REESE LIBRARY UNIVERSITY OF CALIFORNIA CRYSTALLOGRAPHY STORY-MA SKELYNE Bonbon HENRY FROWDE OXFORD UNIVERSITY PRESS WAREHOUSE AMEN CORNER, E.G. ({ten? MACMILLAN & CO., 66 FIFTH AVENUE CRYSTALLOGRAPHY A TREATISE ON THE MORPHOLOGY OF CRYSTALS BY N. STORY-MASKELYNE, M.A., F.R.S. PROFESSOR OF MINERALOGY, OXFORD HONORARY FELLOW OF WADHAM COLLEGE AT THE CLARENDON PRESS 1895 PRINTED AT THE CLARENDON PRESS BY HORACE HART, PRINTER TO THE UNIVERSITY PREFACE THE establishment of Crystallography as a science at the hands of Haiiy dates back a hundred years from the present time; and midway in that period (in 1839) Pro- fessor W. H. Miller published his now classical Treatise. The notation by index-symbols, the representation of the relative positions of crystal faces by the distribution of their ' poles ' on a sphere, xhe stereographic projection of the sphere and of the poles lying upon it, and some of the methods that Miller employed in dealing with the symbols of crystal faces, may indeed be shown to have been introduced in various memoirs by earlier geometers. Thus Bernhardi (1809), Neumann (1823), Frankenheim (1826), and Grassmann (1829) had all represented crystal faces by their normals ; the three latter had projected the poles of faces and of zones on the great circles of a sphere : Neumann further represented a face by a symbol that was a first approximation to the simple form suggested by Whewell (1824-5) an d afterwards by Justus G. Grassmann (1829) before it became in the hands of Miller an effective implement by which to rear the structure of modern Crystallography. Dr. Whewell, Miller's immediate predecessor in the Cambridge Chair, had indicated the method of deriving the symbol of a face from those of two other faces truncated by it. But, after the labours of previous crystallographic writers vi Preface. have been thus recognised, the methods and systematic treatment of Crystallography in Miller's Treatise remain indisputably his own. The rationality of the anharmonic ratio of any four tautozonal planes was his, independently of a similar result afterwards published in the memoirs of Gauss ; and to him belongs the merit of combining the methods of his predecessors with the stereographic pro- jection into a complete and elegant system, in which the power of the indicial symbols in grouping the faces of the forms of crystals, and in colligating tautozonal faces as well as tautohedral zones, was manifested, and the foundation laid on which the laws of crystal symmetry have been well established. The system thus identified with the name of Miller has met at length with an almost universal acceptance. Adopted forty years ago in Vienna by the school of crystallographic physicists in which Grailich and V. von Lang were pioneers, it has in recent times formed the crystallographic language employed in such complete trea- tises as those of Liebisch and of Mallard, in the encyclo- paedic Mineralogy of Dana, and in that great storehouse of crystallographic information, the Zeitschrift of Groth. The growth of Crystallography during the last sixty years has resulted, notably, from the recognition of the limitations imposed on its symmetry by the homogeneity of a crystal. By various methods, Hessel in 1829, Bravais, von Lang, and Gadolin in 18667, and, among later investigators, more especially Sohncke, Schonflies and Fedorow, have defined the varieties of symmetry which can be presented by crystals. The present Treatise, dealing solely with the Morpho- logy of crystals, represents the substance of courses of Preface. vii lectures in which it was often found necessary to treat Crystallography in the simplest form compatible with strict geometrical methods ; the classes, in such cases, consisting of students from other departments of science in which familiarity with mathematics was not demanded. On other occasions students of physics with high mathematical training formed the class. I trust that, while endeavouring to fulfil the requirements of readers of the former kind, this book will not be found lacking in demonstrations that may satisfy those of the latter class, for whom indeed it may be said to commence at Article 53, p. 65. Several chapters, those for instance on Symmetry, are written with more detail than a geo- metrical student might recognise as needed ; but this seemed unavoidable if the usefulness of the book was not to be confined to such readers. Among my old students there have been some who have taken a great interest in the subject and in my book : to their relations towards it and towards myself I may only advert here in a few too inadequate words. To a remoter time belongs Professor Lewis, formerly my colleague at the British Museum, and now Professor Miller's successor in the Mineralogical Chair at Cambridge. More especially are my cordial thanks due to the friend who succeeded me in the Keepership of the Mineral Department of the British Museum, Mr. L. Fletcher, for numerous and valuable suggestions and additions to the original MS. and to the proofs which he has so carefully revised. To Mr. Miers' skilful hand I am indebted for numerous figures, the drawing of which I found, with failing eyesight, to be increasingly difficult. viii Preface. Various features that I have adopted from the remark- able Treatise (1866) of my old friend Viktor von Lang, formerly, for a time, my colleague at the British Museum, justify my numbering the distinguished Vienna Professor among those to whom I am as much indebted for the matter of my book as I am for their sustained friendship. It is intended in a future volume to deal with the physical problems necessary to the practical crystallo- grapher. It being my purpose in that as in the present work to bring crystallography into more familiar use by students of chemistry, mineralogy, and petrology, it was necessary that the treatment of the subject should not demand the advanced mathematics needed for reading parts of the master-work of Liebitsch. That the principles of crystallographic optics can be thus treated without the surrender of exact geometrical method is evidenced by Mr. Fletcher's Tract on the Optical Indicatrix ; and there are other parts of crystallographic physics capable of being represented with a like simplicity. The greater part of the present Treatise was long ago written, and indeed in print ; and for the delay in its publi- cation its author is alone responsible. The causes have been numerous, partly arising from the distractions of other unavoidable and not unimportant duties, but mainly from a certain indecision habitual to the workman, who has felt how ' easy it is to begin but to finish how difficult.' For the acknowledgement of the longsuffering and kindly treatment he has experienced at the hands of that unique institution, the University Press, he has not words. N. S.-M. CONTENTS CHAPTER I. ON THE GENERAL PROPERTIES OF CRYSTALS. PACK The crystalline condition i Morphological characters 3 Physical characters 5 CHAPTER II. MODES OF EXPRESSING AND REPRESENTING THE RELATIONS BETWEEN THE PLANES OF A SYSTEM. Elementary considerations as to the methcds of estimating the mutual inclinations of the planes of a system 15 Expression for the direction of the edge formed by two planes . . 22 A crystalloid system. Principle of rationality of indices . . . 25 On the sphere of projection, and the principles of its stereographic representation 27 Expressions for determining the position of a pole on the sphere . . 41 CHAPTER III. ON ZONES AND THEIR PROPERTIES. Expressions for a zone 44 Relations connecting three tautozonal planes ..... 46 On t-he signs of the indices of a plane as determined by the position of the plane in respect to a given zone . . . . . . 51 x Contents. PACK Relations connecting four tautozonal planes . . . . . 55 Analytical investigation of the zone-law ...... 65 On isogonal zones 75 CHAPTER IV. THEOREMS RELATING TO THE AXES AND PARAMETERS OF A CRYSTALLOID SYSTEM. On changing the axial system to which a crystalloid plane-system is referred . So The axes of a crystalloid system are necessarily origin-edges or face- normals ........... 91 CHAPTER V. ON THE VARIETIES OF SYMMETRY POSSIBLE IN A CRYSTALLOID SYSTEM OF PLANES. Application of the principles of geometrical symmetry to crystals and crystalloid plane-systems . 97 Conditions for a crystalloid system of planes to be symmetrical to one of its planes 106 Conditions involved in a crystalloid polyhedron being symmetrical to more than one of its planes 109 The type of symmetry in which = . . . . . . 121 The type of symmetry in which < = . . . . . . 126 4 The type of symmetry in which = 1 30 Q The type of symmetry in which

- 134 Three heterozonal planes of congruent symmetry 144 General discussion of the systematic triangle . . . . . 149 CHAPTER VI. CRYSTALS AS CRYSTALLOID POLYHEDRA. Mero-symmetry 156 On composite- and twin-crystals 172 Contents. xi CHAPTER VII. THE SYSTEMS. PACK The Cubic (or Tesseral) System 188 Holo-symmetrical forms ........ 188 Mero-symmetrical forms 204 Combinations of forms 219 Twinned forms 232 The Tetragonal System 245 Holo-symmetrical forms . . 245 Mero-symmetrical forms . . . . . . . . 252 Combinations of forms ........ 264 Twinned forms . 268 The Hexagonal System 273 Holo-symmetrical forms . . 273 Mero-symmetrical forms 283 Combinations of forms ........ 309 Twinned forms ..... ..... 318 The Ortho-rhombic System . ........ 331 Holo-symmetrical forms 331 Mero symmetrical forms 336 Combinations of forms 339 Twinned forms 345 The Mono-symmetric (or Clino-rhombic) System . . . . 352 Holo-symmetrical forms 352 Mero-symmetrical forms ........ 358 Combinations of forms 360 Twinned forms 364 The Anorthic System . 370 Holo-symmetricai forms 370 Mero-symmetrical forms 373 Combinations of forms 3/3 Twinned forms .......... 375 CHAPTER VIII. THE MEASUREMENT AND CALCULATION OF THE ANGLES OF CRYSTALS. The goniometer 388 Crystallographic calculation 417 xii Contents. PAGE The Oblique Systems 427 The Anorthic System ..... .427 The Mono-symmetric System ..... 436 The Rectangular-axed Systems 441 The Ortho-rhombic System ........ 446 The Tetragonal System ........ 448 The Cubic System 453 The Hexagonal System ....... .463 CHAPTER IX. THE REPRESENTATION OF CRYSTALS. Parallel projection ....... 474 Orthogonal projection 475 Gnomonic projection .......... 492 Description of the Plates INDEX CRYSTALLOGRAPHY. CHAPTER I. ON THE GENERAL PROPERTIES OF CRYSTALS. 1. The Crystalline Condition. Most substances, whether chemical elements or compounds, assume the crystalline condition when they become solid under circumstances favourable to the gradual and unconstrained deposi- tion of their particles. Under conditions conducive to the growth of separate individuals, crystals are polyhedra with plane faces and without re-entrant angles. The processes by which substances pass into the crystalline condition belong generally to one or other of the following classes : (a). From sublimation : in this case the substance passes directly from the gaseous to the solid condition. Iodine, arsenic and camphor are familiar examples of crystal- lisation from sublimation. (&). From fusion : when the substance passes directly from the liquid to the solid condition. Both bismuth and sulphur afford examples of crystallisation from a fused mass during cooling ; and water, on freezing, assumes the crystalline condition, though the individual crystals of ice are in general difficult to distinguish. (c). From solution-, the deposition of crystals may result from 2 On the general properties diminution of the solvent capacity of a liquid holding the substance in solution : and this may arise from change of temperature, or of osmotic pressure ; or from removal, by evaporation or otherwise, of the solvent liquid ; or, again, from that liquid losing an ingre- dient that imparts to it higher solvent power, or receiving a fresh ingredient that diminishes that power. These various methods of crystallisation from solution are uni- versally employed in the processes of the laboratory, and, on a larger scale, in the operations of technical chemistry. (d}. By change in the solid condition. It sometimes happens that a substance passes from a non-crystalline to a crystalline condition, or from one crystalline type to another, without passing through the liquid or gaseous state. Non-crystalline (vitreous) arsenious anhydride in lapse of time developes octahedral crystals ; again, the transition of (tetragonal) crystals of the red mercuric iodide into those of the yellow (ortho- rhombic) type, and the reconversion from the latter type into the former, as the temperature is successively above and below i26C., is a familiar example of a numerous class of changes. Of such transformations the remarkable optical researches of Mallard and others have contributed illustrations; prominent among these are the passage of boracite at a temperature of 265 C., and of leucite at about 500 C., in each case from a pseudo-cubic symmetrically grouped aggregate of crystals (orthorhombic in the case of boracite) to a single crystal of cubic type, and the reconstruction of aggre- gates of pseudo-cubic type below .those temperatures (see Article 166, p. 187). Further, under any of the preceding processes, new compounds produced as a result of the mutual decomposition of two or more substances may assume the crystalline condition. Many of the largest and finest crystals met with among minerals have resulted from natural processes involving mutual decompo- sition, and numerous illustrations of artificial processes of the same character are afforded by the microscopic crystals produced in the course of micro-chemical analysis. 2. The characters of crystals may be referred to two different classes : of crystals, 3 I. Morphological characters, which result from the distribution and geometrical relations of their plane faces ; II. Physical characters, which result from their homogeneity and the distribution of the physical properties. 3. I. Morphological Characters. Conclusions drawn from observations on numerous crystals of one and the same substance are the following : On any individual crystal, faces presenting similar physical characteristics, superficially exemplified in the lustre, striation, hardness, c., of their surfaces, may usually be recognised as recurring on different parts of the crystal, and, indeed, recurring in a certain ordered and symmetrical arrangement. In general the faces of a crystal are not all alike either in form or in the characters of their surfaces ; they exhibit lustre that may vary from an ada- mantine or a metallic brilliance, through a glassy or a nacreous reflection, to a dulness that reflects no image : or, again, a striation, that in some cases consists of a fine linear tracing, in others of a coarse channelling of the surface ; the direction of striation being generally parallel to certain edges of the crystal. All the faces of the crystal fall into one or into several such groups or forms ; each form comprising the symmetrically recurring faces characterised by similar features and properties. 4. Crystallographic law. All the faces belonging to any one crystal are connected by certain geometrical relations which obey a simple law known as the Law of Rationality of Indices. Different crystals of the same substance may present an indefinite variety in their forms and combinations of forms : such crystals may even have no form in common, and therefore no faces that are directly comparable with each other. Yet, by virtue of the law just mentioned, it is practicable to determine from any one crystal of a substance all the faces that may possibly occur on the same or different crystals of that particular substance, and to establish a system of planes that shall be characteristic of it. By reference to this system of planes, it is possible to establish the morphological relationship of all crystals of the same substance, whatever faces they may exhibit. The faces of crystals of a given substance, even when they belong B 2 4 On the general properties to the same form upon the same crystal, are usually found to differ in size ; but while they obey no law as regards their relative mag- nitude, the mutual inclination of every pair is the same as that of every corresponding pair, whether of the same or different crystals of the given substance, at the same temperature. 5. Crystallographic systems. Whereas the different forms upon crystals of the same substance differ not only in the mutual inclina- tions of their faces, but also in other characteristics, such as lustre, striation, &c., they will all be found to conform to the same type of symmetry. Further, while in all crystals of the same substance the morpho- logical features are distributed in accordance with one type of orderly arrangement or symmetry, it will be hereafter shown that there can be six and only six such types of symmetry to one or other of which every crystal whatsoever can be referred. These are termed the crystallographic systems and are distin- guished as: I. The Cubic system. II. The Tetragonal system. III. The Hexagonal system. IV. The Ortho-rhombic system. V. The Mono-symmetric (or C lino-rhombic) system. VI. The Anorthic system. 6. Crystallographic elements. The geometrical relations connect- ing the faces of a given substance are expressed by means of certain constants termed the crystallographic elements, and, from what has been said in Article 4, it follows that these are characteristic of the particular substance. The crystallographic elements, and, as follow- ing from them, the essential morphological characters of a crystal, thus depend, not on the relative dimensions of its faces or lengths of its edges, but on the relative directions of both, and therefore on the dihedral angles of the latter. While the crystallographic elements of an individual substance are thus the same at a given temperature for all the crystals of that substance, those of the different substances which crystallise in any one of the systems present indefinite variety. Crystals of the Cubic system are an exception to this statement ; for the crystallographic of crystals. 5 elements in this system are the same for all, so that analogous forms have identical angles on such crystals. A like constancy of angle attaches also to certain forms on crystals of the Tetra- gonal and Hexagonal systems : the faces of such forms are parallel to a particular direction, termed the morphological axis, peculiar to such crystals, around which, either singly or in pairs, they are symmetrically repeated in quadruple, sextuple, or triple recurrence. 7. II. Physical Characters. Crystals are further distinguished from other matter in that while the physical characters of ordinary uncrystallised matter are generally the same, in crystals they are different, in different directions. At the same time it is generally true that the properties characteristic of any given direction in a crystal are found to characterise also other directions in it. But the different directions thus similarly endowed, which may be considered as if they were repetitions of the first direction, will be found to be repeated sym- metrically and in general accordance with the principle of symmetry that controls the repetitions of the morphological features on the crystal. A brief review of some of the distinctive physical properties that characterise crystals will serve to illustrate the above principle. 8. Elasticity and cohesion. (a). The discussion of the conditions of elasticity in crystals involves very complicated mathematical expressions. In the most general case the determination of the stress requisite to produce a given homogeneous strain involves as many as twenty-one inde- pendent constants termed coefficients of elasticity : the constants, however, become reduced as the symmetry of the crystal assumes a higher type, and are reduced to three in the case of a cubic crystal. In terms of these constants the coefficients of elasticity of volume and the coefficients of elasticity of figure, or the rigidity, can be ex- pressed. It is found that directions which correspond in their morpho- logical relations are endowed with the same characters as regards elasticity. (). When a solid body is acted upon by forces which produce deformation it may behave in one of various ways. 6 On the general properties The deformation may be permanent or it may be only tem- porary : if it be wholly or in part permanent, the original arrange- ment of the particles is not restored when the stresses to which the strain was due have ceased to operate ; a ductile body, for example, undergoing a permanent elongation under a tensile stress ; a malle- able body admitting of entire change of form by successive impacts from a hammer or the continuous pressure of a roller, in both cases without disruption. It is obvious that though a crystal may possess such qualities, the exercise of them is incompatible with its particles retaining their crystalline arrangement. (c\ Glide-planes. Certain remarkable changes, however, involving permanent deformation in a crystal without disruption have been effected by pressure at the edges or quoins (solid angles). Fig. i. A simple mode of producing such a deformation in a cleavage- rhombohedron of Iceland spar is one first suggested by Baumhauer. Three edges of the rhombohedron meet on the morphological axis at an apex where the three plane angles are each obtuse, being 109 8' 12". If a knife-blade represented by the plane bgg f be applied at a point c' not very far from that apex, with its faces perpendicular to one of the edges e, and be subjected to a steady pressure or a slight blow, a wedge-shaped fissure c'gg'k is readily formed, and the portion of the crystal between the blade and the original face r of the rhombohedron is moved to a new position. of crystals. 7 A plane parallel to the edge is not lettered in the figure. The angles at which the axes are inclined on each other will be designated the angle YOZ or YZ as ,, ZOX or ZX as 77, XOY or XY as ' Each plane of the system must, if produced, intersect one and may intersect two or three of the axes. The length along any axis intercepted between the origin and the point in which a Fig. 2. System of plane-normals. 1 7 plane of the system is met by that axis is the intercept of the plane on that axis. If several planes be supposed parallel to each other, their inter- cepts on the several axes will only differ by a common factor : where this factor is negative, the planes lie in opposite octants or on opposite sides of the origin, being represented by opposite signs. Where two or more planes are not parallel to each other, they must differ either in the relative magnitudes of their intercepts on one or more of the axes, or in the signs of these, or in both of these respects. 16. Normals to Planes. If a perpendicular from the origin be drawn to any plane of the system which must be supposed to be extended if necessary for the perpendicular to meet it, then the direction in space of this plane and of any planes parallel to it is known when the direction of this perpendicular is determined in reference to the axes. A perpendicular so drawn through the origin to a plane is called the centro-normal, or briefly the normal, of that plane. In this treatise the relative positions of planes will be represented by expressions denoting the relative positions of their normals, and normals will therefore be supposed to be drawn to all the planes of the system. We proceed to discuss the mode in which the relative positions of planes can be thus simply represented. 17. If a plane P cut the axes X, Y, Z in the points A, B, C, and for simplicity be supposed to lie in the first octant ; i. e. to intersect with all three axes belonging to that octant ; and if the intercepts of the plane be OA = a, OB = b, OC c, and if OP (Fig. 3) be the normal of the plane ABC\ then OP cosPX, i.e. cosPOA ^\ OA cosPr=^, and C osPZ~. Whence OP a cos PX = b cos PF = c cos PZ, expressions which give the direction of OP and of the plane to which it is the normal, whatever be the distance of that plane from the origin: C i8 Position of a plane. this direction being thus represented by the direction cosines of the normal OP expressed in terms involving the intercepts of the plane P. Let now a second plane Q inclined to the first plane and lying also for convenience in the first octant intersect the axes X, Y, Z in the points H, K, L respectively ; then the intercepts OH, OK, OL of this plane may be expressed by values involving those of Fig. 3- the intercepts of the plane P ; as for instance by taking factors h, k, and /, such that OH = \OA=^ OK=~OB = L OL = OC = j. h h k k II And, if OQ be the normal of the plane Q, OQ = Otfcos QX, = ^cosQX= -cosQr=- 7 Similarly, QZ t (A) CL J) C ~p^ ~ q C( ~r would indicate the direction of a third plane R of the system, the intercepts of which would be in the ratios : - : - on the p q r several axes taken in the order X, F, Z. Parameters Symbols. 19 18. The ratios a : b : c of the intercepts of some one plane chosen as a standard or parametral plane are termed the para- metral ratios or parameters of the system as referred to the axes X, Y, Z, and these ratios are evidently two in number. The literal symbols hkl, pqr, &c., or any numbers in the ratios of hkl, &c., and generally the simplest numbers which represent these ratios, are termed the indices of the planes Q, R, &c. The indices of a plane placed between brackets, e.g. (hkl}, (pqr], (321), &c., &c., form a compact symbol, which is the symbol of the plane. The parametral plane P evidently has for its symbol (i 1 1), since a b c its intercepts are - : - : - iii N. B. The brackets are in practice frequently omitted where the use of the unbracketed symbol may involve no ambiguity. In the cases so far considered the planes in question were supposed to lie in the positive octant, i. e. to intersect, either actually or if extended, the three positive axes. If however a plane will intersect two only of the axes, it cannot but be parallel to the third. Its intercept then on this last axis will be indefinitely great, as its point of intersection with it is infinitely remote. The index for the particular axis will thus become zero ; AO a since, for instance, an intercept , i.e. , is infinitely great. Hence (hko), (p OM' OD i i UG~"OL OM' OD OQ i 6* (> and OHOKOP OKOROL OM' OD OH.OQ OK. OP OK. OR OL.OQ and, by the symmetry of the problem, OK OL.OP OH. OR Here ^ = \ , &c. ; TST-f* r r * J kq kp Therefore mcrcraA-ap = ^' &c., &c., = &c. Substituting these values in the ratios and dividing by the com- mon factor obey we obtain OD OK OM' a(kr-lq) ~ b(lp-hr) ~ c(hq-kpY which expression gives the ratios of the coordinates of any point in a line through the origin parallel to the edge of the planes hkl and/^r, in terms of the indices of the two planes. These ratios a(kr-lq) t b(lp-hr\ c(hq-kp) A crystalloid plane-system. 25 may be written briefly as an, dv, -w, if u = kr lq, v = Ip hr, w = hq kp. DEF. A plane parallel to any plane of a system but passing through the origin will be termed an origin-plane, and any line through the origin parallel to an edge of two planes of the system will be termed an origin-edge, and hereafter a zone-line or zone- axis ; and in speaking of the planes of a plane-system the term 'face' will be more particularly applied to them when considered as the faces that bound a polyhedron. SECTION III. A Crystalloid System. Principle of Rationality of Indices. 21. In considering the general character of the expressions for the relations of the planes in a system as referred to axes of coordinates, the indices of a plane were not limited to any special kind of values, integral or fractional, rational or irrational, and the axial system might be arbitrarily chosen. If however the nature of the system of planes be limited by the condition that for a plane to belong to the system its indices must be rational, that is to say, capable of being represented by integral numbers, or one or two of them by zero, it will be obvious that some limita- tion must also be imposed on the selection of the axes to which the planes are referred. 22. It will be shown in Art. 75 that the axes must, in the case supposed, be themselves possible zone-lines of the system. A special case, confined to a single zone, will however serve here to illustrate this important principle. Let us suppose that OX, OZ are axes arbitrarily taken to which two planes are referred, that may for convenience be prismatoid planes, cutting only these two axes, and parallel to the third. Let the lines AC, AL be the intersections of these planes with the axial plane XOZ, which is that of the figure ; let OA = a, OC = c be the intercepts on X and Z of one of the planes ; and let a and c 26 A crystalloid axial system. be taken as the parameters : and of the other plane let OA and OL = - c be the intercepts. Then - is the index on Z of the plane AL, and if the ratio of OC to OL be capable of being expressed by whole numbers, is rational. If we arbitrarily choose another axis OZ f elsewhere in the plane XOZ, and take OC' and OL' as the intercepts on that axis of the two planes j it is evident that the ratio of these will vary with the direction of OZ' and is not necessarily rational. Wherefore the axial system may not be arbitrarily chosen in the case of a sys- tem of planes of which the indices are rational. If, again, we change the axial system in such a manner that C becomes the origin and CA, CO the new axes; and if AO and AL be the lines of inter- section of two planes with the axial Fig. 8. plane CO A ; then CA and CO, the intercepts of the plane OX, may be taken as parameters for the system ; and the intercepts of the other plane on the new axes are CA = a', and CL = *^.<:, so that its indices in respect to these axes are / h and /, and are obviously rational. Hence, in the special case supposed, any planes, the origin- edges of which form axes to which it is possible to refer a system of planes with rational indices, must themselves fulfil the con- dition required for all planes of the system. 23. By the term a crystalloid system of planes we shall under- stand an assemblage of planes parallel to the faces of a poly- hedron finite in number and presenting such mutual inclinations that if they be referred to an axial system formed by three different origin-edges parallel to edges of the system, and with parametral Projection of poles on a sphere. 27 ratios determined by the intercepts of any plane of the system, it shall be a necessary condition in order for a plane to belong to the system that its indices be rational. An axial system with axes and parameters so chosen will be termed a crystallographic axial system. The elements of such an axial system are five in number ; viz. the three axial angles f, 77, and f, and the two parametral ratios a c T anc * T ' b b SECTION IV. On the Sphere of Projection, and the principles of its Stereographic Representation. 24. A convenient means of representing and comparing the relations of a system of planes forming a polyhedron is afforded by treating their normals as radii of a sphere. A sphere of arbitrary radius termed the Sphere of Projection is supposed to be described round any point within the system taken as its centre and as the origin of a system of centre-normals, or briefly of normals, perpendicular to the faces of the polyhedron. The point in which any such normal meets the sphere is termed the pole of the plane to which the particular normal is perpendicular. A pole may therefore also be defined as the point of contact of the sphere and a tangent-plane parallel to a plane of the system on the same side of the origin with the plane. Where the system of planes is also referred to an axial system, with the centre of the sphere for its origin, the point in which an axis penetrates the surface of the sphere will be called its axial point. It is evident that if the poles of planes be connected by great circles, their distances and relative positions, and therefore the inclinations and relations of the planes themselves, may be measured and investigated by the methods of spherical trigonometry : for in the plane of the great circle, thus connecting the poles of any two planes, the normals of these planes must lie ; and the arc between their poles as measured on a great circle is that subtended by the angle contained by the normals, and is therefore the supplement of the angle of inclination of the planes themselves. 28 Stereographic projection. Another great advantage of this method of representing the positions of all the planes of a system by points distributed on a sphere is, that by a simple process of laying down such points in a projection of the sphere upon a plane we do not need the somewhat elaborate process of drawing a crystal by projecting its edges, in order to give a complete con- spectus of all that crystallography seeks to represent; that is to say, of the general symmetry of the poly- hedron and the dis- tribution and relative inclinations of all its faces. Fig. 9 repre- sents in orthographic projection the faces and the poles of the cubo-octahedron, i.e. of.. the two regular solids the cube and octahedron united into a single figure in which the faces of the one figure truncate the solid angles (or quoins) of the other figure. Fig. 10 represents the poles of the same faces and the great circles passing through those poles in what is termed the Stereographic projection. In the former case, which is that usually employed for the projection of the edges of crystals in crystallographic figures, the eye is at an indefinitely great distance (the crystal being seen as if Fig. 9. Plane of projection. 29 from a considerable distance through a telescope) ; the visual rays being parallel, and as a consequence all lines parallel in the ob- ject remaining parallel in the figure that represents it. The representation of the faces of a polyhedron by the stereographic projection of its poles has the great advantage over a drawing that it does not aim at representing the relative magni- tudes of the faces ; while also by this method the poles of any number of planes may be laid down at their correct angular distances with speed and accuracy, whereas the number of faces admitting of representation in a drawing is necessarily limited. Furthermore, crystallographic problems may often be solved and calculation greatly simplified by its means. 25. In the Stereographic Projection, which is the simplest form of projection of a sphere with the above view (Fig. 10), the eye is supposed to be at a point of the sphere's surface and to see such poles or great circles as are distributed on the hemisphere opposite to it projected (as on a screen) upon a plane passing through the centre of the sphere and cutting the sphere in the great circle at the pole of which the eye is situate. The plane of projection thus bounded by a great circle of the sphere is represented by the plane of the paper on which the circle is drawn, which latter will be termed the circle of projection or primitive circle. The advantage of this over other forms of pro- jection of the sphere is that any great or small circles of the sphere on the hemisphere opposite to the eye are by it projected either as straight lines or as circular and not as elliptical arcs, and thus, by means of a protractor and com- passes, all the great circles can be laid down on which the poles of planes are distributed. That this is the case follows at once from the properties of the ob- lique cone ; but it may be otherwise proved thus : suppose S, Fig. n, to be the point of sight on a sphere of which is the centre and OS therefore the radius. Let PP' 30 Stereographic projection. represent the plane of projection. The circle of projection will then be a great circle of which S, the position of the eye, is one of the poles. The apparent position on the plane of pro- jection of any point A on the sphere as seen by the eye at will evidently be that point in which a straight line drawn from to A meets the plane PP f . Thus the centre O of the circle of projection will be the point at which T, the pole of that circle opposite to S, will be projected. So the arc FTP' on the opposite hemisphere will be seen from S as a straight line coincident with PP', and any great circle passing through T will be projected as a diameter of the circle of projection ; such great circles or parts of them are therefore projected as straight lines. Thus a portion AB of the arc PTP' will be seen as db, a portion of PP' limited by the points a and b, which are the projections of the points A and B. It will further be seen that while all points on the hemisphere opposite to the eye will be projected in points within the circle of projection, the projections of points lying on the same hemisphere with S will lie beyond the circumference of that limiting circle. 26. We proceed to establish further that an arc of any circle on the sphere not passing through the point of sight is projected as a circular arc. Let ADB be a circular section of the sphere, for convenience a section by a small circle; and let Fig. 12 represent a section through S and also through any two points A and B on this small circle. Let PP' be the trace of the plane of projection ; a, b the points in which lines SA and SB cut PP' ; they are therefore the projections of A and B. Draw a tangent LS. Then Therefore the four points A, B, b, a lie on a circle. Now A and B in the section ABS being any points on the Projections of circles. 31 small circle, the locus of db must be the section by the plane of projection of any surface containing all such circles as have been proved to contain any two points and their projections. That there is such a surface and that it is a sphere, and that consequently the projection adb of the circle ADB is itself a circle, will be evident from the following considerations. Erect a perpendicular to the plane of the circle ADB from its centre; then every point in the circle is equidistant from any point in this perpendicular ; and a sphere described round such a point C taken at equal distance from B and b will carry on its surface all the four points A, B, D, b. And d, the projection of any other point D on the original circle, will also lie on the surface of this sphere. For if it do not, it will lie somewhere else in the line SD, as at a point 8. But, as in the case of the projections a, b of the points A and B, we have proved baS = ABS] whence, by comparison of the triangles baS and ABS, we obtain the reciprocal proportion Sa . SA = Sb . SB. Similarly, we should obtain for the points A, D, a, 8 Sa.SA = S&. SD. But also, as SD must cut the described sphere somewhere, as in a point*/, Sa.SA = Sd.SD is also true, which can only be possible if d and 8 are one and the same point. And this point is therefore at once the projection of D and situate on the surface of the described sphere. The locus of ab is therefore, as asserted, the section by the plane of projection of the described sphere ; that is to say, is a circle. 27. The proof applies equally to the section of the sphere by a great circle : it may also be thus illustrated. Let AB, Fig. 13, be a great circle intersecting with the plane of projection, of which the trace is PP f t in a line perpendicular at to the plane of the figure ; which plane passes in this case through the centre of the sphere as well as through S. From S draw a perpendicular to the plane AB meeting the plane of projection in C, and draw SA through a the projection of A, and Sb through Stereographic projection. B to meet the plane of projection produced in b which will be the projection of B : then these lines will necessarily lie in the plane of the figure. As in the previous case, Sab = SBA, whence Aab = bBA, and the four points A,a,B,b lie on a circle ; and it will follow, as in the previous case, that every point of the great circle AB will lie in the circular section in which the plane of projection will cut a sphere that shall be so described as to carry on its surface the four points A, a, B,b. Fig. 13. COR. 1. The centre of the circle in which the original great circle is projected will be C, the point in which the perpendicular from -S" on the plane of AB meets the plane of projection ; for, since SAB = SbC = CSb, Ca=.CS=Cb; and since aSbT lie on the same circle of which C is the centre, two points in which the circle of projection is cut by the plane through -S 1 and perpendicular to the plane of projection will be the points of intersection of the circle of projection and the circular arc in which that circle, whose trace is A and B, is projected. COR. 2. Since ASb is a right angle, b may be at once obtained by drawing Sb perpendicular to AS and meeting the continuation ofPP'ml,. For the practical applications of the Stereographic Projection, of which continual use will be made in this treatise, the following propositions will be found necessary. To measure a projected arc. 33 28. PROBLEM I. To determine the magnitude of the arc of a great circle which is represented by the projection of that arc. Let V and C be two great circles, Fig. 14, which intersect in the extremities of the diameter AA' of the sphere of projection, and let their poles be P and S. Now, every circle on the sphere, whether great or small, passing through the points P and S e.g. the great circle U or the small circle U' will manifestly cut in a similar manner the two circles V and C; and more- over, any two circles on the sphere thus passing through the poles of two great circles on it must intercept on these two great circles arcs of the same magnitude; whence it is evident that the arcs intercepted on the great circles V and C by the two circles U and U', or those intercepted by U or U' ', and by a third plane, say U", passing through A, must be equal ; so that A Q = AR, A (/= AR', (?(/= RR', if Q, R be the points of intersection of a circle U with the great circles C and V, and (/, R' be those in which these great circles are intersected by the circle U'. If now the plane of the great circle C be taken for the plane of projection, S being the position of the eye, every circle U (U f , U", &c.), whether great or small, will be projected as a straight line passing through p the projection of P. Indeed, Fig. 14. 34 Stereographic projection. since every such circle U lies in a plane passing through P, S, and a point R (or 7?') on the great circle V, straight lines drawn from S to points on the circumference of the circle U can only intersect with C in points upon a straight line passing through />, which is at once the projection of the circle U upon, and the intersection of its plane with, the plane C. Consequently, while the great circle V will be projected in the circular arc ArA', every one of the circles U t U', &c. passing through the points R, R', &c. will be projected in a straight line pQ) (pfft) & c -> which will further cut ArA', the projection of the circle V, in a point r, (r f , &c.) which will be the projection of the point R (or of R', &c.) ; r (or /, &c.) being in fact the point in which the planes of three great circles V t U (or U', &c.) and C intersect with each other. It is thus that straight lines drawn from p, the projection of the pole of the great circle V, through r and r' to the circumference of the circle of projection (which straight lines are the projections of two circles U, only one of which can be a great circle,) come to intercept on this primitive circle an arc QQ' ; and this arc QQ'= RR', the arc of which r/ is the projection, and QQ there- fore measures the arc represented by r/. Whence follows the rule : To determine the value of any arc of a great circle as represented in projection, find the projection of the pole of this great circle (which may be done by the succeeding problem) ; then i. The value of an arc of which the projection is given may be measured by determining on the circle of projection the arc con- tained between two straight lines drawn from the projection of the pole through the extremities of the projected arc, Fig. 15; and, 2. An arc of a great circle of given magnitude is represented in the projection of that circle by the portion of the projection Pole of a great circle projected. 35 determined by the intersection with it of two straight lines drawn from the projected pole to the circle of projection and intercepting on that circle an arc of the required magnitude. If the point in which one of the straight lines intersects with the projection of the great circle be fixed (i.e. is the projection of a given point on the great circle), then the other extremity of the projection of the required arc will alone have to be deter- mined by the latter of the two methods. COR. If the plane of a great circle, of which the projection is given, be perpendicular to the plane of projection, the great circle passes through S, the point of sight, and its projection becomes (by Art. 26) a diameter of the circle of projection C ; and the pole of the great circle will lie on the circle C, at the point of intersec- tion with it of a diameter perpendicular to that in which the great circle is projected. And this pole and its projection manifestly coincide. Hence arcs intercepted on the circle of projection by straight lines drawn from this pole through the diametral line in which the great circle is projected, will determine on that diameter the pro- jection of an arc of any required angular magnitude. PROBLEM II. Given the projection of a great circle, to find that of its pole. 29. Let Diy, Fig. 16, be the diameter in which the given projection, and consequently also the original great circle, intersect with the circle of projection. Since the pole required will ne- cessarily lie on the diameter per- pendicular to that in which the given projected circle intersects with the circle of projection, and must lie at a distance equivalent to a quadrant on that diameter from the point in which the given circular projection intersects with it ; let V be the point of this intersection, V that in which a D 2 Stereographic projection. line D V produced meets the circle of projection. Then, by COR. PROB. I, if V'P* be a quadrant, and a line DP' cut the diameter through V and O in P, VP would be the projection of V'P* on the line VP as seen from Z>; and since a similar construction would hold good were the great circle AD'P' to be drawn perpen- dicular to the plane of the figure, so as to be seen as A OP and to pass through S the point of sight, and since the true pole of V will lie on this great circle, the point P will be the projection of that pole. PROBLEM III. To draw the projection of a great circle, in which projection two points are given, that do not loth lie on the circle of projection. 30. Since only one great circle can pass through two points on the sphere not extremities of a diameter, the centre of the sphere and two such points suffice to determine the direction of the plane, of such a great circle. Hence the projections of two points and the centre of the sphere being given on the plane of projection, it should be possible to describe the circle which is the projection of the great circle on which the two points lie. The most convenient way of doing this is to find the projection of the point on the great circle which is the op- posite extremity of the diameter on which one of the points lies of which the projection is given. Thus, if two points on a great circle V are pro- jected in the points P and Q, Fig. 17 both of which do not lie on the circle of projection Fig. 17. DAI/ and if it be re- quired to draw V t the projection of V, it is necessary to find the projection of a third point in the circle V'\ and the point diametrically opposite to either A great circle projected. 3 7 of the points P and Q is convenient for this purpose. If then we would project in P', the point diametrically opposite to that point of which P is the projection (and it is preferable for this purpose to select the more remote from the centre of the two projected points P and Q), we have to draw through the remoter point P a diameter of the circle of projection ; and, where P does not lie on the circle of projection, from 0, the centre of that circle, a per- pendicular on PO is drawn to a point A in the circle of pro- jection. A therefore is the projection of the pole of the great circle which is projected in the diameter through P ; and P' will lie on the line PO at a distance equivalent in the projection to an arc TT from P. From A draw a perpendicular to AP, meet- ing the prolongation of PO in P f then, by article 27, COR. 2, P f and P are the projections of diametrically opposite points on the original great circle, since the construction would equally determine P f were the point A revolved round PP' till it became coincident with S the point of sight. Perpendiculars from the points of bisection of the straight lines joining Q, P, and P r will now meet in a point C ; and from C as a centre a circle drawn through P and Q will be the required projection V of the original great circle V . It frequently happens that the points P and P' coincide with the extremities of the diameter DD' in which the two circles V and C intersect. Otherwise; where the distance from the circle of projection differs appreciably for the two points P and <2, an elegant mode of deter- mining the position of the diameter DD' is the fol- lowing. Through P and Q, Fig. 1 8, draw any circle intersecting the circle of projection in points p and q ; (any circular disc laid on the figure will determine these points). Let the two straight lines PQ and pq be drawn to meet in M. Then D&, the diameter of the circle of Stereograpkic projection. projection which would traverse M if continued, is the diameter required. Through PQ and D describe an arc of a circle intersecting the line MD in a second point A. Then MP. MQ-Mp.Mq = MD . and A and D' are the same point. Hence, DD' is the diameter at the extremities of which the arc V (the projection of the arc V) intersects the circle of projection. If PQ and pq are parallel they are parallel to DD'. COR. In order to draw the projection of a great circle where the projection of its pole is given : draw a diameter of the circle of projection through the point M in which the pole is projected; then, as in COR. PROB. I, by aid of the lines Pm, Pq, where the fJT arc mq = - , find the point Q on this diameter equivalent to a quadrant's distance from M, the projected pole. A second dia- meter PP f , perpendicular to the first, will meet the circumference in the points of intersection with it of the required great circle ; which may now be drawn by the help of Problem III. N.B. The centre K, from which this circle is to be drawn, will be the point in which a perpendicular on PQ from B, the point of bisection of PQ, will meet the diameter through QM. And the case in which this centre K falls on the circle of pro- jection is that in which OM and OQ represents each an arc of - when K coincides with C, and CQ = CP = chord 90 = r. 4/2 = 1.414^, the radius of the required circle being CP. That in this case, where OM and OQ each represent an arc of - , the radius of the circle to be drawn is the chord CP is evident ; for then, To project a circle in position. 39 qPP^lqOr^y and CQP = ---=-+-= QPC; so that CPQ is isosceles, and CP = CQ. PROBLEM IV. To draw the projection of a great circle which intersects with another great circle at a given angle and in a given point ; the projections of the latter great circle and of the point being given. 31. Let a great circle V intersect a second great circle W in a point r at an angle 0. Let V ', Fig. 20, be projected in the arc V, and / in the point r. It is required to draw the projec- tion of the great circle W. Project the pole of V in P, and from r draw the line rPp to the circle of projection ; on which circle let the points p and q inter- cept an arc equivalent to : draw U, the projection of the circle of which r would be the projected pole. U will therefore pass through P; and let Q be the point in which U intersects with qr. Draw the projection W of the great circle W', the pole of which would be projected in Q: it will be seen that the projection W will pass through r\ and furthermore that it will be inclined to the pro- jected arc V at the required angle 6. For the distance of the poles of two great circles, as measured on a great circle tra- versing them on the sphere, is necessarily equal to the angle at which the two circles intersect, and since r is the pole of the projected circle through P and Q, the arc PQ represents the arc on the great circle U measured by pq ; that is to say, represents the angular magnitude 0. Hence the circular arcs V and W are the projections of two great circles V' and W' t which intersect in r' at an angle 0. Fig. 20. Stereographic projection. PROBLEM V. Given the projections T and P, Fig. 21, of two poirits on the sphere ; to determine the position of a third point A which shall be the projection of a point on the sphere distant by an angular arc (j) from the point of which T is the pro- jection, and by an arc from the point of which P is the projection. 32. If we suppose the triangle APT to be drawn, and if the angle at P = , and that at 7 = f, and the arc TP = a ; then cos < cos cos a cosf = cos = sin sin a cos0 cos(/>cosa sin 9 sin a Draw, by Prob. Ill, Cor., UV, WV t the projections of two great circles of which P and T are respectively the projected poles ; and let them intersect in a point V. From P and T draw straight lines P Vp, TVt meet- ing the circumference in p and t, and through a point x at a circumferential distance 77 f from/) draw P.r, inter- secting with the great circle VU in U', and through 2 at a distance TT f from / draw Jz, intersecting with the great circle VWm W. Through U and W draw the projection of a great circle (Prob. Ill), and find A the Fig. 21. projection of its pole (Prob. II). Then will A be the point required. For, by construction, APT and UVW are projections of polar triangles. And since in UVW, UV=-n-, WV=v-, and the angle at A-na, the angle 7=7r 0, and angle Whence in the triangle APT, A T represents an arc an arc 0. and AP Position of a face-pole. 41 33. The manner in which the different varieties of crystals are represented in stereographic projection will be considered in future chapters. It is only necessary here to observe, that the plane of projection is always so selected as to contain one of the most important of the crystallographic planes, and is generally a plane which divides the crystal symmetrically. In the stereographic projections employed in this volume the representation is such as would result from looking down on a plane of projection on which the poles of the hemisphere nearest the observer had been previously laid down, as seen by an eye at the opposite pole of the circle of projection; that is to say, at the nether pole of that great circle. It is often con- venient to be able to represent the poles of both hemispheres within the same great circle of projection. In such case the poles of the upper hemisphere, as seen by an eye at the nether pole, will be represented by black dots ; those belonging to the nether hemi- sphere, as seen by an eye placed at its upper pole, will be repre- sented by small eyelets. Where two poles fall on the same spot the black dot is encircled by the eyelet. Where literal or numerical symbols are employed to express the character of the faces to which these poles belong, the signs, or other values of these numerals, will usually serve to indicate to which hemisphere they are to be applied. When the symbols of both sets of poles are introduced, those belonging to the nether poles will be the fainter and smaller in type upon the projection. SECTION V. Expressions for determining the position of a pole on the sphere. 34. Let X, F, Z be the axial points, A,B,C the poles of the axial planes YZ, ZX, XY to which a crystalloid system of planes has been referred. Hence ABC and XYZ, Fig. 22, are polar triangles, and A is 100, B is oio, C is ooi. Let P be the pole of a plane the indices of which are + h, k, + 1. If however P lie on one of the great circles passing through two of the poles A, B, C, it is the 42 Position assigned to a face-pole. pole of a face parallel to one of the axes, and one of its indices is zero ; that is, the symbol is okl for any pole lying between two poles B and C, hoi for a pole lying between two poles C and A, and hko when lying between two poles A and B\ and in each case the index in question must change its sign as it passes from one to the other side of the respective great circles. Whence the poles of all faces lying in any given octant will lie within the corresponding one of the eight spherical triangles into which the sphere is divided by the great circles passing through two of the poles +A, + B, +C and the poles opposite to them A, B, C: and the signs of the indices of the face P will correspond with those de- signating the particular spherical tri- angles within which its pole lies: e.g. the pole hkl lies within the spherical Fig. 22. triangle +A B C. 35. Let P be the pole of a plane of the system lying within the spherical triangle ABC. Through P, Fig. 22, draw the quadrantal arcs XR, FS, ZT. Then, cos PX sin PR = sin CP sin BCP = sin BP sin CBP, cos PY sin PS sin AP sin CAP = sin CP sin ACP, cos PZ sin PT sin BP sin ABP sin AP sin BAP. But the symbol of P is hkl, and by the fundamental equation A in article 17, ^-cosPX =|cosPJr= y cosPZ. hkl Substituting the above values for cos PX, cos PY, cos PZ we obtain six equivalent expressions, | sin CP sin BCP = | sin CP sin A CP, h k b - sin AP sin CAP = j sin AP sin BAP, A? / C - sin BP sin ABP = | sin BP sin CBP-, I ti Expressions for position of a pole. 43 whence are obtained the equations h asmBCP k b sin CAP I csinAP k tsmACP I c s'mAP h a sin CBP* which give the relations between the parameters and the indices of the face P in terms of the angles which the arc joining its pole hkl to any of the poles 100, oio, ooi forms with the adjacent pairs of the arcs that unite these latter poles. CHAPTER III. ON ZONES AND THEIR PROPERTIES. SECTION I. Expressions for a Zone. 36. Definitions. If the centre of the sphere of projection coin- cide with the origin of the axes to which a system of planes is referred, the direction of any plane passing through this centre (origin-plane) is determinable when the positions are known of any two radii of the sphere not on the same diameter that lie in the plane in question. And if these radii be the normals of two planes of the system, the poles of these planes will be points on the great circle in which the origin-plane intersects with the sphere of projection. Further, the two planes, and therefore also the edge in which they mutually intersect, will be at once perpendicular to the plane of the great circle containing their poles, and parallel to the dia- meter of the sphere which is the normal of that plane : this is true for all the planes the poles of which lie on the great circle, and for the edges in which each pair of them may intersect. Thus, the direction of the plane of this great circle and that of its normal may be determined indifferently from any pair of these planes. The great circle which contains two or more of the poles be- longing to a system of planes will be called a zone-circle, and the plane containing a zone-circle its zone-plane : the planes or faces perpendicular to the zone-plane are the planes or faces of the zone. The diameter of the sphere normal to the zone-plane, and to which therefore the edges formed by the intersections of faces Symbol of a zone. 45 of the zone are parallel, is the tone-axis. Two or more poles (or their faces) are said to be tautozonal or heterozonal with a third, according as they lie in the same or different zone-circles (or zones) with it ; and when two zones have a face in common, that is to say when their zone-circles intersect in a pole, they will be spoken of as tautohedral in that face or pole. 37. Symbol for a zone. That two different centre-normals, and therefore two faces not parallel, suffice for the determination of the position of the zone-plane to which the faces are per- pendicular is further evident from this, that two points, and therefore two poles on a sphere, not ex- tremities of the same diameter, can only be traversed by one great circle : and the direction of the zone-plane contain- ing such a circle is Fig. 23. known when that of its zone-axis is known. In fact, if two planes in the zone be PI or (h-i k^ /j), and P 2 or (h^ k z / 2 ), the coordinates for any point on its zone-axis are (Art. 20) in the ratios, A convenient symbol for representing a zone is formed by placing the letters or symbols representing the faces by which its direction is determined within square brackets, or so placing the coefficients of the parameters a, b, c in the above expres- sion. Thus, PP / . / or or 46 Three tautozonal planes. and, if P 3 be a third face of the zone, [A ?*] or [u 2 v 2 w 2 ] , [P s P 2 ] or [14 v, wj , are symbols that equally represent the zone [P l P z P 3 ~\ . A. zone, its zone-axis and zone-plane or zone-circle, will be represented by the same symbol. It is however to be observed that the form in which this symbol is presented has not the same signification as the symbol for a plane of the system : moreover in the coordinates an, &v, 3 V 3 ; ^i Vi]> and [u 3 v 3 w 3 ] being [^^A; >M 2 / 2 ]. And as these symbols equally represent the direction of an identical zone-axis, it is clear that their indices can only differ in their actual and not in their relative magnitudes; and these Different equivalent zone-symbols. 47 actual magnitudes can only differ, therefore, in the various symbols, by a series of common factors. It will thus be seen that it must be necessarily true that, for instance, u k I k I _ s _ Ms- <,1 . T' 1 '*2 /V 3 ""3 ' V 2 where the value of A may in general be determined from either of these ratios. It often happens, however, that from, for instance, certain indices being zero, one or two of these expressions will assume the indeterminate form - Since, however, all the indices o cannot equal zero, the value of A can usually be got by in- spection and selection of the indices ; but it may always be found if the entire symbols be compared, that is, by determining the value of which is A. r i w i] K v i W J 39. Notation for Factor-ratios. This relation between the symbols of a zone as derived from those of different pairs of the planes lying in the zone will presently be seen to have much significance. A convenient notation for the representation of such a relation is afforded by confining the symbols of the planes in question between square braces or simply between vertical lines, the symbols or their equivalents being in the form of a fraction. Thus, if p or fa ^ /,), Q or fa Z 2 / 2 ), R or fa k z / 3 ), be three tautozonal planes, their zone may be equally expressed as [PQ], [Q-R], or [RP}} but as these several symbols differ generally by a common factor, we should have, for instance, *.*, A, , h^l^ h^k*} ' = A, Notation. as various ways of representing the relation of the symbols for the zone as deduced from two pairs of its planes ; and indicating in this case that u 3 = Au 15 v 3 = Xv p and w 3 = Aw r Where we would indicate that an expression for the zone is to be derived by the cross multiplication of the symbols of a particular pair of planes of the zone, the symbol may be written thus, or where the ratio of two such expressions is to be indicated, as in the above example, the expression will take the form of double line therein represented. Thus, if the planes P or (211), Q or (in), R or (100), S or (oil), belong to the same zone, we may indicate this zone as 211 [PQ]; i.e. as [211, in], or II I which gives its symbol as [on] ; or it may be designated from the planes PS, therefore, as [211, oil] or [022] ; or from R and Q as [oil], or from R and 6" as [oil], &c. And the ratio PQ PS 211, III 211, Oil Oil 02:2 and the value of A may be variously represented by A = J. So the ratio IOO RQ C\T III on RS UI IOO oil oil PQ RQ I ~PS * RS ~~ 2 And represents the proportion of these ratios. In expressions of the kind under consideration, the direction in which an arc joining two poles on the sphere is considered to be estimated, and therewith its sign, is indicated by the order of the letters or symbols which represent the poles ; so that QP=-PQ, and PQ_ QS QP QP &C. Condition for tautozonality . 49 40. Condition for a plane (hkl) to lie in a zone [uvw]. It further results from the geometrical unity of a zone-axis and the consequent invariability of the ratios of the indices in the various symbols obtained for it as representing the edge formed by one or other of the different pairs of planes belonging to the zone, that, taking the symbols for any three tautozonal planes as before, U 2 V 2 W 2 is evidently true. Since the denominator of this last ratio is identically zero, as is seen on substituting the values of u 2 v 2 w 2 in terms of h k l / x and A s 3 / 3 , the numerator must also be so ; and consequently, 1 1 w 1 = o, .e. ^(Vs-W an equation establishing a relation between the symbols of any three planes in a zone. 41. Symbol for a plane (hkl) in which two zones [u 1 v 1 w 1 ] and [u 2 v 2 w 2 ] are lautohedral. Since (h k /) belongs to each of the zones in question, ,u 1 + /fcv 1 + /w 1 = o; and /u 2 + /v 2 + /w 2 = o: whence h (iij w 2 w x u 2 ) + k ( v x w 2 w x v 2 ) = o ; and /^(U 1 v 2 -v 1 u 2 ) + /(w 1 v 2 -v 1 w 2 ) = o; h _ VjWa-w^a h d,lbU - k wu or, - = - - = - ; V 1 w 2 -w 1 v 2 W 1 u 2 -u 1 w 2 U 1 v 2 -v 1 u 2 wherefore the indices of the plane (hkl) have the ratios repre- sented by the symbol KW.J w^, W 1 u 2 -u 1 w 2 , i^Va-VjUa). And it will be seen that the form of the expression representing the indices of a plane in terms of the symbols of two zones tautohedral in it, is identical with that of the symbol of a zone as derived from the symbols of two of the planes tautozonal in it. E Derivation of determinants. 42. Expedient for deducing the determinant symbols. This similarity in the form assumed by the symbol of a zone as de- rived from a pair of its planes and by that of a plane common to two zones (as obtained in Art. 40) leads to the adoption of a similar process for obtaining the symbol in either case. An ex- pedient for performing this operation, useful when dealing with complicated symbols, is that of writing, one under the other, the two symbols to be operated upon; each symbol being once repeated on its own line and the first and last index on each of the lines being struck out. The differences of the cross products of each successive pair of indices on the two lines (these indices being connected in the subjoined example by an X) form the new indices, the product of the indices joined by the thin stroke being deducted from the product of those joined by the thick stroke. Thus if ^ 2 - 2 / 2 and ^ 3 / 3 / 3 be two planes in a zone, we have, for the value of k 2 / 2 h z V XXX k z ? 3 hs k z Ik I I h I 23 23 ii i? J? i ! . where Ms - or 2. 3- [V s -/ a 8> is the symbol of the zone sought. Similarly, we get for the face (h k /) in which two zones [u v w] and [u'v'w'J are tautohedral, the symbol (vw' wv', wu' uw', uv' vu') or (h k I]. The symbol for the zone containing the faces (342) and (324) 4234 II II 2432 or 2 43 2 4234 is 12 , -6 ~fi) or 12, 6, 6, 12, 6, 6; which, reduced to their simplest forms, are [211] or [211], ac- cording to the order in which the two planes are taken. Relations of edges and normals. 5 1 The same symbol [211] or [211] is similarly obtained from the poles (ni) and (oil) which also belong to the above zone. So again, the opposite poles in which two zone circles [in] and [oTi] would intersect are (2!!) and (211). 43. Relations connecting the inclinations of the edges and of the normals of three planes. If XOY, FOZ, ZOX, Fig. 24, be three planes, OX, OF, OZ the zone-lines parallel to their edges, the great circles joining the axial points X, Y, Z of these zone-axes upon the sphere form a spherical triangle the sides of which evidently measure the plane angles at which each pair of edges meet in the solid angle at ; the angles at X, Y, and Z on the other hand are those of the inclinations of the planes. If now OA, OB, OC be the normals of the planes YZ, ZX, XY- A, B, C being the poles of these origin-planes ; ABC and XYZ are the angular points of two polar triangles, and the arcs AB, BC, CA are P> Fig. 24. the supplements of the angles at which the planes YZ, ZX', ZX, XY; XY, YZ are inclined to each other ; while the angles at A t B, and C are the supplements of the angles YOZ, ZOX, XOY at which the edges of the planes meet. The arcs AB, BC, CA are generally capable of being deter- mined by processes of measurement, so that from these the other values can be calculated. SECTION III. On the signs of the indices of a plane as determined by the position of the plane in respect to a given zone. 44. Two poles are said to be on the same or on opposite sides of a given pole lying in a zone with them according as E 2 52 Signs of indices. loth or as only one of them may lie within an arc-distance TT from that pole as measured in the same direction on the zone-circle that contains the two poles. Let [uvw] be a zone-circle containing the poles p^ q^ r 1 , p 2 g 2 r 2 ; then the equation u^ + vy+wg- = o gives the necessary condition for a plane efg to lie in the zone [p 1 q^ r lf A ^2^2]' Wherefore, for the plane hkl not belonging to the zone, u/$ + v/ + w/> or ', 02!; and of / 2 , 031. SECTION IV. Relations connecting four tautozonal planes. 46. Let ^(Wi), &('!/!&), G a (' a /,^) and /> a (W 2 ) be four poles lying on the same zone-circle, and let X, Y. Z be * ,/A< ,:& t; cos = cos XP 2 = cos the axial points in which the axes to which the system of crystalloid planes is referred meet the sphere of projection. Then i cos P,Q, + sin XQ l sin P& cos P&X, i cos P& + sin XQ 1 sin P& cos P&X\ = cos XQ l sin />& cos P& + sin ^ft sin P& sin^ft cos ^^ X, sin P^i = cos XQ^ sin ^ft cos P& -sin Z<2 X sin P& sinP^ cos whence cos XP^ sin P Z Q, + cos J^P 2 sin P& = cos ^Tft sin P 2 In the same way sin P 2 Gi + cos FP 2 sin P 1 Q 1 = cos Y & sin P 2 56 therefore sin P, ft Problem of four planes. sin ftP 2 cos YQ^ - cos JT 2 cos XQ l cos XQ l cos yP 1 - cos YQ l cos XP 1 cos 17^ -cos FP 2 cosXP^ Similarly, by considering the poles P lt ft, ft, and again the poles jP 15 ft, P z , we may shew that the above expressions are equivalent to sin ft ft sin ^ ft cos XQ 2 cos J^ft-cos FQ 2 cos XQ l ~ cos XQ 2 cos FP 1 cos -Fft cos XP, sin Q P cos ^^ cos YQ Z - cos IT^a cos Zft From the fundamental equations (A), c ! = f COS Z/*!, I, - cos ^ ft = e i fi cos XQ 2 = cos YQ, = - cos - cos XP 2 = ~ cos FP 2 = - cos ZP 2 , h, k z / 2 By substituting values for cosXP^ cosXQ l} &c. sin^ft / t cos IT 3 ! k^-h,f 2 _ = sin ft ft ^ cos^ft / VA/; " " sn sinft/> 2 Hence _ /, cos ly, ^ a -^^ a _ _A = &c. = ft A (1) sin/> i(? 2 . sin _ft^ 2 _ k * e *- h iA . /*%< sin Pj ^ ' sin ft /* 2 ~~ k h^h^ k 2 ' f^ /i 2 < ft?, C Problem of four planes. 57 It may similarly be proved that (2) sin A ft t sin A ft _ sin P l ft ' sin P z ft Aft Aft If ft be external to A tne relation may be put into the form V ' sn ft sinP 2 ft sinAft' sin Aft" A" In the expression (2) the ratio is positive, in (3) it is negative, and these two relations, representing the cases where ft is internal and where it is external to P z , may be comprised under the single expression sinAftsin(Aft-AA)_ Aft sin (Aft- A A) sin A ft Aft where A may be positive or negative. = A. By analogy, sin Aft ^ A sin^ft A Aft Aft 5 or sn ft _ sinP 2 ft Aft Aft *2/2 *2/2 ^2/2 ^2/2 c- M i r A Sm A ft Similarly for - - =^-~ 1 ; and we have A smP 2 ft' sin A ft sin (/, Q, -/,/,) sin (A ft- A A)" sin P, ft _ ^2 Pi = A D' 58 Anharmonic ratio, four planes. where [p^rj, [p 2 q 2 rj are [^Vi A/xz;], [ 2 2 /2 A pv] re- spectively, (A/xz/ 1 ) being the symbol of an arbitrarily taken pole ^external to the zone-circle [P 1 Q Z ]- By selecting for K a pole presenting one or two zeros in its symbol, this symmetrical expression takes a very simple form. 47. It is seen from the form of the expressions leading to C and D that a fourth plane in the zone is needed in order to obtain a relation between the faces of a zone independent of the axial distances of the several poles. It will moreover be seen that the expressions thus obtained for the relations of four faces belonging to a zone are in the form of one or other of the anharmonic ratios of the normals of the four faces ; which form a sheaf of lines lying in the plane of the zone and meeting at the origin. And since these four normals are homographic with the traces on the zone-plane of the origin- planes parallel to the four tautozonal faces, it may be asserted alike of the normals and of the faces, that in a crystalloid system the anharmonic ratios of any four tautozonal planes must be rational ; for it is obvious that the right-hand sides of the expressions C and C' as well as of D and D' are rational. The anharmonic function is in each case equivalent to the ratios of the first minors of the . determinants formed by the symbols of the faces taken in corresponding order. Since there are three anharmonic ratios resulting from the division of an angle or of a line, those of the four tautozonal planes P 1 Q I} Q^P 2 are /I \ Aft ft ft l/fg\ V 1 ) /o\ AA ftA ftA frr #r \A) /q\ Aft Aft ft ft Aft A ( e ifz^' (^2^24) respectively, and the arcs P 1 Q 1 and PI.PV i.e. the positions of the poles P l Q 1 and P 2 , are known. From the equation D we get sin P, Q n sin P, 0, tan 0, sin(P 1 (2 2 ~P 1 / > a where A = = A sin (P, Q,-P,P and from this equation 6 can be determined, since the second limb of the expression consists of known quantities. If the expression D' be employed, the value of A is obtained from the right-hand side of that equation. In order to reduce the expression into a form adapted for the use of logarithms, we have, -tan sin (P, Q,-P l P^-smP, Q 2 cos i (2 P l Q, - = - tan (P l Qt-\P sn - cotan and tan (/^ ft-l/^) --tan \P, = taniP 1 P 2 tan(i 3 5-^) ..... E 49. Secondly, where the three angles between the four tauto- zonal planes and three of the symbols of the planes are known, and it is required to find the symbol of the fourth plane : Let the angles P 1 Q 1J P l Q zt P^P 2 be given, and also the symbols of P lf Q I} P 2 , viz. h^kj^ e^g^ h^kj^ respectively: it is required to find the symbol of <2 2 , viz. Putting the equation D into the form A A = 5 6o Problem to find a symbol. where A is to be obtained from the left side of either of the m expressions D or D', --is rational and can be found from the n known quantities constituting the right-hand side of the equation. Then Aft Aft and whence m ^ e 2 = m a / 2 A by symmetry ; and we have for the indices in the required symbol of ft> e = nh-mh \ Examples. I. On a crystal of Diopside there occur in a zone four faces, their symbols, and the arcs between their poles, being P l or (^ Vi) 01 ( IOO X ft or fe/i^i) or ( I01 ). PI ft = 4939 / P 2 or (h,kM or (ooi), ^P a = 73 59' ; or where the arc /\ Q 2 is to be determined. From expression D, or IOO 301 OOI 301 OIO 030 Aft! Aftl IOO IOI OOI IOI In order to find the position of the pole Q 2 in the zone, the Examples. 61 symbols of and arcs between the other poles being given as above, we have by equation E, 3 sin 24 20 tan (P, ft- ^ A A) = tan 36 59' 30" tan 103 20' 43", = tan 107 28' 46"; ' A <2 2 -36 59' 30" =107 28' 46", and P,Q 2 = i4428'i6". The value of A might have been equally obtained from the expres- sion D'. Taking the pole (oio) for K, i.e. for (A, JK, v); we have for [p^rj, and 100 OIO = [ooi], and for [p 2 q 2 r 2 ], ooi oio o + o i o + o i -3 + + ' 1+0 + or A = 3 II. A zone on a crystal of Felspar presents the faces p i or (203), Q, or (In), 7^ = 31 1 2', Q. 2 or (241), PiQ z is the arc required, P\ or (130), Pfi = 86 12', and \P,P,= 43 6'; _ _ = = Aft 203 241 12 4 8 Aft 3l2 I 3 o 241 3 i 2 Aft 312 and A= 4; =-4-- 5 and = -68 25' 47" Whence tan (P, Q,- - P^ P 2 ) = tan 43 6' tan 23 25' 47", = tan 2 2 4' 2 7", and In order to determine the value of A by the use of expression r , we may take for k the pole ooi. Then wK = [020], and p 2 q 2 r 2 = I *3 || = [ 3I0 j. ooi 62 Four tautohedral zones. And by D', A = : - - = 4 ; the same result as by the other process. Conversely, if the symbols in the above zone for the poles P l , Q! , P 2 are given and the arcs P l Q l and P^ P 2 as before, but the arc P v Qi be observed as 65 20"; and it be required to find the symbol of Q v Then 203, in 130, In sin 65 20' sin (3 1 12'- 86 1 2') sin 31 12' sin (65 20'- 86 12') _- _ _ s l n J^20 / sin55 _____ sin 31 1 2' sin 20 52' m 4 Assuming = > we have by equation F for the symbol of Q 2 (-2-4, 0+12, 3-0), i.e. (6, 12, 3) or (241). It will be seen, however, that on the assumption that the symbol of Q 2 is ("241) and that the arcs P 1 Q 1 and P^P^ had been cor- rectly determined, the true value of the arc P^Q t would not be 65 20', as measured, but is, approximately, as calculated in the previous paragraph, 65 ic/27". Problems relating to four tautohedral zones. 50. The method of introducing a fifth pole external to the zone in which four poles lie, in order to represent the anharmonic ratios of these four poles in terms involving two zone circles intersecting with that of the original zone, may readily be extended so as to involve four zone-circles passing through the poles of the four tautozonal planes and also through an arbitrarily taken pole external to their zone. If k be this arbitrarily chosen pole and P lt Q lt Q 2 , P 2 be as before four poles lying on a zone to which k is external, then k will be the pole of an origin plane K or (Ajmv), and zone-circles passing through k and through P I} Q lt Q^ P 2 will intersect with the great circle of which k is the pole in the points/^, q^ q z , p% (Fig. 27). Through p, the point in which the zone-circle P, P meets the Problems involving four zones. great circle K, draw a straight line intersecting with radii of the sphere Op lt Oft, Oq Ofa in a', &', /,/> 2 . The zone-plane \P l P^\ will intersect the plane kpp^ in a line pd which will meet in abed lines drawn from to P lt ft, P 2 , and Q 2 , and from k to a V // 2 : thus the pencil OP l OQ 1 OQ Z OP 2 is homo- graphic with the pencil Op l Oq^ Oq^ Op^ which pencils are the traces of the four original zone-planes on the planes OP l OP 2 and Op^ Op 2 , and their anharmonic ratios are, as in the expression D, sin ft g a sin (A ft -A A) _ sinP 1 (? a sm(/ 1 (? 1 -/ 1 / a ) sin (A? 2 -AA) sinftft sin (P^ Q^-P^ = A, where the arcs A?i>A 3i-> **& P\P* measure the angles at which the zone-circles kP^ /fcft, ft, kP^ are inclined to each other. It will be seen then from this construction that if there be two poles ft, ft and the zone-circle denoted by them intersects two other zone-cir- cles the symbols of which are [p : q t rj, [p 2 11U 7 ah , q, r) and (A/, Xq, Ar), the indices in the symbol for an origin-plane of a crystalloid system may be multiplied by any number positive or negative, or be divided by a common divisor. And the same is true for the symbol of a zone-axis, the equation to which is x y z ua v<$ w- It may be written [uvw], or more generally [/xu/otvjuw]. 57. If (^! j /j), (^ 2 2 4)' (A ^s 4) t> e tnree origin-planes intersecting in an identical zone-axis, their equations are (1) ^ + ^+^ = 0, (2) j.f + ^ + 4? = o (3) ^f +H ! = The mle of zones. Now x,y> and z have the same values in these three equations and are not all equal to zero, consequently the determinant V = = o; that is to say, ^ ~~ MI \^2 3 ^2 ^3/ ~f~ ^1 (/2 ^3 ^2 ^3) ~f~ A (^2 ^3 2 3/ : ~ :=: ^* 58. Conversely, the three planes intersect in the same zone- axis, if V = o. For if the zone-axis in which, say, (2) and (3) intersect be the line or that is to say, the line the symbol for which is formed of the first minors of the determinant of the above three equations, the line is x y z and the plane h^ k^ / x will contain this line if h^ Uj + k^ v x + / x Wj = o, that is, if V = o. 59. And furthermore it will be seen that the necessary and geometrically sufficient condition for the plane hkl to contain a possible zone-axis [u v w] is /^u + ^v + /w = o ; for the plane is (2) a o c and the equation for the line must be x y z an <5v <:w ' and any values for x, y> z satisfying (2) will satisfy (1); by sub- stitution therefore in (1) of the values from (2) for the ratios x y z 5 ^ 5 - j we obtain ^u + ^v + /w = o. a o c Since a fresh expression for a zone-axis is obtained from each pair of planes in the zone, as, for instance, in the zone 68 Analytical investigation. the following symbols may be obtained for the zone-axis : [u^wj, [u 2 v 2 w 2 ], [u 3 v 3 w 3 ]; where Uj Vj Wj represent h n k n or koLi ,-h,L and similarly for the others : but as these can only differ in their several actual, but not in their relative, magnitudes, the actual magnitudes of the different symbols can only differ by a series of common factors ; that is, adopting the previous notation, u 2 v 2 w 2 or 2 2 2 h k / J w results identical with those previously obtained. 60. The equation h z Ug-f-^g v 3 -}-/ 3 w 3 = o, which represents the condition for a plane (7z 3 k 3 / 3 ) to belong to the zone [u 3 v 3 w 3 ] or [^^/i, ^ 2 ^2 4] ^ s indeterminate ; the condition however which has to be fulfilled by the symbol of the plane may be put into another and more immediately applicable form. Thus every origin-plane, the symbol of which has the form and (h z / 2 7 2 ), lies in the same zone with the two planes and is a plane of the system if is rational. For the determinant = zero. And, conversely, if (>$ 3 /^ 3 / 3 ) be the symbol of a plane belonging to a zone determined by the planes (h^ ^ 4) and (/^ 2 2 / 2 ), its symbol in general not its simplest, but some equivalent symbol can be represented in the form For if these two sets of indices represent the same plane, 4 =-"' Tautozonal symbols. relations which may also be expressed thus, ( 1 ) A h^ -f ft h^ + v A 3 = o, (2) A^ +/u^ 2 -\-vk z = o, By the reasoning in Article 57, we have h, h n / k k k K K = 0; wherefore the above equations are consistent, any pair of them giving the same values for A, //, v. Thus (2) and (3) give A v V 8 -/ 2 A -.4-4*1 or ~ = = ; x " (3) and (1) give = ~ = : (1) and (2) give A -J^L - W Q 1 Having then found values from any one of these systems for A, jn, v, the ratios of which must clearly be rational, we may write for (h z k z / 3 ) the equivalent symbol or (A ^ which was the expression to be arrived at. Example. To find the symbols of a series of planes lying in the same zone with the planes (m) and (320), i.e. in the zone [231]. Let A = 2, p. i, then the symbol is (542), A =-2, /*= i, (102), A= i, p= 2, (751), A -i, fj.= i, (21!); all of which symbols belong to planes of the zone [231] : thus from the symbol (542) we have 5x2 4x3 + 2x1 =o, and so for the others. 7 o A nalytical investigation. 61. COR. Where A=/x= + i, the process is simply the addition or subtraction of the indices in the symbols (h^ k^ /J and (h^ / 2 / 2 ). Whence, whether we take the sums or the differences of the corresponding indices in two symbols, we equally obtain a symbol for a face belonging to the zone. A face, the symbol of which is obtained by adding the indices in the symbols of two other faces, will cut off or replace, and in certain cases, where the faces are symmetrically disposed, will truncate their edge; that is to say, will, in the latter case, be equally inclined on the faces. In cases where a face truncates an edge, symbols for faces that bevil the edge (that is to say, would be inclined each at the same angle on a truncating face) are obtained by adding the indices of the symbol for the truncating face to those of the symbols for any other pair of corresponding faces that meet in and bevil the edge. [See Article 133.] Thus, if (no) and (101) be the symbols of two faces the edge of which is truncated by the face (211), the same edge would be bevilled by the faces (321) and (312), as well as by the faces 532 and 523, &c. The problems, of four tautozonal planes. 62. Let there be a system of tautozonal planes; the equations to two of which are u = o and v = o ; where - a b c ' Any plane passing through the same zone-axis [u v] with these planes p^ g l r^ and / 2 g z r z must be represented by an equation of the form u + /xv = o, or t =o (2) But if the plane be crystalloid and (hkt) its symbol, its equation may also be written in the form Problems on tautozonality . 71 In order that these equations may be identical we must have whence /x must be rational if the remaining letters represent rational numbers; i.e. if the planes be crystalloid. As in Article 46, let P 15 ft,P 2 , ft be four planes of a zone [u v], of which u and v are any two planes ; and let u + fa v = o be the plane P 1 or (^ ^ / a ), u + ^v = o Q 1 or (tfj u + M 3 v = o P 2 or (/$ u + // 4 v = o ft or (, ft = ^A, y. t = !S* Hence the anharmonic ratio is - 2 f T? f i / *i J i\ i K ft] = 74 A nalytical investigation. [ACJ = [A and If by inverting the expression A, -r becomes A, and we have the form A of the ratio D', as in Art. 46 ; and similarly for any other form of the anharmonic ratio. Zones with crystallometric angles* SECTION VI. On Isogonal Zones. 63. Harmonic division of a zone. In investigating the relations which connect the planes belonging to a zone, and establishing the principle which in fact is but a more philosophical form of enunciating the fundamental law of a crystalloid system that the anharmonic ratio of four tautozonal planes is in such a system rational, we are brought into a position from which we may advance to discuss a problem which involves the whole principle of crystalloid symmetry. This problem deals with the conditions under which the angle at which any two planes of a zone are inclined on each other may be repeated in the zone. The simplest case to be considered will be that in which two planes of the zone are equally inclined on a third at an angle <. Thus, if P and P' be two origin planes the angle between which is bisected by the plane S, as in Fig. 28, where the lines OP, OP', &c. are the traces of these planes on the zone-plane which is that of the figure ; it results from the principle of the harmonic division of an angle, which is only a particular case of the anharmonic division, that if 2 be a plane in the zone perpendicular to S, smPP' sinSS (1) sin .PS sinP / = 2; sin P2 smP'S_ \6 ) . T-. ^. * ~ -r^tf-l A sin/tf sinSP' i. (d) snTPP > 'sinS 4 S'~2' results easily verified by substituting the values for the angles in the expressions ; thus expression (3) is sin (j) cos i 2 sin . cos tf> sin 90 2 76 Harmonic division of a zone. Since the expressions are independent of the value of $ and have rational values, we may assert : 1. That where two planes in a zone are equally inclined on a third, a fourth plane perpendicular to the last plane is a possible plane of the zone ; and 2. That, in a crystalloid zone containing two perpendicular planes, for every possible plane of the zone another plane may be found equally inclined with it on the two perpendicular planes, which fulfils the condition necessary for its being a plane of the system, namely that of its having rational indices. In fact if S be (efg) and P and P' be (hkl) and (h f then, sinPP' sinSS sin PS and thus - is rational j p is determined from the relation PP' : PS o \* = kl k'l' fg qr SP' kl qr f k'l where uvw are the indices of the zone h kl Hence the indices p q r of 2 are necessarily rational that is to say, fulfil the necessary condition for a possible plane of the system. This how- ever, as will be hereafter seen, is not always a sufficient condition in order that a plane may exist in a symmetrical system of crystal- loid planes. It is obvious that any relations that are established regarding the anharmonic ratios of the planes in a zone apply equally to those of their normals and to the sines of the angles of the arcs joining their poles on the zone-circle. It will further be evident that what particular values of may be possible, or whether any two angles between three consecutive planes in a zone can have the same value , will depend on the nature of the zone, and ultimately on the axial elements to which it is possible for the particular system of planes to be referred. 64. We may next discuss the more general problem regarding The cry stallometric angles. 77 the repetition of the same angle of inclination between several consecutive planes in a zone : where however this angle is limited, by the condition that the number of planes in a crystalloid zone cannot be infinite, to such angles as are commensurable with TT ; so that the recurring angle where p and q are integers. And it is obvious that if the anharmonic ratios of four con- secutive tautozonal planes inclined at the same angle $ are rational, those of three of them and a fifth plane also inclined on one of them at the angle < are rational, and that in fact the whole zone-circle may be divided by n of its origin-planes into 2 n sectors, the angles of which are each $, i. e. 2 TT. DEF. A zone thus divided by n equally inclined consecutive origin-planes will be termed an isogonal zone; and the angular values which ( may be able to assume will be termed crystallo- metric arcs or angles. We shall proceed to prove that the number of possible values for $ is extremely limited, and that in fact the only crystallometric angles are 90, 60, 45, and 30. It will be only necessary to establish this for the case of four consecutive poles in a zone. 65. The only possible isogonal zones in which the angle () between consecutive origin-planes, and there- fore between the normals of consecutive faces, is a sub- multiple of TT are those in which > -> and o. 2346 Let P, Q, P f , Q be four poles in such a zone-circle, so that PQ= Qp' = p>Q> = . sin 2 = a rational quantity = A ; sin 9 . sin 9 2 cos 20 = A 2 and is a rational quantity. Isogonal zones ; By trigonometry* we have 2 COS ^2$ = (2 COS27T = 2; .'. (2COS24>) g -M 2 (2COS2(/>) 9 - 2 +... = 2. Thus 2 cos 2 (/> must be a rational root of the Equation x q + A. 2 x q -* + AtX-*+... = 2 . t But if the coefficient of the highest power in a rational algebraical equation be unity and the other coefficients integers, the rational roots must be zero or integers. Therefore 2 cos 2(> = or = or = + 2 for any other integer would give an impossible value for cos and , 7T 7T 277 n 2 = - 3 - 5 5 TT or o , 2 3 3 7T 7T 77 7T

and any fourth face belonging to the zone be taken ; then any planes in the zone inclined on this fourth face at the same crys- tallometric angle $, or at any angle an integral multiple of $, will fulfil the condition necessary for being possible planes of the system; i.e. their indices will be rational. Let /> Q, P 2 , R be four tau- Fig. 20. tozonal planes, the arcs between the poles of which are P^Q = QP 2 = <, P 2 R = a ; then, if Tbe a plane lying in the zone such that RT = , Tis a possible plane of the system. * Todhunter, Trigonometry, Article 286. f Todhunter, Theory of Equations, 113. their properties. 79 For by the principle of rationality of anharmonic ratios, sin 7\ P z sin QR __ sin 2 $ . sin ($ 4- a) _ sin 7*! 7? sin (XP 2 ~" sin (2 + a) . sin$ = 2 cos 6-. ~- ^ ......... (i) r sm(2$ + a) Also sin Pj Q sin 77*2 _ sin $ sin ( + a) . sin P l P 2 sin T^? sin 2 sin (2$ + a) let 2 cos = 30, and 7\S = = 45, then S is not a plane of the system. For the anharmonic ratio sin 7*2 Q sin SP^ __ sin <> sin 2 sin P 2 P 1 sin SQ ~ sin 2 $ ' sin ( + 0) ~ 3 _}_ ,/ ^ ' which is irrational. And, 2. If R is, as in the last paragraph, a plane belonging to the zone with P ly Q and P^ , then T 7 and T 7 ' are possible planes of the zone forming with R three planes successively inclined at the same angle $ at which the planes P 1 and P 2 are inclined on Q ; and therefore a plane inclined on R at 45, if 4> be 30, or at 30 if $ be 45, is not a plane of the system. It is evident that in a zone containing three or more planes inclined on each other successively at a crystallometric angle, each of these planes will, together with planes perpendicular to them, harmonically divide the zone ; and the latter planes therefore fulfil the necessary condition for being possible planes of the zone. CHAPTER IV. THEOREMS RELATING TO THE AXES AND PARAMETERS OF A CRYSTALLOID SYSTEM. SECTION I. On changing the Axial System to which a Crystalloid Plane-System is referred. 68. IN crystallographic operations it occasionally becomes necessary to change the parametral plane or to refer the crystal to a new set of axes or to effect both operations simultaneously. The expressions necessary for performing these transformations may either be obtained directly by the methods of algebraic geometry or may be deduced from the expression previously obtained for the anharmonic ratios involved in four tautohedral zones. The latter, the more brief and elegant of these methods, is due to Professor Miller (Tract on Crystallography, 21). Both processes will however be given here as affording different points of view of the operations performed. (i) To change the parametral plane only. 69. a, b, c being the original parameters and a', b', c' the new ones as determined by the intercepts of a plane (efg), i.e. by the ratios a b c ' /' ? then a = a'e, b = b'f, c = eg, Transformation of axes. 81 and the intercepts of a plane (hkl) as expressed by the new parameters are f e f & #' ) b-ri c f -> n k / and the new indices of the plane are j,' v /' h k I ft . K , i or j T.J - ' f 8 i.e. the symbol is (hfg, kge, lef). If it should happen that any of the indices e, f, g be unity, the corresponding parameter will remain unaltered. ( ii ) To transform a crystalloid system of planes referred to one set of axes to another set of axes formed by edges of the system. 7O. Let the system of planes be referred to axes OX, OF, OZ with a parametral plane ABC, the equation to which is - + i + -=r- a o c Let OX', OY', OZ' be zone-lines of the system which are to form the new axes ; and let the equation to OX' be i x _ i J / _i __ I Uj a v x b w x c 0j Then the plane ABC will cut the new axis OX' in a point A' in which the coordinates of the plane and line are identical; whence the coordinates of A' are u, 7 v, w, * = ' =*' =<' W l ' '- and x = - -- .................. (1) The new parameter for the axis ^' is Oyl', which is the diagonal of the parallelepiped of which the sides are the old axial planes, and the edges are the coordinates of A' on the original axes. If now HKL be a plane of the system the equation to which referred to the original axes is G 82 Transformations . . . a o c the coordinates of the point H' in which it cuts the new'axis of X, that is, cuts i oc _ i _r _ i z _ i -a.! a Vi b \v l c 2 U l z V l W l are # =0. , jy=. , 3 = f.-J. A, SO and ^ = But, clearly OH^ _ x^ _ 0, ~OA' ~~ ~x ~ 6 similarly, . W where 0^ r and OL' are the intercepts of the plane HKL on two zone-lines u 2 v 2 w 2 and u 3 v 3 w 3 , taken for the new axes of Y and Z, and cut by the parametral plane ABC in ff and C'. In fact the equation to the plane HKL referred to the new axes that is to say, is U 3 v 3 w 3 x y ~OH f x y z h' k' I' in which the denominators are the intercepts, and the indices h' ', k', I' of the plane HKL as referred to the new axes are the reciprocals of the coefficients in these denominators of the parameters a', b', c, that is to say of OA f , Off, OC'. of axes and parameters. 83 , , ,, OA' wherefore / Similarly the zone-axes t^VjWj, u 2 v 2 w 2 , u 3 v 3 w 3 are the edges of three origin planes p l ^ ^ , p 2 q^ r^ , p z q z r s , so that KvjwJ is [ [u 2 v 2 w 2 ] is [ [u 3 v 3 w 3 ] is [Aftri* values which may be substituted, if required, in the above ex- pressions for >', ', /'. If only one axis, say the axis of Z be changed, the plane A ? 3 r 3 > common to the other two unchanged axial zone-lines, remains unchanged and is ooi. Whence u i = 2v v i = A> w i = > and -A These expressions give the values for the indices of a plane in a crystalloid system when transformed to a new set of crystalloid lines as axes, but referred to the same parametral plane. (iii) T/" /# ~~Z~ ' ^ ' and Hence and the indices of the plane HKL as transformed to the new axes, and also to the new parameters, become ' ^ u i + ^ v i + ^ w i Derivation of the expressions for transformation from those for the anharmonic ratios. 72. Let the plane-system be referred to three new zone-lines as axes, the symbols for which are deduced from any of the faces belonging to their several zones. Let [VW], [WU], [UV] be zones of which the symbols are Fig. 30. [ujViwJ, [u 2 v 2 w 2 ], [u s v 3 w 3 ] as referred to the original axes, and let the new axis of of entire axial system. 8 5 X be the zone-line [u^Wj] which accordingly becomes [100], Y [> 2 v 2 w 2 ] [oio], z K^WS] [i"J; UVW being poles in which the zone-circles intersect. Let now P be the pole of a plane with the symbol (hkt) under the old axial system, and Q be similarly the pole of a plane (efg) ; then by the expression in article 51, which represents the form adopted by Professor Miller for the anharmonic ratio, we have sin V W/> sinUW/* u + v + w/ +v 2 _ + ^2 7 ~ ' ' ' sinUW<2 ~ * + Vj/+ w x ' u 2 * + sinWV/ > sinUV/ > 3 3t sinWV<2 'sinUV<2 ~ ^^ + v 1 /+w 1 ^' u 3 ^-(-v 3 /+w 3 ,^' ' and if the symbols of P and Q when referred to the new axial system become (h'Kl'} and (e'f'g'), while those of [u 2 v. 2 w 2 ], [u s v 3 w s ] become [100], [oioj, [ooi], sin V WP sin U WP hk' sinVW<2 sinUW<2 ''f'' sin_WVP sinUV/ J _^ slrTw V^ : sin U V (2 ~ / : /' wnere by substitution and division, from (1) and (2), Ul ( A 2* r ^ Fig. 31- (p 3 (? 3 r 3 ); and let two zone-circles [hkl], [efg] intersect with the zone-circles [UV], [VW], [WV], viz. Symbols of zones. 87 [hkl] with [UV] in H, with [VW] in K, with [WU] in L, [efg] with [UV] in E, with [VW] in G, with [WTJ] in F; then, by D', article 46, sinUH sinVH h + k + r h + k + r 2 l , x -0 . . ( ^ ) sinWF sinUF / 3 e + ^ 3 f-j-r 3 g A e + ?i f + r i On referring the plane-system to new axes, let the poles U, V, W become (100), (oio), (ooi) under the new axial system, and let the new symbols of [hkl], [efg] at the same time become [h'k'l'j, [e'fg']. Then, by substituting and transposing in (1) and (2), we have sinUE ' sinVE ~ sinWL sinUL /> 3 h + ^ 3 k + r 3 l p, h + ^ k-l-r, *~~" * f' Equations which are satisfied if e'^e f r = e + f + gr, > .. .. ,. N from which expressions the symbols of any zones in the system may be determined if the symbols of the three poles referred to the old system are known. The symbol of a zone when the parameters but not the axes are changed. 74. [u v w] being the symbol of the zone \h k /, efg] as de- termined by the original parameters, let [u'v'v/] or \h ' k' 'I 1 ', e f g'\ be its symbol as determined by the new parameters, and let the new parameters be a'b'c ; u v w is kg If, I e h g, hf k e, uVw' is /&y-/y, /v-^y, h'f-k'e' and from article 69, e'=eh'kl, f = fhk'l, g'^ghkl', h'=he'f g) k'^kefg, l'=lefg'' } 8 8 Transformations . whence u' = K g ~t f = (kg -If) e f'g = u * v ' = r / _y / =(le-Ag) c'fg' = v / Hence the new symbol of the zone is Examples. I. To transform a crystal of Quartz from the customary axes to a new set of axes such that the pole (41^) becomes the pole (100) of the axial plane YZ, (241) the pole (oio) of the axial plane ZX, and (i"24) the pole (ooi) of the axial plane XY. Then [ui v i w J is [241, 124], i.e. [210], [u 2 v 2 wj is [124, 412], i.e. [021], [u 3 v 3 w 3 ] is [412,241], i.e. [102]. The symmetry of quartz is of a type which renders it possible and convenient to refer the crystal to an axial system in which the angles at which the axes are inclined to each other are equal while the parameters also are equal. It results from this that in trans- forming a crystal of quartz from one axial system of this kind to another of the same kind, the same face serves as the parametral plane for both systems. Consequently, / = / = /= i =e=/=g; and the equations M become _, tL^ + Vi/fc + Wj/ 2h+k fl = - : - - = 3 ,,_ u 2 + v 2 + w 2 3 , _ u s h + v 3 k + w s / _ 2 /+ h ^ u 3 + v 3 + w 3 3 ' or (h'k'l') is (2h + k, 2k + l, 2l+h\ Therefore, for the face 100 or r in the lettering of Miller (Brooke and Miller's Mineralogy, p. 246), a'=2, ^=o, r=i, and the symbol under the new axial system becomes 201 ; for 2. or Y22, the transformed symbol is 063, i.e. 021. Examples. 89 And the new symbols for the following faces,. a, oil; b', 2li; b, 2?; k, n 4 7; II 4 7, become 112"; ilo; oil; 651; 651; those for AT, 4 I 2; ", 4^1; ^, 10 2 5; , 8 I 4, become 740 ; 212 ; 2lo ; 5^0 ; and those for w, 14 16 7; 14716; ^, 16178; 16817, become 4 13 o; 7 10 6; 5 14 o; 8 n 6; and 17 8 16; /, 10 14 5, become 14 o 5; and "2 n o. II. A crystal of the (oblique) mineral Sphene as referred to the axial system employed by M. Des Cloizeaux may present the faces 010, 001, 100, III, 110, 102, 102, 112, O2I. It is required to transform these symbols into accordance with the axial system employed by Professor Miller for this mineral ; in which the zone-axis loo oio , i.e. [ooi] is [u 1 v 1 wj and becomes [100]; [oio] is [u 2 v 2 w 2 ] and remains [oio]; , i.e. [201] is [u 3 v 3 w 3 ] and becomes [ooi]. The equations M here become 7 / / I 7, f , k , , h=e 5 /=/, l=g -g / And any plane of the system, the symbols for which according to both axial systems are known, will serve to give the ratios of the indices in the new symbol (h'tff) to which the original symbol of the plane (h k I) has been transformed ; or, conversely, will give those of (h k /) the original symbol from the indices of (h f k' /'). The face In on the old system has for its symbol 123 on the new : let (efg) then be In, (e'fff) be 123. Then >&'=/, k f =2k, l'=l-2h. Let now (h kl) be 1 10 ; then for the new symbol h' k' I' 02^, i.e. = oil. So if (hkt) be Io2, h f - 2, '= o, l'= 4, and (k'tfl') is 102 ; i.e. the old symbol Io2 becomes the new symbol 102. 9O Transformations. Similarly, 102 becomes 100, ooi becomes 101, and 112 be- comes no. Conversely, for the face (h'k'l') or 112 of Miller the original symbol would be (h k /), and we have for this '=I=/, k'=T. = 2k, f=2=l2h; .-. 2h = i, and (hkt) is Ii2. Similarly, 163 on the new system corresponds to 131 on the old. III. A crystal of the (anorthic) mineral Axinite is referred under the axial system adopted by Professor vom Rath * to axes which would be the zone-lines of the zones [oio, ioT], [lol, 101], and [101, oio] under the axial system to which Professor Miller refers this mineral. Professor Miller's axes on the other hand are the zone-lines which in vom Rath's system would have the symbols or To ill i.e. fujVjW/l for the axis of X, 01 1 oil I or [loo], i.e. [u 2 v 2 w 2 ] Y, Oil 100 or [on], i..e. [u 3 v 3 w 3 ] Z. Whence by the equations M f+g * f-g The face 102 under vom Rath's system becomes the parametral plane in under Miller's; and therefore efg is 102, and e f g is in. Hence, * = *L, K=h, /'= - 2 2 For the new symbols therefore of the face 101 (hkt) we have '=4, '=!, /':=!, or 1 2 1 is the symbol required ; and the symbols on the system of vom Rath, IOI, OOI, TO2, Y2O, I2O, III, ill, 211, III, Til, * Pogg. Annal. cxxviii. 20 and 227. Axes are crystalloid lines. 91 become 121, 101, iTi, ili, nT, oil, on, 120, no, iTo severally, on the system of Professor Miller. So also for the symbol iY2 of Miller ; since ,, k + l lk h = i = - 5 k = i = h, and / = 2 = - > 2 2 the symbol under vom Rath's system is 113, and Miller's face 012 is 122 with vom Rath's axial system. SECTION II. The axes of a crystalloid system are neces- sarily origin-edges or face-normals. 75. In establishing the expressions in article 7O for the trans- formation of an axial system the ratios of the values u^Wj &c. were assumed as rational ; these formulae however are entirely general and would be equally true were this restriction not intro- duced. In that case however the component symbols resulting in the symbol [u^wj would not be necessarily rational. It will however be seen that in every case in which the symbols of the planes as referred to the new axes are rational, these axes must necessarily be zone-lines of the system and as such present rational symbols. In the article referred to it has been proved that if the equation to the new axis X be \x_\y_\z U-! a Vj_ b Wj c and hjiji be the transformed symbols of the plane hkl as referred to the new axes, we have _A or where h^ and h k I are by hypothesis rational. In a similar way, if p^ ^ r be the new rational symbols for a plane pqr, we have 92 Plane- and zone-systems ; and, solving these two simple equations, we get values for the Tl "V ratios and - - which must necessarily be rational. Hence any axes for which the law of a crystalloid system of planes holds good are themselves possible zone-lines of the system. On the reciprocity of a zone-system and a plane-system. 76. It has been previously established that while the inter- section of two origin-planes is a zone-axis, that of two zone-planes is a normal to a face of the system ; or, which is the same thing, that while two zone-axes lie in an origin-plane, two normals must lie in a zone-plane. It may further be proved, that whereas in a crystalloid system of planes any set of origin-edges may be taken, together with a face intersecting with them, for the axial system to which the system of planes and of zone-axes parallel to the edges of these is referred ; so, on the other hand, any set of normals of faces belonging to the system may be taken together with a parametral zone-plane, for the axial system to which may be referred the system of zone- planes and of 'rays' (i.e. of radii of the sphere coincident with normals to the planes of the system) in which these zone-planes intersect. And the expressions for a zone-axis as referred to three zone- axes with a parametral plane belonging to the system are identical in form with those for a 'ray' as referred to the axial system formed by three normals and a zone-plane. In the one case, for instance, the expression for the zone-axis is that already obtained in art. 53, namely x _ y z \\.a vb we' in the other case, that for the ray belonging to the pole hkl is x _ y_^ z where a, /3, y are the parameters on a normal system of axes, in which the axes are the normals to the axial planes of the former system. their reciprocity. 93 This may be thus proved. If OA, OB, OC be normals to the axial planes YZ, ZX, XY to which a plane-system has been referred, and (hkt) be the symbol of P a pole referred to these normals as axes, see Fig. 32; then a zone-circle through A and P will intersect the zone- circle BC in a pole D which will have for its symbol (p k /). The position of a point P on the normal of the plane (hkt) is determined by the lines LM, LN, LP parallel to the axes Fig. 32. (and proportional to the inter- cepts of the plane) ; and clearly the points 0, L, D are in a right line. y_ _ LN _ sin L ON _ smDC ~z~Wd~~sm OLN ~~ sin DB ' by the fundamental equation (A) 1 -cosZ)F = ^cosjDZ } k L or j sin DC sin BCA=. C - sin DB sin CBA, K I smDC 77 sin to Thus and k . _ " - sin LA b - sin AB c X a \jy oyu 7 ' - sin BC a X h^L y z ~kp- ly" where a ft y smBC a sinCA smAB b c 94 Plane- and zone-systems. Hence equation (1) represents the normal or 'ray' of the face P as referred to normal axes ; and again, if x y z - = ^ = - and x y z be the equations to two such rays, these rays will lie in a plane of which the equation is x y z u hv^+w = o ; a /3 y where u = /W- Ik', v = lh'-hl', w = hk'-kh', and are rational. Thus, if OU y OV,OWbe the intercepts of a plane parallel to [uvw], then OU _ OV_ _ OW a : 1T ~ h k / and a, /3, y are the intercepts of the parametral zone-plane [i 1 1]. The reciprocity in the expressions for a face-normal and for a zone-plane as referred to an axial system of the kind adopted in this treatise, and for a zone-plane and a face-normal referred to such an axial system as has been discussed in this article, is com- plete. And it will further be seen that the indices are the same for the same face or for the same zone-plane as referred to the two axial systems, though the symbols in which they are embodied have a different significance in the different systems. Some of the results of this reciprocal relation between the zone- system and the plane-system of a crystalloid system of planes have been examined by Professor Miller in his elegant tract ' On the Crystallographic Method of Grassmann' (Part V of the Pro- ceedings of the Cambridge Philosophical Society, Cambridge, 1868), wherein he has shewn that all the problems of crystal- lography may be approached from the side of a system of rays referred to normals as axes, and that this method yields expressions identical in form with those which are obtained by the other method. Zone-lines and normals. 95 Case of a zone-axis being coincident with a plane-normal. 77. An important question however arises as to the possibility of a zone-axis being not only a normal belonging to a system of zone-planes reciprocal to the system of actual planes, but being also a normal to one of the faces of this actual system. It is clear that in general it is not so; i.e. that a zone-axis and a plane-normal, or that a zone-plane and an actual plane, can only in particular cases be coincident. Those cases will form a subject of enquiry in the Fourth Chapter, in connection with the subject of Symmetry. It will be well however to investigate here the general conditions to which a plane-system is subject when presenting a plane or planes the normals of which are zone-axes. Taking the most general case, that namely in which the plane- system is referred to oblique coordinates, let the origin-line Imn perpendicular to the plane Ax + By+Cz = o be - = 4 = -> ua vo \vc then the condition for this line to be perpendicular to the plane is that it shall be so to every origin-line I'mn lying in the plane. But for the angle between the lines Imn and I'm'n, cos 6 = II' + mm +nn' + (mri + m'n) cos f + (nf+ n'T] cos r? + (lm f + I'm] cos f, f, TI, f being the axial angles YZ, ZX, and XY\ and this ex- pression equals zero, when the lines are perpendicular. The condition for the line I'mn to lie in the plane Ax + By + Cz = o is At +Bm'+Cn'= o. We have therefore /+ ncosrj + m cos = kA, m + I cos f + n cos f = kB, cos f + / cos 77 = k C ; where Al+Bm+Cn 9 6 Conditions of coincidence. By substitution, the equation to the plane to which the line x y z ua v$ we is perpendicular is (/ + n cos if] -f m cos f ) AT -f (m + / cos f + cos f ) jy H- (tt + w cos f + / cos ??) z o ; that is to say, is cos f +w<: cosf )jr ;3 = o. Comparing this expression for the plane in question with the equation to an origin-plane parallel to the plane (efg), i.e. with !*+/, + 0, where are the inverse ratios of the intercepts on the axes of the plane (efg] ; we find for the case where the zone-axis [uvw] is normal to the plane cos v< + u/>', qq are bisected in m and n, the zone-circles [//'] an d \$f\ are harmonically divided by s and m and s and n respectively : and therefore m and n are possible poles of the system. Therefore \rtin\ is a possible zone of the system. But m and n lie in the plane S which must there- fore be at once, potentially, a zone-plane and a plane of the system. The necessary conditions therefore for a crystalloid system of planes to be symmetrical to a plane are, that this plane shall be at once a plane of the system and a zone-plane; or, they may be expressed in the form, that two planes of the system are perpendicular to a third plane of it. 91. Restrictions imposed on a crystalloid system by its being symmetrical to one only of its planes. In the general case con- sidered in the last article, if the arc mn = ^, the origin-planes 2i M and N, of which m and n are the poles, will be perpendicular to each other and will become potentially planes of symmetry orthosymmetrically dividing the zone \S~\ ; but also each becomes a zone-plane, M of a zone [PP'], N of [(?(/]. They are therefore potentially planes of symmetry to the entire polyhedral system : a condition inconsistent with the uniqueness of S as a plane of symmetry to that system. Evidently therefore, if S is to be the only plane of symmetry of the system, no two planes belonging to the zone [S] can be perpendicular to each other. Nor, it may be added here, can any two of the planes belonging to the "zone, the zone-plane of which is the primarily assumed plane of symmetry, be inclined on a third plane at any other crystallometric angle : for it will hereafter become apparent that if such were the case, the zone lying in the plane of symmetry would itself present trigonal, tetragonal, or hexagonal symmetry, ac- cording to the value of the particular crystallometric angle between the planes. And the symmetry of the whole plane- system will be found to follow that of the zone in question, so that we should io8 A mono symmetrical system. pass from the symmetry of the plane-system to a single plane on to a kind of symmetry of a much higher order. 92. Axial-system where there is one plane of symmetry. Cha- racter of a form. The two conditions that a crystalloid system symmetrical to one of its planes must satisfy are most simply embodied in an axial system wherein the plane of symmetry S, and any pair of planes such as M and N y Fig. 39, perpendicular to it but inclined on each other at an angle generally greater than 60 and less than 90, are taken as the axial planes, so that the axes Zooi g. 39- are the normal of S taken for the axis Y and the intersections of the planes M and N with the plane which are taken for the axes Z and X. And, whereas these two planes are necessarily oblique in their inclination on each other, the obtuse angle /3 which represents their inclination (and cannot be of crystallometric value) is taken for the positive angle ; that namely of X O Z and X Z ; the supplemental angle /3'( TT 77) being taken for that of X O Z and X OZ. The symbol of the plane of symmetry is then oio, and its normal, the axis F, will coincide with the axis of the zone containing the poles 100 and ooi that is to say, with the zone- axis [oio]. Conditions for several planes of symmetry. 109 The planes M and N will have for their symbols H- 100 and -hooi, and their poles will lie on the great circle of symmetry S, distant from each other by an arc ft. The parametral ratios may be provided either by a single plane intersecting with all three axes, or by a plane in each of two out of the three zones \MS\, \NS\, or [MN]. The axial-system is thus represented by the expression f = 90= C, j] > 9o< 120, a : b : c, wherein two out of the five elements are fixed and the remaining three are unfettered by conditions. The first, fourth, fifth, and eighth octants, viz. XFZ, xYz, x~r~z, ~XFZ~ are similar : so are the remaining four octants adjacent to them. The poles of an independent form {hkl} will lie on a great circle passing through the pole oio and the diplohedral form will have four faces. If the pole in which this great circle con- taining the poles of the form intersects with the zone-circle [o i o] lie between ooi and 100, the symbol is {hkl}, and the four faces are h k /, h k /, h k /, li k T; if it intersects with the zone-circle [oio] in_ a pole lying between ooi and Too, the symbol of the form is {h k 1} and its faces are h k /, h ~k /, h k 7, h k I. A pole lying on the zone-circle of symmetry \S\ will belong to a form {hoi} or to a form {h o /} which will comprise only two parallel faces. A form {hko} will have four faces the poles of which lie on the great circle [100, oio]. The four poles of a form {o//} will lie in the great circle [oio, ooi]. The normal to the plane of sym- metry oio is an axis of diagonal symmetry when the system of planes is diplohedral. SECTION III.- Conditions involved in a crystalloid poly- hedron being symmetrical to more than one of its planes. 93. Where a plane-system is symmetrical to more than one plane it is obvious that not only must each pole or plane or other actual morphological feature, but that also each zone-circle and each plane of symmetry, must be virtually as such repeated over no Definitions and Nomenclature. each and every plane of symmetry of the system. Where one plane of symmetry S^ is so repeated over a second plane of symmetry 2 the third plane of symmetry S z is originated ; and the distribution of all the features of the system, as illustrated for instance by the poles belonging to a form, will necessarily be identical when viewed as circumjacent to the two planes of symmetry S. But the distribution of these features of the system in respect to either of the groups of planes will not be the same, nor will it ever be so, in respect to two adjacent planes of symmetry. DEF. Where the situation of a pole or where the distribution of the poles of a form is different when considered as circumjacent to one or to another of two planes of symmetry, these two planes are said to present unconformable symmetry ; where the situations of the poles fall into congruence by such a revolution of the system round the zone-axis of the two planes as brings one of the planes of symmetry into coincidence with the position previously occupied by the other, the two planes of symmetry will be termed similar, or of conformable, or also of congruent symmetry. Further, it may happen in certain cases that the distribution of the features of a crystal may be unconformable in respect to the two halves into which each of three planes of symmetry is divided by the common zone-axis ; so that for instance three similar zone- circles, as in Fig. 45, article 115, may present conformability in the symmetry due to alternate hemizones. Such zone-circles or planes of symmetry will be- termed hemicy die ally conformable in the symmetry they govern. 94. Nomenclature for planes of symmetry. DEF. The plane or planes to which a plane-system is symmetrical will hereafter be called its systematic planes; where it is symmetrical to different planes or groups of planes not conformable in their symmetry, these several planes or groups of planes are designated as proto- systematic, deutero-systematic, and trito-systcmatic planes or groups of planes : and in this treatise these designations will correspond to the letters S, 2, and C by which the different planes and groups of planes of symmetry are denoted. 95. Planes of symmetry are inclined at crystallomelric angles. Symmetral planes are isogonal. 1 1 1 It follows from what has been said regarding the mutually re- petitive character of planes of symmetry, that two planes S 1 and 2 1? reflected each by the other in planes S 2 and 2 2 , &c., form a zone of planes of symmetry in which the planes alternate with the planes 2, and the inclinations of the planes on each other are equal. This equality in the angles at which successive planes of sym- metry are inclined to each other, leads directly to the necessity of these angles having only crystallometric values; and indeed having only a single crystallometric value in the case of planes of symmetry lying in any particular zone. And it is further evident that a zone cannot be symmetrical simultaneously to two inde- pendent sets of planes. Were the angles in question not commensurate with TT, these angles would continue to recur in the zone through each successive revolution round the zone-axis, while also in each such revolution new series of planes of symmetry inclined on each other at new angles of inclination would present themselves until the number of such planes would become indefinitely great, and the symmetrical character of the zone would entirely disappear. The necessity will thus become apparent for the limitation which was imposed in article 65, on the character of crystallo- metric angles, whereby they were confined to such as were commensurate with TT and not greater than - 96. And this necessity for the angles between planes of symmetry being crystallometric is no less imperative in the case of a plane system than it is in the case of the symmetry of a zone ; so that we have to recognise that the condition, necessary and sufficient for a single plane to divide the plane system sym- metrically namely, that it shall be simultaneously a zone-plane and parallel to a face is no longer sufficient in the case where a second plane is, simultaneously with the former plane, a plane of symmetry ; but that this has to be supplemented by the condition that when a certain plane is established as a plane of symmetry to a zone or plane-system, any other plane or planes of symmetry can only be inclined on it at crystallometric angles. H2 Symmetry in the case of crystals. 97. Relations between the degree of symmetry of a crystalloid plane-system and the axial systems to which it may be referred. The equations P, obtained in article 77, implicitly contain the conditions under which a crystalloid plane-system may present symmetry to one or more of its planes. It has been proved that a plane of symmetry must be parallel to a face of the system, and that when there are more planes of symmetry than one these must be inclined on each other at crystallometric angles. The equations P give the conditions ne- cessary for a zone-axis to be perpendicular to a face, and it is obvious that these equations will become greatly simplified in cases where the plane-system can be referred to axes that are rectangular and where two or all three of the parameters are equal. On the other hand it is evident that where there is a plane of symmetry the plane system is capable of being referred, as in art. 92, to axes whereof one is perpendicular to the other two. We might proceed to enquire what would be the conditions under the different varieties of axial systems to which a crystalloid polyhedron might be referred, in order that the normal of a face and a zone-axis may be coincident in direction. But hereafter, when the changes of volume accompanying changes of temperature in a crystal are discussed, it will be shewn that, in a crystal as distinguished from a crystalloid polyhedron, the parametral ratios can never be permanently rational except where one or both of them is unity; and that the cosines of the axial angles are equally only capable of being momentarily rational where the axes containing them are not coincident with the normals of actual or possible planes of the system, or, which is an equivalent statement, do not lie in an isogonal zone. 98. It will be sufficient, then, for our purpose, to consider here the cases arising under each kind of axial system in which zone- planes will be parallel to faces of the system ; i. e. the conditions under which the substitution of the designated values for the axial elements in the equation P, article 77, gives rational indices for the coincident normals and zone-axes. And in fact it will be seen that with the selected axial elements this resolves itself into Crystals with rectangular axes. 113 determining all the cases in which the equations P will reduce to the form u v w i.e. to the cases in which the zone and the face to which it is parallel have the same indices in their symbols. I. Clearly one series of values by which this condition is satisiied will be that in which the plane-system is capable of being referred to an axial-system in which the axial-angles are = ,= = 90 and the parameters are equal, i. e. a = b = c. Then 5 = v = HL ' f g is true_/0r the symbol of every plane and of a possible zone-line normal to if, in the system. II. If, the axes being as before rectangular, two only of the parameters are equal, for instance a = b $ c, the equations P become u _ v _ r 2 w ~7"" ; where the third expression must be taken as irrational (since ^ can only be temporarily rational), unless, (a) w = o and g o, and therefore the condition holds good for all the normals in the zone [ooi] for which efo is the symbol so long as e andy are integers or one only of them o. It holds therefore for the normals of the faces 100 and oio : and (b] it is true also for the normal of the face ooi, since it is true for the case where u = v = o = -/) = (n-i)S. So long as 6 is irrational this can only be true provided either that nfe = o, ng-f= o, and 6" = o = t+/+g t I 2 1 1 6 Res^d^lary cases. U V "WT that is, -== , where e +/+ g = o ; * / g or that / * = o, ngf o, and n i = o = w' i ; that is, u = v = w and * ==./'= " There are therefore two cases that here arise in which the coincidence of face-normals and zone-axes is possible ; the one is the case of all normals of faces the indices of which fulfil the con- dition e +f+g = o, i. e. for the normal of every face in the zone [111]; and the other case is that of this zone itself, the axis of which is the normal of the face (in). 100. VI. It will have been noticed that the cases in which the coincidences under consideration are the more numerous are those in which the greater number of the axial elements are fixed in their values, and that in case IV, where only a single zone-plane was parallel to a face of the system, two of the axial elements were fixed. And all remaining cases that may be conceived will be found, where they present any zone-line coincident with a plane-normal, to resolve themselves into one or other of those already discussed. Thus, for example, if we take we have to eliminate the cosines of f and f from the equations P, and we get u wcosrj &* v w u cos 77 _(U + W)(I-COST?) u + w e+g , a* , i x or M = , where M = -jol* *) v / ^ 5 and is irrational ; and the equation is satisfied if v = o, /=o, and if u + w -o, *-(- = o, i.e. if w= u, g e. In the case supposed then there will occur at least one case of a coincident symbol for a zone-line and a normal, that, namely, of the normal to the plane (*o^) or lol. But this normal must of The kinds of crystalloid symmetry. 1 1 7 necessity bisect the arc Too,ooi, since the parameters a and c are equal; and the normal 101 will bisect the supplementary arc 100,001. And the zone [oio] is thus symmetrical to the two perpendicular planes 101 and lol : and, since the axis of that zone is also perpendicular to the normals 100 and ooi, and therefore to 101 and roT, the case in question resolves itself into one presenting identical conditions with those discussed under case III of this article. The assumption of irrationality of the parameters and of the cosines of the axial angles, on which the reasoning in articles 97, 98 and 99 is founded, involves statements regarding physical characters which, while true of a crystal, have no place in a plane- system that is simply crystalloid. For the discussion of the principles involved in the parallelism of zone-axes and normals in a system of the latter kind, see a memoir by H. J. S. Smith, Savilian Professor of Geometry, in the Proceedings of the London Mathematical Society, vol. viii. Nos. 109 and no, an abstract of which is given in the Proceedings of the Crystallogical Society, Phil. Mag. y Ser. V. vol. iv. p. 18. 101. Conditions for more than one plane of symmetry. It has been seen that the conditions necessary for a single plane to be a plane of symmetry to a crystalloid system, namely, that it be at once a zone-plane and parallel to a face, are not sufficient to impart to a second plane the character of a plane of symmetry. Such a second plane, in fact, must furthermore be inclined on the first plane, and therefore also on every other plane of symmetry, at one of the crystallometric angles. The method of reasoning adopted in article 90 suffices to prove that every plane of symmetry to a crystalloid plane-system must be also, by that fact, the plane of a zone : and it is shown in article 96 that two planes of symmetry must always belong to an isogonal group in the zone that contains them. In fact, if S l be a plane of symmetry and Sj be a plane of the system, Sj will be symmetrically repeated over S 1 ; and where the two planes are inclined at a crystallometric angle, the zone [*S*2] will be isogonal as regards the repeated planes and symmetrical to each of them. And by article 63 the zone will further be sym- 1 1 8 Crystals planes of abortive symmetry. metrical to a series of planes perpendicular to the planes 6" and 2, and therefore also included with them in an isogonal group harmonically dividing the zone : indeed in all cases except where < = - these supplementary planes will each fall into coincidence o with one or other of the planes *S" or 2. It is evident that in this case each of the planes of the isogonal group is at once parallel to a face and to a zone-plane. And each will, in accordance with the reasoning in article 90, be potentially a plane of symmetry to the entire plane-system. That a plane inclined at other than a crystallometric angle on a plane of symmetry cannot be a true plane of symmetry to a plane - system may be seen by considering the class of cases that have been already alluded to in articles 98. I and II a, and 99. V; in which a series of tautozonal planes fulfil the primd facie conditions for being planes of symmetry to the zone they lie in, while, from the plane of that zone being parallel to a possible face, it might be assumed that all or some of them would be planes of symmetry to the entire plane-system. And yet they are not true planes of symmetry either to the system or even to the zone ; for the reason that they are not inclined at crystallometric angles on certain planes belonging to the zone, which, being at once (like the planes in question) zone-planes and parallel to faces, are on the other hand unlike those planes in belonging also to an isogonal group, and so being established in the position of true planes of symmetry alike to the zone and to the entire plane-system. 102. Planes of abortive symmetry. The cases just alluded to, in which all the planes lying in a zone may in unison with other planes perpendicular to them (in accordance with article 63) ortho symmetrically divide the zone, need some further consider- ation. It is clear that for any plane belonging to such a zone the symbol of another plane can be calculated that shall be rational, provided this second plane is equally inclined with the first on some third plane belonging to the zone. In fact, the symbols of the three planes will, with the symbols of a plane perpendicular to the last, form a harmonic ratio. Every plane of the zone would in short fulfil the first condition of a possible plane Abortive symmetry. Case I. 119 of symmetry to the zone ; and by virtue of a plane perpendicular to it, and of the plane of the zone itself being both planes of the system, each plane of the zone would seem presumably to be a plane of symmetry to the entire plane-system. But such presumptive planes of symmetry are evidently pre- cluded from really possessing symmetral characteristics by the principle that if they were actual planes of symmetry they would of necessity be recurrent ; whereas if they were so they would mutually repeat each other in numbers without limit, since their angles of mutual inclination cannot be commensurate with n. For it is the essence of a plane of symmetry, actual or potential, that all the morphological features of a zone or of any form be not capriciously or partially, but systematically, or not at all, repeated in respect to it. Where a plane may hereafter be spoken of as only potentially a plane of symmetry, it will be implied that its influence on a form is as it were suspended or in abeyance in respect to the entire form. In the cases under consideration however a zone would contain an indefinite number of planes; and the faces of a form would be repeated at an ever-increasing variety of angles : from a plane-system we should pass to a solid with a curved surface. Symmetral characters in planes of the kind under discussion cannot therefore be spoken of as being merely in abeyance : they are impossible, and such planes are con- sequently abortive as planes of symmetry, and that for the reason that they are not inclined at crystallometric angles on certain particular planes which in a crystal are naturally selected from among the possible planes of the zone as true planes of morpho- logical symmetry. 103. The several cases of abortive symmetry. In articles 98 and 99 the whole of the cases have been recounted in which planes of abortive symmetry occur. Case I in that article pre- sents an entire plane-system the faces of which are all such that they are parallel to possible zone-planes ; and it will be seen that these faces, when a system of this kind falls under consideration, will divide themselves into such as are parallel to true systematic planes (of symmetry) and such as cannot be parallel to such planes nor be inclined on them at crystallometric angles. 1 20 One zone of Case II, one of Case V. The other cases are those of case II, article 98, and case V, article 99, which however are each confined to the faces of a single zone. In either case we shall find that the true planes of sym- metry in the zone have a crystallometric angle less than - : such, in fact, are the only cases not included under case I in which we shall meet with zones of this kind. The point under discussion is sufficiently important to receive illustration from an example, which may be taken from the second case in article 98. In that case the plane oo i is parallel to the zone-plane containing the axes X and Y and also the poles 100 and oio which lie on the normals of the planes YZ and ZX ; the parameters on these axes being equal. Conse- quently, two planes 2 1? 2 2 , Fig. 40, perpendicular to each other bisect the right angles between the planes ZX and YZ which may be designated S l and S 2 , Fig. 40. and these four planes are successively inclined at 45, and will be recognised in a future article as the planes of symmetry for the zone [ooi] and also for the whole plane-system. A pole p 1 on the zone-circle [ooi] will be repeated over the plane 2 X in a pole //, and this over the plane S 3 in a pole p z ; and the angle 100 on pi equals the angle oio on / 2 , and the arc p 1 p z is a quadrant. So /j fulfils the primary condition for being a plane of symmetry to the zone. In fact, if we assign a rational symbol, say 320, to the pole^, then a pole q^ equidistant with 100 from p l must have a rational symbol. In fact, the symbol of />/ will be 230, and of p 2 will be 1230, and the ratio is harmonic, and 100 100 Types of crystalloid symmetry. 121 230 hko 230 IOO 320 hko 320 IOO whence 5/6 = i2h, and the symbol of ^ is 5 12 o. Now taking the poles 100, p lt 110,010, by the problem of four planes, the arc 100,^ = 334i' = A?i and the arc^, oio = 2237 / . So that if^ were the pole of P a plane of symmetry, this plane P and the plane S l would be mutually repeated at angles of 3 3 41', while with ^ and S 2 , P would form a series of planes inclined at n 19" and 56 19', while Q the plane of which q is the pole would furnish repetitions with these planes at again new angles. It would be futile to pursue such repetitions into their results. In a word, the zone can exhibit no symmetry other than to the planes and 2. 104. It has been established in the preceding articles that in order for a plane-system to be symmetrical to more than one of its planes, each such plane must be parallel to a possible zone- plane and inclined on each other plane of symmetry at a crystal- lometric angle. It is however to be observed that where this condition is fulfilled by two planes of an isogonal group in a zone that are not supplementary, it is necessarily true of the remaining planes belonging to that group. We may now proceed to discuss the various kinds or types of symmetry which result, in the first place from assuming different crystallometric angles between planes in a zone fulfilling the above conditions, and in the next place from the discussion of the problem of the possible modes in which such isogonal zones are capable of intersecting with each other. CASE I. The type of symmetry where (b = - 2 105. The first case to be considered will be the simplest, that namely in which two planes of symmetry are perpendicular to each other. If there be two and only two planes of symmetry and 2, 122 Two Symmetral planes perpendicular. Fig. 41, in a zone, these must be perpendicular to each other and divide the zone-circle or tho symmetrically: and the zone-plane C containing the normals of the two planes will be parallel to the face in which their two zone-circles intersect and be itself potentially a plane of symmetry. And the three zone-lines j/, o-o-', cc, which are the normals as well as origin-edges of the three planes S, 2, C, will, where the plane C is an actual plane of symmetry, be axes of orthosymmetry to the system. And it will further be seen that the system will, as a consequence of its symmetry to the plane C as well as to S and 2, be centrosymmetrical. The conditions of symmetry assumed in the particular type under discussion preclude the possibility of other than two per- pendicular symmetral planes in either of the zones [S2], [2C], or [CS]. And they therefore preclude the possibility of a pole of any form lying on a great circle that should bisect either of the right angles formed by the intersection of the planes (or zone-circles) S, 2, C, and therefore also of a pole bisecting any of the quadrantal arcs connecting the poles of the .planes S, 2, C. For if such a pole existed, e.g. if a pole m 1 were to bisect one of the quadrants on the great circle [C] between the poles of the planes S and 2, a great circle [m 1 c~\ would bisect the angle 2 and would be perpendicular to a second zone- circle \cm\ bisecting the supplementary right angle of 2, and these two zone-circles thus intermediate to, and equally inclined at 45 on 6" and 2 would each be potentially a plane of symmetry to the system ; and this would superpose a fresh condition to those assumed for the type of symmetry under discussion; so that the plane-system would in fact belong to another and a more complex type of symmetry than that to only three perpendicular planes. In the type under consideration, therefore, any independent Systematic triangle. 1 2 3 pole p must be situated asymmetrically, that is to say, at a point on the sphere of projection the distances of which from the great circles S2 and C must all be different ; wherefore, every plane of an independent form (to which such a point p would be the pole) must be inclined at different angles on the three planes of sym- metry and will meet their zone-axes j/, cro-', cc at different distances from the origin. 106. The systematic triangle. The necessity for this unsym- metrical or eccentric position of the pole in a case where three adjacent great circles of symmetry so intersect to form a spherical triangle as that other great circles of symmetry are precluded from invading the triangle, is not confined to the case in which the triangle is quadrantal. It in fact is true for every spherical triangle formed by the intersections of adjacent great circles of symmetry. And it will be well therefore to make a brief digression, in order to give form to this principle. Evidently a spherical triangle of the kind in question will have for each of its angles an axial-point in which a zone-axis of a zone of symmetry-planes and is consequently an axis of symmetry meets the sphere of projection ; while, further, each such point is the pole of a possible face. DEF. A spherical triangle formed by the intersection of ad- jacent planes of symmetry with the sphere of projection, and which therefore may not be intersected by any other circle of symmetry, will be termed the systematic triangle for the particular type of symmetry to which it belongs and which moreover it charac- terises; since it is not conceivable that the surface of the sphere should be symmetrically subdivided into systematic triangles of more than one kind. 107. The general independent form is a scalenohedron. It is obvious that one and only one pole of a form can occur in each systematic triangle, and that the position of this pole in every such triangle will be the same relatively to corresponding sides and angles. It is also evident that the angles of a systematic triangle can have only crystallometric values. Furthermore, since from the nature of a systematic triangle no two of its sides can be in a crystallographic sense homologous, 1 24 General Scalenohedron. Type ^ -. and since the edges of adjacent faces of an independent form drawn in equipoise will lie in the several planes to which those faces are symmetrical, the edges of each face will necessarily be three in number and will all be dissimilar ; so that every face of such a general independent form will have the character of a scalene triangle. Such a general form therefore, in every case where the type of symmetry admits of a systematic triangle, may be termed a general scalenohedron of the system. 108. Systematic triangle and axial system where <\> = -. The systematic triangle in the case last under consideration, that namely of three perpendicular planes of symmetry, will be formed by three quadrantal arcs of the great circles S, 2, and C, and be represented by the expressions TT o = 2j = L = 5 2 s = o- = c = 90 ; S, 2, C being the arcs that form the sides; s, o; c the angles opposite to them, of this quadrantal triangle. Taking the three planes of symmetry for the axial planes, their normals become the axes for the polyhedral system and the axial octants coincide with the eight systematic triangles. The octants and the systematic triangles adjacent to each other, and the faces of any form of which the poles lie in them, will evidently be anti- strophic in the character of their symmetry, those belonging to attingent octants will be metastrophic. The axes being the zone-lines or origin-edges [SO], [2], [2S] are dissimilar, since from 105 it is seen that no plane is possible in the system which intersects any pair of these axes with equal intercepts ; so that equal, and therefore commensurate, parameters are equally precluded. For the purpose of uniformity in the representation of crystals that accord with the same type of symmetry, it will be desirable to assign an ' orientation ' of a definite kind to the different axes ; and for this purpose in the type under consideration the order of the magnitudes of the parameters will be adopted. Thus the longest parameter will be that assigned to the X axis, the mean to the Y axis, and the least to the vertical or Z axis. Forms are or tho symmetrical. 125 The expression representing the axial system will therefore be in which the parametral ratios a\b\c are unfettered by conditions and may be different for each distinct system of planes conforming to this type of symmetry. The remaining three permanently fixed elements of the axial system are therefore engaged in satisfying those conditions which all plane-systems must fulfil in order to be- long to this type of symmetry ; the conditions namely that a plane of the system is the plane of a zone symmetrical to one of its planes, or, as a consequence, that the plane-system is symmetrical to three perpendicular planes which are also zone-planes. 109. The character of a form. As each octant is conterminous with a systematic triangle, eight faces will be comprised under the symbol of an independent form {hkl} ; see Fig. 42. And as the intercepts on any one of the several axes will have the same value for every face of the form, the position of the indices in their symbols will not admit of permutation ; the signs of these will however change, following those that designate the octant in which a particular pole may lie ; and therefore undergoing every possible interchange, the eight planes are therefore hkl, Jikl, hkl, hkl, Tkl, Jikl, hkl, JiTl. The position of the axes in this system being so taken that the zone-lines [SC], [2CJ, and [S2] are the axes X, Y, Z respectively, the plane S has for its symbol (oio), 2 is (100), and C is (ooi). The prismatic forms {hko}, {hoi}, and {okl} are constituted each of four planes, the first form being technically termed a prism; the other two, domes (from the Greek fioyia). Thus the dome-form {101} comprises the planes (101), (loi), (iol), (i~oT). The parametral form { 1 1 1 } is a scalene octahedron. The symbols of 126 Type < = - ; five symmetry planes. CASE II. The type of symmetry in which < = - 4 110. The case next to be considered involves the condition precluded by the conditions of the last case, which required two adjacent planes of symmetry to be perpendicular to each other. If a pole be recognised as possible on a great circle that would bisect an angle and the quadrantal side opposite to it of the systematic triangle in the case last considered, we admit the con- dition that a face of the system may be equally inclined on and intersect with equal intercepts two of the axes, for instance, the axes X and Y ; for this would evidently be true of every plane the pole of which lies on such a great circle. Then the pole in question will with the pole C (or ooi) serve to designate a zone-circle intersecting with the great circle C in another pole equidistant, that is to say, separated by an arc of - 4 from the poles of the axial-planes ZX and FZ; see Fig. 42. The plane corresponding to this last pole would thus be inclined at the crystallometric angle of - on each of the two perpendicular 4 planes of symmetry S and 2 characteristic of the last considered type. It, and obviously also a plane perpendicular to it and also lying in the zone [S2], would therefore each fulfil the necessary conditions for a plane potentially symmetral. Adjusting the letters to indicate conformable planes of sym- metry, it will be seen that we have in the case under consideration two proto-systematic perpendicular planes S lt S 2 alternating with two perpendicular deutero-systematic planes 2 A , 2 2 , tautozonal with the planes S and forming with them an isogonal zone with the crystallometric angle of 45. Each pair of planes S and of planes 2 will be conformable inter se, but unconformable each with the other. And the plane C of the zone-circle [S2] will also be potentially a trito-sys- tematic plane of symmetry to the system unconformable with both the pairs of planes and 2. Moreover, it will be evident that the poles of a form on either of the hemispheres divided by the equatorial plane C will be repeated in the same manner of The tetragonal Scalenohedron. 127 distribution on the opposite hemisphere, whether the repetition be due to the system being centrosymmetrical or to the influence of the plane C as an actual plane of symmetry. The sphere of projection will be divided by the five planes A^ , 2 X , S t , 2 2 , and C into sixteen systematic triangles, each having two of its sides S and 2 quadrants and the third side C = - 4 The systematic triangle will therefore be represented by the expression e v r ^ o=2/ = ? C = j 2 4 s = o- = 90, c = 45. 111. The distribution of the poles of the tetragonal scalenohedron. If under any type of symmetry the letters designating the sys- tematic triangles be read in one order of rotation (e. g. that of the hand of a clock) it will be seen that these triangles fall into two groups indicated by letters taking the order, in the one group ccrs, in the other group csv. The triangles of the one group and the faces whose poles lie within them are mu- tually metastrophic, but are antistrophic to those of the group designated by letters in inverse order to theirs. Thus if in the type under consider- ation the poles in the group of triangles cscr be designated as p lt /> 2 , &c., and those in the triangles ccrs as //, //, &c., the scalenohedron {p} will consist in the assemblage of the faces AAAA> P\ / 2 /s /*> AAAA> P\ p\ P\P\\ wherein the minus sign is used to indicate poles on the lower of the hemispheres divided by the plane C, and the faces be- 43- 128 A morphological axis. longing to the poles p are antistrophic to those belonging to the poles /'. 112. The axial system for this type. The necessary conditions for the type of symmetry under discussion are four in number, and may be embodied in the statement that a plane of the system is a zone-plane, and that a second plane of the system also parallel to a zone-plane is inclined on the former plane at 45. Of the five elements constituting the axial system four will be constants occupied in satisfying these conditions, a single element only remaining to vary with the particular system of planes. As in the previous case, three of the perpendicular planes of sym- metry, namely the two planes S and the equatorial plane C, are taken as axial-planes, the zone-axis [S2] becoming the Z axis, and the zone-axes \Sf\ [S 2 C] the axes X and F, respectively. While any plane having its pole situate on one of the zone- circles [2] will meet the X and Y axes with equal intercepts, such a plane will, under the conditions assumed for this type of sym- metry, meet the Z axes at a distance incommensurable with the intercepts on the axes X and Y\ that is to say, the parameters a and b are equal but are unequal to and generally incommensurate with the parameter c. Hence also there can be no pole on a great circle bisecting the quadrantal arcs S or 2 of the systematic triangle or the right angles which they subtend. Taking then for a parametral plane a face belonging to the zone S l , the axial system is represented by the expression f = ?? = C=9> a = b ^ c. The symbols of the axial-planes will be for S 1} S^ the poles of which lie on the Y and X axes respectively, oio and 100; the symbol for the pole of the plane C which will lie on the Z axis being ooi. DEF. Where two or more planes of symmetry lying in a zone are conformable, their zone-axis will be termed a morphological axis or axis of form for the system ; and where there is only one such axis to the plane-system, the plane (potentially symmetral) to which this axis is the normal will conveniently be termed the equatorial plane. Symmetry of forms ditetragonal. 129 In the type of symmetry under discussion the morphological axis is an axis of tetragonal symmetry for all forms of the system, since two congruent planes of symmetry perpendicular to each other intersect in this axis; and when the symmetry is complete it is ditetragonal. Of each zone-circle S and 2 the two hemizones on either side of the morphological axis are similar. 113. Symbols for forms of tetragonal type. Each octant of the axial system is composed of two systematic triangles t antistrophic to each other, in which the order of the indices, like that of the letters indicating the systematic triangle, will be direct for metastrophic, inverse for antistrophic planes. Hence the indices h and k relating to the similar axes X and Y will be interchanged in position in the symbols for the two faces of a form {hkl} that lie in the same octant ; the position and value of the index / re- maining unchanged, except that its sign is + or according as the face intersects with the axis Z above or below the origin ; see Fig. 44. K 130 Symmetry-type, cf) = - ) The symbols of the faces of the general scalenohedral form will therefore be hkl khl, hkl 'khl, Jikl Yhl, hll khl, hTl khl, hk~l khJ, hkl khl, hkl ~khl. If the poles lie on the zone-circles 2, h and k do not differ in value, and the symbol of the form is {hhl}, which is an isosceles octahedrid form and, for the parametral plane, becomes { 1 1 1 } ; while the zones C and 2 are tautohedral in the faces of a four- faced form {no}. If the poles of the form lie on the zone-circles S, the symbol is {hoi}, and the form has the eight faces h o I, oh I, hoi, oh I, hoi, oh I, hoi, o hi. And the symbol for a form consisting of eight poles distributed on the zone-circle C will be {hko}, all the faces being parallel to the axis Z. The angles between planes belonging to this zone will be constant for all plane-systems presenting this type of sym- metry. The zone-axes [SC] and [2C] are, as in the type of symmetry previously discussed, axes of orthosymmetry, since they are the intersections of two perpendicular planes of symmetry. The abortive character of the symmetry which every plane in the zone-circle C simulates has already been exposed in article 103. It is only in the case of the systematic planes that this symmetry is real. CASE III. The type of symmetry in which = - 114. We have next to enter on the consideration of the case in which a plane of symmetry is inclined on another plane of the system at the angle = Here therefore there will be two planes of symmetry S^ and S. 2 inclined to each other at 60, which will be mutually repeated in a third plane S 3 symmetrical to each in respect of the other and inclined on both at 60. Three simultaneous tautozonal planes S lt S 2 , S 3 result; their common zone-line being a morphological axis for the system of planes. This axis divides the zone-circles into hemicyclically conformable Potential symmetry-planes. 131 hemizones. And the great circles [S] divide the sphere of pro- jection into six lunes, the alternate lunes becoming congruent by a revolution through 120 round their zone-axis as an axis of trigonal symmetry. 115. Distribution of the poles of a form of trigonal type. A form of a system symmetrical to three such planes will present,, if/ be an independent pole, six poles / ditrigonally grouped round the axis of form : viz. p lt p\, p 2 , p' z , / 3 , />' 3 , as in Fig. 45, in which the poles on the nether hemisphere are indicated by eyelets, those on the hitherward hemisphere by dots. If the pole lie in a zone-circle S, there will be but three such poles, viz. r lt r 2 , r s , or f lt / 2 , /,. Since however the form is to be generally assumed to be centro- symmetrical, and therefore diplohedral, there will be six addi- tional poles p in the former case, or three new planes r or / where they lie on the zone-circles S. There are, thus, the poles A> /i, A, / 2 > A> / 3 ; A> /i> A /2>_ A / 3 ; and r lt r^ r 3 , r^ r 2 , r 3 ; or / t , /, / 3 , 7 15 / 2 , / 3 . Since the zone to which the planes S belong is symmetrically divided by these three planes, it may therefore, by article 101, also be symmetrical to three new planes 2, each perpendicular to one and inclined at 30 on the other two planes S; and these planes 2 will thus be also potentially planes of symmetry for the entire plane- system : as is also the equatorial zone-plane C. Hence, that these planes 2 or the plane C may become actual planes of symmetry entails no condition that is not involved in those originally assumed in this case ; a point in which the type of symmetry now being considered differs from the otherwise somewhat analogous case where two intermediate planes of sym- metry are equally inclined on two perpendicular symmetral planes. K 2 132 Type $ - merged in Type

= - 117. The discussion of the last case shows that no new fundamental conditions will have to be assumed in order to pass to the consideration of a plane system in which a plane of sym- metry is inclined at the crystallometric angle of on another plane of the system which is at the same time a zone-plane. It is in fact the case in which the symmetry resulting from a plane parallel to a zone-plane and to a face being inclined at the angle - \j on a plane of symmetry has received its complete developement : it is the case, namely, in which the latter kind of plane system is symmetrical simultaneously to its centre and to its equatorial plane ; and in which as a consequence the planes 2 influence the system as a triad of planes of actual symmetry (of deutero- symmetry). The polyhedron thus becomes symmetrical to seven planes, namely, to one triad of proto-systematic planes S, a triad of deutero-systematic planes 2 unconformable with the planes S, and to the equatorial plane C as a trito-systematic plane. These planes 2 lf 2 a , 2 3 are then perpendicular each respectively to one of the planes S lf S 2 , S s and inclined at 30 to the other two, their mutual inclination being 60 : the systematic triangle where the symmetry is thus complete being represented by the symbol S = S = -, C = l, 2 6 s = o- = 90, c 30. It will be seen that the sphere of projection is partitioned into twenty-four such triangles. The number of fa.ces presented by an independent form is therefore twenty-four. And the morphological axis [-5*2] becomes an axis of hexagonal or generally of dihexa- gonal symmetry. The conditions which the crystalloid axial system and therefore also the particular polyhedral system that is to accord with such A. rectangular axial system. 135 an axial system has to satisfy are embodied in the statements that a plane is to be at once a plane of the system and a zone-plane, and that it is to be inclined either at - or at - on a second plane which must be parallel to a face of the system. In satisfying these conditions four out of the five axial elements will be em- ployed, one only being left, as in the case where the morpho- logical axis was tetragonal, to vary with the different varieties of the plane systems. 118. Axial Systems. Various axial systems may serve for the geometrical treatment of such a polyhedral system. Thus : (1) Three of the planes of symmetry, perpendicular to each other, e.g. S l} 2 1 , and C, may be taken as the axial-planes; and if C be taken as parallel to the plane ooi and therefore the morphological axis be the axis Z, a plane the pole of which lies on the zone-circle S 3 may be taken for the parametral plane ; or the plane S 2 may be taken to determine the parametral ratio for the axes X and Y\ this ratio having therefore the constant value j = A/3 ; while another plane the pole of which lies in a great circle S 1 or 2j will serve to determine the parametral ratios - or - for the axis Z. The axial elements would thus be represented by the ex- pression f=i? = C=- a : 6 : c, 4/3:1 :c; the paramental ratio for the axis Z being the single varying element. Such an axial system, the details of which have been elaborated by Schrauf (Sitzb. d. k. Acad. Wien, 1863), presents the insu- perable disadvantage, that while the three planes of symmetry S divide the sphere symmetrically with respect to a trigonal axis, the axial-planes so divide it that congruent lunes are not similarly situated in regard to the axes, so that even the simplest trigonal forms have to be represented by double symbols. (2) This difficulty of representing by a single symbolical ex- 1 36 Isoparametral oblique axes. pression even the simplest and most frequent forms of a crystal presenting trigonal or hexagonal symmetry, when its forms are referred to rectangular axes, led to the adoption by some crystal- lographers of an axial system itself according with this symmetry, the three proto-symmetral planes being taken with the equatorial plane C as axial-planes. Thus, their intersections form four axes to which the system of planes is referred, three of these presenting an axial-angle of 60 with each other and being perpendicular to the fourth which is the morphological axis. Since however three points are sufficient to determine a plane, an axial system by which a plane has in fact or virtually to be represented by four points involves an element in excess of what is needed. The further discussion of such an axial system will be entered on in a future chapter. 119. The axial system of Hauy and Miller. On the other hand, an axial system more in accord with geometrical method is provided by the selection for axial-planes of three origin-planes parallel to faces of the system, symmetrical in regard to and therefore equally inclined on the morphological axis ; the poles of which planes lie on the great circles of proto-symmetry S. Thus, r x being the pole of a plane R^ and lying on the zone-circle [SJ, two other poles r 2 and r 3 , poles of planes R z and R z , will lie on the alternate hemizones of the zone-circles [S 2 ] and [S s ~\, equi- distant with r x from c the pole of the equatorial plane C. Accordingly the zone-axes [r 2 r a ], [rjrj, [i^rj which are the edges of the planes R Z R Z , & 3 R l} and R^R^ become the axes X, Y) Z, and the axial-points A x , A 2 , A 3 in which they meet the sphere will also be equidistant from <:, on the same side with r lf r 2 , r, respectively on the circles [S^], [S z ], [S 3 ]; and they will only coincide with the poles TJ, r 2 , r 3 in the case in which the planes R and therefore their edges also are perpendicular to each other. This however involves a condition that would remove the system of planes into another type of symmetry, in which not only would the parameters be equal, but the axial-angles would, besides being equal, become right angles. In fact it will be seen hereafter that tan arc r^ = 2 cotan arc Aj c % Twenty-four systematic triangles. 137 so that where r^ and Aj coincide r^c \c = 54 44.14' and r^ 2 = \ 1 \ 2 = 90. 120. That in the axial system under consideration the parameters will be equal is involved in the statement that the pole c is equidistant alike from the poles r and the axial-points A.. For then, evidently, a face parallel to C, the equatorial plane, meets the axes with equal intercepts and serves as the parametral plane in or III; the former symbol being taken for that lying in the upper hemisphere on C. Such an axial system as that here defined will be represented by the expression =i) = f f a = & = c; where the required four conditions are satisfied by an equal number of the axial elements, and only the particular angle TJ at which the axes are inclined remains a variable element character- istic of the particular system of planes. Great circles passing through each pair of the axial-points XYZ, X Y Z will divide the sphere into octants, two of which, XYZ and X Y Z, are similar, while the remaining six, viz. ZXY, YXZ, XYZ, are also similar to each other but in ' zig-zag/ that is, alternately inverted in their position on the sphere. It will thus be seen that the systematic triangles are not co- terminous with the octants formed by the axial system : and, as a consequence, the symbols of a complete hexagonal form will in certain cases have a double character. Thus of the general scalenohedron, one pole will lie in each of the twenty-four systematic triangles : but the poles lying in those adjacent pairs of triangles that have in common for one of their sides an arc S containing one of the axial-points X, Y, Z or of the poles 100, oio, ooi, will have different intercepts on these axes from those of the planes the poles of which lie in the triangles which in pairs alternate with them. Hence the symbol for the general form will be of a double kind; the poles corresponding to those of a simple trigonal form retaining in their symbol indices which will be distinct from those in the symbols for the poles of the other 138 General 2 /[.-faced Scalenohedron. trigonal form correlative to the former, and which united with the former complete the form in its hexagonal type. Retaining the letter p for the general trigonal form and desig- nating the trigonal form correlative to it by the letter q, the general symbol for the completed form will be {pq}. The dis- tribution of the poles, including certain of those on the negative hemisphere, is seen in Fig. 47. They will be AAA, P\P\P'*> the faces in the two left-hand blocks being, as in article 109, antistrophic to those in the right- hand blocks, while the faces the symbols of which lie in either block are mutually metastrophic. The six poles r and six poles / in Fig. 47 unite to form a double form {rt}, the poles of which lie on the proto- systematic great circles S ; while the poles u, alike twelve in number in the trigonal (article 115) and in the hexagonal type, constitute a form of which the poles lie on the great circles 2. The poles of a form m on the great circle C will also be twelve in number in the hexagonal as in the trigonal type of symmetry. The poles of the proto-systematic plane S are six, lying in the zone-axes [2 C] on the great circle C, namely, ^li S 1> S 2> S 2> S 3> ^3 J those of the planes 2 being "i> o^'i, " 2 > a 'v "s> "'s on the axes [SC]-, while the zone-circle C has two poles c and /. 121. Symbols of the different forms. The poles r lf r a , r s of the Fig. 47. Symbols of planes of symmetry. 139 axial-planes R^R^ R^ must have for their symbols 100, 010,001; and since (in accordance with the principle established in article 99) the planes of symmetry [S] which pass through these poles and the pole c or 1 1 1 have the same indices in their symbols as the zone-axes have which are their normals, their symbols are, severally, in for ,, , i.e. on or on ; 100 for 6*2, loT or Toi ; and for S 3 , ilo or Tio. Of these symbols, by article 45 the former of the two will in each case be that of a pole lying on the same side with 100 of the great circle passing through the poles in and oio, the latter will be the poles lying on the same side of that zone-circle with the pole ooi. The symbols of the planes 2 lf 2 2 , 2 3 , the poles of which lie in the intersection of the zone-circles S and C, are, of 2 X , "21 1 or 2!!; Fig. 48. of 2 2 , 121 or 121 ; and of 2 8 , 112 or 112. And of these the former will be the symbol of the poles lying on the same side with ooi of the zone-circle passing through in and ilo. The symbols will then be distributed as in Figs. 48 and 49. 140 Zone of abortive symmetry -planes. The symbols of all the axial-points forming the angles of the systematic triangles having been determined, we may proceed to consider those of a pole lying on one or other of the sides of the systematic triangle. With respect to the symbol of any form of which the poles lie on the zone-circle [m], it is evident that the sum of the three indices is zero ; i. e. the symbol has to fulfil the condition p + q + r = Q or p=q r. And this is precisely the zone which corresponds to one (namely to Case V) of the two cases in which it was shown in articles 98 and 99 mm. that a plane-system might present a zone which could be con- ceived as being symmetrical to each of its planes, all these planes being parallel to possible zone-planes. In respect to these planes however it was shewn that this symmetrical character can be only abortive where the planes in question are not inclined at crystallo- metric angles upon any of the systematic planes S or 2, that is to say, must be so for all planes other than these. In considering the arcs S forming the sides of the systematic triangle we shall have to distinguish between those which contain the poles of the form {100} and those which do not; since the poles of this form on either of the hemispheres that stand on C lie Symmetry of a form di-hexagonal. 141 only on the quadrantal arcs S of alternate systematic triangles. Now whereas the symbol of any pole lying on the great circle [-SJ i.e. [oil] which traverses the pole r lt must fulfil the condition kl=o, it is clear that the symbol must be of the form mnn\ and if it lie on the positive side of the great circle [in], m + 2n must be greater than zero ; if, again, it lie on the same side of the great circle [2!!] with the pole 100, 2m2n>o and m>n; and if it lie on the other side of [2 IT], m < n. Forms fulfilling the former condition will be termed direct, those fulfilling the latter will be termed inverse. If the pole r 1 for which m > n have for its symbol (hkK), and the so-called ' transverse ' pole / equidistant with r from in on the other side of in, and therefore also homologous with r, be (eff\ then / 1? / 2 , / 3 will be three poles homologous with and severally correlative to r lt r 2 , r 3 , that is, to (hkk\ (khk], and (kkti). Now /j will be symmetrical to r 2 in respect to the plane 2 3 and to r s in respect to the plane 2 2 , and a great circle passing through /, and r z will also pass through i il ; / x therefore is the pole in which the two great circles [112^ oio] and [oil] are tautohedral and the indices in the symbol (eff) are ^kh, k+zh, k+2h. Thus, for example, the poles correlative to 100, oio, ooi are 722, 212, and 221". Hence the six homologous poles r and / lying on the great circles S on one side of the zone-plane C will have their two correlative triads of symbols connected by the relation just estab- lished between the symbols hkk, khk, kkh and the symbols eff, fef, ffe ; and on the opposite hemisphere the symbols of planes parallel to these will only differ from them in having opposite signs. The symbol for a pole (min) lying on the side 2 of a systematic triangle is characterised by one of its indices being the arithmetic mean of the other two. Thus, a pole hkl lying on the great circle [2J, i.e. on [2!!] or [211], must fulfil in its indices the condition 2hklo or 142 Composite symbol for scalenohedr on. k + / where h - For a pole situated on the positive side of the zone-plane C, i.e. of [in], h + k + l > o or k + l > o; and if it be also situated on the same side with oio of the zone [oil], k I > o, that is k > /. Whence if min be the symbol of a pole u where m > n and z'= - , the poles on the upper or positive hemizones of the great circle 2 2 are mtn, m'm, 2 X imn, tnm, and on 2 3 mni, nmi; the poles on the nether or negative hemisphere of faces parallel to these having their signs reversed. 122. Composite symbol of the general di-scalenohedron. Of the general independent form hkl a face lies eccentrically in each of the twenty-four systematic triangles of the hexagonal system. If the pole hkl\)Q that lying in the triangle cv^'^ Fig. 47, the pole symmetrical with it in respect to the plane S l will lie in the triangle ca l s 3 on a great circle passing through the poles oil and oTi : and since the positive sides of the great circles [aTI] and [in] are those containing the pole 100, the symbols for the poles in the two systematic triangles in question must satisfy the conditions zhkl>Q and h + k + l > o, or 2h>(k + l)' and h>(k + t). So that the first index must be greater than the other two ; and as h > k > / is the assumed order of magnitudes of the indices, the first index is h in the symbols for both the poles. So again the pole hkl is on the same side with oio of the great circle S 1 or [oil], and therefore the second index is greater than the third, while for the pole lying in adjoining systematic triangles the third index is greater than the second. Hence the symbols of the poles in the triangles cv^s'i and ro-jjg are hkl and hlk, and in C(T z s \ an d cv^'^ are khl and Ihk, C(T Z S\ and co- s s t are klh and Ikh. Symbols of correlative semiforms. 143 The symbol of the pole q transverse to and correlative with a pole/ or (hkl) may be readily found by the problem of four planes. It lies on the zone \J>c\ t i.e. or [k /, / h, hK\, at a distance qc=ipc=0 from c. And as this zone will intersect with the great circle [in] in a pole d, or (pqr), the symbol of which will be 2 h-k-l, 2 k I h, 2l-h-k, m n cd ^~ (article 49), k} sin 6 cos / /A h k 2sin0cos0 2' and the indices in the symbol efg of the pole q are obtained by equations P, article 49. They are, substituting the values obtained for/^r, e = npmh = 2(-{- /)//, g = nrml= where t c, also/" = 3/ 3/^, where, / being greater than l,f /, also q > r, So that the absolute relative magnitudes of the indices are / > q > r for all poles not lying at the intersections with C of the great circles S or 2 ; and these for the axial points at the intersections of the zone-circles give q = r = i, while those at the inter- sections of the zone-circles 2 gives p = r = i, the values of p q r being taken absolutely. 1 44 Congruent heterozonal symmetry-planes. Planes of congruent symmetry not in one zone. 124. The four cases have now been considered in which it is possible for two or more tautozonal planes of symmetry to be inclined on each other at one of the crystallometric angles ; and they have been seen to involve three distinct types of sym- metry. In fact the symmetry of the whole system of planes is controlled in these cases by the symmetry of the zone to which the proto- and deutero-systematic planes belong. The question however remains as to what other types of sym- metry may be possible that are not included under these three and that of symmetry to a single plane. Thus of the polyhedral systems hitherto considered some were symmetrical to planes at once tautozonal and conformable in their symmetry; but it remains to be determined whether it may not be possible for three or more heterozonal planes of symmetry to present conformability; and after these have been considered, there will remain the question whether there may not be yet other types of crystalloid symmetry. Since it follows that an axis of symmetry potentially tetragonal will result from the existence of an independent pole lying on a circle that bisects one of the right-angles formed by three perpendicular symmetry-zones and bisects therefore also the quadrant of the systematic triangle which subtends that right-angle ; we may en- quire what will result from the further condition that any pole or poles may lie on a great circle bisecting the right-angle formed by another pair of the three perpendicular planes. Or, which is the same thing, it may be asked what will be the nature of the sym- metry resulting from a third plane of symmetry being conformable with as well as perpendicular to either and therefore to both of two perpendicular and conformable planes of symmetry. CASE V. Three heterozonal planes of congruent symmetry. 125. Case of three conformable planes of symmetry that are hetero- zonal. In the case suggested in the last article each of the three right-angles s, a; and c of the systematic triangle, Fig. 40, will be Three symmetry -planes conformable. 145 bisected by a zone-circle lying in what will be potentially a plane of symmetry but not conformable with the two planes with which it intersects. Hence also each of the three zone-lines in which the proto-symmetral planes intersect becomes an axis of tetra- gonal symmetry, since in these same zone-lines two perpendicular deutero-symmetral planes will intersect with the two former planes at 45- Assigning similar letters to conformable planes of symmetry, namely, S to the three planes of proto-symmetry and 2 to the planes of deutero-symmetry, we have three perpendicular planes -S" intersected by six planes 2 (see Fig. 50) that are in pairs tautozonal with two and perpendicular to the third of the planes S. It will be seen that one zone-circle 2 of each of the three deutero-symmetral pairs must intersect with other two belonging to *'ig- 50. the other pairs, in a point o that will be equidistant from the poles of the planes of proto-symmetry, and this will be the axial point of an axis of trigonal symmetry. For the three zone-planes 2 X , 2 2 , 2 3 (Fig. 50) will obviously intersect with each other at the crystallometric angle of 60; since 146 Cu bo-octahcdra I Symmetry . in the triangles hdo (Fig. 50) we have the angles h 45, d 90. and the side/id or = -; whence also ho or D = 54 44-14', and 4 <&? or # = 35 15-86', and D + ff= 90, and of the eight points the mutual distance of any two adjacent poles as measured on that arc of the zone-circle 2 which traverses a pole d is 70 3 1-7', while the distance of two poles o measured on the arc traversing a pole h is 109 28-3'. On comparing the relative distances of the points o and the points h with the angles between faces of the polyhedron known as the cubo-octahedron, it will be seen that they are supplementary to each other, and that in fact the points o and h correspond to the poles of the regular octahedron and cube respectively which combine to build up that figure. The conditions supposed will thus give rise to a type of crystalloid symmetry different from those which have been hitherto considered. 126. The systematic triangle, and axial system. In it the sphere of projection will be divided by the nine intersecting circles -5" and 2 into forty-eight systematic triangles, of which the sides 0, D, II opposite respectively to the angles o, d, h have the values = ^, = 54 44- 14', ^=35 15-86', while the angles are o = 60, d= 90, h 45; and there will be three pairs of tetra-symmetral poles h, four pairs of tri-symmetral poles o, six pairs of ortho-symmetral poles d. The general scalenohedron under such a type of symmetry will therefore have forty-eight faces. Taking the proto-symmetral planes S for the axial planes and consequently their perpendicular intersections for the axes, and taking a face of the octahedron for the parametral plane, it is clear that since the latter truncates a quoin of the cube it will cut the axes with equal intercepts, so that all the parameters are equal : and the conditions for this type of symmetry as embodied in the axial system thus chosen are expressed by the symbol Forty -eight systematic triangles. 147 It will be seen that all the five axial elements are required to have special values in order to fulfil the general conditions of the system .; no element remaining variable to characterise any different systems of planes that may conform to this type of symmetry. The six poles h are those of three symmetral planes S, parallel to the faces of the cube ; and they are also the axial points in which the axes of the quoins of the octahedron meet the sphere ; the eight poles o are those of the faces of the octahedron and are the axial points of the quoins of the cube ; and the twelve poles d are those of the six symmetral planes 2, parallel to twelve faces which, truncating the edges alike of cube and octahedron, con- stitute the form {no}, termed the rhombic dodecahedron (the dodecahedral rhombohedron), a figure the quoins of which have axial points in common with those of the cube and of the octa- hedron. 127. Symbols for the forms in such a system. Since the axes and the edges of the proto-symmetral planes S are coincident, it is evident that the faces of the cube will have the six symbols arising from the various permutations of the indices 100 and the interchanges of the sign of the unit index ; and the different faces of the octahedron will be represented by the eight interchanges of + and sign of which the general symbol { 1 1 1 } for this form is susceptible. And since the axial octants are formed by the intersections of the proto-systematic planes S, each of them will be conterminous with six of the systematic triangles ; so that six poles of the general scalenohedron will lie in every octant. In fact, since the edges S 2 S 3t S S S 13 S 1 S 2 , and therefore also the axes, are necessarily similar, a face presenting three different indices in its symbol will be so often repeated in the octant as is necessary to interchange each pair of the indices for every two axes ; so that the different symbols for the faces in an octant will be six in number, corresponding to the six interchanges of position in their indices of which three different numbers are susceptible, and falling each into one of the six systematic triangles in the octant. Further, if we consider the symbols thus indicating the six poles of the form {hkl} in an octant, it will be seen (see Fig. 49) that those in which the indices follow the same order as L 3 148 Cyclic permutations in symbols. hklhk or as Ikhlk are symbols of poles lying in alternate systematic triangles, which, as in article 125, may be designated as hdo or hod, and their faces are metastrophic; while those in which the order of the indices is reversed belong to antistrophic faces lying in adjacent triangles. In passing from one octant to another, it is obvious that the six faces belonging to any octant will have their signs in the same position in their symbols, the position namely of the signs of the XYZ which designate the octant. The symbols of the faces of the general independent scaleno- hedral form in this system will consequently represent all the permutations of three numbers taken positively and negatively. iety and distribution is given in the following table TABLE A. i. iii. v. vii. ii. iv. vi. viii. hkl, Ill, hkl, hkl, hkl, hkl, hkl, h~kl, Ihk, Ihk, Ihk, fhk, Ihk, Ihk, Ihk, Thk, klh, ~klh, "klh, klh', klh, klh, klh, klh', hlk, hlk, hlk, hlk, hlk, hlk, hlk, hlk, khl, khl, khl, khl, khl, khl, khl, Thl, Ikh, Ikh, Ikh, lkh\ Ikh, Ikh, Ikh, Tkh\ I \i. Ihk, Ihk, Ihk, Ihk, Ihk, Ihk, Ihk, Ihk, a II. Ilia, khl, khl, khl, khl, khl, khl, khl, khl, ft IV. Ikh, Ikh, Ikh, l~kh\ Ikh, Ikh, Ikh, Tkh; where the columns represent each an octant ; the first four giving the symbols of the poles lying in the octants XYZ and those attingent to it and adjacent to XYZ; the remaining four columns giving the poles in the octant XYZ and those attingent to it. The blocks I p. and IV ^. represent the systematic triangles metastrophic to each other and to the triangle containing the pole hkl, the blocks II a. and III a. represent the triangles antistrophic to the former, but mutually metastrophic. The symbols of a form the poles of which lie on a great circle 6" will have a zero in the place of the index corresponding to that axis which is normal to the great circle ; and since all the eight Types of the systematic triangle. 1 49 arcs on each of the great circles S are similar and will each carry a pole of the form, the form will have twenty-four poles, in the symbols for which two of the indices are different and one is zero. These then will correspond with the twenty-four various interchanges of position in the indices and of character in their signs of which the general symbol {hko\ is susceptible. The poles of a form lying on a great circle 2 will be the poles of planes intersecting with identical intercepts on two of the axes. Two of the indices must therefore be identical ; hence the general symbol for a form the poles of which lie on the great circles 2 will be either {hkk} or {hhl} ; and according as its position lies on one or the other side of the pole of the octahedral form {in}, it will present the one or the other of these types of symbol. In fact, when the pole lies on an arc H its indices for two axes are greater than that for the third and the form is {hhl}, when it lies on an arc D its symbol is {hkk}. The form in either case has twenty-four faces symmetrical to the great circles 2; their symbols interchanging the positions of the indices in each octant and the character and position of their signs from octant to octant. General discussion of the systematic triangle. 128. We have so far considered certain special cases in which a crystalloid polyhedral system may be supposed to be sym- metrical to one or simultaneously to several planes. These cases have included all the possible conditions under which such planes of symmetry may lie in the same zone, and certain conditions under which other planes heterozonal to these may also be planes of symmetry for the system. It remains however to determine whether these are the only possible cases of crystalloid symmetry, or whether some polyhedral systems may not exist the law of whose symmetry may have to be represented by a different systematic triangle from any yet con- sidered. And for this we may discuss the general characters of such a triangle and the limits these impose to its variation ; and the most general form of stating this problem will be that of determining under what conditions three great circles may inter- sect at crystallometric angles. 150 Six possible systems. 129. The six systems of crystallography deduced from the crys- tallometric law. Let S, C, 2 be the sides and s, c, a- be the angles respectively opposite to them of such a spherical triangle. Then as s, c, and -, g ; TTT O O O T ^ 77 III. 90 , 90 , 45 ; -5 IV. 9 o, 90, 90; - 2 > - 2 > I- If to these we add (V) the case of a system symmetrical to a single plane, and (VI) that of a system merely symmetrical to a centre, we shall have represented every possible case in which a crystalloid polyhedral system can be said to be symmetrical at all, It is evident that these are precisely the cases that have been investigated in this chapter. These varieties of symmetry will hereafter be distinguished by the following designations : I. 3 planes S, 6 planes 2, Cubic System. II. 3 S, 3 2, i plane C, Hexagonal System. III. 2 S, 2 ,, 2, T C, Tetragonal System. IV. i S, i ,, 2, i C, Orthosymmetric System. V. i S, Monosymmetric System. VI. a centre of symmetry, Anorthic. Cubic involves trigonal symmetry. 1 5 1 And the planes of symmetry which characterise these several systems, and by their intersections with the sphere of projection in arcs of great circles determine the systematic triangle in each system, will henceforward be designated only as systematic planes. 130. Relations of the cubic system to the trigonal and hexagonal system. It results from this that the trigonal axes of the first of these systems those namely which represent the normals of the regular octahedron can in no case become axes of hexagonal sym- metry, and therefore the planes of the octahedron cannot be planes of symmetry for that system. Of course planes belonging to a form analogous to the form {mi'n}, the u of Fig. 47 of the trigonal system, and lying in great circles that bisect the angles 313 SSL Fig. 51. at which three planes 2 meet each other, may exist on crystals of this type. But they are essentially trigonal and not hexagonal in the character of their symmetry round the axes 0. It will be furthermore apparent in the comparison of the cubic system with the trigonal type of symmetry, Figs. 50 and 51, that the case alluded to in article 119, where tan r c = 2 cotan A c, is that in which a form in the trigonal system is directly comparable to one belonging to the cubic system ; since then rc = ho = 54 44-14' = ff and r t r 2 = h z h^ 90 in the cubic system, and the three axes are perpendicular. 131. Symmetry of faces. The features that undergo symmetrical 152 Symmetry of faces. repetition in the faces of a polyhedron are the edges that form its sides and the plane angles in which any two of these edges meet so as to form one of the sides of a quoin. The character of the boundary line of a face, as being an edge, is determined, not by the length of the side, but by the angle at which the face is inclined on the other face meeting it in the edge ; and generally edges of which the angles are the same are geo- metrically similar and homologous, except in the ambiguous case of such angles being right-angles. It is however necessary, especially where they are right-angles, to enquire as to the character of the faces that lying in the zone can intersect each pair of edge-forming faces, and to determine whether two different edges can have faces so replacing them as to cut off the edge in each case at the same angles to the corresponding faces. And the symmetry of a face will be known when we know the law of repetition of its edges and angles; and this will obviously depend on the number and nature of the planes of symmetry that may intersect with it perpendicularly. When it is not parallel to a zone-plane and is therefore also not parallel to a plane of symmetry it can only be perpendicularly intersected by a single plane of symmetry, and where it is not perpendicular to such a plane of actual or potential symmetry it can have no symmetry at all, except where the system is symmetrical to a single plane, when a face parallel to that plane will be centro-symmetrical. And when we consider any other position that a face may occupy on a crystalloid polyhedron, it is clear that its pole can only lie on a side or at an angle of a systematic triangle, or must be an independent pole ; in which last case it is without symmetry. When its pole lies on a side of a systematic triangle, the face is traversed perpendicularly by one plane of symmetry to the trace of which it is euthy-symmetrical ; when the pole lies in an angle of a systematic triangle, and therefore at the intersection of two or of four, of three or of six planes, the face is symmetrical to an axis of symmetry and is ortho-symmetrical or ditetragonal, ditrigonal or dihexagonal in character. Symmetry of quoins. 153 Striations and recognisable physical features in the case of a crystal often throw light on the character of the symmetry that the face obeys which exhibits them ; and it is from the aid which such characteristics, as exhibited in important faces, afford for the determination of the type of symmetry, not merely of the face but of the entire crystal, that this study of these features derives its significance : and indeed the information thus attained will be found often to go deeper than a symmetry that is merely morphological, and to involve the symmetry that rules in the dis- tribution of physical properties and underlies the geometrical symmetry. 132. The symmetry of a quoin is determinate in a similar manner to that of a face. For the quoin is composed of edges and plane angles, and where these recur symmetrically the quoin will be symmetrical to a line which is an axis of symmetry of a corresponding order. Thus, where a quoin is symmetrical to a zone-axis, its summit is capable of being truncated by a plane parallel to the corre- sponding zone-plane, and according with it in symmetry ; where it is not symmetrical to a zone-axis, it may be symmetrical to a single plane or it may be altogether without symmetry. And it is evident that the symmetry which a quoin will present will corre- spond with that of the diameter of the sphere which meets its vertex. If, as in the case of the axis of symmetry in the clino- rhombic system, the diameter in question is an axis of diagonal symmetry only, the quoin or a face replacing it is diagonally symmetrical to this axis. If, again, the diameter is a normal to a plane the pole of which lies on a side of a systematic triangle, the quoin is euthy-symmetrical to the systematic plane in which the arc lies that carries the pole. Where the axis of the quoin meets the sphere at the angle of a systematic triangle, the quoin is symmetrical to the zone-axis which at that point meets the sphere. In every other case the quoin is devoid of symmetry. And the characteristics of the quoins of a crystal, as in the case of the faces forming them, offer one of the most important features by which to recognise the type of the crystal's symmetry. J 54 Symbols for truncating planes. 133. Symbols of truncating and bevilling planes. From the principles established regarding crystalloid symmetry it will be seen that the only cases where the edge formed by two faces is truncated by a third face or bevilled by pairs of faces of the system will occur when the faces forming the edge are adjacent faces of a form symmetrical to a systematic plane, or else lie on a great circle traversing an axis of symmetry in regard to which they are sym- metrical ; so that the pole of a face truncating an edge will lie on an arc and may lie at an angle of a systematic triangle. It further results from the symmetrical character of the axial systems adopted for each crystalloid type that the symbols for two adjacent faces of a form either differ only in the signs of one or of two indices, or else differ by the permutation of certain of their indices. In either case, the ratios of the indices in the symbol of the truncating face is obtained by the addition of corresponding indices in the symbols of the planes whose edge is truncated. In the Hexagonal system this rule will be found to hold directly only for those faces of, for instance, the general form [hkl efg} which belong to the trigonal semiform {hkl}, or else to those belonging to the correlative semiform inverse to it {efg} ; for in attempting to apply the rule to adjacent faces belonging, the one to a direct the other to an inverse form, it appears to fail. In fact, however, the principle involved in the rule is only obscured. The symbol of a form derived from the symbol of an inverse form by the same method as the latter is derived from that of a direct form should evidently be the identical symbol of the original direct form ; so that the inverse form to {efg} should be {hkl}. If how- ever it be derived by aid of the formulae given in article 122, this symbol will be found to be not (hkl) but (g& g>); whence it is evident that if the condition above asserted is to be fulfilled we should have to consider the indices of the form inverse to hkl, i.e. 2 (* + /)-*, 2 (l+h)-k, 2 ( + )-/, as equivalent not to efg but to %e sfsg, and in order to compare /Wwith efg on, so to say, equal terms, we should take efg as ranking with 3 h 3 k 3 /. In order then to determine the symbol of a face truncating an edge of adjacent faces of a form {h k I efg} we have, where the faces belong the one to a direct the other to Case of hexagonal forms. 155 the inverse semiform, to multiply the indices in the symbol of the face of the direct semiform by a common factor 3, and to add them to the indices belonging to the face of the inverse semiform. The rule will then be found to be general, and it applies equally, of course, to other forms besides those of the general scaleno- hedron. Thus, for example, the face truncating the edge (hlk) (e/g), that is to say, the edge of the faces (3^ 3/3^), and k-2l+h, lzk + k), is 4/1 2 k -\- I, k j r l2h, k + l2h, or 2!!. CHAPTER VI. CRYSTALS AS CRYSTALLOID POLYHEDRA. SECTION I. Mero-symmetry. 134. THE properties of a system of planes mutually related by the law of the ' Rationality of Indices' have been so far in- vestigated as a crystalloid system from a purely geometrical point of view ; and, by establishing as one of these properties the principle that the varieties of isogonal zones that can be extant in such a system are limited to four, it has been possible to shew that only a limited number of types or systems of symmetry can be illustrated in crystalloid plane-systems. When we turn to the natural polyhedra presented in crystals in order to determine to what extent these actually accord in their geometrical characters with the crystalloid systems hitherto considered, we cannot fail to recognise that whereas the .crystallographer, guided heretofore solely by observation and experience, referred every crystal to one or other of six crystallographic systems, those systems furnish precisely the several types of symmetry which coincide in their distinctive features with the six crystalloid types of symmetry resulting from the above principle. But in order to carry on the enquiry by means of exact ob- servation into the geometrical relations connecting the faces of a crystal, we must have recourse to instrumental methods admitting of the requisite precision. This object is attained by the use of the Goniometer, an instrument constructed for the measurement of the angular inclinations of planes, of which the description and the use will be given in a future chapter. Crystals as crystalloid systems. 157 The results that have been accumulated by means of this instru- ment form a body of observations on which crystallography as a science rests ; but in dealing with these results the crystallo- grapher is often more or less embarrassed by errors incidental to the use of instruments, and still more by difficulties due to peculiarities and imperfections presented by the faces of the crystals themselves. In proportion however as the errors arising from such sources are diminished, it has been found that the values obtained for the angular inclinations of the faces of a crystal more and more closely accord with those which would result from the crystal being a crystalloid polyhedron ; that is to say, from the Law of the Rationality of Indices being the fundamental law presiding in its construction. And that this is true for all temperatures at which the integrity of the crystal is maintained may be assumed, since it is true within the limited ranges of temperature at which such measurements can be effected ; while within these ranges of temperature some crystals are near the highest limit at which they can exist, while others are examined at temperatures far lower than those at which they have been formed. The analogy of the law that indices are integral coefficients of the parametral ratios to the fundamental law of chemical com- bination by which bodies unite in simple multiples of their weight- equivalents, can hardly escape notice ; and the inductive method by which each has been arrived at has consisted in an accumu- lation of experimental results scarcely less extensive and exact in the case of the crystallographic than in that of the chemical law. 135. A significant illustration of the occurrence on crystals of only such forms as are possible in a crystalloid polyhedron, is furnished in the fact that of the five regular solids, three, namely, the cube, octahedron, and tetrahedron, are frequently crystal forms, whereas the dodecahedron and the icosahedron have never been met with on any crystal. The three first figures are crystalloid in their symmetry ; the faces of the two last cannot be expressed by symbols with rational indices, and they furthermore present 158 Mero-symmetrica I crystals. a pentagonal symmetry which is of an order impossible, as has been seen, in a plane system obeying the law of rational indices. Experience however has, on the one hand, proved that a crystal is not merely thus externally and geometrically, but is also phy- sically and throughout its substance symmetrical and seolotropic ; while, on the other hand, it has led to the recognition of a natural principle which in a great number of cases limits the complete- ness of the symmetry of the crystal. Thus it not unfrequently happens that certain of the faces on a crystal which, in accordance with the geometrical principles of symmetry laid down in the last chapter, should constitute a form, will present in their physical characteristics differences so marked and occasionally so contrasted that it is impossible to view them all as equally repetitions of the same face. 136. This partition of the faces geometrically similar into phy- sically dissimilar groups is, however, found to be itself obedient to principles of symmetrical distribution which concord with those of the crystallographic system to which the crystal belongs : and such an interruption in the complete accord of physical and geometrical symmetry will be seen to be a particular case only under a more general law which deals not only with a division of the faces of the crystal into correlative groups, but in general also with the entire suppression of all the faces not belonging to one of the groups. 137. Mero-symmetry. In the last chapter the character of a form under each of the different types of symmetry were con- sidered, and the trigonal type was treated as a partial and incom- pletely developed variety of hexagonal symmetry. While observations directed to such crystals shew that this incompletely developed type is represented abundantly in nature, numerous analogous cases of incomplete symmetry are also met with in other crystallographic systems. DEF. A holo-symmetrical form in any system will be the term applied to a form in which all the faces required to complete the symmetry of the system are present, and are physically as well as geometrically similar. The term mero-symmetrical will be employed in all cases in which the faces requisite to build a geometrically complete form Hemi-symmetry ; t-wo kinds. 159 are partially suppressed, or in which these faces fall into physically contrasted groups ; the suppression of faces or of the features characteristic of the form taking effect however in a certain sym- metrical manner. Mero-symmetrical forms may be hemi-symmetrical, and will then present one-half of the faces of the complete form ; or tetarto-sym metrical, presenting one-quarter only of the faces of the, holo-symmetrical form; a form of the hemi-symmetrical kind will be termed a semiform or a hemihedron, one of the latter kind a tetartohedron. And the term merohedral will be reserved for certain cases in which a defalcation is met- with in the faces of a crystal out of accord with any fixed law of symmetry ; though sometimes such a merohedral crystal simulates the mode of grouping of a crystal belonging to a different type of symmetry from its own. 138. Hemi-symmetry. Now in considering in what ways it may be possible, while conserving the essential idea of each type of symmetry, to suppress one-half of the faces of a form, we have to keep in view the principle that in surrendering or modifying the symmetral character of a systematic plane or zone-line, each cor- responding similar systematic plane or zone-line must simulta- neously undergo the same degree of deprivation of its symmetral character. And again, the kinds of mero-symmetrical forms will be essentially different according as the suppression of their faces is due to the form ceasing to be symmetrical to its centre, or to the symmetral character of a plane or group of planes of symmetry falling into abeyance. If the crystal be not centro-symmetrical, each origin-plane will be represented by only one of its two poles on the sphere ; or, to adopt the corresponding fiction of centro-normals, each normal will be represented by a single ray, that is to say, will carry but one face and one pole. Where the form is centro-symmetrical, on the other hand, the suppression will affect the faces in parallel pairs; so that only one-half the origin-planes corresponding to faces of the crystal and only one-half the number of normals will be extant, the remaining half being absent. 1 60 Classes of mero-symmetrical forms. And a mero-symmetrical form may further be conceived such that alternate normals only should be extant and should each carry but a single face. 139. Holo- and mero-sysiematic forms. Since failure of sym- metry in the number of normals or of origin-planes belonging to a form in any system can only result from abeyance of symmetral character in one or more of the planes or groups of planes of symmetry which have already been designated as ( proto-, deutero-, trito-) systematic planes, we may avoid the ambiguity in which the terms hemihedrism, tetartohedrism, &c. are involved by the more restricted or wider senses in which different authors have em- ployed them, if we adopt a nomenclature consistent with our use of the former term. DEF. A holo-systematic form, then, is a form in which all the origin-planes or normals required by the complete symmetry of the system are extant. A hemi-systematic form is a form in which only half the origin- planes or normals are extant, the correlative half being absent. In a tetar to- systematic form, only one-fourth of the origin-planes or normals can be considered as extant. A diplohedral form will, as before defined, be a form in which every origin-plane is parallel to two faces (or has both its poles extant) ; or in which each normal is made up of two rays or carries two faces and their poles. In a haplohedral form each origin-plane or each normal is repre- sented by a single face and its pole. 140. Kinds of mero-symmetry. Whence there is I. Holo -symmetry, where a form is at once holo-systematic and diplohedral. II. Hemi-symmetry, where a form is or i. holo-systematic and haplohedral, ) Semiforms ii. hemi-systematic and diplohedral. } hemihedra. III. Tetarto -symmetry, where the form is i. hemi-systematic and haplohedral, ) . i ^ i- i i j i J Tetartohedi or 11. tetarto-systematic and diplohedral. j L aw of mero-symmetry. 161 IV. Hemimorphism is the term for a particular case of haplohedral mero-symmetry. One-half or, it may be, one-fourth of the faces of the original form are present in the hemimorphic form: but these all lie on one side of a systematic plane, the symmetral character of which is in abeyance. 141. The law of mero-symmetry. The conceivable modes in which either one-half of the normals or one-half of the faces cor- responding to the full complement of normals (each represented by a single face) might be suppressed are evidently numerous and varied. And in the resulting polyhedra we should in many cases look in vain for any characteristic features of the symmetry of the system to which the holo-symmetrical form belonged. But in crystals, as has been before observed, some special quality dis- tinguishing the original type of symmetry is always preserved in all their mere-symmetrical forms ; and it is in accordance with this experience that we seek for a geometrical principle that shall embody such a condition. Now the only geometrical assumption that can be made regarding the mero-symmetrical suppression of the faces of a system so as to satisfy this condition is one which we find in Nature to include all known cases of mero-symmetry, while without extension of its terms it will also be found to embrace the symmetrical conditions presented by holo-symmetrical forms. It may be stated then in .the form of a general law of crystal- lographic symmetry, that on a crystal the extant or absent features of a form must be extant or absent in the same way in respect to equivalent systematic planes. This is the second fundamental law of crystallography. 142. The nature of the forms necessitated by this law in the different systems will be discussed hereafter. But certain of the general results which are involved in its application may be pointed out here. Thus hemimorphism can only exist in relation to a unique systematic plane, since it could not hold in the case of two con- formable systematic planes. It is thus precluded from every form of the Cubic system. It may, on the other hand, occur on a form otherwise holo- or hemi-systematic, and so be either hemi- or M 162 Tetragonal hemi-symmetry . tetarto-symmetrical in its character (i. e. presenting only the half or the fourth of the faces of the complete form). 143. So, again, a tetragonal axis of symmetry is, so to say, the creature of the two pairs of alternating planes of symmetry S and 2 of which it is the zone-line, and in the holo-symmetrical case the poles of an independent general form {hkl} are grouped ditetragonally round this zone-line. If, now, we suppose one of these pairs of systematic planes say the planes 2, Fig. 52 (i) to fail of being symmetral, the result will be that either the planes S continue planes of symmetry and their zone-axis becomes an axis of ortho-symmetry, as in Fig. 52 (2); or the planes S also fail as planes of symmetry, while the zone-axis retains its character as an (3) axis of tetragonal but not of ditetragonal symmetry, the grouping of the faces round it being in alternate systematic triangles, as in Fig- 52 (3)- 144. In the same way, Fig. 53 (i), an axis of hexagonal (in the general case dihexagonal) symmetry is the zone-axis of two triads of alternating planes of symmetry; and the mero-symmetrical sup- pression of half the poles of a form can be effected by the suppression either of the symmetral character of one of the triads of systematic planes, or of both triads simultaneously. If, for example, the 2 planes are the triad of which the symmetral character is in abey- ance, the grouping of the six faces that remain extant out of the twelve of the original scalenohedral form {hkl} lying on one side of the equatorial plane will be such that the dihexagonal axis becomes a ditrigonal axis; see Fig. 53 (2). If, on the other hand, both triads of planes are no longer planes Hexagonal hemi-symmetry. 163 of symmetry, the twelve faces may become reduced to six in such a way that the poles lie in alternate systematic triangles, see Fig- 53 (3) ; the zone-axis, then, continues to be an axis of hexagonal but not of dihexagonal symmetry. In a trigonal system, indeed, in which the axis of form is an axis of ditrigonal symmetry and is the zone-line of three con- formable systematic planes S lt S z , S 3 , it is evident that the abeyance of the symmetral character must take effect on all three or on none of these planes ; that is to say, the ditrigonal axis becomes a trigonal axis, or else the system, if conceived of as (3) derived from one originally diplohedral, must become hemimor- phous in respect to the zone-plane [^ S z S 3 ~\. 145. In the case of an axis of ortho-symmetry which is the zone- axis of two perpendicular planes of symmetry 6* and 2, Fig. 54 (i), (0 Fig. 54- (2) if the symmetral character of one and one only of these planes is in abeyance, for instance that of the plane 2, their zone-axis will not be an axis of symmetry. In this case, however, it will be M 1 164 Orthogonal hemi-symmetry . seen that in a holo-systematic system the zone-axis of the planes S and C (C being in a diplohedral system a third systematic plane perpendicular to S and 2) must be an axis of ortho-symmetry, and that the system will be hemimorphous in regard to the plane 2, see Fig. 54 (2) and (3). On the other hand, the symmetral character of the two planes S and C may both be in abeyance ; and then there is no symmetral plane and each zone-axis becomes an axis of diagonal symmetry, as in Fig. 54 (4). (3) Fig- 54- (4) 146. In the case of the Mono-symmetric system, obeying only one plane of symmetry of which the normal is an axis of diagonal symmetry, the only available varieties of mero-symmetry are hemimorphism resulting from the abeyance of the symmetral character of this single systematic plane, and the case of a semi- form presenting two poles symmetrical to that plane. For, were the form diplohedral, it would retain but a single normal and its symmetry be undistinguishable from that of an anorthic crystal. The varieties of mero-symmetrical partition, which faces of a general independent form may undergo in any particular crystallo- graphic system, will have to be considered in detail in chapters specially devoted to the description of the forms of the different systems. But their character is always determined by the necessary conditions that the distribution of the faces must be consistent both with the law of mero-symmetry, and with the rules which have been laid down in the preceding articles regarding the order of the symmetral influence which an axis of symmetry may retain when some or all of the systematic planes of which it is the zone- axis lose their symmetral character. Simultaneous abeyance. 165 147. That the different forms of the same crystal cannot be simultaneously obedient to different types of symmetry, that is to say, cannot belong to different systems, is as obvious a neces- sity as that the different features of the same form cannot be so. There remains however the question whether a crystal hemir symmetrical in regard to a particular form or forms can exhibit holo-symmetry in regard to other forms; for instance, where geometrically diplohedral forms are found concurrent with haplo- hedral forms, it may be asked whether the possibility of such a concurrence is not proved. The general answer to this question is however to be found in the principle that planes of symmetry are such for all features of a crystal, and, where they are in abeyance at all, they are in abeyance for all the forms. If the effect of any particular mero-symmetrical principle in influencing the different kinds of forms of the same crystal be considered, it will be seen that what in the case of one variety of form will result in the suppression of the half of its faces, may in another produce not a suppression of any of the faces, but a cor- responding loss of symmetry in the outline or in the physical characters and molecular structure of each and all the faces of the form. The latter case, that namely in which the suppression takes effect, not in the obliteration of half the faces of the form but in that of half the features of each face in fact in the partial suppres- sion of the symmetry which these faces would obey in the holo- symmetrical form occurs wherever the poles of the form lie on any systematic great circles whereof the symmetral character is (l) (2) Fig. 55- in abeyance. A cube with its alternate quoins truncated by the 1 66 Mero-symmetry : notation. faces of a tetrahedron would illustrate such a suppression. Its six faces are all ortho-symmetrical, not tetra-symmetrical. Thus the striations on the faces of the cube in Fig. 55 (i) will be seen to run parallel only to the edges these faces form with those of the tetrahedron which truncate its alternate quoins ; while in Fig. 55 (2) the cube faces are striated parallel to their intersections with alternate pairs of faces of the rhomb-dode- cahedron. Fig. 55 (i) represents a crystal of blende symmetrical to the 2-planes only and haplohedral; Fig. 55 (2) is that of a crystal of pyrites symmetrical to the S-planes only, but diplohedral. In both the symmetry of the cube-faces is seen to be orthogonal, not tetragonal. 148. A uniform notation to represent the kind of mero-symmetry presented by any correlative pair of hemihedra or group of four tetartohedra is of some importance ; and the more as the Greek letters which have been employed as prefixes to the symbols of holo-symmetrical forms in order to represent their semiforms have received different significations from different authors. In the Tetragonal system, for instance, the semiforms represented by Prof. Miller as A {hkl}, K {hkl\, and a \hkl} carry in the treatise of Prof. V. von Lang the symbols y{hkl], \{hkl} and K {hkl} respectively. The symbol TT is alone in carrying by general consent a con- stant signification, namely, that the semiform it designates is diplo- hedral ; but as employed in the Cubic and Tetragonal systems, for instance, it represents different ideas of symmetry. To avoid confusion, therefore, a notation will be adopted in this treatise such that, in the cases where ambiguity has heretofore arisen, the letters employed as prefixes will recall by their sounds the nature of the symmetry that is not in abeyance and which therefore controls the extant form. The following prefixes will accordingly be-employed, in the case of hemi-symmetrical forms, to represent that the faces of these forms which are extant (or absent) are so symmetrically, only (as haplohedral and holo-systematic forms) i. to one or more zone-lines of symmetry a Mero-symmetry : notation. 167 2. to one or more such resultant zone-lines, and also to the (proto-systematic or) S- planes s to the (deutero-systematic or) 2 -planes o- to the (trito-systematic or) C-plane, see below, The diplohedral character of the last three kinds of form is sug- gested by letters which involve the sound of TT (opposite poles on the sphere separated by a distance IT being extant in such forms), the meaning of the affix TT being restricted to a special case ; while the double letters x and f serve to recall the letters CS or C2 that represent those of the systematic planes which alone retain an actually symmetral character and thus determine the nature of the symmetry ; p has been used by V. von Lang to represent hemimorphism in general, and is here retained for a frequent case of hemimorphism, that on the trito-systematic plane. The usual mode of representing a tetarto-symmetrical form is that of uniting the prefixes corresponding to two out of the three pairs of hemihedra that may be constituted out of the faces of the four correlative tetartohedra. Thus, in the Tetragonal system we have for the mero-symmetry of the general form {hkl} (see Plate II) three hemi-symmetrical pairs of forms, s {hkl}, s {khl} ; o- {hkl}, a- {hkl} ; {hkl}, $ {khl} : and these three sets of correlative semiforms may be produced by combining in distinct pairs four tetarto-symmetrical forms, which may be therefore indifferently designated as sir {hkl}, s{hkl}, s{khl}, s{hkl}, Or MA' M'A' Fig. 56. holo-symmetrical polyhedra into constituent correlative hemihedra, the principle of the partition was not discussed. Evidently each semiform may appropriate one face from the pair belonging to every normal, or, on the other hand, may be built up of pairs of parallel faces belonging to alternate normals. But there are consequences depending on this character of the mero-symmetry which must not be lost to view. Thus, in the haplohedral holo-systematic case the original form is so disparted into two semiforms that, for each face of the one semiform, a face, parallel to it in the complete form, belongs to the other semiform. Whether the two semiforms can be brought into congruence will depend on whether their faces are severally capable of being so, meta- Enantio-morphous forms. 169 strophically ; and this, again, on the mode in which these faces are grouped. From the general scalenohedron of a system may be derived two kinds of correlative semiforms. These may be such that the poles of one semiform lie in alternate systematic triangles and so, therefore, that the faces of the one semiform are metastrophic to each other, but antistrophic to the faces of the other semiform : or, it may be that metastrophic are united with antistrophic faces in each of the semiforms. But it is impossible to partition the faces of a semiform of haplohedral character between two tetarto- hedral forms, otherwise than so as that each of the latter forms shall have all its faces antistrophic to the faces of the other correlative tetartohedron. The configuration of the one tetarto- hedron will then correspond to that of the other as seen in a mirror. In a word, the two tetarto-symmetrical forms are enantio- morphous. And since antistrophic asymmetric faces on a crystal cannot be brought into congruence by the revolution of the crystal round any diametral line, it is not difficult to determine whether in any particular case correlative mero-symmetrical forms are enantio- morphous or tautomorphous ; i.e. cannot be brought into congruence, or can be so brought by revolution round one or more zone-lines. If the tetartohedra in Figure 56 that are represented by different letters are antistrophic and those with the same letters metastrophic to each other, of the correlative pairs of hemihedra formed by their combination those represented by union of different letters and formed by antistrophic tetartohedra will be tautomorphous, viz. AM with M'A', AM' with MA' , while the pairs represented by union of the same letters, viz. AA' and MM' ', are formed by meta- strophic tetartohedra but are themselves enantiomorphous. 151. It has been stated in articles 135 and 136 that, whereas the hemi-symmetrical developement of a form implies in general the suppression of one of the correlative groups of its faces, the two groups may nevertheless be concurrent on the crystal; but that, whether they are so concurrent or are found only on separate crystals, they are often distinguishable from each other by differences 170 Antihemihedrism. Rotatory polarisation. in external feature or otherwise in physical character. It may be evidenced by variation in smoothness or lustre, or in roundness or plane character of surface, in the directions, depth and form of striations or of hollows, or in the relative magnitudes habitual with the faces of the respective semiforms ; or, also, it may be associated with polarity of character in the physical properties of the correlative hemihedra, especially under pyroelectric excitement due to changing temperature. Such differences, then, may generally be held to indicate a mero-symmetrical habit, and they often impart a very marked contrast to the faces of the correlative semiforms. It may occur, on the other hand, that the distinctive features of concurrent mero-symmetrical forms may not be apparent or recognisable. That they should nevertheless exist follows as a consequence of the principles of crystallographic symmetry. In the case of semiforms which are holo-systematic, and there- fore haplohedral and not centro-symmetrical, each normal of a form would carry either a single face or else two parallel faces which differ in physical features; and the fulfilment of the con- ditions imposed by the mero-symmetry of the system is compatible with the supposition that the crystal is endowed with different or also, in a polar sense, opposite properties in opposite directions of any given line. This character has been designated by V. von Lang as Antihemihedrism. When the crystal is at the same time hemi-systematic and hap- lohedral the forms are tetartohedral, and for two of the four quarter- forms which are tautomorphous the character of the dis- tribution of the properties and of the features (as, for instance, of the poles) round corresponding lines in the crystal will be meta- strophic, but will be antistrophic to that round corresponding lines in the two quarter-forms enantiomorphous to the former. Along the principal axis of symmetry in particular crystals of the Tetragonal and Hexagonal systems, and along every direction in certain crystals of the Cubic system, a ray of plane-polarised light acquires rotatory polarisation. That this property should be con- fined to haplohedral crystals, hemi-symmetrical or tetarto-sym- metrical, in which all the symmetral planes of the original holo- symmetrical form are in abeyance, will be shown hereafter, when Ultimate significance of symmetry. 171 the physical characters of crystals are under discussion, to follow from the laws of symmetry. 152. In this chapter the subject of mero-symmetry has been treated as involving the presence or the absence of certain faces, consequent upon the abeyance of the actual symmetral character of planes which are otherwise potentially planes of symmetry. But in this treatment of the subject a symmetral influence has still been recognised as, so to say, latent in these dormant systematic planes ; inasmuch as the zone-lines, which may be considered as becoming axes of symmetry by virtue of the original symmetral nature of those planes, generally retain this character in a greater or less degree, notwithstanding the abeyance of a direct symmetral influence in the planes themselves upon the forms of the crystal. By an inverse method of treating the subject of symmetry, it would have been possible to have evolved the laws of symmetry, and deduced those of mero-symmetry, from a discussion of the con- ditions regulating the degrees of symmetry possible round a zone-axis, and to have considered the various planes and groups of planes of symmetry, not as originating axes of symmetry so much as being the results of the symmetral character of such axes. It is however evident that either method, and indeed that the whole treatment of crystallographic symmetry on the assumption of planes and axes of symmetry, actual or potential, represents a geometrical abstraction ; an abstraction that needs for its develope- ment and due explanation a complete science of position applied to the molecular mass-centres, competent to embrace not merely the relative distribution inter se the intermolecular distribution of the chemical molecules constituting the crystallised substance, but also the intramolecular arrangement of the atoms, or molecules of secondary order, whereof the molecules of the substance are themselves composed. Then the true significance of the ideal planes and axes of symmetry will be understood ; and they will assuredly retain a place in the explanation of crystalline symmetry, since they rise into recognition directly from the fundamental principle of rationality of indices and are controlled by its con- sequences. 172 Composite crystals. SECTION II. On Composite and Twin Crystals. 153. Crystals have thus far been considered as single structures, each complete in itself: but this structural individuality is far from being the only or even the most frequent form of their occurrence. Whether as minerals or as products of the laboratory, crystals continually present themselves as aggregates ; often, undoubtedly, united by no definite law, but often also so combined that, while corresponding faces of different individual crystals are quite or approximately parallel, they appear as belonging to a single crystal with its faces interrupted by recurring and by re-entering edges, or tesselated by surfaces not lying precisely in a plane. And a large proportion of the crystals that appear as single individuals are thus composite, built up of more or less numerous single but similar crystals, nearly but often not quite parallel in orientation, though continuous in their substance and in optical contact. In many crystals these component individuals exhibit faces, generally minute, to which it is only possible to assign symbols of a complex kind, that is to say, with indices that are high and often only approximate in their ratios; and to this cause numerous pecu- liarities have frequently to be traced, such as belong to forms of which the faces are rounded, tesselated, or terraced, or which exhibit ridged or ' drused' surfaces, wartlike protuberances, re- entrant edges, or hollows whereof the sides and base are facetted with crystallographic planes. Instances of these peculiarities are familiar to the mineralogist in apophyllite, tourmaline, quartz, idocrase, galena, blende, dia- mond, calcite, etc. But there is another and somewhat more regular manner in which a composite structure asserts itself, that, namely, in which the corresponding faces of the united crystals, though not in the same plane, have a definite relative orientation. A law which, by the geometrical fiction of a rotation of one of the crystals, expresses the character of this orientation will be enunciated in the ensuing article. Such crystals as obey it are termed hemitropic, macled, or twinned crystals. Certain cases, however, which this law does not suffice to explain will be discussed when the forms and combina- tions presented under the different systems are described. They Twin crystals. 173 belong for the most part, though not exclusively, to symmetrically grouped tetartohedral forms. 154. DEF. Twin-crystals. Two crystals are said to be hemi- tropic or twinned when, presenting identical forms, they are united together in such a way that, if we conceive one of them as being turned through half a revolution round a particular line which will be termed the twin-axis, the two crystals would have identical orientation ; that is to say, corresponding faces and edges in the two crystals would become parallel. Or, if the initial orientation of the crystals was the same, such a rotation would bring them into the relative position of twin-crystals. The plane to which the twin-axis is perpendicular is termed the twin-face or twin-plane. The twin-axis may be (i) a face-normal, or (2) a zone-line, or (3) it may in certain cases be at once a face-normal and a zone- line : finally (4) there are crystals in which the twin-axis has been stated to be a line perpendicular to a zone-line and parallel to a face of the zone, while not itself either an edge or a normal. In fact, it is the result of observation that in the four first, or ortho- symmetrical, systems, in all of which it has been seen that three lines, at once normals and zone-axes, co-exist perpendicular to each other, the twin-axis is almost invariably a face-normal, and is, in some cases, at the same time a zone-axis. In the Mono- symmetric system the axis of twinning occurs as either a zone-axis or a face-normal, but by the conditions of the system cannot be at once a zone-axis and a normal, if the crystal be holohedral, since the single systematic axis is already an axis of diagonal symmetry. In the Anorthic system the twin-axis is found to be either a normal or a zone-axis; unless, further, as is maintained by some eminent crystallographers, there may be cases where it is neither of these, but forms with a normal and a zone-line perpendicular to each other a third line perpendicular to both. This question will recur for discussion in the section on the twins of the Anorthic system. In no case, however, can an axis of actual diagonal symmetry or one of higher symmetry, except in the case of a trigonal axis, be a twin-axis for the two crystals. Otherwise, the half rotation of either crystal round such a diagonally 174 Twins : their plane of union. symmetral axis would only serve to bring the two crystals again into an identical aspect, and they would as at first merely present the condition of a parallel aggregation, not to be confounded with a twinned structure. It will also be evident that, a twin-axis being thus precluded from being an axis of diagonal symmetry, a face of one crystal can only be parallel to the corresponding face of the other, when it is either parallel to the twin-axis or perpendicular to it. Where the twin-plane is a crystallographic plane, it must be parallel to an identical origin-plane or zone-plane for both the crystals, and will have the same symbol whether considered as belonging to one or the other crystal : the symbol, indeed, of the twin-plane will be the same for both crystals even in cases where this is not a crystallographic face and its symbol therefore has not rational indices. In Fig. 57 the rotation of the regular octahedron a round the Fig. 57- normal of the face i il would bring that figure into the position b. The figure c exhibits the. two octahedra a and b united so as to form a twin-crystal : it is the so-called spinel-twin, being of frequent occurrence in the mineral spinel. Hemitropic crystals, in cases where they are merely juxtaposed (the cases to which the term hemitropic was more exclusively applied), are frequently but not invariably united at the surfaces of their common twin-plane : in fact, if we assume with Haidinger that the plane of junction must have the same relation to the two crystals, it will be clear from what has been said above in this article that the surface at which the two crystals are in contact must be either the twin-plane or a plane in the zone perpendicular to it. The face or plane in which two crystals are thus in contact is termed the face or plane of union, or also the combination-plane. There Degrees of inter penetration. 175 are cases in which this plane would seem to have irrational indices and thus not to be a face of the crystal. 155. In certain cases all or some of the faces of one crystal can have rational symbols when referred to the same axes and parameters as the other crystal. Such rationality is however con- fined to cases (i) where the crystal belongs to the Cubic system, or (2) where the crystal belongs to the Tetragonal or the Hexagonal system and the twin-plane is parallel or perpendicular to the morphological axis, i. e. is a face belonging to a zone containing planes of abortive symmetry in both crystals, or is perpendicular to that zone. 156. The two individual crystals which compose a twin-crystal never have their individuality merged in the resulting structure, the material of the one being never so intimately blended with that of the other that the two cease to coexist independently side by side, however minute the lamina? or intercalated parts may be which represent the several individuals; and there are cases in which the twin-structure recurs in successive parallel repetitions so numerous as to be represented by a series of laminae of the utmost tenuity. But the degree of intimacy in combination which twin-crystals may present is very varied. Fig. 58 a. Fig. 58 5. The two individuals may present a mere contact at a common surface or plane of union, as in the case of twins by hemitropic juxtaposition ; such is fas juxtaposed twin represented in Fig. 57 c, Article 154 : or there may be an interlocking of the crystals, each 1 76 Poly synthetic twins. being bedded more or less deeply in the other, as in the (so- called Carlsbad) embedded twin of orthoclase, Fig. 58 a : or again, there may be a complete mutual inter penetration of the individuals, as in the Fig. 58 b of an inter penetr ant twin of galena, generally with plane surfaces of junction, occasionally, however, the material of the one being so intercalated in that of the other that the individuals are united at surfaces with jagged, or waved, or other- wise irregular outlines. And in the case of polysynthetic twins several or almost innumerable hemitropic individual crystals may be combined each individual being formed of a crystalline plate, and all being twinned on the same plane so as to build up an essentially laminated structure, the alternate lamina being in crystallographic orientation parallel to each other but hemitropic to the crystal-laminae that intervene between them. Character- istic groovings or striations are often produced by the outcrop of these alternating laminae where they present edges that are actually or nearly parallel in the two series, but are formed by faces which do not for either series coincide with a plane perpendicular to that of the laminae. Such striations are thus due to ridges formed by the alternate crystal-layers, and they result in a corrugated surface which, when the laminae are very thin, has the appearance of a crystalline face; as in Fig. 59 of a polysynthetic twin of albite and Fig. 60 of labradorite. Fi g- 59- Fig. 60. 157. Where the twin-axis is a crystallographic line which in accordance with crystal-symmetry would be repeated in the crystals, it does not follow that the twinning process will be repeated for the other lines, whether normals or zone-axes, homo- logous to that line. Repetition of the twinning on similar twin- Twins : re-entrant angles. 177 faces may indeed occur, and in certain kinds of zones the twinning often does recur, but not as a necessary result of the law of symmetry. Such crystals are triple, quadruple, &c. hemitropes (or triplings, fourlings, &c.). And crystals occasionally exhibit twinning of more than one kind ; that is to say, one or more individuals twinned on a given crystal round one axis may be united with another individual or twin-group twinned on the same nuclear crystal round another axis not homologous with the former axis. 158. A noteworthy feature in hemitropic crystals is the mode in which the substance of the crystals is distributed in different directions; it being a frequent habit of twins that the thick- ness of the combined crystals in the direction of a twin-axis is no greater and is often less, relatively to the thickness along other directions, than would be the case for a single individual not twinned but otherwise corresponding in dimensions with the twin. Fig. 61. 159. It will be seen that, in the case of two hemitropic diplo- hedral crystals, the twin-plane becomes in a crystallographic sense a plane of symmetry to the twin-structure ; but at the same time each crystal in the hemitropic group retains its individuality, not- withstanding the mutual interpenetration of the crystals. From this it results that two faces of the different individuals may meet in an edge of which the internal angle is greater than TT ; or, in other words, the edge may be re-entrant, which is not the case in a simple crystal. In Fig. 61, if PP be the traces of two parallel planes of one individual, P'P' those of the corresponding planes of the other individual, the trace of the twin-plane being T and the twin-axis /, it will be seen that in the hemitrope position, N 178 Twins of semiforms. as in the figure, one pair of the faces forms a re-entrant angle P'P 2 and the other pair a salient angle P'P =26. Re-entrant edges of this kind then are highly but not exclusively characteristic of twinned crystals ; at the same time they are not always to be met with upon them (see Fig. 62). If in Fig. 61 be a right angle, there can be no geometrical evidence, afforded by the faces PP' or PP', of the twin structure. It may happen that the twin-faces of the two individuals in cases where the plane of junction is perpendicular to these faces may form a single plane, or again, as in Fig. 62 of a crystal of hcematite, that faces belonging to a zone, the zone-line of which is the twin- axis, thus fall into coincidence, and in the crystal in question, Fig. 62, both these conditions occur: but it is generally possible, at Fig. 62. least in the latter case, to trace on the composite face the line of junction of its component faces ; and frequently the needed evidence of twin-structure is afforded by the fact that the direc- tions of the striations on these faces are symmetrically inclined on the line in question. 160. It follows from the foregoing statements that, in the case of diplohedral forms, whether holo- or hemi-symmetrical, a plane of actual symmetry to the individual crystals is precluded from being the twin-plane of their hemitropic union. It will be seen, however, that in the case of haplohedral crystals a face parallel to a plane of actual symmetry may be a twin-plane, since the normal of such a face is not an axis of diagonal symmetry. In the case where a hemi-symmetrical crystal is thus twinned on a systematic plane, the poles of the two individuals will evidently fall into the same positions on the sphere as those of a simple holo- symmetrical crystal. Hence it might be anticipated that cases would occur in which it might be a question whether we had to deal with Twins : ambiguous cases. 1 79 a hemi- symmetrical crystal disguised by twin structure, or with a crystal, really holo-symmetrical, but exhibiting in its growth a composite structure simulating the characters of a twinned crystal. And further it might be suggested that in the case of a hemi-symmetrical crystal, on the forms of which the faces of both the correlative semiforms were concurrent, the resulting appearance of a holohedral developement may be due to the twinning of the correlative forms with each other. But in each of the supposed cases the question would in general be answered by the inspection of the crystal itself : since the two crystal-elements com- posing a twin can in fact in almost every case be distinguished from each other, owing to their retaining their individuality side by side, however minute the individuals may be and however com- pletely they may exhibit mutual interpenetration. In the case, for instance, of the haplohedral Cubic mineral blende, all the faces of the octahedron, that is to say, the faces o and the faces w of the two correlative tetrahedra, may be present together on a crystal without twin structure, so that the geome- trical character of the crystal would be holohedral ; that the crystal is however of hemi-symmetrical character will be readily recog- nised by the faces of the octahedron in attingent octants being found to differ in physical character from those in the octants adjacent to them. The diamond, on the other hand, offers an instance of a Cubic mineral presenting bright plane faces of the regular octahedron, or more or less rounded faces of other forms, developed in exactly the same manner geometrically and physically in all the octants, as if they belonged to a holohedral crystal. The edges, however, which lie in the proto-systematic planes, e. g. those of the octahedron, are frequently furrowed more or less deeply with re-entrant grooves, which are facetted with faces rounded when those adjacent to them are so, or in the case of the simple octahedron, are formed by plane faces parallel to the adjacent ones of the octahedron *. A question of great difficulty has arisen whether diamond is to be considered as a crystal of tetrahedral (haplohedral) de- velopement, twinned on the faces of the rhomb-dodecahedron, * SeeSadebeck, Zeitschrift d. dentsch. geoL Gesell. 1878. N 2, 1 8 o Twinning of diamond. or whether it is in fact a holohedral crystal, in which the furrow- ing of the octahedral edges is to be explained, not by a principle of twinning, but by a strong tendency to a lamellar developement during its growth ; the crystal having, for so hard a body, a very facile cleavage parallel to the faces of the regular octahedron. The difficulty of answering this question is not diminished by the dissimilarity in habit of the diamond to other crystals; and in support of the latter of the two views the following consider- ations have been put forward : first, the occurrence of a dode- cahedron face as the twin-plane for haplohedral crystals of the Cubic system is otherwise rare, and when such twins occur they have a very marked character as interpenetrating twins of an entirely different habit from the crystals of diamond ; which mineral, on the other hand, frequently occurs in twins of the spinel- twin variety : secondly, that, although simple crystals of diamond exhibiting indubitable tetrahedral habit (e. g. with forms of the hexakis-tetrahedron) do occur, yet they are among the rarest specimens*; and holosymmetrical crystals, such as magnetite, spinel, and gold, are also described as occurring with distinct tetrahedral habit : thirdly, that there is no evidence of any internal structure suggesting the idea of an aggregation of separate individuals : and finally, that there is clear evidence in the crystals of the diamond of a lamelliform structure similar to that which imparts to some unquestionably holo-symmetrical Cubic minerals, such as magnetite, steinmannite and cuprite, re-entrant octahedral edges and grooved surfaces on the planes of the rhomb-dodecahedron, somewhat similar to those which are met with in octahedra and rhomb-dodecahedra on the diamond. In cases in which a hemi-symmetrical crystal is twinned on a systematic plane, the normal of which would be at least a dia- symmetral axis were its symmetry not in abeyance, it results that systematic planes of each group as well as equivalent lines will present parallelism in the two crystals. It will also be seen that any one of the systematic planes of the group to which the * In the British Museum there are two diamonds in the form of hexakis- tetrahedra, and two others that are hexakis-tetrahedra with faces of the tetra- hedron. Supplementary twins. 181 twin-plane belongs may be itself regarded as the twin-plane. Further, as stated above, the two crystals are mutually interpene- trant ; sometimes, indeed, in a manner simulating the features of holo-symmetrical crystals. DEF. These combinations of correlative semiforms thus have the character of parallel growths and were termed by Haidinger supplementary twins. Certain correlative tetartohedral forms may be twinned in a manner analogous to that of supplementary twins ; but they will obviously only build up a constructive hemihedral form, and the symmetry will be of the nature characterising that form. 161. There is a remarkable tendency in crystals to assume by the aid of twin-composition a higher degree of symmetry than that characterising the system to which they belong. And where the twin-plane, as in the case of haplohedral crystals, does not become a plane of symmetry, it will occasionally happen that the instinct, so to say, for symmetry will be satisfied by a face other than the twin-face, but perpendicular to it, being the plane of junction ; this face becoming a plane of symmetry to the composite structure. Formerly Professor Groth, in his definition of twin-structure, virtually restricted it to ' symmetrical-twins^ in which the individuals are symmetrically disposed with respect to a plane which is not a plane of symmetry for either of them; a definition the bearing of which will be considered in a future chapter. 162. The twin-law, though true in the form in which it has always been enunciated so far as concerns a representation of the nature of the union of hemitropic crystals, appears to permit of considerable divergence from precision in the relative orienta- tion of the crystals subject to it ; the angles obtained by measure- ment from faces on the different individuals giving in many cases results which accord less exactly with those obtained by calculation than is the case with the angles on the individual crystals. On hemitrope crystals of albite, the twin-axis of which was in each case normal to (oio), Des Cloizeaux * found variations in the angle between a pair of faces theoretically parallel which amounted to from 40' to i 40'. * Man. de Mineralogie, t. i. p. 320. 1 82 Determination of the twin-plane. 163. It results from the law of hemitropy that each pair of corresponding faces on the two crystals lies in one zone with the twin-plane and that the faces make equal angles with it. So that, Fig. 63, if P, a pole on one of the individuals, correspond to P', a pole on the other individual, and a second pole Q on the first correspond to a pole (/ on the second, T being the pole of the twin-face, TP = \ PP', TQ = \Q(?; and if a pole L on either crystal can be found and determined in the same zone with P and P', and a pole R on the same crystal in a zone with Q and Q', the indices of T may be found, since [QK] and [PL] are tautohedral in T. If great circles be drawn through PQ and PQ', we have cosP(/= cos TPcos T(? + sin TP sin T&cosPTQ', cos PQ = cos TP cos TQ + sin TP sin TQ cos PTQ, and thus cosPQ / = 2 cos TPcos TQ-cosPQ ; an equation by means of which the angle between any two faces belonging to the two individuals may be found. In order to find the indices of the twin-plane where they are not given directly by inspection or by the zone-rule from recognisable faces, it is necessary in the first place to determine, by measure- ments with the goniometer and by calculation, the position of a face of the second individual as referred to the axes of the first. Thus if (7, Fig. 64, be the pole of a face of the second individual and Q, C, A be poles of known faces on the first, Q and Q' being Determination of the twin-plane. 