mm; The Cenozoic Evolution of the San Joaquin Valley, California By J. ALAN BARTOW U.S. GEOLOGICAL SURVEY PROFESSIONAL PAPER 1501 UNITED STATES GOVERNMENT PRINTING OFFICE, WASHINGTON : 1991 DEPARTMENT OF THE INTERIOR MANUEL LUJAN, 1m, Secretary U.S. GEOLOGICAL SURVEY Dallas L. Peck, Director Any use of trade, product, or firm names in this publication is for descriptive purposes only and does not imply endorsement by the U.S. Government Library of Congress Cataloging-in-Publication Data Bartow, J. Alan. The Cenozoic evolution of the San Joaquin Valley, California / by J. Alan Bartow. p. cm.—(U.S. Geological Survey professional paper ; 1501) Includes bibliographical references. Supt. of Docs. no.: I 19.161501 1. Geology, Stratigraphic—Cenozoic. 2. Geology—California—San Joaquin River Valley. 3. Sedimentation and depo— sition—California-San Joaquin River Valley. I. Title. II. Series. QE690.B34 1991 551.7’8’097948—dc20 89—600313 CIP For sale by the Books and Open-File Reports Section, U.S. Geological Survey, Federal Center, Box 25425, Denver, CO 80225 CONTENTS Page Page Abstract 1 The sedimentary record—Continued Introduction 2 Paleogene—Continued Setting 2 Upper Paleocene and lower Eocene sequence ———————— 17 Previous work 2 Eocene sequence 18 Purpose and approach 3 Lower Oligocene sequence ---------------------- 19 Geology 3 Upper Oligocene sequence —————————————————————— 19 Northern Sierran block 3 Neogene and Quaternary 20 Southern Sierran block 6 Lower and middle Miocene sequence ——————————————— 20 Northern Diablo homocline 8 Middle and upper Miocene sequence ——————————————— 21 West-side fold belt 9 Upper Miocene, Pliocene, and Pleistocene sequence———- 23 Maricopa-Tejon subbasin and south-margin deformed Upper Pleistocene and Holocene deposits ——————————— 23 belt 10 Basin evolution 24 Major controls on sedimentation ———————————————————————— 12 Paleocene 25 Tectonics 12 Eocene 25 Plate tectonics 12 Oligocene 28 Regional tectonics 13 Miocene 29 Sea-level change 15 Pliocene 31 Climate 16 Pleistocene 31 The sedimentary record 16 Holocene 33 Paleogene 16 Conclusions 33 Great Valley sequence 16 References cited 34 ILLUSTRATIONS [Plates are in pocket] PLATE 1. Generalized geologic map and cross sections of the San Joaquin Valley area, California. 2. Correlation of the Cenozoic stratigraphic units of the San Joaquin basin with tectonic, volcanic, and sea-level events. Page FIGURE 1. Index map of central California 4 2. Diagram showing interrelation of factors affecting eustasy 16 3. Diagrammatic cross section of the northern San Joaquin Valley showing stratigraphic relations of Quaternary alluvial deposits 24 4. Maps showing evolution of regional stress patterns in the San Joaquin Valley area 26 5—13. Maps of the San Joaquin basin showing: 5. Late Paleocene paleogeography 27 6. Early to middle Eocene paleogeography 28 7. Middle Eocene paleogeography 28 8. Oligocene paleogeography 29 9. Early Miocene paleogeography 30 10. Middle Miocene paleogeography 30 11. Late Miocene paleogeography 31 12. Pliocene paleogeography 32 13. Pleistocene paleogeography (San Joaquin Valley) 32 THE CENOZOIC EVOLUTION OF THE SAN JOAQUIN VALLEY, CALIFORNIA By j. ALAN BARTow ABSTRACT The San Joaquin Valley, which is the southern part of the 700-km-long Great Valley of California, is an asymmetric structural trough that is filled with a prism of upper Mesozoic and Cenozoic sediments up to 9 km thick; these sediments rest on crystalline basement rocks of the southwestward—tilted Sierran block. The San Joaquin sedimentary basin is separated from the Sacramento basin to the north by the buried Stockton arch and associated Stockton fault. The buried Bakersfield arch near the south end of the valley separates the small Maricopa-Tejon subbasin at the south end of the San Joaquin basin from the remainder of the basin. Cenozoic strata in the San Joaquin basin thicken southeastward from about 800 m in the north to over 9,000 m in the south. The San Joaquin Valley can be subdivided into five regions on the basis of differing structural style. They are the northern Sierran block, the southern Sierran block, the northern Diablo homocline, the west- side fold belt, and the combined Maricopa-Tejon subbasin and south- margin deformed belt. Considerable facies variation existed within the sedimentary basin, particularly in the Neogene when a thick section of marine sediment accumulated in the southern part of the basin, while a relatively thin and entirely nonmarine section was deposited in the northern part. The northern Sierran block, the stable east limb of the valley syncline between the Stockton fault and the San Joaquin River, is the least deformed region of the valley. Deformation consists mostly of a southwest tilt and only minor late Cenozoic normal faulting. The southern Sierran block, the stable east limb of the valley syncline between the San Joaquin River and the Bakersfield arch, is similar in style to the northern part of the block, but it has a higher degree of deformation. Miocene or older normal faults trend mostly north to northwest and have a net down-to-the-west displacement with individ- ual offsets of as much as 600 m. The northern Diablo homocline, the western limb of the valley syncline between the Stockton arch and Panache Creek, consists of a locally faulted homocline with northeast dips. Deformation is mostly late Cenozoic, is complex in its history, and has included up-to-the—southwest reverse faulting. The west-side fold belt, the southwestern part of the valley syncline between Panoche Creek and Elk Hills and including the southern Diablo and Temblor Ranges, is characterized by a series of folds and faults trending slightly oblique to the San Andreas fault. Paleogene folding took place in the northern part of the belt; however, most folding took place in Neogene time, during which the intensity of deformation increased southeast- ward along the belt and southwestward toward the San Andreas fault. The Maricopa-Tejon subbasin and the south-margin deformed belt are structurally distinct, but genetically related, regions bounded by the Bakersfield arch on the north, the San Emigdio Mountains on the south, the Tehachapi Mountains on the east, and the southeast end of the fold belt on the west. This combined region, which is the most deformed part Manuscript approved for publication, November 16, 1988. of the basin, has undergone significant late Cenozoic shortening through north-directed thrust faulting at the south margin, as well as extreme Neogene basin subsidence north of the thrust belt. The sedimentary history of the San Joaquin basin, recorded in terms of unconformity-bounded depositional sequences, has been con- trolled principally by tectonism, but it has also been controlled by eustatic sea-level changes and, to a lesser degree, by climate. Plate tectonic events that had an influence on the basin include (1) subduction during the early Tertiary that changed from oblique to normal convergence in the later part of the Eocene, (2) the mid-Oligocene encounter of the Pacific-Farallon spreading ridge with the trench, and the consequent establishment of the San Andreas transform, (3) the northwestward migration of the Mendocino triple junction that induced extensional tectonism and volcanism in adjacent areas, and (4) the change in plate motions at 5 Ma that resulted in an increased component of compression normal to the San Andreas transform. Other tectonic events of a more regional scale that affected the San Joaquin basin include (1) clockwise rotation of the southernmost Sierra Nevada and tectonism that produced large en echelon folds in the southern Diablo Range, both perhaps related to Late Cretaceous and early Tertiary right slip on the proto-San Andreas fault, (2) uplift of the Stockton arch in the early Tertiary, (3) regional uplift of southern California in the Oligocene that was a precursor to the ridge-trench encounter, (4) extensional tectonism in the Basin and Range province, particularly in the Miocene, (5) wrench tectonism adjacent to the San Andreas fault in the Neogene, (6) northeastward emplacement of a wedge of the Franciscan Complex at the west side of the Sierran block and the associated deep-seated thrusting in the Cenozoic, and (7) the acceler- ated uplift of the Sierra Nevada beginning in the late Miocene. The early Cenozoic sedimentary history of the San Joaquin basin differs from that of the later Cenozoic: the former is characterized by a few long-lasting basinwide depositional sequences, whereas the latter is characterized by shorter sequences of more local extent. This change in style of sedimentation took place during the Oligocene at about the beginning of the transition from a convergent continental margin to a transform margin. Paleogene basin history was controlled principally by subduction-related and proto—San Andreas fault-related tectonics and, to a lesser extent, the effects of changing eustatic sea level. A eustatic fall in sea-level was probably the principal cause for the regression recorded at the end of the upper Paleocene and lower Eocene depositional sequence, and it contributed to most other Paleogene regressions. Tectonic events related to the approach of the Pacific- Farallon spreading ridge became important in the Oligocene. Neogene basin history was controlled principally by the tectonic effects of the northwestward migration of the Mendocino triple junction along the California continental margin and by the subsequent wrench tectonism associated with the San Andreas fault system. Compression normal to the San Andreas in the latest Cenozoic, resulting from changes in relative plate motion, contributed to compressional deformation at the west side of the valley. Eustatic sea—level effects are less discernible in 1 2 THE CENOZOIC EVOLUTION OF THE SAN JOAQUIN VALLEY, CALIFORNIA the Neogene, but a middle Miocene highstand probably contributed to the Widespread transgression at that time. Climate was an important factor in basin history only in the latest Cenozoic (late Pliocene and Pleistocene), when alpine glaciers in the Sierra Nevada and a pluvial climate influenced sedimentation. The San Joaquin basin, which at the end of the Mesozoic formed the southern part of an extensive forearc basin, evolved during the Cenozoic into today’s hybrid intermontane basin. Its evolution com— prises the gradual restriction of the marine basin through uplift and emergence of the northern part in the late Paleogene, closing off of the western outlets in the Neogene, and finally the sedimentary infilling in the latest Neogene and Quaternary. INTRODUCTION SETTING The Great Valley of California, a 700-km-long by up to 100—km-wide alluvial plain between the Sierra Nevada on the east and the Coast Ranges on the west, is divided into the Sacramento Valley in the north and the larger San Joaquin Valley in the south. The south-flowing Sacra- mento River, draining the Sacramento Valley, and the north-flowing San Joaquin River, draining the northern part of the San Joaquin Valley, join in the Sacramento- San Joaquin Delta near Stockton (pl. 1, fig. 1); the delta in turn drains westward into San Francisco Bay. The Tulare Lake basin in the south-central San Joaquin Valley and the Buena Vista Lake basin at the extreme south end of the valley contain closed depressions, and both receive part of the drainage, at times, from the Kings and Kern Rivers. Geologically, the San Joaquin Valley is an asymmetric structural trough with a broad, gently inclined, and little-deformed east flank and a relatively narrow west flank; the west flank is a steep homocline in the northern part of the valley, but becomes a belt of folds and faults in the southern part of the valley (pl. 1). The trough is filled with a prism of upper Mesozoic and Cenozoic sediments that reaches a thickness of over 9 km in the west-central part of the valley and at the south end. The sedimentary prism represents, in a broad sense, the fill of the San Joaquin sedimentary basin; however, this basin is, in a strict sense, a composite of a late Mesozoic and early Cenozoic forearc basin that was largely open to the Pacific Ocean on the west, and a later Cenozoic trans- form-margin basin. The basin-filling sediments rest on a westward-tilted block of crystalline basement composed of Sierra Nevada plutonic and metamorphic rocks under the eastern part of the valley and mafic and ultramafic rocks of a presumed ophiolite of Jurassic age under the central and western parts of the valley (Cady, 1975; Page, 1981). On the west side of the valley, the Mesozoic and early Tertiary Great Valley sequence, together with the conformably underlying ophiolite, is juxtaposed with the Franciscan Complex along a boundary fault termed the Coast Range thrust as first proposed by Bailey and others (1964). For many years, the Coast Range thrust was interpreted as a fossil subduction zone, but recent work based on seismic reflection and refraction suggests that the Franciscan has been thrust eastward as a wedge between crystalline basement below and the Great Val- ley sequence above (Wentworth and others, 1983; Went- worth and others, 1984) (pl. 1, sections A, B). The boundary between the Franciscan and the Great Valley sequence, then, becomes the roof thrust of the wedge and, unlike the hypothesized Coast Range thrust, ex- tends no farther east than the tip of the wedge. The Great Valley sedimentary basin is divided by the buried, transverse Stockton arch and Bakersfield arch. The Stockton arch, which is a broad structure that is bounded on the north by the Stockton fault (pl. 1) but has a poorly defined southern limit, separates the San Joaquin and Sacramento sedimentary basins. The Bakersfield arch separates the Maricopa—Tejon subbasin at the south end of the San Joaquin Valley from the remainder of the San Joaquin sedimentary basin. Neither arch has appreciable structural relief, but they did have an influence on sedimentation, as will be shown. The Tertiary depocenters of these basins are approximately coincident with the Pleistocene and Holocene Buena Vista and Kern Lakes basins in the south and the Tulare Lake basin in the central part of the valley. The Teha- chapi-San Emigdio Mountains uplift that bounds the valley on the south might be considered a third trans- verse structure. Cenozoic strata in the San Joaquin Valley thicken southeastward from about 800 m over the western part of the Stockton arch to over 9,000 m in the Maricopa—Tejon subbasin in the south (pl. 1, section D). The Mesozoic and early Tertiary Great Valley sequence, on the other hand, thins southeastward and is apparently absent south of the Bakersfield arch. PREVIOUS WORK Although geological observations of rocks bordering the San Joaquin Valley date back to the late 1800’s (Shedd, 1932), the valley itself received scant attention at that time. Geological study of the sedimentary deposits in the valley was spurred on in the early 1900’s following the discovery of oil at the McKittrick (1887), Coalinga (1887), and Kern River (1901) oil fields. Knowledge of the geology of the valley accumulated as oil exploration progressed in the years preceding, and especially those following, World War II. The first general review of the Cenozoic history of the valley was that of Hoots and others (1954), although Reed (1933) and Reed and Hollister (1936) touched on the San Joaquin Valley in their broader summaries of California GEOLOGY 3 and southern California geologic history, respectively. The Cenozoic history of the valley was updated by Repenning (1960) in a succinct, but stratigraphically comprehensive, summary and was further revised by Hackel (1966). Bandy and Arnal (1969) applied a new technique— based on the analysis of benthic foraminiferal faunas from marine Tertiary rocks in the southern part of the valley—in an attempt to quantify basin subsidence and uplift. Foss’ (1972) interpretation of the Tertiary marine stratigraphy emphasized the apparent synchroneity of depositional cycles on the east and the west sides of the valley, even though a different type of depositional sequence characterizes each area. ‘ More recently, geologists have gone beyond describing the basin stratigraphy and history and have sought tectonic mechanisms that have controlled different as- pects of basin evolution. Nilsen and Clarke (1975) dis- cussed the tectonic setting for Paleogene sedimentation in the Great Valley together with other regions of California. Harding (1976) tied the structural evolution of the west-side fold belt to the history of movement on the San Andreas fault. Subsequently, others (notably Blake and others, 1978; Dickinson and Snyder, 1979; Howell and others, 1980) have related the origin of the San Joaquin basin, along with other California Neogene basins, to plate tectonic processes. PURPOSE AND APPROACH The theory of plate tectonics, since its emergence in the 1960’s, has given a new perspective to the interpre- tation of regional tectonics (Blake and others, 1978; Howell and others, 1980; Page and Engebretsen, 1984). Concurrently, revisions in regional stratigraphy, result- ing mostly from the application of recent improvements , in global correlations and the work toward a standard global chronostratigraphic scale, allow more precise comparison of the timing of depositional events from widely separated parts of the San Joaquin basin. The goal of this report is to interpret the Cenozoic sedimentary record of the San Joaquin Valley in terms of external controls on sedimentation and to speculate, where possi- ble, on the nature of the tectonic events responsible. This report is chiefly a review of the Cenozoic geologic history of the San Joaquin basin in the light of current ideas on plate tectonics, regional tectonics, and eustatic sea-level change, although no exhaustive effort has been made to summarize all the extensive geological literature on the basin. It incorporates the results of several years of U.S. Geological Survey research by myself and others (notably D.E. Marchand, B.F. Atwater, J .W. Harden, and W.R. Lettis) on the San Joaquin Valley, the purpose of which was to elucidate the regional tectonic setting of the valley as background for more specific geologic hazards studies required in the siting, design, and construction of nuclear powerplants. A basin-study ap- proach to understanding regional tectonic history was adopted. This assumes a basic cause and effect relation between tectonics and sedimentation, and also that the sedimentary fill in a basin is a record of tectonic activity. GEOLOGY Although the San Joaquin Valley, as the southern part of the Great Valley, constitutes part of a discrete geomorphic and structural province within the western Cordillera of North America, the geology is internally variable in both stratigraphy and style of deformation. Stratigraphically, the greatest variation is in the N eo- gene deposits, which comprise a thick section of marine sediments in the southern part of the basin but a relatively thin and entirely nonmarine section in the northern part. Structurally, the greatest differences are between the west-side fold belt and the little-deformed sedimentary cover of the Sierran block on the east side of the valley. To facilitate description of the geology, the valley is subdivided into five regions on the basis of structural style (fig. 1, pl. 1). Although each region is structurally distinct in style of deformation and tectonic history, the boundaries between areas are necessarily arbitrary. NORTHERN SIERRAN BLOCK The northern Sierran block region of the San Joaquin Valley consists of the stable east limb of the valley syncline from the Stockton fault on the north to about the San Joaquin River on the south. The region, which is the least deformed part of the San Joaquin basin, includes as its dominant element the broad and poorly defined Stockton arch. The Stockton arch is evident principally as an area where Paleogene and uppermost Cretaceous strata have been erosionally truncated (Hoots and others, 1954). There is little evidence of arching in overlying Tertiary units (Bartow, 1985) and no evidence of basement arching (Bartow, 1983) (pl. 1, section D). This structure probably formed initially in the latest Cretaceous or Paleocene, perhaps by local thickening of the Cretaceous section, and had a major period of uplift in the Oligocene. Its origin will be discussed further in the section “Regional Tectonics.” The structure was a low-relief positive fea- ture through most of the Paleogene. The stratigraphy of the Modesto-Merced area is typical of that on the northeast side of the valley (pl. 2, col. 3); farther west, the stratigraphy is similar to that of the THE CENOZOIC EVOLUTION OF THE SAN JOAQUIN VALLEY, CALIFORNIA 8 8 30° {‘1 5’90 {‘1 /\ / (D I I -' ‘ l I rn San FranCIsco I 33 ' ' E :0 \ 3 39° F ’ o ]> —I D ‘n E/ E a» 0 CI B‘PLANATION <3 A; \ n ------ Boundary of structural region i‘ N O E —Dashed where approximate —-' Fault —Dashed where a r ximatel O < DP 0 )1 IV 5‘: E) E located; dotted where concealed > (J U) I > 5: A 1 O ‘7 m > N 5 7 E >11 "’ 2 SACRAMENTO VALLEY N \ O 390 SAN JOAQUIN \‘E Z VALLEV 5s ,. 36° \ -; 017,735." c lye ..... I (A 7’ . | m ...... INDEX MAP OF CALIFORNIA I 33 y I V m t ‘ Z Z .1" l ‘ O m :8 I. m < a I m '“ )> O I \ 1; O \ 9)., ('3 r > In I; a D 050 > If \ 2 E 0 U) 0 I l l \ 96° (5 4/ x I' . ountalns J40 \ goo/<3 Tenachap‘ GARLOCK FAULL , a ’ ' K % ‘K B x o 10 20 30 40 so KILOMETERS I_I_I__I___._I._I \ .3 / / / 5° & R o 5% s FIGURE 1. —Index map of central California showing the five structural regions of the San Joaquin Valley in relation to principal geographic and structural features. NSB, northern Sierran block; SSB, southern Sierran block; NDH, northern Diablo homocline; WFB, west-side fold belt; M-TS, Maricopa-Tejon subbasin and south-margin deformed belt. GEOLOGY 5 Orestimba Creek area on the west side of the valley (pl. 2, col. 1). Over the Stockton arch (pl. 1), Paleogene strata are absent and nonmarine Neogene strata rest directly on the Great Valley sequence (Church and Krammes, 1958; Bartow, 1985). The Cenozoic deposits in this part of the valley are relatively thin (about 1,100 m) compared to the southern part of the valley, whereas the underlying Great Valley sequence is much thicker (over 3,000 m) (Hoffman, 1964) (pl. 1, section A). Cenozoic deformation has consisted mostly of west or southwest tilting of the rigid Sierran block as evidenced by the subtle angular unconformities with discordances of generally less than 1° that separate the Cenozoic units along the northeast side of the valley (Grant and others, 1977; Marchand and Allwardt, 1981). Evidence of the earliest Cenozoic tilting, however, is provided by the truncation of Upper Cretaceous and Paleocene units by Eocene strata in the subsurface (Bartow, 1985). Discord- ance between Eocene and younger units is much less apparent than that between Eocene and pre-Eocene units, but there is some suggestion of tilting in the Oligocene, based on the differences in gradient of depo- sitional surfaces in the Ione and Valley Springs Forma— tions at the eastern edge of the valley (Marchand, 1977). These data are questionable, however, because a lack of traceable markers and erosional relief at the contacts makes it difficult to reliably determine gradients or dips in these units. Although there is little reliable evidence of Oligocene westward tilting, truncation of older units over the Stockton arch indicates uplift of that area, which, as the southern part of the basin continued to subside during the Oligocene, produced a southward tilt rather than a westward tilt. A hiatus representing most of the Oligo- cene is evidence that there was negligible subsidence in the western part of the block during that interval. In the Miocene section, there is little evidence of discordance between the Valley Springs and Mehrten Formations, although this evidence is again difficult to assess accu- rately. Later Neogene and Quaternary units, however, do show appreciable differences in gradient (Marchand, 1977; Marchand and Allwardt, 1981). It seems most probable that, while there may have been regional uplift or southward tilting of the northern Sierran block in the middle Tertiary, there was little southwest tilting until the late Miocene or Pliocene. Tilting continues to the present, probably at an accelerating rate. Most of the Cenozoic faulting is localized along the Foothills fault system, consisting of the Bear Mountains and the Melones fault zones (pl. 1, fig. 1). This fault system originated as a major Mesozoic (pre-batholith) shear zone or suture and has been locally reactivated in the Cenozoic. Studies of the fault system by Woodward— Clyde Consultants for Pacific Gas and Electric Co} revealed several locations where Cenozoic deposits are offset across the fault zones. Displacement at one locality on the Melones fault zone has been demonstrated to be younger than about 4 Ma (Bartow, 1980), and Quaternary movement is indicated elsewhere by shearing or offset of soils or Pleistocene colluvial deposits (Marchand, 1977; Schwartz and others, 1977). There is, however, no indication of present-day seismicity along these zones (Wong and Savage, 1983). Cenozoic normal faulting in the foothills belt, and elsewhere near the tectonic hinge line, was probably approximately coincident with the tilting; the faulting suggests that the west or valley side of the Sierran block was subsiding faster than the Sierra Nevada was rising, resulting in tensional faulting near the hinge. Features possibly related to the Cenozoic normal faulting are the numerous northwest-trending linea- ments in the eastern part of the valley (Marchand and Allwardt, 1978; Hodges, 1979). Most of these are proba- bly not faults, but a few have 1 to 2 m of normal displacement of Pleistocene units (Marchand, 1977). Small normal faults with offsets of a few meters are present at a few localities in exposed Tertiary strata as well. There also appears to have been substantial dis- placements of the Eocene Ione Formation along a system of lineaments east of Merced (Marchand, 1977; Marchand and Allwardt, 1978), but detailed gravity profiles across one of the more prominent lineaments do not support significant offset of the basement surface. Data from one profile permit 2 m of fault offset of the basement surface Within a few meters of the lineament; however, the interpretation of these gravity data is ambiguous because of uncertainties about erosional relief on the basement surface, lateral density variations in the basement, and density variations in overlying sediment (A. Griscom, written commun., 1978). Few subsurface faults have been recognized in the northern part of the San Joaquin Valley; the largest of the known subsurface faults is the Stockton fault, which bounds the Stockton arch on the north (pl. 1). The Stockton fault is a south-dipping reverse fault that trends transversely to the regional structure. The fault, which appears to have a complex history, has a total down- to-the-north dip slip of as much as 1,100 m (Hoffman, 1964). It may have originated in the Late Cretaceous as a normal fault, or possibly a left-lateral strike-slip fault with a south-facing scarp (Teitsworth, 1964). It was reactivated as a reverse fault in the latest Cretaceous or Paleogene and was probably active through the early Miocene, although most of the down-to-the-north offset occurred during the Oligocene (Hoffman, 1964; Teitsworth, 1964; Bartow, 1985). In the Merced- Chowchilla area, another west-northwest—trending fault 1Unpublished report on geology of proposed Stanislaus nulear project by Woodward-Clyde Consultants for Pacific Gas and Electric Co., 1977. 6 THE CENOZOIC EVOLUTION OF THE SAN JOAQUIN VALLEY, CALIFORNIA is recognized mostly on the basis of apparent offset of the post-Eocene unconformity (Bartow, 1985). Its inferred trace appears to coincide with a diffuse surface lineament visible on satellite images (Antonnen and others, 1974; Hodges, 1979). The lineament, termed the Kings Canyon lineament, crosses the valley north of Chowchilla, paral- lels the south fork of the Kings River in the Sierra Nevada, and continues southeastward nearly to Death Valley. The ophiolite remnant at Del Puerto Creek and a major bend in the Ortigalita fault lie on the northwest projection of the lineament in the Diablo Range. The reverse faulting on the Stockton fault, and the consequent elevation of Cretaceous rocks south of the fault to form the Stockton arch, indicates a general north-south compression from about the Paleocene through the early Miocene. Late Cenozoic southwest tilting of the Sierran block and subsidence of the west side, with concurrent normal faulting near the hinge, suggest east-west to northeast-southwest extension. The normal faulting, however, insofar as it represents flex- ural stress as the west side of the block subsided faster than the east side rose, is not necessarily evidence of regional extension. Present-day seismicity in the south— ern part of the northern Sierran block indicates north- south to northeast—southwest compression producing predominantly strike—slip and reverse faulting at depths greater than 12 km (Wong and Savage, 1983). SOUTHERN SIERRAN BLOCK The southern Sierran block comprises the southern part of the stable and little—deformed east limb of the valley syncline. Its south boundary is the crest of the Bakersfield arch, a broad southwest-plunging ridge of basement rock, and the north boundary is arbitrarily placed at the San Joaquin River (fig. 1, pl. 1). Both Cenozoic and Mesozoic sedimentary deposits thicken gradually southward and together total more than 5,000 m in the area south of Tulare Lake. Cenozoic strata alone reach a thickness of more than 4,500 m, whereas the Mesozoic rocks thin southeastward and pinch out or are truncated against the north flank of the arch (pl. 1, section D). The stratigraphy of the Bakersfield arch area (pl. 2, col. 9) is typical of the southern part of this area. Outside the arch area, Tertiary rocks, particularly the older Tertiary, are not well known because of the absence of Tertiary outcrops between the San Joaquin River and the Tule River and because of the sparsity of deep wells. For much of the Neogene, the central part of the Southern Sierran block was a broadly fluctuating zone of transition between nonmarine deposition on the north and east and marine deposition on the south and west. The Cenozoic stratigraphy in the subsurface of the Hanford-Tulare area (pl. 2, col. 6) probably has some similarity to both the Bakersfield arch area to the south and the Kettleman Hills area to the west. The San Joaquin Valley part of the southern Sierran block is structurally similar to the valley part of the northern Sierran block; differences are principally in degree of deformation rather than in style of deforma- tion. The southwest-to—west tilt of the entire Sierran block increases southward so dips of exposed Tertiary units in the Bakersfield area average 4°-6°, in contrast to the 1°—2° dips in the north (pl. 1, sections A, B, C). Further indication of the increased tilt is provided by the greater height of the southern Sierra Nevada and the greater depth to basement in the southwestern part of the valley, although part of this difference in elevation is a result of normal faulting along the west edge of the southern Sierra Nevada. Truncation of Cretaceous and Paleocene(?) strata indi- cates tilting prior to the middle Eocene of the southern as well as the northern Sierran block. Minor angular dis- cordance between the Walker Formation or Vedder Sand and overlying J ewett Sand is evidence of tilting near the end of the Oligocene. An unconformity at the base of the “Santa Margarita” Formation that truncates older units, and a more extensive unconformity and truncation at the base of the Kern River Formation are evidence of the accelerating uplift and westward tilt of the southern Sierran block beginning in the late Miocene. Normal faults along the east side of the valley are concentrated in the area of the Bakersfield arch. These faults generally trend northwest to north, although a secondary west to west-northwest trend is apparent (pl. 1). The net displacement is down to the southwest, although down-to-the-northeast faults are present (Bar- tow, 1984). One of the principal faults of this group is the Kern Gorge fault, along which basement rocks to the southwest have been downdropped more than 600 m. An important exception to the northwesterly fault trend is the Poso Creek fault that trends in a westerly direction through the Tertiary outcrop belt and then curves to the northwest to merge with the subsurface Pond fault. Faulting appears to die out northwestward along the east edge of the valley, partly because Quaternary deposits overlap the Tertiary strata onto the basement rocks north of Deer Creek. Buried (or partially buried) faults that offset the basement rock surface have been inferred in the area between Porterville and Dinuba (Croft and Gordon, 1968) and near Clovis northeast of Fresno (Page and LeBlanc, 1969). The presence of these inferred faults is based principally on surface lineaments and a steeply west-sloping basement surface, but no fault offsets have been convincingly demonstrated. These faults are not included on plate 1. GEOLOGY 7 Many subsurface faults have been inferred west of the Tertiary outcrop belt by others (Los Angeles Depart- ment of Water and Power, 1975, fig. 2.5.1—7A). Most of these faults seem to be small and have a predominant northwest trend; they have been recognized only where well density is sufficient for delineation of faults, that is, mainly in oil fields. No attempt has been made to generalize these on plate 1. The Pond fault and Greeley fault system are, however, major structures. The Pond fault, actually a zone of subparallel southwest-dipping normal faults up to 2 km Wide, apparently joins the Poso Creek fault to the southeast (Los Angeles Department of Water and Power, 1975). Down-to-the-southwest offsets decrease upward from a maximum of over 500 m on the basement surface. Near the town of Pond, a zone of cracks extends to the ground surface, which has been downdropped as much as 23 cm across the fault (Holzer, 1980). The buried Greeley fault system consists of an en echelon set of northwest-trending normal faults (pl. 1). The basement surface is downdropped on the northeast as much as 615 m, but offsets decrease upward so there is no apparent offset of strata younger than late Miocene (Los Angeles Department of Water and Power, 1975). The Greeley fault has been reported to have a large component of lateral displacement (Sullivan and Weddle, 1960). Webb (1977) inferred 670 m of right slip on the basis of apparent offset of Miocene channel sands, but he later reinterpreted (Webb, 1981) the apparent offsets as meanders in the channels. The Greeley fault system is paralleled on the southwest by a series of short low- amplitude folds that have their strongest expression in early Miocene and older strata. This folding could be (1) genetically related to strike-slip faulting, (2) due to compression that also would have produced reverse faulting, as is found on faults with similar trend farther west in the basin, or (3) a result of drape over a buried fault scarp. An intensive study of the Greeley fault system for a proposed nuclear powerplant site astride the northern segment of the fault, based on seismic-reflection profiles and oil well data (Los Angeles Department of Water and Power, 1975), concluded that the movement has been normal (down-to-the—east) and that there is no evidence of lateral displacement. This study apparently did not consider the possibility of reverse movement; however, the geometry of the Greeley structure, as seen on seismic-reflection sections, is sufficiently different from reverse fault structures like Semitropic anticline to seriously weaken the reverse fault hypothesis for the origin of the Greeley structure. A large number of northwest-trending surface linea— ments in the Kern River area were described by Warne (1955), who implied a relation to deep lateral faulting. More recent trenching of selected lineaments, however, shows no evidence of near-surface faulting (Los Angeles Department of Water and Power, 1975). The surface lineaments in the southeastern part of the valley are similar to those (described above) in the northeastern part of the valley. Their origin is unclear, but in neither case do they seem to be related to bedrock faults. In contrast with the northern Sierran block Where the normal faulting is mostly late Cenozoic in age, the faulting appears to be mostly Miocene or older in the southern part of the block. Although it is difficult to determine the time of inception of the normal faulting, subsurface evidence from both well sections (Bartow, 1984) and seismic sections (Los Angeles Department of Water and Power, 1975) indicates greater offset of the basement surface than of late Miocene or Pliocene horizons. Faults with a general north trend (northwest to north-northeast) and those, such as the Poso Creek fault, with a general west trend (west to west-northwest) seem to be similar in that offset decreases upward. In general, north-trending faults were active in the early Tertiary and again beginning in the late Miocene. West-trending faults may have had their origin in the latest Oligocene and early Miocene like those in the Maricopa-Tejon subbasin at the south end of the San Joaquin Valley, as Will be shown in the section “Maricopa-Tejon Subbasin and South-Margin Deformed Belt,” and were probably active until about the late Miocene. The Greeley fault, farther west and near the center of the valley, may have had its origin in the Cretaceous or earliest Tertiary and shows no offset of horizons younger than early Miocene (Los Angeles Department of Water and Power, 1975). Part of the movement of the normal faults in the southern Sierran block was, then, concurrent with the late Mio- cene to recent uplift of the Sierran block (pl. 2). However, a significant part of the offset was pre-uplift, and faulting seems to have ended in the Pliocene while uplift presum— ably continued. There are few faults on the north side of the Bakersfield arch that offset Quaternary deposits. The exceptions seem to be largely due to subsurface compac- tion as a result of fluid withdrawal—oil in the case of the Kern Front and Premier faults (Castle and others, 1983; Bartow, 1984) and ground water in the case of the Pond fault (Holzer, 1980). In addition to the normal faults involving basement rocks, a number of syndepositional growth faults formed during late Miocene sedimentation in the area west of Bakersfield (MacPherson, 1978). North-trending normal faults of pre-Miocene age (in- cluding northwest-trending faults like the Greeley and Pond) indicate approximate east-west to northeast- southwest extension in the early Tertiary; these faults may be the only manifestation of a north-south regional compressive stress at that time, although there may be some possibility of minor right-lateral strike slip on northwest—trending faults like the Greeley fault. East- 8 THE CENOZOIC EVOLUTION OF THE SAN JOAQUIN VALLEY, CALIFORNIA trending normal faults indicate north-south extension for the period during which they were active, probably about late Oligocene to late Miocene. NORTHERN DIABLO HOMOCLINE The northern Diablo homocline consists of the west limb of the valley syncline from the Stockton arch in the north to Panoche Creek in the south. It includes the northeast flank of the northern Diablo Range (fig. 1, pl. 1). The stratigraphy of the Orestimba Creek area and the Los Banos-Oro Loma area (pl. 2, cols. 1 and 2) are representative of the Diablo homocline. Approximately 1,400 m of Cenozoic deposits in that area thin northwest- ward toward the Stockton arch, mostly through trunca- tion of the marine older Tertiary units (Hoffman, 1964; Hackel, 1966; Bartow and others, 1985). Paleogene marine rocks, however, reappear in the Corral Hollow- Lone Tree Creek area southwest of Tracy. The present Diablo Range has resulted principally from Neogene tectonism, although there is some evidence that the northern Diablo Range existed as a positive area as far back as the Paleogene (Clarke and others, 1975; Nilsen and Clarke, 1975; Bartow and others, 1985). The relation between the Paleogene Diablo uplift and Stockton arch is unclear, but Neogene structures in the northern Diablo Range appear to be superimposed on the older positive areas. The Cenozoic rocks of the northern Diablo Range form a northeast-dipping homocline in which the dips of the Tertiary strata generally range from 30° to 50° (pl. 1). Subordinate structures are principally faults, but folds are associated with the Vernalis and Black Butte faults near Tracy at the west end of the Stockton arch and a small anticline near Patterson produces a local reversal of dip in the homocline. Near Gustine, the dips of Tertiary strata flatten abruptly to 10° or less northeast of a northwest-trending fault. Folding or tilting is mostly of Neogene age, although some deformation did take place in the Paleogene. The slight unconformity between the Great Valley sequence and overlying Paleogene units is evidence of mild defor- mation in earliest Tertiary time. Truncation of Paleogene units at the base of the Valley Springs Formation is apparent along the Diablo homocline, as it is elsewhere along the south side of the Stockton arch; this relation indicates post-Eocene uplift or tilting of the arch. Al— though the beginning of Neogene uplift of the Diablo Range is evidenced by the formation of coarse alluvial fan deposits derived from the range in the late middle to late Miocene (pl. 2), the angular unconformity at the base of the latest Pliocene and Pleistocene Tulare Formation marks the principal uplift of the range (Bartow, 1985). The principal Cenozoic faults or fault zones of the northern Diablo homocline are (1) the Black Butte fault, a northwest-trending fault west of Tracy, (2) the Vernalis fault, a subsurface fault that parallels the Black Butte fault and trends at a right angle to the Stockton fault near its west end, (3) the Tesla-Ortigalita fault zone, the west boundary of the Diablo homocline and the present bound- ary between the Franciscan Complex and the Great Valley sequence, and (4) the San Joaquin fault zone, which lies along the west edge of the valley. The history of faulting is complex and, for some faults, not well understood. As with the folding, most Cenozoic faulting seems to be Neogene in age and it is difficult to identify specific structures as Paleogene in age because of the strong overprint of Neogene tectonism. The Black Butte and Vernalis faults are subparallel, southwest-dipping reverse faults, eachwith an associ- ated anticline on the upthrown side. The Black Butte fault involves units as young as the Tulare Formation and, therefore, must have been active as recently as the Pleistocene (Raymond, 1969). The age of the Vernalis fault is less well known because it is an entirely subsur- face structure. Large offset at the base of the Valley Springs Formation (Bartow, 1985) suggests that most of the movement took place in the Miocene or later. Although the upper limit of faulting is not known and there is no evidence of Quaternary movement, the fault-plane solution for a 1977 magnitude 3.5 earthquake near Patterson approximately on-trend to the southeast indicates the same style of faulting as for the Black Butte fault (Wong and Ely, 1983). The Tesla-Ortigalita fault is a zone of high-angle faults with a net down-to-the-east displacement that may total thousands of meters. The dip of the fault plane is not everywhere known, but it is locally a southwest-dipping reverse or thrust fault (Briggs, 1953). In the big bend segment of the Tesla-Ortigalita fault between Hospital and Del Puerto Creeks, the fault plane generally dips steeply in the direction of the downthrown block, which suggests that it is locally a normal fault (Maddock, 1964; Raymond, 1969). As Maddock pointed out, however, the fault may have been folded subsequent to its formation. Although movement on the fault zone has been predom- inantly dip slip, it is not known how much was in a reverse sense and how much might have been in a normal sense. The southern part of the zone from Quinto Creek to Little Panoche Valley shows evidence of right-lateral strike-slip displacement (Lettis, 1982; Anderson and others, 1982), and numerous fault-plane solutions for this part of the zone show chiefly right-lateral displacement (LaForge and Lee, 1982). The Holocene strike slip, however, may have been only recently superimposed on the predominant dip slip. GEOLOGY 9 The history of the Tesla-Ortigalita fault zone is very poorly understood. What seems to be a nearly continuous fault zone may actually be an aggregate of fault segments having different origins and different histories. Some segments may have originated during Paleogene uplift, but most of the dip slip occurred in the Neogene. Similar elevations for an isolated 9-Ma basalt flow east of the fault zone near San Luis Reservoir and the base of the upper Miocene Quien Sabe volcanic field west of the fault zone led Lettis (1982, 1985) to conclude that there had been no appreciable differential vertical movement since the late Miocene. More recent work, however, suggests that the isolated flow was derived from a local vent in or near the fault zone itself and had no connection with the Quien Sabe Volcanics (D.H. Sorg, oral commun., 1986). The absence of vertical offset of Quaternary units across the southern segment of the fault zone indicates that there has been no appreciable Quaternary dip slip, but this segment does show evidence of late Cenozoic strike slip (Lettis, 1982; Anderson and others, 1982). The northern segment of the fault zone, the Tesla fault proper, juxtaposes upper Miocene deposits with the Franciscan and, therefore, must have had considerable post-late Miocene dip slip. The history of the big bend segment of the fault between Hospital and Del Puerto Creeks is much more difficult to assess. The present bend in the fault trace might be due to folding since the time of fault formation. If so, the timing of the folding is not known. The San Joaquin fault zone is marked by a series of east-facing scarps and offset Quaternary depositional surfaces that were interpreted by Herd (1979b) as evidence of down-to-the-east normal faulting. Along much of the zone’s length, however, the inferred faults are covered by upper Pleistocene and Holocene alluvium, so that there is some question about both the continuity and the dip of the faults. Bartow (1985) reinterpreted the zone as a series of reverse faults, a conclusion which seems more compatible with the regional framework. Available evidence, which shows that units as young as Pleistocene are offset, suggests that the San Joaquin fault zone may have been active at the same time as the Black Butte and Vernalis faults. A set of subparallel faults between the Tesla-Ortigalita and the San Joaquin fault zones south of San Luis Reservoir (greatly generalized on pl. 1) was termed the O’Neill fault system by Lettis (1982, 1985). This fault system consists of numerous northeast-dipping faults that offset Quaternary pediment surfaces by as much as 100 m (Lettis, 1982, 1985). The faults are apparently bedding-plane slips in the underlying Great Valley se- quence that formed in response to the strong bending of the upturned strata. These faults caused offsets of Quaternary erosion surfaces and their associated depos- its that lie across the beveled edges of the Great Valley sequence. One of the most fundamental structural features of the Diablo Range, as well as elsewhere in the Coast Ranges, is the contact between the Franciscan Complex and the Great Valley sequence (pl. 1, sections A, B). The original. contact, although it has been greatly modified by younger faults like the Tesla-Ortigalita, is apparently tectonic (Page, 1981). This fault contact, commonly termed the Coast Range thrust, is interpreted as the roof thrust of a Franciscan wedge (Wentworth and others, 1983; Went- worth and others, 1984) that has had an influence on Cenozoic regional tectonics since, perhaps, as early as the Paleogene. Paleogene deformation of the northern Diablo Range, which seems to have consisted mostly of broad regional uplift, implies northeast-southwest compression; how- ever, the orientation of the stress cannot be determined with any certainty. Neogene structures reflect a general northeast-southwest compression, but latest Cenozoic right—lateral strike slip and seismicity on the southern segment of the Tesla-Ortigalita fault indicate a north- south or north-northeast—south-southwest compression producing a northwest-southeast shear, at least for the area between San Luis Reservoir and Panoche Valley. WEST-SIDE FOLD BELT The west-side fold belt extends along the southwest side of the valley syncline from about Panoche Creek on the north to the Elk Hills in the southwesternmost San Joaquin Valley. The belt includes the southern Diablo and Temblor Ranges and is characterized by Cenozoic folds and faults that trend, for the most part, slightly oblique to the San Andreas fault on the southwest (pl. 1). The stratigraphy of the west-side fold belt is variable, as might be expected in a tectonically active area. Stratigraphic columns for four separate areas—the Val- lecitos syncline, Kettleman Hills north dome, Lost Hills- Devils Den area, and Elk Hills area (pl. 2, cols. 4,5,7,8)—provide some indication of the variation. Total thickness for the combined Mesozoic and Cenozoic section may be over 9,500 m near the San Joaquin Valley syncline axis. As with the southern Sierran block part of the valley, there is a northward-thinning trend for the Cenozoic (pl. 1, sections B, C) and, particularly for the Neogene, a northward trend toward shallower marine and nonmarine facies. Middle Tertiary deposits repre- senting some of the deepest water in the San Joaquin basin are found in the southern Temblor Range. Older rocks are not as well known in the southern part of the 10 THE CENOZOIC EVOLUTION OF THE SAN JOAQUIN VALLEY, CALIFORNIA fold belt because of the absence of outcrops and the sparsity of wells that reached Paleogene strata. The northernmost fold in the west-side fold belt is the Vallecitos syncline, located just south of Panoche Creek. The southeast boundary of the fold belt is arbitrarily placed east and south of Elk Hills Where the fold trends change from northwest to west. The east boundary deviates from the valley syncline axis near Cantua Creek and south of Kettleman Hills to include the subdued Turk, Buttonwillow, Bowerbank, and Semitropic anti— clines that, although lying east of the valley axis, are structurally more akin to the west-side fold belt than to the less-deformed southern Sierran block. The intensity of deformation increases southeastward along the fold belt as well as southwestward across the belt toward the San Andreas fault (pl. 1). The increased intensity is evidenced by tighter folds and an increased number of reverse and thrust faults (Vedder, 1970; Dibblee, 1973a). Thrust faults seem to be predominantly west dipping, although the faulting in the interior of the Temblor Range is complex. Recent thrust-fault-gener- ated earthquakes at the Coalinga anticline (May 1983) (Eaton, 1985b) and Kettleman Hills (August 1985) (Went- worth, 1985) are evidence of thrusting beneath major west-side folds and indicate the style of Holocene defor- mation along the east side of the fold belt (Wentworth and others, 1983; Wentworth and others, 1984; Namson and Davis, 1984; Medwedeff and Suppe, 1986). The west-side folds are, then, partly a reflection of deep- seated thrust deformation that is related to emplacement of a wedge of the Franciscan Complex. Deflection of the shaleout line of the subsurface, lower Eocene Gatchell sand (of local usage) around the down- plunge end of the Coalinga anticline in the northern part of the fold belt provides evidence that the anticline probably formed in the Paleocene or early Eocene (Harding, 1976). Paleogene deformation is difficult to identify in the southern part, however, because of the deep burial of Paleogene rocks and the strong overprint of Neogene deformation. Harding (1976) outlined the Neogene development of the fold belt in relation to the history of strike slip on the San Andreas fault. The first en echelon folds in the Temblor Range or southern part of the fold belt date from the late early Miocene (near the Saucesian-Relizian boundary), whereas the easternmost anticlines in the fold belt (Buttonwillow, Bowerbank, and Semitropic) are entirely Pleistocene in age. The age of faulting in the fold belt is not well constrained, but eastward-verging thrust faults seem to have formed fairly late in the deformation history in the more tightly folded area near the San Andreas fault (Harding, 1976) and are still active at the west margin of the valley. A fault along the southwest side of the Semitropic anticline has been interpreted as a normal fault (Los Angeles Department of Water and Power, 1975), but the asymmetry of the fold and its abrupt southeast boundary, as seen on proprietary seismic-reflection sections, sug- gest that it may be a northeast-dipping reverse fault. A structure interpreted as a reverse fault by Wentworth and others (1983) appears on a seismic-reflection section in a position on-trend with the Semitropic anticline fault to the northwest. The association of the fault at Semi- tropic With a fold is, in itself, suggestive of compressive deformation. The age of the fault is difficult to assess, but if it is genetically related to the fold, it would be Pliocene or Pleistocene in age. It may, however, be an older structure that has merely served to control the location of the younger fold. The structures of the west-side fold belt cumulatively indicate north-south to northeast-southwest compression through the Cenozoic. During the early Paleogene and most of the Neogene, this compression was apparently manifested as a northwest-southeast shear couple. A tendency for Pliocene and Pleistocene structures to be oriented more parallel to the San Andreas fault indicates an increasing component of compression normal to the fault in the latest Cenozoic. Present-day seismicity at the San Joaquin Valley-Coast Ranges boundary in the north- ern part of the fold belt indicates continuing northeast- southwest compression (Eaton, 1985a). MARICOPA-TEJON SUBBASIN AND SOUTH-MARGIN DEFORMED BELT The Maricopa-Tejon subbasin and the south-margin deformed belt are structurally distinct areas, but they are probably genetically related. The Maricopa-Tejon subbasin is located at the extreme south end of the San Joaquin basin between the Bakersfield arch on the north and the deformed belt of the north flank of the San Emigdo Mountains on the south. These areas are bounded on the east by the Tehachapi Mountains of the southernmost Sierra Nevada and merge westward with the southeast end of the west-side fold belt (fig. 1, pl. 1). The western part of the Maricopa-Tejon subbasin, the Maricopa subbasin proper, is characterized by its great depth—probably more than 9 km to basement in the central part. The south-margin deformed belt is charac- terized by the northward—directed thrust faulting at the south edge of the basin. Extreme Neogene subsidence, together with thrust faulting that resulted in several kilometers of crustal shortening in the late Cenozoic (Davis, 1983), is evidence that the south end of the San Joaquin basin is the most highly deformed part (pl. 1, section D). The Maricopa subbasin contains the thickest Cenozoic deposits in the San Joaquin basin. Neogene and Quater- nary strata are more than 6,100 m thick at the Paloma oil GEOLOGY 11 field, a few kilometers east of Buena Vista Lake Bed (pl. 1). The thickness of Paleogene strata in the central part of the basin is not known because few wells have reached the Paleogene and none have reached basement; how- ever, more than 1,750 m of Paleogene strata crop out near San Emigdio Creek on the south side of the basin (pl. 2, col. 10) and a greater thickness might be present downdip to the north. There are no known Cretaceous or Paleocene deposits south of the Bakersfield arch. Eocene strata rest on basement rocks in the San Emigdio Mountains and at South Coles Levee oil field at the west end of the Bakersfield arch (Church and Krammes, 1957), but no wells have reached the basement in the intervening area. Paleobathymetries recorded in the middle Tertiary deposits of the Maricopa-Tejon subbasin are the deepest found in the San Joaquin basin. Abyssal depths (about 1,800 m) were reached in the Zemorrian, Saucesian and Luisian Stages (Bandy and Arnal, 1969). Paleogene nonmarine strata were deposited on the east and south- east, and the basin gradually shallowed through the late Neogene and became entirely nonmarine in latest Plio- cene time. Structural trends are variable in the Maricopa-Tejon subbasin and south-margin deformed belt, but there is a general west trend along the south margin of the basin. The northwest fold trends of the west-side fold belt change to west-northwest where that region merges with the deformed belt at the south end of the valley. The folds and faults of the San Emigdio Mountains, dominated by the Pleito thrust fault system, form a northward-directed salient with an average west fold trend. To the north and northeast, the northeast-trending White Wolf fault is the dominant structure. The White Wolf fault and the smaller Springs fault to the southeast both trend approx- imately parallel to the Garlock fault, which lies along the southeast side of the Tehachapi Mountains. Both faults, like the Garlock, show some geologic evidence of left- lateral movement. Farther northeast, the northwest- to west-trending Edison fault is an older Tertiary normal fault with down-to—the-north offset of over 1,500 m (Dibblee and Chesterman, 1953; Bartow, 1984). The south margin of the San Joaquin basin, in addition to being the most highly deformed part of the basin, probably has the most complex tectonic history. Evi- dence of possibly the earliest deformation is provided by paleomagnetic data that indicate a clockwise rotation of the Tehachapi Mountains of 45° to 60° that took place between 80—100 Ma and 16 Ma (Kanter and McWilliams, 1982; McWilliams and Li, 1985). Some of this rotation probably occurred in the Late Cretaceous or early Tertiary and the remainder took place after eruption of volcanic rocks in the earliest Miocene (Plescia and Cal- derone, 1986). Geologic evidence of the earliest Cenozoic deformation is a major angular unconformity in the western San Emigdio Mountains where upper Oligocene and lower Miocene sediments of the Temblor Formation overlap truncated older Tertiary units and rest on basement rocks (Nilsen and others, 1973; Davis, 1986). Although no specific faults can be positively identified as having been active during the period of tectonism, which may have begun in the late Eocene and extended into the Oligocene, Davis (1986) suggested that Oligocene uplift of the San Emigdio Range was produced largely by a major south-verging thrust fault. The Caballo Canyon fault, identified by Davis (1986) as the Oligocene thrust, is an obscure fault (not shown on pl. 1) that has been subject to other interpretations (Davis, 1983), so the hypothesized Oligocene thrusting remains somewhat questionable. Normal faults at the south margin of the basin have generally west trends (from northwest to northeast) and occur mainly in the subsurface (Hirst, 1986; Davis, 1986). These faults were active during the latest Oligocene and early Miocene, concurrent with volcanism dated at 22.1 to 22.9 Ma2 (Turner, 1970) and basin subsidence (Hirst, 1986; Davis, 1986). The mostly west-trending Edison normal fault, as well as other normal faults of general west trend in this region of the basin, was also active at that time. Most of the deformation of the San Emigdio Moun- tains, including uplift and folding, is late Cenozoic and is directly related to thrust faults of the Pleito fault system (Davis, 1986). These thrusts date only from the Pliocene and, on the basis of the earliest appearance of coarse detritus in the basin to the north, most of the uplift was in the late Pliocene and Pleistocene (Davis, 1986). Al- though the basin continued to subside through the Miocene, subsidence accelerated during the Pliocene (Davis, 1986; Hirst, 1986). The White Wolf fault, which was the locus of the magnitude 7.2 Arvin-Tehachapi earthquake of July 1952, is a southeast-dipping reverse fault (Oakeshott, 1955; Stein and Thatcher, 1981). Total vertical separation on the basement surface has been at least 3,600 m (Stein and Thatcher, 1981) or possibly more than 4,600 m (Davis, 1983). Although seismologic data from the 1952 earth- quake indicate a component of left-lateral slip (Oake- shott, 1955; Stein and Thatcher, 1981), evidence for large cumulative left-lateral displacement is ambiguous and the total lateral offset may be small relative to the large vertical offset (Davis, 1986). The early history of the White Wolf fault is uncertain, but it may have originated as a down-to-the-northwest normal fault during the late Oligocene and early Miocene 2Dates have been converted from old to new (1977) constants according to Dalrymple (1979). 12 THE CENOZOIC EVOLUTION OF THE SAN JOAQUIN VALLEY, CALIFORNIA period of normal faulting (Davis, 1986). There is strati- graphic evidence of continued down-to—the-northwest movement accompanying basin subsidence through the Miocene, probably as a normal fault (Davis, 1986). More recently, probably during the Pliocene or Pleistocene, the configuration of the fault was apparently changed to the southeast-dipping reverse fault that it is today. The stress regime in which the early Oligocene defor- mation took place is obscure, but it presumably involved an approximate north-south compression. The latest Oligocene and Miocene normal faulting and volcanism, in contrast, clearly indicates extension, probably with a general north-south orientation. The Pliocene to H010- cene thrust faulting is also a clear indication of strong compressive tectonism, again with a north-south orien— tation. The tectonic history of the south end of the San Joaquin basin seems, therefore, to be one of alternating periods of compression and extension, all in a north-south direction. MAJOR CONTROLS ON SEDIMENTATION The Cenozoic stratigraphic record in the San Joaquin basin seems, at first glance, to be a far-from-ideal record of basin history. It is incomplete, particularly in the northern part of the basin; it is poorly dated in many places; and, it exhibits wide variations in facies from area to area. The gaps and complexity, however, are impor- tant parts of the record and they can provide important clues to basin history. Stratigraphic sections from different parts of the basin (pl. 2) can be informally divided, where they consist mostly of marine deposits, into depositional sequences that are composed of transgressive-regressive couplets that formed principally in response to relative changes in sea level in combination with sedimentation. A relative rise in sea level, that is, the eustatic rise plus the effect of subsidence, does not necessarily equate with trans— gression, nor does a relative fall in sea level necessarily equate With regression. If, for example, sedimentation exceeds the relative rise of sea level, then a regression will result. The marine sedimentary sequences of this report, which are commonly but not necessarily unconformity bounded, facilitate correlation from area to area within the basin. In a few cases an unconformity-bounded marine sequence may be approximately correlated with a nonmarine sequence on the basis of the bounding uncon- formities. The fact that correlatable sequences are present throughout the basin provides evidence for external control of the sedimentary record, and although the sequence is the primary record of basin history, the unconformities bounding the sequence are equally impor- tant. The goal in deciphering basin history is to identify the cause or causes of each event. The major external controls on sedimentation are tectonism, eustatic sea-level change, and climate. The sedimentary record represents the complex interplay of all of these factors, although tectonism is clearly domi- nant. Any thick accumulation of sediments, such as that found in the southern San Joaquin basin, clearly implies tectonic subsidence. Furthermore, the location of this basin along an active continental margin virtually assures tectonic activity in some form, throughout the Cenozoic. The other factors, sea-level change and climate, play important roles as well, perhaps more so than previously recognized. TECTONICS Tectonics, as it applies to the Cenozoic San Joaquin basin, includes basin subsidence, uplift of the adjacent Sierra Nevada and Coast Ranges, and contemporaneous deformation of the basin itself such as faulting and folding. Closely associated with tectonism is volcanism at the margins of the basin and in adjacent regions. The various aspects of Pacific Coast Cenozoic tectonics should be explicable in terms of the interactions of the crustal plates at the western edge of North America. Since the ascendency of the plate tectonics paradigm, knowledge of how plate interactions have influenced regional tectonics on the California margin has grown steadily. Before discussing the regional tectonic events that played a part in the evolution of the San Joaquin basin, it is appropriate to briefly review the plate tectonic events that are most relevant to the central California part of the continental margin. PLATE TECTONICS A subduction zone has existed at the western margin of North America throughout the Cenozoic (pl. 2). From the Late Cretaceous until about the middle or late Eocene (75 to 40 Ma), the relative plate motions resulted in oblique subduction of an oceanic plate, probably the Kula plate (Page and Engebretson, 1984). Rapid convergence rates during this period produced a low-angle subduction zone and consequent displacement of arc magmatism eastward from the Sierra Nevada into Colorado (Lipman and others, 1972; Snyder and others, 1976; Coney and Rey- nolds, 1977; Cross and Pilger, 1978). Oblique subduction at the central California margin continued until nearly the end of the Eocene when the Farallon plate, which had a more normal component of motion relative to North America, supplanted the Kula plate at central California latitudes (Page and Engebretson, 1984). Slowdown in the MAJOR CONTROLS ON SEDIMENTATION 13 convergence rates from the late Eocene into the Oligo- cene resulted in steepening of the subduction zone and the consequent migration of volcanism southwestward from Idaho and Montana into Nevada (Lipman and others, 1972; Snyder and others, 1976; Cross and Pilger, 1978). The San Andreas transform originated in mid-Oligo- cene time (28-30 Ma) (Atwater and Molnar, 1973; Enge- bretson and others, 1985) when the ancestral East Pacific rise first encountered the subduction zone. The term “San Andreas transform” is used here, as it was by Dickinson and Snyder (1979), for the whole system of subparallel faults that constitute the plate boundary. The initial slip was probably offshore on faults at or near the continental margin (Garfunkel, 1973; Dickinson and Sny- der, 1979). Slip on the San Gregorio-Hosgri fault zone and San Andreas fault proper probably did not begin until nearly middle Miocene time (about 16—17 Ma); most of the initial slip was on the San Gregorio-Hosgri fault (Gra- ham, 1978). The transform lengthened as paired triple junctions migrated northwestward and southeastward along the continental margin. Relative positions of the North American and Pacific plates in the Neogene, recon- structed according to the global-circuit method (Atwater and Molnar, 1973), differ somewhat from the reconstruc- tion by the hot-spot method (Engebretson and others, 1985). Although the difference between the two recon- structions is within the limits of probable error (Enge- bretson and others, 1985), the northward migration history of the Mendocino triple junction from the global- circuit method seems to provide the best fit to geologic history. The unstable configuration of the migrating triple junction (trench and transform not colinear) in- duced a wave of extensional tectonism in nearby regions (Dickinson and Snyder, 1979; Ingersoll, 1982). Local volcanism in west-central California was approximately coincident with the passage of the triple junction and is a further manifestation of the extensional regime (Dickin- son and Snyder, 1979; Johnson and O’Neil, 1984; Fox and others, 1985). The plate reconstructions of Atwater and Molnar (1973) suggest an increase in relative motion between the North American and Pacific plates at about 10 Ma, although this increase is expressed as a change in average rates for the period of 21 to 10 Ma versus 10 to 4.5 Ma and the change may have been a gradual one over several million years. Page and Engebretson (1984) showed an increase in slip rate at about 15 Ma, and Cox and Engebretson (1985) inferred a small change in motion at 8.5 Ma, but nothing at 10 Ma. The differences may be more apparent than real and may be simply a result of the different methods used in the reconstructions. In any case, there was an acceleration of the slip rate on the San Andreas fault at 10 to 12 Ma (Huffman, 1972; Graham, 1978). At about 5 Ma the motion of the Pacific plate changed to a more northerly direction, resulting in a component of compression normal to the San Andreas transform (Min- ster and Jordan, 1984; Page and Engebretson, 1984; Cox and Engebretson, 1985). Opening of the Gulf of California at about the same time, 5.5 Ma according to Moore and Curray (1982), indicates increased coupling between the sliver of former continental terrane west of the transform and the Pacific plate. This increased coupling resulted in an acceleration of the slip rate on the San Andreas fault. REGIONAL TECTONICS The earliest Cenozoic tectonic events that affected the region of the San Joaquin basin were probably related to movements of the proto-San Andreas fault during the Paleocene and possibly early Eocene. Right-lateral strike-slip movement on the proto-San Andreas was concurrent with oblique subduction and is generally believed to have ended by about the end of the Paleocene (Nilsen and Clarke, 1975; Dickinson and others, 1979). Inasmuch as oblique subduction at the central California margin continued until nearly the end of the Eocene, strike-slip movement could conceivably have continued well into the Eocene, although the evidence is equivocal. A clockwise rotation of the southernmost Sierra Nevada, demonstrated by paleomagnetic data, has been inferred to reflect oroclinal bending due to right-lateral shear along the proto-San Andreas fault (Kanter and McWilliams, 1982; McWilliams and Li, 1985). This oro— cline might also be considered a tectonic effect of the accretion of the Tujunga terrane (part of the Salinia composite terrane) to the North American craton in the Mojave region near the end of the Paleocene (Howell and others, 1987; Nilsen, 1987). The large folds at the northwest end of the fold belt—that is, the Vallecitos syncline, Joaquin Ridge anticline, and White Creek syncline—are apparently of the right age and orientation to have originated as an en echelon fold set associated with right slip on the proto-San Andreas fault (Harding, 1976). Early Paleogene fold growth might also be con- sidered an indication of thrusting associated with early eastward movement of a Franciscan wedge at depth. The evidence is insufficient to make a definitive statement, but both processes may have been operative. The Stockton arch at the north end of the San Joaquin basin has a more enigmatic origin. It has been suggested that it formed by crustal buckling at the tectonic transi- tion between a region of oblique subduction with proto- San Andreas strike slip to the south, and a region of oblique subduction without strike slip to the north (Nilsen and Clarke, 1975; Dickinson and others, 1979). 14 THE CENOZOIC EVOLUTION OF THE SAN JOAQUIN VALLEY, CALIFORNIA This origin is unlikely because of the absence of basement arching (pl. 1, section D). The broad high of Cretaceous rocks made apparent by later truncations is probably a result of localized structural or sedimentary thickening of the Cretaceous section. Structural thickening, although possible, seems less likely because there is no evidence of stratigraphic repetition by thrust faults or any other deformation within the Cretaceous section. Sedimentary thickening, on the other hand, seems more likely because there is some evidence of thickness changes associated with the arch. An isopach map of the Lathrop sand (of local usage), for example, shows an abrupt northward thinning across the trend of the Stockton fault (Hoffman, 1964). The total Cretaceous section is also thicker south of the fault, even though some of the section has been removed by post-Eocene erosion (pl. 1, section D). Well data indicate that the basement is higher north of the Stockton fault than it is to the south, under the arch (Hoffman, 1964; Teitsworth, 1964; Bartow, 1983), and thickness changes Within the Cretaceous section imply down-to—the-south faulting concurrent with sedimenta- tion. Inasmuch as Cenozoic movement on the fault has been down to the north, there must have been a major south-side-down offset of the basement surface during the Cretaceous. The high basement on the north and the increased Cretaceous thickness on the south can be alternatively attributed to post-Cretaceous left-lateral slip on the Stockton fault, but the amount of offset required (several kilometers) makes this an unlikely interpretation. Latest Cretaceous or Paleocene south- side—up movement on the Stockton fault would reduce the Cretaceous throw on the basement surface and raise the Cretaceous rocks in the area to the south. The feature that has come to be known as the Stockton arch might be, then, simply an up—tilted fault block. Whatever its origin, the Stockton arch area persisted as a positive element throughout the remainder of the Cenozoic. The Franciscan-Great Valley sequence fault boundary (the Coast Range thrust) may have been reactivated in the Tertiary, initially during the period from about 60 to 50 Ma when plate convergence was at a maximum (Page and Engebretson, 1984). Cenozoic activity at this bound- ary probably resulted from the emplacement of a wedge of Franciscan between the Great Valley sequence above and crystalline basement below, as proposed by Went— worth and others (1984) (pl. 1, sections A, B). Oligocene events in southern California had an effect on the southernmost San Joaquin basin. A regional uplift in the south, together with the formation of fault- bounded alluvial basins, has been ascribed to the ap- proach of the ancestral East Pacific rise to the North American plate and subduction of young, buoyant litho- sphere somewhat in advance of the actual arrival of the spreading ridge at the trench in mid-Oligocene time (Nilsen, 1984; Crowell, 1987). The principal effect for the San Joaquin basin seems to have been uplift and faulting of the south end of the basin, particularly the San Emigdio Mountains and southernmost Sierra Nevada (Davis, 1983, 1986). The evolution of extensional deformation in the Basin and Range province probably also had an indirect effect on the San Joaquin basin. The beginning of the exten- sional stress regime in the Basin and Range during the Oligocene is related to the evolution of the arc-trench system. The transition from compression to intra-arc extension and then to back-arc extension took place as the subduction angle steepened and the eastern limit of magmatism consequently migrated southwestward (Eaton, 1979). The intra-arc and back-arc extension was oriented at right angles to the trend of the trench (Zoback and others, 1981) and may have produced compression in the region (including the San J oquin basin) between the Basin and Range province and the trench. ' Wrench tectonics in conjunction with deep-seated thrusting along the southwest side of the basin adjacent to the San Andreas fault dominated the Neogene. The earliest conclusive evidence of en echelon folding appears in the stratigraphic record near the end of Saucesian time (about 16-17 Ma) (Harding, 1976). Additionally, the provenance and distribution of Miocene sandstone in the Temblor Range suggest that strike slip may have begun by late early Miocene time on the central California portion of the San Andreas fault (Graham and others, 1986). This timing is consistent with the fault offset history of Huffman (1972, fig. 13). Progressive basinward expansion of the fold belt, together with cessation of folding near the San Andreas while it continued farther east, suggested to Harding (1976) that the folds and the San Andreas fault were independent responses to a diffuse coupling in the deep crust, and that the folds propagated outward in an expanding deformational front. The fact that younger folds, like the Kettleman Hills and Lost Hills anticlines, are approximately parallel to the San Andreas and not oblique to it indicates that they are not purely a response to shear in the San Andreas system. The basinward expansion of the Kettleman Hills-Lost Hills part of the fold belt seems to be, in contrast to the model proposed by Harding (1976), a response to an eastward-advancing thrust front at depth associated with the emplacement of a Franciscan wedge at the base of the Great Valley sequence (Wentworth and others, 1983) (pl. 1, sections A, B). Extension in the Basin and Range province again had an effect on the San Joaquin basin in the Miocene. Basin and Range faulting began in the late Miocene, probably about 10 Ma (Zoback and others, 1981), and probably related left-lateral movement on the Garlock fault is assumed to have begun at about the same time. This MAJOR CONTROLS 0N SEDIMENTATION 15 extension resulted in the westward movement of the Sierra Nevada block, carrying the San Joaquin basin with it, and the consequent formation of the bend in the San Andreas fault (Davis and Burchfiel, 1973; Hill, 1982; Bohannon and Howell, 1982). The space problem arising from this westward movement probably caused compres- sion normal to the San Andreas at the west side of the Sierran block (Wentworth and Zoback, 1986). The last major uplift of the Sierra Nevada is also believed to have begun after 10 Ma (Christensen, 1966; Huber, 1981), but the uplift and the westward movement may not have been directly related. It has been sug- gested that the late Cenozoic uplift of the Sierra Nevada was caused by thermal thinning of the lithosphere after northward passage of the Mendocino triple junction (Crough and Thompson, 1977; Mavko and Thompson, 1983). The cold subducting slab north of the triple junction insulated the overlying continental lithosphere, whereas subduction had stopped south of the triple junction which allowed the base of lithosphere to be heated and converted to less-dense asthenosphere. Acceleration in the slip rate on the San Andreas fault in latest Miocene and Pliocene time correlates with an increase in deformation in the fold belt adjacent to the fault (Harding, 1976); this acceleration may have contrib- uted to the rapid subsidence of the southern San Joaquin basin (Dickinson and Snyder, 1979; Davis, 1983). Fault- normal compression in Pliocene and Pleistocene time, resulting from changes in relative plate motion at about 5 Ma, produced fault-parallel folds and reverse faults (Zoback and others, 1987). This compression probably caused uplift of the Temblor and Diablo Ranges (Enge- bretson and others, 1985) and, together with the devel- oping bend in the fault, was probably the principal factor leading to northward-directed thrusting at the south end of the basin. The Cenozoic subsidence history of the San Joaquin basin in relation to regional tectonics is not well known. Inferences about subsidence have been made from esti- mates of paleobathymetry and from the present depth and basinward-thickening trends of individual strati- graphic units, but because of the lack of precision in both paleoecology and absolute age of the commonly used benthic foraminiferal faunas, some margin of error exists in reconstructions of subsidence history. Preliminary attempts at geohistory analysis have been made by Dickinson and others (1987), Moxon (1986), and Olson and others (1986). Collectively, these studies suggest periods of rapid subsidence in the (1) late Paleocene and earliest Eocene, (2) middle Eocene, (3) latest Oligocene and early Miocene, and (4) middle and late Miocene. Uplifts are suggested in the Oligocene and near the early Miocene- middle Miocene boundary. These generalizations are based on preliminary geohistory analyses of widely separated parts of the basin and, consequently, an event identified from any one locality is not necessarily a basinwide event. It should be noted that a rapid rise in relative sea level can also result from steady basin subsidence in combination with a eustatic rise in sea level. Nevertheless, geohistory analysis is a promising technique and will ultimately provide valuable informa- tion on basin evolution. At the present time, however, a detailed subsidence history has not been established for the San Joaquin basin, nor is it possible to identify with much certainty the specific causes of tectonic subsidence. SEA-LEVEL CHANGE Eustatic sea-level change can result from changes in the volume of ocean water, changes in the volume of the ocean basin, or possibly both. The processes that can contribute to sea-level change were reviewed by Pittman (1978) and Donovan and Jones (1979). Those that are potentially most significant in terms of rate and magni- tude are (1) fluctuations in continental ice sheets, (2) changes in volume of the mid-ocean ridge system, and (3) desiccation and flooding of isolated ocean basins. An additional process, suggested by Schlanger and others (1981), is mid-plate thermal uplift and volcanism in ocean basins. Ultimately, all processes affecting sea level can be traced back, directly or indirectly, to global tectonics (fig. 2). Sea-level change controls sedimentation by controlling the environment of deposition. This is most obvious near the strandline where change in sea level produces lateral shifts of nonmarine and shallow-marine environments. The stratigraphic record of sea-level change along an active continental margin will probably be obscure be- cause the effects of the prevailing tectonism will tend to mask the relatively minor effects of sea-level change. Without a global standard sea—level curve to which local sections may be compared, it would be virtually impos- sible 'to identify any particular event in the sedimentary record as sea-level controlled. The coastal-onlap curves of Vail and coworkers (Vail and others, 1977; Vail and Hardenbol, 1979) and the eustatic sea-level curve of Haq and others (1987) provide a standard for comparison. The eustatic sea-level curve (Haq and others, 1987) used in this report (pl. 2) has been adjusted to fit the Cenozoic chronology of Berggren and others (1985). Although the basic concept of eustatic fluctuation of sea level through geologic time is generally accepted, questions have been raised about the actual influence of sea level on the stratigraphic record and about the validity of the Vail sea—level model (Watts, 1982; Parkinson and Summer- hayes, 1985; Miall, 1986). The Vail model is still being tested and revised, but some results to date suggest that it may be accurate enough, if used with caution, to serve 16 THE CENOZOIC EVOLUTION OF THE SAN JOAQUIN VALLEY, CALIFORNIA as a useful tool in interpreting continental margin history (May and others, 1984; Poag, 1984; Poag and Schlee, 1984; Aubry, 1985; Poag and Ward, 1987). The coastal-onlap curve of Vail and others (1977) was originally equated directly with relative change of sea level. The asymmetric shape of the curve, representing long periods of sea-level rise followed by apparently instantaneous fall, provoked some controversy. It is now recognized that the coastal-onlap curve does not equate directly with global change in sea level, but the lows in the sawtooth pattern, representing downward shifts of coastal onlap, mark times of global unconformities. These unconformities correlate with inflection points on the eustatic sea—level curve during periods of falling sea level, so that the lowstand of sea level actually comes shortly after the downward shift in coastal onlap (Vail and others, 1984). Unconformity—bounded sequences of local sections can then be compared with the eustatic curve by correlating unconformities with the inflection points on the curve. Correlation of unconformities be- tween the global standard and local sections is evidence that supports sea-level control, but it does not prove exclusive sea-level control because global tectonism can affect sea level as well as local tectonic activity. CLIMATE With the exception of glacial and periglacial environ- ments of the Ice Ages, climate is the least influential of / GLOBAL TECTONICS / // l / / / ¢ Epei rogeny / / II \ // / I Subduction \\ / / l V \ / I, ' M.O.R. \ / l “ volume 0 rogeny, \\ I l . isostasy \ I \ Geoudal | l \ va riation 4 l I \ , I l‘ ‘ l/ I, \ Basin Ocean-basin / / \\ desiccation volume // ll \ / / Ma ri ne Glaciation // sedimentation \ i // EUSTATIC SEA LEVEL FIGURE 2. —Interrelation of factors causing eustatic fluctuations of sea level. The major controls on volume changes of the ocean basins and of the global hydrosphere are enclosed in boxes. Ultimately, global tectonics is the overriding influence, either directly (solid lines) or indirectly (dashed lines). M.O.R., mid-ocean ridge. From May and others (1984). the controls on sedimentation. The climatic influence is more likely to be reflected in the character of the sediments, that is, facies or mineral composition, than it is in the control of transgressions or regressions. The Tertiary was a period of general climatic deterio- ration from the very warm global climates of the Late Cretaceous to the cool glacial climate of the Quaternary. Climates were warmest during the Eocene, when a low latitudinal temperature gradient and high precipitation prevailed (Frakes, 1979; Wolfe, 1978). A rapid deterio- ration near the Eocene-Oligocene boundary led to glacial conditions in Antarctica during the Oligocene (Frakes, 1979; Mathews, 1984) and generally cooler, dryer global climates. Temperatures warmed somewhat during the late Oligocene, early to middle Miocene, and latest Miocene, but at no time were temperatures as warm as those of the Eocene (Wolfe and Hopkins, 1967; Addicott, 1970). The climate fluctuated in the Neogene, but the overall trend was toward cooler temperatures. Sea-level glaciation in the Arctic and alpine glaciation in the Sierra Nevada both date from the late Pliocene (Frakes, 1979). In the San Joaquin basin, the warm, wet tropical climate of the Eocene is reflected in the quartz-kaolinite sandstone and lignite, along with the associated laterites, of the Eocene deposits. Outwash from alpine glaciers in the Sierra Nevada contributed to the San Joaquin basin alluvial sedimentation beginning in late Pliocene time; the pluvial climate of the Pleistocene resulted in a series of large lakes in the San Joaquin Valley. THE SEDIMENTARY RECORD The early Cenozoic sedimentary history of the San Joaquin basin is fundamentally different from that of the later Cenozoic, as can be seen on plate 2. The early Cenozoic is characterized by a few long-lasting basinwide depositional sequences, whereas the later Cenozoic is characterized by shorter sequences of more local extent. The change took place during the Oligocene at about the beginning of the transition from a convergent continental margin to a transform margin. This fundamental change in sedimentation patterns seems to show a clear correla- tion to the change in continental margin tectonics, but other more localized sedimentary events are not always easily analyzed. . PALEOGENE GREAT VALLEY SEQUENCE The Upper Cretaceous and lower Tertiary part of the Great Valley sequence represents the last phase of deposition in the late Mesozoic to early Tertiary forearc basin. It consists principally of deep-sea fan deposits and associated facies on the west side of the basin and THE SEDIMENTARY RECORD 17 shallow-marine to deltaic deposits on the east side (Ingersoll, 1979; Cherven, 1983). The uppermost or lower Tertiary part of the sequence consists mostly of west- ward-prograding slope, shelf, and deltaic facies (Cher- ven, 1983). The Great Valley sequence is apparently absent south of the Bakersfield arch, as noted earlier. This absence may be due to uplift associated with the oroclinal bending of the southernmost Sierra Nevada in the early Tertiary. The Great Valley sequence is separated from the overlying upper Paleocene and lower Eocene sequence, consisting principally of the Tesla and Lodo Formations, by an unconformity (pl. 2). In the northern Diablo Range at the west end of the Stockton arch, there is a slight angular discordance at the unconformity, whereas far- ther south on the west flank of the northern Diablo Range, the Moreno and Tesla Formations are concord- ant. The contact between the Moreno and Laguna Seca Formations appears to be gradational in exposures just south of Los Banos (Briggs, 1953), but still farther south at the type area of the Lodo Formation, there is paleontologic evidence of a hiatus (Berggren and Aubert, 1983); in the Vallecitos syncline there is evidence of an unconformity with westward overlap of the Lodo For- mation on the Great Valley sequence (White, 1940; Dibblee, 1979a). Despite apparent conformity locally, there is probably at least a disconformity at the contact throughout the basin, and the base of the overlying sequence is transgressive. An angular unconformity at the top of the Great Valley sequence was probably produced in the northern part of the basin by uplift of the Stockton arch during the Paleocene. In the central and possibly southern Diablo Range, the unconformity was probably a result of either concurrent en echelon folding associated with movement on the pr0t0~San Andreas fault (Harding, 1976) or. thrusting associated with emplacement of a Franciscan wedge. The angular discordance is always slight or nonexistent, however, and indicates only mild deforma- tion. The unconformity between the Great Valley sequence and the upper Paleocene and lower Eocene sequence correlates with the boundary between global supercycles “TA1” and “TAZ” in the sequence stratigraphy of Haq and others (1987) (pl. 2). The good correlation suggests that sea—level change was a major contributing factor to the regression that produced the unconformity. The widespread nature of the unconformity in the San J oa— quin basin and the absence of evidence for strong deformation also support this interpretation. UPPER PALEOCENE AND LOWER EOCENE SEQUENCE The deposits of the upper Paleocene and lower Eocene sequence show a prominent shoaling trend northward onto the Stockton arch (Nilsen and Clarke, 1975). The Lodo Formation in the Vallecitos syncline area, and to the southeast, consists of thin neritic deposits at the base that are overlain by middle or lower bathyal deposits (Berggren and Aubert, 1983). In the northern part of the basin, the equivalent units consist of neritic or shallower facies that include common nearshore marine and fluvial- deltaic facies flanking the Stockton arch (Dickinson and others, 1979). The amount of deepening during this rapid transgression in the southern part of the basin was 400 m or more (Berggren and Aubert, 1983). This is more than could be accounted for by a sea-level rise alone and indicates a pronounced southward or southeastward tilt of the basin during latest Paleocene or early Eocene time. Deposition of the upper Paleocene and lower Eocene sequence ended after a regression that culminated in a widespread unconformity (pl. 2). The overlying Eocene sequence, consisting of the Domengine Sandstone, the Kreyenhagen Shale, and their correlatives, rests on rocks as old as Cretaceous in the southern Diablo and northern Temblor Ranges (Dibblee, 1973a) and laps onto Sierran basement rocks on the east side of the basin (Bartow, 1985). Although the sequence is not in deposi- tional contact With Franciscan rocks, Franciscan detri- tus, in the form of red and green radiolarian chert pebbles or glaucophane, is present in basal sandstones of the sequence in the southern Diablo Range (Nilsen and Clarke, 1975; Dickinson and others, 1979). The uncon- formity seems to be present throughout the northern part of the basin, as evidenced by the local truncation of lower Eocene and even Paleocene rocks (Church and Krammes, 1958; Bartow, 1985). However, from the Kettleman Hills southeastward, the upper Paleocene and lower Eocene and the overlying Eocene sequences ap- pear to be conformable (Church and Krammes, 1959). There are virtually no data on rocks older than late Eocene in the southern Temblor Range. The offset equivalent of these older rocks on the opposite side of the San Andreas fault, however, now lies in the Santa Cruz Mountains more than 300 km to the northwest (Clarke and Nilsen, 1973). The deep-sea fan deposits of the offset Point of Rocks Sandstone Member of the Kreyenhagen Shale (San Joaquin basin) and Butano Formation (Santa Cruz Mountains) span the time represented by the regression, but indicate continued bathyal sedimentation in the southwestern part of the basin (Clarke, 1973; Nilsen and Clarke, 1975) and in its western extension (Nilsen and Clarke, 1975; Stanley, 1985). The unconformity between the upper Paleocene and lower Eocene sequence and the overlying Eocene se- quence correlates with the boundary between the “TA2” and “TA3” global supercycles of Haq and others (1987) (pl. 2). Similarly correlative unconformities have been recorded in several areas on the Pacific coast (Berggren and Aubert, 1983; May and others, 1984), in Libya (Barr and Berggren, 1981), and in several areas of Europe (Aubry, 1985). The global nature of this unconformity is 18 THE CENOZOIC EVOLUTION OF THE SAN JOAQUIN VALLEY, CALIFORNIA strong evidence for lowered sea level at the end of the early Eocene. However, an angular discordance at the unconformity and Franciscan detritus above the uncon- formity provide convincing evidence of concurrent tec- tonic activity in central California. Coarse Franciscan detritus appears to be concentrated in a belt that lies in the southern Diablo Range as far north as the Vallecitos syncline. Assuming 305 km of Neogene offset on the San Andreas fault (Clarke and Nilsen, 1973) and 115 km on the San Gregorio-Hosgri fault trend (Graham and Dick- inson, 1978), the belt would lie adjacent to the inferred Paleogene position of the north end of the Salinia terrane. If 150 km of offset is assumed for the San Gregorio- Hosgri fault (Clark and others, 1984), the belt would lie just north of the inferred north end of the Salinia terrane. This location of the belt suggests a relation between uplift of the Franciscan Complex and emplacement of the Salinia terrane. Franciscan source areas may have been uplifted following emplacement of the Salinia terrane to the west, as suggested by Dickinson and others (1979). Inasmuch as emplacement of the Salinia terrane opposite the southern San Joaquin basin in the early Tertiary must have involved strike slip on the proto-San Andreas or closely related faults, the uplift in the area of the Diablo Range may, then, have been due to related wrench tectonism that continued into the early Eocene. The role of wrench tectonism at that time is, however, question- able, and the uplift might better be considered as evidence of early Tertiary thrust emplacement of a Franciscan wedge at depth under the southern Diablo Range, just north of the north end of the Salinia terrane. Whatever the tectonic mechanism, the regression at the end of the early Eocene was probably produced by a combination of eustatic sea-level change and local uplift. EOCENE SEQUENCE Deposition of the Eocene sequence began during a rapid transgression. A minor hiatus near the base of the sequence (Milam, 1985) is associated with a condensed section, as evidenced by abundant glauconite and low sedimentation rates in the basal Kreyenhagen Shale. Milam (1985) calculated a sedimentation rate of less than 1 cm/1,000 years for the lower part of the Kreyenhagen. The hiatus and condensed section are results of rapid rise of relative sea level that produced starved—basin-type sedimentation and was probably caused by rising global sea level combined with basin subsidence. Deposition of the bathyal shale that makes up most of the sequence corresponds to a highstand of sea level on the eustatic sea-level curve of Haq and others (1987). A regression at the end of the Eocene is apparent mostly on the flanks of the Stockton arch in the northern part of the basin and in the San Emigdio Mountains at the south end of the basin (pl. 2). A minor reversal of the overall Paleogene transgressive trend along the south- eastern margin of the basin is evidenced by intertonguing nonmarine and shallow-marine deposits (Bartow and McDougall, 1984). Elsewhere in the southern part of the basin, deep-marine sedimentation prevailed into the Oligocene with only slight to moderate shallowing; an unconformity in the Temblor Range area (pre-Temblor Formation) was interpreted by Carter (1985) as a result of submarine erosion at bathyal depths. Evidence of tectonic activity near the Eocene-Oligocene boundary appears in the Poverty Flat Sandstone along the east flank of the Diablo Range in the northwest, and in the Tecuya and Pleito Formations in the south. The Poverty Flat contains a conglomerate that consists principally of red radiolarian-chert pebbles derived from the Fran- ciscan Complex and a few other pebbles of Franciscan and ophiolite lithologies (Bartow and others, 1985). This conglomerate represents the earliest appearance of ap- preciable coarse Franciscan detritus in the northern Diablo Range. Lenses of granitic breccia at the base of the Tecuya (Nilsen and others, 1973) and in the lower part of the Pleito in the San Emigdio Mountains were interpreted by DeCelles (1986) as a result of a seismically triggered rockslide and associated submarine mass move- ments. Syndepositional deformation structures in coeval sediments were ascribed to the results of seismic shak- ing. This inferred seismic event may mark the beginning of Oligocene tectonic activity at the south end of the basin. Uplift of a Franciscan source area in the northern Diablo Range at the end of the Eocene was probably, as was the earlier uplift in the southern Diablo Range, a result of thrust emplacement of a Franciscan wedge at depth. This is, in turn, inferred to be a subduction-related process. A change from oblique to normal subduction is believed to have taken place near the end of the Eocene, although there was a net decrease in the normal compo- nent of plate convergence through the Oligocene and a consequent steepening of the angle of subduction (Page and Engebretson, 1984). The approach of the spreading ridge to the continental margin (Engebretson and others, 1985) would have resulted in the subduction of young, buoyant lithosphere. No definite cause and effect rela- tions can be established, but it seems probable that regional tectonic activity from the latest Eocene into the Oligocene was related to these plate tectonic events. Furthermore, Paleogene deformation in the northern Diablo Range seems to be consistent with subduction- related tectonics. The late Eocene regression is, coincidentally, approxi- mately correlative with an interval of lowered sea level in the lower part of supercycle “TA4” of Haq and others THE SEDIMENTARY RECORD 19 (1987) (pl. 2). The pattern of the regression—that is, strongly developed in the north and south, weakly developed on the southeast and west margins, and apparently absent in the deeper parts of the basin—sug- gests that the local effects of tectonism may have been augmented by a fall in sea level. Tectonism was dominant in the north, in the area of the Diablo Range, and possibly at the south end of the basin. A minor regression is recorded elsewhere along the basin margins where the fall of sea level outpaced basin subsidence, but the record in much of the deeper parts of the basin is not clear. LOWER OLIGOCENE SEQUENCE The lower Oligocene sequence is present only in the southern San Joaquin basin. Along the southwest side of the basin, deep-marine deposition continued from the Eocene into the Oligocene with only minor shallowing and the two sequences are not clearly separated. At the south end of the basin, deep-marine deposition resumed after the late Eocene regression, while in the north, an extensive hiatus indicates that the Stockton arch re- mained a positive area through most of the Oligocene (pl. 2). Eocene and Paleocene units are truncated over the crest of the arch, and later Tertiary nonmarine strata rest directly on Cretaceous rocks (Church and Krammes, 1958). The sea also withdrew from most of the Sacra- mento basin at the end of the Eocene, leaving only a narrow embayment occupying the former Markeley sub- marine canyon (Almgren, 1978). Extensive marine de- position was restricted to the southern part of the San Joaquin basin from the Oligocene through the Pliocene. Continued mild uplift of the northern San Joaquin basin and concurrent reverse movement on the Stockton fault during the Oligocene, while subsidence continued in the southern part of San Joaquin basin, was probably a continuation of the subduction-related tectonism that began in the late Eocene. Oligocene deep-marine deposition in the southern San Joaquin basin was interrupted at mid-Oligocene time by a regression (pl. 2). Evidence for the regression is best developed in the western San Emigdio Mountains at the extreme southwest end of the basin where upper Oligo- cene rocks of the Temblor Formation overlap Eocene rocks to lie directly on the basement (Nilsen and others, 1973; Lagoe, 1986). Along the west-side fold belt, a thin shallow—water sandstone unit, the Wygal Sandstone Member of the Temblor Formation, occurs within a deep-water shale section (Addicott, 1973; Carter, 1985). A slight angular unconformity is present at the base of the Wygal locally in the fold belt, but the units may be conformable farther east and south (Harding, 1976; Carter, 1985). Evidence for a mid-Oligocene regression elsewhere in the basin is somewhat questionable, al- though a major mid-Oligocene unconformity is inferred on the margins of the La Honda basin (Stanley, 1985), the offset western continuation of the southern San Joaquin basin. The mid-Oligocene regression appears to be approxi- mately coincident with a major lowering of sea level at about 29 to 30 Ma (Haq and others, 1987) (pl. 2). The amount of relative sea-level change required in the San Joaquin basin, however—a shallowing from middle bath- yal to inner neritic depths (1,500—2,000 m)—-is far too much to be accounted for by eustatic sea-level change alone. The encounter of the Pacific-Farallon ridge with the North American continental margin was also at about 29—30 Ma (Atwater, 1970; Atwater and Molnar, 1973). This is, as Stanley (1985, p. 11) termed it, a “cruel coincidence between major eustatic and tectonic events.” Uplift of southern California in response to the approach of the spreading ridge, as proposed by Nilsen (1984), may have been felt as far north as the southernmost end of the basin, where it would have caused the uplift of the San Emigdio Mountains area. Farther north, the ridge itself would not have had an effect, but the subduction of young, buoyant lithosphere in the east flank of the approaching ridge might have. The regional tectonic framework in which the uplift took place includes, in addition to the approach of the spreading ridge, a steepening of the angle of subduction of the Farallon plate and consequent southwestward migration of the arc volcanism into Nevada (Snyder and others, 1976; Cross and Pilger, 1978), as well as the onset of extensional deformation in the Basin and Range (Zoback and others, 1981). Broad uplift of the region between the trench and the westward-advancing volcanism and Basin and Range extension might, then, be considered a subduction- related event, but the exact cause of the abrupt uplift at the west margin of the San Joaquin basin is not known. It may have been a continuation of uplifts that started at the end of the Eocene, which were probably related to the subduction of young lithosphere and to the change from oblique to normal subduction. If the mid-Oligocene regression was basinwide, as it appears, and not just restricted to the south and west margins, it may be due to a combination of eustatic sea-level change and local tectonism. UPPER OLIGOCENE SEQUENCE The upper Oligocene sequence is also restricted to the southern San Joaquin basin, although alluvial sedimen- tation of the Valley Springs Formation began in the northern part of the basin in the late Oligocene. The sequence in the Kettleman Hills area is atypical (pl. 2) in 20 THE CENOZOIC EVOLUTION OF THE SAN JOAQUIN VALLEY, CALIFORNIA that sedimentation continued into the Miocene after a minor reversal of the regressive trend at the Oligocene- Miocene boundary. A regression near the end of the Oligocene produced unconformities around the northwest, north, and east margins of the basin and a shoaling at the south end. Part of the Coalinga-Kettleman Hills area remained high well into the early Miocene (Kuespert, 1983, 1985). An uncon- formity at the base of the Agua Sandstone Bed of the Santos Shale Member of the Temblor Formation3 trun- cates older units in the northern Temblor Range (Heik- kila and MacLeod, 1951; Carter, 1985; Pence, 1985), but the units become conformable farther southeast and the Agua pinches out. Where present, the Agua indicates a shallowing, similar to that of the Wygal Sandstone Member, from bathyal to neritic depths (Carter, 1985). In the Bakersfield arch area, the deep-water Vedder Sand is disconformably overlain by shallow-water basal deposits of the Jewett Sand (Bartow and McDougall, 1984). There is apparently no major eustatic sea-level event that correlates with this final Paleogene regression, although a lowstand at about 25 Ma (Haq and others, 1987) is close (pl. 2). The amount of relative sea-level change that took place would rule out eustasy as a primary cause anyway. The encounter of the Pacific- Farallon ridge with the North American margin had, by late Oligocene time, resulted in the formation of a triple junction at the continental margin. However, this triple junction was still located off southern California (Atwa- ter, 1970), and triple-junction tectonism should not have affected the San Joaquin basin at that time. Uplift near the end of the Oligocene at the south end of the basin was probably a continuation of the southern California uplift; elsewhere, it may have been a continuation of seemingly subduction related tectonism that began earlier in the Oligocene. This tectonism seems to have had the most pronounced uplift effects on the west or northwest side of the basin and lesser effects elsewhere. An indirect effect of the regional tectonism and asso- ciated volcanism in central Nevada that began in the Oligocene was the deposition of rhyolitic ash-flow and air-fall tuffs in the northern Sierra Nevada and adjacent northern San Joaquin basin (Slemmons, 1966). Rare tuffs date from before 30 Ma, but more widespread pyroclastic deposition in the latest Oligocene (Dalrymple, 1964) was concurrent with the beginning of alluvial sedimentation (Valley Springs Formation) that continued into the Miocene and may indicate uplift east of the basin. 3This awkward name was introduced into the literature by Maher and others (1975); it is little used. NEOGENE AND QUATERNARY LOWER AND MIDDLE MIOCENE SEQUENCE The regression near the end of the Oligocene was followed by a marine transgression in the southern part of the basin that began near the Oligocene-Miocene boundary and brought about a rapid return to the bathyal or abyssal depths of the Oligocene (Bandy and Arnal, 1969). Lavas, mostly of basaltic and andesitic composition but including minor dacitic lava, erupted at the southeast end of the basin in the Tehachapi-San Emigdio Mountains area at about 22—23 Ma and flowed westward or north- westward across the strandline (Nilsen and others, 1973). Volcanism and extensional tectonism also characterized the late Oligocene-early Miocene history of the western extension of the San Joaquin basin in the Santa Cruz Mountains (Stanley, 1985). In the northern part of the San Joaquin basin, extensive alluvial sedimentation of the Valley Springs Formation continued into the Mio- cene. The apparent coincidence between extensional tecton- ism, as shown by basin subsidence and volcanism, and passage of the Mendocino triple junction has been noted in the section on “Plate Tectonics.” The northward progression of volcanism and its association with triple- junction migration, of which the volcanic rocks in the San Emigdio Mountains are one element, has been well documented by Johnson and O’Neil (1984). The case is not so clear for basin subsidence, however, because the data of Bandy and Arnal (1969) indicate that the south end of the basin was as deep during the Oligocene, before passage of the triple junction, as it was in the Miocene, after passage of the triple junction. Nevertheless, geo- history analysis (Olson and others, 1986) indicates that the basin subsided rapidly after the brief regression that intervened between the late Oligocene and early Miocene deep-basin intervals. Extensional tectonism is demon- strated by a latest Oligocene and early Miocene episode of normal faulting recorded in the San Emigdio Moun- tains (Davis, 1986; Hirst, 1986). The most likely expla- nation for extensional tectonism and basin subsidence beginning about 24 Ma at the s0uth end of the basin is the passage of the Mendocino triple junction that created an extensional stress regime in its wake (Dickinson and Snyder, 1979; Ingersoll, 1982). Alluvial sedimentation of the Valley Springs Formation, however, is too old and too far north to have been related to triple-junction passage and is more probably a result of increased sediment supply due to uplift in the source area. The Valley Springs Formation in the northern San Joaquin Valley, and its associated rhyolitic pyroclastic deposits, was succeeded in the middle Miocene by exten- sive andesitic volcaniclastic sediments of the Mehrten THE SEDIMENTAR‘Y RECORD 21 Formation. There is no apparent angular discordance between the two units (Marchand, 1977; Grant and others, 1977), although there is an unconformity with as much as 120 m of erosional relief in the eastern part of the outcrop area (Gale and others, 1939). Although there was obviously no major tilting of the northwest edge of the basin at this time, there may have been regional uplift of the Sierra Nevada and the San Joaquin basin without a southwest tilt. A minor regressive pulse, evidenced by a nonmarine tongue (the lower variegated unit) in the Temblor Formation, can be seen on the west side of the basin as far south as Kettleman Hills north dome (pl. 2). This regressive pulse suggests a regional uplift of the northern part of the basin. Deposition of the lower and middle Miocene sequence ended after a regression that is apparent along the southeast margin of the basin and in the northern Temblor Range segment of the west-side fold belt (pl. 2). The Olcese Sand forms a clastic wedge of shallow-marine and nonmarine sandstone between the deeper water Freeman and Round Mountain Silts in the Bakersfield arch area (Addicott, 1970; Bartow and McDougall, 1984). Abrupt changes in foraminiferal faunas suggest the presence of a disconformity, at least locally, within the Olcese near Bakersfield (Bartow and McDougall, 1984). A nonmarine conglomerate unconformably overlies older Miocene rocks in the Tehachapi and San Emigdio Moun- tains area (Nilsen and others, 1973; Bartow and McDou- gall, 1984). In the northern Temblor Range area, an unconformity truncates early Miocene and older rocks over fold crests and is overlain by a shallow-marine sandstone, the Relizian-age Buttonbed Sandstone Mem- ber of the Temblor Formation (Dibblee, 1973b; Harding, 1976). The Buttonbed is absent farther southeast, but an unconformity is present between Saucesian and Relizian- age units in structures along the west side of the San Joaquin Valley (Harding, 1976). Still farther south in the southern Temblor Range, the lower Miocene is generally too deeply buried to determine the presence or absence of an unconformity with any confidence; however, in the offset western extension of the southwestern San Joa- quin basin in the Santa Cruz Mountains, there is a widespread unconformity at the top of the Saucesian (Stanley, 1985). The unconformity at the top of the lower and middle Miocene sequence provides conclusive evidence of the earliest en echelon folding along the southwest margin of the basin (Harding, 1976) that can be stratigraphically dated at a minimum age of 16—17 Ma (pl. 2). The west-side folding is probably a result of the initial stages of San Andreas wrench faulting. The unconformity in the Santa Cruz Mountains area, together with the regressive elastic wedge on the east side of the San Joaquin basin and the unconformity in the Tehachapi-San Emigdio area, provides evidence of regional tectonism (Olson and others, 1986; Dickinson and others, 1987) that probably cannot all be ascribed to wrench tectonism. It has been suggested that this early middle Miocene uplift was an isostatic response to the northward movement of the Mendocino fracture zone, which marked the northern edge of a slab of young, buoyant lithosphere, under the basin (Loomis and Glazner, 1986). This is an appealing idea, but it requires a shallow subduction angle so that the subducted plate is in contact with the overlying lithosphere under the basin and can, therefore, affect the overlying plate isostatically. The distribution and timing of magmatism in the western Cordillera indicates much steeper subduction by the middle Miocene (Coney and Reynolds, 1977; Keith, 1978). Paleomagnetic data indi- cate that much of the clockwise rotation of the Tehachapi Mountains occurred in the early Miocene (Plescia and Calderone, 1986), presumably under right-lateral shear stress after passage of the Mendocino triple junction. To what extent this may have influenced uplift near the end of the early Miocene is not really known. The problem remains unresolved. MIDDLE AND UPPER MIOCENE SEQUENCE Deposition of the middle and upper Miocene sequence began during a rapid subsidence. Shallow-marine trans- gressive sandstone was deposited at the base (Buttonbed Sandstone Member of the Temblor Formation on the west side and the upper part of the Olcese Sand on the east side). Sporadic influxes of coarse clastic sediments at the southeast, south, and west basin margins fed deep- sea fan systems (Stevens sandstone of local usage) in the deep-basin areas (MacPherson, 1978; Webb, 1981). The sequence is characterized, however, by its thick accumu- lation of fine-grained siliceous sediment (mostly included in the Monterey Formation). The transgression reached its greatest areal extent at about mid-Mohnian time, resulting in broad, shallow shelves along the north and east basin margins (Graham and others, 1982). A thin marine unit in the subsurface at the Chowchilla gas field (about 70 km northwest of Fresno) has yielded late middle Miocene(?) diatoms (J .A. Barron, written com- mun., 1986). This unit is the northernmost marine Miocene deposit in the San Joaquin basin and very probably represents the approximate northern limit of the middle Miocene transgression. The siliceous lithology of the Monterey-type sediments and their high compo- nent of pelagic organisms are due to a combination of broad shelves that caused terrigenous sediment to be trapped in shallow estuaries or lagoons (Graham and others, 1982) and prolific middle Miocene diatom produc- tivity caused by changes in oceanic circulation (Ingle, 1981; Barron, 1986). 22 THE CENOZOIC EVOLUTION OF THE SAN JOAQUIN VALLEY, CALIFORNIA The middle Miocene transgression approximately co- incides with a eustatic highstand of sea level shown by Haq and others (1987). High sea level may well be the primary factor in the widespread transgression, but the basin also appears to have reached its maximum depth at progressively later times northward (pl. 2). This north- ward progression suggests that tectonism also played a part and that the northward migration of the Mendocino triple junction may have induced a northward—moving wave of basin subsidence in the San Joaquin basin. Beginning near the end of the middle Miocene, nonma- rine, coarse clastic sediments derived entirely from Coast Range sources were deposited along the northwest side of the San Joaquin basin. These alluvial fan deposits are included in the Oro Lorna Formation (Briggs, 1953) and the Carbona unit of Raymond (1969); the latter was mapped as late Miocene and early Pliocene(?) fanglomer- ate by Bartow and others (1985) (pl. 2). The base of the Carbona unit is dated by vertebrate fossils at 10 Ma (Raymond, 1969; Bartow and others, 1985), but Lettis (1982) suggested that the Oro Loma might be older because it apparently does not contain detritus from the nearby Quien Sabe Volcanics, which range in age from 10.7 to 7.5 Ma (Prowell, 1974; Drinkwater, 1983). Nev- ertheless, because the Oro Loma and the Carbona have very similar lithologies and are in the same stratigraphic position on the east flank of the Diablo Range, they probably record the same tectonic event. This event must have begun at, or shortly before, 10 Ma and indicates the beginning of Neogene uplift of the Diablo Range and exposure of the Franciscan core. The uplift seems to have begun in advance of the northward-migrating Mendocino triple junction, using either the global-circuit reconstruc— tions of Atwater and Molnar (1973) or the hot-spot method of Engebretson and others (1985). The eruption of the Quien Sabe Volcanics, on the other hand, was approximately coincident with the passage of the triple junction and is one further element in the northward progression of volcanic events (Dickinson and Snyder, 1979; Johnson and O’Neil, 1984). Deposition of the middle and upper Miocene sequence A was interrupted along the southeast margin of the basin by a brief regression near the middle Miocene-late Miocene boundary. An unconformity at the base of the nonmarine Chanac Formation, or its marine equivalent the Santa Margarita Formation, truncates older Miocene units (Bartow and McDougall, 1984). This unconformity indicates a local uplift of the southern Sierra Nevada and Tehachapi Mountains that may have been the first pulse of the gradually accelerating late Cenozoic uplift of the Sierra Nevada. Hay (1976) first proposed that late Cenozoic uplift of the Sierra Nevada began earlier in the south and he also pointed out the relation between the timing of that uplift and the evolution of the San Andreas transform, but it was Crough and Thompson (1977) who proposed what is probably the most likely mechanism for the uplift. That mechanism was thermal thinning of the lithosphere following the northward migration of the Mendocino triple junction and the end of subduction (see section on “Regional Tectonics”). The regressive phase of the middle and upper Miocene sequence was characterized by an increase in terrigenous material, along with a shallowing of the basin. Shallow- marine sandstone (Santa Margarita Formation) was deposited on the north and east side of the restricted marine basin and nonmarine sediments (Chanac Forma- tion) were deposited on the southeast side. The middle and upper Miocene sequence is separated from the overlying upper Miocene, Pliocene, and P1eistoCene se- quence by an unconformity around the margins of the southern San Joaquin basin, but deposition was appar- ently continuous in the center of the basin. A local unconformity Within the nonmarine Mehrten Formation along the northeast margin of the basin (Wagner, 1981) may correlate with the unconformity in the marine section farther south. The late Miocene regression in the San Joaquin basin was approximately synchronous with tectonic events in the surrounding regions that are not precisely dated, but that seem to cluster at about 10 Ma. The regression also correlates with a pronounced fall in sea level at 10 to 11 Ma on the Haq and others’ (1987) eustatic sea-level curve (pl. 2). In the Basin and Range province, there was a clockwise change in the direction of least-principal stress (from west-southwest—east-northeast to west-north- west—east-southeast) at about 10 Ma, which is consistent with the superposition of right-lateral shear in that region (Zoback and others, 1981). An apparently syn— chronous event was the accelerating uplift of the Sierra Nevada (Christensen, 1966; Huber, 1981). Folding along the southwest side of the San Joaquin basin, on the other hand, has been apparently continuous since the early middle Miocene; there has been no particular change in rate, merely a shift from one structure to another in a general basinward progression (Harding, 1976). The cause of tectonic activity at about 10 Ma is unclear, partly because the possible changes in plate motion at that time are also unclear, as discussed in the section on “Plate Tectonics.” An acceleration in Pacific—North American relative plate motion might well have been an influence, but the imprecision in the timing of that change makes it difficult to relate it to specific tectonic events in central California. Regardless of plate motions, however, there was an acceleration of slip rates on the San Andreas fault through the Miocene, particularly the late Miocene (Huffman, 1972; Graham, 1978), probably due to in- creased coupling between the Salinia terrane west of the fault and the Pacific plate. A resulting gradual increase in THE SEDIMENTARY RECORD 23 tectonic activity throughout the region may have initi- ated a regression, but it is probable that the fall in sea level at 10 to 11 Ma was a strong contributing factor. UPPER MIOCENE, PLIOCENE, AND PLEISTOCENE SEQUENCE Deposition of the upper Miocene, Pliocene, and Pleis— tocene sequence in the southern San Joaquin basin was started with transgression of the Etchegoin Formation over older Miocene units. Alluvial fans and deltas pro- graded basinward as abundant coarse detritus was de— livered to the basin from the rising Sierra Nevada on the east, the San Emigdio Mountains on the south, and eventually from the Coast Ranges on the west. Alluvial fan deposition along the southeast margin of the basin (the Kern River Formation) began about 8 Ma, although there was no comparable event at that time in the northeast. The coarse elastic sediments of the Kern River may, then, be evidence that the accelerating late Ceno- zoic uplift of the Sierra Nevada began earlier at the south end of the range. In the northeastern part of the basin, some fine arkosic alluvium of late Pliocene age from the Sierra Nevada (Laguna Formation) is Virtually unweath- ered and resembles modern rock flour produced by glaciers eroding granitic rocks (Marchand, 1977). The presence of this rock-flour—like alluvium suggests a late Pliocene onset of alpine glaciation in the Sierra Nevada. The final regression, which began in the latest Mio- cene, was greatly accelerated through the Pliocene as progradation of coarse clastic sediments continued from all sides of the basin, and it culminated with the final retreat of the sea by about the end of the Pliocene. The stratigraphic sequence in the center of the southern San Joaquin basin records a gradual shallowing from shallow- marine shelf (Etchegoin Formation) through restrictive marine to brackish facies (San Joaquin Formation) and finally to freshwater fluvial and lacustrine facies (Tulare Formation) in the late Pliocene to middle Pleistocene. This shallowing took place even as the basin continued to subside, rapidly in the western part of the Maricopa- Tejon subbasin. The San Joaquin and Tulare are conform- able in the center of the basin and both interfinger eastward with Kern River alluvial fan deposits, but an unconformity is present at the base of the Tulare along the west and south margins of the basin. The San J oaquin-Tulare conformable contact at Elk Hills, and presumably elsewhere at the south end of the basin, is dated at 2.5 to 3.0 Ma (C.A. Repenning, written com— mun., 1980), which is somewhat older than the equivalent boundary farther north. A general decline in sea level after a highstand at about 5 Ma (Haq and others, 1987) may have contributed to the regression during the Pliocene, but it is more likely that the principal cause was tectonism. Increasing tectonic activity and uplift to the east, west, and south, especially following the change in relative plate motion and the consequent increase in compression normal to the San Andreas fault at about 5 Ma, resulted in greatly increased sedimentation that outpaced basin subsidence. Contrib- uting factors in the transition to a nonmarine basin in the late Pliocene were the progressive closing off of the basin’s western outlet by continued northwestward mi- gration of the Salinia terrane, and folding and uplift in the Temblor and Diablo Ranges. The unconformity at the base of the Tulare Formation is due to continued defor- mation of the western and southern basin margins in response to compression across the San Andreas fault. In the San Emigdio Mountains, major north—directed thrusting on the Pleito fault system produced the coarse alluvial sediments of the Tulare Formation (Davis, 1983, 1986). The rapid subsidence of the western part of the Maricopa-Tejon subbasin during the Pliocene and early Pleistocene, which was concurrent with the shallowing trend, was probably due to tectonic loading by thrust plates at the south margin of the basin. UPPER PLEISTOCENE AND HOLOCENE DEPOSITS Late Quaternary sedimentation in the San Joaquin basin consisted of episodic deposition of alluvial sedi- ments at the valley margins (Marchand and Allwardt, 1981), which grade basinward into a more continuous section containing a series of lacustrine deposits (Croft, 1972; Marchand, 1977). By about the middle of the Pleistocene, the San Joaquin basin drainage outlet was closed or nearly closed, and the impounded drainage created a. large lake, evidenced by a widespread lacus- trine clay—the Corcoran Clay Member of the Tulare (Frink and Kues, 1954) and Turlock Lake (Marchand and Allwardt, 1981) Formations (fig. 3). Disappearance of the Corcoran lake was approximately coincident with, and was probably caused by, the establishment of the present Central Valley drainage outlet through the Carquinez Strait and San Francisco Bay at about 0.6 Ma (Sarna- Wojcicki and others, 1985). The sedimentary record of the latest Quaternary is similar to that of the middle Pleistocene, but it contains a succession of smaller pluvial lakes. Tectonism has played an important role in the Quater- nary history of the San Joaquin basin. Closing of the valley’s drainage outlet and continued uplift of the surrounding ranges that supply sediment to the alluvial basin are the consequences of tectonism, but the Quater— nary sedimentary record reflects climatic controls more than tectonic. Cycles of alluviation, soil formation, and channel incision in the Quaternary deposits of the north- eastern San Joaquin basin can be correlated with climatic 24 fluctuations and the resultant glacial stages in the Sierra Nevada (Bateman and Wahrhaftig, 1966; Marchand, 1977). A similar cyclical pattern is apparent in the alluvial fan deposits on the west side of the basin that were derived from the unglaciated Diablo Range (Lettis, 1982, 1985). This pattern suggests that the inferred climatic control of sedimentation is more complex than a simple correlation of alluviation event With glacial outwash event; it involves, as well, the effect of climate on rates of weathering and on changing vegetation patterns, and how these factors, in turn, influence sediment supply (Marchand, 1977; Lettis, 1982, 1985). Creation or peri- odic enlargement of pluvial lakes in the center of the basin can also be correlated with the cyclic alluvial deposits and with Sierran glaciations (Atwater and others, 1986). The appearance and disappearance of these lakes has been dependent on the balance between the inflow volume on one hand, and basin subsidence and the growth of alluvial fan dams on the other. 100 San Joaquin River , \ . l. . 100— l f , ::~","o::"' _ We - /\ I , > \ . ‘ _, _ - Lacustnneclay _ ”,3 \_\—_,:,_ \\-,.'.o ._..D. \x‘L"\,’," IsL" X’ /\,°'°.° D ,, °.'.°l \ , \_: \ , \ « / “(,4 'o- o‘ o 0 ° _F|TIT1T Contact—Hachures denote a 8 _ \e . . . .. ’ - I ~/- a 0 buried 50115 or oxxdized THE CENOZOIC EVOLUTION OF THE SAN JOAQUIN VALLEY, CALIFORNIA BASIN EVOLUTION The Great Valley of California, which is today an alluvial plain surrounded by mountains, was, at the beginning of the Cenozoic, occupied by a marine shelf and slope system that was part of an extensive forearc basin at the west edge of North America (Dickinson and Seely, 1979; Ingersoll, 1979). The forearc basin, which origi- nated in the Mesozoic in a convergent-margin setting, evolved during the Cenozoic into the hybrid intermon- tane basin in a transform-margin setting that exists today. Each of the five structural regions of the basin, which show differences in style of deformation, have somewhat different tectonic histories as a result of the changes in stress regimes through the Cenozoic. This evolution of Cenozoic stress, discussed separately for each region of the basin in the section on “Geology,” is integrated into the generalized summary diagrams of figure 4. Changes in regional stress are closely related in ' f ~ ' EXPLANATION o , ‘ . 1' ,' °~ .° . . i - . ‘ ." Sierra Nevada detritus Coast Range detritus horizons W Cut and fill—Diagrammatic — _q/ Approximate location of 30 KILOMETERS | /_ _ facies change FIGURE 3. —Diagrammatic cross section of the northern San Joaquin Valley showing stratigraphic relations of Quaternary alluvial deposits in the valley subsurface. Modified from Lettis (1982). BASIN EVOLUTION 25 space and time to the northwestward migration of the Mendocino triple junction and the consequent evolution of the San Andreas transform. The changing stress regimes and the resulting tectonic changes are reflected in the varying patterns of sedimentation and changing paleogeography during the Cenozoic evolution of the basin. The discussion that follows, which also serves as a brief summary of some of the main points from foregoing sections of this report, will make reference to a series of nine paleogeographic maps of the San Joaquin basin and surrounding regions. These maps were constructed for fairly narrow time slices of the Tertiary, shown on plate 2 as stippled bands, rather than for broader intervals such as stages (Zemorrian, Saucesian, and so forth) or even epochs, as has commonly been done in the past. This procedure greatly reduces the problem of trying to show too many, often conflicting events on one map, but it has the disadvantage of implying greater precision in corre- lation, particularly in the earlier Tertiary, than it is presently possible to achieve. The maps were con- structed on palinspastic bases that assume 305 km of Neogene right-lateral slip on the San Andreas fault (Clarke and Nilsen, 1973; Graham, 1978) and an unspec— ified amount of early Paleogene right slip on the proto- San Andreas fault, together with 150 km of Neogene right slip on the San Gregorio fault (Clark and others, 1984). It is also assumed that the original trace of the San Andreas fault was more or less straight and that the present big bend near the south end of the San Joaquin Valley was acquired in the late Neogene and Quaternary. The paleogeography was compiled from published maps and modified to accord with more recent stratigraphic and sedimentologic data. In many cases where data are sparse or even nonexistent, the maps represent the interpretations and biases of the author. PALEOCENE The forearc basin that existed through the late Meso- zoic and into the earliest Tertiary began to change in the Paleocene, although the basin geometry of the old arc-trench system persisted. The principal factors influ- encing Paleocene paleogeography were right slip on the proto—San Andreas fault and uplift of the Stockton arch, which together reflect an overall north-south compres- sive stress (fig. 4A). This stress was apparently a consequence of oblique subduction with a northerly to northeasterly convergence direction (Engebretson and others, 1985). The proto-San Andreas fault, which orig- inated in the Late Cretaceous and had, by Paleocene time, produced a continental borderland of small wrench- fault basins in the Salinia terrane (Nilsen and Clarke, 1975), was active through the Paleocene. Shear stress associated with right-lateral faulting may have been responsible for en echelon folding in the northern part of the west-side fold belt (Harding, 1976) and for oroclinal bending or rotation of the southern Sierra Nevada (Kanter and McWilliams, 1982; McWilliams and Li, 1985). At least part of the folding and rotation may have taken place during the Paleocene. Uplift of the Stockton arch and concurrent up-to-the-south movement on the Stock- ton fault began in the Paleocene and strongly influenced sedimentation patterns in the northern part of the basin. Figure 5 shows the paleogeography of the San Joaquin basin in the late Paleocene during the transgressive phase of the upper Paleocene and lower Eocene deposi- tional sequence. The northern and eastern parts of the basin were occupied by a marine shelf; deeper marine slope and basinal facies were restricted to the southwest. An upland, probably of low relief, lay to the northeast, and the shelf and slope were largely open to the ocean on the west. Uplift of the Stockton arch produced a broad west-trending peninsula between the San Joaquin and Sacramento basins. It is not known how much of the arch was exposed at this time because erosion has removed Paleocene strata, but it is assumed that some shallow or nearshore marine deposition took place over the west end of the arch. The extent of the Diablo uplift is also not known, but it was probably not large and represented only a portion of the structural high in the subduction complex at the southwest side of the forearc basin that was uplifted with the Stockton arch. At the south end of the basin, the first stages of the oroclinal bending of the southern Sierra Nevada had produced a westward devi- ation of the southeast-trending shoreline and left the future Bakersfield arch and the Maricopa—Tejon subbasin area emergent. EOCENE The Eocene, as a result of recent revisions in Cenozoic geochronology (Berggren and others, 1985), is the long- est of the Cenozoic epochs. Although the Paleogene was generally “quieter” than the Neogene, a number of events, including a major regression separating two basinwide depositional sequences, affected the basin during the Eocene. The combined effects of tectonism and eustatic sea-level change resulted in broad fluctua- tions in the shoreline and produced major changes in paleogeography. Tectonic activity included uplifts in the Diablo Range area in late early and late Eocene, and possibly in the San Emigdio Range area near the end of the Eocene. In the north, uplift was probably in response to northeast-southwest subduction-related compression that might be considered evidence of Paleogene emplace— ment of a deep-seated Franciscan wedge, whereas in the south, it was probably in response to regional north- south compression (fig. 4A). 26 THE CENOZOIC EVOLUTION OF THE SAN JOAQUIN VALLEY, CALIFORNIA Stockton _...o a' "a; Z ‘7 z 3’: 33 (D “a; C ‘2‘ Stockton . . D. . Stockton Stockton . . . D. . . . .0. . 0 Fresno FIGURE 4. —Evolution of regional stress patterns in the San Joaquin Valley area. A, Early Paleogene. B, Late Oligocene-early Miocene. C , Late Miocene-early Pliocene. D, Late Pliocene-Quaternary. Edge of present valley alluvium and present major faults generalized from figure 1 for location. Small arrows indicate inferred local stress, large arrows indicate inferred overall compressive stress, paired half-arrows indicate shear couple; queried where uncertain. BASIN EVOLUTION 27 A major regression occurred at the end of the upper Paleocene-lower Eocene depositional sequence. This re- gression was largely a result of eustatic lowering of sea level that left the marine basin greatly restricted (fig. 6). Although their presence somewhat speculative, large deltas are inferred to have prograded westward across the basin from the central Sierra Nevada, which was the principal source of Eocene sediment. Parts of the sub— duction complex at the west side of the basin were emergent and contributed some sediment, and Salinia terrane highs were emergent to the southwest (Nilsen and Clarke, 1975). At the beginning of the ensuing transgression, basal sands containing Franciscan detri- tus onlapped the formerly emergent areas on the west side of the basin. Much of the formerly emergent area at the south end of the basin, including the Bakersfield arch, was also inundated. A condensed section in the lower part of the Kreyenhagen Shale (Milam, 1985) immediately above the basal sand of the Eocene depositional sequence is an indication of a rapid transgression. The point of maximum transgression for the entire Tertiary was reached at middle Eocene time (fig. 7). EXPLANATION ‘ Marine deposits—Solid line indicates inferred shoreline; hachures indicate inferred shelf edge; queried where uncertain Nonmarine deposition—Dotted line indicates in- ferred extent; queried where uncertain Lacustrine deposition Emergent area—Queried where uncertain AAAAAA AAAAAAA AAAAAA Volcanic center Faults—Queried where uncertain. Arrows indicate direction of relative movement -—:—— Probably active Possibly active Future trace of Neogene San Andreas fault Thrust—Sawteeth on upper plate Explanation for figures 5 through 13. Widespread pelagic sediments indicate that most of the present-day San Joaquin Valley was covered by deep- marine waters and the basin was largely open to the west, as it had been in the Paleocene. A large deep-sea fan was constructed in the southwestern part of the basin that had its source and proximal part on the Salinia terrane west of the present San Andreas fault (Clarke, 1973; Clarke and Nilsen, 1973). The east side of the basin was fringed by a belt of fluvial and deltaic deposits. The regressive phase of the Eocene depositional se— quence near the end of the Eocene is recorded in the northern part of the basin and at the south end, whereas the record indicates continued deep-water deposition in the central part. Uplifts at this time represent the beginning of tectonic activity that continued into the Oligocene, and probably reflect the approach of the Pacific-Farallon spreading ridge and the transition from oblique to normal subduction (Engebretson and others, 1985). Mount 3 “393503 {- Diamon’Canyon r. 4’" H Isn‘t}, ’Imm’lm 4/ / 0 10 20 30 40 50 KILOMETERS LLl—I_I_l o Bakersfield “In” min“ ”m \\I\“‘"” ’IIII/ I," 1,," Hm” ‘ FIGURE 5. —Late Paleocene (about 59 Ma) paleogeography of the San Joaquin basin area. Based on data from Repenning (1960), Clarke and others (1975), Dickinson and others (1979), Nilsen and McKee (1979), Clark and others (1984), Fischer (1984), and Stanley (1985). 28 OLIGOCENE The Oligocene marks the onset of change throughout the western United States. Following the change in convergence direction near the end of the Eocene, the angle of subduction steepened during the Oligocene (Page and Engebretson, 1984), leading to changes in the patterns of volcanism (Snyder and others, 1976) and to the initiation of extension in the Basin and Range province (Zoback and others, 1981). The most important event affecting California during the Oligocene was the ridge-trench encounter off southern California that initi- ated the San Andreas transform system (Atwater, 1970; Atwater and Molnar, 1973). All these events had an effect, whether directly or indirectly, on the San Joaquin basin during the Oligocene and, augmented by eustatic sea-level change, produced major changes in the central California paleogeography. Continued uplift of the Stockton arch in the northern part of the basin, concurrent with movement on the 4 ;~\ - ”4"... "S"? - . "Jim" : fidiim} 7,, , § ' Santa Km i\\"<“"“um¥’ \ “II V 0 lo 20 30 4O 50 KILOMETERS ..__.._;_._._a FIGURE 6. —-Early to middle Eocene (about 52 Ma) paleogeography of the San Joaquin basin area. See figure 5 for explanation. Based on data from Repenning (1960), Clarke and others (1975), Graham (1978), Graham and Berry (1979), Nilsen (1979), Nilsen and McKee THE CENOZOIC EVOLUTION OF THE SAN JOAQUIN VALLEY, CALIFORNIA Stockton reverse fault, and of the San Emigdio area in the south are both indications of a general north-south compression. In the north, the tectonism was presumably subduction related. At the south end of the basin, at least during the later Oligocene, the tectonism was part of a major uplift throughout southern California in response to the ridge-trench encounter (Nilsen, 1984). The entire northern part of the basin was emergent through the Oligocene, while deep-water sedimentation continued from the Eocene into the Oligocene in the southwestern part. At the time of maximum regression in the middle Oligocene (fig. 8), the Stockton fault was active, the Stockton arch was being eroded, and alluvium was deposited to the north and south of the arch. The earliest rhyolitic tephra were also deposited in the northern Sierra Nevada at about this time. The Diablo Range and probably the northern Temblor Range areas were emergent, so deep-marine deposition was restricted to the southwestern part of the formerly extensive basin. In addition to the nonmarine deposits south of the 4/ / 0 10 20 30 40 50 KILOMETERS FIGURE 7.—Middle Eocene (about 44—45 Ma) paleogeography of the San Joaquin basin area. See figure 5 for explanation. Based on data from Repenning (1960), Clarke (1973), Clarke and others (1975), (1979), Slagle (1979), and Stanley (1985). Nilsen (1979), Nilsen and McKee (1979), and Palmer and Merrill (1982). BASIN EVOLUTION 29 Stockton arch, a narrow fringe accumulated along the east side of the marine embayment, while coarser alluvial fan deposits derived from uplifts to the south accumu- lated along the south and southeast margins of the basin. A north-south axial profile of the basin floor at this time would start above sea level in the north (probably not more than a few tens of meters) and reach depths of over 1,800 m in the south, illustrating the marked southward tilt of the basin in the Oligocene. MIOCENE The evolution of the San Joaquin basin was accelerated by tectonic events of the Miocene, most of which were a result of the northwestward migration of the Mendocino triple junction. The interval during which the triple junction was located opposite the basin nearly coincides with the Miocene epoch (Snyder and others, 1976; Johnson and O’Neil, 1984) (pl. 2). Paleogeographic we on. STOCKTON ‘40,} v -" 7 ' \EDISON FAULT 0 IO 20 30 40 60 KILOMETERS _._._._._. FIGURE 8. —Oligocene (about 30 Ma) paleogeography of the San Joaquin basin area. See figure 5 for explanation. Based on data from Repenning (1960), Addicott (1968), Bandy and Arnal (1969), Greene and Clark (1979), Nilsen and McKee (1979), Nilsen (1984), and Pence (1985). changes took place at a faster pace, particularly adjacent to the developing San Andreas fault system. Marine deposition was restricted to the southern part of the basin, but extensive nonmarine deposition began in the north. There was also a major change in regional volcan- ism, as the rhyolitic pyroclastic deposits of the late Oligocene and earliest Miocene were replaced near the end of the early Miocene by reestablished andesitic arc volcanism in the northern Sierra Nevada (Slemmons, 1966; Stewart and Carlson, 1976). The are volcanism was then progressively shut off from south to north as the Mendocino triple junction migrated northward and cut off subduction (Snyder and others, 1976). The patterns of regional stress, which had begun to change in the Oligocene, continued to change through the Miocene. This was first apparent at the south end of the basin where east-west-oriented normal faulting and sub- sidence, probably beginning in the latest Oligocene, and volcanism in the early Miocene indicate north—south extension (Davis, 1986; Hirst, 1986) (fig. 43). En echelon folding in the west-side fold belt, beginning near the end of the early Miocene and continuing through the Miocene, is a manifestation of a newly established northwest- southeast-oriented shear couple centered on the San Andreas fault system (Harding, 1976). The accelerating uplift of the Sierra Nevada during the late Miocene (Huber, 1981) was accompanied by north-south-oriented normal faulting that indicates minor east-west extension in the southern Sierran block. The Diablo uplift and the eruption of the Quien Sabe Volcanics in the late Miocene are closely associated with the passage of the Mendocino triple junction (Johnson and O’Neil, 1984). The uplift seems to indicate compression, presumably oriented northeast-southwest, and was followed immediately by minor local extension in a developing northwest-south- east shear regime. The early Miocene marine embayment (fig. 9) was not very different from the Oligocene embayment. The northern Temblor Range area that was briefly exposed at mid-Oligocene time was inundated in the early Miocene, as it had been in the late Oligocene, and the early Miocene strandline advanced even farther eastward onto the southern Sierran block. Nonmarine deposition expanded northwestward as tuffaceous alluvial plain deposits cov- ered the northern basin and Stockton arch areas. The last stages of the previously extensive coarse alluvial fan deposition took place at the south end of the basin. The paleogeography changed considerably near the early Miocene-middle Miocene boundary (fig. 10). Uplift of the southern part of the basin produced a regression there as alluvial fan and fan-delta deposits prograded basinward. Farther north, however, there was a trans- gression, as the strandline advanced northwestward onto the Diablo uplift in the Coalinga area and in the Vallecitos 3O syncline. There was probably a shallow seaway trending northwest through the Vallecitos syncline. The initiation of wrench tectonism on the southwest side of the basin resulted in uplifts in the adjacent Salinia terrane and nonmarine deposition in the southern Diablo Range area. The beginning of andesitic volcanism in the northern Sierra Nevada is reflected in the nonmarine volcaniclastic deposits of the northern San Joaquin and Sacramento THE CENOZOIC EVOLUTION OF THE SAN JOAQUIN VALLEY, CALIFORNIA. fan deposits were derived from the east, the south, and the southwest. By late Miocene time (fig. 11) the northward move- ment of the Salinia terrane, composed of isolated highs surrounded by shallow seas (Graham, 1978), west of the San Andreas fault was beginning to close off the San basins. After the early to middle Miocene regression, marine embayment expanded to its Neogene maximum Joaquin basin on the west. A new seaway had opened through the Priest Valley area west and northwest of Coalinga, but there was no longer a deep-marine outlet to the the Pacific Ocean. The deep-marine embayment was becoming more restricted as shallow-marine shelf depos- extent, approximately coincident with a middle Miocene its and nonmarine deposits prograded basinward along highstand of sea level (pl. 2). Marine deposits of late the east side of the basin. Sedimentation in the northern middle Miocene age reach as far north as Chowchilla (70 part of the basin was still dominated by volcaniclastic km northwest of Fresno). The basin axis at that time sediments derived from the extensive andesitic volcan- seems to have been considerably farther east than the ism in the Sierra Nevada, but the inception of coarse present axis, probably because uplift of the southern alluvial fan deposition of sediments derived from the Diablo Range and consequent sediment influx from the west forced the northern basin axis to the east. In the deep southernmost part of the basin, extensive deep—sea Mount Diablo - O} Fresno hi11thimxmyhhhh”mummm n , ,: *2 '5; c. , ‘3 F; "a \. “a“ 1 ’Ihmm : m mamas“ . /« ’2' ’9’." 55,6. 1 "”411, . 4." .1” (a . . ,mk - Santa Cruz I Q 4L *4, a e . a \ ‘. 1”"! ma mh‘w‘ 1m ,1. mamhmmmlflm 4 0 IO 20 30 IO 50 KlLOMETERS 14, __._.__ nnnh Diablo Range on the northwest indicates uplift of that range. Volcanic centers were active in the Sierra Nevada (Moore and Dodge, 1980) and the central Diablo Range. 3 s ' ' Relief Peak 5: volcanic 'A. Mqhnl biablo . "gFresno f/ O S 01 ’ Hum,,,,m\ o 10 20 so 40 so KILOMETERS ._.__._‘_._. -€‘%‘i-. -.; . I \7 DOV/5 “unkind”Mimi/m, FIGURE 9. — Early Miocene (about 20—21 Ma) paleogeography of the San Joaquin basin area. See figure 5 for explanation. Based on data from Gale and others (1939), Repenning (1960), Addicott (1968), Bandy and Arnal (1969), Graham (1978), Kuespert (1983), Pence (1985), and Stanley (1985). FIGURE 10. —Middle Miocene (about 16 Ma) paleogeography of the San Joaquin basin area. See figure 5 for explanation. Based on data from Repenning (1960), Addicott (1968), Bandy and Arnal (1969), Fritsche (1977), Graham (1978), Cooley (1982), Kuespert (1983), Bate (1984), Bent (1985), Pence (1985), and Stanley (1985). BASIN EVOLUTION 31 Flows from the Sierra Nevada centers reached at least to the basin margin along the ancestral Stanislaus and San Joaquin Rivers. A Widespread unconformity in the southern part of the basin marks the culmination of the late Miocene regres- sion (pl. 2). Coarse alluvial fan sedimentation along the southeast margin of the basin in the latest Miocene marks the beginning of the accelerated late Neogene uplift of the Sierra Nevada. PLIOCENE Neogene tectonic activity around the San Joaquin basin increased in intensity during the Pliocene, leading to the elimination of the marine embayment by the close of the Pliocene. The San Andreas fault had become the principal element of the transform system by the begin- ning of the Pliocene (Graham, 1978), and the consequent increase in slip rates caused the Salinia terrane to move Slanlslaus volcanlc center San Joaquin volcanic 0‘. Fresno ' ’ center 4/ / 0 ‘0 20 30 to SD KILOMETERS V i EDISON FAULT WHITE WOLF FAULT GARLOCK _' FAULT E FIGURE 11. —Late Miocene (about 9—10 Ma) paleogeography of the San Joaquin basin area. See figure 5 for explanation. Based on data from Repenning (1960), Addicott (1968), Bandy and Arnal (1969), Fritsche (1977), MacPherson (1978), Phillips (1981), and Graham and others (1982). rapidly northward, cutting off the southwestern marine connection with the Pacific Ocean. The regional stress pattern that originated in the Miocene remained in effect into the Pliocene, with only moderate change (fig. 4C). The northwest-southeast shear couple associated with the San Andreas fault extended farther northwest, and there was an increase in compressive stress normal to the San Andreas as a result of changes in plate convergence direction near the Miocene-Pliocene boundary (Page and Engebretson, 1984; Engebretson and others, 1985). This change in plate motions, together with the westward movement of the Sierran block as a result of extension in the Basin and Range province (Eaton, 1979), caused northeast-south- west compressive stress along the west side of the Sierran block and was largely responsible for increased late Neogene deformation in the fold belt, including deep-seated thrust faults (Wentworth and Zoback, 1986; Zoback and others, 1987). Strong north-south compres- sion at the south end of the basin, probably due in part to the developing bend in the San Andreas fault, was responsible for the onset of northward-directed thrusting in the late Pliocene. The increased loading of the south end of the basin by thrust plates was, in turn, probably responsible for the accelerated subsidence of the western part of the Maricopa—Tejon subbasin in the latest Plio- cene. The paleogeography of the Pliocene (fig. 12) differed significantly from that of the late Miocene. The embay- ment was much smaller and the basin, mostly brackish by this time, was enclosed on the south and southwest. Nonmarine deposits prograded into the shallowing em- bayment from all sides and the emergent Salinia terrane was transported northwestward to completely close the marine outlet by about the end of the Pliocene. A developing uplift lay south of the basin, While the'western part of the Maricopa-Tejon subbasin was subsiding rap- idly. A shallow seaway west of Coalinga connected the rapidly shallowing embayment with the Pacific Ocean. In the northern part of the basin, there was an increasing sediment supply to the west-side alluvial fans from the rising Diablo Range. On the northeast side of the basin, a change from volcaniclastic to arkosic alluvium indicates that major Sierran rivers had cut down through the blanket of volcanic rocks. Although alpine glaciers in the Sierra Nevada probably appeared before the end of the Pliocene, there is no direct evidence of glaciation prior to about 2.5 Ma. PLEISTOCENE By the beginning of the Pleistocene, the San Joaquin basin Was entirely emergent and was largely enclosed by the ice-capped Sierra Nevada on the east and by low hills 32 THE CENOZOIC EVOLUTION OF THE SAN JOAQUIN VALLEY, CALIFORNIA of the Coast Ranges on the west. The valley itself differed from the present valley principally in having its outlet somewhere in the southwest rather than through the Carquinez Straits to San Francisco Bay, as at present. Uplift and westward tilting of the Sierra Nevada continued through the Pleistocene, while major deforma- tion and uplift of the Coast Ranges, begun during the late Pliocene, also continued. Regional patterns of stress changed little during the Pleistocene (fig. 4D). North- east-southwest compression normal to the San Andreas fault resulted in the southern part of the west-side fold belt being uplifted as the Temblor Range. The Diablo Range was also uplifted, largely as a whole, with little internal differential vertical movement (Page, 1981). Right slip on the Ortigalita fault is evidence that the northwest—southeast shear was also imposed on the Diablo Range (Lettis, 1982, 1985). A very strong north- south compressive stress at the south end of the valley resulted in overthrusting on the faults of the Pleito 3 o E g' gi an E a VNlAVH ' ‘ '_ oS‘tockt‘o'h: nnva swimwear; onus/um FAULT '- . 0' .1 ’.Fresno'-._ WHITE OLF FAULT 0 W 10 30 w 50 KILOMETERS FAULT GARLOCK _' FIGURE 12.—Pliocene (about 3—4 Ma) paleogeography of the San Joaquin basin area. See figure 5 for explanation. Based on data from Repenning (1960), Galehouse (1967), Foss (1972), Cole and Armen- trout (1979), and Greene and Clarke (1979). system and reverse movement on the White Wolf fault (Davis, 1986). A major feature of the Pleistocene paleogeography was the large lake, the Corcoran lake, that occupied nearly the whole valley for a brief interval near the middle of the Pleistocene (fig. 13). This lake was the largest and perhaps the earliest of a succession of lakes that occupied the valley during the Quaternary. Alpine glaciers in the Sierra Nevada fed rivers as far south as the Kern River, which deposited an apron of outwash along the east side of the valley and built deltas into the lake. After the withdrawal of the sea from the marine embayment at the end of the Pliocene, the drainage outlet of the valley probably remained along the old Priest Valley seaway for a short time. It seems likely, though, that continued uplift and deformation along the San Andreas fault zone between the the Diablo Range and Gabilan Range to the west would have soon closed this outlet. A possible alternative outlet lay farther south at Bitterwater Val- ley, where the valley drainage could have crossed the northern Temblor Range (pl. 2) to flow down the now CALAvsnAs FAULT ORTIGALITA FAULY "i ‘ '3 : WHITE WOLF FAULT 0 1D 10 30 w 50 KILOMETERS "e ‘—‘——‘—‘—' 1_;.. PLEIYO \FAULT GARLOCK -' FAULT FIGURE 13. —Pleistocene (about 0.6—0.7 Ma) paleogeography of the San Joaquin Valley area. See figure 5 for explanation. Based on data from Wahrhaftig and Birman (1965), Croft (1972), and Page (1986). CONCLUSIONS 33 underfit Cholame and Estrella Creeks to join the Salinas River north of Paso Robles. This alternative was chosen for the mid—Pleistocene paleogeography of figure 13. In either case, the drainage was at least partly impounded at that time to form the Corcoran lake. The disappear- ance of the lake (at about 0.6 Ma) is probably a result of the opening of the present Central Valley drainage outlet through the Carquinez Straits (Sarna-Wojcicki and oth- ers, 1985). HOLOCENE It is commonly assumed that Quaternary tectonism continues unabated to the present day, although the specific evidence is limited. The Corcoran Clay Member of the Tulare Formation today lies at depths of 60 m to . more than 200 m below sea level along the synclinal axis of the San Joaquin basin (Miller and others, 1971; Croft, 1972), indicating the magnitude of subsidence in the valley in the past 600,000 years. The sharp upbending of the Corcoran along the west side of the syncline, further- more, is evidence of Coast Ranges uplift during the same period. Historical subsidence due to fluid withdrawal (Poland and Evenson, 1966), however, tends to mask recent tectonic subsidence. Geodetic measurements also seem to indicate continuing deformation (Burford, 1965; Stein and Thatcher, 1981), although the probable errors inherent in surveying often approach in magnitude the deformations being measured. The most unambiguous evidence of continuing tecton- ism is seismicity. Although historical seismicity in Cali- fornia has been dominated by the San Andreas fault system, there have been a few moderate to large earthquakes within the San Joaquin Valley, most notably the 1952 magnitude 7.2 Arvin-Tehachapi and the 1983 magnitude 6.5 Coalinga earthquakes. The 1952 Arvin- Tehachapi earthquake was centered on the White Wolf fault (Oakeshott, 1955; Stein and Thatcher, 1981), and the oblique slip during that event, reverse slip plus a left-lateral component, is evidence of an existing north- south to northeast-southwest compressive stress at the south end of the valley. The 1983 Coalinga earthquake occurred on a northeast-verging thrust fault under the Coalinga anticline (Eaton, 1985b) and may be related to folding and thrusting along the entire west margin of the Central Valley (Wentworth and Zoback, 1986). Lower level seismicity has been recorded from several areas in the San Joaquin Valley (La Forge and Lee, 1982; Eaton, 1985a; Wong and Ely, 1983; Wong and Savage, 1983) and collectively indicates north-south to northeast-southwest compression. Coseismic uplift of as much as 45 cm associated with the Coalinga earthquake (Stein, 1985) demonstrates the continuing growth of young anticlines at the west side of the valley. CONCLUSIONS The Paleogene history of the San Joaquin basin was dominated by a tectonic regime resulting from the presence of a subduction zone lying along the continental margin to the west. Oblique convergence in the early Paleogene (Page and Engebretson, 1984) produced a north-south compressive stress and a right-lateral shear couple in the western part of the continent. Right-lateral slip on the proto-San Andreas fault and the northwest— ward movement of the Salinia terrane into position opposite the south end of the basin (Nilsen and Clarke, 1975; Graham, 1978; Dickinson and others, 1979), large en echelon folds in the southern Diablo Range (Harding, 1976), and clockwise rotation of the southernmost part of the Sierra Nevada (Kanter and McWilliams, 1982; McWilliams and Li, 1985) are all consequences of the early Paleogene stress regime. Although this tectonism shaped the underlying structural framework and strongly influenced Paleogene geography, eustatic sea- level change also had a major influence on the Paleogene sedimentary record and geography. A eustatic fall in sea level was probably the principal cause for the regression at the end of the upper Paleocene and lower Eocene depositional sequence; it was also a contributing factor for each of the other Paleogene regressions, except the final one at the end of the upper Oligocene sequence. Neogene tectonism and basin evolution were controlled at first by the tectonic effects of the northwestward migration of the Mendocino triple junction along the California continental margin, and they were later con- trolled by wrench tectonism associated with the San Andreas fault system (Dickinson and Snyder, 1979; Page and Engebretson, 1984). The first effects of Mendocino triple-junction passage, felt at the south end of the basin beginning at about 23—24 Ma, were extension-induced subsidence and volcanism. These events were followed at 16—17 Ma by regional uplift in the southern part of the basin; the uplift seems to have been associated with passage of the triple junction and may have been related, in some way, to the presence of the subducted fracture zone under the basin (Loomis and Glazner, 1986). Con- tinued subsidence after the uplift, accompanied by wrench tectonism in the fold belt, may have been augmented by thermal decay of the subducted plate. The transgression resulting from middle Miocene subsidence was augmented by a eustatic highstand of sea level (Graham and others, 1982). Two lines of evidence from the San Joaquin basin, the inception of en echelon folding near the end of the Saucesian (Harding, 1976) and the distribution and inferred western provenance of Temblor Formation detritus (Graham and others, 1986), indicate that San Andreas fault movement may have begun as early as late early Miocene time along the Temblor Range 34 THE CENOZOIC EVOLUTION OF THE SAN JOAQUIN VALLEY, CALIFORNIA segment. Folding continued through the later Cenozoic and deformation increased in intensity near the San Andreas fault in the Pliocene and Pleistocene as a result of increased fault-normal compression. However, ongo- ing deformation at the east edge of the Coast Ranges, and by implication, the basinward expansion of the fold belt, may be considered evidence for deep-seated, eastward- directed thrusting (Wentworth and Zoback, 1986). 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FLOHR U.S. GEOLOGICAL SURVEY PROFESSIONAL PAPER 1502 Petrographic features, chemistry, and origin of protoliths, which included gel-like materials, of the manganese-rich carbonate, silicates, and oxides that form lenses in cherts of the Franciscan Complex UNITED STATES GOVERNMENT PRINTING OFFICE, WASHINGTON: 1990 US. DEPARTMENT OF THE INTERIOR MANUEL LUJAN, JR., Secretary U.S. GEOLOGICAL SURVEY Dallas L. Peck, Director Any use of trade, product, or firm names in this publication is for descriptive purposes only and does not imply endorsement by the US. Government Library of Congress Cataloging in Publication Data Huebner, J .S. Microbanded manganese formations: protoliths in the Franciscan Complex, California / by J. Stephen Huebner and Marta J .K. Flohr. p. cm. — (US. Geological Survey professional paper ; 1502) Bibliography: p. Supt. of Docs. no.: I 19.161502 1. Manganese ores—Geology—California—Buckeye Mine Region. I. Flohr, Marta J .K. 11. Title. 111. Title: Protoliths in the Franciscan Complex. IV. Title: Franciscan Complex. V. Series: Geological Survey professional paper ; 1502. TN490.M3H78 1990 553.4’629’097941 — dc20 89—600191 CIP For sale by the Books and Open-File Reports Section, US. Geological Survey, Federal Center, Box 25425, Denver, CO 80225 CONTENTS Page Page Abstract ........................................................................... 1 Mineral characterization and chemistry—Continued Introduction ...................... 1 Caryopilite and chlorite ................................................ 39 Acknowledgments ........ 2 Taneyamalite and phase A 42 Previous work ................... 4 Santaclaraite ...................... 44 Methodology ..................................................................... 9 Rhodochrosite ... ........... 44 Regional geology ............................................................... 11 Braunite .................... 45 Regional lithologies ...... 12 Hausmannite . .. ........... 45 Provenance ................................................................. 19 Discussion .................................................................. 45 Regional metamorphism ................................................ 19 Vein minerals .............................................................. 46 Protoliths ............................ 21 Origin .............................................................................. 47 Chert ............................ 21 Modern processes of marine manganese deposition ............ 47 Rhodochrosite protolith 25 Modern hydrothermal analogues ............................ 53 Caryopilite protolith ..................................................... 25 Some possible ancient analogues ..................................... 56 Taneyamalite .............................................................. 30 Projected metamorphic path .................................... 56 Chlorite protolith ......... 30 Origins of ancient deposits ............. 58 Gageite ...................................................................... 32 Origin of Buckeye deposit ............................... 61 Hausmannite protolith .................................................. 32 Environment near Buckeye deposit ............ 61 Braunite protolith ............. 33 Manganese deposition at Buckeye deposit.... 62 Diopsidic acmite protolith... 33 Diagenesis and metamorphism ...... 64 Summary of protoliths ................................ 33 Regional framework ....................................... 64 Mineral characterization and chemistry ................................. 34 Possible environments .................................................. 64 Gel-like materials ......................................................... 34 Summary and future work .................................................. 67 Gageite ...................................................................... 37 References ....................................................................... 67 ILLUSTRATIONS Page FIGURE 1. Geologic map of the Buckeye mine area and sample location maps ................................................................................ 3 2. Photographs of outcrops and hand specimen of chert ..................... 18 3. Pressure-temperature grid for metagraywacke ......................................................................................................... 21 4. Photographs of slabbed hand specimens of different protoliths ..................................................................................... 22 5. Photomicrographs of characteristic features of protoliths ............. 26 6. Photomicrographs of gel-like and partly recrystallized materials .................................................................................. 28 7. Graphs showing rare-earth element patterns of country rock and ore ........................................................................... 30 8. Photomicrographs of minerals and textures discussed in the text ................................................... 31 9. Ternary diagrams showing summary of chemical analyses plotted in the system Mn-Si—Z Others ..................................... 40 10—14. Diagrams showing: 10. Compositions of caryopilite and chlorites ...................................................................................................... 41 11. Nickel and zinc concentrations in caryopilite and chlorites .............................................................................. 43 12. Compositions of taneyamalite and Phase A ....................................... 44 13. Rare-earth element patterns, exclusive of the Buckeye deposit ....................................................................... 50 14. Predicted greenschist-facies assemblages for Buckeye protoliths projected onto the composition planes MnO—SiOZ— 2 Others and MnO—Si02—02 ............................................................................................................... 57 15. Sketches showing a possible mechanism for the creation of the paleodepositional environment for the Buckeye protoliths ..... 66 III IV TABLE 1. 2. 3. 4. 11. 12. 13. CONTENTS TABLES Page Known and hypothetical manganese minerals and common analogues discussed in text ..................................................... 6 Standards used for electron microprobe analysis of samples from the Buckeye deposit, California Coast Ranges ..... 10 Constituents of graywackes from the Buckeye deposit, California Coast Ranges ............................................. 13 Characterization of metasandstones, metacarbonates, and metavolcanic rocks from the Buckeye deposit, California Coast Ranges, by X—ray powder diffractometry ........................................................................................................... 14 Compositions of minerals from nonsiliceous host rock, in weight percent, from the Buckeye deposit, California Coast Ranges, determined by electron microprobe analysis ........................................................................................... 15 Chemistry and mineralogy of selected protoliths from the Buckeye deposit, California Coast Ranges .................................. 16 Characterization of siliceous samples from the Buckeye deposit, California Coast Ranges, by X-ray powder diffractometry.... 20 Compositions of gel-like materials, in weight percent, from the Buckeye deposit, California Coast Ranges, determined by electron microprobe analysis ............................................................................................................................ 35 Compositions of silicates from the Buckeye deposit, California Coast Ranges, determined by electron microprobe analysis 36 Compositions of vein minerals from the Buckeye deposit, California Coast Ranges, determined by electron microprobe analysis ........................................................................................................................................................ 37 Compositions of rhodochrosite from the Buckeye deposit, California Coast Ranges, determined by electron microprobe analysis ........................................................................................................................................................ 38 Compositions of the oxides braunite and hausmannite from the Buckeye deposit, California Coast Ranges, determined by electron microprobe analysis ............................................................................................................................ 39 Comparison of the Buckeye deposit, California, and some modern deep marine Mn-rich deposits ........................................ 49 MICROBANDED MANGANESE FORMATIONS: PROTOLITHS IN THE FRANCISCAN COMPLEX, CALIFORNIA By]. STEPHEN HUEBNER and MARTA J.K. FLOHR ABSTRACT The Buckeye manganese deposit, 93 km southeast of San Francisco in the California Coast Ranges, preserves a geologic history that provides clues to the origin of numerous lenses of manganese carbon- ate, oxides, and silicates that occur with interbedded radiolarian chert and metashale of the Franciscan Complex. Compositionally and miner- alogically laminated Mn—rich protoliths were deformed and dismem- bered, in a manner that mimics in smaller scale the deformation of the host complex, and then were incipiently metamorphosed at blueschist- facies conditions. Eight phases occur as almost monomineralic proto- liths and mixtures: rhodochrosite, caryopilite, chlorite, gageite, taney— amalite, braunite, hausmannite, and laminated chert (quartz). Braunite, gageite, and some chlorite and caryopilite layers were deposited as gel-like materials; rhodochrosite, most caryopilite, and at least some hausmannite layers as lutites; and the chert as turbidites of radiolarian sand. Some gel-like materials are now preserved as trans- parent, sensibly isotropic relics of materials that fractured or shattered when deformed, creating curved surfaces. In contrast, the micrites flowed between the fragments of gel-like materials. The orebody and most of its constituent minerals have unusually Mn-rich compositions that are described by the system MnO—SiOz— Oz—COZ-HZO. High values of Mn/Fe and U/Th, and low concentra- tions of Co, Cu, and Ni, distinguish the Buckeye deposit from many high-temperature hydrothermal deposits and hydrogenous or diage- netic manganese and ferromanganese nodules and pavements. This chemical signature suggests that ore deposition was related to fluids from the sediment column and seawater. Tungsten is associated exclusively with gageite, in concentrations as high as 80 parts per million. The source of the manganese is unknown; because basalts do not occur near the deposit, it was probably manganese leached from the sediment column by reducing solutions. Low concentrations of calcium (0310 approximately 0.6 weight percent) suggest that the host sedi- ments formed beneath the carbonate-compensation depth. The most probable cause of the microbanding is changing proportions of chemical fluxes supplied to the sediment-seawater interface. The principal fluxes were biogenic silica from the water column, carbon dioxide from organic matter in the sediment column, 02 and other seawater constituents, and Mn+2-bearing fluid. The presence of A1203 and TiO2 (supplied by a detrital flux) in the metashale but not the ore lens suggests rapid ore deposition. Material supply-rate changes were probably due to a complex combination of episodic variations in the hydrothermal flux and periodic flows of radiolarian sand (silica and C02 fluxes) that may be related to climate variations. Manuscript approved for publication, April 4, 1989. The processes that form recent marine hydrothermal mounds may be the same as processes that formed the Buckeye deposit. Features common to both include the presence of Mn-oxyhydroxide crusts (corresponding to the Buckeye orebody), a large Mn/Fe ratio, low abundances of most minor elements, and small size. The most impor- tant differences are the absence of rhodochrosite and manganese silicates, interlayered with oxide, and the absence of adjacent chert in the contemporary deposits. These differences may be due to an absence of the debris of siliceous pelagic organisms, which accumulated in the Buckeye paleoenvironment. Periodic turbidity flows of chert-forming radiolarian sand could provide the changes in the fluxes of silica and organic matter necessary to form manganese carbonate and silicates. Turbidity flows of graywacke indicate proximity to an environment with high relief. A possible paleodepositional environment is an oceanic spreading center approaching a continental margin at which subduction occurred. INTRODUCTION This report documents our initial effort to understand the origin and metamorphism of banded sedimentary manganese formations. The term “manganese forma- tion” (Huebner, 1976) was specifically chosen to empha- size the similarities in mineralogy and texture that are shared by iron formations, such as the Biwabik of Minnesota and the Hammersley of Australia, and some manganese deposits of the Pacific coast region of the United States. In this paper we will describe the petro- graphic, mineralogical, and chemical characteristics by which a family of sedimentary protoliths can be recog- nized and will speculate upon their depositional environ- ment, thereby creating a deposit model. Hundreds of supergene manganese-oxide pods in chert-graywacke terrains of California were prospected during the First and Second World Wars. At first, only supergene oxides could be used as metallurgical-grade oxide ore, so mining of a deposit ceased when the deposit was completely mined or when carbonate and silicates, rather than oxides, were encountered. When it became economic in the 1940’s to use rhodochrosite, mining in the larger deposits exposed manganese carbonate, silicates, and primary oxides, all precursors of the supergene oxides. It is these precursors that are the subject of this paper. 2 MICROBANDED MANGANESE FORMATIONS: PROTOLITHS IN THE FRANCISCAN COMPLEX, CALIFORNIA As a group and as individual deposits, the manganese orebodies of California are well documented. Trask and others (1943), Trask (1950), and Trengrove (1960) described the location, occurrence, and production of hundreds of deposits. Taliaferro and Hudson (1943), Crerar and others (1982), and Hein and others (1987) proposed origins for these deposits. We chose to inves— tigate the Buckeye mine, the second largest producer of manganese in California, because its primary (sedimen- tary or metamorphic) ore is exposed, the deposit is believed to be representative of many deposits in the California Coast Ranges, and an extensive collection of specimens was available as a result of the work of Huebner (1967). Although most ore had been removed (the walls of the enclosing chert are exposed), the north orebody and a nearby prospect-adit were sampled in 1963 (fig. 1). Samples were also obtained from piles of ore during the summer of 1963 and from surface outcrops during 1965. The nomenclature of manganese-rich phases, particu- larly the sheet silicates, is arcane but need not be so because many of the Mn phases have compositions anal- ogous to those of better known Mg or Fe minerals. Because a major purpose of this report is to present criteria for recognition of similar deposits, we summarize in table 1 the Mn minerals that are mentioned below or that we sought and list the corresponding Mg, Fe, and Al endmembers. In compiling this list, we used mineralog- ical summaries (Fleischer, 1981, 1987; Fleischer and Schafer, 1981, 1983) and their cited references. A detailed discussion of the crystal chemistry of the phases that we observed follows the discussion of the lithologies. The term “gel-like” is used in this paper to describe materials that resemble the less-than-O.1-p.m fine—clay fraction from Lake Abert, Oregon (separated from sam- ple 23de of Jones and Weir, 1983), which we have been able to examine. This material is pale brown, transpar- ent, flows if deformed slowly, and fractures if deformed rapidly or shocked by striking a plastic container that contains the gel—like material upon a hard surface. Because these gel-like materials are largely crystalline, albeit extremely fine grained, they would be expected to have compositions similar to those of their mineral constituent and to recrystallize (coarsen) to form monom— ineralic or polymineralic layers, depending upon their initial mineralogy. ACKNOWLEDGMENTS This study is an outgrowth of a chapter in the first author’s Ph.D. dissertation, written while he was a graduate student at The Johns Hopkins University. Partial support was provided by the University and by NSF Graduate Fellowships. Some laboratory and field expenses were defrayed by NSF grants to HP. Eugster; unfortunately, he is no longer alive to see What became of the samples. The Buckeye deposits are located on the Willow Springs Ranch; access was made possible by G. Purinton, owner in 1963, and by L. Douglas and M. Hall, owner and foreman, respectively, in 1965. Field assis- tance was provided by C.E. Beverley (1963) and E.Z. Huebner (1963, 1965). At the time of these visits, D.F. Hewett enthusiastically shared his knowledge of, and stories about, California manganese deposits. J .J . Fitz- patrick and J .J . Matzko participated in the early stages of the project’s revival at the US. Geological Survey (USGS). The continuing dedication of J .J . McGee of the Reston Microprobe Laboratory made feasible the collec- tion of the many microprobe analyses by Flohr. B.F. Jones of the USGS taught us much about seawater- sediment interactions and made us aware of the less— than-0.2—um smectite gel reported in Jones and Weir (1983). R.A. Koski (USGS) loaned us two thin sections, one of which in shown in figure SD. We greatly appreci- ate the enthusiastic cooperation of the following staff of the USGS chemical analysis laboratories who turned our “fishing expedition” into a study of the matrix effects in samples that are both highly manganiferous and distinct from the marine nodules: P.A. Aruscavage, M.W. Doughten, J. Fletcher, J .N. Grossman, R.G. Johnson, B. Libby, and H. Kirschenbaum. We benefited immensely. Constructive reviews were provided by P. R. Brett, J. Webster, and E. Force (all USGS) and L. Raymond (Appalachian State University). Brett sug- gested that serpentinization at low temperature might drive convection through abyssal sediments far removed FIGURE 1.—Geolog'ic map and sample locations. A, Distribution of chert-metashale, graywacke-sandstone, and manganese deposits in the Franciscan Complex near the Buckeye and Ladd mines, northern Diablo Range of the central California Coast Ranges. Adapted from Cox and others (in Trask, 1950, pl. 4) and Raymond (1973b, fig. 2). Inset adapted from Bailey and others (1964, pl. 1). Note the association of manganese deposits with chert and the undulatory contacts between chert and graywacke. The Carnegie fault and northern part of the Pegleg fault are parts of the Tesla-Ortigalita fault system. B, Geologic sketch map of the vicinity of the Buckeye mine. The base is aerial photography. Subdivision into broken formations follows usage of Raymond (1973a): Kstg, Sulphur Gulch broken formation; KJfg, Grummett broken formation; KJfo, Oso broken formation. C, Location of samples collected from surface outcrops and dumps. Base is identical to that used for B. Samples designated Hxac correspond to those labeled 65Hmc in text. Sample B112 is a grab sample from the gulch below (south of) the north orebody and is not plotted. D, Location of samples collected from the open cut, 1837- and 1805—ft levels of the north Buckeye orebody. Mine workings and trend of ore lens adapted from maps and sections by Crittenden and others (pl. 18 of Trask, 1950). E, Location of samples collected from exploration adit between the north and south Buckeye orebodies. INTRODUCTION xocxéwEEEO :mEEEO 85 :52). 250:.— aoafi 5:6 Siam v>mxuzm £30m mimic—am 552 nmEEan >eco;m5_ vumg cflnmm O'JOFN I—u—v— v-‘NMV‘W‘DNCD \\ 360qu ommcmmcmE aw. o—IW A2882, tcm 908392 66800 $86ch EmeE, ncm 968892 85:53 >w__m> 690 E ZOF \s\ .I/ \ \X\\\\\\ 5/ I’ll \ \xkkw? M» \\W\ \\ \\w\\\\\\\\\\\\\\aw ~ \\\~ VIA" 1‘3 mo nu v n wEEEBiow om ov om ON 3 o JEiiLiI. 832% 9. on cm H: o wmz_s_ w>mxuam mum 8&9:ch cum. I 0.550 52‘ 4 MICROBANDED MANGANESE FORMATIONS: PROTOLITHS IN THE FRANCISCAN COMPLEX, CALIFORNIA 0 500 1000 1500 2000 FEET | l | | J l l | l I l l O 100 200 300 400 500 600 METERS EXPLANATION a m as Contact between broken formations (see text), following Raymond (1973a); dashed where repositioned (see tables 4, 6) Graywacke V////A Metamorphic rocks Basal conglomerate Contact between lithologies within Grummett broken formation Ribbon chert in KJfg — — — — Trace of prominent white chert E Strike and dip of OUtCTOD (reef) bedding A Aragonite-bearing vein + Anticline 10 Diamond drill hole 8 from a spreading center. Although we did not adopt this suggestion for the Buckeye, serpentinization may be an important factor in the origin of laterally extensive diagenetic deposits. Raymond challenged us to expand our discussions of the relationship between the environ- ment of deposition and accretionary complexes. N H40 H41 H12,13 \_ FCm H28 -—\02 -.\N BuckeyeJ/n IE §3§1€1€| lynx 8109-110,H78 H11 _H19-212 H123 12 _____ q— S _Buckeye Exploration adit _H53 54 H LB4_5J\:< \< -62'65 11 H43-49,51 _26»128130-\_ H60,61 \— H23-25 _TEG: 0 500 1000 1500 2000 FEET I I I I I l l l l l l l 0 100 200 800 400 500 600 METERS EXPLANATION Sample from outcrop 10 Diamond drill hole ,_ _ _ _l —< Adit LEEJ Loose sample of ore /\/ Road PREVIOUS WORK Previous investigators dealt with aspects of the min- eralogy, petrology, chemistry, and genesis of the Buck- eye (and similar) deposits, but none has considered all of the different kinds of data that must be integrated to understand deposits such as these. In the following paragraphs we review the observations and data of our predecessors and show that there is still ambiguity about the fundamental nature and origin of the ore. The most complete description of the California Coast Ranges deposits is by Taliaferro and Hudson (1943) Who made frequent reference to the Buckeye mine When discussing the origin of similar deposits. Unique obser- vations were made while ore was being removed. Most PREVIOUS WORK 5 Open cut ~ 1970 ft [FE—lgél 0 30 60 9012OFEET 35 B72 0 1O 20 SOMETERS 1837‘ adit EXPLANATlON Red chert-argillite \\_ Green chert-argillite E White chert Sample from outcrop LEESJ Loose sample of ore Trend of ore lens; elevation in feet _r_ Strike and dip of bedding <—*~ Syncline showing plunge of axis 30 FEET | | | l l | 10 METERS O——O EXPLANANTION E White chert, argillite Red chert, argillite Sample number E —L Strike and dip of bedding <—)~(— Syncline showing plunge of axis FIGURE 1. —Continued. manganese deposits are associated with thick lenses of light-colored massive chert, which in turn are enclosed in darker, rhythmically bedded radiolarian cherts. The converse is not true: the vast majority of massive cherts are not associated with manganese deposits. Many cherts are associated with volcanic flows, but this is not the case near the Buckeye mines. Taliaferro and Hudson thought that the cherts were originally oozes rich in colloidal silica. On becoming a gel the ooze expelled the impuri- ties, thereby concentrating them in what are now the argillaceous interbeds. Thus the rhythmic chert layering was thought to be the product of diagenetic segregation. Presumably, they thought that the precursor to the massive cherts was an ooze so pure that there were insufficient impurities to form argillaceous layers. Orebodies known to Taliaferro and Hudson formed lenses less than 11 m thick and less than 240 m in maximum dimension. Folding and faulting obscured the shape of the orebodies in the plane parallel to the layering, but internally they were banded, being com- posed of smaller lenslike bodies that lay parallel to the layering in the surrounding cherts. These lenses con- sisted principally of manganese carbonate and silicates. Unfortunately, neither the spatial distribution of these two components within the lens nor the nature of their contact with the surrounding chert was discussed. An important observation, based in part on analysis of thin sections but overlooked by some subsequent investiga— tors, is that fine banding was present in material that Taliaferro and Hudson called manganiferous opal (1943, p. 240). The lenses are now partly recrystallized to pink rhombohedra of rhodochrosite and to yellow, orange, and brown fibers of manganese silicates called bementite. Hausmannite and braunite were uncommon and, because of association with barite and copper, were regarded as having formed during subsequent hydrothermal action. (Fleischer and Richmond (1943) reported the presence of braunite, but not hausmannite, at the Buckeye mine.) Taliaferro and Hudson thought that the deposits were “chemical sediments formed at the same time and in the 6 MICROBANDED MANGANESE FORMATIONS: PROTOLITHS IN THE FRANCISCAN COMPLEX, CALIFORNIA TABLE 1. —Known and hypothetical manganese minerals and common analogues discussed in text [—, not applicable; MVI/TIV, ratio of octahedrally coordinated to tetrahedrally coordinated cations] Mn species Ideal formula MVI/TIV Fe analogue (Mg,Al,Ca) analogue Rhodochrosite ................. MnCO3 — Siderite Calcite. Hausmannite .................. Mn304 — Magnetite Unknown. Bixbyite ...................... Mn203 — Hematite Unknown. Pyrolusite ..................... Mn02 — Unknown Unknown. Todorokite .................... Mn+2Mn3+4O¢ H20 — Unknown Unknown. Nsutite ....................... Mn;2Mnf3x02‘2x(OH)2X — Unknown Unknown. Braunite ...................... Mn+2Mng38i012 — Unknown Neltnerite. Birnessite ..................... Na4Mn14027~9H20 — Unknown Unknown. Vernadite ..................... (Mn+4,Fe +3, Ca,Mn)(O,OH)2~ nHzO — Unknown Unknown. Pyrophanite ................... MnTiO3 — Ilmenite Geikielite. Pennantite .................... Mn10A12(Si,Al)8020(OH)16 1.5 Chamosite Clinochlore. Gonyerite ..................... Mn1(,Fe;3(Si,Fe+3)8020(0H)16 1.5 Unknown Unknown. Bannisterite ................... (K,Ca)Mn10(Si,Al)16038(0H)8(H20)2_6 .625 Unknown Unknown. Ganophyllite ................... (K, Na,Ca)6Mn24(Si,A1)40(O,0H)112(H20)21 .6 Unknown Unknown. Caryopilite .................... MnGSi4Ow(OH)8 1.5 Greenalite Unknown. Bementite ..................... Mn7Si6015(OH)8 1.17 Unknown Unknown. Unknown ..................... (1/2Ca,Na)0‘66Mn6+2(Si,A1)8020(OH)4(H20)8 .75 Unknown Saponite. Unknown ..................... (Vzca, Na)0‘66Mn4+3(Si,A1)8020(OH)4(H20)8 .50 N ontronite Unknown. Unknown ..................... MnSSi8020(OH)4 .75 Unknown Talc. Unknown ..................... Mn308i40096(OH)28 .75 Minnesotaite Unknown. Ashley (1986) .................. K2Mn6(Mn+‘n5,Al)ZSi6020(OH)4 .75 Biotite Phlogopite. Unknown ..................... K2Mnjf3(Mn+3,Al)2Si6022(OH)4 .50 Unknown Muscovite. Akatoreite .................... Mn5,Alei8023(OH)9 .90 Unknown Unknown. Piemontite .................... Ca2Mn;3AlSi3012(OH) 1.0 Epidote Clinozoisite. Gageite ....................... Mn581209_x(0H)2x 2.5 Unknown Balangeroite. Taneyamalite .................. NatMnIZSimOgomH)14 1.0 Howieite Unknown. Unknown ..................... Mn6(Mn+3,Al)38i6020(OH)5 1.5 Deerite Unknown. Unknown ..................... K0_1Mn13(Al,Si)18042(OH)14 .72 Zussmanite Unknown. Parsettensite .................. K(Mn,Al)7Si8020(OH)8-2H20 .67 Unknown Unknown. Unknown ..................... KsMn48(Si63A19)O 168' (OH) 48 .67 Ferrostilpnomelane Lennilenapeite. Unknown ..................... K5Mn183(Si63A19)0216- 36H20 .67 Ferristilpnomelane Unknown. Spessartine ................... Mn3A12(SiO4)3 1.67 Almandine, andradite Pyrope, etc. Calderite ...................... Mn3+2l<‘e;3(SiO4)3 1.67 Unknown Unknown. Unknown ..................... Mn3(Si04)(F,OH)2 3.0 Unknown Norbergite. Alleghanyite .................. Mn5(SiO4)2(OH)2 2.5 Unknown Chondrodite. Manganhumite ................. Mn7(SiO4)3(OH)2 2.33 Unknown Humite. Leucophoenicite ............... Mn7(SiO4)3(OH)2 2.33 Unknown Unknown. Sonolite ....................... Mn9(SiO4)4(OH,F)2 2.25 Unknown Clinohumite. Tephroite ..................... MnZSiO4 2.0 Fayalite Forsterite. Donpeacorite .................. MnMgSi206 1.0 Ferrosilite Enstatite. Kanoite ....................... MnMgSiZO6 1.0 Clinoferrosilite Pigeonite. J ohannsenite .................. CaMnSi206 1.0 Hedenberg'ite Diopside. Ashley (1986) .................. NaMn’r‘D’SiZO6 1.0 Acmite J adeite. Rhodonite ..................... CaMn4(SiO3)5 1.0 Ferrobustamite Unknown. Pyroxmang‘ite ................. Mn7(SiO3)7 1.0 Pyroxferroite Unknown. Inesite ........................ CaQMn7Si10028(OH)2(H20)5 .90 Unknown Unknown. Santaclaraite .................. CaMn4Si5014(OH)(OH)- H20 1.0 Unknown Unknown. Nambulite .................... (Li,Na)Mn4Si5014(OH) .80 Unknown Unknown. Manganbabingtonite ............ CazMnFe +3Si5014(OH) .80 Babingtonite Unknown. Marsturite .................... N212021.2Mn68i10028(0H)2 .80 Unknown Unknown. Tirodite ....................... anMg5Si8022(OH)2 .88 Grunerite Cummingtonite. Dannemorite .................. anFe58i8022(OH)2 .88 Grunerite Cummingtonite. Kozulite ...................... NaNazMn4(Fe +3,Al)Si8022(OH)2 .88 Arfvedsonite Magnesioarfvedsonite. Tsilaisite ...................... Na(Mn1.5A11.5)A16(BO3)3Si6018(O,0H,F)4 1.0 Schorl Elbaite. Saneroite ..................... Na.2Mn10(Si,V)12034(OH)4 .83 Unknown Unknown. Welinite ...................... Mn6(W,Mg)ZSi2(O,OH)14 4.0 Unknown Unknown. PREVIOUS WORK 7 TABLE 1. —Known and hypothetical manganese minerals and common analogues discussed in text—Continued [—, not applicable; MVl/Tw, ratio of octahedrally coordinated to tetrahedrally coordinated cations] Mn species Ideal formula MVI/TIV Fe analogue (Mg,Al,Ca) analogue Franciscanite .................. Mn6[V,[:] ]ZSi2(O,OH)14 4.0 Unknown Unknown. Orebroite ..................... Mn6(Sb"5,Fe+‘°’)ZSi2(O,OH)14 4.0 Unknown Unknown. Pumpellyite-Mn2+ .............. CazMn+2A12(Si04)(Si207)(OH)2- H20 1.67 Ferropumpellyite Unknown. Okhotskite .................... CazMn+2(Mn+3,Al)2(Si04)(Si207)(OH)2‘ H20 1.67 J ulgoldite Pumpellyite. Sursassite ..................... Mn2Ala(SiO4)(Si207)(OH)3 1.67 Unknown Unknown. Mcfallite ...................... CazMn;3(Si04)(Si207)(0H)3 1.67 Unknown Unknown. Manganaxinite ................. CazMn+2A12BSi4015(OH) 1.0 Ferroaxinite Magnesioaxinite. Kanonaite ..................... Mn+3AlSiO5 1.0 Unknown Andalusite. Carpholite .................... MnAIZSi206(OH)4 1.5 Ferrocarpholite Magnesiocarpholite. Serandite ..................... NaMnZSi308(OH) .67 Unknown Pectolite. J ohinnesite .................... NazMg4Mn12As;5Si12043(OH)6 1.33 Unknown Unknown. Manganpyrosmalite ............ anSi12030(OH,Cl)20 1.33 Pyrosmalite Unknown. Schallerite .................... Mnf628i12A5§ 3036(OH)17 1.33 Unknown Unknown. Mcgillite ...................... Mn88i6015(OH)8012 1.33 Unknown Unknown. Friedelite ..................... MnSSi6015(OH,CI) 10 1.33 Unknown Unknown. same marine environment as the cherts” (p. 272). In their interpretation, the cherts were deposited as siliceous oozes and the manganese—rich materials as fine-grained gray manganese carbonate and thinly banded, resinous, almost optically isotropic manganiferous opal containing 14 weight percent H20. Silica and manganese were thought to be associated with volcanism, and the man- ganese was supplied as carbonate and oxides. The mas- sive cherts and the manganese orebodies represent peri— ods of rapid deposition. After examining many deposits, these authors found no evidence for replacement of chert by ore (Taliaferro and Hudson, 1943, p. 273). Trask and Pierce (in Trask, 1950, p. 211—221) focused on the Ladd-Buckeye area. Their observations were based in part on fieldwork during 1940—42, when the deposit was actively mined. Ore was always associated with white, usually massive, chert. They reported two kinds of ore: (1) massive, fine-grained gray rhodochrosite with bementite layers and minor hausmannite, rho- donite, and braunite and (2) a mixture of rhodochrosite and bementite, disseminated in chert. This second type forms a thin transition zone between massive carbonate and chert at the sides and ends of the lenses. Trask and Pierce thought that the pinching and swelling of the chert bodies reflected deposition in marine basins. Rec— ognition that the red color of chert represents an oxidized state of iron and that rhodochrosite represents a reduced state of manganese led them to propose that the manga- nese ores and white chert were formed in reducing basins and the oxidized chert formed under shallower marine conditions. The generally sharp contacts with the sur- rounding chert, at both the sides and the extremities of the manganiferous lenses, were thought to be caused by presumed distinct mechanical consistencies of the man- ganiferous sediments and silica gel. Hydrothermal activ- ity was thought to be indicated by the presence of quartz veins and Cinnabar, by the lack of bedding and non— uniform crystallinity of the gray rhodochrosite, and by the presence of hausmannite, rhodonite, and braunite. But despite this hydrothermal activity, the manganese did not migrate into the wall rocks. Subsequent observers also found massive ore. Trask (1950, p. 287—288) reported that, in 1942, massive ore was exposed in the north and south Buckeye orebodies. Crittenden (in Trask, 1950, p. 288—289) examined the orebody in 1944, at which time the primary ore was well exposed at levels subsequently accessible to Huebner (1967) and Hein and others (1987). Crittenden reported that along strike, the north Buckeye orebody was defined by change in manganese content rather than thickness, gradually changing to chalcedonic quartz and thence to chert. This is the only report of a gradational contact from the orebody into the chert. Crittenden described the ore as “an exceedingly massive and inti- mate mixture” (p. 288) of (in decreasing abundance) gray rhodochrosite, massive braunite and possibly hausman- nite, brown to tan manganese silicates, pink rhodochros- ite, neotocite, rhodonite, inesite, and sulfides. The older minerals (p. 289) were gray rhodochrosite, braunite, hausmannite (if present), and manganiferous chert (pre- sumably neotocite). Of these minerals, gray carbonate was regarded as “original” (p. 288) and the braunite and hausmannite as possibly metamorphic. Younger miner— als regarded as clearly hydrothermal in origin (p. 289) were pink rhodochrosite, quartz, rhodonite, inesite, sul- fides including molybdenite, brown and tan manganese silicates, and neotocite. Again, the spatial distribution of these minerals within the ore lens was not given. The property was drilled by the Bureau of Mines in 1940—41. Volin and Matson (1949) reported that the ore 8 MICROBANDED MANGANESE FORMATIONS: PROTOLITHS IN THE FRANCISCAN COMPLEX, CALIFORNIA consisted of rhodochrosite, bementite, rhodonite, psilom- elane, and pyrolusite. The last two minerals are undoubt- edly supergene. The primary ore was a mixture of carbonates and silicates, but layering was not noted. The boundary between the primary ore and chert was dis- tinct. Four drill holes encountered only low concentra— tions (1-11 percent by weight) of Mn and demonstrated that the high grade of the mined orebodies did not continue downward or along strike. Subsequently Tren- grove (1960) summarized this work as indicating that “a large mineralized zone of low-grade manganiferous chert” surrounded the north orebody. Huebner (1967) described the mineral associations, using X-ray powder diffractometry and thin sections to identify the minerals. He determined that the major ore-forming minerals were hausmannite, braunite, rhodochrosite with lattice constants nearly identical to those of pure MnC03, and What had been called bement- ite. He found that bementite from the Buckeye and elsewhere was a mixture of phases probably related to septechlorite (7A, serpentine), chlorite (14A), and the pyrosmalite group of minerals. He also found 9A and 6.9A reflections, now recognized as due to the presence of taneyamalite (Matsubara, 1981) and gageite (Phillips, 1911), and in thin sections observed pseudomorphs “more slender than most rhodonite crystals” (p. 66) of a mineral now known as santaclaraite (Erd and Ohashi, 1984). Unlike other workers, he did not find rhodonite, inesite, or neotocite. Huebner did not explicitly address the massiveness of the ores, but it is clear from his descriptions and photographs that he encountered both layered and massive ore. He recognized that the deposit had an unusual bulk composition that could be closely modelled by the system MnO—SiOZ—OZ—COZ—HZO. He suggested that the Buckeye deposits and enclosing cherts formed as chemical sediments in local depressions, rapidly precipitated from thermal waters in the intervals between turbidite (graywacke) units. Rapid deposition of the manganiferous material and adjacent silica diluted the supply of clastics, represented by the argillaceous layers within the chert rhythmites, providing an expla- nation for the high purity of the deposit and the absence of shale interbeds in the massive chert adjacent to the ore. In the absence of associated volcanic rocks and in view of the rapid deposition, he did not favor the leaching of extrusive flows as the source of the manganese. Rather, because of the high Mn/Fe ratio, he preferred a hydrothermal source and thought that the carbonate and silicates resulted from mixing of hydrothermal and oce- anic waters. Most important, he noted that the Mn-rich sediments at the Buckeye were relatively oxidized and proposed that their high intrinsic oxygen fugacity values were inherited from initially oxidized sediments. This concept was later developed more clearly (Huebner, 1969, 1976). Hewett (1972) reviewed the occurrences and signifi— cance of hausmannite and braunite, concluding that hausmannite formed from hypogene (rising) solutions, whereas braunite could be either hypogene or super— gene. In discussing the manganese deposits of the Cali- fornia Coast Ranges, Hewett stated that (p. 87) “layers or lenses of nearly pure manganese carbonate and thin layers of hydrous manganese silicate (neotocite or ‘man— ganese opal’) were laid down either in or near persistent layers of chert. Under the influence of later hydrother- mal solutions at the Buckeye deposits, the carbonate was thought to alter to hausmannite and the hausmannite to bementite and neotocite; braunite has also been identi- fied in this assemblage.” Clearly, Hewett saw the lay- ered nature of the ore and thought that carbonate was primary, that opaline material was both primary and formed by alteration of carbonate, and that all hausman- nite and braunite were formed by alteration of earlier formed minerals. Raymond (1974) discussed the lithologies of the Mt. Oso area of the Diablo Range, which includes the Buck- eye mine, and advocated a depositional environment that combined an abyssal ocean floor or trench with an ocean ridge. The manganese deposits were not discussed, but subsequently Raymond (1977) placed the Ladd-Buckeye district in the context of a seafloor spreading center. Crerar and others (1982) initiated a detailed geochem- ical study of manganese deposits of the Franciscan Complex. They considered the 800 known deposits to be similar and focused on two deposits in northern Califor- nia, the Blue Jay and South Thomas mines. Crerar and others proposed an origin involving hydrothermal pro- cesses analogous to those forming the mounds near the Galapagos rift (Corliss and others, 1978). Among the principal lines of evidence cited are the linear distribu- tion of orebodies and the fact that massive ore is devoid of detritus, is depleted in Fe and some trace elements relative to marine nodules, and has rare-earth-element (REE) patterns similar to patterns thought to be of hydrothermal origin. High heat flow associated with a spreading center was assumed to provide the energy needed to drive the hydrothermal system. Crerar and others favored deposition at either a midocean ridge or back-arc basin. Stable-isotope data for rhodochrosite from the Buck- eye mine were provided by Hodgson (1966) and Yeh and others (1985). Highly negative 813CPDB values of —45 to —54 per mil (referred to Peedee belemnite) were inter- preted as indicating that the CO2 was derived by the oxidation of methane (Hathaway and Degens, 1969). Because this conclusion does not depend upon partition- ing of carbon isotopes between fluid and unusual phases METHODOLOGY 9 with unknown behavior, we accept an origin for the 003’ that involves decomposition of organic matter. From a single SEOSMOW value (+19.5 per mil, referred to stan- dard mean ocean water) for a rhodochrosite sample assumed to have been deposited from seawater, Yeh and others (1985) assigned a temperature of formation of 75 °C. From 81805M0W values of 18.7 to 26.6 for eight rhodochrosite samples from deposits within the Fran- ciscan Complex, Hein and Koski (1987) obtained temper- atures of formation of 12 to 120 °C. The significance of these temperatures is in doubt because the fractionation factor for rhodochrosite precipitation is uncertain (see discussion by Okita and others, 1988, p. 2683) and because, as we will show, all rhodochrosite from the Buckeye deposit observed by us is admixed with other phases of unknown oxygen isotope fraction behavior and all samples of Buckeye rhodochrosite observed by us are at least partially recrystallized. Huebner and others (1986a) briefly described mineral- ogical banding and the presence of relic gels (the gel-like materials in this report) in the Buckeye deposit. Carbon— ate mud, interlayered with silicate and oxide gels, was deposited at the sediment-seawater interface. The layer- ing was thought to have been caused by relatively rapid variations in the supply fluxes and may have been climatically induced. Hein and others (1987) provided chemical, mineralog- ical, and isotopic data for the Buckeye and adjacent Ladd deposits. They cited Huebner (1967) for observing abun- dant hausmannite and Erd and Ohashi (1984) for “rare” santaclaraite, apparently because they observed neither mineral in their own samples. Because we observed these minerals in many samples collected at the Buckeye, we believe that sampling by Hein and coworkers may not have been as comprehensive as that of Huebner (1967). They proposed that the Buckeye and Ladd deposits formed in a deep basin at a continental margin by replacement of thin turbidites of radiolarian sand by carbonate. The massive chert, which consists of lami- nated chert without argillaceous interbeds, was thought to have formed from silica released by this replacement process, but the composite nature of the massive chert was not explained. Because opal-CT was reported to occur in the manganese ores but not in the surrounding rocks, this replacement process was thought to occur at less than 80 °C and at a depth of 100—700 m in the sediment pile. Hein and others believed that the manga- nese was originally derived from manganese oxides and oxyhydroxides dispersed in adjacent chert-metashale layers, but by comparison with the compositions of average shales, argillites, and cherts (Pettijohn, 1957), we do not find that the chert-argillites of the Ladd- Buckeye district are depleted in Mn. Hein and Koski (1987) summarized available stable- isotope data for the manganese deposits of the Fran- ciscan Complex, including the Ladd and Buckeye depos- its. The dominant ore mineral was reported to be rhodochrosite; some samples contained braunite and bementite; and kutnahorite, manganiferous calcite, pen- nantite, serandite, and sursassite were reported to be less abundant. No mention was made of compositional banding. They reported the “existence of replacement textures of rhodochrosite and silica polymorphs” (p. 725) but gave no examples. In their preferred scenario, manganese was originally deposited within the rhythmic chert sequences as hydrogenous oxides and oxyhydrox- ides. During diagenesis, buried organic matter produced CH4 that rose into the overlying sediments and was oxidized, in situ, by the oxides and oxyhydroxides, forming COZ. COZ, CH4, and reduced manganese moved through fluids produced by compaction and silica dehy- dration to form rhodochrosite at or below the zone of sulfate reduction and sulfide precipitation, below the seawater-sediment interface. In their model, it is not clear why rhodochrosite did not form at the same time and place at which the oxides and oxyhydroxides within the sediment column were reduced. A replacement ori- gin was implied, but the internal structure and composi- tional diversity of the orebody were not explained. Most early investigators regarded the gray manganese carbonate and manganiferous opal as chemically precip- itated sediments, but in recent work Hein and others (1987) and Hein and Koski (1987) concluded that the carbonate is the product of a replacement process. Most investigators also appeal to later hydrothermal processes to form the diverse mineralogy, but Huebner (1967; 1986a,b) interpreted this diversity to be a feature of the sedimentary environment. Although there are some reports of banded or layered ore at the Ladd and Buckeye mines, most reports are of massive ore at the working face of the Buckeye mine. The recent papers by Hein and his coworkers make no reference to layered ore. If similar deposits or their metamorphosed equiva- lents are to be recognized elsewhere, it is essential that the internal structure, compositional diversity, and min- eralogy be known. METHODOLOGY Sample locations are shown in figure 1. Data were obtained by using transmitted and reflected light optical microscopy, X—ray powder diffractometry (XPD), electron-microprobe analysis (EMP), and chemical bulk analyses. Because the manganese-rich materials are het- erogeneous, it was necessary to examine a large number of samples. We examined 77 polished thin sections, 37 10 MICROBANDED MANGANESE FORMATIONS: PROTOLITHS IN THE FRANCISCAN COMPLEX, CALIFORNIA covered thin sections, and 24 polished blocks. We crushed 87 samples for bulk chemical or X-ray diffraction analyses. Each crushed sample represents a single litho- logic type, and most were immediately adjacent to material used for a thin section. Because much of the ore consists of thin layers, many of these crushed samples were less than 2 g in weight. Approximately 33 addi- tional small samples were systematically examined by XPD. Thus, we were able to integrate diverse kinds of measurements made on essentially identical material. The seven samples chemically analyzed for this report received special handling. Possible Fe, Co, Cu, Mn, Ni, or Zn contamination by the saw blades was reduced by grinding sawed surfaces with silicon-carbide grit fol- lowed by cleaning ultrasonically in deionized water and acetone. These samples were crushed in a hardened steel mortar (Fe, Cr) and ground with an agate mortar and pestle. To reduce sample-to-sample cross contamination, the first crushed material for each sample was set aside and used for XPD rather than trace-element chemical analyses. The bulk chemical analytical methods are sum- marized in Baedecker (1987). Total contamination (by the process of sawing, crushing, and grinding) and cross contamination (by the previous sample) were investi— gated by subjecting spectroscopically pure silica glass to identical procedures (both before and after the aforemen— tioned seven samples). The second—crushed silica glasses contained less than 4 ppm Cr, less than 50 ppm Fe, and less than 1,600 ppm Mn, concentrations which are much lower than those in the protoliths, indicating that con- tamination was not a significant factor. We are confident that observed large differences in trace-element concen— trations of our Mn-rich samples are real. The X-ray diffractometer used CuKa radiation, a proportional counter, and pulse-height analysis that effectively discriminated against MnKa fluorescence from Mn-rich samples. Even so, the sheet silicates gave such poor-quality patterns that useful unit-cell dimen- sions could not be obtained. (Attempts to obtain good patterns with a Hague-Guinier camera equipped with a monochromator were even less successful, perhaps because, in the Guinier technique, X-rays pass through the powdered sample rather than reflect from its sur- face.) The goniometer divergence, receiving, and anti- scatter slits were 1°, 0.1 mm, and 1°, respectively; the radius was 170 mm; and the takeoff angle was 6°. At a 20 scanning rate of 1° per minute, the patterns routinely yield a. crystallinity index (Murata and Norman, 1976) of 10.5 to 11.5 for powder obtained by crushing and grind- ing (to pass ZOO-mesh screen) a large quartz crystal of quality suitable for electronic oscillators. Electron microprobe analyses were performed on a unit with 8 wavelength-dispersive channels operated at 15 kV and 100 nA beam current (15 nA nominal specimen TABLE 2,—Standards used for electron microprobe analysis of sam- ples from the Buckeye deposit, California Coast Ranges [See Huebner and Woodruff (1985) for fuller explanation; na, not analyzed] Phase analyzed Element Oxides Carbonates Silicates Na ............... FSLC na FSLC Mg ............... OXTB CDOS PXEN A1 ................ OXGH na FSLC Si ................ FSLC na FSLC K ................ na na FSBO, MSFPl Ca ............... FSLC CDOS FSLC Ti ................ OXIL na SPHC V ................ OXVA OXVA OXVA Cr ................ OXTB na OXTB, OXBU Mn ............... OXPA CRAP OLST Fe ............... OXIL CSIG OLSF, MBLM Co ............... OLCO na na Ni ................ OLNI OXNC OLNI Zn ............... OXGH OXGH OXGH Sr ................ na CSTR na Ba ............... GLBA GLBA GLBA1 F ................ na na MSFPl As ............... OXAS,2 ARDN2 na na Explanation of acronyms ARDN ............ Ardennite, Pennsylvania State University Standard 5—114. CDOS ............ Dolomite, Oberdorf, Austria. CRAP ............ Rhodochrosite, Alma Park, N. Mex. CSIG ............. Siderite, Ivigtut, Greenland. CSTR ............ Strontianite, Oberdorf, Austria. FSBO ............ Orthoclase, St. Lawrence Co., NY. FSLC ............ Labradorite feldspar, Lake County, Oreg. GLBA ............ Synthetic barium—bearing glass. MBLM ........... Biotite, Lemhi, Idaho. MSFP ............ Synthetic fluor-phlogopite, KMgsAlSi3010F2. OLCO ............ Synthetic 0028104. OLNI ............ Synthetic NizSiO4. OLSF ............ Synthetic fayalite, FeZSiO4. OLST ............ Synthetic tephroite, MnZSiO4. OXAS ............ Synthetic As203, National Bureau of Standards Standard Reference Material 833'. OXBU ............ Chromite, Bushveld Complex, S. Africa. OXGH ............ Gahnite, Brazil. OXIL ............. Ilmenite, Ilmen, USSR. OXNC ............ Synthetic bunsenite, NiO. OXPA ............ Synthetic bixbyite, Mn203. OXTB ............ Chromite, Tiebaghi, New Caledonia. OXVA ............ Synthetic V203. PXEN ............ Synthetic enstatite, MgSi03. SPHC ............ Titanite, Hemet quadrangle, California 1 Used regularly only for parsettensitelike phase and to check other silicates. 2 Used to analyze phase D only. current) and using a focused beam (estimated activation volume less than 10 um3). The standard or unknown was exposed to the electron beam for 20 to 80 seconds. Analytical software was described by McGee (1985). Mineral standards, documented by Huebner and Wood— ruff (1986), are summarized in table 2. Backgrounds were obtained by interpolation, based on the mean atomic REGIONAL GEOLOGY 11 number (Z) of the unknown, between the count rates obtained on quartz or MgO (low Z) and on tephroite, NiO, or V203 (high Z). Peak intensity data were cor- rected by the method of Bence and Albee (1968). Alpha factors used for constituent oxides were measured by Albee and Ray (1970) and calculated from first principles. Carbon was not determined, but the carbonate analyses were corrected in a similar manner, providing that CO2 had been excluded from the analysis of the reference standard (and the calculation of its set of B—factors). Analyzed compositions of all phases were compared with an energy dispersive analysis spectrum to determine whether any elements present in significant quantities had been missed in the wavelength dispersive analysis. Fluid inclusion techniques were not used in this study because fluid inclusions are rare in the Buckeye ore. The only inclusions found were in a minute amount of barite that appeared to replace rhodochrosite in sample B29. These inclusions were minute and had small vapor bubbles. REGIONAL GEOLOGY In lithologic variation and deformation, the thinly banded ore mimics the host Franciscan Complex but in miniature. Thus, in addition to providing a geologic framework for manganese deposition, the regional geol- ogy may provide clues to the origin of some delicate textures of the ores. The area containing the Ladd and Buckeye mines has been mapped by Huey (1948), Cox and others (in Trask and others, 1950, pl. 4), Maddock (1955), Raymond (1973a,b), and Raymond and Maddock (unpub. mapping, 1976—78). Detailed geologic descrip- tions of the immediate vicinity of the Buckeye mines were published by Pierce (in Trask, 1950, pl. 17) and by Volin and Matson (1949). Huebner (1967) recognized that the metagraywacke sequences at the Buckeye mine were turbidites that retained clastic texture after low- temperature and high-pressure metamorphism. Ernst (1971) correlated the textural grade of the metagray- wackes with the development of metamorphic assem- blages containing pumpellyite, albite, lawsonite, and jadeitic pyroxene but did not find jadeitic pyroxene near the Buckeye. We will demonstrate below that the meta- graywackes correspond to his textural grades 1 and 2 and mineral zone 2. Raymond (1973a,b) provided metamor- phic and tectonostratigraphic maps. He found lawsonite and albite in the immediate vicinity of the Buckeye mine and recognized both jadeite and aragonite elsewhere in the unit that contains the Buckeye mine, but he found no relationship between metamorphic grade and texture (Raymond, written commun., Feb. 6, 1988). Huebner (1967), Hein and others (1987), and Hein and Koski (1987) provided many other relevant observations, but no maps. The vicinities of the Buckeye and Ladd mines are each characterized by sandstones containing an unusual abun- dance of chert (fig. 1A), most of which is interbedded with argillaceous layers. Each area contains one large and several smaller manganese deposits. The eastern chert-rich sequence contains the large north Buckeye orebody and the smaller south Buckeye, Sulphur Gulch, Tiptop, Grummett, Grummett-Knox, Liberty, and Moran Brothers deposits, each closely associated with the chert. The western (Ladd) sequence is similar. These chert sequences pinch out and are truncated by shear zones to the west (Buckeye) and to the east (Ladd sequence). The similarities in outcrop pattern, regional strike (west—northwest), and alignment of both chert and manganese horizons might suggest that the eastern and western districts were once a continuous manganiferous horizon that was broken into distinct segments (depos— its), but mapping by Raymond (1973a,b; written com— mun., Feb. 6, 1988) shows that the deposits lie in several lithologically distinct units. The Buckeye mines lie in the northern side of Buckeye Gulch, in an area characterized by steep slopes, a high ratio of rhythmic chert to graywacke, and prominent outcrops (reefs) of northerly dipping massive chert (fig. 13). Sulphur Gulch, to the north, is characterized by gentler topography and by sheared and altered gray- wacke with much less chert. South of the chert-rich section, near the bottom of Buckeye Gulch, are blocks or pods of glaucophane schist and carbonatized ultramafic rock in sheared graywacke, below a layer of coarse conglomerate. The south side of the gulch is graywacke with distinctly less chert than the north side. Raymond (1973a) recognized that this terrain consists of broken units and subdivided the area into three broken forma- tions, which we here use informally: the graywacke-rich Sulphur Gulch, the chert-rich Grummett, and the south- erly Oso broken formations (Kstg, KJfg, and KJfo, respectively, in fig. 18). We have informally adopted Raymond’s subdivision because it is useful in describing the graywacke-rich and chert-rich units in the vicinity of the Buckeye deposits. The Grummett broken formation contains the Buckeye mines and consists of the first 800—900 in of the Buckeye stratigraphic section by Hein and Koski (1987, p. 723), from the conglomerate at the base to approximately the greenstone. Glaucophane schist, greenstone, and carbonate-rich blocks are either erosional remnants of an overthrust unit or slivers of basement brought up along faults bounding the Grum- mett broken formation. In either case, the composition and metamorphism of these blocks do not relate directly to the history of the area. To describe the degree to which the bedding of the graywackes, chert, and manganiferous sediments was disrupted, we adopted the classification of Raymond 12 MICROBANDED MANGANESE FORMATIONS: PROTOLITHS IN THE FRANCISCAN COMPLEX, CALIFORNIA (1984, his fig. 1, classification type VIII). In this scheme there is a progression from coherent (well-stratified) units through broken units (in which the fragments are moved slightly relative to each other) and dismembered units (in which there is no suggestion of the initial relative positions) to a melange (in which disoriented fragments are engulfed in a matrix). We understand that there is no consensus on the terminology used to describe complexes and melanges; for instance, the classification of Cowan (1985) places more emphasis on lithologic types. We chose the scheme of Raymond because we found it useful in describing the disruption of unusual manganese—rich lithologies. Near the Buckeye mine, the degree of stratigraphic continuity decreases with decreasing scale of the domain considered. Raymond (1973a) mapped the regional units as broken formations. Within the Grummett broken formation, the chert bodies have irregular shapes in outcrop pattern (see Trask, 1950, pls. 4, 17) that suggest intricate folding; the chert appears to float in sandstone yet retains a strike and dip that is predominantly parallel to the regional trend. One of us (Huebner) had difficulty following sedimentary contacts on a scale exceeding several hundreds of meters because the chert reefs consist of slightly displaced blocks (called phacoids by Raymond, 1973a, 1977). At the scale of the chert reefs, the structure is transitional between that of the broken and disrupted units. We will show that much of the ore, on the scale of a hand specimen and thin section, is a breccia with cataclastic to mylonitic textures. This intensely disrupted material may represent the massive ores described by some of our predecessors. Neverthe- less, layered and laminated ore, intact on at least the scale of a hand specimen, does occur. Some breccia fragments in the disrupted ore are layered and lami- nated, evidence that they were once part of a well- layered sediment. Despite disruption of the stratigraphic section, the nonmanganiferous host rocks provide important clues to the sources of sediment, the nature of the depositional environment, and the subsequent metamorphism. Most of the sediments are either detritus from a continent or a magmatic arc or skeletal debris from marine pelagic organisms. Deposition of each type was predominantly by turbidity flows. Metamorphism was at very high pressures and low temperatures, implying rapid subsid— ence and uplift. REGIONAL LITHOLOGIES Coarse conglomerate occurs at the base of the exposed Grummett broken formation in the western part of Buckeye Gulch. Rounded cobbles of black and green chert, white vein quartz, feldspar porphyry with green matrix, and shale form clasts that are suspended in a matrix of greenish graywacke. This conglomerate is probably from the same provenance as the matrix of the massive graywacke elsewhere in the Grummett unit and may incorporate earlier Franciscan sediments. The turbidite units are dominantly massive graywacke and include minor laminated siltstone, shale, and intraformational conglomerates in which shale chips are suspended in greenish-gray to gray graywacke matrix. Graded beds are rare; one unusually complete unit grades from conglomerate to shale (Huebner, 1967, p. 28) and indicates that, locally at least, the north-dipping beds are not overturned. Ten representative graywackes from the Grummett broken formation and its contact zones were examined in thin section (table 3) and by XPD (table 4). All graywackes retain clastic texture. The framework consists of albite, quartz, chert, micropor- phyries, shale and clay chips (some black and of moder- ately high reflectivity, presumably due to organic mat- ter), biotite, muscovite, reddish chromite, and zircon, in decreasing order of abundance. Most quartz clasts are monocrystalline and unstrained. Quartz clasts that are polycrystalline or that do not extinguish uniformly under crossed nicols are uncommon. The compositions of some detrital minerals are summarized in table 5. Pyroclastic components, if present, have been transported and reworked by sedimentary processes. Postdepositional processes included compaction of the matrix, corrosion of framework grains, and incipient recrystallization, corre- sponding to the textural grades 1 and 2 of Ernst (1971). The fabric varies from essentially unfoliated to slightly foliated in hand specimen (distinctly foliated in thin section). Of the metamorphic minerals, lawsonite is ubiquitous and develops in framework albite and in the matrix. Other metamorphic minerals are concentrated in the matrix. Chlorite (IIb structural type of Bailey, 1980), phengitic muscovite, and titanite occur in every section. Calcite and chloritized biotite occur in most sections; brown stilpnomelane appears in several thin sections and in one thin section was confirmed by microprobe chemical analysis (table 5). Glaucophane, clinopyroxene, and pale- green Ti02 (anatase) are uncommon, and green tourma— line is rare. J adeite, laumontite, pumpellyite, and clinop- tilolite were sought but never identified in our samples. Aragonite occurs in White veins in sheared or altered graywacke and greenstone, which occur near the con- tacts between the broken formations, but, in contrast, coarsely crystallized (primary) calcite with rhombohe- dral cleavage is the characteristic polymorph in gray- wacke of the interior of the broken units. With the exception of the albite-lawsonite association, petro- graphic criteria for an equilibrium assemblage are lack- ing. Representative chemical analyses of metamorphic minerals are given in table 5. These minerals should be REGIONAL GEOLOGY 13 TABLE 3.—Constituents of graywackes from the Buckeye deposit, California Coast Ranges [Modes of clasts are visual estimates only, obtained from thin sections. tr, trace; x, present; -, not observed] Sample B44 B110 65H10 65H27 651-135 65H72 651-173 65H74 65H110 65H119 Modes of clasts, in volume percent 60 50 55 50 40 35 35 50 45 55 5 10 10 10 20 30 15 10 20 5 20 25 20 20 25 20 25 20 25 20 Lithic fragments ............... <5 <5 <5 <5 <5 <5 <5 tr <5 tr Groundmass ................... 15 15 15 20 15 15 20 20 10 20 Mineralogy Quartz ........................ x x x x x x x x x x Albite ........................ x x x x x x x x x x Lawsonite ..................... x x x x x x x x x - Glaucophane ................... x - x - - — x - x - Ca—carbonate .................. x x x x x - x - x - Biotite (chloritized) ............ x x x x x x x x x x Chlorite ....................... x x x x x x x x x x Muscovite ..................... x x x x x x x x x x Stilpnomelane ................. x - - - - - - - - - Spinel-chromite ................ x x - x x x x - - - Titanite ....................... x - x - - x x - x x Anatase. . x x - x x - - x - x Zircon .................. . . . x x x - x x x x - - Tourmaline .................... - x - x - - - x - - Clinopyroxene ................. x - - - x - - - - - Fe-oxide or hydroxide .......... x - x x - x x x x x Green claylike material1 ........ x x x x — x - - x - 1Present in very sparse amounts. regarded as index minerals rather than as metamorphic assemblages. The critical associations are quartz + albite + lawsonite + calcite + chlorite and quartz + albite + lawsonite + aragonite + chlorite. The mineralogy of the framework elements and the bulk chemistry of the graywackes from the Grummett broken formation and close to the Buckeye deposit are potential indicators of sediment source and depositional environment. Some discriminants, reviewed by Taylor and McLennan (1985), include analyses of modern sands (Maynard and others, 1982) and Phanerozoic sandstones (Dickinson and others, 1983). Interpretation of the Buck- eye graywackes is ambiguous. The high proportion of quartz clasts (table 3) suggests derivation from a conti- nental block or uplifted orogenic zone; Without knowl- edge of the original lithic clast population, which may have been altered during diagenesis or metamorphism, we cannot distinguish between these two environments. The small value of K20/Na20 (table 6) suggests an island-arc setting. However, the apparent island-arc signature may merely reflect loss of K20 due to metaso- matism. The range of rare-earth—element patterns for seven Buckeye graywackes (see fig. 7A; average values in table 6; Huebner and Flohr, unpub. data) are similar to patterns for the quartz-intermediate graywackes of Tay- lor and McLennan (1985). This group includes recycled orogens, continental blocks, and dissected magmatic arcs but excludes a forearc basin deriving sediment from a young andesitic arc. We favor a sediment source such as a deeply dissected continental magmatic arc complex, augmented by intraformational clasts of shale and chert derived from near the site of deposition. In studying graywackes from throughout the Franciscan Complex, Dickinson and others (1982) observed a smaller propor- tion of monocrystalline quartz clasts and tentatively concluded that potassium feldspar was originally present but has been replaced by albite. They concluded that the Franciscan graywackes of the Diablo Range were derived from the southern portion of the Sierran- Klamath magmatic arc, near the Mojave block. Seiders and Blome (1988) examined conglomerates in the Fran- ciscan Complex of the Diablo Range. They concluded that conglomerates rich in volcanic clasts were trans- ported directly westward and that chert-rich conglomer- ates were transported southward. However, they did not report data for the conglomerates shown in figure 13. The contacts between the graywacke units and the thick sequences of interbedded chert and metashale, although not well exposed, were originally thought by Huebner (1967) to be sedimentary. Raymond (1974) suggested that, at least locally, some contacts between chert and graywacke are sedimentary, yet Raymond (1973a; written commun., 1988) stated that most of the intraformational contacts between chert and graywacke are now sheared as a consequence of postdepositional 14 MICROBANDED MANGANESE FORMATIONS: PROTOLITHS IN THE FRANCISCAN COMPLEX, CALIFORNIA TABLE 4. —Charactem'zation of metasandstones, metacarbonates, and metavolcanic rocks from the Buckeye deposit, Caltfomia Coast Ranges, by X—ray powder diflmctometry [Color terms from Goddard and others (1970). Meta-vole, metavolcanic rocks; meta-carb, metamorphosed carbonate rocks. Estimated intensities of X-ray powder diffraction intensities: V, very; S, strong; M, moderate or moderately; W, weak; -, not observed] Sample B44 B110 65H18 65H20 65H27 65H28 65H28 Color Greenish gray Light olive gray Light olive gray Light olive gray Light olive gray Light olive gray White Foliation None None Weak None None None None Rock type Graywacke Graywacke Graywacke Meta-vole Graywacke Graywacke Vein Quartz ............ VS VS M S VS S VW Low albite ......... S VS M VS S S — Chlorite ........... VW VW M M MS M - Muscovite ......... VW VVW W - - - - Calcite ............ - W - M VW - W Aragonite .......... - - - - - - M Lawsonite ......... - - — - - W - Sample 65H29 65H29 65H29B 65H30A 65H30B 65HSOC 65H311 Color Grayish olive Very light gray Olive gray White Light gray Olive gray Mottled gray brown Foliation None None N one None Laminated Laminated Weak Rock type Greenstone Vein Greenstone Vein Meta-carb Meta-earl) Meta-carb Quartz ............ MW VVW M M S VS MS Low albite ......... - - W - - - - Chlorite ........... S - MS - VVW VW - Muscovite ......... - - - - - - - Calcite ............ VW M - M VVW MS MW Aragonite .......... W W - M W M MW Lawsonite ......... - - VW - - - - Dolomite .......... - - - — VS S - Sample 65H33 65H33 65H34 65H35 65H43 65H43 65H51 Color Medium dark gray White Light olive gray Light olive gray Dark gray White Pale yellowish brown Foliation Slight None Slight Slight None None None Rock type Greenstone Vein Graywacke Graywacke Hornfels Vein Hornfels Quartz ......... VS S S VS S W M Low albite ...... MW - VS VVS - - - Chlorite ........ MW - M VW MW - M Muscovite ...... — - VW? VVW? W - — Calcite ......... - VVW - - - W W Aragonite ....... - W - - — MS M Lawsonite ...... W - VW - W - VW Glaucophane - - - - MW — - Sample 65H52 65H55 65H55 65H56 65H57 65H59 65H60 Color Light olive gray Light olive gray White Light olive gray Light olive gray Olive gray Dark gray Foliation None Slight None None Slight None None Rock type Greenstone Graywacke Vein Meta-carb Graywacke Meta-vole Hornfels Quartz ......... M MS W M S MS S Low albite ......... S M - - S M - Chlorite ........... M W - M W MS W Muscovite ......... - - - - - - - Calcite ............ - - S - - - VVS Aragonite .......... W - VVW MW - - VW Lawsonite ......... - - - W - - - Sample 65H65 65H72 65H73 65H74 Color Light olive gray Medium gray Medium gray Greenish gray Foliation Slight None None Slight Rock type Graywacke Graywacke Graywacke Graywacke Quartz ............ VS VVS VVS VS Low albite ......... VS W VS S Chlorite ........... M VVW M M Muscovite ......... - - - W Calcite ............ - - VVW - Aragonite .......... — - - - Lawsonite ......... - - W - 1 XPD patterns from 65H31 also contain a weak reflection at 2.894 A. REGIONAL GEOLOGY 15 TABLE 5. —Compositions of minerals from nonsiliceous host rock, in weight percent, from the Buckeye deposit, California Coast Ranges, determined by electron mzcroprobe analysis [Total Fe reported as FeO for all minerals. Ferrous and ferric iron calculated assuming ideal stoichiometry of 3 cations per 4 oxygens for chromites. Analyses used are average of 3 points for all minerals except chlorite in sample 65H73; nd, not detected; na, not analyzed. H2O was not analyzed, resulting in low oxide sums for tourmaline, muscovite, glaucophane, stilpnomelane, lawsonite, chlorite, and possibly titanite; C02 was not analyzed, resulting in low oxide sums for carbonate minerals] Detrital minerals Titanite1 Augitez Chromite3 Tourmaline Muscovite Sample 65H73 B44 65H73 B110 65H30 65H31 65H27 65H74 Si02 ........ 29.6 50.9 0.03 0.05 nd nd 36.3 50.5 A1203 ....... 1.09 4.28 35.4 9.86 2.94 8.30 31.7 28.8 Ti02 ........ 36.1 .43 .05 .22 nd nd .29 .28 V203 ........ .50 .05 .20 .24 .21 .21 .15 nd Cr203 ....... na .24 32.6 51.9 61.1 59.2 .03 na FeO ........ 1.24 5.81 17.1 33.4 28.6 23.5 6.73 3.15 MnO ........ 17 .12 .24 .57 .52 .41 .09 nd MgO ........ 10 15.4 14.6 2.33 5.38 7.43 8.05 2.50 ZnO ........ nd na na na .18 .16 na nd NiO ........ nd nd .10 nd nd .05 nd nd CaO ........ 28.2 21.9 nd nd .12 .13 1.34 .05 BaO ........ nd nd na na na na na .23 N320 ....... 03 .29 nd nd nd nd 1.81 .13 K20 ........ na nd na na na na nd 9.25 Sum .. 97.03 99.42 100.32 98.57 99.05 99.39 86.49 94.89 FeO ........ - - 15.1 29.1 23.1 20.8 - - Fe203 ....... - - 2.24 4.81 6.13 2.93 — - Metamorphic minerals Glaucophane Stilpnomelane Albite4 Lawsonite4 Chlorite5 Titanite6 Dolomite7 Calcite7 Aragonite7 Sample 651173 B44 65H73 65H73 65H73 65H73 65H3l 65H31 65H30 Si02 ........ 56.2 48.0 67.0 37.7 28.0 30.7 na na na A1203 ....... 8.50 7.36 20.7 31.4 18.0 5.46 na na na Ti02 ........ . 10 nd nd .06 .09 30. 8 na na na V203 ........ .05 .05 nd nd nd .47 nd nd nd Cr203 ....... na na na na na na na na na FeO ........ 15.3 24.1 .05 .54 24.6 1.00 6.08 .46 nd MnO ........ .14 1.87 nd .06 .69 nd .48 1.88 nd MgO ........ 9.05 5.84 .13 .08 15.5 .16 17.7 .52 .18 ZnO ........ nd nd na na . 10 nd nd nd nd NiO ........ nd nd nd nd nd nd nd nd nd CaO ........ 1.23 .89 .65 16.5 .13 28.5 29.3 53.1 54.4 BaO ........ nd .21 nd nd nd nd nd nd nd NaZO ....... 5.97 .72 11.0 .04 .03 .04 na na na K20 ........ .04 .59 .17 nd .09 .07 na na na Sum . . .. 96.58 89.63 99.70 86.38 87.23 97.20 53.56 55.99 856.93 1 Fragmented titanite in groundmass. 2 Augite occurs with quartz. 3 First two chromite analyses are of the most aluminous chromite and most chromium-rich chromite, respectively, analyzed in the graywackes. Third and fourth analyses are from carbonates. 4 Lawsonite occurs as laths within albite clast. 5 Pale green chlorite with Mg/(Mg+Fe+Mn) = 0.531; 4 points averaged. 5 Anhedral titanite grains within chloritized clast. 7 Calculated CO2 values, assuming ideal stoichiometry, are 46.4 weight percent for dolomite, 43.8 weight percent for calcite, and 43.5 weight percent for aragonite. 8 Sum includes 2.35 weight percent SrO. soft-sediment and tectonic deformation. Hein and Karl (1983, p. 35—36) and Hein and others (1987 , p. 210) also thought that the contacts were sedimentary. Hein and Koski (1987, p. 725) noted “gradational sedimentary contacts between the underlying sandstone and the radiolarian chert-argillite sections.” Subsequently they reported that “the field relations clearly show deposi- tional contacts between the graywacke sandstones and the rhythmically bedded chert-argillite sections” (Hein and Koski, 1988, p. 470). However, the undulatory and lenslike outcrop pattern (figs. 1A,B) of slivers of chert in graywacke may be the result of soft-sediment foundering 16 MICROBANDED MANGANESE FORMATIONS: PROTOLITHS IN THE FRANCISCAN COMPLEX, CALIFORNIA TABLE 6. —Chemistry and mineralogy of selected protoliths from the Buckeye deposit, California Coast Ranges [Chert, average of 35 cherts from the Ladd-Buckeye district (Hein and others, 1987); analyses by XRF, ICP, and INAA methods; metashale, average of 7 metashale samples, Ladd- Buckeye district (Hein and others, 1987); graywacke, average of 7 graywacke samples (B44, B110, 65H27, 65H35, 651-172, 651173, 65H74), Buckeye district; modes for these samples are given in table 3. W237—, sample number prefix assigned by Sample Control, Branch of Geochemistry. USGS. ICP (inductively coupled plasma atomic emission spectrometry) by H. Kirschenbaum; INAA (instrumental neutron activation analysis) by J .N. Grossman; FAAS (flame atomic absorption spectrometry) by H. Kirschenbaum; SQES (semiquantitative DC-arc emission spectroscopy) by Janet Fletcher; XRF-EDA (X-ray fluorescence with energy dispersive analysis) by R.G. Johnson; GAAS (graphite-furnace atomic absorption spectrometry) by M.W. Doughten; Sep (extraction preceded analysis) by MW. Doughten, B. Libby, and P.J. Aruscavage; Coul., coulometric determination; Pen., modified Penfield method; Grav., gravimetric determination; pct, percent; ppm, parts per million; ppb, parts per billion; —, chemistry not reported or not available or mineral not observed in Buckeye samples Mineral mode not reported for chert and metashale. All Buckeye samples have less than 2 ppm Rb by XRF and less than 2 ppm Se by INAA. Estimate of mineral modes from visual examination of X-ray powder diffraction patterns] Sample B50 B64 B112 BS4 B95 B104 651179 Chert Metashale Graywacke W237— 507 503 506 505 511 510 509 SiO2 ........... pct ........ ICP ......... 9.4 38.7 17.0 33.2 16.1 8.3 22.6 94.39 58.13 67.9 A1203 .......... pct ......... ICP ......... .40 .21 2.14 3.25 1.25 .070 .047 1.71 16.0 12.8 F62031 ......... pct ......... INAA ....... .187 .164 1.47 2.15 .892 .189 .095 1.208 8.58 5.3 MgO .......... pct ......... ICP ......... 1.2 .94 3.83 9.28 2.55 .66 2.28 .59 3.21 2.5 MnO ........... pct ......... ICP ......... 60.4 31.9 47.6 35.8 64.9 79.5 63.4 .21 .27 .22 CaO ........... pct ......... ICP ......... .32 4.27 1.68 1.04 .18 .12 .04 .12 .89 1.6 NaZO .......... pct ......... INAA ....... .008 .015 .058 .023 .015 .007 .009 .28 1.52 4.4 K20 ........... pct ......... FAAS ....... <1 <1 <1 <1 <1 <1 <1 .34 4.08 1.0 002 ........... pct ......... Coul ......... 23.6 23.0 19.8 3.09 5.06 4.69 .66 - - .25 H20+ ......... pct ......... Pen. ........ 3.2 .3 4.6 9.0 3.7 2.7 7.5 2.72 26.0 33.3 H20— ......... pct ......... Grav. ....... .1 .1 .9 1.8 .1 .1 .4 - - - P205 ........... pct ......... ICP ......... <.06 <.06 .12 .37 <.06 <.06 <.06 .05 .35 .09 Ti ............. ppm ........ ICP ......... 93 81 370 970 390 72 63 419 5215 3342 V ............. ppm ........ ICP ......... 91 <5 1200 480 470 460 140 20.4 128.3 127 Co ............ ppm ........ INAA ....... 6.61 1.72 22.1 13.1 26.2 8.8 5.26 8.0 27.8 16.6 Ni ............. ppm ........ ICP ......... 170 79 350 150 840 650 740 22.4 105 53 Cu ............ ppm ........ ICP ......... <5 11 110 64 59 8 <5 44 130 21 Zn ............ ppm ........ FAAS ....... 530 110 320 220 1300 2700 630 24.8 105.4 92 W ............. ppm ........ Sep, ICP .... 40 <1 <1 1.7 22 30 89 - - <1 Th ............ ppm ........ INAA ....... .214 .18 .97 2.26 1.48 .180 .073 - — 6.04 U ............. ppm ........ INAA ....... .55 <.3 1.23 .59 .84 1.07 1.05 - - 1.84 Te ............. ppm ........ Sep, GAAS . . .03 <.02 .13 .13 .14 <.02 <.02 - - - Cr ............. ppm ........ GAAS ....... <20 14 7.0 16 12 2.3 7.5 10.6 89.4 170 As ............ ppm ........ FAAS ....... 94 5.0 63 110 120 190 210 — - 10 Cd ............ ppm ........ Sep, GAAS .. 1.5 .56 1.5 .43 .64 1.5 3.6 - - - Sb ............. ppm ........ INAA ....... 12.0 .122 1.62 14.0 6.01 22.6 24.1 - - 1.31 Mo ............ ppm ........ Sep, ICP . . . . 36 1.2 4.0 740 3.5 73 29 — — <2 Be ............ ppm ........ Sep, GAAS .. <2 <2 .28 .52 .43 .25 .78 - - .96 B ............. ppm ........ SQES ....... 71 <3.2 230 580 390 100 74 - - — Li ............. ppm ........ Sep, FAAS .. <50 12 12 42 12 <50 <50 12.9 36.3 42 Sc ............. ppm ........ INAA ....... .995 .419 2.45 5.51 4.20 1.547 1.06 - - 14.9 Sr ............. ppm ........ ICP ......... <2.5 120 33 27 3.0 <2.5 <2.5 - - 156 Ba ............ ppm ........ XRF-EDA. . . 21 5200 70 400 74 <5 <5 214 870 337 Zr ............. ppm ........ XRF-EDA. .. <5 <5 <5 50 33 25 <5 — - 137 Hf ............. ppb ......... INAA ....... 106 450 331 830 490 177 <200 - - 3420 Nb ............ ppm ........ Sep, ICP <1 <1 <1 2 <1 <1 <1 - - 8 Ta ............. ppb ......... INAA ....... 17 16 90 237 88 <20 <100 - - 624 Y ............. ppm ........ ICP ......... <5 <5 <5 15 <5 9 <5 6.1 37.4 16 La ............ ppm ........ INAA ....... .71 1.59 8.2 14.0 3.26 14.7 .82 - - 20.0 Ce ............ ppm ........ INAA ....... 1.66 1.97 12.2 26.9 14.3 4.5 <.2 - - 36.9 Nd ............ ppm ........ INAA ....... <4 <6 8.0 15.2 3.9 12.6 <7 — - 16 Sm ............ ppm ........ INAA ....... .248 .454 1.91 2.99 .84 3.15 .117 - - 3.60 Eu ............ ppb ......... INAA ....... 57 118 420 690 195 782 <90 - - 818 Tb ............ ppb ......... INAA ....... 22 79 287 422 196 526 35 - - 473 Ho ............ ppb ......... IN AA ....... <600 <700 <900 670 <900 940 <900 - - - Yb ............ ppb ......... INAA ....... 151 550 860 1230 610 1460 810 - - 1700 Lu ............ ppb ......... INAA ....... 28 86 142 226 138 246 169 - - 256 1 Total Fe reported as Fe203. 2 Loss on ignition. 3 Average of total water content of 6 samples, excluding B44; for which there was insufficient sample for analysis. REGIONAL GEOLOGY 17 TABLE 6. —Chemistry and mineralogy of selected protoliths from the Buckeye deposit, Cahform'a Coast Ranges—Continued Sample B50 B64 B112 B84 B95 B104 65H79 Chert Metashale Graywacke W237— 507 503 506 505 511 510 509 X-ray modes Quartz .......................................... - 35 2 - - - - Mn—carbonate .................................... 80 65 70 25 25 15 2 Caryopilite ...................................... - — 25 65 20 2 Chlorite/smectite ................................ - - 5 5 - - - Gageite ......................................... 20 - - - 45 25 90 Hausmannite .................................... — - - - - 60 10 Braunite ........................................ - - - - 55 - - Barite .......................................... - - 1 - - - - 4 Estimate based on thin-section optics; gageite not observed in X-ray pattern. or tectonic dismembering. We conclude that transitions between graywacke and chert-metashale sequences did occur in the sedimentary environment but that some of the complicated smaller scale features may be of later origin. Chert layers consist of more than one lamination and form beds that are commonly 2 to 20 cm thick. Chert beds are separated by metashale beds (or interbeds), which are several millimeters to 10 cm thick (fig. 2A). In a general way, the thicknesses of the metashale interlay— ers are correlated with the color of the chert. Interlayers associated with red chert are comparable in thickness to the red chert layers, interlayers associated with green chert are distinctly thinner than the chert beds, and the metashale partings within white and gray chert beds are insignificant (fig. 23), resulting in massive character. Within a lens of chert and metashale layers, individual beds of chert are of uniform thickness rather than thickening in the noses of tight folds or thinning as they approach the lateral outcrop margin of a lens. In unusual cases, individual beds bifurcate or terminate abruptly (see Taliaferro and Hudson, 1943, their figs. 3—4). These observations, combined with the assumption that color was associated with purity of chert, led early students, including Huebner (1967), to think that the rhythmic layering developed during diagenesis. The recognition of laminations and graded bedding within individual layers of chert (Hein and others, 1987a, p. 213) suggests that these chert layers are siliceous turbidites (see N isbet and Price, 1974). Folding in the cherts is spectacular (see Huebner, 1967, figs. 11—8 and 11—10). Sharp folds are common; units of chert on outcrop scale exhibit uniform and symmetric chevron folding (see Johnson and Ellen, 1974). In other places, several sequential chert layers are contorted into S—shapes, yet adjacent layers are not affected. Individual chert layers pass smoothly and continuously about the noses of folds. There is no cleavage. These latter features are characteristic of soft-sediment deformation of layers that remained intact. The chert beds are now out by quartz veins that do not extend into the adjacent meta- shale layers. Rare syneresis (shrinkage) cracks in indi— vidual chert layers and a brecciated chert reef in which brown chert fragments are engulfed by white silica were noted by Huebner (1967). However, we have the impres- sion that there is little evidence for through-going frac- tures through which fluids could move perpendicular to layering, although the metashale layers or their contacts with the adjacent chert might provide pathways through which fluids could move parallel to the bedding. Red cherts have a framework of spherical or elliptical skeletons of radiolaria set in a matrix of radiolarian fragments, iron oxides and hydroxides, and clays. Although the clays may represent a slow yet continuous background deposition of fine clastic detritus, coarse detritus of the kinds found in the graywackes is absent. In contrast to the red chert layers, the green, gray, and white cherts contain only a small proportion of oxide- hydroxide-clay component, and skeletal debris is pre- served only as ghosts in microcrystalline quartz. Within chert layers of all colors, laminations are indicated by variable concentrations of opaque “dust.” The north Buckeye orebody is enclosed in white chert (locally stained black by supergene manganese oxides) that lacks the metashale interbeds and therefore is described as massive. Actually, the massive chert is composed of chert laminations or, adjacent to the ore— body, chert interlaminated with the manganese silicates santaclaraite, caryopilite, and taneyamalite. These lam- inations impart a fissility that is particularly evident at the surface, above the north orebody. The massive chert reef and the conformably enclosed orebody are folded in an S-shaped kink without major fractures perpendicular to the chert-orebody contact (see Huebner, 1967, fig. II-lO; Taliaferro and Hudson, 1943, fig. 8). The siliceous phase in all cherts and cherty materials examined by us is quartz. Hein and Koski (1987) reported cristobalite-like peaks in X-ray diffraction patterns of silica samples that were associated with manganese. They concluded that emplacement of manganese within 18 MICROBANDED MANGANESE FORMATIONS: PROTOLITHS IN THE FRANCISCAN COMPLEX, CALIFORNIA FIGURE 2,—Representative chert from near the Buckeye deposit. A, Rhythmic gray chert. Some chert beds are clearly composite. The chert layers are thick relative to the layers of metashale. Scale is 16 cm long. B, Surface outcrop of north orebody in “massive” white chert. The white chert is actually laminated and has some fissility. Width of open cut about 5 In; view is eastward. C, Sample 65H66. Laminated chert from contact with orebody, southeast wall of cut. Laminations are parallel to regional layering in the chert reefs and are caused by varying concentrations of manganese silicates, rhodochrosite, and “dust” (less-than-Z-pm particles of clays or oxy- hydroxides). The white bleached zones are channels through which fluids passed, leaching manganese minerals and dust and leaving behind pure chert that is more coarsely crystallized than the impure, laminated chert. 1 I 1m s i! agrmc 1 REGIONAL GEOLOGY 19 the sedimentary pile arrested the transformation of opal to quartz. In contrast, we found no evidence of any relic opaline phases in the rhythmic chert, in massive chert, in chert interlayered with manganese minerals at the mar— gin of the orebody, or intimately intermixed with man- ganiferous minerals within the orebody. In the ore lens, much (presumed) skeletal debris has been replaced by rhodochrosite or caryopilite, compositions that have been confirmed by energy—dispersive X-ray analysis.The best preserved textures are “necklaces” of anhedral carbonate crystals that lack the orderly arrangement of skeletal plates of organisms; these necklaces may not originally have been siliceous. In X-ray diffraction pat- terns, quartz is well crystallized. The quintuplet of peaks resulting from the (122), (203), and (301) reflections is generally well resolved, and the few cases of poor resolution can be attributed to admixed phases. In particular, the (030) reflection of rhodochrosite coincides With the (212) reflection of quartz. The crystallinity index a/b (table 7) based on these quartz reflections, which is a qualitative measure of grain size, structural order, and goniometer slit-widths and alignment, averages about 10 on a scale of 11.6. Thus, our values are greater than the values of 6 to 7 (on the scale'of 10 proposed by Murata and Norman, 1976) reported by Hein and others (1987). The existence of such well-crystallized quartz is inconsis- tent with the presence of opaline phases. In a final attempt to confirm the report of opaline silica, we dissolved the carbonate from 11 samples, using 2 N HCl, but found no reflections attributable to cristobalite or tridymite. Mineral impurities found in the cherts and quartz-rich materials are rhodochrosite, taneymalite, caryopilite, chlorite, smectites with spacings from 15A to 25A, acmitic clinopyroxene, and iron oxyhydroxide (table 7). The discovery of chert and volcanism in modern deep ocean basins has led to the use of major-element compo- sitions to distinguish between pelagic (organic), detrital (abiogenic), and hydrothermal sources of silica (Adachi and others, 1986; Yamamoto, 1987). By this reasoning, the hydrothermal component is Fe- and Mn-rich and Al- and Ti-poor, the detrital component is Al- and Ti-rich, and the pelagic component has low concentrations of all four elements. Hein and others (1987) presented average compositions for 35 cherts, 4 argillaceous cherts, 7 sili- ceous argillites, and 7 argillites (metashales) from the Ladd-Buckeye district. The compositional contrast of these rocks with Franciscan cherts and shales deposited above metabasalt is striking (Yamamoto, 1987). At the Buckeye, the cherts appear to be pelagic with a minor detrital, rather than hydrothermal, component. The interbedded metashales have A1203 and TiO2 contents that are similar to those of average shales and gray- wackes; thus the Buckeye metashales appear to have a significant detrital component, perhaps related to the finest fraction of the graywacke. Later we will show that the rare—earth-element (REE) patterns of the cherts and shales mimic the patterns for the graywackes, reflecting an REE-rich detrital component. However, because the detrital (graywacke) component tends to be REE- enriched, even a small proportion of detrital component could obscure the contribution of a hydrothermal compo- nent to the REE pattern for the chert or metashale. Complete trace-element data for all three rock types might permit better estimates of the proportions of detritus. PROVENANCE Sediments of the Grummett broken formation, host of the Buckeye manganese deposits, were predominantly elastic, both biogenic and abiogenic. The metashale inter- beds associated with the chert may in part represent a chemically precipitated component, perhaps of hydro- thermal origin, but the proportion of such a component, if present, is uncertain. The biogenic flux consists of radiolarian debris and whatever pelagic contribution is contained in the metashales and thus was ultimately derived from a marine water column. The abiogenic flux is represented by the conglomerates, metagraywackes, and associated shales, and a background component of clays that formed the metashales. Clasts of chert, shale, porphyritic volcanic rocks, plagioclase, coarse quartz, and chromite found in the conglomerate and graywacke cannot have come from a single lithologic source. Three or four sources are needed: one of low metamorphic grade, perhaps Within the Franciscan Complex itself; a quartz-bearing igneous or metamorphic terrain, perhaps a continental margin or magmatic arc; an ultramafic (or ophiolitic) terrain that could provide the detrital chro— mite; and an ultramafic to mafic source that could provide the iron— and magnesium-rich graywacke matrix. REGIONAL METAMORPHISM The presence of lawsonite + quartz + albite + chlorite and minor glaucophane, combined with the absence of zeolite, zoisite, and epidote, indicates metamorphic con- ditions between 175 and 300 °C and greater than 4 kbar (fig. 3; see also Cotkin, 1987). Because aragonite is known to transform readily to calcite at low pressure, the presence of calcite within the Grummett broken forma- tion is not diagnostic. However, the presence of aragonite-bearing veins in the graywacke near the boundaries of the Grummett broken formation is an indicator of the minimum pressure achieved in the veins 20 MICROBANDED MANGANESE FORMATIONS: PROTOLITHS IN THE FRANCISCAN COMPLEX, CALIFORNIA TABLE 7. —Characterization of siliceous samples from the Buckeye deposit, California Coast Ranges, by X-my powder diflmctometry [Color terms from Goddard and others (1970). Estimated intensities of X-ray powder diffraction intensities: S, strong; M, moderate or moderately; W, weak; VW, very weak; -, not observed. a/b, crystallinity index explained in the text] Sample B10 B64 B25b B72 B74 B77 B93 Color Moderate Pink with Very pale Pale red Pink, brown, Pale brown Pale olive yellowish gray veins orange and gray brown Rock type Chert Carbonate Vein Chert Carbonate Chert Argillite Quartz .................. S M M MS M S S Chlorite ................. - - - - - - M Caryopilite .............. MW - - - - - - Smectite ................ W - - - VW VW - Biotite .................. - - - - - — MW Muscovite ............... - - - - - — MW Acmitic pyroxene ........ - - - - - - MW Rhodochrosite ........... VW S W S M - Ca—Mn carb .............. - - — - 7 W - - Hematite ............... - - - ? W - ‘3 W - Other ................... - - - - - ? W - a/b ..................... 10.7 6.4 7.4 9.8 (1) 10.2 10.0 Sample B96 B97a 65H23 65H24 65H66Aa 65H66Ab 65H66Ac Color Dark Grayish Light Pinkish Pinkish Olive gray Dark yellowish orange brownish gray gray yellowish brown and pink gray brown Rock type Carbonate Carbonate Chert Chert Chert Chert Chert Quartz ................... M M S S S S S Chlorite .................. VW — - - - - — Taneyamalite ............. - — - - - MW MW Smectite ................. W W - - - W - Acmitic pyroxene ......... MW - - - - - - Rhodochrosite ............ S S - - W - - Other .................... W - - - - W - a/b ...................... 10.0 (I) 11.5 9.0 10.0 11.1 12.0 Sample 65H67 65H68a 65H68b 65H69a 65H69b 65H690 65H69d Color Very light Pale yellowish Dark yellowish Medium gray White Light olive Brownish gray brown brown gray gray Rock type Chert Chert Chert Chert Chert Chert Chert Quartz ................... S S S S2 S S S Taneyamalite ............. - - - MW - W W Smectite ................. - W VW W W - - Acmitic pyroxene ......... - W - - - - - Rhodochrosite ............ - - W - MW — W Other .................... - ? W - - - ~ - a/b ...................... 11.4 9.5 10.5 8.1—8.8 10.1 11.1 9.4 Sample 65H69e 65H69f 65H71 65H76a 65H76b 65H76c 65H171 Color Speckled Brownish Very light Pale yellowish Pale reddish Dark Brownish yellowish gray gray brown brown yellowish gray gray brown Rock type Chert Chert Chert Chert Chert Chert Chert Quartz ................... S S S S S S S Chlorite .................. - - - - - VW W Taneyamalite ............. - W - - - - - Smectite ................. - - W ? W - — Acmitic pyroxene ......... — - MW MW MW - VW Rhodochrosite ............ W W - — - - - , a/b ...................... 11.4 11.6 10.2 10.3 10.2 10.1 10.65 1 Unable to determine crystallinity index because of interference by (030) peak of rhodochrosite. 2 Weak reflection present at 218° is too sharp for opal. PROTOLITHS 21 12 10— Pressure (kbar) 250 350 Temperature (°C) FIGURE 3.—Pressure-temperature grid for metagraywacke. All reac- tions are written with the high-temperature assemblage on the right side of each equation. 1, heulandite = lawsonite + quartz + fluid. 2, jadeite + quartz = low albite. 3, aragonite = calcite. 4, lawsonite + glaucophane = epidote + chlorite + albite + quartz + fluid. 5, lawsonite + albite = zoisite + paragonite + quartz + fluid. 6, glaucophane + clinozoisite + quartz + fluid = tremolite + chlorite + albite. In the vicinity of the Buckeye deposit, the assemblage is lawsonite + quartz + albite + chlorite :- glaucophane. Aragonite is nearby. Pumpellyite, jadeite, and members of the zoisite group are absent. Pressures of 4 to 7 kbar at 180 °C or 10 kbar at 300 °C are possible. We favor temperatures of no greater than 175—250 °C (stippled area) for the Buckeye deposit because relic gel-like mate- rials are present and a pervasive metamorphic fabric did not develop. Curves largely after Cotkin (1987, fig. 3); the calcite-aragonite curve is from Johannes and Puhan (1971). and tentatively is regarded as an indicator of minimum pressure within the Grummett unit, 5 kbar at 180 °C (Johannes and Puhan, 1971). The occurrence of jadeite + albite + quartz in other samples from within the Grum- mett broken formation (Raymond, 1973a,b) suggests that the peak metamorphic pressure might have been 7—8 kbar (at 180 °C). Although temperature and pressure estimates of such assemblages are uncertain, the preser- vation of palimpsest features, the development of only an incipient foliation, and the disordered state of the sheet silicates suggest metamorphism at the low-temperature end of the range of conditions, perhaps 150 to 200 °C and 7 to 8 kbar. Maintenance of relatively lOW temperatures at such high pressures requires a low geothermal gradi— ent. If hydrothermal convection of the kind proposed by Lonsdale (1977) or Crerar and others (1982) was involved in the deposition of manganese at the Buckeye, meta- morphism could not have occurred in the presence of the hydrothermal heat engine. This separation of processes could have been brought about by allowing the heat source to decay with time or by moving oceanic crust with its mantle of sediments and manganese deposits away from the heat source before subduction. PROTOLITHS The goal of this study has been to look back through metamorphic and diagenetic overprints to characterize the original sediments that resulted in the north Buckeye and, by analogy, other orebodies of the Franciscan Complex. Without knowledge of the original nature of these materials, it is impossible to deduce their origins. By volume, four phases (rhodochrosite, caryopilite, braunite, and hausmannite) compose virtually the entire orebody. Ten phases form monomineralic or almost monomineralic layers with sedimentary characteristics. Many of these phases also occur as mixtures that form other layers. We are confident that six kinds of layers and laminations have a sedimentary origin and thus represent compositions, if not mineralogies, of distinct sedimentary components, albeit now dehydrated and to some extent recrystallized. Two more minerals probably represent sedimentary components. Each of these sedi- mentary protoliths is named on the basis of its charac- teristic mineralogical component: chert, rhodochrosite, caryopilite, chlorite, hausmannite, braunite, and perhaps taneyamalite and gageite. (Nominal formulas for these minerals are given in table 1.) A layer rich in diopsidic acmite also has sedimentary characteristics. In addition, talc occurs as a green lens in brown chert (B10) but is too rare to be considered a component that influences the composition of the orebody. In the following paragraphs, we describe the occurrence of these materials, making reference to the series of photographs arranged to show increasing disruption of original layering (fig. 4). Seven homogeneous layers were sampled to yield 25- to 50—g splits for initial major- and trace-element analyses. The large sample size, in some cases, prevented removal of a pure sedimentary component. These seven samples (table 6) represent rhodochrosite, caryopilite, gageite, hausmannite, and braunite protoliths. Layers of chlorite and taneyamalite are too thin and of insufficient lateral extent to sample for bulk chemical analysis (1 gram) Without contamination by other protoliths and are chem- ically characterized only by electron microprobe tech- niques. Average chert and metashale analyses can be found in Hein and others (1987) and are summarized in table 6. In describing the protoliths, we give the charac- teristic X-ray reflections so that later workers will be encouraged to identify these phases in fine-grained mix- tures, using X-ray powder diffractometry. We hope that our observations will be found to be generally applicable to many deposits of the Franciscan Complex and else- where. CHERT Chert surrounds the orebody but is not interlayered with the other protoliths. From this fact, we infer that 22 MICROBANDED MANGANESE FORMATIONS: PROTOLITHS IN THE FRANCISCAN COMPLEX, CALIFORNIA PROTOLITHS 23 FIGURE 4.—Slabbed hand specimens of different protoliths from the Buckeye deposit, California, arranged to show increasing degree of soft‘sediment deformation. Following the scale of Raymond (1984), coherent units are disrupted, then dismembered, and finally only relics of beds are seen engulfed in a once-fluid matrix to form a melange. A, Sample BS7. Alternating layers of caryopilite, haus— mannite disseminated in rhodochrosite, and rhodochrosite. Layering is still fairly coherent despite late polymineralic veins and recrystal- lization of rhodochrosite (grayish-pink pods). B, 65H79. Thick layer of gageite (black) in massive hausmannite (dark gray). Thin veins of gageite originated in the thick layer. C, B25. Coherent layers of caryopilite can be traced across hand specimen despite brecciation and the presence of late white veins of quartz, rhodochrosite, smectite, and relic santaclaraite. D, B26. Alternating layers of caryopilite (dark gray) and rhodochrosite. Layers are still coherent, even though much of the carbonate has recrystallized to spherules. E, BS4. Coherent interlaminations of chlorite, rhodochrosite, and caryopilite (top). The thick caryopilite layer (bottom) is internally brecciated, making it impossible to follow individual bedding lamina- tions across the hand specimen. F, B81—1. Disrupted braunite—rich layers (dark gray) in carbonate-rich material (light gray). The slightly displaced breccia fragments can be mentally and visually rearranged, permitting some layers and laminations to be traced across the specimen. G, B53. Layers of braunite (black), hausmannite (grayish red), and rhodochrosite (grayish pink); texture is intermediate between disrupted and dismembered. Upper and lower surfaces of individual layers and laminations are indistinct. Displacement of brec- cia fragments is so great that reconstruction into continuous layers is not certain, but compositional contrast clearly indicates orientation of original bedding. H, 65H86. Dismembered layers of gageite (black) and rhodochrosite (grayish pink) in hausmannite and rhodochrosite (grayish red). Layer contacts are indistinct; reconstruction of the layers is not possible. Compositional contrast still suggests orientation of bedding. 1, B58. Gray rhodochrosite protolith, with slightly grumous texture, and gageite (black). We interpret this specimen originally to have been interlayered rhodochrosite and gageite. Disruption has been so intense that the orientation of original layering is not evident, giving it a massive nature. J, B78. Massive micromelange of rhodochrosite (gray- ish pink), hausmannite disseminated in rhodochrosite, caryopilite, and braunite (black). Neither individual layers nor the orientation of bedding is clear. Scale in centimeters. 24 MICROBANDED MANGANESE FORMATIONS: PROTOLITHS IN THE FRANCISCAN COMPLEX, CALIFORNIA FIGURE 4. —Continued. chert does not occur within the ore lens. Massive chert contains manganiferous laminations (1 to 5 mm thick) adjacent to the orebody, but the laminations are nonman- ganiferous away from the contact. The distinction between laminae is based on impurities. The least pure chert laminations are made cloudy by opaque “dust” (presumably oxides and hydroxides) and by smectite. Impure layers are characteristically fossiliferous, have fine—grained quartz, and, adjacent to the orebody, may contain bundles of manganese-silicate fibers. The pure layers are devoid of dust and smectite, do not preserve fossils, are composed of more coarsely crystallized quartz, and may contain irregularly shaped or rhombo— hedral bodies of carbonate. In the transitional interval of at least several centimeters surrounding the north ore- body, the chert contains thin laminations 0f manganifer- ous sheet silicates, which cause partings, and some of the chert contains santaclaraite (figs. 5C,D). Chert lamina- tions are coherent to disturbed; soft—sediment deforma— tion has not been extensive. Impure laminae are transected by irregularly shaped bleached zones of well- crystallized pure chert; the boundaries between impure laminae and bleached zones are gradational (fig. 20). These bleached zones mark the pathways by which fluids escaped from the soft sediment. Rarely, laminations have been disrupted perpendicular to layering (fig. 5D), as if fluid had pushed through the laminations. This toe-like texture was probably formed by escaping fluids during compaction and diagenesis. Veins of coarsely crystallized quartz have sharp contacts, rarely contain bundles of manganese silicate fibers, and were clearly formed after the siliceous sediment was indurated. Although there is evidence that solutions removed man- ganiferous components from the chert (figs. 20, 5C), there is no indication that the manganiferous laminations were introduced by vein-forming processes (fig. 50). Within the chert, these manganiferous laminations appear to be primary sedimentary features. The average chemical compositions of chert and met- ashale in the Ladd—Buckeye district (Hein and others, 1987) are compared with the compositions of the manga- niferous protoliths in table 6. The major distinctions are that chert has a smaller Mn/Fe and, in terms of absolute concentrations, more Na and K. There is less Mn, Mg, Ca, 002, Ni, V, and Zn in the chert than in the seven manganiferous samples analyzed, but, because the large amount of silica tends to dilute the concentration of all other constituents, the smaller values are not unex- pected. Clearly, the chert is not mineralized. The REE patterns of the chert and Mn sediments are similar (see fig. 7). In general, the Ce anomaly (relative to seawater) is distinct in chert. The analyses of metashale are dominated by a fine clastic sediment component (represented by 0.875 PROTOLITHS 25 weight percent Ti02). Copper and nickel concentrations exceed the small amounts expected of graywackes (Tay- lor and McLennon, 1985) and could be due to Mn—poor mineralization. The REE patterns of the metashales are similar to, but more enriched than, those of the gray- Wackes (fig. 7A). Ce anomalies are prominent in both. This similarity suggests that the pattern is being domi— nated by the finest fraction of the turbidites; any contri- bution to the REE pattern that resembles the patterns of Buckeye ores (fig. 7A) is obliterated by the presence of the elastic material. Hein and others (1987) and Hein and Koski (1987) argued that the Buckeye orebody formed by the replace- ment of chert by rhodochrosite and suggested that the silica released by this process contributed to the forma- tion of the massive cherts. It is important to realize that many of the laminations in the massive chert contain relic skeletal debris and that some of these laminations pre- serve frameworks supported by flattened radiolarians. We conclude that most or all of the laminations were originally composed of the debris of pelagic organisms with variable amounts of smectite and oxide-hydroxide “dust.” Thus, a direct major flux of silica from the site of rhodochrosite deposition to the site of massive chert accumulation is precluded, making it unlikely that mas- sive chert could form as a direct consequence of ore formation. Further, if an orebody with the size and manganese concentration of the Buckeye were formed by replacement, one might find a halo of replacement fea- tures about the orebody. There are no such features. The manganese components that occur in massive chert appear to have been deposited With the massive chert. RHODOCHROSITE PROTOLITH Manganese carbonate appears to be the most abundant mineral at the Buckeye deposit, but this abundance may be in part an artifact of the selective mining of higher grade oxide-rich (hausmannite and braunite) ore (Hueb- ner, 1967). Carbonate protolith is best preserved in samples B42, B50, B58 (fig. 41), B103, and B107; it now consists of extremely fine-grained, medium—gray rho- dochrosite that is so turbid in thin section that the characteristic optical properties of carbonate cannot be recognized (fig. 5A). The rhodochrosite protolith can be identified by the (012), (104), and (018, 116) reflections at 242°, 31.4°, and 518° in XPD patterns made with copper radiation. The (104) of rhodochrosite is so strong that it is a sensitive indicator of as little as 2 percent carbonate in mixtures. However, the (012) reflection overlaps with the (002) of caryopilite. Partial recrystallization to coarser, lighter gray rhodochrosite results in a grumous texture with distinct optical properties in thin section. More advanced recrystallization results first in light- gray carbonate and loss of the patchy texture (as in samples B17, B28, B108) and ultimately in pink rhodo— chrosite (B64, B69, B73, B74, and B98). Small segrega- tions of clear yellow, sensibly isotropic gel-like material (B50, figs. 6G,H) occur within the gray carbonate. The carbonate forms a breccia of equant to tabular bodies, 0.5 to 3 cm in size and with irregular to serrated margins, that are separated by selvages of gageite (B45, fig. 5A; B50, B58, B108). We interpret the finest grained dark- gray carbonate to be relic primary carbonate. The yellow bodies are relic gel-like materials, residues of a siliceous component that presumably once was more uniformly distributed throughout the carbonate. Small amounts of smectite similarly occur in several samples. The gel-like material may have imparted a sufficiently cohesive qual— ity to the fine—grained carbonate (micrite) that it frac- tured into equant bodies, about Which gageite flowed. In other samples, the micrite flowed about broken layers of caryopilite (B54) and of braunite and gel-like material (B71b, figs. 6A,B). The chemistry of the rhodochrosite protolith, repre- sented by B50 (table 6), illustrates the enrichment of manganese relative to iron and titanium (and most other major rock-forming oxides). The mineralogy consists of rhodochrosite, gageite, and devitrified or partly devitri- fied gel-like material of chlorite composition and is con- sistent with the bulk chemistry. The 002 concentration is 23.6 percent by weight, compared with 38 percent for pure rhodochrosite. Al and Mg are associated with yellow, partially devitrified gel-like material of chlorite composition, and silica is contained in gageite and the gel. Zn, Mo, Ni, As, Ti, B, and W are the only trace elements that are present in concentration greater than 25 ppm. Compared with other protoliths from the Buck- eye deposit, rhodochrosite has low concentrations of REE (fig. 7B). The Ce anomaly is not well defined, perhaps due to the fact that Nd values for carbonate were below the detection limit. However, Sm values are higher than would be expected if the Ce anomalies were prominent. In comparison with many manganiferous marine sediments, particularly most ferromanganese nodules and pavements, the carbonate and other proto- liths from the Buckeye deposit contain small concentra- tions of Co, Ni, Cu, and Ba. CARYOPILITE PROTOLITH Caryopilite is found in claylike masses (B38; B84, fig. 4E), weakly foliated layers (B20, fig. 58; B25, fig. 4C), and thin, well-foliated layers (B26, B54) and fragments of layers (B24, B83). The most poorly crystallized caryopil- ite is claylike (or rarely gel-like) and represents de— watered protolith. Caryopilite is identified by its (001), (002), (20—1, 130), and (20—2, 131) X-ray reflections at A FIGURE 5.—-Characteristic microscopic features of protoliths in the Buckeye deposit, California. A, Sample B45. Serrated septa of dark-red to opaque (black in photograph) gageite surround irregular fragments of extremely fine grained rhodochrosite mud. This texture is presumably caused by soft-sediment deformation of interlaminated carbonate and gageite, not by late-stage hydrothermal veining. B, B20. Interlaminated caryopilite (c) and taneyamalite (t). Taneyama- lite is squeezed from primary layer and intrudes caryopilite layers. Note presence of transparent caryopilite, designated cg. C, 65H76. Brecciated santaclaraite—bearing chert cut by quartz veins. The 120°, 243°, 320°, and 358° CuKa, respectively, in accordance with the indexing by Guggenheim and others (1982). We also observed broad reflections at 56.5° and 580°. In thin section, the relatively high birefringence of claylike caryopilite distinguishes it from chlorite. Evi- dence that some caryopilite may have originated as gel-like material is the occurrence of transparent layers of clay-sized particles that may represent devitrifying gel (B20, fig. 5B) and one occurrence of isotropic gel-like material with caryopilite composition (B91, fig. 8D). In claylike mixtures, the presence of caryopilite is best indicated by its X-ray pattern or composition. The cary- opilite protolith commonly occurs as 0.5- to 3-mm layers interlaminated with carbonate or, less commonly, with taneyamalite or chlorite. Ghostlike outlines of spheroidal skeletal debris are present, and transparent orange— brown ovoids (skeletal casts of radiolaria?) are rare (B38). Dismembered caryopilite layers are engulfed by carbonate (B24), caryopilite-carbonate mixtures (B39), . i. , y. u».- 7 ,1 f‘ 'a. u ' _.C , . m4; .«z' "9&9 new B abundance of santaclaraite is controlled by bedding laminations, and this mineral clearly was not introduced by the later, crosscutting vein fluids. D, 185910. Dewatering texture in laminated chert. Dark layers are manganiferous sheet silicates (top); discrete crystals are san- taclaraite. Fluids moved perpendicular to layering, cutting across earlier manganiferous laminations. Compare with similar texture in braunite, in E. E, BS5. Dewatering texture in braunite, similar to dewatering texture in chert (compare with D). Reflected light. F, B95. Thin laminations with braunite composition. Note also the coarse euhedra of braunite. or taneyamalite (B20, fig. 53; B29) or form spectacular intraformational microbreccias (B83; B84, fig. 4E). The composition of the caryopilite protolith is repre- sented by B84 (fig. 4E). The analyzed split consists of caryopilite with minor rhodochrosite and chlorite or smectite. Again, the mineralogy is consistent with the chemistry (table 6): Al and Mg reflect the chlorite/smec- tite and 002 the carbonate. The FeO content is greater in B84 than in the carbonate protolith (B50) and reflects the presence of caryopilite. The value for M0, 740 ppm, is unusually high and is due to intimate intergrowths of fine-grained (less than 5 mm) flakes of molybdenite and caryopilite. This intergrth has a patchy distribution but is not obviously related to the late veins that cut the sample (fig. 4E). The increased Ba value, relative to B50, is probably due to postdepositional replacement by bar- ite. Although barite has not been found in thin sections of B84, it occurs as veins in B29 (caryopilite), B31 (dolomite near contact between Grummett and Sulphur Gulch bro— PROTOLITHS 27 28 MICROBANDED MANGANESE FORMATIONS: PROTOLITHS IN THE FRANCISCAN COMPLEX, CALIFORNIA FIGURE 6.—Gel-like and partly recrystallized materials from the Buckeye deposit, California. A, B71b. Braunite (top) and fragments of gel-rich layers (bottom) displaced by fractures and engulfed in rhodochrosite. B, Enlargement of previous photograph. The frag- ments consist of clear, colorless, isotropic gel-like material (white; table 8, analysis 6) interlaminated with braunite (black) and rhodo- chrosite (gray). Mottling of the carbonate matrix is caused by admixed yellow gel-like material. Both gel-like materials have chlo- rite composition. C, B84. Gel-like laminations (fig. 4E, top) having chlorite composition (white) interlayered with caryopilite (brown) and carbonate (brownish gray). Plane-polarized light. D, Detail under crossed nicols. The margins of the gel-like layer have been replaced by caryopilite and the interior of each layer has recrystal- lized to chlorite. E, B24. Fragment of pinkish (yellowish in photo- graph), transparent, gel-like layer (table 8, analysis 4), now surrounded by carbonate and taneyamalite. Plane-polarized light. F, Detail, crossed nicols. The gel-like material is slightly recrystallized to chlorite and contains tiny rhombohedra of rhodochrosite. G, B50. Residual pale-yellow gel-like material of chlorite composition (table 8, analysis 3) surrounded by gageite and rhodochrosite. Plane-polarized light. H, Same, crossed nicols. Gel-like material is isotropic. I , B80—4. Disrupted braunite layer with internal, curved (conchoidal), branching fractures. This shattered texture can be more easily explained by a process such as shrinkage or shock than by pervasive (external) shear deformation. Reflected light. J, B91. Rosettes of pale-yellow gageite growing against isotropic gel-like material of caryopilite composition (table 8, analysis 1) that contains crystals of braunite and rhodochrosite. PROTOLITHS 29 30 MICROBANDED MANGANESE FORMATIONS: PROTOLITHS IN THE FRANCISCAN COMPLEX, CALIFORNIA 10,000 EXPLANATION O Metashale |:l Graywacke <1 Chert ||ll|||| Sample / (Seawater x 1,000) La Ce Pr Nd Sm Eu Gd Tb Dy Ho Er Tm Yb Lu A FIGURE 7.—Rare-earth-element (REE) patterns of country rock and ore from the Buckeye deposit, California, normalized to concentra- tions for seawater (Hogdahl and others, 1968). A, 4 metashales, the range for 7 graywackes, and 12 cherts. From Hein and others (1987, p. 218—219, Ladd-Buckeye district) and unpublished data for the Buckeye deposit by Huebner and Flohr. B, Mn-rich lithologies from the Buckeye deposit. Sample B104 is hausmannite rich, B84 is ken formations), and B64 (quartz vein cutting pink recrystallized rhodochrosite; table 6). The REE abun- dances are enriched relative to seawater and other protoliths (fig. 7B). The Ce/La is 1.9, and the Ge anomaly (relative to seawater) is very distinct. TANEYAMALITE Taneyamalite occurs as rare monomineralic layers conformable with laminations of caryopilite (B20, fig. 53), as two laminations interlayered with chlorite and carbonate (B38, fig. 8A), and as veins crossing bedding planes (B24; B29; B20, fig. 53). We interpret the vein material as a soft sediment of taneyamalite composition that flowed during compaction from bedding laminations into veins, although taneyamalite is so uncommon that we are not absolutely certain that it represents a sedi- ment composition. A resinous golden color in hand spec- imen, yellow color in thin section, and relatively high birefringence are indicators of the possible presence of taneyamalite. The XPD pattern is characteristic: the (010), (—110), (-130), (—231), (032), (023), and (014, 4—23) reflections occur at 9.5°, 11.0°, 272°, 320°, 334°, 340°, and 406°, respectively. Insufficient pure material is available for a bulk analysis. Microprobe analyses indicate that taneyamalite is the most sodic manganifer- ous phase at the Buckeye. 10,000 l lllllll |l|||lll | I 1,000 H llllllll 100 Sample/(Seawater x 1,000) 10lll||ll|lll|| La Ce Pr Nd Sm Eu Gd Tb Dy Ho Er Tm Yb Lu B caryopilite rich, B112 is caryopilite and carbonate, B95 is braunite rich, B64 is a vein of pink recrystallized rhodochrosite and quartz, 65H79 is gageite, and B50 is unrecrystallized gray carbonate with gageite. The chemical analyses and mineral modes for these seven samples are given in table 6 and plotted in figure 9D. The range in REE contents of 17 additional Mn-rich protoliths (Huebner and Flohr, unpub. data) is comparable to that of the 7 samples plotted in this figure. CHLORITE PROTOLITH The chlorite protolith is represented by two textures: gel-like material, which occurs as thin laminae (B84, figs. 4E, 6C,D) or fragments of gel layers (B24, fig. 6E,F; B57; B71b, figs. 6A,B), and massive layers of semi- oriented, clay-sized crystallites having, collectively, 10W birefringence (B11, B24, B25, B26, B31, B81a, 65H70). Texturally, gel-like material of chlorite composition dis- FIGURE 8. —Minerals and textures of rocks from the Buckeye deposit, California, discussed in text. A, B38. Interlaminated taneya- malite—phase A mixture (dark), chlorite (micaceous), and rhodochro- site (light gray) surrounded by caryopilite. B, B80. Mass of recrys- tallized gel-like material (dark, near center) in the caryopilite- chlorite mixture (mottled, medium gray). Note the rim of transparent caryopilite (white) adjacent to braunite layer (dark). C, B24. Coarsely crystallized caryopilite, relic gel-like material of chlorite composition, and a mixture of caryopilite, wispy chlorite, and relic gel-like material. The chlorite-rich composition of the gel—like material may be due to removal of Mn by crystallization of caryopilite from a gel-like material having initial chlorite-caryopilite composi- tion. D, B91. Colorless to pale-yellow gageite rosettes (white to gray in photograph; table 9, analysis 2) in isotropic gel-like material of caryopilite composition (table 8, analysis 1) with disseminated rho- dochrosite rhombs. Crossed nicols; field of view is part of figure 6J. E, B24. Bundles of radiating yellowish-orange fibers of phase A (table 9, analysis 10) in recrystallized rhodochrosite (lightest gray, table 1], analysis 5) and chlorite (ch) (pale brown, table 8, analysis 5). F, B6. Layers of braunite (massive) and of hausmannite idioblasts in carbonate. PROTOLITHS 31 32 MICROBANDED MANGANESE FORMATIONS: PROTOLITHS IN THE FRANCISCAN COMPLEX, CALIFORNIA plays stages of “devitrification” that range from sensibly isotropic, through partially crystallized (wispy flakes of chlorite in residual gel-like material), to fully crystallized material with the characteristic anomalous low birefrin- gence of chlorite. Commonly, gel-like material and recrystallized gel-like material of chlorite composition are clear in transmitted light, whereas claylike masses of chlorite composition are cloudy. The occurrence of the (001) X-ray reflection at 14.3° is diagnostic of the pres- ence of chlorite. Mechanically, the gel-like material appears to have fractured, forming curved surfaces (B24, B71b), rather than to have flowed to surround fragments of other material. The chlorite laminations are too thin to be sampled for bulk chemistry. GAGEITE Gageite forms brownish-black laminations and layers, 0.5 mm to 1.5 cm thick, interlayered with hausmannite (B106; 65H79, fig. 4B), rhodochrosite, or mixtures of rhodochrosite and hausmannite (B45; B48; 65H86, fig. 4H). In thin section, the layers are opaque to dark red or dark brown and massive (granularity is not visible); orange to yellow anisotropic patches that appear fibrous are rare (65H79). X-ray diffraction reflections at 129° (200, 020), 14.3° (120), 26° (400, 040), and 27.5° (330) and a broad reflection at 328° are diagnostic. Gageite layers are commonly monomineralic, but in B106 some gageite laminations contain hausmannite idioblasts. Gel-like material of gageite composition does not occur, although some gageite is closely associated with residual gel-like material of chlorite composition. Thus, the nature of the gageite precursor is unknown. Gageite occurs both as broken layers in dismembered ore (65H86, fig. 4H) and as veinlets, apparently originating within a primary layer, intruding hausmannite protolith (65H79, fig. 4B). The mechanical behavior of the gageite protolith is intermediate between that of a fluid carbonate mud and that of the tougher hausmannite layers. A 1-cm thick layer of gageite (65H79) appears mono- mineralic, but XPD results and the presence of 0.7 percent CO2 suggest contamination by surrounding haus- mannite and carbonate, respectively (table 6). The chem- istry of this sample is almost completely described by the system MnO-SiOZ-HZO. Compared with other protoliths, gageite has the highest concentration of tungsten. Tung- sten was detected only in samples that contained gageite, and the concentration of tungsten is roughly proportional to the amount of gageite in the mode (table 6). Gageite is also associated with relatively high values of As and Ni. The gageite protolith has the most depleted light-REE abundances of all sediments, but the enrichment of heavy REE relative to light REE exceeds that of the other protoliths (fig. 7B). The Ce concentration is below the detection limit, preventing detection of a Ce anomaly, if present. Nevertheless, this REE pattern is most unusual. The only similar pattern of which we are aware was obtained from “Siliceous Mn-oxide ore” from the Ladd-Buckeye district (Hein and others, 1987, p. 218). Because Hein and others did not recognize gageite in any of their samples, we cannot verify that this unusual REE pattern is characteristic of gageite. HAUSMANNITE PROTOLITH Hausmannite forms well—developed crystals in thin coherent layers (B55; B56; B87, fig. 4A), in fractured layers (B53, 65H172), and dismembered layers (65H86, fig. 4H) and is disseminated in rhodochrosite layers (B106; B6, fig. 8F). In addition to its occurrence in sedimentary layers, hausmannite occurs as massive oxide (B104; 65H79, fig. 4B; 65H171) that is not obvi- ously sedimentary and may represent the “hydrother— mal” hausmannite of earlier workers. In all occurrences, the deep-red color in transmitted light and the deep—red internal reflections in reflected light, combined with the characteristic equant shape, pitted surfaces, and distinct anisotropy in reflected light, distinguish hausmannite from opaque braunite, deep-red gageite, and oxidized caryopilite. However, hausmannite from the Buckeye is not as extensively twinned as is hausmannite from rocks of higher metamorphic grade. The relative lack of twin- ning may reflect subsidence and deformation while the orebody was still a soft sediment; conversely, it may be due to the common occurrence of Buckeye hausmannite in easily deformed carbonate. Except when disseminated in rhodochrosite, the hausmannite fractures rather than flows. Hausmannite is responsible for X-ray reflections at 180°, 290°, 324°, 361°, 585°, and 59.9° (101, 112, 103, 211, 321, and 224 reflections, respectively), but its optical properties are so distinctive that it was not necessary to rely upon the characteristic X—ray reflections. Massive hausmannite protolith (B104) containing car- bonate and gageite impurities was analyzed (table 6). Considering that the mineralogy is basically that of an oxide, the FeO value of 0.19 percent is extraordinarily low. Hausmannite has the highest Zn concentration of all the protoliths analyzed, but no other trace-element con- centration appears to be characteristic. The 30 ppm W reflects the presence of gageite in the sample. The REE abundances of B104 are enriched (fig. 7B), but the pattern is unusual. The Ce/La ratio is only 0.3, resulting in a slightly negative Ce anomaly. The enrichment of the heavy REE, relative to seawater, is greater than for any of the other Mn-rich protoliths. The lack of a Ce anomaly and the heavy—REE enrichment result in a pattern that is almost flat. PROTOLITHS 33 BRAUNITE PROTOLITH Braunite occurs as thin laminations (10 um) commonly grouped into layers (B71b, fig. 6A; B81, fig. 4F; B95, fig. 5F) that may be so closely spaced as to appear massive (65H19, 65H170). Opaque braunite layers range from poorly crystalline layers (lacking metallic reflectance but giving the characteristic braunite X—ray reflections) to coarsely crystalline mosaics of anhedral crystals that exhibit the characteristic braunite anisotropy in shades of brownish gray. X-ray reflections at 33.0°, 38.1°, and 553° are characteristic. We found no braunite 11 (see De Villiers, 1980). Braunite is interlaminated with rhodo— chrosite, caryopilite, gageite, and, rarely, hausmannite. The coarsest crystals, 0.2 to 0.5 mm in size, invariably grow against carbonate at the margins of laminations. In their extent of deformation, the layers range from coher- ent through broken (B6; B81, fig. 4F) and dismembered (B53, B55) to a micromelange in which laminated braun- ite layers are engulfed in carbonate and give no indica- tion of their original spatial relationships (B59). Braunite layers fractured into fragments, but protolith braunite was never observed to have flowed to surround frag- ments of another protolith. On a smaller scale, braunite layers contain many fractures that originate within, rather than pass completely through, the layers. Some braunite layers shattered such that the individual frag- ments are slightly separated but did not change their relative positions (B80, fig. 61). This behavior suggests that braunite had gel-like mechanical properties. An unusual texture in which “toes” of coarsely crystallized braunite protrude into a mixture of rhodochrosite, chlo- rite, caryopilite, and fine-grained braunite (B95, fig. 5E) probably reflects the loss of fluids by passage through a braunite layer. This texture is similar to the dewatering texture in chert (fig. 50) mentioned previously. A braunite-rich protolith with carbonate, caryopilite, gageite, and chlorite as impurities was analyzed chemi— cally (B95, table 6). The only major constituents (greater than 2 percent) are Mn, SiOz, COZ, H20, and Mg. This protolith has relatively high Co and Ni (26 and 840 ppm, respectively), but no other trace-element concentrations are characteristic. The 22 ppm W reflects admixed gageite. The REE abundances are higher than those in the carbonate (B50) and gageite (65H79) protoliths but lower than those in the caryopilite, graywacke, and metashales (fig. 7B). The Ce/La is 4.4 and the Ce anomaly is very well developed. The contrast between the patterns for the hausmannite-rich and braunite-rich protoliths is striking. Because Ce has both trivalent and quadrivalent oxidation states, whereas La is exclusively trivalent, the variation in Ce/La may indicate relative redox states during deposition of the protoliths, with the hausmannite protolith being deposited under more reducing conditions than the braunite protolith. This interpretation is consistent with the Mn+2/Mn+3 in these oxides. DIOPSIDIC ACMITE PROTOLITH In addition to the chert and metashale, a nonmangan- iferous bed composed of extremely fine grained diopsidic acmite (B94, B96) occurs adjacent to braunite in the exploration adit that lies at approximately the same horizon as the south Buckeye orebody. SUMMARY OF PROTOLITHS Most Mn-rich samples from the Buckeye deposit con- tain relic layering, suggesting that the orebody was originally layered rather than massive, composed of interlaminated and interlayered sediments that are now represented by eight minerals. We believe that the surfaces bounding the laminations represent the original bedding planes, parallel to the sediment—seawater inter- face. While in a soft-sediment state, the more rigid, gel-like layers broke or fractured and the less competent muds flowed, resulting in internal structures that range from layered and laminated to massive. This range of structures is probably responsible for the conflicting descriptions of the ore by our predecessors. By this reasoning, their massive ore corresponds to our most intensely dismembered material. Because there is no clear evidence of bioturbation, the disruption and dis- membering of layers probably is due to compaction or tectonism. Organisms had a passive role in providing a detrital component (radiolaria). Direct evidence for either an active or passive role in precipitation of manganese is lacking, even though marine bacteria are known to oxidize and reduce manganese (Nealson, 1983). At a scale of 0.1 to 1 pm, we observed no oval structures that might be indicative of bacterial cell walls (Ghiorse and Hirsch, 1979) and no casts of bacterial or algal filaments encrusted with oxides (Alt, 1988) or sulfides and oxides (J onasson and Walker, 1987). In contrast, Ostwald (1981) found fossil algal oncolites and probable coccoid bacteria in Cretaceous shallow-marine manganese ores from Groote Eylandt, Australia. On the basis of this finding and the existence of microorganisms that precipitate manganese oxides, he concluded that 10- to SO-um—thick laminations in manganiferous metashales have “organo- sedimentary structure” (p. 561—562). A recent report of delicate orange bacterial mats near low-temperature vents (Malahoff and others, 1987) is tantalizing, in part because the existence of such mats would be consistent with the lack of bioturbation, but we have no evidence to 34 MICROBANDED MANGANESE FORMATIONS: PROTOLITHS IN THE FRANCISCAN COMPLEX, CALIFORNIA prove that the laminations in the protoliths at the Buckeye deposit are of organic origin. Replacement textures such as islands of relic Mn—poor sediment in Mn—rich sediment, which would indicate introduction of manganese after deposition of sediment, were neither observed by us nor reported by earlier workers. Indeed, it is hard to imagine that the extremely fine-grained gel-like materials could survive manganese metasomatism without recrystallizing or that a lami- nated nonmanganiferous sediment could be replaced by the observed Mn-rich compositions while at the same time preserving the intricate laminations and developing the striking compositional contrast between layers. Thus, the manganese-rich nature of the orebody and the compositional contrast between laminations appear to be primary features, a conclusion similar to that reached years ago by Taliaferro and Hudson (1943, p. 272). All fibrous and sparry rhodochrosite, braunite, hausman- nite, and fibrous brown Mn-silicates observed by us are recrystallized primary sediments. These minerals are not diagnostic of postsedimentary hydrothermal or supergene activity, a view promulgated by Hewett (1972). The Buckeye orebody is extraordinarily manganese rich; most protoliths can be described by the system MnO—SiOz—OZ—COZ—HZO. Trace metals occur at much lower bulk concentrations than in many other marine manganese deposits, but the range of trace-element concentrations among protoliths is so large that the maximum values of some trace elements (Sc, Cr, V, Mo, Ba, W) equal or exceed average values (Cronan, 1977) for some trace-element-rich ferromanganese crusts and nod- ules. The bulk chemistry of the orebody reflects pro- cesses that separated manganese from iron and sulfur with extreme efficiency. The complementary iron does not occur within the orebody or the surrounding enve- lope of massive chert. The metashales have high Fe/Mn and may contain this iron complement, but we have not determined whether the metashales reflect an original detrital composition, contain a hydrothermal component, or are a residue (manganese was leached from the protolith of the metashale). The bed of diopsidic acmite is evidence that at least some iron-rich sediment was deposited adjacent to a manganese—rich sediment. No concentrations of sulfur (pyrite or other sulfide) were found, and the protoliths contain only trace quantities of iron and copper sulfides. MINERAL CHARACTERIZATION AND CHEMISTRY Representative microprobe analyses are given in tables 8 to 12. These analyses and additional analyses are plotted in figure 9. Each plotted point represents either an average of three or more analyses of homogeneous phases (hausmannite, braunite, santaclaraite, parsetten- site(?), talc, pennantite, clinopyroxene, smectite, phases A, B, C, D, and most rhodochrosite) or an individual spot—analysis of a heterogeneous phase (gageite, chlorite, caryopilite, some phase A) or mixture of phases (chlorite- caryopilite, taneyamalite—phase A). (The nominal com- positions of most of these phases are listed in table 1; phases A—D have not yet been identified as known mineral species and are discussed later.) Minerals present in thick laminations were initially identified optically and were confirmed by XPD. These identifica- tions formed the basis for the initial selection of materials for microprobe analysis. Identification of layers that were too thin for routine sampling and XPD was prob- lematic. Microprobe analyses of these laminations dem- onstrated that we could not rely upon optical techniques alone to identify the fine-grained phases. Thus, micro- probe chemical analysis became an essential tool in routine mineral identification. Manganiferous materials display textures ranging from gel-like through partially recrystallized gel-like material to crystalline material; from subcrystalline to granoblastic; and from massive and claylike to well foliated. Although this variety of textures is shown in the photographs, it is important to recognize that the diver- sity is largely due to overprints. The original sediments were gels, or gel-like materials, clay, and micrite. GEL-LIKE MATERIALS Our least recrystallized gel-like materials are color- less, pale yellow or pink, optically isotropic, and have compositions of sheet silicates (chlorite, caryopilite). The gel-like materials appear to be cohesive and to have fractured, rather than flowed, to form curved surfaces. Gel-like materials of varied compositions are known to form in other environments. Nahon and others (1982) described a colorless to straw-colored trioctahedral Mn- rich smectite “plasma”; this material may be similar to our silicate gel-like materials. Hoffert and others (1978) found gel-like inclusions of Mn-rich oxyhydroxides in Fe- and Si-rich marine sediments. These inclusions appeared to crystallize to rancieite and todorokite. Haggerty (1987; oral commun., 1987) reported dredging a nearly amorphous white mass with the consistency of petroleum jelly from a seamount in the Mariana forearc. This material contains Mg and Si but no Al and gave a very weak X—ray pattern similar to that of allophane. Brett and others (1987) reported the occurrence of gel with serpentine composition from the Juan de Fuca Ridge. Thus, there is precedent for the formation of silicate and oxide gel-like materials in recent geologic environments. MINERAL CHARACTERIZATION AND CHEMISTRY 35 TABLE 8. —Compositions of gel-like materials, in weight percent, from the Buckeye deposit, California Coast Ranges, determined by electron microprobe analysis [Total Fe and Mn reported as FeO and MnO, respectively. nd, not detected; na, not analyzed. H20 not determined, resulting in low oxide sums for caryopilite, caryopilite-chlorite, and chlorite] Caryopilite- Caryopilite Chlorite Chlorite Braunite Sample B91 B24 B50 B24 B24 B71b B80 B48 B80 Column 1 2 3 4 5 6 7 8 9 Si02 ............................. 37.2 33.8 29.5 31.1 36.2 36.4 34.7 33.9 10.4 A1203 ............................ .95 11.7 17.7 17.2 12.9 14.0 13.9 14.0 nd Ti02 ............................. nd nd nd nd nd nd nd nd .36 V203 ............................ nd nd nd nd nd nd nd nd nd MnO ............................. 47.8 23.5 15.6 11.8 11.4 4.20 5.55 4.38 78.4 MgO ............................. 2.90 16.5 23.8 24.0 23.6 28.8 31.0 33.3 nd FeO ............................. .40 2.39 .83 1.53 3.01 .39 .20 .20 3.20 NiO ............................. .10 .69 .31 1.05 1.64 .33 .41 1.49 nd ZnO ............................. .17 .31 nd .33 .77 .67 1.12 ha .11 C30 ............................. nd .05 nd .14 .19 .47 .11 nd .48 Na20 ............................ .04 .04 .04 .05 .08 .11 .13 nd nd Sum ....................... 89.56 88.98 87.78 87.20 89.79 85.37 87.12 87.27 92.95 1. Partly devitrified caryopilite with gageite laths (table 9, analysis 2; fig. 8D); 4 points averaged. 2. Devitrified yellow mass within rhodochrosite (fig. 8C); 9 points averaged. 3. Isotropic gel-like material within rhodochrosite layer (fig. 6G,H); 3 points averaged. 4. Pink, isotropic gel-like material; contains rhombs of rhodochrosite (fig. 6E,F); 4 points averaged. 5. Partly devitrified gel—like material with phase A (table 9, analysis 10); 3 points averaged. 6. Isotropic gel-like material with braunite (figs. 6A,B); 5 points averaged. 7. Partly devitrified gel-like material with anomalous deep caryopilite; 3 points averaged. blue birefringence and a high Zn content within layer of 8. Partly devitrified chlorite with high Mg and Ni found with gageite and rhodochrosite; 3 points averaged. 9. Layer of now-crystallized gel-like material (fig. 61); 3 points averaged. The preservation of gel-like materials from Jurassic or Cretaceous time was initially surprising to us but appears to be possible if metamorphism is at low tem- peratures and under dry conditions. Various textures of gel-like materials are shown in figure 6, and representative compositions are given in table 8. Most well-preserved gel-like materials have chlorite composition with variable concentrations of mag— nesium and minor elements (table 8, analyses 3—8); one isotropic gel-like material has caryopilite composition (table 8, analysis 1). A nearly isotropic fragment of very pale yellow gel-like material, removed from a thin section of B57, gave a strong X-ray powder diffraction pattern of chlorite. Isotropic gel-like material of chlorite composi- tion occurs as fragments (fig. 6E, table 8, analysis 4; fig. 63, table 8, analysis 6) and as residues within gageite and rhodochrosite (figs. 6G,H, table 8, analysis 3). Note the similarity between the texture of this residue and the texture of the dismembered carbonate protolith (fig. 5A). Commonly, gel-like material having chlorite composition is partly recrystallized, and sometimes it occurs With gageite (table 8, analysis 8), caryopilite (fig. 83, table 8, analysis 7), or braunite (fig. 63, table 8, analysis 6). Totally isotropic material with a gageite composition has not yet been found. However, the materials from which gageite has crystallized have residues depleted in gageite component (figs. 6G,H, table 8, analysis 3). In addition to rare isotropic gel—like material of caryopilite composition (fig. 8D, table 8, analysis 1), disrupted layers and frag- ments of layers with a partly devitrified to wispy texture yield compositions between those of caryopilite and chlorite (fig. 8C, table 8, analysis 2). A further indication that some caryopilite originally was a gel-like material is the occurrence of remarkably transparent yet anisotrop- ic caryopilite layers in B20 (fig. 53). Evidence that braunite layers were originally deposited as gel-like materials is the shattered texture due to curved and branching fractures that are confined to a braunite layer. This texture is probably caused by partial dehydration and shrinkage (fig. 61, table 8, analysis 9) or by tectoni— cally induced shock. The compositions of individual silicate species are not uniform, even within a single sample or layer, indicating that equilibration between the silicates (and between silicates, oxides, and carbonate, as discussed below) did not occur. In part, the range of compositions is attributed to very fine scale mixing of two silicates, which cannot be resolved with the microscope or the microprobe (fig. 9); the silicates also occur as monomineralic material within the same sample. 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Awmmo < 33: .me .Emo wEEoSO 63235 go: .a: 63933. .8: 65 $33.35: 33%.582: :383» on 39:58:: .mmgsfl Ego Egcbgb .fimoaw: 38:35 33 23% 3:238 Kc wggtmoREoDI .m mama; MINERAL CHARACTERIZATION AND CHEMISTRY 37 TABLE 10. —Compositions of vein minerals from the Buckeye deposit, California Coast Ranges, determined by electron microprobe analysis [nd, not detected; nay not analyzed] Talc Smectite Parsettensitelike phase Pyroxene Phase B Phase C Phase D Sample B71 B7 B59 B29 B94 815 B15 core B15 rim Bl5 B17 Column 1 2 3 4 5 6 7 8 9 10 Oxides, in weight percent SiO2 ................. 62.1 46.9 52.9 44.7 52.5 32.9 (32.1—33.7) 36.9 35.4 32.2 0.54 A1203 ................ .39 7.34 2.75 6.13 1.50 .51 (0.38—0.69) 24.4 16.2 3.92 .17 Ti02 ................. nd nd nd .46 .21 .77 (0.36—1.44) 2.39 .27 .47 nd V203 ................ nd nd nd nd nd 34.0 (32.4—36.0) 6.83 16.5 31.8 22.8 MnO ................. 2.69 2.31 .71 31.6 2.42 1.57 (0.99—2.43) .31 .52 1.23 58.7 MgO ................. 29.1 27.1 26.6 2.10 2.22 1.62 (0.92—2.41) .08 .25 1.33 .65 FeO ................. .37 2.28 nd .16 24.1 1.06 (0.73—1.73) .17 .41 .65 .23 N10 ................. nd .09 1. 66 na nd nd -- .07 nd .15 .13 ZnO ................. nd nd 1.59 na nd .08 (nd-O. 15) .07 .11 .10 . 10 CaO ................. .13 1.52 .66 1.03 3.82 15.1 (12.7—16.9) 15.8 13.8 11.8 nd BaO ................. na na nd .42 nd .07 (005—0. 17) . 10 . 10 .20 nd NaZO ................ .09 .22 .17 .18 11.0 1.37 (0.81—1.74) .04 .03 .05 nd K20 ................. na nd na 2.22 ha nd -- nd nd nd nd Sum ........... 94.87 87.76 87.04 89.00 97.77 89.05 87.16 83.59 83.90 8551* Number of cations and anions per formula unit , Si ................... 7.984 6.749 7.541 8.000 1.993 6.026 6.054 6.255 6.092 0.157 A1IV ................. .016 1.251 .459 0 .007 0 0 0 0 0 AlVI ................. .043 .007 .003 1.292 .060 .110 4.717 3.384 .874 .057 Ti ................... 0 0 0 .062 .006 .107 .294 .036 .067 0 V ................... 0 0 O 0 0 4.992 .897 2.333 4.829 5.352 Mn .................. .293 .281 .086 4.794 .078 .243 .043 .078 .197 14.567 Mg .................. 5.572 5.803 5.651 .560 .126 .442 .020 .066 .375 .284 Fe .................. .040 .274 0 .024 .020 .163 .023 .061 .103 .055 Ni ................... 0 .010 .190 0 0 0 .009 0 .023 .030 Zn .................. 0 0 .167 0 0 .011 .008 .014 .014 .033 Ca .................. .018 .238 .101 .197 .155 2.966 2.764 2.608 2.390 0 Ba .................. 0 0 0 .029 0 .005 .006 .007 .015 0 Na .................. .022 .061 .047 .062 .810 .488 .013 .010 .018 0 K ................... 0 0 0 .507 0 0 0 0 0 0 Cation sum ........... 13.988 14.674 14.245 15.527T 3.999H 15.553 14.848 14.852 14.997 20.925TH Anions ............... 22 22 22 1 1 6 24 24 24 24 24 * Sum includes 2.19 weight percent A5203. l Cations normalized to 8 Si. 1. Talc vein; 3 points averaged. ” Sum includes 0.744 Fe”. m Sum includes 0.390 As. 2,3. Smectite within quartz and rhodochrosite veins, respectively; 3 points averaged. 4. Lath within quartz vein; 3 points averaged. 5. Yellow-green, slightly pleochroic diopsidic acmite forming laths and fibers within quartz vein. Calculation of ferric iron, assuming ideal stoichiometry, yields Fe203 = 26.1, F‘eO = 0.64, oxide sum = 100.41; 3 points averaged. 6. Green laths and fibers in quartz vein; range in parentheses; 9 points averaged. 7,8. Columnar grain in quartz vein, showing core-to-rim zonation, with pink to colorless pleochroism; 2 points averaged. 9. Vanadium-rich lath that appears to be compositionally intermediate between phase B and other phase C grains yet contains essentially no Na compared to phase B; 3 points averaged. 10. Vanadate, orange-red; 12 points averaged. GAGEITE Gageite, the most manganese-rich silicate analyzed, is most striking when it occurs as black to dark-red monomineralic septa within massive rhodochrosite (figs. 41, 5A) and as layers and veins within massive hausman- nite. The principal reason for believing that this gageite is a sedimentary protolith, rather than a product of a postsedimentary process, is the less obvious occurrence of gageite in layers and laminations that are mixtures of phases, suggesting that gageite is a sedimentary compo— nent. In these mixtures, gageite occurs as pale-yellow to nearly colorless mats of fine crystals associated with carbonate and chlorite (B50, fig. 6G), as radiating laths growing from a layer now represented by carbonate and residual gel-like material of caryopilite composition (B91, fig. 8D), and intergrown with braunite in laminae (B95). Gageite was analyzed in seven samples (represented in table 9 by analyses 1—4). In comparison with the other manganese-bearing silicates, particularly caryopilite and 38 MICROBANDED MANGANESE FORMATIONS: PROTOLITHS IN THE FRANCISCAN COMPLEX, CALIFORNIA TABLE 11. —Compositions of rhodochrosite from the Buckeye deposit, California Coast Ranges, determined by electron microprobe analysis [All carbonates also analyzed for Sr, Ba, Zn, Ni, and V, but these elements were not detected. C02 calculated from stoichiometry, assuming C=1.000. nd, not detected] Sample B45b BS3 B53 B6 B24 B53 Column 1 2 3 4 5 6 Oxides, in weight percent MnO ........... 59.6 56.9 57.4 57.5 53.3 52.7 MgO ........... 1.17 2.19 1.21 1.51 .41 .74 CaO ............ .13 1.78 2.34 1.68 5.80 6.89 FeO ............ .11 .09 .08 .09 .46 .08 Subsum 61.01 60.96 61.03 60.78 59.97 60.41 CO2 ............ 38.64 39.10 38.88 38.90 39.00 39.21 Sum ....... 99.65 100.06 99.91 99.68 98.97 99.62 Number of cations per formula unit Mn ............. 0.962 0.902 0.917 0.922 0.862 0.839 Mg ............. .033 .061 .034 .043 .012 .021 Ca ............. .003 .036 .047 .034 .119 .139 Fe ............. .002 .001 .001 .001 .007 .001 C .............. 1.000 1.000 1.000 1.000 1.000 1.000 Cation sum ..... 2.000 2.000 1.999 2.000 2.000 2.000 1. Coarsest grained rhodochrosite from rhodochrosite protolith (fig. 5A); 4 points averaged. 2. Rim of coarse—grained rhodochrosite in contact with braunite (table 12, analysis 1); 3 points averaged. 3. Core of same coarse-grained rhodochrosite; 3 points averaged. 4. Fine-grained rhodochrosite with hausmannite (table 12, analysis 5; fig. 8F); 4 points averaged. 5. Coarse rhodochrosite with phase A (table 9, analysis 10; fig. SE); 3 points averaged. 6. Rhodochrosite vein cutting braunite; 3 points averaged. chlorite, the composition range of gageite is very small. No consistent correlation of composition with color, texture, or associated minerals was found. The greatest range in composition was found in samples 65H79 and 65H86. The observed color differences may be due to variable amounts of Mn in other than the +2 oxidation state. There is a good inverse correlation between Mn and Si + Mg (table 9, analyses 1—4). Small amounts of nickel (up to 0.5 weight percent NiO) were detected in most gageite. Chemical formulas obtained for gageite from the Buck- eye are inconsistent with those reported by Moore (1969), Dunn (1979), and Ferraris and others (1987) for gageite from other localities. The crystal structure of gageite described by Moore (1969) consists of walls of edge-sharing octahedra corner-linked to bundles of edge- sharing octahedra. Silicate tetrahedra reside in pipes or channels and support the framework structure by a network of oxygen bonds. Moore proposed M42(Si12036) [06(OH)48] as the formula, where M represents the divalent cations Mn, Mg, and Zn, and M/Si = 3.50. Ferraris and others (1987 ), using electron diffraction and transmission electron microscopy, confirmed the general octahedral structure but found that the distribution of the silicate tetrahedra within the channels was not consistent with the crystal-chemical model of Moore. They found two kinds of interlinked modules built by chains of edge-sharing octahedra and proposed M4206 (OH)40(Si4012)4 with M/Si = 2.625 as the formula for gageite. Dunn (1979) analyzed gageite from Franklin, N.J., and proposed the empirical formula M4oSi15050 (OH)40 with M/Si = 2.67. In the analyses by Dunn, M/Si ranges from 2.63 to 2.74. Significant ZnO and MgO (3.8—5.2 weight percent and 10.1—12.9 weight percent, respectively) were also present, leading to the sugges- tion that Zn and Mg are essential constituents. Unlike gageite analyzed by Dunn (1979), gageite from the Buckeye contains little or no Zn, and there is only minor substitution of Mg for Mn, indicating that Zn and Mg are not essential structural constituents. Most Buckeye gageite has M/Si or M/(Si+Al) of about 2.49 to 2.55, outside of the range of the analyses of Dunn (1979) and consistent with the formula M5(Si,Al)2O(9_x)(OH)2x (ideal M/Si = 2.50). Because of scatter in our data, some analyses are consistent with the formula of Dunn (1979) and others are inconsistent with any of the discussed formulae. The best agreement with our empirically derived formula (MzSi = 5:2) is obtained when there are 4.5 to 4.9 Mn cations per 9 anions; as Mn decreases from 4.5 to 4.1 cations, Si increases to about 2.2 and M/Si decreases to about 2.11. In a few analyses with fewer than 3.9 Mn cations, Si decreases with decreasing man- ganese content. We do not know whether the trace amounts of tungsten in gageite—bearing protoliths occur in gageite or another phase. Despite the extreme color variation—from almost transparent and colorless, through deep red or brown, to opaque in thin section—we found no relationship between gageite composition and color. A possible expla- nation relates to the intense absorption of the Mn+3 ion, which dominates the Mn+2 ion in spectra of oxides. Thus, even minute amounts of Mn+3 ion would color the gageite, yet we would not be able to see any difference in gageite composition by electron microprobe techniques. The occurrence of gageite supports this explanation: the centers of gageite septa (deformed protolith layers) tend to be intensely colored, whereas gageite laths growing into gel-like material or against carbonate tend to be almost colorless. We initially thought that dark color in gageite was due to supergene oxidation by fluids that followed gageite veins and did not alter the enclosing rhodochrosite. However, we observed that pieces of carbonate, left on the surface for 20 years, developed a black oxide rind even in the dry environment of the Diablo Range. Thus, in the absence of any other evidence of supergene alteration, such as alteration of the carbon- ate immediately adjacent to the gageite, we propose MINERAL CHARACTERIZATION AND CHEMISTRY 39 TABLE 12. —Compositions of the oxides braunite (columns 1—/,) and hansmannite ( columns 5—8) from the Buckeye deposit, California Coast Ranges, determined by electron microprobe analysis [nd, not detected; 113, not analyzed. MnO, Mn203, FeO, Fe203, Mn”, Mn”, Fe”, Fe+2 calculated by assuming ideal stoichiometry of 8 cations per 12 anions for braunite and 3 cations per 4 anions for hausmanniteJ Sample B53 B53 B6 65H170 B6 B106 65H79 65H170 Column 1 2 3 4 5 6 7 8 Oxides, in weight percent SiO2 ................. 9.79 9.88 9.87 10.0 0.22 nd nd nd Ti02 ................. nd nd nd nd .05 nd nd nd Mn203 ............... 77.5 76.7 78.4 78.6 67.8 69.2 69.8 69.1 Fe203 ............... .23 .51 .47 .24 .480 0 .21 .40 A1203 ................ nd nd .27 nd nd nd nd nd Cr203 ................ nd nd na na na na na na V203 ................ nd nd nd nd .05 .12 .08 nd MnO ................. 10.9 10.6 11.1 11.6 0 30.3 29.0 30.6 FeO ................. 0 0 0 0 0 0 0 0 MgO ................. .05 .11 .15 nd .03 .36 1.33 .46 NiO ................. .14 .33 nd nd nd .08 .15 nd ZnO ................. nd nd nd nd .07 .09 nd nd COO ................. nd nd nd nd nd nd nd nd CaO ................. .34 .40 .18 .15 .07 nd nd nd BaO ................. nd .03 nd nd nd nd nd nd Na20 ................ nd nd nd nd nd nd nd nd Sum ........... 98.95 98. 56 100.44 100.59 99.77 100.15 100.57 100.56 “Mn0”* .............. 80.52 79.59 81.63 82.19 91.89 92.56 91.71 92.74 “FeO”* .............. .21 .46 .42 .22 .43 nd .19 .36 Number of cations per formula unit Si ................... 0.995 1.006 0.985 1.000 0.008 0 0 0 Ti ................... 0 0 0 0 .001 0 0 0 Mn+3 ................ 5.992 5.947 5.961 5.984 1.967 1.996 1.991 1.982 Fe‘L3 ................ .018 .039 .035 .018 .014 0 .006 .011 A1 ................... 0 0 .032 0 0 0 0 0 Cr ................... 0 ‘ 0 0 0 0 0 0 0 V ................... 0 0 0 0 .002 .004 .002 0 Mn”'2 ................ .938 .917 .944 .980 1.000 .973 .922 .978 Fe+2 ................ 0 0 0 0 0 0 0 0 Mg .................. .008 .017 .022 0 .002 .020 .074 .026 Ni ................... .011 .027 0 0 O .002 .005 0 Zn .................. 0 0 0 0 .002 .003 0 0 C0 .................. 0 0 0 0 0 0 0 0 Ca .................. .037 .044 .019 .016 .003 0 0 0 Ba .................. 0 .001 0 0 0 0 0 0 Na .................. 0 0 0 0 0 0 0 0 Cation sum ..... 7.999 7.998 7.998 7.998 2.999 2.998 3.000 2.997 * Total Mn as MnO and total Fe as FeO, obtained by electron microprobe analysis. 1. Coarse-grained braunite rims in contact with rhodochrosite (table 11, analysis 2); 3 points averaged. 2. Fine-grained braunite with rhodochrosite in cores of grains (rim composition is given in this table, analysis 1); 3 points averaged. 3. Braunite coexisting with hausmannite (analysis 5, this table; fig. 8F); 3 points averaged. 4. Braunite coexisting with hausmannite (analysis 8, this table); 6 points averaged. 5. Hausmannite from hausmannite-braunite-rhodochrosite sample; 3 points averaged. Braunite is analysis 3, this table. 6. Hausmannite from hausmannite-rhodochrosite sample; 6 points averaged. 7. Hausmannite layer within gageite; 3 points averaged. 8. Hausmannite coexisting with braunite (analysis 4, this table); 3 points averaged. instead that the intense coloration of the gageite proto- CARYOPILITE AND CHLORITE lith reflects its initial oxidation state and that the light- colored marginal laths have inherited the (presumably) Caryopilite generally is orange or orange brown and more reduced state of the adjacent carbonate and cary- contains about 0.1 weight percent each of NiO and ZnO; opilite protoliths. the concentrations of V203 and TiO2 are generally below 40 MICROBANDED MANGANESE FORMATIONS: PROTOLITHS IN THE FRANCISCAN COMPLEX, CALIFORNIA Si Rdc iln protlolithsl 2 Others I Si D It®1|1ll| 2 Others 2 Others FIGURE 9. —Summary of chemical analyses of samples from the Buck- eye deposit, California, plotted in the system Mn-Si-Others, Where Others consists principally of the elements Mg, A1, Fe, V, Ti, Ni, Zn, Na, and Ca. Cation proportions. A and B, microprobe analyses of discrete phases; C, analyses of mixtures of phases, plus single-phase vein carbonates; D, bulk analyses of representative protoliths. The clustering of microprobe analyses does not represent the bulk composition of the deposit. Bulk analyses of protoliths fall near Mn on the detection limits of the microprobe (table 9, analyses 5—7). The iron concentration is commonly less than 3 weight percent FeO. The aluminum and magnesium concentrations of material with the appearance of cary- opilite range from those of near endmember caryopilite 2 Others the Mn-Si join. Symbols: Ta, taneyamalite; Ca, caryopilite; Ga, gageite; Br, braunite; Mn-chl, Mn-rich chlorite; Mg-chl, Mg-rich chlorite; Rdc, Mn-rich carbonates; Pa, parsettensitelike mineral; Sa, santaclaraite; A, B, C, and D, minerals designated phase A, B, C, and D; Tc, talc; Px, acmitic diopside; Sm, smectite; Ti, titanite; Ha, hausmannite. In C, squares represent analyses of phase A—taneyamalite mixtures, circles represent analyses of caryopilite-chlorite mixtures, and crosses repre— sent analyses of gageite-caryopilite mixtures. to those of near endmember clinochlore (fig. 9). It is probable that small amounts of Mg and Fe can substitute for Mn in caryopilite, and of Mn for Mg in chlorites, within the two structure types, but the fact that Mg is positively correlated with Al over much of the composi- MINERAL CHARACTERIZATION AND CHEMISTRY 41 tion range indicates that most of the compositional variation is due to mixing between these two phases. When Mg exceeds about 1 cation per 14 anions (about 5 weight percent MgO) in caryopilite, the concentration of Al increases linearly with the Mg, indicating that mix- tures of caryopilite and chlorite have been analyzed. This is the composition limit separating caryopilite from mix- tures of caryopilite-chlorite in figure 9. Mixtures of Mg-chlorite and caryopilite trend toward two chlorite compositions, one with lower A1 and higher Mg than the other (fig. 10). A few points identified as mixtures (fig. 10) with Mg less than 1 and about 0.5 A1 are from B38 and are slightly more Fe-rich than caryopilite analyzed from other samples. With the exception of sample B24, com- positions within a given sample fall on only one trend. In B24, two distinct chlorite compositions are found, as discussed below. Rarely, caryopilite has high Mg (B17, table 9, analysis 6; fig. 10) without correspondingly high A1 and low Si, suggesting that more than the arbitrary 5 weight percent MgO can substitute for Mn in the cary- opilite structure (rather than being due to admixed chlorite or pennantite). These high Mg values cause the overlap between the caryopilite field and the mixed caryopilite-chlorite field (compare figs. 93, C). Cary- opilite also occurs with gageite. In addition to the discrete caryopilite and gageite, sample B95 contains deep-orange to deep-red material, suggestive of the color of gageite but with intermediate composition (fig. 9C) attributed to intergrowths of caryopilite and gageite. B17 is similar, but with only a trace of mixed caryopilite- gageite. B54 contains discrete caryopilite and the mixed material, but discrete gageite is absent. Evaluation of microprobe analyses of caryopilite and determination of its composition limits are made even more difficult because caryopilite has a modulated struc- ture (Guggenheim and Eggleton, 1987), which results in an excess of tetrahedrally coordinated cations and a deficiency of octahedral cations relative to the ideal serpentine formula unit, Mg68i4010(OH)8. Caryopilite from the Buckeye deposits has octahedral/tetrahedral cation ratios of 1.23 to 1.32, similar to but outside of the range of 1.36 to 1.44 found by Guggenheim and others (1982). The deficiency of octahedral cations in Buckeye caryopilite may in part be due to the relatively oxidized state of the orebody, causing substitution of Fe+3 or Mn+3 for Fe” or Mn+2 (thereby creating vacancies), or to admixed trioctahedral smectite. An interesting textural relationship between caryopi- lite and layers of mixed caryopilite and chlorite is observed in sample B80 (fig. BB). The sample is com- posed of disrupted layers of braunite, caryopilite, and chlorite. At the boundary between caryopilite-chlorite and braunite layers, a rind of near-end-member caryopi- lite (table 9, analysis 7) separates the mixed silicate layer 5.0 I l 4.5 — BBO\ o — 0 ©0 4.0 — d) — o 0 ga O % — u & o o o I] o _ g mg]: <1- IEDD _ Ba 2 ea 69 £9 a) _ o I I I I 0 0.5 1.0 1.5 2.0 2.5 AI/14 anions EXPLANATION O Chlorite O Caryopilite D Caryopilite-chlorite mixture 63 Mn-rich chlorite FIGURE 10.—Compositions of caryopilite and chlorites from sample B80 and 14 other samples from the Buckeye deposit, California. There appear to be two chlorite-composition clusters and two mixing lines toward caryopilite. Caryopilite analyses from sample B80 cluster at very Mg—poor compositions, chlorite analyses cluster at very Mg—rich compositions, and caryopilite-chlorite mixtures span a very large compositional range. The gaps between the endmember caryopilite and chlorite compositions and the compositions of the caryopilite-chlorite mixtures in sample B80 illustrate the lack of equilibrium between caryopilite and chlorite as discussed in the text. from the oxide layer. The compositions of the caryopilite rind, mixed caryopilite-chlorite, and chlorite in B80 are indicated in figure 10. The mixed layer in B80 has compositions that span almost the entire range of the high-Mg trend of the mixed caryopilite-chlorite analyses from all samples; in B80, however, caryopilite and chlorite are distinctly more Mg—poor and Mg-rich, respec- 42 MICROBANDED MANGANESE FORMATIONS: PROTOLITHS IN THE FRANCISCAN COMPLEX, CALIFORNIA tively, than the mixing line, illustrating the lack of equilibrium between the silicate phases. Further, the rind of caryopilite is not the result of equilibration between the mixed silicate and oxide layers, as no correlations between compositions of caryopilite and braunite were found. The amount of substitution of other cations for Mn in caryopilite from B80 is among the least found in the Buckeye samples, and these compositions (and those from B24, table 9, analysis 5) probably represent the purest caryopilite in the Buckeye samples. Most chlorite is the product of incipient recrystalliza- tion of gel-like material. Rarely, chlorite forms claylike layers (B24). Most chlorites are poorly crystallized, and their compositions are generally magnesian and sili- ceous, with about 4—16 weight percent MnO and as much as 2 weight percent FeO. Chlorite that forms claylike layers in B24 has a composition very similar to the pink isotropic gel-like material in B24 (table 8, analysis 4), containing only slightly less Mg and Al and slightly more Mn and Si. There is no correlation between the degree of crystallization of the gels and their compositions (table 8, analyses 3—8). Coarsely crystalline chlorite is uncommon (found only in B38 and B84), and its composition overlaps that of the gel-like and claylike layers. Cation sums of the coarsely crystalline chlorite are low (fig. 8A, table 9, analysis 8), suggesting that some disorder may exist within the structure or that very minor amounts of caryopilite may be interlayered with the chlorite. Com- positions of the Mg-chlorites, including gels having chlo— rite composition, are variable within single samples, particularly with respect to the amount of manganese. This variation may in part be due to fine—scale mixing with caryopilite. The compositional boundary between chlorite and caryopilite-chlorite mixtures (figs. 9, 10) is arbitrarily defined at 23 weight percent MgO, corresponding to about 3.2 Mg cations per 14 anions. The concentrations of minor elements (Fe, Ni, Zn, V, and Ti) vary considerably between samples. With the exception of smectite, chlorite has the highest concentrations of Zn and Ni. In chlorite and caryopilite-chlorite mixed layers, Ni and Zn concentrations are greatest in the Mg-rich mixed layers (fig. 11). In some samples, chlorite and chlorite—composition gel exhibit a range of textures, again with no correlation between textures and compo- sitions. In B24, however, two distinct groups of gels with chloritelike composition were found. One, discussed above (table 8, analysis 4) forms a layer—fragment of essentially isotropic pink gel-like material that contains rhombohedra of rhodochrosite. The second material with chloritelike composition (table 8, analysis 5) is partially crystallized and colorless; it occurs within layers of rhodochrosite with either caryopilite or phase A (fig. 8E) and has significantly less Al and more Si, Fe, Ni, and Zn than the pink gel-like material. A trace quantity of material with the composition of the Mn-rich chlorite, pennantite, was found disseminated within caryopilite in only one sample (B31, table 9, analysis 9). TANEYAMALITE AND PHASE A Taneyamalite, the Mn analogue of howieite (table 1), and a compositionally similar phase (referred to in this report as phase A) occur as discrete crystals. More commonly, they occur as intimate mixtures that show a range of compositions. Because of the close association, the two phases are discussed together. The best formed taneyamalite occurs interlaminated with caryopilite or chert. Taneyamalite laminations in chert appear to be thin protoliths. When interlaminated with caryopilite, taneyamalite also forms soft-sediment injection veins (fig. 53). Examination of one such vein in B24 With the scanning electron microscope showed fine fibers and laths. Taneyamalite also forms isolated bun- dles or tufts of radiating fibers within chert laminations adjacent to the orebody. These fibers are morphologi— cally similar to fibers of phase A. There is considerable variation in the composition of taneyamalite, both within a single sample and between samples (fig. 9). Taneya- malite in layers or veins contains less MgO, A1203, and SiOZ, and more FeO and MnO, than taneyamalite in isolated tufts (table 9, analyses 13—14). These differences may be caused by contamination with fine-grained smec- tite, which is ubiquitous in some chert layers. All taneya- malite analyzed in our samples is deficient in sodium relative to the ideal formula of Matsubara (1981), NaManSi12(O,OH)44. Under the microprobe beam, the Na X-ray count rate did not decrease with time, indicat- ing that Na was not lost due to exposure to the electron beam. Thus, the sodium deficiency appears to be real and to reflect either deviations from the ideal structural formula or intergrowth with a Na-poor phase such as phase A (see below). Taneyamalite from other samples has compositions within the range of the analyses plotted in figure 12 (values given are cations per formula unit): Sample Na Fe 65H66 ............................. 0. 722—0. 860 1229—1. 458 65H68 ............................. 0824—0859 1266—1318 B10 ................................ 0. 732—0872 0.744—1.099 B7 ................................. 0. 683—0. 862 0852—1. 101 In most samples, the nickel and zinc contents of taneya- malite are at or below the detection limits of the micro- probe, although in several samples (B24, B38, B71) as much as 0.74 weight percent ZnO was found. Phase A occurs as bundles of radiating yellow fibers in rhodochrosite (B24, fig. 8E, table 9, analysis 10). Com- pared with taneyamalite, phase A contains notably more MINERAL CHARACTERIZATION AND CHEMISTRY 43 0.2 l I BE] U 53 X X§ X 0.15 —— X _ EH m R: c a g1 x E Ba @1555: <§ <- 0.1 — EB EEC] — E % EWE D C I: N a fi 33 33 A + 33 2 5533 gm 5 E % Aff x EB 63 A 0.05 — E)“; E 69 % _ x 9 69 xx x X A A o g l l l | 0 1 2 3 4 5 Mg/14 anions EXPLANATION 824 BBC 395 BS4 Caryopilite I o x A Caryopilite-chlorite EB 69 X mixture Chlorite III 0 x A A 0.1 l I l I I Z O x 0.08 —- <§ x — (b X a; EB X X U) _ _ .5 0.06 SD C 3 EB '3 D [I E e C X N 0.04 —% X A E III — x 336963 A3 A E333 $33 BED 1A A. 53 EAAEEE figs (#5; CIEI A f Dmé [III x I EB BEI _ 0.02 EBA fl El D I o ' I I | I I I 0 0.02 0.04 0.06 0.08 0.1 0.12 0.14 Ni/14 anions EXPLANATION 824 B80 395 BS4 Caryopilite l o x A Caryopilite-chlorite EB 69 X mixture Chlorite III 0 x A B FIGURE 11. —Relationship between Ni, Zn, and Mg in caryopilite, chlorite, and mixtures of the two minerals from the Buckeye mine, California. A shows that Ni and Zn are associated with Mg-rich (Chlorite-rich) compositions, but 8 shows that the proportion of Ni to Zn is variable in the Buckeye deposit. Fe and much less Na. The formula of phase A (table 9, analyses 10—11), calculated on the same anion basis as taneyamalite, yields similar cation values and sums. This similarity suggests that phase A may be Na-depleted taneyamalite, analogous to K—depleted zussmanite, K0‘1A1M138i12042(OH)14, which rims K—rich zussmanite in ferruginous metachert (Muir Wood, 1980). Although the K—depleted zussmanite described by Muir Wood appears to be the result of leaching, phase A occurs intergrown with taneyamalite, occurs as well-formed crystals, and does not appear to be a product of alter- ation. On the possibility that phase A is the Mn-rich analogue of deerite, (Fe+2,Mn)6(Fe+3,Al)3Si6020(OH)5, as taneyamalite is of howieite, we calculated analyses of phase A to the deerite formula (15 cations:22.5 oxy- gens). Analyses of phase A approach the formula M;2M+3Si7020(OH)5, although most analyses have excess Si and a deficiency of divalent and trivalent cations relative to this formula. Recalculation of phase A analyses to other formula units proved unsuccessful. We calculated phase A by using the taneyamalite formula unit and effective ionic radii for tetrahedrally and octa- hedrally coordinated cations (Shannon, 1976) and found it to be unlike any of the modulated 2:1 structures consid- ered by Guggenheim and Eggleton (1987, their fig. 5a). On the basis of their scheme, phase A recalculated according to the formula unit MQLZM+?’Si7020(OH)5 has a mean octahedrally coordinated cation radius (all cations except Na, Ca, and Si) that ranges from 0.78A to 0.79A and a mean tetrahedrally coordinated cation radius (Si) of 0.26A. These values plot near the boundary of the known field for zussmanite, suggesting that phase A is structur- ally similar to zussmanite. Phase A most commonly occurs in layers intergrown with taneyamalite, and its presence is deduced from microprobe analyses (table 9, analysis 12) showing compositions that lie between those of taneyamalite and those of the fibers in B24. Layers of mixed phase A and taneyamalite also occur in B38 (fig. 8A). In that sample, the analyses that are richest in phase A component have significant vanadium (table 9, 44 MICROBANDED MANGANESE FORMATIONS: PROTOLITHS IN THE FRANCISCAN COMPLEX, CALIFORNIA 3-5 l I l l Fe/37.5 anions X X o I l l I 0 0.2 0.4 0.6 0.8 1 Na/37.5 anions EXPLANATION 824 BS8 BZO B71 b Taneyamalite D o x A Taneyamalite- I o x A phase A mixture Phase A EB 69 FIGURE 12. —Distribution of taneyamalite and phase A compositions in four samples from the Buckeye deposit, California. Compositions from B24 and B38 appear to define two distinct mixing lines, although there is overlap at the more sodic compositions. analysis 11), and analyses that are richest in taneyama- lite have minor amounts of titanium, indicating that V and Ti are associated with phase A and taneyamalite, respectively. Mixed layers of phase A and taneyamalite are far less common than mixed layers of caryopilite and chlorite. Compositions with at least 1 weight percent NazO, equivalent to 0.5 cations per formula unit, are here defined as taneyamalite; those with 0.1 to 1 weight percent Na20 as phase A—taneyamalite mixtures; and those with less than 0.1 weight percent as phase A. In mixtures of taneyamalite and phase A, sodium and iron define a linear trend when plotted against each other (fig. 12). Each sample defines its own trend, although the distinction is lost as phase A composition is approached. Analyses from sample B71b form two distinct groups, with taneyamalite analyses displaced to higher Fe values than those of mixed taneyamalite and phase A, suggest- ing that an additional phase may be present in the mixture—perhaps smectite, which would account for the high Mg contents of the mixtures. SANTACLARAITE Santaclaraite is invariably associated with rhodochro- site, quartz, and smectite. These minerals form irregular veins or “intrusions” (B7; B20; B25, fig. 40; B84, fig. 4E; B91) that cut across laminations of protolith and may have been pathways for escaping fluids. Fragments of caryopilite layers are suspended in the “intrusion” in figure 4C. The details of the paragenesis are not clear. It is certain, however, that these veins postdate early consolidation of the caryopilite and chlorite protoliths and that much of the santaclaraite has subsequently been replaced. Santaclaraite is recognized by its rhodonite-like mor- phology, brilliant second-order birefringence, and char- acteristic X-ray reflections at 11.5°, 12.6°, 18.5°, and 283°. We confirm the discrepancy between the strong calculated and weak observed intensities of the (0—24) reflection at 332° (Erd and Ohashi, 1984). The laths are so characteristic that pseudomorphs of santaclaraite by rhodochrosite can be easily recognized. These are the pseudomorphs noted by Huebner (1967). We found no evidence for the occurrence of either rhodonite or pyrox- mangite at the Buckeye deposit. In B7, B20, and 65H68B, santaclaraite has a very narrow compositional range, represented by santaclaraite in B7 (table 9, analysis 15). Analyses yield cation proportions that are in excellent agreement with the ideal structural formula, CaMn4[Si5Ol4(OH)](OH)-H20 (Ohashi and Finger, 1981). Santaclaraite from the Buckeye deposit is more homoge- neous but has slightly more substitution of Fe and Mg for Mn than the type material (Erd and Ohashi, 1984), which is from another Mn deposit in the Franciscan Complex. RHODOCHROSITE The carbonate adopts four distinct textural forms: micritic, spherulitic, tufted, and sparry. Sparry rhodo- chrosite forms by the direct recrystallization of the micrite, without passing through intermediate stages. The spherulites are uncommon, fibrous, exhibit a distinct MINERAL CHARACTERIZATION AND CHEMISTRY 45 black cross under crossed nicols, occur in micrite, and appear to be a secondary, probably diagenetic, feature. The rare tufts are composed of well—aligned fibers; by analogy with the sperulites we presume that the tufts are also diagenetic. There is no systematic compositional distinction between these forms. Rhodochrosite from six bulk samples (B22, B28, B35, B45, B74, B108) has cell dimensions ofa = 4.775—4.782A and c = 15.63—15.69A, close to the values for pure MnCO3, 4.777A and 15.66A (Huebner, 1967). Primary micritic and recrystallized sparry rhodochrosites commonly contain less than 2.4 weight percent each of CaO and MgO (table 11, analyses 1—4). Values of 3 to 8 weight percent CaO are uncommon (fig. 8E, table 11, analysis 5). Within a given sample, both micritic and sparry rhodochrosite have about the same compositional range, consistent with the idea that the sparry carbonate is simply recrystallized micritic protolith. Except for very small concentrations of iron, no other elements were detected in the carbonate by means of wavelength- or energy-dispersive microprobe techniques. Specifically, we did not detect Ni, Ba, or Sr in the carbonate grains. Some rhombohedra are zoned, having slightly higher calcium in cores than in rims. A slightly higher concentration of magnesium was found in rims of rhodochrosite grains in one sample (B53, table 11, analyses 2—3); these grains are in contact with braunite, but no corresponding zonation in MgO was found in the braunite. Rhodochrosite that forms crosscutting veins can contain as much as about 10 weight percent CaO and 3 weight percent MgO (analysis 6 in table 11 is represen- tative). Compositions are variable within a single vein and between samples (see table 11 and fig. 9). BRAUNITE Braunite has close to the ideal composition of braunite I, (Mn+2)6(SiMn+3)024 (Baudracco-Gritti, 1985). The composition (fig. 9) varies little within a single sample, but differences between samples were noted, particu- larly in the iron content. The range of Fe203 is 0.20 to 1.64 weight percent (all Fe is assumed to be ferric). Minor amounts of Ca, Mg, or Ni occur in some samples. The compositions of braunite both in contact with and more distant from rhodochrosite in B53 are given in table 12 (analyses 1 and 2). The calcium and magnesium values are not significantly different, but the braunite in contact with carbonate contains slightly more nickel and iron and less manganese. Braunite in B53, which forms distinct layers, appears to be texturally variable. In parts of the sample, braunite appears to be fine grained and inter- grown With equally fine-grained rhodochrosite, but, where in contact with coarse rhodochrosite, braunite forms coarse grains. In other layers, cores of braunite grains contain blebby to irregularly shaped rhodochros- ite grains. Rims of these braunite grains, whether in contact with other braunite grains or with the adjacent rhodochrosite layer, show the same coarsening as observed in the fine-grained braunite and rhodochrosite layers, with the same variation in composition (cores contain less nickel and iron). In sample B80 (fig. SB) a compositional difference between coarse and fine braun- ite is also found. Coarse braunite contains significantly less iron and calcium and more manganese than the finer grains. Despite the range of textures and minor-element compositions, the Si concentration in Buckeye braunite is constant, at a value of 1 atom per 12-oxygen formula unit. Braunite can occur with hausmannite (B6, fig. 8F; 65H170), but no partitioning of iron on the basis of weight percent concentration was found between these two oxides (table 12, analyses 3,5 and 4,8). HAUSMANNITE Hausmannite has close to endmember composition. Manganese greatly exceeds all other cations, and, when recalculated on the basis of an ideal Mn+2Mn3304 for- mula unit, the analyses total approximately 100 percent (fig. 93; table 12, analyses 5—8). Significant but very small concentrations of Fe, Mg, V, Zn, Ni, Ca, Ti, and Si were detected. Most of the slight composition variation was found between samples, With very small ranges of compositions within a single thin section. DISCUSSION The fine-grained textures and microprobe analyses expand the idea that the ore originated as chemically precipitated sediments in which eight components formed layers (protoliths). The new observations are a ninth component (phase A) and mixed layers. Thus, the deposit consists of layers of one component and mixtures of two components. This distribution is what would be expected if the conditions of a sedimentary environment changed such that one field of deposition or chemical precipitation was supplanted by another. The mixtures would form if conditions coincided with those of two or three depositional fields or, more likely, if there was mechanical mixing as chemical precipitates settled into place. Although the textural and microchemical evidence indicates a lack of equilibrium during diagenesis and metamorphism, the fine laminae of contrasting composi- tions do indicate that processes in the depositional envi- ronment also changed, presumably in response to chang- ing conditions, involving the rates of supply of the major components MnO, C02, 02, H20, SiOz, and A1203 and the minor components N a20, MgO, and FeO. 46 MICROBANDED MANGANESE FORMATIONS: PROTOLITHS IN THE FRANCISCAN COMPLEX, CALIFORNIA VEIN MINERALS Two generations of veins occur. Earlier veins tend to be narrow (less than 100 um), short (less than 2 mm; rarely to 3 cm), and devoid of fragments of transected layers. They are monomineralic and reflect the mineral- ogy of adjacent protolith. There is no chemical distinction between these vein minerals and the corresponding minerals in the adjacent metasediments. Later veins are wide (to 2 cm), traverse many layers, and commonly contain fragments of the transected protoliths. The late veins are polymineralic; in addition to wall-rock frag- ments, they contain either quartz or rhodochrosite and minerals that are chemically distinct from the minerals in the enclosing protoliths. These veins introduced addi- tional chemical components to the ore-forming system, and there is a correspondence between these components and the characteristic vein mineralogy. The presence in the veins of titanite, a stilpnomelanelike mineral such as parsettensite, barite, smectite, clinopyroxene, and vari- ous unidentified minerals is evidence that Ti, K, Ba, 804, Mg, Na, V, and As were mobile after the host sediments became indurated. These minerals are not as Mn—rich as the protoliths, and many plot primarily along the join between Si and “others” (fig. 9B). Talc forms veins that cut across spherulitic rhodo— chrosite (B71) and are composed of pale yellow “books” about 40 um across; it has near endmember composition with only minor substitution of Mn and Fe for Mg (table 10, analysis 1). The relative time of formation is not known but is probably late. Smectite and related interlayer compounds occur as fine to coarse (100-ptm) colorless flakes in quartz and rhodochrosite veins and as minute pale brown flakes in Mn-silicate layers and in laminated chert. These smec- tites were identified by their optical properties, compo- sition, and ex andable basal X-ray diffraction reflections at 14A to 25 . Chemically analyzed (coarse) smectites from Buckeye samples have the composition of the trioctahedral smectite, saponite. Some smectite is simi- lar to talc in that minor amounts of iron and manganese substitute for magnesium (table 10, analysis 2). Other smectites contain as much as 1.66 weight percent NiO and 1.59 weight percent ZnO (table 10, analysis 3). In minor-element concentrations, these latter smectites are similar to the gel-like material of Mg-chlorite composi- tion. Several laths with the composition of parsettensite, a manganese-rich stilpnomelane-like mineral, were found in a quartz—barite—apatite vein in one sample, B29. This phase has near endmember parsettensite composition, and only minor substitution of Mg for Mn (table 10, analysis 4). It is the only silicate analyzed in this study that contains significant barium. Barite occurs in the aforementioned quartz-apatite- parsettensite vein and as a replacement (or in-filling) of a unique patch of colloform rhodochrosite in B29. Apatite occurs only as a minor constituent in quartz veins. Diopsidic acmite with slight pleochroism in green to yellow green occurs with titanite and apatite in quartz veins that cut across the sample of the diopsidic acmite bed collected from the exploration adit (B94 and B96). The vein-forming clinopyroxene is similar in composition to the acmitic host and was undoubtedly derived from the adjacent layer. The concentration of jadeite component is small, 3 mole percent (table 10, analysis 5). The vanadium-rich silicate referred to herein as phase B (B15, table 10, analysis 6) forms pleochroic light- to medium-green fibers and laths within quartz veins that cut rhodochrosite. The crystals are very small, the maximum dimensions being about 5 by 150 um, and were too small to obtain an interference figure. The crystals have approximately parallel extinction, maximum inter- ference colors of low second order, and relief greater than that of quartz. The reflectivity of phase B is slightly greater than that of pyroxene. The composition of phase B does not correspond to that of any vanadium silicate reported by Evans and White (1987). X-ray or electron diffraction data are needed. Another vanadium—rich silicate, presumably a single phase (table 10, analyses 7—9), is herein called phase C and occurs in quartz veins in B15, the same sample as phase B. Phase C is pleochroic pink to colorless and forms columnar laths; rarely, hexagonal forms are observed. This mineral has pronounced optical and com- positional zoning, with cores being enriched in aluminum and depleted in vanadium compared to rims. A very good negative correlation between aluminum and vanadium exists in all grains analyzed. This mineral is uniaxial (—) and has parallel extinction, relief greater than that of quartz, and a reflectivity slightly greater than that of pyroxene. Its crystal habit, optical properties, and pro- nounced zoning are like those of tourmaline-group min- erals, but cation proportions are not consistent with the formulae for tourmalines. It is conceivable that phases B and C form a solid-solution series, Na0'0_0.5Ca2_3(A1,V)5 Si6024. X-ray diffraction data are needed. An arsenian vanadium- and manganese-bearing phase, presumably a hydrous vanadate, was found in sample B17 (table 10, analysis 10). Phase D is orange red, has a fine-grained texture, and appears as pseudomorphs of a phase within rhodochrosite. Its deep, color masks its interference colors. Phase D has a reflectivity greater than that of titanite but lower than that of an oxide. This mineral has also been found in hausmannite— and ORIGIN 47 tephroite-rich samples from the Manga—Chrome mine located in Nevada County, Calif. (Flohr and Huebner, unpub. data), and is probably related to flinkite, Mn3 (As04)(OH)4. Well-crystallized titanite occurs in several samples and is associated with quartz veins, particularly in the mas— sive diopsidic acmite, and as trains of crystals in caryo- pilite. Titanite contains less than 1 weight percent V203 and no significant amounts of other minor elements. Its occurrence, particularly in the veins, is evidence that Ti was mobile at the low temperature involved in modifying the manganese deposit. Trace quantities of minute yellow and gray sulfide grains (probably pyrite, chalcopyrite, chalcocite, covel- lite or digenite, molybdenite, and possibly sphalerite) occur in veins. The grain size was not sufficient for quantitative microprobe analysis, but X-ray spectra revealed peaks for Cu, Mo, and S. The paragenesis of the sulfide-bearing veins is not certain; they are thin and short, like the early veins, yet they introduce additional components, like the later veins. The fact that Buckeye minerals contain Mn+3 coupled with the absence of appreciable quantities of iron sulfide in or near the Buckeye deposit suggests that the adjacent sediment column was never so reducing that marine sulfate was reduced to make sulfide available for sulfide precipita- tion. (Thus the presence of even minute quantities of copper sulfides signals a local origin or later activity.) The veins provide clues to the mobile components after the manganiferous sediments were sufficiently well indu— rated to fracture. During the first stage of vein forma- tion, the manganiferous components of the protoliths were mobile but did not travel far. During later vein formation, the protoliths were more thoroughly indu- rated (resulting in brecciation), and, with few excep- tions, the manganiferous components were not mobile. The source of the later vein fluids is not known with certainty, but in composition the vein minerals tend to have affinities With seawater and nonmanganiferous marine sediments. Perhaps these late mobile compo- nents were incompatible components that were carried by fluids expelled during compaction of the sediment pile. The precipitation of well-crystallized titanite in a low-temperature sedimentary deposit was not expected and is evidence that Ti can be mobile and concentrated even in an environment in which the bulk composition is unusually low in titanium. Similarly, Brett and others (1987) found anatase in hydrothermal vent chimneys. As a general rule at the Buckeye, occurrence of an element (or pair of elements) corresponds to the appearance of a vein mineral, indicating that the chemical system was responding in a predictable manner to changes in the fluid compositions. Thus, Ba results in the parsettensite- like mineral, Ba and 804 in barite, PO4 in apatite, and Ti in titanite. ORIGIN Two theories for the origin of the Buckeye and similar deposits are currently popular and involve hydrothermal and diagenetic processes. In the following pages we discuss some marine sedimentary processes known to be depositing or redistributing manganese today and exam- ine some modern and ancient deposits in terms of these processes. None is an excellent analogue for the Buckeye deposit, which can best be explained on the basis of two interacting processes such that diagenesis influences the composition of fluids that vent at the seafloor. Finally, we discuss possible tectonic settings for the Buckeye deposit. MODERN PROCESSES OF MARINE MANGANESE DEPOSITION Modern marine environments contain no interlayered manganese carbonate-oxide-silicate deposits that are analogues of the Buckeye deposit, but examination of the processes that deposit and redistribute manganese at ocean-floor environments will help us understand the origin of deposits such as the Buckeye. In principle, there appear to be three kinds of processes: hydroge- nous, diagenetic, and hydrothermal. In practice, many manganese deposits record more than one of these processes. Hydrothermal deposition is usually thought to involve hot fluids, but recent monitoring of some seafloor vents that are associated with Mn—rich precipitates in areas of igneous activity reveals water that is barely above ambient seafloor temperature (Hoffert and others, 1978; Vonderhaar and others, 1987). These cool vents cast doubt on the necessity of heat for Mn transport, Mn precipitation, and even fluid movement, thereby sug- gesting the possibility that some Mn precipitates could be related to fluid expulsion driven by compaction and subduction instead of by thermal convection. The three processes of Mn precipitation are better distinguished if, for the purposes of this discussion, we define a hydro- thermal processs as one that involves transport with a moving fluid either beneath or above the seafloor, a hydrogenous process as one that involves precipitation and gravity settling of particulates through a stationary fluid above the seafloor, and a diagenetic process as one that involves the diffusion of dissolved species through a stationary fluid, commonly below the seafloor. Each of the three processes can result in a distinct product. Characteristic features of these products, when com- pared with the Buckeye ore, may provide clues to the origin of the Buckeye deposit. These characteristics, which are discussed below and in summaries by Margolis 48 MICROBANDED MANGANESE FORMATIONS: PROTOLITHS IN THE FRANCISCAN COMPLEX, CALIFORNIA and Burns (1976), Cronan (1977), Raab and Meylan (1977), Rona (1978), Toth (1980), Fleet (1983), and Lalou (1983), are compared with features of the deposit in table 13. Because we are discussing marine environments, we, like Courtois and Clauer (1980), normalized the REE concentrations of the products to the REE concentra- tions of seawater (Hogdahl and others, 1968). In this way, we hope that our REE patterns will help us distinguish the signatures brought about by the opera- tion of each of these processes upon fluid that, originally, was seawater. Purely hydrogenous deposits form by the precipitation and settling of manganese and iron oxyhydroxides directly from cold seawater onto the top of the sediment column. This process results in nodules and crusts that are exposed at the sediment surface, thin coatings on fresh basalt, particles of Fe—Mn-oxyhydroxides in the sediment, and films of oxyhydroxides that coat detrital particles. Because the manganese concentration in nor— mal seawater is only 0.03 parts per billion (ppb) (Bru- land, 1983), the growth rates are slow and large nodules and thick crusts occur only on old ocean floor. A related factor is the occurrence of hydrogenous deposits in tectonically and volcanically inactive areas having low sedimentation rates. Thus, nodules and crusts commonly are found on siliceous ooze and red clay of deep ocean basins, below the carbonate compensation depth and far from sources of detritus, or where currents suppress sedimentation. The fields of nodules and crusts are regional in extent, and surface coverage may exceed 75 percent (Glasby, 1976). Nodules and crusts are layered, and their upper surfaces, which are directly exposed to seawater, commonly are smoother than the lower sur- faces, which are exposed to sediment (see Heye and others, 1979; Marchig and Halbach, 1982). The nodules and crusts are highly oxidized (most manganese is quadrivalent and iron is trivalent). A characteristic Mn phase is vernadite (the 8—Mn02 of Burns and Burns, 1977). Rhodochrosite and Mn-rich silicates, which require manganese that is predominantly divalent, never occur in association with the oxidized nodules and crusts at the sediment surface. Most hydrogenous nodules and crusts have ferromanganese compositions with Mn/Fe ranging from 0.1 to 10. Relative to diagenetic and hydrothermal components, the hydrogenous component is enriched in Co, Fe, Th, Hf, and the REE (Dymond and others, 1984). Halbach (1986) noted that hydrogenous crusts contain, on average, 0.5 parts per million (ppm) Pt. The seawater—normalized REE signature of hydrog— enous products (fig. 13A) is enriched overall, has a pronounced positive Ce anomaly (large Ce/La and Ce/Sm), and is relatively depleted in the heavy REE. These enrichments can be attributed to long exposure to seawater, to the high surface areas of the precipitates, and to the tunnel structures of the constituent oxides. Because of their tendency to undergo diagenetic alter- ation and to form on oceanic sediments that will ulti- mately be subducted, hydrogenous crusts and nodules are uncommon in the geologic record (Jenkins, 1977). We should look for thin (perhaps less than a meter thick) but laterally extensive horizons of nodules or crusts that contain, at least at low metamorphic grade, quadrivalent manganese oxides having nodular or knobby structure, perhaps preserving concentric layering, and having the characteristic chemical signature. One might look for this record in slowly deposited seafloor sediments that lie immediately below an unconformity or that have been preserved as fragments of ocean crust that were accreted to continents. Audley-Charles (1965) and Margolis and others (1978) described nodules and slabs (crusts) in Cretaceous red clay that forms an exotic block in an olistostrome on Timor. On the basis of their intermediate Mn/Fe, enrichment in Co, U, and Th, and high Th/U, some of these nodules may record a hydrogenous com- ponent. The crust and another nodule have high Mn/Fe and low Co and may represent hydrogenous precipitates that have been altered by diagenetic processes. In con- trast, the Buckeye deposit records none of the charac- teristics of the hydrogenous processes (table 13). Early diagenetic processes involve pore fluids that act upon substances incorporated within marine sediments. These processes may redistribute earlier formed manganese-rich precipitates, progressively refining their chemistry through repeated dissolution, transport, and reprecipitation. Diagenesis that is driven by chemi- cal disequilibrium between oxygenated seawater and unconsolidated sediments rich in organic material results in three chemically distinct products: ferromanganese oxyhydroxides formed by oxic diagenesis, manganese- rich oxyhydroxides formed by suboxic diagenesis, and sulfides and manganese carbonate formed by anoxic diagenesis. Processes that occur within the zone of dissolved oxygen (oxic zone) at the top of the sedimentary column (see Froelich and others, 1979) largely involve the redis- tribution of components that had a hydrogenous or detrital origin. Included are the release of trace metals from decomposing organic tissues and the extraction of iron and manganese from sedimentary components (opaline skeletal debris, hydrogenous coatings on sedi- mentary clasts) to form ferromanganese nodules and nontronite (Dymond and others, 1984; Lyle and others, 1984). The Mn oxidation state in the top 5 cm of sediment at two Pacific sites, 3.3 to 3.9, greatly exceeds that in the suboxic zone where Mn is divalent (Kalhorn and Emer— son, 1984). 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E0308: 0300 330 33803330 3.300030% 033003033 0333 K0 $003033§00| .3 3.3302? 5O MICROBANDED MANGANESE FORMATIONS: PROTOLITHS IN THE FRANCISCAN COMPLEX, CALIFORNIA I | I | I | I | I | | I 100,000 : EXPLANATION E E E1 Hydrogenous marine I _ Mn and Fe deposits — — <1 Hydrothermal marine _ — Mn and Fe deposits _ _ O Shale - X Plankton 10,000 E 8 Z 8 _ g E _ >< < - 5 E 3 3 ‘2 1,000( E ‘o‘. E m a) 1 E < J 100 : E 10 I I I I I I I I I I I I La Ce Pr Nd Sm Eu Gd Tb Dy Ho Er Tm Yb Lu A T I l I I T I I I | | l | 100,000 — : E EXPLANATION : : N Red chert, Apennines I — O Braunite ore, Apennines — — x Yellow ore, Harlech _ — I Carbonate, average, Harlech - )1 Red ore, Harlech 10,000 : El Microspherulitic ore, Harlech : s = E o _ q _ _ >< _ _ 6 _ E E £ 1,000 E E I a _ E _ N w _ 100 10 | | l I I l l I l I I I I La Ce Pr Nd Sm Eu Gd Tb Dy Ho Er Tm Yb Lu C 100,000 Sample/(Seawater x 1,000) 10 La Ce Pr Nd Hydrogenous nodules (Elderfield and others, 1981) |||||||ll |||l|| lllllll EXPLANATION Sm Eu Gd Tb Dy Ho Er Tm Yb Lu Corresponding sediments (Elderfield and others, 1981) + < o D X B 10,000 a 0 ca Z a a s m 0) L”, a a E N (I) Nodules Average 5-Mn02thin crust on basalt, Galapagos mounds Todorokite—rich crust, Galapagos mounds Birnessite-rich crust, Galapagos mounds Average nontronite, Galapagos mounds Amorphous coatings l l | | | | I EXPLANATION O Mn-rich lenses, Blue Jay mine <1 Cherts, Blue Jay mine I | I l La Ce Pr Nd Sm Eu Gd Tb Dy Ho Er Tm Yb Lu ORIGIN 51 EXPLANATION Rhodochrosite-rich nodules El Surrounding rocks 10,000 8 o o. 2 1,000' 5 ‘5 3 (U ('D ‘2 E Ta. E 100 (I) 10 | I l | | | l I | I I | J La Ce Pr Nd Sm Eu Gd Tb Dy Ho Er Tm Yb Lu E FIGURE 13. —Seawater-normalized rare-earth-element (REE) patterns of Mn- and Fe-rich deposits, exclusive of the Buckeye deposit and other materials. A, Recalculated from Fleet (1983) and Gromet and others (1984, average shale). Hydrogenous marine Mn-Fe deposits have the greatest REE enrichment and Ce anomaly and are depleted in heavy relative to light REE. Hydrothermal marine Mn and Fe deposits are not as enriched overall, lack the Ge anomaly, and are flat (heavy REE neither enriched nor depleted). Shales are less enriched, overall, but have both the Ce anomaly and heavy REE depletion. Plankton show the least enrichment, relative to seawater, and lack fractionation between individual REE. B, Relationship between REE pattern and kind of precipitate. Hydrogenous nodules and the sediments on which they sit (Elderfield and others, 1981) have the greatest enrichment, the most pronounced Ce anomaly, and the greatest depletion of heavy relative to light REE. Thin 8-Mn02 crusts on basalt dredged near the Galapagos mounds (Corliss and others, 1978) combine the overall enrichment and Ce anomaly that are characteristic of hydrogenous deposits but lack the depletion in heavy REE. Various crusts and sediments dredged from the Galapa— gos mounds (Corliss and others, 1978), and interpreted as having a hydrothermal origin, show a weak Ce anomaly but have acquired neither the overall REE enrichment nor the depletion in heavy REE that is characteristic of the hydrogenous deposits. REE patterns for the Buckeye ores (fig. 7B) are distinct from those of the hydrogenous materials but overlap with patterns of materials dredged from the Galapagos mounds. C, REE patterns for braunite—rich ore Z—17 and red chert Z—lR from the Apennines (Bonatti and others, 1976) and quadrivalent or trivalent state and be insoluble in the pore fluids. However, some manganese remobilization occurs and may contribute substantially to nodule growth. Dymond and others (1984) concluded that oxic diagenesis was the principal process forming nodules at the three Pacific sites studied and resulted in Ni- and Cu-rich manganese oxide (todorokite) with Mn/Fe of 5 to 10. Under steady-state conditions in which oxygen was being consumed by the sediment, Sundby and others (1986) and Westerlund and others (1986) found that surficial sediment immobilized Fe, Mn, and Co from both I I I | | | I | I | I | l 8 O 0. ‘— Stage3 if 5-Mn02 CD ‘5 3 EU in — — Q %_ Caryoleite E Braunlte (U m Todorokite-birnessite Hausmannite Rhodochrosite Fe-rich clays and oxides Stage 1 I I I I I I L 1 I I I I I La Ce Pr Nd Sm Eu Gd Tb Dy Ho Er Tm Yb Lu F for the red, microspherulitic, yellow, and carbonate ores from Harlech, Wales (Bennett, 1987). D, REE patterns of chert and the Mn-rich lenses at the Blue Jay mine (Chyi and others, 1984, their table 2). E, REE patterns for rhodochrosite nodules and associated mudstone, chert, and shale from the Inuyama district, Japan (Matsumoto, 1987). The signature of the Inuyama rhodochrosite appears to be due to contamination by, or inheritance from, the surrounding rocks, which include chert, shale, and mudstone. The pattern of the Inuyama rhodochrosite is more enriched in REE, and has a more pronounced Ce anomaly, than either hydrothermal marine crusts (fig. 138) or Buckeye rhodochrosite (fig. 78). F', Sketch, not drawn to scale, showing possible evolution of the REE patterns of sediments precipitated by vent fluids that are progressively diluted with seawater. Stage 1 represents Fe-rich clays and Fe-rich oxides precipitated from cool fluids near a vent. Stages 2 and 3 represent Mn-rich sediments associated with mounds or vents, perhaps on stage 1 deposits. Stage 4 represents Mn-rich and Mn-Fe oxides deposited at some distance from the mounds and includes hydrogenous nodules. the overlying water and the underlying (and presumably suboxic) sediment and released Cd, Cu, Ni, and Zn to both the overlying water and underlying sediment. Con- sidering the mobility of these trace elements at the sediment-seawater interface, it is not surprising to find ferromanganese nodules enriched in C0, Cu, Ni, and Zn. Were oxic processes to have terminated in carbonates and silicates, instead of todorokite, we would still expect the deposit to contain unusually high Co, Ni, Cu, and Zn concentrations and to have relatively low Mn/Fe. These are not the characteristics of the Buckeye deposit. 52 MICROBANDED MANGANESE FORMATIONS: PROTOLITHS IN THE FRANCISCAN COMPLEX, CALIFORNIA Organic matter, incorporated in the sediment column, decomposes by a progressive series of suboxic and anoxic COZ-producing reactions that consume oxygen, reduce MnOz, form N2, reduce Fe203 (or FeOOH), reduce sulfate to form sulfide, and finally form methane (Froelich and others, 1979). These reactions provide a mechanism for supplying soluble Mn+2 (and Fe”) to pore fluids. These cations can then diffuse upward to the oxic zone, where they precipitate as oxyhydroxides near the top of the sediment column (Lynn and Bonatti, 1965). The intensity of reduction is favored by excess of organic matter (high biological productivity) and time: ferric oxyhydroxides will not be reduced before quadrivalent manganese oxyhydroxides and nitrate (Sawlan and Mur- ray, 1983), and methane will not be formed before manganese, iron, and sulfate have been reduced. Thus, methanogenesis requires a supply of organic reductant that exceeds the supply of the preceding oxidizing agents. The diffusion of dissolved Mn+2 (and Fe”) in response to an oxygen potential gradient is dependent upon the presence of nearby oxidized seawater. Because diffusion of Mn” is a relatively slow process, it is favored by slow sedimentation (and can be arrested by deposition of a thick, perhaps organic—rich, overburden that displaces the oxidizing seawater). Dymond and others (1984) identified the product of suboxic diagenesis in nodules from only one of the three Pacific sites studied and concluded that the suboxic process was intermittent and was related to pulses in the supply of organic debris. The characteristic product forms nodule bottoms, has a high Mn/Fe (20—70), and is enriched in Sb (124 ppm) and U (7.7 ppm). Had suboxic diagenesis been sufficiently intense to produce sulfide or methane, ferric iron would have already been reduced, resulting in the formation of sulfide, in situ, or precipitates with smaller Mn/Fe. The Buckeye deposit offers the organic matter (debris of radiolarians) required by the suboxic model, but the model does not explain the absence of replacement features, low Sb and U concentrations, and the lack of iron-rich precipitates that would be expected, particu- larly if methane was produced. Mn—rich carbonate within modern sediment columns has been discussed by Suess (1979) and by Pedersen and Price (1982). The carbonate occurs in coarse-grained or porous horizons, such as layers of volcanic ash, and the primary precipitates have spheroidal or botryoidal tex— ture. Calvert and Price (1977) considered the carbonate activity to be the critical factor in the presence or absence of Mn-rich carbonate. In contrast, Pedersen and Price (1982) regarded a plentiful supply of (hydrogenous) manganese oxides to be more important for rhodochros- ite formation than an unusual supply of dissolved carbon- ate. The latter opinion is important because it suggests that, following reduction and dissolution, manganese would be reprecipitated as carbonate, close to the site of original oxides. In either case, it is difficult to imagine the in-situ production of sufficient Mn or CO2 to produce a thick layer of rhodochrosite. Transport over great distances, exceeding that possible by diffusion alone, appears to be be necessary. No modern diagenetic carbonate has a composition of the rhodochrosite endmember. Many recent manganifer- ous carbonates contain calcium (but only low concentra— tions of Mg and Fe), and those of Loch Fyne, Scotland, coexist with calcium carbonate (Calvert and Price, 1970). Ancient Mn-rich carbonate and rhodochrosite, inter- preted to have had an origin involving marine diagenesis, occur in the Inuyama district, Japan (Matsumoto, 1987). In most respects, Buckeye rhodochrosite is unlike Inuyama carbonate. Like the modern diagenetic Mn-rich carbonates, Inuyama rhodochrosite is spherulitic and nodular. The Buckeye rhodochrosite is layered (and interbedded with other Mn-rich phases). There is only a small proportion of radial (tufted) or spherulitic rhodo- chrosite at the Buckeye, and that material clearly replaces earlier, extremely fine grained, unoriented rhodochrosite. Inuyama rhodochrosite occurs in bedded chert and has similar large Mn/Fe but smaller concentra- tions of Cu and Ni, much higher REE concentrations, a better developed Ce anomaly (fig. 13E), and less nega- tive values of 813C. Hydrothermal deposits precipitate from mixtures of fluids that were originally marine: fresh seawater drawn beneath the seafloor by convection; connate seawater from the sediment column; possible juvenile fluids; and more fresh seawater. As it circulates through sediments and (or) igneous rocks, the fluid is reduced (Eh potential lowered) by interaction with organic matter (see Froelich and others, 1979) and (or) ferrous-iron-bearing rocks, acidified by the removal of Mg to form smectitelike and talclike phases (Thornton and Seyfried, 1985), and pos- sibly heated. This fluid leaches manganese and iron from the column of sediments and igneous rocks and trans- ports both dissolved and suspended constituents toward the seafloor. Dilution and cooling, brought about by mixing with fresh, relatively oxidizing and alkaline, cold seawater, causes precipitation within the fracture sys- tem or near seafloor vents. These precipitates form rapidly. Manganese that does not settle to the seafloor can be greatly diluted with normal seawater (Baker and Massoth, 1986) and carried for thousands of kilometers between the seafloor and surface by buoyant fluid plumes (Klinkhammer and others, 1986). These plumes are asso— ciated with metalliferous sediments (Edmund and oth- ers, 1982; Klinkhammer and Hudson, 1986) and may be a source of hydrogenous manganese that is subsequently reworked by diagenetic processes. ORIGIN 53 The mineralogy and chemistry of marine hydrothermal deposits are varied but distinctive. The common Mn-rich phases are birnessite and todorokite, rather than verna- dite as in the hydrogenous nodules and crusts. Some hydrothermal precipitates are described as gel-like (Hof- fert and others, 1978; Brett and others, 1987; Haggerty, 1987). Nontronite (see Bischoff, 1972; Corliss and others, 1978; and Alt, 1988) and talc (Lonsdale and others, 1980) are also found. Manganese and iron can be efficiently fractionated from each other in a pH- or an Eh-potential gradient (Krauskopf, 1957; Hem, 1972), such as might be brought about when reducing and acid solutions contain- ing dissolved iron and manganese are progressively diluted with oxidizing and relatively alkaline seawater (see Edmund and others, 1979). Progressive dilution should result in a continuous distribution of Mn/Fe ratios. However, most deposits considered, on the basis of close spatial association with seafloor vents that debouch fluids, to be hydrothermal have Mn/Fe values that are either low (less than 0.1) or high (greater than 7). The relative scarcity of demonstrably hydrothermal deposits that combine low trace-element concentrations and intermediate Mn/Fe (values of 0.1 to 10) may be due to inadequate sampling or absence of iron in the rising solutions. (Large Mn/Fe values would occur if iron was precipitated as sulfides or oxyhydroxides at depth.) Alternatively, different reaction kinetics or an excess of MnO2 (relative to the supply of reducing agent) might cause manganese but not iron to be dissolved by the circulating solutions (see Thornton and Seyfried, 1985). Obviously, if iron was not taken into solution, iron-rich precipitates would not be present. Hydrothermal depos- its have low concentrations of Co, Ni, Cu, and REE, no Ce anomaly relative to fresh seawater, and a flat REE pattern (fig. 13). Hydrothermal deposits will have diverse manifesta- tions in the geologic record. One should look for sulfide, oxyhydroxide, and silica vein systems and vents (Boyce and others, 1983; Herzig and others, 1988) that cut across sedimentary layering; Mn-rich or Fe-rich crusts that formed on the seafloor adjacent to vents (Bonatti and others, 1976) and, in the case of Mn-rich crusts, under- lying sediments such as ferruginous clays that lack detrital-terrestrial, pelagic, and volcaniclastic compo- nents; or umbers on ophiolites. The hydrothermal pre- cipitates may consist of layers and laminations that differ in composition, color, or texture. Because of their close association with fluid-filled fissures, hydrothermal vein deposits might be expected to have small lateral extent. Vented warm fluids would rise and quickly mix with fresh seawater, causing nearby precipitation. The 56- km2 sheet of bedded nontronite on the floor of the Red Sea (Bischoff, 1972) is an exception, almost certainly caused by venting of hot but dense brines, thereby restricting vertical mixing with fresh seawater (and favoring lateral spreading). Long-lasting hydrothermal activity could result in a suite of deposits that record either separate hydrothermal pulses (the opening and closing of subsurface fluid conduits in response to mechanical disturbances and to blockage of channels by rapidly formed precipitates) that are progressively younger, upward, in the sediment column, or the lateral movement of the ocean floor relative to sources of heat (Crerar, 1982). Many Mn-rich deposits described as having a hydrothermal origin at or beneath the seafloor are known from midocean ridges and tectonically active areas. Their preservation may be due to rapid burial by sediments or volcanic rocks, a process that would pre- vent upward mobilization of manganese by diagenesis. MODERN HYDROTHERMAL ANALOGUES Features of the Buckeye deposit are more similar to those of hydrothermal deposits formed on the seafloor than to those of subsurface hydrothermal, hydrogenous, or diagenetic deposits (table 13). Major differences between the Buckeye and modern marine hydrothermal Mn deposits are the greater compositional and mineral- ogical diversity, the absence of volcanic bedrock, and the presence of chert, shale, and graywacke at the Buckeye deposit. Ironically, the best studied system at which the hydrothermal fluids interact with sediments (Guaymas Basin) does not precipitate any Mn-rich crusts, probably because of high fluid temperatures at the vents. How— ever, other manganiferous lenses in the Franciscan Com- plex, long considered to have the same origin as the Buckeye deposit (Taliaferro and Hudson, 1943), are associated with basalt. Elsewhere, ancient Mn-rich lenses of apparent hydrothermal origin are intimately associated with chert. In the following paragraphs we will examine these differences and attempt to explain how they could arise from rising fluids, using as the starting point for the discussion processes operating at moundlike or ridgelike deposits that are now forming at midocean ridges. Mounds occur 20 km south of the Galapagos spreading center at 86° W. longitude. Lonsdale (1977) described their distribution and morphology. Corliss and others (1978) and Schrader and others (1980) gave mineralogical and chemical analyses of dredged samples. Physical- property measurements and core examinations were summarized by Dymond and others (1980), Hekinian and others (1978), Hoffert and others (1980), and Honnorez and others (1981). Galapagos mounds are steep-sided cones, 5 to 20 m high, aligned in chains that are presum— ably related to fractures in basaltic bedrock. In plan view they are similar in size to the Buckeye ore lens (25 to 100 m in diameter). The internal structure of a mound is 15 to 30 m thick, extends below the elevation of the surround- 54 MICROBANDED MANGANESE FORMATIONS: PROTOLITHS IN THE FRANCISCAN COMPLEX, CALIFORNIA ing surface, and consists of nontronitic clay that overlies calcareous and siliceous nannofossil ooze and is capped with a todorokite—birnessite crust. Cores through the sediment column adjacent to the mounds revealed only nannofossil ooze. Although no fluid venting has been observed on the Galapagos mounds, the heat flow is greater through the mounds than through the surround- ing flat sediments. Measured thermal gradients are not linear, and fluids 2 to 8 °C above ambient bottom-water temperature seeped from holes punched into the mounds. These observations indicate the presence of a hydrothermal system and suggest that Mn (and Fe) could be leached from underlying basalt and sediments by convecting fluids. The chemical signatures of the Galapa— gos sediments are distinctive: Mn/Fe exceeds 82 in the Mn crusts, Mn/Fe is less than 0.02 in the nontronite layers, and both materials have small concentrations of Co, Ni, Cu, and Th, as at the Buckeye. The REE patterns are also strikingly similar (compare figs. 78, 133). Thus, the Galapagos mounds, which show evidence of active hydrothermal processes, have some of the same morphological and chemical features of the depositional process recorded by the Buckeye deposit. However, the graywacke, the chert and shale, and the compositional diversity Within the ore lens, all of which occur at the Buckeye, are missing from the Galapagos mounds. Manganese-rich crusts have been dredged from the base of the median—valley scarp at the Trans Atlantic Geotraverse (TAG) site on the Mid-Atlantic Ridge (Scott and others, 1974). Crust from site 13 is composed of 5- to 10-mm-thick layers of birnessite with minor todorokite. Radiometric data indicate rapid growth of the crust, 0.1 to 0.2 m/106 yr. The chemical signature is not distinctly that of either a suboxic diagenetic or a hydrothermal process. The concentrations of Co (maximum 25 ppm), Cu (less than 119 ppm), and Ni (less than 660 ppm) are relatively small, and the U/Th232 ratio ranges from 2.3 to 6.6. The large Mn/Fe (the minimum value is 364) favors a hydrothermal process, but the concentration of U (9 to 16 ppm) is larger than in other hydrothermal deposits. Ferromanganese crust with 1- to 5—mm laminations, dredged from TAG sites 2B and 10G, had similar concen- trations of U (11 to 18 ppm) but, in contrast, much smaller U/Th232, suggestive of a hydrogenous process. Influenced by a small increase in the temperature of bottom water and by the presence of Fe-rich suspended particles, Scott and others (1974) concluded that the crust from site 13 was deposited by a hydrothermal spring. Klinkhammer and others (1986) revisited the area and found anomalously high temperatures (as great as 0.6 °C above ambient) and concentrations of manga- nese and silica in fluids collected near vents, supporting a hydrothermal origin for crust at site 13. Seafloor deposits in the French American Mid-Ocean Under Sea (FAMOUS) area of the Mid-Atlantic Ridge were retrieved by Hoffert and others (1978). Water samples taken near two vents showed neither a temper- ature nor a composition anomaly, but a thin wedge of surficial precipitate spread outward from each vent, decreasing in thickness from 1 to 0.1 m and covering an area of about 40 by 15 m. The underlying sediment was fossiliferous and CaCO3-rich. Surficial materials rich in Fe and Si and composed of glauconite-celadonite and nontronite occurred near the vents, Whereas Fe-Mn oxyhydroxides lay farther from the vents. With distance, there was the following progression of materials: “gel-like inclusions of manganite, gel-todorokite, gel- rancieite, birnessite-rancieite, and gel—cryptomelane” (Hoffert and others, 1981, p. 81). Some interlayering between clay-rich material and oxide—hydroxides occurred. The clays had Mn/Fe values of 0.1 to 0.3, low concentrations of Co, Ni, and Cu, and Co/Zn values less than 2, thereby falling into the Fe—rich hydrothermal category. The Mn-rich materials had Mn/Fe values of 2 to 3, like many hydrogenous and diagenetic deposits, but had lower concentrations of Co, Ni, Cu, and Zn than oxic diagenetic or hydrogenous deposits. Because of their association with vents and ferruginous clays, we favor an origin involving hydrothermal over suboxic-diagenetic processes. Perhaps these Mn-rich materials are samples of the intermediate stage in the fractionation path between Fe-rich and Mn-rich hydrothermal precipitates. In contrast, basalts collected some distance from the vents are covered with Fe-rich crusts. These coatings have Mn/Fe values of 0.3 to 0.5, high concentrations of Co, Ni, and Cu, and a Co/Zn of 5.7 to 8.2. This different chemical signature reflects hydrogenous or oxic- diagenetic processes. Although the composition of the crusts found adjacent to the vents is too Fe-rich to be a good analogue for the Buckeye, the FAMOUS site demonstrates that hydrothermal processes develop tab— ular (almost lenslike) bodies, form gel-like materials, and develop compositional diversity by fractionation on a very local scale. Recently, a new mounds field has been discovered in the Mariana back-arc basin. Some observations may bear upon the origin of deposits such as the Buckeye. Leinen and others (1987) reported that the Mariana mounds are associated with high heat flow and faults, have morphol- ogies ranging from cones 2 m high to hummocks half that height, and are associated with finely laminated sedi- ments. Leinen and others (1987) also related the forma- tion of nontronite to a supply of biogenic silica. Fluid advects from the centers of the mounds over a distance of 30 m (Leinen and others, 1987; Wheat and McDuff, 1987; Dadey and Leinen, 1987). Although we do not discount the importance of precipitation at the seawater-sediment ORIGIN 55 interface, lateral flow parallel to sediment laminations provides a mechanism for distributing additional fluxes while preserving earlier formed layers of contrasting composition. Vents in the Guaymas Basin, on the northern exten- sion of the East Pacific Rise (EPR), debouch hydrother- mal fluids that interacted with a thick sedimentary pile after leaving the presumed basaltic basement (Von Damm and others, 1985). The sediments in the southern trough consisted of siliceous skeletal debris and detrital clays but, unlike the Buckeye deposit, had 10 to 15 percent Ca003. The Mn content of the solutions was not as great as at the sediment-starved ridge vents, presum- ably because the vented solutions were alkaline and with pH of 6.5, due to dissolution of CaCO3 and decomposition of organic matter to produce NH3. Nevertheless, reported Mn concentrations exceed those of seawater by a factor of 104, and Lonsdale and others (1980) found surficial Mn-rich crusts on talc in the northern trough of the basin. All Mg and sulfate could be attributed to mixing or contamination with fresh seawater, but the appreciable H28 content suggests that degradation of organic matter was more than sufficient to mobilize Fe+2 and that ferrous iron sulfide should have precipitated at depth. Vent temperatures exceeded 250 °C. Bowers and others (1985) modeled both the interaction of hot EPR fluids with Guaymas sediment at 315 °C and the mixing of 315 °C Guaymas vent fluid with fresh, cold seawater. The calculations were not carried to temperatures lower than 5 °C, corresponding to fluid mixtures containing less than 1 percent of the original hydrothermal component. Quartz, talc, sulfides, and smectite were the dominant precipitates, and the oxygen fugacity did not increase sufficiently to precipitate quadrivalent Mn oxides. Bow- ers and others did not, unfortunately, consider the interaction of fresh seawater with sediments alone, par- ticularly calcium-carbonate—free sediments, as occur at the Buckeye. Campbell and others (1988) found that, upon dilution, dissolved Mn emitted from Guaymas vents precipitated within 1 week (or within several kilometers) and settled, contributing to the Mn anomaly in the surface sediments. Data for the REE-enriched hydrogenous nodules and crusts abound, but REE analyses of the relatively depleted hydrothermal deposits, modern or ancient, are scarce. Preliminary analysis suggests that three charac- teristics of the REE patterns can be correlated with the nature of the mineralizing process (table 13). Relative to seawater, the REE patterns of hydrothermal oxyhy- droxides and clays are less evolved—depleted and flat— than are patterns of hydrogenous materials (fig. 13A). Examination of REE patterns for a variety of materials from modern deposits (figs. 13A,B) suggests that a Ce anomaly can develop without appreciable overall enrich- ment and that, even in the region in which enriched patterns overlap, the hydrogenous patterns show a depletion of heavy REE whereas the hydrothermal patterns are relatively flat. These observations suggest the following progression of features with increasing degree of REE enrichment (fig. 13F). The first charac- teristic to develop is the Ge anomaly (pattern 2), which becomes distinct before appreciable overall enrichment in REE (pattern 3). The last characteristic to develop is the depletion in heavy REE (pattern 4) relative to the intermediate REE (pattern 3). This last pattern proba- bly develops long after the third stage and may be the result of diagenetic as well as hydrogenous processes. The earlier stages of this sequence correspond to the progressive dilution of the vented fluids. Comparison of figures 7A and 13E suggests that the Buckeye protoliths have characteristics that are little evolved relative to seawater and plankton and that are similar to patterns from hydrothermal materials. It is clear that, although no modern analogue for the Buckeye deposit has been found, marine hydrothermal deposits record some of the fluxes that were previously proposed for the Buckeye. Further, the late-stage and highly fractionating hydrothermal processes in the marine environment record some of the geochemical signatures that were found in the Buckeye protoliths. Sources for two of the sedimentary fluxes (dissolved Mn, Si) are found in the venting solutions at the modern deposits. At vent sites that have no siliceous sediments, the dissolved silica is precipitated as iron-bearing clays, late in the progressive mixing of vented fluids and seawater. At the Guaymas Basin, where hot fluid inter- acts with a siliceous sediment column that is thicker than the chert-rich section at the Buckeye, quartz is a major product of precipitation. Perhaps, were the solutions cooler or in contact with siliceous sediment for a shorter time, late-stage Mn silicates might precipitate before the Mn is oxidized and precipitated as oxyhydroxides. Fresh seawater, a possible source of O2 to precipitate hausman- nite and braunite and of Mg necessary for Mg-rich chlorite and Mg-substituted caryopilite, is ubiquitous near the vents. Missing from the modern hydrothermal environments is direct evidence for the dissolved-002 flux, although measured high values of alkalinity and pH (Von Damm and others, 1985) are suggestive of its presence. Carbon-dioxide species must have been present in the modern systems because skeletal CaCO3 is present in some sediments and because diagenetic pro- cesses make HCO; available to the solutions during all stages of the oxidation of organic matter (Froelich and others, 1979). As in the case involving a deficiency of dissolved silica to precipitate Mn silicates, a higher concentration of dissolved CO2 is needed to precipitate 56 MICROBANDED MANGANESE FORMATIONS: PROTOLITHS IN THE FRANCISCAN COMPLEX, CALIFORNIA Mn as MnCO3 before quadrivalent oxides. Perhaps abun- dant siliceous turbidites, such as those at the Buckeye, can provide both. Were siliceous ooze to be abundant in the modern mounds-forming environments, in which cool fluids are vented, there could be three important chemical differ- ences. (1) The siliceous skeletal debris could provide soluble opaline silica to form the Mn-silicate proto- liths—the gel—like materials and clays of caryopilite, taneyamalite, and gageite compositions. (Without the source of easily soluble silica, hot solutions would be necessary to dissolve silica from silicates in basalt in the sediment column.) (2) Abundant organic debris would decompose and ultimately be oxidized to HCO; or COZ, providing the dissolved carbonate necessary to precipi- tate rhodochrosite. (3) A consequence of the decomposi- tion of organic matter and CO2 generation is the con- sumption of dissolved oxygen in fresh seawater to produce fluids with intermediate to low redox potentials. These reduced fluids would stabilize Mn+2 ions so that Mn could be dissolved and transported from sediments and (or) basalt. Progressive dilution with fresh seawater at the vent would reverse the process by increasing the alkalinity and Eh of the fluids, causing rhodochrosite, hausmannite, braunite, and Mn-silicates to precipitate. Pulses in the flux of silica and organic matter, caused by nearby turbidites of radiolarian sand that occurred at the Buckeye, provide one possible mechanism for developing layers and laminations with strong compositional con— trast. Each turbidity flow would immediately disturb the fluids near the seawater—sediment interface, more slowly influence the dissolved silica concentrations, and ulti- mately, through diagenetic processes, influence the flu- ids that contribute to the supply of Mn and C02. No modern deposits of rhythmically interbedded chert and shale protoliths are known (Hein and Parrish, 1987), with or without hydrothermal precipitates. A clue to their occurrence might be the association of a zone with very high productivity of siliceous pelagic organisms, seafloor vents that discharge cool fluids, and a seafloor that lies below the carbonate compensation depth. SOME POSSIBLE ANCIENT ANALOGUES Many manganese-rich deposits occur in the geologic record. A review of some of these deposits, particularly those associated with interbedded chert and shale, may provide additional clues for the origin of the Buckeye deposit. Because none of these deposits is as little metamorphosed as the Buckeye, their mineral associa- tions or assemblages differ from those of both the modern deposits and the Buckeye. In the following paragraphs we will discuss how the Buckeye protoliths might change with increasing metamorphic grade and discover that some metamorphosed deposits record orig- inal features that are similar to sedimentary features recorded by the Buckeye. PROJECTED METAMORPHIC PATH Manganiferous sediments that have been subjected to metamorphic temperatures greater than those experi- enced by the Buckeye deposit should develop distinctive suites of Mn-rich minerals. Many possible minerals are included in the compilation (table 1). Of this list, the minerals that will actually be present depend as much upon the bulk composition of the manganese deposit as upon metamorphic grade. In the case of the Buckeye, Mn, Si, C, O, H, and perhaps Al and Mg are the controlling elements. The minerals most likely to form include tephroite, pyroxmangite, spessartine, bixbyite, chlorite, and perhaps the rare Mn-chlorites, pennantite and gonyerite. Tephroite and pyroxenoids will form at the margins of the lens by reactions involving rhodo- chrosite and chert (Huebner, 1967). Under appropriate conditions and suitably high fH20 and sz (or low fCOz), the humite-group minerals sonolite, manganhumite, and alleghanyite might appear. We suspect that these min— erals are more common than has been previously recog- nized. The scarcity of MgO and FeO in the Buckeye deposit is not conducive to the formation of amphiboles (tirodite—dannemorite). The paucity of Na20, MgO, and Fe would severely limit the appearance of pyroxenes— donpeacorite, kanoite, johannsenite, or the unnamed NaMnJr38i206 found by Ashley (1986) and by Lucchetti and others (1988)—and the amphibole kozulite. The scarcity of CaO, A1203, and Na20 make the formation of akatoreite, piemontite, the manganese pumpellyites, carpholite, and most hydrous pyroxenoids unlikely. Thus, a consequence of a restricted bulk composition is that the chemically simple phases should persist over a wide range of metamorphic conditions. At the Buckeye, much of the braunite, hausmannite, and rhodochrosite should persist to higher metamorphic grades. Huebner (1967, 1976) predicted that, with increasing temperature and fC02 sufficient to stabilize rhodochros- ite, 1‘02 would fall or maintain a relatively constant value but would not rise. There would be a series of decarbon— ation reactions by which protoliths of rhodochrosite, hausmannite, braunite, and quartz would react to assem- blages that contain tephroite and (or) a pyroxenoid. Bixbyite or quadrivalent oxides would not appear unless the protolith was more highly oxidized than at the Buckeye. The caryopilite, taneyamalite, and gageite protoliths, which were not originally considered by Huebner (1967, 1976), plot very near the Mn-Si join, shown in ORIGIN 57 2 Others EXPLANATION Ideal compositions: Rh-Rhodonite Sp-Spessartine Br-Braunite Rdc-Rhodochrosite Ca-Caryopilite H-Hausmannite T-Tephroite Bi-Bixbyite Ta-Taneyamalite CI-Clinochlore FIGURE 14,—Predicted greenschist-facies assemblages for Buckeye protoliths in which the principal Others components are A1203 and MgO in chlorite and gel of chlorite composition. Sample numbers refer to analyzed protoliths (table 6). A, Projection from 02, 002, and H20 onto the plane MnO—SiOZ—EOthers. This diagram is suitable for silicate-rich and carbonate-rich protoliths in which most manga- nese is divalent. Mole percent. Symbols for protolith samples are the same as in figure 9D. B, Projection onto the plane MnO—Si02-02 from all other components. This diagram is suitable for protoliths MnO—Si02—02 and MnO—SiOz-EOthers projections (fig. 14). A gageite-rich protolith, represented by 65H79, might transform to a mixture of hausmannite, tephroite, and vapor at relatively high f02 but, if the ambient fC02 was sufficiently high, rhodochrosite would take the place of hausmannite. A carbonate-gageite protolith such as B50 would also yield carbonate, tephroite, and perhaps hausmannite. Caryopilite-rich protolith, represented by B84 (caryopilite—carbonate-chlorite), should react to carbonate, tephroite, spessartine, and vapor. Our caryopilite—carbonate protolith (B112) would yield the same minerals, but in different proportions. Were the protolith very caryopilite-rich, pyroxmangite would be a reaction product. Because the manganese in these CI \ Sio2 Rhysp’Ta ca T 65H79, MnO B1 12 EXPLANATION Ideal compositions: Rh-Rhodonite Br-Braunite Sp-Spessartine Fldc-Rhodochrosite Ca-Caryopilite H-Hausmannite T-Tephroite Bi-Bixbyite Ta-Taneyamalite Cl-Clinochlore B rich in hausmannite, braunite, or bixbyite. The anticipated metamor— phic assemblages involve tephroite, rhodonite, and spessartine, in addition to the low-temperature phases braunite, hausmannite, rhodochrosite, and quartz, which will persist to high metamorphic grade. Because there are so few minerals in chemically simple systems such as those at the Buckeye, these metamorphic assemblages should persist over a range of conditions. Assemblages involving spessartine and one of the oxides, hausmannite, braunite, or bixbyite, are unlikely because chlorite does not occur in the “oxidized” protoliths. assemblages is predominantly divalent, braunite would not appear. More oxidized layers, represented by a braunite-rich protolith such as B95, would form a tephroite-hausmannite or tephroite-carbonate assem- blage if 02 were free to leave the system, but if f02 remained constant, braunite could persist to higher temperatures. Hausmannite is more reduced and stable at higher temperatures, so a hausmannite-rich protolith, represented by B104, would retain most of its low- temperature characteristics, with only minor amounts of tephroite formng from admixed caryopilite and gageite. The sodium in taneyamalite might stabilize nambulite, saneroite, or serandite. We think that because CaO is low in the Buckeye protoliths, the pyroxenoid might be 58 MICROBANDED MANGANESE FORMATIONS: PROTOLITHS IN THE FRANCISCAN COMPLEX, CALIFORNIA pyroxmangite, but rhodonite would be a more likely product of metamorphosing santaclaraite-rich veins or horizons. With increasing metamorphic grade, the possible assemblages that could form are severely limited by the restricted bulk composition of the Buckeye ores and other Mn-rich deposits. The variety of Mn minerals (table 1) reported from Mn deposits metamorphosed to greenschist and amphibolite grades reflects, in large part, the availability of elements that are found in only low amounts or are essentially absent at the Buckeye. ORIGINS OF ANCIENT DEPOSITS Of the deposits that might have an origin similar to that of the Buckeye, few rival its diversity of Mn-rich lithologies, and most others include lithologies that are chemically distinct. To identify deposits formed in similar environments, we must not ignore deposits composed of fewer protoliths than at the Buckeye or deposits that contain significant additional chemical components, per- haps reflected in new lithologies. Unfortunately, few of our predecessors described the combination of geologic setting and compositions of individual layers that will be necessary to identify true analogues. In the following paragraphs we will summarize critical features of some possible analogues to the Buckeye deposit (and features of some deposits that are not suitable analogues). The analogues have a worldwide distribution. Like the Buck- eye, many appear to have their origins in a chert-forming marine environment. The Smith prospect, Sierra Nevada Foothills, Nevada County, Calif. (I.F. Wilson, in Trask, 1950, p. 167—168; Hewett and others, 1961; Huebner, 1967; Flohr and Huebner, 1988), lies in a belt of chert, slate, mafic igneous rocks, and graded crystal tuffs of probable marine origin. The deposit is a lens of rhodochrosite and laminated hausmannite enveloped by massive white to gray chert. Metamorphic minerals are rhodonite, teph- roite, and small amounts of spessartine and sonolite; their occurrence is controlled by local bulk composition. At least some of the rhodonite is a reaction product between carbonate and chert (Huebner, 1967). Interbed- ded chert and metashales are nearby. Huebner noted the occurrence of pyrite crystals and “colorless to brown glass...incipiently recrystallized to a platey yellow sili- cate with 7A spacing” (p. 75). The “glass” may corre- spond to the gel-like material of chlorite composition found at the Buckeye, and the pyrite may signify reduc- tion of seawater sulfate to form sulfide. Spessartine occurs with rhodonite and chert, but not hausmannite, much as chlorite layers at the Buckeye avoid the more oxidized assemblages. The area contains serpentine and mafic volcanic rocks of zeolite- or lower greenschist- facies grade. It is clear that tephroite and rhodonite can form at very low metamorphic grades. We expect the compositions of the protoliths at the Smith prospect to have higher CaO contents but otherwise to resemble the compositions reported for the Buckeye (table 6). Hueb- ner (1967) advocated an origin for the Smith deposit that involved thermal springs. We see no reason to discount the connection between manganese deposition and a hydrothermal ore-forming system driven by an igneous heat source at the Smith prospect. The setting of the Manga—Chrome mine is similar to that of the Smith prospect, which lies three miles to the south (I.F. Wilson, in Trask, 1950; Hewett and others, 1961; Flohr and Huebner, 1988). We examined a suite of tephroite-bearing samples, one of which is shown by Hewett and others (1961, their fig. 1). These specimens show sedimentary layers and laminations on a scale similar to that of the Buckeye protoliths. The layers consisted of rhodochrosite, the material called neotocite by Hewett and others (1961), but which is probably gel-like material of chlorite composition, and hausmannite—rich metasediment. Some tephroite forms layers parallel to bedding and may represent metamor— phosed gageite-rich layers. We expect that the composi- tion of these sediments would resemble those of the Buckeye protoliths. A metamorphosed volcanic fragment sits in laminated carbonate-rich mud, suggesting a close spatial association between volcanism and deposition of manganese-rich sediments. Manganiferous metasediments at the Hoskins mine, New South Wales, Australia (Ashley, 1986) lie between ferruginous metachert (compositionally similar to a mix- ture of chert and Al—poor nontronite) and overlying metasiltstone and metasandstone. The metachert over- lies metabasalt of MORB (midocean-ridge basalt) compo- sition and probable greenschist-facies metamorphic grade. This suite was deposited on the seafloor of the Cowra trough. Ashley compared the contorted and brec- ciated laminations with those of jasper at the Blue Jay and South Thomas mines, Franciscan Complex (Crerar and others, 1982); we would extend the comparison to deformed protoliths at the Buckeye deposit. The jasper grades into massive manganese—rich metasediment that now contains tephroite and rhodonite with minor haus- mannite, Mn—rich chlorite, Mn-rich garnet, and relic manganoan calcite and quartz. Texturally and composi— tionally laminated Mn—rich sediment in which much Mn and all Fe are trivalent may overlie the massive ore. The minerals include braunite, manganoan pectolite, amphi- bole (near kozulite in composition), an unnamed Mn+3 analogue of acmite, and an Mn-rich micaceous phase. The compositions of Mn-rich metasediments at the Hoskins mine are similar to compositions of the Buckeye proto— liths but have slightly higher concentrations of A1203, ORIGIN 59 Fe203, and 0210 and significantly higher concentrations of alkalis and the trace elements Ba, Co, and Sr. The two Mn-rich metasediments at Hoskins can be distinguished by the higher As and lower Co, Cu, Sr, and Zn in the massive ore. Ashley (1986) proposed an origin in which laminated silica and iron hydroxide gels were overlaid by mounds of Mn—carbonate, Mn-oxides and hydroxides, and silica that were deposited near vents. The possibility of Mn—silicate protoliths was not discussed. Possible precursors for the laminated ore, suggested by Ashley solely on the basis of the chemistry of the layers, include alkali feldspar or alkali-silicate gel; clays; oxides and hydroxides incorporating Mn, Ba, and K; barite; and Ca—Ba—Mn carbonates. Perhaps caryopilite should be added to his list. Deposits in the Ashio mountainland, Japan, best reveal the geology of the bedded manganese deposits in the Chichibu geosyncline, Japan (Watanabe and others, 1970). These deposits are stratiform and occur with thin-bedded and massive cherts and basic volcanic rocks. The amount of Mn ore correlates with that of associated massive chert. The primary precipitates include rhodochrosite, hausmannite, bementite, and “siliceous material represented by colloidal silica” (Watanabe and others, 1970, p. 139). This material may correspond to the relic gel-like material found at the Buckeye. Regional metamorphism resulted in braunite, tephroite, rhodo- nite, spessartine, and piemontite. The conformably bed- ded and mineralogically diverse deposits described by Watanabe and others (1970) are more similar to the Buckeye deposit than are the spherulitic rhodochrosite nodules of purported diagenetic origin from the Inuyama district, Japan, described by Matsumoto (1987). Banded and massive manganese deposits are associ- ated with chert-basalt contacts in the Apennine ophio- lites (Bonatti and others, 1976). Base-metal deposits occur in the basalts. The manganese deposits are con- tained in layered chert, some of which is radiolarite, 20 to 30 m above the basalt. Limestone and calcareous shale, but not graywacke, succeed the chert. Iron-rich sedi- ments (Fe-oxides, ferruginous chert, or argillite) are absent; the authors attributed this absence to the early removal of iron (as sulfide) from a hydrothermal system. Banded manganese deposits are stratiform and contain layers of Mn minerals interbedded with red chert at a thickness scale of 1 cm. Massive deposits the size of the Buckeye lenses occur at the hinges of folds, are brecci- ated, and grade laterally into banded deposits. Braunite is the principal manganese mineral; it is commonly accompanied by traces of rhodochrosite, parsettensite, chlorite, rhodonite, and piemontite. As is the case with the Buckeye ores, the bulk compositions of the Apennine ores fall close to the join Mn+2Mng3Si012—Si02, with minor Fe, Al, Mg, Ti, and alkali contained in nonmanga— niferous silicates. The Mn/Fe and U/Th values are large and the concentrations of Cu and Ni are small. The Co concentration (11—600 ppm range), although higher than in most deposits thought to have a hydrothermal origin, is distinctly lower than in typical hydrogenous deposits. Bonatti and others (1976) presented two REE patterns that are puzzling even when the labeling of their table 7 is made to conform With their figure 6 and text. The seawater-normalized pattern (fig. 130) for a braunite— rich sample is depleted like the Buckeye carbonates but has a well-developed (and unique) negative Ce anomaly; the mid-range is flat. The chert is depleted overall. Bonatti and others (1976) proposed that the Mn was deposited as a sedimentary precipitate and that the observed mineralogy developed during subsequent met- amorphism. We think that the Apennine deposits dem- onstrate several sedimentary precipitates with an origin related to volcanism and hydrothermal processes. The similarity of the Apennine and Buckeye deposits sug- gests that the Buckeye may also have had a hydrother- mal origin. The Blue Jay (Trinity County) and South Thomas (Mendocino County) deposits in the Franciscan Complex, California, are deposits that may also be analogous to the Buckeye deposit. Crerar and others (1982) described massive Mn-rich lenses in thinly bedded chert that is underlain by basalt. Crerar and others (1982) did not report massive chert, but I.F. Wilson (in Trask, 1950, p. 138—139) noted the presence of massive white chert at the South Thomas mine. At the Blue Jay mine, sandstone occurs in contact with both chert and basalt (Crittenden, in Trask, 1950, p. 308). Crerar and others (1982) referred to the ore as massive but reported few results of a thin-section examination of the ore. We have found that even the most massive hand specimens of Buckeye braunite and hausmannite are laminated when examined as polished thin sections, and we suspect that the braun- ite from the Blue Jay and South Thomas mines would also prove to be laminated, were it so examined. Trask and Trauger (in Trask, 1950, p. 309—310) mentioned only hausmannite, carbonate, bementite, and native copper in the ore from the Blue Jay mine. Crerar and others (1982) identified braunite and minor rhodochrosite, hausmann- ite, bementite, neotocite, rhodonite, inesite, pyrolusite, todorokite, birnessite, nsutite, and vernadite, but they found that much of the Mn-rich material was so poorly crystallized that it could not be characterized. Trace- element data were given by Crerar and others (1982) and Chyi and others (1984). In many respects, the analyses are comparable to those of an average Buckeye compo- sition. The ores have high Mn/Fe and U/Th, and low concentrations of Al and Ti, but Buckeye values for Zn are higher and for Cu lower. Most REE patterns (fig. 60 MICROBANDED MANGANESE FORMATIONS: PROTOLITHS IN THE FRANCISCAN COMPLEX, CALIFORNIA 13D) show little overall enrichment and relatively flat slopes, similar to patterns for the Buckeye and the modern hydrothermal materials, but it is puzzling that the two most REE-enriched samples have the smallest Ce anomaly. The REE patterns for most of the cherts are similar to those of the most enriched cherts at the Buckeye. Clearly, there are morphological, mineralogi— cal, and chemical similarities among these three deposits. As in the case of the Apennine deposits decribed by Bonatti (1976), the similarity of Blue Jay, South Thomas, and Buckeye deposits suggests processes associated with seafloor volcanism and hydrothermal activity. Compared with Mn deposits in the Franciscan Com- plex, stratabound Mn-rich lenses of Northland and Auck- land, New Zealand, have similar lenticular shape but are smaller and lack associated massive chert (Stanaway and others, 1978, p. 24). Associated rock types are interbed- ded cherts and argillites, marbles, submarine lavas and tuffs, massive sulfide lenses, and ferromanganese depos- its. The Mn—rich laminae and lenses consist of hausman- nite, braunite, bementite, and manganite but not carbon— ate. Stanaway and others (1978) invoked diagenetic unmixing and recrystallization of sedimentary Mn-rich clay precipitates under alkaline conditions to develop the observed coarser textures and colloform structures. The Mn/Fe values and trace—element concentrations for most primary deposits in Auckland are similar to those for the Buckeye deposits, but silica is lower and alkali higher. Stanaway and others (1978) regarded the primary ferro- manganese precipitates as having been amorphous and now best represented by the cores of oolites. These New Zealand deposits demonstrate a close association with volcanic processes and textural diversity that increases with diagenetic reprocessing. Three stages of marine hydrothermal ore formation may be represented: early sulfide formation, Fe precipitation, and late Mn precipi- tation. The Buckeye deposit records only the stage of Mn precipitation. Further, postdepositional processes such as diagenesis do not appear to have been important at the Buckeye. Other stratiform and banded manganese formations with mineralogy similar to that of the Buckeye lack the close association with chert and have lateral dimensions that greatly exceed those of the Buckeye lenses. The Hotazel Formation in the Kalahari Basin, South Africa, contains Mn-rich sediments (braunite, hausmannite, bementite, traces of rhodochrosite) and banded iron- formation (De Villiers, 1970; Kleyenstuber, 1984). Vol— canic shards (in the Mn sediments), silicified rock, jasper, and andesitic volcanic rocks, but not graywacke, are present. Kleyenstuber advocated a volcanogenic— sedimentary origin. Unlike the Buckeye, the Hotazel has no interbedded chert-metashale sequences. The lateral extent of individual manganiferous horizons (more than 35 km) exceeds that found in most modern marine analogue environments (basins, rifts) or that of the Ladd-Buckeye district. Thus the ore-forming process must have been capable of delivering tremendous quan— tities of Mn and dispersing it throughout an entire basin. Banded greenschist-facies metasediments of Harlech, Wales, form a 40-cm-thick horizon that covers an area of 190 km2 and correlates with quartz-spessartine metapelite horizons located 30 km to the west (Bennett, 1987). The Harlech Mn-rich horizon extends throughout the area and consists of Mn-rich carbonate, spessartine, chlorite, and silica. We think that the Harlech protoliths could have been composed of Mn-carbonate, Mg—chlorite, and quartz or of taneyamalite and Mg-chlorite (see fig. 14). The mean trace-element concentrations (Mohr, 1956; Bennett, 1987) are similar to those of modern hydrother- mal precipitates (table 13). The REE patterns (Bennett, 1987), converted to our seawater-normalized scheme (fig. 130), resemble Buckeye patterns. Red laminated ore shows the greatest REE enrichment, consistent with the aluminosilicate fraction. The pattern of yellow con- cretionary ore, now composed largely of carbonate, spessartine, quartz, and chlorite, closely resembles the pattern for the caryopilite-carbonate protolith at the Buckeye (fig. 78, B112). Caryopilite and carbonate are reasonable protoliths for the observed mineral associa- tion of the yellow layers at Harlech. Microspherulitic ore is reported to be composed of carbonate, but the REE patterns are more enriched than those of Buckeye rhodochrosite. Perhaps this distinction can be attributed to the opaque phase, presumably a Mn-oxide, that is evident in Bennett’s photomicrograph (1987, his fig. 7C). The “average carbonate” (Bennett, 1987, p. 13) is not described. Like Buckeye carbonate, it has low concen- trations of REE. Like Buckeye gageite, the Harlech carbonate is enriched in the heavy rare-earth elements Yb and Lu. Perhaps Harlech carbonate had a protolith consisting of rhodochrosite and gageite. As in the case of the Hotazel deposits, the Mn-rich sediments of Harlech have similarities to the Buckeye deposit and its modern analogues, but the rhythmic cherts are lacking and the areal extent is larger. Needed is a process to introduce Mn and to disperse it over an area of 190 kmz. Bennett (1987) proposed that this process was the precipitation of oxides or, less probably, carbonates directly from a hydrothermal brine. Were this brine to be denser than cold seawater and to spread laterally to fill a basin, as at the Red Sea (see Bischoff, 1972, his fig. 2), Mn could be spread over an area the size of the Harlech or Kalahari Mn-rich horizons. We conclude this section by noting that there may be more than one environment for the formation of proto— liths that in some way resemble those found at the Buckeye deposit. However, the themes of hydrothermal ORIGIN 61 activity and volcanism are common to descriptions of both modern seafloor deposits and ancient deposits that might, before diagenesis and (or) metamorphism, have had similar protoliths. Lacking is a consistent set of chemical and isotopic observations that can be uniformly applied to all deposits. In many cases, we are not confident that the reported mineralogy is complete or correct. Most serious is the almost total lack of petro- graphic data on internal structures that might help distinguish primary sedimentary processes from diage- netic and metamorphic processes. We urge future work- ers to sample these deposits on the scale of the original sedimentary units and to present petrographic data in addition to chemical data. ORIGIN OF BUCKEYE DEPOSIT The foregoing descriptions provide clues to the nature of the environment in which the Buckeye deposit formed and t0 the processes of manganese concentration and precipitation that might have operated in that environ— ment. By extension, other manganiferous lenses in the Franciscan Complex may have similar origins. We will summarize the local environment, discuss the combina- tion of processes that we believe was responsible for Mn deposition, then move on to discuss the regional geologic frameworks that might permit the operation of these processes. ENVIRONMENT NEAR BUCKEYE DEPOSIT The association of conglomerate, graywacke and shale, chert, and manganiferous units to form a thick unit (the Grummett broken formation) appears to be caused by primary sedimentary processes rather than secondary tectonic juxtaposition. Radiolarian cherts are marine, occur in orogenic belt sequences (Hein and Karl, 1983), and are deposited in environments that are isolated from coarse terrigenous elastic material such as that which would form graywackes. Although it would be conve- nient to call upon tectonic processes to juxtapose the chert and graywacke, no field evidence supports this idea. The Buckeye deposit apparently formed in an environment that permitted the alternation of chert- forming and graywacke-forming processes. There is evidence for a high-energy distant environ- ment and a low-energy nearby environment. The occur- rence of thick graywacke units coupled With the coarse basal(?) conglomerate and intraformational shale-chip conglomerate further indicate that one environment had high potential energy, such as might be provided by a continental slope, walls of a rift valley, or slopes leading outward from a midocean ridge or into a trench. The lateral continuity of the thin chert beds and interbedded metashales, which are uniform over at least the scale of outcrop, indicates the presence of a second environment with 10W potential energy that had a gently sloping or flat seafloor, perhaps in the form of a small, shallow basin. The high-energy environment provided differentiated plutonic components (alkali feldspar, quartz, volcanic clasts), ultramafic and mafic components (chromite, ch10- rite), chert, and lithified but not recrystallized sediments (shale chips). The source must have been distant and exposed a cross section including recent sediments, differentiated igneous rocks, and ultramafic to mafic basement. The ribbon cherts, representing the nearby low-energy environment, contain two components. One is clearly local in origin and consists of the debris of siliceous pelagic organisms, Which accumulated on the ocean floor and periodically flowed into the site of manganese deposition. The second component is repre- sented by the fine, claylike material that formed the metashale interbeds and mixed with the accumulating debris of organisms to form the included “dust” and thin partings in the cherts. The similarity between the aver— age TiOZ, A1203, and alkali contents of seven metashales from the Ladd—Buckeye district (the argillites of Hein and others, 1987) and averages for metashales (Petti- john, 1957) and graywacke (Pettijohn, 1963) suggests that the source material for the metashales was detrital, perhaps fine detritus related to the graywacke. This is confirmed by the REE patterns, which mimic those of the graywackes (fig. 7A). Deposition of the metashales was probably continuous, forming a background that was periodically overwhelmed (diluted) by a turbidity flow or deposition of a manganese lens. The combined lack of current structures, algal struc— tures, bioturbation, and calcareous fossils together with the preservation of delicate laminae suggests deposition in deep water, consistent with the topography necessary to accelerate the turbidites. The depth of the seafloor is not known; the absence of calcareous skeletal debris and the relatively low concentrations of CaO in the ores and surrounding sediments suggests deposition below the carbonate compensation depth (or, conversely, suggests that there were no pelagic calcium-secreting organisms). The abundance of radiolarian chert suggests oceanic upwelling that enriches surface waters in nutrients (Hein and Parrish, 1987). Because even hot solutions vented at the seafloor have been observed to move laterally rather than reach the surface of the ocean (Klinkhammer and others, 1986; Baker and Massoth, 1986), it seems unlikely that there would be a direct connection between fluids vented at the ocean floor and a pelagic bloom near the surface. 62 MICROBANDED MANGANESE FORMATIONS: PROTOLITHS IN THE FRANCISCAN COMPLEX, CALIFORNIA MANGANESE DEPOSITION AT BUCKEYE DEPOSIT Traditional interpretation of the origin of deposits such as the Buckeye involved inorganic hydrothermal pro- cesses that culminated in thermal springs and precipi- tates on the ocean floor. Recently Hein and others (1987) and Hein and Koski (1987) invoked organic diagenesis at depth that culminated in the replacement of chert by manganese carbonate within the sediment pile. This model provides a plausible explanation for the source (quadrivalent Mn oxyhydroxides in the sediment column) and solubilization (reduction to Mn+2 state) of the man- ganese. It also provides a mechanism (methanogenesis and subsequent oxidation to COZ) for generating carbon— ate that is strongly depleted in 13C. An origin involving only diagenesis and replacement, however, is not com— patible with all features at the Buckeye deposit. Our principal objections to a model based on diagenesis and replacement are the following. (1) Despite the large number and diversity of samples examined, we observed no islands of relic (unreplaced) chert. (2) There is evidence that Mn was removed from, not introduced into, the chert at the margin of the orebody. (3) We observed no cases in which the orebody transected the layering of the surrounding chert. (4) The scale at which most of the ore is laminated is finer than the scale of layering within the chert and metashale. (5) There is a large halo of Mn enrichment, rather than Mn depletion, surrounding the orebody. The MnO content decreases from an average of about 50 weight percent in the orebody to about 5 weight percent in the adjacent wallrocks drilled by Volin and Matson (1949). Average values for different lithologies in the series chert- metashale from the Ladd-Buckeye district range from 0.21 to 1.29 weight percent MnO and 1.20 to 8.57 weight percent total iron as Fe203 (Hein and others, 1987). Compared with broader scale averages (Pettijohn, 1957; Cressman, 1962), these materials appear enriched, not depleted, in MnO. Additional analyses (Huebner and Flohr, unpub. data) of chert and shale from the vicinity of the Buckeye deposit confirm the MnO enrichment. The MnO concentrations of seven graywackes range from 0.02 to 0.74 weight percent and thus, overall, appear enriched rather than depleted in MnO (compare with Pettijohn, 1957, 1963; Taylor and McLennan, 1985). (6) According to the model, silica replaced by rhodochrosite contributed to the formation of massive chert (Hein and others, 1987, p. 220). However, the so-called massive chert is thinly layered (bedded). The displaced silica has not been found. (7) The model does not provide a mechanism to form layers of six to nine distinct compo- sitions in the orebody. Further, the massive chert and interbedded chert and metashale lack the lithologic (com- positional or textural) diversity of the orebody, making it unlikely that the observed layering in the orebody reflects layering of some precursor. (8) Gel-like materials occur in the orebody, yet we would not expect such fine-grained materials to form during the replacement of chert and shale or to survive burial diagenesis in a wet, warm environment. (9) The spherulitic and botryoidal textures ascribed by others to precipitation of rhodo- chrosite during diagenesis are rare at the Buckeye and, where they do occur, clearly replace earlier, very fine grained rhodochrosite. (10) The Mn protoliths, including the Mn-silicates, have depleted REE patterns, relative to those of the chert and metashale (fig. 7). Claylike silicates formed by replacement inherit the trace- element signatures of their precursors (Mosser, 1979; Mosser and others, 1979). If the Mn protoliths, including the silicates, formed by replacement, we would expect less-depleted REE patterns. (11) The orebody and sur- rounding graywackes are sulfide poor, yet the suggested diagenetic reactions would have brought together dis- solved Fe+2 and HZS' to precipitate FeSZ. (12) Diagen- esis of organic matter produces methane only after all ferric iron is reduced to soluble Fe”. Thus, in the absence of a sink for iron (precipitation as sulfides), the model fails to explain the high Mn/Fe observed in the orebody. (13) The model calls for zones of Mn reduction and oxidation, separated by a zone of diffusion. Such a process should result in a single Mn-rich layer or single set of Mn-rich layers, one of each protolith. It is difficult to imagine a diffusion process at depth that will produce cyclically alternating compositions, such as the carbonate and caryopilite observed at the Buckeye. Were the oxic zone raised, the zone of Mn precipitates should be dissolved and reprecipitated at a higher level. There is no petrographic evidence for such a shift in position. (14) It is unlikely that diffusion alone would be the mechanism for scavenging Mn from the surrounding volume of chert, metashale, and graywacke. Considering the distances involved (the zone of Mn enrichment extends hundreds of meters), it is probable that moving fluids played an important part in transporting the manganese. (15) The diagenetic model accounts for the absence of modern deposits like the Buckeye by having them form beneath the seafloor but does not explain the absence of modern equivalents of the associated interbedded cherts and metashales, which must have formed on the ocean floor. Until the modern environment for deposition of interbed- ded chert and shale is found, the modern environment for deposition of a Buckeye deposit cannot have been found. Our model, based on a cool hydrothermal system, combines diagenesis to dissolve the manganese incorpo- rated in the sediment column, fluid flow to transport the Mn, and precipitation at the seafloor to develop the fine laminations and diversity of compositions. These pro- cesses will be discussed in the sequence in which they interact with fluid in the sediment pile. ORIGIN 63 Oxic and mildly suboxic diagenesis occurs near the top of the sediment column. This process consumes buried organic matter using, as an oxidant, oxygen that is dissolved in the pore fluid, that is bound to quadrivalent Mn, or that diffuses (as molecular 02) downward from the water column. The Mn+2 produced is dissolved in the pore fluid. Some CO2 dissolves to form H2003 and HCOQ. At the same time, the fluid equilibrates with opaline skeletal debris, taking some silica into solution. Deeper in the sediment column, intensely suboxic and anoxic conditions occur, but any Fe”, HZS_, and CH4 produced under these conditions are precipitated in place or, if they migrate upward, oxidized and perhaps precip- itated before they reach the upper levels. The oxidants are carried by fluids that pass through the sediment column. Iron is precipitated as oxyhydroxide (or sulfide), HS‘ is converted back to SOQZ, and CH4 is oxidized to CO2 with negative 8130 before reaching the mildly sub- oxic and oxic zones. Some 002 and CH4 may move as vapor bubbles. An important element of the diagenetic portion of the model is that any anoxic fluids are neutral- ized (made mildly suboxic) by interaction with oxic to suboxic fluid—either slightly modified seawater that circulates beneath the seafloor or pore fluids expelled by compaction from deeper and less organic-rich (or less reactive) sediments. The results are a supply of aqueous fluid carrying dissolved species of Mn, 002, and SiOz, the absence of sulfides, and Fe-poor precipitates, as observed at the Buckeye deposit. The source of the manganese is enigmatic. Mafic volcanic rocks, which appear in models for seafloor mounds, are not part of the stratigraphic column at the Buckeye, although such volcanic rocks are spatially associated with many other manganese deposits in the Franciscan Complex. The most likely source of manga- nese is the sediment column, including the interbedded chert—metashale, as in the diagenesis model of Hein and Koski (1987), or the graywacke, from which manganese could be leached and transported in the divalent state by relatively reducing solutions. The source sediment could lie below the deposit or be laterally displaced from it. The source might even be a lithology that is not represented in the Grummett broken formation. Dissolved constituents, and perhaps included vapor bubbles, were transported by fluids that flowed within the sediment column and vented at the seafloor. The forces driving the fluids were heat and (or) pressure. Heat would cause convection that draws fresh, oxygen- ated seawater into the sediment column; favored pas- sageways would be channels that open to the seafloor. As a result of sediment compaction, pressure would expel fluids into channels and upward toward the seafloor. In a tectonically active environment, such as that in which the Buckeye formed, semiconsolidated and consolidated sed- iments would be expected to have been fractured and to influence fluid flow at higher levels, much as fractures in sediment-covered basalts are thought to influence the distribution of mounds and vents near midocean ridges. Fractures, ranging from the quartz- and carbonate- bearing shear zones that separate broken formations (fig. 13) to veins that cross Mn-rich sediments but do not deposit Mn minerals (figs. 4A,E,J) are evidence that moving fluids were channeled. In one case (fig. 4A, B87), hausmannite-rich layers became more carbonate rich near the vein, suggesting that the vein fluid had lower redox potential than the original sediment and was COz—rich. Fluid flow permitted scavenging of Mn from distances greater than diffusion fields, separation of the anoxic region of methane generation from that of ore precipitation, and rapid delivery of ore-forming constit— uents. The ephemeral nature of vein systems, which open and close in response to tectonic disturbances, subsidence, and precipitation, provides a means for quickly turning the supply of ore—forming constituents on and off, leading to groups of orebodies, each with sharp boundaries against the enclosing cherts. Mixing of fluid from within the sediment column with fresh seawater and subsequent precipitation on the sea- floor satisfies many of the observed constraints. There will be no residues—as phases or chemical signa- tures—of a replaced lithology. Because the composition of the mixedfluid will vary with the composition of the subsurface fluid, the flow rate of the vented fluid, and the degree of mixing with fresh seawater, the nature of the precipitated layers may change with time or distance from the vent and may show cyclical variation, and the layers may be thick or thin. The model permits rapid delivery of ore-forming materials, necessary to avoid contamination (terrestrial, hydrogenous, or diagenetic), and rapid precipitation from the fluid mixture, necessary to localize the deposit. Changes in the fluxes supplying chemical components to the depositional site varied and caused compositional layering within the orebody. These variations must have been rapid, perhaps on the scale of seasonal climatic variations that, through winds, affected the upwelling of nutrients and that have been shown to affect the rates at which diatom tests are supplied to the seafloor (Honjo, 1982; Takahashi, 1986). Fluids from the sediment column probably provided fluxes of dissolved Mn, SiOz, 002, and minor to trace amounts of the “hydrothermal” elements such as Zn. Seawater probably contributed fluxes of 02, MgO, and minor and trace amounts of Ba, Mo, V, and 804. The composition of the seawater itself may have varied, particularly with respect to dissolved 02, which could vary seasonally. Thus, the valence of Mn in indi- vidual protoliths, and the Ge anomaly, could depend not 64 MICROBANDED MANGANESE FORMATIONS: PROTOLITHS IN THE FRANCISCAN COMPLEX, CALIFORNIA only on the ratio of fluids in the mixture but upon the composition of the seawater component. DIAGENESIS AND METAMORPHISM The relatively oxidized sediments (Mn+3 is present) were preserved rather than subsequently modified by diagenesis. Had the Mn—rich precipitates experienced suboxic diagenesis after burial, braunite, and perhaps hausmannite, would not have survived. We presume that little organic matter was buried with the Mn—rich and surrounding sediments or, if present, that it was isolated from the deposit. Our observations provide seemingly contradictory evi- dence for the existence of a fluid phase during diagenesis and metamorphism. By analogy with modern marine sediments, we presume the initial graywacke sands, cherts, shales, and Mn—rich layers were very water rich. Veins of quartz, aragonite, and calcite clearly mark fluid pathways. However, the non-uniform distribution of jadeite within the Grummett broken formation, the presence of relic gel-like materials within the orebody, and the preservation of oxidized Mn (in braunite) suggest the absence of a fluid phase that would promote recrys- tallization or regional redox equilibrium. To reconcile these observations, we propose that compaction during burial and subsidence expelled most of the trapped pore fluids throughout the section, leaving relatively dry (and thus unreactive) materials, such as chert. Subsequent fluid loss at metamorphic pressures was concentrated along the contacts between the broken formations, at some distance from the Buckeye orebody. These contacts were kept open to fluid loss by shearing, which appears to have been sufficiently intense, in some cases, to transport dense blocks of glaucophane-bearing schists. Fluid in these shear zones may ultimately have reached seafloor vents. Higher metamorphic temperatures at greater depths may have caused decomposition of the clay- and chlorite-rich matrix of the metagraywackes, providing an additional source of fluids. The Mn—rich mineralogy at the Buckeye provides a clear record of high oxygen-fugacity values during meta— morphism. The occurrences of braunite and hausmannite clearly record an intrinsic oxygen fugacity that is orders of magnitude greater than that of the surrounding gray- wackes (Huebner, 1967, 1976), which contain ferrous silicates (table 5) and, probably, organic matter. Because this f02 is so high, it cannot have been brought about by metamorphic equilibration with surrounding rocks and must reflect the premetamorphic history of the sedimen- tary environment (Huebner, 1967). Huebner (1969, p. 476) suggested that there might be oxidation halos surrounding such highly oxidized orebodies. In the case of the Buckeye, the surrounding interbedded chert and metashale are highly oxidized, but this state is probably a primary rather than a secondary feature. It is more difficult to read the metamorphic temperatures and pressures. One difficulty is the absence, in the Buckeye deposit, of mineral associations that can be proven to be equilibrium assemblages. By analogy with howieite, which is thought to be stable only at high pressure and low temperature (Lattard and Schreyer, 1981), the occurrence of the mineral taneyamalite might indicate high pressures of formation. Calculations by Huebner (1967) indicated that the partial pressure of CO2 at the stage recorded by the mineralogy was an order of magnitude less than the total pressure estimated from the mineral assemblages in the metagraywacke. Either no fluid phase was present or the fluid was dilute with respect to C02. At such high f02 values and equilibrium, CO, CH4, and H2 would not be abundant species. There- fore, any fluid present during metamorphism must have been aqueous. But preservation of relic gel-like materials suggests that an aqueous phase was not present during metamorphism and therefore that no fluid was present. REGIONAL FRAMEWORK The spatial and temporal relations between the sites of Mn deposition and deep burial (blueschist-facies meta— morphism) are enigmatic. Convecting fluid, even cool water, requires a heat source, yet rapid subsidence that generates 5—8 kbar pressure without exceeding 150—200 °C requires a small regional thermal gradient. If the Buckeye Mn lenses were precipitated from fluids driven by a heat source, it must have been highly localized, decayed before subduction, or moved relative to the lenses. However, if manganese and 002 were dissolved in, transported by, and precipitated from fluids expelled by compaction of the sediment pile, it is conceivable that no heat source would be necessary. POSSIBLE ENVIRONMENTS Mn-rich mounds have been observed to form in oceanic island arcs and oceanic spreading centers, where they are associated with high heat flow and nearby hot or warm fluids. If cooler fluids can leach manganese and iron from the sediment column, Mn—rich mounds might occur in two additional environments. One is the abyssal floor at great distance from the midocean ridge. Here, hemipelagic sediments should be underlain by mafic and ultramafic ocean crust. Were serpentinization and other alteration processes not completed in the crust—forming ridge environment, they would continue, albeit at much lower temperatures, as the crust moved away from the ridge, releasing sufficient heat to drive fluid convection ORIGIN 65 and causing an increase in rock volume (Fyfe, 1974). This volume increase might fracture the overlying sediments, thereby channelling fluids. In the geologic record, these deposits would be found associated with hemipelagic sediments but, unless subsequently juxtaposed by tec- tonics, probably not with graywacke turbidites. Another environment is the top of a subduction complex. Water- rich sediments in the trench (or surficial expression of the subduction complex) would release cool pore water as they were subducted. The boundaries between slabs of sediments would serve as channels for escaping fluids. Vents or chains of vents might occur on the walls of the trench. If cool fluids are able to leach manganese from the sediments, mounded deposits of Mn-rich precipitates might form on the trench walls. In which paleoenvironment were the Buckeye deposit and related sediments of the Grummett broken forma- tion deposited? Raymond (1974, p. 145) originally pro— posed that the Franciscan rocks of the Mount Oso area were deposited in an environment characterized by “a combined trench—abyssal ocean-floor plus ocean ridge.” Subsequently (Raymond, 1977) he associated the manga- niferous sediments with seafloor spreading centers. Sny- der (1978) reviewed the literature on manganese de- posits associated with chert-greenstone complexes, including deposits in the Franciscan Complex, and chose environments in which oceanic hot springs could form: oceanic spreading centers, marginal oceans, and the base of island arcs and oceanic islands. Crerar and others (1982) favored an oceanic spreading center over island arcs, back—arc spreading centers, and convergent plate margins. Hein and others (1987) interpreted the Fran- ciscan sediments of the Ladd-Buckeye district as having been deposited near a continental margin, then made reference to possible fore-arc, back-arc, and rifted con- tinental margin settings. Subsequently, Hein and Koski (1987) advocated a deep, rapidly deposited continental margin facies, such as the Yolla Bolly terrane of northern California described by Blake and others (1982). Ray- mond (1988) disagreed with the analogy because it refers to chert—poor lithologies, whereas the Grummett broken formation is chert rich. To choose the most appropriate environment, we need first to review the facts that serve as boundary condi- tions for the range of possible environments. (1) The cobble conglomerate exposed near the base of the Grum- mett unit must have been derived from an environment with substantial topographic relief and must have been deposited relatively near its source. (2) There must have been three or four sources for the elastic sediments and pathways by Which detritus could move from each source to the depositional environment. (3) These sources sup— plied quartz-rich but lithic-fragment—poor sands. (4) The boundaries between conglomerate, metagraywacke, interbedded chert and metashale, and the manganese deposit are primary sedimentary contacts. Thus, the depositional environment must be capable of generating these four basic lithologies in a continuous stratigraphic section. (5) The chert layers are turbidites that were deposited in an environment that was intermittently exposed to a supply of coarse detritus. (6) The manga- nese deposit has the size, morphology, and trace-element composition of a deposit that is genetically associated with a seafloor vent. (7) The compositional layering of the orebody signifies an environment in which the deposi- tional parameters changed frequently. (8) Mn deposits such as the Buckeye are invariably associated with chert and shale. Mn deposits are not enclosed in graywacke. (9) Some Mn deposits, unlike the Buckeye, are associated with basalt. (10) The metagraywacke and enclosed sedi- ments at the Buckeye were together subjected to the high pressures and low temperatures characteristic of subduction complexes at continental margins. Given these boundary conditions, we can eliminate two envi- ronments. The abyssal floor model is unsuitable. Unlike the environment in which the Buckeye formed, the abyssal environment has low topographic relief and lies far from possible sources of the cobble conglomerate and quartz- rich graywacke. Although possible sources of heat are mantle hot spots or serpentinization of heretofore unal- tered oceanic crust, serpentinization is unlikely. Were this process to operate, fluids convecting through the sediment pile must have supplied the H20 necessary for serpentinization and, by association, become alkaline (high pH). Such fluids would be too alkaline to leach and transport manganese and iron (Barnes and O’Neil, 1969). Thus, even though the ocean crust With its mantle of abyssal sediments might be carried into a subduction complex, the crust is unlikely to arrive with manganese deposits such as the Buckeye. Deposition of manganese within the trench is an appealing hypothesis because it directly involves the subduction complex and provides a mechanism for bring- ing together sediments of diverse origins. We postulate two variations on the model associated with trenches. In the first, the fluid-expulsion model, compaction Within the pile forces Mn-bearing fluids upward along shear zones between subducted slices of terrane. Because the dominant lithology is graywacke and the observed shear zones are in graywacke, we would expect at least some deposition of Mn-rich lenses on graywacke sands. The fact that the Mn-lenses are invariably associated With chert, a minor lithology, contraindicates the first mech— anism. Further, the model also fails to explain the presence of submarine basalts, which underlie the cherts that are associated with many Mn lenses in the Fran- ciscan Complex and elsewhere. If the Buckeye formed by 66 MICROBANDED MANGANESE FORMATIONS: PROTOLITHS IN THE FRANCISCAN COMPLEX, CALIFORNIA the same set of processes that formed the Mn deposits that are closely associated With basalt, the model in Which fluids were expelled by compaction is also inap- propriate for the Buckeye deposit. The second trench—related hypothesis involves the subduction of a midocean ridge at a continental margin. A possible modern example is the collision of the Chile Rise with the Peru—Chile trench (see Forsythe and others, 1986). In this model, the continental margin is a region of oceanic upwelling that brings nutrient-rich waters to the surface and causes high organic productiv- ity (radiolarians). As the ridge (with its grabenlike topography) approaches the trench, chert and shale are deposited in protected basins, either directly on ridge basalt or on graywacke. Graywacke sands and conglom- erate, derived from dissected, quartz—rich continental crust, flow into the trench and periodically spill into protected basins on the oceanic side of the trench axis, blanketing all other lithologies. Some coarse conglomer- ates and graywackes are locally derived from trench walls that oversteepen and collapse. The distal portions of both locally derived and distant flows provide a continuous supply of fine detritus that settles slowly to form shale. Shale deposition is frequently overwhelmed by flows of sands derived from the sites where the debris of radiolarians settles. Thus, the scene is set for Mn deposition on chert that can be both closely associated with, and distant from, basalt. Residual heat from the decaying ridge or from short-lived, near-trench thermal events (predicted by DeLong and Fox, 1978) drives fluid circulation that leaches, transports, and deposits Mn by the processes previously discussed. The residual heat is, in most cases, insufficient for continued basaltic magma- tism. Some fluid could also be driven by expulsion from the sediment pile. Subduction buries the Mn deposit and may tectonically dissociate the Mn mounds or lenses (and their host rocks) from oceanic basement and crust formed at the ridge. To be acceptable for the Buckeye deposit, the ridge- trench model must be compatible with the evolution of what is now western California. Schweikert and Cowan (1975), Dickinson and others (1982), Ingersoll (1982), and Seiders and Blome (1988), who drew upon numerous earlier studies, provide useful summaries. In Middle Jurassic time, there existed a west-facing continental- margin arc and, to the west, an east-facing oceanic arc. Farther to the west, there must have been a spreading center (source of oceanic crust) such as the back-arc spreading center of Ingersoll (1982). By Late Jurassic to Early Cretaceous time (the dates of microfossils within the Grummett broken formation), the oceanic crust between the two arcs had been subducted, leaving the single westward-facing Sierran-Klamath magmatic arc complex, trench, and remnant of the spreading {J .7 .w TSC FAB SL OSC cc DMA €72 cc SL TSC MiddIe Cretaceous FIGURE 15.—Possible mechanism for the creation of the paleo- depositional environment for the Buckeye protoliths, adapted from Dickinson and others (1982) and Ingersoll (1982) with embellish- ments. Drawn not to scale but to emphasize features of the deposi- tional environment. During the Late Jurassic, an oceanic spreading center (OSC) with median valley containing restricted basins approached the continental margin, a source of quartz-bearing sands. The spreading center was consumed by subduction by Early Creta- ceous time. If the spreading center was still warm as it approached the trench and subduction complex (TSC), hydrothermal Mn—rich deposits (Mn, black), and hemipelagic sediments (HPS, cherts and shales) could form near the continental margin, perhaps in locally sheltered basins or along remnants of the median valley (MV). Turbidity flows of sand, originally derived from the dissected Sierran-Klamath magmatic arc (DMA), flowed longitudinally north- ward along the axis of the trench and fanned outward, forming massive graywackes (stippled). Episodically, major sand-laden cur-- rents overflowed the restricted basins, permitting the stratal inter- layering of hemipelagic sediments and graywackes. Other abbrevia- tions: SL (sea level); GVS (Great Valley sequence) deposited on CRO (Coast Range ophiolite); OC and CC (oceanic and continental crust, respectively); FAB (forearc basin); SC (subduction complex). center (fig. 15). The Great Valley sequence was depos- ited in the forearc basin immediately to the west of the eroded are complex. Farther westward, Franciscan sed- iments flowed both westward and longitudinally from the south. These sediments were deposited along (and fanned westward from) the break in slope formed Where the eastern trench slope and the oceanic crust met. At the same time, oceanic crust east of the remnant spread- ing center was consumed by the trough-subduction REFERENCES 67 complex, bringing the spreading center toward the trench. If the spreading center was still warm as it approached the trench, or if fluids were expelled from the sediment pile, the scene was set for operation of the ridge-trench model as outlined above. Manganese depos- its and cherts, some but not all associated with basalt, formed. Subsidence and deep burial deformed the sedi- ments, expelled fluids, and caused the blueschist—facies overprint. SUMMARY AND FUTURE WORK Textural, mineralogical, microchemical, and trace- element data collected from similar (and spatially related) metasediments from the Buckeye deposit sug- gest that manganese carbonate, silicates, and oxides were deposited at the seafloor from dilute mixtures of hydrothermal fluid with seawater. Although similar deposits have been described in the literature, our data focus on well-characterized individual sedimentary lay- ers rather than on individual mineral grains within a layer or on groups of layers. The chemistries of the individual layers and laminations record fluctuations in the marine environment, caused in part by periodic flows of radiolarian sand. At the Buckeye, the contrasting layer compositions record eight sedimentary compo- nents, which must contain valuable clues to the geochem- ical and sedimentological variables in both ancient and active marine environments. N o doubt other manganese deposits formed in a similar environment, but to our knowledge the Buckeye is the only described deposit that reveals more than one Mn-silicate protolith. The appar— ent uniqueness of the Buckeye is probably due more to the inadequacies of available descriptions than to any singularity in the geologic record. It is also possible that similar deposits are forming on the seafloor today. We need to be certain that the reasoning leading to the characterization of Mn-forming environments and proc- esses does not become circular. Especially frail is the path of reasoning (1) chert and layered manganese deposits that are closely associated with basalt are volcanogenic, (2) therefore most chert and layered man- ganese deposits, even those not associated with basalt, have a volcanogenic origin, and (3) a particular layered manganese deposit formed by volcanogenic processes. The discovery and characterization of actively forming, laterally restricted volcanogenic-hydrothermal Mn-oxide deposits has done much to strengthen the reasoning, but interbedded manganese oxides, silicates, and carbonates have not yet been found in modern environments, and laterally extensive deposits occur in the geologic record. Until we know why these ancient layered deposits differ from the actively forming deposits, we cannot be certain that the depositional environments are similar. Detailed studies of the Buckeye deposit provide a basis for two research directions, now being undertaken. (1) We are attempting to characterize the chemical signa- ture of each sedimentary component in order to verify the sources of each of the chemical constituents and to discover the nature and causes of the variations in the seafloor environment. In particular, we want to develop criteria that will enable us to distinguish between mafic igneous rocks and the sediment column as sources of manganese, iron, and base metals, and we want to make firm our hypothesis concerning the role of biogenic silica. We hope that the results of this effort will help us understand the origin of laterally extensive stratiform manganiferous sheets that are not associated with chert. (2) We are using petrographic and microchemical crite- ria, developed with reference to the Buckeye deposit, to determine the protoliths of deposits that have lost their obvious primary characteristics due to pervasive meta- morphism. If correctly read, such deposits may be valu- able paleoenvironmental indicators in high—grade meta- morphic terranes. 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COVER.—Mississippian formations in Burnside quadrangle, Pulaski County, Kentucky; Monteagle Limestone, Hartselle Formation, Bangor Limestone. and Paragon (formerly Pennington) Formation. “LUUMENTS DEPARTMENT JAN 14 1991 1 a LIBRARY~l g. NWERSITYWQLQ flown Mississippian Rocks in Kentucky By EDWARD G. SABLE ana’ GARLAND R. DEVER, JR. U.S. GEOLOGICAL SURVEY PROFESSIONAL PAPER 1503 Work done in cooperation with the Kentucky Geological Survey Strata representing Kinderhookian, Osagean, Meramecian, ana’ Chesterian Series and equivalents reflect largely marine deposition in shallow cratonic basins and on shelves and platforms UNITED STATES GOVERNMENT PRINTING OFFICE, WASHINGTON: 1990 DEC 1 71990 DEPARTMENT OF THE INTERIOR MANUEL LUJAN, JR., Secretary U.S. GEOLOGICAL SURVEY Dallas L. Peck, Director Library of Congress Cataloging-in-Publication Data Sable, Edward G. (Edward, George), 1924— Mississippian rocks in Kentucky / by Edward G. Sable and Garland R. Dever, Jr. p. cm. — (U.S. Geological Survey professional paper ; 1503) “Work done in cooperation with the Kentucky Geological Survey.” “Strata representing Kinderhookian, Osagean, Meramecian, and Chesterian series and equivalents reflect largely marine deposition in shallow cratom'c basins and on shelves and platforms.” Includes bibliographical references. Supt. of Docs. no.: I 19.16: 1503 1. Geology, Stratigraphic—Mississippian. 2. Geology—Kentucky. I. Dever, Garland R. II. Kentucky Geological Survey. III. Title. IV. Series. QE672.822 1990 551.7'51'09769—dc20 89—600367 CIP For sale by the Books and Open-File Reports Section, U.S. Geological Survey, Federal Center, Box 25425, Denver, CO 80225 Any use of trade, product, or firm names in this publication is for descriptive purposes only and does not imply endorsement by the U.S. Government. CONTENTS Page Page Abstract ........................................... 1 Mississippian rocks—Continued Introduction ....................................... 1 Rocks of mostly Osagean age—Continued History of investigations ......................... 2 Age ---------------------------------------- 53 Scope and methods .............................. 2 Paleotectonic implications ..................... 53 Acknowledgments ............................... 3 Osagean-Meramecian series boundary ............... 54 Geologic framework .............................. 3 Rocks of late Osagean and Meramecian age ......... 55 Physiography, outcrop, and scenic features .......... 20 afifibfiiegggmm """""""""""" g: D”Eifiiifi‘séifiéfi’xgi‘ffid' ensue; : : :1: 1:: : :3 Seleee Lieeeeeee end seem eee Weeeew Feeeeeem Bedford Shale and Berea Sandstone ................ 31 “m :"2 """""""""""""""""""" 56 Devonian-Mississippian systemic boundary 32 St' Louis Limestone """""""""""""" 58 _ , , , """"""" Ste. Genevieve Limestone ..................... 61 MISSISSIPPI” rocks ' ’ ‘ " """"""""""""""" 33 Stratigraphic relationships ..................... 66 R001“ of @flefihmklan and early Osagean age (Early St. Louis and older unit relationships ........ 66 MISSISSIPPI”) """""""""""""""" 33 St. Louis-Ste. Genevieve relationships ....... 67 Sunbury Shale ---------------------------- 33 Sources of sediments and depositional environments 69 Maury Formation equivalent ................... 33 Paleotectonic implications ..................... 71 Rockford Limestone .......................... 35 Meramecian-Chesterian series boundary ............. 71 Kinderhookian-Osagean unit relationships ........ 35 Rocks of Chesterian age .......................... 72 Paleotectonic implications ..................... 36 Rocks west 0f the Cincinnati arch .............. 73 Rocks of mostly Osagean age ..................... 36 Carbonate-dominated units ................. 73 Borden Formation ............................ 36 Terrigenous elastic units ................... 74 Farmers Member ......................... 33 Rocks east of the Cincinnati arch ............... 77 Nancy and New Providence Members ''''''' 39 Lithologic trends and interbasin correlations ..... 82 Cowbell, Halls Gap, and Holtsclaw Members . . 40 Sources of sediments and depositional environments 85 Nada and Wildie Members ................. 40 Paleogeography and paleotectonic implications ' ‘ ' 87 Re fr M be 42 Mississippian-Pennsylvaman-younger rock relationships . . A 87 n O em 1' ........................... . . . Summary of thicknesses and lithologic trends ........... 92 Muldraugh Member ....................... 45 C li d 't' 103 yc c eposi ion .................................... Floyds Knob _Bed """"""""""""" 45 Paleontology ....................................... 104 Gramger Formation .......................... 48 Macrofossils __________________________________ 104 Fort Payne Formation ------------------------ 48 Microfossils ..................................... 107 Strata overlying Borden and Fort Payne Formations 51 Conodont identifications ....................... 107 Depositional history of the Borden and Fort Payne Flora .......................................... 107 Formations ................................ 51 References cited .................................... 113 ILLUSTRATIONS Page PLATE 1. Map of Kentucky showing 71/2-minute quadrangles ................................................. In pocket FIGURE 1. Map showing generalized structural elements of Kentucky and adjoining areas ........................... 4 2. Map showing distribution of Mississippian, pre-Mississippian, and post-Mississippian rocks exposed in Kentucky 5 3. Map of Kentucky showing 71/2-minute quadrangle boundaries and geographic divisions used in this report . . . . 5 4. Index map of Kentucky showing quadrangles in which Mississippian rocks are exposed .................... 6 5. Map of Kentucky showing control point localities of Mississippian surface and subsurface information other than that from geologic quadrangle maps ............................................................ 7 6. Pre-Pennsylvanian—post-Ordovician Megagroups and Sequences in the Eastern Interior basin and adjoining areas 20 7. Correlation chart showing stratigraphic nomenclature of the Mississippian System in Kentucky and Illinois . 21 8. Correlation chart showing stratigraphic nomenclature of the Chesterian Series‘and equivalent strata in Kentucky 22 9. Cross section showing Mississippian rock units and relationships in Kentucky ............................ 23 10. Physiographic diagram of Kentucky ................................................................ 24 11. Map of Kentucky showing locations of selected exposures of Mississippian rocks, highways. and other features 25 III IV FIGURE 12. 13. 14. 15. 16. 17. 18. 19. 20. 21. 22—27. 28. 29. 30. 31. 32. 33. 34. 35. 36-40. 41. 42. 43. 44. 45. 46. 47—49. 50. 51-64. CONTENTS Map showing thickness of Upper Devonian rocks and their relationship to major structural elements in the east- central United States ........................................................................ Diagram showing generalized relationships between Berea Sandstone and ‘Bedford Shale in Vanceburg quadrangle, northeastern Kentucky ........................................................................ Photograph of Sunbury Shale overlying the Bedford Shale and underlying the Farmers Member of the Borden Formation .................................................................................. Photograph of Maury Formation equivalent ......................................................... Map showing distribution, thickness, and sedimentary transport directions of selected sandstone units in the Borden and Fort Payne Formations in Kentucky ........................................................ Restored cross section of the Borden Formation delta “front” in Howardstown quadrangle, north-central Kentucky, showing relationships of Borden units ........................................................... Generalized stratigraphic diagram of lower part of the Borden Formation and underlying units in northeastern Kentucky ................................................................................... Photograph of Borden Formation; contact of Cowbell Member and underlying poorly resistant Nancy Member Sections showing relationships of siltstone units in the Borden Formation in the area between Brodhead and Bighill, east-central Kentucky ......................................................................... Diagrams showing relationships of the clastic units of the Borden Formation, central and south-central Kentucky Photographs showing: 22. Nancy Member and overlying Muldraugh Member of the Borden Formation ........................ 23. Cowbell Member of Borden Formation (siltstone and shale) ...................................... 24. Halls Gap and Muldraugh Members of Borden Formation ....................................... 25. Nada Member of Borden Formation and overlying Slade Formation consisting of Renfro Member and limestone and dolomite mostly of the St. Louis and Holly Fork Members ............................... 26. Dolosiltite and calcarenite 1n Muldraugh Member of the Borden Formation ........................ 27. Upper part of Muldraugh Member of Borden Formation showing westward- -thickening calcarenite lenses Generalized diagram showing relationships of Salem- Warsaw, Salem, Harrodsburg, Borden, and Fort Payne Forma- tions in three Kentucky quadrangles ............................................................ Photograph of Fort Payne Formation in roadcut along launching ramp road, Lake Cumberland State Park Photograph of Salem and Warsaw Formations undivided and lower part of St Louis Limestone ............. Map showing approximate distribution of Science Hill Sandstone and Garrett Mill Sandstone Members of Warsaw Formation and J abez and Knifley Sandstone Members of Fort Payne Formation 1n south-central Kentucky Photograph of cherty dolomite in upper part of St Louis Limestone .................................... Photograph of dolomite 1n middle part of St Louis Limestone .......................................... Generalized diagram showing relationships between Ste Genevieve and St. Louis Limestones in part of western Kentucky ................................................................................... Stratigraphic section and description showing lithologies of St. Louis and Ste. Genevieve Limestones and Lost River Chert Bed, west-central Kentucky .............................................................. Photographs showing: 36. Lost River Chert Bed ...................................................................... 37. Ste. Genevieve and St. Louis Limestones ...................................................... 38. Upper part of Mooretown Formation, Beaver Bend Limestone, and shale and sandstone of the Sample Sand- stone ................................................................................. 39. Big Clifty Sandstone Member of the Golconda Formation ....................................... 40. Hardinsburg Sandstone conformably overlying Haney Limestone Member of the Golconda Formation . . Generalized map and cross section showing distribution and relationships of Mooretown Formation-Bethe] Sand- stone channel fill in central to western Kentucky .................................................. Diagram showing relationships of Glen Dean Limestone. Tar Springs Formation, and lower part of Buffalo Wallow Formation, west-central Kentucky .............................................................. Photograph of roadcut mostly in Slade (Newman) Formation, Rockcastle County .......................... Photograph of section at Strunk Crushed Stone Company quarry. Tateville, Pulaski County ................ Diagram showing relationships of Girkin Formation with coeval units of Chesterian age. west-central Kentucky Map showing distribution of sandstone and shale in Big Clifty Sandstone Member of Golconda Formation in west- central, central, and western Kentucky, and Hartselle Formation in south-central Kentucky ............. Photographs showing: 47. Sandstone of Caseyville Formation with basal thin coal bed overlying limestone equivalent of Kinkaid Limestone 48. Caseyville Formation disconformably overlying Buffalo Wallow Formation ......................... 49. Sandstone of Caseyville Formation overlying Vienna Limestone .................................. Generalized cross sections showing Pennsylvanian and and Mississippian unit relationships in northeastern Kentucky Maps showing: 51. Total thickness of Mississippian rocks in Kentucky ............................................. 52. Cumulative thickness of Bedford Shale, Berea Sandstone, and Sunbury Shale in eastern Kentucky, and thickness of approximate age-equivalent strata in other parts of Kentucky .............................. 53. Thickness of terrigenous elastic units of the Borden Formation, New Providence and Grainger Formations, and basal shale beds in the Fort Payne Formation .......................................... Page 31 32 34 35 37 38 39 39 40 41 42 43 44 45 46 47 49 50 56 58 59 60 61 63 64 65 74 75 76 77 78 79 80 83 85 88 89 90 92 93 93 94 FIGURE TABLE 54. 55. 56. 57. 58. 59. 60. 61. 62. 63. 64. CONTENTS Thickness of Muldraugh Member of Borden Formation and of Fort Payne Formation exclusive of basal shale units, and distribution of unusual lithic components ......................................... Combined thickness of Muldraugh—Fort Payne-Salem-Warsaw-Harrodsburg units in central to western Kentucky and probable equivalent Renfro Member of Slade Formation in east-central and southeastern Kentucky ............................................................................. Thickness of Harrodsburg Limestone in central, south-central, west-central, and western Kentucky . . . . Cumulative thickness of Salem, Salem-Warsaw, St. Louis, and Renfro (excluding Muldraugh equivalents) units in Kentucky ........................................................................... Thickness of St. Louis Limestone and St. Louis Member of Newman Limestone and Slade Formation . . Thickness of Ste. Genevieve Limestone and probable and inferred equivalents ...................... Thickness and generalized lithofacies of Chesterian rocks and equivalents in Kentucky ............... Thickness of Kidder Limestone Member of Monteagle Limestone and equivalents in eastern to south-central Kentucky, and cumulative thickness of Paoli Limestone through Elwren Sandstone and Renault Forma- tion through Cypress Sandstone in west-central and western Kentucky ......................... Thickness of combined Hartselle Formation and Bangor Limestone in eastern to south-central Kentucky and thickness of Golconda Formation in west-central and western Kentucky ........................ Thickness of Paragon and Pennington Formations in eastern to south-central Kentucky and combined thickness of Glen Dean—Tar Springs—Vienna—Waltersburg formational units in west-central and western Kentucky Generalized thickness of interval from base of Menard Limestone and equivalent units in Leitchfield and Buffalo Wallow Formations to base of Caseyville Formation ......................................... 65. Diagram of stratigraphic occurrences of Mississippian fossil fauna helpful in recognition of map units in Kentucky 66. Diagram comparing major conodont zonal classifications for the Mississippian System in North America ..... 67. Map showing quadrangles of Mississippian and Devonian conodont-bearing samples in central, east-central. and south- central Kentucky ............................................................................. TABLE S Kentucky 71/z-minute US. Geological Survey geologic quadrangles in which Mississippian rocks are exposed ...... Selected exposures of Mississippian rocks in Kentucky .................................................... Conodonts from top one inch of New Albany and Sunbury Shales in east-central, eastern central, and south-central Kentucky Conodonts from basal part of Nancy (New Providence) Member of the Borden Formation and from basal beds of the Fort Payne Formation in east-central and south-central Kentucky ............................................ Conodonts from basal (New Providence) part of Nancy Member of the Borden Formation in east-central and south-central Kentucky ....................................................................................... Conodonts from basal part of New Providence Shale Member of the Borden Formation in central Kentucky ....... Page 94 95 95 96 96 97 97 98 98 99 99 106 108 109 Page 8 26 1 10 111 112 112 MISSISSIPPIAN ROCKS IN KENTUCKY By EDWARD G. SABLE and GARLAND R. DEVER, JR.l ABSTRACT Mississippian rocks in Kentucky reflect a history of largely marine deposition in shallow cratonic basins and on shelves and platforms. Strata represent the Kinderhookian, Osagean, Meramecian, and Chesterian Series and their equivalents. Maximum thicknesses of more than 2,800 feet of Mississippian strata were deposited in western Ken- tucky in the Eastern Interior basin, and about 2,000 feet in eastern Kentucky on the margins of the Appalachian basin. Positive struc- tural features from which Mississippian strata have been largely eroded and which were alternately submergent and emergent during the Mississippian were the Cincinnati arch and parts of the adjacent Waverly arch. The area of the Pascola arch in westernmost Kentucky was a negative feature during most of Mississippian time. Variations in depositional thicknesses resulted from differential tectonic move- ments, from deposition on surfaces of uneven topographic relief, and locally, from subaerial and submarine erosion. Strata include a wide variety of oomplexly related detrital, chemical, and biologically derived sediments. Crustal instability within parts of the region is recorded by disconformities representing missing strata and by features inter- preted to represent subaerial conditions, but few multiple hiatuses due to widespread epeirogenic movements or eustatic sea-level changes have been recognized within the stratigraphic succession. Limestone and dolomite compose about two-thirds of the Mississip- pian rocks in Kentucky. Carbonate deposition, probably encroaching from the west, reached western Kentucky in Early Mississippian (Kinderhookian) time. During Osagean time deltaic sediments pro- graded westward as far as west-central Kentucky, and carbonates, which were initially restricted to western areas. spread as deposition of terrigenous detritus waned. Carbonate strata reached their max- imum extent during Meramecian time. Although areally more restricted during Chesterian time, carbonate rocks periodically accumulated over large areas in and beyond the Eastern Interior basin and Appalachian basin. Evaporites and associated dolomitic strata were deposited during mid-Meramecian time and marked an episode of restricted circulation related to cratonic tectonism or eustatic changes. Land-derived detrital rocks constitute about one-third of the total preserved Mississippian succession. The greatest volume of sediment was contributed from source areas in highlands northeast and east of the present Appalachians and in the eastern Canadian Shield areas; in Late Mississippian (Chesterian) time, a possible minor source area was a highland to the south or southwest of Kentucky. Large volumes of detritals from northeastern sources were deposited in Kentucky by major river systems and accumulated as deltaic complexes dur- ing deposition of the Lower Mississippian Borden Formation and in Late Mississippian (Chesterian) time. The Cincinnati arch, chiefly a barrier to sediment dispersal, may have contributed small amounts of detritus during very early Osagean and Meramecian time. Silioeous and cherty rocks are abundant in strata of Osagean age in southern Manuscript approved for publication April 20, 1989. 1Kentucky Geological Survey, Lexington, KY. and western Kentucky, and southern or eastern sources may have con- tributed clay-size detrital silica in these areas. Marine sedimentary environments were mostly shallow to very shallow-water neritic over large areas during the Mississippian. but deeper water perideltaic neritic environments were present in western Kentucky during Kinderhookian, Osagean, and early Meramecian time. Seas are surmised to have opened and deepened southward and westward, with western connections to widespread Mississippian seas across and north of the Ozarks, and eastern connections to Appala- chian areas through the Cumberland saddle of south-central Kentucky. Lower delta-plain environments characterized large areas of Kentucky periodically during Chesterian time. In general. westward-deepening, low-energy environments are in- dicated by the fining grain size of Kinderhookian rocks. and shallower higher energy environments are indicated by coarser and better sorted rocks in Osagean and early Meramecian time. Deposits of middle Meramecian age indicate a low-energy environment, and alternations of high- and low-energy environments characterize Chesterian time. Mississippian rocks attest to a mild climatic regimen during the period, with aridity in mid-Meramecian time, and possibly an intermittently wet climate during Chesterian time. N ortheast- and northwest~trending structures, mostly inherited from Late Devonian time, characterize the Mississippian tectonic frame work. N ortheast-trending negative structural features responded most actively to tectonic stresses. Positive structural features such as the Cincinnati arch and Waverly arch influenced some Mississippian depositional patterns. Crosscutting linear features. now expressed as the Rough Creek and Kentucky River fault systems, were active fault zones or hinge lines during the Late Mississippian. Tectonic movements affecting the region during Mississippian time probably included relative uplift and partial emergence of the Trans- continental arch west of Kentucky. and corresponding subsidence of a subparallel northeast-trending trough, the Michigan and Eastern Interior basins. following Kinderhookian time. Regional southwest- and west-dipping paleoslopes developed during Osagean time and per- sisted into Pennsylvanian time. Relative uplift of preexisting positive structural features resulted in restricted seas during Meramecian time. At about the close of Chesterian time, a major episode of southward tilting and general emergence took place, preceding deposition of Penn- sylvanian sediments. These structural movements were accompanied by marked beveling of strata near basin margins and on some gentle uplifts within the basins, and by widespread channel-cutting. INTRODUCTION This report summarizes the lithostratigraphy of Mis- sissippian rocks in Kentucky. It includes descriptive and nomenclatural discussions and some resulting en- vironmental and tectonic interpretations. 2 MISSISSIPPIAN ROCKS IN KENTUCKY Many significant features described and discussed in this report are referenced to the 1961—1978 GQ maps or other relatively recent publications, although some of these features had been recognized by earlier workers. Where appropriate, the previous work is cited as well. HISTORY OF INVESTIGATIONS Summary reports on Mississippian rocks of Kentucky and adjoining States include chapters in Miller (1919), McFarlan (1943), and Cumings (1922), and reports by Weller and Sutton (1940), Swann (1963), Shaver and others (1970), Pryor and Sable (1974), Willman and others (1975), Sable (1979a), and Rice and others (1979). A sobering review of difficulties and inconsistencies per- taining to mappability of some formational contacts bearing on series and other time-equivalent boundaries, encountered during the 1960—1978 mapping program, was given by Pohl (1970). The development of stratigraphic nomenclature of Mississippian strata in Kentucky and adjacent States falls into four general stages. During 1854—1900, sys- temic, series, and formational names for gross units based on lithology and fauna] content were first intro- duced. Most stratigraphic names such as St. Louis and Ste. Genevieve were extended from adjoining States, although some, such as Knobstone and Mammoth Cave, were of Kentucky origin. Between about 1900 and 1930, units were subdivided and in part renamed by workers such as Stuart Weller, E.O. Ulrich, and Charles Butts. Intensive systematic studies of macrofossil taxonomy and its use for correla- tion purposes marked this period. The Mississippian and Pennsylvanian outcrop belt along the margins of the Eastern Interior basin was mapped in relative detail by cooperative arrangement of State surveys (J .M. Weller and Sutton, 1940); and meaningful regional cor- relations, particularly of Upper Mississippian rock units, were accomplished. During the period 1930—1960, concepts of time- equivalent but lithologically different sedimentary rock facies were stressed. Stockdale (1931, 1939) used these concepts in his studies of Lower Mississippian rocks in Indiana and Kentucky. Divisions and correlations of Upper Mississippian rock units in west-central and western Kentucky were refined by Stouder (1938, 1941) and McFarlan and others (1955), in eastern Kentucky by McFarlan and Walker (1956), and in nearby southern Indiana by Malott (1952). In northeastern Kentucky and adjoining States, a pioneer surface and subsurface regional study incorporating lithologic correlations of lowermost Mississippian and uppermost Devonian clastic units with interpretations of sedimentary environments and paleogeography was completed by Pepper and others (1954). In cooperative arrangement between the US. Geological Survey and the Common- wealth of Kentucky, all 71/2-minute quadrangles in Ken- tucky were mapped topographically on a 1:24.000 scale, setting the stage for detailed geologic mapping. Between 1960 and 1978, Kentucky was mapped geologically on 71/2-minute quadrangles, at a scale of 1:24,000 (Cressman and N oger, 1981). Many refine- ments were made in Mississippian lithostratigraphic interpretations and nomenclature. During this period mappers recognized the Early Mississippian Borden delta complex and delineated its morphology. Relation- ships of Upper Mississippian strata in eastern Ken- tucky were also clarified during the mapping program. Mapping of major sandstonefilled channels in Chester- ian rocks in western and westccentral Kentucky led to development of a deltaic model of deposition like that previously interpreted for similar deposits in Illinois. Resource investigations by the Kentucky Geological Survey of oil, gas, limestone, and clays in Mississippian rocks accompanied the stratigraphic studies. Finally, other investigators in academic, industry, and govern- ment circles used the geologic maps as bases for research on Mississippian stratigraphic, sedimentation, fauna], and engineering studies—as evidenced by the many reports cited in this text. Since 1978, further studies of Lower and Upper Mis- sissippian rocks, mostly in eastern Kentucky, have been accomplished by Kentucky Geological Survey person- nel and faculty and students from many universities. These studies continue, using the GQ maps as practical framework references. SCOPE AND METHODS Sources for this report are mainly published surface information. US Geological Survey Geologic Quad- rangle (GQ) maps, products of the 1960—1978 US. Geo- logical Survey and Kentucky Geological Survey cooperative program, provided most of the basic data. Borehole data were obtained from published and un- published reports and Kentucky Geological Survey files, and included sample-study logs, drillers’ logs, and geophysical logs interpreted by us and other in- vestigators. Paleontological determinations and use of identifiable fossils by field geologists are incorporated here mostly as practical biostratigraphic tools evaluated during the mapping program. Other data used in this report are cited from dissertations, theses, and other studies which developed concurrently with or subse- quent to the mapping program, until about 1983. The INTRODUCTION 3 reader is also directed to the most recent geologic map of Kentucky (McDowell and others, 1981; McDowell, 1986), which depicts the distribution of Mississippian rocks and those of other systems. The bases for changes in Mississippian stratigraphic nomenclature during the 1960—1978 mapping program, such as those of the Borden Formation and its members, and new names for units of Meramecian and Chesterian age in southern and eastern Kentucky, are the criteria of mappability of lithologic units and of con- tinuity of strata as proved or inferred by detailed map- ping. However, suggested nomenclatural changes for some Mississippian units based on the above criteria have not been adopted, and therefore some nomen- clatural inconsistencies remain. One of these is the con- tinued use of the name Warsaw in Kentucky; another is the use of Chesterian formational names over wide areas within which some named units vary considerably in lithology. For the most part, however, Mississippian terminology in Kentucky used in the Geologic Quad- rangle maps follows the Code of Stratigraphic N omen- clature (American Commission on Stratigraphic Nomenclature, 1961, 1970, 1983). Regional thicknesses of Mississippian rock units, shown herein in figures 51—64, are based on approx— imate thicknesses calculated for each Geologic Quad- rangle (GQ), thicknesses derived from data given in columnar sections and from measurements based on map patterns. Data from about 200 surface and sub- surface stratigraphic sections were also incorporated. Plotting of lithofacies for individual units or intervals, in most cases, resulted in rather poor definition of trends; instead a more specific portrayal of lithic types such as sandstone, shale, and limestone and their ap- proximate limits are shown in some thickness maps in this report. Field photographs in this report were taken by GR. Dever, Jr., in 1986 and 1987. ACKNOWLEDGMENTS W.W. Hagan, Director of the Kentucky Geological Survey, and his staff, and AD. Zapp, P.W. Richards, W.W. Olive, and ER. Cressman, successive Chiefs of the Kentucky Geology Branch of the US. Geological Survey, deserve special thanks for the successful im- plementation and completion of the cooperative map- ping program. We wish also to acknowledge the work done by the many US. Geological Survey field geologists who mapped Mississippian rocks in Kentucky. G.W. Weir, R.C. Kepferle, R.D. Trace, J .C. Phflley, W.L. Peterson, R.Q. Lewis, Sr., D.H. Amos, R.C. McDowell, A.R. Taylor, and Benjamin Gildersleeve made special contributions to the description, measurement, analysis, and synthesis of Mississippian strata in several Ken- tucky areas. GEOLOGIC FRAMEWORK The centrally located Eastern Interior basin (fig. 1), also referred to as the Illinois Basin by some investi- gators (McDowell, 1986), is a major negative element of the eastern midcontinent region. It encompasses much of western Kentucky, Illinois, and Indiana, and parts of Missouri and west-central Tennessee. The western margin of the larger Appalachian basin trends southwest through eastern Kentucky. Major positive cratonic elements within Kentucky are the Cincinnati arch, including the Jessamine dome and Cumberland saddle, the east side of the Pascola arch, and the Waver- ly arch. Maximum structural relief of the Precambrian sur- face in the Eastern Interior basin is about 8,500 ft; that of the Appalachian basin is about 15,000 ft in Kentucky, but is as much as 20,000 ft farther east (King, 1969). In the Eastern Interior basin, Mississippian strata are more than 2,700 ft thick in western Kentucky and about 3,300 ft thick in southern Illinois (Sable, 1979a); in the Appalachian basin they are as much as 2,000 ft thick in southeastemmost Kentucky and are more than 7,000 ft thick farther east in southwestern Virginia (de Witt and McGrew, 1979). Mississippian rocks crop out near the major posi- tive structures in Kentucky such as the Cincinnati arch, Pascola arch, and Waverly arch; a narrow belt of outcrop also occurs along the west side of Pine Mountain in southeastern Kentucky (fig. 2). Because of an extensive cover of Pennsylvanian rocks, however, most Mississippian strata in Kentucky occur in the subsurface. Strata of Mississippian age constitute the bedrock in about two-thirds of the area of Kentucky, about 25,850 of the total 40,395 mi2. The volume of Mississippian rocks in Kentucky is about 1,965 mi3, of which roughly 60 percent are marine carbonate and siliceous rocks, and 40 percent are dominantly marine and marginal marine shale, siltstone, and sandstone. Faults that displace Mississippian rocks are the east- southeast-trending Rough Creek—Shawneetown and Pennyrile fault systems in western Kentucky, and the colinear east-northeast-trending Irvine—Paint Creek fault system in eastern Kentucky. Numerous faults also strike north-northeast to east-northeast from the Mis- sissippi Embayment of westernmost Kentucky and ad- joining States. The Kentucky River fault system strikes 86° MISSISSIPPIAN ROCKS IN KENTUCKY 84° 32° 13096» ! OZARK UPL|F4 ‘Q \ .0. ~ 7 f4 M N | CL N>E’>’ /\ A KKK ’r ka/Y ~‘___~ 190%“ Vka -» , . ____.\ ..__ .......... K’T‘rr—‘(z Q‘Y’Kk \(VKV V?) y 36a __ I.” 4 L“~‘~‘« >190} ‘< y 7‘7—1’ 2) *1 \L q\ 4‘ »‘ NASHVILLE a e} ARKANSAS @ $0 to .x i 3’ v r és‘b/ “if"“wm q, MIssIsswm \ AlABA MA l WARRIOR BASIN l Mia’JHH} w“ J)’ . QR W355 044 (law \NMOORMAN? 7 ,1, N i4 49 ( EXPLANATION ) K MICHIGAN 4/ -r ‘44,) r—r Structural form lines on Paleozoic and Precambrian surfaces—Hachures point towards structural depression JESSAMINE éié‘iifié Positive structural elements and monocline FAIRFIELD BASIN .4.) Negative structural elements HQHV A'lHEl/WM ____& Faults and fault zones , 85/? 00 444,0 (5 etc Area of exposed Precambrian rocks V; n 100 MILES awnings: \ l—I—I—I—I—l f my. rm \ LARGHNA * ‘\ \ \ GEORGIA l FIGURE 1,—Generalized structural elements of Kentucky and adjoining areas. Modified from Sable (1979a). east-northeastward from the Jessamine dome of central Kentucky, and extends across eastern Kentucky in the subsurface. The easterly trending fault systems across Kentucky are considered to be related to the 38th parallel lineament (Heyl, 1972), possibly the trace of a major east-west basement fault. Movement along major faults shown on figure 1 displaces all Paleozoic rocks, but locally, earlier movements on these faults seem to have influenced at least Late Mississippian deposition. Geographic divisions in Kentucky used in this report are along quadrangle boundaries. Mississippian rocks crop out mainly in the northeastern, east-central, south- central, west-central, western part of the central, and in the western geographic divisions (fig. 3). Mississip- pian surface exposures have been mapped in more than 360 Kentucky quadrangles (fig. 4 and table 1). In addi- tion, selected outcrop and borehole sections of Mis- sissippian rocks were used during report preparation (fig. 5; indexed in Varnes (1979)). The sections represented range from complete sections of Mississip- pian strata to partial sections representing rocks of a single Mississippian series. Kentucky and surrounding areas were almost con- tinuously inundated by Mississippian epeiric seas in which a variety of detrital and chemical sedimentary rocks were deposited. Terrigenously derived clastics were mostly deposited in deltas, and were derived from major source areas east, northeast, and perhaps south of Kentucky during the Mississippian. Carbonate deposits accumulated in areas adjoining lobes of detrital sediments or during times when little detritus was be- ing transported. Arid climate and restricted circulation of shallow marine waters during the middle part of Mississippian time resulted in evaporite precipitation. In Late Mississippian time rhythmic alternations of carbonate- and detrital-dominated units characterized deposition on a relatively stable shelf in western INTRODUCTION 5 89° 88° 87° 8'13“ 15° 8‘4“ 313° el2° l p . (bf \\ OHIO I \S INDIANA #3 I; I 45" ( 38° ILLINOIS 37° WEST VIRGINIA Pennsylvanian rocks Mississippian rocks 9 [37? L TENNESSEE _ i 8’ 4 ‘1' ‘ ‘ ‘ ‘ — ‘- - | I | | | l D 50 100 MILES EXPLANATION Quaternary deposits not shown Intricate outcrop patterns generalized TK Cretaceous and Tertiary rocks Pre-Mississippian rocks """" 0""' Erosional edge of Mississippian rocks where covered by younger strata "’ Selected faults and fault zones FIGURE 2.—Distribution of Mississippian. pre-Mississippian, and post-Mississippian rocks exposed in Kentucky. FIGURE 3.—Map of Kentucky showing 7‘/2-minute quadrangle boundaries and geographic divisions used in this report (C, E, N, S, W refer, respectively, to central, east, north, south, and west). Kentucky and to some extent on an unstable shelf in eastern Kentucky. The Eastern Interior basin region, which includes central, west-central, and western Kentucky, contains the standard type section for the Mississippian System in North America. The Mississippian System divisions equate with the lower part of the Carboniferous System of Europe. The Mississippian Series in the United States include the Kinderhookian (Meek and Worthen, 1861), Osagean (Branner, 1888), Meramecian (Ulrich, 1904), and Chesterian (Worthen, 1860). These four series have been adopted by the US. Geological Survey and several State surveys in the Eastern Interior basin. The Illinois State Geological Survey currently uses a three- fold series subdivision, the Kinderhookian, Valmeyeran (combined Osagean and Meramecian), and Chesterian Series. In south-central and eastern Kentucky, the US. Geological Survey adheres to an informal two-fold designation: Lower (Kinderhookian and Osagean age equivalents), and Upper (Meramecian and Chesterian equivalents) Mississippian. Classification of Mississippian and other Paleozoic strata in the region, other than conventional rock- and time-stratigraphic designations, are classifications by Megagroup (Swann and Willman, 1961) and Sequence (Sloss and others, 1949; Sloss, 1963; fig. 6 of this report). Although the Megagroup and Sequence concepts are 688.»: Emmancasw :3 how H 293 and H .3 3m. .38an can 332 :sEnmmmmmmmE 5.33 E mofiwqahcmsv mfigosm @33an we mafi Novfilé 559nm ms. E 3 ms m: a: 2m \ a a: um am 3 a2 , __ mm SE .5 i 8 w: a G mmmwMZZm—H 2, a s a 2 B 5 am F um _ 3 s: m , 3 mm E mm 3 8 mm 2m ex 3 .m 3 .E "2.. oz .1 E 5 a“. E a MISSISSIPPIAN ROCKS IN KENTUCKY <_Z_0~=> a 3. 3 2 ,m as. 8 a flu _: a 2. a. E a .5 3 a i i .3 5. m u: , é a .5 e, a a, as a .5 a 5 mm ,, , as 3 .m m 8 3 z z a an 3 a a: Q ) s, 5 . x 202:: a a 8 um i a _ 5 <_z_om_> : i . Emma w z x _ 3 3 2, 5 s E 8 o a) Lu (I) z' 31;; 2 U) a 28 Sub-Absaroka unconformi ty CHESTER EXPLANATION E .. .. I ‘~ . -_ E Sandstone n. St'e.Gia'rie:/.i-(;\'/e,I I I I I I ; I MERAMEC g St. Louis, Salem, Ullin I L-L (7; 5 unconfo m' '_— ‘9 _’:Y _ M_A_MMOLH E 3 Shale and mudstone I 1 FT 1 'I—[ CAIVEI Tl—I | OSAGE U) 3 I H I I I I I ‘1—1— 5 E __ _¥ _ '_ _-I= — — — KINDERHOOK “mm“ UPPER Dolomite 2 1‘ Z MIDDLE g Sub-Kaskaskia Sub-Kaskaskia I B A uncorliformity unconformity I g D. I LOWER E) o. a I I [ I I I 1 EL I [TiIIIIIIIIIII 8 I 7 I I L I CAYUGAN- z z I I ' I I .Hqu/m/YI , I r I NIAGARAN s < I 1 l I I I [I I I I I I fl g 8 #1 I I I I I I I l I d it 4 I l I I I I I I . U) — VA'II'IIIII'I‘I'I4v'f :- ‘~ I. I I I I I I I IiI l Exe=~_ .. ALEXANDRIAN FIGURE 6.—Pre-Pennsylvanian—post—Ordovician Megagroups (capitalized italic) and Sequences in the Eastern Interior basin and adjoining areas (modified from Swarm and Willman, 1961). valuable in establishing broad lithogenetic, tectonic, and time frameworks within which Mississippian events can be placed, this report discusses Mississippian history in detail that requires conventional, specific rock and time divisions. The following discussion on stratigraphy of the Mississippian System in Kentucky stresses lithostratig- raphy, and includes discussion of depositional environ- ments, and paleotectonic implications. Interstate and intrastate correlations of the Missis- sippian strata of Kentucky based on reports by Pryor and Sable (1974) and by Rice and others (1979) are shown in figures 7 and 8. Although regional correlations are principally lithostratigraphic, based on field map- ping, microfauna and macrofauna have been useful both in a lithostratigraphic sense and as tools in defining time-unit boundaries. (See section, “Paleontology.”) Representative sections of Mississippian rocks and an interpretative cross section showing vertical and lateral relationships constitute figure 9. PHYSIOGRAPHY, OUTCROP, AND SCENIC FEATURES Mississippian strata underlie four of Kentucky’s six principal physiographic regions: The Knobs, Mississip- pian Plateau, Western Coal Field, and Cumberland Plateau (fig. 10). The Knobs region is a narrow, arcuate belt of conical hills around the periphery of the Blue Grass Region of central Kentucky, a lowland underlain by early Paleozoic rocks. The Knobs are erosional rem- nants, composed mostly of Lower Mississippian (Osagean) shale and siltstone, standing along the front INTRODUCTION 2 1 Eastern Interior Basin Appalachian Basin E: g lllinois Kentucky "7 a: >‘ an East Central and SC, EC, NE S th to Southeastern Western West Central 30"”1 Central Northeastern (Ettensohn and Wiggly/1235,3331) (as mapped) others, 1984) . Pennington Pennington *Paragon Formation Formation Formation 2 : Upper 'E Bangor member ‘3 (See fig. 8) Limestone a: J: Hartselle *Several 0 Formation “’35:; members w (See fig. 8) ”Kidder : Limestone 2 g Member 3 'Leyc‘as Lgrgiestone 'Levias ‘3 E em r o Limestone 0 ‘1’ ._ Renault Limestone E g Member .§ 5 I 5 5 Tfflgegfibder :19 g Aux Vases 3 g Rosiclare . 7.3 E 3;; 8 Greenbrier :3 Sandstone 5 $ Sandstone Ste.Genevreve ‘6: Ste. Genevieve g Ste. Genevieve g ._E_ Formation q g Member Limestone g Limestone Limestone c -J Ste. 24 ‘Fredonia E Member Member ‘5 g c Genevieve m Limestone g I g E .3 Limestone Member l E 5 o * 2 E 3%; Uppg; I Lower member ._ - .. mem r _ a: .St- L°”'s 3 3; St. Louis Limestone 2 Limestone ... E sr. Louis Member W— Lower Limestone E -‘ member I E ... Salem *Renfro «n Salem . Salem .3 Limestone leestone and Member _v_: Warsaw 2 Ullin LWarstaW Harrodsburg Formations I Limestone __"12531‘2._,_mean_r _______ ______|.. _____ _._q ______ Fort Payne Fort Payne ’Muldraugh I Fort Pa ne Formation Formation Member Egfifl‘ngg S l Cher); a: ______I— Floyds :nob J‘Wilcblie E : Be em er O .. o Nada 'fi Holtsclaw I’Halls Gap : Member I: E Siltstone Member *3 8 .8 8 g :: *Na ncy *Cowbell o is; Member ’Nancy Member Grainger _ no Member Formation Q) 3 *Kenwood *Na ncy 3 Siltstone Member Member Springville New Providence New Providence ”Farmers Shale Shale shale Member J Member ________ s 5 Ch Rockford E112}? .- outeau Li to ‘3 Limestone (locarl'?es reggnt) >‘ g V P g g (l; Berea g B . “‘13.: Sandstone o a 1, (Maury'Formation 230) g; .E Hannibal Hannibal equwalent) Bedford 33 -= 5‘ Shale Shale Shale E m _ '—"’ _____________ "— o — — o = > a New Albany Chattanooga New Albany Chattanooga - .82 Group Shale Shale Shale 31“ng FIGURE 7.—Stratigraphic nomenclature of the Mississippian System in Kentucky and Illinois. Asterisk (*) indicates type section in Kentucky. Modified from Pryor and Sable (1974) and Rice and others (1979). of the Cumberland or Pottsville Escarpment across Muldraugh Hill is a limestone-capped east-facing es- east-central Kentucky and along the front of Muldraugh carpment forming the east border of the Mississippian Hill across west-central and south-central Kentucky. Plateau region. 22 MISSISSIPPIAN ROCKS IN KENTUCKY E Eastern Interior Basin I Appalachian Basin ‘0 a .2 East Central > a: Western West Central South Central and Southeastern <0 w Northeastern (Pine Mountain) llllllllllllllllll lllll ll'll '(illlll lllllllll llll; \ Grove Church \ Shale \ Kinkaid _? \ Limestone LIttle Stone Gap \ South Central, East Central, Degonia Membe; \ and Northeastern Sandstone ; (Ettensohn and others, 1984) 2 \ Clore Tc 5 . Limestone 3 kg '2 c Pennington 2 E 9.0 Formation Palestine 3'2 3 2 g 0 Upper shale member Sandstone =|L g g c g M d 5” 33 .g a Limeegidne ‘ E (E Limestone member 7 .9. 8 . Waltersburg Stony Gap 5 3 Clastlc member Sandstone Sandstone a ‘3 V' Merr71ber ; g Ienna o. a . - 0 Lower dark Limestone 7 Upper ‘ shale member — member E g Sandstone ' *Poppin Rock Member Sf '3 ”Glen Dean :1”; ; Limestone g Lg) ’Hardinsburg B ”Madmifitirfnm '- angor E Sandstone Limestone t: a *Ramey Creek Haney .. Member Limestone Member § Golconda I339 Clifty Hartselle 0 g 3 *Tygarts Creek Formation Sandstone Member Formation o 2 333 Member Beech Creek g 2 <3 E . Limestone a; g " lg ’Armstrong HIII Member 3 Upper ,g Lower Member Cypress Elwren .. 3 member 2' member “Cave Branch Bed Sandstone Sandstone 2 3 g E . g E E g : *Mill Knob Member Reelsvrlle o E 3 o (u Limestone g g o g z E ._ _‘ Q! Paint Creek ”Sample 5 ‘5 g g 3 'Warix Run Member Limestone Sandstone I: E 9 3 3 (Shale) 9 LE 9 g ,\r Beaver Bend 5 1‘ / Limestone 5 3 / 1: ’Bethel Mooretown 52 / Sandstone Formation ‘ / Renault Paoli / Limestone Limestone FIGURE 8.—Stratigraphic nomenclature of the Chesterian Series and equivalent strata in Kentucky. Asterisk (*) indicates type section in Kentucky. Based on Pryor and Sable (1974). The Mississippian Plateau region is a broad, arcuate belt around the Western Coal Field. It extends eastward to the Pottsville Escarpment where the Mississippian outcrop becomes a narrow belt across east-central and northeastern Kentucky. The region consists of two prin- cipal parts divided by the Dripping Springs Escarp- ment, an east- and south-facing ridge generally capped by the Big Clifty Sandstone Member of the Golconda Formation (Chesterian). The outer, eastern part is a broad plain of low relief, locally with karst development where underlain by St. Louis and Ste. Genevieve Limestones (Meramecian); the western portion of this plain is commonly called the Pennyroyal or Pennyrile. The inner, western part of the Mississippian Plateau region is a dissected upland of moderate relief underlain by limestone, sandstone, and shale (Chesterian), local- ly called the Sand Hills country. The Western Coal Field, part of the Eastern Interior basin, is a gently rolling to hilly upland underlain by Pennsylvanian (Morrowan-Virgilian) shale, sandstone, EAST WE ST A" supIuap — qlnouisuod Limos EEEI FEET 100 23138 — UBBJE) Buumog IUD MILES FORMATION LEE Ban I or Limestone FURMA TIUN artselle Formation SIUI'IE I Monteagle Lime 55% E “III II??- min!" “I“ “\ Ian-I i JIII‘I'IIIIII'“ I\i\\ H‘IIIIIIIIIHII ‘ 0/770 IIII I KnIery Sandstone Member Cane Valley Limestone Member INTRODUCTION E a a a c. L I I 1 I l J .5. E NUILVWHDi NUlSNINNJd 3N01§3WIT NVWMEN IN:I H39NIVH9 g g '5 E ,. .‘ ‘ “I li° . E a = 2: E .2 . N c = .— w .t.‘ ' ~ W I:.;-.~'~ % .2 g g ‘E g 1: ._ , I I l5 s 3 g E. 1: S I / II 122 B 3: 3 .2”: '3 / II ”-6 2 m 0 Lu 0 O I , M Le a I / a: ’I/ + I / EII I I / fiII ‘I' I I / t I + I ,/ . / = 1 ymsm'unv- I m H I E {E E II 3 = _: II '33 Z E 3'? 137° 9, fi- 2 = 8 a w 2 we»: *- 3 .8 3 85 85 =t-E ‘2‘ E e 3.: g a a? 3.3 E o o u u -— E = E: I. S '5 '3 E E 5.": 3: 0.9 Q. Q Q (I) < < O X LLI | .2? fl .1: (I! m 5 O .5 E = f: m 3,2. Sandstone Siltstone Shale _L .1. _n_ Calcareous shale Limestone _L__|_.| _L__.L_._I. I I I I South A’ Portsmouth Bowling Green New Providence Member limestone UJSWSW ENOLSJWII awoisawn I Moukum . _. I . 2H vmuuaua smm lS waws MVSHVM mm '13 h g':_ 332-} {.31 :5: '._':j':.';- 'j-fi-j; '81 mm awoisawn I anmsawn I 51 NDIiVWHOi -..-. .-,-- :-:-‘ --. ~3N39 '31 smm ‘13 waws mm 3mm: 13 :1 w m :7 ‘3 4 In 2 ‘5 < - z x I z r— — c: g z: I z u: 4 n: r: m w m 5.1 A §§§§§§§3§ SEEEEEE 2 _, E E > % z E 3 g m ,_ gm m < w 13: a: m : u: 5 E 8 ‘-’ E g ‘g‘ >5 § l s I I T I I I I I | a g g L ; 1 a E’ m S g 23 FIGURE 9.—Mississippian rock units and relationships in Kentucky. All scales approximate; modified from Rice and others (1979, p. F6). 24 /”/.y;,«,P/ raging»? , *S I sis I‘P P) U 50 L J I I I l MISSISSIPPIAN ROCKS IN KENTUCKY “A 100 MILES ~. 24" e9“ I ON FIGURE 10.—Physiographic diagram of Kentucky (modified from Lobeck, 1929). and economically important coal. The resistant thick Caseyville Formation of Pennsylvanian (Morrowan) age forms ridges and cliffs along parts of the coal field border, and these make up a subdued and intermittent topographic escarpment in that area. In eastern Kentucky, the Cumberland Plateau is an intricately dissected upland of V-shaped valleys underlain by Pennsylvanian (Morrowan-Virgilian) shale, sandstone, and coal. It is bordered on the west by the Pottsville Escarpment, a northwest-facing ridge made up largely of Mississippian limestones and silt- stones, and capped by sandstone of the Upper Missis- sippian and Lower Pennsylvanian Lee Formation. Relief increases abruptly in southeasternmost Ken- tucky. Pine and Cumberland Mountains, two northeast- trending ridges with relief as much as 2,200 ft, consist largely of thick Mississippian clastic and carbonate rocks capped by very thick Lower Pennsylvanian (Morrowan) sandstone and underlain by Devonian organic shale. Weathering and erosion of Mississippian rocks in Kentucky have produced a variety of scenic features of interest to both laymen and geologists (McFarlan, 1958). The Mississippian Plateau of western Kentucky is an internationally known classic karst region, with a broad sinkhole plain and extensive systems of under- ground drainage and caverns, including the Mammoth Cave—Flint Ridge cave system (Livesay, 1953), devel- oped in the St. Louis, Ste. Genevieve, and Girkin Lime- stones. In eastern Kentucky, limestone caves are locally developed in the Monteagle and Newman Limestones and Slade Formation along and northwest of the Potts- ville Escarpment. These include the Carter Caves (McGrain, 1954) in northeastern Kentucky and the Sloans Valley cave system (Malott and McGrain, 1977) near the southern border of the State. The conical hills of The Knobs standing above the outer Blue Grass Region lowlands form a strikingly unique example of an erosional landscape, remnants of the uplands left behind the retreating Muldraugh Hill and Pottsville escarpments (McGrain, 1967). Mississippian rocks are well exposed in many road- cuts along highways in Kentucky such as the Bluegrass, Western Kentucky, Cumberland, and Mountain Park- ways, U.S. Interstate 65 south of Louisville, U.S. Inter- state 75 south of Berea, and Interstate 64 east of the Licking River. These and other exposures are described in several field conference guidebook articles, for exam- ple, Weir (1970); Ohio and Kentucky Geological Soci- eties (1968); Sable and Peterson (1966); Smith and others (1967); Lewis (1963); Ferm and others (1971); Dever and others (1977); Lewis and Potter (1978); and Ettensohn and Dever (1979). Locations of selected ex- posures of Mississippian strata and information about them are shown in figure 11, and keyed to quadrangle maps and referenced publication information in table 2. DEVONIAN AND MISSISSIPPIAN ROCKS Units discussed in this section are those which underlie known Early Mississippian strata and are: 25 DEVONIAN AND MISSISSIPPIAN ROCKS .fi 033 E 2:533 3 v93“— Nvlfi 333:5 man—Same .850 v5. 63:9. .3533: 305% .bqosuqavfi E maven gin—BEES: «a $58an goo—om we mnofiauoaléa EDGE L! K“ m4 54 Hr \\ fi/JJ 02E ”3thva w é , ., , N. fig _, : Vflfl‘f\(\ < / COC»® O > ~ OLODmCAvBO Q \ 1/ Zr(h\\ \ t\ $22 8— am a 26 MISSISSIPPIAN ROCKS IN KENTUCKY TABLE 2.—Selected exposures of Mississippian rocks in Kentucky [Numbers of sections keyed to map. fig. 11] Stratigraphic units exposed US. Geological Survey Geologic Quadrangle Maps Location and access Features Pertinent references Northeastern Kentucky 1. Lee Portsmouth GQ—312 South Portsmouth section. Gradational contacts. Nada Calvert, Bernhagen, and Borden (Sheppard, 1964); South on US. Hwy. 23, red and green shales. others (1968). Nada Friendship GQ—526 southeast on Ky. Hwy. 7. Cowbell (Erickson, 1966). west on blacktop, north Nancy at first junction. 2. Borden Vanceburg GQ—598 Apple Tree Hill section, Ky. Bedding features Ohio Geological Society— Nancy (Morris and Pierce. 1967). Hwy. 59. Zoaphycas (Taonurus) Geological Society of Farmers fucoid in Borden. Kentucky (1968. p. 56-57). Sunbury Berea Bedford 3. Lee and Breathitt Grahn GQ-1262 (Englund, Numerous roadcuts and Detrital rocks of Bedford, Philley (1970); Farm and Paragon 1976); Olive Hill GQ-1270 outcrops along Interstate Sunbury. Borden, Carter others (1971); Ettensohn Carter Caves (Englund and Windolph. Hwy. 64 between mile- Caves, Paragon. Complex and Dever (1979, Slade 1975); Soldier GQ—1233 post 132 (east of Licking carbonaterock sequence p. 84-162); Chaplin (1980); Borden (Philley and others, 1975); River) and US. Hwy. 60 in Renfro and Slade. Up— Ettensohn (1981). Renfro Cranston GQ-1212, interchange. per and lower systemic Nada (Philley and others, 1975); boundaries. Nature of Cowbell Morehead GQ-1022 (Hoge upper boundary (grada- Nancy and Chaplin, 1972); tional vs. erosional) is Farmers Farmers GQ-1236 controversial. Sunbury (McDowell, 1975). Bedford Ohio East-central and southeastern Kentucky 4. Lee and Breathitt Clay City GQ-663 (Simmons, Mountain Parkway from Solutiorrcollapse features in Dever (1971). Paragon 1967); Stanton GQ-1182 Interchange with Ky. Slade Formation filled Slade (Weir, 1974a); Slade Hwy. 1057 eastward to with shale and sandstone Borden GQ-1183 (Weir, 1974b). 2.1 mi east of Slade of lower tongue of Renfro interchange with Ky. Breathitt. Representative Nada Hwy. 11. Slade and Breathitt. Cowbell Complete Slade section is Nancy present along the New Albany parkway. 5. Lee and Breathitt Stanton GQ—1182 (Weir, Numerous roadcuts and Erosional features and Dever and others (1977). Paragon 1974a); Means GQ-1324 adjacent quarry sections depositional patterns in Slade (Weir, 1976); Frenchburg along Ky. Hwys. 15, 213, Slade and Paragon related Borden GQ—1390 (Hogs, 1977b); 36, 1274. 801, and US. to intra-Mississippian Renfro Scranton GQ—1488 Hwy. 460. tectonism. Nada (Haney and Hester, Cowbell 1978); Ezel GQ-721 (Pipi- Nancy ringos and others, 1968); Farmers Bangor GQ-947 (Hylbert New Albany and Philley, 1971); Salt (also Sunbury Lick GQ-1499 (Philley, and Bedford) 1978). 6. Lee Frakes-Eagan GQ-1249 Roadcnts along Ky. Hwy. Fort Payne Chert underlain Pennington (Newell, 1975). 1595. by Floyds Knob Newman glauconite. Fort Payne Grainger 7. Pennington Bledsoe GQ-889 Roadcuts and quarry along See quadrangle map Hauser and others (1957. Newman (Csejtey, 1971). U.S. Hwy. 421, north side columnar section. p. 13—16); Wilpolt and Grainger of Pine Mountain. Marden (1959, p. 622-625). Chattanooga 8. Lee Louellen GQ—1060 Hurricane Gap section. See quadrangle map Wilpolt and Marden (1959, Pennington (Froelich, 1978). Roadcuts and quarries columnar section. p. 631-636). Newman along Ky. Hwy.160. Grainger DEVONIAN AND MISSISSIPPIAN ROCKS TABLE 2.—Selected exposures of Mississippian rocks in Kentucky—Continued [Numbers of sections keyed to map, fig. 11] 27 Stratigraphic units exposed US. Geological Survey Geologic Quadrangle Maps Location and access Features Pertinent references E...‘ ‘ ‘and .. . K 'y—r‘ , 9. Lee Whitesburg-Flat Gap Roadcuts and quarry along See quadrangle map Pennington GQ—1119 (Rice and US. Hwy. 119, north side columnar section. Newman Wolcott, 1973). of Pine Mountain. Grainger 10. Pennington Jenkins West GQ-1126 Pound Gap section. Wilpolt and Marden (1959. Newman (Rice, 1973). Roadcuts and quarry p. 645—648). Grainger along U.S. Hwy. 23. 11- Newman Hellier-Clintwood GQ-950 Secondary road and quarry See quadrangle map Smith and others (1967. Grainger (Alvord. 1971). along Mountain Branch; columnar section. p. 11—13). Sunbury south side of Ky. Hwy. Berea 197. Ohio 12. Lee Elkhom City—Harman Secondary road along Blue See quadrangle map Smith and others (1967, Pennington GQ—951 (Alvord and Head Branch and quarry columnar section. p. 14—16). Newman Miller, 1972). near head of Rough Branch; south side of Ky. Hwy. 197. Southern central and south-central Kentucky 13- Salem Halls Gap GQ—1009 (Weir, Halls Gap Section U.S. Typical Borden of this area Weir (1970, p. 33-35, Borden 1972). Hwy. 27 at Halls Gap. overlain by Salem. 43-44). Muldraugh Floyds Knob Nancy Halls Gap 14. Paragon Wildie GQ-684 (Gualtieri. Renfro Valley interchange. Renfro type section and up Weir (1970, p. 38—40, Slade 1968a); Mount Vernon Interstate Hwy. 75 and per Borden. Glauconite in 45—46); Ettensohn and Borden GQ-902 (Schlanger and US. Hwy. 25. Roadcuts Wildie. Representative Dever (1979, p. 170-181). Renfro Weir, 1971). along 4 miles of US. Newman. Wildie Hwy. 25 north from inter- (Floyds Knob) change and roadcuts along Halls Gap 1.5 mi of Interstate Hwy. Nancy 75 south from interchange. 15. Fort Payne Mannsville GQ-562 (Taylor. Ky. Hwy. 76, north of bridge Representative Fort Payne; Sedimentation Seminar 1966). across Baker Branch. Floyds Knob exposure. (1972). 16. Science Hill Maretburg GQ-338 Roadcuts in Science Hill Lewis and Taylor (1979). Sandstone Member (Schlanger. 1965). along Ky. Highway 70, Rockcastle County. Prob- ably same as section 33 of Lewis and Taylor (1979). 17. Fort Payne Cane Valley GQ-369 Fisher Bend Bluff north of Knifley type section. Sedimentation Seminar Knifley (Maxwell and Turner, Green River Reservoir. (1972) (Section 1). 1964). Difficult access. 18. Fort Payne Cane Valley GQ-369 Quarry along Butler Cane Valley type section. Kepferle and Lewis (1974). Cane Valley (Maxwell and Taylor, Branch on Ky. Hwy. 55. 1964). 19. Monteagle Delmar GQ—909 (Lewis, Cumberland Parkway east Bedded-appearing chert in Dever and Moody (1979b). St. Louis 1971a). of Fishing Creek (Lake Muldraugh. Large-scale Salem and Warsaw Borden Muldraugh Floyds Knob Nancy Cumberland); about 8 mi west of West Somerset. Quarries in Monteagle Limestone on Smith and Hale Knobs south of Ky. Hwy. 80. foreset beds in Borden. Stromatolitic beds in St. Louis. Relict-evaporite features in lower St. Louis. Salem and Warsaw unit calcarenite and dolomite. 28 MISSISSIPPIAN ROCKS IN KENTUCKY TABLE 2.—Selected exposures of Mississippian rocks in Kentucky—Continued [Numbers of sections keyed to map, fig. 11] figfiggfi Goaligigegifgmzps Location and access Features Pertinent references Southern central and south-central Kentucky—Continued 20. Fort Payne Creelsboro GQ-204 (Thaden West side of Wolf Creek Representative Fort Payne. Lewis and Potter (1978). and Lewis, 1973); Wolf Dam and roadcuts along Creek Dam GQ-177 Ky. Hwy. 1730. (Lewis and Thaden, 1962). 21. Salem and Warsaw unit Jamestown GQ-182 (Thaden Shores of Lake Cumberland Carbonate mud mounds Lewis and Potter (1978). Fort Payne and Lewis, 1962); J abez near Lake Cumberland and crinoidal limestone Cane Valley GQ-483 (Thaden and State Park. bodies in Fort Payne. Lewis, 1966). J abez Sandstone Member of Fort Payne. 22. Monteagle Frazer GQ-1223 (Lewis, Ky. Hwy. 790, south of Kidder Limestone Member Lewis (1971b). Kidder 1975). Kidder. type section; Hartselle Formation composed of shale. 23. Breathitt Burnside GQ—1253 (Taylor Roadcuts along 2 mi of Ettensohn and Chesnut Paragon and others, 1975). US. Hwy. 27 north of (1979a, 1979b). Bangor Sloans Valley. Strunk Hartselle Construction Co. quarry, Monteagle east side of US. Hwy. Kidder 27, south of Tatesville. 24. Hartselle Cumberland City GQ-475 Roadcuts east of Cartwright Ste. Genevieve completely Monteagle (Lewis and Thaden. 1965). along Ky. Hwy. 90 and exposed. Kidder along secondary road Ste. Genevieve leading southward to St. Louis Poplar Mountain. 25A. Monteagle Albany GQ-550 (Lewis and Wago quarry. east of Ky. Lewis and Potter (1978, Kidder Thaden, 1966). Hwy. 639, north of Wago p. 39—41). Ste. Genevieve 3/4 mi. St. Louis 253. Monteagle Albany GQ—550 (Lewis and Huddleston quarries, east Complete, or nearly com— McFarlan and Walker Kidder Thaden. 1966). side of US. Hwy. 127, plete Kidder and Ste. (1956, p. 13). Ste. Genevieve 2.5 mi north of Albany. Genevieve sections near western limit of Appalachian basin. 250. Hartselle Albany GQ-550 (Lewis and Gaddie Shamrock, Inc. Monteagle Thaden, 1966). quarry, north side of Ky. Kidder Hwy. 1590, west of Ste. Genevieve Albany 1.5 mi. Western, central, and west-central Kentucky 26. Elwren New Amsterdam—Mauckport Battletown quarry east of Best exposures of Ste. Stokley and McFarlan Reelsville GQ—990 (Amos, 1972). Ky. Hwy. 228, north of Genevieve in region. Aux (1952, p. 64—68). Sample-Mooretown Battletown V2 mi. Vases(?) equivalent. Paoli Ste. Genevieve 27. St. Louis Rock Haven-Laconia US. Hwy. 60 at Grahamton Rarely exposed St. Louis Salem GQ—780 (Withington and section. Sable, 1969). Upper part of Salem and lower part of St. Louis are well exposed in at least two other localities: Vulcan Materials Co. Brandenburg quarry, east side of Ky. Hwy. 933. Rock Haven—Lacenia GQ-780 (Withington and Sable, 1969) Roadcuts along Ky. Hwy. 1638 west of Doe Run Mill. Rock Haven—Laconia and Guston GQ’s. Guston GQ-1481 (Palmer, 1978) 28. St. Louis Fort Knox GQ-1375 Round Hollow section, U.S. Shaly Salem. Reference Sable, Kepferle, and Salem (Kepferle and Sable, Hwy. 31W north of section of Harrodsburg. Peterson (1966). Harrodsburg 1977). Muldraugh. Muldraugh with crinoidal Borden limestone beds. DEVONIAN AND MISSISSIPPIAN ROCKS TABLE 2.—Selected exposures of Mississippian rocks in Kentucky—Continued [Numbers of sections keyed to map. fig. 11] 29 ffiéfigggsh; Gegligigesrfizlngslmgps Location and access Features Pertinent references Western, central, and west-central Kentucky—Continued 29A. Harrodsburg Elizabethtown GQ-559 Bluegrass Parkway about Large roadcuts. Borden (Kepferle. 1966b). 4 to 6 mi east of Muldraugh Elizabethtown. Floyds Knob Nancy 293. Harrodsburg Elizabethtown GQ-559 Vulcan Materials Co. Striking foreset bedding in Kepferle, Peterson, and Muldraugh (Kepferle, 1966b). Elizabethtown quarry Muldraugh. Sable (1964, p. 31—32). north of U.S. Hwy. 62, 23/4 mi northeast of Elizabethtown. 290. Salem Elizabethtown GQ—559 Tunnel Hill section; Classic localities. Butts (1917, 1922); Harrodsburg (Kepferle, 1966b); Coles- Louisville and Nashville Stockdale (1939). Muldraugh burg GQ—602 (Kepferle. Railroad cuts northeast 1967). of Tunnel Hill. 30. Chester units Summit GQ—298 (Moore, U.S. Hwy. 62. 1/2—1 mi east Fair exposures. USGS core Paoli to Big Clifty 1964a). of Summit. hole here (Moore, 1964b). Big Clifty asphaltic sand- stone in quarries of Summit. Western Kentucky 31. 32. 33. 34. 35. 36. 37. Big Clifty to Glen Dean Leitchfield Caseyville Leitchfield Renault Ste. Genevieve Tar Springs to Cypress Salem Warsaw Fort Payne Fort Payne Big Clifty GQ—192 (Swadley, 1962). Leitchfield GQ-l316 (Gildersleeve, 1978). Caneyville GQ-1472 (Gildersleeve and Johnson. 1978). Burns GQ-1150 (Amos, 1974). Olney GQ-792 (Trace and Kehn, 1968). Grand Rivers GQ-328 (Hays, 1964); Calvert City GQ-731 (Amos and Finch, 1968). Grand Rivers GQ-328 (Hays, 1964); Birmingham Point GQ-471 (Fox and Olive, 1966); Fenton GQ-311 (Schnabel and MacKallor, 1964); Fairdealing GQ-320 (Wolfe. 1964). Scattered cuts along U.S. Hwy. 62 and Western Kentucky Parkway. Western Kentucky Parkway; first cuts west of Leitch- field interchange. Western Kentucky Parkway. Barrett quarry U.S. Hwy. 60; 5 mi north of Smith- land, then 11/: mi south- east on secondary road. Western Kentucky Parkway 3V2—4l/z mi east of Princeton. Reed Crushed Stone Co. quarry U.S. Highway 62 at Lake City. Best exposures are along Kentucky Lake shoreline. Residuum and poor ex- posures along and near U.S. Hwy. 68. Geologic map does not show Western Kentucky Parkway. Fossiliferous Glen Dean in railroad cuts at West Clifty. Seldom exposed poorly resistant section; partly overgrown and slumped. Excellent Pennsylvanian- Mississippian contact exposures. Generally only residuum exposed; chert content 2060-40 percent. An excellent exposure of Fort Payne (interbedded chart and limestone) is present on the east shore of Lake Barkley in a roadcut along Ky. Hwy. 295, west of Old Kuttawa. Eddyville GQ-255 (Rogers, 1963). Vincent (1975, p. 50—51. 64). Williamson and McGrain (1979, p. 34—35). Williamson and McGrain (1979, p. 33-34); Whaley and others (1979, p.42-44) Dever and McGrain (1969, p.100-109L Trace (1981). Dever and McGrain (1969, p.48—57) 30 MISSISSIPPIAN ROCKS IN KENTUCKY TABLE 2,—Selected exposures of Mississippian rocks in Kentucky—Continued [Numbers of sections keyed to map, fig. 11] Stratigraphic US. Geological Survey . . units exposed Geologic Quadrangle Maps Location and access Features Pertinent references Western Kentucky—Continued 38. Renault Princeton East GQ—1032 Kentucky Stone Co. Fredonia, Rosiclare, Levias, Dever and McGrain (1969. 39. Ste. Genevieve Chester series (Trace, 1972). Princeton East GQ—1032 (Trace, 1972). 40. Salem Canton GQ—279 (Fox and Warsaw Seeland, 1964). 41. Bethel Hopkinsville GQ—651 Renault (Klemic, 1967). Ste. Genevieve 42. 'I‘radewater Morgantown GQ-1040 Caseville (Gildersleeve, 1972); Leitchfield Sugar Grove GQ-225 Glen Dean (Miller, 1963); Hadley Hardinsburg GQ-237 (Rainey, 1963); Golconda Rockfield GQ—309 Girkin (Rainey, 1964). Princeton quarry via Ky. Hwy. 91, 2% mi southeast of Princeton, Ky. Walches Cut. Illinois Cen- tral Railroad, via Ky. Hwy. 91 and secondary roads, about 4 mi east- southeast of Princeton, Ky. Kentucky Stone Co. Canton quarry US. Hwy. 68, 1 mile east of Canton. Christian Quarries quarry, east side of Hopkinsville, south of US. Hwy. 68. Green River Parkway, from interchange with US. Hwy. 231 at Bowling Green, northward to interchange with US. Hwy. 231 at Morgantown. and Renault distinguished. Classic locality. Dipping beds, in part faulted. Renault to Kinkaid. Core drill site (Warsaw to Chattanooga). See quad- rangle map columnar section. Good exposures of Chesterian units, particularly Beech Creek Member of the Golconda Formation. p. 118—133). Dever and McGrain (1969, p. 27—41 and fig. 6). Dever and McGrain (1969, p. 168—175). Ste. Genevieve (1) of known Devonian age (Ohio Shale and in part, Chattanooga Shale), (2) known to span the Devonian- Mississippian systemic boundary (New Albany Shale and in part Chattanooga Shale), and (3) of equivocal age relationships in which investigators are not in total agreement about the position of the boundary (Bedford Shale and Berea Sandstone). NEW ALBANY, CHATTANOOGA, AND OHIO SHALES Rocks of Middle and Late Devonian age which under- lie Early Mississippian strata in Kentucky are mainly “black shale” units consisting of organically rich, fissile shale and thin-bedded siltstone. Three nomenclatural units, the New Albany, Chattanooga, and Ohio Shales, are laterally continuous with one another; their names have been extended into Kentucky from Indiana, Ten- nessee, and Ohio respectively. Nomenclature] bound- aries of these units cropping out in Kentucky arbitrarily coincide with mapped 71/2-minute quadrangle bound- aries. In general, the name New Albany Shale is used across central and into east-central Kentucky; the Chattanooga is present in western, southwestern, south- ern west-central, south-central, and southeastern Ken- tucky; and the Ohio Shale is restricted to the exposure belts in northeastern and east-central areas. Maximum thicknesses of the Ohio, Chattanooga, and New Albany Shales, the lower part of the Knobs Mega- group (Swann and Willman, 1961), are more than 440 ft in western Kentucky (Schwalb and Potter, 1978), and more than 1,700 ft in extreme eastern Kentucky (Fulton, 1979; fig. 12 of this report). The units thin to less than 40 ft thick along the Cincirmati arch, which was a relatively positive area during the Middle and Late Devonian; they are known to be absent in at least two locations in south-central Kentucky, where Missis- sippian rocks overlie Ordovician and Silurian strata (Potter, 1978). The two correspondingly negative areas of thick accumulations on either side of the arch are the Moorman syncline in western Kentucky, and the west- ern flank of the Appalachian basin depositional trough in eastern Kentucky. Thickness variations of the Devo- nian shale units along the Rough Creek fault system north of the Moorman syncline indicate pre- Mississippian tectonic activity there (Schwalb and Potter, 1978). DEVONIAN AND MISSISSIPPIAN ROCKS 31 88° 85° FOREST CITY ' BASIN 40° 1.1 KANSAS I mesons: l 35°— g .91) OZARK UPLIFT ~~~~a OKLA. (MOE 360 M»: M“ N EXPLANATION —700— lsopach of thickness of Upper Devonian rocks. in feet—Dashed where approximately located or restored —0_ Zero limit of Upper Devonian rocks 34° ‘ MEESI‘PESHWE U 100 200 mm W; l l l [1' I: ,’ | MICHIGAN ““1" “‘ “ BASIN FIGURE 12.—Thickness of Upper Devonian rocks and their relationship to major structural elements in the east-central United States (from Sable, 1979; Schwalb and Potter, 1978; Potter, 1978; Fulton, 1979, de Witt and McGrew, 1979). BEDFORD SHALE AND BEREA SANDSTONE The Bedford Shale and Berea Sandstone (N ewberry, 1870) overlie the Ohio and Chattanooga Shales in eastern Kentucky with apparent conformity. Together, they form a wedge which thins southwestward in east- central Kentucky (McDowell and Weir, 1977). The Berea is mappable from the Ohio border as far south as Stricklett and Head of Grassy quadrangles (Morris, 1965b; 1966a); the Bedford extends farther southward and during mapping was recognized as far as the vicini- ty of the Means quadrangle (Weir, 1976). In the sub- surface of eastern Kentucky, the Bedford has been traced as far south as Knox County in southeastern Kentucky (Kepferle and others, 1978) and pinches out to the southwest. The Bedford Shale is principally gray to greenish-gray claystone with pyritic nodules and thin siltstone layers. The overlying and intertonguing Berea Sandstone is light-gray to buff, very fine to fine grained subgray- wacke sandstone. Oscillation ripple marks trending generally N. 50° W. to due west (Morris, 1965a, 1966b; Morris and Pierce, 1967), crossbedding, and penecon- temporaneous deformation features are common. Grains are predominantly subangular quartz with minor chert, feldspar, and rock fragments. Combined max- imum thickness of Bedford and Berea strata is less than 200 ft in eastern and southeastern Kentucky (fig. 52), which indicates two minor depocenters corresponding to the Red Bedford and Virginia-Carolina deltas of Pepper and others (1954). Thickness trends indicate a general west to southwest paleoslope. 32 A classic regional analysis of these units in Ohio and West Virginia was given by Pepper and others (1954), but extended only into northeasternmost Kentucky. The Bedford and Berea are discrete units in some areas of northeastern Kentucky, but elsewhere they inter- tongue and the Berea is in part a submarine channel fill in the Bedford (Morris, 1966a; Morris and Pierce, 1967; fig. 13 of this report). They thin and apparently grade into dark shales of the uppermost Chattanooga and New Albany Shales (Elam, 1981). Overlying thin Sunbury equivalents extend southwestward as the up- permost beds of the Chattanooga into south-central Kentucky and northern Tennessee (Elam, 1981). In northeastern Kentucky, lithofacies and thickness distribution of sandstone-dominated lobes (de Witt and McGrew, 1979; fig. 52 of this report) suggest westerly and southwesterly transport directions for the Bedford and Berea sediments from source areas east and north- east of the present Appalachian Mountains (Pepper and others, 1954). The sandstones were derived probably from earlier Paleozoic detrital rocks (Pepper and others, 1954, p. 91, 95). The ripple marks of N. 50° W. to due west trend in the Berea of this area and throughout a large adjacent area of southern Ohio have been ascribed to northeasterly prevailing winds (Bucher, 1919; Pepper and others, 1954, p. 91) or shoreline coastal control (Hyde, 1911). Crossbedding and sandstone-filled chan- nels characterize the sequence, and indicate deposition in a shallow-water deltaic complex. Sole markings in some sandstones suggest that they were deposited by density currents, probably at the delta front (Wilson, 1950; Rich and Wilson, 1950). MISSISSIPPIAN ROCKS IN KENTUCKY In southeastern Kentucky, the Bedford and Berea are mappable units southward to the Roxana (Maughan, 1976) and Benham (Froelich and Stone, 1973) quad- rangles. In the eastern Kentucky subsurface, they thin to a combined thickness of less than 10 ft along a north- trending line from Leslie to Wolfe Counties. DEVONIAN-MISSISSIPPIAN SYSTEMIC BOUNDARY In Kentucky, southern Indiana, and Tennessee, the Devonian-Mississippian boundary can be determined fairly closely although its position in northeastern and southeastern Kentucky has been strongly debated. The uppermost part of the New Albany Shale in its type area of southern Indiana spans the boundary (Huddle, 1934; Campbell, 1946; Lineback, 1968a). Beds of Kinder- hookian age are represented in the top approximately 3 ft of the New Albany where the New Albany totals about 100 ft thick. The base of the lowest Kinder- hookian bed coincides closely with a subtle lithologic break. In the upper 3 ft, which comprise the Underwood, Henryville, and Jacobs Chapel beds (Campbell, 1946) of the uppermost New Albany, conodonts are of Kinder- hookian age. A similar section occurs in Kentucky in the Louisville West quadrangle (Kepferle, 1974), but in the adjacent Brooks quadrangle to the southeast (Kepferle, 1972b), conodonts in the upper 4 ft of the New Albany are of probable Late Devonian age. All conodont collections from the uppermost beds \of the New Albany of central Kentucky farther south either . 0‘ . 6‘ ,3“in $3 \ ‘6 38 °30' FIGURE 13.—Generalized relationships between Berea Sandstone (M Db) and Bedford Shale (M Dbd) in Vanceburg quadrangle, northeastern Kentucky (Morris and Pierce, 1967). Berea Sandstone thickens eastward, fills channel cut in Ohio Shale (Do) as shown in panel X -X '. Vertical exaggeration about X60. ROCKS OF KINDERHOOKIAN AND EARLY OSAGEAN AGE 33 indicate a probable Late Devonian age or are non- diagnostic (J .W. Huddle, written commun., 1967). The position of the Devonian-Mississippian boundary in northeastern Kentucky is extrapolated from ex- posures in Ohio, and was interpreted by de Witt (1970), using conodont and floral evidence, to lie within the basal few feet of the Bedford-Berea detrital wedge that separates the Sunbury Shale of Mississippian (Kinder- hookian) age from the underlying Late Devonian Ohio Shale. More recent spore evidence (Eames, 1978) indi- cates that the boundary lies between the Berea-Bedford and the Sunbury Shale in northeastern Ohio. The systemic boundary in northeastern Kentucky is also considered by Sandberg (1981) to lie at the base of the Sunbury Shale. Conodonts from beds in the Sunbury Shale, the up- permost part of the New Albany Shale, and basal beds of the Fort Payne Formation in east-central, central, and south-central Kentucky are shown in tables 3—6 of this report. Their distribution indicates that the upper- most beds of the New Albany in east-central Kentucky at least as far south as the Berea and Bighill quad- rangles are of probable Sunbury (Kinderhookian) age. Southward in Kentucky, conodonts from the uppermost beds of the New Albany are nondiagnostic in places; and beds of the basal Borden and Fort Payne Formations (Maury Formation equivalent) contain conodonts of Kinderhookian age in some localities and Late Devonian age in others (Hass, 1956). Very slow deposition and gaps in conodont assemblages seem to have character- ized the Devonian-Mississippian boundary conditions in south-central and parts of central Kentucky. In some areas, a hiatus above the uppermost beds of the New Albany Shale is indicated by conodonts of probable up- per Burlington (Osagean) age in the basal beds of the Borden Formation (Rexroad and Scott, 1964). The evidence suggests that deposition was generally continuous across the Devonian-Mississippian bound- ary in the northern part of northeastern and central Kentucky, but that during this time nondeposition or very slow deposition, periodically interrupted by sub- marine scour, characterized south-central Kentucky (Conkin and Conkin, 1979). MISSISSIPPIAN ROCKS ROCKS OF KINDERHOOKIAN AND EARLY OSAGEAN AGE (EARLY MISSISSIPPIAN) Earliest Mississippian (Kinderhookian) rocks in Ken- tucky are widespread, but they are relatively thin and constitute a small part of the total Mississippian rock volume. In eastern Kentucky, the strata which succeed the Bedford-Berea deltaic wedge are terrigenous organic clastics. During Kinderhookian time a thin distinctive green claystone unit was deposited across southern Kentucky, and a thin unit of carbonate rocks with in- terbedded mudstones was deposited in west-central and western Kentucky. These units are, respectively, the Sunbury Shale, the equivalent of the Maury Formation of Tennessee, and the Rockford Limestone (fig. 7). SUNBURY SHALE The Sunbury Shale (Hicks, 1878) provides an easily recognizable horizon and is extensively used as a struc- tural datum; it consists of fissile organic-rich claystone and siltstone similar to that in the older Ohio and Chat- tanooga Shales. It is 10—25 ft thick in northeastern Ken- tucky (fig. 14) and as much as 55 ft thick along Pine Mountain, southeastern Kentucky. Both the upper and lower contacts appear to be conformable. The unit is readily distinguishable by its radioactivity profile (Et- tensohn, 1979b; Ettensohn and others, 1979). Still far- ther south and west, beds in the uppermost part of the New Albany and Chattanooga Shales have been recog- nized as Sunbury equivalents by their contained con- odonts and by geophysical log studies (Elam, 1981). The conodonts, principally Siphonodella spp., occur in the top few inches of the New Albany Shale in the Berea (Weir, 1967) and Bighill (Weir and others, 1971) quadrangles. Except for southwestward thinning, the Sunbury Shale exhibits no definitive clues to the transport direc- tion of its sediment. Following progradation of Bedford- Berea sediments under shallow aerobic conditions, the Sunbury accumulated in an anaerobic, probable deep- water environment during a marine transgression, prob- ably from the same general eastern provenance and under conditions similar to those which produced the Devonian-Mississippian black Shales. Lineback (1970) considered that the black Shales of the eastern midcon- tinent were deposited in shallow water with circulation restricted by the presence of an algal floatant. Deep- water environments for these black Shales were favored by Rich (1951) and by Elam (1981). MAURY FORMATION EQUIVALENT South and west from about the vicinity of Berea, a few inches to about a foot of greenish claystone with phosphatic nodules, glauconite, and lag concentrates containing conodonts, unidentified fossil fragments, and fish remains directly overlies the New Albany or Chat- tanooga Shale (Elam, 1981; fig. 15 of this report). This lithic and positional equivalent of the Maury Formation of Tennessee (Safford and Killebrew, 1900) is also 34 MISSISSIPPIAN ROCKS IN KENTUCKY FIGURE 14.—Sunbury Shale (above vehicle) overlying the Bedford Shale (mostly talus-covered slope) and underlying the Farmers Member of the Borden Formation (tabular light-hued beds). Milepost 132.6, Interstate Highway 64, Farmers quadrangle, Rowan County. reported in basal beds of the New Providence Shale Member of the Borden and Fort Payne Formations in many quadrangles in south-central and central Ken- tucky. These include Eli, Faubush, Delmer (Thaden and Lewis, 1965a; 1969; Lewis, 1971a) and as far west as Dubre quadrangle (Lewis, 1967) in south-central Ken- tucky, and Louisville West, Shepherdsville, and Howardstown (Kepferle, 1974; 1968; 1966a) in western central Kentucky. Similar greenish claystone above black shale is reported in many well descriptions in southern and western Kentucky by Freeman (1951, 1953). Conodonts from several outcrops in southern Ken- tucky and Tennessee suggest that the Maury is a time- equivalent of most of the Bedford, the Berea, and the Sunbury (Collinson and others, 1962, p. 13), and that it locally contains elements younger than the Sunbury (Hass, 1956, p. 23). In these areas, the Maury may repre- sent generally uninterrupted deposition during most or all of Kinderhookian time (Conant and Swanson, 1961, p. 67). In others, as along the Cincinnati arch in the western part of central Kentucky, Maury lithic equiva- lents contain a mixed conodont assemblage of Devo- nian, Kinderhookian, and Osagean ages, and are interpreted as a lag concentrate at an erosional hiatus, which possibly extended through Kinderhookian and early Osagean times (Rexroad and Scott, 1964). This in- terpretation supports the concept of very slow deposi- tion and essentially starved basin conditions over much of Kentucky and Tennessee during earliest Mississip- pian time. The widespread, thin claystone of the Maury Forma- tion and its lithic equivalents in the basal Borden and Fort Payne probably were deposited remote from source areas (Conant and Swanson, 1961, p. 68), at a slow rate, in a low-energy environment favorable to the precipita- tion of phosphate. The concentration of phosphate nodules in the Maury equivalents appears to represent a lag concentrate from which most of the fine detrital material was winnowed by submarine currents; this en- vironment is also suggested by mixed conodont “lag” assemblages near the Cincinnati arch. South of Ken- tucky, thin sandstones occur in the Maury along the western margin of the Nashville Dome and suggest local source areas (Conant and Swanson, 1961, p. 53). The normally subjacent Chattanooga Shale is also locally absent there, indicating local uplift or local scour and resultant deposition along the arch. The abundant phosphatic nodules in the Maury Formation equivalent may indicate that southern Kentucky and Tennessee occupied a broad shelf north of a deep basin from which upwelling ocean currents contributed nutrients such as phosphate. Phosphatic nodules have also been reported in the underlying New Albany Shale and in the overly- ing New Providence Shale Member of the Borden For- mation, indicating that conditions for the precipitation of phosphate existed periodically from Late Devonian into Osagean time. ROCKS OF KINDERHOOKIAN AND EARLY OSAGEAN AGE 35 FIGURE 15,—Maury Formation equivalent (Mme). 0.8 ft thick, underlying Fort Payne Formation (pr) and overlying Chattanooga Shale (Dc). East side of Kentucky Highway 61, 4.7 mi south of junc- tion of Kentucky Highways 90 and 61, east side of Burkesville. Frogue quadrangle, Cumberland County. ROCKFORD LIMESTONE In much of Indiana and adjacent parts of central and west-central Kentucky, earliest Mississippian strata are represented by the thin but widespread Rockford Limestone and thin shale beds which are superjacent to or in the uppermost few feet of the New Albany Shale. The Rockford, first named the Rockford Goniatite bed by Meek and Worthen (1861), was given formational status by Kindle (1899). The Rockford, a gray to greenish-gray, micritic, glauconitic limestone or dolomite, was reported to contain both Kinderhookian and Osagean conodont elements in Indiana (Rexroad and Scott, 1964) but Kinderhookian foraminifera in In- diana and northwestern central Kentucky (Conkin and Conkin, 1979). In northwestern central Kentucky, the Rockford is locally present south of the Ohio River in the Louisville West quadrangle (Kepferle, 1974) and was reported farther south in the Brooks quadrangle (Con- kin and Conkin, 1979, p. 57). In this area, it is as much as 3 ft thick and directly overlies New Albany Shale. Southward, the Rockford grades to shale (Conkin and Conkin, 1979, p. 57), and thin carbonate strata in the position of the Rockford are also reported to the south- west in well logs of northern Meade and Breckinridge Counties. In the Louisville West quadrangle, the Rock- ford apparently is correlative with lithologies of the Maury equivalent. In western Kentucky, some well records in counties along the Ohio River indicate that the Rockford Lime- stone (Chouteau Limestone of Illinois usage) is present there. In the Canton quadrangle, Trigg County, a thin limestone within the unit referred by Fox and Seeland (1964) to the New Providence Shale may also represent the Rockford. If this limestone is the Rockford, the 34 ft of shale between it and the older Chattanooga Shale is probably equivalent to the Kinderhookian Hannibal Shale of Illinois. Carbonate rocks of the Rockford Limestone in In- diana and parts of northern Kentucky were mostly deposited in a notably low energy environment, on a sea floor having little relief. A high iron content and a low proportion of terrigenous detritus in Indiana may in- dicate a low land area to the east along the Cincinnati arch; dolomitic beds may suggest an intratidal deposi- tional environment, but the enclosing sediments in- dicate a subtidal marine environment. The Rockford Limestone in northwestern central Ken- tucky seems to be coeval with the Maury Formation equivalent farther south. The Maury equivalent may en- compass several small-scale disconformities ranging from Late Devonian to Osagean age, expressed by superposition of and mixing of lag concentrates in a starved shelf or basin environment. Landward, such small-scale disconformities might be expressed individ- ually by separate detrital units containing lag con- centrates, as suggested by Conkin and Conkin (1979) to be present at the Devonian-Mississippian and Kinderhookian-Osagean boundaries. KINDERHOOKIAN-OSAGEAN UNIT RELATIONSHIPS Fine detrital rocks, mostly of the New Providence and Nancy Members (Osagean) of the Borden Formation, overlie Sunbury and New Albany Shales in northeast- ern, east-central, central, and west-central Kentucky. Judging from the widespread persistence of the thin Sunbury, the Maury equivalent, and the Rockford units, little hiatus preceded deposition of Borden sediments except locally along the western side of the Cincinnati 36 MISSISSIPPIAN ROCKS IN KENTUCKY arch. There, an unconformity at the base of the Fort Payne Formation in the Petroleum quadrangle, south- ern west-central Kentucky, was reported by Myers (1964). The Rockford Limestone is also locally absent in the southern Indiana outcrop belt (Lineback, 1964), and shallow channels filled by Borden strata cut into the New Albany Shale in northwest-central Kentucky (R.C. Kepferle, oral commun., 1967). Scour prior to or during deposition of Borden Formation sediments is therefore indicated in those areas. In much of the region southwest of the limit of rocks assigned to the Borden, in southern and western Ken- tucky and western Tennessee, mudstones in the New Providence Shale Member of the Fort Payne Formation rest with apparent conformity on the Maury Formation and its lithic equivalents in places, but abrupt contacts also exist between overlying Fort Payne siliceous rocks and the Maury. These were considered by Conant and Swanson (1961, p. 68) to be due to sudden changes in depositional environments. Conodont faunas collected at scattered localities in southern Kentucky, however, indicate that basal beds of the Fort Payne may vary in age from place to place (J .W. Huddle, written com- mun., 1967), and an obscure nondepositional or sub- marine erosional hiatus may therefore be reflected between Maury and Fort Payne strata. Such relations would be expected for a distal, sediment-starved area basinward of deltaic deposits which were subsequent- ly overlain by transgressive carbonate strata of the Fort Payne. PALEOTECTONIC IMPLICATIONS Because no known physical evidence points to inter- systemic unconformities of much magnitude, structural elements during Kinderhookian time in Kentucky were probably of extremely low amplitude. The region was mildly negative, except for the Cincinnati arch, which may have been a barrier to westward dispersal of Late Devonian and Kinderhookian clastic sediments. If a shelf-trough depositional and tectonic model is invoked, the widespread thin deposits of the Rockford and Chouteau limestones in Kentucky could have ac- cumulated on the southern part of a broad stable shelf. Maury Formation equivalents accumulated either on the southern extension of this shelf, or in a negative ele- ment of larger magnitude which adjoined the shelf to the south. The northward and westward change from these phosphatebearing Maury equivalent rocks to car- bonate rocks of the Rockford Limestone may suggest northward transition from a subsiding oceanic basin, the Ouachita trough. Alternatively, considering a trough model without transition to a shelf, a eustatic rise in sea level could have initiated or extended starved basin conditions. The Rockford Limestone in such a model might represent a deep-water carbonate deposit (R.C. Kepferle, oral commun., 1985). ROCKS OF MOSTLY OSAGEAN AGE Rocks of Osagean age are comparatively thicker, lithologically more diverse, and exhibit more complex interrelationships than earlier Mississippian rocks (figs. 7 and 9). They comprise two marine rock assemblages which are dominant in specific areas: 1. Older terrigenous detrital clastics (Borden Forma- tion, New Providence Shale Member, Grainger Forma- tion, and basal clastic parts of Fort Payne Formation) deposited as prograding deltaic wedges. These are most- ly confined to the eastern and central parts of Kentucky, but their thinner distal equivalents extend throughout much of the southern and western parts of the State. They are generally bracketed in Kentucky by underly- ing “black shale” units and Maury Formation lithic equivalents and by overlying dominantly carbonate- rock units. 2. Younger siliceous, argillaceous, dolomitic, and crinoidal carbonate-rock units with local sandy ter- rigenous clastics (most of the Fort Payne Formation, Muldraugh Member of the Borden Formation and Renfro Member of the Slade Formation), which extend from east-central Kentucky across southern and west- ern Kentucky and Tennessee into southeastern Illinois and southwestern Indiana. During the 1960—1978 geologic mapping program, the concept of deltaic deposition for Borden and Fort Payne terrigenous clastic rocks in Kentucky (Borden delta) was developed (Peterson and Kepferle, 1970), a concept that has stimulated related research by individuals and groups; see for instance Sedimentation Seminar (1972); Whitehead (1976); Benson (1976); Kepferle (1972a, 1977a); and Kepferle and Lewis (1974). Thickness and directional transport components of sandstone units of the Borden and Fort Payne are shown in figure 16. Distribution of distinctive lithic units, dark shales, crinoidal limestones, and greenish mudstones, which make up significant rock volumes in some areas, is shown in figure 54 and discussed on pages 51 and 100—101. BORDEN FORMATION In eastern and central parts of Kentucky, units of Osagean age are dominated by terrigenously de- rived detrital rocks in the lower part, overlain by 88° 88° ROCKS 0F MOSTLY OSAGEAN AGE 87" 88° 85° 37 82° l *"‘i L e Z _ 4 Area depicting selected sandstone units 1 Farmers Siltstone 39" _ EXPL‘ANATION l ) lsopach thickness in feet— Thickness limits given where not depicted by isopachs <— Member (Moore and Clarke. 1970) and “Weir” sandstone of subsurface terminology 38° _ 2 “Rockcastle freestone” (Weir, 1970) 3 Jabez and Knifley Sand- stone Members (Kepferle, Lewis, and Taylor, 1972; ' Kepferle and others, 1980) 4 Kenwood Siltstone :3, .3. Member (Kepferle 1977) _‘ Sediment transport directions as given in references listed for areas 1—4 37° — 58 l88 MlLES FIGURE 16.—Distribution (stipple pattern). thickness, and sedimentary transport directions of selected sandstone units in the Borden and Fort Payne Formations in Kentucky. Base includes selected faults and fault zones. carbonate-rich beds in the upper part. The Borden For- mation (Weir and others, 1966), in part correlative with the Cuyahoga and Logan Formations of Ohio (Hyde, 1915), the Borden Group of Indiana (Cumings, 1922), and the Pocono Group of West Virginia, makes up all or most of Osagean age-equivalents in northeastern east-central, central, and parts of south-central Ken- tucky. The Borden Formation consists of 10 members. The terrigenous clastic part of the Borden in Kentucky typically consists of lower units of gray and green mudstone and siltstone (Nancy and New Providence Members) containing planar-bedded sandstone (Farmers and Kenwood Members) and lenses of crinoidal limestone. Sandstones and siltstones are com- posed largely of subangular to subround quartz and feldspar grains with quartz and calcite cement; they are mostly subgraywackes originating in a provenance of largely felsic plutonic rocks (Kepferle, 1977a). Tongues and lenses of siltstone in the middle part of the Borden in Kentucky grade northward and eastward into thicker and more abundant units of coarser siltstone and sand- stone in Ohio and West Virginia. In Kentucky these tongues and lenses include the Cowbell, Halls Gap, and Holtsclaw Members, and thinner, less extensive units such as the Gum Sulphur Bed of the Nancy Member and “Rockcastle freestone” of the Wildie Member. The detrital units form a elastic deltaic wé’dge which thins southwestward, and in large exposures they exhibit large-scale foreset bedding with westerly dip com- ponents (fig. 24). The uppermost units, the Wildie and Nada Members, are composed mostly of shale, including variegated varieties. Contacts of elastic units within the Borden Formation are generally gradational and do not show evidence of significant depositional or erosional breaks, except for thin glauconitic beds that are inter- preted to mark a depositional hiatus or an interval of slow sedimentation. As mapped, the uppermost, dominantly carbonate rock divisions of the Borden included the Renfro Member and the Muldraugh Member. The Renfro Member has been reassigned as the basal member of the Slade Formation by Ettensohn and others (1984). It is, however, discussed here with Borden Formation rocks with which it is in part equivalent. The Renfro includes dolomitic limestone and dolomite in northeast- ern, east-central, eastern, and south-central Kentucky. The Muldraugh Member, a thicker unit of light-colored cherty and silty dolomite and limestone, crops out in central and south-central Kentucky. The carbonate rock units are commonly separated from underlying elastic strata by thin glauconitic siltstone and limestone beds such as the Floyds Knob Bed of the Muldraugh Member in central Kentucky, and by thin glauconitic siltstone beds in northeastern, east-central, south-central, and west-central Kentucky. The Muldraugh is overlain by the Harrodsburg Limestone or the Salem and Warsaw 38 MISSISSIPPIAN ROCKS IN KENTUCKY SW NE FEET 400 Harrodsburg Limestone (crinoldal biorudite) 14f ///ew $114-1 _—_—~_—:_1—_—_‘*:_—____—fi—_—;::r‘_—_ Shale Member —‘_‘—_ —_—_—__—f——_:_—_‘__ _ A __ - .2 .. r. all-4 _..._...._._L ...,’,”_‘_;7_‘ Muldraugh Member 43:2,?” 495‘4:_:J_—O_. --(do|o§iltite and calcgiltite))-,Hfi/,j. _ ”AL—L", 3% L". fiNancy Membe ' ..’__;(gray'to greefljhale a—n_d silt . ,’ New Albany Shale (fissile organic shale) lllLL) l 2 MlLES l | FIGURE 17.-Restored cross section of the Borden Formation delta “front” in Howardstown quadrangle (Kepferle, 1966a), north-central Kentucky, showing relationships of Borden units. Datum, top of New Albany Shale. Modified from Kepferle, 1966a. Formations unit. Westward thickening of the carbonate rock units and reciprocal thinning of the underlying detrital units are characteristic internal relationships in the Borden. Contacts between these rocks are along generally southwestward-sloping planar surfaces (Peter- son and Kepferle, 1970; figs. 9 and 17 of this report). The southwest-thinning terrigenous elastic wedge of the Borden is an upward-coarsening succession of beds, representing westward progradation of the Borden delta. As indicated in the cross section (fig. 9), two pulses of clastic deposition culminated in deposition of the Farmers Member and the Cowbell Member; shales of the Nancy and New Providence Members represent distal prodelta sediments of the actively prograding deltaic system, followed by cessation of delta encroachment during which time the glauconite-bearing beds in the Nada Member and Floyds Knob Bed were deposited. FARMERS MEMBER In northeastern Kentucky, the Farmers Member is the basal unit of the Borden Formation (fig. 14). The Farmers includes the Vanceburg Sandstone Member of Hyde (1915), and was termed the Farmers Siltstone Member of the New Providence Formation by Stockdale (1939). The Farmers in its type area is 60 percent planar- bedded subgraywacke sandstone and 40 percent shale. It is more than 200 ft thick in northeastern Kentucky, thins southward into the Olympia quadrangle (McDowell and Weir, 1977) and extends into the Clay City quadrangle (Simmons, 1967; fig. 18 of this report). It is mapped with the Nancy Member of the Borden Formation in the Preston, Means, and Levee quad- rangles (Weir and McDowell, 1976; Weir, 1976; McDowell, 1978), where it consists of the Clay City (sandstone) and underlying Henley (shale) beds. Directional features, principally sole markings, indi- cate westward paleocurrent transport directions of the Farmers (Rich and Wilson, 1950; Rich, 1951; Wilson, 1950; fig. 16 of this report). The member is interpreted by Moore and Clarke (1970) to be a turbidite deposit. The “Weir Sand,” a driller’s term for several subsurface sandstones in eastern Kentucky and adjoining States, is in about the same stratigraphic position as the Farmers (Pepper and others, 1954). Of the two apparent south-trending lobes of sandstone in northeastern SW ROCKS OF MOSTLY OSAGEAN AGE 39 Olympia quadrangle NE SYSTEM SERIES FORMATION, MEMBER, AND BED SERIES SYSTEM Nancy Member of Borden Formation MISSISSIPPIAN Lower Clay City Bed l Farmers Member of Borden Formation Lower MISSISSIPPIAN Henley Bed l / x ___ __7___7_ datum Sunbury Shale l Bedford Shale Berea Sandstone 7 7 l a l 3 : . Z n- a) < 3 | o. —- NewAlbany . a. z E g Shale : OhloShale 3 S LI>J 33 | g g a E l w > .— _ Lu 2 | E o l s l FIGURE 18.—Generalized stratigraphic diagram of lower part of the Borden Formation and underlying units in northeastern Kentucky (from McDowell and others, 1981). Kentucky shown in figure 16, the western lobe represents the Farmers, strictly speaking, and the eastern lobe, more than 100 ft thick, is a “Weir Sand,” which may be a subsurface continuation of the Farmers. NANCY AND NEW PROVIDENCE MEMBERS The widespread Nancy Member, from about 150 to 300 ft thick, represents distal foreset and bottomset strata of the Borden delta. For the most part poorly resistant greenish-weathering gray silty shale and siltstone, the Nancy gradationally intertongues with the distal portions of several resistant siltstone-dominant members and beds (Cowbell, Holtsclaw, Roundstone, Conway Cut) (fig. 19). The Nancy Member also contains the Gum Sulphur Bed, a lentil of resistant siltstone in the Nancy shales (fig. 20) that emphasizes the elastic wedge character of the lower Borden. In central Ken- tucky, beds equivalent to the lower part of the Nancy, mostly greenish-weathering clay shale with sideritic claystone nodules and lenses, are termed the New Prov- idence Shale Member of the Borden Formation (Kepferle, 1971). The New Providence Member in the Louisville West quadrangle (Kepferle, 1974), 120 to 250 ft thick, encompasses the Kenwood Siltstone Member, a unit similar to the Farmers Member but thinner, finer grained, and less extensive. The Kenwood, FIGURE 19.—Borden Formation; contact of Cowbell Member (resist- ant unit) and underlying poorly resistant Nancy Member. US. Highway 25 at Boone Gap, Berea quadrangle, Rockcastle County. 40 MISSISSIPPIAN ROCKS IN KENTUCKY FEET 300 200 100 3 4'1 E13 MILES Location of sections FIGURE 20.—Sections showing relationships of siltstone units in the Borden Formation in the area between Brodhead and Bighill, east-central Kentucky (from Weir and others, 1966). an illite subarkose to illite-arkose, was studied intensive- ly by Kepferle (1972a, 1977a), who concluded it to be a pro-delta turbidite apron deposit. Directional elements in the Kenwood indicate west-southwest sediment transport directions (fig. 16). The New Providence and Nancy locally contain crinoidal limestone lenses and concentrations of fossils at many localities, including the classic Button Mould Knob fauna locality of Butts (1917, p. 11—17) and the Coral Ridge fauna, both studied by Conkin (1957), Kammer (1982), and Gordon and Mason (1985). Relationships of these clastic units in the Borden of central to south-central Kentucky are shown in figure 21A, B. In western central Kentucky the Nancy and New Providence are overlain abruptly by the Muldraugh Member (fig. 22) or they inter-tongue with siltstone beds of the Holtsclaw Member. In westernmost Kentucky, the New Providence Shale is given formational rank as a unit between the Fort Payne Formation and the New Albany Shale, as used in the Briensburg quadrangle (Lambert and MacCary, 1964); it is equivalent to the Springville Shale (Savage, 1920) of Illinois, and possibly to the basal fine—grained green shale of the Fort Payne above the Maury Formation equivalent in south-central Kentucky. COWBELL, HALLS GAP, AND HOLTSCLAW MEMBERS Resistant siltstone members of the Borden, made up of dominantly gray subgraywacke siltstone, generally with indistinct bedding because of extensive bioturba- tion, include the Cowbell Member in northeastern and east—central Kentucky (fig. 23), the Halls Gap Member in central, south-central and east-central Kentucky, and the Holtsclaw Siltstone Member in western central Ken- tucky. These mapped units, generally less than 100 ft but as much as 250 ft thick, include large-scale deltaic foreset bedding; and they intertongue with the Nancy Member. The Halls Gap Member exhibits these foreset beds in exposures such as the railroad cut at Kings Mountain in the Halls Gap quadrangle (Weir, 1972; fig. 24 of this report). These beds dip in westerly and south- westerly directions at angles of generally less than 5 °. The Cowbell and Halls Gap Members thin or grade to extinction westward. The Halls Gap extends as far west as the Saloma and Raywick quadrangles (S.L. Moore, 1976; Kepferle, 1973). NADA AND WILDIE MEMBERS Two fine-grained clastic units in the upper part of the Borden in east-central and northeastern Kentucky are ROCKS OF MOSTLY OSAGEAN AGE B 41 KOSMOSDALE VALLEY STATION 338%? QUADRANGLE QUADRANGLE RANGLE FEET . 500 Harrodsburg Limestone Muldraugh Member — — 400 Holtsclaw Siltstone Member c — é — 300 g Nancy Member 8 — E, -- 200 E o m Kenwood Siltstone Member 100 New Providence Shale Member datum\ New Albany Shale ' o A o 1 2 3 4 5 MILES l l | | J SHEPHERDSVILLE BROOKS / I CRAVENS 1 NEW HAVEN l fPUHLINGTOlIV IYOSEMITE datum FEET § Muldraugh Member -300 / \ / Halls Gap Member \ 2___ \ — 200 Nancy Member Holtsclaw Siltstone /\ Member New Providence Shale Member _100 Siltstone — 0 Member / 0 10 20 30 40 MILES l’J l l l I l FIGURE 21.—Relationships of the elastic units of the Borden Formation. A, As mapped in Kosmosdale, Valley Station, and Brooks quadrangles. central Kentucky (from Kepferle, 1971). B, As mapped from southern Jefferson County to Casey County, central and south-central Kentucky (from Kepferle, 1971). Dashed line, relationships uncertain. 42 MISSISSIPPIAN ROCKS IN KENTUCKY FIGURE 22.——Nancy Member (at vehicle level) and overlying Muldraugh Member of the Borden Formation. Milepost 97.8, Inter- state Highway 65, 3.5 mi north of Elizabethtown exit, Colesburg quadrangle, Hardin County. the Nada and Wildie Members (fig. 9). The Nada (fig. 25), 30—65 ft thick, is predominantly variegated (olive gray, grayish red, grayish purple), clayshale and silt shale with siltstone and glauconitic siltstone; it extends from northeastern Kentucky southeastward through the Berea quadrangle (Weir and others, 1966, p. F15) and the northern part of the J ohnetta quadrangle (Gualtieri, 1968b). In northeastern Kentucky the Nada locally contains beds of crinoidal limestone, as in the Cranston quadrangle (Philley and others, 1974). Glauconite—rich layers at the base and top or within the member occur south of the Berea quadrangle (Weir, 1967), and a glauconite layer occurs a few feet below the top of the Nada farther north. The lower part of the Nada is interpreted to grade southwestward into the Nancy Member and the siltstone of the Halls Gap Member, and the upper part into greenish siltstone and shale of the Wildie Member. The Wildie Member contains very minor amounts of variegated, mostly greenish shale, common beds of glauconitic siltstone, and locally phosphatic nodules at its top, base, or both (Brown and Osolnik, 1974; Gualtieri, 1967a; Schlanger and Weir, 1971). In general, reddish hues in these units diminish southward along the eastern Kentucky outcrop belt. The Nada and Wildie Members are both overlain by the Renfro Member (fig. 25). The Wildie merges westward with the Halls Gap Member (Weir, 1972) or may thin to become the Floyds Knob Bed (Whitehead, 1976). In earlier mapping, the Nada was considered part of the Muldraugh Member, as in the Haldeman quadrangle (Patterson and Hosterman, 1961). An infor- mal unit of limited extent in the Wildie Member is the “Rockcastle freestone,” in which paleocurrent features indicate westward directions of transport (fig. 16), and bedding features suggest that it is a turbidite (Weir, 1970, p. 39). RENFRO MEMBER Carbonate rock units named the Renfro and Muldraugh Members (Weir and others, 1966) were placed in the uppermost part of the Borden. These units were considered part of the Borden until 1984, when the Renfro was placed in the basal part of the Slade For- mation, overlying the Borden (Ettensohn and others, 1984). The Renfro Member (Schlanger, 1965) of east-central, northeastern, and south-central Kentucky, with its sub- surface and southeastern Kentucky equivalents, is a widespread unit throughout much of the eastern part of the State. It consists dominantly of aphanitic to fine- ly crystalline, argillaceous dolomite and dolomitic lime- stone with local interbeds of gray micritic limestone. The dolomite in part represents dolomitized calcarenite with few relict grains. At some localities, siliceous car- bonate rocks, probably Muldraugh Member equiva- lents, have been included in the basal Renfro, and St. Louis Limestone micritic lithologies have been included in the upper part of the Renfro. The unit weathers to distinctive yellow and orange hues. Macrofossils are very sparse. Grayish-green shale beds are relatively common, as are arenaceous and glauconitic grains, par- ticularly in east-central Kentucky. In most places the Renfro conformably overlies glauconitic siltstone beds of the Nada or Wildie Members, and in the Woodstock quadrangle where the Wildie pinches out, the Renfro rests on the Halls Gap Member of the Borden Forma- tion (Weir and others, 1966). In northeastern Kentucky, the Renfro is thin, and was included with the Newman Limestone on some geologic quadrangle maps, for ex- ample Brushart (Denny, 1964) and Olive Hill (Englund and Windolph, 1975). Renfro-type dolomite lithologies can also be recognized in the basal Newman Limestone (“Greenbrier” or “Big Lime”) in many boreholes of eastern and southeastern Kentucky. They also occur ROCKS OF MOSTLY OSAGEAN AGE 43 FIGURE 23.—Cowbell Member of Borden Formation (siltstone and shale). Milepost 145, Interstate Highway 64. Cranston quadrangle, Rowan County. sporadically along the Pine Mountain outcrop belt, southeastern Kentucky, verified by Dever at three sites: the Burdine quarry north of Jenkins, in Hurricane Gap near Cumberland, and in an abandoned quarry at the head of Limestone Branch in Frakes quadrangle. Renfro-type dolomite is also present on Interstate Highway I-75 south of Jellico, Tenn. (Sedimentation Seminar, 1981) and at Cumberland Gap, Va. Subsurface studies of the “Big Lime” (lower and middle Newman Limestone) in eastern Kentucky (Pear, 1980) and southeastern Kentucky (Hetherington, 1981) indicate that dolomite facies possibly equivalent to Renfro dolomite are intermittently present in eastern Kentucky and more persistent in southeastern Kentucky in the basal and lower parts of thick sections of the “Big Lime.” These possible Renfro equivalents reach a thickness of more than 30 ft, and contain petroleum and gas reservoir beds. The upper contact of the Renfro according to Weir and others (1966) is a conspicuous diastem. Inter- tonguing of Renfro dolomitic strata with the overlying St. Louis dense micritic limestone has been reported in the Wildie (Gualtieri, 1968a) and Brodhead (Gualtieri, 1967b) quadrangles, but subsequent examination of these areas by Dever and others (197 9d) suggests that the reported intertonguing may simply reflect the fact that discrete bodies of Renfro-er dolomite occur in the St. Louis Limestone Member of the Newman, and con- versely, interbeds of micritic limestone like that in the St. Louis occur in the Renfro. Such occurrences appear to indicate fluctuations in depositional environments during Renfro and subsequent St. Louis time without representing true intertonguing along contemporaneous time boundaries. Subsurface studies in eastern and southeastern Kentucky (Pear, 1980; Hetherington, 1981) suggest that basal dolomitic beds of the “Big Lime” were deposited in submarine channels cut into the underlying Grainger sediments or in other submarine topographic lows. In the east-central Kentucky outcrop belt, the Renfro thins northeastward; the overlying St. Louis Limestone Member maintains a relatively con- stant thickness. The sharp contact between the Renfro and the St. Louis in east-central Kentucky may repre- sent a hiatus, but observations in recent years suggest that it is a diagenetic contact between dolomitized and undolomitized limestone. Lobate patterns shown by 44 MISSISSIPPIAN ROCKS IN KENTUCKY FIGURE 24.—Halls Gap (dark) and Muldraugh (light) Members of Borden Formation, looking west. Inclined bedding along front of Borden deltaic sediments in center of photograph. Railroad cut northwest of Kings Mountain. Halls Gap quadrangle, Lincoln County. isopach maps of the underlying detrital deposits in east- central and south-central Kentucky suggest that the topography on the top of the Grainger may be mainly depositional rather than the result of erosion. The major part of the Renfro is reported to merge southwestward with the lower and middle parts of the St. Louis Limestone of south-central Kentucky (Lewis and Taylor, 1979; Dever and Moody, 1979a; Dever, McGrain, and Moody, 1979). Laterally, the lower and middle Renfro merges westward with the Muldraugh Member of the Borden Formation and with the Salem and Warsaw Limestones in the vicinity of the Crab Orchard and Brodhead quadrangles (Gualtieri, 1967a, 1967b); rock types in this interval in the Crab Orchard quadrangle in particular contain lithologies typical of these units and also of the Harrodsburg Limestone. Because Renfro lithologies characterize the unit west- ward to the Halls Gap quadrangle, an arbitrary west limit of the unit was placed at the Halls Gap—Crab Orchard quadrangle boundary (Weir, 1972). Fossils in the Renfro are mainly corals, crinoids, and brachiopods. Butts (1922) reported on collections in the present Brodhead quadrangle from Renfro beds which he termed Warsaw Formation, and the fauna was reported by him to have both Osagean and Meramecian affinities. Foraminifera from the middle part of the Renfro in the Bighill quadrangle (Weir and others, 1971), were reported by BA. Skipp (written commun., 1966) to include endothyrid species generally considered to be of Meramecian age. Con- odonts from the Renfro in the Wildie quadrangle (J.W. Huddle, written commun., 1966) indicate that the collections seem to be representative of the Gnathodus texanus—Apatognathus zone (early Val- meyeran or Osagean) of Collinson and others (1962) and also of their Taphrognathus van‘ans—Apatognathus zone (late Valmeyeran or Meramecian). Thus the Renfro would seem to represent late Osagean to early Meramecian ages, in agreement with Butts’ conclusions. ROCKS OF MOSTLY OSAGEAN AGE 45 FIGURE 25.—Nada Member of Borden Formation (Mbn) and overlying Slade Formation consisting of Renfro Member (Msr) and limestone and dolomite mostly of the St. Louis and Holly Fork (Ettensohn and others. 1984) Members (Mssh). Milepost 146.2, Interstate Highway 64, Cranston quadrangle, Rowan County. MULDRAUGH MEMBER The Muldraugh Member of the Borden Formation (Weir and others, 1966), is 50 to 100 ft thick in southern central and south-central Kentucky and as much as 300 ft thick in the western central Kentucky outcrop; it is the main unit in the uppermost Borden in these areas and in adjoining Indiana. Highly resistant, it is dominantly an olive gray, siliceous dolomitic siltstone (dolosiltite) or silty dolomite (fig. 26). Silica and car- bonate (dolomite and calcite) are main matrix minerals and constitute as much as 85 percent of the rock. Quartz-lined geodes and concretions are locally common. Fine-grained components are highly biotur- bated. Crinoidal calcirudite lenses and patches of skeletal limestone composed dominantly of crinoid and bryozoan debris (fig. 27) are also common. Large crinoid stem fragments reaching to more than an inch in diameter are similar to those in the Fort Payne Forma- tion and in limy lenses of Borden clastic units. The size and the robust character of brachiopod shells and crinoid columnal fragments are distinctive features of these units in Kentucky, and are not typical of younger Mississippian units. The lower contact of the Muldraugh Member with the Nancy, Halls Gap, and Holtsclaw Members is common- ly abrupt and marked by one or more thin glauconitic beds that have been previously ascribed to the Floyds Knob Formation by Stockdale (1939). These contact features suggest a depositional hiatus, followed by sudden resumption of deposition of mixed clastic and carbonate strata. FLOYDS KNOB BED The Floyds Knob Formation of Stockdale (1931, 1939), commonly a thin unit of glauconite or limestone and glauconite, was designated the Floyds Knob Bed of the Muldraugh Member of the Borden Formation in western central Kentucky by Kepferle (1977a). There, it is a widespread unit and an important stratigraphic marker within the Borden. In that area, for example, mapping of the abrupt southwestward stratigraphic drop of the Floyds Knob Bed relative to the base of the Borden enabled Peterson and Kepferle (1970) to recognize a northwest-southeast-trending foreset slope of the deltaic front which marks the southwestern limit of thick Borden detrital deposits of shale and siltstone. 46 MISSISSIPPIAN ROCKS IN KENTUCKY ~ .3‘ a 4. 1 FIGURE 26,—Dolosiltite and calcarenite in Muldraugh Member of the Borden Formation. Milepost 96.8, Interstate Highway 65, 2.5 mi north of Elizabethtown exit, Elizabethtown quadrangle, Hardin County. To the east, in east-central and northeastern Kentucky, two or more seams of glauconite occur in the upper part of, or at the top of, Borden terrigenous clastic strata. Southward, in south-central Kentucky, glauconite is also common in the uppermost part of the New Prov- idence Member of the Fort Payne Formation. The strati- graphic intervals represented by these occurrences are here considered to be approximately correlative with the Floyds Knob Bed of central Kentucky, in general agree- ment with the model proposed by Whitehead (1976, 1978b); and they are herein referred to as the Floyds Knob. Rare exposures in the southwestern part of Pine Mountain, southeastern Kentucky, show a glauconite bed, possibly the Floyds Knob, underlying the Fort Payne Chert. The Floyds Knob Bed of the basal Muldraugh in western central Kentucky consists of a single glaucon- itic layer or two glauconitic layers separated by 5—25 ft of phosphatic, siliceous silty dolomite, dolosiltite, clayey siltstone, and, locally, oolitic limestone (Kepferle, 1977a, 1979b). The two glauconitic layers converge into one layer along the Borden delta front (Kepferle, 197 9b). The Floyds Knob and the overlying lower part of the Muldraugh in northern central Kentucky and southern Indiana have been studied intensively by Whitehead (1976, 1978a). In southwestern central Kentucky, the Floyds Knob is a glauconitic zone, 5—7 ft thick, with the glauconite concentrated in seams and disseminated in the siltstone between seams (Moore, 1977). To the east, where the unit is included in the uppermost Nancy and Halls Gap Members, it is 5—10 ft thick and consists of one to three glauconite seams interbedded with silty shale, glauconitic siltstone, and, locally, crinoidal lime- stone; it contains chert and geodes (Lewis and Taylor, 1971; Lewis and others, 1973; Weir, 1972). The Floyds Knob in the uppermost Nancy Member grades eastward and northeastward into the Wildie Member, which consists of as much as 25 ft of shale and siltstone with persistent seams of commonly phosphatic glauconitic siltstone and limestone at the top and base ROCKS OF MOSTLY OSAGEAN AGE 47 FIGURE 27,—Upper part of Muldraugh Member of Borden Formation (Mbm) showing westward-thickening calcarenite lenses. Harrodsburg Limestone (M h) (uppermost light-hued, planar-bedded resistant ledges) at upper left side of photograph. Milepost 3.3, north side of Bluegrass Parkway. Elizabethtown quadrangle, Hardin County. of the member. Northeast of the Wildie-Nada boundary, the equivalent of the Wildie or Floyds Knob forms the upper part of the Nada Member, with persistent seams of glauconitic siltstone and limestone occurring at the top and near the middle of the Nada in southwestern east-central Kentucky. Discontinuous beds of glaucon- itic siltstone and limestone also occur in the lower part of the member (Rice, 1972; Weir and others, 1971). In east-central and northeastern Kentucky, the Floyds Knob Formation as defined by Stockdale (1939) was restricted to the glauconitic seam and associated limestone which occur at the base of the Wildie and ex- tend into the middle part of the Nada. Stockdale iden- tified the Floyds Knob as the most persistent of the several glauconitic seams present in the upper Borden of the eastern outcrop belt. Local occurrences of a glauconitic siltstone near the middle of the Nada were noted during mapping in central and northeastern east- central Kentucky, for example in the Stanton and Olympia quadrangles (Weir, 1974a; McDowell and Weir, 1977). In northeastern Kentucky, a phosphatic, glauconite-rich seam is present at the base of the Nada (Philley and others, 1975) and was considered cor- relative with the glauconitic siltstone near the middle of the Nada in east-central Kentucky (see Stockdale, 1939, pl. 16). A glauconite-rich shale present about 4 ft below the top of the Nada in exposures along Interstate Highway 64 in eastern Rowan County and western Carter County (Chaplin, 1980) may be correlative with the glauconitic seam at the top of the Nada and Wildie in southwestern east-central Kentucky. The areal extent of the Floyds Knob on the foreset slope of the Borden delta front and in the basin south- west of the front is not completely known. Peterson and Kepferle (1970) mapped the glauconite zone down the delta front in at least part of western central Kentucky and speculated that its local absence probably resulted from scouring by currents. In Taylor County, southeast- ward along the front, a core studied by the Sedimenta- tion Seminar (1972) showed that the Floyds Knob extends southwest of the Borden delta front and under- lies basinal deposits of the Fort Payne Formation. Far- ther to the southeast, the distribution of the glauconitic shale in the Delmer quadrangle (Lewis, 1971a), Pulaski County, indicates that the Floyds Knob is present on the upper part of the front, but at least locally absent on the lower part. It appears to merge southwestward with the Maury Formation equivalent at the base of 48 MISSISSIPPIAN ROCKS IN KENTUCKY the Fort Payne Formation (R.C. Kepferle, written commun., 1985). The Floyds Knob Bed and equivalents are fossilifer— ous, containing pelmatozoans, brachiopods, bryozoans, gastropods, pelecypods, cephalopods, trilobites, con- ulariids, ostracodes, and fish remains (Kepferle, 1979a; Stockdale, 1939; Weir, 1967; Weir and others, 1971). Foramin ifera were studied by Conkin (1954, 1960), and conodont fauna are reported by Weir and others (1971) and by Whitehead (1978a). Study of Floyds Knob glauconites by the Sedimen- tation Seminar (1972) showed that the glauconite occurs as dark-green microcrystalline pellets, up to 0.5 mm in diameter, which are concentrated along bedding planes and in burrows. The ovoid pellet shape and close asso- ciation with intense bioturbation suggest a fecal-pellet origin. Concentration of the Floyds Knob glauconites in a thin, widespread zone suggests accumulation dur- ing a period of decreased sedimentation. GRAIN GER FORMATION The Grainger Formation (Keith, 1895), exposed along Pine Mountain in southeastern Kentucky, is from 200 to 500 ft thick. Lithologies of the Grainger, largely shale and siltstone, are strikingly similar to those parts of the Borden Formation; and the formations probably in- tergrade or interlense laterally in the subsurface west of the Pine Mountain fault. The Grainger is character- istically gray and greenish-gray shale and siltstone similar to the Nancy and New Providence Members of the Borden, and commonly contains an upper unit of resistant gray, greenish-gray, and reddish-gray silt- stone, shale, and sandstone similar to those strata in the Nada Member of east-central Kentucky. Southward the overall grain size of the Grainger strata seems to diminish, and in Tennessee and Virginia, adjoining the southernmost part of the southeastern Kentucky out- crop belt, quadrangle descriptions report variegated shale as the main or only lithic component of the Grainger (Englund, 1964b). Locally, cherty beds which are Fort Payne equivalents are mapped as uppermost Grainger beds (Englund, Landis, and Smith, 1963; Englund, 1964b; Englund and others, 1964). The Grainger is the equivalent of the Nancy Member of south-central Kentucky and the New Providence Shale Member of central Kentucky. The Grainger is overlain by the Newman Limestone or the Fort Payne Chert. It is separated from the Newman by a relatively sharp diastem. Basal beds of the Newman are mostly micritic limestone character- istic of the St. Louis Limestone Member, but include local dolomitic limestone and dolomite, similar to those in the Renfro Member, and also to the Little Valley Limestone of adjoining Virginia (Wallace de Witt, J r., oral commun., 1965). The Fort Payne Chert, 0—20 ft thick, in the southwestern part of the Pine Mountain outcrop belt (Rice and N ewell, 1975; Newell, 1975; Rice and Maughan, 1978), is considered to be a thin distal eastward extension of the Fort Payne Formation. Ex- posures are largely of chert residuum; in fresh ex- posures, chert together with dolomitic limestone is locally interbedded with shale and sandstone (Englund, 1969). Although these beds have been interpreted to in- tertongue with the Grainger (Englund, 1969), it seems more likely that the Grainger—Fort Payne contact is a discrete interface marked by glauconite much the same as the base of Muldraugh in central Kentucky, as sug- gested by Whitehead (1976). In southeastern Kentucky, although glauconitic beds are not reported in the quadrangles mapped along Pine Mountain, glauconite is abundant in beds at the top of the Grainger Formation and in basal beds of the overly- ing Newman Limestone succession along US. Inter- state 75 near the Kentucky-Tennessee border in J ellico West quadrangle. A glauconite bed there was identified as the Floyds Knob Bed (Sedimentation Seminar, 1981). Glauconite has also been identified by Dever at two locations in Frakes quadrangle. Hasson (1973) reported a glauconitic zone in the type Grainger area in Ten- nessee. Whitehead (1976, p. 209—231) considered that this is part of a single glauconite zone which may con- sist of one or more beds occurring in the Borden (Floyds Knob), Grainger, and Fort Payne, and which extends over a very large region of the eastern and central United States. Whitehead’s conclusion was that the glauconitic beds are related to major eustatic sea-level rise in late Osagean time. FORT PAYNE FORMATION Rocks of the Fort Payne Formation (Smith, 1890) make up most of the interval between the underlying Chattanooga Shale, Maury Formation equivalent, or New Albany Shale, and the overlying Warsaw or Salem and Warsaw undivided, Harrodsburg Limestone, and Ullin Limestone (Lineback, 1966) in a broad belt en- compassing southern and western Kentucky and parts of Tennessee, southern Illinois, and southwestern In- diana. The Fort Payne and Ullin are interpreted to be successively younger units that onlap Borden delta detrital rocks in Illinois and Indiana (Lineback, 1966). In Kentucky, similar relationships indicate that both the Muldraugh Member of the Borden Formation and the Fort Payne are younger than Borden detrital rocks. The Muldraugh is contemporaneous with at least the lower part of the Fort Payne, but beds in the upper part of the Fort Payne in the western part of south-central ROCKS 0F MOSTLY OSAGEAN AGE 49 Kentucky and in the subsurface of west-central and western Kentucky may be younger than the Muldraugh. Interpretations of Fort Payne and Muldraugh basal relationships in central Kentucky (fig. 28) have ranged from intertonguing to discrete erosional or nondepositional surfaces. In Kentucky, the Fort Payne Formation is mostly a drab gray siliceous dolostone and dolosiltite, crinoidal limestone and chert, with lesser siltstone and shale, and locally thick sandstone. It is mapped in south-central, southern west-central, and western Kentucky. Four for- mal members, the New Providence Shale Member (Kepferle and Lewis, 1974), the Cane Valley Limestone and Knifley Sandstone Members (Kepferle and Lewis, 1974), and the J abez Sandstone Member (Kepferle and others, 1980), and the informal Beaver Creek limestone member (Klein, 1974) are exposed in south-central Ken- tucky. A thin cherty unit ascribed to the Fort Payne GREENSBURG QUADRANGLE SALOMA QUADRANGLE RAWVICK QUADRANGLE (Taylor and others, 1968) (Moore, 1976) (Kepferle, 1973) St. Louis Limestone St. Louis Limestone 'fi' 1 I'l'_‘ Eroded ‘.1 .1 -‘ .1 cu C 2 Salem and 8 Warsaw Limestone E Shale member Salem Limestone g—E/E :— —i_"— Harrodsburg Harrodsburg Shale :LL— Limestone Limestone n; C :m Halls Gap 9 L' -I—'-- Muldraugh Member E imestone ._ Member '5 "L C Muldraugh _,__ ‘ 3:) E ,9 Member 1: g Gap ‘5 3 H— Member LL 5 E Siltstone g '9 and 0 8 shale 1:: Not exposed . New Providence Nseriggragfiggf Shale Member ‘1‘ (Rice and Newell, 1975; Newell, 1975; Rice and Maughan, 1978) is recognized in the Pine Mountain area of southeastern Kentucky. Most of the Fort Payne in south-central Kentucky consists of generally uniform dolosiltites that are olive gray to medium gray, very fine grained, spally, and slightly argillaceous (fig. 29); their silicification ranges from irregular patches to almost complete replacement of patches of crinoidal and bryozoan debris. Evidence of intense bioturbation is common in south-central Ken- tucky. In a matrix of generally fine dolomite rhombs and clay minerals (illite, chlorite, and kaolinite), the framework is mostly quartz silt and sand grains, and minor glauconite pellets and fossil fragments. Many dolomite rhombs also appear to be detrital. Geodes and blebs are locally common, containing mostly quartz, gypsum, and anhydrite with minor sulfide minerals. Most of the Fort Payne in south-central Kentucky FIGURE 28.—Generalized diagram showing interpretations of relationships of Salem-Warsaw, Salem, Harrodsburg, Borden, and Fort Payne Formations in three quadrangles in central and south-central Kentucky (from S.L. Moore, 1976). FIGURE 29.-Fort Payne Formation in roadcut along launching ramp road, Lake Cumberland State Park, Jamestown quadrangle, Russell County. closely resembles the Muldraugh Member of the Borden Formation but is somewhat darker hued. It ranges frOm about 200 to more than 300 ft thick in south-central Kentucky. In western and southwestern Kentucky the Fort Payne is thicker (to more than 600 ft), darker, more siliceous and cherty (as much as 40 percent chert), is interbedded with limestone (Fox and Olive, 1966) rather than dolomite, and is generally more planar bedded than the fighter hued, highly bioturbated succession in south- central Kentucky. The westernmost Kentucky Fort Payne is interpreted to represent a basinal facies and the central Kentucky unit to represent platform slope and platform facies, roughly similar to the interpreta- tion of deposition on the Borden platform by Benson (1976). The lowermost unit of the Fort Payne Formation in south-central Kentucky, the New Providence Shale Member (Kepferle and Lewis, 1974), thins westward from 150 to a few feet thick. Lithologically like the New MISSISSIPPIAN ROCKS IN KENTUCKY Providence Member of the Borden Formation and commonly including basal phosphatic claystone iden- tical to the Maury Formation equivalent, it represents the distal foreslope and bottomset beds of the Borden- Grainger deltaic deposits. A glauconite-rich bed, rare- ly reported in south-central Kentucky geologic quadrangles, at least locally separates the siliceous Fort Payne beds from the underlying New Providence Member. This is correlated with the Floyds Knob Bed of western central Kentucky. Within the dominant siliceous and dolomitic rock types in the south-central Kentucky outcrop area, the Fort Payne contains elongate lenses of light-hued crinoidal calcirudite limestone with characteristic ac- companying green-tinged mudstone. The largest of these lenses, the Cane Valley Limestone Member, is as much as 150 ft thick. It lies west of southeast-trending lenses of sandstone more than 250 ft thick, the Knifley Sandstone Member (Kepferle and Lewis, 1974). The Beaver Creek limestone member of the Fort Payne (Klein, 1974) is another calcirudite unit which is locally a petroleum reservoir. These limestone and sandstone lenses occur parallel to and west of the southeast- trending Borden delta front (fig. 54). They are inter- preted to represent two types of carbonate banks, as mud mounds and as skeletal sands (Lewis and Potter, 1978). The Cane Valley and Knifley Members have been intensively studied (Sedimentation Seminar, 1972). Beds in the Cane Valley Limestone Member inter- finger with Fort Payne dolosiltites and locally inter- finger eastward with the Knifley Sandstone Member. Limestones are dominantly biorudites, coarse-grained skeletal bryozoan and pelmatozoan limestones with minor quartzose sand grains in a matrix of sparry calcite and minor microcrystalline dolomite. Partial replacement by silica is common. Depositional dips are mostly southwestward but are locally bimodal. Greenish-gray mudstone occurs as conspicuous inter- beds and as matrix between fossil fragments. Other largely northwest trending related limestone lenses as much as 100 ft thick exposed in the Fort Payne of south- central Kentucky are composed largely of echinodermal debris and include large crinoid stem segments more than an inch in diameter (Taylor, 1962, 1964; Thaden and others, 1961). The Cane Valley has been interpreted to be a slope edge or platform edge shoal bank deposit into which fossil debris on the deltaic platform to the east was transported, partly winnowed, and concen- trated (Sedimentation Seminar, 1972, p. 20; Lewis and Potter, 1978). It is considered mostly younger than the Knifley Sandstone Member, and formed during an interval when coarse elastic terrigenous sedimentation was weak. Cane Valley depositional types, mostly occupying the middle part of the Fort Payne, extend ROCKS OF MOSTLY OSAGEAN AGE 51 northwestward in the subsurface and may have accumu- lated as a deeper water submarine bank or fan deposit. The Beaver Creek limestone member, similar lithologically to the Cane Valley Member, occurs in the lower part of the Fort Payne down-dip from the Cane Valley Limestone Member bodies. It consists of coarse- ly crinoidal biohermal-type deposits of varying grain size and bedding thicknesses. Klein (1974) interpreted the deposits to be a series of submarine fans deposited by flow mechanisms in approximately 300 ft of water at the toe of a prograding carbonate platform. Sandstone in the Knifley Member is fine-grained, silty, argillaceous subgraywacke with angular grains, dominantly an illite-sublitharenite (Kepferle, 1977a). Mineral composition is about 30 percent clay and 6 per- cent dolomite matrix within a framework of 90 percent quartz, 5 percent feldspar and micas, rock fragments, glauconite, and opaque minerals. West to southwest depositional dips are dominant (fig. 16); grain size generally increases upward, but the bedding in the Knifley is poorly defined because of intense bioturba- tion. The Knifley has been interpreted to be a slope break shoal deposit (Sedimentation Seminar, 1972). The J abez Sandstone Member of the Fort Payne (Kepferle and others, 1980) is a body similar to and along strike with the Knifley in south-central Kentucky. Subsurface well logs indicate that a dark shale facies occurs in the Fort Payne—Borden succession along a northwest-trending belt from about 5 to 15 mi wide and 80 mi long in the subsurface of the northern part of western and west-central Kentucky (fig. 54). This belt lies west of the Borden delta front and northeast of the crinoidal limestone—greenish shale facies, along strike of the Knifley Sandstone. West of the dark shale facies are dark siliceous basinal Fort Payne rocks. The shale is generally described (Freeman, 1951, p. 167, 230) as dark-gray to dark-brown limy shale or shaly limestone in contrast to the hard siliceous shale and limestone that are characteristic of the Fort Payne. Because the dark shale facies lies along strike of the Knifley Sandstone Member, the shale may represent fines that were win- nowed from Knifley sands or which passed over or around Knifley sand deposits and settled west of and marginal to the Borden delta slope break. Transporta- tion agents may have been northwest-flowing currents along the delta slope. High carbonate and silica content is characteristic of Fort Payne rocks, but origin of the silica content is uncertain. Analyses of the Fort Payne in south-central Kentucky and Illinois show that quartz of silt and clay size is an important although variable constituent of these rocks (Sedimentation Seminar, 197 2, p. 4; Lineback, 1966, p. 23). Silica content in the Fort Payne has also been ascribed to chemical precipitation or replacement during deposition and diagenesis or to secondary causes such as weathering (Bassler, 1932, p. 154—155). Sponge spicules are also abundant consti- tuents of some of these rocks (Gutschik, 1954). STRATA OVERLYING BORDEN AND FORT PAYNE FORMATIONS Borden and Fort Payne strata, herein treated as in- cluding the Renfro Member, are overlain conformably by units mapped as Warsaw Limestone, Salem and Warsaw Formations undivided, and Harrodsburg Limestone in south-central and western Kentucky. Isolated outliers of the Salem and Warsaw Formations unit above more continuous Borden and Fort Payne strata across the Cumberland saddle in south-central Kentucky permit correlations west of the saddle with those in eastern Kentucky. In eastern Kentucky, the Salem and Warsaw are at least in part continuous with strata of the Renfro Member, exposed along the western margins of the Appalachian basin. In northeastern Ken- tucky these units are absent because Pennsylvanian rocks unconformably overlie Borden Formation. Fort Payne rocks are locally overlain by Cretaceous and Ter- tiary beds along the margins of the Mississippi Embay- ment in western Kentucky (Olive, 1965; Wilshire, 1964). The Grainger Formation and Fort Payne Chert are overlain abruptly by lowermost beds of the Newman Limestone along parts of the Pine Mountain outcrop belt. In places, the basal beds of the Newman are dolomitic limestones which are like those in the Renfro Member of the Slade Formation in east-central Ken- tucky; and they are here provisionally correlated with the Renfro. DEPOSITIONAL HISTORY OF THE BORDEN AND FORT PAYNE FORMATIONS That the Borden Siltstone of Illinois and the elastic units of the Borden Formation in Kentucky and Indiana were both deposited in a deltaic framework (Frund, 1953; Swann and others, 1965; Lineback, 1966; Weir and others, 1966; Peterson and Kepferle, 1970) is well established. According to Lineback (1966), crinoidal car- bonate banks in western Illinois grew to heights of 200—300 ft above the sea floor of a deep-water basin located in central and southern Illinois. As the Borden deltaic complex advanced westward into Illinois, its southward deflection by the carbonate banks on the west determined the direction of growth of the long, tongue-shaped Borden delta there. Lineback (1966) con- cluded that sediment at the foot of the delta was deposited in water depths exceeding 600 ft, and inter- preted several sandstone bodies in Illinois to be 52 MISSISSIPPIAN ROCKS IN KENTUCKY turbidites deposited largely on the pro-delta plain (Lineback, 1968b). After active delta growth ceased, dark siliceous carbonate rocks of the Fort Payne were deposited in the adjoining deep-water basin and on foreset slopes of the delta, partly filling depressions ad- jacent to the delta. Although deltaic structure in the Fort Payne has not been proven, convex-upward pro- files of upper surfaces of the unit in Illinois where it is thick (Lineback, 1966, p. 26-27) and some current struc- tures suggest deposition of very fine detritals in en- vironments also favorable to carbonate accumulation. Progradation of the Borden delta into Kentucky, however, probably preceded that of the Borden delta in Illinois, as indicated by the biostratigraphic work of Gordon and Mason (1985). After deposition of the basinal Fort Payne, according to Lineback (1966, 1969), an irregular submarine topog- raphy in part with starved basin conditions was left in southern Illinois. There, deep narrow depressions in the sea floor were filled by Muldraugh-like sediments of the Ullin Limestone, which overlapped the Fort Payne and eventually onlapped terrigenous clastics of the Borden delta. Cross-stratified fossil-fragmental carbonate sediments (Harrodsburg) in the upper part of the Ullin Limestone were deposited on a shallow-water platform on the Borden delta, and filled in the adjoining depres- sions, resulting in shallow water throughout the area. Deltaic deposition of Borden terrigenous strata in Kentucky was probably similar to that just described for Illinois, except that the delta in Kentucky advanced as a broad depositional shelf. Evidence includes wester- ly and southwesterly depositional dips in Borden detrital rocks in south-central and central Kentucky (Weir and others, 1966; Kepferle, 1968), and abrupt reciprocal thickness relationships between westward- thinning Borden siltstone and shale and overlying Muldraugh Member carbonates, which are separated by a discrete depositional delta-front interface (Kepferle, 1966b; Peterson, 1966; Peterson and Kepferle, 1970). The depth of water probably did not exceed 375 ft in northern west-central Kentucky (Kepferle, 1977a, p. 38), and restricting crinoid banks west of the encroaching deltaic sequence were absent or else minor in thickness and extent. Probable turbidite sandstone and siltstone bodies include, in approximate decreasing age order, the Farmers, the Kenwood, and the “Rockcastle freestone.” Their emplacement was possibly triggered by seismic shock (Kepferle, 1977a, p. 40). Discontinuous crinoidal biostromal limestones, such as the Cane Valley Lime- stone Member and Beaver Creek limestone member, and the elongate bar-like sandstone bodies such as the Knifley Sandstone Member, lie parallel and marginal to the main mass of Borden detrital rocks in west- central and south-central Kentucky. Carbonate skeletal material was washed from platform areas of the delta into deeper water where it accumulated in bar-er and fan deposits along the delta front, possibly on a shelf- break on the delta slope and on the delta toe adjoining the basin. According to Hannan (1975), Fort Payne rocks in south-central Kentucky represent deposits by gravity flow mechanisms along the southwest-facing clinoform slope of a carbonate platform edge. The deposits in- clude toe, slope, shallow water, and evaporite facies of a southwestward-prograding carbonate platform which succeeded the more actively prograding Borden delta. The Cincinnati arch area, “Cincinnatia” of Pepper and others (1954), was probably submergent during most or all of Early Mississippian time. Thicknesses of Borden strata and their depositional vector directions do not show evidence that such a barrier was present during Borden—Fort Payne deposition (Whitehead, 1976, p. 269—270). It has been suggested that the Cin- cinnati arch was slightly emergent during earliest Mississippian time and even contributed minor amounts of fine-grained sediment initially to the basal Borden (Sable, 1970). That phosphatic nodule accumula- tions likely caused by upwelling along a single shelf were present both east and west of the arch (R.C. Kepferle, written commun., 1985) argues against the presence of an extensive emergent arch during any part of Early Mississippian time. The protoquartzites or subgraywackes prevalent in detrital Borden units (Potter and Pryor, 1961) contrast strongly with the clean orthoquartzite characteristic of Upper Mississippian sandstones; Borden rocks are rela- tively immature, and their mineralogy reflects a source terrane of metamorphic and felsic plutonic rocks. Major source areas for Borden sandstones have been inter- preted as being east and north of the Appalachian basin (Potter and Pryor, 1961; Walker, 1962), in the Canadian Shield (Potter and Pryor, 1961), and possibly in north- ernmost Canada (Swann and others, 1965, p. 15). Whitehead (197 6, p. 267) presented evidence for an easterly source area, and rejected distant northern Canada sources. The volume and thickness trends of detrital sediments transported into the Eastern Interior and Appalachian basins indicative of transport direc- tions also suggest to us that eastern rather than north- ern Canada sources were dominant, perhaps located in or east of the present Piedmont belt or the New England Acadian mountain systems, and that the Canadian Shield was not an important source area. Sources east and northeast of the Appalachian basin contributed a large quantity of sediment to the eastern United States, but only the distal portions of this large volume of detritus reached Kentucky. ROCKS OF MOSTLY OSAGEAN AGE 53 Location of source areas for the fine detrital com- ponents of the Fort Payne of southern and western Ken- tucky is uncertain; if the silica contained in the Fort Payne is largely clastic detritus, this might indicate dis- tant topographically low eastern or southern sources. Perhaps supporting the possibility of southern source areas is the presence of relatively thick mudstones in the basal Fort Payne in some places in southwestern Kentucky and in Tennessee (fig. 9). Paleogeographic reconstruction for late Borden—Fort Payne time (Sable, 1979a) indicates that shallow marine waters covered most of the areas, but westward-deepening troughs ex- isted in western Kentucky (figs. 54, 55, 56; Lineback, 1969, p. 123), later to be filled with the Fort Payne For- mation, the Harrodsburg Limestone, and the Warsaw Limestone of Butts (1917). AGE In the type Mississippian Mississippi Valley succes- sion, the Meppen Limestone (Collinson, 1969) and Fern Glen Limestone are considered to be of earliest Osagean (Valmeyeran of Illinois) age, the Burlington Limestone to be of middle Osagean, and the Keokuk Limestone to represent late Osagean time. Beds representative of earliest Osagean or Val- meyeran time (Meppen in the Mississippi Valley (Collin- son, 1969)) have not been recognized in Kentucky. Megafauna in the lower part of the Borden of northeast- ern and east-central Kentucky (New Providence group of Butts, 1922) were assigned to Fern Glen and possibly Burlington ages by Butts (1922, p. 50). In central Ken- tucky, however, megafauna, foraminifera, and con- odonts in the basal part of the Borden (New Providence Shale of Butts) are reported as Burlington in age (Butts, 1917, p. 17; Conkin, 1957; Collinson and Scott, 1958; Rexroad and Scott, 1964). Thus a considerable hiatus representing early and part of middle Osagean time seems to be indicated at the base of the Borden Forma- tion in some Kentucky areas. Such a time gap would represent the time taken for the Borden delta front, en- croaching from the east or northeast, to reach central and south-central Kentucky, time during which starved- basin conditions existed west of the delta front. During this time, only thin red and green mudstones in Ken- tucky, central Indiana, and Ohio were interpreted to have been shed from Cincinnati arch areas (Sable, 1970), but even these may represent distal sediments from sources farther east or northeast. Fossils in the Muldraugh Member include crinoids, brachiopods, and bryozoans. Identifications by Macken- zie Gordon, Jr. (written communs., 1965, 1971) indicate a late Early Mississippian (late Osagean) age. Conodonts from the Floyds Knob in south-central and east-central Kentucky (Science Hill, Delmer, Bighill, Wildie, Mt. Vernon, Maretburg, Halls Gap, and Yosemite quadrangles) and from the type Floyds Knob Bed at Floyds Knob, Indiana, were identified by J .W. Huddle (written communs., 1964, 1965; see tables 3—6). Gnathodus texanus Roundy is relatively abundant in those samples, and is representative of the Gnathodus texanus—Taphrognathus zone (lower Valmeyeran or Osagean) of Collinson and others (1962, fig. 66). Paleon- tologic identifications by Whitehead (1976, p. 71—141) of conodonts from the Muldraugh of Indiana and Ken- tucky, including the Floyds Knob, confirmed Huddle’s interpretation of the age of the Floyds Knob in central Kentucky and Indiana as the Gnathodus texanus— Taphrognathus zone. Whitehead placed overlying beds of the Muldraugh in the Taphrognathus varians— Apatognathus zone of Collinson and others (1962), which ranges through the Warsaw Limestone and Salem Limestone in Illinois and according to Nicoll (1971) into the St. Louis Limestone in Indiana. The Gnathodus texanus-Taphrognathus zone according to Nicoll and Rexroad (1975, p. 16) ranges through the Edwardsville Formation, Ramp Creek Formation (Stockdale, 1929), and part of the Harrodsburg Lime- stone in Indiana; and the Taphrognathus varians— Apatognathus zone extends from the upper part of the Ramp Creek and Muldraugh Formations (Muldraugh Member of Kentucky) through the Harrodsburg and most of the Salem, becoming rare in the St. Louis Limestone. Thus this evidence suggests that the Floyds Knob Bed and glauconitic zones of Kentucky are of late Osagean (Keokuk) age and that the Muldraugh Member of the Borden Formation is of late Osagean and early Meramecian age. This is not reflected in the correlation chart (fig. 7), which indicates this boundary to lie above the Muldraugh Member, pending further verification of the interpretation discussed herein. Megafauna in the Fort Payne of south-central, cen- tral, and west-central Kentucky was reported by Butts (1922, p. 76—88) to be of late Osagean (Keokuk) age. Butts obviously included strata now considered to be in the Muldraugh. Few recent collections have been made, and none shed more light on specific ages of the Fort Payne within Kentucky. PALEOTECTONIC IMPLICATIONS Parts of the Ozark region, northeastern Missouri, and western Illinois were uplifted during early Borden time. Farther east, in Illinois, Indiana, and western Kentucky, a differentially subsiding basin existed. Still farther east, a stable, submerged shelf was present in eastern Kentucky. 54 MISSISSIPPIAN ROCKS IN KENTUCKY The Cincinnati arch, including the Nashville dome, was a stable to slightly positive structure that separated somewhat more rapidly sinking basins. The LaSalle anticlinal belt of Illinois including its southeastward extensions in Kentucky was stable to slightly positive. After possible slight uplift early in Osagean time, the Ozarks and their marginal areas in western Illinois and Missouri became a slowly subsiding platform. North of the area, the Transcontinental and Wisconsin arches, probably emergent in early Osagean time, were also slightly negative later in the interval. A major negative feature in Early Mississippian (early Osagean) time was a southward-deepening trough that extended from the Michigan Basin southwestward across central and southern Illinois and southward under the present Mississippi Embayment (Pryor and Sable, 1974, p. 293). This trough may have continued into the deep Ouachita geosyncline of Arkansas and Oklahoma. OSAGEAN-MERAMECIAN SERIES BOUNDARY The Osagean-Meramecian Series boundary has been extremely difficult to recognize in the Eastern Interior basin. Uncertainties of correlation result from disagree- ments regarding specific ages of megafaunal assem- blages at or near the boundary, and from imperfect understanding of the complex depositional relations. Although many published reports on the western part of Kentucky and on Indiana, Tennessee, and Missouri refer to the Osagean and Meramecian Series designa- tions, the Illinois State Geological Survey has combined these into a single series, the Valmeyeran. Most geolo- gists agree that no regional hiatus marks the series boundary in the Eastern Interior basin, and that deposi- tion was generally uninterrupted, although in some areas such as east-central Kentucky, depositional en- vironments changed markedly. Osagean-Meramecian Series boundary problems have been mostly related to the age assignments and correla- tions of the Warsaw Formation (or Warsaw Shale) near its type area in western Illinois and in its eastward sub- surface extension; of rocks termed Warsaw in Kentucky and Tennessee; and of the Harrodsburg and Salem Limestones in Indiana and adjoining Kentucky. Shales and limestones of the Warsaw in western Illinois have been variously assigned to the Osagean or Meramecian or both (S. Weller, 1909; Butts, 1922; Moore, 1928; Van Tuyl, 1925; Laudon, 1948; Wanless, 1957; Weller and Sutton, 1940; J .M. Weller and others, 1948; Sando and others, 1969). Subsurface work by Lineback (1966) in- dicated that shale in the type Warsaw merges eastward into the Borden Siltstone, thereby suggesting that the shale is of Osagean age. However, Lineback’s cross sec- tions indicate that part of the Warsaw may descend into the Borden and part maintain a high position within the upper Borden. As a discrete unit, the Warsaw is recog- nizable only in western Illinois and a short distance eastward into the Bordeh of the Illinois subsurface; thus far, it has not been possible to establish conclusive physical continuity or contemporaneity with the Ken- tucky Mississippian succession. Butts (1922) first used the name Warsaw in western Kentucky for rocks overlying the Fort Payne chert or Holtsclaw Sandstone of Butts (1915), currently the up- permost Borden detrital rock units in Jefferson COun- ty, Ky. The name Warsaw remains in current use in parts of Kentucky and throughout Tennessee. In Ken- tucky, in addition to this usage, Warsaw has been used in a restricted sense for rocks corresponding to the “Up per” Harrodsburg of Indiana (McFarlan, 1943, p. 75). Because the type Warsaw in Illinois is neither directly traceable into nor lithologically identical with the War- saw of Kentucky and Tennessee, both usages of War- saw in Kentucky and Tennessee, in the opinion of the present authors, should be abandoned. The 1960—68 mapping in Kentucky confirmed Stockdale’s (1939) opinion that Butts’ Warsaw unit includes lithologic and age equivalents of the Salem (Meramecian), Harrods- burg (Meramecian and Osagean?), and Muldraugh (Osagean). Examples of varied interpretations in this stratigraphic interval in central and south-central Ken- tucky are shown in figure 28. Rocks called Warsaw in Tennessee, even farther from the type Warsaw in II- linois, are probably also correlative with part of the Salem, the Harrodsburg, and the Muldraugh. In much of east-central and northeastern Kentucky, the Renfro Member of the Borden and Slade Formations and Renfro equivalents in the basal part of the Newman Limestone, as well as younger beds, directly overlie Borden detrital rocks. In outcrop, the Renfro lies be- tween Borden detrital rocks and upper St. Louis equiva- lents in the Slade Formation, and is relatively thin. In northeastern south-central and southwestern east- central Kentucky, thin Harrodsburg-like crinoid- and bryozoan-bearing, light-gray limestone lenses and beds appear in the middle part of the Renfro and thicken westward, as the lower and middle parts of the Renfro grade respectively into the Muldraugh and the Salem (Weir and others, 1966); the upper part of the Renfro is absent in this crucial area because of Quaternary ero- sion. The upper Renfro, however, has been demon- strated to be equivalent to the lower and middle parts of the St. Louis Limestone of south-central Kentucky (Dever and Moody, 1979a). Nicoll and Rexroad (1975) indicated that the Harrods- burg Limestone and part of the Salem Limestone in ROCKS OF LATE OSAGEAN AND MERAMECIAN AGE 55 Indiana contain conodont elements similar to those of the Warsaw Shale and overlying Salem Limestone of Illinois. These data suggest that the Harrodsburg- Salem boundary of Indiana and Kentucky is only slight- ly younger than the Warsaw-Salem boundary of Illinois. Lineback’s (1966, p. 14) correlation equating the Western Illinois Warsaw with part of the Borden Siltstone may relate only to Illinois stratigraphy. On the basis of con- odont evidence, the Warsaw Shale equates with the up- per part of the Muldraugh and lower part of the Harrodsburg in Indiana because of Taphrognathus varians—Apatognathus zone forms in these units (Nicoll and Rexroad, 1975, p. 16). In the Cincinnati arch area erosion has removed most of the rocks spanning the Osagean-Meramecian bound- ary, so that all except the lower units in south-central Kentucky are separated by at least 80 mi from their western counterparts. Lithologic and faunal evidence, however, indicates that all major units were once con- tinuous at least across the Cumberland saddle in south- central Kentucky. The extensive yellowish-weathering carbonate rocks of the Renfro Member of the Slade Formation and its lithic equivalents in the basal Newman Limestone span the Osagean-Meramecian boundary in east-central Kentucky but appear to be a St. Louis equivalent, and thus are entirely Meramecian in northeastern Kentucky (Dever, McGrain, and Moody, 1979, fig. 5.4). The Renfro grades westward into the Salem, Harrodsburg, and Muldraugh, as well as into the Salem and Warsaw Formations undivided unit in south-central and central Kentucky (Weir and others, 1966). N omenclatural history of the Harrodsburg Limestone in Indiana is complex (Hopkins and Siebenthal, 1897; Cumings, 1922, p. 493—499; Smith, 1965), and ages of its faunal elements, which were compared to those in the Illinois Warsaw and the underlying Keokuk Lime- stone, have been strongly debated (Laudon, 1948). In the Indiana outcrop, the Harrodsburg overlies the Ramp Creek and Muldraugh Formations (usage of N icoll and Rexroad, 1975), these latter two being equiv- alent to the Muldraugh Member of the Borden Forma- tion in Kentucky; the Harrodsburg underlies the Salem Limestone. Currently, the siliceous and dolomitic car- bonate rocks of the lower Ramp Creek Member of the Harrodsburg of Stockdale (1929) are included in the Muldraugh or Ramp Creek Formations, formerly units of the Borden Group in Indiana. The younger Leesville and Guthrie Creek Members (Stockdale, 1929) and an uppermost unnamed division, the “Upper” Harrods- burg, dominantly pelmatozoan crinoid- and bryozoan- bearing skeletal limestone, have been retained in the Harrodsburg by Nicoll and Rexroad (1975). The base of the “Upper” Harrodsburg has been considered to be the Osagean-Meramecian Series boundary in Indiana Geological Survey reports since 1954, although the en- tire unit had been assigned to the Osagean by others (Stockdale, 1931, 1939). Nicoll and Rexroad (1975) in- dicated that the conodont assemblage in the Harrods- burg Limestone of Indiana and adjacent Kentucky equates approximately with that of the Warsaw Shale of Illinois. The Kentucky Harrodsburg is a close litho- logic and time equivalent of the Indiana Harrodsburg (Sable and others, 1966). The Kentucky Harrodsburg as such is the practical mapping unit used in geologic maps of western central Kentucky such as in the Fort Knox (Kepferle and Sable, 1977), Colesburg (Kepferle, 1967), and Rock Haven (Withington and Sable, 1969) quadrangles. ' ROCKS OF LATE OSAGEAN AND MERAMECIAN AGE Rocks of late Osagean and Meramecian age in Ken- tucky are predominantly limestone, dolomite, and Siltstone that accumulated on intracratonic platforms and in shallow basins. Sandstone and mudstone, which form relatively minor constituents in the succession, mainly occur in south-central and western Kentucky. Bedded evaporites in west-central Kentucky indicate a period of shallow restricted seas and aridity during part of Meramecian time. No regional hiatus is recognized within the succession. Principal lithologies in the stratigraphic succession characteristic of Early to Late Mississippian (mostly Meramecian) time are, in ascending order, fossil- fragmental limestones deposited under moderately high-energy subtidal conditions (Harrodsburg, Warsaw, Salem, and the Salem and Warsaw Formations unit (fig. 30)); very fine grained chemically or organically precipitated dolomitic carbonates and evaporites deposited in quiet-water, subtidal to probable supratidal environments (Renfro, St. Louis), and oolitic and bioclastic limestones deposited in shallow-water, moderately high energy subtidal environments (Ste. Genevieve). Generalized relationships of these units are shown in the cross section (fig. 9). Besides the above units, two additional formational units of predominantly carbonate rocks are the Mont- eagle Limestone and the Slade Formation. These repre- sent equivalents to part of the Meramecian succession west of the Cincinnati arch as well as Chesterian equivalents. The Monteagle Limestone, of Tennessee derivation (Vail, 1959; Stearns, 1963), is restricted to south-central Kentucky and includes units between the St. Louis Limestone and the Hartselle Sandstone; it comprises the Ste. Genevieve and Kidder Limestone 56 MISSISSIPPIAN ROCKS IN KENTUCKY FIGURE 30.—Salem and Warsaw Formations undivided and lower part of St. Louis Limestone. Base of St. Louis shown by arrow. Upper- most part of Muldraugh Member of Borden Formation (dark beds) at extreme lower left. Milepost 85.6, north side of Cumberland Parkway, Delmer quadrangle, Pulaski County. Members (Lewis, 1971b). The Slade Formation (Etten- sohn, Rice, and others, 1984) in east-central and north- eastern Kentucky includes the Renfro, St. Louis, and Ste. Genevieve Members, 10 additional younger members, and one named bed. HARRODSBURG LIMESTONE In Kentucky, the Harrodsburg Limestone (Sable and others, 1966) consists of light-gray, crossbedded to planar-bedded, pelmatozoan-bryozoan, relatively pure biocalcirudite and biocalcarenite. It extends northwest- ward from central Kentucky through Indiana to cen- tral and southwestern Illinois. It is equivalent to the “Upper” Harrodsburg unit of Indiana. Harrodsburg equivalents are present in the Ullin Limestone of Illinois and in the Warsaw and subsurface “Big Light” (drillers’ term) of western Kentucky. The Harrodsburg of cen- tral Kentucky pinches out eastward and southward in south-central and east-central Kentucky into the Salem and Warsaw Formations unit, the upper part of the Muldraugh Member of the Borden Formation (Weir, 1972; Lewis and others, 1973), and laterally correlative rocks of the Renfro Member (Gualtieri, 1967a; Weir and Schlanger, 1969). The Harrodsburg averages about 30 ft thick in its outcrop belt in central Kentucky and thickens westward in the subsurface to form part of the more than 500 ft of “Big Light” or Warsaw Limestone strata in western Kentucky. WARSAW LIMESTONE The name Warsaw Limestone is used in western Ken- tucky for a 250 to 500 ft-thick unit of light- to medium- gray biocalcirudite, biocalcarenite, and dolomitic limestone which overlies the darker, siliceous beds of the Fort Payne Formation. It is the “Big Light” of western Kentucky drillers’ terms. Much of the Warsaw comprises crossbedded relatively pure limestone like that in the Harrodsburg Limestone. The lower part con- sists of, in part, dolomitic and siliceous limestone, similar lithologically to the Muldraugh Member of the Borden Formation. The Warsaw, as mapped in western Kentucky (Fox and Seeland, 1964), is considered to be equivalent to the Ramp Creek, Muldraugh, and Har- rodsburg of Indiana, the Ullin and Harrodsburg of II- linois, and the Warsaw of western Tennessee. A detailed treatment of the Warsaw in western Kentucky is given by Trace and Amos (1984). SALEM LIMESTONE AND SALEM AND WARSAW FORMATIONS UNIT The Salem Limestone, named for Salem, Washington County, Indiana (Cumings, 1901), in Kentucky consists of conspicuously crossbedded, medium- to coarse- grained biocalcarenite composed of fossil-fragmental, pelletal, and minor oolitic limestone interbedded with micritic dolomitic limestone, calcareous mudstone, and ROCKS OF LATE OSAGEAN AND MERAMECIAN AGE 57 minor sandstone. Biocalcarenite units range up to sev- eral tens of feet thick and are dominantly biosparites with varying amounts of argillaceous matrix. In a few places they contain units of the well-sorted, winnowed high-calcium biosparites like that of the Salem building stone facies in Indiana; in Kentucky this lithology is limited to very thin beds of endothyrid and pelmatozoan-bryozoan biocalcarenite. For the most part, dark argillaceous biocalcarenite and calcareous mudstone typify the Salem in western central and south-central areas of Kentucky; dark biocalcarenite consisting of fossil fragments, endothyrid tests, and oolitic and pelletal fragments is characteristic of the Salem map unit in western Kentucky. The Salem thickens irregularly from generally less than 100 ft in its Indiana outcrop belt to more than 350 ft in southern Illinois. Strata in the Indiana outcrop belt, except for the exposureless break across the Ohio River, are directly traceable into Kentucky (Withington and Sable, 1969; Kepferle and Sable, 1977). In central and south-central Kentucky, the Salem Limestone and Salem and Warsaw Formations unit range from about 50 to 170 ft thick. In general, the unit thickens westward, and the areas of greatest thickness are in northwestern central and southwestern south- central Kentucky. Meaningful correlation of the Salem in these areas with strata in western Kentucky, how- ever, is equivocal, because reliable subsurface informa- tion across much of west-central and western Kentucky is widely spaced. Based on a lithologic succession roughly comparable to that in central and west-central Kentucky, the Salem interval in western Kentucky, as mapped in the Fredonia, Crider, and Princeton East quadrangles, is only 120—130 ft thick. However, if the Salem is expanded to include strata mapped as the lower member of the St. Louis Limestone (upper part of the Illinois Salem) which overlies this interval, the total Salem thickness in western Kentucky is about 350 ft. In south-central Kentucky, most of the rocks between the Fort Payne Formation and the St. Louis Limestone were mapped in the early stages of the mapping program as Warsaw Limestone, for example, in the Austin quadrangle (S.L. Moore, 1961). Later, as it became apparent that beds equivalent to and litho- logically like the Salem Limestone of central Kentucky and southern Indiana were present in part of this unit, it was designated the Salem and Warsaw Formations (or Limestones) undivided map unit, as in the Holland quadrangle (Nelson, 1962). This compound name does not indicate that Salem and Warsaw beds are “lumped” for ease of mapping; it designates one mappable unit which is not practically divisible. The name Warsaw is retained herein for areas in south-central and western Kentucky because of its long history of usage. As previously stated, however, the type Warsaw cannot be directly traced from its type area in western Illinois into Kentucky, and the lithologies in the widely separated areas are not closely similar. We therefore believe that the use of the name “Warsaw” in Kentucky is inappropriate. Biocalcarenite, calcareous mudstone, and argillaceous limestone (Somerset Shale of Butts, 1922; Lewis and others, 1973) are dominant lithologies in the Salem and Warsaw Formations unit, but dolomitic limestone and lesser amounts of sandstone (Garrett Mill Sandstone of Butts, 1922, p. 107; Science Hill Member of the Warsaw, Lewis and Taylor, 1979) constitute appreciable parts in south-central Kentucky. Argillaceous rocks in the unit there, such as in the Science Hill quadrangle (Taylor and Lewis, 197 3) and in the Salem farther north (S.L. Moore, 1976; Withington and Sable, 1969), are also common in western central Kentucky and southern Indiana. The Garrett Mill Sandstone Member in the upper part of the Salem and Warsaw Formations unit, and the Science Hill Sandstone Member in the basal part are each less than 50 ft thick. Their distribution (fig. 31) in the Cumberland saddle area is similar and also in part overlaps the distribution of the older J abez and Knifley Sandstone Members of the Fort Payne Formation. They show two directional distribution com- ponents, north-northwest, parallel to the J abez-Knifley sandstone trend, and normal to that, east-northeast. Apparent age-equivalent strata to the east, west, and northwest are fine-grained terrigenous clastics with limy admixture, ranging from calcareous mudstones to calcareous siltstones. Pebbles occur in the upper part of the Science Hill Member throughout its outcrop area. Directional data for the upper part of the Science Hill (Lewis and Taylor, 1979) indicate that the member was a shallow subtidal deltaic sand body derived from an eastern source. More detailed study of these sandstone units and related fine clastics both in Kentucky and Tennessee is needed to better understand the period of transition from delta-dominated elastic deposition to shelf-controlled carbonate sedimentation phases of middle Mississippian time. The basal strata of the Salem and the Salem and Warsaw Formations unit in Kentucky—biocalcarenite, argillaceous limestone, or sandstone—in some places contrast strongly with the lithologies of the under- lying units, the Harrodsburg, Borden, and Fort Payne; but the contacts do not seem to indicate a major depositional hiatus. In western central Kentucky, the Salem-Harrodsburg contact is generally abrupt, from relatively pure calcarenite upwards to calcareous mudstone or shale, but as much as a few feet of argil- laceous Salem calcarenite are transitional in some 58 89° 88° 87° 83° MISSISSIPPIAN ROCKS IN KENTUCKY l l I I EXPLANATION Jabez and Knifley Sandston Members Science Hill Sandstone Member Dominantly calcareous silt- stone and shale in Salem and Warsaw Formations unit Garrett Mill Sandstone Member 38° INDIANA ll.LlNOlS 37° CHIC) e WEST /\ “BOWL: (1 100 MILES FIGURE 31.—Approximate distribution of Science Hill Sandstone and Garrett Mill Sandstone Members of Warsaw Formation and J abez and Knifley Sandstone Members of Fort Payne Formation in south-central Kentucky. exposures. In certain south-central Kentucky quad- rangles, the Salem-Warsaw unit, dominantly argilla- ceous to sandy biocalcarenite, locally contains beds that are lithologically similar to the Harrodsburg. As mapped in western and southwestern Kentucky, the Salem is commonly restricted to strata containing coarsely crystalline biocalcarenite with oolitic over- growths, and pelletal calcarenite with the abundant foraminifer Globoendothyra (Endothyra) baileyi (Trace, 1974). This definition of the Salem is more restricted than that used by the Illinois Geological Survey (Baxter and others, 1963, p. 7). According to Trace and Amos (1984) the basal Salem contact corresponds to the base of the middle unit of the Illinois Salem as used by Baxter and others (1967, p. 9) in the Fluorspar district adjacent to Kentucky. In Illinois, the Salem in- cludes younger argillaceous limestone beds bearing “endothyrids” and “lithostrotionoid”1 colonial corals, which in western Kentucky are placed in the lower member of the St. Louis Limestone. In addition, rocks in the basal unit of the Illinois Salem have been assigned 1“Lithostrotionoid” coral species used as biostratigraphic indicators of Mississippian strata in Kentucky have been referred to as Lithostrotion castelnaui Hayasaka, 1936; Lithostrotion canadense Milne-Edwards and Haime, 1851; and Lithostrotion [Lithostrotionella] proliferum Hall, all from the St. Louis and Salem Limestones, and to Lithastmtion harmodites Milne- Edwards and Haime from the Ste. Genevieve Limestone. The first three above have been reassigned to the genus Acrocyathus by Sando (1983). Sando (writ- ten commun., July 1985) has referred specimens of Lithostration harmodites to Schoenophyllum aggregatum Simpson, 1900. to the Warsaw Limestone in western Kentucky. Line back (1972), after subsurface study of the Salem and St. Louis, indicated that the Salem and St. Louis litholo- gies in Illinois and Indiana, based on relative abundance of biocalcarenite versus dolomitic and evaporitic strata in the Salem and St. Louis, respectively, are intergrada- tional and intertonguing. The formational boundary, therefore, has no regional time-stratigraphic signif- icance. (See section “St. Louis and older unit relation- ships,” p. 66.) Both the upper part of the Salem (Kepferle, 1967) and the basal St. Louis (Kepferle and Sable, 1977) in western central Kentucky contain thick beds of micritic to cal- carenitic, dolomitic limestone and dolomite similar to the “finely granular argillaceous dolomitic limestone” of the Salem in Indiana (Pinsak, 1957, p. 37 and pl. 5). This development of dolomitic lithologies is considered by Sable (1979b) to signal a precursor of the evaporite environments in the succeeding St. Louis Limestone. It is interpreted to represent a regressive trend which resulted in intertidal and supratidal environments encroaching over a large area of previously subtidal deposition. ST. LOUIS LIMESTONE The St. Louis Limestone (Engelman, 1847) overlies the Salem and the Salem and Warsaw Formations unit in western, west-central, central, and south—central ROCKS OF LATE OSAGEAN AND MERAMECIAN AGE 59 Kentucky. That geologic mapping was difficult because clearly delineated contacts could scarcely be discerned suggests that in many areas the contact is gradational and intertonguing. During the mapping program, rocks originally equated with the St. Louis of central and western Ken- tucky were assigned in east-central and northeastern Kentucky to two formations (Dever and Moody, 1979a; Dever, McGrain, and Moody, 1979). The dolomite and interbedded limestone of the lower part of the St. Louis were included in the Renfro Member of the Borden Formation (Weir and others, 1966) together with older rocks correlative with the Salem-Warsaw unit and Muldraugh; limestone of the upper St. Louis was desig- nated as the St. Louis Limestone Member of the Newman Limestone (Hatch, 1964). Most of the St. Louis Limestone in Kentucky is similar to that in adjoining States, and consists of very fine grained micritic to lutitic carbonate rock with lesser terrigenous material as dark carbonaceous shale and grayish-green shale in the lower and middle parts of the formation. Abundantly fossiliferous beds associated with biocalcarenites and biorudites are common in the upper St. Louis of eastern and south-central Kentucky. Chert is a common to abundant accessory and occurs as irregularly shaped masses, spherical nodules, discon- tinuous beds, and replacement layers (“scraggy” or “scraggly” chert) of limestone and dolomite (fig. 32). In some areas chert occurs in fairly discrete widespread “zones.” In west-central and central Kentucky, subsurface beds of gypsum and anhydrite as much as 15 ft thick, with associated dolomite, occur within a stratigraphic interval of as much as 200 ft in the lower part of the St. Louis; these are related to similar occurrences ex- tending from west-central Illinois and south-central In- diana into Kentucky (Saxby and Lamar, 1957; McGregor, 1954; McGrain and Helton, 1964). The lower and middle St. Louis of south-central and east-central Kentucky contains multiple zones of brecciated dolo- mite associated with quartz nodules, celestite, and pyrite, which are considered to have formed during FIGURE 32.—Cherty dolomite in upper part of St. Louis Limestone. J .F. Pace Construction Company quarry, Glasgow North quadrangle, Barren County. Hammer for scale. 60 MISSISSIPPIAN ROCKS IN KENTUCKY dissolution and replacement of evaporites (Dever and others, 1978; this report, fig. 33). Beds of carbonaceous shale containing marine fossils and plant debris, reported in the lower part of the St. Louis in west- central Kentucky (R.C. Kepferle, oral commun., 1966; Withington and Sable, 1969), are in about the same stratigraphic position as the evaporite beds. Carbonate strata in this part of the section include laminated limestone, very probably of stromatolitic origin, and fine-grained limestone breccia beds. The St. Louis as mapped shows a general eastward thinning across the State. On the west side of the Cin- cirmati arch, average thicknesses range from 475 ft in western Kentucky, through 300 ft in west-central Ken- tucky, to 230 ft in western central and south-central Kentucky. The thinning seems to occur largely in the interval assigned to the upper member of the St. Louis north and west of the Caledonia and Johnson Hollow quadrangles. The “Lithostrotionoid” coral-bearing lower member averages about 250 ft in thickness in western, west-central, central, and south-central Kentucky. In western Kentucky where the St. Louis map unit is 450—525 ft thick, it includes rocks assigned to the lower part of the overlying Ste. Genevieve Limestone in the outcrop belt east of Trigg County (fig. 34). On the east side of the Cincinnati arch, average thicknesses of the St. Louis range from 125 ft in south- central Kentucky to 25 ft in northeastern Kentucky. Northeastward thinning along the outcrop belt is notice- able principally in the sequence of dolomite and inter- bedded limestone of the lower and middle St. Louis and their equivalents included in the Renfro of east-central and northeastern Kentucky. This dolomitic sequence ranges in thickness from 75 ft in Pulaski County to 2 ft in Greenup County. The distinctive, cherty upper limestone of the St. Louis maintains a relatively uniform thickness of 15—25 ft across the outcrop belt. The St. Louis is absent in parts of northeastern, east- central, and eastern Kentucky, the result of erosion associated with Late Mississippian tectonic activity along the Kentucky River fault system and Waverly arch (Dever, 1973, 1977, 1980b). Subtidal St. Louis sediments originally were deposited across the entire area. Deposition was interrupted by uplift along the Waverly arch, resulting in subaerial exposure and vadose diagenesis of the subtidal limestone, but without large-scale, extensive erosion. Diagenetic fabrics in- dicative of exposure and vadose diagenesis are present FIGURE 33.—Dolomite in middle part of St. Louis Limestone. Young man pointing to zone of nodular quartz and brecciated dolomite which represents dissolved evaporite beds. Burnside Island State Park, Burnside quadrangle, Pulaski County. ROCKS OF LATE OSAGEAN AND MERAMECIAN AGE 61 AREAS WEST AND NORTH OF CHARACTERISTlC FEATURES CALEDONIA QUAD- N RANGLE AND AREAS CALEDONIA OUADRA GLE TO EAST AND SOUTH Levias m Limestone Light—gray limestone, : Member some oolitic, elastic, and .3 very fine grained d.) .E -‘ Rosiclare Sandstone, 3 Sandstone siltstone, and .g Member Ste limestone E Genevieve 8 Limestone .- ,Fedonia mile. 6 imestone . . . _ . Ste. Member Lisrtrld-s‘lgfie Thick oolltlc limestone Genevieve Limestone _ ~17); o—f z‘arTaBl' _ ' ' Chert occurs locally abundant chert a, Limestone, in part oolitic E Upper g member Top of zone of abundant nodular chart E 3 Cherry limestone, in part oolitic 3 A Lower Top of abundant "lithostrotionoid" corals (n member Lower ° . St. Louis member LTrhleLsfighs‘e Limestone and dolomite, chert common Limestone FIGURE 34.—Generalized relationships between Ste. Genevieve and St. Louis Limestones as mapped in and near Caledonia quadrangle, western Kentucky (from Ulrich and Klemic, 1966). at the top of the St. Louis in the eastern outcrop belt as far southwestward as northern Rockcastle County. Erosional removal of the St. Louis and part of the underlying Borden Formation followed recurrent move- ment of the Kentucky River fault system during or im- mediately after Ste. Genevieve time. Eroded areas are mainly on the north (upthrown) side of the fault system. The upper limestone unit of the St. Louis, mapped as St. Louis Limestone Member of the Newman but cur- rently in the Slade Formation, also is absent to the south in parts of Estill and Jackson Counties (Rice, 1972; Haney and Rice, 1978); but the dolomite and in- terbedded limestone representing the lower and middle St. Louis are present. In adjacent areas, limestone of the upper unit locally has convolute bedding, exhibiting ball-and-pillow structure, and projects several feet into the underlying dolomite. On the Pine Mountain overthrust block, southeastern Kentucky, an interval of cherty limestone and dolomite in the basal Newman Limestone was identified on the basis of lithology as St. Louis by Butts (1922) and Hauser and others (1957), and as the Hillsdale Member of the Greenbrier Limestone of Appalachian basin terminology by Wilpolt and Marden (1959). The domi- nant lithologies, micrograined limestone, very finely crystalline dolomite and chert, are typical of the St. Louis; and the interval commonly is overlain by Ste. Genevieve-type calcarenite, although distinctive St. Louis megafossils, such as “lithostrotionoid” corals, have not been reported. The interval commonly is about 40 ft thick, but in the Pineville area, Hauser and others (1957) and Butts (1922) assigned 80 and 115 ft, respec- tively, of basal Newman to the St. Louis. STE. GENEVIEVE LIMESTONE The Ste. Genevieve Limestone (Shumard, 1860, p. 406), the youngest Meramecian formation in Ken- tucky, is composed principally of carbonate rocks: light- colored, medium- to coarse-grained, oolitic and bioclastic calcarenite; light-colored to gray, bioclastic calcirudite; gray calcilutite; and gray, very finely crystalline dolomite. The oolitic and bioclastic calcarenites are commonly considered to be important lithologic criteria for recognizing the Ste. Genevieve. Principal constitu- ents in the bioclastic calcarenite and calcirudite are 62 MISSISSIPPIAN ROCKS IN KENTUCKY pelmatozoans, brachiopods, and bryozoans. Clay shale and sandstone are relatively minor constituents of the formation, but they are more common in western Ken- tucky, where they form named stratigraphic units. Chert is a relatively minor accessory, occurring as nodules, irregular masses, and siliceous replacements of fossiliferous beds such as the Lost River Chert Bed of Elrod (1899). The Ste. Genevieve Limestone is a roughly tabular unit from western central and south-central Kentucky across west-central and western Kentucky. It averages from about 180 to 240 ft thick in a distance of about 140 mi, thus suggesting that the rates of deposition and subsidence were essentially in equilibrium west of the Cincinnati arch. In western Kentucky, the Ste. Genevieve averages about 240 ft thick and ranges to more than 300 ft. There it is divided into three members, in ascending order, the Fredonia Limestone Member (Ulrich and Smith, 1905); Rosiclare Sandstone Member (Ulrich and Smith, 1905); and Levias Limestone Member (Sutton and Weller, 1932). The Fredonia Limestone Member is character- ized by oolitic limestone including the drillers’ unit, “McClosky oolite,” an important oil reservoir in some areas. The Fredonia ranges from 170 to 260 ft and averages 205 ft thick. In western Kentucky, 20—30 ft below the top of the Fredonia, a possible shale and sand- stone equivalent of the Spar Mountain Sandstone of Illinois (Tippie, 1945) was noted by Amos (1967, 1974) and Amos and Hays (1974). The Rosiclare Sandstone Member, sandstone and green shale with local sandy limestone, is 5—25 ft thick, averaging about 10 ft, in western Kentucky. The overlying Levias Limestone Member, finely crystalline to micritic to oolitic lime- stone, ranges from 10 to 35 ft thick and averages 25 ft. The three members are not mapped in the major part of the Ste. Genevieve outcrop west of the Cincinnati arch because the Rosiclare Sandstone Member sepa- rating the Fredonia and Levias Limestone Members grades into limestone southeast of Caldwell County and thus does not remain a mappable unit. However, a number of useful stratigraphic units are recognizable within the Ste. Genevieve west of the arch, in ascending order, the Lost River Chert Bed (Shaver and others, 1970); silicified oolitic limestone unit; Schoenophyllum aggregatum (formerly Lithostrotion (Siphonodendron) genevievensis) zone; Rosiclare Sandstone equivalent; and Bryantsville Breccia Bed (Shaver and others, 1970). The Lost River Chert Bed (Elrod, 1899), whose type area lies in southern Indiana, is a distinctive unit of one or more commonly silicified highly fossiliferous lime- stone beds that ranges from 1 to about 10 ft thick. In its type area it lies 20 or more feet above the Ste. Genevieve’s base, as defined by oolitic limestone beds (Malott, 1952, p. 8). When weathered this limestone is a porous, siliceous coquinoid rock having a chalky matrix in which the fossil fragments (relatively large fenestellid bryozoan fronds, and large orthotetid, productid, and spiriferoid brachiopod whole shells and fragments) are outlined or filled with stain from bright- red clay. In Kentucky this lithology is described in western central Kentucky in the Howe Valley and Rock Haven quadrangles (Kepferle, 1963a; Withington and Sable, 1969), and in west-central Kentucky (fig. 35). Similar rocks are described in several western Kentucky quadrangles (Sample, 1965; Amos, 1974; Amos and Hays, 1974). McGrain (1969) also recognized this chert bed east of the Cincinnati arch in Wayne and Pulaski Counties (fig. 59), where it serves as a useful strati- graphic marker as much as 20 ft above the horizon that separates Ste. Genevieve calcarenitic and oolitic lime- stone lithology from the underlying lithostrotionoid coral-bearing micritic limestone of the St. Louis (fig. 36). In south-central Kentucky it is the uppermost part of the Horse Cave Member of the St. Louis Limestone of Pohl (1970). Such a siliceous layer is a valuable map- ping tool in areas of low relief, poor exposure, and thick residual soil. It is also recognizable in cuttings and cores of bore holes (Kepferle and Peterson, 1964). Other cherty limestone beds which weather to residuum somewhat similar to that of the Lost River Chert Bed occur both above (Withington and Sable, 1969) and at (fig. 37) the Ste. Genevieve—St. Louis contact in central and south-central Kentucky. The Lost River Chert Bed is also locally absent in parts of south-central Kentucky, and thus the other cherty units could be confused with it during geologic mapping. The Rosiclare Sandstone Member of the Ste. Gene- vieve, as mapped in western Kentucky, grades south- eastward from Caldwell County into a silty to sandy, peloidal and intraclastic calcarenite. This calcarenite, although not a mappable unit, has been found to form a distinct bed, 1—10 ft thick, which can be traced, through quarry and roadcut sections, across the Ste. Genevieve outcrop belt from western Kentucky into west-central, south-central, and central Kentucky where it is considered to be the Rosiclare equivalent (Dever, McGrain, Ellsworth, and Moody, 1979; Dever, 1980). Both the calcarenite bed and the Rosiclare are within the upper interval of the formation bracketed by the Schoenophyllum aggregatum (formerly Lithostrotion (Siphonodendron) genevievensis) zone and Bryantsville Breccia Bed. Commonly associated with the calcarenite are micritic crusts and stringers developed during vadose diagenesis; identical diagenetic features occur in the Bryantsville Breccia Bed at the top of the Ste. Genevieve. ROCKS OF LATE OSAGEAN AND MERAMECIAN AGE 2 v: FORMATION E ‘é‘ AND LITHULOGV "1mg? 0 E s c R i P r l o N a “6:“ MEMBER '5‘ ‘ - Limestone, shale, and chart breccia: Limestone, light- to medium-gray, finely to medium crystalline; few beds are sublithographic; medium to thick bedded; oolitic beds , , , 15-25 local in upper part, some beds locally ‘ ' ' ' Shale, ' g“ g t. ' l , ay, in part ‘ thin' ‘ ‘ .Chert breccia, medium- to light-gray veryfina 1 T ' ' grained chert fragments in sparse to abundant matrix of light-gray sublitliogrepliic limestone; large chert fragments as much as 1 font in diameter consist of well-cemented small angular cliert fragments of various shades of gray; at top of unit, locally absent; bed is the Bryentsvilla Breccia of Melett (1952, l p. B). J t . " g.‘ , Limestone and sandstone: Limestone, very light gray to medium-gray, finely to coarsely crystalline, excellent abundant and well-developed white to light-gray oolites ‘ _I' i I' ‘l «‘73 60-80 common in upper half of unit in zones as thick as 15 feet; medium to thick bedded, less commonly thin bedded; crossbedding in coarsely crystalline beds; ‘ scattered gray fine-grained chart nodules that weather chalky white at and near top of unit; few slightly sandy beds about middle, dolomitic beds near top and base; limestone breccie or intraforrnational conglomerate locally in upper part; Plalycrini'tes penicillus Meek and Worthen common. Sandstone, grey, very calcareous, medium- to thick-bedded, in upper part; locally absent. Unit generally well exposed throughout map area. 135-195 1 i; i L r 15.20 Shale and limestone: Shale, dark—green to greenish-gray, slighty calcareous. Limestone, medium-gray, finely crystalline, medium- to thick-bedded, It I t J t Y 1' n . 1 . r y I Tl . r y l | fiffi~ Limestone and dolomite: Limestone, very light gray to medium-gray, sublithograpliic to medium-crystalline; oolitic beds in upper and lower thirds; medium to thick ‘ , ‘ . ‘ .‘ 50-70 bedded, less commonly thin bedded and laminated; light-gray, fine-grained nodules of chart 15 to 25 feet above base; much of upper half of unit is dolomitic. Dolomite, gray, finely crystalline, medium- to thick-bedded, near middle of unit. 2 :4 i I . 1 i < Lost Riverl?) *J J ' , _ l ’, ,‘g,”’,r‘ ', . Limestone and chart: Limestone, very light ten to light-yellowrsh-gray, medium- to fine crystalline, medium- to thick-bedded; ebundem fenestellid bryozeans end Chartof ,,;,, 514 . _ ‘ _ Elrod (1899) ’ ' ' brachiopods lespecialfy Orthotetes sp.) on bedding plane surfaces. Eliert, light- to medium-gray, commonly grey mottled, very fine grained, medium beds to I J [I r [I 1 '1 thin elongated lenses, wavy bedding plane surfaces. (in upland surfaces unit weathers to angular residual slabs and blocks with Iimonite-stained irregular m E I ' r‘ r ‘ 1 surfaces. Well exposed in bluffs along Ohio River. 2 fl 'f ' * 20-35 g . limestone, light- to medium»gray, medium-crystalline to oolitic, thick to medium-bedded, few thin beds. Contact between Ste. Genevieve and St. Louis Limestones n' s has been defined by other workers as approximately at the bottom of this unit 20 to 35 feet below the base of the Lost Rivarl‘!) Chart (Ray and others, 1946; _ E Malott, 1952i a: E c: I I I r 2; g L J_ m 2 E _ g : Limestone, dolomite, and chert, Limestone, brownish- to medium-gray, medium- to finely crystalline, commonly dolomitic in upper half; lower half commonly w "’ 130. argilleceous; scattered beds have light-gray to light-brown chert nodules; thick to medium bedded, few thin beds. Dolomite, medium- to dark-gray, finely zoo crystalline, thick- to mediumvbedded, few beds argillaceous; in upper part. Chart, light-gray to light-tannish-gray, very fine grained. medium-bedded, wavy m bedding plane surfaces; grades laterally to lenses; at top of unit, 5 TI l‘K | r l‘ t t t l I l I i‘r'l'i 340-375 ‘7 —l _ I,' i Limestone end gypsumlll: Limestone, medium— to dark- to brownish-gray, fine-grained to sublitliographic, tliick- to medium-bedded; some thin to shaly bedded to T‘Z;T:_‘ laminated argilleceous limestone near middle; in part dolomitic; “Lithostrotion” spp. and Syringopora 5p. present; petroliferous odor common when I I ‘ If 60-70 broken. Gypsum not present at surface in map area but penetrated by core drill hole in the adjacent Guston quadrangle [Kepferle and Peterson, l962l; large 1T1 ' J ; springs in bluff about 0.8 mile east of Brandenburg (Gallaher, 1964) are at the same stratigraphic positions as bedded gypsum encountered in the drill I T I I. hole. ‘ . 1 . ‘l’ T I l x1 I l L i . II J l‘ l f 1' l i J 1 I; r " I l r; f ‘ r r—Tt 1 E] r .V L _ Limestone, medium- to dark- to brownish-gray; some light olive gray in lower part; fine grained to sublithographic; few beds in lower half medium grained organic J'flégfi: 55.30 detrital; thick to medium bedded, few thin to laminated beds near middle; dolomitic at base and near top; commonly argilleceous near middle, scattered gray cliert nodules about middle and near base; few small spiriferid brachiopods; strong petroliferous odor when broken, Salem Limestone, light-brownish-gray to brownish-gray, medium- to coarse-grained, medium- to thick-bedded, slightly crossbedded; some dolomitic. Dnly upper few I' 10+ feet exposed in extreme southeast corner of map area. FIGURE 35.—Stratigraphic section and description showing lithologies of St. Louis and Ste. Genevieve Limestones and Lost River Chert Bed in New Amsterdam quadrangle, west-central Kentucky (from Amos, 1972). 63 64 MISSISSIPPIAN ROCKS IN KENTUCKY FIGURE 36.—Lost River Chert Bed (above hammer handle) about 2.5 ft thick. Roadcut on north side of Kentucky Highway 96 at Touristville, Mill Springs quadrangle, Wayne County. The distinctive colonial coral Schoenophyllum aggre- gatum Simpson 1900 (Lithostrotion (Siphonodendron) genevievensis and Lithostrotion harmodites of earlier reports) has long been recognized as a useful guide fossil for the Ste. Genevieve (for example, Ulrich and Smith, 1905; Ulrich, 1917; Butts, 1917, 1922). The coral has a narrow stratigraphic but widespread geographic range across the Ste. Genevieve outcrop belt west of the Cin- cinnati arch (Dever and others, 1980). Its occurrence is restricted to a zone 1—10 ft thick (more commonly, 1-2 ft thick) in the upper part of the formation. The zone commonly is about 20 ft below the top of the Ste. Genevieve in northern west-central, central, and south- central Kentucky, and about 40—50 ft below the top in southern west-central and western Kentucky. The coral also occurs in the Ste. Genevieve in parts of south- central Kentucky (Butts, 1922; Lewis, 1971b) where it is locally abundant, but generally rare (for example, Lewis and Taylor, 1976; Taylor, 1977). Some zonation in this area was also noted by Lewis (1971b), but the stratigraphic range of the coral within the unit has not been well defined. The top of the Ste. Genevieve in the outcrop west of the Cincinnati arch is marked by a widespread zone of altered limestone, 1—5 ft thick, which has been cor- related with the Bryantsville Breccia Bed of Indiana (Patton, 1949; Malott, 1952). Diagenetic features in the limestone indicate that alteration resulted from subaerial exposure and vadose diagenesis. The exposure zone, mostly darker colored than the underlying lime- stone, has a variety of lithologic expressions in the out- crop belt, displaying various combinations of carbonate lithotypes and diagenetic fabrics, ranging from rubbly to massive, highly brecciated calcilutite and calcisiltite to unbrecciated calcarenite containing micritic crusts and stringers. Cherty silicification of the diagenetic crusts and stringers is common. The Ste. Genevieve crops out east of the Cincinnati arch in the northeast-southwestward-trending belt of Mississippian rocks along the western border of the ROCKS 0F LATE OSAGEAN AND MERAMECIAN AGE 65 FIGURE 37.—Ste. Genevieve Limestone Member of Monteagle Limestone (Mmsg) and St. Louis Limestone (Msl). Arrows indicate contact between members at top of l-ft cherty limestone bed. Kentucky Highway 80, Pulaski County. Eastern Kentucky coal field; it is absent along the axis of the arch. During the geologic mapping program, the Ste. Genevieve in this eastern outcrop belt was reduced in stratigraphic rank and mapped in south-central Ken- tucky as the Ste. Genevieve Limestone Member of the Monteagle Limestone (Lewis and Thaden, 1965; Lewis, 1971b); in northeastern, east-central, and northeast- south-central Kentucky, it was mapped as the Ste. Genevieve Limestone Member of the Newman Lime- stone (Hatch, 1964; Cohee and West, 1965). In 1984, the Ste. Genevieve in east-central and northeastern Ken- tucky was assigned to the Slade Formation (Ettensohn and others, 1984) after a more comprehensive under- standing of the stratigraphic relations of Upper Missis- sippian strata was reached. Lithologies in the Ste. Genevieve are virtually the same on both sides of the Cincinnati arch; some included stratigraphic markers occurring on the west side have been recognized east of the arch. The Lost River Chert Bed is present 15—20 ft above the base on the east in parts of south-central Kentucky, but it commonly is un- fossiliferous (McGrain, 1969). Northeast of Somerset, a bed of cherty limestone is at the top of the mapped St. Louis; it weathers to a chert similar in appearance to the Lost River Chert. A zone of altered limestone, with features indicative of subaerial exposure and vadose diagenesis, caps the Ste. Genevieve east of the Cincinnati arch and has been correlated with the Bryantsville Breccia Bed at the top of the unit west of the arch (McFarlan and Walker, 1956). In south-central Kentucky as in central Ken- tucky, the breccia bed is bracketed by diagnostic crinoid fauna, Merarnecian Platycrinites penicillus in the Ste. Genevieve, and Chesterian genus Talarocn‘nus. In south-central Kentucky, the unit containing Talaro- cn‘nus is named the Kidder Limestone Member of the Monteagle Limestone (Lewis, 1971b). Northeastward along the outcrop belt, identification of the Bryantsville Breccia Bed and top of the Ste. Genevieve is com- plicated by (1) the presence of multiple exposure zones, lithologically similar to the Bryantsville, in both the Ste. Genevieve and overlying limestones, (2) absence or sparse presence of diagnostic crinoid fauna, and (3) northeastward thinning of the carbonate units (Dever, Hester, and others, 1979). Rocks in east-central and northeastern Kentucky assigned to the Ste. Genevieve Limestone by Butts (1922) and McFarlan and Walker (1956), and designated as the Ste. Genevieve Limestone Member of the Newman Limestone during the mapping program, for 66 MISSISSIPPIAN ROCKS IN KENTUCKY example in the Tygarts Valley (Sheppard, 1964) and Bangor (Hylbert and Philley, 1971) quadrangles, con- sist of two distinct limestone units, separated by an ero- sional unconformity (Dever, 1973, 1980b). The older Platycn'nites-bearing Ste. Genevieve, composed main- ly of bioclastic and oolitic calcarenite and capped by the Bryantsville Breccia Bed, extends along the outcrop belt from south-central into northern east-central Ken- tucky (fig. 59) where the unit was erosionally truncated following Late Mississippian movement along the Ken- tucky River fault system. In addition to being truncated on the north, the Ste. Genevieve in the east-central area pinches out eastward toward the axis of the Waverly arch, which remained a positive feature following the earlier uplift that interrupted St. Louis deposition. The younger limestone unit included in the Ste. Genevieve was deposited after the period of uplift and erosion associated with recurrent movement along the Kentucky River fault system. Extensive erosion, mainly on the upthrown (north) side of the fault system, resulted in erosional thinning and truncation of the Platycn'nites-bearing Ste. Genevieve and erosional thin- ning and removal of the St. Louis and upper Borden (Renfro, Nada, and upper Cowbell) in parts of northeast- ern and east-central Kentucky. The younger limestone, named the Warix Run Limestone Member of the N ew- man (Dever, 1977) and later of the Slade Formation (Ettensohn and others, 1984) was deposited on the ero- sional surface developed on the uplifted northern block, where it rests unconformably upon the Borden (mainly on the Cowbell Member) and only locally upon the older Ste. Genevieve and St. Louis. South of the fault system, it rests unconformably upon the Ste. Genevieve and St. Louis. The Warix Run Member, as much as 100 ft thick, con- sists mainly of crossbedded quartzose calcarenite, with lesser amounts of calcilutite. The calcarenite is com- posed of peloids, with sparse to locally abundant micrite-enveloped grains, ooliths, and bioclastic grains. The unit contains abundant quartz silt and sand, and, locally, grades into calcareous sandstone (Klekamp, 1971). Material derived from eroded members of the Borden and Newman is present in the basal part; grains and granules of St. Louis chert and limestone are com- mon constituents in much of the unit. Rocks assigned to the Warix Run Member of the Slade Formation accumulated in erosional lows on the uplifted northern block of the Kentucky River fault system, partly filling them. The member commonly reaches its maximum thickness, as much as 100 ft (Englund, 1976), near the middle of these lows, and it thins and pinches out along the margins of each area. Thus, the member forms a series of isolated deposits in the present outcrop of northeastern and northern east-central Kentucky (Dever, 1977; Ettensohn and others, 1984). South of the Kentucky River fault system where the unit is more widespread, it is thinner; here it forms a blanketer deposit of calcarenite which has been traced as far south as central Rockcastle County (fig. 59). In northeastern and northern east-central Kentucky, Warix Run calcarenite is overlain by calcilutite of the upper member of the Newman or Slade. The lithologies of these two units form a transgressive-regressive se- quence; the contact between them appears conformable, in part sharp and in part intertonguing. Diagenetic features indicative of exposure and vadose diagenesis occur at the top of the Warix Run in parts of the area, but their meager development and the absence of ex- tensive alteration in the limestone suggest formation during relatively brief periods of exposure. On the Pine Mountain overthrust block in southeast- ern Kentucky, an interval in the lower Newman Lime- stone, composed mainly of oolitic and bioclastic calcarenite, was identified as Ste. Genevieve by Butts (1922) and Hauser and others (1957). The calcarenitic interval, as much as 100 ft thick, overlies the zone of cherty limestone and dolomite in the basal Newman which was identified as St. Louis. Above the calcarenitic interval are beds correlated by de Witt and McGrew (1979) with the Taggard Red Member of the Greenbrier Limestone of Wilpolt and Marden (1959), a West Virginia unit characterized by the presence of variegated limestone, mudstone, and shale. Butts (1922) reported the occurrence of Lithostron'on (Siphonoden- dron) genevievensis, now Schoenophyllum aggregatum Simpson 1900, in the Ste. Genevieve at Pineville. Platycrinites penicillus has been found in the interval below the Taggard at localities in Letcher and Whitley Counties, Ky. In West Virginia, the Taggard has been placed at the Meramecian-Chesterian boundary (Wells, 1950) and in the basal Chesterian (de Witt and McGrew, 1979). STRATIGRAPHIC RELATIONSHIPS ST. LOUIS AND OLDER UNIT RELATIONSHIPS West of the Cincinnati arch in Kentucky, field rela- tionships between the St. Louis Limestone and the underlying Salem Limestone or the Salem and Warsaw Formations unit appear conformable, but lithologic units at the mapped boundary vary (Withington and Sable, 1969). On a 71/2-minute quadrangle scale, bound- ary units commonly interlayer strata characteristic of each unit, or else the lithologic contact can be sharp and unequivocal. In larger areas, the relationships are conformable and probably gradational or intertonguing, ROCKS OF LATE OSAGEAN AND MERAMECIAN AGE 67 so that inconsistencies arise when regional correlations are attempted. Lineback (1972), in an attempt to reconcile differences in the Salem and St. Louis boundary, traced contacts in the subsurface eastward from the St. Louis, Mo., type area of the St. Louis and westward from the Salem, Ind., type area of the Salem into areas of Illinois, and con- cluded that the two formations partly intergrade and reciprocally thicken and thin in Madison and Bond Counties, Ill. Lineback virtually restricted the Salem to strata containing biocalcarenitic and oolitic limestone (“biocalcarenite facies”). His criteria for this usage are similar to those used in western Kentucky. Both the older (Baxter, 1960; Baxter and others, 1963, 1967) and newer (Lineback, 1972) usages are shown on the cross section (fig. 9). Contact criteria between the Salem and St. Louis Limestones in central Kentucky generally follow those used in adjacent Indiana, but according to Pohl (1970, p. 3), the criteria are inconsistent. The contact in central Kentucky is placed between underlying biocalcarenite, argillaceous shaly limestone, or saccharoidal dolomitic limestone and overlying even-bedded cherty, dense, micrograined or micritic, in part laminated limestone and dolomitic limestone. The contact is based on gross lithologic differences, but it is generally sharp to grada- tional over a few feet (or at the most, 10—20 ft) in cen- tral, west-central, and south-central Kentucky, where the combined thickness of the St. Louis and Salem ranges from about 100 to 400 ft. In western Kentucky, however, the combined thickness increases from about 400 to more than 700 ft; here a unit of dark, partly argillaceous limestone as much as 170 ft thick inter- venes between biocalcarenite beds typical of the Salem, and the dense micritic limestones considered typical of the St. Louis (Trace, 1974). In some quadrangles the Salem and St. Louis have been mapped as an undivided unit (Fox, 1965; Rogers, 1963); in more recent maps the units were differentiated (Trace, 1974; Rogers and Hays, 1967 ). In western Kentucky, the uppermost boundary of the Salem is placed at the top of the highest biocalcarenite or oolitic limestone bed. This corresponds to the boundary of Lineback (1972) in Illinois. Elsewhere in Kentucky, the current lithologic boundaries of the Salem also appear to generally correspond to those in Illinois. To early workers concerned with the relative age of the St. Louis, faunal and lithologic differences indicated that a hiatus or disconformity separated the St. Louis from older rocks in the Mississippi River Valley (S. Weller, 1909; Van Tuyl, 1925). More recent studies indicate that conodont faunas are transitional upwards into basal St. Louis beds, but that a sharp widespread break in the conodont succession exists within the lower part of the St. Louis and is associated with limestone breccias in some places (Collinson and others, 1971, p. 382). This break, between the Taphrognathus van'ans-Apatognathus zone and the Apatognathus scalenus—Cavusgnathus zone, may mark a widespread hiatus. Similar positions of this zonal boundary are reported by N icoll and Rexroad (1975) in Indiana adj a- cent to north-central Kentucky, and in general the break may correspond with occurrence of evaporite beds and breccia beds in Illinois, which have been considered to represent remnants of fractured carbonate beds asso- ciated with dissolved evaporite strata (Collinson, 1964, p. 9). The Renfro Member of the Borden and Slade Forma- tions apparently spans the Osagean-Meramecian bound- ary; its conformable stratigraphic relationships with underlying Borden clastic units and with the overlying St. Louis have previously been discussed. In some areas, however, glauconite in and underlying the basal Renfro suggests a depositional hiatus there. Reciprocal thicknesses of the Renfro Member and the overlying St. Louis Limestone Member of the Slade For- mation in east-central Kentucky are indicated by Weir and others (1966, p. F20), although the Renfro includes equivalents of Muldraugh, Salem and Warsaw Forma- tions unit, and about the lower two-thirds of the St. Louis. Thickness reciprocity is inferred by probable in- tertonguing of the Salem and St. Louis in areas west of the Cincinnati arch. Thus, the thicknesses of the com- bined Warsaw-Salem-Renfro and St. Louis thicknesses (fig. 57) are considered to represent a more generally correct gross chronostratigraphic unit than do isopach maps of the separate units. ST. LOUIS—STE. GENEVIEVE RELATIONSHIPS The contact between the St. Louis and Ste. Genevieve Limestones and their equivalents in Kentucky east of the Cincinnati arch is based on general lithologic and faunal differences. It has been considered to be regional- ly inconsistent in Illinois (Swarm, 1963, p. 27). Likewise, in western Kentucky, some abrupt vertical offsets of this contact (fig. 34) have resulted from differences in contact criteria used by geologists who mapped adj a- cent quadrangles (Pohl, 1970, p. 6), considerations of dif- ferent criteria used by adjoining States, the lack of detailed faunal studies, and the characteristically poor exposures of rocks associated with this contact. The Lost River Chert Bed of Elrod, discussed pre- viously, has been used in west-central, central, and south-central Kentucky (McGrain, 1969) to approximate the St. Louis—Ste. Genevieve contact, which occurs in areas of characteristically poor exposures. This zone or its identical lithologies have been reported in many 68 MISSISSIPPIAN ROCKS IN KENTUCKY quadrangle section descriptions from south-central to western Kentucky. Identical lithologies have been observed at least as far west as near Anna, southern Illinois, by Sable, and may extend into Missouri and to northwestern Illinois (F.J. Woodson, written commun., 1983). In western and west-central Kentucky these rocks have been mapped as part of the St. Louis Limestone (Rogers and Hays, 1967). The Lost River Chert Bed is considered by Sable to mark a widespread virtually time-equivalent unit which lent itself by its porosity and permeability to relative ease of silicification. Criteria for discerning the base of the Ste. Genevieve Limestone vary considerably throughout Kentucky, as they have in adjoining States. In Kentucky, the basal contact has been mapped at the following successively lower horizons and approximations of horizons: 1. The base of abundant oolitic limestone beds; this contact corresponds to the base of the Fredonia Lime- stone Member, and approximates the contact as mapped in Illinois. It has been used commonly in west- ern Kentucky, particularly in the Fluorspar district (Trace and Amos, 1984). There it coincides with the base of a laminated dolomitic limestone and the top of a zone of nodular light-gray chert, the “upper” or “first” cherty zone of mapping geologists in western Kentucky (Trace, 1962). This is the contact currently recognized in that area. 2. The base of all oolitic or biocalcarenitic limestone beds in the St. Louis—Ste. Genevieve interval, at the top of a “lower” or “second” cherty zone. This contact was used in earlier mapping of the western Kentucky and Illinois fluorspar district (Weller and Sutton, 1951), and has generally been considered to be the boundary be- tween the two formations in Indiana (Malott, 1932; McGrain, 1943) and in central to west-central Kentucky. 3. The uppermost occurrence of “lithostrotionoid” corals which are commonly silicified and are con- spicuous in deeply weathered areas. This involves only minor lithologic differences but has been used in both west-central and western south-central Kentucky (Haynes, 1966). 4. At or as much as 20—50 ft below the Lost River Chert Bed (Kepferle, 1963b; Taylor, 1976). The upper- most “lithostrotionoid” corals occur within 10—25 ft or less below the Lost River Chert Bed in south-central and southern east—central Kentucky, but the interval between the corals and the chert bed increases west- ward and may be as much as 110 ft below the top of the Lost River Chert lithologic equivalent in western Kentucky. As previously mentioned, the lithologic equivalents of the Lost River Chert Bed have been observed in several western Kentucky quadrangles (for example, Rogers and Hays, 1967). A possible candidate for the Lost River Chert Bed equivalent in western and west-central Kentucky is a chalky-weathering chert con- taining abundant fenestellid bryozoans and brachiopods below an interval of abundant nodular chert. This would correspond to the lower, or second, chert of the upper member of the St. Louis Limestone (Klemic, 1966a, 1966b; Klemic and Ulrich, 1967; Ulrich, 1966; Ulrich and Klemic, 1966). Geologists mapping in that area, how- ever, interpreted this lithology either to occur sporadically throughout a thick stratigraphic interval of as much as 250 ft in the upper member of the St. Louis, or to represent secondary vadose or other ex- posure silicification after deposition in keeping with a new tectonic regime, possibly post-Paleozoic or post- Mesozoic. They therefore did not relate this lithology to a specific stratigraphic position. Nevertheless, the unique abundance and association of fossil fauna are very distinctive. The chert may be a diagenetic feature or a replacement product of a widespread subtidal deposit which preceded minor uplift or sea-level with- drawal enough to expose the beds to supratidal condi- tions, initiating silicification by vadose circulation. It is quite certain that only one such zone containing one or more cherty beds exists in Indiana and west-central, central, and south-central Kentucky. It is difficult to explain more than one such zone in western Kentucky, which lies basinward of the above area, and where repeated exposure seems more unlikely than in Shelf areas. In addition to the mapped contacts described above, other St. Louis—Ste. Genevieve boundary positions have been proposed. Pohl (1970) placed the boundary several feet above the Lost River Chert Bed and proposed a new subdivision, the Horse Cave Member of the St. Louis Limestone, to include the transitional lithologies be- tween the lowest prominent oolitic limestone in the St. Genevieve and the highest occurrence of spheroidal (“ball”) chert and amoeboid to lensatic chert in the St. Louis dolomitic micritic lithologies. The approximate upper limit of the Horse Cave, according to Pohl, marks a “viable extinction” of a foraminifer genus and a dasyclad algal genus. Macrofossils historically con- sidered to be the guide fossils of the Ste. Genevieve (Platycn'nites penicillus [Meek and Worthen] and Pugnoides ottumwa [White]), however, extend as much as 65 ft below the Lost River Chert Bed in western south-central Kentucky according to Pohl. An even higher St. Louis—Ste. Genevieve boundary in southern Illinois, the base of the Spar Mountain Sandstone Member of the Ste. Genevieve, is based on conodont zonation (Rexroad and Collinson, 1963; Burger, Rex- road, and others, 1966). In south-central Kentucky, con- odont studies suggest to Rexroad that the upper limit of the St. Louis lies roughly 2 to 10 ft or more above ROCKS OF LATE OSAGEAN AND MERAMECIAN AGE 69 the Lost River Chert Bed (F.J. Woodson, written commun., January 1983). These contacts, although they combine both lithologic and faunal criteria, do not lend themselves to mapping definition in that the lithologic criteria are subtle, rarely observable, and extremely dif- ficult to map in the poorly exposed areas in which they occur. As mapped, the relationships between the St. Louis and Ste. Genevieve west of the Cincinnati arch are ap- parently conformable and gradational. In south-central Kentucky, east of the arch, the contact between the cherty limestone and dolomite of the upper St. Louis and the basal Ste. Genevieve calcarenite also appears conformable. However, in the northeastern part of south-central Kentucky, a conglomerate as much as 10 ft thick, composed of abundant clasts of St. Louis-type chert in an oolitic matrix, has been reported at the base of the Ste. Genevieve (Butts, 1922; Lewis, 1971b). In parts of the area around Somerset, roadcut exposures show that from 4 to 18 ft of Ste. Genevieve-type cal- carenite is present between the base of the chert-bearing conglomerate and the top of the cherty calcilutite and calcisiltite of the St. Louis. Across most of east-central Kentucky, the Ste. Genevieve rests unconformably upon an exposure zone at the top of the St. Louis and commonly contains a thin, basal conglomerate of St. Louis chert and limestone clasts. The St. Louis was removed from parts of northeastern Kentucky by intra- Mississippian erosion; where present, it is unconform- ably overlain by limestone and shale of the upper part of the Slade Formation (formerly Newman Limestone), which is considered to be a Chesterian equivalent. SOURCES OF SEDIMENTS AND DEPOSITIONAL ENVIRONMENTS Although all preserved rocks of Meramecian age were deposited in marine or marginal marine environments, the distribution of terrigenous detrital material in- dicates transport from source areas mostly east and northeast of the Appalachian basin. Lesser sources of sediment may have been east of the present-day south- ern Appalachians, and small amounts of sediment may have been shed from areas of low relief along the Cin- cinnati arch and Ozark uplift. Williams (1957, p. 315—316) suggested three source areas for detritals in Warsaw and Salem rocks for the midcontinent region—Wisconsin, Ozarkia, and Appalachia. Rubey (1952, p. 50) reported sand grains derived from igneous and metamorphic rocks in the St. Louis of eastern Mis- souri, and suggested the presence of newly exposed land areas in the Ozark region. Directional data for the Garret Mill Sandstone Member are reported by Lewis and Taylor (1979). They interpreted the Science Hill Member of the Warsaw to be a shallow deltaic sand body derived from an eastern source area. Thus the Science Hill, at least, appears to represent a late southwestward spillover along the southern part of the Borden delta front after clastic deposition had generally ceased in more northern areas such as in central Indiana. Source areas and transport directions are not known for the conspicuous mudstones of the Salem and Warsaw Formations unit (“Somerset Shale”) in the Cumberland saddle area of south-central Kentucky and adjacent Tennessee and those of the Salem in central Kentucky. These mudstones are interpreted to be genetically related to the sandstones in those units. Their general distribution and thickness suggest west- ward and northward transport. They, along with the sandstones of the Garret Mill and Science Hill Members, may have been swept westward from sources east of the southern Appalachians possibly through the Cumberland saddle, with the fine .clastic muds carried farther westward and northward along the west flank of the Cincinnati arch. These latter two possi- bilities seem likely because eroded pre-Mississippian units on the Jessamine or Nashville domes probably did not contain sufficient sand to be the source for the sandstones. A northeastward-increasing sand content and thick- ening of the Warix Run Member of the Slade (Newman), in northeastern Kentucky and correlatives in southern Ohio, northern West Virginia, and western Pennsylvania suggest a northeastern source area for that member (de Witt and McGrew, 1979). Southwestward- and westward- dipping regional paleoslopes are indicated during Borden and, presumably, ensuing Mississippian deposi- tion (Potter and Pryor, 1961). In contrast, sediment transport to the northeast is indicated by paleocurrent measurements in the calcarenites of the Warix Run in western Carter County (Klekamp, 1971). The calcar- enites, interpreted as tidal-channel deposits, were trans- ported in migrating large-scale sand waves. Klekamp suggested that northeastward transport in the area did not necessarily reflect regional paleocurrent directions, but may have resulted from coastline configuration, wind direction, or flood- and ebb-dominated tidal cur- rents. The Warix Run of northeastern Kentucky was deposited on the irregular topography of an intra- Mississippian erosional surface cut down as deeply as into the Borden. In western Carter County, the Warix Run also was studied by Ferm and others (1971) and Home and others (1974), who considered it to represent tidal-bar belt deposits and, around topographic highs, a complex of beach, bar, and tidal-channel deposits. The Spar Mountain Sandstone Member (Tippie, 1945) of the Ste. Genevieve Limestone in Illinois and the 70 MISSISSIPPIAN ROCKS IN KENTUCKY younger Rosiclare (Aux Vases Sandstone) in Illinois and western Kentucky are two detrital tongues in the up- permost part of the otherwise carbonate-dominated Meramecian sequence. Sand in both units was con- sidered by Swann (1963) to have been transported from northeastern source areas by a southwest-flowing river system, the Michigan river, which was active also dur- ing Chesterian time. N 0 studies of current directional criteria in these units are known to have been made in Kentucky. Depositional environments for Meramecian-age sediments were largely very shallow marine except for the darker and finer grained rocks of the Salem and St. Louis in westernmost Kentucky and southernmost Il- linois, where the water may have been moderately deep (more than 500 ft?) during Salem and early St. Louis time. The textures of the shallow-marine carbonate rocks reflect a wide variety of depositional conditions including oolite shoals, lagoons, reefoid or bank detritus areas, and bars. Waters ranged from clear to turbid, and from agitated to quiet. High-energy environments pro- duced by wind-driven and (or) tidal currents combined with shallow water (less than 100 ft) over most of Ken- tucky are indicated by fossil fragmental, crossbedded, and interlensing beds in the Harrodsburg, Salem and Warsaw Formations unit, Ste. Genevieve, and Rosiclare (Aux Vases) strata, whereas quiet water of probable bay and lagoon intertidal-supratidal environments is inferred for the St. Louis evaporites and other fine- grained carbonate rocks. The Harrodsburg’s relatively pure carbonate com- position, abundant disarticulated fossil remains, and crossbedding indicate a striking change from turbid water, in which the underlying Borden was deposited, to widespread clear water. Fossil-debris beds, biorudites, that fill depressions marginal to Borden delta platforms (fig. 17) probably are the disarticulated hard parts of fauna indigenous to the platforms, swept by currents into adjacent depressions on the sea floor (Peterson and Kepferle, 1970). Pinsak (1957) concluded that near-shore, shallow- water offshore (shelf), and deep-water offshore (basin) environments are represented in limestones of the Salem Limestone of northern, central, and southwestern Indiana. The shallow-water offshore environment of Pinsak has been compared to the environment on the present-day Bahama Banks (Sedimentation Seminar, 1966). Clear-water conditions are shown by the Salem in Indiana, but markedly turbid water is indicated by the argillaceous content of the Salem and the Salem and Warsaw Formations unit in Kentucky and by associ- ated sandstone strata in the Cumberland saddle area. A distinct change to very low energy conditions is re- flected by rocks of the St. Louis Limestone. Evaporites in the St. Louis Limestone in Illinois, Indiana, and western Kentucky are indicators of a probable sabkha shelf environment along the Cincinnati arch trend (J orgensen and Carr, 1973). A seaway opening to the south and intermittently connected with the Michigan basin, where evaporite deposition also occurred, is in- ferred to have been the source of waters for the _ evaporite deposits in the St. Louis (Sable, 1979b). The widespread limestone and dolomite breccias in the St. Louis Limestone west, south, and east of known evaporites are interpreted to result from dissolution of contiguous evaporite beds which occurred over a much wider area than present evaporite occurrences (Collin- son, 1964, p. 7; Dever and others, 1978). Carbonaceous mudstones and limestones in lower St. Louis beds of west-central Kentucky (Kepferle, 1966b; Withington and Sable, 1969), probable time equivalents of the evaporites, may indicate that land along the Cincinnati arch acted as a barrier to free circulation. Rocks in the upper St. Louis largely represent a general transition to clear, freely circulating but quiet water without terrigenous clastic influence, perhaps restricted by conditions similar to those of the Florida Bay, in which organically precipitated carbonates from organisms such as calcareous algae could accumulate. A slow but major transgression during this time prob- ably inundated all or much of the Cincinnati and Waver- ly arches. Fine grain size, tabular beds, and general scarcity of terrigenous elastic debris indicate that wave and current activity was weak over a large area and that source areas were low or remote. Dolomitic beds, the relative scarcity of fossil remains, and scattered occur- rences of gypsum also suggest that a hypersaline en- vironment existed in some areas throughout much of later St. Louis time. During deposition of the Ste. Genevieve, clear, very shallow oxygenated seas with normal open circulation prevailed. A general vertical transition to shallow agi‘ tated water occurred from St. Louis to Ste. Genevieve time throughout the basin, as indicated by an upward increase of oolitic limestones, current structures, and prolific shallow-water faunas and sedimentary limestone breccias of probable supratidal and subaerial exposure origin. Low-energy protected lagoon or bay conditions in which lime mud was dominant were supplanted by subtidal shelf and oolitic shoal and bank environments as general marine transgression occurred. Terrigenous clastics of the Spar Mountain, Aux Vases, and less widespread units in the central and southern part of the Eastern Interior basin are generally sheetlike deposits in lobes that accumulated in this shallow marine en- vironment. These clastics and more subtle examples of cyclicity in carbonate depositional environments, as in the Ste. Genevieve of south-central Kentucky (Sandberg MERAMECIAN-CHESTERIAN SERIES BOUNDARY 71 and Bowles, 1965), represent the onset of cyclical deposi- tion which characterizes the marine and continental environments displayed by Chesterian deposits still to come. Paleogeographic interpretation indicates that during most of Meramecian time, Kentucky was inundated by a fluctuating shallow sea. Seaway connections existed mainly to the south, and connections with the Ap- palachian basin may have been through the Cumberland saddle. The Cincinnati and Waverly arches were inter- mittently emergent. There, in northern east-central and northeastern Kentucky, after uplift resulted in cessa- tion of St. Louis deposition, the Waverly arch remained partly emergent during the remainder of Meramecian time and early Chesterian time. Paleogeographic reconstruction for Meramecian time would show topographically low peninsulas along the Cincinnati and Waverly arches southward into Ken- tucky. During an early St. Louis marine regression (evaporite interval), low-lying land may have extended northwestward along the Kankakee arch (Sable, 1979b). In Ste. Genevieve time, source areas south or east of Kentucky may have shed a small amount of sandy sedi- ment northward. Evidence for a Michigan river system (p. 85) lies in the youngest Meramecian units in western Kentucky. Prior to these, the river may have had little sediment- carrying capacity due to widespread aridity, or because it headed in lowlands. Most likely, the point where the river debouched into the sea was too far distant for much sediment to reach the Eastern Interior basin region. In eastern Kentucky, however, either in late Meramecian or early Chesterian time, northeast- trending bars composed of carbonate and silica-sand ad- mixture were prominent along the Waverly arch. PALEOTECTONIC IMPLICATIONS Trends and positions of major tectonic elements inherited from Osagean time stabilized considerably during ensuing Meramecian time, and infilling of ir- regular depositional topography continued. The Eastern Interior basin in western Kentucky was a major negative feature, as shown by accumulation of more than 1,100 ft of sediments in western Kentucky, and thinning towards such positive features as the Cincin- nati and Kankakee arches. Maximum subsidence of the basin in western Kentucky occurred during Salem and early St. Louis time. This major differential downwarp- ing ceased in late St. Louis time, and wide areas sub- sided gently and evenly, the exceptions being eastern, northeastern, and east-central Kentucky, where the Waverly arch and Kentucky River fault system were rejuvenated. The Cincinnati arch and Ozark uplift restricted seaways during St. Louis evaporite deposition, although they contributed little detrital sediment. In northeastern, east-central, and eastern Kentucky, discontinuous deposits of sediments imply a broad, unstable platform, the Waverly arch (Woodward, 1961), between the Cincinnati arch and the Appalachian basin trough. The platform was modified by a shallow basin in southeastern Kentucky and emergent areas in north- eastern Kentucky during part of Meramecian time. MERAMECIAN-CHESTERIAN SERIES BOUNDARY The Ste. Genevieve Limestone is the youngest forma- tion of the Meramecian Series in Kentucky. In adj oin- ing Illinois, the youngest Meramecian (Valmeyeran) rocks are assigned to different formations (Swarm, 1963). The top of the Ste. Genevieve in eastern Illinois is correlative with the top of the Fredonia Limestone Member of the Ste. Genevieve in western Kentucky. The Rosiclare Sandstone and Levias Limestone Members of the Ste. Genevieve in Kentucky correlate with the Aux Vases Sandstone and Levias Limestone Member of the Renault Limestone, respectively, in Illinois. The Ste. Genevieve is overlain by the Renault Lime- stone in western Kentucky, the Girkin Formation in southern west-central and south-central Kentucky, and the Paoli Limestone in central and northern west-central Kentucky. In the northern west-central area, a sandy limestone or calcareous sandstone, mapped in the basal Paoli, represents the Popcorn Sandstone Bed of Swann (1963). It was identified as the Aux Vases Sandstone of Malott (1952) on geologic quadrangle maps of the area, for example in the New Amsterdam quadrangle (Amos, 1972). East of the Cincinnati arch, the Ste. Genevieve Limestone Member of the Monteagle Lime- stone, as mapped, is overlain by the Kidder Limestone Member of the Monteagle Limestone in south-central Kentucky and by the upper member of the Newman Limestone (Mill Knob through Poppin Rock Members of the Slade Formation of Ettensohn and others, 1984) in east-central and northeastern Kentucky. The boundary between the Chesterian and Merame- cian Series in Kentucky is marked by both a change in crinoid fauna and a break in deposition. J.M. Weller and Sutton (1940) considered the unconformity at the Chesterian-Meramecian boundary to be the most impor- tant stratigraphic break within the Mississippian System in the Eastern Interior basin, citing variations in thickness and absence of upper members or all of the Ste. Genevieve within comparatively short distances, overlap of Chesterian units on older beds, and thickness 72 MISSISSIPPIAN ROCKS IN KENTUCKY variations and conglomerates in basal Chesterian for- mations. Swarm (1963), however, considered that no im- portant “time break” occurred between Ste. Genevieve and Chesterian deposition. Late Meramecian rocks are characterized by the com- mon presence of Platycn'nites penicillus and early Chesterian rocks by species of Talarocrinus (other than T. simplex) (Swann, 1963). The abundance of crinoid- bearing limestones in this part of the Mississippian sec- tion in much of Kentucky makes the presence of these forms a useful field criterion. In conjunction with the crinoid “break,” the Bryantsville Breccia Bed exposure zone at the top of the Ste. Genevieve has been traced across western, west-central, central, south-central, and east-central Kentucky, indicating widespread interrup- tion of deposition at or near the end of Meramecian time. The change in crinoid fauna and the Bryantsville exposure zone are the most reliable field criteria for iden- tifying the top of the Ste. Genevieve. However, addi- tional exposure zones with identical or similar diagenetic features are present below the Bryantsville in the Ste. Genevieve and above the Ste. Genevieve in the Girkin Formation, Kidder Limestone Member of the Monteagle, and upper member of the Slade (Newman) Formation (Dever, Hester, and others, 1979; Dever, McGrain, and Ellsworth, 1979; Dever, McGrain, and others, 1979). In the outcrop west of the Cincinnati arch and in south-central Kentucky east of the arch, vertical distribution of the diagnostic crinoid fauna can be used to distinguish the Bryantsville from older and younger exposure zones. Criteria used for identifying the Bryantsville in east-central Kentucky where diagnostic fauna are absent or sparse are outlined by Dever, Hester, and others (1979). In the subsurface of eastern Kentucky, the top of the Ste. Genevieve is even more difficult to determine. There, it is largely delineated on the basis of projected regional trends and, in a few wells, by the presence of red shale and limestone. These latter lithologies are con- sidered correlative with the Taggard Formation (Reger, 1926) of the Appalachian basin, which was placed in the basal Chesterian by de Witt and McGrew (1979). The Warix Run Member of the Slade Formation was formerly identified as Ste. Genevieve (Butts, 1922; McFarlan and Walker, 1956; Sheppard, 1964; McGrain and Dever, 1967; Hylbert and Philley, 1971). The Warix Run, separated from the Platycrinites-bearing Ste. Genevieve by an erosional unconformity (Dever, 1973, 1980b), was deposited on a post-Ste. Genevieve ero- sional surface. In northeastern Kentucky and northern east-central Kentucky, the Warix Run rests unconform- ably upon the Borden and, locally, St. Louis; and in east- central Kentucky, from Menifee County southwestward into Rockcastle County, it rests on the Bryantsville Breccia Bed at the top of the Platycrinites-bearing Ste. Genevieve. The question of a Meramecian or Chesterian age for the Warix Run has not been resolved. Microfaunal studies have been inconclusive (Pohl and Philley, 1971; Horowitz and Rexroad, 1972). Warix Run calcarenite in northeastern and northern east-central Kentucky is overlain by a calcilutitic unit, forming a transgressive- regressive, fining-upward sequence. The calcilutite, which locally intertongues with Warix Run calcarenite, contains Endothyranella, indicating a late Genevievian or later age (Pohl and Philley, 1971); it has been cor- related with Talarocn'nus-bearing limestones to the southwest and Chesterian equivalents in east-central and south-central Kentucky (McFarlan and Walker, 1956). Determination of a Chesterian age for the Warix Run would suggest possible correlation with the Pop- corn Sandstone Bed (Swann, 1963), the basal Chesterian unit in Lawrence County, Ind., equivalents of which may be present in northern west-central Kentucky. In northeastern and northern east-central Kentucky, erosional thinning and, in parts of the area, complete removal of Meramecian rocks followed post-Ste. Genevieve movement along the Kentucky River fault system (Dever, 1977, 1980b). The Ste. Genevieve is preserved on the uplifted side of the fault system only in limited parts of Bath and Menifee Counties. Elsewhere, the youngest preserved Meramecian unit is the St. Louis, which generally is unconformably overlain by limestone and shale of the upper member of the Newman (Slade), units considered by McFarlan and Walker (1956) to be Chesterian equivalents. ROCKS OF CHESTERIAN AGE Rocks of Chesterian age (figs. 7, 8) are characterized by distinct cyclical alternation of detrital and carbonate strata in western Kentucky, and less obvious, but recognizable cyclicity in eastern Kentucky. Whether cyclicity is truly synchronous between western and eastern Kentucky has not been determined. The strata are preserved in three separate areas: west of the Cin- cinnati arch from south-central Kentucky into Indiana, Illinois and southeastern Missouri; east of the arch in northeastern, east-central, and south-central Kentucky and in the eastern Kentucky subsurface; and in the Pine Mountain and Cumberland Mountain belts of south- eastern Kentucky. Detailed correlations among the somewhat different sequences in the three areas are uncertain. The succession is the Chesterian Series in the Eastern Interior basin and its age equivalent in the other areas. ROCKS OF CHESTERIAN AGE 73 A voluminous literature covers many aspects of Chesterian Series rocks in the Eastern Interior basin. The synthesis by Swann (1963) discusses Illinois, west- ern Kentucky, and Indiana; it reviews nomenclatural history of units; discusses time and rock stratigraphy, biostratigraphy, and depositional framework; and it includes an exhaustive, pertinent bibliography. Petro- graphic and environmental studies of Chesterian Series sandstone-dominated units include papers by Potter and others (1958), and Potter (1962, 1963). Conodont studies include those from the type Chesterian area in southwestern Illinois (Rexroad, 1957). Rocks of Chesterian age in Indiana which are directly pertinent to Kentucky stratigraphy were discussed by Malott (1952) and those in western Kentucky by Ulrich (1917), Butts (1917), and McFarlan and others (1955). Literature on Chesterian equivalents in eastern Ken- tucky includes papers by Butts (1922), McFarlan and Walker (1956), Vail (1959), Weir (1970), Dever and others (1977), Ettensohn (1980), Ettensohn and Dever (1979), and Ettensohn and Peppers (1979). Because of the many units in the Chesterian Series, the formations are not described individually here and the reader is referred to the geologic quadrangle series maps of 1961—1979 and reports such as Sedimentation Seminar ( 1969); Calvert (1968); Englund and Windolph (1971); Vincent (1975); McFarlan and others (1955); McFarlan and Walker (1956); Ferm and others (1971); Stouder (1938, 1941). Trace and Amos (1984) gave ex- cellent descriptions and discussions of relationships of Chesterian units in the Fluorspar district of western Kentucky. ROCKS WEST OF THE CINCINNATI ARCH Rhythmically deposited units of limestone and minor dolomite, and clay- to sand-size terrigenous clastics characterize the Chesterian Series in the Eastern In- terior basin. Subdivision into more than 20 formations is shown on the correlation chart (fig. 8). Formations have been defined in outcrops in the Chester district in southwestern Illinois; in southern Illinois; in western, west-central, and south-central Kentucky; and in south- central Indiana. Correlations of nomenclatural units are generally consistent across State boundaries, although some units which are not divisible in some areas are readily divided in others. Physical criteria for some for- mational boundaries are different in adjoining States, and variations in terminology and groupings of units occur from State to State. Chesterian strata in the Eastern Interior basin com- prise five formal groups in Illinois and three in Indiana. Groupings are based on lithologic similarity. Facies changes were produced by shifting loci of terrigenous clastic accumulations (Swarm, 1963, p. 21—22). Time- stratigraphic divisions include the post-Genevievan, successively younger Gasperian, Hombergian, and Elviran Stages in Illinois (Swarm, 1963, p. 21—23); the stage boundaries are considered to closely correspond to rock-stratigraphic boundaries. CARBONATE-DOMINATED UNITS Widespread units that are mostly limestone west of the Cincinnati arch in Kentucky include parts or all of the Renault Formation, the Paint Creek, Paoli, Beaver Bend, and Reelsville Limestones. the Girkin Formation, the Beech Creek and Haney Limestone Members of the Golconda Formation, and the Glen Dean, Vienna, Menard, Clore, and Kinkaid Limestones. They range from a few feet to 200 ft thick and generally consist of relatively pure limestones with micritic microcrystalline to sparry calcite matrix. Oolitic and pelletal limestones occur locally in nearly all Chesterian carbonate- dominated units. Argillaceous and limonitic material is locally common. Framework grains identified in the field and under the microscope consist of foraminifers, corals, bryozoans, brachiopods, echinoderms, mollusks (gastro- pods and pelecypods), and arthropods (trilobites and ostracodes), as well as ooids, pellets, detrital quartz, and carbonate rock fragments. Chert and silicified limestone are relatively rare, although they locally characterize some units such as the Haney Member of the Golconda Formation and the Vienna Limestone—and thus are valuable mapping criteria. Dolomitic limestone beds are not abundant, but some form marker “zones” such as those with calcite concretions in the Beaver Bend Limestone. Interbedded mudstone is generally more abundant in the middle and upper Chesterian units such as the Glen Dean, Menard, and Clore than in the lower ones. Thin and discontinuous shale beds in the Girkin Formation of west-central and south-central Kentucky are distal facies of thicker, dominantly sandstone and shale formations—Bethel (Mooretown), Sample, Elwren (Cypress) to the north and west (see Sandberg and Bowles, 1965). The lower surfaces of limestone units are commonly more planar than those of detrital units (fig. 38), but some gradational and interfingering relation- ships between limestone and underlying mudstone and sandstone, such as the Sample and Reelsville in west- central Kentucky (Sable, 1964), and local thickening of limestone units at the expense of underlying clastic units have been recognized. Several limestone units within the Leitchfield and Buffalo Wallow Formations in west-central Kentucky are correlated with the Vienna, Menard, and Kinkaid of western Kentucky areas (Stouder, 1938; Clark and Crittenden, 1965; Gildersleeve, 1971; Johnson, 1977). 74 MISSISSIPPIAN ROCKS IN KENTUCKY FIGURE 38.-Upper part of Mooretown Formation (Mm) underlying 18.5 ft of Beaver Bend Limestone (Mbb) overlain in turn by shale and sandstone of the Sample Sandstone (Ms). Kentucky Stone Company Upton Quarry, Upton quadrangle, Hardin County. Fairly persistent detrital units within carbonate rock units are reported in the Paoli Limestone in central and west-central Kentucky (Kepferle, 1963a), where prom- inently crossbedded quartzose calcarenite and oolitic limestone occur, and in the Renault Formation of west- ern Kentucky, where green shale occurs (Amos, 1965; Sample, 1965). The Paoli elastic beds may correspond to the middle shale break of the Paoli in Indiana (Perry and Smith, 1958). The Renault clastic beds are equiva- lent to the Yankeetown Shale in southern Illinois (Baxter and others, 1963, 1967). Chesterian limestone units west of the Cincinnati arch which are most widespread and therefore of great value for long distance correlation are the Beech Creek (sub- surface “Barlow Lime”), the Glen Dean (“Little Lime”), the Vienna (“Brown Lime”), the. Menard, and the Kinkaid. Chert is particularly useful in correlation of the Haney Limestone in the outcrop belt of central, west-central, and south-central Kentucky. This is characteristically a whitish-weathering replacement of oolitic and fossil fragmental limestone and is conspicuous in weathering residuum. Similar chert has been observed above the Hartselle Formation in the Albany quadrangle, in south-central Kentucky (Preston McGrain, written com- mun., 1964, verified by Sable); but chert is also common below the Hartselle equivalent in east-central and north- eastern Kentucky. Chert also is a valuable widespread correlation tool in the Vienna Limestone of west-central, south-central and western Kentucky. This latter is also a replacement chert but weathers to brown-tinged, darker hues than does chert in the Haney. TERRIGENOUS CLASTIC UNITS Dominantly detrital units in western, west-central and western central Kentucky include, in general ascending order, the Bethel Sandstone or Mooretown Formation, Sample Sandstone, Paint Creek Shale, Cypress Sandstone or Elwren Formation equivalent (Malott, 1919), Big Clifty Sandstone Member of the Golconda Formation, Hardinsburg, Tar Springs, Waltersburg, Palestine, and Degonia Sandstones. The Grove Church Shale (Swann, 1963), the youngest known ROCKS OF CHESTERIAN AGE 75 Chesterian formation of Illinois, is documented only in the subsurface of Webster County, western Kentucky (Hansen, 1975). The Leitchfield Formation of west- central Kentucky includes largely mudstone equivalents of the Tar Springs and younger elastic and minor limestone units; the adjacent Buffalo Wallow Forma- tion is similar lithologically but excludes Tar Springs beds (fig. 8). Mudstone and sandstone regionally constitute roughly 50 and 25 percent respectively of Chesterian rocks in Kentucky. The proportions and thicknesses of mudstone and sandstone show great lateral variation. In many places thick sandstones such as the Big Clifty (fig. 39) make up most or all of a formation. Their lower boundaries are commonly erosional, and truncation of underlying beds can be intraformational or can involve removal of one or more underlying formations. The morphology and internal features of the sandstones established some of them as bar-fingers and channel- fill or tidal current deposits (Calvert, 1968); some, such as the Big Clifty, may be regressive shoreline sheet sands. Where the basal parts of elastic units are fine- grained sedimentary rocks, perhaps bay-fill or overbank deposits, their basal contacts are generally planar and apparently conformable with underlying carbonate units (fig. 40). However, splay(?) channel fills of mud- stone or of mudstone and sandstone admixtures are also present (Sable and Peterson, 1966, p. 25) although rarely seen. Marine fossils occur in the lower parts of many sandstones. Thin coaly beds and unfossiliferous red shales are locally present in the upper parts of some units such as the Mooretown and Big Clifty (Sable, 1964; Amos, 1972). Suggesting alternating shoreline regression and transgression, the depositional regime was that of lower delta plain and delta front environments. Most Chesterian sandstones are dominantly fine- to coarse-grained orthoquartzites as compared to the subgraywackes of Kinderhookian and Osagean ages. Some sandstones in the upper Chesterian strata, such FIGURE 39.—Big Clifty Sandstone Member of the Golconda Formation showing tabular beds, gently cross-laminated beds. and minor channel fills. Note asphaltic exudation as drip and flow features. Milepost 120.7. Western Kentucky Parkway, Big Clifty quadrangle, Hardin County. 76 MISSISSIPPIAN ROCKS IN KENTUCKY FIGURE 40.—Hardinsburg Sandstone (M h) conformably overlying Haney Limestone Member of the Golconda Formation (Mgh). Milepost 114.8, Western Kentucky Parkway, Summit quadrangle, Grayson County. as in the Pennington Formation of eastern Kentucky, are subgraywacke types, however. Framework is pre- dominantly quartz and minor alkali and sodic feldspars, chert, fossil fragments, rock fragments, and heavy minerals. Locally, pyrite grains are common. Sideritic nodules are also locally common. Matrix consists of common quartz overgrowths, sparry calcite, micrite, clay minerals (reported as illite and kaolinite in several reports), and iron oxides. Other constituents are clay pellets, carbonized plant impressions, Sideritic and limonitic nodules, carbonized wood fragments, and tree trunks, with a few in growth positions. Conglomeratic sandstone is rare; the Mooretown (Bethel) Formation contains scattered granules and pebbles of white quartz in a thick channel fill in western central Kentucky, and the Cypress Sandstone contains sandstone clasts in western Kentucky. A striking example of a thick channel-fill deposit is the Bethel (Mooretown) Sandstone in central, west- central and western Kentucky. This deposit extends for more than 150 mi, and the channel has cut through more than 250 ft of previously beveled pre-Bethel strata as old as the St. Louis (Sable and Peterson, 1966; Reynolds and Vincent, 1967) (fig. 41). This deposit is interpreted to have been a submarine shelf channel fill (Sedimenta- tion Seminar, 1969). Other elongate channel sandstone bodies have integrated distribution patterns suggesting delta plain stream channels, some of which are repeated as stacked channel deposits (Potter, 1962, 1963) in the north-central part of the western Kentucky fluorspar district (Trace and Amos, 1984). Another thick, southerly-trending unit is the Tar Springs Sandstone in northern west-central Kentucky (Clark and Crittenden, 1965; fig. 42, this report), con- sidered by Calvert (1968) to have been a tidal current sand. Siltstone, mudstone, and claystone in strata of Chesterian age are commonly medium dark gray to greenish gray. Reddish-gray varieties occur in several clastic units, including the upper part of the Big Clifty Sandstone Member of the Golconda Formation and units within the Leitchfield and Buffalo Wallow Forma- tions; they are common in the Hardinsburg and Palestine Sandstones of western Kentucky. Dark-gray ROCKS OF CHESTERIAN AGE 77 Map area , / l / ,‘7/ Louisville r \ _\ //\ ' I. a ‘ -' ~, \ xv ; “ -L \\ i " /" Henderson \" f Owensboro o Elizabethtown HOPKINS ./{ COUNTY 0 10 20 30 “MILES ;|_._l_a NW FEET SE r—ZOO Sample Sandstone Paoli Limestone ~100 datum\ Beaver Bend Limestone Mooretown Formation ' m Ste. Genevieve Limestone 0 1 2 l l l 3 4 5 MILES | | l FIGURE 41.—Generalized map showing distribution of Mooretown Formation—Bethe] Sandstone channel fill in central to western Kentucky and cross section showing relationships of channel fill to other rock units. (Map modified from Reynolds and Vincent. 1967; cross section northwest of Elizabethtown from Peterson, 1964.) to black carbonaceous shale with siderite nodules is associated with thin and discontinuous coal beds in the upper part of the Big Clifty and the Mooretown (Bethel) in west-central Kentucky and in the Cypress, Hardins- burg, and Tar Springs Sandstones of western Kentucky. Perhaps the thickest is a l-ft bed reported in the Cub Run quadrangle (Sandberg and Bowles, 1965) of south- central Kentucky. ROCKS EAST OF THE CINCINNATI ARCH East of the Cincinnati arch, Chesterian age equiva- lents crop out along the western border of the Eastern Kentucky coal field in a belt extending across south- central, east-central, and northeastern Kentucky; they also are exposed along Pine and Cumberland Mountains in southeastern Kentucky. Carbonate rocks are domi- nant in the lower part of the succession of Chesterian correlatives; the upper part mainly consists of ter- rigenous clastic rocks. During the 1960—1978 geologic mapping in south- central Kentucky, the interval dominated by carbonate rocks was assigned, in ascending order, to the Kidder Limestone Member (Lewis, 1971b) of the Monteagle Limestone (Vail, 1959; Stearns, 1963), Hartselle Forma- tion (Smith, 1894) (a relatively thin unit of sandstone and shale), and Bangor Limestone (Smith, 1890). In east-central, eastern, and northeastern Kentucky, cor- relatives of the Kidder, Hartselle, and Bangor general- ly were mapped together as the upper member of the Newman Limestone (Campbell, 1893). The overlying interval dominated by terrigenous clastics was desig- nated as the Pennington Formation (Campbell, 1893), but in northeastern Kentucky, following the usage of Englund and Windolph (1971), these rocks generally were mapped in the Newman Limestone. The Carter 78 MISSISSIPPIAN ROCKS IN KENTUCKY Buffalo Buffalo _ Wallow WaIIovv Formation FormatIon Tar Tar Springs _ Springs Formation '. '_ Formation u ‘5 a Q) .0 I— a.) a; s2 2) E 3 E '1’ a: C C 0 o ‘0‘: :7; Q’ a) E E —‘ _I C : ‘5 I m G) I I (D 0 o I: I I C 2 .“3 0 _ | l | I I I I | I I I I I I I _ ~ 0 E" 8 I I l | I I | I I I | I | I I a) 3 3 E | I I I I | I I I I I I I I I I 3 E o a, I I 1 I I I I I I I I I I I 3 a; -' E I I I I I l I I I I I I I I l I I I I flI I_ E __ ‘ I I I I I I I I I DII—I _ —‘ —‘ | I I I I _ I | I I I I I I I | I I l I I l I I l I l I l | l l FIGURE 42.—Diagram showing relationships of the Glen Dean Limestone. Tar Springs Formation, and lower part of Buffalo Wallow Formation in Mattingly quadrangle, west-central Kentucky. A, local section at Bull Creek; B, typical of remainder of quadrangle (from Clark and Crittenden, 1965). Caves Sandstone (Englund and Windolph, 1971) is a linear body of sandstone occurring within the terrigenous-clastic sequence of northeastern and north- west eastern Kentucky. It commonly rests disconform— ably upon limestones of the Newman. In east-central and northeastern Kentucky, as previ- ously mentioned, the names Slade and Paragon Forma- tions have replaced the Newman Limestone and Pennington Formation used during the mapping pro- gram (Ettensohn and others, 1984). The Slade Forma- tion (fig. 43) includes 9, possibly 10 (Warix Run) members of Chesterian age, including the unit former- ly identified with the Glen Dean and Bangor Limestones to the west and south, and the Cave Branch Bed. The overlying Paragon Formation, mostly fine grained clastic rocks (fig. 44), is divided into four informal members of contrasting shale and carbonate rock. Because the gross units, Slade and Paragon, closely ap- proximate the stratigraphic limits of the previously used Newman and Pennington terminology, which is well entrenched in the literature, these terms are used interchangeably in the discussion here, with Newman and Pennington generally first mentioned because they are the terms used on the geologic maps. Changes from the older names are based on a rationale which considers the older Appalachian basin terms inappropriate because of correlation difficulties. The various members of the Slade and Paragon are significant subdivisions of these units in that they allow study of detailed depositional environments and authigenic processes. ROCKS OF CHESTERIAN AGE 79 FIGURE 43.—Roadcut mostly in Slade (Newman) Formation. Bench above truck is top of Mill Knob Member. Lower tongue of Breathitt Formation (arrow) (Pennsylvanian) above topmost vertical face of Slade limestone. Milepost 60.7, Interstate Highway 75, Mount Vernon quadrangle, Rockcastle County. The limestone, dolomite, shale, and sandstone of the Kidder, Hartselle, Bangor, and the equivalent upper member of the Newman (Slade) form a relatively uniform succession of lithologic subunits which can be traced along the outcrop belt bordering the Eastern Kentucky coal field (Butts, 1922; McFarlan and Walker, 1956). Carbonate rocks in the lower part of both the Kidder and upper member of the Newman (Slade) con- sist of bioclastic and oolitic calcarenite alternating with calcilutite and dolomite. To the northeast, the lower in- terval is dominantly calcilutite. The calcarenites and calcilutites form multiple fining-upward sequences, com- monly capped by exposure zones which, in part, are altered by secondary silicification and dolomitization. A prominent exposure zone which can be traced the length of the outcrop belt caps the interval of fining- upward cycles. It is overlain by the Cave Branch Bed (Dever, 1980a), a thin but widespread shale that forms a useful marker within the carbonate section. Overlying the Cave Branch Bed in the middle part of the Kidder and upper Newman (Slade) are oolitic and bioclastic calcarenite and thick-bedded, crinoidal calcirudite, characterized by an association of Agassizo- crinus, Pentremites, and a distinctive, large, uniden- tified crinoid columnal (McFarlan and Walker, 1956). In northeaStern Kentucky, deposits of calcilutite and dolomite underlie this subunit. The crinoidal calcirudite is overlain by a complex sequence of bioclastic and oolitic calcarenite, calcilutite, dolomite, and shale. The presence of nodular chert is a distinctive feature of these upper calcarenites, particularly in east-central and northeastern Kentucky. The Hartselle Sandstone in south-central Kentucky and along the Kentucky-Tennessee State line consists of very fine to medium-grained quartzose sandstone and shale. N ortheastward along the outcrop belt, the sand- stone pinches out and the Hartselle and its equivalent in the upper Newman (Slade) are composed of shale characterized by thin, discontinuous beds and lenses of calcilutite. The Bangor and correlative limestone of the upper Newman (Slade) are mainly bioclastic calcarenite containing zones of dolomitic limestone and locally, oolitic calcarenite. The limestones are commonly argil- laceous, in part silty and sandy, and locally cherty; they generally are darker colored than limestones of the Kidder and underlying Newman (Slade). The unit is thick bedded in the lower part and grades upward into thinner beds with shale partings, forming a gradational contact with the Pennington (Paragon) Formation. The upper, thinner bedded interval is very fossiliferous. The Pennington (Paragon) and correlative rocks of northeastern Kentucky are composed of shale, sand- stone, siltstone, limestone, and dolomite. The sequence of lithologies, in ascending order, consists of (1) gray 80 MISSISSIPPIAN ROCKS IN KENTUCKY FIGURE 44.—Section at Strunk Crushed Stone Company quarry, Tateville, Burnside quadrangle, Pulaski County. Monteagle Limestone (Mm); Hartselle Formation (Mh); Bangor Limestone (Mb), and Paragon (formerly Penn- ington) Formation (Mp). ROCKS OF CHESTERIAN AGE 81 shale, (2) interbedded dolomite and limestone (south) or sandstone (north), and (3) gray shale grading upward into red and green shales with interbeds of dolomite and siltstone. In south-central Kentucky, carbonate rocks are important constituents of this dominantly terrigenous-clastic sequence. Fossiliferous limestone is interbedded with the basal gray shale, which is overlain by an interval of interbedded dolomite and limestone; a thin but widespread limestone occurs near the middle of the formation, and dolomites are associated with the upper red and green shales (Ettensohn and Chesnut, 1979a, 1979b). Northeastward along the outcrop belt, carbonate-rock deposits are restricted mainly to the middle limestone unit and upper dolomites. Sandstones occur in the middle and upper Pennington (Paragon) of south-central Kentucky and in the middle and lower parts of the unit in east-central and northeastern Ken- tucky. They commonly are slightly argillaceous and micaceous; but orthoquartzitic sandstones, similar to those of the Mississippian and Pennsylvanian Lee For- mation, are present within the sequence and include the Carter Caves Sandstone of northeastern Kentucky and a sandstone in the upper Pennington (Paragon) of south- central Kentucky (Smith, 1978). Thin coals have been found locally in the Pennington (Paragon) in east-central Kentucky (Ettensohn, 1977; Ettensohn and Peppers, 1979; Rice, 1972). In southeastern Kentucky, rocks of Chesterian age are present along Pine Mountain in the Newman Lime- stone (upper member and part of lower member), Penn- ington Formation, and tongues of Lee Formation (Campbell, 1893) occurring within the Pennington. Chesterian correlatives exposed on Cumberland Moun- tain along the Kentucky-Virginia and Kentucky- Tennessee State lines are the upper member of the Newman Limestone, Pennington Formation, Pinnacle Overlook Member (Englund, 1964a), and Chadwell Member (Englund, 1964a; Englund and others, 1963) of the Lee Formation. The White Rocks Sandstone Member of the Lee Formation, formerly listed as Mississippian in age, is now assigned to the Pennsyl- vanian (Englund and others, 1985). The Newman on the Pine Mountain overthrust block has been divided into two informal members. The lower member is composed of limestone and minor dolomite; the upper member is mainly shale, with lesser amounts of limestone, dolomite, siltstone, and sandstone. The ap- proximate boundary between Meramecian and Chesterian equivalents is within the lower member, about 250 ft below the top, based on the position of the Taggard Red Member of the Greenbrier Formation (Wilpolt and Marden, 1959). The Taggard is a distinc- tive unit, commonly from 5 to 20 ft thick, consisting of grayish-red to grayish-red-purple and greenish-gray calcarenite, calcilutite, mudstone, and shale. It is a useful marker in the central and northeastern parts of the Pine Mountain belt; in the northeast, however, distinct units with similar coloration and lithology also occur at several positions in the lower half of the lower member of the Newman. Limestones of the Newman lower member above the Taggard are principally bioclastic calcarenites. Im- mediately above the Taggard, they are partly oolitic and interbedded with calcilutite and dolomite. The calcar- enites are increasingly argillaceous and darker colored upward within the member and, in the upper part, inter- bedded with argillaceous limestone and thin shales. Fossil content also increases upward within the member. Chesterian crinoid genera, Talarocn'nus and A gassizocrinus, have been found in the lower member in Harlan and Letcher Counties (Greenfield, 1957). The calcarenite, argillaceous limestone, and shale of the lower member grade upward into the upper member of the Newman, which is mainly medium gray to dark- gray and greenish-gray shale, with lesser amounts of siltstone. Limestone is interbedded with calcareous shale in the lower part; sandstone, in discontinuous lenses, occurs in the middle and upper parts. At the northeastern end of Pine Mountain, a zone of grayish- red and greenish-gray shale with lenses of dolomite is present at the top of the Newman (Alvord and Miller, 1972). Along Pine Mountain the Newman is overlain by the Pennington Formation, which consists mainly of siltstone, sandstone, and shale. Rocks assigned to the Pennington principally are of Late Mississippian age, but the presence of Pennsylvanian rocks locally in the upper part of the formation is indicated by the occur- rence of the spore, Laevigatosporites (mostly L. ovalis) (Maughan, 1976). Average thickness of the formation is about 450 ft in the southwestern part of Pine Moun- tain, 900 ft in the central part, and 750 ft in the north- east. At Pineville, the Pennington thickens abruptly, from 500 ft on the west side to 1,100 ft on the east side of the Rocky Face fault, a north-south-trending fault with strike-slip displacement (Froelich and Tazelaar, 1974). The N ewman-Pennington contact in the northeastern part of Pine Mountain is placed at the base of the Stony Gap Sandstone Member (Reger, 1926) of the Penn- ington, which was mapped along the outcrop belt in Pike County and part of Letcher County (Elkhorn City through Whitesburg quadrangles). To the southwest, correlative rocks were mapped as part of the lower member of the Pennington. The Stony Gap is dominant- ly crossbedded, quartzose sandstone, with tongues and interbeds of variegated shale and siltstone. Southwest- ward from central Letcher County, sandstone in the 82 MISSISSIPPIAN ROCKS IN KENTUCKY lower Pennington commonly is less quartzose, ripple- bedded, and interbedded and interlaminated with shale and siltstone. In the southwestern part of the outcrop belt, siltstone and shale are dominant lithologies in the lower member (Newell, 1975; Rice and Newell, 1975). The upper Pennington above the Stony Gap in the northeastern part of Pine Mountain consists mainly of siltstone and shale, with lenticular bodies of sandstone. The siltstone and shale range from variegated grayish red and greenish gray to dark gray and carbonaceous. Lithologic descriptions on the geologic quadrangle maps indicate that the sandstone content of the upper Pennington is greater to the southwest. Tonguelike bodies of conglomeratic, quartzose sandstone, similar to that of the overlying Lee Formation, occur in at least two positions within the Pennington (Maughan, 197 6). These have been mapped as the “lower tongue of Lee Formation” (Englund and others, 1964), “sandstone tongue(?) of Lee Formation” (Csejtey, 1970; Froelich, 1973; Froelich and Tazelaar, 1974), and “sandstone tongue of Lee(?) Formation” (Rice and Maughan, 1978). The sandstone or lower tongue of Lee occurring in the upper member of the Pennington in the Pineville area (Englund and others, 1964; Froelich and Tazelaar, 1974; Rice and Maughan, 1978) is considered to be correlative with the Pinnacle Overlook Member of the Lee on Cumberland Mountain (Rice, 1984). The Little Stone Gap Member (Miller, 1964) of the Pennington, composed of marine fossiliferous shale, silt- stone, and limestone, was mapped in Pike County and part of Letcher County. There, it occurs near the middle of the Pennington section above the Stony Gap Member. To the southwest, discontinuous deposits of fossiliferous, calcareous shale and siltstone, and lime- stone near the middle of the formation may be correla- tive with the Little Stone Gap. Marine fossil-bearing beds also occur locally at various positions in the upper and lower parts of the Pennington. Coal beds are fairly common in the upper Pennington of Letcher and Harlan Counties, and one bed has been reported at the base (Maughan, 1976). The coals general- ly are thin, but locally are as much as 3 ft thick (Froelich, 1973). Plant remains occur in sandstones of the Pennington, including the Stony Gap Member. The youngest Mississippian unit in southeastern Kentucky is the Chadwell Member of the Lee Forma- tion, which crops out along Cumberland Mountain. Dur- ing the mapping program, the Chadwell (previously designated as “sandstone member A”) and the generally overlying White Rocks Member were considered to be of probable Pennsylvanian age, but they were assigned a Late Mississippian age by Englund (1979). Englund and others (1985) later reassigned the White Rocks back to the Pennsylvanian designation. The older Pinnacle Overlook Member of the Lee (previously designated as “lower tongue of Lee Formation”), which also crops out on Cumberland Mountain, occurs mainly as a tongue of Lee sandstone within the Pennington. All three members consist of very light gray to white, fine- to coarse-grained, quartzose sandstone which is partly con- glomeratic, with well-rounded quartz pebbles 1%; to 1 in. in diameter. They are thick bedded to massive, and crossbedded. The presence of an unusual abundance of quartz pebbles is the main distinguishing characteristic of the White Rocks Member (Englund, 1964a). The Chadwell Member overlies the Pennington. Basal sandstone of the Chadwell intertongues with upper Pennington shale and laterally grades into argillaceous sandstone of the Pennington (Englund, 1964a). South of Cumberland Gap, the upper member of the Penn- ington pinches out and the Chadwell rests on the Pin- nacle Overlook Member (Englund, 1964b). The White Rocks Member (Pennsylvanian) locally overlies the Chadwell. The White Rocks thins southwestward from its type locality on the crest of Cumberland Mountain, near Ewing, Va., and pinches out southwestward about 5 mi northeast of Cumberland Gap. Thicknesses of the Lee members are varied; they reach a maximum of about 350 ft for each member. In southwestern Virginia, northeast of the Kentucky outcrop, the Chadwell and Pinnacle Overlook intertongue with rocks of the Blue- stone Formation (equivalent to upper Pennington) and pinch out to the northeast (Englund, 1979). A Chadwell correlative may be present on Pine Moun- tain in southwestern Harlan County, where the Penn- ington is overlain, in ascending order, by conglomeratic sandstone and marine shale (C.L. Rice, US. Geological Survey, oral commun., 1981). The sandstone and shale were mapped as the basal part of the Middlesboro(?) Member of the Lee (Froelich, 1972). LITHOLOGIC TRENDS AND INTERBASIN CORRELATIONS A lithofacies depiction of the total Chesterian succes- sion in the Eastern Interior basin (Sable, 1979a) results from combining the many rhythmic alternations of detrital and carbonate units, which are modified by ir- regular amounts of erosion in the upper part of the in- terval. In the most complete Chesterian rock sections in the southern part of the basin, sandstones are most abundant in southern and southeastern Illinois, and are common in western Kentucky. Lobate sandstone tongues converge towards the center of the basin in southern Illinois as shown by Swann and Bell (1958). Increase of carbonate rocks along the southernmost limits of Chesterian strata in west-central and south- central Kentucky results mostly from the southward thinning and disappearance of pre—Big Clifty detrital ROCKS OF CHESTERIAN AGE 83 units into the Girkin Formation (fig. 45). A westward increase in mudstone in Chesterian units such as in the Big Clifty is reported by Swann (1963, p. 15; 1964, p. 649) and is shown by comparison of Kentucky GQ maps (for example, Big Clifty quadrangle versus Olney quadrangle); a southeastward increase in the mudstone: sandstone ratio also occurs in post-Glen Dean rocks of west-central Kentucky. Relationships between Chesterian units of the East- ern Interior basin and presumed equivalents in the Ap- palachian basin are critical for understanding the Mississippian System in Kentucky. These rocks have been removed by erosion along the axis of the Cincin- nati arch; outcrops in the two basins are about 50 mi apart at their nearest point in the Cumberland saddle area of south-central Kentucky. Two major lithologic trends indicate a continuity of deposition between the two basins. The southeastward decrease in detrital input in the Eastern Interior basin during early Chesterian time extended into the western part of the Appalachian basin, as reflected by the dominance of car- bonate rocks in both the Girkin Limestone, west of the Cincinnati arch, and the Kidder Member of the Mont- eagle Limestone, east of the arch. Chesterian rocks in most of the Eastern Interior basin, as noted previously, Big Clifty Sandstone Member of Golconda Formation Beech Creek Limestone Member of Golconda Formation ypress Formation Paint Creek Limestone Bethel Sandstone Renault Limestone consist of a cyclic sequence of limestones alternating with sandstones and shales. In contrast, the upper part of the Chesterian succession in both the eastern part of the Eastern Interior basin (Buffalo Wallow and Leitchfield Formations) and the western part of the Ap- palachian basin (Paragon and Pennington Formations) mainly consists of shale with lesser amounts of sand- stone and relatively minor amounts of limestone and dolomite. Specific correlations between Chesterian-age units of the Eastern Interior and Appalachian basins, based on megafaunal elements and the similarity and sequence of lithologic units, were proposed by Butts (1922), Stokley and McFarlan (1952), and McFarlan and Walker (1956). The stratigraphic units and nomenclature of McFarlan and Walker (1956) have been utilized in reports of the Kentucky Geological Survey and in papers and theses of other Kentucky workers, but were not considered applicable by the US. Geological Survey during the geologic mapping project because of lack of mappable continuity and specific paleontologic and lithologic correlations of many units east and west of the Cincinnati arch. The Hartselle Formation, as mapped in eastern south- central Kentucky (Lewis and Thaden, 1965), the only i: .9 ,_. (U E l. O u. .E x .L' (3 FIGURE 45.—Relationships of Girkin Formation with coeval units of Chesterian age as mapped in the Homer quadrangle. west-central Ken- tucky. A, typical of the western part of the quadrangle; B, typical of central and eastern parts (modified from Gildersleeve, 1966). 84 MISSISSIPPIAN ROCKS IN KENTUCKY sandstone occurring in the carbonatedominated section between the Ste. Genevieve and Pennington (Paragon), may be a key to understanding relationships between Chesterian—age units in the two basins. Correlation with two different sandstone-bearing units west of the Cin- cinnati arch has been suggested: Hardinsburg Sand- stone (Stokley and McFarlan, 1952; McFarlan and Walker, 1956; Lewis and Thaden, 1965; Ettensohn, 1980) and Big Clifty Sandstone Member of the Golcon- da Formation (Butts, 1922; Peterson, 1956; Vail, 1959; Horowitz and Strimple, 1974; Sable, 1979a; Horowitz and others, 1979). It should be noted that the wide- spread shale facies in the Hartselle was correlated with the Golconda by Butts (1922) because in northern Ten- nessee, the shale lies above the sandstone facies which was correlated with the “Cypress” (Big Clifty). Correlation of the Hartselle with the Hardinsburg is based in part on characteristics of the enclosing lime- stones. The Hartselle is overlain by limestone similar to the Glen Dean of west-central Kentucky, and is underlain by limestone similar to the Haney Limestone Member of the Golconda Formation, and at some places containing chert like that in the Haney. However, Haney-type chert in limestone overlying the Hartselle has been reported in the vicinity of Albany, Clinton County (see section, “Carbonate-dominated units,” p. 73). Microfaunal elements from a core taken in northern Tennessee, just south of the Kentucky-Tennessee State line, show that the Hartselle is overlain and underlain by beds of Golconda age, the basal Bangor and upper- most Monteagle respectively. This indicates that the Hartselle is correlative with the Big Clifty, the middle member of the Golconda in the Eastern Interior basin (Horowitz and others, 1979). Massive sandstones are well developed in the Hardinsburg Sandstone in the northern part of west-central Kentucky, but the sandzshale ratio of the Hardinsburg decreases southward (compare Mattingly and Homer geologic quadrangle maps). The Hartselle in south-central Ken- tucky and north-central Tennessee contains consider- able sandstone. It thus appears that the Hardinsburg clastic ratios do not correspond with those of the Hartselle. The Big Clifty, on the other hand, is largely massive thick-bedded sandstone to its erosional limits in western south-central Kentucky; and its lithofacies pattern can, with a fair degree of assurance, be com- pared favorably to that of the Hartselle. Directional depositional components (crossbedding and lobes of sandstone lithofacies (fig. 46)) of the Big Clifty in west- and south-central Kentucky (Potter and others, 1958), if they represent primary sand input, suggest westward and northwestward transport through the Cumberland saddle (unlike most Michigan river southwestward transport features). This may further suggest that the thick Big Clifty sandstones may be related to the Hart- selle in Kentucky. In addition to possible correlation of the Hartselle with units west of the Cincinnati arch, a southwestern source for the type Hartselle Sandstone of Alabama was suggested by Thomas and Mack (1982). The body of sandstone in northern Alabama pinches out to the northeast (Thomas, 1972, 1974). Its exact relationship with the sandstone in the Hartselle of northern Ten- nessee and south-central Kentucky, about 100 mi north, is uncertain because detailed studies along the outcrop belt in Tennessee have not yet been done. Thus, the Hartselle Sandstone of Alabama may or may not equate with that in Kentucky. During the mapping program, rocks in the unit that Butts (1922) had identified as Glen Dean in south- central and east-central Kentucky were assigned to two formations. The thick- to medium-bedded bioclastic limestone forming the main part of the Glen Dean of Butts (1922) was designated as the Bangor Limestone in south-central Kentucky; it was included in the up- per Newman Limestone (Slade Formation) in east- central and northeastern Kentucky. The shale and in- terbedded limestone at the top of the Glen Dean of Butts (1922) were included in the Pennington Forma- tion; these uppermost beds are the principal source of Glen Dean—age megafauna (Butts, 1922; Horowitz, 1965; Weir and others, 1971; Ettensohn and Chesnut, 1979b; Chesnut, 1980). The Bangor in the northern Ten- nessee core studied by Horowitz and others (1979) con- tains foraminifera and conodonts which indicate a Glen Dean age for at least part of the formation; the older Golconda age, as noted above, was determined for the basal Bangor. On Pine Mountain in southeastern Kentucky, lime- stone similar to the Bangor is present in the upper part of the lower member of the Newman. The overlying upper member of the Newman is correlated with the Bluefield Formation of southern West Virginia and southwestern Virginia (Wilpolt and Marden, 1959), which generally is considered to be of Glen Dean age (Butts, 1940; Cooper, 1944). Age determinations for the unit designated as Paragon Formation of Ettensohn and others (1984) (formerly Pennington Formation), along the western border of the Appalachian basin, and reported correla- tions with Upper Mississippian units of the eastern Ap- palachian basin and Eastern Interior basin are not entirely compatible. Paleontological data indicate the presence of younger rocks in the Paragon than are sug- gested by lithostratigraphic correlations. Recent studies of the palynology and microfauna indicate a Glen Dean to Grove Church age for the Paragon in and near the ROCKS OF CHESTERIAN AGE 88° 87° 86° 85° I J ( ( i ‘ s I I I 39" — EXPLANATION ,7 ' 1.,“ § .7 »- Sandstone <— General direction of sediment ,jfi) 1 Q. n ,2 j V ' transport (from Potter and a?“ ,1 .. ,me \v A \ o 30 70 100 PERCENT others. 1958) {w ~- , g» , _ a ,7 j "\ ; it MNQKS 37° —— )UU MILES FIGURE 46.—Distribution of sandstone and shale in Big Clifty Sandstone Member of Golconda Formation in west-central, central, and western Kentucky. and Hartselle Formation in south-central Kentucky, showing sediment transport directions. Kentucky fault patterns shown on base. outcrop belt along the western border of the Eastern Kentucky coal field (Ettensohn and Peppers, 1979; Horowitz and others, 1979). Rocks designated as Para- gon in this outcrop belt have been correlated with the upper member of the Newman, or Bluefield, on the Pine Mountain overthrust block (Englund and Windolph, 1971; Englund and Randall, 1981). The Bluefield, as noted previously, is considered to be Glen Dean in age. Englund and Henry (1979) and Englund and Randall (1981) indicated that as a result of progressive west- ward, post-Mississippian truncation of Upper Mississip- pian units, the equivalents of the Pennington Formation on the Pine Mountain overthrust block are not present in the Paragon outcrop belt along the western border of the Eastern Kentucky coal field. The Pennington on Pine Mountain is approximately correlative with the Hinton Formation, Princeton Sandstone, and Bluestone Formation of West Virginia and Virginia (Wilpolt and Marden, 1959), which range in age from Menard to Grove Church or younger (Gordon and Henry, 1981). SOURCES OF SEDIMENTS AND DEPOSITIONAL ENVIRONMENTS An ancient southward-flowing river system, first en- visioned by Stuart Weller (1927, p. 26) and later named the Michigan river (Swarm, 1963, p. 12), is interpreted to have transported detrital Chesterian sediments into and across the Eastern Interior basin. Evidence for the Michigan river consists of regional thickness and facies distribution of Chesterian units (Swann and Bell, 1958), southward-dipping crossbeds in generally southward trending sandstone bodies (Potter and others, 1958; Potter, 1963), and channel-fill morphology of sandstone bodies (Potter, 1962, p. 28—29; 1963; Reynolds and Vincent, 1967; Sedimentation Seminar, 1969). The main sediment source was in eastern Canada, either in the Canadian shield or east of the northern Appalachian fold belt. The possibility that the uplifted Franklinian geosyncline in northern Canada may have been a major source was also suggested by Swarm (1964). According to Swann, the Michigan river flowed southwestward across Michigan and northern Indiana into a shallow sea, where detrital sediments accumulated as a birds- foot delta projecting southward beyond a N. 65° W.- trending shoreline. Lateral northwest or southeast shifts in the course of the Michigan river of as much as 200 mi produced belts of sand and mud in different parts of the region at different times. Major northeast and southwest oscillations of the shoreline, perhaps as much as 600 to 1,000 mi, produced numerous marine transgressions during which carbonates were deposited in the basin and surrounding areas and the amount of clastic detritus was relatively low. The resulting highly 86 MISSISSIPPIAN ROCKS IN KENTUCKY variable but rhythmic depositional complex of sediments includes shallow-marine detrital and car- bonate facies, littoral detrital facies, and continental detrital and coaly facies. Superimposed on the system of shifting shorelines and positions of the river system, Swarm (1963, p. 14—15) postulated a northwest-flowing sea current or drift which carried muds northwestward, leaving relatively clear water in the southeastern (south- central Kentucky) part of the basin where limestone ac- cumulated. Sea depths in the Eastern Interior basin during Chesterian time have been estimated on the basis of water depths near modern deltas, increased by the estimated amount of compaction of the sediments deposited. These estimates place the depth of water at 50—75 ft, with a range of from 30 to 100 ft (Swarm, 1964, p. 652—653). A low dip of the paleoslope, low relief of the sea floor, and a widespread shallow-marine environment are in- dicated by (1) the distribution of tabular carbonate units which individually cover thousands of square miles and indicate similar depositional environments across these large areas, (2) the presence of oolitic limestones and current-bedding features, and (3) numerous shallow- water fossils. Likewise, the widespread sheets of ter- rigenous clastics also indicate generally uniform shallow-marine, shoreline and lower delta plain environ- ments, in contrast to environments of the earlier Borden deltaic beds, which prograded into deep water and were onlapped by deep-water carbonates deposited along the delta front. The major sources for terrigenous elastic sediment of the Pennington Formation were highlands of sedimen- tary and metamorphic rocks lying generally east of the Appalachian basin (de Witt and McGrew, 1979). Whether detrital material from Appalachian basin source areas contributed to Chesterian rocks west of the Cincinnati arch in the Eastern Interior basin as may be suggested by Big Clifty—Hartselle distribution (p. 84) is uncertain. Some contribution in late Chesterian time may also be suggested by lithologic similarity of the Pennington and Paragon Formations of eastern Ken- tucky and the Leitchfield and Buffalo Wallow Forma- tions of west-central Kentucky. Carbonate-dominated units of earlier Chesterian and Meramecian age were deposited across the Cumberland saddle area as shown by their lithic and faunal similarities, and their thick- ness trends indicate that the saddle was then a negative element athwart the Cincinnati arch. In southeastern and eastern Kentucky, sandstones in the Pennington and Paragon, which thin to extinction westward and southward, have been interpreted to have been trans- ported southwestward along the Appalachian basin from a northeastern source area (Vail, 1959, p. 59), but in view of the proposed Paragon-Bluefield correlations discussed previously (p. 84—85), this conclusion may be invalid. The northwest sea-current drift proposed by Swann, which moved muds discharged by the Michigan river westward, explains the mudstone in the western part of the Eastern Interior basin. A connection across the Oimberland saddle area (Cumber- land strait) also could provide a passage for late Chesterian (Pennington-Paragon) fine-grained sedi- ments from Appalachian sources carried by westward- flowing marine currents to form Leitchfield-Buffalo Wallow clastic strata in the Eastern Interior basin. Mixing of Appalachian sediments with those from the Michigan river would thus have taken place in west- central Kentucky. Depositional environments of the rocks of Chesterian age in the upper member of the Newman (Slade), the Kidder-Hartselle-Bangor sequence, and Pennington (Paragon) along the western border of the Eastern Ken- tucky coal field have been studied extensively in recent years. Carbonate rocks in the lower part of both the Kidder and the upper member of the Newman (Slade), below the Cave Branch Bed, form multiple fining- upward sequences. These sequences indicate transgressive-regressive cycles, with shallow, subtidal carbonate sands grading upward into prograding tidal- flat and supratidal deposits of lime mud and silt. (Dever, 1973, 1977). Individual sets of supratidal and tidal-flat deposits commonly are capped by exposure zones. The entire interval of fining-upward sequences is capped by a prominent exposure zone which can be traced the length of the outcrop belt of these units. Limestone, shale, and sandstone of the upper Newman (Slade) overlying the widespread exposure zone, and sediments of the younger Pennington (Paragon) Formation were deposited in a major transgressive-regressive sequence (Ettensohn, 1975, 1977, 1980; Ettensohn and Chesnut, 1979b). The trans- gressive sequence consists of intertidal mud flats (Cave Branch Bed), lagoonal lime mud (calcilutite), carbonate sand belt (calcarenite and calcirudite), shallow open- marine deposits (fossiliferous calcarenite, calcilutite, and shale), and deeper open-marine deposits (shale and calcilutite). The change from transgression to regres- sion is considered to have occurred during deposition of this open-marine shale, an equivalent of the Hartselle. Succeeding regressive deposits consist of carbonate sand belt (calcarenite; Bangor equivalent), lagoonal deposits (fossiliferous shale and limestone of basal Pen- nington (Paragon)), and carbonate and detrital tidal flats with local coal-forming swamps (dolomite and sandstone; see Ettensohn and Peppers, 1979). The regressive sequence was temporarily interrupted by a marine advance with deposition of a thin but wide- spread limestone. Succeeding the limestone are prodelta MISSISSIPPIAN-PENNSYLVANIAN-YOUNGER ROCK RELATIONSHIPS 87 deposits of prograding shoal-water deltas or tidal flat sediments (shale, siltstone, and dolomite of uppermost Pennington-Paragon). As each of the depositional en- vironments migrated with transgression or regression across the region, its lithologic expression assumed a sheetlike geometry forming a stack of widespread, tabular lithologic units (Ettensohn, 1977). The linear body of the Carter Caves Sandstone in northeastern Kentucky has been described variously as an offshore bar (Englund and Windolph, 1971), a beach-barrier island system (Home and others, 1974), a tidal-channel deposit paralleling the Waverly arch (Ettensohn, 1977), and a distributary-channel deposit of a Pennington (Paragon) delta system (Short, 1978). Deposition of Chesterian-age rocks in northeastern and east-central Kentucky was influenced by the Waverly arch, which was a positive feature, and by recurrent movement along the Kentucky River fault system, as described in Dever and others (1977), Ettensohn and Dever (1979), and Ettensohn and Peppers (1979). Depositional environments of the Newman and Pen- nington in southeastern Kentucky on the Pine Moun- tain overthrust block have not yet been studied extensively, but the environments of deposition for cor- relative units in southwestern Virginia and southern West Virginia have been discussed by Englund (1979), Englund and others (1981), and Miller (1974). Rocks of Chesterian age show a general upward transition from shallow-marine shelf and nearshore-marine deposits to nearshore tidal-flat, beach, lagoon, and marsh deposits. The Pennington, in particular, is characterized by deposition in alternating near-coastal terrestrial and nearshore marine environments. PALEOGEOGRAPHY AND PALEOTECTONIC IMPLICATIONS In general, stream and shoreline positions lay in western Kentucky through much of Chesterian time. The Michigan river system was the dominant transport- ing agent. A delta-complex at its mouth included both sheet sands and linear sand bodies such as channel fills, point bars, and distributary mouth bars. Sediment discharged by the Michigan river may have been deposited as far south as northwestern Alabama and northeastern Mississippi. Only minor coaly beds formed in interdistributary swamps on the delta plain, suggest- ing that rates of clastic deposition were high, with rapid shifts of distributaries and splay channels. Highlands east of the Appalachian basin contributed detrital sediments, some of which in late Chesterian time were probably carried through the Cumberland saddle and intermingled with Michigan river sediments in western Kentucky. The northern part of the Cincinnati arch in Ohio and possibly Kentucky was a low-lying peninsula or shoal area which contributed little sediment but may have acted as a partial barrier between the Eastern In- terior and Appalachian basins. Abundant marine faunas and oolitic limestones in- dicate subtropical or tropical conditions during Chesterian time. Scattered coaly beds and fairly abun- dant fossil plant remains in sandstones and siltstones suggest humid terrestrial conditions. Red shales are common in some detrital units such as the Big Clifty, Pennington, and Leitchfield Formations; they may in- dicate the presence of deep residual soils in source areas (Vail, 1959, p. 52). Mild but persistent subsidence characterized broad areas of western Kentucky, and sediment thicknesses indicate that the greatest subsidence was in the Fair- field basin in Illinois and Moorman syncline in Ken- tucky. The lateral persistence of individual formations and their small thickness variations show that sub- sidence was relatively even. Minor differential move- ments probably occurred along the La Salle anticlinal belt, folds in Illinois and Indiana (Siever, 1951, p. 569), and the Rough Creek and Pennyrile fault systems. A regional southwestward-dipping paleoslope and a mildly negative trough across Michigan, Indiana, Illinois, and western Kentucky controlled the trend of the Michigan river system. The area of the Cumberland saddle is presumed to have been a mildly downwarped element between the Jessamine and Nashville domes that con- nected eastern and western basins in Kentucky. In eastern Kentucky, the area between the present Cincinnati arch and the Appalachian basin, the Waverly arch, was a relatively high and unstable platform during Chesterian age deposition. Minor differential movement occurred along the Kentucky River fault system. MISSISSIPPIAN-PENNSYLVANIAN- YOUNGER ROCK RELATIONSHIPS Detrital rocks of terrigenous origin of Pennsylvanian and Cretaceous age unconformably overlie rocks of all Mississippian series in Kentucky. Only in the southeast- ern part of Kentucky has it been described that Missis- sippian and Pennsylvanian strata are conformable. Recent literature on systemic relationships includes a comprehensive synthesis by Rice and others (197 9). Pennsylvanian rocks overlying Mississippian strata are dominantly lower delta plain deposits of sandstone, mudstone, conglomerate, clay, and coal with very minor marine beds including limestone and mudstone. These basal strata of Morrowan and Atokan ages are the lower part of the Lee and Breathitt Formations in the eastern part of Kentucky, and the Caseyville Formation in the west. About 100 mi separates the two main belts of exposures. 88 MISSISSIPPIAN ROCKS IN KENTUCKY A major erosional hiatus between Mississippian and Pennsylvanian rocks is well documented in much of Kentucky; it is marked by progressively deeper bevel- ing of pre-Pennsylvanian strata north of Kentucky in northern Illinois and Indiana, where as much as 1,500 ft of Mississippian section may have been removed (Sable, 1979a). Channels superimposed on a gently roll- ing surface are as much as 450 ft deep in southeastern Illinois (Siever, 1951). In western Kentucky, as much as 900 ft of Mississippian strata is believed to have been removed, with channels incised as much as 250 ft into the Mississippian surface (Bristol and Howard, 1971). In northeastern and east-central Kentucky pre- Pennsylvanian erosion is evinced by a southward- or south-southeastward-sloping beveled surface locally marked by paleokarst topography developed on Missis- sippian limestones (Dever, 1971; Weir, 1974b; Hoge, 1977). The beveling appears to have been controlled by growth of the Cincinnati and Waverly arches (Englund, 1972). In west-central Kentucky, pre-Caseyville For- mation beveling has truncated progressively older Chesterian units in general eastward or southeastward directions, toward the Cincinnati arch, as shown in figures 47, 48, and 49; the illustrated localities lie along an 18-mi line of section and show the Caseyville For- mation lying on post-Kinkaid Limestone beds, on post- Menard Limestone beds, and on the Vienna Limestone, respectively, from northwest to southeast. Channeling into this surface is locally pronounced, and relief along the borders of the deeper channels is commonly about 60—80 ft. Reconstruction of Mississippian strata prior to Pennsylvanian erosion indicates that 160 ft of Borden and Newman and an undetermined amount of Penning- ton may have been removed in the vicinity of the Bell Branch channel in Pomeroyton quadrangle (Weir and Richards, 1974). On the west side of Indian Fort Moun- tain in the Bighill quadrangle (Weir and others, 1971), as much as 240 ft of upper Newman (Slade) and Pennington (Paragon) strata may have been present prior to erosion. Several southwest-trending sub-Pennsylvanian chan- nels in central, west-central, and western south-central FIGURE 47.—Sandstone of Caseyville Formation (PC) with basal thin coal bed (c) overlying limestone equivalent of Kinkaid Limestone in Buffalo Wallow Formation (Mbwk). Intervening shale probably of Mississippian age. Caneyville Crushed Stone Company quarry, Caneyville quadrangle. Grayson County. MISSISSIPPIAN -PEN N SYLVAN IAN-YOUN GER ROCK RELATIONSHIPS 89 FIGURE 48.—Caseyville Formation (PC) disconformably overlying Buffalo Wallow Formation (Mbw). Exposed Buffalo Wallow units are (descending) unnamed gray shale; 6-ft thick Menard Limestone equivalent (M bwm), unnamed greenish and reddish shale and dolomite (Mbwd). Milepost 101.0, Western Kentucky Parkway, Caneyville quadrangle, Grayson County. Kentucky are incised as much as 250 ft in the Mississip- pian surface, following truncation which may have removed as much as 1,000 ft of Mississippian strata (Rice and others, 1979). East of and colinear with the southernmost channel, isolated hilltop outliers of sand- stone, shale, and conglomerate, interpreted to be remnants of basal Pennsylvanian channel fill, extend along a west-southwest linear trend across parts of Ed- monson, Hart, and Larue Counties, west-central and south-central Kentucky (Burroughs, 1923; McFarlan, 1943, p. 96). These outliers mapped in Hibernia (RE. Moore, 1976) and other quadrangles overlie strata of the Ste. Genevieve and upper part of the St. Louis Lime- stones. Growth of the Cincinnati arch prior to channel cutting is suggested by these relationships. The main channel continues southwestward across the southern part of the western Kentucky coal field as part of the channel complex overlying Chesterian units, described by Shawe and Gildersleeve (1969) and Sedimentation Seminar (1978), and termed the Brownsville channel by Bristol and Howard (1971, p. 9). Rice and Weir (1984) interpreted the Brownsville paleochannel to be the distal part of the much larger southeast-gradient Sharon-Brownsville paleovalley system which headed north of Pennsylvania. In general, Pennsylvanian sandstones are composi- tionally and texturally similar to Mississippian sand- stones, and in many places unfossiliferous mudstone, shale, and siltstone constitute the strata between un- mistakable Mississippian and unmistakable Pennsylva- nian rocks so that recognition of the systemic boundary is difficult. Two-group discriminant functional analysis of geochemical data of Pennsylvanian and Chesterian sandstones was reported by Connor (1969) and Connor and Trace (1970) to be of potential use in future discrimination of similar rocks of the two systems. In southeastern Kentucky, the Mississippian- Pennsylvanian systemic boundary occurs within rock sequences that generally were considered to be con- formable. Along Pine Mountain, the boundary locally is in shale and siltstone sequences of the Pennington Formation. The Pennington rocks are mostly of Late Mississippian age, but the occurrence of the spore, Laevigatosporites (mostly L. ovalis), in the upper part of the formation indicates the presence of rocks of Pennsylvanian age (Maughan, 1976). On Cumberland 90 MISSISSIPPIAN ROCKS IN KENTUCKY FIGURE 49.—Sa.ndstone of Caseyville Formation (Pc) overlying 8-ft thick Vienna Limestone (Mv). Basal Caseyville consists of 6 ft of quartz- pebble conglomerate. Section below Vienna is 26 ft of Tar Springs Formation (Mts) shale. sandstone, and limestone overlying Glen Dean Limestone (Mgd). Cardinal Stone Company Quarry, Bee Spring quadrangle, Edmonson County. Mountain, Englund and Smith (1960), Englund (1964a), and Englund and Delaney (1966) reported intertongu- ing and lateral gradation between rocks of the Lee and Pennington Formations which, at that time, generally were considered to be of Pennsylvanian and Mississip- pian age, respectively. Lower members of the Lee, the Pinnacle Overlook, Chadwell (previously designated as “sandstone member A”), and White Rocks Members, which intertongue with the Pennington, later were assigned a Late Mississippian age by Englund (1979). The oldest Pennsylvanian unit on Cumberland Moun- tain, according to Englund (1979), was the Dark Ridge Member (previously designated as “sandstone and shale member B”) of the Lee Formation, which apparently was conformable with Mississippian rocks of the Lee and Bluestone Formations. The Dark Ridge was de- scribed as gradational and intertonguing with the Chadwell and White Rocks (Englund, 1964a, 1964b; Englund, Landis, and Smith, 1963). Rice (1984), however, suggested that the systemic boundary may be an unrecognized paraconformity within the Dark Ridge. More recently, Englund and others (1985) reassigned the White Rocks to the Pennsylvanian System and showed the White Rocks and Dark Ridge Members of the Lee Formation to unconformably overlie Mississippian rocks of the Bluestone Formation and Chadwell Member of the Lee Formation. The conclusion that an unconformity between the Mississippian and Pennsylvanian Systems extends throughout eastern Kentucky is supported by a sub- surface study that, in southeastern Kentucky and southwestern Virginia, identifies a 350-ft-deep, southwest-trending valley fill at the base of the Penn- sylvanian called the “Middlesboro paleovalley” (Rice, 1985). The reassignment of the White Rocks Sandstone Member of the Lee Formation from Mississippian to Pennsylvanian age by Englund and others (1985) has suggested to Rice (in Shepherd and others, 1986) that MISSI SSI PPIAN—PENN SYLVANIAN -YOUN GER ROCK RELATIONSHIPS 91 sediments of the White Rocks filled the Middlesboro paleovalley where that valley intersects Cumberland Mountain. An intra-Pennsylvanian unconformity originating within the lower part of the New River Formation of West Virginia and Virginia was considered by Englund (1974, 1979) and Englund and Henry (1979) to be coex- tensive with an unconformity at the base of the Middles- boro Member of the Lee in southeastern Kentucky and with an unconformity occurring between Mississippian and Pennsylvanian rocks along the western border of the Eastern Kentucky coal field. More recently the un- conformity beneath the Pineville Member of the New River Formation in West Virginia and Virginia was ex- tended southwestward beneath the White Rocks, Dark Ridge, and Middlesboro Members of the Lee Formation along the Kentucky-Virginia State line where it is coex- tensive with the Mississippian-Pennsylvanian systemic boundary (Englund and others, 1985). Where the Mid- dlesboro Member of the Lee overlies the Pride Shale, its base marks the unconformity at the systemic bound- ary according to CL. Rice (written commun., 1987). The presence of an unconformity at the Pennsylvanian- Mississippian systemic boundary in northeastern Kentucky has been challenged by several workers. Deposition of the Carboniferous rocks of northeastern Kentucky as part of a gradational sequence of westward- prograding fluvial, deltaic, lagoonal, shoreline, and marine sediments was proposed by Home and Ferm ( 1970), Swinchatt (1970), Ferm and others (1971), Home and others (1971), Ferm (1974), and Home and others (1974). Their depositional model involved rocks of the Borden, Newman (Slade), Pennington (Paragon), Carter Caves, Lee, and Breathitt; intra- and post-Mississippian unconformities, identified by earlier workers, were con- sidered to be facies or depositional boundaries. In the model, orthoquartzites (Carter Caves, Lee) were inter- preted as beach-barrier deposits which grade landward into lagoonal-bay and deltaic-fluvial shales, subgray- wackes, and coals (Breathitt). The beach-barrier sand- stones grade seaward into marine shales (Borden and Pennington) which surround limestones (Newman) deposited as carbonate barriers, bars, and tidal-flat- island complexes. The model was developed incor- porating the exposures of Carboniferous rocks along Interstate Highway 64 in Carter and Rowan Counties. Study of the rock units along the interstate highway and in adjacent areas has shown that the field relation- ships do not support the proposed model (Dever, 1973; Ettensohn, 1975, 1979a, 1980, 1981; Rice and others, 1979). For example, a large body of marine shale which is shown in the model as occurring between and grada- tional with isolated limestone bodies and with ortho- quartzites does not exist at that stratigraphic position (fig. 50, upper cross section). The area of northeastern Kentucky used for the depositional model is on the up- thrown block of the Kentucky River fault system and astride the axis of the Waverly arch, but these tectonic elements were not recognized during the model’s devel- opment. Uplift and movement along these features during the Carboniferous resulted in extensive intra- and post-Mississippian erosion in the area and partly controlled deposition of Mississippian and Pennsylva- nian units (Dever, 1973; Dever and others, 1977; Englund, 1972; Ettensohn, 1975, 1980, 1981; Ettensohn and Dever, 1979; Ettensohn and Peppers, 1979; Haney, 1976; Haney and others, 1975; Home and Ferm, 1978; Sergeant and Haney, 1980; Short, 1978). Short (1978) also proposed that the Mississippian- Pennsylvanian systemic boundary in northeastern Ken- tucky is within a gradational sequence, with continuous deposition from deltaic and marine sediments of the Pennington into deltaic and fluvial sediments of the Lee and Breathitt. He recognized that local disconformities occur in the sequence at the base of channel-fill sand- stones, but suggested that the extensive intra- Mississippian unconformity in the area commonly is misidentified as a post-Mississippian unconformity. Both Short (1978) and Ettensohn and Peppers (1979) suggested a Late Mississippian age for the Olive Hill Clay Bed of Crider (1913) which traditionally has been assigned to the Pennsylvanian. Their suggested age is based on the occurrence of palynomorphs that may in- clude pollen from an eroded Mississippian upland, ac- cording to CL. Rice (written commun., 1987). On the other hand, Haney (1979, 1980) reported that the systemic boundary is coincident with an unconform- ity in areas that were tectonically active during the Car- boniferous, such as northeastern Kentucky, but that in areas distant from active tectonic features, such as south-central Kentucky, the systemic boundary com- monly is within a gradational sequence. In the latter areas, occurrences of an erosional surface between Penn- sylvanian and Mississippian rocks are considered to be related to downcutting during intra-Pennsylvanian ero- sion. Rice (1980), in rebuttal, contended that regional relationships indicate the presence of a widespread un- conformity coincident with the systemic boundary, and he reported the development of an extensive consequent drainage system after emergence of the region in Late Mississippian time. Subsurface analysis of oil and gas logs by C.L. Rice and others (written commun., 1987) indicates that Lower Pennsylvanian strata thin and onlap onto older Mississippian rocks northward in east- ern Kentucky. This suggests that some localities in northeastern Kentucky were emergent during Early Pennsylvanian time—no strata were deposited there. In parts of south-central Kentucky where no obvious Lee Formation MISSISSIPPIAN ROCKS IN KENTUCKY EAST Breathitt Formation " FEET 4 MILES Modified from Farm and others |197i, fig, 13] | and Home and others (1974, fig. 2] 10” 200 Slade and Paragon Fms BORDEN FORMAT I0N Orthoquartzite sandstone Limestone Dolomite EXPLANATION Red and green shale _ Siltstone Sandstone, siltstone, and shale undifferentiated FIGURE 50,—Generalized cross sections showing two interpretations of Pennsylvanian and Mississippian unit relationships along Interstate Highway 64, northeastern Kentucky (from Rice and others, 1979, modified from Dever, 1973). erosional surface is recognized between Mississippian and Pennsylvanian rocks, the systemic boundary is con- sidered to be a paraconformity which may be misinter- preted as a normal bedding plane or facies-related boundary (Rice, 1980). Detrital rocks of the Tuscaloosa and McNairy Forma- tions of Late Cretaceous (Gulfian) age lie on an erosional surface of Mississippian and older rocks in the Missis- sippi Embayment area of southern Illinois, westernmost Kentucky, Tennessee, and southeastern Missouri. More than 3,000 ft of Mississippian strata were removed by pro-Cretaceous erosion in westernmost Kentucky and southern Illinois, the result of the growth of the Pascola arch and its denudation (Schwalb, 1969). There is little indication of growth of the Pascola arch in western Ken- tucky during Mississippian time; only the isopach pat- tern of latest Chesterian sediments (fig. 64), may suggest influence of a positive feature such as the Pascola arch to the south and west of western Kentucky. Through much of Mississippian time, however, a south-southwest- trending depositional trough or basin in which more than 3,300 ft of Mississippian rocks accumulated is evidenced by the record of Mississippian strata. Thicken- ing of most Mississippian stratigraphic intervals shown in figures 54-63 is towards the Pascola arch. SUMMARY OF THICKNESSES AND LITHOLOGIC TRENDS The generalized isopach maps (figs. 51—64) portray thicknesses of single or multiple units of Mississippian strata and are based largely on data from geologic quad- rangle maps of Kentucky and individual measured sur- face sections; they also rely upon subsurface data from published reports and from files of the Kentucky Geo- logical Survey. Isopach intervals are variable between maps and also within some individual maps. Thick- nesses shown reflect in-place depositional thicknesses modified by subsequent burial and induration. The iso- pachs give only general unit thicknesses for two reasons: (1) Considerable range in unit thicknesses is given in col- umnar sections of mapped quadrangles so that an accurate representative average thickness figure for a unit in any given quadrangle is difficult to obtain. The average thicknesses used in thickness calculations were therefore based on average thicknesses shown in the col- umnar sections and augmented by map inspection. (2) Some unit thicknesses given in well descriptions are highly subjective because of varying interpretations by different geologists who described the subsurface rocks SUMMARY OF THICKNESSES AND LITHOLOGIC TRENDS 93 89° 88° 87° 86° 85° 34° 83° 82" I I K I l l E « \. ,, l l ‘ 39° _ l WT ,2 > » may. 3 2 f. {x 3 \V . / mammal ,5, 38° — El “Nikita 00’» ~ “ ,i» A m [800 | D 50 100 MILES FIGURE 51.—Total thickness (in feet) of Mississippian rocks in Kentucky. Solid isopachs show thicknesses of strata underlying Pennsyl- vanian rocks; dotted lines where overlain by Cretaceous and Tertiary rocks or in exposure areas of Mississippian rocks. See figure 2 for distribution of units. Selected faults and fault zones shown on Kentucky base. 89° 88° 87° 86° 82° 39° I I a! I I — / T k 4.: a i \ / iNE)lL‘aN.-¥ , ...... X . I {W} WEST "I VIRGINIA llLENOIS 37° — glfifwu: WT. ,n. ,_ n . , . 'I l l l l] 50 100 MILES |_;_;l_l_J%—l FIGURE 52.—Cumulative thickness (in feet) of Bedford Shale, Berea Sandstone. and Sunbury Shale in eastern part of Kentucky, and thickness of approximate age-equivalent strata (Maury Formation, Rocldord Limestone. and Hannibal Shale equivalents) in other parts of Kentucky. +, thickness uncertain, less than 10 ft. 94 MISSISSIPPIAN ROCKS IN KENTUCKY 89° 88° 87° 86° 85° 84° 83° 82° 39° _ l, \ T‘ 1/ YNIREANA 38" ~ Elilfmflié [1 El] 100 MILES FIGURE 53.—Thickness (in feet) of terrigenous elastic units of the Borden Formation (New Providence, Nancy. Cowbell, Halls Gap. Wildie, N ada, Holtsclaw, Farmers, Kenwood), New Providence and Grainger Formations, and basal shale beds (New Providence Memberi in the Fort Payne Formation. 89° 88° 87° 86° 85° 84° 83° 82° l 39°- EXPLANATION < :_’ N , Dominant to predominant E Cane Valley Limestone dark-gray to brown shale Member of Fort Payne and siltstone (from sub- Formation surface records: limits uncertain)‘ Outcrop and surface area of crinoidal biocalcirudite and green shale 10 to 165 ft 33° — thick mmsm lLLlNOlb [] 50 100 MILES FIGURE 54.—Thickness (in feet) of Muldraugh Member of Borden Formation and of Fort Payne Formation exclusive of basal shale units, and showing distribution of unusual lithic components. SUMMARY OF THICKNESSES AND LITHOLOGIC TRENDS 95 59° 88° 37° 86° 85° 84° 83° 82° I I \ | | T 39" _ a) .1 r“: l f ,1 3 j ENDMEEA 38° — \? ——* {LUNOXS v: :43: MA I ’HEE‘NESSEE‘ L l l “j C300 < U 50 100 MILES \_l_;.1__x__J—| FIGURE 55.—Combined thickness (in feet) of Muldraugh—Fort Payne-Salem-Warsaw—Harrodsburg units in central to western Kentucky, and probable equivalent Renfro Member of Slade Formation (Msr) (previously of Borden Formation) in east-central and southeastern Kentucky. Dashed line is arbitrary cut-off of Renfro Member isopachs. 39° 88° 87° 86° 85° 84° 83° 82° Willi} 1/ IM’NANA iUJNOlS: [J 50 100 MILES FIGURE 56.—Thickness (in feet) of Harrodsburg Limestone in central. south-central, west-central, and western Kentucky. Dashed isopachs in areas of little control. 96 MISSISSIPPIAN ROCKS IN KENTUCKY 89° 88° 87° 86° 85° 84° 83° 32° l | l | I in _ 1 l 1 39°_ m M M : > , ‘3 OHM": {I l j E z /) INDIANA I' /_. f 1 / x /' x a, “0/ wee? » magma aa°— f _ {LLINOIS -\,’._ ‘- J TENNEEaJEEMI ‘ “ [] 50 100 MILES |_L__l_|_l__l—¥ FIGURE 57.——Cumulative thickness (in feet) of Salem, Salem-Warsaw, St. Louis, and Renfro (excluding Muldraugh equivalents) units in Kentucky. 89° 88° 67° 86° 85° 84° 83° 82° I | | I 7 A l l 1 33° _. E ("l \ ’ (KN (“\f— g 3 , V \\ OHIO f T i “o f .4 ,/ ~’ \_ _ , i ,3 1NMANA J “ z / ‘ pi / , , / , ”a" x L,” f ‘ J "7’ WEST 5 Q magma 38° — ,5“ ~ k) _ ,7 , (\ {LUNOIS 1 100 MILES FIGURE 58.—Thickness (in feet) of St. Louis Limestone and St. Louis Member of Newman Limestone and Slade Formation. Top of unit placed at top of Lost River Chert Bed of Elrod (1899) in south-central and west-central Kentucky and inferred equivalent in western Kentucky. SUMMARY OF THICKNESSES AND LITHOLOGIC TRENDS 97 88° 88° 87° 83° 85° 34° 83° 82° I I I | I { ,. l l I 39” —— EXPLANATION ' ’ , / \— Distribution of Warix Run Area of reported distribution / " Member of Platycrinites penicillus and \ Distribution ofconglomeratic Lithostrotion harmodttes m .9 beds at base of Ste south-central Kentucky—p. : Genevieve reported isolated occurrence ,2 § A rea of reported outcrop ‘, , 2:. ‘ ‘\\\ occurrence of Lost River fl ,\ r’ ..'> ” ~ . _ a 1.1:??? A o Chert Bed in south-central A ’ * ' “ ‘ ° 3 U ‘ I“ 39 ‘ Kentucky _ lLUNOIS u ' so 100 MILES l_i__l_l_l_L___—l FIGURE 59.—Thickness (in feet) of Ste. Genevieve Limestone and probable and inferred equivalents (Warix Run and Ste. Genevieve Members of Slade Formation and Newman Limestone, and Ste. Genevieve Limestone Member of Monteagle Limestone). Base of Ste. Genevieve in west-central and western Kentucky placed at top of Lost River Chert Bed of Elrod (1899) or inferred equivalent. 89° 33° 37° 35° 85° 34° 33° 32° l | | l l 1 39°- EXPLANATION .j‘ j ..... \ mm [/ij— ‘ 3 ' A .1 ( Shale Sandstone Sandstone Limestone and shale . , and dolomite 0 50 100 PERCENT —0—— Approximate erosional edge of Chester Series and 38° — equivalent rocks {Llth'HS 0 50 100 MILES l_1._\_|_L_l_—l FIGURE (SQ—Thickness (in feet) and generalized lithofacies of Chesterian rocks and equivalents in Kentucky. 98 MISSISSIPPIAN ROCKS IN KENTUCKY 89° 88° 37° 95° 32., I I 390— ”W I l L— I / \ I 1 / INDIANA :3 / x “/1 XV; r" j WEST 53 VIRGINIA 38°~ ILLINOIS LN. K I} .350 /\ K» ,CP'u/Jgo‘x I ' . 37°— \ I ~~~~~ \ MO J . 5:!“ hf»~~m_mnnwh‘:_/I I TENNESSEE. I l I I I 0 50 100 MILES FIGURE GIL—Thicknm (in feet) of Kidder Limestone Member of Monteagle Limestone and equivalents in eastern to south-central Kentucky, and cumulative thickness of Paoli Limestone through Elwren Sandstone. and Renault Limestone through Cypress Sandstone in west- eentral and western Kentucky. 89° 88° 37° 39° i I / INDIANA / ILLINOIS [I 50 IUD MILES I_I_I__I_I_L—__I FIGURE (ta-Thickness (in feet) of combined Hartselle Formation and Bangor Limestone in eastern to sonar-central Kentucky and thickness of Golconda Formation in west-central and western Kentucky. SUMMARY OF THICKNESSES AND LITHOLOGIC TRENDS 99 89° 88° 87" 86° 84° 83° 82° l | 39° _. lNDlANA 38° — lLLlNOiS .._.z.-v «V -, TENNESSéE [] 50 100 MILES I_I_I__I_.I__L______l FIGURE 63.—Thickness (in feet) of Paragon and Pennington Formations in eastern to south-central Kentucky and combined thickness of Glen Dean—Tar Springs—Vienna—Waltersburg formational units in west-central and western Kentucky. Dashed isopach lines indicate approximate or inferred thickness. Area of anomalous thickness patterned. 89° 88° 87° 88° 34° 33° 82° T | H I | l l l 39° _ \_ I OHIO \d \ A / I INDIANA KVN‘ ' kl / I’ N’TVT‘ H / ‘ J Lz’J K , f WEST \ VIRGINIA 38° — ILLINOIS 5‘» C \ ."j 7 \ \\/ (P/;::\O\.\ 37° — \S\< ‘1 , £+ MO I . k,_ - (4 $:£[~J{:’MT,W;_ .I.. 1.4m I TENNESSEE I M I ‘ " ”I u 50 mo MILES L_I___L___L_.I___|_._____l FIGURE 64.—Generalized thickness (in feet) of interval from base of Menard Limestone and equivalent units in Leitchfield and Buffalo Wellow Formations to base of Caseyville Formation (Pennsylvanian). 100 at different times in their nomenclatural history. These isopach maps were compiled by Sable, who has at- tempted to use criteria consistent with surface interpre- tation where possible. Because of the above factors, general thickness trends shown on the maps are consid- ered to be valid, but positions of isopachs should not be considered to be exact. For instance, the known linear trend in the thick, narrow Bethel (Mooretown) sandstone- filled channel (see section, “'Ibrrigenous clastic units,” p. 74), is not adequately shown in the corresponding thickness map (fig. 60), which portrays the early Chesterian interval within which the Moorean occurs (recall fig. 8). In the following discussion relating to figures 51—64, some reiteration of material previously discussed is included for the sake of emphasis. Factors affecting the total thickness of Mississippian rocks (fig. 51) in Kentucky are post-Mississippian ero- sion, variations in Mississippian sediment volume distribution, and Mississippian tectonic movements. Erosional effects include regional beveling after deposi- tion of Chesterian rocks but prior to deposition of Penn- sylvanian strata, and Mesozoic and Cenozoic erosion that has stripped Mississippian rocks from the Pascola arch in westernmost Kentucky and the Cincinnati arch in central Kentucky. Thickness variations of Mississip- pian deltaic deposits in parts of the region, shifts in loci of detrital deposition, and filling of troughs peripheral to deltaic platforms by carbonate and detrital rock sediments appear to be less important factors than late or post-Mississippian erosion in portrayal of present total thicknesses. In western Kentucky, Mississippian strata thicken towards the Fairfield basin in Illinois to more than 2,800 ft in Crittenden County, western Kentucky. Deviations in general trend directions suggest control by warping along the Rough Creek—Shawneetown and Pennyrfle fault zones. In eastern Kentucky, a broad, irregular northeast-trending platform area is represented by 700—900 ft of Mississippian strata, east of which the rocks thicken rapidly into the Appalachian basin. The thickest strata east of the Cincinnati arch trend are on the east side of the Cumberland saddle area in south- central and southeastern Kentucky, and locally in northeastern Kentucky east of the Waverly arch. The elastic wedge of latest Devonian and earliest Mississippian rocks in Kentucky, comprising the Bedford-Berea-Sunbury units, is less than 200 ft thick. Isopachs of these units (fig. 52) indicate the distal parts of major deltaic deposits (Pepper and others, 1954), with minor depocenters in northeastern Kentucky, and southwest-trending lobes which are interpreted to reflect deltaic lobes originating east of Kentucky. The Pine Mountain fault does not appear to affect isopach trends. ' MISSISSIPPIAN ROCKS IN KENTUCKY In south-central and western Kentucky, elastic rocks of Kinderhookian age (Maury Formation and Hannibal Shale equivalents) are for the most part extremely thin (fig. 52), and their constitutents appear to represent lag deposits resulting from winnowing of distal deltaic deposits by bottom currents. Some areas in which Fort Payne or New Providence strata rest directly on the Chattanooga Shale, mostly in western Kentucky (see section, “Kinderhookian-Osagean unit relationships,” p. 35), may indicate areas of mild uplift scoured by strong current action and swept clean of distal deltaic fines. Isopachs of the terrigenous clastic units in the Borden, basal Fort Payne, New Providence and Grainger Formations (fig. 53) indicate an irregular depositional platform area in eastern Kentucky in which axes of the thicker clastic lobes trend southwestward, normal to the conspicuous northwest-trending Borden delta front slope deposits that extend in an almost straight-line trend from west-central through south- central Kentucky. The Borden delta front and the mild- ly irregular delta platform topography in eastern Kentucky represent the last phase and finally cessation of active Early Mississippian deltaic deposition in Ken- tucky. Southwestward paleoslopes were dominant, and eastern source areas were probably the important contributors to the sediment wedge as shown by distri- bution and transport indicators of some sandstones (fig. 16). West of the Borden delta front, thin distal green shales are generally less than 20 ft thick, and locally absent in western Kentucky (fig. 53). A northwest- trending belt in which the carbonate and siliceous rocks of the Fort Payne Formation strata directly overlie the Chattanooga Shale occurs in the southern part of western Kentucky subparallel to the Borden front, and may indicate that a low submarine platform occupied this area during deltaic deposition. Another area in which basal clastics are absent is part of the fluorspar district of western Kentucky, which may have been a dome before collapse and mineralization. Southwest of this, however, a thickening of greenish shales inter- preted here to be Osagean in age suggests the upper end of a westward-deepening mud-filled trough. Possibly the area in the fluorspar district was a low plat- form that acted as a barrier to sediments from the Borden delta of Illinois (Willman and others, 1975, p. 137) and the Borden delta deposits in Kentucky. Carbonatedominated units, which form the Mul- draugh Member of the Borden Formation and the bulk of the Fort Payne Formation (fig. 54), thicken south- westward parallel to the Borden delta front across west- central and south-central Kentucky, and, farther west, thicken westward and southwestward to more than SUMMARY OF THICKNESSES AND LITHOLOGIC TRENDS 400 ft towards the Fairfield basin of Illinois and to more than 600 ft into the Mississippi Embayment. Litholo- gies are mostly dark siliceous silty dolostones and silty limestones except for two northwest-trending belts of strikingly different strata recorded in subsurface sec- tions: (1) a belt of crinoidal biocalcirudite with associ- ated green shale which extends northwestward from the outcrop area of Cane Valley Limestone Member of south-central Kentucky, and (2) a dominantly dark gray to brown shale and siltstone, in places more than 200 ft thick, occupying most of the interval which is commonly siliceous carbonate rocks. The shale belt is parallel to the biocalcirudite—green shale belt, and on strike with the Knifley Sandstone Member of the Fort Payne For- mation of south-central Kentucky. (See section, “Fort Payne Formation,” p. 48.) The biocalcirudite—green shale interval in the Fort Payne Formation largely coincides with a northwest- trending belt of thicker Fort Payne strata. The greater thickness is inferred to be the result of uneven deposi- tional bottom topography rather than filling of a tec- tonically controlled depression. Spatial relationships and directional trends of the crinoidal biocalcirudite and green shale and the related Cane Valley Limestone Member, the dark shale unit, the Knifley Sandstone Member, and the Borden delta front indicate genetic relationships of these features. The biocalcirudites and green shale formed southwest of and adjoining the Knifley Sandstone Member and the dark shale unit. The dark shale unit may be equivalent to the Knifley, a. distal fine sediment winnowed from the Knifley sands by longshore currents and deposited to the northwest by them. The crinoidal limestones and the green mud- stones, rather than being a slope edge deposit derived from an area of delta platform origin as interpreted by Sedimentation Seminar (1972), may have been sub- marine bank deposits growing in a peridelta belt prox-‘ imal to the deltaic bottom slope deposits and swept by currents that maintained a nutrient supply, but from which muds were trapped by the in-place crinoid organ- isms. Green coloration of the muds may indicate accumulation in a mildly reducing, open circulation envi- ronment. Basinwards, darker sediments accumulated more slowly perhaps in a deeper anoxic environment, as indicated by the tabular bedding and fine-grained to aphanitic character of much of the Fort Payne strata. In figure 55, cumulative thicknesses are shown for all pre-St. Louis carbonate-dominated units of Osagean and . Early Meramecian age, including the Harrodsburg. Salem, and Warsaw Limestones. In this and in the Harrodsburg Limestone thickness map (fig. 56), westward-thickening strata culminate in a west- to northwest-trending trough trending toward Fairfield basin of Illinois. The 300-ft isopach on figure 55 101 encompasses a broad area in west-central and south- central Kentucky, roughly reciprocal with the thickness trends shown for the Muldraugh—Fort Payne carbonate rock thicknesses in figure 54. Thicknesses of the Renfro Member in southeastern Kentucky (fig. 55) are derived mostly from subsurface information, and correspond reciprocally with the thick- nesses of the underlying Borden Formation clastic strata of figure 53. This type of relationship is con- sidered to result from filling of underlying irregular depositional topography by the overlying carbonates. However, the degree of thickening into the trough in western Kentucky is not related to such causes, but in- dicates filling of a structural trough which either predated carbonate deposition, existing under starved basin conditions, or. more likely, which developed in late Osagean and early Meramecian time during carbonate sediment deposition. Rocks of mostly Meramecian age (figs. 56—59) are best developed in parts of eastern and western Kentucky. Pre-Pennsylvanian and intra-Mississippian erosion has removed much strata from former areas of deposition in parts of northeastern Kentucky. PreCretaceous ero- sion has removed very thick sections of rocks in westernmost Kentucky and southernmost Illinois. Thicknesses of Meramecian rocks (Sable, 1979a) range from 400 to more than 1,100 ft. The thickest accumula- tion of sediment was in western Kentucky, southern Illinois, and southwestern Indiana. Marginal to the Cin- cinnati arch in eastern Kentucky, thicknesses are gener- ally less than 200 ft. Strata of Meramecian age are predominantly car- bonate rocks throughout the State. The bordering areas in which terrigenous detrital components are concen- trated are those in which the upper, dominantly lime- stone units, such as the St. Louis and Ste. Genevieve, have been eroded; in south-central Kentucky (Cumber- land saddle area) and western central Kentucky, fine detritals in the lower units such as the Salem and Warsaw make up a significant proportion of the strata that remain. Mudstone is also present in these units on the west side of the Cincinnati arch from southern In- diana to the Nashville dome in Tennessee. Quartz sand grains are present in the Ste. Genevieve Member of the Newman (Slade) and Warix Run Member of the Slade in northeastern Kentucky and their equivalents in southern Ohio and West Virginia, and farther south in eastern Kentucky. The thicknesses of the Harrodsburg—Warsaw Lime- stone interval in western Kentucky, more than 300—500 ft in Trigg and Crittenden Counties (fig. 56), are inter- preted to reflect filling of troughs peripheral to banks formed on earlier Fort Payne deposits. (See Dever and McGrain, 1969, fig. 6.) Westerly transport directions of 102 carbonate debris and westward thickening into the Fair- field basin in Illinois are indicated. Of interest is the con- siderable volume of clean, winnowed and sorted bryozoan- and crinoid-bearing debris interpreted to originate from shoals on the surface of the older Borden delta and Fort Payne accumulations. The regional strike of the Harrodsburg Limestone in Kentucky is nearly at right angles to strike of the earlier Borden delta and to the strike of the Borden and Fort Payne carbonate units of figure 54. This seems to reflect general filling of peridelta areas and the basin in southern Illinois. In Illinois, the St. Louis and the Salem Limestones have generally been considered to be intertonguing units so that their boundary cannot be considered to approximate a regional time rock boundary (Lineback, 1972). The field relationships and reciprocal thicknesses of the St. Louis and Renfro indicated by comparisons of quadrangle maps do not reflect the intergrading and interlensing of the two units as much as they do incon- sistent mapping of the contact. In figure 57, the upper limit of the St. Louis is arbitrarily placed at the top of the Lost River Chert Bed in south-central, central, and west-central Kentucky and at the top of inferred equiva- lents in western Kentucky. The resulting thickness map shows a gradual thickness increase towards the Fair- field basin of Illinois; the regional strike of the isopachs swings from north-northwest east of the Cincinnati arch to northeast and east-northeast in western Kentucky, reflecting rather even basin filling and indicating that the irregular bottom topography which characterized the region during Borden deposition had disappeared probably by Salem or early St. Louis time. Thickness of the St. Louis Limestone alone in Ken- tucky (fig. 58), shows a rather even basinward thicken- ing similar to that discussed above. Difficulties of tracing both the base and top of this unit in western Kentucky, however, make thickness interpretations there uncertain. The Ste. Genevieve Limestone and its equivalents represent largely shoal water deposition over a wide area. Isopachs of this unit and its presumed equivalents in eastern and southeastern Kentucky, the Ste. Genevieve Member of the Monteagle and Newman Limestones and Slade Formation (fig. 59), show an ap- parent westward—thickening trend across the Cincinnati arch and development of a distinct basin in western Kentucky south of the Moorman syncline. There thick- nesses exceed 300 ft. Thicknesses in southeastern Ken- tucky are uncertain but appear to be generally about 50—7 5 ft, except for a few estimates along Pine Moun- tain, where strata in the Newman Limestone which are lithologically like the Ste. Genvevieve and contain Platycn'nites penicillus are as much as about 100 ft thick. MISSISSIPPIAN ROCKS IN KENTUCKY All originally deposited thicknesses of Chesterian age rocks (fig. 60) in Kentucky have been modified by post- Mississippian erosion. The youngest known Mississip- pian units, the Kinkaid Limestone and Grove Church Shale, occur in the southern part of the basin in western Kentucky. There, nearly 1,200 ft of Chesterian Series rocks are recorded, but the original upper surface of the Mississippian deposits cannot be confidently restored. Within Chesterian units that are most widespread, how- ever, the Glen Dean Limestone and older Chesterian strata thin towards the margins of the Eastern Interior basin; this thinning is considered to be depositional thin- ning towards uplifted belts. Strata of the Chesterian Series and equivalents are more than 1,100 ft thick in both eastern and western Kentucky. The strata are thin or absent, however, in northeastern Kentucky in the Waverly arch area and along the margins of the Cincinnati arch. Irregular thicknesses along the east side of the Cincinnati arch are largely the result of irregular original thickness dif- ferences as affected by positive tectonic and irregular topographic features. The latter feature resulted from earlier intra-Mississippian erosion and to a lesser extent, from Late Mississippian or pre-Pennsylvanian erosion prior to deposition of the Lee and Breathitt Formations. In western Kentucky, basinal outlines are shown along the Moorman syncline and subparallel to the faults of the Pennyrile fault system. Thicknesses of intra-Chesterian intervals (figs. 61-64) show the continuing basinal character of western Ken- tucky, but do not definitively show the Cincinnati arch trend. A depocenter in or near the Cumberland saddle area is indicated in figures 61 and 62, as is the influence of the Waverly arch either during or following deposi- tion of the Paragon Formation (fig. 63). Thickening of sediments towards the present Pascola arch in early and middle Chesterian time (figs. 61—63) indicates that the arch area was still negative, but isopachs of latest Chesterian strata (fig. 64) show an east-west-trending basin along the Pennyrile fault system, suggesting that the arch began to grow before the Mississippian- Pennsylvanian erosional interval began. In the eastern part of Kentucky, isopachs of rocks show a northeast- trending belt of variable sediment thickness ranging from 150 to more than 200 ft which, taken with the dominant carbonate lithofacies, seems to reflect a trend of carbonate banks fringing the Appalachian basin (fig. 60). In summary, the selected thickness maps of the Mississippian and maps showing lithologic trends (Craig and Connor, 1979) reflect the onset of deltaic deposition in eastern Kentucky during Late Devonian and Early Mississippian time followed by the main southwestward progradation of the Borden delta. A CYCLIC DEPOSITION trough or depocenter was maintained in extreme south- western Kentucky during Kinderhookianl?) and early Osagean time. This shifted northward in late Osagean and early Meramecian time, and concurrently a southwest-dipping paleoslope developed. Depositional infilling west of the present Cincinnati arch appears to have slowed by middle Meramecian (middle and upper St. Louis) time. In western Kentucky a shallow deposi- tional basin developed, the depocenters of which appear to have shifted throughout Chesterian time. This shift- ing may have been in part due to tectonic causes such as sags along the Pennyrile fault system, and in part to depositional deltaic depocenters, depending on whether tectonism or sediment load was a more impor- tant factor. In eastern Kentucky, history of downsinking of the northeast-trending Appalachian basin is not well docu- mented in this report because reliable subsurface infor- mation is scarce. Early Mississippian strata of the Borden show little indication of strong northeast linear trough development. Rocks considered equivalent to the St. Louis, Ste. Genevieve, and Chesterian strata below the Paragon and Pennington likewise show no appreci- able basinal thickening in Kentucky, but Pennington strata do show a decided southeastward thickening, which may reflect both tectonic downsinking and loading response to Pennington sediments. The role of the Cincinnati arch in Kentucky during the Mississippian is not clear. Judging from the isopach thicknesses and trends, the arch seems to have been rather quiescent or only mildly active until late Chesterian time. The Waverly arch also does not seem to have exerted control of sediment thicknesses until post-St. Louis time. Between Osagean and Chesterian time, the area of the Cincinnati arch in Kentucky may have been a broad, irregular platform downwarped to the west, with vague northeast- to north-trending hingelines west of the present arch axis. Subsequent growth of the arch is shown by the apparent increased rates of thinning of St. Louis, Ste. Genevieve, and Chesterian age strata towards the arch in south-central Kentucky. The average thicknesses of St. Louis beds west and east of the present Cincinnati arch are about 229 and 166 ft respectively, with a thickness ratio west:east of 1.4. Beds of the Ste. Genevieve average about 166 and 68 ft thick respectively, with a ratio west:east of 2.4. Depositional rates thus appear to have increased from St. Louis through Ste. Genevieve time within Kentucky, with areas to the west demonstrating a greater relative amount of downsinking during this interval. During Chesterian time and the post- Mississippian—pre-Pennsylvanian interval, the arch seems to have been well developed, as indicated by the Bethel (Mooretown) channel remnants which cut 103 progressively older Mississippian strata northeastward, and by the basal Pennsylvanian channel remnants in central Kentucky, which also cut progressively older Mississippian strata eastward. CYCLIC DEPOSITION Two major pulses of terrigenous detrital sediments during Mississippian time followed deposition of the Sunbury Shale, which overlies the shallow- to deep- water deltaic Bedford-Berea units. These terrigenous pulses resulted in the Borden-Grainger offshore delta units and the rhythmic Chesterian lower delta plain deposits. The two pulses were separated by a wide- spread shallow-water marine transgression in which ex- tensive carbonate rocks as well as minor evaporites were deposited. Transitional units between the earlier deltaic deposits and the carbonate-dominated succession are the Muldraugh and Renfro Members of the Borden For- mation and siliceous carbonate rocks of the Fort Payne Formation. The Devonian-Mississippian Bedford-Berea-Sunbury units become finer grained upwards, but in the eastern United States, including most of Kentucky, conditions favorable to carbonate sedimentation did not occur until after the pulse of clastics of the Borden-Grainger suc- cession. However, the organic, low-energy Sunbury Shale is probably the eastern time equivalent of exten- sive carbonate rocks in Indiana, Illinois, Missouri, and Iowa, and thus may represent the late stage of a regional broad cycle of deposition. Cessation of Borden deltaic deposition and subsequent infilling by the upward-fining carbonate succession culminating in the St. Louis carbonate and evaporite strata may represent a second broad cycle. The Ste. Genevieve does not in itself seem to fit neatly into a cyclic framework, but thinner rhythmic upward-fining units are reported within the Ste. Genevieve (Sandberg and Bowles, 1965) and are discussed herein. St. Louis lithologies reflect very low energy environ- ments and probably represent protected lagoonal and shallow bay conditions over a large area. Internal cyclicity is reflected by upward-fining successions gen- erally beginning by a pulse of fine terrigenous debris, green shales such as those reported in quadrangles in west-central Kentucky (Kepferle, 1963b; Withington and Sable, 1969), and associated fine-grained calcar- enites and calcsiltites with scattered fossils which grade upward into calcilutite limestone. Because the St. Louis is very poorly exposed, little evidence for cyclical repeti- tions is recorded from surface exposures. However, in exploratory well cores, Kepferle and Peterson (1964) recorded upward alternations of oolitic crossbedded 104 limestone to fine-grained dolomitic limestone and dolomite to fine-grained micritic limestone capped by cherty micritic limestone. (Also see Fox and Seeland, 1964; Seeland, 1968.) Examples of cyclicity in Ste. Genevieve strata prior to the rhythmic repetition of Chesterian carbonate and clastic strata are discrete units of widespread sandstone and green shale in the upper part of this otherwise carbonate-dominated unit. Shales which may be Spar Mountain Sandstone equivalents and units referred to the Aux Vases Sandstone (Amos, 1971, 1972) and Rosiclare Sandstone Member (Amos, 1965) are ex- amples of periodic interruption of the dominantly carbonate depositional regime. These shales in them- selves do not necessarily support a hypothesis of cyclicity, because they may simply be the results of lateral migration of deltaic channels and channel splays in a general downsinking region. However, in south- central and the southern part of west-central Kentucky, the Ste. Genevieve Limestone and the overlying Girkin Limestone display rhythmic alternations of carbonate rocks. Units of crossbedded sandy or oolitic limestone are overlain by fossil fragmental and micritic limestone and capped by cherty limestone (Sandberg and Bowles, 1965). Upward-coarsening cycles are also recognized in the Girkin (Dever and Moody, 1979b). Columnar sec- tions in other quadrangles (Sable, 1964; Ulrich, 1966) suggest similar cyclicity in which crossbedded oolitic or sandy limestone and green shale represent repetitive breaks in otherwise similar-appearing sections. In the lower part of the Ste. Genevieve, a succession of alter- nating dolomite and oolitic limestone 30 ft thick has been recognized in Breckinridge, Hardin, Hart, and Warren Counties. As more detailed information becomes available, intraformational cyclic successions such as the preceding may become valuable correlation indicators. In east-central and northeastern Kentucky, columnar sections of considerable detail (Delaney and Englund, 1973; Gualtieri, 1967b; McFarlan and Walker, 1956, pl. 2) show lithologic repetition which has been ascribed to relatively local tectonic movements of the Waverly arch and along the Kentucky River fault system (Dever and others, 1977). In these sections, thin units of subtidal oolitic and sandy limestone, irregularly bedded micritic limestone, dolomitic limestone, cherty limestone and green shale, or a part of this succession are broken by breccias with dark micritic matrix interpreted to repre- sent subaerial exposure or vadose zones (Dever and others, 1977). Associated structures include birdseye texture and contorted piercement “tepee” structures that attest to repeated submergence and emergence during Chesterian and late Meramecian time. Inter- preted from a tectonic viewpoint, the above evidence MISSISSIPPIAN ROCKS IN KENTUCKY might indicate repeated oscillations of the source area as well as tectonic- or otherwise-induced sea-level movements within the depositional area. Causes for the apparent cyclical sedimentation in the Chesterian are unresolved. J .M. Weller (1956) suggested that tectonism was chiefly responsible for late Paleozoic cyclicity. Swarm (1964, p. 656—657) considered climatic fluctuations, primarily changes in rainfall in the source region of the Michigan river combined with even basin subsidence, to be the chief factor. He (Swann, 1964, p. 654) also cited eustatic sea-level changes as possible factors in some cycles in the upper Chesterian series, and suggested that alternation between pluvial and in- terpluvial stages corresponded to fluctuations of the margins of continental glaciers in the southern hemi- sphere. About 13 world-wide synchronous depositional sequences of Kinderhookian through Chesterian ages resulting from eustatic sea-level changes were postu- lated by Ross and Ross (1985). Major regressions include those in early Kinderhookian, early and middle Meramecian (St. Louis evaporites), and latest Chesterian times. They cited possible mechanisms for the eustatic changes to include oceanic crust volume changes, ocean trench activity, and orogenic activity along continental margins. “Jostling” of continental plates during a mid-Paleozoic collision of northeastern North America and Europe (Craig and Varnes, 1979) may have periodically uplifted source areas and may be a realistic tectonic concept to account for apparent cyclicity. PALEONTOLOGY During the geologic mapping program, fossils were used as practical mapping aids during quadrangle map- ping. Paleontologists of the US. Geological Survey assisted in field identifications of genera and species of macrofossils, and in some instances laboratory deter- minations of fauna and flora. An excellent summary of the paleontological zonation of Mississippian rocks in the United States (Dutro and others, 1979) included discussions of foraminiferal, brachiopod, ammonoid, and conodont zonation. MACROFOSSILS Taxonomy and zonation of macrofossils in Mississip- pian rocks stem from extensive early studies in Ken- tucky and adjacent States by S. Weller (1920, 1926), J.M. Weller (1931), Butts (1915, 1917, 1922), and ED. Ulrich (1917), and others, reviewed and updated by Weller and Sutton (1940). Crinoids, brachiopods, PALEONTOLOGY blastoids, bryozoans, solitary and colonial corals, and echinoids are dominant forms in the Mississippian assemblage; pelecypods, gastropods, and trilobites are locally abundant. Crinoid studies by Horowitz (1965), and biofacies studies of a Chesterian rock unit (Vincent, 1975) are two examples of the many selective studies done in recent years. One significant break in the crinoid fauna marks the Meramecian-Chesterian Series boundary in western, west-central, central and south-central Kentucky—that between strata containing Platycn'nites penicillus Meek and Worthen, a Meramecian form, and strata contain- ing Chesterian forms of Talarocrinus spp. The faunal change corresponds to the time of formation of a wide- spread zone of altered limestone and breccia (Bryants- ville Breccia Bed) interpreted to have developed during subaerial exposure and diagenesis. Other series bound- aries, with the possible exception of the Kinderhookian- Osagean boundary, appear to occur within intervals of continuously deposited strata, and faunal criteria for specific boundary demarcation are not conclusive. However, many specific and generic forms have proved valuable aids in practical recognition and mapping of stratigraphic units. Figure 65 shows general strati- graphic occurrences of selected fossil faunal elements which have been helpful in discriminating Mississippian rock units in Kentucky. Macrofossils of Late Devdnian and Kinderhookian ages are scarce in Kentucky. Sparse brachiopod and molluscan faunas in the New Albany, Chattanooga, Ohio, Bedford, and Sunbury Shales present difficulties in determining the systemic boundary (Campbell, 1946). Studies of macrofloras by Cross and Hoskins (1951, 1952) in regard to the Devonian-Mississippian systemic boundary were also generally indeterminate and in some cases contradictory to age determinations of macro- fossil assemblages. Savage and Sutton (1931) concluded that the lower part of the black shale (New Albany (Chattanooga)) in Allen County, Ky., is Devonian and the upper part Mississippian. Macrofossils in units of mostly Osagean age, the Borden, Fort Payne, Grainger and lower part of the Harrodsburg, are generally uncommon and scattered in terrigenously derived clastic strata. Fossil remains consist largely of scattered crinoid columnal frag- ments and brachiopod shells, with minor bryozoan fragments. Locally, concentrations of a more varied, well-preserved fauna occur in thin limestone lenses in clay shale of the New Providence Member of the Borden, such as the localities at Buttonmold Knob, Bullitt County, and Kenwood Hill, Jefferson County (Butts, 1915, 1917; Conkin, 1957). The New Providence fauna has most recently been studied by Kammer 105 (1982). In northeastern Kentucky, in Stricklett and Head of Grassy quadrangles, large spiriferoid brachiopods, crinoids, and bryozoans are locally abundant in the Cowbell Member of the Borden (Morris, 1965b, 1966a). Chaplin (1980) reported on fossil con- centrations in the Nancy, Cowbell, and Nada Members of the Borden. Mason (1979) and Mason and Chaplin (197 9) also described cephalopod faunas in the Farmers, Nancy, and Cowbell Members; and ammonoid faunas indicating westward progradation of the Borden in Kentucky are discussed by Gordon and Mason (1985). In the Borden, Fort Payne, and lower part of the Harrodsburg, biostromal accumulations of crinoid and bryozoan debris occur at various horizons. They include the Cane Valley Limestone Member and Beaver Creek limestone member which are thick and areally extensive in south-central Kentucky (Thaden and others, 1961; Sedimentation Seminar, 1972; Kepferle and Lewis, 1974). Biostromal lenses in which crinoid and other echinoderm fragments are common are also reported in the Fort Payne in western Kentucky (Rogers, 1963; Hays, 1964; Fox and Olive, 1966). Macrofossils of Meramecian age, compared to the earlier Mississippian occurrences, are abundant and varied, particularly in the Salem, the Warsaw, the Salem and Warsaw map unit, and the Harrodsburg Limestone. Brachythyrid, spiriferoid, and productid brachiopods, solitary corals, echinoid spine and test fragments, fenestrate bryozoans, and ubiquitous crinoid columnals form calcarenitic, calciruditic, and coquinoid beds. Fossils are best preserved in limy shales (Lewis, 1971a; Kepferle, 1967) and are generally more fragmental in the coquinoid and marly fine-grained limestones and dolomitic limestones. Fewer forms are found in the St. Louis Limestone, which is largely micritic, containing scattered colonial corals, brachiopods, and echinoids; fenestrate bryozoans are locally common, as are crinoidal calcarenite and calcirudite. Faunal elements in the Ste. Genevieve are more abundant and varied than those in the St. Louis, and shelly coquinoid beds occur particularly in the upper part of the unit. Many of these are crinoidal biorudites and biocalcarenites in which stem segments and calyx bases of the crinoid Platycrinites are abundant. Formations of Chesterian age in western to south- central Kentucky, consisting of rhythmically alter- nating units of limestones and detrital rocks, have abundant macrofossils in the carbonate rocks, and scat- tered remains in the clastic strata. Some carbonate units can be identified with a good degree of assurance by recognition of species of brachiopods, crinoids, and bryozoans and to a lesser extent of corals and pelecypods. Limy shales are locally very fossiliferous; 106 MISSISSIPPIAN ROCKS IN KENTUCKY {’3 SOUTH-CENTRAL E WESTERN WEST-CENTRAL AND U) E AST- CE NTRAL 1% 3 5% m 5 g c Splrifer lncrebescens Hall fig 5 Splrlfer lncrebescens Hall 5 2" 9 3 .9“ .. 5 ,5: g Composlta subquadrata Hall 2E E Composlla subquadrula Hall 27% - c m .. ._ 3 “’3 E138 E E Pterotocrlnus spp. % Sulcatoplnna mlssourlensls m 5 £8 E 2 c 2 5% A m d s * a % Pterolocrinus spp.” g 9 Pterolocrlnus spp.‘ 2’73? Tc me es pp. 5 E c 3 Prismopora serrulala Ulrich 5.3 3 G: Archimedes Spa” 5 E Archimedes spp.“ m] E l3 3 .1 i a 3 5 3 5.5 Archimedes spp. g? C E g -5 E g; 2 Large crinoid stem segments“ 0.2 m a: Inflalla lnflala (McChesneyv H“! H l l 2 Pentremltes spp.“ ' 2 Agasslzocrlnus spp. H .2 3 A . , s: §§ g g, g .6 gasslzocr nus spp. .E 5 5 9 Talarocrlnus spp. £1, E Lithodromus veryl (Greene) '3 2 an: "’ . C . '6: 9, gt 3 is: Talarocrmus spp. 3 ‘9 Talarocrinus spp. 0- 5: °_ :2 E E or: o ._ ___________ _9_>__. __ _._____.______ 2 -‘ _________________ a: Schoenophyllum aggregatum Efinopmlfin agregalum : > "thhostrotlon" (Slphonodendron) g "Lllhostrotlon"($lp oncdendmn) a Platycrlnltes penlclllus Meek and o o ‘5 g geneuleuensls .5 2 geneuleuensls a Worthen w ._. a) 2 Z 5 g Plalycrlnlles peniclllus Meek and E, 8 Platycrlnlles penlclllus Meek and GE Worthen (a E . ,_ Worthen E! " 05 —‘ w G Acrocyathus proliferum Acrocyathus prollferum — ”thhostrotlon" proliferum Hall a "thhostrotlon"prollferum Hall” "Lllhoslrotlon"prolllerum Hall” 0 "a; : Acrocyathus florlfarmls floriformls g E .2 : Lithostrotlonella castelnaul Hayasaka g .3 thhoslrotlonella caslelnaul a .9 Acrocyalhus Ilorllormis florlformls E E j E HaYasaka. —l g thhostrotlonella caste/naul .1 —— ._ é _ Hayasaka’ u:- 3 ”’4 Melonechlnus sp. (n_’ Melonechlnus sp. SWMSOPOTU 3P- : Syrlngopora sp. Archeocldarls sp. é Syrlngopora Sp. LU a) Endothyra balleyl Hall 2 E 8 Endothyra balleyl Hall (is? Hapslphyllum sp. a E V) c - E .9 la "' 3 Brachythyrls subcardilformis (Hall) g g Brachythyris subcardllformlslHaII) ; g (0.5 H . h ll 5 'g g Hapslphyllum sp. Echlnocrlnus Sp.“ '1 apsq) y um p. g E 2 Splrlfer Iateralls %_I In E % Penlremlles conoldeus '- a: gag Talarocrlnus sp. g 5% Marglnlrugus magnus _l '- 0-1 ‘33 g —7 — Splrlfer Iateralis —?‘— :I: 3 g C 3-2 Ortholetes keokuk (Hall) a. g 0 : Very large crinoid stern segments“ 2 t 5 S rln olh "'5 text slHaIl) £2 u H :5 8m y g y é‘ig c .. 8 g a) 8 g Very large crinoid stem segments' ”- >3 u. 2.: 0.0) g I a: Z FIGURE 65.—Stratigraphic occurrences of Mississippian fossil fauna, selected on basis of abundance and ease of identification, that are helpful in recognition of map units in Kentucky. Asterisk following name denotes very abundant forms. Lined areas denote intervals of largely terrigenous detrital strata. PALEONTOLOGY shales in the Glen Dean Limestone and younger units are notable examples. Brachiopods in sandstones are locally common but mostly rare and scattered in such units as the Big Clifty and Bethel (Mooretown). In east-central and northeastern Kentucky and along Pine Mountain, the lower Chesterian equivalents below the Cave Branch Bed are generally less fossiliferous than their western counterparts. Units in the upper parts of the section such as the Bangor Limestone and its equivalents and limy lenses in the Pennington For- mation contain a more abundant macrofossil fauna. On Pine Mountain, Chesterian equivalents are considerably more fossiliferous than Meramecian units. In general, probable supratidal conditions and hypersalinity con- tributed to the dearth of fossil remains in the lower part of the Chesterian equivalent section; rapid clastic deposition and high turbidity probably inhibited the growth and abundance of forms now found in most of the Pennington Formation rocks. MICROFOSSILS The microfossils in Mississippian rocks of Kentucky include conodonts, endothyrid and paleotextulariid foraminifers, and ostracodes. Although no systematic studies of the entire system have been done in Ken- tucky, foraminiferal studies include those by Browne and Pohl (1973), Browne and others (1977), Conkin (1954, 1956, 1960, 1961), Pohl and others (1968), Pohl (1970), and Pohl and Philley (1971). Conodont studies, following zonation used in the Mississippi valley (Col- linson and others, 1962, 1971), include those by Rex- road (1958, 1969), Nicoll and Rexroad (1975), Rexroad and Liebe (1962), Horowitz and Rexroad (1972), and Chaplin and Mason (1979). Conodonts currently seem to be the most reliable faunal elements used in separating Devonian and Mississippian marine rocks (see section “Devonian- Mississippian systemic boundary,” p. 32) and for zona- tion of Mississippian marine strata. Zones and ranges of conodont assemblages have been established in the upper Mississippi River valley (Collinson and others, 1962; Rexroad and Scott, 1964, reviewed in Collinson and others, 1971) (fig. 66). Their use in delineating the Devonian-Mississippian system boundary in the East- ern Interior basin has also been discussed by Sable (1979a) and in the Appalachian basin by de Witt and McGrew (1979) and Sandberg (1981). Locations of conodont collections from Upper Devonian and Lower Mississippian rocks in Kentucky are shown in fig- ure 67; the collections are discussed below and in tables 3-6. 107 CONODONT IDENTIFICATION S Samples of Late Devonian and Early Mississippian ages were collected at scattered localities in east-central, south-central, and central Kentucky during the geologic mapping program. They were identified and commented on by J .W. Huddle. His identifications and comments are included in tables 3—6, arranged on the basis of stratigraphic position and geographic area of the samples collected. Huddle (written commun.) commented in 1967: The interpretation of these collections [Samples USGS 22787-PC through 22794-PC] and those in KG-65—43 is not certain"*. Most of the forms that were starred as possibly reworked are heavy forms that could stand transportation or remain in lag concentrates. It seems certain that the deposition in late New Albany and early New Prov- idence time was very slow and gaps may be present, but the presence of phosphate nodules fish remains and conodonts representing several zones suggests that the area was under water and the gaps are due to non-deposition and submarine erosion. The absence of the cono- dont zones in the lower part of the New Providence in southern In- diana and north-central Kentucky [central Kentucky of this report] was determined by Rexroad and Scott (1964).*** The sequence [up- permost New Albany Shale and lowermost Borden Formation] seems to be most complete to the southeast, in a diagonal tier of quadrangles from Burkesville to Panola. The Bactrognathus-Taphrognathus zone is at or near the base of the New Providence in the Lebanon Junction, Howardstown and New Haven quadrangles and the Bactrognathus- Polygnathus communi zone is present in the Shepherdsville quad- rangle. The older Mississippian zones in these quadrangles in north- central Kentucky are thin or absent. FLORA Fossil plant remains occur as replacements by iron and manganese oxides and silica, and as carbonized woody fragments, tree trunks (some in growth at- titudes) in sandstones such as the Big Clifty, and macerated plant remains in carbonaceous shale and thin coaly beds in the Bethel (Mooretown), Big Clifty, and younger units. Spores occur in the coaly parts of these Chesterian units and in the Pennington Formation (Et- tensohn and Peppers, 1979). The zonation of plant microfossils in western Kentucky and in adjacent States Eastern Interior basin strata has established criteria for distinguishing Mississippian terrigenously derived clastics from lithologically similar Pennsylvanian strata (Jennings, 1977). Rare lycopod occurrences in the basal part of the St. Louis Limestone of central Kentucky were reported by Browne and Bryant (1970) and from the Salem and Warsaw unit in south-central Kentucky by Dever and Moody (1979b). Concentrations of plant debris are reported in this part of the Mississippian succession in the Elizabethtown quadrangle (R.C. Kepferle, oral commun, 1965) and in the Rock Haven quadrangle (Sable, oral commun., 1968). MISSISSIPPIAN ROCKS IN KENTUCKY 108 .253 .323 6.8 "82500 Bod Ramayana 8in< Auto Z 5 83am ginmmmmmflfi 23 new mnofiuowmmmfiu 3:8 235:8 3.38 we :Omfimmaooldw 55on .I :uxuox .miszx manoéczmoaoi .xfim :20. 3:2 02 um». 88:; Stucco—Em M 38:56 SEE—Bani. 58:sz .w._m‘.33:um u=ubozocgm w. 39:51 W. 2235.5 .mruESEPiug c=owocofi5 5235.6 .9832 233:0...»5 w 88:53.33: .m 2238 tumoou .m. 32:25 2303 .mrcauamon u:uuo:ocsw I I analoofluaoolqwl I #3353 “3.0520 Ban: 1308 .m. 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W 33—03. mzfiuzuoinoh 3:83 330530 mafiuzmoiuuhazcuxw. 2.30530 9 L1 M 3833 w «co—mm mafiunmaun<ézutu= uncguzm2£auh 8mm 5 250:8 .25 53:55. m :8: 83:5,: m v.30.— .«w uafiutmgauoéazflaum mafia—5923‘ a m. o>£>o=m0 .Sw U .322“. 3896.3 mzfiuzmgaunvaaumsg m‘iofiunb tam 9:62.00 I.| c _ .. g . 32:0 .320 :83 v.33 usfiutmmzauofiaumsza 26053.0 m>___m.u_ >95: 92925.5: 8:3 02 W :80 :20 :xufi mafiucmowuifiauufizn 33.230 % 35:5 .5... m a: o_> w mhznmhmzw; 3.5:» 352.30qu 3952 2:35; 9.20 2:326: mafiutmgauszfuzmoqu Ecomcn. >§>>§§3£®Smfifi > ( £:;:g££ amtom ncoumczou. >m=~> Eafiflmflé Amom: 39.on can .zoom .com:___oo 8mm: .wumnmg 109 PALEONTOLOGY .hxoaunovm Quanwoéuaom v5 €550-38 .1550 E 833% mfiaoa.a:cvc:8 §Eo>ofl v.8 fififimmmmmg we mflmnwavaaw wfikoam 9:2le manure <~Z.O~=> SNNNémmNm NmémnNN g _ _ _ mmmmuzzmfi E: 8:20....) :m :oF8> «552 22 .2280 etc 8 3_Ewmo> => 5.3.00 5 .529»: u.— “m~_m:5_ua=c 9.55:8 m5 ; E rhea: mvaoizv coca—Eon cache... 5 2:5 02:00:20 9:95th :2 //,,I\\ -/’\/’/ :wgwum :2 uamguohm a 29.3. E 9022.: K. SEED 8 3:0 >20 8 mmémnuw a ., 22:5 :5 2.33.1.5 5 , x, , / aao m=n_._ 3: 55031530: 3: NEWN a ,, / I 5.35 .5 5:: >3~z :z T , . ommmwwbfi A mwhwm um cone—.3. .5533 3 :1 H \ if: x8.— «Emm ._n_ ~___>mv_w:no:w 5 V. x I. 2::— 2 9.09m om umcocmrfiznsa flmnmhvmzc «.235 \L hwmg acozaEuou 2.55; to..— van cannon .«o 23:52 851305 :32 van 3252 we 8an «mo—p.532 an 3353 .0 .355: >256 393280 .m.D mmn NNKmA NN Gaza—nuke“— j awn—w “En 2.3355 can—3&2 *0 9:5sz £59. gm I :n£< 252 vb \ we :2: «mo—Ewan: Ea: «29:: «o 23E:: 2an ES"— omor 9 U For I _ xi ( l L 3:2 2: JOEKZSQXM _ b _ , _ _ owm 0mm 03 0mm 0mm omm 110 TABLE 3.—Conodonts from top one inch of New Albany and Sunbury Shales in east-central, eastern centraL and south-central Kentucky [Locations shown in fig. 67; identifications by J .W. Huddle. 1964; number of specimens shown in parentheses] Samples 1010-1090 collected from uppermost 1 in. of New Albany or Sunbury Shales. Samples 1010: State Hwy. 15, about 3 mi east of Clay City and ‘Aa mi northeast of where Hwy. 15 crosses Hatton Creek, Clay City quadrangle, Kentucky. Hindeodella sp. (7) Eupn’oniodina sp. (6) Spathognathodus sp. (1) Scolecodont (1) Fish scales, conical fish teeth, plant trash, linguloid and or- biculoid brachiopods Sample 1020: about 1,000 ft south of southernmost part of Ravenna, Ky., city limits, on the left bank of Cow Creek above L&N Railroad, Irvine quadrangle, Kentucky. Hindeodella sp. (6) Polygnathids indeterminate (4) Bryantodus sp. (1) Siphonodella sp. (4) Elictognathus sp. (1) Euprioniodella sp. (1) Ligonodina sp. (1) Conical fish tooth (1) Sample 1030: About 2 mi south of Panola, Ky. on dirt road about 600 ft southwest of Knob Lick School and about 1,300 ft northeast of Knob Lick Cemetery, Panola quadrangle, Kentucky. Euprioniodina sp. (9) Hindeodella sp. (51) Spathognathodus sp. (3) Ozarkodina sp. (8) Gnathodus? sp. (2) Lonchodina sp. (1) Polygnathids indeterminate (16) Linguloid and orbiculoid brachiopods Sample 1040: US. Hwy. 25, about 21/2 mi south of L&N Railroad tunnel in Berea, Ky., and about ‘% mi north of Boone Gap, Berea quadrangle, Kentucky. Siphonodella Sp. (17) Siphonodella duplicata Branson and Mehl (2) Hindeodella sp. (33) Ligonodina sp. (2) Bryantodus sp. (2) Euprioniodina sp. (4) Spathognathodus sp. (9) Pn'oniodina sp. (2) Ozarkodina sp. (2) Dipiododella sp. (1) Falcodus sp. (1) Polygnathids indeterminate (6) Linguloid brachiopod Sample 1050: About 2% mi east of Crab Orchard on US. Hwy. 150, about 900 ft east of Slate Creek and about 800 ft west of Lincoln-Rockcastle County line, Brodhead quadrangle, Kentucky. MISSISSIPPIAN ROCKS IN KENTUCKY Hindeodella sp. (14) Ozarkodina sp. (1) Lonchodina? sp. (1) Euprioniodina sp. (1) Hibbardella sp. (1) Polygnathid indeterminate (3) Orbiculoid brachiopods Sample 1060: On edge of reservoir near road from old US. Hwy. 27 to Mayfield, Ky., about 1/2 mi northeast of Halls Gap, Ky., Halls Gap quadrangle, Kentucky. Hindeodella sp. (14) Hibbardella sp. (2) Spathognathodus sp. (3) Pinacodus? sp. (1) Euprioniodina sp. (1) Lonchodina sp. (1) Ligonodina? sp. (1) Spores abundant Sample 1070: State Hwy. 1248 about 3% mi southwest of West Somerset on the east side of Lake Cumberland near bottom of hill, Delmer quadrangle, Kentucky. Eupn'oniodina sp. (1) Hindeodella sp. (1) Spathognathodus sp. (2) Abundant spores and linguloid brachiopods Sample 1080: About 31/2 mi southwest of Cartersville, Ky. along road about 3/5 mi southwest of Pine Grove Church and about 3/5 mi southeast of Bottom Lick Knob, Paint Lick quadrangle, Kentucky. Hindeodella sp. (1) Spathognathodus sp. (1) Shark’s tooth Linguloid and orbiculoid brachiopods Sample 1090: About 11/2 mi southeast of Bighill, Ky. along road and about 800 ft east of point where the road crosses Owsley Fork of Red Lick Creek, Bighill quadrangle, Kentucky. Hindeodella sp. (5) Siphonodella sp. (1) Spathognathodus sp. (1) Polygnathids indeterminate (2) “Worm trails” “All of the above samples were collected from the top inch of the black fissile shale (New Albany or Sunbury Shale). Near- ly all of the samples are more or less weathered and most of the conodonts are altered. The conodonts characteristic of the Sunbury fauna are Siphonodella, Elictognathus, Pinacodus and Gnathodus and these genera are also found in the Maury Formation. Samples 102C, 1040, and 1090 are definitely Mississippian, Kinderhookian in age. Samples 103C and 1060 are probably Mississippian in age. The age is based on the questionably identified Gnathodus and Pinacodus. There are no diagnostic conodonts in the other samples, and they could be either Devonian or Mississippian. Hass (Prof. Paper 286, p. 24) reports a Siphonodella fauna in the basal New Providence Shale at his locality 6 (1956, p. 27). near Sample 107C in Pulaski Co. *** this same Siphonodella fauna also occurs in the top of New Albany Shale throughout southern Indiana ***” PALEONTOLOGY 1 1 1 TABLE 4.—Conodonts from basal part of Nancy (New Providence) Member of the Borden Formation and from basal beds of the Fort Payne Formation in east—central and south-central Kentucky [Locations shown in fig. 67; identifications by J .W. Huddle, 1967; number of specimens shown in parentheses; starred forms may be reworked] Samples 227 95-PC—22799-PC from lowermost beds of Nancy Member, Borden Formation. USGS 22795-PC, field No. 103A, lowest bed in the Nancy Member, Borden Formation (New Providence Shale), about 2 mi south of Panola, Ky., 600 ft southwest of Knob Lick School and about 1,300 ft northeast of Knob Lick Cemetery, Panola quadrangle, Kentucky. Diplododella sp. (5) Gnathodus antetexanus Rexroad and Scott (19) Hindeodella sp. (137) Ozarkodina roundyi Hass (18) Polygnathus communis Branson and Mehl (81) Polygnathus sp. (10) *Pseudopolygnathus dentilineata Branson (29) *Siphonodella quadruplicata? (Branson and Mehl) (3) *Spathognathodus crassidentatus (Branson and Mehl) (11) *S. stabilis (Branson and Mehl) (8) Synpfloniodina sp. (3) The presence of Gnathodus antetexanus suggests that this may be as young as Cu II beta (G. semiglaber—Polygnathus communis zone). Spathognathodus crassidentatus suggests that Cu II alpha (Siphonodella cooperi-S. isosticha zone) may be represented and Pseudopolygnathus dentilineata is charac- teristic of Cu I strata. Very slow deposition or a lag concen- trate is suggested. This seems more likely than reworking, another possible explanation. USGS 22796-PC, field No. 104A, lowermost Nancy Member, Borden Formation (New Providence Shale Member), US. Hwy. 25, about 21/2 mi south of Berea, Ky., and about 3/: mi north of Boone Gap, Berea quadrangle, Kentucky. Polygnathus communis Branson and Mehl (1) Pseudopolygnathus prima Branson and Mehl (6) Siphonodella duplicata (Branson and Mehl) (1) Siphonodella quadruplicata (Branson and Mehl) (32 fragments) Spathognathodus stabilis (Branson and Mehl) (1) Spathognathodus sp. (3) This collection probably belongs in the Siphonodella duplicata zone of Collinson and others (1962). USGS 2297-PC, field No. 105A, lowermost Nancy Member, Borden Formation (New Providence Shale Member), about 23/4 mi east of Crab Orchard, Ky., on US. Hwy. 150, about 900 ft east of Slate Creek and about 800 ft west of the Lin-r coln and Rockcastle County line, Brodhead quadrangle, Kentucky. Bactrognathus? sp. (1) Hindeodella sp. (5) Polygnathus communis Branson and Mehl (1) Pn'oniodina sp. (1) Pseudopolygnathus pn'ma Branson and Mehl (8) Siphonodella duplicata (Branson and Mehl) (3) Siphonodella sp. (29 fragments) *Spathognathodus aculeatus (Branson and Mehl) (4) Spathognathodus sp. (4) The presence of Siphonodella duplicata and P. prima suggests that this collection also represents the S. duplicata assemblage zone. The specimens of Spathognathodus aculeatus are interpreted as reworked. Bactrognathus has never been reported below the “Sedalia” Limestone. Its presence in this sample may be explained by contamination, misidentification, stratigraphic leak, or as an extension of its range. USGS 22798-PC, field No. 107A, lowermost Nancy Member, Borden Formation (New Providence Shale Member), State Hwy. 1248 about 3% mi southwest of West Somerset on the east side of Lake Cumberland near bottom of hill, Delmer quadrangle, Kentucky. Gnathodus commutatus Branson and Mehl (2) Hindeodella Sp. (14) Ozarkodina roundyi Hass (2) Polygnathus symmetrica Branson (8) Polygnathus sp. (2) *Spathognathodus aculeatus (Branson and Mehl) (10) S. anteposicornis Scott (7) S. linguliferus? (Branson) (3) S. praelongus Cooper (45) S. stabilis (Branson and Mehl) (4) This collection is placed in the upper part of the Spathognathodus costatus zone (equivalent to the Louisiana Limestone) bcause of the presence of Spathognathodus anteposicornis and Gnathodus commutatus. USGS 22799-PC, field N 0. 107B, same locality as 107A, from rock less than 1 in. thick transitional between the New Albany Shale and New Providence Shale Member. Hindeodella sp. (2) Spathognathodus praelongus Cooper (4) S. stabilis (Branson and Mehl) (3) Synprioniodina sp. (1) Spathognathodus praelongus has previously been reported from the S. costatus zone in Montana. 112 TABLE 5.—Conodonts from basal (New Providence) part of Nancy Member of the Borden Formation in east-central and south-central Kentucky [Locations shown in fig. 67; identifications by J .W. Huddle, 1967; number of specimens shown in parentheses; starred forms may be reworked] Samples 22793-PC and 22794-PC from lowermost Fort Payne Formation and basal beds of Nancy Member, Borden Formation. USGS 22793-PC, field No. 2 of 5/7/65 Huddle, Branson, and Lewis. Limestone lens about 1 ft above the Chattanooga Shale in the Fort Payne Formation, in a small west-flowing tributary of Bear Creek, 1.23 mi west of Seminary School, Burkesville quadrangle, Kentucky. Bryantodus sp. (1) Gnathodus antetexanus Rexroad and Scott (79) Hindeodella sp. (14) Polygnathus communis Branson and Mehl (13) Pn'oniodina pulcher Branson (2) Pseudopolygnathus multistriata Mehl and Thomas (6) *Siphonodella duplicata (Branson and Mehl) (4) *S. quadruplicata (Branson and Mehl) (24) *S. obsoleta? Hass (2) *Spathognathodus aculeatus (Branson and Mehl) (9) Synpn'oniodina sp. (2) The presence of Gnathodus antetexanus and Pseudo- polygnathus multistriata in this collection suggests that the lower part of the Fort Payne Chert is equivalent to the upper part of the Rockford Limestone of Indiana (Rexroad and Scott, 1964) and the “Sedalia” Limestone. The assemblage probably represents the Gnathodus semiglaber-Pseudopolygnathus multistriata zone of Collinson and others (1962). USGS 22794-PC, field N o. 1 of 5/5/65 Huddle, Branson, and Weir (same locality as USGS 22796-PC and USGS 7652-SD). 0.0-0.8 ft above base Nancy Member of the Borden Forma- tion (New Providence Shale Member), US. Hwy. 25 about 21/2 mi south of Berea and 3/: mi north of Boones Gap, Berea quadrangle, Kentucky. Hindeodella sp. (2) Polygnathus communis Branson and Mehl (2) P. inornata Branson (1) P. permarginata Branson (1) P. scorbiformis Branson (1) Pseudopolygnathus prima Branson and Mehl (1) Siphonodella duplicata (Branson and Mehl) (10) S. cooperi? Hass (7 fragments) This collection is assigned to the Siphonodelhz duplicata zone of Collinson and others, 1962. TABLE 6.—Conodonts from basal part of New Providence Shale Member of the Borden Formation in central Kentucky [Locations shown in fig. 67 ; identifications by J .W. Huddle, 1967; number of specimens shown in parentheses; starred forms may be reworked] Samples 22787-PC—22792-PC from lowermost beds of New Providence Shale member. Borden Formation. USGS 22787-PC, field No. 5 of 5/12/65 Huddle and Branson. 0-1.2 ft above base of New Providence Shale Member, on knob south of road to Bemheim Forest opposite the County Farm near Kentucky Turnpike, Ky. State coord. 1,584,600 E. by 158,100 N ., Shepherdsville quadrangle, Kentucky. MISSISSIPPIAN ROCKS IN KENTUCKY Bactrognathus hamata Branson and Mehl (7) Hindeodella sp. (18) Neopn'oniodus sp. (2) Ozarkodina sp. (1) Polygnathus communis Branson and Mehl (7) *Polygnathus inomata Branson (6) *P. longiposita Branson (6) *P. symmetn’ca Branson (5) *Pseudopolygnathus pn'ma Branson and Mehl (18) *P. sp. (1) *Siphonodella cooper-i Hass (13) *Siphonodella duplicata (Branson and Mehl) (14) *S. quadruplicata (Branson and Mehl) (4) *Spathognathodus aculeatus (Branson and Mehl) (23) The specimens in this collection do not look reworked and the abundance of S. aculeatus suggests the presence of the Lower or Middle Spathognathodus cos tatus zone (to V1). The young- est zone present, the Bactrognathus—Polygnathus communis zone, is indicated by Bact'rognathus hamata and P. communis. USGS 22788-PC, field N o. 1 of 5/12/65 Huddle and Branson. 0.6-1.8 ft above the base of the New Providence Shale Member, roadcut on north side of US. Hwy. 62, about 1% mi east of Boston, Ky., Lebanon Junction quadrangle, Ken- tucky State coords. 1,596,400 E. by 107,700 N. Gnathodus texanus Roundy (2) Hindeodella sp. (6) Spathognathodus sp. (2) Fish remains and white hollow spheres uneven in size All of the conodonts are weathered white. The age is presumably the same as USGS 22792—PC and represents the time equivalent of the upper Burlington Limestone, according to Rexroad and Scott (1964). USGS 22789-PC, field No. 2 of 5/ 12/65 Huddle and Branson. 0.0-0.6 ft above base of New Providence Shale Member, same locality as USGS 22788-PC. Bactrognathus distorta? Branson and Mehl (1) Bryantodus sp. (1) Hindeodella sp. (17) Polygnathus communis Branson and Mehl (2) *Siphonodella sp. (two or more species) (17 fragments) *Polygnathus inomata Branson (8) *P. bngiposita? Branson (2) *P. cf. P. scorbiformis Branson (10) *Pn'oniodina sp. (1) *Spathognathodus aculeatus (Branson and Mehl) (21) *S. costatus? (Branson) (3) *Spathognathodus aff. S. disparilis (Branson and Mehl) (5) Spathognathodus sp. (4) The conodonts in this collection are weathered white and the forms starred are thought to be reworked. It is possible that there are thin layers at the base representing the Spathognathodus costatus zone and the Siphonodella zones, but reworking of the older forms seems more probable. This collection apparently belongs in the Bactrognathus— Taphrognathus zone of Collinson and others (1962) and is equivalent to the upper part of the Burlington Limestone. USGS 22790-PC, field No. 7 of 5/12/65 Huddle and Branson. Basal 0—1.3 ft of the New Providence Shale in roadcut on north side of Blue Gap, coord. 2,053,500 E. by 493,500 N., New Haven quadrangle, Kentucky. Gnathodus texanus Roundy (2) Hindeodella sp. (1) REFERENCES CITED TABLE 6.—Conodonts from basal part of New Providence Shale Member of the Borden Formation in central Kentucky—Continued [Locations shown in fig. 67; identifications by J .W. Huddle. 1967; number of specimens shown in parentheses; starred forms may be reworked] Pn’oniodina sp. (1) *Pseudopolygnathus pn’ma Branson and Mehl (3) *Siphonodella sp. (4) *Spathognathodus aculeatus Branson and Mehl (8) S. sp. (4) Most of the conodonts are fragmented, and only a few can be identified. They are weathered white, and some are stained with limonite. The presence of Gnathodus texanus indicates that the upper part of this sample, at least, belongs in the Bactrognathus— Taphrognathus zone. USGS 227 91-PC, field N o. 2 of 5/11/65 Huddle, Branson, Sable, Peterson, and Kepferle. Basal 0.8 ft of the New Providence Shale Member, new roadcut in Kentucky. State Hwy. 247, Ky. State coord. 2,053,200 E. by 470,300 N., Howardstown quadrangle, Kentucky. Bryantodus sp. (1) Gnathodus antetexanus Rexroad and Scott (14) G. distorta Branson and Mehl (3) Hindeodella sp. (35) Lonchodina sp. (1) Ozarkodina sp. (1) *Palmatolepis gracilis Branson and Mehl (1) Polygnathus communis Branson and Mehl (27) *Polygnathus inomata Branson (12) *P. permarginata Branson (2) *P. symmetrica Branson (12) Prioniodina sp. (1) Prioniodina sp. (1) Pseudopolygnathus prima Branson and Mehl (12) *Siphonodella duplicata (Branson and Mehl) (10) *8. sp. (10) *Spathognathodus aculeatus (Branson and Mehl) (60) *S. anteposicornis Scott (3) *S. dispan'lis (Branson and Mehl) (3) S. aff. S. werneri Ziegler (54) S. sp. (6) Conodonts and fish remains are abundant in this sample, but most of them are broken and cannot be identified. The relative abundance of the species is not properly represented by the counts above. The interpretation of this collection is uncertain. A zone of large phosphate nodules at the base suggests slow deposition and lag concentration. The starred forms represent Late Devo- nian and Early Mississippian conodonts. They may have been reworked or several zones may be present in the basal 0.8 foot interval of the New Providence Shale Member. Inch by inch collecting would be necessary to prove or disprove this possibility. The youngest form present is Gnathodus antetexanus, which suggests that at least the upper part of the interval is equivalent to the upper part of the Rockford Limestone; and the presence of Spathognathodus anteposicornis suggests that the equivalent of the Louisiana Limestone is present. USGS 22792-PC, field N o. 3 of 5/11/65 Huddle, Branson, Sable, Peterson and Kepferle. 0.8—1.9 ft above the base of the New Providence Shale Member. Same locality as USGS 227 91-PC. Gnathodus texanus Roundy (15) Hindeodella sp. (22) 113 Polygnathus communis Branson and Mehl (3) Pn’oniodina acuta Branson (3) P. pulcher Branson (2) Pseudopolygnathus prima Branson and Mehl (3) *Siphonodella sp. (1 fragment) *Spathognathodus aculeatus (Branson and Mehl) (3) *8. cf. S. abnormis (Branson and Mehl) (6) *S. subrecta (Holmes) (1 weathered white) Cusp fragments, clear with no white matter (7) Gnathodus texanus has not been reported previously below the upper Burlington Limestone and first appears in the Bactrognathus—Taphrognathus zone, according to Rexroad and Scott (1964). Starred forms probably reworked. REFERENCES CITED Alvord, DC, 1971, Geologic map of the Hellier quadrangle, Kentucky- Virginia and parts of the Clintwood quadrangle, Pike County, Ken- tucky: U.S. Geologic Quadrangle Map GQ-950. Alvord, DC, and Miller, RC, 1972, Geologic map of the Elkhorn City quadrangle, Kentucky-Virginia and part of the Harmon quadrangle, Pike County, Kentucky: US. Geological Survey Geologic Quadrangle Map GQ-951. 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Geological Survey Geologic Quadrangle Map GQ—941. _1972, Geologic map of the New Amsterdam quadrangle, Kentucky-Indiana, and part of the Mauckport quadrangle, Ken- tucky: US. Geological Survey Geologic Quadrangle Map GQ-990. 1974, Geologic map of the Burna quadrangle, Livingston County, Kentucky: US. Geological Survey Geologic Quadrangle Map GQ-l 150. Amos, D.H., and Finch, W.I., 1968. Geologic map of the Calvert City quadrangle, Livingston and Marshall Counties, Kentucky: US Geological Survey Geologic Quadrangle Map GQ-731. Amos, D.H., and Hays, W.H., 1974, Geologic map of the Dycusburg quadrangle, western Kentucky: US. Geological Survey Geologic Quadrangle Map GQ-1149. Bassler, RS, 1932, The stratigraphy of the Central basin of Tennessee: Tennessee Division Geology Bulletin 38, 268 p. Baxter, J .W., 1960. Salem Limestone in southwestern Illinois: Illinois State Geological Survey Circular 284, 32 p. 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Earthquake-Induced Liquefaction Features in the Coastal Setting of South Carolina and in the Fluvial Setting of the New Madrid Seismic Zone By S.F. OBERMEIER, R.B. JAGOBSON, ].P. SMOOT, R.E. WEEMS, G.S. GOHN, ].E. MONROE, and BS. POWARS U.S. GEOLOGICAL SURVEY PROFESSIONAL PAPER 1504 UNITED STATES GOVERNMENT PRINTING OFFICE, WASHINGTON: 1990 DEPARTMENT OF THE INTERIOR MANUEL LUJAN, Jr., Secretary U.S. GEOLOGICAL SURVEY Dallas L. Peck, Director Any use of trade, product, or firm names in this ublication is for descriptive purposes onlyT and does not imply en orsement by the .S. Government Library of Congress Cataloging in Publication Data Earthquake-induced liquefaction features in the coastal setting of South Carolina and in the fluvial setting of the New Madrid seismic zone / by Stephen F. Obermeier [et 3.1.]. p. cm.——(U.S. Geological Survey professional paper ; 1504) Bibliography: p. Supt. of Docs. no. : I 19.16 : 1504 1. Geology—South Carolina—Atlantic Coast. 2. Geology—Missouri-New Madrid Region. 3. Soil liquefaction. 4. Geology. Structural. I. Obermeier, Stephen F. II. Series: Geological Survey professional paper ; 1504. QE162.A85E37 1990 557.57—dc20 89—600177 CIP For sale by the Books and Open-File Reports Section, US. Geological Survey, Federal Center, Box 25425, Denver, CO 80225 CONTENTS Page Page Abstract ............................................................................ 1 New Madrid Seismic Zone—Continued Introduction.. 1 Characteristics of and Criteria for Earthquake-Induced Coastal South Carolina ........................................................ 2 Liquefaction Features—Continued Regional Setting—Geology and Liquefaction Susceptibilityn 3 Fissures ............................................................ 26 Characteristics 0f and Criteria for Sand-Blow Formation ----- 4 Intruded Features .............................................. 27 Filled Sand-Blow Craters ......................................... 5 Features of Unknown or Nonearthquake Origin ............... 34 Vented-Sand Volcanoes ........................................... 8 Sand Boils ..................... 34 Featgres1 1Showmg Ev1dence of Lateral Spreads or Ground 11 Mima Mounds ................. 34 sc1 9. ions ........................................................... Regional Distribution of Sand Blows ........ 12 332d Structures .................................................... 35 . . . er Features ..................................................... 38 Other FOSSIL-’18 01191.15 """ """"""""" 13 Local Geologic Controls on Production of Vented Sand ...... 38 Features of Weathering Origin .................................... 14 T t t Thi kn 38 Overview of the South Carolina Liquefaction Study ......... 18 ops ra um , c ess """ Earthquake Ages ................................................... 19 Topstratum ”“9108? """" 38 Shaking Severity Estimation ____________ 19 Substratum Grain Size ............ : .......... ~ ..................... 3 9 Holocene Earthquake Shaking __________ 19 Resistance of Source Sand to Liquefactlon ................. 39 New Madrid Seismic Zone ............................................. 20 Overview Of Studies ........................................................... 39 Regional Geologic and Seismotectonic Setting ___________________ 22 Geologic Criteria ......................................................... 39 Characteristics of Quaternary Alluvium ..................... 23 Types of Earthquake Features ..................................... 40 Seismotectonic Setting ............................................ 24 Geologic Controls ......................................................... 4O Characteristics of and Criteria for Earthquake-Induced Suggestions for Future Research ................................. 41 Liquefaction Features ......................................... 24 Relevance of Liquefaction Features ...................................... 42 Vented-Sand Volcanoes .......................................... 24 References Cited ............................................................... 42 ILLUSTRATIONS [Plate in pocket] Page PLATE 1. Typical load structures produced by rapid sedimentation, observed in trench near Marked Tree, Arkansas .................. In pocket FIGURE 1. Map showing 1886 and older sand-blow sites ................................................................................................................ 2 2. Schematic cross section of representative barrier showing sediment types, ground-water table locations, filled sand-blow craters, and Bh soil horizons ................................................................................................................................ 4 3. Sketch and photograph of craters produced by the 1886 earthquake ................................................................................. 6 4. Schematic cross section of normal type of filled sand-blow crater. .................................................................................... 7 5. Ternary diagram showing grain sizes of paired samples at identical depths inside and outside liquefaction craters ................... 7 6. Schematic cross sections showing sand-filled fissures interpreted as resulting from liquefaction and flowage during the 1886 earthquake ................................................................................................................................................ 9 7. Schematic vertical section of representative vented-sand volcano ..................................................................................... 10 8. Photograph of vented-sand volcanoes that have coalesced to form a continuous sheet of sand on the ground surface ................. 11 9. Schematic cross section of filled sand-blow crater, illustrating aspects associable with downslope movement ........................... 12 10. Schematic cross section showing pedogenic tonguing of BE- and E-horizon sand into underlying B horizon and a graph showing particle-size data for a fractured pedogenic tongue ...................................................................................... 15 11. Sketch of cross section through a white, pedogenic sand tongue at site HW, near Hollywood, 8.0. ....................................... 16 12. Sketch of vertical section through BE’ horizon at site HW, near Hollywood, S.C. .............................................................. 18 13. Map showing late Quaternary alluvial deposits of St. Francis and Western Lowlands Basins ................................................ 21 14. Map showing area covered by vented sand, estimated epicenters of strongest 1811—12 earthquakes, and faults and fault zones.. 22 15. Schematic east-west cross section showing geologic and ground-water setting of St. Francis Basin ....................................... 23 16. Block diagram showing the configuration of the buried New Madrid Rift Complex ............................................................. 24 III IV 17. 18. 19. 20. 21. 23. 25. Table 1. CONTENTS Map of northern Mississippi Embayment showing earthquake epicenters, plutons, rift boundaries, and faults ......................... 25 Photograph showing stratigraphy of vented-sand volcano with organic-rich silt between two fining-upward sequences of sand 26 Photographs and line drawings of an “eruptive vent” that cut stratified deposits of a vented-sand volcano .............................. 27 Aerial photographs showing vented sand, interpreted as the product of liquefaction and flowage during the 1811—12 earthquakes ...................................................................................................................................................... 28 Photographs showing sand dikes and sills, interpreted as having originated by liquefaction and flowage during the 1811—12 earthquakes ........................................................................................................................................... 31 Sketch and photographs of section showing earthquake-induced intrusions in Holocene sediments and underlying Wisconsinan braided-stream sands observed in ditch about 15 km northwest of Marked Tree, Ark. ................................. 32 Aerial photograph of mima mounds in the northern part of St. Francis Basin ..................................................................... 36 Sketches showing pseudonodules formed in a shaking experiment by Keunen ................................................................ 37 Schematic drawing of the development of load-casted ripples, caused by ripple crests sinking into soft mud ....................... 37 TABLE Page Estimated relative susceptibility of saturated cohesionless sands to liquefaction during strong seismic shaking ........................... 4 EARTHQUAKE-INDUCED LIQUEF ACTION FEATURES IN THE COASTAL SETTING OF SOUTH CAROLINA AND IN THE FLUVIAL SETTING OF THE NEW MADRID SEISMIC ZONE By S.F. OBERMEIER,1 R.B.JACOBSON,1 J.P. SMOOT,l R.E. WEEMS,1 G.S. GOHN,1 ].E. MONROE,2 and BS. POWARS1 ABSTRACT Many types of liquefaction—related features (sand blows, fissures, lateral spreads, dikes, and sills) have been induced by earthquakes in coastal South Carolina and in the New Madrid seismic zone in the Central United States. In addition, abundant features of unknown and nonseismic origin are present. Geologic criteria for interpreting an earthquake origin in these areas are illustrated in practical applica- tions; these criteria can be used to determine the origin of liquefaction features in many other geographic and geologic settings. In both coastal South Carolina and the New Madrid seismic zone, the earthquake-induced liquefaction features generally originated in clean sand deposits that contain no or few intercalated silt- or clay—rich strata. The local geologic setting is a major influence on both develop- ment and surface expression of sand blows. Major factors controlling sand-blow formation include the thickness and physical properties of the deposits above the source sands, and these relationships are illustrated by comparing sand blows found in coastal South Carolina (in marine deposits) with sand blows found in the New Madrid seismic zone (in fluvial deposits). In coastal South Carolina, the surface stratum is typically a thin (about 1 m) soil that is weakly cemented with humate, and the sand blows are expressed as craters surrounded by a thin sheet of sand; in the New Madrid seismic zone the surface stratum generally is a clay-rich deposit ranging in thickness from 2 to 10 m, in which case sand blows characteristically are expressed as sand mounded above the original ground surface. Recognition of the various features described in this paper, and identification of the most probable origin for each, provides a set of important tools for understanding paleoseismicity in areas such as the Central and Eastern United States where faults are not exposed for study and strong seismic activity is infrequent. INTRODUCTION The near—surface and surface expressions of earthquake-induced liquefaction are highly dependent on the local geologic setting. This paper discusses the types of features, primarily sand blows, that formed on level or nearly level ground in two very different geologic set- Manuscript approved for publication April 20, 1989. 1U.S. Geological Survey, Reston, Va. 2U.S. Army Corps of Engineers, Memphis, Tenn. tings, one in which the parent sediments have a marine or near-marine origin (coastal South Carolina) and one in which the parent sediments have a fluvial origin (New Madrid seismic zone). The diverse types of sand blows and the equally diverse controls on their formation became apparent during field studies recently conducted to locate regions subjected to strong earthquake shaking, as indicated by the presence of liquefaction-induced features. In coastal South Carolina, field studies focused on sand blows of very late Pleistocene to Holocene age, as well as features caused by the 1886 Charleston earth- quake. In the New Madrid seismic zone, the search was largely restricted to sand blows caused by the 1811—12 earthquakes. In both areas, features of nonearthquake origin occur that might be confused with earthquake- induced features. Geologic criteria have been developed by which the earthquake-induced liquefaction features can usually be distinguished. (“Liquefaction” in this paper is defined as transformation of water-saturated sediments from the solid to liquid state as a consequence of increased pore pressure; this transformation indicates that grains are suspended by pore water. “Fluidization” is defined as the process of both suspension and transport of grains by pore water.) The scope of the paper includes both intruded features (for example, dikes and sills) and vented features (for example, sand blows). The term “sand blows” is used to indicate features formed where earthquake shaking causes liquefaction at depth followed by the venting of the liquefied sand and water to the surface. Features described as sand boils in this paper form in the absence of earthquake shaking and involve transport of sediment to the surface by artesian flow (springs). This distinction in terms is made because the processes within the ground that lead to development of earthquake-induced features differ from processes not related to earthquakes. Sand blows are thought to often form in response to liquefac— tion that is in turn followed by segregation of sand and 2 EARTHQUAKE-INDUCED LIQUEFACTION FEATURES IN SOUTH CAROLINA AND THE NEW MADRID SEISMIC ZONE water at depth, upward development of a vent, and finally the violent discharge of soil and water that soon diminishes to an ebbing flow (Scott and Zuckerman, 1973). (A slightly different model for some sand deposits is proposed in this paper.) In contrast, sand boils form by the downward development of a vent that typically does not enlarge violently and that continues to flow as long as high artesian pressure remains, commonly for days or years. This difference in development processes between sand boils and sand blows can often be distinguished in the field by use of techniques discussed in this paper. COASTAL SOUTH CAROLINA The strongest historic earthquake in the Southeastern United States took place in 1886 near Charleston, SC. Throughout much of the epicentral region, an area about 35 km wide and 50 km long, the Modified Mercalli intensity ranged from IX to X (Bollinger, 1977). The estimated body-wave magnitude (mb) was between 6.6 and 7.1 (Nuttli, 1983a). The potential for a future earth- quake having the strength of the 1886 earthquake is a major concern in engineering design in the Southeast. The concern is reinforced by a 300—year historical record of continuing weak seismic activity near Charleston. The source of the earthquakes in the Charleston area remains unknown, and seismotectonic hypotheses are widely disparate, despite many geologic, geophysical, and seis- mic studies during the past decade. No faults or fault systems have been identified that adequately explain the large 1886 Charleston earthquake or the other smaller, historic earthquakes that have occurred throughout much of South Carolina (Hays and Gori, 1983; Dewey, 1985; Science News, 1986). Because direct evidence of seismotectonic conditions is lacking and because the historic earthquake record is too limited to provide a dependable basis for estimating the frequency of moder— ate to strong earthquakes, we undertook a search for pre-1886 sand blows. Results of the search are shown on figure 1. Figure 1 shows the approximate boundary of the 1886 Charleston earthquake meizoseismal zone; the sites conspicuous in 1886 for development of many sand blows, described as “craterlets” by Dutton (1889); and the sites of pre-1886 sand blows that we discovered. The unshaded portion of figure 1 encompasses the area that was searched for sand blows. Radiocarbon ages of sand-blow materials at site HW show that at least three pre-1886 Holocene earth- quakes have produced sand blows in that area (Weems and others, 1986). It is not yet known how many earth- quakes are represented by the sand blows at the widely scattered sites on figure 1, nor are the seismic source zones known for these prehistoric sand blows. What is known is that the prehistoric sand blows extend far beyond the limits of 1886 sand blows (see fig. 1) in 34° 79° — — — Approximate boundary of 1886 meizoseismal zone (Bollinger, 1977) = Areas conspicuous in 1886 for craters (Dutton, 1889) ' Pre-1886 sand-blow site designation (this study) X Outer limit of historically documented 1886 sand blows (Georgetown) LOCATION OF STUDY AREA 0 30 MILES 0 30 KILOMETEHS FIGURE 1. —1886 and older sand-blow sites. Unshaded onshore region is predominantly of marine sediments younger than about 240,000 years. Shading pattern denotes region of older marine sediments that was not reconnoitered. Younger fluvial sediments occur locally. All sand-blow sites in the region with no shading are in marine- related deposits, and all sites in region with shading are in fluvial deposits. Numerous sites discovered in and near the 1886 meizoseis- mal zone are not shown because of lack of space. Abbreviations adjacent to sand-blow sites are specific site designations. sediments having approximately the same liquefaction susceptibility (Obermeier and others, 1986; unpublished data) and that the strongest Holocene shaking has prob- ably been near Charleston (Obermeier and others, 1989). All the pre-1886 sand blows that we found have no expression on the ground surface that is discernible by onsite examination or on aerial photographs. The sand— blows are seen only where exposed in walls of excava- tions at least 1.5 m deep, typically in drainage ditches COASTAL SOUTH CAROLINA 3 and borrow pits. At most sites shown on figure 1, at least three or four sand blows are exposed within a few hundred meters of one another. The following section focuses on the geologic setting in which these sand blows originated. REGIONAL SETTING—GEOLOGY AND LIQUEFACTION SUSCEPTIBILITY In South Carolina, the coastal region is known locally as the “low country” because it has low local relief (1—3 m) and low elevation (0—30 m) and because vast expanses of swamp and marshland are under water much of the year. Most of the Carolina low country is covered by a 5- to 10—m—thick blanket of unconsolidated Quaternary marine and fluvial deposits, which lies on semilithified Tertiary sediments (McCartan and others, 1984). The Quaternary sediments primarily occur as a series of six well-defined, temporally discrete, interglacial beaches and associated back barrier and shelf deposits that form belts subparallel to the present shoreline. The oldest beach deposits are farthest inland and are at the highest altitudes; younger beach deposits are progressively closer to the ocean and are at successively lower alti- tudes. Most beach deposits are 8 to 15 m thick. Cutting across these marine and marginal-marine deposits at nearly right angles are four major rivers, the Savannah, Edisto, Santee, and Pee Dee (fig. 1). Border- ing these rivers are fluvial terrace sediments of rather limited extent that consist almost exclusively of clean sand (that is, sand without clay, silt, or gravel). Figure 1 shows the approximate areal extent of the marine-related deposits (beach, shelf, and open-sound back barrier) designated as Q1, Q2, and Q3 by McCartan and others (1984). The part of figure 1 containing units Q1, Q2, and Q3 is shown Without shading. Q3 deposits are about 200,000 to 240,000 years old (Szabo, 1985) and are present as far as 20 to 40 km inland from the modern coast. The intervening Q2 deposits are about 80,000 to 130,000 years old (Szabo, 1985). Unit Q1 is closest to the ocean and is made of younger deposits. The search for sand blows was generally restricted to units Q2 and Q3. Older units have such a low susceptibility to liquefaction (due to effects of chemical weathering) that the likelihood of forming sand blows has been extremely low during the late Pleistocene and Holocene. Because unit Q1 generally has such a high ground-water table, the possibility of ‘ finding exposed sand blows was quite limited. Formation of sand blows in any geologic setting depends primarily on the depth to the water table, the properties and thickness of materials in the depth range susceptible to liquefaction during shaking, and the thick- ness and characteristics of sediments above the zone that was liquefied during shaking. Specific relations between liquefaction susceptibility and subsequent formation of sand blows in the South Carolina low country are as follows: (1) A water table very close to the ground surface usually greatly increases the susceptibility to liquefac- tion, even in comparison with a water table at depths of only 3 to 4 m. The modern water-table depth is generally 0 to 1.5 m throughout the low country and is typically a subdued mimic of the surface topography. The water table is deepest under hilltops and may come to the surface in swales. As surface elevations decrease toward the ocean, the water table is generally nearer the sur- face; within 15 km of the ocean, the water table is rarely deeper than 1.5 to 2 m. (2) Clean sands are generally the only materials observed to have liquefied in the Charleston region. At one site (site SAN, fig. 1) the source sand bed contains as much as 3 to 5 percent clay; typically there is less than 1 percent silt and clay at all other sites. The liquefied sands are generally fine-grained, well-sorted (that is, uni- formly graded) beach sands. Principal properties of sand that control liquefaction susceptibility during shaking are degree of compaction or state of compactness (known as “relative density” by geotechnical engineers), sand-grain size and sorting, and cementation of the sand at grain-to-grain contacts. The state of compactness is commonly a reflection of the energy (or mode) of deposition. To illustrate, beach deposits laid down in a high-energy environment such as a pounding surf zone are generally more dense than sand deposited in a quiet zone away from the influence of the surf. Higher density makes the surf-zone deposits more difficult to liquefy. Locally within the surf zone, though, there are many regions of low-energy deposition where the sand is not so compacted by wave pounding. In addition, for a given relative density, the fine-grained, well-sorted sands of ancient and modern beaches throughout the low country are much more susceptible to liquefaction than standard sands used for engineering analysis (Cullen, 1985), and this increased susceptibility due to grain-size effects and lower local compactness must account in part for the widespread liquefaction during the 1886 earthquake. Cementation in near-surface subaerial environments is chiefly a reflection of the age of the deposit. Even slight cementation by agents such as silica, calcite, or clay dramatically reduces liquefaction susceptibility; thus liq- uefaction potential is related to age of deposits in many geologic settings (Youd and Perkins, 1978), and this relation is particularly apparent in the low country. Table 1 lists deposits in the low country shown in figure 1 in terms of depositional environment (type of deposit) and age and provides an estimate of their relative susceptibilities to liquefaction during strong seismic shaking. 4 EARTHQUAKE-INDUCED LIQUEFACTION FEATURES IN SOUTH CAROLINA AND THE NEW MADRID SEISMIC ZONE Near-shore deposit . . - of shelly, silty, . . ~ and clayey sand SE NW I4 L] I‘ 200—500 m r] /Water table Filled sand-blow craters Water table 2‘5 m /atsurface V _—_'i ,_T _ _IT _ . _ . agoonal deposi _- agoona .-_ _ - ~ '- g : -: . _, : ..,.—..—:of clay:~ :deposit_ —_ _ uBnaiiolrenri-lgarigeegcs’snd Black, Bh soil horizon' ' — Semilithified Tertiary marl FIGURE 2. ——Schematic cross section of representative barrier showing sediment types, ground-water table locations, filled sand-blow craters, and Bh (humate—rich) soil horizons. Modern shoreline is located southeastward. Lagoonal clay deposit at left is younger and lower in elevation than the barrier-bar deposit. Features large enough to be interpreted as possibly having an earthquake origin in the low country were found only in sand deposits having a total thickness exceeding 2 to 3 m; within this 2— to 3-m—thick deposit, the thinnest individual source stratum was 0.3 m. (3) The local geologic setting has a major role in the formation of earthquake-induced sand blows. The geo- logic setting most frequently associated with sand blows is the crest or flank of Pleistocene beach ridges, where a thin surficial cover of a clay-bearing sand or humate-rich sand overlies clean sand. According to first-hand obser- vations of effects of the 1886 earthquake by Earl Sloan, “these craterlets are found in greatest abundance in belts parallel with (beach) ridges and along their anticlines” (Peters and Herrmann, 1986, p. 68). A schematic cross section through a typical low-country beach ridge, such as the ridges described by Sloan, is presented in figure 2. To a much lesser extent, sand blows have been found in back-barrier environments. A thin clay—bearing stratum (or other stratum having very low permeability) above the liquefied zone is gen- erally an important control on development of sand blows (Scott and Zuckerman, 1973; Obermeier, 1988; Ishihara, 1985). A veneer of nonliquefiable sediment, 1 to 2 m thick, aids greatly in the formation of and recognition of sand blows in the low country. On the other hand, a clay-bearing or other low-permeability stratum thicker than 4 to 5 m prevents sand—blow formation at the great majority of sites in the low country; a thickness greater than 2 to 3 m seriously impedes such formation. CHARACTERISTICS OF AND CRITERIA FOR SAND-BLOW FORMATION Two kinds of pre—1886 sand blows have been recog- nized: (1) filled sand-blow craters (craterlets) and associ- ated sedimentary structures and (2) sand volcanoes that have vented to the surface, leaving relict sand mounds. The crater-type sand blows generally occur only where a surficial soil having less than several percent clay has formed on a parent material of clean sand. Where the surficial soil is richer in clay, vented-sand volcanoes are much more likely to form. Exact locations were not known for 1886 craterlet sand blows when our study was initiated in 1983. Only one 1886 vented type of sand volcano had been discovered and examined (Cox, 1984). Thus it has been necessary to locate sedimentary features that display structures con- sistent with an earthquake origin and to develop criteria for interpreting whether or not these features have an earthquake origin. TABLE 1.— Estimated relative susceptibility of saturated cohesionless sands to liquefaction during strong seismic shaking [Sourcez Youd and Perkins (1978). Strong seismic shaking is deter- mined by two parameters, peak horizontal acceleration and duration of largest acceleration. For a mb=5 earthquake, strong seismic shaking is defined as an acceleration of about 0.2 g for at least several seconds; for a stronger earthquake, the threshold acceleration is about 0.15 g for a duration of 10 seconds; for a much stronger and longer duration earthquake, the threshold acceleration can be less than 0.1 g (T.L. Youd, Brigham Young University, oral commun., 1985)] Liquefaction susceptibility for deposits of various ages Types of deposit <500 findizl; yr Pleistocene Pre-Pleistocene Dunes .......... High Moderate Low Very low Beach (low wave energy ........ High Moderate Low Very low Foreshore ....... High Moderate Low Very low Beach (high wave energy) ........ Moderate Low Very low Very low River channel. . . . Very high High Low Very low Flood plain ...... High Moderate Low Very low COASTAL SOUTH CAROLINA 5 Geologic criteria that we have developed for interpret- ing whether near-surface features are earthquake— induced sand blows generally have four elements: 1. The features have sedimentary characteristics that are consistent with an earthquake—induced liquefaction origin; that is, there is evidence of an upward-directed, strong hydraulic force that was suddenly applied and was of short duration. 2. Characteristics such as shape, width, and depth are consistent with historical observations of liquefaction during the 1886 earthquake. 3. The features are in ground-water settings where a suddenly applied, strong hydraulic force of short dura- tion could not be reasonably expected except from earthquake-induced liquefaction. In particular, these settings are extremely unlikely sites for artesian springs. 4. Similar features occur at multiple locations, prefer- ably within a few kilometers of one another, having similar geologic and ground-water settings. Where evi- dence of age is present, it should support the interpre- tation that the features formed in one or more discrete, short episodes that individually affected a large area and the episodes were separated by long time periods during which no such features formed. As fewer of these criteria are satisfied, the confidence in an earthquake origin generally diminishes. Subse- quent sections describe the application of the four crite- ria. Whether earthquakes or other mechanisms induce small liquefaction-flowage features is often impossible to determine. Small synsedimentary liquefaction-flowage features such as dikes and sills as much as 0.25 to 0.5 m long and a few centimeters thick are not unusual in point—bar deposits and in beach surf zones. Very small features similar to sand blows are also common in beach surf zones. These small features result from a variety of forces, including dynamic wave loadings and static slumping. An earthquake origin was considered a possi- ble mechanism in this study only if the flowage features were much larger than these small features and if, in addition, the flowage features cut the surface soil profile. FILLED SAND-BLOW CRATERS All filled sand-blow craters belong to a single morpho- logic group having many common features in the fill sediments, although systematically occurring variants also occur. The normal type of filled sand-blow crater is discussed first. In a later section there is discussion of two variants that may indicate association with earthquake-induced landslides. Almost all pre-1886 sand-blow sites shown on figure 1 have sand blows whose original morphology and size are comparable to the 1886 craters described by Dutton (1889), except that the craters are now filled with sediment. Figure 3 shows craters that represent moderate- to large-sized craters produced by the 1886 earthquake. A crater is a hole at the ground surface that forms as liquefied sand vents to the surface. In the process, the forceful upward surging of sand and water also scours and enlarges a hole and deposits sediment beyond the crater. When flowage stops, a surficial sheet of ejected sand and soil surrounds the rim of the crater, and clasts of dark soil are commonly scattered along the base of the steep wall (fig. 3). Examination of photo- graphs shows that, in 1886, the surficial sheets commonly appear to have had thicknesses near crater rims of about 15 to 20 cm and maximum diameters rarely exceeding about 3 to 4 m. The maximum reported thickness of vented sand was 1 m, and the maximum crater diameter was about 6 m (Dutton, 1889). About 75 percent of the sites on figure 1 are on barrier and nearshore marine sands. The sands are almost exclusively well-sorted, fine— to medium-grained quartz, with less than 5 percent heavy minerals and mica (McCartan and others, 1984; Gelinas, 1986). Surface weathering has imposed a soil profile on these marine— related sands. The soils are classified as spodosols, alfisols, and ultisols, but most sand blows occur in poorly drained areas where humic spodosols (humods) have formed. Humods are characterized by a thin (<10- to 15-cm) surficial A horizon (organic matter and several percent sand) overlying a thin (<10- to 15-cm), very light gray E horizon; the E horizon overlies a thick (0.5- to 1.5-m) black Bh horizon (humate-enriched sand contain- ing a few percent clay) and a variably thick (0. 1- to 1-m), gray to light-yellow B—C horizon (transition zone between B and C horizons). The B—C grades down into C-horizon sands (parent material), which are very light gray in the upper 1 to 2 m and grade down to a greenish hue. Beneath the upper 0.5 to 1 m of the C horizon, the original bedding consists of thin, horizontal, black heavy— mineral laminae about 0.25 to 0.5 cm apart. The sand- blow features cut the solum and the C horizon. The source sand beds that liquefied during earthquake shak— ing generally occur within the depth range of 3 to 10 m. Figure 4 is a vertical section of a filled sand-blow crater that is representative of the type observed at almost all of our study sites (fig. 1). The figure illustrates characteristics that we consider to be compatible with an earthquake-induced liquefaction origin. In figure 4, the soil horizon is cut by an irregular crater, which is filled with stratified to structureless (that is, nonstratified) and graded sediments. The fill materials are fine- to medium-grained sand and clasts from the Bh, B—C, and C soil horizons and sand from depths much below the exposed C horizon. Walls of the crater are generally 6 EARTHQUAKE-INDUCED LIQUEFACTION FEATURES IN SOUTH CAROLINA AND THE NEW MADRID SEISMIC ZONE FIGURE 3. —Craters produced by the 1886 earthquake. A, Sketch from a photograph of an 1886 crater (sand blow at Ten Mile Hill, near the present Charleston airport). Note that the crater contains sand sloughing toward the lowest parts and that there is a constructional sand volcano located in the right part of the crater (at arrow). The smooth and sharp when viewed up close, especially in the lower part of the crater. Walls of some craters are very jagged, however. The Bh horizon generally is much thinner over the central part of the filled crater than on the sides, and the Bh horizon of the laterally adjoining undisturbed soil is abruptly thicker. Clay content in the Bh horizon in the crater is much less than in the undisturbed soil. Figure 5 is a sand-silt-clay ternary diagram of particle sizes of pairs of samples taken at identical depths inside and outside the liquefaction craters. The lines connecting pairs of samples show that crater samples have consis- tently less clay and silt than the adjacent undisturbed soil. The Bh horizon on the filled crater typically is thicker, is more clay rich, and has better developed soil structure (that is, peds) with increasing age; craters older than about 5,000 to 10,000 years have Bh horizons that approach the thickness and development of those in laterally adjacent undisturbed soils. A sequence of five layers, each having specific charac- teristics, occurs beneath the Bh horizon in the filled crater. The sedimentary characteristics of these layers are less distinct in older craters because of pedogenesis in the crater deposits. Layer 5 (fig. 4) is a structureless (that is, massive), gray, humate-stained sand, which overlies a thinly (2- to 3-mm) laminated sequence of alternating light- and dark-colored sands (layer 4). The lamina typically are discontinuous and irregular in thick- ness, as illustrated in figure 4. The dark color is generally crater is surrounded by a thin blanket of sand partly veneered with cracked mud. B, Photograph of typical crater produced by the 1886 earthquake. Note the thin blanket of ejected sand around the crater and sand and clasts of dark soil within the crater. (Photograph from the archives of the Charleston museum.) imparted by humate staining; the dark lamina may contain appreciable amounts of silt and clay. The basal bed of this sequence (layer 4) is clay-rich in perhaps 10 percent of the filled craters and is rarely thicker than 1 cm. The basal bed sharply overlies a medium-gray struc- tureless sand (layer 3). Layer 3 contains many small clasts (1- to 5—mm diameter) of Bh material, charcoal, and wood. This clast-rich layer grades down into a structure- less sand zone (layer 2) containing many intermediate- sized clasts (5— to 20-mm diameter) of friable Bh material and occasional extremely friable clasts of light-colored sand. The clasts of Bh material and sand have, respec- tively, the same color, mineralogy, consistency (that is, resistance to being crushed between fingers), and fria- bility as the adjoining sands of the B—C and C horizons. Layer 2 grades down into layer 1, containing densely packed intermediate-sized (1—5 cm) and large-sized (>5 cm) clasts of Bh material in a structureless sand matrix; the large clasts have diameters exceeding 25 cm in many filled craters. Many of the clasts in layer 1 have their long axes vertically oriented. At and below the thinly strati- fied sequence (layer 4), the sides of the bowl are sharply defined by a color boundary and by the presence of clasts within the bowl. Beneath the bowl are vents containing structureless clean sand. Sides of the vents sharply cut bedding in the C horizon. The matrix sand in layers 1 through 3 contains an extremely small percent of clay-sized material and clay COASTAL SOUTH CAROLINA Bh / Layer 4: / . _ . Layers: structureless san'd ‘ Bedded sequence Undlsturbed -.~' .' ,- -- .- “ : _- -l\/ ofalternatmg clean soil ' ‘ ,'~_'.'Vand organic-matter- / -_ 1, rich sand' Layer 3: Sand and I many small clasts '- .' .~"'-’\.I¢‘-'.1'\..;.’r .. . .4.“ 5 :T:: L‘ 7‘% B—C . .3 '. .' -' Layer 2: Sand and scattered-'2 T472“ - :'_‘_—_—._'_ x ‘ E g clasts of clean C-horizon sand and . . D. B—C —:—:~::—:—::—:{ rrr QAchh were, - 949mm :—_'_—_—_*T—_—3 W8” ' - ' ‘ ‘ (7. :3 H; w _ , _ C _____ _\ ~ ' ~ ' ' ‘ rLayer 1: Sand and large clast57:::'_ __ .fi —:of Bh_horizon material _:__—,_—:__—_—__‘ ND VERTICAL EXAGGERATIDN FIGURE 4. —-Schematic cross section of normal type of filled sand-blow crater. Letters correspond to soil horizon designations. The filled crater in this figure much predates the 1886 earthquake, based on thickness of Bh horizon in the filled crater. 10%5‘“ minerals. Both the percent of clay minerals and percent of clay- and silt-sized material in layers 1 through 3 are much less than in the laterally adjoining undisturbed B—C and C horizons, particularly for craters formed less than a few thousand years ago (Gelinas, 1986). The maximum grain size of the matrix sand in layers 1 through 3 is greater than in the laterally adjoining and overlying undisturbed materials in some filled craters. The following phases have been interpreted in the formation of the filled sand-blow craters: (1) after earthquake-induced liquefaction at depth, a large hole is excavated at the surface by the violent upward discharge of the liquefied mixture of sand and water; (2) a sand rim accumulates around the hole by continued expulsion of liquefied sand and water after the violent discharge; (3) sand, soil clasts, and water are churned in the lower part of the bowl, followed by settling of the larger clasts and formation of the graded-fill sequence of sediments; and 100% sand 0% silt 10% clay o undisturbed soils 0 liquefaction features FIGURE 5. —Ternary diagram showing grain sizes of paired samples at identical depths inside and outside liquefaction craters. (4) the crater is intermittently filled by adjacent surface materials to form the thin stratified-fill sequence, during the weeks to years after the eruption. In the craters 8 EARTHQUAKE-INDUCED LIQUEFACTION FEATURES IN SOUTH CAROLINA AND THE NEW MADRID SEISMIC ZONE predating the 1886 earthquake, the sand blanket ejected from the crater is indistinguishable in the field from the surface and near-surface (A, E, and Bh) soil horizons, because the blanket has been incorporated within these soil horizons. This interpretation of origin of the filled craters is based in part on comparison with photographs and descriptions of 1886 craters. The filled craters are similar to the 1886 craters shown in figure 3 in that the dimen- sions (diameters) at the surface are about the same and the depths to the contact of the stratified fill to the graded fill (see fig. 4) are about the same. The lowermost stratified layers of filled craters (layer 4) are composed of humate-stained, slightly clayey or clean sand that gen— erally contains a few clasts of Bh horizon material and, in a few filled craters, clasts of C horizon sand. (See fig. 4.) Presence of the intact very weak, friable clasts of C horizon sand suggests very rapid initial infilling of the crater, as illustrated in figure 3B. In the filled craters, clasts of C—horizon material first must have been ejected onto the adjacent ground surface or walls of the crater before falling back or washing back into the bottom of the crater and being deposited within the beds of layer 4. We know of no other reasonable explanation of the means by which these clasts could have been transported to the stratified zone. The presence of friable, angular clasts of C- and Bh-horizon material in the graded-fill portion is consis- tent with a short—lived, churning type of upwelling from the vent. Water commonly flows for a day or so from earthquake-induced sand blows. The violent, boiling phase is much shorter in duration. Hence, the presence of friable clasts argues against a long-term artesian spring origin for these features; a spring-induced long- term churning phase, lasting days, that slowly dimin- ishes in flow would abrade, round, and (or) disintegrate the clasts of Bh- and C—horizon material. Short-term, nonearthquake-related springs have been eliminated as a possible mechanism by Which craters are formed along the crest of the beach ridges, because such springs cannot form in this topographic-geologic setting. (This point is discussed in detail later.) Our interpretation of the origin of the craters is also supported by the presence of sand-filled tabular frac- tures, whose overall shape and dimensions strongly suggest that they are “incipient craters.” These fractures are rather common at some places in the meizoseismal zone of the 1886 earthquake, where craters are plentiful. Figure 6 shows V- and U-shaped fractures (fig. 6A also shows a connecting vent) that are filled with sand we believe was transported upward from depth, on the basis of the freshness of minerals in the fractures. The frac- tures, which are tabular, generally widen with depth until they connect to a single, near-vertical large sand- filled fissure (that is, a vent). The sand-filled fractures probably represent the early phase of development of craters; for the features in figure 6, however, the upward forces were too weak to excavate the overlying material. It is possible that liquefaction led to the production of craterlets because of a fortuitous combination of sedi- ment properties in and above the zone that liquefied during earthquake shaking. The source beds that lique- fied were exceptionally susceptible of liquefaction, in that generally they were very loose (engineering sense), fine-grained, uniformly sized, and free of clay (Dickenson and others, 1988); these properties would cause the source beds to liquefy abruptly and, once liquefied, to flow readily (Seed and others, 1983; Youd, 1973). We suspect that the liquefied sand strata suddenly applied a large point force to the overlying sediment (through a hole or weak zone such as that left by a decayed root), causing a V— or U—shaped crack to form, through which the liquefied sand violently vented because of its excep- tional ability to flow. The V— and U-shaped cracks occurred because overlying sediment is humate ce- mented, has no pronounced planes of weakness, and is very brittle; the process is similar to formation conchoi- dal fracture in an isotropic, brittle medium, caused by the application of a point load. In summary, the filled craters that we found have a morphology that is consistent with descriptions and photographs of craters caused by the 1886 earthquake. The general geologic setting (Pleistocene beach crests and flanks) and the locations of swarms of sand blows reported by geologists immediately after the 1886 earth- quake (Peters and Herrmann, 1986) are very near or coincident With two sand-blow sites found during this study (HW and ARP on fig. 1). The morphology of the walls of the craters, the stratigraphy of the fill of the craters, and the evidence that they formed in relatively sudden, discrete episodes serve to demonstrate that the filled craters are the result of earthquake-induced lique- faction. Alternate origins, such as short- or long-term artesian springs, ocean wave pounding, thrown trees, or other mechanisms that have the potential to create similar features are discussed in detail in the section entitled “Other Possible Origins.” VENTED-SAND VOLCANOES Figure 7 is a schematic cross section of a pre-1886 vented-sand volcano. Where the zone that liquefied at depth is overlain by a thick clay-rich stratum, a sand blow typically is expressed on the ground surface as a mound of sand. The thickest part of the mound ranges from a few centimeters to as much as 0.25 m. At a few COASTAL SOUTH CAROLINA I:- Shovel / Pre-1886-filled sand-blow crater BANK OVERHANG fissur/ ~ / B—C - § /;C:'_—.'___ \A _ ./:—.ZZ£—Z— 0 20 INCHES FLOOR OF DITCH 0 30 CENTIMETERS A ND VERTICAL EXAGGERATION BANK OVERHANG /Brownish—black, massive Bh-horizon sand Sand-filled fissure Sand-filled fissure ' bot : _: .-——@ fl ' —+»+ ——~—'_Ac|astsof 20 INCHES B FLOOR 0F DITCH o 30 CENTIMETEHS N0 VERTICAL EXAGGERATION FIGURE 6. —Schematic cross sections showing sand-filled fissures interpreted as resulting from liquefaction and flowage during the 1886 earthquake. Light-yellow, intruded sand in fissures is determined to have been vented from a depth of 6 m, on the basis of grain—size and mineralogical data. A, V-shaped sand-filled fissure and vent. Fissure cuts soil horizon developed on pre-1886 filled sand-blow crater. B, U-shaped sand-filled fissure. 10 EARTHQUAKE-INDUCED LIQUEFACTION FEATURES IN SOUTH CAROLINA AND THE NEW MADRID SEISMIC ZONE ______1___#__ :Clasts of clay-bearing stratum _ :maximum depthE _ to unweathered : clean sand in vent: mime—athe—refilgn ;n_d—::: "t —_—to highly weathered :: ' EOE-Leamgfini—E} _ _ _ _ 7 A : — Eynweathe'eEZ—EEEEEEEi —_—_—_ clean sand,_—_—_:—;—__—_—_—_: 7 :structureless:—_ :_ # _—_—_ __ FIGURE 7. —Schematic vertical section of representative vented-sand volcano. localities, mounds have discernible bedding. The mounds are generally thickest above their junctions With the widest steeply dipping sand-filled dikes (that is, feeder vents) that extend downward through the clay-bearing stratum. Often the sand in the mound and in the dikes contains clasts of the clay-bearing stratum that have been torn from the walls of the vent. The sand in the dikes is structureless and has no discernible bedding; the sand in the central parts of the dikes may be better sorted and coarser than that near the edges. Dike widths range from about 0.25 to 1 In. An 1886 sand blow of this type was described by Cox (1984). Similar sand blows have been observed at many places around the world, including the New Madrid seismic zone (to be discussed later). Figure 8 shows a variant of this type of sand blow, in which the vented sand has coalesced into a continuous surface cover; some of the white surface sand is pedogenic E horizon, which is virtually indistinguishable from the older, vented sand. The volume of fluidized sand expelled to the surface has been so large at some places that the clay-bearing stratum has downdropped noticeably. At the site shown in figure 8, for example, comparison of soil structure and clay content of the undisturbed soil with the clay—bearing stratum above the hand shovel showed that the stratum above the hand shovel had been down- dropped about 1 m. Near-surface sediments in the depth range of 1.5 to 2 m are commonly so intensely weathered and discolored that textural analysis is required to determine a possible origin by venting. A useful (but not sufficient) test for venting is comparison of the coarsest sand fraction in the suspected vent With the grain size of sand in the laterally adjoining clay-bearing stratum or soil horizon. An earth- quake origin for the sand is not considered likely unless the coarsest sand in the dike is significantly different in size from that in the crosscut clay-bearing stratum. Such a textural difference cannot be the result of soil—forming processes. In addition, there must be no possibility that the coarsest sand fraction has been introduced from above the vent. At three vented-sand volcano sites shown on figure 1 (sites CH, BR, and SAN) that have been interpreted as earthquake induced, other evidence of venting is also present. Examples include clay-bearing clasts in the sand mound combined with sand—filled sills and dikes that Widen downward and, at depth, extend into slightly weathered and unweathered sediments. At some places, the sand-filled dikes and sills cut through ground that appears to have been shattered (that is, irregularly, intensively fractured and intruded), which is very suggestive of forceful intrusion. Features similar to the vented-sand volcanoes, but for which springs or other nonearthquake sources cannot be easily eliminated as possible origins, are common in COASTAL SOUTH CAROLINA 11 FIGURE 8. ——Vented-sand volcanoes that have coalesced to form a continuous sheet of sand on the ground surface. At least two episodes of venting separated by long periods of time are represented. Note irregular pattern of fracturing. (Shovel is 60 cm long.) many lowland areas. These sites have not been included on figure 1. FEATURES SHOWING EVIDENCE OF LATERAL SPREADS OR GROUND OSCILLATIONS Lateral spreads3 were commonplace features of the 1886 earthquake (Peters and Herrmann, 1986). Most of these spreads developed in fluvial terrace deposits, bor- dering streams in low areas. Obvious surface evidence of lateral spreads has not persisted to the present, and ditches and pits are so rare in the wet locales where lateral spreads formed that none has been found. How— ever, along the flanks of some Pleistocene beaches, reverse shears are present that may indicate an incipient formation of lateral spreads or ground oscillations. Shear displacements commonly range from 1 to 4 cm. Slope of the ground surface is typically less than 1 percent for hundreds of meters downslope or upslope. These slopes are so gentle and the possibility of high artesian pres- sures is so remote that gravity-induced slumping is virtually impossible. Some of these reverse shears almost certainly have an origin in earthquake-induced liquefaction. At one site, for example, reverse shears 3A lateral spread is a landslide formed by a laterally moving slab, commonly of large areal extent; earthquake-induced lateral spreads commonly form where surface slopes range between 0.5 and 5 percent (Youd, 1978). The presence of lateral spreads generally indicates a large areal extent of liquefied material. dipping in opposite directions (toward one another) formed about 10 m apart in the stratum that liquefied during shaking, and sand blows traceable to this liquefied stratum formed between the shears; the most likely mechanism that could have formed the opposite facing shears was alternating directions of ground movement, caused by earthquake oscillations, in the liquefieWa— tum. (Such a mechanism is illustrated as fig. 2—11‘in “Liquefaction of Soils during Earthquakes,” published by the National Academy Press, Washington, DC, in 1985.) v Reverse shears can occur as isolated features but ar generally found in association with sand blows. Figure 9 shows the typical relationship for filled craters. A reverse shear is present on the downslope side of the crater, and the upthrown block cuts the C, B—C, and Bh horizons. The shear formed prior to venting of sand from the source stratum at depth, because the vent is not cut or distorted. At some sites, the shears along crater edges could have formed only in response to earthquake-induced lateral spread movement because the shears are trace- able into and along the bedding of the stratum that liquefied. Only rarely is an exposure deep enough to allow determination of whether the shear goes into a stratum that liquefied, and thus an earthquake origin cannot be confidently assigned to all sites. However, we are of the opinion that these reverse shears along crater edges suggest an earthquake origin, even Where the 12 EARTHQUAKE-INDUCED LIQUEFACTION FEATURES IN SOUTH CAROLINA AND THE NEW MADRID SEISMIC ZONE Ground surface \ 7:? \\m\ Bh or anic-matter-rich sand /,3_' Undisturbed Layer 3: Sand and many small clasts I '. j scattered N0 VERTICAL EXAGGERATION Liam Si .Strliétureleé$ sand 55 ‘ :IL'ayéEz'; Saha' aha _'clean sand and 5 I; 3'. Bil-horizon materialf j' . :Ej/entsonaim 6%} 4—— Downslope (0.5—2 percent) Undisturbed /////°/ 1 Layer 4: Bedded sequence 1/ of alternating clean and _ _"__ __ _'_‘__, ; _/\c<)rgan|c-matter-r|ch sand ragga W/flfi/j '” 5/! z crater wall clasts of .3 5Q @Q -__ @: :iafi 1—2 SEid'and IaTgeFaEtE: .' {#:of Bh-horizon materialii—L FIGURE 9. —Schematic cross section of filled sand—blow crater, illustrating aspects possibly associable with downslope movement. A reverse shear soil is along the lower left side of the filled crater; an underturned edge forms the lower right part of the filled crater beneath the B—C and C soil horizons; large clasts along the right side are much higher than in other soil parts of the filled crater. shears have formed on gently sloping ground (less than 2 percent) as much as 5 m below the beach crest. Another aspect of filled craters that possibly indicates an incipient lateral spread is also illustrated by the position of the clasts along the right side of the crater of figure 9. Large clasts occupy the region from the vent to the vicinity of the bedded sequence (layer 4). The lower part of this clast zone turns beneath the B—C and C horizons. These clast relations are found in perhaps 25 to 50 percent of craters having reverse shears. The consis- tent positional relationship of underturned edge with clasts along the crater edge suggests control by minor downslope movement, which took place while the sedi- ments in the crater were still fluid enough to segregate slightly. REGIONAL DISTRIBUTION OF SAND BLOWS The regional distribution of sand blows is systematic and predictable in coastal South Carolina, in terms of size and number of sand blows. This distribution conforms with the pattern that would be anticipated from an earthquake origin. Numerous worldwide observations show that the num- ber, size, and type of earthquake-induced liquefaction features are a reflection of three principal factors. Of primary importance are (1) severity of shaking (con- trolled by earthquake accelerations and duration (Seed and Idriss, 1982)), (2) liquefaction susceptibility (con- trolled largely by state of compactness and cementation (Youd and Perkins (1978)), and (3) local geologic controls (affected primarily by depth to water table, thickness of impermeable sediments above liquefied stratum, defor— mation properties, permeability of sediments above liq- uefied stratum, and permeability of liquefied stratum (Ishihara, 1985; Obermeier, 1989; Obermeier and others, 1986)). The local geologic controls on the Pleistocene beaches in coastal South Carolina are constrained within a very narrow range because (1) bedrock accelerations should have been amplified about the same amount at many places by previous earthquakes, (2) the liquefac- tion susceptibility of the source sand beds has been about the same, and (3) local geologic controls on morphology COASTAL SOUTH CAROLINA 13 and size of sand blows on beach ridges has been about the same, for a time period extending at least throughout the Holocene (Obermeier and others, 1989; also discussed later). Thus, in the vicinity of the epicentral region, the sand blows should generally be largest (have largest diameters) and be most abundant. This hypothesis is confirmed in the Charleston region by observations of effects of the 1886 earthquake (Peters and Herrmann, 1986). Sand blows produced by the 1886 earthquake were abundant Within the 1886 meizoseismal zone, which was a region about 35 km Wide and 50 km long. Beyond this zone, the sand blows were smaller and scattered. Only rare, small sand blows formed more than 10 km beyond the meizoseismal boundary. Because all the factors involving sand-blow production are about the same in many places throughout coastal South Carolina, this same relation of sand blows to epicenter location should hold true for pre—1886 Holocene earthquakes. In particular, it has been found that for craters having one apparent age (based on soil profile) and whose diameters (measured near the ground surface) are less than about 1 m, there are at most two or three craters exposed in a nearby l-km-long ditch cutting across beach ridge deposits. Wherever maximum diameters of craters having one apparent age are about 2 m, there are more (as many as 5 to 10) craters exposed in a nearby 1-km—long ditch. Wherever maximum diameters of cra- ters having one apparent age are 3 m or larger, there are a greater number (as many as 20) exposed in a nearby l-km-long ditch. This well-defined relation between number of sand blows and sand-blow diameters is con- sistent with an earthquake origin in our opinion. We emphasize that a single, isolated feature that appears to be earthquake-induced would not be inter- preted by us to be compelling evidence for prior earth- quake shaking. Compelling evidence requires at least several features, scattered over a region of at least several square kilometers. OTHER POSSIBLE ORIGINS Origins other than earthquakes for filled sand-blow craters and vented-sand volcanoes that have been con- sidered include compaction-induced dewatering and soft- sediment deformation; artesian springs; landslides; fill- ings in decayed stump and root holes; ground disruption by fallen, root—wadded trees; and liquefaction caused by storm—induced, ocean-wave pounding. Criteria for assessing each of these potential sources are discussed below. Compaction—induced dewatering and defamation.— Syndepositional and postdepositional dewatering by compaction occurs in sediments during or shortly after their deposition. This dewatering generally takes place in response to rapid deposition of sediments (especially coarser, denser sediments) above very soft, clay-rich sediments, which causes buildup of pore-water pressure and gravitational instability (Dzulynski and Walton, 1965; Allen, 1984; Lowe, 1975, 1976); deposition of silts or fine sands rapid enough to cause buildup of pore-water pressure can also lead to instability (Dzulynski and Smith, 1963; Sanders, 1960). The kinds of sedimentary structures formed by these processes include load struc- tures, dish structures, convolute lamination, sand dikes, and faults (Pettijohn and Potter, 1964). In our study, earthquake—interpreted features generally have soil hori— zons that are much thinner and less well developed (and thus younger) than soil horizons on laterally adjoining, undisturbed parent sediments; in the relatively few instances where both the parent sediments and crosscut- ting features have essentially the same degree of soil development, the earthquake—interpreted features con— tain clasts of Bh material at depths generally about 0.5 m below the laterally adjoining Bh material in the parent sediment. The apparent difference in age between the parent sediment and filled-crater or vented-sand volcano determined on the basis of soil development, combined with lack of reason to suspect sudden, nonseismic surface stressing or long-term pore-water pressure buildup, is sufficient reason to eliminate postdepositional dewater- ing as a source mechanism. Artesiom springs. —The regional and local topographic and ground—water setting of many sites rules out any significant likelihood for the occurrence of a sudden, strong increase in the hydraulic force of a spring. The beach crests are generally flat lying for many kilometers along their crests, and the crests are well above the lagoonal deposits. Where filled craters are found on ancient beaches, a short- or long-term spring origin is not believed possible if the following conditions are met: (1) the filled craters cut humate-rich sandy soils that are also cut With numerous, highly permeable sand-filled root holes and burrows that extend well into the C horizon, (2) the filled craters are much above the lagoonal deposits adjoining the beach (as illustrated in fig. 2), and (3) the filled craters are Within 1 to 2 m of the beach crest. Short-term springs induced by a hurricane deluge (or any other mechanism) have not been observed where these criteria are met. Short-term springs are suspected to be rather common in lowland areas of lagoonal deposits, however. Features interpreted as earthquake-induced sand volcanoes are restricted to sites where artesian springs are thought to have been unlikely, and in addition, there is other evidence for an earthquake mechanism, such as frac- tured ground (as illustrated in fig. 8). Typical sites are elevated locations near deeply entrenched rivers, where artesian pressures would have been relieved by lateral 14 EARTHQUAKE-INDUCED LIQUEFACTION FEATURES IN SOUTH CAROLINA AND THE NEW MADRID SEISMIC ZONE flow to the rivers rather than by vertical flow to higher elevations, which would have been required to form the volcanoes. Landslides. —All sites on figure 1 are on level or nearly level ground, hundreds of meters from any steep slopes. Downslope movement on these nearly level sites could be initiated only by seismic shaking, considering relations between surface topography, ground-water setting, and strength of materials. Fillings in root holes—Holes caused by decayed stumps and roots, and later filled with clean sand, are common in the study area. Although the filled holes are generally circular in plan view, many display poorly defined layers of clay mineral segregation (due to weath- ering) and gradually taper downward; they do not have the well-defined laminar bedding of the filled craters and underlying graded zone of sediments. Typically, maxi- mum depths of root penetration are about 2 to 3 m. Ground disruption by trees. —Tree throw in the South Carolina low country is generally restricted to hardwood species having wide, shallow root systems. These trees may blow over in wind storms and rip up a wad of sediment caught within their root mats, thus creating pits and mounds. Taprooted pines and cypress trees very rarely tend to throw; instead, these species break off near the ground surface. Pits excavated by hardwood tree throw tend to be shallow (usually less than 50—100 cm deep); when filled, they do not contain sediment introduced from depth, and they almost always lack the orderly internal stratigraphy of liquefaction craters. At some few places, though, pits excavated by thrown trees can be distinguished from craters excavated by earthquake—induced liquefaction only by the presence of feeder vents or by the presence in the crater of sediment (generally sand or silt) that has been introduced from strata beneath the base of the crater. Verification that sediment has been introduced from depth may require mineralogical, weathering, and grain-size analysis (Geli- nas, 1986). Ocean-wave pounding. —The disruption of subaerially formed soils shows that liquefaction occurred long after deposition of the parent sediments. Storm-induced, ocean-wave poundings are not a credible mechanism of liquefaction at most of the widely scattered sites because the elevations are well above modern sea level (up to 15 m) and are too far inland. In addition, no sedimentary records indicative of inland surges of the ocean, such as soil horizons buried by storm-deposited sediments, have been found. FEATURES OF WEATHERING ORIGIN A wide variety of features produced by chemical weathering mimic earthquake-induced liquefaction fea- tures. Such weathering features include the white, E- horizon sand that commonly blankets the surface; pedo— genic tongues; and BE or fragipan horizons. Distinguishing liquefaction features from weathering features is much more difficult where older liquefaction features have been extensively weathered. A loose, clean, white sand blanket covers large parts of the South Carolina low country that is underlain by sandy sediments of barrier beach and nearshore marine origin. In undisturbed soil profiles, the white sand under- lies a thin, 0- to 15-cm-thick, dark-gray A horizon. Although some of this white sand has been periodically remobilized by surficial processes, it is a pedogenic E horizon, formed by weathering and leaching of the under— lying sandy sediments (Gamble, 1965). The pedogenic origin of the E horizon is demonstrable by its eluvial- illuvial relationship with the underlying B horizon. Clays and labile minerals have been removed from the E horizon, and weathering products have been deposited in the B horizon; however, particle-size distribution and resistant heavy-mineral percentages are nearly identical in both horizons. In addition, the boundary between the E and B horizons is commonly abrupt and irregular and is characterized by narrow, near-vertical tongues of white E horizon penetrating downward into the B hori- zon. Laterally continuous, interpenetrating boundaries of this type are more likely to be indicative of geochem- ical leaching rather than clastic deposition. At some sites resistant sedimentary features, such as thin pebble beds, pass through the horizon boundary, showing that it is not a sedimentary contact. In summary, although a blanket of ejected white sand often exists at earthquake liquefaction sites, all white sand blankets are not necessarily formed by earthquake liquefaction. In younger liquefaction features, bedding within ejected sand blankets helps to demonstrate lique- faction origin if other fluvial and eolian origins can be rejected. With age, the usefulness of this criterion decreases as soil mixing by flora and fauna destroys bedding, making ejected sand blankets appear superfi- cially like massive pedogenic E horizons. The pedogenic boundary between E and B horizons can be gradational or quite sharp and can also be highly convoluted. Gamble (1965) describes boundaries between loose, white E-horizon sand that grades over 1 to 2 mm of depth to brown, clayey sand. The boundary also commonly has 2- to 3-cm-wide, 5- to 10-cm-long tongues of E horizon descending vertically into the underlying B horizon. Locally, we have observed tongues of E-horizon sand that extend more than a meter into thick, red to brown (7.5YR 5/6—5YR 5/8), clayey B horizon (fig. 10). Tongues of this size and shape can give the impression of fractured and brecciated ground and might be mistaken for liquefaction features unless examined carefully for sedimentary characteristics. COASTAL SOUTH CAROLINA 15 Masswe. light-gray to right-yeiIMishmbw : ‘ senate *9:va n Ground surface A horizon E horizon f BE horizon B horizon C horizon A Samples from B horizon 0 Samples from tongues 100 | i l 6 E 90 — é _ t 80 _ A samples fromBhorizon _ 3 0 samples from tongues 8 70 - 2’ so — A _ g 50 — g — a; a. 40 — _ ‘3 '5 30 — — 2 3 2 _ _ E 0 5 10 — — 0 A Q | J | -1 0 l 2 3 4 5 B Particle size, phi units The single field criterion that is most useful for distin- guishing pedogenic tongues from liquefaction features is the downward closing of the narrow, nearly vertical sand bodies. Pedogenic tongues almost always close down- ward. Alternatively, if they connect at depth with a source bed, an earthquake-induced liquefaction origin is possible. Unfortunately, many exposures are too shallow to allow use of this criterion. [1 20 INCHES O 50 CENTIMETERS N0 VERTICAL EXAGBERATION FIGURE 10.—Schematic sketch and grain-sized data for pedogenic tonguing. A, Pedogenic tonguing of BE- and E-horizon sand into underlying B horizon of an exposure in a drainage ditch near Rincon, Ga. (near Savannah). B, Cumulative particle-size distri- butions for sand fraction samples from Rincon, Ga., shown in A. B-horizon samples (triangles) are virtually indistinguishable from tongue samples (circles), indicating that the tongues are probably not vented sand. Pedogenic tongues can range in morphology from tubular (Gamble, 1965) to planar (defining B horizon polygons; Nettleton and others, 1968a). Hence, tongue morphology is tenuous evidence for pedogenic or earth- quake origin. An example of pedogenic tonguing is shown in figure 10A, which is a schematic drawing from an exposure in a drainage ditch near Rincon, Ga. The tongues extend 16 EARTHQUAKE-INDUCED LIQUEFACTION FEATURES IN SOUTH CAROLINA AND THE NEW MADRID SEISMIC ZONE Bhir horizon 0 20 INCHES Approximate level of seasonal ground-water table, pre-ditch excavation—>l 0 so CENTIMETERS s'umped “dime“ N0 VERTICAL EXAGGERATIDN 7 le, masszve, we —sorte san , , ' '.very loose and friable ‘ , . -. . Ehorizon ' Grayish-black, massive Bh-horizon sand, I ‘— -‘~ 4 ' J @5991 144/ Dark»reddish-brown, massive Bhir-horizon sand, very firm FIGURE 11. —Cross section through a white, pedogenic sand tongue from an exposure in a drainage ditch at site HW, near Hollywood, 8.0. Prime designations on E and Bh horizons indicate the lower horizons of a bisequal weathering profile. Bhir is iron—enriched Bh material. downward from a massive, pale-brown to gray E hori- zon and narrow with depth. Tongues may form prefer- entially along soil structure polygon boundaries (ped boundaries) or where tap roots have penetrated the B horizon. Once formed, tongues become the loci of con- centrated weathering because the higher permeability of the leached E-horizon sand guides infiltrating solutions through the clayey B horizon. Increased weathering in the tongues may alter the particle-size distribution of the original sediment either by producing or destroying minerals in the finer particle-size fractions. Therefore, a comparison of the particle-size gradation exclusive of the clay and silt fractions (less than 63 micron) may show whether the tongue sand has been injected from a separate source. Sand size and cumulative particle-size distributions of six samples taken from areas marked in figure 10A are shown in figure 103. The extreme simi- larity between the tongue and the nontongue portions strongly suggests that the tongues were weathered in place, although there is a remote possibility that injected sand could have the same sand-particle-size distribution. Alternatively, a liquefaction origin would be more strongly suggested if the tongue sand-particle-size dis- tribution was distinctly different from that of the adja- cent soil. Other evidence for pedogenic versus liquefaction ori- gin of tonguelike features is the mineralogy of the sand fraction. Because weathering is concentrated in the E-horizon tongues, the presence of abundant fresh, labile minerals, relative to adjacent soil mineralogy, would be good evidence for injection. Conversely, if the tongue and adjacent soil have similar mineralogies, or if the tongue has more highly weathered minerals than the adjacent soil, a pedogenic origin is more probable. By using mineralogic criteria, Gelinas (1986) assigned a liquefaction origin to sand vents at the McL, SAN, and CH sites (fig. 1) by demonstrating that suspected vent sands have greater abundances of easily weathered feldspars and hornblendes than the adjacent undisturbed soil. Another type of pedogenic tonguing is sketched in figure 11 from an exposure in a drainage ditch near site HW (fig. 1), where the ditch crosses the crest of a relatively well drained beach ridge. At least 10 features of this size and orientation were exposed in a 60-m section of the ditch. In vertical exposures, 10— to 30- cm-thick tongues of White sand dip gently downslope. The tongues are surrounded by black to dark-orange, humate and iron—oxide-stained sand. Some of the near— horizontal parts of the tongues can be traced for dis- tances up to 7 m. At the upslope end of each tongue, the feature abruptly turns up, breaks through the overlying Bh soil horizon, and flares toward the surface. At the surface, the tongue is continuous with white sand of the E horizon. The downslope end of the tongue is commonly terminated by black-and-orange-stained rind that is con- tinuous with the Bh horizon; in other cases the tongue- rind contact becomes diffuse downslope. The white sand tongue features were originally inter- preted by us as intrusions of liquified sand (Gohn and COASTAL SOUTH CAROLINA 17 others, 1984, p. 11); however, subsequent observations have led to the conclusion that the tongues are weather— ing features unrelated to liquefaction events. Essen— tially, they are extreme convolutions in the pedogenic E horizon caused by concentrated infiltration of soil solu- tions at places where taproots of trees have broken through brittle, relatively impermeable Bh horizons. This interpretation relies on several field observations: 0 The tongues are continuous with white E-horizon sand overlying the Bh horizon. Pedogenic origin of the E horizon sand is established by satisfaction of the sedimentologic and mineralogic criteria discussed previously. 0 The rind surrounding the white tongues is zoned into black Bh and dark-orange, iron-enriched Bh material (Bhir) stripes identical to the sequence found at the top of undisturbed B horizons. The vertical sequence of horizons in an undisturbed soil profile shows that dark organic compounds are deposited closer to the surface than iron oxyhydroxides after solutions infil— trate through the overlying E horizon. A similar zonation in the rind surrounding the tongues suggests that soil solutions are migrating laterally along the tongues and outward toward their margins. O The sharp to diffuse contacts between the tongues and surrounding sands show no appreciable sand- grain—size variation across them. The only difference between the tongues and the rinds is that the tongues contain black and orange colloidal material that bridges and coats sand grains. 0 No bedding is present in the tongues. o The flared portion of each tongue (the portion closest to the surface) is characterized by evidence of a taproot, which is either a rotted root in-place or a narrow V-shaped zone of loose, organic-stained sand subjacent to the White sand tongue. E-horizon tongues were found in all stages of development, from incipient leaching and bleaching surrounding areas adjacent to relatively fresh taproots to wider and more deeply bleached zones that formed as the taproots became more decayed. O The tongues all dip downhill in the direction of the low-gradient, shallow ground-water flow system. Mottles around rootlets in the C horizon are also elongated in downhill directions. Coincidence of the tongue orientation with ground-water flow direction suggests that after the infiltrating solutions break through the Bh horizon where taproots have decayed, the infiltrating solutions are entrained in the shallow ground-water flow system. Dissolved organics and iron oxyhydroxides in the ground water are then deposited downgradient as a rind adjacent to the E-horizon tongues. Another category of pedogenic feature that might be confused with earthquake-induced liquefaction is the BE or BE’ horizon. (The prime designation is used to denote the lower sequence of eluvial and illuvial horizons in a bisequal profile, in the general order A, E, Bh, E’, BE’, B (t,x), C.) Bisequal profiles with BE’ horizons form at the transition between poorly drained and moderately well drained landscape positions (Nettleton and others, 1968a,b). BE or BE’ horizons are transitional between eluviated E horizons and illuvial B, Bt (argillic), or Bx (fragipan) horizons and are characterized by irregular to prismatic bodies of clay-rich sand surrounded by leached, clean sand. Studies of this type of weathering profile in the North Carolina coastal plain indicate that the clean sand forms from the progressive destruction of a clay- rich Bt horizon (Daniels and others, 1966; Nettleton and others, 1968a, b; Steele and others, 1969). In this pro- cess, a Bt horizon is leached at the depth of a fluctuating water table, which removes clay and labile minerals and leaves patches of white to gray quartz sand that often coalesce to define a polygonal pattern in plan View. This horizon, composed of patches of leached and unleached material, is termed an E’ or BE’ horizon, depending on the extent of leaching. With continued leaching of clay and labile minerals, the soil volume decreases, resulting in collapse and the formation of a dense Bx horizon. In the ditch at the HW site, bisequal soils occur between red, oxidized spodosols on beach ridge crests and black, organic-rich spodosols in interridge depres- sions. For the example shown in figure 12, the BE’ horizon is a layer of pale-brown, clayey sand and White sand. The top of the layer is 1 to 2 m beneath the ground surface, and the layer is 0.3 to 0.5 m thick. Both above and below the layer is light-colored, well-sorted, fine- to medium-grained quartz sand. This sand cuts vertically across the clay layer at many places and creates irregular masses of the brown clayey sand. In three dimensions it can be seen that the sand forms irregular vertical walls. In vertical section, the sand walls are typically about 5 to 10 cm wide but can be as much as 30 cm wide. They are spaced at both irregular and at regular intervals. The contacts of the sand and the brown clayey sand are typically sharp with regard to both color and texture. The sand-grain sizes in both the leached sand and clayey sand masses are essentially the same. Sharp contacts between the leached quartz sand areas and the pale—gray to pale-brown clayey material origi- nally suggested that this feature was formed by some type of ground disruption, possibly liquefaction. How- ever, the similarity with features attributed to pedogen- esis elsewhere and the consistent occurrence in horizons underlying undisturbed pedogenic horizons led us to interpret these features as pedogenic. 18 EARTHQUAKE-INDUCED LIQUEFACTION FEATURES IN SOUTH CAROLINA AND THE NEW MADRID SEISMIC ZONE Bank overhang I 2'0 INCHES l o——o l 50 CENTIMETERS N0 VERTICAL EXAGGEHATION Massive Bh horizon sand; Not exposed grayish-black grading down c to dark-reddish-brown / .3 5 .C .C a: White, massive; well-sortéd sand - 8 . B .C A C O .u ‘6 .5 Eu m 33 White, wellr-sortedisand‘, -' locally stained palebrown Not scraped FIGURE 12.—Vertical section through BE’ horizon at site HW, near Hollywood, S.C. OVERVIEW OF THE SOUTH CAROLINA LIQUEFACTION STUDY Pre-1886 sand blows were first discovered in 1983 (Gohn and others, 1984; Obermeier and others, 1985) near the town of Hollywood (site HW, fig 1). There, the sand blows are exposed in an unusually deep ditch (up to 3 m) for a distance of 5 km. Over a hundred sand blows have been discovered in this ditch, and the depth of the ditch has permitted detailed study of entire features to depths that include source vents. For these reasons, site HW is generally used for the descriptions of filled craters in this paper. Since the discovery at Hollywood, features we interpret as sand blows have been found at sites throughout much of coastal South Carolina. Features at all sites shown on figure 1 are interpreted to be of earthquake origin, although the confidence level differs for various sites. Sites where we have greatest confidence of an earthquake origin are those where the following features occur: (1) craters have formed on topographically high beach crests, (2) numerous craters are present near where craters were reported to have been abundant during the 1886 earthquake, (3) ground oscillation shears have formed in opposite directions, (4) lateral spreads that could not be gravity-induced have formed and have shears traceable into a liquefied stra- tum, or (5) shattered ground is cut by numerous sand- filled dikes in settings Where high artesian pressures could not have been involved. Sites for which we have the highest confidence of an earthquake origin are BR, AR, HW, ARP, RRR, CH, FM, WV, SAN, 0L, and SOPO. All other sites on figure 1 are filled craters that are more than several meters below the beach crest, causing the confidence level to be lower. Some craters at site MYRB have reverse shears, however, an occurrence that makes an earthquake origin seem likely. ' Elimination of all sites from figure 1 except those in which we have the highest confidence does not affect our interpretation of Holocene seismic activity (discussed subsequently). Our interpretation about earthquake COASTAL SOUTH CAROLINA 19 ages and relative severity of shaking is based only on data from the sites for which we are most confident of an earthquake origin. EARTHQUAKE AGES Craters are typically the only features for which radiocarbon ages related to earthquake ages can be generated, because other liquefaction-related features are not found in association with preserved organic matter. Three methods have been used to bracket the times of crater formation (Weems and others, 1986): (1) radiocarbon ages of woody material (tree limbs or pine bark) that fell into the open crater soon after crater formation, (2) dating of roots sheared off at the edge of the crater (predating crater formation) and dating of roots that grew into the stratified fill portion of the crater (postdating crater formation), and (3) dating of clasts of Bh material that fell into the graded fill zone of the crater. The first method yields a highly accurate age for the time of earthquake occurrence, Whereas the other two yield a broad range of possible ages. Sufficient data have been collected at site HW (near Charleston; fig. 1) to show that at least three pre-l886 earthquakes pro- duced sand blows within the past 7,200 years. Radiocar- bon dating of a clast of pine bark in a crater at site ARP (also near Charleston) independently verifies the middle of these three events. The only definitive statement about earthquake recurrence that can presently be made is that near Charleston there have been at least four sand—blow—producing (mb probably >5.5, discussed later) earthquakes within the past 7,200 years (including the 1886 event). Accurate ages of crater formation have been obtained from some sites more than 100 km from Charleston. These dates differ from ages near Charles- ton, thereby suggesting that the craters far from Charleston originated from epicentral regions also far from Charleston. At many sites far from Charleston, there are at least two generations of craters that are long separated in time of formation. SHAKING SEVERITY ESTIMATION Insufficient radiocarbon ages have been collected from liquefaction features throughout the Carolina coastal region to define epicentral regions of separate earth- quakes. Adequate data have been collected, however, to estimate the relative shaking severity throughout the coastal region during the Holocene. This estimate is provided by measurement of the number and size of craters at the sites shown on figure 1. The methodology for estimating shaking intensity is based on the premise that the number and size of liquefaction features are greatest where earthquake shak- ing has been strongest for a fixed geologic setting and liquefaction susceptibility. The condition of a fixed geo- logic setting is met almost ideally on many of the Pleistocene beaches, as discussed in an earlier section. The condition of a fixed liquefaction susceptibility is also almost certainly satisfied at the widely scattered sites on figure 1. Source sands typically are loose (based on limited Standard Penetration Test data and numerous observations of ease of augering) and have about the same thickness. Moreover, the thickness and properties of nonliquefiable sediments overlying the source stratum lie within a narrow range. It is also a certainty that recurrences of liquefaction do not greatly diminish the potential for formation of more large craters in loose sands. This statement is verified by the observation that at site HW there are many large craters that formed in each of at least three generations of Holocene earth- quakes, with each generation widely spaced in time. Thus, at sites in beach deposits on figure 1, liquefaction susceptibility is generally high and has not been greatly reduced by previous occurrences of liquefaction. The other major variable, depth to the water table, is about the same from site to site (very shallow depth) and probably has been shallow throughout the Holocene (Obermeier and others, 1987). Evidence for location of the water table throughout the Holocene is provided by location of the base of the Bh horizon. (See fig. 4 for location of this horizon at a typical filled crater.) The maximum depth of the seasonal water table during the Holocene is marked very nearly by the base of the Bh horizon. (The Bh is defined as the subsoil zone of accumulation of organic matter and is formed in these soils at the lower limit of vertical infiltration of water.) Throughout the coastal region, the base of the Bh (generally 0.6 to 1 m below land surface) is nearly coincident with the present—day water table. Radiocar- bon ages from the basal Bh horizon are 5,000 to 10,000 years at site HW (Weems and others, 1986, p. 7). Because these ages are mean residence times of organic matter in a dynamic system characterized by continuing vertical infiltration of younger organic matter, some of the organic matter has been there even longer. Thus, it can be concluded that the water table has been very shallow throughout the Holocene over wide areas of the South Carolina Coastal Plain. HOLOCENE EARTHQUAKE SHAKING Both the abundance and diameters of pre-1886 Holocene craters are greatest within the 1886 meizoseis- mal zone for a given age of craters. On the basis of these criteria, we know that shaking has been much weaker north of the Santee River (Obermeier and others, 1989). Intermediate shaking has taken place between Charles- 20 EARTHQUAKE-INDUCED LIQUEFACTION FEATURES IN SOUTH CAROLINA AND THE NEW MADRID SEISMIC ZONE ton and the Santee River and also between Beaufort and the Savannah River. Confidence in this interpretation is high for the area between Charleston and Wilmington, because of the hundreds of kilometers of ditches we searched. Our confidence is also high for the 1886 meizoseismal zone and for the area between Beaufort and the Savannah River. Our confidence is not nearly as high for the area between the Beaufort and the Edisto River nor for the area south and southeast of the 1886 meizoseismal zone; this lower confidence is caused by the limited number of ditches and pits available for inspection. Whether or not the pre—1886 Holocene shaking in the 1886 meizoseismal zone is associable with earthquakes stronger than the 1886 event can be determined only by , additional radiocarbon ages for craters at sites far beyond the 1886 meizoseismal zone. Based on worldwide observations in the field, the minimum earthquake strength required for liquefaction- induced features is mb equal to approximately 5; such features are rare for mb less than 5.25 to 5.5 (Carter and Seed, 1988). It is likely that an earthquake slightly stronger than about 5.5 is adequate to produce numerous small liquefaction features in coastal South Carolina because of the exceptional liquefaction susceptibility of many marine sand deposits there (discussed previously and discussed in Dickenson and others, 1988). Many of the pre-1886 craters near Charleston that we have observed probably were not produced by earth- quakes as small as mb 5.5, however. Many pre—1886 craters are large (diameters of as much as 3—4 m are not uncommon) in comparison to historical descriptions of 1886 craters (Dutton, 1889) and our observations of the sizes of 1886 craters. As a result, we suspect that some of the pre—1886 craters were formed by earthquake shaking that was stronger at those sites than in 1886. Direct comparison of 1886 and pre-1886 crater sizes cannot be used for estimating earthquake magnitudes, however, because of the lack of knowledge about distances between craters and their associated epicentral regions and lack of knowledge about changes in liquefaction susceptibility caused by a previous occurrence of lique— faction. About the only comment that can be made with much assurance is that the prehistoric craters were very likely the result of earthquakes stronger than mb 5.5; some of the earthquakes probably were much stronger because of the widespread distribution of large craters. NEW MADRID SEISMIC ZONE The succession of great earthquakes collectively des- ignated as the New Madrid earthquakes of 1811—12 caused severe and widespread ground failure throughout a large area near the Mississippi River in southeastern Missouri, northeastern Arkansas, western Kentucky, and western Tennessee. The earthquakes caused multi- tudes of fissures and sand blows (Fuller, 1912), set off numerous landslides (Fuller, 1912; Jibson, 1985), and caused localized doming and submergence of the ground surface (Russ, 1982). Earthquake effects were particu- larly severe in the St. Francis Basin (fig. 13). According to the earliest extensive documentary account (Fuller, 1912), three major shocks occurred: December 16, 1811; January 23, 1812; and February 7, 1812. The surface- wave magnitudes (Ms) of these earthquakes are esti- mated to have been between 8.3 and 8.8 (Nuttli, 1983a). Estimated Modified Mercalli (MM) intensities are XI to XII throughout large areas near the epicenters (Nuttli, 1973); these intensities are regional values based largely on historical accounts of liquefaction-induced ground failure. No faults associated with the 1811—12 earth- quakes have been found that cut through alluvium, loess, or older strata to the surface. The epicenters are esti- mated to lie within the large area of sand blows near the Mississippi River, shown on figure 14. This interpreta- tion of epicenters is based on the study by Fuller; a study of MM intensities by Nuttli (1973); recent geologic, geophysical and modern seismicity studies (McKeown and Pakiser, 1982; Crone and others, 1985); and engineering—geologic studies of factors controlling the distribution of sand blows (Obermeier, 1989). (The epi- central regions during the 1811—12 earthquake and the region of epicenters on figure 14 define the “New Madrid seismic zone.”) Figure 14 is a map by Obermeier (1988) that shows the percent of the ground surface covered by sand vented to the surface in the St. Francis Basin. The map is the latest of a series of maps (Fuller, 1912; Saucier, 1977; Heyl and McKeown, 1978) showing sand blows throughout the alluvial lowlands of the basin. Significant differences appear between each of the maps, particularly north of the town of New Madrid. These differences occur for a number of reasons, the most likely being that (1) some surface soils are so sandy that sand blows can be observed only on the older aerial photographs used by Obermeier, (2) the modern farming practice of land- leveling has destroyed many sand blows since the 1950’s, (3) some nonearthquake features cannot be distinguished from sand blows except by field excavations, and (4) the map by Obermeier extends more to the limits of ground covered by vented sand, whereas the earlier maps emphasize areas of abundant sand blows. Sand-blow deposits and other manifestations of liquefaction-induced flowage occurred far beyond the limits of sand-blow deposits shown on figure 14, but beyond these limits the deposits were generally NEW MADRID SEISMIC ZONE 21 >2 0 20 MILES 0 20 KILOMETERS H Mississippi EXPLANATION Alluvium on small streams Mississippi River meander belts Late Wisconsinan glacial outwash River Early Wisconsinan glacial outwash Undifferentiated pre-Wisconsinan depositional terraces FIGURE 13. —Late Quaternary alluvial deposits of St. Francis and Western Lowlands Basins (from Saucier, 1974). restricted to modern flood-plain sediments adjoining rivers. These very young (late Holocene) sediments generally have higher liquefaction susceptibility than the late Wisconsinan and early Holocene fluvial deposits, which underlie the area of sand-blow deposits shown on figure 14. Liquefaction features were especially common- place in alluvium along some of the small streams of the Western Lowlands Basin (fig. 13), particularly those nearest Crowleys Ridge. Sand blows were reported (McDermott, 1949) in alluvial deposits as far north as Cahokia, 111. (which is very near to St. Louis, Mo.), and as far northeast as the Wabash River valley (Street and Nuttli, 1984). Some possible sand blows were formed in some of the river valleys beyond the limits of sand blows on figure 14. For example, Dickey (1985) reports fea- tures on aerial photographs in the Western Lowlands that appear to be sand-blow deposits. At many places, though, sand-blow deposits on modern flood plains have been covered by a veneer of alluvium deposited since the 1811—12 earthquakes. In the New Madrid area, visible sand-blow deposits are still plentiful on the ground surface, and the epicen- tral regions are relatively well established. These char- acteristics permit a more detailed evaluation of geologic 22 EARTHQUAKE-INDUCED LIQUEFACTION FEATURES IN SOUTH CAROLINA AND THE NEW MADRID SEISMIC ZONE 91° 90° 37° 36° ‘ EXPLANATION m Upland areas U Alluvium with few or no observed sand blows Alluvium with recognizable sand-blow deposits (>1 per— cent ground coverage), but not major ground coverage Alluvium with more than 25 percent of ground surface covered by sand-blow deposits + Epicenters for three largest 1811—1812 earthquakes accordingto Nuttli (1979) / Fault / / Fault zone / // / 0 20 MILES 0 20 KILOMETERS FIGURE 14. —Map showing area covered by vented sand ( Obermeier, 1988), estimated epicenters 0f strongest 1811—12 earthquakes (from Nuttli, 1979), and faults and fault zones (from Hamilton and Zoback, 1982). controls on the formation of liquefaction features than is possible in coastal South Carolina. REGIONAL GEOLOGIC AND SEISMOTECTONIC SETTING The St. Francis Basin is a topographic lowland con— taining 30 to 60 m of late Quaternary alluvium, which originated from deposition associated with the Missis- sippi and Ohio Rivers and their tributaries. The lowlands are typically very flat, having about 0.3 to 2 m of local relief. Numerous small scarps, 2 to 6 m high, result from depositional or erosional processes. The water table is very high and is within 1 to 2 m of the ground surface at many places. Elevations in the lowlands exceed 100 m near Cairo, 111., and decrease southward to less than 60 m near Memphis, Tenn. Widespread floods were common prior to the construc- tion in this century of manmade levees along the Missis- sippi River. Standing water occupied the lower parts of the lowlands throughout much of the year before the levees were built and large drainage ditches were exca- vated. Until about 50 years ago, dense forests and cypress swamps covered most of the basin; today the forests have been replaced by large fields of soybeans, rice, and other row crops. NEW MADRID SEISMIC ZONE 23 sediments ‘substraturnr'. Dominantly clay-rich Braided stream deposits—>k— