM AND ELECTRICITY. BEFORE proceeding to the study of the very intimate relations existing between these two forms of Energy in Nature relations upon which all the applications of electricity to the purposes of practical life depend it will be well to con- sider briefly some of the elementary phenomena of, and some of the terms used in connection with, Magnetism. The force of attraction in this form of energy was first noticed many hundred years ago in certain hard black stones found in Magnesia in Asia Minor (whence the name mag- net), but afterwards in other parts of the world. This lodestone (i.e., leading-stone) as it was called, was afterwards shown to be a peculiar iron ore, a combination of iron and oxygen, and although it was at first thought that its attrac- tive influence was confined to iron and steel, further experiments (as in the case of electric attraction) showed that a large number of other substances were thus affected by it, though in a less degree. In the tenth or twelfth century it was noticed that such stones when hung up 128 ENERGY IN NATURE. by a thread pointed in definite directions, North and South, rapidly taking up that position again when disturbed from it, and shortly afterwards it was found that iron and steel, when rubbed in certain directions with a piece of lodestone, acquired these same properties. In 1600 Dr. Gilbert published the results of very careful ex- periments with magnets, adding greatly to the knowledge then existing. It is, however, per- haps scarcely necessary to say that even at the present day we are as ignorant of the nature of magnetism as we are of electricity none of these forms of energy are recognisable apart from matter, as has been already pointed out. There are strong reasons for believing that the phenomena of magnetism are in some way con- nected with the motion of the particles of those bodies, which, like iron, become magnetic ; that, in fact, it is another form of the molecular motion spoken of in Chaps. I. and II. On this view of the case, which has quite recently received strong support from experiments exhibited to the Royal Society by Prof. D. E. Hughes, the difference between the arrangement of the particles in a magnet and in an ordinary piece of steel or iron, might be likened to the difference in the packing arrangements of two boxes of eggs in the first (corresponding to the magnet) the eggs are carefully packed, lying side by side parallel to each other and to the sides of the MAGNETISM AND ELECTRICITY. 120 box, with their small ends all turned in the same direction, and therefore touching the larger end of the adjoining egg ; while in the second (ordi- nary iron or steel), badly packed, the separate eggs lie in all sorts of positions with regard to each other, and at all angles of inclination to the sides of the box. Another and quite different physical theory of magnetism will be alluded to later; but it may be noted with advantage in this connection that the magnetism of iron and steel is always materially lessened, and some- times entirely destroyed, by changing the mole- cular condition of the iron ; this may be done by subjecting a magnetic rod to a mechanical twist, or strain of any kind, or by heating it, all magnetism disappearing at a cherry-red heat. The influence of temperature upon magnetism is well seen in the case of manganese, which only becomes magnetic when cooled to below zero Fahr. If a bar-magnet, i.e., a straight piece of steel which has been magnetised, be carefully ex- amined, by holding the different parts of it near to a small nail suspended by a long thread (Fig. 47), it will be found that its attractive force is most strongly exerted by the two ends, to which the term poles is given. Moreover, if one pole be thrust into a heap of nails, and withdrawn again, it will be observed that not only do many nails adhere to the magnet itself, but that other j 130 ENERGY IN NATURE. nails adhere to them, and that quite a string of them may be thus drawn up ; if, however, the nails actually in contact with the magnet be removed from it, the attraction of the other nails for each other at once ceases. This shows that a FIG. 47. magnet is capable of inducing magnetism tem- porarily in other pieces of iron somewhat in the same manner as is observed in the case of elec- trified bodies (p. 90). Further, this attractive force between a magnet and iron is mutual, for if a magnet which is free to move be brought near to a fixed piece of iron, the latter will attract the magnet (Fig. 48). MAGNETISM AND ELECTRICITY. 131 It has been already stated that a bar-magnet, freely suspended by the middle of its length (either by a loop of string or on a point of support), will take up a definite position. If, now, another bar-magnet be brought near to one end (say that FIG. 48. pointing northwards) of it, the two ends of the second magnet will behave very differently to- wards it, and careful observation will show that when two poles of the same kind (/. 21-100W-8/84 U. C. BERKELEY LIBRARIES