183 recognisable as corresponding faces on the two individuals, the angles Q'C and QfCA must be determined by measurement and calculation, so that we have the values of the arcs QC and QC and the angle QCQ', for QCQ'= QCA-QCA : from the triangle QCQf we then obtain Qff, and therefore \QQf or QT, and also CQ@. Hence, further, from the triangle TCQ, in which QC, QT, and CQff are now known, the values of TC and TCA may be found, since TCA = ACQ + TCQ. From these two values the indices of T can be obtained by methods which will hereafter be given for finding the indices of a face from the requisite data under each system. Fig. 64. The values of Q'C and Q'C A can only be deduced from two measured angles, unless it should happen that a zone can be found on the first individual into which the pole (/ of the second individual falls, in which case the measurement of a single angle is sufficient; and where two zones can be found containing (/, no measured angle is required. 164. The practical method to be pursued in the investigation of a twin-crystal will thus be seen to consist, first, in determining the elements of one of the crystals, which of course involves our knowing those of both. Then, by having recourse to principles of symmetry and to the features characteristic of the faces of particular forms, we proceed to identify those faces which belong to some one or more forms on both the crystals, and to deter- mine the symbols of the faces which lie in zones common to the two. Where a face can be recognised as belonging equally to the two individuals, or when a face on one crystal is parallel to a 184 Investigation of a twin-crystal. corresponding face upon the other, this may be the twin-face ; or otherwise it is a face perpendicular to the twin-face, and therefore belongs to a zone the axis of which is the twin-axis. And often a careful inspection enables us to recognise such a plane either as the twin-plane or the plane of junction. Where these methods of attacking the problem wholly or partially fail, recourse must be had to others which may be suggested in each case by the character of the crystal itself, and which will depend on the principles laid down in the last article ; but then especially must measurements be made of all zones containing faces of both crystals. A line traversing a face may be the trace of a plane of junction of two crystals, and often some physical character such as striation evinces differences on either side of the line, and perhaps also a symmetrical disposition in respect to it, thus serving as a guide to the discovery of the twin-plane. And the position and nature of re-entrant edges at one part of the structure, and of faces on another part combined in accordance with a higher symmetry than that which governs an individual crystal of the substance, may help in the solution of the problem. In the case of a transparent crystal, polarised light will often lend invaluable aid in establishing the existence of a composite structure, by shewing in a section or cleavage fragment, or even in an entire crystal, dark and light or differently tinted bands, representing regions in which the directions of the optical principal sections are not the same. 165. Many crystals belonging to the Ortho-rhombic and Mono- symmetric systems fall crystallographically into one of two groups in which the angles between the faces of the prevalent prism or of a dome have values which approximate either to a right angle, or to an angle of 60. And such crystals, and particularly those of the latter group, often simulate, in the twin-structures they build up, the character of crystals endowed with much higher symmetry than their own. Thus copper-glance, aragonite, witherite, and other ortho- symmetrical carbonates isomorphous with the latter minerals, occur as groups of crystals which are constructed by a repeated twinning on the prism plane : and they present a symmetry closely resembling Simulation of higher symmetry. 185 that of a hexagonal crystal. Fig. 65 represents a triplet (or triple twin) of chrysoberyl (alexandrite), the character and relative orientation of the individual crystals that compose it being shewn in the three smaller crystals grouped around it. The lines / x / 2 are the twin axes, 7J T 2 the traces of the twin-planes on which the Fig. 65. crystal A is twinned so as to assume positions parallel to those exhibited by the figures I and II respectively. Faces of the dome { 101 }* are taken in the fig. as the twin-planes : the faces of this dome present the normal-angles i o i on To i = 60 1 4', 101 on 100 = 59 53'; tne faces oio of the different individuals * The above was Kokscharow's interpretation of these triplets. Though, offering a more simple illustration of the simulation of hexagonal forms, it is possibly less correct than the view of Hessenberg, as lately confirmed by Cathrein, viz. that a face of the form {301} is both twin- and junction-plane (Groth's Zeitschr. 1882, p. 257). 1 86 Simulated symmetry of leucite. are perpendicular to those of {101}, and unite to form a plane common to the crystals of the group. The striations of these faces parallel to the edges [oio, 100] of the three individuals intersect in a feathered pattern on this plane. 166. Leucite offers another striking illustration of the simulation by twin-crystals of a symmetry higher than that of the simple individual. Long treated as a typical crystal of the Cubic system in which it represented the form {211}, (a variety of icosite- trahedron formerly termed the leucitohedron), it was removed by the researches of Prof, vom Rath to the Tetragonal system, the crystals being viewed by him as twins in which two individuals presenting combinations of an isosceles (tetragonal) octahedron {111} and a scalene dioctahedron {421} are twinned on a plane parallel to a face of the form {201}, which is also the plane of union. The incomplete and anomalous character of the cleavage, a decided action on polarised light not easily explained in a cubic crystal, and pecularities in the striations on the faces, some of which occasionally exhibit a re-entrant angle, had pre- viously induced doubt as to leucite being correctly ascribed to the Cubic system. M. Mallard has, subsequently to vom Rath's researches, further investigated crystals of leucite and as a con- sequence removes the symmetry of this mineral still further from that of the Cubic system, the result of his investigation going to shew that the crystals are mono-symmetrical, but capable of being referred to an axial system not widely removed from that of a cubic crystal. And in the same memoir M. Mallard has con- siderably extended the number of minerals in which he recognises the simulation of high symmetry by twinned crystals belonging to systems of comparatively simple symmetry. Among them is boracite, a mineral the forms and angular measurements of which are entirely in accord with the symmetry of a crystal of the Cubic system of haplohedral type: the cube being usually the most prominent form ; and of this form the quoins are truncated by octahedral faces, of which the faces o of the form cr { 1 1 1 } are large and bright; while the faces co of the form o-jln} are either absent or small and of no lustre, and acquire an electrical potential opposite to that of the faces o under changes of tern- Case of boracite. 187 perature ; for, with a falling temperature down to 225C., the smooth faces are positive, and then become negative till the tem- perature falls to about i2oC., when they again become positive until the ordinary temperature is reached: the rough tetrahedral faces exhibiting inverse phenomena. M. Mallard, guided in the case of boracite entirely by the phenomena presented by sections of a certain tenuity when examined both in parallel and in diver- gent polarised light, arrived at the conclusion that, notwithstanding their cubic haplohedral symmetry and the apparent accord of their measured angles with those of a cubic crystal, they are complicated structures in which twelve orthorhombic crystals are united into a single pseudo-cubic combination ; each individual being a pyramid with its apex at the centre of the crystal and its base conterminous with a face of a pseudo-rhomb-dodecahedron. The advance of crystallography has, indeed, for some time been marked by the gradual removal to lower types of symmetry of crystals previously assigned to systems of higher symmetry. And the tendency of exact investigation seems in the direction of con- tinuing this process of removal ; as well by establishing the existence of slight variations from what had previously been deemed to be rectangularity of the axes or equality of parameters, as also by as- serting a more or less elaborately composite structure in crystals in which heretofore only simple forms and an almost typical repre- sentation of high types of symmetry had been recognised. Recent investigations by Mallard and Klein respectively have led to the discovery that the optical characters of boracite and leucite undergo a sudden change at a temperature which, in the former case, is about 265C., and, in the latter, is probably lower than the melting-point of zinc : above these critical temperatures the optical behaviour is in each case that of a cubic crystal. In the passage of boracite through the critical temperature there is an absorption or emission of heat amounting to 4-77 thermal units. Klein considers that the peculiar optical behaviour of these minerals at ordinary temperatures is of a merely secondary character, and a consequence of the contraction of the crystals on cooling. CHAPTER VII. THE SYSTEMS. SECTION I. The Cubic (or Tesseral) System. A. Holo- symmetrical Forms. 167. THE symmetrical characters of a form belonging to the Cubic system have been already considered and the systematic triangle determined (Articles 125, 126, and 127). The distribution of the poles of the general scalenohedron, the tetrakis-hexahedron, and the cube is shewn on Fig. 66. Those of the octahedron, the rhomb-dodecahedron, and of the two remaining forms, the triakis-octahedron and icosi-tetrahedron, are exhibited on Fig. 75, Article 173. Fig. 66 \L represents a systematic triangle of the system metastrophic with that con- taining thevpole hkl\ Fig. 66 a a systematic triangle antistrophic to the former. It is only requisite to state, in recapitulation, that a crystal belonging to this system, if it be holo-symmetrical, will exhibit symmetry to two groups of systematic planes, see Fig. 50, p. 145 ; viz. to three proto-systematic mutually perpendicular planes S, and to six deutero-systematic planes 2 ; which latter planes intersect 1. with each other in triads, in four trigonal axes o ; 2. with each other in pairs, perpendicularly, and with the planes S in pairs at 45, in the three tetragonal axes h ; 3. and each individually, perpendicularly, with a plane S, there being one such intersection in each of the six ortho- symmetral axes d. The letters h, o, d indicate at once the axial points for these axes and the angular points of the forty-eight systematic triangles into Holo symmetry. 189 which the sphere of projection is divided by the planes S and 2; and they also coincide with the poles /i, of the three axial planes ; i.e. of the proto-systematic planes S parallel to the faces of the regular hexahedron or cube {100}, o, of the parametral planes parallel to the eight faces of the regular octahedron {in}; and d, of the planes, also parametral, parallel to the twelve faces of three similar and concurrent square prisms, which together constitute the form {no}, the rhomb-dodecahedron. These viewed as origin-planes are the deutero-systematic planes 2. The origin-planes indicated by the poles o are not symmetral planes ; wherefore the symmetry on the axes o will only be tri- gonal or ditrigonal, and not hexagonal. The symbols and mode of distribution of the forty-eight poles 190 Cubic system. of the general scalenohedron {hkl} have already been discussed. They are contained in the subjoined TABLE A. 7 viii III hkl hkl hkl hkl Ihk Ihk Ihk Ihk klh Ylh klh kill (hlk Jiik liik hTk \khl Yhl "khl kill \lkhTkh Ikh lYh hkl hkl hkl hkl Ihk Ihk Ihk Thk ~kih klh kil Ylh hlk hlk hl~k ~hTk "khl kill khl Yhl Ikh Ikh Ikh Tkh all where the poles in each column belong to a single octant and the blocks marked a contain the symbols of faces antistrophic to the faces of which the symbols lie in the blocks indicated by /x The six remaining forms are those of which the poles lie on one or other of the three sides of the systematic triangles, and those of which the poles lie at the angles of these triangles. They will be represented by symbols in which one or two of the indices are zero, or in which two of the indices are equal; and in the latter case the two equal indices may be greater or may be less than the third, that is to say, they may be represented as {Ihh} or {hkk}. In the parametral octahedron all the indices are equal. The following are the seven holo-symmetrical forms of this system : 1. {hkl}, the hexakis-octahedron or forty-eight scaleno-hedron. 2. {Ihh}, the triakis-octahedron or the octahedrid pyramidion. 3. {hkk}, ihe icositetra-hedron or twenty-four deltohedron. 4. {hko}, the tetrakis-hexahedron or the cube-pyramidion. 5. {no}, the rhomb-dodecahedron or twelve rhombohedron. 6. {in}, the regular or equilateral octahedron. 7. {100}, the cube or square hexahedron. The names of these figures are more concisely expressed by the terms derived from the Greek numerals : the alternative English names here proposed for them have the single advantage of representing the contour of the figures by recalling certain Holo symmetry. 191 characteristic features : the term pyramidion being employed in the case of forms in which a pyramidion or small pyramid composed of similar isosceles triangles surmounts every face of a simpler figure, the faces namely of a cube, octahedron, or dodecahedron : such a figure is then an isoscelohedron. An isoscelohedron, scalenohedron, deltohedron, rhombohedron, &c. are figures formed severally of similar and congruent (but not necessarily metastrophic) isosceles or scalene triangles, deltoids, rhombs, &c. : an equilateral octahedron is the regular octahedron bounded by equilateral triangles. For brevity, the term ' faced ' in e.g. the forty-eight-faced scalenohedron, twenty-four-faced delto- hedron, &c., usually employed in the nomenclature of these forms, is omitted since no confusion can arise from this adjectival use of the numbers. It is obvious that names thus employed to represent some of the characteristics of a crystallographic figure can really only strictly describe it as an ideal figure constructed in equipoise ; a figure that can have only an exceptional occurrence in nature. If we bear in mind however the special characteristics of crystallographic symmetry, it will be seen that this is the simplest mode of considering a crystal-form; and consequently it will be employed in the following descriptions, in which the forms will be discussed in the order of the simplicity of their indices. 168. The square hexahedron or crystallographic cube {100} con- sists of the six faces parallel to the three axial or proto-systematic planes S, the normals to which are the crystallographic axes and the tetragonal axes of symmetry h. The three planes -S 1 being similar, the pairs of faces parallel to them will be simultaneous in their occurrence and similar in their geometrical and physical characters. The resulting form, see Fig. 69, when in equipoise, is the cube of geometry, a 'regular solid/ with equal squares for its faces; though as a crystal-form the faces are frequently rectangles. It has twelve crystallographically similar edges, the angle of each being 90. And it has eight similar three-faced quoins, the edges of which meet at right angles, and which are symmetrical to the trigonal axes of symmetry o. Cubic system. The symbols of the six faces of the form are IOO OIO OOI Too oYo ooT. Among minerals presenting the cube form, galena (lead sulphide) is remarkable for the facility of its cleavage parallel to the faces of this form. The metals gold, silver and copper, com- mon salt (NaCl) and sylvine (K Cl), fluor spar, cuprite, occasionally diamond, are among the minerals which present themselves as simple cubes. Pyrites also occurs in cubes, but Fig. 67. Fig. 68. Fig. 69. the striations often carried by the crystals prove them to be mero-symmetrical. See Fig. 55(2), p. 165. 169. The equilateral or regular octahedron {in}, Fig. 67. The equilateral octahedron is the parametral form of the system. The intercepts of its faces are equal on all the axes ; and the eight faces are equilateral triangles when the form is in equipoise. It then represents the regular solid from which it is named. The twelve edges of the form are all similar and have the dihedral normal-angle of the regular octahedron, viz. 70 31-7' = 2 arc H. The distance of two alternate poles of the form, i. e, of poles lying in attingent octants or measured over a quoin, is the arc 2 D = 109 28- 3'. The poles of the faces are the axial points o of the tri-symmetral axes, and its six quoins are symmetrical to the tetragonal axes h (in which lie the poles of the cube). The quoins are consequently formed by the meeting of four faces with plane angles of 60, or of four edges of which the normal-angles are each 70 31-7'. Holo symmetry. 193 The symbols of the eight faces of the octahedron are in In ill nT ill Til Hi TIT. Each edge of the cube subtends an arc formed of two con- secutive arcs H of a zone-circle 2, and each joins two poles of the octahedron : and, similarly, the edges of an inscribed octa- hedron join the poles of the cube; the quoins of the latter figure may thus be truncated by the faces of the octahedron, as may the quoins of the octahedron by the faces of the cube. The octahedron is represented as an isolated form by copper, silver, and by argentite, cuprite, senarmontite, fluor, spinel, chromite, periclase, magnetite, pyrochlore, franklinite, and, very rarely, the diamond. 170. The rhomb-dodecahedron {no}, Fig. 68. A face with the symbol no will evidently be a parametral face parallel to the axis Z, and since the axis Z coincides with one of the tetra-symmetral axes h, the face will be repeated in four faces, no Iio ilo ITo, forming a square prism. Similarly, the faces 101 Toi lol YoT will constitute a dome form or horizontal prism parallel to the axis Y, and the faces on oil oil oil a dome parallel to the axis X. And since the axes X, Y, and Z are identical with the tetragonal axes h. and are similar to each other, the three square prisms concur in building a form with the twelve congruent rhombic faces no Tio ilo TTo 101 Yoi loY YoY on oYi oiY oYY. And the axial points d of the axes of ortho-symmetry are at once the poles of the deutero-systematic planes 2 and of the faces of this form {no}. Two contiguous poles d not lying on the same great circle S will be symmetrically situate with regard to an arc D of one of the great circles 2. See projection. Fig. 50, Article 125, p. 145- The edge D of the corresponding faces will therefore lie in the plane of this great circle 2, and will subtend an arc of it which is the side D of a systematic triangle. O 194 Cubic system. These edges D will be twenty-four in number, and identical in feature. Contiguous faces with poles on the same great circle S will meet with two other contiguous faces with poles on a great circle S perpendicular to the former, in a quoin symmetrical to a tetragonal axis h. And the three contiguous faces sym- metrical to an axis o will meet on that axis in a trigonal quoin. The twenty-four edges of the dodecahedron will therefore meet in six four-faced quoins h, formed by identical acute plane angles, and in eight three-faced quoins o, of which the plane angles are also identical but obtuse. The normal-distance of a pole d from a pole h being 45, that between two adjacent poles d on different great circles S, for instance between oil and Tio (see projection in Fig. 75), is obtained by the equation cos (oiT, Tio) = cos 2 45 = cos 60 : the edge D has therefore a normal-angle of 60. And as in the zone-circle [oiT, Tio] there lie the four other poles To i oTi i To and loT, distant 60 from each other, and as the edges of the faces corresponding to these six poles will be parallel to each other and to the zone-axis [ni], it follows that if either of the trigonal axes o of the system, e. g. the axis {in}, be placed vertically, the rhomb- dodecahedron presents the character of a hexagonal prism parallel to that axis, and ter- minated by the faces of a rhombohedron which in the case assumed has the faces at the upper end no 101 on at the lower end TTo ToT oTT. Lines joining contiguous trigonal quoins o will give the edges of a cube. Hence of such an inscribed cube the edges are the short diagonals of the rhomb-dodecahedron in the figure. And the dia- gonals of the faces of this cube are evidently each equal and parallel to a pair of the longer diagonals in the same rhomb-dodeca- hedron. So that the ratio of a shorter to a longer diagonal of a rhomb-dodecahedron = the ratio of the side to the diagonal of a square = sin 45 = - : . Holo symmetry. 195 Whence for the plane angles of the rhomb, o hi since cotan - = tan - = 5 2 2 J 2 the angle h = 70 31 -7', and the angle o = 109 28 -3', which are also the normal- distances of two faces of the octahedron in adjacent and attingent octants respectively. It will be seen from the position of the edges of the dodeca- hedron that its quoins are truncated by the faces of the cube and octahedron, and that its faces in turn truncate alike the edges of the octahedron and those of the cube. The rhomb-dodecahedron is of frequent occurrence in com- bination with other forms, but is more rare in an isolated condition : it is however the habitual form of some varieties of garnet, sodalite, as well as of (haiiyne or) lapis lazuli ; while the minerals blende (Zn S) and lapis lazuli (or haiiyne) present cleavages in six directions parallel to the faces of this form. Diamond, gold, and electrum are among the substances that occur in rhomb-dode- cahedra. 171. Of the three simple forms hitherto considered, the faces are severally perpendicular to the three sets of axes of symmetry of the system, two or more zone-circles of symmetry being tauto- hedral in their poles. The forms next to be considered are those of which the poles lie upon the several sides of the systematic triangles; the form {hko} having its poles on the sides O of the systematic triangles, while those of the form {hhl} lie on the sides H and those of {hkk} on the sides D of those spherical triangles: the edges of the faces of the several forms will consequently lie in the sectors of each zone-plane corresponding to the arcs O, H, or D on which their poles do not lie. 172. The ietrakis -hexahedron, or the cube-pyramidion [hko], Figs. 70-2. If the poles of the form lie on the arcs O, its faces will form zones of which the tetragonal axes h are the zone-lines, and they will have a zero for the first, the second, or the third O 3 196 Cubic system. index of their symbol, according as the zone-plane in which the pole lies is the plane S 3 , or S 2 , or S lt Fig. 50, p. 145. In any zone-circle S, a pole of the form {hko} lies on the Fig. 70. Fig. 71. arc separating every two adjacent poles of the forms {100} and {no}; eight such poles lying in each zone-circle. The form will therefore have twenty-four faces symmetrical in pairs to the poles of the forms {100} and { 1 10} ; the edges of either of these latter forms would thus be bevilled by faces of the form {hko}. The figure presents the aspect of a cube each face of which is sur- mounted by an obtuse pyramid, and it may, on this account, be termed the cube-pyramidion. Since the faces are euthy- symmetrical to a plane S, the triangles that form them are crystallographically iso- sceles, and the figure is a twenty-four-faced isoscelohedron. The thirty-six edges of the form are of two kinds, viz. twelve similar edges H formed by faces which are symmetrical to and meet in the H sectors of the planes 2, and which are therefore coincident in direction with the edges of the cube, and twenty- four edges D that are similar and are formed by faces symmetrical to the D sectors of the zone-planes 2. These D edges meeting in fours form the six terminal quoins of the pyramidions Fig. 72. Holosymmetry. 197 of the figure symmetrical to the tetragonal axes h; while, of the H edges parallel to the edges of the cube, three, alter- nating with three of the D edges, meet with them to form a six- faced trigonal quoin o and of these quoins there are eight. The symbols of the faces of a form {hko} are arranged in TABLE B. hkQ hko lik hko kho ~khv ~khQ kho ohk ohk Qhk ohk okh okh okh okh koh koh koh koh hok hok hok hok where h and k may be any integer numbers. The distribution of their poles on the sphere is seen in the projection, Fig. 66, Article 167. In the cases of known crystals, the varieties of the cube- pyramidion include the following forms, 510, 410, 310, 520, 210, 320, 430, 540. These are more or less frequent on several crystallised bodies ; 510, for instance, on cuprite, 410 on silver and on gold, 520 on copper and on fluor, 320 on blende, 430 on perowskite, while 310 is a common variety of pyramidion. But the form {210} is by far the most frequent in occurrence, and presents the remarkable property that its H edges have the same dihedral angle as its D edges ; see Fig. 70. In this case it will be proved in Chapter VIII that cos H = cos D - j 5 and U= Z>= 3 652'ii-7". 173. The icositetrahedron^ or twenty -four deltohedron [hkk}> Figs. 73-4. This form has its poles situate on the arcs D of the systematic triangle. The edges consequently lie in the H and O sectors of the 2 and planes, and they are of two kinds, viz. twenty- four edges H and twenty -four edges 0. Of the twenty-six quoins, six are four-faced quoins h symmetrical to the tetragonal axes h, 198 Cubic system. eight three-faced quoins o symmetrieal to the trigonal axes o, twelve four-faced quoins d ortho-symmetrical to the axes d. The twenty-four faces are euthy-symmetrical to the traces of the sectors D, and have thus the form of symmetrical trapezia or deltoids. Fig- 73- Fig- 74- The icositetrahedron occurs rarely as an isolated form. Anal- cime, indeed, presents such crystals with the symbol {211}, and the attribution of analcime to the Cubic system, though it has been disputed, is now recognised *. The form {211}, Fig. 73, which is the commonest variety, is met with in a large number of crystals, replacing by its trigonal quoins those of the cube, and occasionally replacing the quoins of the octahedron by its tetra- gonal quoins h. Fluor, garnet, cuprite, and galena are among the minerals that exhibit the form {211}. This particular form {211} was termed by Haidinger the leucitohedron, and the general form {hkk} the leucitoid, from the crystals of leucite having been, though erroneously, attributed to this form. The character of these crystals has already been discussed in Article 166. This variety of the icositetrahedron is however an important one, not only from its frequent occurrence in combination with other forms, but also from the circumstance that its poles lie in the edge zones, i. e. in the zone-circles perpendicular to the edges, of the rhomb-dodecahedron, so that its faces truncate the edges of that * See Arzruni and Koch (Zeitsch. f. Kryst. 1881, p. 483), and Ben Saude (Jahrb. f. Min. 1882, p. 41). Holosymmetry. 199 figure. Thus the two adjacent poles of the dodecahedron (no) and (101) lie in the zone [In]; whence the poles lying on this zone-circle fulfil the condition h + k + l o, or h = k + l, which in the case of the icositetrahedron becomes h = zk and the symbol is therefore {211}. Another important icositetrahedron {311}, Fig. 74, occurs on the cubic native metals, on galena, pyrites, fluor, magnetite, and spinel, generally replacing the quoins of the cube by its trigonal quoins o. The symbols of the faces of a form {hkk} are arranged in the following TABLE C. hkk "hkk hk~k hkk hkk hkk hkk h~kk khk Ilk khk khk ~khk khk khk ~kh~k kkh Ykh ~kkh kkh ~kkh kkh kkh ~k~kh. iTo tfo Fig. 75- The distribution of the poles of the form {211} on the sphere is shown in the projection, Fig. 75. 174. The triakisoctahedron, or odahedrid pyramidion {hhl}> Figs. 2oo Cubic system. 76-7. The poles of this form lie on the arcs H, and its edges con- sequently in the sectors D and O : twenty-four in the former, and twelve longer than these in the latter. Hence the twenty-four faces are isosceles triangles, euthy-symmetrical to the traces on them of the sectors H. The figure will have eight trigonal quoins o. ,, six ditetragonal quoins h. Its aspect is that of an octahedron, each of the faces of which forms the base of an obtuse pyramid, and the more acute the pyramidion the more nearly it approximates in aspect to a rhomb- dodecahedron. Fig. 76. Fig. 77. Hence it is a twenty-four-faced isoscelohedron, and may be termed the octahedrid pyramidion. The form {221} exists on the diamond, and this form, as also the form {331}, occurs asso- ciated with the cube, or bevilling the edges of the octahedron, on galena, and occurs also on argentite, spinel, fluor, magnetite, franklinite, and pharmacosiderite. It is easily seen that the deltohedron which would truncate the edges of the form {211} must be that with the symbol {332}. In fact the addition of the symbols (211) and (121), which are those of adjacent faces symmetrical to the 2-plane [ooi, no], gives the symbol (332) of the face truncating the edge of the former faces. The form occurs on garnet. The symbols of the faces of the form {hhl} are given in Holosymmetry. 201 TABLE D. hhl III hhl hll hhl hll hhl 111 Ihh Yhh Ihh ill Ihh fhh Ihh 111 hlh Jilh III hll llh hlh hll HI. The distribution on the sphere of the poles of the triakis- octahedron {221} is shown in Fig. 75. 175. There only remains to be considered the hexakis- octahedron, or forty-eight scalenohedron {hkl}, Figs. 78-80. This form has received numerous designations, for the most part recalling the characters of the different figures which result from the indices receiving more or less widely differing relative values. Such are the terms octakishexahedron, hexakisocta- hedron, tetrakisdodecahedron, which may be represented in an English form as the eight-on-six, six-on-eight, and four-on-twelve scalenohedron; and they in fact indicate the different aspects the form assumes, as it approximates to a cube with an eight- faced, an octahedron with a six-faced, or a dodecahedron with a four-faced pyramid on every face. In general these figures cannot be legitimately designated as true pyramidions, since the bases of the pyramids do not actually coincide with the faces of the cube, octahedron, or dodecahedron, respectively : in cases, however, where the indices present the ratio h = k -f- / the basal edges coincide in position with those of the dodecahedron, and the figure, then, is a true dodecahedrid pyramidion. The most general designation is the tetrakontaoctahedron (or, forty-eight-faced form); the most usual term is the hexakis- odahedron; the simplest designation for this, the most complex of crystallographic forms, is the forty-eight scalenohedron. Each of the forty-eight systematic triangles contains one pole of the form ; in the case of some of the more frequent varieties of the form the poles lie either on great circles passing through a pole of the octahedron and bisecting the angles of inclination of two adjacent great circles 2, or on great circles passing through two adjacent poles of the rhomb-dodecahedron, situate sym- metrically in regard to a plane S. The edges in which a face of the form meets the three faces, 2O2 Cubic system. adjacent to it will lie in the three systematic planes containing the sides of the systematic triangle; and the faces themselves will be crystallographically scalene triangles. Hence there will be three sorts of edges, namely, twenty-four edges H and twenty- four edges D, which alternating in triads with each other form eight ditrigonal quoins o, and twenty-four edges 0, which alter- nating in fours with four of the D edges form six ditetragonal quoins h, and again alternating in pairs with pairs of the H edges form twelve ortho-symmetrical quoins d. The symbols of the faces of a form {hkl} have been set out in Table A, and the distribution of its poles on the sphere is seen in the projection, Fig. 66, Article 167. In considering the particular variety of this form, of which the poles lie on great circles bisecting the angles formed by each pair of great circles 2, it will be seen that poles lying on such intermediate great circles correspond to those which in a Rhombohedral crystal may occur on the great circles of the deutero-systematic planes of the Hexagonal system. In the Rhombohedral type of that system the symmetral character of these deutero-systematic planes is in abeyance, and the poles lying on their great circles belong to forms of trigonal type as they are constrained to do in the Cubic system by the conditions of its symmetry. The symbol of a form of this kind in the Rhombohedral system would be Ti{hil}, where i ; and that this relation between the indices must hold good in the Cubic system also may be shewn by taking the value for the cosine of the arc between two poles in this system, as will be deduced in Chapter VIII, Section 2. Thus, for the adjacent poles hkl and hlk meeting in an edge D, it will hereafter be shewn that we have and for the poles hkl and khl meeting in an edge H, we have Whence the condition for the edges D and H to have the same Holo symmetry. 203 dihedral angle is h 4- / = 2 k. Forms fulfilling this condition would be {321}, {531}, {543}, &c. The other noticeable variety of the forty-eight scalenohedron is that the poles of which lie in the edge-zones of the rhomb- dodecahedron, the faces of which consequently bevil the edges of that form. We have already seen, Article 173, that the poles of the form { 2 1 1 } lie in such an edge-zone-circle, its faces truncating the edges '12 Fig. 78- Fig. 79. of the rhomb-dodecahedron: and it was also shewn in Article 173 that the indices of a plane lying in one of these zones must fulfil the condition that one of them equals the sum of the other two. The forms {321}, {532}, {431} are among those which belong to this variety of scalenohedron; the form {321}, Fig. 78, is thus remarkable as being common to both the mentioned varieties. 204 Cubic system. Since the faces of any form of the latter variety, e. g. those of the form {431} in Fig. 79, bevil the edges of the rhomb-dodeca- hedron, the complete form has the character of a pyramidion developement of the rhomb-dodecahedron, each face of the latter figure being surmounted by a rhomb-based pyramid, to which it forms a conterminous base. These therefore are the forms that may be correctly designated as tetrakisdodecahedra or dodecahedrid pyramidions. The manner in which the quoins and edges of the cube, octahedron, and dodecahedron respectively are modified by asso- ciation with the forms hitherto considered is exemplified in the following figures. Fig. 81. Cubic System. B. Mere-symmetrical Forms. 176. In order that mero-symmetrical forms of the Cubic system may satisfy the law of mero-symmetry in respect to the two groups of systematic planes *S* and 2, it is not necessary that either group retain its symmetral character, provided that the character of the symmetry peculiar to the system be preserved in the resulting forms. Where both groups thus fail in directly con- Mero symmetry. 205 trolling the symmetry of the forms under consideration they in effect indirectly control it, inasmuch as the axes of symmetry in such a case must continue to regulate the symmetry of these forms. They can however do this, as far as the geometrical sym- metry is concerned, only in the case of the general form of the system, the forty-eight scalenohedron {hkl} : for there must be six faces arranged round a trigonal axis and eight round a tetragonal axis in order that, if half the faces are suppressed, the remaining half may be grouped trigonally in the one case and tetragonally in the other. Where only one group of systematic planes is operative as a group of actual planes of symmetry, the character of the resulting forms will be entirely different according as the group is that of the proto-systematic planes, the zone-axes of which are tetra- gonal in their symmetry, or is the deutero-systematic group, the planes of which intersect in threes, in zone-axes that are axes of trigonal symmetry. If a group of six faces of the scalenohedron lying in one octant be considered, it will be evident either that all the six faces must be suppressed simultaneously, or that only those three can be so which, lying in alternate systematic triangles, are metastrophic to each other. In the former case the 2 or deutero-systematic planes may be actual planes of symmetry, in the latter case they can only be potentially such. And if an alternate suppression take effect in one octant, a similar suppression must take effect in every octant in the case of a semiform. In the case however where all the six faces in one octant are suppressed, the only way in which the forty-eight scaleno- hedron can be divided into two correlative semiforms is by all the faces in any one octant, and in the three octants attingent to it, being simultaneously present or absent. A form of this kind is evidently haplohedral and holo-systematic, and its faces are symmetrical to the planes of the 2 group only; its symbol will be o- {/$//} or Fig. 85. Fig. 86. say in the sense of a physical hemi-symmetry, that we can speak of a cube, a rhomb-dodecahedron, or a cube-pyramidion pre- senting tetrahedrid hemi-symmetry. The tetrahedron or hemi-octahedron, o-{in} or o-jIII}, Figs. 85-6, is the simplest of the hemi-symmetrical forms belonging to the section under consideration, and as an isolated figure can only exist with equal faces. In the tetrahedron the four alternate faces of the octahedron, those namely in alternate octants, are suppressed. The resulting semiform corresponds in all respects with the regular tetrahedron of geometry. Bounded by four equilateral triangles, as an isolated form it can only exist in equipoise. The symbols of its faces are for the form o- {in}, in, Hi, III, ill, for the form o- {III}, III, nl, ill, In. P 2io Cubic system. The six edges of the figure will lie in the deutero-systematic planes 2, each edge being the trace on the faces forming it of two consecutive D sectors of a 2-plane. The four quoins are trigonal ; each axis o meeting a quoin o or CD on one side, and the pole of a face co or o on the opposite side of the origin. The normal-distance between two faces is measured by two consecutive arcs D, and is therefore 2D = 109 28-3'. Fahlore (or tetrahedrite), blende, eulytine, lead nitrate, and a variety of garnet from Elba are among the substances that present this form. Sometimes, as in helvine and in eulytine, the two correlative tetrahedra concur, but the faces of the one form are distinguished by being more largely developed than those of the other. Fig. 87. Fig. 88. 179. The hemi-triakisoctahedron, or twelve-deltohedron, v {hhl} or of the same axes, alternating with the former. And there are six four-faced quoins h on the tetragonal axes. Of the twenty-four edges, the twelve J9-edges meet in threes in the quoins o, and the twelve A-edges meet in threes in the quoins co. The symbols of the faces of the twelve-deltohedron a- {hhl} are hhl hhl hhl hhl, hlh hlh hlh hl\ Ihh Ihh Ihh Ihh. Those of the correlative semiform a {hhl} are the faces of the triakis-octahedron supplementary to these; they have an odd number of negative indices. The semiform a- {332} occurs onfahlore, and o- {221} on blende. 180. The hemi-icositetrahedron, or tdrahedrid pyramidion, o- {hkk} or & {hkk}, called also the trigonal dodecahedron, or twelve-hoscelohedron, Figs. 89, 90. The suppression of the faces of an icositetrahedron (or twenty- four-trapezohedron) which lie in alternate (i.e. attingent) octants produces a pyramidion figure, namely, a tetrahedron with a three- faced pyramid on each of its faces. Since the poles of the form lie on the D arcs of the systematic triangles, its twelve pyramidal edges H lie in the H sectors of the 2 planes, and the remaining six edges D coincide in position and direction with those of the tetrahedron. 212 Cubic system. The /Hedges meet in threes in the four quoins o or co ; the remaining four quoins co or o being each formed by the meeting Fig. 89. Fig. 90. of three edges H with three edges D. The symbols of the faces of the form a {hkk} are hkk hlk hkk hTk khk Yhk lh~k khk kkh Tkh ~kk~h kkh. Those of the form a {hkk} are the symbols of the remaining faces of the trapezohedron ; and in these the negative signs of the indices are one or three in number in each symbol. The form a- {32 2} occurs on tennantite; a {211} on fahlore and tennantite ; o- { 3 1 1 } on blende and fahlore. 181. The hexakis-tetrahedron, a {hkl} or a- \hkl], Fig. 91. The hemi-hexakis-octahedron, like the two preceding forms, presents gene- rally a tetrahedrid aspect, each axis o meeting at opposite extremities quoins which are ditrigonal but dissimilar. The six faces in each octant are scalene triangles and meet in six edges, of which alter- nate triads H and D are similar, while the remaining edges of the figure represent broken edges of the tetrahedron and are similar; each successive pair meeting two edges H and D in an ortho- symmetrical four-faced quoin h. Fig. 91. Mero symmetry. 2 1 3 The form has therefore thirty-six edges ; viz., twelve edges D, twelve edges H, and twelve edges A: fourteen quoins; four obtuse (or acute) ditrigonal quoins o, four acute (or obtuse) ditrigonal quoins o>, and six four-faced tetragonal quoins h. The symbols of the faces of the form a- {hkl} are given in the columns i, iii, v, vii; those of the form a {hid} in the columns ii, iv, vi, viii of Table A, Article 167. 182. B. II. Hemi-systematic diplohedral forms; hemi- tesseral semiforms. The second section of tesseral hemi-symmetrical forms is that under which the symmetry is hemi-systematic ; i.e. half only of the normals of the integral form are represented by faces ; but in the hemihedral case each of these normals carries its two parallel faces, so that the form is centro-symmetrical ; at the same time the proto-systematic planes *$* are alone planes of symmetry; and the poles of extant faces of the scalenohedron {hkl} circum- jacent to the trigonal axes must lie in alternate systematic triangles. Furthermore, no forms having their poles on zone-circles 2 can be hemihedral as regards the number of their faces, though every such form while presenting its full complement of faces will reflect in the distribution of their crystallographic (physical and geome- trical) characters a symmetry analogous to that represented in the semiforms is {hkl} and ^{khl}] since in fact this abeyance of symmetrical conditions must be the consequence of the mole- cular structure of the entire crystal. The geometrically hemihedral forms of this class will therefore be confined either to such as have their poles lying on the zone-circles S and symmetrical to the proto-systematic planes, and they will thus be semiforms of the cube-pyramidion ; or else they will be semiforms of the general scalenohedron {hkl}. 183. I" 1 he pentagon-dodecahedron, T:{hko} or n {kho}, Figs. 92-5. The pentagon-dodecahedron represents the hemi-systematic form derived from the tetrakishexahedron or cube-pyramidion {hko}. The symbols of the faces of one of the semiforms lie in alternate rows in Table B, Article 172, those of the correlative semiform in the rows alternating with these. Each face is divided euthysymmetrically by the trace of the 214 Cubic system. systematic plane S in which its pole lies ; and the edge O, formed by two adjacent faces of which the poles are on the same great circle, will lie in a second plane S perpendicular to the former. The edges G of adjacent faces, the poles of which lie on different great circles S t will not lie in any systematic plane : each face of the semiform will be adjacent to four such faces, and will thus have five sides formed by one edge O and four similar edges G, as in Figs. 92 to 95. Fig. 94 . Fi S-95- The semiform then has six similar edges and twenty-four similar edges G gyroidally symmetrical in threes on the trigonal axes o : these meet in eight trigonal quoins o formed each by a triad of G edges, and twelve quoins k formed each by two edges G and one edge O. Each face is thus an irregular pentagon symmetrical to the trace on it of a systematic plane S perpendicular to its edge 0. Mer asymmetry. 215 In the semiform Tt{hkl} this trace of the systematic plane becomes an edge, each pentagonal face of the form {hko} being 'broken' into two trapezoidal faces. (Compare Figs. 92 and 96.) The pentagon-dodecahedron approximates in character to the regular dodecahedron of geometry in proportion as the dihedral angles of its G and edges approach equality, resulting in those edges also approximating to each other in length. Were the pentagonal faces to become equilateral and equi- angular the edges and G would be equal, and thus the angle (ohk, ohk) would equal (phk, hko)-} whence, as will be proved in Chapter VIII, Section II, hk = tf-k' i and ~= I+ 5 , which is /v 2 irrational. The regular dodecahedron of geometry, thus impossible as a crystallographic form, is the limiting figure between the two classes of pentagon- dodecahedra, in which an edge O either is larger or is smaller in its dihedral angle than an edge G. In proportion as the length of the edge increases, the figure ap- proaches in form to the cube, the ratio j becoming greater: K where, on the other hand, this value approaches unity, i. e. as h approaches k in value, the figure approximates in form to the rhomb-dodecahedron {no} and the length of the edges is small relatively to that of the edges G. The twelve-pentagonohedron is a very characteristic form of certain mineral species which belong to a small group, of which pyrites is a conspicuous member. The forms 77(230}, 77(210}, 77(310} occur on pyrites, and the forms 77(410} and (210} on cobaltine. Sixteen other varieties of this form have also been met with on the former mineral. 184. The dyakis-dodecahedron or twenty-four-trapezohedron ; the diplohedron 77 [hkl], Figs. 96, 97. The poles of this form lie in the alternate triad of systematic triangles in each octant, while in any two adjacent octants the systematic triangles containing extant poles of the form are those which are mutually symmetrical on a systematic plane -S". The edges G of the triad of planes in each octant are therefore similar, and, like those of the form 77(^0}, are gyroidal in their 2l6 Cubic system. distribution round the trigonal axes; the edges 12 formed by pairs of contiguous faces in adjacent octants lie in the systematic planes S: and so also do the remaining edges 0, which correspond to the 'broken' edge O of the form Tt{hko], and are formed by other pairs of faces likewise in adjacent octants, but the poles of which do not lie in contiguous systematic triangles. Figs. 96 and 97 represent the correlative semiforms TT {231 } and TT {321 }. The twenty-four faces of the semiform are therefore quadrilateral figures corresponding to ' broken' faces of the semiform TT {hko}, and, as in that figure, the similar adjacent edges G are not similar to the remaining two ; and of the latter the one represented by an edge 12, is larger and the other represented by an edge is shorter Fig. 96. Fig. 97. than an edge G. Each face is thus a trapezoid. The form has then twenty-four edges G, twelve edges 12, and twelve edges O] and since the deutero-systematic planes fail of being symmetral, the axes h become axes not of tetragonal but of ortho-symmetral character, the six quoins h of the form being made up of two edges 12 alternating with two edges O : the eight quoins O correspond to those in the pentagonohedron and are made up of three edges G, and the remaining twelve quoins are formed by two edges G meeting an edge 12 and an edge O, both of which lie in the same systematic plane S. The terms dyakis-dodecahedron and diplohedron have been employed to convey the idea of the form being a doubled or ' broken-faced ' pentagon-dodecahedron. The symbols of the faces of the form Tt{hkl} are contained in Mer asymmetry. 217 Blocks I and II, those of the form v{khl} in Blocks III and IV of Table A. A particular case of the diplohedron occurs where one of the edges G is parallel to an edge 12. In such a case the form 77 {M/} will have e.g. its face hkl in the same zone with Ihk and Ihk, i. e. in the zone [o^//], whence by the doctrine of zones h k hi = / 2 or r = -7- K I The indices of the form 77(421} fulfil this relation. Such a form will have trapezia instead of trapezoids for its faces. This form 77(421} occurs on pyrites. Other diplohedra are 77(531}, 77(321}, and 77(543}, which are met with on crystals of pyrites, and occur also on those of hauerite and cobaltine. 185. B. III. Hemi-systematic haplohedral forms; tetar- tohedrism. Another case of mero-symmetry in the Cubic system still remains to be considered ; and it presents considerable interest from the association with this peculiar kind of mero-symmetry of the optical property of rotatory polarisation. It is the case in which a hemi-systematic form is only haplo- hedrally developed, resulting in a tetartohedral form. Evidently such a form can only exist as a geometrically independent form in a single case, that of the general form {hkl} ; the twenty-four normals characterising which are reduced to twelve. If therefore the half of the faces of each of the twenty-four-faced semiforms o- {hkl} or 77 {hkl} be mero-symmetrically suppressed, the re- sulting figure will be the twelve-faced tetartohedron in question. And as this suppression can take effect only on three faces in an octant simultaneously, it must be that three extant faces in alternate octants will be those to be suppressed. The resulting tetartohedral solid is the tetrahedrid twelve-penta- gonohedron n, and twelve quoins k in each of which an edge V meets an edge G and an edge f. Fig. 98. The symbols of the four correlative tetartohedra are contained each in one of the blocks in Table A, Article 167, and Figs. 98 and 99 represent two of the four quarter-forms derived from the scalenohedron {321}, viz. TTO- {231 } and TTCT {321}. Since the tetartohedral form may be derived from either of the three species of hemi-symmetric forms of the general scalenohedron {hkl}, it may equally well be represented by symbols av{hkl\ or tetrahedron o- {Yi i } are very marked in the mineral blende. The faces now usually selected from the two correlative semiforms to represent the faces, which are brilliant in lustre and smooth. These differences are represented in Fig. 125, of a twin-crystal of blende, in which both the correlative tetrahedra are present in association with the faces of the cube. In crystals where only one of the correlative forms occurs with the cube, the alternate quoins of the latter figure are truncated by the faces of the tetrahedron, an example of which is afforded by pharmakosiderite (cube-ore) from Cornwall. It occurs also on blende, see Fig. 55 (i). The faces of the co tetrahedron in fahlore are large, and striated parallel to the edges of the tetrahedron ; inverted therefore as compared with those of the o faces of blende, on which the striations are parallel to the edges of the octahedron, that is to say, the lines in which the striations meet correspond to the H sides of the systematic triangle in fahlore, and to the D sides of the triangle in blende ; the o faces are very small in comparison with the to faces. The iriakistdrahedra O}, IT {kho}. Pentagonohedra are illustrated almost exclusively by the group of minerals of which pyrites (iron disulphide) is the most familiar member, and hauerite, cobaltite, and gersdorffite, severally the corresponding sulphides or arseno-sulphides of man- ganese Mn S 2 , cobalt Co (S, As) 2 , and nickel Ni (S, As) 2 , are the other distinct minerals. Much discussion and laborious investiga- tion have been devoted by Friedel, Gustav Rose, Brezina, Schrauf, and E. S. Dana to the endeavour to establish some connection between the thermo-electric or the pyro-electric properties of different crystals or parts of crystals of these minerals and their crystalline forms. The result arrived at from the whole series of these investigations may be summarised in the conclusions that (i) pyro-electricity, i.e. the production of opposite electric con- dition in different parts of a body, while its temperature is changing, has no place in the case of the pyritoid minerals; (2) that as regards thermo-electricity, evidenced by a current set up by a difference of temperature at two contacts of one substance with another, the character of the forms of the crystal has no influence on the thermo-electric sign (positive or negative potential) ; and (3) that, though the variations in potential do exist, they have nothing to do with crystallographic symmetry, but are dependent on the relative density, and probably on differences in chemical composition of the crystals or parts of crystals investigated ; the less dense specimens generally representing the electro-positive, the more dense the negative varieties. Of the different pentagonohedra known on the pyritoid minerals the only one that is self-existent is the ' pyritohedron ' (of Hai- 228 Cubic system. dinger) 77(210} or 77(120}, which is common in pyrites and cobaltite. The correlative semiforms being superposable by a quadrant- revolution round a tetragonal axis no distinction can be drawn between the two semiforms as regards crystallographic develop- ment in alternate octants. It is, however, an exceptional occur- rence when two pentagonohedra of symbols 7r{/$/o}and7r {k'h'o } , the poles of which do not lie in the same systematic triangles, concur on a crystal: for usually, where two or more different forms occur together, their symbols are either all of the type i:\hko} or all of the type Tt{khQ}. And the same observation holds regarding the concurrence of diplohedra represented by a general symbol 77 {hkl\ with those of which the symbol would be On the other hand, crystallographers have recorded the occur- rence of the correlative semiforms 77 (210} and 77 (120}, 77 (320} and 77(230}, 77(430} and 77(340}, 77(540} and 77(450}, 7r{52o| and 77(250}, 77(650} and 77(560}; the symbol being determined by the association of the semiform with others belonging to octants adjacent to those in which the faces of the particular semiform lie. Correlative diplohedra with symbols 77(321} and 77(231}, 77(421} and 77(241}, 77(432} and 77 {342} have had their exist- ence attested in a similar way by Rome de 1'Isle, Haiiy, Mohs and Struver. Thus, too, Naumann and Zippe describe the union of 77(123} with 77(435}. Struver describes five other pentagono- hedra of type IT {hko} associated with 77(120}. And finally G. Rose records 77 (435} an <3 77 (324} as concurrent with 77 (l2o}. But these are few, and comparatively exceptional cases, met with among the very extensive and varied series of crystals that this group of minerals contributes to mineral collections. The pentagonohedron presents in the symbols of the forms that have been observed a larger range than does the cube-pyramidion, of which the pentagonohedron is the semiform. Thus the forms * |53}> ^ (43}> 77 (540}, 77 (650}, and 77 (607} are known of which the corresponding pyramidions have not been observed, Combinations. 229 whereas the hemihedron derived from the cube-pyramidion {520} has not yet been met with. Twenty-one distinct pentagonohedra have been recorded as existing on pyrites as well as seven kinds of tetrahedrid pyramidion, three of deltohedron, and thirteen of diplohedron. A remarkable combination of pyritohedron and octahedron is a not uncommon form of pyrites and cobaltite. It resembles in aspect the regular icosihedron of geometry, and is formed by the union of the two forms 77(210} and 7r{iii} in equipoise. The eight faces of the octahedron are equilateral triangles, and the twelve faces of the pyritohedron assume also a triangular form ; two sides of each of these triangles being formed by intersection Fig. 115. Fig. 1 16. with adjacent octahedron faces, the third side being the edge between two adjacent faces of the pyritohedron. Consequently the latter are isosceles triangles, and the figure would be a regular icosihedron but for the shorter length of the third side as compared with the sides of the octahedron faces. This combination is represented in Fig. 115. The Diplohedron TT \hkl\ or TT \khl\ is known to occur as a self-existent form on pyrites from Traversella with the symbol ^{321}, and on that from Brosso with the symbol ^{421}. The several other diplohedra occur in combination with one or more of the forms 7r{22i},7r{2ii},7r {311}, the cube, octahedron, and dodecahedron. But the forms are so varied, so intricate in aspect, but, withal, so simple in their crystallography, that detailed description of them is quite unnecessary. Fig. 116 represents a pyrites crystal with the forms 7r{i2o}j 210 Cubic system. 77(231}, 77(543}, and 77(100}; and Fig. 117(0) a crystal after Striiver with the forms 77(241}, TT {5 n 2}, TT {122} with TT {120}, 77 { 100 }, and 77 { 1 1 1 }. Fig. 1 1 7 (f) represents a quoin of the last crystal drawn on a larger scale. It is only requisite to observe, in regard to those complete forms of which the faces are grouped in triads but not ditrigonally round the trigonal axes, and which therefore do not admit of disparting into correlative semiforms, that these forms equally undergo hemi- symmetrical modification where they are concurrent with hemi- systematic semiforms. They are the cube, dodecahedron, icosi- tetrahedron, octahedrid pyramidion, and the octahedron itself. It has been mentioned in Article 147 that the cube may be striated in Fig. ii 7 (a). only one direction, but symmetrically to the -S'-planes in the case of its association with diplohedral forms : and that in the case of haplohedral forms it is striated in one diagonal direction symmetri- cally to the 2-planes only. Similar peculiarities of striation or of outline consequent on the abatement of some element of symmetry, and following the extant symmetry of the crystal, will be observed in all these forms. So that we are quite precluded from excluding from their symbols the characteristic o- or 77 which marks the symmetry or abatement of symmetry in the crystal. C. III. Combinations of Tetarto-symmetrical Forms. 191. The tetartohedron of the Cubic system is unknown as a self-existent form ; when met with it is always associated with other forms which are from the geometrical point of view either haplo- Combinations. 2 3 r hedrally or hemi-systematically developed. The forms (nr {351} and O-TT {421} occur on Barium nitrate. The original discovery by Marbach (Pogg. Annalen^ Vols. 91 and 94) of the tetartohedral character and the property of rotatory polarisation belonging to Sodium chlorate, Sodium bromate, Sodium-uranyl acetate long stood by itself. Now, however, the number of substances tetarto- hedral in symmetry has been increased, and includes the nitrates of Barium, Strontium, and Lead ; though in these the rotatory action on the plane of polarisation of plane polarised light either does not occur or is too feeble to be recognised. The fact that there can only be a single kind of tetarto- hedron in the Cubic system, that namely resulting from a haplo- hedral hemi-systematic developement of the forty-eight-faced scalenohedron, does not preclude a crystal from having tetartohedral symmetry, even though its forms do not include one of the type O-TT { hkl}. We find, for instance, the faces of a tetrahedron or of distin- guishable correlative tetrahedra associated with those of a twelve-pentagonohedron in crystals of Sodium chlorate. Here the faces of a cube are associated with those of a tetrahedron o- { 1 1 1 } and of the py- Fig. 1 18. ritohedron i:\2io}. Their proper sym- bols are therefore cnr {100}, O-TT {m}, O-TT {210}, since they afford evidence of the crystal being, concurrently, haplohedral for one form, and hemi-systematic for another form, where the faces of neither semiform group ditrigonally round the trigonal axes and cannot therefore be disparted into several tetarto-symmetric groups. Fig. 118 represents a crystal of Barium nitrate (described by Prof. Lewis) which carries the faces of the octahedron, really of the two tetrahedra, those of the icositetrahedron {311}, which like the former is to be supposed resolved into two tetrahedrid pyramidions, and finally, the tetartohedra o"7r{24i}, and an o tetrahedron meeting in an edge in the twin-plane. Fig. 125. Fig. 126. Fig. 126 represents a twin also of blende with the forms Fig. 153 (0- Since pro to- and deutero-sphenoidal forms cannot concur on a crystal, and it is at the option of the crystallographer to take either pair of similar axes as crystallographic axes, the analogy with tetrahedrid forms in the Cubic system points to the selection of an axial system such that, when sphenoidal semiforms occur on a crystal, they are treated as deutero-sphenoidal : and in usage therefore they are termed simply sphenoidal semiforms. 213. (g) Another variety of holo tetragonal mero-symmetry is presented in the case of the hemimorphous dioctahedron p {hkl} wherein the systematic plane C fails of being symmetral. And since this kind of hemi-symmetry permits of the other systematic planes being symmetral, we may have hemimorphous forms in which the indices h and k are equal, or one of them is zero, and of which therefore the poles lie on one of the great circles S or 2, or on both. Such semiforms comprise those with the symbols p {hhl\, p{m}, p {hoi}, p{ioi}, /o{ooi}. None of these hemimorphous pyramids or prisms can exist except in association with other forms. 214. II. Hemisystematic diplohedral forms; hemi- tetragonal diplohedra. The tetragonal isosceles octahedron or hemidiodahedron {hkl} or {khl}, Figs. 154 (a), (c). In a hemi-systematic form of the Tetragonal system four normals are absent, and the extant four are diplohedral : a distribution which can only occur in one manner, so that there is only one type of hemi-systematic diplohedral form. Of the faces, as grouped round the morphological axis, only alternate faces are extant, but S 2 260 Tetragonal system. the adjacent faces of the form symmetrical on the trito-systematic plane C are concurrent with them, since these are the faces parallel to the former and thus have normals in common with them. The only plane of symmetry is the trito-systematic plane C, the symmetral character of the S and 2 planes being in abeyance ; and the form is obviously centro-symmetrical. The symbols of the correlative semiforms are, of 4>{hkl), hkl khl h~kl khl, ~hkl khl hk~l ~khJ; and of {khl}, khl hkl Yhl hkl, Yhl hkl khl ~hkl The form has the character of a tetragonal octahedron, Figs. 154 (a), (c), its section perpendicular to the Z-axis being a square, the sides Fig. 154 0). Fig. 154 Fig. 154(0. of which are however not parallel to those of the axial or diagonal forms ; the pyramidal edges are gyroidally grouped in tetragonal symmetry round the ^-axis and are similar; so again are the basal edges. Hence the faces have the character of metastrophic isosceles triangles. The quoins are of two kinds, two gyroidal tetragonal quoins symmetrical on the morphological axis, and four similar four-faced quoins geometrically but not crystallographically ortho-symmetrical on two lines passing through the origin. 215. The hemidiprism {hko} or (p {kho}, Figs. 155 (a), (c). The alternate faces of the ditetragonal prism (Fig. 155 b) pro- duce a prism with a square section which is the limiting form of a series of hemidioctahedra having the same ratio for ; they Merosymmetry . 261 are tetragonally instead of, as in the diprism, ditetragonally dis- posed round the morphological axis. The faces of the form {hko} (Fig. 155 c) are, hko ~kho Jiko kTiOj and of the form [kh o} (Fig. 155 a), kho hko ItliQ hko. Their edges are similar, but symmetrical to no plane except the trito-systematic plane to which the faces are euthysymmetrical. And it will be seen that the sections of the forms {hkl\ and {hko} perpendicular to the morphological axis do not accord in the character of their angles with a crystallographic square. The association of the hemidioctahedron and hemidiprism with holo-symmetrical forms imparts also to the latter a quasi-mero- 20 "S -L 001 ! 2^3^. ! i i | 1 20 2301 230 i 320J i i L j 530 Fig- 155 () Fig. 155 (). Fig. 155 (c). symmetral character, since they thereby lose the special symmetry which characterises their edges ; and, as in the analogous case in the Cubic system, it cannot be doubted that this is only the external exponent of an interruption in the symmetry of the physical characters throughout the crystal. In this sense such forms as {hhl} } ^{hol}, ${ooi}, (j> {100} and ] axis, they must be reduced by hemi-systematic suppression to four normals tetra- gonally disposed round that axis. But the single face correspond- 262 Tetragonal system. ing to a normal may be extant or absent alternately on one or the other side of the trito-systematic plane, or all four faces may be simultaneously extant or absent on one side of that plane. Hence the two following forms may be originated : (i) The hemidisphenoid, so- {hkl}. The faces common to each pair of forms of a proto- and a deutero-disphenoid combine in producing one of the four quarter- forms s \hkl\, those in the second and third rows the correlative form$ {khl}, (see Plate II). (2) The hemimorphous hemidioctahedron. The symbols of the faces belonging to the several quarter-forms are ; for ap\hkl}, hkl khl hkl khl, ap{khl}, khl hkl Thl hkl, ap\Ykl}, hkl khl hkl Thl t ap{Wl], Thl hkl khl hkl. Each of them is formed by four alternate faces of the diocta- hedron lying above or lying below the trito-systematic plane C, and can only occur in combination with those of other forms. Fig. 157 represents the hemimorphous hemidiocta- hedron ap {321} in combination with the forms ap {100} and ap{Ti~i}. Those faces of which the symbols lie in the first and fourth rows would concur to build up a trapezo- hedron a{hkl], those in the second and third, the form a {khl} those in the two upper, or in the two lower rows, would constitute a hemimorphous diocta- hedron p\hkl} or p{7ikl}. Taken alternately, the first with the third or the second with the fourth row, the faces represented by these symbols would by their union produce a hemidioctahedron ($>{hkl} or respectively (see Plate III). There is as yet no proof that either of the above tetartohedral developements has been observed on tetragonal crystals : Werther, indeed, has described crystals of urea which presented a single Fig. 157- 264 Tetragonal system. pinakoid plane {001} in combination with a square prism {no} and a sphenoid a- { 1 1 1 }, but the occasional absence of a single plane can scarcely be regarded as sufficient evidence of the actual occurrence of tetartohedral crystals. Tetragonal System. C. Combinations of Forms. 217. The simpler character of the symmetry of the Tetragonal system as compared with that of the Cubic system is conspicuous in even the most complex combinations, since the faces of all the forms are seen grouped round a morphological axis with much regularity, and frequently with an approximation to equipoise developement. The following figures illustrate the dispositions of the faces of some prominent forms when combined with each other. Fig. 159. Fig. 1 60. Fig. 158 represents the combination of the axial prism with the axial octahedron. Fig. 159 shews the diagonal prism and octahedron in com- bination, and Fig. 160 the axial prism and diagonal octahedron. /..... lol Fig. 161. 110 illO oil- Fig. 162. Combinations. 265 In Figs. 161-165 are illustrated combinations of several other simple forms. Fig. 163. Fig. 164. Figs. 1 6 6, 167, 168 represent respectively crystals of anatase, 321... Fig. 165. Fig. 1 66. / ooi v_;, :;, g 38 , 2 ,\ III! MMJlp 10 jf iac '\frr~ QIC 120 no 210 '! si i\iai ~~-^-~l g 121 / in s^ Fig. 167. cromfordite, and cassiterite which have been actually observed, and 266 Tetragonal system. they illustrate the concurrence in various combinations of the diprism, the dioctahedron, the axial and diagonal forms, and the pinakoid. 218. (a) Of the mero-symmetrical forms of the Tetragonal system the asymmetric forms are not known to be represented on crystals, but in the case of hexa-hydrated strychnine sulphate, by a process of etching on the faces, Baumhauer developed traces of faces grouped asymmetrically. (<5) Of the other types of hemisymmetrically developed forms, the tetrahedrid (or sphenoidal) is illustrated by the minerals copper- pyrites and edingtonite. Copper pyrites occurs as a deutero- sphenoid faces belonging to the form o- {TIT}, which on the other hand are lustrous and without striation. The crystals therefore shew considerable analogy to those of blende. They sometimes carry also the faces of the deutero-disphenoids cr {316} and q > r ; and in the symbol {min} the index i is the arithmetic mean of the other two indices (i.e. i = - ), of which m is assumed to be algebraically the greater. The seven holo- symmetrical forms will be designated as follows : 1. {hkl, efg}, the dihexagonal scalenohedron or discalenohedron. 2. {pqr}, the dihexagonal prism or diprism. 3. {hkk, eff}, the (proto-dihexahedron or) dirhombohedron. 4. \min\, the (deutero-dihexahedron or) hexagonal pyramid. 5. {2!?}, the hexagonal proto-prism or -S'-prism. 6. {ioT}, the hexagonal deutero-prism or 2-prism. 7. { 1 1 1 }, the hexagonal pinakoid. The positions of the poles of such forms on the sphere of projection are illustrated in Fig. 183 for the case where = n = e=ii2M' (as in the mineral willemite). In Table F the poles of the di- scalenohedron are grouped in triads; those of the semiform {hkl\ (to which the axis [-5*2] is an axis of ditrigonal symmetry) taken in the order hkl are indicated by p, and in the order hlk by p' \ the poles of the correlative semiform {efg} are indicated in a similar way by q and q. 224. i. The discalenohedron {hkl, efg\, Fig. 184. The symbols Holosymmctry. 277 of the faces of the general independent scalenohedron of the Hexa- gonal system are contained in TABLE F. p...hkl Ihk klh hlk khl lkh...p', ITk Yh kh...p', egf feg gfe...q'-, p ...hk hk ih q...efg gef fge wherein h > k > I and h + k + / ^ o, and any of the literal indices may represent either positive or negative values inde- pendently of the sign in the general symbol. Fig. 184 represents the form {20!, 425} corresponding to the above parametral angle. J4S 415 Fig. 184. Fig. 185. The twenty-four alternately metastrophic triangles which com- prise the form are grouped round the morphological axis, and form two pyramids united by a common base in the horizontal plane C } a figure which, though doubly terminated, is by crystallographic usage termed a pyramid. Any section of this figure perpendicular to the morphological axis will be a symmetrical hexagon, of which only the alternate angles are equal. Two dihexagonal quoins form the vertices of the pyramids and are composed by edges and 2 alternating with each other, ad- jacent edges representing dihedral angles of different magnitudes. The twelve basal edges C common to the two pyramids are similar ; but the six lateral quoins which these edges form by meet- ing pairs of edges S are dissimilar from the six alternating quoins in which they meet pairs of edges 2. These lateral quoins are ortho-symmetrical, the former six on the axes [*S*C], the latter on the axes [2 C]. 278 Hexagonal system. 225. 2. The dihexagonal prism or hexagonal diprism { 185. Since discalenohedra with any given dodecagonal base in common may be indefinite in number, but will differ from each other in the acuteness of the apex of their pyramids, we may consider the case in which the angle formed by the pyramidal edges with the morphological axis [*S"2] vanishes, and the edges themselves become parallel with this axis. In such a case the twenty-four edges of the discalenohedron will become twelve, from the coincidence of each pair of edges sym- metrical to the trito-systematic plane; and the resulting form will have twelve faces parallel to the hexagonal axis [S"2]. It will therefore be a symmetrical (not regular) dodecagonal prism, an open form, the section of which perpendicular to its edges is the same as that of the discalenohedra of which it is the limiting form. But it is to be observed that it is, so far as its geometrical characters are con- cerned, also the limiting form of any twelve of the faces of the same figure if they be so selected that no pair is symmetrical on the equatorial plane C. If M/be a pole of one of the group of discalenohedra having a common section with the diprism {pqr}, a zone-circle passing through the poles (m) and (hkl} will contain corresponding poles of every discalenohedron of the group and also a pole of the form {pqr} ; and the symbol of the pole (pqr), in which the zone-circles [in, hkl\ and [i 1 1] are tautohedral, will be ( 2 h-k-l 2k-l-h 2l-h-k), a symbol which fulfils the conditions p -\-q-\-r = o and p > q > r, since h > k > I. If the symbol be derived from the correlative pole efg or the poles Tiki, efg, the two first of these three poles will give the symbol opposite to the face pqr. Thus the zones [* I I ]j that is to say, -h 2(l+h)-k 2(h + k}-l, in] and [in] are tautohedral in the face The hexagonal diprism will have two sorts of edges alternating with each other, and lying respectively in the proto- and in the deutero-systematic planes. Fig. 185 represents the diprism Holosymmetry. 2 79 An important feature of the hexagonal diprism results from its faces belonging to a zone, all the planes of which, except the sys- tematic planes and 2, are planes of abortive symmetry. They in fact present a stereotyped feature of unchangeability whether for crystals with different parameters or for different temperatures. The following are the normal-angles between the face (pqr) of some of these prisms and the face 2 IT. The angle (2 IT, pqr), where pqr is 523= 6 35', 3 l2 = io54', 725 =13 54', 4^3 = 16 6'; 514=19 6', 615 = 21 3', 7i6 = 2227', 8T7 = 2 3 2 5 '; 918 =24 1 i', 101=30, 112; = 60, oil = 90. 226. 3. and 4. The isosceles dodecahedra. The culminating edges of the discalenohedron being of two kinds, the one symmetrical to the proto-, the other to the deutero-systematic planes, the faces of a form truncating the edges of one kind will be dissimilar from those which truncate the edges of the other kind. Both the forms will be twelve-faced and their faces isosceles triangles, meeting in two vertical quoins symmetrical to the hexagonal axis. Perpendicular to that axis the section of a figure of either kind is a regular hexagon. Thus they are isosceles dodecahedra or hexagonal pyramids. The form of which the poles lie on the proto-systematic zone- circles has for its symbol \hkk, eff}, and may be regarded as composed of two correlative rhombohedra, formed by planes having in their symbols the indices h k and ef respectively. And since the rhombohedral type of hemi- symmetry, to which the sca- lenohedron also belongs, is of preponderating importance among all the types of this system, the relation of the hexagonal to this trigonal type is recalled by the use of a terminology for the hexa- gonal forms corresponding to the composite nature of their symbols. The hexagonal proto-pyramids will therefore be termed dirhom- bohedra, while the others, of which the faces truncate the 2-edges of the discalenohedron, will be designated simply as hexagonal pyramids, since they belong equally to the hexagonal and trigonal types. The general symbol for the hexagonal pyramids will be \min\\ a symbol in which, as has already been seen, the index 280 Hexagonal system. i is the arithmetic mean of the other two : as in fact is evident, since the symbol for a systematic plane 2, which is also a zone- plane containing four of the poles of a form \mtn\, is that of a plane of the form {1^1}, and thus m 2z'+n = o. 227. 3. The dirhombohedron {hkk, eff], Figs. 186-7. Tne symbols of the faces of the isosceles dodecahedron {hkk, eff} are hkk khk kkh, eff f'f //; hkk Yh~k Ykl, where e=k + 4k,f = 2h-\-k, since eff is the pole in which the zones [nI, khk~\ and [oil] are tautohedral ; that is to say, is (4k h t Fig. 1 86. Fig. 187. The dirhombohedron may also be treated as the form truncating the *S*-edges of a discalenohedron. If hkl, hlk be two adjacent faces of such a discalenohedron, since the symbols are symmetrical we obtain the symbol of the truncating face by the addition of their indices, i.e. the face in question is (2 h k + l / + /). The poles of a dirhombohedron {hkk, eff} which lie on the zone-circle [-SJ or [oil] are hkk eff hYk Iff, [S 2 ] or [lol] are khk fef ~kli~k f~ef, [S s ] or [ilo] are kkh ffe Ykli ffe. Holo symmetry. 281 Figs. 1 86 and 187 represent the dirhombohedra {4!!, 877} and (100, 122} corresponding to the given parametral angle. 228. 4. The hexagonal pyramid {min}, Fig. 188. The faces of the hexagonal pyramid will have the following symbols, and lie on the several zones [2] in the subjoined order : on zone [2J or [1^1], min nim min nim; on zone [2 3 ] or [112], nmi mni nmi mni\ on zone [2J or pn], inm imn inm imn. In Fig. 1 88 is represented the hexagonal pyramid {513} corre- sponding to the above parameters. The symbol of the form truncating the 2 -edges of a di- scalenohedron {h k /, efg] may be obtained either by determining the symbols of the face in which a zone containing two adjacent faces of the discalenohedron symmetrical to a plane 2 is tauto- hedral with the zone of which 2 is the zone-plane ; for instance, the face in which \hkl,gfe\ and [I2l] are tautohedral; or by the briefer method of adding corresponding indices of the two symbols hkl gfe when brought into corresponding form, as indi- cated in article 133, p. 154. A dirhombohedron and a hexagonal pyramid are precluded by the symmetry of the system from being mutually congruent : nor can a pole of the form {hkk, eff\ be equidistant with a pole of the form \min\ from the pole { 1 1 1 }. A pole of a form {min} equi- distant with a pole (hkk) from (i 1 1) would in fact have the symbols the indices of which can only be rational when h = k, and the symbol (min) becomes (m), or when 2k + h = o, and the symbol (min) becomes (in); that is to say, in the cases where the hexagonal pyramid passes over into one of its limiting forms, the pinakoid or the deutero-prism. 229. The hexagonal prisms. The general symbol \pqr\ has been assigned to such forms as have their poles on the equatorial zone-circle C. Where such a form has three different literal indices the form is the diprism (Art. 225). But since p = (q + r), if q = r the symbol becomes {2 IT}, a particular case of the 282 Hexagonal system. symbol {hkk}, and thus represents a form having its poles on the proto-systematic zone-circles. If, again, p = r, then q = o, and the symbol is { ioY}, a par- ticular case of the symbol {mzn}; it thus represents a form having its poles on the deutero-systematic zone-circles. This symbol is in fact that of a face truncating the faces (hkk} and (e/f), i.e. (3^ 3^ 3^) and (h ^k zh + k 2k + k), namely (zhk kh k h\ or (2TT); and similarly a face truncating the edge \rnin nim] is (m n o n m) or loT. 230. 5. The hexagonal proto-prism {2!!}, (Fig. 189). This form, which may be considered as the form of which the faces truncate the equatorial edges of the dirhombohedron, or as a limiting form Fig. 1 88. Fig. 189. Fig. 190. of the figures which may be produced by combining those faces of the dirhombohedron which have only h and k or e and f in their symbols, has for its poles the axial points of the axes [SC] ; on which axes therefore its faces are ortho-symmetrical. The faces are parallel to the deutero-symmetral planes 2, those parallel to 2 t being 2!! and 211, those parallel to 2 2 being 12! and ill, those parallel to 2 3 being IT2 and 112". Its edges also lie in the planes 2 and are parallel to the hexagonal axis. It is an open form without quoins, but its faces have an ortho-symmetrical character. Holosymmetry. 283 231. 6. The hexagonal deutero-prism jioT}, (Fig. 190). This form, which is identical in features with the proto-prism, has for the normals of its faces the ortho-symmetral axes [2C], the faces themselves being parallel to the proto-systematic planes S. The faces parallel to S^ are oil and oTi, to S 2 are lol and Toi, to S 3 are iTo and Yio. The edges of the form also lie in the planes S. The horizontal sections of the proto- and deutero-prisms are regular hexagons, and the edges of the one form are truncated by the faces of the other form, and are bevilled by the faces of the diprism. 232. 7. The pinakoid { u i }. This form, the two faces of which are parallel to the trito-systematic plane C, has the morphological axis for its normal, and is, as its symbol implies, the pyrametral form, meeting the three positive or the three negative arms of the crystallographic axes with equal intercepts. The form is further, in holo-symmetrical crystals, dihexagonally symmetrical on the [-S2] axis. Its two faces (in) and (ITT) truncate the terminal quoins of the discalenohedron and the isosceles dodecahedra, and they close the dihexagonal and hexagonal prisms (Figs. 185, 189, 190) with faces that are symmetrical dodecagons in one set of cases and equiangular hexagons in the other. Hexagonal System. B. Merc-symmetrical Forms. 233. The mero-symmetrical forms that are possible in the Hexa- gonal system are numerous and varied in their types ; the faces of the discalenohedron being capable of partition, in accordance with the principles of mero-symmetry, into correlative forms in which they possess one or other of the following kinds of alternate distribution : I. Twelve faces corresponding to twelve normals are extant or are absent : holohexagonal haplohedral forms. II. Twelve faces corresponding to six normals are so : hemi- hexagonal diplohedral forms. 284 Hexagonal system. III. Six faces corresponding to six normals: hemihtxagonal haplohcdral forms. IV. Six faces corresponding to three normals : tctarto-hexagonal diplohfdral forms. V. Three faces corresponding to three normals: tdarlo-htx- agonal haploJudral forms. In the following table of the symbols of the faces of a discaleno- hedron \hkL cf\, the symbols of the pair of faces belonging to each normal form a column in the upper or in the lower half of the table ; and the triads of faces being for convenience in notation indi- cated by the letters employed for them in Articles 114, 115, 116 and 120. pp. 130-138, those designated as />./', q, q' will be mutually metastrophic, and antistrophic to the remaining faces of the form. TABLE G. p...hkl Ihk klh hlk khl lkh...p', p...hk~l lh~k ~kTh ~hl'k ~khl l~kh ...p' t q...cfg gff fg fgf ffg gf <-, q, p' or q', but they may concur with those of any other of the latter triads. Thus, we may only have combinations of the following kinds : I. i. p and q with p' and q', and its correlative p qp' /. iL p and p' with q and q' 7 ,. ., pp f q q f . iii. p and q' with p' and y, ., ,. pq* ' p' ' q. iv. /and/*' with q and q'. ., ., pp'y^- II. And. in a hemi-systematic diplohedral cn-stal, any triad /, q. p' or / must be accompanied by the corresponding parallel triad /, q, p' or q*. So that the only possible combinations are : i. / and p with />' and />', and its correlative qqq f q f - ii. p and p with / and q', iii. p and p with q and q, Mer asymmetry. 285 III. A haplohedral form of a hemi-systematic crystal must belong to one of the tetartohedral types resulting from the concurrence of the following face-triads : i. p with p' : and the three correlatives q q', p'p , tf q. ii. p with?': ?/,/?> /A iii. p with q\ 3P,p'7, // iv. p with / : q /, p p', q ?. v. p with / : q p', p?,q p' . vi. p with q : //, / q , p'tf. IV. And since a tetarto -systematic partition of the twelve normals into four groups of three normals is also possible, the discaleno- hedron may yield four diplohedral correlative forms. They are the face-triads that concur in one of the four following correlative groups : p with p, q with q, p' with p', and / with q'. V. A tetarto-hexagonal haplohedral form would be represented by the faces p, and the discalenohedron would yield seven other forms correlative to it. These octo-forms would be hemimorphous. 235. The following table exhibits the forms which result from these mero-symmetrical modes of distributing the faces of the dis- calenohedron ; and with them are associated such mero-sym- metrical developements of the other holo-symmetrical forms as are geometrically distinct from the forms from which they may be derived. I. Holo-systematic haplohedral forms ; or holohex- agonal haplohedra: i. Symmetrical to no systematic plane The ditrapezohedron a (hkl, efg} or a {hlk, tgf\. ii. Symmetrical to the C- and ^-systematic planes The di trigonal (j>roto- or} S-pyramid x \hkl\ or x \efg\- The ditrigonal (proto- or) S-prism . x \pqr\ or x [pqr\. The trigonal (proto- or) S-pyramid . x \hkk\ or x \cff\* The trigonal (proto- or) S-prism . . x {211} or x {^n}. 286 Hexagonal system. iii. Symmetrical to the C- and 2-systematic planes The ditrigonal (deutero- or) ^-pyramid {hkl,gfe} or {hlk,gef}. The ditrigonal (deutero- or) HL-prism {pqr} or \prq\. The trigonal (deutero- or) ^-pyramid {min} or f \mni\. The trigonal (deutero- or) ^-prism f { ioT} or f { iYo}. iv. Symmetrical to the S- and 2-planes Hemimorphous hexagonal forms : Discalenohedral hemimorphs p\hkl, efg\ or p{hkl, efg\\ &c. II. Hemi-systematic diplohedral forms; or hemihex- agonal diplohedra. i. Symmetrical ditrigonally to the -^-systematic planes The ditrigonal scalenohedron i:\hkl} or Tt\efg\. The rhomb ohedr on TT {hkk\ or 'R\eff\* ii. Symmetrical ditrigonally to the 2-planes The deutero-scalenohedron -ty \hkl, gfe} or \// {efg, lkh\. The deutero -rhombohedr on ^\f\min\ or \jf\nzm}. iii. Symmetrical to the C-plane Gyroidal forms : The tritopyramid ${hkl, efg} or ${lkh, gfe}. The hemi-diprism {pqr} or (j> {rqp}. III. Hemi-systematic haplohedral forms; or hemihex- agonal haplohedra: each represented by four cor- relative forms : i. Normals symmetrical to the -S-planes - The trigonal trapezohedron an {h k I}. ii. Normals symmetrical to the 2-planes The trigonal deutero-trapezohedron a\j/ \hkl}. iii. Normals symmetrical to the C-plane The skew trigonohedron x$\hkl\. Hemimorphous hemihexagonal forms : iv. Symmetrical ditrigonally to the S-planes The hemi-protopyramid PTT \h k /}. The hemi-protorhombohedron pir {hkk\. Merosymmetry* 287 v. Symmetrical ditrigonally to the 2-planes The hemi-deuteropyramid p-ty \h k I}. The hemi-deuterorhombohedron p\j/ \m in}. vi. Symmetrical to no systematic plane The hemi-tritopyramid /o< {hkl}. IV. Tetarto-systematic diplohedral forms; tetarto- hexagonal diplohedra. Three extant normals. The hemiscalenohedron or skew rhombohedron 7r< \hkl\. V. Tetarto-systematic haplohedral forms. The hemimorphous hemiscalenohedron pTt($){hkl} ; &c. Of these combinations, the third under the holo-systematic type with the merosymmetrical prefix f, the second under the hemi- systematic diplohedral type distinguished by the prefix \f/, and the second under the haplohedral type of the latter division with prefix a\jf have only a theoretical interest, since if any hexagonal crystal should present forms corresponding to either the ditrigonal pyramid or the scalenohedron, the systematic planes to which such forms were symmetrical would offer themselves for choice as the proto- systematic group, for it is contrary to mero-symmetrical principles that, on any crystal, forms symmetrical to only one group should be associated with such as are symmetrical to a different group of systematic planes. The consideration of such forms has however a theoretical interest, and their recognition is so far necessary that without them a complete view of the modes of mero-symmetrical dissection of which the hexagonal discalenohedron is susceptible cannot be taken. 236. I. Holo-systematic haplohedral forms. i. The ditrapezohedron a {hkl, efg] or a {hlk, eg/}, Figs. 191 (a), (c), is contained by either set of alternate faces of the dis- calenohedron, the other faces forming the correlative figure ; all the faces of one of the semiforms are antistrophic to those of the other, and the semiforms themselves are enantiomorphous. 288 Hexagonal system. The symbols of the twelve faces comprised under the form- symbol a{hkl, efg} are hkl Ihk klh hll ~klil Tkh efg S e f the correlative form a [hlk, eg/} comprising the remaining faces of Table G, Art. 233. Figs. 191 (a) and (c) represent the forms a{2ib, 452} and a (20!, 425}, respectively, derived from the discalenohedron {20"!, 425} represented in Fig. 191 (3). The faces are disposed in hexagonal (not dihexagonal) sym- metry round the axis [*S*2], so that the six culminating edges E, which unite in a quoin to form the apex of the figure at either Fig. 191 (). Fig. 191 (c\ end, are similar. But the figure has no plane or centre of symmetry. Its remaining edges F and G are of two kinds traversing the equatorial plane in zigzag. The faces are trape- zoids bounded each by two edges E, an edge F, and an edge G. The twelve lateral quoins are similar, each being formed by the meeting of three dissimilar edges E, F, and G. The forms a (P a-{hkk, eff}, a {min}, a {2!!}, a {iol} and a {in} are geometrically identical with the holo- symmetrical forms from which they are derived. No crystal presenting this type of hemi- symmetry has yet been observed. 237. ii. and iii. To the next two subdivisions under holo- hexagonal merosymmetry belong forms which, by the condition of the division, are not centro-symmetrical. They are, however Mer asymmetry. 289 symmetrical to the trito-systematic plane, and to one or other of the triads of systematic planes and 2. It has already been observed that in reality we need only take cognizance of one of these types as of actual crystal-forms ; for the two cannot concur, and the occurrence of one type on a crystal would ensure that triad of systematic planes to which it was sym- metrical being selected for the proto-systematic planes S. 238. ii. The dilrigonal proto-pyramid or S-pyramid x {hkl\ or x \efg\, Figs. 192 (a), (c). In the ditrigonal proto-pyramid the sym- metral character of the deutero-systematic planes is in abeyance. The dihexagonal axis of the original discalenohedron becomes a ditrigo- nal axis by virtue of its being the zone-axis of three similar planes of symmetry S lt S z , S 3 . The plane C being also a plane of sym- metry, the following are the constituent faces of the form x {hkl}, hkl Ihk klh hlk khl Ikh, e f 8*7 Fig. 192 (a). Fig. 192 (6). Fig. 192 (c}. They correspond to the groups />, />', g, q' of Table G : the form x {^fg} comprises the remaining faces of Table G, viz. those of the groups p,p', ? rqp. Figs. 193 (a) and (c) represent the forms ^{514} and ^{ respectively, derived from the diprism {5!?} shown in Fig. 240. The trigonal proto-pyramid or S-pyramid x (h k k} or x { eff}, Figs. 194 (a), (c), may be regarded either as truncating the S- or S'-edges, respectively, or as being a limiting case of the ditrigonal proto-pyramid, in which pairs of faces symmetrical to the *S*-planes of symmetry have become coincident. The figure s thus a double pyramid with an equilateral triangle for base. There are six similar culminating edges S or S / lying in the S-planes of symmetry, and three similar basal edges C lying in the equatorial plane. Fig. 194 (a). Fig. 194 Fig. 194 (0. The symbols of the faces of the form x [h k k} are hkk khk kkh *77 7*7 771 those of the form x {eff} being hYk Yh~k ~k~kh eff fef ffe. Figs. 194 (a) and (c) represent the forms ^{877} and ^{41!}, respectively, derived from the dirhombohedron {4!!, 877} repre- sented in Fig. 194 (). 241. The trigonal proto-pr ism or S-prism x {2 11} or x {211}, Figs. 195 (a), (c), is an open prism with an equilateral triangle for U 2 292 Hexagonal system. base. The poles lie at the intersections of the S- and C-planes, and the three similar edges -S or S' lie in the *S"-planes of symmetry. The faces of the form x {2!!} are 2i7, 2!, 7i2, those of the form x {ssii} being "211, ili, nI. 2ia all Fig. 195 (a.} Fig. 195 Fig. 195 Figs. 195 (a) and (<:) represent the forms x {211} and x {211}, respectively, derived from the hexagonal proto-prism {2!!} repre- sented in Fig. 195 (d). The forms x{min}, x {ioY}, and x {111} are geometrically identical with the holo-symmetrical forms from which they are derived. 242. iv. Hemimorphous hexagonal forms. By the condition of this subdivision only the S- and 2-systematic planes retain their symmetry. Hence the faces of any form be- Fig. 196 (a\ Fig. 196 Fig. 196 longing to it will all lie at one side of the equatorial plane, and the figure will be represented by the upper or lower half of the corresponding holo-symmetrical form. The only forms which are geometrically distinct from those presenting holo-symmetry are Mev 'o symmetry. 293 p{hkl, efg}> p{hkk, e//}, p{min], and p{m}, with their correlatives. Figs. 196 (a), (b\ (c) represent respectively the forms p { 201, 425}, p (411, 877}, and p {513}. closed by the form p {HI}- 243. II. Hemi-systematic diplohedral forms. The characteristic distinction of the mero- symmetrical forms of the Hexagonal as contrasted with those of the Tetragonal system is, that in the Tetragonal system centre-symmetry and symmetry to the equatorial plane are concurrent conditions, whereas in the Hexagonal system these two kinds of mero -symmetry are quite independent of each other ; so much so indeed that a centro-sym- metrical semiform in the latter system can only be symmetrical to the equatorial plane in the case of a form which is symmetrical to no other plane than this. Of diplohedral semiforms therefore we have two kinds. In the one kind, the normals are symmetrical to one or other but not to both of the systematic plane-triads, and each carries its two faces ; in the other kind, alternate normals, symmetrically distributed round the axis of form as a hexagonal (not dihexagonal) axis, are diplo- hedral. In the former kind the discalenohedron is dissected into two similar scalenohedra, in the latter kind the partition is into two correlative forms of which each is a double pyramid, with a geometrically equilateral hexagonal base. The scalenohedra can in theory be of two kinds ; proto-scaleno- hedra symmetrical to the proto-systematic planes S, and deutero- scalenohedra symmetrical to the deutero-planes 2. The three planes, however, to which the scalenohedral forms are symmetrical being those which naturally offer themselves as the proto-systematic planes, we have only to deal practically with the scalenohedron as a proto-systematic diplohedral form. In accordance with the notation adopted for such a form its symbol will be Ti{hkl} or -n\efg}\ that of a deutero-scaleno- hedron would be -^ \hkl, gfe} or \jr {hlk, eg/}. 244. i. The ditrigonal scalenohedron, it {hkl} or TT {efg}, Figs. 197 (a), (c). The symbols of the twelve faces of the scalenohedron 294 Hexagonal system. 7T {h k 1} symmetrical to the proto-systematic planes S correspond to the groups p, /', p, p' in Table G (Art. 233) and are hkl Ihk klh hlk khl Ikh, hYl Thk Yl~h Yl~k Yhl Tkh\ those of the form TT {efg} lie in the two lower rows of Table G, and correspond to the groups q, q', g, g'. They are, efg e f fS e e gf f e gf e > efg g e f fg e e gf f e g gf e - Each face of the form is a scalene triangle, of which two of the edges S and S', culminating in a ditrigonal quoin on the axis [*S"], lie in the planes S, while the third edge lies obliquely to the plane C. Fig. 197 (a). Fig. 197 Fig. I 9 7 (<:). The figure has therefore two ditrigonal quoins forming its vertices, and constituted by three edges alternating with three edges S'. It has moreover six lateral edges G, which are similar but lie in zigzag athwart the plane C, and meet in six quoins similar but alternately inverted in position, in each of which an edge -5* and an edge S f meet two of the zigzag edges G symmetrically as regards a plane S. The two correlative scalenohedra are tautomorphous, since adjacent faces on each form are antistrophic to each other. And a revolution of either figure through an angle that is an odd multiple of 60 brings it into congruence with Its correlative form. Figs. 197 (a) and (c) represent respectively the forms 71(201} and TT {425} derived from the discalenohedron {20!, 425}. 245. The ditrigonal prism, TT {pqr}. The zone-circles passing through the pole in and successive poles of a scalenohedron will Merosymmetry. 295 intersect the zone-circle \S~\ in the poles of a prism the faces of which are parallel to the axis of the zone []. From a geometrical point of view the figure, considered as an open form, is identical with the diprism {pqr}. Crystallographi- cally however it is not so, as is evident when a ditrigonal form is combined with the prism. The ditrigonal prism is in fact the limiting form of the two correlative scalenohedra, in the case in which their faces become parallel to the morphological axis and their poles fall on the equatorial zone-circle. 246. The rhombohedron, v{hkk} or TT {e//}, Figs. 198 (#),(<:), 199 (a), (c). The relation of the rhombohedron to the scaleno- hedron is analogous to that of the dirhombohedron to the discale- nohedron; and, as the faces of two correlative scalenohedra have, in the one, symbols into which only the literal indices hkl, and Fig. 198 (a). Fig. 198 (b). Fig. 198 ). in the other, symbols into which only the literal indices efg enter, so the faces of two correlative rhombohedra have in their symbols the indices hkk and eff respectively. If the normal-angle of two adjacent faces of the scalenohedron be supposed to become zero, the faces come to lie in a plane, and each pair of antistrophic faces becomes a single quadrilateral face, euthysymmetrical to the line originally representing their edge, which is the trace on the face of a plane of symmetry : the opposite angles are equal in pairs, and the form of the face is geometrically a rhomb. Crystallographically however it is not so, since its adjacent culminating edges which represent the S"-edges of the scalenohedron are not similar to those which represent the lateral or G-edges of the latter figure, though they have become parallel to them. 296 Hexagonal system. The twelve faces of the scalenohedron being represented by six faces in the rhombohedron the figure is a rhombic hexahedron or six-faced rhombohedron, and may be acute or obtuse according as the three-edged quoins which are the vertices on the morpho- logical axis are formed by edges which meet in three acute or three obtuse angles. Figs. 198 (a) and (c) represent the correlative acute rhombohedra 77 {877} and TT {4!!} derived from the dirhombohedron {4!!, 877} of Fig. 198 (), while Figs. 199 (a) and (c) represent the corre- lative obtuse rhombohedra TT {^22} and TT {100} derived from the dirhombohedron {100, 722} of Fig. 199 (<5). Fig. 199 (a). Fig. 199 (<:). Fig. 199 The summit-quoins are symmetrical ditrigonally on the [S] axis. The six other quoins are symmetrical to no axis, but only to the -S-planes of symmetry, and are each formed by the meeting of a culminating edge S with two of the six lateral or zigzag edges G. In each lateral quoin of an acute rhombohedron two lateral edges make an acute angle with each other and an -obtuse angle with a summit-edge. In each lateral quoin of an obtuse rhombo- hedron two lateral edges make an obtuse angle with each other and meet a summit-edge in two acute angles. The alternate quoins are directly congruent ; those intermediate to them are also Mero symmetry. 297 congruent with them, but are inverted in their orientation relative to the morphological axis. The limiting form dividing the acute from the obtuse varieties of the rhombohedron is the cube, the faces of which are geo- metrically squares. The Cubic system is in fact a developement of the Rhombohedral system resulting from the condition that, when the faces of the rhombohedron become squares, the zigzag edges become crystallographically, as well as geometrically, similar to the culminating edges. 247. The trigonal dihexahedron, ^{min}. Should the poles of a scalenohedron fall on the great circles corresponding to the deutero-systematic planes, the resulting twelve-sided figure would evidently be a limiting form between the two series of correlative scalenohedra. Such a form is geometrically identical with the hexagonal dihexahedron already considered, but its adjacent faces are crystallographically antistrophic. The forms TT {2!!}, ^{lol} and -77(111} will likewise be geometrically identical with the corresponding holo-symmetrical forms. 248. The zigzag edges of a scalenohedron, and therefore also those of a rhombohedron, are truncated by the faces of the hexa- gonal deutero-prism {ioT}. For if the poles of two adjacent faces meeting in one of these lateral edges be considered, the poles hkl and lk~h for instance, in the one form, or the poles h k k li~k Ji in the other, the sum of their indices gives the symbol (ioT) for the face truncating the edge ; and similarly for the other edges of the form. And the lateral quoins in both figures will be replaced symmetrically by the faces of the hexagonal proto-prism {121}, which are perpendicular to the proto-systematic planes to which these quoins are symmetrical. The summit-edges of the scalenohedron will be truncated by the faces of rhombohedra, direct or inverse according as the poles of the scalenohedron faces forming these edges are disposed symmetrically in respect to such quadrants of the systematic great circles S as contain the poles of the form {100}, or to the remaining quadrants of those great circles. In fact, the edge of the faces hkl and h Ik is trun- cated by the face (zh k-\-l & + 1), the symbol of which is obtained 298 Hexagonal system. by adding the indices of the two symbols, and has the form h'&k', while the edge of the faces Ihk and / k h is truncated by the face (2! h + k h + k), the symbol of which has the form //'/'. 249. The indices of a face will all have positive values where the pole of the face lies within the spherical triangle of which the angular points are at the poles 100, oio, and ooi, and they will be all negative when the pole lies in the triangle with its angular points at the poles Too, ooi, oio. The values of one or of two of the indices will be negative in every other symbol. 250. Forms consisting of two correlative scalenohedra or rhombo- hedra associated together but differing in their physical characters are of very frequent occurrence ; so frequent in fact that the existence of truly holo-symmetrical hexagonal crystals has been disputed : Professor Miller indeed only recognised a Rhombohedral system, holosymmetrical in itself, and referred no crystals to a Hexagonal system. That there exists, inherent in the laws which regulate the coordination of the crystal-molecules, a cause for the great prevalence of trigonal diplohedral symmetry in crystals belonging to this type may be accepted as a result of experience ; but that it is a cause which precludes the recognition of a Hex- agonal system, such as is necessary to the theoretical completeness of the principles of geometrical mero-symmetry, is hardly to be admitted. It would not be so were the evidence against the existence among known crystals of holo-symmetrical hexagonal forms complete; but in fact this evidence is not complete, and there are crystals, of which those of beryl may be taken as an example, which in their cleavage and in the physical as well as geometrical characters of their forms offer no sufficient grounds for referring them to a trigonal rather than a hexagonal type of symmetry. 251. ii. The deutero-scalenohedron, \|/- \hkl\ and deidero-rhombo- hedron, \ff { m in } need only to be noticed as forms of which some cognizance must be taken in a complete review of the various mero-symmetrical partitions of which the faces of a discaleno- hedron and a hexagonal pyramid are theoretically susceptible. Detailed descriptions of these deutero-symmetrical forms are unnecessary, inasmuch as in everything but in the form of their Merosymmetry. 299 symbols and the particular planes to which they would be sym- metrical they are identical in character with the forms considered in the foregoing articles. 252. iii. Gyroidal forms. There remains a group of centro- symmetrical forms belonging to the hemi-systematic division of the Hexagonal system, which present no symmetry to the proto-or deutero-triad of systematic planes, but which are symmetrical to the trito-systematic plane C. The morphological axis is an axis of simply hexagonal symmetry for such forms, in which therefore of the faces of the discalenohedron which lie on the same side of the equatorial plane only alternate ones can be extant. It is only the discaleno- hedron and the diprism that will present geometrically distinct forms under this type, and from their symmetry to the plane C they have been termed the trito-pyramid and trito-prism or hemi-diprism. 253. The trito-pyramid, <$){hkl, efg\ or $\lkh, gfe], Figs. 200 (a\ (c], differs from the ditrapezohedron in that, while in the Fig. 200 (a). Fig. 200 Fig. 200 (c). latter figure the whole of the faces of a semiform were meta- strophic, only those on one side of the plane C are so in the trito- pyramid, those on the other side being symmetrical, and therefore antistrophic, to the former. The correlative forms are thus tauto- morphous, being capable of being brought into congruence by a rotation round the morphological axis, after interchange in the positions of the vertices of one of them. The figure is formed by two hexagonal pyramids, the base common to which is a regular hexagon. Its two summit- quoins are formed each by six similar edges, and each of its ;oo Hexagonal system. six lateral quoins by the meeting of two of these edges with two of the basal edges, which are all similar and lie in the equatorial plane. It is evident however from the gyroidal position of its faces in respect to the vertical axis, that none of its summit- edges can undergo truncation, since no two planes of the system can be equally inclined on them. The symbols of the faces of the form ${hkl, efg} are contained in the left-hand half of the Table G (Art. 233). They are, hkl Ihk klh hkl Ihk fg klh, Those of the form $\lkh,gfe\ are contained in the right-hand half of that Table. Figs. 200 (a) and (c) represent respectively the forms $ {20!, 425} and $ {Io2, 524} derived from the discalenohedron (20!, 425} represented in Fig. 200 (3). 423 lag 14S Fig. 201 (a). Fig. 201 Fig. 201 (c). 254. The hemi-diprism or trito-prism, $>{pqr] or ${prg\, Figs. 201 (a), (c), has the geometrical character of a regular hexa- gonal prism, its edges having normal-angles of 60. But its poles do not lie at angles of the systematic triangles, and the faces are crystallographically symmetrical only to the equatorial plane. Figs. 201 (a) and (c) represent respectively the forms $ {54^} an d {514} derived from the diprism {514} shown in Fig. 201 (&). The forms e//}, ${mtn] and are geometrically identical with the corresponding holo-symmetrical forms. 255. III. and IV. Tetarto-symmetry. The distinct types of tetartohedra that may occur in the Hexa- gonal system, apart from those resulting from hemimorphism, are four in number. Three of these types are haplohedral, and in them each of the six alternate normals of the discalenohedron is represented by a single face; they correspond, in fact, to the six different hemi-systematic forms from which they are the haplohedral derivatives. The fourth is a unique case of tetarto-symmetry in which three normals only are represented, but by both their faces: it is therefore of diplohedral tetarto-systematic type (Art. 265). Four correlative tetartohedra admit of being combined in three different ways, and so can only reproduce three distinct pairs of correlative hemi-symmetrical forms. It will thus be seen that four different tetrads are needed to build up six distinct hemi- symmetrical derivatives from the discalenohedron ; for one pair of hemi-symmetrical forms must be common to any two of the groups that are built up by separate tetrads of tetarto-symmetrical forms. All four of the tetarto-symrnetrical forms alluded to must there- fore take part in the construction of the six hemi-symmetrical forms which are not hemimorphous. The projections in plates IV to VII exhibit the relations of these forms to one another. The tetartohedral forms of whatever kind may be treated on a principle analogous to that followed for the hemi-symmetrical forms. In the latter, the symmetrical distribution of the poles of a form in respect to the different systematic planes was taken for this purpose. In the tetarto-symmetrical forms it is, further, the distribution of those normals which are conceived as extant that determines the nature of the resulting quarter-forms. Thus the normals which are represented each by a pole may be symmetrical to the proto-, to the deutero-, or to the trito- systematic planes ; or, symmetrical to none of these, they may be gyroidally grouped round the axis of form. A form of the last kind is however necessarily hemimorphous in its character. 302 Hexagonal system. 256. III. Hemi-systematic haplohedral forms. If the six normals are to be symmetrical in respect to the proto-systematic planes, they will be the same normals which in a ditrigonal scalenohedron 77 \hkl\ are diplohedral ; or which in the trapezohedron a{hkl, efg\ and ditrigonal 2-pyramid {hkl, gfe] are haplohedral. Now these normals may carry their six faces all on one side of the plane C in a simply hemimor- phous way (Art. 261) ; or, the faces may be distributed partly above and partly below that plane, and this can only occur in one way, that namely indicated in the projections in Plate V. 257. i. The trigonal trapezohedron, an [hkl\, Figs. 202 (a], (c), (d), (/) The figure corresponding to any one of these four pro- jections has trapezoids for its faces, which meet in two trigonal quoins on the [S] axis, and have in a crystallographic sense three sorts of edges. The faces of each tetartohedron are mutually metastrophic. The symbols of the faces of the four quarter-forms are as follows : /x r ,, 7 , (hkl Ihk klh hlk khl Ikh or (1) an\hkl\ 1 P P (2) an {hlk} (3) *v\'fg\ L P JiYl Thl ITh hlk khl Ikh or p p>_ e fg g e f fge e gf feg gfe or (4) **{'g/\ {'SS-S'ffg* eg/ /eg gft Of these forms the first and third, and the second and fourth, are tautomorphous, but, taken otherwise in pairs, the forms are enantiomorphous. In Figs. 202 (a) and (c} are represented the forms a 77 (20!} and an (2lo}, which together compose the form 77(20!} shown in Fig. 202 () : the remaining correlative tetartohedral forms a 77 {425} and a 77 (45 2} shown in Figs. 202 (d) and (f) together compose the form 77 (425} represented in Fig. 202 (e). The two enantiomorphous groups an {hkl} and a77 (,/} are of great interest from the occurrence of several forms of one or Merosymmetry. 303 other of these particular groups on crystals of certain minerals, of which quartz is a conspicuous example ; the particular group, when it occurs on the crystal, indicating by its presence the nature of a rotatory influence of the crystal on a ray of polarised light traversing it in the direction of the optic axis, which is the morphological axis [*S*2]. In a crystal of quartz the forms a-n{hkl] are indicative of Isevo -rotatory, the forms aTt{hlk} of dextro-rotatory action. Fig. 202 (a). Fig. 202 (&}. Fig. 202 Fig. 202 (d). Fig. 202 (*). Fig. 202 (/). The form an {hkk} is geometrically identical with the form T:{hkk}) and the forms 077(2!!}, a7r{m} with the corre- sponding holo-symmetrical forms; the remaining forms air {pqr}, a-n{min}, and aTrjio!} are geometrically identical with the ditrigonal forms {pqr}, {mz'n}, and f {10!}, and only differ from the forms represented in Figs. 193, 194, and 195 in that they are symmetrical to the 2-planes instead of the -S-planes. 258. ii. The trigonal deutero-trapezohedron^ a-fy{hkl}. The six normals to which its extant faces belong will be symmetrical to the 304 Hexagonal system. deutero- systematic planes, the faces of any two symmetrically placed normals being in opposite hemispheres. The symbols a^t\hkl\, a^{hlk}, a\j/\efg\, a\l/\egf\ would represent the tetrad of forms. Mutatis mutandis, the figure is quite similar to that of the trigonal trapezohedron described in the last article. If the extant poles of the pairs of symmetrical normals lay on the same hemisphere, the form would be the hemimorphous tetartohedron p^{hkl], (Art. 263). 259. Where the six extant normals are in pairs symmetrical to the trito-systematic plane, the faces will either all lie on one side of that plane and form a gyroidal hemimorphous form p$ {hkl}, (Art. 264), or they will be distributed symmetrically in respect to the plane C and form a pyramidal figure in which two trigonal pyramids (of which the faces, though geometrically isosceles, are crystallographically scalene) stand base to base and are trigonally symmetrical on the morphological axis of the system. 260. iii. The skew trigonohedron, x<\>\hkl\, Figs. 203 (a), (c), (d), (/}. The faces of the form which carries the face hkl are those which are common to the forms <$>{hkl}, x{hkl\, and f \hkl\, their symbols being hkl Ihk klh e fg The summit-quoins are three-faced, formed by trigonally similar culminating edges metastrophic to each other, which can only be replaced by planes which do not truncate them ; so that two of these edges belonging to a face are not alike in their relations to that face. The three lateral quoins are four-faced, two culmi- nating edges alternating with two lateral edges, but they are symmetrical to no axis. In Figs. 203 (a) and (c) are represented the forms oc {20!} and x(f) {425}, which together compose the form {2oT, 425} shown in Fig. 203 (d); the remaining cor- relative tetartohedral forms x

{210, 452} represented in Fig. 203 (e). The form x$ {pqr} would be a skew three-sided prism with an Merosymmetry. 305 equilateral section, and would consist of the three faces pqr, rpq, qrp\ the forms x${hkk} and x<$> {2!!} would be geometri- cally identical with x{hkk} and x {2!!}, and x$ {mzn}, x{ioi} with {min], f {ioT}: the form x$ {m} would carry both its faces. Fig. 203 (a). Fig. 203 (). Fig. 203 (V), Fig. 203 (d). Fig. 203 (,?). Fig. 203 (/). No crystal is as yet known which carries the faces of a skew trigonohedron. 261. iv. v. vi. Hemimorphous tetartohedral forms. The hemi- morphous derivatives from hemi- symmetrical forms will be repre- sented by three tetartohedral modes of dissecting the general hemimorphous form p{hkl, efg], or p {h ~kl, efg }, and the forms p{hkk,eff}, p{min\, p\pqr}, &c. Each tetrad of correlative tetartohedral forms in this division will therefore reproduce the two correlative hemihedral forms with 306 Hexagonal system. the above symbols, and also two corresponding correlatives of the six remaining hemi-symmetrical forms. Their symbols, taking that one of the four forms which contains a pole hklioi example, are, iv. the hemi-protopyramid pit {hkl}, v. the hemi-deuteropyramid p^{hkl}, vi. the hemi-tritopyramid p<$>{hkl}. 262. iv. The hemi-protopyramid, or, more completely expressed, the hemimorphous ditrigonal protopyramid, as represented by the form PK {hkl}, is the form the normals of which are symmetrical to the S-planes (Fig. 204) : its faces therefore are those of the upper half Fig. 204. Fig. 205. of a scalenohedron TT {hkl}, or of a ditrigonal ^-pyramid x {hkl}, as well as of p { h k 1} . The symbols of the tetrad are pi: {hkl}, pv\e/g}, pv{hkl}, pir{e/g}. The hemimorphous ditrigonal prism pit\pqr} is a ditrigonal prism with six faces, forming a symmetrical hexagon, of which the alternate edges are similar and adjacent edges dissimilar, as are the forms which close its opposite ends. The hemimorphous rhombohedron and hemimorphous trigonal S-pyramid represent in the forms p7t{hkk} and px {hkk} the upper halves of those figures ; geometrically the same figures, they do not differ crystallographically. Their symbols, taking pit for the designating letters, are p*{hkk}, pv{eff}, pv{hYk}, pit {I//}. A hemimorphous dihexahedron p f n{min} would be identical with the form p\min\, excepting in its crystallographic association with ditrigonal forms. Mero symmetry. 307 263. v. The hemi-deuteropyramid p^{hkl}, hemi-deuteroprism p \fs \p q r } , and hem i- deuterorhombohedron p-fy {mzn}, would be analogous forms to those just described if the deutero-systematic series of forms were to be recognised as actual forms ; but they have only a theoretical interest, for the same reason as that which removes the ditrigonal deutero-scalenohedron and the deutero- rhombohedron from among the forms belonging to practical crystallography. 264. vi. The normals represented in the hemi-tritopyramid are symmetrical to no systematic plane, but are hemihexagonally disposed round the axis of form. In the form taken as example, they are the normals which are common to the forms p{hkl, efg}, a \hkl}, and $ \h k /}, (Fig. 205). The tetrad is composed of the forms p{hkl, efg}, p\hlk, eg/}, p{hkl, e/g\, p \hl~k, ~eg/}. The hemimorphous tritoprism p${pqr} differs crystallographi- cally from the hemi-diprism ${pqr} in the different character of the forms closing its opposite extremities, and, so far only, is also geometrically different. 265. IV. Tetarto-systematic diplohedral forms. The hemiscalenohedron or skew rhombohedron TT(f> {hkl}, Figs. 206 (a), (c), (d), (f), belongs to the remaining tetarto-symmetrical type, namely, that in which each of the three extant normals carries both its faces. The symbols of the faces of the form TT(/> {hkl} are hkl Ihk klh hkl Ihk klh. The figure is geometrically a rhombohedron : it differs from the crystallographic rhombohedron of Art. 246 in that its edges do not lie in systematic planes, and are thus incapable of truncation or bevilment : further, the two three-faced quoins on the morpho- logical axis are trigonally, not ditrigonally, symmetrical. In Figs. 206 (a) and (c) are represented the forms TT(#> {20!} and i:(f) {2i"o}, respectively, which together compose the scaleno- hedron TT {20!} shown in Fig. 206 (3), and in Figs. 206 (d) and x 2 308 Hexagonal system. are represented the remaining correlative forms TT { 45 2} and K {425}, which together compose the correlative scaleno- hedron -TT {425} shown in Fig. 206 (e). The forms Ar{2ii},^<|>{ioi}, and x $ { 1 1 1 } are geometrically identical with the holo-symmetrical forms {zYT}, (iol},and {in}, and the forms x<$>{pqr], x${hkk}, x${miri\ with the hemi- symmetrical forms < {pqr}, 77 {hkk}, and \|/ {min} respectively. Fig. 206 (a). Fig. 206 (). Fig. 206 (c). Fig. 206 (d). Fig. 206 Fig. 206 (/). 266. V. Tetarto-systematic haplohedral forms. The remaining type of mero-symmetry is one in which only three normals are present, each carrying a single face. The symbols of the faces of the form pTr

to the discalenohedron {467, 942}, and the faces ba to the proto- and deutero-prisms respectively. Fig. 207. Fig. 208. 269. (b) Hemi-symmetrical forms. Of the varieties of hemi- symmetry of which the Hexagonal system is susceptible, that diplohedral type in which only the proto-systematic planes are symmetral, often designated as the Rhombohedral system, is the most frequent, and, indeed, the habitual type to which crystals in the Hexagonal system belong. In rhombohedral crystals the trigonal grouping round the mor- phological axis is quite as marked a feature as the hexagonal grouping in the holo-symmetrical crystals, or the tetragonal grouping in the crystals of the system last considered. Where prism-forms are extant, the crystals assume a hexagonal aspect ; for the orthogonal projection of the side- or zigzag-edges of a rhombohedron on a plane perpendicular to the trigonal axis is a regular hexagon, the sides of which are the traces on the plane of projection of the faces of the hexagonal deutero-prism {iol}. Combinations. 311 Thus the aspect of crystals in which prism-forms are present, even if they be not predominant, differs considerably from that of crystals in which only rhombohedral or scalenohedral forms are extant. Figures 209 (a), 210, 211 (a), 212, represent in ortho- gonal projection on the equatorial plane the relations of a direct Fig. 209 (a). 2ZZ Fig. 209 Fig. 211 (a). Fig. 211 Fig. 212. and an inverse rhombohedron to the proto-prism and deutero- prism; Figs. 209 (), 211 () represent combinations of forms corresponding respectively to those of Figs. 209 (a), 211 (a), but projected on a plane distinct from the equatorial plane. 270. Rhombohedra and scalenohedra are not unfrequently com- bined in tautozonal series, the faces of one rhombohedron trun- cating the edges of another more acute. In the following table any symbol in either of the inner columns is that of a rhombo- hedron, of which the faces truncate the edges of the rhombo- hedron having its symbol in the other inner column and on the 312 Hexagonal system. line next below : a symbol in either of the outer columns is that of a rhombohedron transverse to (i. e. correlative with) the rhombohedron of which the symbol stands on the same line with it and in the inner column : T 4* Z i cj S" 1 Inverse Forms. Direct Forms. {141717} {655} {233} {1077} {255} {211} {Oil} {4n} {122} {IOO} {III} {5"} {755} (3"} {533} {1777} {31 17 17} " 55 Thus the form {122} is an inverse rhombohedron transverse to the direct rhombohedron {100}, the faces of which truncate the edges of the inverse rhombohedron {Tn}, and the edges of which are themselves truncated by the faces of the inverse rhombohedron {on}. Figs. 213-218 represent combinations of forms occurring in calcite. 271. The other variety of hemi-systematic diplohedral forms exemplified on known crystals is the gyroidal type of which apatite, a phosphate and chloride or fluoride of calcium, offers the most conspicuous, if not the only illustration: a corresponding mero-symmetrical character has been developed by an etching process on faces of pyromorphite, an analogous compound in which lead takes the place of calcium. The poles of a gyroidal Combinations. 313 form ${hkl t efg] are those of the hexagonal discalenohedron in the symbols of which the indices all follow either the direct order h kl, efg, or else the inverse order Ikh, gfe ; in either hemisphere the distribution of the poles is thus in asymmetric hexagonal (not dihexagonal) symmetry, and at the same time the extant faces of the form lie symmetrically with respect to the equatorial plane. Fig. 219 illustrates such a form, namely (j> {524, To2}, in asso- ciation with other forms having a holo-symmetrical hexagonal Fig. 213. Fig. 214. Fig. 215. Fig. 216. 'ISO Fig. 217. Fig. 218. aspect. In fact crystals of apatite usually present a considerable number of forms quite hexagonal in their symmetry, while only a few forms exhibit, in the defalcation of their alternate faces, the gyroidal hemi-symmetry, which, however, must be held really to dominate the structure of the entire crystal. 272. Hemimorphous forms are not rare in the Hexagonal system, but they occur most often as hemimorphs of hemi- symmetrical types of crystal, and are then tetartohedral in their symmetry. But as representing the hemimorphous type of a 314 Hexagonal system. crystal otherwise holosymmetrical, greenockite, the cadmium sul- phide, occurs in crystals carrying generally hexagonal pyramids (or dirhombohedra) arranged in series tautozonal with the pinakoid and the hexagonal deutero- (or proto-) prism ; but the faces of some of these forms exist only on one side of the equatorial plane, and the crystals often exhibit on the other side of that plane only a single Fig. 219. Fig. 220. pinakoid-face (Fig. 220). Artificial crystals of cadmium sulphide have the parameters of greenockite, but present both rhombo- hedral and scalenohedral forms. Perhaps with greenockite may be associated the hexagonal zinc sulphide, wurtzite. 273. (c] Tetar to-symmetrical forms. Of the four types of tetarto- symmetry that, exclusive of hemimorphs of hemi-symmetrical forms, are possible in this system, two are illustrated in known crystals : they may both be derived from the rhombohedral type of hemi-symmetry, the one as a haplohedral, the other as a diplo- hedral derivative. The trapezohedron is the general tetartohedron of the former type ; of the latter, or tetarto-hexagonal type, the general form is the hemiscalenohedron or skew rhombohedron. Of the trapezohedral tetartohedron, quartz and sodium periodate afford examples in their crystals : of the hemiscalenohedron, in- stances are met with on certain crystals of phenakite, dioptase, and ilmenite. 274. As already mentioned in Art. 257, the trapezohedra that occur on quartz belong to two correlative groups associated, the one with Isevo-rotatory, the other with dextro-rotatory polarisation : and the forms of the two groups, if conceived as occurring simultaneously, would be symmetrical with respect to the protosystematic planes. When examining with a nicol-prism divergent light originally Combinations . 315 plane-polarised that has traversed a quartz-plate of a certain thickness with its faces cut perpendicularly to the axis, it will be found that on turning the analysing prism to the right (as the hands of a watch move) the isochromatic rings contract and their centre passes through tints in the order blue, plum-colour (the ' sensitive ' tint), orange, red, when the crystal is 'left hand ;' the rings dilate and the tints follow the order red, orange, plum-colour, blue, when the crystal is 'right hand:* the phenomena being reversed in either case if the analyser be turned towards the left. Fig. 221 (A.). Fig. 221 (/>). In quartz the predominating faces of the laevo-rotatory forms aTi{hkl} lie in zones [102], [210], [021] on the upper or positive hemisphere, and in zones [120], [012], [201] on the negative hemisphere ; those of the dextro-rotatory are in the latter zones on the positive, in the former zones on the negative hemisphere. These zones are tautohedral in faces of the rhombohedron air {100}, the S-prism air {n^}, and the hexagonal pyramid an {412}, (Figs. 2 2 1 A and p). In the case of quartz the faces of the form a 77 {41 2:} or a IT \4~2i} are small and rhomboidal in shape: they are usually striated parallel to their intersections with faces of the forms aTTJioo}, a TT { 112 j, (see plate V). Edges of the predominating trapezohedra (the so-called plagihedral forms) are parallel to those edges of the form air {412} which run athwart the striation. A crystal of quartz, when so placed that the faces 100 oio ooi are at its upper end, will, if right-handed, present on three alternate 316 Hexagonal system. quoins at each end of the prism plagihedral faces arranged in the form of a right-handed screw. Furthermore the two plagihedral faces, belonging to a single form, which are associated with any of the three prism-faces 2!! 12! 112 will be to the right of the observer as he looks at the prism-face (Fig. 221 r). On a left- handed crystal the plagihedral faces are arranged in the form of a left-handed screw and the two associated with any of the above prism-faces are seen to the left of the observer (Fig. 221 /). The faces of the form air {122} denoted in the figures by the letter z are generally smaller and more dull than the faces of the form a7r{ioo} denoted by the letter r: in Figs. 221 (/) and 221 (r) the s faces are the rhomb-faces of the form air {4^}, and the x faces are those of the plagihedral forms air {4^1} and air respectively. Fig. 221 (/). Fig. 221 (r). 275. A group of dithionates (or hyposulphates) offers examples of tetartohedrism of the type under consideration ; the lead salt in particular (Pb S 2 O 6 . 4 H 2 O) exhibits trapezohedral forms in con- junction with rotatory action on plane polarised light. These forms are, however, so distributed that of the two prevalent correlative rhombohedra the more developed would have to be taken as the form CLTT {122} transverse to the axial rhombohedron cm {100} in order that the situation of the plagihedral faces relative to the latter form might correspond with that presented by crystals of quartz, that is to say, that their faces might be gyroidally to the left of the primary rhombohedral faces in laevo-rotatory, and to the right in dextro-rotatory crystals. The more developed rhombohedron, how- ever, is usually taken as air {100}, so that the gyroidal distribution of the plagihedral forms becomes inverse to that obtaining in quartz. Combinations. 276. Sodium periodate crystallised with three molecules of water also has a rotatory action on plane-polarised light, and carries forms of trapezohedral type indicative of the direction of the rotatory action ; the crystals exhibit the additional peculiarity that they are hemimorphous in developement. Fig. 224 represents one end of a crystal of sodium periodate projected on the equatorial plane : at the other end only the pinakoid plane is present. These crystals will be further considered under the subject of twin-crystals belonging to this type of mero-symmetry. 277. The hemiscalenohedron, when present, is subordinate to rhombohedral forms, as in Figs. 222 and 223. The first of these represents a crystal of dioptase in which the hemiscalenohedron \ioi\\xto Fig. 222. Fig. 223. 7T< {310} is combined with the rhombohedron TT$ {100} and the deutero-prism 7r<|>{ioT}: in Fig. 223 is illustrated a crystal of ilmenite presenting the hemiscalenohedron ir(j) {31!} in combina- tion with the rhombohedra Tr {nT}. Fig. 224. Fig. 225. 278. Of the hemimorphous developement of crystals of rhombo- hedral type tourmaline is a conspicuous example, different forms Hexagonal system. being present on the opposite sides of the equatorial plane. A not infrequent accompaniment of hemimorphism, the pyroelectric character, is strongly illustrated in this remarkable mineral. Fig. 225 represents a crystal of tourmaline in which the lower extremity of the morphological axis is the so-called analogous pole, and the upper the antilogous pole, being respectively positive and negative in electrification when the temperature is rising. Hexagonal System. D. Twinned Forms. 279. I. Twins of holo-symmetrical crystals. Simple holo-sym- metrical crystals are of such rare occurrence in this system that few examples of twin-structure of holo-symmetrical types are to be expected, and in fact the only one on record is a minute crystal of zinc oxide, obtained accidentally as a furnace product, which has been described by vom Rath *. The twin-plane was very near to (100), although the measurements obtained indicated a face of more complex symbol. It seems quite possible that there is in this case only an accidental simulation of twin-structure. 280.11. Twins of hemi-symmetrical crystals . Hemi-symmetrical crystals afford abundant examples of twin-structure : their great sil '. (2U) (&) Fig. 226. Fig. 227. variety in aspect is however due rather to the diversities exhibited by individual crystals, even of the same substance, than to any great variety in the twin-laws under which crystals belonging to * Pgg- Annal. vol. 144. p. 580. Twinned forms. this system are united. It is in the numerous crystals of rhombo- hedral type that we must look for examples of such unions ; and Fig. 228. of these examples the multiform mineral calcite presents the most conspicuous and varied illustrations. 281. The twin -laws governing the union of rhombohedral crystals are the following : i. Twin-plane a face of a direct rhombohedron. (a) Twin-plane a face of the form {100}. Figures 226, 227, 228 represent respectively the rhombohedron TT{IOO}, the hexagonal proto-prism 7r{2TY}, and the scalenohedron TT {20!} of calcite twinned upon a face (olo) of the form TT {100}, the twin-plane being likewise the face of union. 282. (d) Twin-plane a face of the form TT { 2 1 1 } . Fig. 229. Fig. 230. Fig. 229 illustrates a crystal of pyrargyrite twinned about the plane (i~2 T), which is parallel to the plane truncating the edge cl 320 Hexagonal system. formed by the faces (no) (on) : in this case the twin-plane is the face of union of the two individuals. Sometimes the twin-plane is at right angles to the face of union and three individuals are in twin-position relative to a central one, as shown in Fig. 230. If the line Ir be at right angles to the edge cl it is the twin-axis for the individuals A B : hence the edges k lc^ of the two crystals fall in the same straight line and the faces no (on) have the same direction; the faces (no) on on the other side of the edges k lc^ are likewise co-planar. The planes truncating the edges cm en are respectively twin-planes for the pair AC and the pair AD. If the above be the true expression of the law of this twin- structure, the face of union, having its pole in a proto-systematic plane and being at right angles to a plane of the form TT {211}, cannot be a plane with rational indices. 283. 2. Twin-plane a face of an inverse rhombo- hedron. (a) Twin-plane a face of the form {on}. Fig. 231 represents a simple rhombohedron 77 {100} of calcite twinned on the plane (Ho) which truncates the edge between the faces loo olo : the twin-plane is also the face of union. Four cleavage-planes of the twin-structure, namely oio, 100, (Too) and (olo), form a prism, the angle between the planes 100 oio and also between the planes (Too) (olo) being 105 5', and the angle between the planes 100 (Too) and also between oio (olo) being 74 55 /: f tne remaining cleavage-planes ooT and (ooi) form a re-entrant angle of 38 8', while ooi and (ooT) form a salient angle of the same magnitude. In scrutinising a transparent block of the calcite from Iceland, known as Iceland spar, there is frequently to be found a very narrow twin-lamina or twin-plate of calcite intercalated in the mass of the crystal in accordance with this law. And in other cases of its occurrence, as at the Rathhaus-berg near Gastein, and at Auer- bach, Hesse-Darmstadt, the intercalated laminae are so thin and so numerous as to give quite a lamellar character to the crystal- aggregate. Crystals of the metal bismuth also occur twinned in obedience to this law. Twinned forms. 321 284. (3) Twin-plane a face of the form {m}. In Fig. 232 is illustrated a scalenohedron 7r{2o7} of calcite twinned on a face YiY of the inverse rhombohedron {Tn} the edges of which would be truncated by the faces of the primary rhombohedron TT{IOO}. The face ill itself truncates the edge cm Fig. 231. Fig. 232. between the faces 2 To . ol2. In the twin-crystal the edges cm c^ m^ are parallel to each other and to the twin-plane which is like- wise the face of union. 285. 3. Twin-plane a face of the pinakoid {in}. (a) Face of union coincident with the twin-plane. Fig- 234. Twinned scalenohedra of calcite from Derbyshire, similar to Fig. 233, are familiar illustrations of this twin-structure. The aspect of the twin is similar to that which would result if the scalenohedron TT {20!} were cut through its centre by a plane y 322 Hexagonal system. parallel to the faces of the pinakoid -TT { 1 1 1 } and then one-half of it turned round the morphological axis through 60, or any odd multiple of that angle. The twin-plane is the face of union : the edges which lie in this plane and are formed by the meeting of the two individuals are salient and re-entrant in alternate pairs. (Z>) Face of union perpendicular to the twin-plane. The crystal of haematite illustrated in Fig. 62, page 178, is an example of this kind of twin-growth. (c) Interpenetrating crystals. Rhombohedra of dolomite, and notably of chabazite, twinned about the morphological axis and mutually interpenetrating afford illus- trations of this variety. Fig. 234 represents a twin-growth of the latter mineral : the former mineral is now regarded as being tetarto- symmetrical in its structure. 286. III. Twins of tetarto-symmetrical crystals. In considering the twin-growths of tetarto-symmetrical crystals we shall be almost entirely limited to those of quartz, the crystals of which besides being the most common of mineral products are seldom entirely simple in their structure. A remarkable class of regular growths of quartz, simulating the aspect of simple crystals, was first explained by Rose. As already stated in Art. 274, a right-handed crystal of this mineral presents on three alternate quoins at each end of the prism plagihedral faces arranged in the form of a right-handed screw, and if the crystal is so placed that the faces 100 oio ooi are at the upper end, the two plagihedral faces belonging to a single form, which are associated with any of the three prism-faces 2TT 2? and TT2, are to the right of the observer as he looks at the prism-face (Fig. 235 a). In the illustrative figures the faces of the rhombo- hedron air {100} are indicated by the letter r and those of the rhombohedron air {122} by the letter z\ the plagihedral faces are denoted by the letter x : suffixes to these letters refer to the position of the simple crystal to which the corresponding faces belong. The crystal represented in Fig. 235 (a), after half a revolution round the morphological axis takes the position represented in Fig. 235 (*") : the faces r l and z l are parallel respectively to the faces s and r of the first position, and the prism-faces (afn) (*"*2) l 1 ^ 1 ) Twinned forms. 323 of Fig. 235 () : the morphological axes of two crystals with these relative positions will be inclined to each other at an angle of 84 34' and will lie in a 2-plane ; further, the r faces of the two individuals will be symmetrically disposed relative to a plane bisecting the 328 Hexagonal system. angle 84 34' between the morphological axes, the prism-faces ii? .(TT2) will be co-planar, and the edge ca of one individual will be parallel to the edge cd of the other. A growth of two individuals with these relative positions will thus be one of the first kind (Fig. 242 a). 294. Again, a half- revolution round the line 0/ 2 of the crystal represented in Fig. 241 (a) will bring the crystal into the position represented in Fig. 241 (c): as before, the morphological axes will be inclined to each other at an angle of 84 3 4' and will lie in a 2-plane ; but now the r faces and the z faces will be sym- metrically disposed relative to a plane bisecting the angle 84 34': the prism-faces nl .[TT2] will be co-planar, and the edge ca of one individual will be parallel to the edge ca of the other. A growth of two individuals with these relative positions will thus be one of the second kind. A crystallographically identical result would be obtained by a half-revolution, round the morphological axis, of one of the two individuals of a growth of the first kind (Fig. 242 a). 295. The positions of the plagihedral faces of a crystal of quartz being defined by those qf the r and z faces and the right or left character of the crystal (Art. 274), the above growths may be classed as twins, always falling under the definition given in Art. 154, whether the two individuals be both right-handed or both left-handed, and may still be geometrically explained by a reference to a single half-revolution even when one individual is right- handed and the other left-handed, if the pair be first placed in homologous positions, as explained in Art. 288. In the majority of the few known examples of this class of regular growths, it is practically difficult to decide, owing to the absence of plagihedral faces, as to the right or left character of both individuals : still specimens have been described in which the individuals are regarded as being both right-handed or both left- handed, or one right-handed and the other left-handed in character. 296. In no case, however, has the simple character of the indi- viduals themselves been satisfactorily demonstrated : we know, indeed, that the observations of Des Cloizeaux have led him to infer that apparently simple crystals of quartz from La Gardette Twinned forms. 329 are not exclusively composed of either the right or the left variety, and that a homogeneous simple crystal of quartz is one of the greatest of mineralogical rarities : further, vom Rath, in his exami- nation of the regular growth from Japan, though he failed to find any evidence as to the right or left character of the individuals, found abundant proof of their compound structure. It is thus quite possible that we have here essentially a single kind of twin- growth, geometrically explained by a half-revolution, round the normal to a plane of the form 077(52!}, of one individual from a position in which it is parallel or homologously disposed to the other, and that the second kind of growth is merely a result of the Fig- 243. fact that one or both the individuals is itself a twin-growth of the kind described in Arts. 286-290. 297. An idea of the actual developement of the individuals and of the difficulty of deciding as to their true character may be obtained from an examination of Fig. 243, which represents a very fine British Museum specimen of a twin-growth of this class from La Gardette. The individual A carries largely-developed plagi- hedral faces characteristic of a simple left-handed crystal. On the edgey^- of the individual B are small notches ss of which the sides are parallel to those faces of the rhombohedron and prism which are connected by the edge, and at the bottom of which is a plane of the form s or a 77 {412} : the plane at the bottom of one of the larger notches carries striations indicative of a right-handed crystal. 330 Hexagonal system. On the lower part of the same individual there are small faces ssx likewise characteristic of a right-handed crystal. It will be seen, however, from Art. 286 that the disposition of these faces on the individual B is that of the faces of a composite crystal twinned about the morphological axis. As the limits of the individuals of which B is composed cannot be traced, and it is difficult in this specimen to distinguish the r from the z faces by means of their physical characters, we cannot be certain as to which of the rhombohedral faces of B belong to the forms a-7r{ioo} and a TT {22} respectively. Some of the rhombohedral faces of both A and B show dull patches, such as are usual in composite crystals twinned about the morphological axis. The boundary of the individuals A and B is of a zigzag shape, as is seen from its trace on the co-planar prism-planes. 298. Of other tetarto-symmetrical minerals than quartz, phena- kite is remarkable for its twin-growths. The individuals are twinned about the morphological axis, and are mutually interpene- trant : owing to the subordinate character of the planes which are tetarto-symmetrically developed the twin-growths have an aspect somewhat similar to that of chabazite twins (Fig. 234). but further exhibit the planes of the hexagonal prism truncating the zigzag edges of the rhombohedron. 299. It has already been remarked that crystals of sodium periodate carry forms which may be regarded as a hemimorphous development of a tetarto-symmetrical type, and that the crystals, like those of quartz, are right-handed and left-handed in their rotation of the plane of polarisation. Twin-growths of this sub- Ortho-rhombic system. 331 stance have been described by Groth. The individuals of a com- posite crystal are respectively right-handed and left-handed in optical character, and are united in a face parallel to the pinakoid ; they are not symmetrical with respect to this plane, but would become so if one of the individuals were turned through 60, or any odd multiple of 60, round the morphological axis (Fig. 244). It will be seen from the figure that a half- re volution of one of the individuals round the line ad would bring it into such a position that the faces of the forms present would coincide with those of the other individual, and that the two individuals would then be in homologous positions. The line ad is parallel to the line be in which a rhombohedron-face meets a plane parallel to the pinakoid ; it is therefore perpendicular to a face of the hexagonal deutero- prism. SECTION IV. The Ortho-rhombic or Ortho-symmetric System. A. Holo-symmetrical Forms. 300. The characteristics of this system are that its holo-sym- metrical forms are symmetrical to three perpendicular planes of unconformable symmetry intersecting in three perpendicular mu- tually incongruent axes of orthogonal symmetry. These planes are, the proto-systematic plane S, the deutero- systematic plane 2, and the trito-systematic plane C which is taken as horizontal in position. The systematic planes being taken for the axial planes, the three systematic axes, which are also their normals, become the crystallo- graphic axes ; the vertical axis \S 2] being taken for the axis of Z, and the zone-lines [2C] and [SC] for the axes of X and Y respectively. The elements of the crystal are f = T\ = C ~ 9 a\ b : c, the parametral ratios having different values. The systematic planes being mutually incongruent, and equally important in their relation to the symmetry of the crystal, any one of them may be selected as the plane 2, S, or C. It would have been more 332 Ortho-rhombic system. satisfactory if in the description of crystals it had been adopted as a convention that the intercepts made on the axes OX, OY and OZ by the parametral plane should be in descending order of magnitude. Very often, however, that axis has been selected as the direction OZ which presents itself as the axis of a well- developed prismatic zone, or as the normal of a large pinakoid face, independently of the magnitude of its parametral intercept; the greater of the two remaining intercepts being then taken for the axis OX : or again, the axes have been so selected as to olo Fig. 245. suggest that the crystals are similar in developement to others having an analogous chemical composition. The systematic triangle is quadrantal and all its angles are right angles, each such triangle being commensurate with one of the octants of the system. The general scalenohedron \hkl\ of the system is the scalene octahedron ; and the remaining six forms, representing those of which the poles lie on corresponding arcs or at the several angles of the systematic triangle, are Holosymmetry. 333 The proto-dome { o k /}. The deutero-dome { h o / } . The prism \hko\. The proto-pinakoid {100}. The deutero-pinakoid {oio}. The trito-pinakoid { oo i } . The positions of the poles of such forms on the sphere of pro- jection are illustrated in Fig. 245 for the case where a : b : c = 1-894 : i : i'797> as in topaz ; the axis of the well-developed prism of this mineral being generally taken for the axis OZ, although the parametral intercept on that axis is greater than the intercept on one of the other axes. Fig. 246. Fig. 247. 301. The scalene octahedron {hkl}, Figs. 246-7, is the general independent form of the system. Its faces are scalene triangles, their symbols being hkl hkl hkl hkl, Ykl h~kl hkl ~hkl. The three systematic planes pass through the twelve edges of the form, the four similar edges in which the form is intersected by each plane giving a rhombic section. The three rhombic sections however in the different systematic planes are obviously not con- gruent, the edges in one section being dissimilar from those in a different section. The six quoins are four-faced and ortho-symmetrical on the respective axes, but the pair on one axis is not congruent with that on a different axis. In Fig. 246 is represented the form {213} corresponding to the above elements. The parametral form {HI} is a scalene octahedron (Fig. 247). 334 Ortho-rhombic system. 302. Prismatid forms. The designations of these open forms, the horizontal prismatid forms as domes, the vertical one as a prism, have already been given in article 109. They are the forms of which the faces truncate the edges of a scalene octahedron, each therefore consisting of a rhombic based prism, the rhombic sections of which have their diagonals parallel to two of the axes of the system. These diagonals are termed the proto- and deutero- diagonals of the prism, and either of them associated with the vertical axis [S 2] forms the pair of diagonals of one of the dome forms. i. The proto- dome {ok I}, Figs. 248-9, has its four edges parallel to the proto-diagonal [2 C], the axis X ; the symbols of its faces are okl okl oYl okl-, 013 Fig. 248. Fig. 249. they are intersected perpendicularly to their edges by the proto- systematic plane S, which therefore divides them symmetrically, the traces of the section being rhombs the diagonals of which are the vertical axis and the deutero-diagonal. Fig. 248 represents the proto-dome {013}, closed by the faces of the form {100}. In the parametral dome {on} (Fig. 249) these diagonals are in the . c ratio - o ii. The deutero-dome {hoi}, Figs. 250-1, has its four edges parallel to the deutero-diagonal [SC], the axis Y\ the symbols of its faces are hoi hoi hoi hoi] they are euthy-symmetrical to the intersections with them of the deutero-systematic plane 2, the diagonals of the rhombic section of the dome being the vertical axis and the proto-diagonal. Fig. 250 Holosymmetry. 335 represents the deutero-dome {203} closed by the faces of the form {oio}. The parametral deutero-dome {101} (Fig. 251) represents in its diagonals the ratio - Fig. 250. Fig. 251. iii. The four faces of the rhombic prism {hko\, Figs. 252-3, have for their symbols hko hkQ h~kv they are euthy- symmetrically intersected by the plane C, which is the plane of their zone, as S and 2 are of those of the proto- and deutero-domes. Fig. 252 represents the rhombic prism {210} 210 JlO Fig. 252. Fig. 253. corresponding to the above elements, closed by the faces of the form {ooi}. The parametral prism {no} (Fig. 253) gives in its diagonals the ratio - b 303. The faces parallel to each systematic plane constitute a distinct pinakoid form. 336 Ortho-rhombic system. Those of the proto-pinakoid {100} are parallel to the proto- systematic plane . They are 100, Too (Figs. 248, 249). The faces of the deutero-pinakoid {oio}, namely oio and oTo, are parallel to the deutero-systematic plane 2 (Figs. 250, 251): and the faces of the trito-pinakoid or basal pinakoid {ooi}, namely ooi and ooi, are parallel to the horizontal plane of sym- metry C (Figs. 252, 253). The poles of the pinakoids form the angular points of the systematic triangles ; those of the prismatid forms lie on the arcs of those eight triangles. Ortho-rhombic System. B. Hero-symmetrical Forms. 304. In the Tetragonal and Hexagonal systems the mere-sym- metrical forms admissible by the conditions of the systems were remarkable for their variety, and except in the case of the rhom- bohedral division hardly less so for the paucity and in some cases the absence of known crystal species that exemplify them. In the Ortho-rhombic system the simpler character of the system is illustrated as well in the few and simple kinds of hemi-symmetry it offers, as in the greater number of crystals by which these are represented. In the holo-systematic section of this system there are four normals to the general form, the scalene octahedron {hkl} ; and in the case of hemi-symmetry a face will be extant for each of these normals. There are two ways in which the suppression of the four absent faces may occur. 305. I. The rhombic sphenoid a {hkl} or a {hkl}, Figs. 254 (a), (c). In the first, the asymmetrical case, no systematic plane is sym- metral ; but each of the three ortho-symmetral axes becomes an axis of diagonal symmetry. Hence the alternate faces of the holohedral form [h k 1} are absent or extant. The resulting form is tetrahedrid in character, its four faces being similar scalene triangles. It is therefore a scalene sphenoid. Its six edges are similar in pairs only, a pair of similar edges being oppositely placed on the crystal and having their directions symmetrically inclined in respect to one of the systematic planes. The four quoins are three -faced and Merosymmetry. 337 similar, but present no symmetry. Figs. 254 (a) and 254 (c) represent respectively the forms 0(213} and a {213}, which together compose the scalene octahedron {213} of Fig. 254 Fig. 254 (a). Fig. 254 Fig. 254 (<). Sphenoidal hemi-symmetry of an ortho-symmetrical crystal can only be represented in a distinct form by faces of the rhombic sphenoid. Any other form of the system than the octahedrid scalenohedron can only exhibit sphenoidal characters in the mero- symmetrical features it acquires by association with sphenoidal forms. II. The second division of the holo-systematic section of this system is one in which, two of the systematic planes being planes of symmetry, the third fails of being so ; conditions resulting in three kinds of hemimorphous forms. i. The trito-hemioctahedron p{hkl\ or p{hkl}. Where the proto- and deutero-systematic planes are symmetral, the form is hemimorphous in respect to the plane C. and the form is a trito- hemioctahedron p{hkl], the correlative form being p{hkl], the former comprising the faces hkl hkl hkl Yki, the latter the faces hkl hkl hkl hkl. ii. The proto-hemioctahedron {hkl} or {h kl}. The form hemi- morphous to the plane S is symmetrical to the planes 2 and C. Its faces are for the form {hkl}, hkl hkl hkl hkl, for the form {hkl}, hkl hkl hkl hkl. 338 Ortho-rhombic system. iii. The deutero-hemioctahedron x {hkl} or x {hkl} is symme- trical to the planes S and C. The faces of the form x\hkl\ are hkl Jikl hkl ~hkl, and of x{hkl} are hkl hkl hll hkl. Since the forms are hemimorphous on the plane 2, in each of them the sign of the k index is the same for every face. In a hemimorphous developement of the scalene octahedron {213} of Fig. 254 (3) the upper and lower halves would be p {213} and ^{213}, the right and left halves {213} and {"213}, and the front and back halves ^{213} and x {213} respectively. It is evident that all the forms may be hemimorphous to a systematic plane with the exception of such as have their faces perpendicular to the systematic plane in respect to which the crystal is hemisymmetrical. Thus in the first case, where the horizontal systematic plane C has its symmetral character in abey- ance, besides the forms p{hkl} and p{hkl}, there may be a hemi-protodome p {okl} or p {o//}, a hemi-deuterodome p{hol] and /){^o/}, and a hemi-tritopinakoid p(ooi) or p(ooY); but the proto- and deutero-pinakoids and the rhombic prism will only betray a hemimorphous character in their association with the other hemimorphous forms: and similarly for the forms f {o//}, f{oio}, and f{ooi}, x{hol\, ^rjioo}, and x {001} in the remaining groups of hemimorphous forms. 306. The question as to the existence of a hemi- systematic section of the merohedral forms belonging to this system pre- sents a certain ambiguity; for the hemi-symmetrical and tetarto- symmetrical forms which might seem to accord with the law of mero-symmetry will be found to present the symmetrical charac- ters of the holo-symmetrical and hemi-symmetrical forms respect- ively of the Clino-rhombic system. So that it is very ques- tionable whether such forms could, in accordance with mero-sym- metrical principles, hold a place in the system under consideration, as not being impressed with any especial characteristics of that system. Thus, if we consider the hemi-systematic diplohedral form, it evidently presents four faces belonging to two normals. Mer asymmetry. 339 The four planes thus concurring will belong to the zone which contains the two normals, and in the plane of which lies the zone- axis to which these are diagonally symmetrical; the systematic plane which is perpendicular to this axis will also belong to the zone, and its trace on the zone-circle will, with the axis normal to it, ortho-symmetrically divide the zone. The form would be a rhombic prism, and, if a form of the Ortho-rhombic system, would be represented by one or other of the symbols it{hkl} or v{hkl} y ^{hkl} or ty{hkl}, ($>{hkl} or < \hkl\. Since no symmetral axes in the Ortho-rhombic system are similar, each axis, as also each systematic plane, is independent of the others in respect to the mero-symmetry it may thus present. But this condition of a plane of symmetry having an axis of diagonal symmetry for its normal is precisely that which charac- terises the holo-symmetrical forms of the Clino-rhombic system. A hemi-systematic ortho-rhombic form would thus differ from a holo-systematic clino-rhombic form, not in the type of its symmetry, but only in the ortho-symmetrical character of the one systematic zone-circle to which it was symmetrical. All the crystals to which this clino-rhombic habit in their hemi- systematic forms had been attributed have been shown, by reference to their optical and other physical characters, to belong either to the Clino-rhombic or to the Anorthic system. Ortho-rhombic System. C. Combinations of Forms. 307. (a) Holo-symmetrical Forms. Crystals belonging to the Ortho-rhombic system present great diversity of aspect in their combinations ; sometimes the predominance of an octahedrid or pinakoid form imparts to the crystal a pyramidal or a tabular character; or again, a more or less prismatid aspect results from the presence of a conspicuous zone of prism- or dome-forms; while frequently the different kinds of form are so balanced that the crystal cannot be classed under either of these three types. In Figs. 255-9 are illustrated various combinations of the forms {in}, {no}, {on}, {101}, {100}, {o i o}, {oo i }, corresponding to the elements given in Art. 300. In Fig. 255 the parametral z 2 340 Ortho-rhombic system. octahedron {in} is predominant and the combination is pyra- midal in aspect : four of the edges of the octahedron are truncated by the faces of the proto-dome {on} and two of its quoins by the faces of the proto-pinakoid {100}; the parallelism of the edges formed by the faces (100), (in), (on), (In), (loo) points to the tautozonality of these faces. The combination shown in Fig. 256 110 Fig- 255. Fig. 256. Fig. 257. is tabular, owing to the size of the faces of the basal pinakoid {001} : and that of Fig. 257 is prismatid through the predomi- nance of the prism {no}, which is closed by smaller faces of the basal pinakoid {001} and the deutero-dome {101}. In the com- binations shown in Figs. 258, 259 more than one form is largely developed: in Fig. 258 two edges of the dome {101} are trun- m... no 010 no ! i | >H2I \Jtt). Twin-plane a face of a prism. 318. Aragonite offers a conspicuous example of the great variety capable of being presented by the twinned crystals of this system. Ortho-rhombic system. The twins of aragonite are frequently pseudo-hexagonal in their character as a result of the prism-angle being not very remote from 60, and the twinning being repeated on the faces of the form {no}. Usually the prism is associated with the pinakoid {100} and the dome {101}, and forms belonging to the zone [100-101] are of frequent concurrence with these. The octahedron {in} is also a frequently prevalent form (Fig. 265). The normal-angle of the faces iio-Tio of the prism {no} is 63 44', and the normal- angle 100-110 is therefore 58 8'. If now the crystal is twinned by the half-revolution of a parallel individual round the normal of the face ilo, and this plane be likewise the plane of junction of the two crystals, the re-entrant normal-angle between the face 100 of the first and the face (Too) of the second individual is (121 52' 58 8' or) 63 4 4', and the ito JJO 110 100 (wo 'too} [770] Fig. 277. Fig. 278. Fig. 279. salient angle between the face no of the first and the face (no) of the second individual is (116 i6 / 63 44' or) 5 2 32'. 319. The repetition of the twinning on the successive prism- faces of the different individuals produces complex crystal-structures, that vary in their aspect and angular relations according to the faces on which the twinning occurs. In Fig. 278 there are three individuals; while the front crystal retains its position, the second crystal is twinned on the normal of the face ilo of the first, and the third on the normal of the face (ilo) of this intercalated second crystal. In Fig. 279 the three individuals are successively twinned, the second as before on the Twinned forms. 349 i To face of the first and left-hand individual, but the third on the (TTo) face of the second crystal. 320. At Herrengrund in Hungary and Girgenti in Sicily are found very fine specimens of aragonite compounded of several individuals, but which at first sight may be taken for simple hexa- gonal prisms terminated by a basal pinakoid. It is seen, however, that the striations on the basal pinakoid are in diverse directions, and that obtuse re-entrant edges traverse some of the faces of the pseudo-hexagonal prism in a direction parallel to its edges. The structure of these crystals is illustrated by Figs. 280-2. Fig. 280 is a projection of three individuals on the basal pina- koid (ooi), each being a combination of the proto-pinakoid {100}, the parametral prism {no}, and the basal pinakoid {ooi}, of wo - '' [ooi] p'zyJ! 110 . f " Fig. 280. which the latter is grooved with striations parallel to its inter- sections with the faces of the proto-pinakoid {100}. The crystals I and II are twinned respectively on the planes Yio and no of the crystal A. The normal-angle iio-Tio being 63 44', the face [TYo] of crystal I makes a small re-entrant angle of n 12' with the face (iTo) of crystal II : the basal pinakoids ooi, [ooi], (ool) are coincident in direction: the faces -ioo-(Too) and the faces Too [100] form re-entrant normal-angles of 63 44', and the faces [Too] (100) a re-entrant normal-angle of 52 32': hence the striations of I and II make an angle of 116 16' with those of A, and an angle of 127 2 8' with each other. 321. If the crystals of Fig. 280 are interpenetrant, the resulting 350 Ortho-rhombic system. compound crystal may present the aspect illustrated in Fig. 281. The faces no, [no] and their parallels no, [no], of crystals A aiad I are coincident in direction : similarly for the faces YYo, (TTo) and their parallels no, (no), of crystals A and II: while the faces (no), [no], and their parallels (no), [no], of crystals I and II make re-entrant normal-angles of 11 12'. 322. If the crystals grow until the faces of the proto-pinakoid disappear, the structure presents the aspect of a pseudo-hexagonal prism, of which each edge has a normal-angle of 63 44', and of Fig. 282. Fig. 283. which two opposite faces are traversed by an obtuse re-entrant edge of 11 12'. In Fig. 282 are shown the striations to be observed on the basal pinakoid of a compound crystal from Girgenti, now in the British Museum, very similar in structure to the compound Twinned forms. crystal of Fig. 281 : corresponding parts of the two figures are distinguished by the same letters and numbers. In the building up of this complex structure two additional individuals III and IV have a part : the individual III is a twin of the individual I about the plane [no], so that the faces [no], {no}, as also their parallels [Ho], {I^o}, are co-planar; the minute individual IV is similarlv a twin of the individual II about the plane (Ho). Fig. 284. 323. Figs. 283 and 284 represent twinned crystals of cerussite, the former being a simple twin on the face iTo, and the latter a triple combination with faces of the form {no} for twin-planes. Copper glance and stephanite again afford examples quite analogous to the above in the character of the twins they form, the twin-planes belonging in each case to the form {no}, and the pseudo-hexagonal character being due to the approximation of the prism-angles to 60 : in the case of copper glance it is so near that value as 59 48'. Crystals of cerussite twinned about a plane of the prism {310}, the faces of which make an angle of 92 45' (nearly 90) with those of the parametral prism {no}, have been observed. III. Twin-plane a face of a pinakoid. 324. It has already been observed that a systematic axis can only become a twin-axis in the event of its symmetral attributes being in abeyance. This can only occur when the crystal is hemimorphous with respect to the systematic plane in which the 352 Mono-symmetric system. zone-axis in question lies. Fig. 285 represents a crystal of struvite twinned about the pinakoid (100), and having for plane of junction the perpendicular face ooi with respect to which the crystal is hemimorphous : crystals of hemimorphite and seignette salt (sodium potassium tartrate with four equivalents of water) also afford examples of this variety of twin. SECTION V. The Mono-symmetric or Clino-rhombic System. A. Holo-symmetrical Forms. 325. The Mono-symmetric system is characterised by symmetry to a single plane. The zone of which this is the zone-plane is accordingly (see Art 91, p. 107) not symmetrical in respect to any of its own planes, so that no faces in the zone can be permanently perpendicular to each other or inclined successively at any crystallo- metric angle. Since the sphere of projection is divided into hemispheres by a single symmetral plane, there is no systematic triangle. The diplohedral form is however symmetrical to the zone-axis of the systematic plane as an axis of diagonal symmetry, the general form {hkl} presenting four faces symmetrical to the systematic plane and to a plane perpendicular to it. The systematic plane and two origin-planes perpendicular to it are taken as axial planes : the lines in which they intersect each other are the crystallographic axes, the one which is normal to the systematic plane being taken as the axis F; the axes X and Zlie in the systematic plane and are perpendicular to the axis Y. The obtuse angle 77 formed by these two axes will be taken for the positive angle XOZ, so that OC, OA the normals of the planes FOX, FOZ are contained within it. The poles 100, Too and ooi, ooT of the axial planes will there- fore lie on the arcs XZ and XZ the arc r[ between the poles 100 ooi or Too ooT being the supplement of the arc r/. In stereographic projections the plane of symmetry is generally taken as the plane of the drawing : the axis of Z being placed in a Holosymmetry. .53 vertical position OA the normal to it in the systematic plane is horizontal. The elements of a crystal in this system are f =C= 9> "n > 9; a\b:c; where the relative magnitudes of the parameters are not indicated by the alphabetical order of the letters. 326. The varieties in the forms of the Mono-symmetric system are: I. Such as have their poles neither on the axis nor on the circumference of the zone-circle [oio] ; viz. (a) the general form, either a positive (prismatid form or) prismatid {hkl}, or a negative prismatid \hkl\ ; (b) particular cases of this form in which i. the poles lie on a zone-circle passing through (100), viz. the ortho-prism {hko}, including the para- metral prism { 1 10} ; ii. the poles lie on a zone-circle passing through (ooi), viz. the ortho-dome {o//}, including the para- metral dome {on}. A a 354 Mono-symmetric system. II. Such as have their poles on the zone-circle [oio], the positive and negative hemi-domes {hoi} and {-o/}, including the parametral hemi-domes {101} and {Toi} ; the ortho-pinakoid {100} ; and the basal pinakoid {ooi}. III. The systematic pinakoid { o i o } . In this nomenclature the term dome is employed not in contra- distinction to the term prism or prismatid^ but, like the latter term, conventionally and merely to distinguish these forms from one another: the dome, by analogy with the Orthorhombic system, being a form with its poles on the zone-circles [oio ooi] and [100 ooi]. Fig. 286 represents in stereographic projection the positions of the poles of these kinds of forms for the case where r) = 106 i' and a : b : c 0-541 : i : 0-913, as in diopside. 327. I. That the general mono-symmetric form {hkl} will be a rhombic prism is evident from its having four poles lying on an orthosymmetrical zone-circle passing through the pole of the systematic plane (oio). If one of its poles lie in the octant formed by the great circles passing through the poles 100, oio, ooi, the form is termed a positive prismatid and its four faces are hkl hkl hkl h~kl\ those four of the octants formed by the great circles in question which contain the poles of the positive form being similar. And the remaining four octants will similarly contain the poles of the negative prismatids, viz. hkl III hkl hkl. The symbol of the zone containing the four faces of the form \hkl\ being [hkl, oio] or [7o^], the first and last index in the symbol of each of the faces must have the same sign : and similarly a face of a form {h k 1} must have different signs in its first and third indices. Figs. 287 (a) and (b) represent respect- ively for the above elements the positive prismatid {632} and Holosymmetry. 355 the negative prismatid {632} closed by the faces of the form {100}. Where the indices have the same magnitudes in each form, a positive and a negative prismatid combine to produce a quasi- 63'J C32 Fig. 287 (a). Fig. 287 (b\ Fig. 287 (c\ octahedral form, as in Fig. 287 (). The faces however of the positive and negative component prismatids are not similar. They are scalene triangles of two kinds corresponding to the different forms ; and the edge in which two adjacent faces of these forms meet is incapable of undergoing truncation or bevilment. V iio \ Fig. 288. Fig. 289 328. Among the varieties of prismatids, of which the poles always lie in a zone perpendicular to the zone-circle of symmetry [oio], two are especially noticeable. One of these varieties includes the vertical or ortho-prism \hko}, usually distinguished as the prism-form, the faces of which lie in A a 2 356 Mono-symmetric system. the zone [100, oio]; in Fig. 288 is illustrated the ortho-prism {210} closed by the form {ooi}. The parametral prism {no} belongs to this type and is generally one of the most frequent and important forms on crystals belonging to this system (Fig. 289); in fact, the zone selected as that of the ortho-prism is usually chosen on account of the pre-eminence of these faces. The other especially important variety consists in the suite of dome-forms with the general symbol {o//} (illustrated in Fig. 290 by the form {032} closed by the faces of the form {100}) lying in the zone [oio, ooi] ; one of them is the parametral dome {on } (Fig. 291). This variety of dome is termed the ortho-dome, Fig. 290. Fig. 291. because, like the ortho-prisms, it has an ortho-symmetrical character, the zone containing it being symmetrical to the axis [oio] and also to the normal of the face (ooi), perpendicular to that axis. Another important zone perpendicular to the plane of symmetry is that passing through the parametral plane in. Its symbol is evidently [ioT], so that for all planes belonging to it the first and last index are equal and have the same sign. This zone is tauto- hedral with the zone [oio] in the two faces 101 and lol of the form {101}. The quasi-octahedrid form constituted by the union of the positive prismatid {m} and the negative prismatid {In} would correspond to the parametral octahedron of a rectangular- axed crystal: Figs. 292 (a) and (c) represent the parametral posi- tive and negative prismatids {m} and {In} respectively, each closed by the faces of the form {100} ; in Fig. 292 (3) is illustrated the quasi-octahedrid form produced by their union. The two faces of the form {loi} are in the zone [oio, In]. Holosymmetry. 357 329. II. With regard to the forms the poles of which lie in the zone [oio], which is symmetrical only to its centre, their faces will of course consist in each case of a single parallel pair ; the various special forms comprised under the general symbol \hol} being in fact a series of pinakoids. And of this series the forms will be positive when their poles lie on the arcs joining the poles Fig. 292 O). Fig. 292 (). Fig. 292 (c\ ooi, 100 and ooT, Too; negative when they lie on the arcs joining ooi, Too or ooT, 100. And if the indices in a positive and negative form irrespective of sign are the same, the two pinakoids, though not of necessity concurrent, may be conceived as uniting to produce a prismatid Fig. 293. Fig. 294. or quasi-dome-form : in Fig. 293 is shown a combination of the pinakoid {301} with the pinakoid {301}, closed by the faces of the form {010} ; Fig. 294 represents the positive and negative parametral pinakoids {101} and {Toi}, closed by the faces of the form {oio}. Such a double form has been termed a clino-dome ; and it will be convenient to retain the terms positive and negative Mono-symmetric system. hemidome, in order to distinguish the forms that actually compose it, the symbols of which are {hoi} and {hoi} respectively, from the particular cases where one of the indices h or / in the symbol {hoi} is zero; to which the term pinakoid will be restricted. The positive hemidome {hoi} comprises the faces hoi and hoi', the parametral hemidome being {101}; the negative hemidome {hoi} comprises the faces liol, hoi, and includes the parametral negative hemidome {Yoi}. The ortho-pinakoid {100} is the form the faces of which are parallel to the axial-plane YZ. Its faces are 100, loo, and are tautozonal with those of the prism (the ortho-prism) (Figs. 287, 290-2). The basal or clino-pinakoid is the form {ooi}, the faces of which, namely ooi and ooT, are parallel to the axial plane YX and are tautozonal with the faces of the ortho-dome (Figs. 288, 289). III. Finally, of the systematic pinakoid {010} the two faces oio and olo are parallel to the plane of symmetry (Figs. 293, 294). Mono-symmetric System. B. Mero-symmetrical Forms. 330. The general form in the Mono-symmetric system, inclusive of the ortho-prism and the ortho-dome, has four poles carried by two normals and is symmetrical to the systematic plane S. Its holo-systematic mero-symmetrical forms will therefore be of two kinds. I. One of these forms presents two poles symmetrical on the plane S; the symbol of the correlative forms being ^therefore s{hkl} and s{hkl} for a positive prismatid, and s{hkl} and s{h~kl} for a negative prismatid. Thus the two extant faces of the form s{hkl} are hkl and hkl, those of the form s{hkl} are Jikl and Ykl Of the prism-form {hko}, the correlative forms are s { h k o } with the faces h k o and h k o, and s{hlto} with the faces Ji~ko and liko. Merosymmetry . 359 And while the ortho-dome is resolved into the correlative forms s { o k 1} with the faces o k I, ok?, and s { o ~k 1 } with the faces o k /, o k I, a form \hol\, the faces of which fall into the zone [oio], will be capable of exhibiting the haplohedral hemi-symmetry in question by one only of its two faces being extant, viz. h o / or hoi. And so of the negative hemi-dome either Tivl or //o/ and of the pinakoids 100 or Too, ooi or ool will be the only extant faces, while the systematic pinakoid {010} will have both its faces extant or absent but without symmetry of form. 331. II. The other hemi-symmetrical variety of the holo- systematic forms is that in which two extant poles corresponding to two normals of the system lie on the same side of the systematic plane; so that the form is hemimorphous on that plane. In accordance with the symbolical notation we have adopted, since the form is symmetrical to the diagonal axis of symmetry of the system, though to no plane of it, the symbol for such a form would be a {hkl} with the faces hkl and hkl, or a{Jikl,\ with the faces Jikl and hkl, in the case of a positive form \hkl\\ a {hkl} or a {Tikl\ being the symbols of the correlative semiforms of the negative form \hkl\. The pinakoid {010} may present this hemimorphism by the absence of one of its planes : but the forms the poles of which lie in the zone-circle [oio] can only exhibit hemi-symmetry of this kind in the distribution of their physical features and in their association with the mero-symmetrical forms of this type. 332. The possibility of a hemi-systematic form, in which a single normal is represented by both the faces belonging to it, involves a question similar to that already considered under the Ortho- rhombic system, Art. 306. For such a semiform would be repre- sented in the case for instance of a positive prismatid form by two faces, viz. hkl and Jikl, and the correlative form would present the faces hkl, hkl. But such a semiform would differ from a holo-symmetrical form of the Anorthic system only in its faces belonging to an ortho-symmetrical zone or one potentially ortho- 360 Mono-symmetric system. symmetrical. But there is no sufficiently characteristic distinction between such a form and an anorthic holo-symmetrical form to satisfy the principle of mero-symmetry in the Mono- symmetric system. Mono-symmetric System. C. Combinations of Forms. 333. (a). Holo-symmetrical forms. The mono-symmetric cha- racter of a crystal in this, the more symmetrical of the two oblique systems, is generally recognisable by reason of the different developement and diversity in the features of the forms it carries. The antistrophic symmetry of the two halves of the crystal as seen divided by an ideal plane of symmetry when it is looked at in the direction of that plane, and the diagonal disposition of its homolo- gous faces from any other point of view, but especially as seen in the direction of its one axis of symmetry, are characters in general easy of recognition. Where however the axial angle rj approxi- mates to a right angle, or where the more prominent prism-forms Fig. 295. Fig. 296. have normal-angles approximating to 45 or to 60, and in particular where the former is united with one or other of the latter specialities, the crystal may occasionally wear the aspect of an ortho-rhombic or even of a hexagonal crystal. In such case goniometrical measurements must be had recourse to. In the not infrequent case of one or more distinct cleavages being apparent, these will, by the presence or absence of symmetrical repetition, generally guide the judgment. 334. The habit of a mono-symmetric crystal is very often distinctly prismatid ; the faces of a prism {no} or {hko} being Combinations. 361 then predominant: often, however, the edges hko, hko and hko, liko are truncated by the faces of the ortho-pinakoid {100}, or the other edges may be truncated by the faces of the systematic pinakoid {oio}. The crystal of datolite in Fig. 295 exhibits the two prism-forms {no} and {210}, the edges of the latter form being truncated by the ortho-pinakoid {100}, while in Fig. 296 a crystal of gypsum is represented with prisms {no} and {120} in which the edges of the latter form are truncated by the syste- matic pinakoid {oio}. The crystals of augite (Fig. 297) and of hornblende (Fig. 299) exhibit prism-forms with both pairs of edges truncated by the faces of the two pinakoids {100} and {oio}. The comparison of the Fig. 297. Fig. 298. crystal of augite in Fig. 297 with that of diopside in Fig. 298, belonging to the same mineral group with it, will serve to show the different aspect assumed by a crystal according as the prismatid forms preponderate over the prism- and pinakoid-forms, or as one or both of the latter are the most developed. 335. In hornblende (Fig. 299) the normal-angles of ooi In and ooi YYi are 34 25', while that of In TTi is 31 32': further, the prism-angle no ilo is 55 30', and the angle no oio is 62 15'. It will be seen, then, that a crystal of this mineral carrying the above forms might readily be mistaken for a rhombohedral crystal, the more so as the angle 100 ooi is 75 2 ', while the angle Too loi is 73 58'. In some of its crystals, augite, on the other hand, presents features, in a nearly square prism {no} of which the angle is 362 Mono-symmetric system. 87 5', and in the presence of a face 102 inclined to 100 at an angle of 89 20', that bring it near in aspect to an ortho-rhombic crystal. 336. The crystal of sphene represented as Fig. 300 exhibits a very oblique aspect due to a considerable prolongation of the Fig. 300. crystal in the direction of a negative prismatid {123}, and in epidote as shown in Fig. 301 the preponderant forms are the ortho-pinakoid {100} and basal pinakoid {001} with ortho-domes and negative prismatids, which latter impart to epidote, by the character of their developement and distribution, a characteristic Fig. 301. Fig. 302. oblique appearance when looked at in the direction of the normal to the ooi face. Fig. 302 represents a crystal of the rare mineral turnerite in the collection of the British Museum: its locality is Cornwall; it serves to give an illustration of a mono-symmetric crystal with very symmetrical developement of a large number of forms. Combinations. 363 337. (b\ Mero-symmetrical forms. The known mero-sym- metrical crystals belonging to this system occur exclusively among the products of the laboratory or of the organic world. In tartaric acid an illustration is afforded of the mode in which correlative forms occur on the crystals of a substance which assumes two characters corresponding to a species of enantiomorphism in its crystals. Racemic acid has the same percentage composition and most of the characters of tartaric acid, but in solution has no action on polarised light : if from the two varieties of sodium ammonium racemate (laevo- and dextro-tartrate) described in Art. 311 the corresponding calcium salts be obtained by the addition of chloride of calcium to their respective solutions, and the calcium salts be then decomposed by sulphuric acid, solutions are obtained which have opposite rotatory actions on plane polarised light : one Fig. 303 of these solutions on evaporation yields crystals of ordinary or dextro-tartaric acid, while the other yields crystals of the same chemical composition which are termed laevo-tartaric acid: the latter crystals have the form shown in Fig. 303 (/), the former that of Fig. 303 (r). The crystals themselves do not possess this rotatory character. It will be seen by the symbols* of the faces present or absent in either case that the form {on} is hemi- symmetrically developed and presents faces with positive indices for the .iF-axis in the one case, and corresponding faces with negative indices in the other. The crystals are thus hemimorphous in developement. 338. The organic substance fichtelite or scheererite, a mineral which occurs in fossil pine-wood in the peat of the Fichtelgebirge, has been described as illustrating the variety of hemi-symmetry 364 Mono-symmetric system. in which four normals of a form {hkl} are represented by two poles symmetrical to the systematic plane. Mono-symmetric System. D. Twinned Forms. 339. The twinned forms in this system are numerous, and present considerable variation in the laws they follow even for the same substance. The analogy which is presented, at once in chemical and in crystallographic type, by many minerals is not confined to those which crystallise in one and the same system. For instance, the ortho-rhombic minerals bronzite and enstatite are homotypic in their composition with the minerals of the augite group in the Mono-symmetric system, and in their crystallographic constants present many points of close resemblance to the latter. So the felspars, which form an important and extensive group of minerals that crystallographically are anorthic, have at least one representative mineral belonging to the Mono-symmetric system. And this felspar, orthoclase, has many crystallographic features in common with the numerous minerals that are grouped under the general name of felspars in the Anorthic system. Among these characters none are more important for comparison than the methods of twinning exhibited by orthoclase, as compared with the twin-structures of the anorthic felspars. In the discussion of clino-rhombic twins this analogy has to be borne in mind. 340. In this system the twinned forms can always be explained by taking for the twin-plane a face of the crystal: but in order to keep in sight the analogy just alluded to, it is well to point out that while a mono-symmetric twin can be most simply explained as being twinned on a face-normal, it may happen that, by analogy with a corresponding anorthic twin that cannot be so simply explained, the mono-symmetric twin may also be described as twinned round a zone- axis perpendicular to the face-normal. 341. The twin-plane for crystals in this system may be a face of a form belonging to the zone [oio], and therefore perpendicular to the plane of symmetry, or it may be a face oblique to this plane. In holo-symmetrical crystals it cannot be the systematic plane itself, as the normal of this plane is an axis of diagonal symmetry. The following are the various twin-laws known in this system : Twinned forms. 365 A. Twin-plane perpendicular to the plane of symmetry. 342. In the known twins falling under this law the twin-plane is either a pinakoid-face or a face of the parametral hemidome {101}. Fig. 304- Fig. 35- i. I win-plane a face of the ortho-pinakoid {100}. Cases of this kind of twin are exemplified in augite (Figs. 304, 305) and horn- blende (Fig. 306). In these twinned forms the combination-plane is parallel to the twin-plane, and the crystals are in apposition. (5io) (Ho) i Fig. 306. The figure of hornblende (Fig. 306) illustrates the singularly symmetrical aspect which a crystal of that mineral assumes, in certain points of view, when thus twinned. The re-entrant angles 3 66 Mono-symmetric system. on the augite crystals (Figs. 304, 305) immediately betray the twinned nature of their structure. Fig. 58 (a) (p. 175) represents a twin of orthoclase from Carlsbad, the kind designated as the Carlsbad twin : in this case the com- bination-plane of the juxtaposed and slightly interpenetrant indi- viduals is perpendicular to the twin-face, and is in fact parallel to the plane of symmetry. The Carlsbad twin may equally be represented as the result of twinning round the zone-axis [ooi]. It is in this way described by Des Cloizeaux as indicating an analogy between the felspars belonging to the two oblique systems : the indices of the planes when the zone-axis [ooi] is assumed to be the twin-axis are shown in Fig. 307. 343. 2. Twin-plane a face of the basal pinakoid {ooi}. This mode of twinning is also known in orthoclase, and is well shown in crystals from Silesia : the crystals are in juxtaposition with the Fig. 308. Fig. 309. twin-plane as face of junction: Fig. 308 represents a specimen in the British Museum. An analogous twin has been recognised in the anorthic felspar, albite, but its occurrence is extremely rare. The twin crystal of epidote represented in Fig. 309 is also an example of this law. In Fig. 310 is illustrated a twin-crystal of sphene in which the basal pinakoid (ooi) is both the twin-plane and the face of junction : often the individuals are interpenetrant and have a second plane of junction normal to the first, as in Fig. 311. 344. Harmotome, long considered to be an ortho-rhombic mineral by reason of the supposed perpendicularity of its axial angles, has been shown by Des Cloizeaux to be mono-symmetric, Twinned forms. 367 and the twinned forms, in which alone the mineral occurs, are recognised as falling, in part at least, under this law. (00.0 The crossed twin Fig. 314 represents a characteristic and striking variety of this mineral from Andreasberg. It is best explained as the result of a double twinning: the first twinning is round the normal to the face (ooi), which is likewise a face of union, as in Fig. 312: such simple twins are not met with in nature, the indi- viduals being always so intergrown that they cross over to opposite sides of the first face of union and have a second plane of union Fig. 312. Fig- 3I3- Fig- 3H- perpendicular both to the first and to the plane of symmetry (Fig. 313) : the second plane of union is very nearly parallel to a face of the hemidome {101}, the angle ooi . 101 being almost exactly 90. Such a twin has therefore three perpendicular planes of sym- metry, and may be mistaken for a simple ortho-rhombic crystal. The second twinning is about a plane of the ortho-dome {on}, 3 68 Mono-symmetric system. inclined to the basal pinakoid at an angle of 45 18': hence the angles between the adjacent twinned pinakoids, which form the re-entrant edges of this complex growth, are 90 36' and 89 24' alternately. 345. 3. Twin-plane a face of the parametral hemidome {101}. Gypsum affords an example of a twin following this law (Fig. 315): the twin-plane is also the face of junction. This twin is Fig. 315- Fig. 316. of frequent occurrence, but the faces of the extant forms of the crystals from Montmartre, near Paris, are usually much rounded, as in Fig. 316. B. Twin-plane oblique to the plane of symmetry. 346. In its second law, where the twin-plane is a face of the ortho-dome {on}, harmotome has already supplied an illustration Fig. 318. Twinned forms. 369 of this mode of twin-growth. The (orthoclase) felspar twin known as the Baveno twin (from one of the localities in which this form of felspar occurs) has for its twin-plane a face of the ortho-dome {021}, which is also the plane of union. An analogous twin occurs, but is very rare, in the anorthic felspar albite. Figs. 317 and 319 (a) represent simple twins according to this law: the systematic and basal pinakoids of the two individuals form a prism of which two normal-angles, namely ooY .010 and (ooi) . (olo), are exactly right angles, and the remaining two, namely oio . (oYo) and ooY . (ooi), are 90 6' and 89 54' respectively. Twins of orthoclase, especially of the variety called adularia, that follow the Baveno law, are often interpenetrant, and exhibit repetitions of the twinning resulting in very composite structures : thus, in Fig. 319 (3) is illustrated one end of a complex growth in which there is 001 Fig. 319 OOJ Fig. 3 J 9 (0- twinning about the faces (021) and (021) of the central individual; Fig. 319 (c) shows one end of a similar growth in which a fourth individual takes a part, being twinned on a face of the form [021] of the left-hand individual ; in Fig. 3 1 8 is shown the latter growth obliquely projected, the form {20!} being omitted for the sake of simplicity. As in the case of harmotome, complicated growths according to two distinct twin-laws are met with in orthoclase, faces of the basal pinakoid {001} and of the ortho-dome {021} being simul- taneously present as planes of twinning. Rare pseudomorphous forms after crystals of orthoclase twinned about a face of the ortho-dome {051} have been described. 347. Fig. 320 is the representation of a twin of wolfram of which the plane of twinning as well as of union is the face (023). Like harmotome, wolfram has been removed from the Ortho- Bb 370 Anorthic system. rhombic system, under which it had been previously classed in a hemi-symmetrical category really incompatible with the symmetry of that system. 348. Twinning about a face of a prismatid is very rare. In Fig. 321 is shown an interpenetrant twin of orthoclase, belonging Fig. 320. Fig. 321. to the British Museum, in which the face (Tn) is the twin-plane. Rare pseudomorphs after orthoclase crystals twinned about a face (454) have also been described. SECTION VI. The Anorthic System. A. Holo-symmeirical Forms. 349. A form in the Anorthic system is constituted by two parallel faces, the only symmetry which characterises the system being that to a centre. No zone on such a crystal can permanently present ortho- symmetry, nor can it have three tautozonal faces inclined con- secutively at crystallometric angles. The three edges to which the axes are parallel will of necessity be inclined to each other at angles of which no two can be right angles, and the elements of the crystal are unfettered by any condition. Where more than one of the axial angles may approximate to a right angle, it is conceivable that changes of temperature inducing changes in the axial elements might momentarily bring two or all the axes into a position' of perpendicularity ; but it will be seen in a future Holosymmetry. 371 chapter that this is a condition transient with the temperature, and is not a sufficient condition for the system to which the crystal belongs to assume a different type of symmetry. In the general case then the axes are to be assumed as oblique to each other and the parameters as unequal; and in order to assign a conventional orientation to such an axial system it will be necessary to determine the ways in which a uniform principle may be applicable to it. Adopting the alphabetical order of the letters a, 5, c as that of the descending magnitudes of the parameters assigned to the axes X, Y, Z, respectively, we might further determine that in all cases the axial angle 77 or ZX should be an obtuse angle, as in the Mono-symmetric system. Now it will be found that under these restrictions it is always possible to make the positive octant such that the three axes which contain it shall be inclined either all at obtuse angles, or so that two of the axial angles are obtuse and one, for which f may be taken, is acute. The axial system would then be represented by the expression f> 9 o, T ? > 9 o, C^9> a > b > c. An orientation of this kind is not however suitable in cases where analogies have to be kept in view between crystals chemi- cally homotypic but belonging severally to the Monosymmetric and Anorthic systems. An orientation corresponding to that em- ployed for the monosymmetric crystal is in such cases adopted in the Anorthic system. 350. The forms of the system being limited to pairs of faces, and related to each other only by the bond imposed on them by the crystalloid zone-law, a nomenclature distinguishing the forms which lie in particular zones, as for instance the zones containing two of the axial planes, possesses even less significance than is the case in the Mono-symmetric system. The sort of octahedrid figure pro- duced by the union of all the four forms in the symbols of which the several indices have the same numerical values is one which has no crystallographic meaning ; for the forms {hkl}, \hkl\, {hkl}, 37 2 Anorthic system. are independent each of the other, and do not in fact concur with any regularity or frequency on anorthic crystals. Hemiprismatic forms would include a positive hemiprism {hko} and a negative hemiprism {hko}, and of such united forms the parametral hemiprisms {no} and {Tio} are more frequent in their concurrence. So two concurrent hemidomes, consisting of a positive pro-hemidome {hol\ and a negative pro-hemidome {hoi}, would build a dome-form with its edges parallel to the axis Y; while a positive para-hemidome {ok I}, with a corre- sponding negative form {o//|, would constitute a dome-form with edges parallel to the J^-axis. Apart from the grounds on which particular faces are selected for pinakoid or for parametral forms in this system, such pairs of forms might be expected to be more frequent in their con- currence as quasi-dome forms than in the case of the quasi- octahedrid forms, inasmuch as in the one case only two hemidome or hemiprism forms with numerically identical indices must concur, while in the latter case four tetarto-octahedrid forms numerically identical in their indices must of necessity be extant together on the crystal. The three pinakoid forms parallel to the axial planes may be termed the para-pinakoid { 100}, parallel to the axes J^and Z\ the pro-pinakoid {oio}, parallel to the axes X and Z\ and the basal pinakoid {ooi}, parallel to the axes X and Y\ the prefixes para and /r0-are suggested by the positions of the pinakoids relative to an observer looking at the crystal in the direction of the _F"-axis; the faces of the para-pinakoid being then at the sides and those of the pro-pinakoid in front of the observer. 351. In selecting the faces that are to determine the axial elements in an anorthic crystal, and assigning to particular faces the cha- racter of axial pinakoids or prismatid or dome-forms, of course in the first place importance has to be attached to the faces which by the comparison of several crystals are recognisable as habitually prominent on them. Sometimes also crystals of this system as is conspicuously the case with the felspars present a close re- semblance in the distribution of their forms with crystals of other systems, and more particularly with crystals of the Clino-rhombic 373 system, with which they are at the same time allied in the type of their chemical composition. In such cases the orientation of the axes is determined in subordination to the principle necessi- tated by the symmetry of the system to which belong the crystals with which a comparison has to be instituted: in Fig. 322 is shown a stereographic projection of the more prominent forms exhibited Fig. 322. by the crystals of anorthite illustrated in Figs. 325 and 326, the axial system of which would be represented by the expression f=8647', 7? ="5 55', C=88' 4 8', a \b\c\\ 0-635 : i : '55- Anorthic System. B. Mero-symmetrical Forms. 352. Hemi-symmetry. The only conceivable case of mero- symmetry in the Anorthic system would be that of a haplohedral form, or forms represented each by a single face. Anorthic System. C. Combinations of Forms. 353. In the previous systems the symmetrical repetition of faces leads naturally to the grouping of forms in zones. In the Anorthic system there is no such necessary tendency. Nevertheless the aspect of an anorthic crystal very usually differs little in this respect 374 Anorthic system. from that of a mono-symmetric or ortho-symmetric crystal. The symbols of the forms in the Anorthic system are usually of a very simple kind, the indices rarely occurring with a higher numerical Fig- 3 2 3- Fig. 324. value than four. Indeed the number of minerals crystallising in the system is very small, though of organic products formed in the laboratory this number is considerable. The forms, however, that these present are usually few in number, and simple in their symbols. Fig. 325- Fig. 326. In Fig. 327 is illustrated a simple crystal of the felspar albite with the forms {ooi}, (oio} 5 {no}, {ilo}, {iol}, and in Fig. 323 another crystal of the same mineral with forms additional to the above : Fig. 324 shows the form of an ideal simple crystal of albite elongated in the direction of the P'-axis, a variety to which the term pericline is applied. Figs. 325 and 326 represent crystals of the Twinned forms. 375 felspar anorthite from Vesuvius (after vom Rath) remarkable from the completeness of their developement. Anorthic System. D. Twinned Forms. 354. In the Anorthic system the twin-growths are of two kinds ; in the one the twin-axis is the normal of a face, in the other it is parallel to a zone-axis ; and as in this system, from the principles of symmetry, no face-normal can be a zone-axis, these two modes of twin-growth are distinct. Another kind of twin-growth has indeed been asserted to exist, in which the twin-axis is a line perpendicular to an edge and lies in a face belonging to the zone to the axis of which the edge is parallel ; and Neumann, Kayser and Rose gave their great authority in favour of such a mode of twin-formation. A line of this kind is not however a crystallographic line in the Anorthic system, as neither the line itself nor the plane normal to it would have a rational symbol : and the line has therefore no significance other than what might be due to its supposed function as a twin-axis. The twins of albite and of the pericline variety of this mineral, for the explanation of which this mode of twinning was virtually called into existence and maintained, can be ac- counted for in a simpler manner, and will be found to be ex- plained in a subsequent article by the mode of twin-growth round an edge. In other cases in which this mode of twinning has been called in, it will also be found that the two more simple kinds of twinning are competent to explain the complicated growths to which the former has been applied; and that where this more complex principle would seem more simply to explain them, accu- rate measurements, on which alone it could be established, are wanting or were not possible by reason of the impracticability of obtaining them. It is in fact only for complex structures con- sisting of several individuals, explicable by one or both of the two simpler methods of twin-growth, that this third mode of explanation has been invoked, and in most cases so invoked to account for the twin-relations of members of the group that are not in contact and are only mutually related through the intervention, so to speak, of one or more other individuals of the group. 355. The non-crystallographic line, round which the pericline- 376 Anorthic system. twin of two individuals was supposed by Kayser to be formed, is perpendicular to the X-axis and is inclined on the JT-axis, the zone- axis [oio], at so very small an angle that it is practically im- possible, in the case of a mineral presenting the striated faces common in pericline, to determine, by direct measurement of the angles between the planes of the twin-growth, which of these adjacent lines is the true twin-axis. The discussion of the argu- ment in regard to these twins will be given later, when the twinning round a zone-axis is treated of in Art. 362. In the case of the twinned groups of albite, which were the first that suggested to Neumann recourse to this irrational axis, the crystals are twinned in pairs, each pair on a face-normal (oio), and adjacent crystals of different pairs round a zone-axis [ooi]. The explanation of the relative position of the first and third indi- viduals offered by Neumann, purely as a geometrical explanation, in which a line normal to a zone-axis and lying in a face is con- ceived to be a twin-axis, introduces in fact a greater difficulty than that of a double twin-law by giving to a line with an irrational symbol a crystallographic function. 356. Besides the felspar-twins alluded to in the last article, the only other cases adduced to support an irrational twin-axis are the following : 1. A single specimen of labradorite 1 from Hafnefjord, con- sisting only of a termination of a twin-crystal formed by a thin lamina of only \\ millimetre in length, and yielding only ap- proximate measurements made with a source of light very close to the goniometer. Vom Rath described this crystal in 1871, but did not again refer to it when in i879 2 he pointed out that the evidence for the variety of twinning under discussion was not sufficient to establish its recognition. 2. A complicated twin-growth of anorthite 3 , which did not admit of accurate measurements and could be satisfactorily explained by the ordinary rational twin-axes, as was pointed out by vom Rath who first described it. - Annal. vol. 144, 1871, p. 277. 2 Groth's Zeitschrift, vol. 6, 1879, ? I2 - 3 Pogg. Annal. vol. 147, 1872, p. 59. Twinned forms. 377 3. A single crystal of kyanite described by Bauer 1 . In this mineral the twin-axis, if perpendicular to the ^-axis as supposed by Bauer, is inclined to a second edge at a small angle which has been determined by Bauer himself as 23', by Brooke and Miller as 15', and by vom Rath on one specimen as 5', and on another as zero. It is therefore more probable that in the specimen described by Bauer this edge, and not the perpendicular to the ^-axis, is really the twin-axis ; and in fact in two other very similar specimens, also described by Bauer, the 2T-axes of the two individuals, instead of being quite parallel, were distinctly inclined to each other. It is quite evident that no new mode of twin-growth could be established by any of these specimens, and that, had not the above mode been considered to be well-established by means of the specimens of pericline, a simpler explanation would have been suggested in each instance. 357. As the characters of the twin-growths observed in other anorthic crystals, as for instance those of brochantite and kyanite, are not essentially distinct from the characters presented by the anorthic felspars, the illustrations will be selected from the last- mentioned and more plentiful minerals. I. Twin-plane a face; the face of union parallel to the twin-plane. Since in this system there is no symmetral plane and the crystallographic axes are consequently selected more or less arbi- trarily from the zone-axes, no essential difference in the twin- growths can be associated with a mere difference in the symbol of the twin-plane : as, however, the lines chosen for axes are usually the intersections with each other of planes either of cleavage or of prominent development, a numerical difference in the symbol will correspond to a distinction in the aspect of the twin-growth. 358. Twin-face the pro-pinakoid {oio}. This mode of twin-growth is very common in all the anorthic felspars. Fig. 327 represents a simple crystal of albite; two nearly perfect cleavages are parallel to the faces (oio) and (ooi), and correspond to analogous faces of the mono-symmetric felspar 1 Zeitsch. d. deutsch. geol. Gesell., vol. 30, 1878, p. 306. 378 Anorthic system. orthoclase. If the crystal be bisected by a plane passing through its centre and parallel to the pro-pinakoid {oio}, the section will have the form defghk and will be centro-symmetrical : hence the section will be congruent with itself after a rotation of 180 round the normal to its plane. If, therefore, the front half of the crystal of Fig. 327 be turned through two right angles round the normal to the face (oio), the sections will again coincide and the resulting compound crystal will have the form shown in Fig. 328, and be symmetrical to the plane of union. No face being per- pendicular to the twin-plane, with the exception of the faces of the pro-pinakoid {oio}, no face of one individual is parallel to a face of the other. The normal-angles made by the planes ooi, Yoi with the twin-plane olo are 86 24' and 86 21' respectively: no oio oio 3 Fig. 327- 3 Fig. 328. Fig. 329. hence there will be two nearly equal re-entrant angles, 7 1 2' and 7 1 8', at the upper end of the twin, and two salient angles of the same magnitudes at the lower end : the angle no. olo being 119 40', the angle no . (TTo) will be salient and equal to 59 20'. 359. If the twinning be repeated the growth has sometimes the form shown in Fig. 329, and may then be otherwise regarded as a single crystal enclosing a twin-lamina : in most cases the twin- ning is repeated several times, as already illustrated in Fig. 59 and in some cases the twin-growth consists of a hundred or more laminae, of which adjacent individuals are in twin- and alternate ones in parallel positions. In the mono-symmetric felspar orthoclase the normal to the corresponding face (oio) is an axis of diagonal symmetry, and is impossible as a twin-plane, for a rotation of the crystal through Twinned forms. 379 two right angles round such a line would bring it into a position not crystallographically distinct from the first : hence the presence of twinning about a face of the pro-pinakoid is sufficient evidence that a specimen of felspar belongs to the anorthic series. 360. Sometimes, as in the fine crystals of albite from the dolo- mite of Roc-tourne in Savoy, described by Gustav Rose 1 , the individuals are interpenetrant. The crystals from this locality are quite tabular through the prominent developement of the pro- pinakoid, and have the habit shown in Fig. 330 : these twin- crystals are remarkable in that the two angles formed at opposite ends by the basal pinakoids of the two individuals, instead of being one salient and the other re-entrant, are both re-entrant, while Fig. 33. Fig. 33 1 - the angles formed at opposite sides by the faces of the form {201} are both salient : further, a vertical furrow bounded by faces belonging to the form {130} traverses each face of the pro- pinakoid {oio}. If the twin-crystal be broken across so as to show the basal cleavages of the two individuals (Fig. 331), it is seen that on the broken part at one side of the furrow the cleavages form a re-entrant angle, and on the part at the other side of the furrow a salient angle, and that each of the cleavage-faces on one side of the furrow is parallel to the diagonally opposite face on the other side of the furrow. The individuals thus appear to cross over to opposite sides of the junction-plane at its intersection with the furrow. 361. Other faces presenting themselves as planes of twinning in 1 Pogg. Annal. vol. 125, 1865, p. 460. 380 Anorthic system. the anorthic felspars are comparatively rare. LeVy 1 and also Schrauf 2 have described specimens of albite twinned about the basal pinakoid (ooi) and similar in aspect to the orthoclase-twin of Fig. 308; growths of albite already twinned about the zone- axis [oio] are likewise known in which there is a further twinning about the basal pinakoid (ooi), as shown in Fig. 340: Amazon- stone from Pike's Peak, a green variety of microcline, is sometimes twinned similarly to the so-called Baveno-twins of orthoclase, namely about a plane (021); an albite crystal has been described by Neumann 3 , and one also by Brezina 4 , twinned about a plane having the same indices. In kyanite, crystals enclosing laminae of which the position is due to twinning about a plane (308), not observed as a face of the crystals, have been described by vom Rath 5 . II. Twin-axis an edge: plane of union perpendicular to the twin-plane. 362. i. Twin-axis the Y-axis [oio]. The most important twin-growths assigned to this law are the common twins of pericline. Their most characteristic feature is the presence of an obtuse re-entrant edge of very small angle traversing a face of the pro-pinakoid {010} in a direction more or less nearly parallel to its intersection with the basal pinakoid {ooi}. The basal pinakoids of the two individuals being parallel, the twin-plane must be either parallel or perpendicular to these faces ; that the latter is the true explanation is at once evident from the fact that corresponding faces of the two crystals, instead of being symmetrically disposed with respect to a plane parallel to the basal pinakoids, are diagonally symmetrical to a line lying in that plane : the exact position of this line, the twin-axis, has been long a matter of doubt. 363. The growth was first mentioned in 1824 by Mohs 6 , whose 1 Catalogue des mineraux de M. Turner, 1837, vol. 2, p. 194. 2 Atlas der Kry stall -formen, 1864. 3 Abhandl. Ak. Berlin, vol. 19, 1830, p. 218. * Tschermak's Min. Mittheil. 1873, p. 19. 5 Groth's Zeitsch. vol. 3, 1879, p. 9. 6 Grundriss der Mineralogie, 1824, vol. 2, p. 295. n^ ^ forms. 381 statement of the law as twin-axis [oio] was accompanied by a figure analogous to Fig. 332, in which the two individuals are represented as intersecting in a plane parallel to the faces of the basal pinakoid; thus the edge X, formed by the intersection of olo . ooi and therefore parallel to the J-axis, is represented as parallel both to the corresponding edge X 1 and to the edge R formed by the intersection of olo . (oYo), pro-pinakoid faces belonging to the different individuals. In 1835 Kayser 1 pointed out that as the line [oio], the .F"-axis, assumed as twin-axis by Mohs, is not at right angles to the J^-axis but is inclined to it at an angle of 8 9 13^' (according to Breithaupt), the edge X 1 instead of being parallel to X ought to be inclined to it at an angle of I 33i / j an d further that the edges X and R ought to have a mutual inclination of 13 n J', as shown in Fig. 333. The question Fig. 332. Fig. 333- Fig. 334- thus arose as to whether the statement of the law or the figure given by Mohs was most nearly in accordance with the features of the specimens themselves. Kayser, and later Rose 2 , after examination of numerous specimens came to the conclusion that all deviations from parallelism presented by the edges X, R, X l were due to the striated and imperfect character of the faces, and that a line exactly perpendicular to the J^-axis, and not the .XT-axis which makes an angle of 89 13^' with that line, must be regarded as the twin-axis : Fig. 334 illustrates the form of the ideal twin corresponding to this view. Kayser's explanation of the twins of pericline became very generally accepted, although three eminent 1 Pogg. Annal. vol. 34, 1835, p. 108. 2 Ibid. vol. 129, 1866, p. i. 382 A nor thi^sy stem. observers, Miller, Des Cloizeaux and Schrauf, adhered to the older statement given by Mohs. By the publication of an elaborate memoir of Vom Rath in 1876 1 the accuracy of the older view may be regarded as now fully established. Vom Rath has pointed out that the approxi- mate parallelism of the edges X, R, X l is only exceptional, and is then due to irregularity in the growth of the individuals beyond their plane of junction, and that the angle between the edges X and R changes considerably for a very slight change in the angles of the individuals, which in albite and its variety pericline vary somewhat with the locality of the specimens : he further states that Kayser's conviction of the parallelism of the above edges was arrived at chiefly from consideration of some excellent twin- growths not of pericline but of oligoclase, a felspar of which the angles are such that the J^-axis [oio] is itself almost precisely normal to the edge X, so that the two modes of explaining the twin become in this particular case practically indistinguishable. Fig. 335- Fig. 336. 364. The relative positions of two individuals of an anorthic felspar after the rotation of one of them through 1 80 round the axis [oio] may be determined as follows: In Fig .335, <2, , c are the points of intersection of the crystallo- graphic axes OX, OF, OZ with the edge formed by the faces ilo .no, with the face olo and with the face ooi respectively: aOa is thus parallel to the edge X and cO to the edges of inter- 1 Monatsber. d. Ak. Berlin, 1876, p. 147. Twinned- forms. 383 section of the prism-faces. Since the normals from a point in a twin-axis to two corresponding faces are co-planar with the twin- axis, the edge of intersection of the faces is perpendicular to that line : hence the edge of intersection of the face olo with the corresponding face of the other individual must be the line in the face oio which is perpendicular to the axis bOb. Hence if the line fbg be in the face oio and be at right angles to bO~b, and eOh, dbk be lines parallel to fbg, the figure defghk will be the intersection of corresponding faces of the two individuals. The position of the \mefg, or of its parallel eh, may be thus calculated : Let the spherical triangle abc (Fig. 336) be obtained from the intersections of the lines Oa, Ob, Oc with a sphere having its centre at : e, the point of intersection of Oe with the sphere, will fall in the great circle passing through c and a, for the line Oe is in the plane aOc, parallel to oTo : further, the arc eb is a quadrant, since Oe is at right angles to the axis Ob : whence, by the ordinary formula cos eb = cos ea cos # + sin ea sin ab cos eab, we have cot ea = tan ab cos eab : ea is the angle which Oe or fg makes with the line Oa, or the edge X, and may be denoted by 0; eab is the angle between the planes aOc, a Ob, or the supplement of the angle between the normals to the faces oYo, ooi ; ab is the supplement of the angle between Oa and Ob : hence cot = cos (/> tan f. 365. In the case of albite from Schmirn = 86 30' and = 92 8', whence = + 3i 23': in albite crystals measured by Breithaupt < = 86 41' and C = 90 47', whence 9 = + 13 18': in anorthite < = 85 50' and f = 88 48', whence 16 5'. Thus while in the case of albite the edge of junction R of the pro-pinakoids of the two individuals would meet the edge X in front, in that of anorthite the two lines would meet if produced backwards, and in the one felspar the inclination may be as high as 31 or as low as 13 in one direction, and in the other felspar is 1 6 in the opposite direction. For the remaining felspars with 384 A north^c system. intermediate parameters the line R will have an intermediate direction, and in oligoclase is almost exactly parallel to the edge X : hence vom Rath points out that the direction of the edge of junction on the pro-pinakoid face may be of occasional service for the determination of the kind of anorthic felspar to which the individuals of such a twin-growth belong. 366. The above section defghk determines the directions of the lines in which corresponding prism and pinakoid faces of the two individuals would meet, and is, so far at least, merely a geometrical fiction and analogous to the twin-axis as an axis of revolution : it is a constructional plane useful for the determination of the directions of the edges in which the corresponding faces would meet, if they met at all, and even in the latter case the whole surface of the figure might not be common to the two crystals. In fact Mohs regarded the plane parallel to the basal pinakoid as being in every case the plane of junction, while Kayser, who first pointed out that the edges of the basal pinakoid could not take up a congruent position on rotation through two right angles about any line in its plane, still considered that this plane was the plane of junction, holding that the frequent intersection in edges was due to the growth of parts which lay outside the boundaries of the surface common to both the individuals. 367. Similar growths to the twins of pericline are met with in anorthite, but in the latter felspar have a more precise character owing to the greater constancy of the angles of the individual crys- tals, and have thus been always and unhesitatingly assigned to this twin-law; in anorthite, too, the faces of the zone [oio] are more numerous and are more prominent in their developement, so that the exact parallelism of the faces of this zone, corresponding to each other on the two individuals, is capable of easy demon- stration. Vom Rath, to whom we are indebted for a careful description of these twin-growths l , has described crystals enclosing- numerous twin-laminse of which the faces are parallel to the above section, and has thence inferred that, notwithstanding its irrational indices, it has generally a physical existence and is the plane of union, whenever corresponding faces of the two individuals actually 1 Pogg. Annal. vol. 147, 1872, p. 42. Twinned forms. 385 intersect, as in Fig. 337. Sometimes, however, the individuals have their basal pinakoids in contact, and present incongruent edges as illustrated in Fig. 338, which represents an actual twin- growth described by vom Rath. Fig. 337- 368. In the case of pericline itself the surface of junction is frequently irregular and is rarely quite plane : sometimes the indi- viduals have their basal pinakoids in contact, and have incongruent edges similar to the anorthite-twin of Fig. 338 : at other times they are more or less interpenetrant, and if the twin be broken parallel to the pro-pinakoid cleavages it presents a zigzag line of Fig. 338. separation of the individuals, one side of the zigzag being deter- mined by the above section and the other by the vertical axis : in two exceptionally good specimens the above section seemed to be actually the face of junction. 369. Simple twins of pericline have not been observed: the crystals always interpenetrate and appear to cross over to opposite sides of the junction-plane, as in the crystals of albite from c c ;86 Anorthic system. Roc-tourne' described in Art. 360, which are twinned about the pro-pinakoid (oio). The edge traversing the pro-pinakoid face thus comes to be re-entrant at both sides of the twin, instead of being re-entrant at one side and salient at the other : such a twin is represented in Fig. 339. Fig. 339- In Fig. 340 is illustrated a specimen of pericline, described by vom Rath, in which two twins of the kind just mentioned are united by their basal pinakoids and are symmetrical to their face of union, the two innermost individuals on the right or left sides of the growth being therefore twinned about the face (ooi): the equality of the inclinations of the edges R, R l to the edge X l in this specimen furnished a convincing proof that the obliquity is a fundamental, not an accidental, character of the pericline-twins. Fig. 340. Fig. 341- 370. 2. Twin-axis the X-axis [100]. This mode of twinning is described by Des Cloizeaux as occur- ring, though very rarely, in pericline from Tyrol: in Fig. 341 is illustrated a simple twin figured by Schrauf. The plane of union Twinned forms. 387 is nearly parallel to the basal pinakoid and intersects the pro- pinakoids in an edge T parallel to the edges X and X 1 : the twin-axis being parallel to the intersection of the basal pinakoid with the pro-pinakoid, a pro-pinakoid face of one individual will be co-planar with a pro-pinakoid face of the other, and the basal pinakoids of both will be parallel. The law is more often met with in complicated twin-growths of eight individuals, twinned in addition about the face (ooi), in the albite of Ala in Piedmont. 371. 3. Twin-axis the Z-axis [ooi]. This law of twinning, which is more rarely met with than the or- dinary pericline law, corresponds to the Carlsbad law of the mono- symmetric felspar orthoclase, and the growths are similar in aspect. As before, the plane of junction is perpendicular to the twin- plane and intersects the crystal in a section which, though sym- metrical to its centre, is not symmetrical to the twin-axis lying in it, whence the edges of the section are not congruent in the two positions. The twins are dissimilar in character from the pericline twins, for there is no growth of the individuals beyond the incongruent edges, nor do the individuals cross to opposite sides of the plane of junction : in Fig. 342 is illustrated such a twin-crystal of anorthite from Vesuvius, described by vom Rath. Fig. 342. c c 2 CHAPTER VIII. THE MEASUREMENT AND CALCULATION OF THE ANGLES OF CRYSTALS. SECTION I. The Goniometer. 372. Two methods have been employed for measuring the angle between the faces which form an edge on a crystal. The one is a mechanical contrivance by which the angle contained between two steel bars brought into contact with the faces of the crystal is read off on a graduated arc ; the other consists in making the crystal revolve round the edge to be measured, and determining by the aid of a ray of light fixed in direction the angle through which it must be turned in order that each of the two faces in succession may be in a position to reflect the light in an identical direction. By the former method only approximately correct measurements can be obtained even from faces of exceptional smoothness and considerable size; while the accuracy of the latter method need only be limited by the precision with which the measuring instru- ment is graduated and the perfection as reflecting planes of the faces to be measured. The instrument employed in either case is termed a 'goniometer'. 373. The contact- or hand-goniometer (Fig. 343). As first employed by Rome* de lisle, and subsequently modified by Haiiy, it has the form of a flat semicircular arc of brass or silver graduated from o to 1 80 and subtended by a flat steel bar, which, for convenience in manipulation where the crystal is entangled with associated mineral, is able to move in the direction of its length, and is constrained so to move by two screw-pins which pass through two long slots cut in the bar parallel to its sides and clamp the bar to a corresponding bar which is fixed in the position of a radius to the graduated arc : one of these screw-pins is fixed at The contact-goniometer. 389 the centre of the arc, the other near its circumference. The edges of this bar are parallel to the diameter which passes through the zero of the graduation. A second moveable bar corresponding to the first has only one slot extending to about half its length, and being held by the central pin only, is capable of being rotated round it as a pivot with any desired amount of friction, while for convenience of adjustment it also can be moved in the direction of its own length. Of the two bars or arms of the instrument thus mounted, the parts of the narrower sides or edges that are to be brought into contact with the faces of the crystal are worked Fig. 343- into perfectly squared and plane surfaces. The limb of the rotating arm which moves over the graduated face of the goniometer is cut away to one half its width and worked to a straight chisel-edge, the continuation of which would thus pass through the centre of the graduated semicircle ; this edge therefore indicates the arc subtended by the two arms, and thus when the arms have been applied to two faces of a crystal indicates the angle between them : the instrument is more convenient when graduated in the opposite direction to that shown in the figure ; the indicated angle will then be that between the poles of the faces. The instrument is usually constructed with a hinge on the graduated arc, whereby one quadrant can be doubled back behind the other, so as not to impede the measurement of an embedded 3QO The reflection-goniometer crystal; and to this purpose also the sliding motion of the arms subserves (Fig. 343). In using the hand-goniometer the points to be attended to are the perpendicularity of the plane of the instrument and of the broader faces of the steel arms to the edge to be measured, and the complete simultaneous contact of both the straight nar- rower surfaces of the arms with the crystal-faces, as tested by examination between the eye and the light. And during the operation, and especially when removing the instrument from the crystal, it is well to maintain a slight pressure of the crystal on the arm that does not rotate, and none, or the least possible, on the crystal-face in contact with the rotating arm which indicates the arc on the graduated circle; the crystal being drawn away from the measured edge along and with a slight pressure against the fixed arm. With every precaution, and where the faces to be measured are well adapted by size, smoothness, and accessibility, the successive readings of the measured arc may accord within the limit of a quarter of a degree. Such cases are however very rare, and it is evident that even this is not a sufficient degree of accuracy for the purposes of exact crystallography. The instrument described is often employed in a simpler form ; the arms being separate from the arc but capable of being applied to it by inserting the pivot of rotation of the two arms in the centre of the metal arc, which then presents the character of an ordinary semicircular protractor. 374. The reflection- goniometer of Wollaston, in its original form, consists of a circular metallic disc four to eight inches in diameter, with a flanged rim graduated with degrees and subdivisions of a degree (Fig. 344). An axle at the centre of the disc revolves in a collar of metal fixed to the support of the instrument, and is firmly attached to a flat circular handle with a milled edge behind the disc, whereby the disc with its graduated arc is carried round. The graduations are read by the aid of fixed verniers. The axle of the disc is hollow, and a second and solid axle or core passing through it and ground accurately into it can be turned independently of the disc by a smaller handle similar to the one which turns the disc itself and parallel to but beyond it: the extremity of this axle, which of Wollaston. projects beyond the face of the goniometer, bears a small and simple apparatus for the support and adjustment of the crystal to be measured. In the adjustment of a crystal this independent rotation of the axle of the instrument is convenient, as it enables the crystal and the apparatus holding it to be turned without moving the graduated circle. For use the goniometer is planted in front of a window, a bar of which may be taken as the object to be reflected in the crystal- faces ; or, preferably, the object or signal may be a slit in a dark screen illuminated by the sky or by artificial light ; or a beam of sunlight may be directed on the crystal by a heliostat and seen through a protecting glass held before the eye. The crystal is now at- tached to the holder by a little plastic material formed by fusing together beeswax and pitch in suitable pro- portions ; this may be kept at hand conveniently if rolled out into a pencil- form. The holder is a small rectangle of thin sheet-brass which is gripped in a slit at the end of a rod, which rod serves to turn and to give a traversing motion to the holder by its play in a collar attached to a curved brass support, which again has a turning motion round a pivot in a second similar support which is fastened to the axle of the gonio- meter; see Fig. 344. The variety of motions that can by these means be given to the holder enables the observer with a little practice to adjust the crystal in any position. For the purpose of measuring, however, especially for following the measurements of a zone, the position Fig- 344- 392 The reflection-goniometer. of the crystal usually presented by books on crystallography is impracticable. The crystal must in fact project clear of the ap- paratus and beyond the different portions of the support ; the eye can then uninterruptedly observe the faces of the zone as they in succession come round and, if properly adjusted, reflect to it the signal, each in turn. Assuming then that the crystal has been or is readily capable of being thus adjusted since the precautions to be taken in the centering and adjustment will have to be discussed presently in detail we may proceed now to the other conditions that have to be fulfilled if a correct measurement of the normal-angle of two of the faces of an adjusted zone is to be made. This can only be attained when the rotation of the crystal round the axis of the goniometer through this normal-angle shall have brought the two faces in succession into a position in which each reflects the axis of a pencil of rays, coming from the centre of the signal, in the same direction, a condition which necessitates the position into which the second face is brought being parallel to and, for exact measurement, coplanar with that previously occupied by the first face. The direction of vision must evidently be unchanged during the measurement. Wollaston achieved this by placing in the line or vision of the reflected signal a second signal similar to it but more faintly illuminated. Then viewing this second signal by direct vision he would bring the image of the first signal, as seen by reflection from one crystal-face, into contact with it, and when the one signal, seen so through a portion of the pupil of the eye, exactly covered the other as seen directly through the remaining portion of the pupil, he arrested the turning motion. A second crystal-face being treated in the same way, the difference of the readings on the circle gave the normal-angle between the faces. Kuprfer substituted for the second signal the image of the first signal as seen by reflection in a mirror of black glass. 375. But the most important modification that Wollaston's goniometer has received is that which, in the hands of Mitscherlich, has made it a new instrument by endowing it with a telescope fitted with cross-wires, by the aid of which the direction of the Improved forms. 393 rays reflected from successive crystal-faces was fixed with great precision. The greater rigidity of direction thus imparted to the axis of vision involved the necessity of a motion either of the telescope or of the crystal in a direction parallel to the axis of the instrument, so that the faces of the zone to be measured might be brought with precision into the field of view. This is usually effected by giving the telescope a sliding movement parallel to itself on a bar that supports it. But Professor Viktor von Lang introduced an im- provement on this method by fixing the ' head* (or part of the goniometer which carries the crystal and the screws for its adjust- ment) on the end of a hollow cylinder, which fits on and can be clamped immoveably to an accurately turned solid cylinder of steel, forming a continuous piece with the solid core of the axle of the goniometer : the hollow cylinder can thus slide on the solid one and be fixed by the clamp. This method offers the advantage that the goniometer being adjusted and fixed in position the tele- scope may be also adjusted once for all to the centre of the re- flected signal ; any variations in situation of the edge to be mea- sured, whether from the magnitude of the crystal or from the con- ditions under which it is mounted, being compensated by the motion not of the telescope but of the 'head' and of the crystal carried by it. If a collimator be used, the signal introduced by Websky is very convenient : it is limited by two brass discs of which the distance from each other can be altered by means of a screw, and by two straight edges parallel to the line joining the centres of the discs. In Wollaston's and Mitscherlich's goniometers the axis is hori- zontal and the plane of the graduated circle is vertical. Professor Miller, however, adopted a form of the instrument in which the axis is vertical and the disc horizontal: a form very simple in adjustment, and furthermore one especially adapted for measuring such crystals as are either too heavy of themselves, or are attached to masses of mineral and rock too considerable, to be carried by a vertical goniometer without causing strains that must conduce to flexure in the support and to very appreciable inaccuracy in the results obtained. 394 The reflection-goniometer. 376. We shall now proceed to discuss the process of putting the goniometer into proper adjustment for measuring a crystal, and for this purpose we shall have recourse to methods independent of the use of a mounted crystal. Certain qualities have of course to be presupposed as being presented by the instrument itself. These include accurate graduation involving a power of reading by the aid of the verniers v (Fig. 345) to 15"; the perpendicularity v Fig. 345- of the axle to the face of the goniometer disc ; a minimum of * backlash ' in all the screws that impart motions ; and a firm fastening of the handles to the axles which they turn, so that any motion of either handle is instantly responded to by the graduated circle or by the mounted crystal, as the case may be. In order to proceed in a defined manner we shall assume the goniometer, in the first place, to be one of the vertical construction with the telescope permanent in its position and the head move- able (Fig. 345). The foot on which the telescope is mounted has Its adjustment. 395 adjustment-screws pp, to regulate in azimuth the position of the plane of observation relatively to that of the goniometer-disc D. There are also screws yy for regulating the horizontally of the cradles or F's in which rest the trunnions xx on which the telescope T turns. Now the following are the ends to be attained in planting the goniometer and adjusting the telescope : a. The goniometer-axis is to be horizontal. b. The plane of observation which passes through the centre of the signal and the optic axis of the telescope is to be vertical, and is to be parallel to that of the goniometer-disc. c. And it is convenient that it should be perpendicular to the plane of the signal. d. The optic axis of the telescope is to intersect the axis of the goniometer. In order to effect these adjustments, and to do so in a certain order, the following adjuncts to the signals employed are of the greatest use : A long wire of substantial thickness, swinging freely and as close to the plane of the signal as is consistent with its carrying a suspended plumb-weight : it must exactly intersect the centre of the signal. A second and similarly weighted wire (for which however may be substituted a distinctly seen vertical line on the wall or window) placed at a distance to the right of the former wire equal to twice the distance of the goniometer-face from the intersection of the cross-wires of the telescope. The latter will be termed the adjust- ment-wire, the former the signal-wire. A flat dish or tray con- taining clean mercury. A metal pin w (Fig. 347), one end of which fits into the ' head ' of the instrument while the other terminates in an accurately turned point. A lens / (Fig. 345) of such focal length that when applied in front of the object-glass of the telescope the crystal can be observed as by a microscope of low power. This lens turning on a pivot can be applied or removed at will : the telescope when used with the lens will be termed the micro-tele- scope. Where a collimalor is not employed it is important that the signal should be at a considerable distance about 20 feet to. 396 The reflection-goniometer. 30 feet from the telescope is sufficient from the goniometer, and, where this instrument is one of the vertical construction, it is desirable that the signal should be at such a height that the angle of incidence and reflection from a crystal-face may be about 45: and the slit or bar employed as a signal should be quite horizontal. 377. In the first place, the goniometer is planted on a firm table, in such a position that the plane of observation is ap- proximately perpendicular to the window or plane of the signal. A method will be given for obtaining this perpendicularity with accuracy, but a first approximation attained by any simple geo- metrical method that may suggest itself according to circumstances is desirable as simplifying the processes. a. Horizontality of axis. The goniometer is to be turned round upon the table until the image of the signal -wire can be seen in the lacquered face of the disc D, and the turning move- ment continued until this image is seen to be in contact at the edge of the disc with the adjustment-wire as seen directly. If the adjustment-wire and the image of the signal-wire are not in con- tact throughout their length but are seen to be inclined to each other, the levelling screws -S* are set in motion to bring them into parallelism when a little separated; after a slight turning of the whole instrument the one wire will then be seen to eclipse the other. A small spirit-level with a stirrup mounting is also convenient for securing the horizontality of the steel core of the instrument. Two objects will now have been effected: the axis of the goniometer will be horizontal and the disc will lie in a vertical plane which bisects the space between the signal- and the ad- justment-wires, so that if the telescope is in correct adjustment, on directing it to the signal, the signal-wire should be seen passing through the cross-point of the telescope-wires in every position of the telescope as it turns on its trunnions. b. Adjustment of plane of observation. But if the centre of the signal lie on one side of this point when the telescope is turned to it, the adjustment-screws pp are brought into use to turn the telescope in azimuth until the cross-wires and the signal-centre are seen as if in contact. The effect is of course to bring the optic Its adjustment. 397 axis of the telescope, when it is in this one position, into parallelism with the plane of the disc. The mercurial trough is now placed in such a position on the floor of the room that the signal as reflected in the mercurial sur- face can be seen in the telescope ; and if the centre of the reflected signal is found to fall on the cross-wire, there is nothing more needed in this part of the adjustment: the telescope obviously must have been moved in a plane perpendicular to the surface of the mercury and therefore containing the signal-wire ; and if the vertical wire of the telescope be correctly placed to cover any part of this signal wire it will continue to do so when the tele- scope is directed to any other part of that wire and its reflected continuation. But if these events do not take place and the signal-centre is on the cross-wire when seen directly and to the side of it when seen reflected in the mercurial surface, the adjustment screws yy that regulate the relative elevation of the trunnions of the telescope are set in action to bring the axis on which the telescope turns into parallelism with that of the goniometer. In fact the correction has to be made to half the extent of the error as shown in the mercurial mirror. If this and the previous operation have been correctly performed, and have in fact been repeated to ensure greater exactitude, the telescope will now be in accurate adjustment as regards the parallelism of the plane of observation with that of the disc of the goniometer and there- fore with the plane containing the graduated circle. c. Plane of observation and plane of signal made perpendicular. So far we have been content with only an approximately perpen- dicular position for the plane of observation in respect to the plane containing the signal. The cross-wires in a telescope are rarely strictly perpendicular to each other; it is not always that they intersect exactly in the centre of the field of view. Adjustments to the true centre can however be effected by turning the eye-piece through 180, and taking for the ' cross-wire' the point on the horizontal wire to which the two positions of the actual wire-crossing are symmetrical. In order to make the plane of observation perpendicular to 398 The reflection-goniometer. the plane of the signal, let the horizontal wire be first turned into a position of exact parallelism with the sides of the signal, which is assumed to have been previously mounted in a horizontal position by the aid of a good spirit-level. On observing the image of the slit from the mercurial surface, if the plane of observation is not strictly perpendicular to that of the signal, the image will now be seen inclined at a certain angle to the horizontal wire of the telescope. Let therefore the eye-piece be turned till the hori- zontal wire bisects this angle. If now the goniometer be moved in such a manner that on the one hand the adjustment-wire is kept in apparent contact with the image of the signal-wire as in the adjustment (a), and so that, on the other hand, the image of the signal-slit seen on the mercury is brought into parallelism with the horizontal wire, the adjustment of the instrument in respect to the signal will be found to be complete. d. Direction of telescope-axis. We have only, in fine, to be careful that the optic axis of the telescope accurately intersects the axis of the goniometer : and this is readily effected by first mounting the pointed metal pin w (Fig. 347), to which allusion has been made, so centiically that when the goniometer -disc is turned the point makes no excursion from the axis; and then by means of the adjustment-screw (not visible in the figure) which regulates the inclination of the telescope the horizontal wire is brought accurately to cover the point of the metal pin as seen in the micro-telescope. Or if, first, one of the traversing screws be placed in a vertical position, and the point of the metal pin be brought into apparent contact with the horizontal wire of the micro-telescope by turning the traversing screw ; and if, secondly, on bringing the second traversing screw into the vertical posi- tion the point has not moved away; or, if it has moved away and after being brought back to the wire by the second tra- versing screw it .remains permanently in contact with the wire as the goniometer-disc is turned, the adjustment is complete. If, however, in the last event the position of the point is not per- manent, the point should be turned by means of the axle into the position of its maximum excursion from the .centre, that namely Its adjustment. 399 in which the goniometer has revolved through 180 from the last position. The declination-screw of the telescope should now be turned until the point is moved through one half the distance separating it from the horizontal wire, and the point itself should be brought down by the second traversing screw into contact with the wire. The adjustment will be found to be now complete. The best assurance that all the corrections have been accurately made will be obtained when a zone, preferably an ortho-symmetrical zone, has been adjusted on the goniometer, and the images from the successive faces have been found to pass through the field of view, each moving symmetrically in respect to the vertical wire and in parallelism to the horizontal. Any deviation from this symmetry or parallelism should be at once traced to its source in one or other of the causes that have been discussed. 378. Where a collimator is used, it is advantageous to have a small triangular prism fixed to it, just above the objective, in such a position that the image of the signal given by a face may be viewed after total reflection in the prism. A pencil of rays from any point of the signal is first reflected from the face in a direction nearly perpendicular to it, then totally reflected in the prism, and next enters the telescope, which in this case is so arranged that its axis can be directed to intersect the axis of the goniometer either directly or after total reflection in the prism. This arrange- ment is occasionally convenient when the faces are much striated or the crystal is attached to its matrix. 379. Before passing from the adjustment of the goniometer to the mounting of a crystal on the adjusted instrument it should be remarked that it is very desirable either to have both the gonio- meter and the signal fixed permanently in position, or to have in front of the permanent signal a fixed stand to which the goniometer can be transferred without involving the necessity of readjustment. The three-armed groove proposed by Sir W. Thomson forms an admirable stand for this purpose. The top of the goniometer-table or a slab Zf that can be fixed to it is formed of hard wood or slate, and has three grooves ggg (Fig. 345) cut in its surface which meet at angles of 120: their section is a right angle, and one of the three cylindrical feet of the goniometer is placed in each groove. 400 The reflection-goniometer. In planting the goniometer in position before the signal and in levelling it, this stand has to be shifted until the adjustment is complete and is then fixed in the position thus determined. The goniometer may now be removed and replaced on its stand in identically the same position as often as is requisite. 380. It has already been indicated that, in order to ensure accuracy in the process of measuring the angles of a crystal, the precautions to be taken relate not only to those preparatory ad- justments of the goniometer and the telescope which have been . Fig- 346- discussed in detail, but also to the proper mounting of the crystal itself; but before defining these latter precautions it will be well to discuss the optical principles involved in the method of measure- ment by a reflection-goniometer, certain of which have been in fact already assumed by anticipation during the discussion of the adjustments of the instrument. Let S, Fig. 346, be the centre of the signal, B> a point in the axis of the goniometer, and EL the optic axis of the observing telescope of the instrument of Mitscherlich, or the line of sight of the naked eye as in the method of Wollaston, and so directed that if continued it passes through B. If then -5", the centre of the slit, is seen reflected by a crystal -face so as to coincide with Error due to imperfect centering. 401 the intersections of the cross-wire in the telescope, the following statements follow from the elementary principles of optics : (1) Every image of the centre of the signal S that is to be seen placed at the intersection of the cross-wires must be due to rays of which the axis is reflected in the direction ^BE. (2) If 2 be the image of S, S and 2 will be symmetrically situate in regard to the reflecting plane. So that if M be the intersection of the line S2 with the plane of the crystal-face, SM= 2JJ/and -5*2 is perpendicular to the reflecting plane ; and this plane forms an oblique section with the cone of rays of which 2 is the apex and It the object-glass of the telescope or the pupil of the eye is the base : the brightness of the image will therefore increase as more of this oblique section is a reflecting surface, and will therefore increase with the magnitude of the crystal-face so long as this is not greater than that of the section. (3) If the crystal-face lie in a plane BM passing through the axis of the goniometer, its position must be at or near B and within the limits of the cone of rays 2//'; the direction of MB being determined by the angle SB E, since the angle SBM is the complement of \ SB E. In the case of the crystal-face lying in a plane not passing through the axis of the goniometer (though necessarily parallel to it), if the plane be parallel to the plane B ' M "the axis of the reflected rays will not intersect the horizontal wire of the telescope, for the rays will appear to proceed from a point not lying in the line ^BE. In order that the image of the slit may be reflected on to the horizontal wire of the telescope by the crystal-face, this face must be turned into such a position that the image of will lie on the line .#2 though it will be at a different point from 2 ; say at 2'. Let KM' be the trace of this plane perpendicular to and bisecting 6*2'. The crystal-face will now lie in some part of this plane, as at If, and will have been turned from its previous position, round an edge perpendicular to the plane of the figure (and there- fore parallel to the axis of the goniometer), through an angle which may be denoted by 0. Let BM and B'M' intersect in R. Then S and 2' will be symmetrical in respect to 'M', and ' Dd 402 The reflection-goniometer. B'R will bisect S^f perpendicularly in M f . From B draw per- pendiculars BN on S2' and BD on B'R. Let M be supposed joined to M' and N. Let .#> = AW= d, SB = r, and SBR = o> ; then 6 = BRD = 2 S2'= MBN. Since the angles at M and A^are right angles, SMNB are points on a circle, and MNM'= MBS o>. Also since -flf and M' bisect S2 and S3', MM' is parallel to 22', and 2JOTjy=#2W =25^252'=: ---a> + 0, 2 and M'MN = -n-MNM'-MM'N = - -0. 2 Also Therefore MM'= sin co COS0 TVTJVT' c' T\,T^\7\/T' Also sin MM' S cos(co 0) Therefore MM'= sin co rS . m m . cos (w 0) Equating these values, we have d rsmO cos ~~ cos (to 0) ' whatever be the value of 0. This angle is however necessarily very small, while, in relation to d, r is always very large ; whence, assuming sin = and cos = i, we have d = r or = - cos co. cos co r T) T~\ It may be observed that, since sin = -^-^ , we have within the assumed degree of approximation, = Error due to imperfect centering. 403 and, substituting this value of 6 in the above expression, we have SB = cos o> whence J5SR = 90, to the same degree of approximation. Hence if d, the distance from the axis of the goniometer of a plane passing through the crystal-face that gives an image of S on the horizontal wire of the telescope, be given, we can find the direction of the plane by drawing a line through S at right angles to S and meeting BM in R, and drawing from R a line RD tangent to the circle described with radius d round B as a centre: the position of the reflecting crystal-face in this plane RD will be determined by the intersection of this plane with the cone S'/r. 381. It will be seen then that the position of a reflecting face as determined by the reflection-goniometer is different according as the plane of the face contains the axis of the instrument or is only parallel to it : and the correction for the error an error of 6 if we estimate the angle and of d if we consider the position of the plane must be treated as positive if it lie on one side of BM, negative if on the opposite side of that plane. If then we are measuring the angle between two faces on a crystal, it is clear (i) that their edge must be parallel to the axis of the instrument, (2) that it should be coincident with this axis. Where however it is not coincident the correction for the errors of angle will be given by = cos cu for the one plane, r Q'= cos co for the other. r And as we can always in practice so centre the crystal as that the axis may fall within the angle formed by the two faces, the correction can be put into the form - cos co ; and this can always be made less than - cos co, where / is the greatest thickness of the crystal ; a fortiori less than - , or the maximum angle which the crystal when placed at B subtends at S. D d 2 404 The reflection-goniometer. And, further, the amount of error will depend on the magnitude of w, becoming smaller in proportion as the directions of the ray from the signal and of the axis of the telescope approach to coincidence with the normal to the reflecting face; and also on the magnitude of r, vanishing when r is infinite and the rays from the signal S become parallel. The latter case, where the rays from -S" are parallel, is a con- dition which can be induced by the use of a collimator ; the illu- minated slit being placed in the geometrical focus of the collimator- lens, and the focus of the telescope adjusted for parallel rays. 382. In the discussion of the adjustments needed for the gonio- meter, the processes employed for detecting and correcting error did not necessarily involve the employment of a mounted crystal : and the method for attaching and properly mounting a crystal remains to be considered. It will have been seen from the result of the theoretical discussion of the last articles that the conditions to be fulfilled are that the edge to be measured should coincide as nearly as may be with the axis of the goniometer, and that the part of that edge selected for measurement should be intersected perpendicularly by the plane of observation. The instrumental means at our disposal for effecting the dif- ferent motions of the crystal are the following, and they belong entirely to the head or moveable apparatus for adjusting and cen-. taring the crystal. (1) Two circular motions cc in planes perpendicular to each other may be imparted to the crystal by reason of its being placed, when mounted, at or near the common centre of two toothed circular arcs worked by tangent screws VV'\ see Fig. 347. The crystal can thus receive a partial rotation, approximately round its own centre, in either or both of two perpendicular planes which are parallel to the axis. (2) Two traversing motions tt' perpendicular to each other and to the axis of the instrument. These are worked by two screws, UU', parallel to the tangent screws that impart the rotatory move- ments, and they operate in the directions of these tangent screws. (3) A motion already alluded to whereby the head can be moved along the cylindrical core A of the goniometer away from or Adjustment of a crystal. 405 towards the disc ; and a means b of clamping the head at any point firmly to the steel core (Figs. 345, 347). (4) A supply of small brass crystal-holders in the form of cubes or flattened prisms, each with a projecting peg fitting into a corresponding socket drilled into the ' head ' in such a manner that the axis of the peg is in the axis of the instrument when the traversing and tangent screws are in their normal position: 17. with the crystal it carries the holder is subject to the motions im- parted by these screws. The forms hh in Fig. 347 are the most useful; the one when a wax cement is the adhesive material employed, the other when the crystal is attached to a platinum wire. The latter is one of the most convenient modes of mounting a small crystal, as then the wire can be screwed firmly to the support and can be bent into any position required for bringing different zones of the crystal into adjustment. When a wire is thus employed 406 The reflection-goniometer. the best cement wherewith to effect the fastening is formed of gelatine and acetic acid, just sufficiently viscous to become hard in the course of two or three hours. Or, as recommended by Klein, gum-arabic thickened with milk-sugar, kept dried and moistened when needed, will answer the purpose. 383. Let it be supposed, as an example, that we have to measure the angles of a zone in which two good reflecting faces P and Q meet in an edge. In the first place, the goniometer itself (Fig. 345) having been adjusted, the apparatus forming the head is brought into the normal position, that namely in which the circular arcs cc worked by the tangent screws are both symmetrically divided by the axis, so that when the crystal-holder is in its place its edges are parallel to the axis ; further, the head is turned round until the traversing screws /'/ are respectively vertical and horizontal, the former being on the upper side and the latter on the side away from the observer. The crystal o is so adjusted on the brass holder A, that the face P is as near as may be parallel to the flat side of the holder, and that the edge to be measured is parallel, to its axis; and care is afterwards taken, when fixing the crystal-holder in its socket, that the flat side is as near as may be horizontal, and therefore perpen- dicular to a definite tangent screw. The head is next clamped to the steel core A in a position in which the crystal can be seen in the micro-telescope T. By means of the traversing screws the edge to be measured is brought as near as possible to the horizontal cross-wire and in focus ; one method of quickly effecting this is as follows: the inner axle is turned until one of the traversing screws is perpendicular to the axis of the telescope, and by means of this screw the edge is brought to the horizontal wire ; the inner axle is then turned until the other traversing screw is perpendicular to the axis of the telescope and the edge is again brought to the horizontal wire in the same way as before : the edge of the crystal is now close to the axis of the goniometer, but is only approximately parallel to it. 384. The inner axle is next turned round until the face P is as nearly as may be in position to reflect light from the signal into the telescope : the face P having been arranged to be approximately Adjustment of a crystal. 407 perpendicular to a definite tangent screw, the requisite position of the head is a constant of the instrument and becomes familiar to the observer. By means of the tangent screw perpendicular to P, the edge to be measured is now brought into parallelism with the horizontal cross-wire, and next into apparent concidence with it by the opposite traversing screw : on turning aside the lens / from the object-glass an image of the signal should now be visible, and its centre may be brought on to the vertical cross-wire by a further rotation of the same tangent screw : the edge will require to be once more brought to the horizontal wire by means of the opposite traversing screw. The inner axle is now turned round until the face Q is seen in the micro-telescope to be illuminated with light from the signal : by a rotation of the second tangent screw the position of Q is altered until the face is at its brightest, the lens / is again turned away from the object-glass, and the centre of the image of the signal then visible is brought on to the vertical cross- wire by means of the same tangent screw, and the edge as seen in the micro- telescope is again brought to the horizontal wire by means of the opposite traversing screw. Since, in the preliminary arrangement of the crystal, the face P was made approximately parallel to the plane of the circular motion produced by the second tangent screw, the adjustment of the face Q by means of this screw will little affect the direction of the face P. 385. These operations must be repeated until, when the gonio- meter disc makes a complete rotation (i) the crystal is seen to turn round the edge as if hinged on the horizontal wire, and (2) the images of the signal reflected from the faces P and Q, and indeed from all faces of the zone, pass in succession through the field of view symmetrically to the vertical wire, and are ortho-symmetrically divided by the two wires when at the centre of the field. The nearer the angle between the faces P and Q approaches to a right angle, the more quickly is the accurate adjustment of the zone arrived at : for, by the preliminary arrangement of the crystal, the face Q will in such cases become more nearly parallel to a tangent screw, and thus be less affected by the adjustment of the other face. 386. The chief advantages of an instrument of the above con- 408 The reflection-goniometer struction over one with a horizontal disc are the following : (i) the graduation being on the edge of the disc is more easily read ; (2) owing to the inclined position of the telescope the work is less fatiguing to the observer ; (3) the crystal, the traversing and adjust- ment screws on the head, and the milled heads of the axles are all more easily accessible than when they are above or beneath the instrument ; (4) the sliding of the hollow cylinder which carries the 'head' renders the adjustment more easy and speedy; (5) the correctness of adjustment of the goniometer itself is easily verified or restored. On the other hand, a goniometer with a horizontal disc can be used for the measurement of larger crystals, and the adjust- ment of the crystal is less liable to disturbance, through the yielding of the wax support during the measurement : also the motion of the telescope renders it possible to alter, when desirable, the angle of incidence of the light upon the reflecting faces; further, the instru- ment can be used for the determination of indices of refraction. 387. In the vertical goniometer (Fig. 348) the ' head ' is fixed to a hollow cylinder which can be clamped to a solid core continuous with the inner axle, but in the horizontal goniometer such an arrangement is impracticable : in the latter instrument the head is fixed to a solid steel cylinder which passes concentrically through the inner axle, and is terminated by a screw : it can be raised or lowered by the rotation of a milled head through which this screw passes. When the crystal has been, brought to the height of the horizontal cross-wire, the cylinder is clamped to the inner axle by tightening a collar situated just above the graduated disc. During the measure- ment of a zone, the inner and outer axles are fixed together by the pressure of a screw. A slow motion of the graduated circle can be produced by an ordinary tangent screw. Finally, the telescope and also the verniers of the graduated circle are fixed to another concentric hollow axle, external to the other two ; this moves in a hollow cone fixed to the three legs of the instrument : hence, if the graduated circle be clamped to the tripod, the angle of rotation of the telescope can be measured : the telescope can be fixed in any of its positions and is provided with a tangent screw for slow motions. The collimator is fixed to the tripod. with vertical axis. 409 Corresponding parts of the vertical and horizontal goniometers (Figs. 345 and 348) are indicated by identical letters. Fig. 348. 388. In the horizontal goniometer, as made by Fuess, the tele- scope, instead of being capable of adjustment, is screwed fast to its carrier : the instrument is so carefully constructed that adjust- ment can be made precise by a simple motion of the cross-wires, and is therefore less easily disturbed. The process of adjustment of the instrument, recommended by Websky, is the following : (1) One of the eyepieces having been adjusted so that its cross-wires are distinctly visible, is inserted in the tube of the telescope until a distant object is in focus. (2) A needle is adjusted in the axis of the instrument, and the eyepiece is turned round until one of its cross-wires is as near as may be parallel to the needle, as seen in the micro-telescope : the cross-wires are then moved horizontally until this wire is in apparent coincidence with the axis of the needle. 4i o The reflection-goniometer. (3) A plate of ' parallel glass ' is adjusted in approximate parallelism to the axis of the goniometer, and the axle is rotated until the plate is as near as may be perpendicular to the axis of the telescope. (4) A small plate of glass is now fastened in front of the eyepiece at an inclination of about 45 to the axis of the telescope: a lamp having been so placed that light is reflected from this plate into the telescope, the cross-wires of the eyepiece are seen both directly by dispersed light and by reflection from the parallel glass : if the latter be adjusted by means of the circular motions so that the images of the cross-wires, due to reflection from opposite sides of the parallel glass, take in turn exactly the same position in the field, the plate will be exactly parallel to the axis of the goniometer. By raising or lowering the cross-wires their centre may be brought into coincidence with its image as seen after reflection : the axis of the telescope is then exactly normal to the plate and therefore to the axis of the instrument. (5) When the outer-axle is rotated, the image of the intersec- tion of the cross-wires will move across the field in a direction exactly perpendicular to the axis of the goniometer : if this direction be inclined to the * horizontal ' wire, the eyepiece must be turned until parallelism is produced : coincidence may be obtained by a vertical translation of the cross-wires. The ' hori- zontal ' wire and the axis of the telescope are now exactly normal to the axis of the goniometer. The glass plate in front of the eyepiece is now removed. (6) Four tubes with signals are generally supplied with the instrument; the signals being respectively, a cross-wire, a small circular hole, a straight-edge slit, and a Websky's slit. The second of these is first inserted in the collimator : the telescope is then turned until the image is seen either directly or after reflec- tion from the parallel glass : the signal is - moved about in the tube of the collimator until the image is in focus : the screws which fasten the pillar of the collimator to the tripod are adjusted so that the centre of the image is seen on the horizontal cross-wire. The straight-edge slit and the Websky's slit are next focussed. Finally, the cross-wire signal is inserted and focussed, and then by means Error due to imperfect adjustment. 4 1 1 of their traversing screws the cross-wires of the collimator are brought into apparent coincidence with those of the telescope. The remaining eyepieces of different magnifying powers are now adjusted by means of the cross-wire signal : in fact, the chief use of the latter is for the verification of the adjustment, since few crystals present faces so perfect as to give images of such a signal. All the eyepieces and signals are provided with sliding collars with a projecting piece which fits into a corresponding notch in the collar of the tube of the telescope or collimator : if this collar be tightened when the tube is in its final position, the eyepiece or signal may be taken away and afterwards replaced in exact adjustment without necessitating the removal of an adjusted crystal. In performing the actual measurements of the successive angles between the faces of a zone, each edge has to be separately adjusted by means of the traversing screws; unless the crystal is very minute' in its dimensions, in which case the crystal, after one of the edges of the zone has been adjusted, may be brought by the traversing screws into a position in which the zone to be measured is seen always symmetrical to the horizontal wire. In this case the resulting error is too minute to be estimated. If the edge itself cannot be seen, from injury or other cause, the centering may be effected by making the profile of each face coincide with the cross-wire parallel to the axis of the goniometer. 389. Error of adjustment. It has been seen that, if A and B be two faces of a zone, their edge will be seen in the field of the micro-telescope to be precisely parallel to the horizontal wire, and can be brought into apparent contact with it when the zone is correctly adjusted ; and the images of the signal reflected from the two faces will each be seen in the telescope to pass over the field of view symmetrically to the vertical wire, and to be ortho-symmetrically divided by both wires when the centre of the image has reached the horizontal wire. Neither of these statements holds good when the axis of the zone \AE\ is not strictly parallel to the axis of the goniometer. Let the angle of inclination of the zone-axis to the axis of the goniometer be a ; and if the face A be adjusted so that the image reflected from A has its centre at the crossing of the wires in the 412 The reflection-goniometer. telescope, let 8 be the distance from this crossing of the centre of the image reflected from B when moved through the field till it is in contact with the horizontal wire. The value of 8 in any particular case can be determined by finding out the angle which a responding distance on the vertical wire represents when an image from a correctly adjusted crystal-face traverses that distance ; i.e. finding the difference of the two readings on the goniometer when the image is central and when its centre is on the vertical wire at the distance 6 from the crossing ; b is twice this difference. Let T, Fig. 349, be the projection of the telescope-axis perpen- dicularly to the plane of the figure, ZJ'the axis of the goni- ometer, ST the direction of the axis of the collimator, or of the ray from the centre of the signal which intersects the goniome- ter-axis in the plane of observa- tion. For simplicity, let the axis of the telescope be assumed to be perpendicular to ST; hence Z, T, and -S 1 may be three J'ig- 349- points on a sphere separated by quadrants. If now A and B are in correct adjustment, and the letters A v B l , &c. in the figure represent the projections on this sphere of the poles of the planes in question, it is evident that for the image reflected from the first face A to be central we must have And similarly for jB lt since the pole of B must be at the point A 1 when the image from it is central, if the zone be in correct ad- justment. Where however the zone-axis is inclined to the gonio- meter-axis at an angle a, let P 1 be the pole of B when the centre of the image from A is on the horizontal wire. Let the angle of the edge \AB\ be y ; then, since the angle between the zone-circles A l S and A l P l will be the same angle a as Error diie to imperfect adjustment. 413 that of the inclination of their zone-axes, and A 1 JB 1 = A 1 P 1 = y, if the position of the pole A 1 is given anywhere on the great circle ST the corresponding position of PI can be determined. When the image from A is on the horizontal wire the pole of A is at A l and the pole of B at P lf and when the image from B is at T' on the horizontal wire the pole of B is at P 2 . Then we have P 2 S = P 2 T'= 45 and TT- 8. And if the great circles -LP l and LP^ intersect ST'mp^ and/> 2 , LP 1 = LP,, and sin P 2 p 2 = sin P 1 p 1 = smA l P l sin P l A l p l = sin y sin a ; also sin P 2 p z = sin SP Z sin P 2 Sp 2 sin 8 = sin 45 sin o = ; V 2 sin 8 , , whence sin a = ......................... (1) V2 sin y The angle, as measured on the instrument, between A and B w ill be __ AS, __ yi A A A further we have tan p 1 A l = tan P 1 A l cos ^ ^j^ = tan y cos a, tan p 2 S = tan P 2 6" cos P z Sp 2 = cos 8. Let E be the error in the measurement of the angle, i.e. the true angle the measured angle ; then tany tan^, p. tany(i cos a) Now tan (y A. A) = \ l = ^-5- i + tany tauA l p l i+tan 2 ycosa . a tan y sin 2 - i + tan" y cos a i cos 8 8 and tan (45 Sp 2 ) = - - = tan--, i + cos 8 2 a and 8 are small quantities and their cubes may be neglected; then a 2 T tany a 2 tan (y A l pj = = sin 2 y, 414 The re/lection-goniometer. The product of these two tangents will thus be of the fourth order, and may be neglected. a 2 8 2 = sin 2 y H 5 4 4 or to the same degree of approximation, _ a 2 sin 2 y + 6 2 4 From (1) sin 2 8 = 2 sin 2 y sin 2 a, and 8 2 = 2 a 2 sin 2 y. 2 a 2 sin y cos y + 2 a 2 sin 2 y Whence E = a 7= sinysin(y + 45), ................ (2) V2 -v/2 sin y jg 1 , a, and 8 are in circular measure, and if E^ a lt ^ be the corre- sponding angles in degrees, we shall have 2 EI = ifo 5" sin y sin ( y + 45 ) ^ = * V_sin(y+45). 1 1 80 2 Jr+cos 2 />F+cos 2 />Z-cos 2 cos 2 PX- cos 2 77 cos 2 P Y- cos 2 C cos 2 /"Z - 2 (cos cos P Y cos />Z + cos 77 cos />Z cos PX + cos C cos PX cos P F) an expression which is symmetrical in respect to PX, PY : PZ, and also to f, r?, . 395. To express cos PX, cos PY, and cos PZ in terms of h, /, I, From the general equations b PV c ~ ~k cos ~ 7 we have h k I a b c Substituting these values in (ii) we get, to determine /, i cos 2 f cos 2 77 cos 2 + 2 cos f cos 17 cos f i 2 T] H ^ sin 2 f 2 - (cos f cos r] cos f ) 2 (COST/ cos f cos f ) 2 (cos f cos f COST?) >; (iii) whence, if /$, ^, /, f , TJ, f, fl, 3, <: be given, / is known, and there- fore also cosPX, cosPF, cosPZ. If A, B, C, Fig. 351, be the poles of the axial planes YZ, ZX, XY, and therefore ABC, XYZ be polar triangles, we have, if BC, CA, AB be a, /3, y, respectively, a = TT JY", /3 = TTY, y = irZ, ACT) /"* /* -4 = 7T , JD = 7T ?/, C = 77 (,. E 6 2 420 Crystallographic calculation. cos X + cos Y cos Z Since cos f = - : ^r^ ^ sin J^ sm Z i - cos 2 J - cos 2 Y cos 2 Z- 2 cos .Y cos .F cos Z sm * = - o T ^ ;~T ^ sm 2 Y sin" Z Let 4 A' 2 = i cos 2 X cos 2 Y cos 2 Z 2 cos X cos .F cos Z, = i cos 2 a cos 2 /3 cos 2 y + 2 cos a cos/3 cosy; then f- 2N 2N ~ sin J^sin Z ~" sin /3 sin y 2 TV 2 A" Similarly, sin 17 = -^ , sin f = - sin y sin a X Fig. 351. Fig- 35 2 - 4 A 72 cos a Also cos cos -T] cos = sm 77 sm cos A = r^- sin 2 a sin (3 sin y and other expressions symmetrical therewith. Substituting in (iii) we get ., _ T cos 2 A cos 2 B cos 2 C 2 cos ^4 cos ^ cos C ~~ a 2 sin 2 /3 sin 2 y be sin 2 a sin sin y _ (r cosM cos 2 ^ cos 2 C 2cos^4 cos,5'cosC)sin 2 asin 2 ^sin 2 y _ ,. !ffi 2 kl i 2 sin 2 ^ + 2 cos a sin /3 sin y > a* be } where the series indicated by 2 sin 2 # is / 2 -fiin z fl4- 3 2 sin 2 a + sin 2 /3 + sin 2 y ; General problems. 421 2kl and that by 2 -= cos a sin /3 sin y is 2kl 2lk 2kk -= cos a sin /3 sin y -\ cos /3 sm y sin a H cos y sin a sin (3. be ca ab But ! _ CO sM cos 2 ^ cos 2 C 2 cos^t cos -5 cos C = sin 2 a sin 2 ^ sin 2 C ; and since 4 ^ 2 4 ^ 2 siir/? = 5 and sin-C = . sm 2 y sm- a sm- a sin 2 /3 4^V 2 we have /> = r- 2 TJ 2 sin 2 a + 2 cosa sin/3 siny a 2 be Substituting in the original expression, we have -" Vs^i kl . _ . i cos a sm p sm y / _ 4^; * V 2 ^ sin2a + 2 ^ " 1 cos a sin /3 sin y /Z . o -2KL . . -5 sm^ a + 2/ - cos a sm p sin y a" 1 be ) 396. In the second problem we have to find the angle between any two normals of a crystal in terms of the parameters, the normal-angles of the axial planes, and the indices of the two faces. If P (h k /) and P' (Ji k' I') be two poles, the axial points being as before X, Y, Z (Fig. 352) ; then XPY= XPP f - and cos XPY = cos XPP' cos P f Pr+ sin XPP f sin P'PY. . . ( vi) cos C cos PX cos PY But also cos*/^: , mPXsinPr ' ........ (-) In the triangles XPP', YP*P, cosP'X-cosPXcosPP' COS XPP = - - ; - . - - - 5 422 Crystallographic calculation. V sin 2 PX sin 2 PP' - (cos P f X - cos PX cos PPJ = - - : nv , ^-^ sm PX sin PP cosP'r-cosPrcosPP* COS YPP = - : - ptr . - 5^7 -- > smPFsmPP 2 TV"- (cos P'Y- cos P.F sin PY sin /Y* By substituting these values and that in equation (vii) in equa tion (vi), we obtain a quadratic equation in cos PP', the co- efficients of which are the cosines and squares of the cosines of PX, PY, P'X, P'Y and f . This equation may be solved in the ordinary way : the solution, however, is more readily arrived at by performing operations identical with the above for the triangles XPZ, XP'Z, whereby a second quadratic equation in cos PP f is obtained, having for coefficients the cosines and squares of cosines of PX, PZ, P'X, P'Z and r? ; from the two quadratics the term cos 2 PP f may be eliminated, and there will remain a simple equa- tion giving cos PP' in terms of the cosines and squares of cosines of PX, PY, PZ, P'X, P'Y, FZ, p g sin/3 siny " v y tan a / 2 fcsin a V7,7 fl / VA/2 ^sina o2/-7 x a tana ^ 0sin/3siny tana'\ in which v fc-sina , fcsina ( AJ/ a sin j8 siny f a sin /3 ,,, <^3 sin y 2/ nn ; - ; fin a sm p sin y v^ 2 ^sina __^ 2 ^ sin p sin y ^r sin a _i_ ^-2 <5 sin y sin a <: sin a sin <:# sin (B ^ n ab sin y - ) a sin (3 sin y fcsin* ^ sin /3 sin y <5 - 1 Z>'2 sin y sin a ^ sin a sin /3 ' r# sin ^3 7/ <2(5 sin y - +/ = ; g sin /3 sin y ^ sin /3 sin y tan a tan a tan /3 tan y tan a tan a tan /3 tan y The equation may also be put into the form ^hh' sin 2 f- 2 (&T + /^) a (cos - cos TJ cos C) cos^= ^ - ^^^^ - , Ox.) in which S=?.tf sin 2 22 Ida (cos -cos 17 cos Q y = 2^ 2 sin 2 -22 If I a (cos - cos ij cos Q- 397. The equations (ix) or (ix a] represent in the most general form, though not a form directly adapted for logarithmic com- putation, the arc-distance of any two poles whatever of a crystal ; and in the most general case, that namely of the Anorthic system, in order to determine the five elements of a crystal there are required five such equations connecting the elements with the indices of the faces between the poles of which five independent arc-distances have been measured, the symbols of the faces being of course supposed to be known. 424 Crystallographic calculation. The use of spherical trigonometry, however, combined with the application of the rules of zones and the methods that will be presented in the discussion of the various systems, render the problem of finding the elements of an anorthic crystal less laborious than it would be if the only method adopted were that of dealing with a series of such equations. Where however the data obtained by the goniometer are not sufficiently exact, and the determination of the elements from these data with the closest attainable precision has to be sought in the employment of the method of least squares, the application of the equation (ix) to the determination of a large series of angles will be found the most direct, since, in the form in which it is here given, the aid of logarithms in determining the recurring constants can be advantageously brought into the calculations of these angles. For other systems than the Anorthic the general equation (ix) assumes forms which become simpler in proportion as the arcs a, /3, y become two or three of them quadrants, and as the para- metral ratios become reduced to a single ratio or to equality. Thus, in the Mono-symmetric system, where the arcs a and y are quadrants and the arc (3 is the arc-distance A C of the poles 100, ooi, the equation is +(hl'+ lh'} b cos/3 + &c. where the expression under the second square root is identical with that under the first, but with h'k't substituted for hkl. In the Ortho-rhombic system the equation becomes ''V + ^ 2 7 +//2 7 and in the Tetragonal and Cubic systems the expression for cosPP' General problems. 425 becomes further simplified as a, &, and c are two of them or are all three of them equal. 398. It is often necessary in crystallographic problems to assign symbols to particular faces of a crystal the relative positions of which have been already determined by measurement and projection, and to proceed to deal with the remaining faces or with the determination of the crystallographic elements by methods which involve the symbols and positions established for these particular faces. For this purpose certain definitions and pro- positions are of general application, and receive special forms in the different systems. 399. A pole will be spoken of as being given in position when its arc-distance from a certain given pole has been ascer- tained, together with the angle contained by two zone-circles, of which one traverses the two poles and the other passes through the given pole, but is only known in symbol; and where this angle is not a right angle it may always be taken as the acute angle in which the zones meet, care being had as to the positive or negative character of the angles as ascertained for different faces referred to a common face and zone; positive angles being always measured in one direction from the zone of reference. In discussing each system methods will be sought for finding the symbol of a face the pole of which is given in position in regard to some deter- mined pole and zone -circle of the crystal. The following propositions will therefore deal with the general methods Fig. 353. for determining the position of a pole or poles : the elements of the crystal are in each case supposed to have been previously determined. I. Given the elements of a crystal and the symbols of two of its poles R and S; given, further, the symbols of two poles P and P' : it is required to find the magnitude of the arc PP'. Instead of calculating PP f directly by means of equation (ix), it 426 Crystallographic calculation. will often be more convenient to calculate, by means of that equa- tion or otherwise, the magnitudes of RP, PS, SR, RP', P'S, Fi g- 353 and thence to deduce the angles PRS, P'XS, and the arc Pf by means of spherical trigonometry. In any system but the Anorthic a pole can be found to represent R, which is also the pole of a zone-circle identical with it in the indices of its symbol. The zone-circle [/'/''] will in such case intersect this zone-circle say in a pole Q so that, taking R and \RQ\ as the pole and zone-circle of reference for deter- mining the positions of P and P f 1 the arcs PQ and P' Q are each a side of a triangle, of which another side RQ is a quadrant, and the arc PP f is the sum or the difference of these two arcs. II. T and T' being two poles of which the symbols are known, R, \RS~\ being respectively a pole and zone given in symbols and position; let P be a pole of which the position relative to W the pole R and the zone \RS\ is to be determined, the arcs PT and PT' being the data as regards P. Here (Fig. 354) RT, SRT t RT', SRT' t and TT f are to be de- termined from the symbols of T and T f , and the known elements of the crystal by means of equation (ix) or otherwise, and by spherical trigonometry RTF, RT'T, PTT', PT'T, and so RTP can be computed, and therefore also the arc RP and the angle TRP in the triangle RPT. Hence SRP and the arc RP which give the position of P are known. Anorthic system. 427 The symbol of P can now be determined by the methods special to the system. III. Let T be a pole of which the symbol is known, and let the arc-distance of T from a pole P be given : the symbol of [uvw] a zone traversing P is given, R and RW being given as the pole and zone of reference. The position of P is required with a view to the determination of its symbol. Let [uvw] intersect the zone-circles [RT] in Q and \RW} in (Fig. 355). The symbols of Q, R, S and T 7 being known, the arcs RS, RQ, QT&nd TS can be found from equation (ix), and then the angles SRT and RQS or PQT can be calculated by spherical trigonometry. In the triangle PQT the arcs PT, TQ and the angle PQT being known, the angle QTP or RTP can be calculated: and finally, from the arcs RT, TP and the angle RTP of the triangle RTP, the arc RP and the angle PRT czn be found. The position of P being thus established in reference to R and [R W\ its symbol may be determined by the methods special to the system. SECTION III. Crystallographic Calculation. The Oblique Systems. I. The Anorthic System. 400. In the Anorthic system the five axial elements have to be determined irrespectively of symmetry, for the only symmetry in a crystal belonging to this system is that to a centre. A, B, C, Fig. 356, being the positive poles of the axial planes YZ, ZX, XY } their symbols are 100, oio, ooi, respectively; and the arcs a, /3, y, or BC, CA, AB, form a triangle polar to that formed by the arcs f, rj, f, or YZ, ZX, XY, traversing the axial points X, Y and Z, arcs which measure the axial angles of the crystal. Thus the angle A = i8o- B = i8o-Tf, C = i8o-C; (i) and for the sides of the triangles XYZ and ABC we have, from spherical trigonometry, 428 Crystallographic calculation. cot f /sin(S- - = A / -- ^ o 2 V sin o o /o \ in o sin (6 a) ?] /sin ( y) sin (S a) 2 = V sinSsin(S-/3) where and C / sin (S- a) sin (S- 13) COt = A / - ; - p; : 77^ 2 V sin o sin (o a _ /sin ( 2 "" A/ ' si y) 2 -77) sin (2-C) sin 2 sin (2 fl /sin (2-Q sin (S COL = A / ; ^ : 7^ 2 V sm-lsin(2/ i,) cot- = where 401. Let P, Fig. 356, be the pole of hkl, and let the zone- circles [AP] t [JBP], [CP] intersect [JBC], [CA], [AJB] in the Fig. 356. poles H, K, L. Then H is o k /, ^T is ^ o /, and Z is ^ /^ o, and from the fundamental equation, -r T _ - TT r cos LY - cos LX, k n cos XX = cos JCZ. Anorthic system. 429 Further, from the triangles HAY, HAZ, since AY = AZ = - = CY = CAY = BZ = BAZ, 2 we have cos HY = sin HA cos HAY = sin HA sin JZ4 C, cos HZ = sin JK4 cos HAZ = sin Zf,4 sin HAB ; and by substitution from these and similar expressions in the preceding equations, b I _ sin HAB < c h _s\nKBC ^ a k _ sinLCA 7~k~ smHAC' ~a 1 ~~ sin A"A4 ' ^"sirTZOZT ^ m For logarithmic computation these expressions may be put into the form tan (HAB- \ CAB] = tan | CAB tan (45- 0), ^ tan - (ivfl) al b h - - ? tan \1/ = - - ; c h a k' or also into the equivalent form c k a I b h where tan Q - - , tan d> = - - > tan \lc = - T ; ^ / c h a k' The arcs HB, KC, LA can now be readily determined. For H t for instance, we know the angles NBA and HAB and the arc AB] and similarly for KC and LA. 402. From the six triangles into which the triangle ABC is divided by the arcs APff, BPK, CPL, we obtain the equations sin AB sin BAP = sin BH sin BHP, sin C^4 sin CAP sin C# sin CHP, sinC sin C^P = sin CK sin C^P, sin^4^P = sin^f^ smAKP, smACP = s'mAL smALP, smBCP sin^Z sin^ZP; where , smALP=sinLP. 430 Crystallographic calculation. Hence, from equations (iii), sin AB sin CH sin CAP c k b /' sin AB sin CK sin CA sin #Z sn sin BCP sin sin (v) Fig- 357- and smIfsmCJsmAL = s'mCH sinAK smL; .. .. (vi) an equation which is true for every point P of the sphere, and is there- fore true for every pole P of the crystal. If any five of the arcs it involves are given, the sixth is known. 403. Let O be the parametral face in, and the poles correspond- ing to H, K, L be D, E, F- } so that (Fig. 357), D is on, Z'is 101, and Fis no. The axial angles may be obtained in terms of the arcs AB,BC, CA by means of equations (iio;), and the parametral ratios in terms of the arcs AB, BC, CA, and of the segments of these arcs as formed by the poles D, Z, F, by means of equations (v). Thus a _ sin BC smAF _ smACO , 6 ~ sin CA sin BF ~~ sin BCO b sin CA sin BD sin c sin AB sin CD c _ sin AB sin CE a ~ The segmental arcs AF, FB, BD, DC, CE, EA may thus be taken as the arc-elements of the crystal, any five of them serving to give the five axial elements, independently of the sixth segment. 404. If the two segments of one of the three arcs a, /3, y are unknown, and the other four segments are given, the two unknown sin CBO Anorthic system. 431 segments can be readily found; for, from (vi), if the segments of AB and CA are given, sin BH sin AK sin BL sin CH ~ sin CK sin AL which may be written as whence = tan i ,(7 tan (4 5 -0); an equation which gives CH, and therefore BH, since BC is known. 405. The position of a pole H or (ok I), K or (hot], L or (hko) in a zone containing two of the poles A, B, C is determinable by the equations (v), supposing the elements of the crystal and the symbol of the pole to be given. And if the position of a pole on one of these zone-circles is known, the same equations give the symbol of the pole. When the elements of a crystal are given, and it is required to determine the position of a pole P of known symbol not lying on one of the arcs a, /3, y, instead of making use of the general equation (ix) of Art. 396 it will usually be more convenient to project the great circles APH, BPK, CPL, and find the arc-distances from P of the poles A, B, C, and the angles which the zone-circles PA, PB, PC make with the arcs a, /3, y. These values are in fact deducible by spherical trigonometry from any two of the angles PAB, PBC, PC A, or any two of the arcs PA, PB, PC, or from one of the angles together with the corresponding arc ; so that if any pair of these data be given, the position of the pole is determined : but the equations (iv<5), and the values assigned in them to tan 0, tan (/>, and tan a//-, enable us to determine the angles PAB, PBC, PCA at once from the symbol of the pole. Hence when this symbol can be assigned in consequence of the known distances of the pole from each of three other poles of known symbols in one zone-circle, or from other data, the position of the pole in question relative to the poles A, B, C can be found by any two of the equations 432 Crystallographic calculation. (iv). The inverse problem of finding the symbol of a pole given in position, the elements of the crystal being known, differs from the last in that here the position of the pole may be given in reference to some two poles or to a pole and zone of the crystal not belonging to the elementary triangle ABC, though known themselves in position relatively to the sides and angles of that triangle. This in fact is the problem for finding the position of a pole in respect to a given pole and zone-circle which has already been considered in Article 399. Taking in place of the pole R and zone of reference [^S'], in Article 399, a pole and a side of the elementary triangle, for instance C and [^C*]; and, in place of T and T', or T and [uv w], taking the poles or pole and zone to which the position of P has been referred, we have to proceed, as in that article, to find the position of P in respect to all the poles and zone- circles of the elementary triangle. And the symbol of P can then be calculated by means of equations (v). 406. To find the arc-distance of two poles with known symbols, the elements of the crystal being given. Instead of calculating the arc-distance by help of the general equation (ix) of Art. 396, we may pro- ceed thus : The poles P and P' can be severally determined in position in regard to a pole and adjoining side of the elementary triangle, by equations (iv#). Thus, for instance, PAC and ^^C as well as PA and P'A being known, the arc PP f is found by spherical trigo- nometry. Or, also, Fig. 358, [-W] intersects the zone-circles a, /3, y in poles S, T, U to which the symbols can be assigned. The arcs SC, S3, TA, TC, UB, UA can be computed by equations (v) : Anorthic system. 433 and the arcs ST'and TU from any two of the triangles STC, TA U, SBU. We have then two groups of four tautozonal faces UTPS and UTP'S from which the arcs UP, UP' and therefore PP r can be determined : see also Art. 408. 407. In the previous articles the position of a pole has been determined relatively to a pole and side of the elemental triangle, the elements of the crystal being given. The problem however of determining the position of a pole when its symbol is given, or of finding its symbol when its posi- tion is given relatively to four other known poles, may be put into a completely general form. Let U, V, PFand T(Fig. 359) be four heterozonal poles, the sym- bols of the zones [VW], [WU], wj Fig. 359- \UV\ being [u^wj, [u 2 v 2 wj, [u 3 v 3 w 3 ] severally, and (efg) being the symbol of T. Then, by spherical trigonometry, if five of the six arcs joining the four poles are given, the sixth can be found, as well as the angles at U, V, W and the angles which [777], [TV}, [TW] make with the arcs joining U Fand W. Let P be a fifth pole with the symbol (hkl). Then, if ~ sm(VUT-VUW) ' sin UVT sm(UVT-UVW)' we have, by articles 48 and 51, \an(VUP-\VUW) = tan J whence the angles which \PU"\ and [PV] make with [^7K], and so the arcs PU and PV, and if needed PW } can be found, and the position of P in respect to any pole and adjacent arc of the triangle UVWis determined. 408. If P' or tik't be a sixth pole of the system, it can also be found in position by an identical method ; and the arc-distance Ff 434 Crystallographic calculation. PP' between two poles of known symbol can then be directly found by the methods of spherical trigonometry. 409. The symbol of a pole P can be found if its arc-distances from four poles of given positions and symbols are known. For if [UT] and [ VT], and \UP] and [ VP] (Fig. 360), intersect the zone- circles [VW] and [UW] in poles R, R', Q, and Q respectively, the positions of these poles on UW and VW can be determined by spherical trigonometry, and there- with the symbols of Q and (X, since the anharmonic ratios of \U Q' R' W] and [VQR W] are then known: the symbol of P, in which the zones [UQ] and [VQ'] of known symbols are tautohedral, is then straightway deduced. 41O. To determine the elements. Since in the Anorthic system the elements of a crystal are five in- dependent quantities, the requisite data for determining them are five measured angles between poles of which the symbols are known but of which none are deducible from the rest. For this purpose therefore three poles forming the angles of a spherical triangle, together with a fourth pole heterozonal to them, and therefore not on a great circle containing a side of the triangle, are available ; since five out of the six angles they form are quite independent : or, the three poles forming the angles and two other poles each lying on a great circle containing a different side of the triangle may be employed, the arcs joining all the five poles being known. If however the faces thus to be employed are initially to have known symbols, it will need a preliminary investigation of the crystal with a view to selecting faces to which it may be possible to assign such symbols, and of which some at least may be employed in determining the axial system, either by taking the axial planes parallel to them or by treating them as parametral faces. For such a selection, the measurement and projection of the zones containing the faces which are the most prominent or Anorthic system. 435 which give the best images, will be undertaken first: and, after independent symbols have been assigned to certain of the faces, it is generally possible, by the rules of zones and of the tauto- hedral law, or by the application of the problem of four planes, to determine the symbols for other faces of which the poles are projected. Usually this assignment of symbols leads directly to the determination of certain arc-elements for the crystal. But sometimes it is not possible to assign at once the poles most suitable for the elementary triangle, or those which offer the best data for determining the elements ; in which case these elementary planes have, in the first place, to be, as it were, tentatively selected and, even then perhaps only approximately, determined. Never- theless, when they have been so determined, the symbols assigned by inspection and the application of the zone-laws to the different poles of the crystal, or calculated for them by aid of the provisional elements, will generally have validity; and ultimately, if a different axial system be adopted, the application of the formulae for the transformation of all or of part of the elements of an axial system will readily convert the symbols of these faces to the new symbols representing them in the transformed system. If however the elementary triangle and the arc-elements cannot all, or some of them, be thus directly determined, they may be deduced from a series of measurements between faces heterozonal to the elementary triangle, to which the symbols have been tentatively assigned consistently with the zone-laws. It is how- ever a case of most improbable occurrence that no one of the zones a, /3, y, and at the same time no one of the poles A, JB, C, can be identified with zones or faces determinable by the goniometer. The simplest method to be followed in such case is that indicated in Articles 407-8, the expressions in which are inde- pendent of the elements of the crystal. Thus, where five of the six arcs joining the four poles U, V, W, T having known symbols are given by measurement, but none of these poles are identified with A, B or C, the arc AC between the two poles A, C having the known symbols 100, ooi can be calculated ; and so on, for the remaining arc-elements. Usually however V t or U and F, can be taken to represent one or two Ff 2 436 Crystallographic calculation. of the poles A, B, C, and not unfrequently also one of the quasi- octahedral parametral forms can be represented by one of the remaining poles in the figure : and the process for determining the elements is proportionately simplified. The Oblique Systems. II. The Mono-symmetric System. 411. In this system, the normal of the plane of symmetry is taken for the axis Y. The axial points Z and X lie, as do the poles C, ooi, and A, 100, of the axial planes XY and YZ, in the plane of symmetry ZX, while the pole B, or oio, of that plane lies on the axis Y', so that in trigonometrical problems recourse can frequently be had to quad- rantal and right-angled triangles. The normal -angle AC, i.e. (100.001), or /3, is the supple- ment of the axial angle 17, and AZ = CX = 90. To determine the position on the sphere of a pole P or hkl, we have from the quadrantal triangles PBZ and PBX (Fig. Fig. 361. X cos PZ = sin BP cos PBZ = sin BP sin PBA, cos PX = sin BP cos PBX sin BP sin (A C-PBA ), ^cosPZ; 7 But - cos PX = - cos PY - k k I whence - sin (PBA and : - sin Jr^oA a I Let be the pole of in and let zone-circles through BO Mono-symmetric system. 437 and BP meet the zone-circle [AC] in E and K respectively. Then E is 101, K is h o /, OB A = AE, arid PBA = AK. For 0, sin (r? -M^) = sin (i8o-^C) = sin EC, and for P, s'm^ + AK) = sin(i8o-^C) = sin^C, and equation (i) becomes for O, a sin^C = I cot OB = c sin ^, \ forP - iuKC-- oiPB-- ' AK\ ^ h sin AE sin ^fC ^ sin yl^' tan -50 whence - = -^ = - - -^ and - = - The arcs EC, AE, OB are parametral, and may be employed as the arc-elements of the crystal in place of the axial elements a c yj T' and T). o o 412. If then tan (PBA + J r/) = tan J ry tan (135-^), and T y sin/^^c = T ysin.r^'^, ^..x ^ <5 / f- .. (m) cot J From the triangles PBA, PBC, cos PA = sinPB cos PBA = sinPB cosAK, ^ . cos PC = sinPB cos PBC = smPB cosKC, i .. ..(iv) = sin PB cos (AK-}- 77). ) 413. The position of a pole K of a hemidome {hol\ is given on the zone-circle [oio] by equations (iii). PB is a quadrant since P coincides with K, h c where tan = - - ; / a 438 Crystallographic calculation. or, where AK is known, the symbol is given by the expression from (ii), h a sinJfC s'mA-E sin / c sin AK sin EC sin AK 414. For a face L of the prism [hko], P in the foregoing formulae becomes Z and PBA vanishes, while k a , k cot OB . and cot LB - - sin A C - - =^ sin ^4 C, h b h s cosZC = sinZ.Z? Also, if/ 7 is the pole of the parametral face no, a h tan AL tan AF b ~~k sin A C h a s'mAC k ~~ b tan AL t&nAL 415. For a face H of an ortho-dome {okl}, BH+HC 90, ^ . cotHB = -smAC= - I b I smAJ? cos HA = sin Z^5 cos A C, . ., _ and T = j- ^ , if D is on; b also we have k _b cotBH _ I c sin^4C / _ tan CD 416. The poles of a form \hkl\ are symmetrical in pairs, where the signs of their k indices are the same, to the axis [oio], and where the signs of their h and / indices are the same, to the systematic plane (oio). Hence if the symbol of P be h k I, the angle between the faces and the angle between the faces hkl.hkl = Mono-symmetric system. 439 The equations ( iii ) may be written h sin EC I sin AE tan B0~~k (v) where A K and KC are obtained as in Article 413 ; the arcs PA and PC being given by equation (iv). 417. If P' or h f K I' be a pole in a zone passing through (oio) and P or (hkt), we have by equating values for cot BP and cot BP', from the third equation in (iii), h k' _ k' I ^ ~h' ~k ~~ I?' from which, P being given in position, the position of P' can be found if its symbol is known, or its symbol can be found if its distance from B is given. 418. If K and K' be any two poles in the zone [oio], we have, from Article 413, / sm(AC-AK) _ l f s' i sin AX ~ whence 7 7/ 77 / _ 7 7/ {cotA-l 7 cotA' = i,, coUC; n fi hh an expression which is often convenient in computing such angles when a table of natural cotangents can be employed. For the parametral hemidome faces E, 101 and E' ', Toi it becomes, if A' be Too, cot AE- 2 cot AC = and for a plane K^ h o / of a single hemidome form cot AE - cQiAK = -^ cQiAC. h h 419. The elements of the crystal being given and the symbols of two poles ) to find the arc joining these poles. P (hkt) and P' (h'k'T) being the two poles, their positions may be determined in reference to B and \BA\ by the equations (iii). Thus, PB, P'B, PBA, and P'BA are known, and the triangle PBP f can be solved. 440 Crystallographic calcidation. 420. To find the arc-elements of a mono- symmetric crystal. Since the elements in this system involve three unknown magnitudes, three equations of the form of equation (ix), Art. 396, would be required in the most general case; that, namely, where the poles, of which the arc-distances are given, are heterozonal and have no zero in their indices. In fact however the problem always presents itself in a more simple form than this, since the preliminary investigation of the crystal in deciding the character of the symmetry will have always given measurements between poles which, by their symmetrical repe- tition, or by the position of one or more of them in the plane of symmetry, or, again, by the identi- fication of one of them with the pole of that plane, lead to the direct ap- plication of the equations (ii) or (iii) (Arts. 411-12). And where the ap- plication is not so simple it is fre- quently possible to obtain the arcs between poles in the zone [100, ooi] by aid of the 'problem of four planes' or of the expressions in Article 396 ; and where the arc-distance of a pole from the pole of symmetry oio is not obtained by direct measurement (as for instance in the absence of this pole), it can frequently be deduced ' from a measured angle between the normals of two symmetrically repeated faces. Let the distances of four poles p l , p 2 , ft , ft be given ; and let Aft = Aft and A ft = Aft Fi g- 362, Let [Aft] [Aft] intersect in S, [A ft] [Aft] in ^> [A A] [ft ft] in#, and [XS] intersect [p L p 2 ] [ft ft] in K and Z. Then \KS\ lies in a plane of symmetry to the crystal, and B is its pole and is (oio). Fig. 362. Also A K = i A A and ft z = 4 ft Rectangular-axed systems. 441 Project the poles on the zone-plane [^T-S 1 ]. BK and BL are quadrants (Fig. 363) ; hence B p 1 and B q^ are known, and from the triangle p l q^B, the angles p l J3q l (and therefore arc KL] and Bp\ $1 ( Kp\ S) mav t> e computed. Hence also in the right- angled triangle Kp^ S, KS can be determined. Let p be in and q^ be Tn. Then K is 101, L is Yoi, R is ooi, and S is 100 ; and from the four poles S, K, R, L known in symbol and known in distance as regards SK and KL the angle KR can be computed; whence the arc-elements SK t KR, and Bpi are found. If the relative positions of p^ and ^ had led to a different appropriation of symbols to those poles, the poles S, K, R, and L would also have different symbols, but the method of procedure would be the same. For instance, if p l be assumed to be in and ^ 021, L becomes ooi ; R, 203 ; K, 101 ; S, 201 ; and the distance of a pole A, or 100, from K has to be found. SECTION IV. Crystallographic Calculation. The Rectangular-axed Systems. 421. The Ortho-symmetric or Ortho-rhombic system represents the most general case of a crystallographic plane-system referred to rectangular axes ; the case, namely, in which the parameters are all different, and the three axes are axes of ortho-symmetry. The three systems which have been referred in this treatise to a rectangular axial system have the directions of their axes deter- mined by considerations of physical as well as morphological 442 Crystallographic calculation. symmetry, though in no system are the three directions so emphatically fixed by physical conditions as in the Ortho-rhombic system ; since all the physical characters which distinguish a crystal in this system are ortho-symmetrical to the three perpendicular axial directions to which the forms of the crystal are referred, and to these alone. The characters which are common to the different systems of planes referred to a rectangular axial system may be considered as introductory to those which more particularly bear on the crys- tallography of the Ortho-symmetric system itself. 422. In a system in which the faces of a crystal are referred to three perpendicular axes the direc- tions of the axes X, F, Z coincide with those of the normals to the axial planes, and the axial points X, Y, Z fall on the poles A, B, C of the axial planes ; which poles are therefore those of the faces belonging to the forms {100}, {oio}, and {ooi}. Hence the fundamental equation (A) becomes (a] From the triangles PCA, PCB, (Fig. 364) cos PA = sin PC cos PC A, j cos PB = sin PC sin PC A, $ cos PC = sin PA cos PA C, and whence, = ^smPCcosPCA, ch. - ck cot PC = cos PC A = sin PC A, ch ck Rectangular-axed systems. 443 and similarly, we obtain tan = 7k ' and tan PBC = . al Squaring equations (3) and adding, cos 2 PA + cos 2 PB = sin 2 PC = i - cos 2 PC, ) and cos 2 PA + cos 2 P+ cos 2 PC = i. \"' From (c), and substituting values from (3) and (a), we have cot PC = ^ and similarly, = "~ and cot = ~ b 423. If ^", K, L be the poles ok I, hoi, hko they will be the poles in which the zones AP, BP, CP intersect the arcs C, CA, AB respectively; and being the pole in, and Z>, E, /'being the poles on, 101, no in which the zone-circles OA, OB, OC intersect the arcs BC, CA, AB, we have from (a) abc 7^ ' hbc cos AP = sin PH = - VS 444 Crystallographic calculation. For the parametral plane 0, An nn be cos AO = sin UD = ? \ Vs ca ~7s ab cos CO = sin OF = These equations may be put into the form a:l\c h cosPPcosPC : k cosPC cosPA ilcosPA cosPP, (g) = cos OB cos OC: cosOCcosOA: cos OA cos 03. (/) 424. If P and P' be the poles of two faces hkl and h'k'l', we have, from the spherical triangle PCP r formed by the arcs CP, CP', PP', and by substitution from (3) and from (/), cos PP f cos PC cos P f C + sin PC sin P'C cos (P'CA - PC A ) = cos PC cos P / C+ sin PC cos PC A sin P'C cos P'CA + sin PC sin PC A sin P'C sin P'CA = cos /M cos P'A + cos PP cos P'B + cos PC cos P'C (h) an equation identical with that to which the general equation (ix), Article 396, becomes reduced by the condition of the axes being perpendicular and the arcs a, /3, y, which also measure the angles f, 77, f, being quadrants. The equation (h], though not directly adapted for logarithmic computation, involves only terms which are readily so computed. The equations in the last article are evidently directly dedncible from the above form (ti) of the general equation by substituting in it the different values of the indices of P and P'. Evidently also the following expressions will hold good : Rectangular-axed systems. 445 If P' coincide with in, i.e. with 0, P being any pole hkl, the expression (ti) becomes and if P' be one of the poles on, 101, or no, i.e. D, E, or F, we have COS P^ = COS P/^ = and if also P be one of the poles D, E, or F, be cos EF = ab 425. Since, by equation (d\ in any system referred to rect- angular axes, PA =-c -cos(Vc+P^)cos( J PC'-P^), [ ...... (A) cos 2 PC = - cos (PA + P) cos (PA -PS};} and since a:d:c cosOjB cos OC : cos 6>C cos OA : cos (9^4 cos OB, by substituting in any two of the last ratios, for cos OA, \ _ / I'fanCP' h' (3) for 430. If, again, the symbol has been determined of a second pole P f t representing a face (h'k'f\ where PP f is heterozonal to 44 8 Crystallographic calculation. A, B, and C, the arc PP* may be found by spherical trigonometry, after the poles P and P f have been severally determined in position relatively to C and CA as in the last article, by the solution of the right-angled triangles PC A and P'CA. 431. A measurement between faces belonging to the prism- zone, combined with one or more in a dome-zone, suffices for determining the parameters of an ortho-rhombic crystal. Or it may be that the angles between the faces of an octahedrid form offer the only or the best images on the goniometer, and an arc can generally be measured between the poles of two ad- jacent faces of such a form ; as, for instance, between h k I and h k /, where \(hkl t hkl) = PH = go-AP. When a second arc, such as (hkl, hkl) = 2PL, or (hkl, h~kl] = 2 PK, can also be obtained, this second arc conjoined with the first gives the position of P; so that the parameters of the crystal can be determined. The Rectangular-axed Systems. II. The Tetragonal System. 432. In a tetragonal crystal the morphological axis is an axis of symmetry for all the physical characters of the crystal ; whereas the axes of ortho-symmetry in which the trito-systematic zone- plane intersects the proto- and the deutero-systematic planes are only to be distinguished from the other possible zone-axes lying in that zone-plane by the fact that they are the normals of actual, not of abortive, planes of symmetry for the Crystallographic forms. The symmetry of the crystal thus leads to the morphological axis being taken for one, namely, for the JT-axis,- one of the other pairs of perpendicular axes of symmetry being taken for those of X and Y. 433. The di-prism. The fundamental equation (A) takes for a tetragonal crystal the form cos PA =cosP^ = CosPC; (1) Tetragonal system. 449 which for the pole L of a form {h k o} belonging to the zone [ooi] becomes AT k AL -Jl a . _ a - cosAL = T n K or 434. The proto-prism {100}, and deulero-prism {no}, are particular cases of the form {hko} in which the poles of the form lie on the proto- and deutero- systematic zone-circles respect- C D IT* A ively. In the one case tan A L = o ; in the other tan^4Z = i, and 435. The di-octahedron {hkl}. If P (Fig. 365) be the pole of a face of a general scalenohedral form {h k 1} , H^ and H^ the poles in which [AP], \JBC] and [BP], [AC] respectively intersect, and Fig. 365. L be the pole h k o in which the zone-circles [ooi, h kl\ and [ooi] intersect, then, following similar reasoning to that in the last section, or, directly from equation (c\ (Art. 422) ; since in a tetragonal crystal a d, we have cotAZ, = cotACP = -v> tan PL = cot CP = -^- cos ACP. ch Similarly, tan PH^ = cot AP = j cos BAP, } (3) tan PH 2 = cot BP = ~ cos CBP. Equations by means of which, if the parametral ratio be given and the symbol of a pole, the position of the pole can be deter- mined, or its position being given its symbol can be computed. 436. The proto-octahedron and deutero-octahedron. H being a pole of the proto-octahedron {h o /}, and A the nearest pole to it of 45 Crystallographic calculation. the form {100} on the same proto-systematic zone-circle, since cosACP = i, we have ............. (4) and if D be the pole of the form (101) with the same signs to its indices, a cot DC - = tan AD, \ / ............ (6) and tan AH = -tan A D. ) Evidently then DC may be taken as the arc-element of a tetragonal crystal, since its tangent gives the value of the para- metral ratio. If K be a pole of the deutero-octahedron hhL and F the nearest pole of the form {no}, cos KCA cos 45 = -=> A/2 and cotC^= -?-= ~ = tan KF ; .......... (6) V 2 cn and for O the pole of the form { 1 1 1 } with the same signs to its indices as K, cot CO = tan OF = whence tan AD = - = \/2 tan OF. c From the expressions (5), the elements of the crystal being given, the position of a pole on a proto-systematic zone-circle can be determined if its symbol be known ; or its symbol be found if its position on the zone-circle be known : and the equation (6) gives the same result in the case of a pole situate on a deutero- systematic zone -circle. 437. If P and P' be any two poles the symbols of which are hkl and h'k'l', equations (/), Article 423, take the forms cos AP = sin PH, = h C , y Jb cos BP = sin PH t2 k cos CP = sin PL I VF a Tetragonal system. 451 where F = ~ = c 2 (h 2 + k 2 ) + a* / 2 . And, if F' = ~ = c* (h'* + '*) + a" l we have similar expressions for P' ; namely, cos AP f = sin ' 7F' &c. &c. &c. Whence also, as in equation (h], Article 424, we obtain cosPP' = (7) a result directly deducible from the equation (ix), Article 396, by making a b and a, /3, y quadrants. 438. By assigning special values to the indices in the symbols of P and P f the arc-distance of any two poles may be computed if the parametral ratio of the crystal be given. And for any two poles mno and m'n'o in the equatorial zone [ooi], we have / , , ^ mm + nn cos (mno, m'n o) = -; (8) V(m* + n*}(m'* + n'*} an expression which is independent of the parametral element of the crystal; so that the normal-angles between faces per- pendicular to the trito-systematic plane must be the same for faces with the same symbols in all crystals of the Tetragonal system, and depend solely on the indices in these symbols ; and further, if mno and n'm'o are poles of the same form, in which the two symbols have their similar indices in the inverse order, but differ in the sign of one of them, COS(;;ZTZO, n'm'o) = o, and the arc-distance is for every form - The zone is in fact a zone of abortive symmetry. Gg 2 452 CrystallograpkU calculation. 439. If P be a pole hkl, Q a pole mno, and hko be L, CQP is a quadrantal triangle ; = smCPcosLQ hm + kn = sinCP 440. If H and H' be two poles of forms {hoi} and 'and K r two poles of forms {hhl} and {h'h'l}, ; cosC7/= ' 441. To find the element of a tetragonal crystal. et and P / be poles of which the known symbols are hkl and h'Kt respectively, and let their arc-distance from each other be given (Fig. 366). Let the zone-circle [ooi] intersect [CP~] in Z, i.e. mhko; [CP'] in L', or tik'o ; and P/" in Q, or wwo: Fa pole Fig. 366. at a quadrant's distance from Q on [ooi] is (nmo), and R or (uvw) the pole in which [PP'] and [CF] intersect is a quadrant's distance from (). The arc QP can therefore be found by the expression in Article 52. Also, T j and tan h, = i from (3); whence LQ is known. m Hence PL can be found from the right-angled triangle PLQ-, thus CP the complement of PL is known. Cubic system. 453 Hence the position of P relatively to C and an arc CA (or CB) is known, and by equations (3), - = y tan PC cos A CP- a ti The Rectangular-axed Systems. III. The Cubic System. 442. The general expressions, obtained in Articles 422 and 423, for the relations of the faces of a crystal referred to rectangular axes, assume their simplest forms when applied to the Cubic system, in which, the parameters being equal, all the elements of the crystal are fixed. Thus the fundamental equations for the direction-cosines of a pole P with the symbol h k I become cos AP _ cos BP _ cos CP ~~h~ T~ ~~T A, B, C being as before 100, 010,001; these poles now belong to a single form, the cube {100}. The equations (e) in Article 422 take the forms cot CP = tan ZAP = tmCBP = -- and corresponding expressions give the position of P in respect to the other poles of the cube. So that the position of P being thus given, its indices can be determined; or, the indices being given, its position is known. 443. As in equations (_/) of the general expressions for crystals referred to rectangular axes, we have Vs cos CP = sin PL \ 454 Crystallographic calculation. where = ff + tf + P and H, K. L are poles of the form {hko}, in which the zone-circles [AP] and [100], [BP] and [oio], [CP] and [ooi] respectively intersect. If be a face of the octahedron {in}, and H be a face of that form symmetrical with in regard to a proto-systematic plane and lying therefore in an adjacent octant, while (/ is a face symmetrical with in regard to a deutero-systematic plane, and lying therefore in an octant attingent to that containing O -, since the pole of O is equidistant from three poles of the cube, we have r cos A = sin OD , V3 D being a face of one of the three equidistant adjacent faces of the rhomb-dodecahedron. Hence the normal-angles between adjacent faces of the octa- hedron and cube, and octahedron and dodecahedron, are AO = 54 44-14', OD = 35 15-86'. And, as has been otherwise proved, article 125, the normal-angle between the faces forming the edges of the octahedron is <9&= 2 0Z>=7o 31-73', while 0(/= 2AO = 1 09 2 8 -2 f = flfl'; the latter being the normal -angle between the faces of the octahedron which meet oppositely at a quoin, and being equally the normal-angle of an edge of the tetrahedron * = % If the poles of H^ and ff 2 are situate as before on a zone- circle S but are symmetrical to a deutero-systematic plane their symbols differ only in the transposition of their indices, and or their symbols also differ in the signs of both their indices, and If the poles of H^ H 2 lying on a zone-circle S are not symmetrical in respect to any systematic plane, the indices of their symbols are transposed and differ in one sign, and cos H^H^ = o ; the two faces are perpendicular and belong in fact to a zone of abortive symmetry, a condition shewn to he true of every zone of the Cubic system. For adjacent faces of the tetrakis-hexahedron, cube, and rhomb- dodecahedron, we have A/ 45 6 Crystallographic calculation. Since cos 2 AH = J?-^, fa 2 Y COS A T~f J? we have -^ ^= 9 , > or = tan AH: h 2 cos 2 AH h whence the normal-angle AH being given the symbol of H is known. 446. The deutero-systematic zone-circles 2 contain the poles of the cube, icositetrahedron, octahedron, triakis-octahedron, and rhomb-dodecahedron. If R and R be faces the poles of which lie on a deutero-sys- tematic zone-circle, and have for their symbols mmn and mm'n', we have for their normal-angle 2 m m' + n n' V 2 m- + 7* 2 A/ 2 m' 2 + n 2 If R and R' belong to the same form, the poles R and R' lie on the same zone-circle 2. If R and R' are symmetrical to a proto- systematic plane, , 2 m 2 n 2 cos RR = 5 * 2 m 2 + n 1 Also we have cos CR = ==== = sin RD ; V 2 m 2 + n 2 whence cos OR = V%\/2 m 2 + n 2 m tan CR Also - = - . n 4i3 = 32 12' 15"; 43 1 * 341" = 2747 / 45 // ; {532}, 532, 523 = is "' 25"; 532, 352 = 464 9 '35"; {54i}, 54i, 5i4 = 38 12' 48"; 54i, 451 = 2i47'i 2 "; {743}, 743, 734 = 9 25' 48"; 743, 473 = 50 34' 12"; {752}, 752, 725 = 2747 / 45' / ; 752, 572 = 32i2'i5' / . 448. Of the three fundamental forms of the Cubic system the octahedron is the only one which can undergo a hemi-symmetrical suppression in the number of its faces, the tetrahedron cr { 1 1 1 } being its haplohedral semiform ; the normal-angle of each of the six edges D of the tetrahedron is 109 2 8. 2 7'. 449. The tetrakis-hexahedron. The edges of the cube are be- villed by the faces of the cube-pyramidion or tetrakis-hexahe'dron {hko}. This figure has two kinds of edges, each face of the form being an isosceles triangle, the edge H, which forms the base of the triangle, being parallel to one of the crystallographic axes, but lying, like each of the remaining edges D, in a deutero- systematic plane. The following angles for different varieties of the form follow from the equations 45 8 Crystallographic calculation. For the form {210}, H= 36 52' 12" = D; {530}, ff= 2 S 4 '2i", D = 4 2 4 o' 5"; {320}, #=2237'i2", .0 = 46 n' 13"; {520}, #=46 2 3 '5o", >= 3 o27' i"; {310}, ^=53 7' 48", -#=25 50' 31"; {410}, #=6i55'39", ^= i9 45' o"; {720}, #= 5 8 6' 33", Z>=222 4 'IO". The pentagon-dodecahedron. The only hemi-symmetrical form of the tetrakis-hexahedron exhibiting a defalcation in the number of the faces of that figure is the pentagon-dodecahedron 77 {kk o} or pyritohedron (Article 183). The symmetrical pentagons which form its faces are euthy-symmetrical to a proto- systematic plane and have one edge O dissimilar to the other four : it lies in a proto-systematic plane perpendicular to the former plane. The remaining edges lie in no systematic plane. 45O. The triakis-octahedron. The faces of the triakis-octahedron or octahedrid pyramidion {hhk} bevil the edges of the octahedron: the edges O, which are parallel to those of the octahedron, lie each in a proto-systematic plane S; the edges D, which form the isosceles sides of the faces of the form, lie in the 2-planes : Article 174. The equations _ 2h*-& n h*+2hk COS O = j- rs 5 COS D = r^ 2h z + k z 2 h* + & give the following normal-angles for the two kinds of edges in some of the more usual varieties of the form : {332}, 0-50 28' 44", 2= 17 20-29^; {221}, 6>= 3 8 56 / 3 3 // , Z>=27i 5 / 58 // ; {331}, 0=26 3 i' 3 i", ^= 37 5i / 49 // ; {441}, 0=20 3' o", JD = 43 30". The hemi-triakisoctahedron or twelve-deltohedron a {hhk}, Article 179, is the only form hemi-symmetrically derived from the triakis- octahedron by the extinction of half its faces. It has two sets of edges, one identical with the edges D of the triakis-octahedron. Cubic system. 459 and the other denoted by A, the normal-angle of which is deter- mined by the equation The following are the normal-angles between the faces forming the edges A for different values of h and k : ^{332}, A = 97so'i6"; a {221}, A = 90; er{ 33 i}, A = 8o54'55"; o-{ 44 i}, A = 75 58' 13". In consequence of the edges A of the form cr { 22 1 } being right- angles, it will be seen that the faces of that form are those of four cube-quoins symmetrically grouped in respect to the axes of sym- metry of the system. Their poles are at a normal-distance of i548 / from those of the adjacent faces of the octahedron, at 70 31' from the more remote of the three nearest poles of the cube ; furthermore, each pole of the dodecahedron is 45 from four poles, and each pole of the form {411 } is 45 from two poles of the form {221}. 451. The icositetrahedron. The faces of the icositetrahedron \hkk\ replace symmetrically the quoins of the octahedron and of the cube (Art. 173). Of the two kinds of edges and H which form the sides of the deltoid faces of a form {hkk}, the normal- angle of the faces meeting in an edge is given by the equation the two faces being symmetrical to a plane S, that of a pair of faces symmetrical to a plane 2 and meeting in an edge H is obtained from the expression the values of these angles for some of the more common varieties of the icositetrahedron are, {322}, 0= 5 82 / 3 // , {211}, = 4 8 n' 23 = 35 5' 48", 460 Crystallographic calculation. {411}, 6>=27i 5 '58", ^=60; {511}, (9 =22 n' 30", ^=6 5 57'2 9 "; {611}, (9= i84o'i8", H=6 9 59' 41". The only hemi-symmetrical form of the icositetrahedron pre- senting a defalcation in the number of faces belonging to that figure is the hemi-icositetrahedron or tetrahedrid-pyramidion cr {h k k} (Art. 180). Its faces are isosceles triangles, and the edges H forming the similar sides of each face are identical with the edges H of the holo-symmetrical figure. The normal-angle of the remaining edge, D, of each face may be computed by the formula Thus for the forms, =7o 3 i'44", o-{ 3 n}, Z>=5o28' 4 4", o-{ 4 n}, >= 3 8 56' 33", =26 3 i'3i". 452. The forty-eight scalenohedron or hexakis-octahedron, {hkl} (Art. 175). Each face of this form is a triangle, scalene in the sense that its three edges are crystallographically dissimilar, there being twenty-four edges of each different kind. If represent any edge formed by two adjacent faces of which the symbols differ in a sign, D an edge in which the highest index retains the same position in the symbols for the two adjacent faces, and H an edge in which the lowest index remains unchanged in its position in the two symbols ; the normal-angles of the three kinds of edges are given by the equations = and the following are the values for the edge's of some of the more frequently occurring of these forms : {321}; =106 36' 6", Z>= 2i 4 7 / i2", J7= 2 i47'i2"; {421}; 0= 25 12' 31", Z>=i745'io", ^ r =3557 / *" \ {531}; 0= 19 27' 47", .0=27 39' 38", H =2f 39' 38"; (543); 0= 50 1 2' 29", D= 11 28' 42", H= 11 28' 42". Cubic system. 461 The distances of a pole of the hexakis-octahedron from the nearest, the next, and the most remote of the three least distant poles of the cube are given severally by the equations h k I Vs Vs Vs 453. Special varieties of the forty-eight scalenohedron have been already considered, Article 175. In one series of these the poles lie in zones with those of the rhomb-dodecahedron, the indices being determined by the equation h = k + / : the twenty- four edges D of such a form are parallel in groups of six to the four trigonal axes O of the system. In the other series the poles lie on zone-circles bisecting the angles between the deutero-systematic zone-circles 2, and the forms correspond to those which in a trigonal system have been designated by the symbol {min}, where 21 = m-\-n\ and in a form of this kind normal-angles of the edges H and D have the same values though the edges are not of equal length nor otherwise similar. Forms of the first series would be {321}, {532}, {431}, &c. , and of the second {321}, {53 1 }, {43 2 }> &c- 454. It has been seen that, from the nature of the symmetry of the Cubic system, it is only the general scalenohedron that is capable of undergoing a hemi-symmetrical partition of its faces in accordance with both of the laws designated by the symbols a- {h k /} and Ti{hkl}. The former of these symbols is that of the hexakis- tetrahedron, the latter is that of the trapezoid dodecahedron or diploheclron. The hexakis-tetrahedron v{hkl}, Article 181, has three sets of edges, the normal-angles of which are determined by the equations tf-2kl _ cos D = ^ > cos H = ^ > cos A = ^ O O O where the angles D and H are those belonging to the respective forms of the hexakis-octahedron. The following are the normal-angles for the edges A of various hexakis-tetrahedra, A being the edge in which the signs 462 Crystallographic calcidation. of two of the indices of the faces forming the edge are dif- ferent : o-{ 3 2i}; A= 158 12' 47"; .{421}; A- 55 9' o"; -{53i}; A- 57 7 'i8"; -{543}; A= 88 51' 14". 7/k? diplohedron, TT {hkl} : Article 184. The edges which form the four sides of the trapezoidal faces of this figure are of three kinds, representing three different normal-angles. The edges G which meet in a trigonal quoin do not lie in the 2-planes, and the normal-angle of the faces meeting in each such edge G is given by the equation hk + kl + lh cosG = y- The two other edges and li of each face meet in a tetragonal quoin, and lie in proto-systematic planes perpendicular to each other. They are formed by faces the symbols of which in each case differ in one of their signs ; and their normal-angles may be computed from the equations AH* 2 -/ 2 tf-*H/ 2 cos 12 = ^ 5 cos = = ; o o where >Q is the edge representing the longer and that represent- ing the shorter side of the trapezoid. The following are the normal-angles for G, O, and for various diplohedra : 77(321}; G = 3i O'IQ", 11 =106 36' 6", 0=6 4 37'23"; 77(421}; = 48 n' 2 3", a=25i2 / 3 i' / , = 5i45'i2"; 77(531}; G = 4 855' 4", &= 19 27' 47", = 60 56' 27"; "{543}; ,G= i 9 56 / 54 // , G = 5oi2 / 2 9 // , 0=68 53' 59". The pentagonal icositetrahedon^ a {hkl}: Article 177. Of the forms in the Cubic system the general scalenohedron is the only one which can undergo a hemi- symmetrical suppression of its faces in accordance with the law denoted by the symbol a ; the resulting semiform being the pentagonal icositetrahedron a [hkl\. The semiform a {hkl} has three sets of edges G, V, W (see Hexagonal system. 463 Figs. 83 and 84, Art. 177), the normal-angles of which are deter- mined by the equations hk + kl+lh tf 2hk-P Thus for 0(785}; G=i8i 9 '39", F= 62 22-10", PF= 5 o55'4"; for a{ 9 86); G= 15 59' 12", F= 63 24' 57", FT =53 2 2V'. Four edges F meet in each tetragonal quoin ; three edges G in each trigonal quoin ; and each edge W would be truncated by a face of the form {no}. The Hexagonal System. 455. As referred to three axes lying in the proto-systematic planes S symmetrically with regard to the zone-axis of these Fig. 367. planes, a crystal of the Hexagonal system has for its parametral plane a face of the pinakoid form {in} which is parallel to the equatorial systematic plane C : this last plane being also the plane of the zone-circle [in]- The only variable element of the system is the axial angle f. If X, F, Z (Fig. 367) be the axial points, A lt A z , A 3 the poles of 464 Crystallographic calculation. the axial planes YZ, ZX, and XY severally ; then A 1 is 100, A 2 is oio, A 3 is ooi, and the arcs A 1 Y, A^Z, A%X, A^Z, A 3 Y r , A 3 X are quadrants ; and the triangles A^A 2 A 3 and XYZ are polar, and by the symmetry of the construction A 1 and X, A% and Y, A 3 and Z lie on the same side of (in), on quadrants of the great circles S which meet in that pole. Further, OX = OY = OZ, and OA l = OA^ = OA 3 , " 1 " 2 ~~~ 23 ^~ 3 1 ' XOY - YOZ = ZOX = 120. Since the axes X and Y are symmetrically situate in respect to a great circle S S) the arc XY is bisected, say in V, by that great circle ; and in the triangle XO V, sin VX = sin OX sin VOX, or sin J f = sin OX sin 60, sin OX = sin 6>J^ = sin OZ = -^~ sin \ f . (i) V3 456. Let /* be the pole hkl of a discalenohedron (Fig. 367). Then the pole symmetrical with it in regard to S 1 is hlk, and the edge of the faces hkl and hlk would, Article 133, be truncated by a face R with the_symbol (2/1, k + l, k + l), which is of the form h'k'tf. The faces hkl t efg which are symmetrical to the equatorial plane C and lie in the zone [in, hkl\ are truncated by a face N for which the symbol is obtained by the addition of the symbols (%h, 3 k, 3/) and efg', that is to say, the symbol is (2h kl t 2k lh t 2lhk), or (pqr), where p + g + r = o, and the face thus belongs to the equatorial zone of the crystal. 457. Let R be the pole hkk of a rhombohedron (Fig. 367). Since the parameters are equal, cos RX cosRF cosXZ T = 7 = and cos Rx cos KZ, (11) and cos RX = cos ( OR - OX) = cos OR cos OX + sin OR sin OX, also cos RY = cos OR cos OY+ sin OR sin OY cos 120, = cos OR cos OX- \ sin Oft sin OX] Hexagonal system. 465 whence by substitution in (ii), (- + jfy sin OR sin OX = (h-k) cos OR cos OX, and tan OR = 2 7- cot OX (iii) h + *k Hence, for a pole A l of the form {100} on the hemisphere which is positive relatively to the zone [m], tanO4 = 2 cot OX; ................ (iv) and if R is a pole of a form \hkk\ lying also on the positive side of [in] and on the same great circle with A lf tan OR = tan OA OR and OA having the same or opposite signs according as R and A are on the same or opposite sides of 0\ i.e. according as the rhombohedron {hkk\ is direct or inverse. And since, from equation (i), sin OX is known when f is given, it is seen from equation (iv) that tan OA determines f : and OA may therefore serve as the arc-element of a crystal in this system. 458. Every pole of a form {hkk} is at a quadrant's distance from two opposite poles of the form {oil} (Fig. 183) ; so that khk and kkh being poles of the form {hkk} on the same side of [m], the great circles [khk, kkh] and [i 1 1] intersect in the poles oil and oil, and from either of these poles the pole hkk is distant a quadrant; the arc-distance of khk and kkh from them is either 9o-f-^A or 90 J A, where A is the arc joining any two of the poles hkk, khk, kkh. 459. R being one of Fig. 368. the above poles of the form {hkk} and T a pole of the form truncating by its faces the edges of {hkk}, the symbol of the truncating form is \2k, h + k, h-\-k\, and we have evidently, equa- ting values of tan OA given by (v), tan OR =-2 tan 0T 7 . nh 466 Crystallographic calculation. The zone-circles [in] and [in, 100] or [SJ intersect in M or 2 IT, a pole of the proto-hexagonal prism, and [2J or [2!!], the zone-circle perpendicular to [S'J, intersects [in] in oil, a pole of the deutero-hexagonal prism. For NI a pole (pqr) of the dihexagonal prism lying on the zone-circle [in] (Fig. 368), cos NX _ cos NY P q From the triangles XON, YON, ON being a quadrant, cos NX = sin OX cos XON, cos NY = sin 01" cos .TOW = sin O^T cos (120 - and since Af)N is MN we have - = \ (\/3 tan MN i) ; but since p + q f r = o, I q T Vz P Now the zone-circle [in] is an isogonal zone with abortive symmetry (Article 99), and every face in it has for its pole the pole of a possible zone, the indices in the symbols for the zone and for the face being identical : hence every face in the zone [in] is perpendicular to another possible face of the zone. If For/'/r' be the face at a quadrant's distance from N t tan MV = tan (MN+ 90) = - I // r 7 .- /> and A/3 P r ~V P' y~ r i / 2 r whence -7 = and --7 = , (vii) If now ^V lie in the zone [in, hkl\, its symbol (/^r) is (2h k /, 2k / h, 2/ h >), and = - ~ -\ p 2/1 K / so that, P being h k /, tan A, OP = 2h-k-l If 7? be a pole h' k' k' of the dirhombohedron the faces of which truncate the alternate edges hkl, hlk, &c. of the discalenohedron Hexagonal system. 467 {hkl}, the angle at R in the triangle FOR is a right angle, and tan OR = tan OP cos ROP and substituting values of hkl for h' K k' (Article 466), tan OX tan OP cos MOP = * k k ! , i tan OA j 2hkl j which may be written ~ . h + k + l cos tan OA, (ix) 460. The position of a pole P or hkl\s determined by the arc OP and the angle MOP, i.e. the arc MN, where ^V is (2h-k-l y 2k-l-h, 2l-h-k\ And if the position of P is known, its symbol can be determined from equations (viii) and (ix). For since the terms of the ex- pression 2hkl may be represented by any numbers, whole or fractional, in the ratios of 2^, k, and /, we may take 2h-k-l= i; ................ (x) ten A, OP then from (vin), kl - ~ ; V3 tan OA, and from (,x), , tan _ while 3 (/&/) = -/s tan ^4 X OP ; two equations from which and from equation (x) the symbol of P is readily obtained. If the symbols were those of two poles of the discalenohedron belonging to the semiform {efg\ correlative with {hkl}, for instance, the poles gfe and g ef symmetrical on S lf expressions identical in form lead to similar results. H h 2 468 Crystallographic calcination. 461. For a pole K lying on a deutero-systematic zone-circle 2, and having a symbol m in; since A^OK = - and, by Article 121, - = z\ we have, for OK where the symbol is given, and for the ratios of the indices of the symbols, where tan OK is known, m _ tan OA + A/3 tan OK i _ tan OA n ~~ tan OA - A/3 tan6>^ ' ~~ tan O4- -/Stan OAT* If tan 0= A/3 tan OK, we have m sin ( OA + 0) 72 ~sn a form adapted to logarithmic computation. 462. To determine the arc joining two poles P and P' not lyino on a systematic zone-circle, where the symbols hkl and h'k'l' of P and P', respectively, are given ; the angles A OP and A OP', and therefore POP', are to be found from equation (viii), and the arcs OP and OP' being found from equation (ix), the third side of the triangle POP', that is to say, the arc PP'. is directly found by spherical trigonometry. Or we may proceed as follows : Let [u v w] = [h k /, h'k'l'\ and the zone-circle PP' or [u v w] meet the zone-circle [in] in a pole Q or efg ; then e = v w, f=. w u, g = u v; and it may be shown that if [OP] meet [i 1 1] in TV 7 , ^.^ Similarly, tan (W = Then, PP'is known, for cos <2P = cos QN sin OP, and cos QP' = cos QN' sin Hexagonal system. 469 463. To find the arc -element of a hexagonal crystal. Where the pole of any face of the crystal has been given in position with respect to the pole (m) and the zone-circle [in, i oo], or [0-4J, or the zone-circle passing through and the nearest pole of the form {100}, the equations (ix) give the arc-element directly ; provided that the symbol of the face is given, and that the face neither belongs to the zone [in] nor is the face (in) itself. Where however we have only symbols and one measured arc of the crystal for data, the problem takes the form of having to Fig. 369. Fig. 370. determine the arc-element from the measured arc-distance between two poles whereof the symbols only are given or can be deter- mined. Here then we have the following cases : first, P' one of the poles may lie on the zone-circle [in], P the other lying either in or out of the zone containing and P'. Or secondly, P f may lie on the zone-circle OP but not on [in]. Thirdly, both P and P' may be discalenohedral poles and their zone lie obliquely to the zone [in]. I. (a) Let P be the pole hkl, P' the pole/^r lying on the zone- circle [in] (Fig. 369). In this case (pqr) is ( 2 h-k-l, 2k-l-h, 2l-h-k). From equation (viii) AflP can be determined, since k-l Also PP' being given, OP is known, for tan OP = cot PP' ; hence AO the arc-element can be found by equation (ix). 470 Crystallographic calculation. I. (f) In the case where P' is not in the zone OP, let N be the pole in which [OP] and [in] intersect (Fig. 370). Thus NMoiAOP is known, from (viii) ; so is P'M and therefore P'N; hence PN in the right-angled triangle PNP' can be computed. Thus OP also is known and P given in position ; so that A can be calculated from equation (ix). If the symbol of P' had not been given but only that of [uvw], a zone traversing PP 7 , then the symbol of P' is |i ^ ^1 II. If neither pole is on the zone-circle [in] but both are in a zone with (in), the arc PP' and the symbol of P being given ; then, if Nbe the pole in which the zone-circles [OP] and [in] Fig. 371- Fig. 372. intersect, the symbol of N can be found, and it determines, as before, the angle A OP (Fig. 371). The four poles N, P', P, O lie in a zone, and of these the symbols of O or (in) and P or (hkl) are given. Also N lies in the zone [m]; and let the symbol [uvw] of a zone traversing P' be also given. Then, by Article 52, sin (2 PNPP') = (2 A- 1) sin PP', where A = an equation by which NP, and therefore tan OP, can be com- puted. So that P is given in position and the element can be found. III. If P and P' (Fig. 372) are both independent poles hetero- zonalto 0, let the zone-circle [111] intersect [PP'] in Q and [OP] Hexagonal system. 471 in N. Then the symbols of Q and N are known. Let W be the symbol of a pole at a quadrant's distance from Q on the zone [in], of which therefore the symbol may be found by equations (vii), and let R be the pole in which [OW] and [QP] intersect. Then, of the four poles Q, P, P / , R let the known symbols of P and R be hkl and efg\ the symbols also of the zone [in] traversing Q, and of a zone [uvw] traversing P', which may be [OP'], are known, as are the arc QR which is a quadrant, and the arc PP' which has been found by measurement. The arc QP can thus be found by the equation = (2A-i)sin/V, where A= -- z -- e+f+g QM and NM, and therefore also QN, can be computed by equa- tion (viii); and thus PN in the right-angled triangle PNQ can be found. Hence OP and A OP are determined, and the arc-element and the axial angle of the crystal can be computed by equation (ix). 464. The least unsymmetrical mode of referring a hexagonal crystal to axes of which one is at right angles to the rest (Art. 118) is that employed by Bravais, and adopted in recent times in the Zeitschrift fur Krystallographie. The axial system adopted in this method assumes for the four axial planes the systematic planes 2 and C, the axial system con- sisting of three lateral axes which are the zone-lines [2 X C] [2 2 C] and [2 S C] and of a vertical axis which will be the zone-line P.S,]. The JST-axis and the J^-axis are the first and third of these, the fourth or zf-axis being the morphological axis perpendicular to them. while the redundant lateral axis may be designated by the letter U\ the general symbol for a form being {h k i /}. The directions of the three lateral axes are so taken that the poles designated in this treatise as oil, ilo and Toi lie on the positive side of the origin, upon the three axes respectively. 472 Crystallographic calculation. The constant relation of the index *, corresponding to the re- dundant axis U t to the indices on the axes X and Y may be easily established. If in Fig. 373 the face flKL intersect the axis U in a point / we have for the intercepts of this plane a a a c v Y 7 j r Since area HOI+ area KOI = area HOK, we have OH. 6>/sin6o+ OK . OIsm 60 = OH . OKsm 120. Hence VH . 01+ OK. 01= OH. OK; or, if we regard lengths as negative when measured on the negative part of an axis, OH. 01+ OK . 01+ OH. OK = o, i i i and but OH= n k In the symbol (h k 2 /) of the face HKIL, therefore, the third index is equal to the alge- braical sum of the first two with its sign changed. For the derivation of sym- bols for zones from those of faces, or the inverse process, the usual operations are re- sorted to; the determinant is Fig. 373- taken of the symbols of any two faces but with one of the first three indices, and of course the same one throughout, omitted from the face-symbol. The symbol of a face obtained from those of two zones has then to be completed by the introduction of the fourth index in accord with the relation h + k + i = o. Fig. 374 represents a projection of some of the forms of a hexa- gonal crystal referred to such an axial system, the four-indexed symbols representing the poles which in this treatise have the three- indexed symbols conjoined with them in the figure. Hexagonal system. 473 Had the S-planes, instead of the deutero-systematic planes, been selected for the axial planes, the symmetry of the distribution of - 374- the scalenohedral forms, and of the indices in their symbols, would have presented greater symmetry and more geometrical elegance. CHAPTER IX. THE REPRESENTATION OF CRYSTALS. 465. The representation of a crystal by a model 'in the round ' may best be effected by apparatus specially constructed for cutting sections of the wood, or other material employed, in directions inclined to each other at angles identical with those of the edges of the crystal ; or they may be cut by the help of determinations deduced from the projection of the crystal on a plane surface, whereby the angles are given at which the edges meet in each quoin of the crystal. But for use in written description recourse is had to representing the crystal by a drawing of its edges, which are projected on a plane, as on a screen, by lines emanating from the eye and traversing each point to be projected. Where the eye is near the crystal the lines are more or less divergent, and the figure on the screen obeys the ordinary rules of perspective. In proportion as the eye is removed to a distance, these rays approximate to parallelism ; so that, by conceiving the eye to be placed at an infinite distance, a figure of the crystal may be projected by means of parallel rays. Perspective figures of the former kind involve complex processes in the drawing from which those of the latter kind are free, while also the projection by the aid of parallel rays offers some important advantages. 466. Parallel projection. A projection of this kind offers the following advantages : I. Parallel lines on the crystal, the edges for instance belonging to a zone, are represented as parallel lines in the projection. The converse however is not true, since lines parallel in the projection do not necessarily represent lines parallel on the crystal ; for, if we consider a plane passing through any two rays, all lines lying in that plane will be seen to be represented on one and the same line in the projection, whatever may be the angles at which they are inclined to the two rays and to each other. Projection on a systematic plane. 475 II. A second important property of the parallel projection consists in this that a straight line on the crystal, if divided in any ratio, is represented in the projection by a line divided in the same ratio. Thus AB, BC, divisions of a line AC inclined at any angle to the plane of projection, are represented by ab, be on ac, the projection of AC; and Aa, Bb, Cc being parallel to each other, we have ab AB It follows from this that, if the axes and parameters of a crystal are given in projection, intercepts on the actual axes will be repre- sented on each projected axis by intercepts proportional to the original intercepts on that axis ; and, from the indices of a plane, its projected intercepts on the axes can be taken. It will also be seen that equal parallel lines on the crystal will be projected as equal parallel lines ; and, further, a line parallel to a visual ray will be represented by a point, and a plane containing a visual ray will be projected as a line. Furthermore, all lines lying in planes parallel to the plane of projection if equal will be projected as equal lines, and if unequal will preserve their ratios in the projection. 467. Orthogonal projection : the plane of projection a systematic plane. Systematic projection. For a simple representation of a crystal, it is best to take the plane of projection perpendicular to the direction of the visual rays, i.e. to employ an orthogonal projection. The crystal may now be placed in any position in the path of the visual rays with a view to its being orthogonally projected ; and the most suitable position will of course depend on the purpose of the projection. Sometimes this purpose is sufficiently fulfilled by making a systematic plane the plane of projection ; the faces of the zone perpendicular to this plane becoming lines which bound the figure, while the edges of that zone are represented by the points in which these lines meet. An orthogonal projection of this kind may be termed a systematic projection. Such a projection presents great facilities to the draughtsman, and is employed, except for the Cubic system, almost exclusively in Professor Miller's classical treatise on Mineralogy. It constitutes in fact a sort of graphic counterpart to the representation of a 476 Representation of crystals. crystal by the stereographic projection of its poles. If the stereo- graphic and the systematic projections of a crystal be constructed with the same systematic plane for the plane of projection in each, it will be seen that for the faces of the zone perpendicular to that plane the poles will be distributed on the circle of projection in the one case, while they are represented by lines in the other case : and these lines will evidently be parallel to tangents drawn through the poles on the circle of projection, if the two projections are similar in orientation. The direction in which the edge of any two faces of the crystal would be projected can be determined by tracing the zone-circle containing the poles of the two faces and drawing a tangent to the projection-circle through the pole in which it and the projection-circle intersect. Fig- 375 () I Fig. 375 All the lines that are to represent the edges of the front half of the crystal can thus be determined so far as their directions are concerned. Their actual position on the projection will depend on the relative magnitudes to be given to the several forms, and for this a small free-hand drawing of the crystal or a view of the crystal itself is desirable. Where faces of the same form are symme- trically repeated, care has to be taken that the area of corresponding faces is maintained constant by keeping corresponding symmetrical lines on the crystal everywhere of equal length in the projection. In practice it will be found that the parallelism of the edges of the faces belonging to each zone rapidly indicates the contour of the Orthogonal projection. 477 faces enclosed by the various edges ; and in fact, when the stereo- graphic projection of the crystal is once correctly figured, the systematic projection is produced by a simple process of evolution from it. In this way the systematic projection of a crystal of bournonite given in Fig. 375 (b} can be immediately obtained from the stereographic projection of the poles given in Fig. 375 (a). 468. Orthogonal projection : the plane of projection not a syste- matic plane. In order, however, to obtain a more complete view of a crystal than is given by the systematic projection, it is necessary to be able to represent the various forms more as they would be seen in a perspective drawing, as well in order to give an aspect of solidity to the figure as to indicate the relative importance of the different forms. The systematic projection, for instance, indicates only by its boundary-lines, and therefore in fact obliterates as faces, the planes in the zone of which the edges are parallel to the line of sight;' and these frequently include important pinakoid-, dome-, or prism- faces, to which the crystal may owe its most characteristic aspect. The drawings are therefore generally made in such a way as that the plane of projection is not in parallelism with any systematic plane, nor, intentionally, with any face. The crystal is in fact placed in such a position that while its orientation gives to the axes nearly the positions in space usually assigned them in geometry, certain rotations through small angles, forward and from right to left respectively, bring into view, and as it were open out, faces that in the systematic projection are represented by lines only; while the idea of solidity is further imparted to the figure by the difference in dimensions that faces of the same form assume when thus moved into positions in which they are differently inclined to the line of sight. 469. Cubic system. Let Ox, Oy, Oz be three rectangular lines of reference fixed in space, Ox and Oy being horizontal and Oz vertical ; let xOz be the plane of orthogonal projection, and the visual rays have directions parallel tojyO. Taking as the simplest case a cubic crystal, we may suppose the initial position of the crystal to be such that the crystal-axes OX, OY, OZ are coincident with the fixed lines Ox, Oy, Oz, respectively : in the corresponding Representation of crystals. projection, the projections of OX, OZ will coincide with the lines Ox, Oz respectively, and the projection of OY will be the point O (Fig. 376). Next suppose the crystal to be rotated, in the direction of the hands of a watch, through a small angle 8 round the fixed line Oz. B $ y Y A. x Fig. 376. The .F-axis will now be represented by a line coincident in direc- tion with the line Ox ; and A', the projection of any point A on the axis OX, will move along Ox towards the origin while the rotation is proceeding (Fig. 377). Since the parameters are equal S' A r y o Fig. 377- we may take in the initiatory position OA = OS = OC = a for the parameters on the axes X, Y, and Z. During the rotation of the crystal, A describes a circle : the visual rays are in the plane of this circle and are perpendicular to the initial position of OA. If we describe a circle (see Fig. 378) through A and B with its centre at the origin, we may determine by a simple construction the values of OA ' and OB', representing the projected lengths a on the -X"-axis and 7-axis, after the rotation of the axes through the angle 5. Projection of rectangular axes. 479 Making A OD = b, we may suppose A to have moved on the circle to D ; when seen by visual rays in the plane of the circle and perpendicular to the initial position of OA, A will appear as at A', where DA' is perpendicular to OA. Similarly, after the rotation, B will have moved to E and be seen as at B' : and OA' = a cos b, OB' a sin 6. The projections OA', OB', OC' of the lines OA, OB, OC on the plane xOz, after this single rotation of the crystal through an angle 8 about the line Oz, are given in Fig. 377. B' Fig- 379- Let now the system further revolve round the line Ox through a small angle e, the point C or C' moving forward, and its projec- tion C" downward along the axis Z. Then the projections of the axes X and J^on the plane xOz will become disengaged from their former coincidence with the line Ox, and will take new directions 480 Representation of crystals. in OX" and OY" : the points A' and B' will appear in the pro- jection to move along lines perpendicular to Ox to the new positions A" and B", while C moves to C" (Fig. 379). The axial system has now taken a new aspect. The axes X and J^come to be represented by lines from the origin through A" and B") and the parameters are measured on these axes and on Oz by the ratios OA" : OB"-. OC" ; which, it will be seen by the constructions in Figs. 378 and 380, may be determined by the expressions B'asinS C C" ctcoss /r Fig. 380. OA' = acosb ) 0.5' = 0sin5 1 B'B" = a cos 8 sin e) = a sm sin = a cos //2 = a* (i -sin 2 8 cos 2 e), and For the angles between OX", OY", and OZ", the projections of the axes OX, OF, and OZ, we have (Fig. 379) = cotan cot Z" OY" = cotan A' A" = yjr : = -tan 8 sine: = -\.mxOY" B'B" = nD , = cotan 8 sin ; whence also X"OY" can be computed. Projection of rectangular axes. 481 470. The values of 6 and e th*at give to a crystal the most advantageous position for exhibiting its features have been differ- ently taken by different crystallographers. Haidinger, who has been very generally followed, took tan 5 = \ and sin 6 = J, corresponding to 6 = 18 26' and e= 7 n', nearly; the projected parametral ratios being a:b:c = 0-957:0-3404: i, and the axial angles as seen in projection 9 2 Q 2 3 ' and m?= iio 33 $'. Fig. 381. 471. Cry sf allographs. When the projection of the axes has been determined for the Cubic system, that for any other system is readily deduced from it. And it is very convenient to have an instrument in the form of Fig. 381, made of brass or other metal of about -|- in. thick, cut to the angles of the projected axes, and graduated along each of its three limbs with divisions subdivided to tenths and in the ratios of the projected parameters of a cubic crystal. Such an instrument or crystallograph serves for laying down on a piece of card, or a sheet of smooth paper strained on i i 482 Representation of crystals. a frame, the projection of a cubic axial system, from which that of the axes and parameters for any other crystallographic system can be deduced in the following manner. (a) Orthosymmetric systems. The Tetragonal and Orthorhombic systems are easily dealt with. In the latter, for instance, the orientation of the axes as projected by the crystallograph remains unchanged, but we have to find parameters on each of the three axes proportional to those of the crystal, but interpreted in accord with the parametral units of length on each limb of the crystallo- graph. In the Tetragonal system, only the parametral length on the ^-axis has to be so adjusted. (b) Hexagonal system. For the purpose of transforming a projection for a cubic axial system into one for a hexagonal crystal, let the axes of the cubic system be XFZ, those of the hexagonal crystal X'Y'Z'. Fig. 382. If now a projected cubic system of axes be drawn, and the axis Z be taken as the morphological axis of the hexagonal crystal, the axes X and Y being taken for the symmetry-axes [S s C] and \_S 9 C] or [ilo] and [112] respectively, the axis Z^of the hexagonal crystal will lie in the YZ plane between Z and Y, and the axes X' and Y f will lie in the systematic planes S l and S 2 which are inclined at 30 to the plane 2 3 and at 60 to S 3 (Fig. 382). Let ABC be any three points on X'Y'Z' equidistant from the origin of the system. Let a perpendicular from A meet the plane XOY"m M, and draw through J/a line parallel to the axis J^and cutting the axis X in N. Then ON, NM, MA are the rect- Projection of the axes of a hexagonal crystal. 483 angular coordinates of A, as referred to the rectangular axes OX, OF, OZ-, and OM= OA cosAOM = OA sinAOZ, ON = OMcos NOM = OA cos 30 sin A OZ, NM = OMsm NOM = OA sin 30 sin A OZ, MA = OA s'mAOM = OA cosAOZ : whence, dividing each by OA sin A OZ, the coordinates of A may be taken as on axis X; cos 30 or 0.866 ; on axis .F; sin 30 or 0.5; on zxisZ; cotan .4 OZ: where cotan AOZ \ tan (ioo-iii), an angle which measures the characterising element of the particular crystal (Art. 457). Similarly, after dividing by OA sin A OZ as before, the co- ordinates of B are found to be on axis OX ; 0-866 ; on axis OF; 0-5; on axis OZ ; cotan A OZ : and the coordinates of C are on axis OX ; o ; on axis OF; i ; on axis OZ ; cotan A OZ. The positions of the projected axes of the hexagonal crystal can now be determined by means of the crystallograph ; lengths cor- responding to the above coordinates are measured along the projected cubic axes, the unit being in each case determined by the limb along which the measurement is made (Art. 466). (c) Oblique systems, (i) For the graphic representation of a crystal in the Monosymmetric system by aid of the crystallograph, the directions of the J^-axis and of the Z-axis are identical in the projections of the crystal and of the cubic axial system, and that of the Z-axis is retained in a vertical position. The elements of the monosymmetric crystal being a\b\c, TJ, it is necessary, as in the last Article, to find the rectangular coordi- nates of A, B and C relative to the cubic axes OX, OF, OZ, where i i 2 4 8 4 Representation of crystals. OA=a, OB = b, OC = c and AOC = rj. If AH be drawn parallel to OZ meeting OX in H (Fig. 383), it will be seen that the coordinates of A in space are on axis A, OH = OA cos (rj - 90) ; on axis Y, o ; on axis Z, HA = OA sin (77 - 90). The coordinates of B are on axis X, o ; on axis Y, b ; on axis Z, o. The coordinates of C are on axis A", o ; on axis Y, o ; on axis Z, c. By measuring along the limbs of the crystallograph lengths representing these coordinates, the projected axes of the mono- symmetric crystal are de- termined as in the last Article. (2) The projection of the axes and parameters of an anorthic crystal can best be obtained by finding the values of the coordi- nates for a point at para- l 33 ' metral distance from the origin for each axis. The Z-axes for the cubic axial system and the anorthic crystal may be taken as vertical, and the A-axis of the crystal may be taken to lie in the plane ZX of the cubic system. Let the cubic axes as projected be X' Y r Z '. The elements of the anorthic crystal being a : b : c, f, 17, let OH, OK, OL be the parametral lengths of its axes. The axial angles of the crystal are f, 77, f, and the angle of 6 between the planes HOL, KOL = i8o-A, A and B being the poles of the faces 100 and oio ; we have also, for the determination of the value of 6, the expression where S= cos S cos (S Projection of the axes of an anorthic crystal. 485 OH lies in the plane XOZ: drawing HS parallel to ZO and meeting the axis OX in S, we have (Fig. 384) i. for the point H the coordinates in space on the ^XT-axis OS = OH cos SOH = a sin rj, jT-axis o, Z-axis SH = OH sin SOH = a cos r? ; ii. for the point K, draw the line KR perpendicular to the plane XOY and meeting it in R\ draw RT perpendicular to OX and meeting it in T, then OR = 6>^cos ROK = OK sin KOL = b sin Fig. 384. Further, 7Y9 and 7?0 being both perpendicular to OL, the angle TOR is the angle between the planes TOL and 7?0Z, that is, the supplement of the angle between the planes HOL and KOL. Hence TOR = AB. We thus have for the coordinates of K, on axis X, OT= OR cosKOT= -sin f cos ^^, r, RT= OR$mROT = + sin f sin ,4 , Z, RK = OK cos KOL = b cos ; and iii. for the coordinates of the point L we have, on the axes of X and Y, o, on the axis of Z, c. Measuring these lengths along the limbs of the crystallograph, the projections of OH., OK, OL are immediately determined. 472. Projections of twin-crystals. In drawing a twin-crystal three preliminary steps have to be taken. We have to determine by the 486 Representation of crystals. Fig. 385. above methods the axial system for one of the individuals as seen in projection ; next the twin-plane has to be represented ; and, finally, the axial system for the second individual has to be determined. We may first suppose the two crystals in apposition, and the twin-face to be the face of combination. We now need to find the position of the twin-axis relatively to the axial system of crystal No. I, or, which is the same thing, to find the point in which this axis meets the twin-face to which it is the normal. Let the twin-plane parallel to the face hkl intersect the actual axes in H l K^ Zj ; and let the twin-axis, the normal to the plane H^K 1 L^ J meet the plane itself in the point D l (Fig. 385). By the aid of the crystallo- graph it is possible, as already explained, to determine OH, OK, OL, the projections of O l ff 1 , O^K^ O l L l : it is now requhed to find OD, the projection of the normal O i D l . Join D l to the angles of the triangle ff l J l L l) and produce the lines to meet the sides of the triangle in M 1 N^ R l , respectively. By calculation or construction, determine the ratios K.M.-.M^L^ L^N.-.N^H^ H.R,: R,K,. These ratios being unaltered by parallel projection (Art. 466), the projected points M, JV, R can now be found by dividing the projected lines KL> LH, UK in the same proportion. The intersection of the lines HM, KN, LR is the projection D of the extremity of the twin-axis. 473. When the axes are rectangular the construction of the above ratios is simple, for the lines O 1 M v O l N v O 1 R l are then perpendicular to the lines K^ Z 15 Zj H v H, K^ respectively, as may be thus proved : K l Z x being the line of intersection of the planes ff l K^ Z x and O l K^ L^ is perpendicular to the lines O l D l} O H^ , normal to those planes, and is thus at right angles to the plane HI O l Z> x and to every line in it ; hence K Z x is perpendicular to 6\ M l : similarly Z a H^ is perpendicular to O l N^ , and H^ K l to O.R,. Projection of a twin-crystal. 487 To construct the ratios we may proceed as follows : con- struct three triangles k^ o l / x , ^ Q I h^, h^ o^ k^ equal to the triangles K^O.L^, L^O^H^ H^O^K^ as illustrated in Figs. 386 a, b, c\ draw the perpendiculars o l throuh in the respective triangles draw lines ^ /, / a h, h^ k having lengths identical with those of the projected lines KL, LH, HK; join / a /, h^h, k^ k Fig. 386 (a). Fig. 386 (J). and draw their parallels m^ m, n^ n, r l r. The positions of the points 71/5 N, R on the sides of the triangle HKL are then deter- mined by setting off lengths KM, LN, HR equal to the lengths X' x m, /j n, h^ r. 474. In order to represent the axial system of crystal No. II, we have recourse to the following construction : Project the axial system for crystal No. I (Fig. 387). Deter- mine on the axes the parametral lengths OA, OB, OC for the face of the form { 1 1 1 } belonging to the octant, and also the inter- cepts OH, OK, OL of the twin- plane hkl. Find the normal OD of the plane HKL, meeting HKL in D, and continue OD to (/ making ig. 387- DO' = OD. Then (/ will represent the origin of the axial system of crystal No. II ; and if O'H, O'K, &L be drawn they will repre- sent in projection the directions of the axes OX' , OF, OZ f of the 488 Representation of crystals. axial system No. II, and they will further represent on those axes the parameters of the plane HKL. If now through A,JB and C, the parametral points of a plane of the form {in} in crystal No. I, parallels to O O f be drawn cutting O'H, UK, (/L, in A', B\ C', these last points will be the points in which the corresponding plane of the form {in} of crystal No. II will meet its axes, O'A', O'B', O'C', being the parametral lengths as represented in projection. The actual face of the form {in} represented by the plane A' B f C' and the axial octant within which it lies will have opposite signs to those for the face ABC of crystal No. I, since the two crystals are conceived .in parallel orientation previous to the assumed rotation of one of them round 0', so that the plane A' B' C' would before and after the rotation lie in an octant opposite to that on crystal No. II which contains the face with the same symbol and signs as (hkt) on crystal No. I. 475. The various kinds of twins will require the axial systems for the two individuals to be transferred relatively to each other into new positions, though their orientation relatively to the direc- tion of the twin-plane and twin-axis is not altered. Thus for an interpenetrant twin the origin for both crystals may be at the same point, or for the one crystal the points and 0' may be slightly removed from each other along the direction of the line OD. For the condition of juxtaposition, the parallel shifting of the axial system for crystal No. II will be such that C/ D f is parallel to OD. In every case the new axes for crystal No. II are parallel to the directions just found for the axes of that crystal. It may happen that we wish to project the two crystals on a plane perpendicular to the twin-face, this face being then repre- sented in the figure by a line through D perpendicular to OO'. The line thus representing the twin-plane is usually, in such a projection, taken as a vertical line. 476. General rules. For the projection of a given crystal we have to first ascertain the requisite data ; which are, the sym- metry and the system of the crystal, its parameters, the forms it presents, and approximately the relative magnitudes with which the faces of these forms are developed on the crystal. General rides. 489 It is in fact very desirable, and indeed, if the crystal presents several forms, necessary to have a free-hand drawing of it, con- structed with sufficient care and accuracy to show the relative im- portance of the faces, and the consequent developement of the edges in which the various minor forms meet with each other and with the more important forms. It will be necessary however in all cases to commence by laying down the axial system in projection by aid of the crystallograph. The axes should be drawn in considerable extension, the para- meters and the intercepts for important faces being marked off at some considerable distance from the origin. If now the edges of two or three of the most prominent forms be drawn on this larger scale and the intersections of the faces of these forms with one another be determined, we have lines of appreciable length, to which the shorter lines nearer to the origin that are actually to represent these edges in the drawing can be made parallel with great accuracy. The edges formed by faces of less conspicuous forms, which are generally those with more complex symbols, and on this account often more numerous from the symmetrical repeti- tion of the faces, can also be now drawn in over the lines repre- senting the edges of the first drawn forms. 477. In order however to make any advance we have to be able to determine the direction of the edge for any two faces. For this we may find the lines in which the two planes severally would intersect the axial planes. Let the two planes (hkl) and (pqr) intersect the axes in HKL and PQR (Fig. 388). HK and PQ lie in the plane OHK, and if produced will meet in a point U unless both are parallel to an axis. So also RQ and KL will meet in a point S, and HL and PR in a point T; and the points S, T, U are all points common to the planes hkl and pqr t and will lie in a straight line which is the edge of intersection of those two planes. Another method, and in general the most satisfactory one, is really a particular case of the preceding. Since the direction of a plane depends, not on the absolute, but on the relative values of the intercepts, and the three intercepts of any plane on the axes may be multiplied by any arbitrary number, the intercepts of the two planes of which the edge is required should be so multiplied that the two 490 Representation of crystals. intercepts on one of the axes say the ^T-axis are identical for both planes. The points corresponding to T, [7, P and H then coincide, say at H f (Fig. 389), and a line joining this point to the Fig. 388. Fig. 389. point of intersection of lines QfR' and K'L', corresponding to QR and KL, will have the direction required. Thus for the planes (362) (313) the intercepts of the first plane on the axes will be in the proportion -:-:-or2#::3r; those of the second plane will have the ratios - : - : , or a : 3 b : c. If O J the second set be doubled, the intercepts of the second plane will be 2 a, 6<5, 2c. Hence, taking OH', OK', OL', OQ', OR', as 2 a, b, 3^, 66, 2c respectively, draw Q'R' and K'L' ; the line H' S' , joining S' their point of intersection to H' t has the direction required (Fig. 389). And of course the direction of the edge may be likewise found by determining the coordinates of a point in the edge considered as an origin-edge. Thus [uvw] being the symbol of the edge, take off (Fig. 390), OU on axis X u, WU=^. Then OP is the normal to the projection-plane, which may be any plane arbitrarily chosen but must intersect 017, 0V, OW giving intercepts Ou, Ov, Ow : OP is inclined on those normals at known angles, viz. (3, POW=y. Then Ou = --, Ov = cos a cos/3 cosy vw = r cos a Vcos 2 /} + cos 2 y 2 cos /3 cos y cos \j/, wu = r cos /3 >v/cos 2 y + cos' 2 a 2 cos y cos a cos $, uv = rcos y \/cos 2 a + cos' 2 /3 2 cos a cos /3 cos 6, expressions by the aid of which the points u v w and P can be projected on the surface of the drawing which is the plane of pro- jection. The plane selected for the purpose, and which is deter- mined in relation to the crystal by the angles a, /3, y, is arbitrary, but usually so chosen as in each different system to exhibit the zones belonging to at least one systematic triangle ; the normals for reference being also selected so as to enable these zones to be laid down within convenient limits. If a sphere of radius r be supposed described round as centre and a great circle pass through two poles or other points A' and B f on the sphere, these points will lie on a straight line upon the plane of projection, which will be the projection of the great circle ; and, 494 Representation of crystals. if the points be poles, will be the projection of their zone-plane and zone-circle. 482. To measure the angle between two lines of which the points of projection .are given. P being the centre of projection, let A B be the line on which 7) JB A the two P oints A/ and B ' are projected in A and B (Fig. 392). Then lies on a line vertically over P, and AOB is the actual angle at between the two normals OA / OB' . In order by a graphic method to measure this angle it will be requisite to lay down a triangle congruent with A OB on the lg ' 3 9 2 ' plane of the drawing. Through P draw a perpendicular to AB, produced if necessary, and meeting AB in D; also a line Pa> r, perpendicular to PD : join Z>co, and on DP or its continuation take Ii such that The triangle DOP will evidently coincide with the triangle if it be turned on its edge DP till falls on oo, and Similarly the triangle DO A becomes coincident with D IA after turning round AD, and the angle DIA is the same angle as D OA which is measured in the projection by the line AD. Hence the angle between any lines represented by points on the projected line AB is the angle between two lines joining these points with a point H found by the above construction. 483. Two zone-planes being projected in CA , CB, intersecting in C, to find the angle of their inclination ; or. conversely , given one zone- plane in projection, to project a second zone-plane tautohedral with it at a given angle in a pole C given in projection. If OC be supposed drawn, and also PC, and a perpendicular to PC and therefore to the plane OPC, be drawn through P inter- secting the two zone-projections in A and B, and continued to o> at a distance = r from P, it will be seen that the triangle Pa>C will be congruent with the triangle POC if the latter be turned round PC till it falls on the projection-plane. Gnomonic projection. 495 If now K, outside the plane of the paper, be the point in which a plane AKB would be intersected by OC perpendicularly, the angle AKB would be the angle of the edge OC formed by the two zone-planes OA C and OB C. Draw PD a perpendicular to Co) (Fig. 393) ; the line PK being perpendicular to OC would fall into congruence with PD when the triangle POC falls on the projection- ^ plane, after rotation round PC. In PC take P& = PD, and draw Then the triangle AKB when turned round AB till it falls on the projection- plane is congruent with AQJB, and the angle ALB is the actual angle Fi g- 393- between the zone-planes CA, CB. Hence the simple graphic con- struction by which PD, and thus Pl, is determined enables us to find the angle between any two zones intersecting in C, or to project a zone intersecting a zone given in projection at any required angle. 484. In the application of these artifices of construction to the projection of a crystal, that is to say to the projections of its zone- planes, it is clear that the area included in the projection must be so limited as not to embrace zones which by their angular distance from the centre of projection would be represented by lines too far removed from that centre. A distance representing 90 of angular measurement from P is infinite in length, and therefore an area the greatest diameter of which would represent an angle not larger than about 45 on each side of P, or 90, is as large as can be conveniently employed. This area of projection needs further to be so chosen as to exhibit as far as possible the essential features of the crystal in regard to symmetry : and for this a systematic triangle or a group of these naturally presents itself as offering the conditions required. In the Ortho-symmetrical systems an octant bounded by three systematic planes, and in the Hexagonal system two adjacent sys- tematic triangles included by two planes -S 1 and the plane C, are the usually projected portions of a crystal. 496 Representation of crystals. The normal OW would in the Ortho-symmetrical systems be the Z-axis [ooi], and in the Hexagonal system the zone-axis [in] ; U and V would be normals lying in the zone-plane [ooi] or [in], in the two cases. The intersections of two of the 2- or two of the ^-systematic planes with this zone-plane are conveniently taken for the two normals in the Cubic, Tetragonal and Hexagonal systems ; and, in the Orthorhombic system, the axes X and Y, or two normals sym- metrically situate in regard to X or Y. The projection-plane is in all such cases taken more or less symmetrically with regard to the normals OU, 0V, OW, and therefore in some cases is not a crystal- face. W V Fig. 394- Fig. 395. Thus in all the systems in which three perpendicular normals are allowed by the symmetry we may take < = ^ = , and the plane uvw as equally inclined on the normals OU and 0V. The centre of projection P will lie on WL, L being the middle point of UV. then cos a = cos/3 = sin y cos 1 = sin y cos e ; and in Fig. 394, WL = sin y cos 7 OL = smy tan UWL = : 7 = tan e cos y. tan 6 siny The triangle UVW can be constructed by the aid of this last ratio. PL r sinycosy_ 2 WL ~~ tan y r Also, Gnomonic projection. 497 so that P can be found on WL, _PW_PU PU "" 5 r PW In the Cubic, Tetragonal and Orthorhombic systems the angle c is taken as 45. Generally y is taken = 45 and cosy = ? V 2 /. cos a = J and a = 60. Then, 7Z= - ^ PZ = i PFZ, P*7 = V 2 If however we take a = (3 = y and 6 = 45, then, Fig. 395, P7=/>F=PPF; cos a = sin a cos 45, tan a = A/2, a =54 44i'5 V3 In the Hexagonal system e = 30. Here cos y is taken = -= ^3 Then cos a = and a = 45. v 2 UL = IWL=PL; PU= ^2 PW. 485. One of the advantages of the gnomonic projection lies in its application to the drawing of crystals in orthogonal projection. The lines in a gnomonic projection are the projections of zone-planes, and therefore the edges of the faces belonging to any zone are per- pendicular to the line in which the zone-plane is projected ; so that the projections of all the edges of a crystal can be drawn in the directions they would have were the crystal projected orthogonally on the plane taken for the gnomonic projection-plane. 486. To obtain a gnomonic projection corresponding to the axes used in Art. 470, we proceed as follows. Let the rect- angular axes fixed in space and passing through the centre of the sphere be OX, OZ, respectively horizontal and vertical, parallel to the plane of the paper, and OF perpendicular to the Kk 498 Representation of crystals. plane of the paper (Fig. 397). Let the paper remain fixed, and the cubic axes OA, OB, OC, which initially coincide with OX, OY, OZ, move under it by first a rotation 6 about OZ and then a rotation e about OX. The first rotation brings the pole (oio) to v where PB 1 = rtanb along the horizontal line; the pole (ooi) remains at an infinite distance along the vertical line PZ, and (100) travels from an infinite distance towards P along the horizontal line. The second rotation brings (oio) to B, found by taking PQ = rtane, and $#=rtan8, as may be seen from the construction in Fig. 396, where OQ = - -, QOB = POB l = 8, rtand cose QB = OQ tan 6 = cose \ Fig. 396. Fig. 397- The line BQ is then the zone-line [oio, 100]; BD the zone- line [oio, oo i ] may be drawn as a line inclined to BQ at an angle representing 90 by the construction given in Art. 483. The poles (100) and (oio) may then be set off along these lines at distances BA, BC, representing 90 by the construction given in Art. 482. The above projection may be more conveniently drawn directly from the crystallograph by drawing the lines CA, CB perpendicular to the B and A arms of the latter respectively and setting off a dis- tance CP = r cote along a line parallel to the C arm (Fig. 397). Then through Q t where PQ = r tan e, draw BA perpendicular to CQ\ ABC are then the extremities of the rectangular axes, or the poles (100) (oio) (ooi) in the Cubic, Tetragonal, or Orthorhombic Drawing implements. 499 systems. The complete projection for a crystal belonging to either of these systems is constructed by laying down the poles of (no) (on) (101) upon the sides of the axial triangle at distances corresponding to their inclinations to ABC. The rhombohedral or hexagonal projection may be derived from the triangle by taking ABC as the poles (iol) (ill) (m) respect- ively, and laying down other poles upon these zones by their angular distances from ABC. The projection of a monosymmetric crystal is obtained by taking C (ooi) at a distance from B repre- senting the angle (100:001) along the line BC, and then laying down other poles in the axial zones as before. The projection of an anorthic crystal is obtained by taking B^ (oio) at a distance from A, representing the angle (100:010) along the line AB and drawing the zone-lines B^ C l and AC^ such that their inclinations to AB represent the angles 77 and f respectively ; and finally laying down other poles in the axial zones as before. 487. Drawing implements. It remains to notice the implements and materials requisite for carrying on the processes described for the projection of a crystal. Good smooth drawing paper or card is the best material on which to carry out the drawing. If paper is used it should be mounted on a drawing board, and be fastened thereto at the corners by a little gum. It should be of sufficient size for carrying out the projection of the axial system of the crystal with axial lengths equivalent to from 5 to 10 inches according to the complexity of the crystal to be drawn. It is generally well, where many faces have to be represented, to draw the crystal-projection at some little distance away from the axial projection obtained by aid of the crystallograph, as already pointed out, and even sometimes to project more than one such subsidiary axial system, all of course in absolutely parallel orienta- tion with one another and with the corresponding lines in the crystal. This, and indeed the ruling of all ordinary straight lines on the drawing, is best effected by help of two similar flat pieces of vulcanite or thin steel, each in the form of a triangle with angles of 90, 60 and 30, and having a hypotenuse 7 or 8 inches long ; K k 2 500 Representation of crystals. for many figures a length of 2 or 3 inches is however sufficient. The sides of the triangles should be as straight as they can be made: the two implements when used together, the hypotenuse of one sliding in contact with that of the other, form an excellent parallel ruler. Pencils of various degrees of hardness and blackness are needed, and they must be used with a very fine point. In use, fainter lines are employed for the purely structural lines, that form as it were the scaffolding of the projection, and these can be rubbed out when the final lines representing the complete drawing have been introduced. A hard pencil, as dark as is consistent with hardness and the retention of a fine point, is needed for the last process, unless a ruling pen with Indian ink is substituted for the pencil. The pen or pencil should lean away from the face of the ruler so that the point may be in close contact with the edge formed by the ruler and the paper. The dotted or broken continuity of line that is employed to indicate the edges of the back-half of the crystal needs an even and careful use of the pen or pencil point to give it uniformity, and the delicacy requisite to prevent its obtrusion on the eye. The simplest way of introducing this representation of the back-half of the crystal is that of the use of tracing paper already described. The projected front-half is traced through and on to the tracing paper, and this traced figure is then turned round in its plane through 180 till corresponding points on it and on the original projection are brought to meet; the quoins are then pricked through on to the paper below : finally, these are to be joined by dotted or interrupted lines. This method of course only applies to diplohedral figures. In others the back-half of the crystal has to be drawn by the same methods as the front-half. Where the method of tracing can be applied it is of great advantage as a test of the accuracy of the original drawing, since all the parts of the one figure ought to join to and exactly meet with the corresponding parts of the other. It is necessary to use tracing paper for this and for transferring a drawn figure to a plate on which it is to be engraved, since the thickness of drawing paper is sufficient to displace points pricked Transference of the figure. 501 through it from their true position, owing to the difficulty of passing a needle-point quite perpendicularly in every case. For transference we may also use a coloured under-surface to the tracing paper, on which a little rouge for instance has been rubbed ; after laying the tracing on the sheet of paper or plate of metal or stone to which it is to be transferred, the lines are gone over with a hard point and a ruler, and are thus impressed on the surface below. Where the figure has to be reversed, as for direct engraving or lithographing, the tracing has, of course, to be turned over and the figure reversed on the surface that is to be engraved or litho- graphed. DESCRIPTION OF THE PLATES. THE Plates I to VIII represent in stereographic projection the poles of a general independent form under all the varieties of mero-symmetry required by the symmetrical conditions of the six crystallographic systems. The total number of holo-symmetrical and mero- symmetrical types is thirty-two ; they are numbered consecutively in the table given below. Some of the hemi- morphous forms, as being readily deducible from those in the Plates, are not represented in the projections, and the two types belonging to the Anorthic system are too simple to require representation ; the omitted types are marked with an asterisk in the table. The plan on which the projections are arranged has been described in Article 149, p. 168. The merohedra corresponding to those forms of which the poles lie in, and the faces of which are perpendicular to, systematic planes of which the symmetry is in abeyance, in most cases reveal their mero-symmetrical nature in the physical characters of their faces. In the Plates the projections of proto-systematic planes are indicated by darker lines than those of deutero- systematic planes. A trito-systematic plane is taken as the plane of projection. Subjoined is a list of the thirty-two types of symmetrical forms, and one or two examples are given in each case of substances whose crystals present that particular type of symmetry, where such are known to exist. PLATE I. CUBIC SYSTEM. Holo-systematic forms. 1. Holo-symmetric (p. 201) . {hkl} fluor. 2. Haplohedral (p. 207) . a {hkl} cuprite. 3 (p. 212) . {hkl| scheelite, stoltzite. 11. Haplohedral (p. 262) . sa {hkl} (no example known). 12 ...... (hemimorphous) (p. 263) . pa {hklj wulfenite. PLATES IV-VII. HEXAGONAL SYSTEM. Holo-systematic forms. 13. Holo-symmetric (p. 276) . {hkl, efg} beryl. ,4. Haplohedral (p. ,87) . a {htl, efg} 5 ..... (P. 89). {hkl}, .{efg}, or f {hkl, efg} \ r^ii ri i greenockite ; silver *io ...... (hemimorphous) (p. 292) . p {hkl, efgj < . ... Hemi-systematic forms. 17. Diplohedral (p. 293) . TT {hkl} . . . .(p. 29 8) . ^ { hkl } 18 ..... (p. 299) . < {hkl, efg} apatite. 19. Haplohedral (p. 302) . aw {hkl} quartz; calcium dithionate. 20 ..... (p. 304) . x

rr{hkl} or p^ {hkl} tourmaline. *22 ...... (hemimorphous) (p. 307) . p^ {hkl, efg} nepheline. Tetarto-systematic forms. 23 Diplohedral (p. 307) .7rjhkl} or $$ {hkl, efg} dioptase, phenakite. *24. Haplohedral (hemimorphous) (p. 308) . pir {hkl} sodium meta-periodate. Description of the plates. PLATE vm. ORTHO-RHOMBIC SYSTEM. Holo-systematic forms. . Holo-symmetric (p. 333) . {hkl} barytes. 26. Haplohedral (p. 336) . .a {hkl} 27 (hemimorphous) (p. 337) . />{hkl}, ^{hkl} or {hkl} hemimorphite, struvite. MONO-SYMMETRIC SYSTEM. Holo-systematic forms. 28. Holo-symmetric (p. 354) . {hkl} augite. 29. Haplohedral (p. 358) . . s{hkl} scolecite. 30 (hemimorphous) (p. 359) .a {hkl} lactose. ANORTHIC SYSTEM. *3i. The Holohedron (p. 372) . {hkl} axinite. *32. The Hemihedron (p. 373) .a {hkl} calcium thiosulphate. The holo-symmetric form of the Hexagonal system, not represented on Plates IV- VII, is given in the adjoining figure on a scale somewhat larger than that of the projections in the Plates. Fig. 398. PLATE I." CUBIC SYSTEM. 505 The hexakis- -octaliedran. CTTTJkhl} JTjJlklJ Ll PLATE II. TETRAGONAL SYSTEM. The scalene - - dioeialiedinuL. PLATE III. TETRAGONAL SYSTEM. uaoi 57 The scalene - dio ciate dron. cr|ldal{ Hemi-clioctahearon. f ILeminior ph ons Hcmim.ojpphoTis - scalenoKedron. - dio c t aliedr oix. Ll 2 508 PLATE IV. HEXAGONAL SYSTEM. For the Discalenohedron {hkl, efg} see Fig. 398, p. 504. AM ^ ttigonoJiedron. - S-^rpramid. 509 PLATE V. HEXAGONAL SYSTEM. -trapexohcdron s calenolie dr on . JT{efgj PLATE VI. HEXAGONAL SYSTEM. PLATE VIL HEXAGONAL SYSTEM. AM scalenoliedrou.. PLATE VIII. ORTHO-RHOMBIC SYSTEM. The scalene - - octahedron. The rhombic sphenoid. - henri- octahedron . MONO-SYMMETRIC SYSTEM. INDEX. The numbers refer to pages. Abeyance of symmetry-planes, 165. Abortive symmetry, 118. Actual symmetry, 106. Adjacent octants, 16. Adjustment of crystal, 404. Adjustment of goniometer, 394, 409. yEolotropy, 13. Albite, 176, 1 81, 374, 376, 379, 380. Alexandrite, 185, 347. Ambiguity of indices, 52. Analysis of forms, 168. Analytical investigation of the zone- law, 65. Anatase, 265. Angle between two planes, 21. Angles of axes of a crystal, 16. of twins, 181. Anharmonic ratio of four planes, 58, 71. Anharmonic ratio, rationality of, 58, 7 1 . Anhydrite, 346. Anorthic system, 370. calculation, 427. combinations, 373. twins, 375. Anorthite, 375, 376, 387. Antihemihedrism, 170. Antistrophe, 99. Apatite, 312. Apophyllite, 172. Aragonite, 184, 343, 347. Argentite, 193, 200. Arsenic, i. Arsenious anhydride, 2. Arzruni, 198. Asymmetric semiforms, 207, 223, 254- Attingent octants, 16. Augite, 36, 365. Axes are crystalloid lines, 91. Change of, 80. Axes of a crystal, 15. of hexagonal system, 471. of magnetic induction, 13. of tetragonal crystals, 259. Projection of, 479. Axial-disphenoid, 255. forms, 249. isosceles octahedron, 250. point, 27. sphenoid, 256. square prism, 251. Axial-system, 27, 112. for hexagonal type, 135. Axinite, 90. Axis of symmetry, 99. morphological, 5. Barium nitrate, 231. Barytes, 343. Basal pinakoid, 336, 358, 372. Bauer, 377. Baumhauer, 6, 266. Baveno-twin, 369. Ben-saude, 198. Bertrand, 239. Beryl, 298, 309. Bevilment of edges, 70. Bismuth, i, 320. Blende, 166, 172, 179, 195, 197, 210, 211, 212, 224, 226, 227, 235. Boracite, 2, 186, 226. Bournonite, 343. Bravais-symbols, 471. Breithaupt, 381. Brezina, 227, 380. British Museum, 180, 222, 223, 226, 2 34> 2 4i> 3 2 5> 329, 34 T > 35, 3 62 , 366, 37* Brochantite, 377. Bronzite, 364. m Index. Calcite, 6, 9, 54, 172, 319, 320, 321, 34 2 . Calculation of crystals, 417, 425. Camphor, I. Carlsbad-twin, 176, 366. Cassiterite, 265, 268. Cathrein, 185. Centre of symmetry, 98, 99. Centre-symmetry, 100. normal, 17. Cerussite, 351. Chabazite, 322. Change in solid condition, Crystallisa- tion by, 2. Change of parametral plane, 80. Chromite, 193. Chrysoberyl, 185. Circle of projection, 29. symmetry, 101. Cleavage, 7. Clinodome, 357. Clinopinakoid, 358. Clinorhombic system, 352. Cobaltine, 215, 217, 227, 229. Coefficients of elasticity, 5. Cohesion, 5. Coincidence of zone-axis and plane- normal, 95, 112. Combination-plane, 174. Combinations, Anorthic system, 373. Cubic system, 219. Hexagonal system, 309. Mono-symmetric system, 360. Orthorhombic system, 339. Tetragonal system, 264. Composite crystals, 172. symbol, 143. Condition for mero-symmetry, 107. several planes of symmetry,! 09, 117. tautozonality, 49, 67, 68. Conductivity, Thermal, IT. Conformable symmetry, no. Congruent heterozonal symmetry- planes, 144. Congruent symmetry, no. Connellite, 310. Contact-goniometer, 388. Copper, 192, 193, 197, 221, 222, 234. Copper glance, 184, 346, 351. pyrites, 266, 270. Correlative semiforms, 143. Cromfordite, 265. Crystalline condition, I. Crystallisation after mutual decompo- sition, 2. from fusion, i . Crystallisation from solution, I. from sublimation, I. in the solid condition, 2. Crystallograph, 481. Crystallographic calculation, 417. elements, 4, 27. systems, 4, 150. Crystalloid plane-system, 25, 157. symmetry, 101. Crystallometric angles, 77, in. Crystals, i. as crystalloid polyhedra, 156. Morphological characters of, 3, 103. Physical characters of, 5. Cube, 146, 191. Angles of, 456. Cube-pyramidion, 195. Cubic system, 188. calculation, 453. holosymmetry, 188. merosymmetry, 204. Projection of, 479. Relation of, to trigonal and hexa- gonal, 151. Cubo-octahedron, 28. Cubo-octahedron symmetry, 146. Cuprite, 180, 192, 193, 197, 198, 220, 223. Dana, 227. Datolite, 361. Deformation of crystals, 6. De 1'Isle, 228, 388. Deltoid-dodecahedron, 210. Derivation of determinants, 50. Des Cloizeaux, 181, 366. Designations for planes, 20. Determinant-symbols, 50. Determination of Crystallographic ele- ments, 434. twin-plane, 182. Deutero-disphenoid, 257. dome, 334. hemioctahedron, 338. pinakoid, 336. prism, 283. rhombohedron, 298. scalenohedron, 298. systematic planes, no. Diagonal disphenoid, 257. forms, 249. isosceles octahedron, 251. sphenoid, 258. square prism, 252. symmetry, 98, 99, 121. Diamagnetism, 13. Index. 515 Diamond, 172, 179, 192, 193, 195, 221, 226, 232, 239. Dihedral angle, 4, 21. Dihexagonal prism, 278. scalenohedron, 142. Dilatation, Thermal, II, 112. Di-n-gonal symmetry, 102. Dioctahedron, 246, 259. Diopside, 60, 361. Dioptase, 314, 317. Diplohedra, Hemitesseral, 213. Diplohedral form, 105, 160. Diplohedron, 213, 229. Angles of, 462. Direct forms, 141. rhombohedra, 312. Direction- cosines, 18. Directions of planes, 17. Dirhombohedron, 279, 280. Discalenohedron, 276. Disphenoid, Tetragonal, 255, 257. Ditetragonal prism, 248. scalenohedron, 247. Ditrapezohedron, 287. Ditrigonal prism, 294. proto-prism, 290. proto-pyramid, 289. scalenohedron, 293. symmetry, 133. Dodecahedrid pyramidion, 201, 204. Dodecahedron, 147. Dolomite, 322. Dome, 125. Dome-forms, 356. Drawing implements, 499. of crystals, 488. Ductility, 6. Dyakis-dodecahedr on ,213. Edges, 103. Direction of, 22. Relations of, to normals, 51. Edingtonite, 266. Elastic deformation, 6. Elasticity, 5. Electricity, 12. Electrum, 195, 221. Elements, The crystallographic, 4, 27. Ellipsoid in crystals, 10, II, 13. of magnetic induction, 13. Embedded twin, 1 76. Enantiomorphous figures, 169, 207, 217, 254, 261, 287,302, 308, 336, 359> 373- Enstatite, 342, 364. Epidote, 362, 366. M Equation of an edge, 65. of a plane, 65. Equilateral octahedron, 192. Equipoised polyhedra, 100. Erosion, 8. Error of adjustment, 411. of centering, 401. Etching, 9. Eulytine, 210, 225, 238. Euthy-symmetrical division, 98. Example of signs of indices, 53. of tautozonal problems, 60, 69. of transformation of axes, 88. Expression for an edge, 22. for anharmonic ratio, 57. for a plane, 1 8. for a pole, 41. for a zone, 44. for normal angle, 421. for position of a face, 418. for transformation of axes, 84. Eyelets in projection, 41. Face, 25, 103. of union, 1 74. Face-pole, 41. Faces of a zone, 44. Symmetry of, 151. Factor-Ratios, 47. Fahlore, 210, 211, 212, 224, 225, 226, 227, 235, 237. Felspar, 61, 364. Fergusonite, 267. Fichtelite, 363. Fletcher, 270. Fluor, 192, 193, 197, 198, 199, 200, 220, 221, 222. Form, 3, 101. Forty-eight scalenohedron, 201. Fourlings, 177. Franklinite, 193, 200. Friedel, 227. Fuess-goniometer, 409. Fundamental equation, The, 1 8. laws of crystallography, 157, 161. Fusion, Crystallisation from, i. Galena, 176, 192, 198, 199, 200, 220, 221, 232, 235, 238. Garnet, 195, 198, 200, 210, 220, 221, 222. General properties of crystal, i. scalenohedron, 123. Gersdorffite, 227. Glide-planes, 6. Gnomonic Projection, 492. rn 2 516 Index. Gold, 192, 195, 197, 221, 234. Goniometer, 156, 388. Gothite, 343. Grassmann, 94. Great circle, 27. Pole of, 35. Projection of, 36. Greenockite, 314. Groth, 181, 236, 238, 243, 267, 271, 273, 325, 33i, 471- Gypsum, 361, 368. Gyroidal forms, Hexagonal, 299. hemihedrism, 207. Habit, Merosymmetrical, 170. Haematite, 178. Haidinger, 174, 198, 227, 270. Hand -goniometer, 388. Haplohedral form, 105, 160. hemisymmetry, 359, 373. Hardness, 8. Harmonic division of a zone, 75. Harmotome, 366, 368. Hauerite, 217, 227. Haiiy, 136, 228, 388. Haiiyne, 195. Helvine, 210, 225. Hemi-cyclical conformity, 1 10. Hemi-deuteroprism, 307. Hemi-deuteropyramid, 307. Hemi-deuterorhombohedron, 307. Hemidioctahedron, 259. Hemidiprism, 260, 299. Hemidisphenoid, 262. Hemihedra, Holotesseral, 206. Hemihedron, 159. Hemi-icosi tetrahedron, 211. Angles of, 460. Hemimorphism, 161. Hemimorphite, 344, 352. Hemimorphous crystals, 267, 313, 3 1 ?' 344, 363- dihexahedron, 306. dioctahedron, 259. ditrigonal prism, 306. ditrigonal protopyramid, 306. - forms, 301, 337, 359. hemidioctahedron, 263. hexagonal forms, 292. rhombohedron, 306. tetartohedral forms, 305. trigonal pyramid, 306. tritoprism, 307. Hemi-octahedron, 209. Hemiprotopyramid, 306. Hemiscalenohedron, 307. Hemispheres, positive and negative, 52. Hemi-symmetrical combinations, 310. twins, 318. Hemi-symmetry, 159. Hemi-systematic diplohedral forms, 213, 227, 259, 293, 359. forms, 1 60, 338. haplohedral forms, 217, 261, 302, 338. mero-symmetry, 59. Hemi-tesseral-semiforms, 213. Hemitetragonal diplohedra, 259. Hemi-triakis- octahedron, 210, 226. Angles of, 458. Hemi-tritopyramid, 307. Hemitropic crystals, 173. Hessenberg, 185, 225. Heterozonal congruent symmetry planes, 144. poles, 45. Hexagonal axes, 135. deuteroprism, 283. dihexahedron, 279, 281. diprism, 278. hemi-symmetry, 163. prism, 281. protoprism, 283. pyramid, 279, 281. symmetry, 98, 99, 134. system, 273. system, calculation, 463. system, combinations, 309. system, holosymmetry, 273, system, mero-symmetry, 283. system, Projection of, 482. system, twins, 318. type of symmetry, 1 34. Hexahedron, 191. Hexakis-octahedron, 201, 221. Angles of, 460. Hexakis-tetrahedron, 212, 226. Angles of, 461. Holohexagonal haplohedra, 287. Holo-symmetrical combinations, 309, 339. 36o. forms, 331, 352, 370. twins, 318. Holo-symmetry, 158. Holo-systematic form, 160. Holo-systematic haplohedral forms, 207, 254, 285, 337, 358. hemihedra, 336. mero-symmetry, 358. Holo-tesseral hemihedra, 206. Holotetragonal semiforms, 254. Homogeneity, 13. Inaex. 517 Homologous poles and planes, 101. positions, 324. Hornblende, 361, 365. Humite, 347. Iceland-spar : see Calcite. Icositetrahedron, 197, 220. Angles of, 459. Idocrase, 172. Ilmenite, 314, 317. Impact-figures, 7. Independent plane and pole, 101. Indicatrix, The optical, 10. Indices, 19. Rationality of, 3, 25, 157. Induction, Magnetic, 12. Integral indices, 25. Intercepts, 17. Interpenetrant twin, 176. Inverse forms, 141. rhombohedra, 310. Iodine, i. lodosuccinimide, 267. Irrationality of parametral ratios, 112. 117. Isogonal zones, 75, 77. Iso-parametral axes, 136. Isosceles dodecahedron, 279. octahedra, 249. Isothermal ellipsoid, n. Juxtaposed twins, 175. Kayser, 375, 381, 384. Klein, 187, 406. Koch, 198. Kokscharow, 185. Kopp, 238. Kundt, 12. Kupffer, 392. Kyanite, 377, 380. Labradorite, 176, 376. Lang, 166, 167, 173, 393. Lavizzari, 9. Law of mero-symmetry, 161. of rationality of indices, 3, 25, Lead hyposulphate, 316. nitrate, 210. Leucite, 2, 186. Leucitohedron, 186, 192. Leucitoid, 198. Levy, 380. Lewis, 231. Libethenite, 342. Light, 9. Line of Symmetry, 97. Lustre, 3. '57- Macled crystals, 172. Magnesium sulphate, 342, 344. Magnetic induction, 12. Magnetism, 12. Magnetite, 180, 193, 199, 200, 220, 221, 234. Mallard, 2, 186. Malleability, 6. Manebach-twin, 366. Manganite, 347. Marbach, 231. Measurement of crystals, 388, 415. Mercuric iodide, 2. Merohedral, 159. Mero-symmetrical combinations, 223, 266, 310, 343, 363. crystals, Drawing of, 491. forms, 204, 252, 283, 336, 358, 373. Mero-symmetry, 156, 158. Metastrophe, 99. Microcline, 380 . Miers, 223. Milk-sugar, 345. Miller, 80, 94, 136, 166, 382, 393, 475. Mimetic crystals, 185. Mispickel, 342, 347. Mitscherlich, 392. Models, 474. Mohs, 228, 381, 384. Molecules, Position of, 171. Monosymmetric system, 352. calculation, 436. combinations, 360. twins, 364. Morphological axis, 5, 128. Morphological characters of crystals, 3, 103- Natrolite, 342. Naumann, 228, 272. Necessary conditions for plane of sym- metry, 1 06. Negative hemidome, 358. hemiprism, 372. hemispheres, 52. parahemidome, 372. prismatid, 354. prohemidome, 372. Neumann, 375, 380. Nomenclature for planes of symmetry, no. Normals as axes of zone-planes, 92. Relations of, to edges, 5 1 . Index. Normals to planes, 17, ,21. Notation for factor-ratios, 47. for mero-symmetry, 166. Oblique axes, 114. systems, Projection of, 483. Octahedrid-planes, 20. pyramidion, 199, 220. Octahedron, 20, 146, 192. Angles of, 457. Octaid-planes, 20. Octakis-hexahedron, 201. Octants, 1 6. as quoins, 105. Opposite octants, 16. sides of a pole, 51. Optical characters of crystals, 9. indicatrix, 10. Orientation of axes, 124. Origin, 15. Origin-edge, 25. Origin-plane, 25. Orthoclase, 176, 366, 369, 370, 378. Ortho-dome, 356. Orthogonal hemi-symmetry, 164. projection, 475. type of symmetry, 121. Orthographic projection, 28. Orthopinakoid, 358. Ortho-prism, 355. Ortho-rhombic system, 331. calculation, 446. combinations, 339. twins, 345. Ortho-symmetric systems, 331. calculation, 441. Projection of, 482. Ortho-symmetrical division, 98, 121, Pajsbergite, 342. Parahemidome, 372. Parallel projection, 474. Parallelism of faces, 105. Paramagnetic, 13. Parameters, 19, 21. Change of, 80. Parametral hemidome, 358. hemiprism, 372. plane, 19. - prism, 355. Parapinakoid, 372. Pentagonal icositetrahedron, 207. Angles of, 462. Pentagon-dodecahedron, 213, 227. Angles of, 458. Pentagonohedron, 207. Periclase, 193. Pericline-twins, 380. Perowskite, 197. Pharmacosiderite, 200, 224. Phenakite, 314, 330. Physical characters of crystals, 5, 104. Piezo-electricity, 12. Pinakoid, 283, 335, 358. planes, 20. Plagihedral forms, 315. Plane, Cleavage-, 7. figures, Symmetry of, 97. Glide-, 7. of projection, 29. of union, 1 74. Symmetry-, 99. system, A, 15. Planes, Mode of expressing, 15. Normals of, 17, 21. of symmetry inclined at 30, 1 34. inclined at 45, 126. inclined at 60, 130. perpendicular, 121. Point, Axial, 27. Polarisation, 9. Rotatory, 315, 344. Pole of a great circle, 35. of a plane, 27. of symmetry, 98, 102. Polyhedron, I, 25. Polysynthetic twins, 1 76. Position of a pole on the sphere, 41. Positive hemidome, 358. hemiprism, 372. hemispheres, 52. parahemidome, 372. prismatid, 354. prohemidome, 372. Potential symmetry, 106. Primitive circle, 29. Prism, 125. Prism-form, 355. Prismatid forms, 334, 354. Prismatoid planes, 20. Problems of tautohedral zones, 62. tautozonal planes, 58, 70. Prohemidome, 372. Projection, 474. of a great circle, 36. of an arc, 33. of a pole, 35. of circles, 31. Sphere of, 27. Propinakoid, 372. Proto-disphenoid, 255. dome, 334. Index. 519 Proto-hemioctahedron, 337. octahedron, 249. pinakoid, 336. prism, 249, 283, 290, 291. pyramid, 289, 291. systematic planes, no. Pseudo-cubic crystals, 186. hexagonal crystals, 185, 341, 347, 348. hexagonal twins, 184, 268. rhombohedral crystals, 361. symmetry, 184. tetragonal crystals, 342. Pyrites, 166, 192, 199, 215, 217, 227, 229, 243. Pyritohedron, 213, 227. Pyritoid minerals, 227. Pyrochlore, 193. Pyroelectricity, 12, 227, 318, 345. Quartz, 12, 88, 172, 303, 314, 322. Quoins, 16, 103. Symmetry of, 153. Rath, vom, 186, 318, 375, 376, 380, 382, 384, 386. Rationality of anharmonic ratio, 58. of indices, Law of, 3, 25, 157. of symbols in twin crystal, 175. of zone-symbol, 65. Ratios, Factor-, 47. Parametral, 19. Ray-surface, 10. Rays, 92. Reciprocity of zone-system and plane- system, 92. Rectangular axes, 113. in hexagonal type, 135. Re-entrant angles, i, 177. Reflection-goniometer, 390. Regular octahedron, 192. solids, 157. Relation of three tautozonal planes, 46, 67. of four tautozonal planes, 55, 70. of edges and normals, 51. Repetition, Symmetrical, 101. Replacement of edges, 70. Representation of crystals, 474. Stereographic, 27. Rhomb-dodecahedron, 193. Angles of, 457. Rhombic prism, 335, 354. section, 382. sphenoid, 336. Rhombohedral system, 298, 309. Rhombohedron, 295. Rose,227, 229, 322,325,375,379,381, Rotatory polarisation, 171, 315. Rutile, 268. Sadebeck, 179, 232, 237. Sal-ammoniac, 223. Salt, 192. Sarcolite, 267. Scalene dioctahedron, 246. octahedron, 333. Scalenohedron, 123. Scheelite, 267, 269. Scheererite, 363. Schrauf, 135, 227, 380, 382, 386. Sclerometer, 8. Seignette salt, 352. Semi-form, 159. Senarmontite, 193. Shear-plane, 7. Sides of a pole, 51. Signs of indices, 19, 51. Silver, 192, 193, 197, 220, 221. Similar edges, 103. faces, 104. planes of symmetry, no. quoins, 104. Simulation of higher symmetry, 184. Skew rhombohedron, 307. trigonohedron, 304. Smith, Prof. H. J., 117. Sodalite, 195, 235. Sodium-ammonium tartrate, 343. bromate, 231. chlorate, 231, 243. - periodate, 308, 314, 317, 330. uranyl-acetate, 231, 267. Solid condition, Crystallisation in, 2. figures, Symmetry of, 99. Solution, Crystallisation from, I. of crystal-faces, 9. of tautozonal problems, 58. Sphene, 89, 362, 366. Sphenoid, Tetragonal, 256, 258. Sphenoidal hemi-symmetry, 337. mero-symmetry, 255. Sphere of projection, 27. Spherical trigonometry, Use of, 27. Spinel, 174, 193, 199, 200, 220. Spinel-twin, 174, 233. Square hexahedron, 191. Staurolite, 346. Steinmannite, 180. Stephanite, 351. Stereographic projection, 27. Stolzite, 267. 520 Index. Striation, 3. Stromeyerite, 346. St diver, 228, 230. Struvite, 344, 352. Strychnine sulphate, 266. Sublimation, Crystallisation from, i. Sulphur, i, 341. Supplementary planes of symmetry, 105. twins, 181. Sylvine, 192. Symbol of a form, 101. of a plane, 19. of a zone, 45. of cubo-octahedral forms, 147. of hexagonal forms, 140. of orthosymmetrical forms, 125. of plane in two zones, 49. of planes with changed axes, 81, 84. of tetragonal forms, 129. of truncating and bevilling planes, of zones with changed axes, 81, 84. Symmetral, 102. Symmetrical twins, 181. Symmetry, 97. Axis of, 99. Centre of, 98, 99. Circle of, 102. Crystalloid, 101. Line of, 97. of crystals, 4, 5. effaces, 151. of quoins, 153. of twins, 181. Plane of, 99. Pole of, 98, 102. Significance of, 171. to one plane, 1 06. Synthesis of forms, 168. System of axes, 15. - The planes of a, 15. Systematic pinakoid, 358. planes, no, 151. projection, 475. triangle, 123, 149. Systems, The six, 4, 150. Tartaric acid, 363. Tartrates, 352. Tautohedral zones, 45. Relations of, 62. Problems of four, 62. Tautomorphous forms, 169. Tautozonal planes, 46, 55. planes, Problems of, 58. Tautozonal planes, Relations of, 55. - poles, 45. Tennantite, 212. Tesseral system, 188. tetartohedron, 217. Tetartohedrism of cubic system, 217, 230. hexagonal system, 301. tetragonal system, 261. Tetartohedron, 159. Tetarto - symmetrical combinations, 3I4- twins, 322. Tetarto-symmetry, 159. hexagonal, 301. Tetarto-systematic diplohedral forms, 307. form, 1 60. haplohedral forms, 308. Tetragonal axes, 128. axial prism, 251. di-sphenoid, 255. hemi-symmetry, 162. isosceles octahedron, 259, 263. pinakoid, 252. scalenohedron, 127. sphenoid, 256, 258. symmetry, 98, 99, 126. system, 245. system, calculation, 448. system, combinations, 264. system, holosymmetry, 245. system, merosymmetry, 252. system, twins, 268. tetartohedra, 261. trapezohedron, 254. type of symmetry, 126. Tetrahedrid mero-symmetry, 208, 254. pyramidion, 211, 224. semi-forms, 208, 223. twelve-pentagonohedron, 217. Tetrahedron, 209. Tetrakisdodecahedron, 201, 204. Tetrakis-hexahedron, 195, 221. Angles of, 457. Tetrakonta- octahedron, 201. Thermal conductivity, n. dilatation, n, 112. Thermo-electricity, 227. Thickness of twin-crystals, 177. Thomson, 399. Topaz, 341. Tourmaline, 12, 172, 317. Transformation of axes, 80. Transverse pole, 141. rhombohedra, 312. Index. Trapezohedron, 302, 314. Triakis-octahedron, 199. Angles of, 458. tetrahedron, 211, 224. Trigonal deutero-trapezohedron, 303. clihexahedron, 297. dodecahedron, 211. proto-prism, 291. proto-pyramid, 291. symmetry, 98, 99, 130. trapezohedron, 302. type of symmetry, 130. Triplings, 177. Trito-diprism, 300. hemioctahedron, 337. pinakoid, 336. pyramid, 299. systematic planes, no. Truncation of edges, 70. Tschermak, 223. Turnerite, 362. Twelve-deltohedron, 210. icoscelohedron, 211. pentagon ohedron, 213. Twenty-four-deltohedron, 197. pentagonohedron, 207. trapezohedron, 213. Twin-axis, 173. Twin-crystals, 173. Projection of, 485. Twin-face, 173. Twin-plane, 173. Determination of, 182. parallel to face of union, 377. perpendicular to plane of union, 380. Twinning on a systematic plane, 1 79. on octahedron-face, 233. on rhomb-dodecahedron-face, 238. on tetrahedron-face, 235. Secondary, 6. Twins, Angles of, 181. anorthic system, 375. cubic system, 232. Twins, hexagonal system, 318. Investigation of, 183. mono-symmetric system, 364. of hemi-symmetrical crystals, 1 78. of quartz, 322. on dome-face, 346. on pinakoid, 321, 351. on prism, 347. on rhombohedron, 319. on scalene octahedron, 346. orthorhombic system, 345. Symmetry of, 181. tetragonal system, 268. - Thickness of, 177. Types of crystalloid symmetry, 121. Unconformable symmetry, no. Urea, 263. Vertical prism, 355. Water, i. Wave-surface, 10. Websky, 393, 409. Weiss, 326. Werther, 263. Witherite, 184, 341. Wolfram, 369. Wollaston, 390. Wulfenite, 267. Wurtzite, 314. Zero-index, 19. Zinc oxide, 318. Zippe, 229. Zircon, 268. Zone-axis, 25, 45. circle, 44. law, 46, 55, 65. line, 25. lines and normals, 95. - plane, 44. symbol, 45. Zones, 44. END OF PART I. 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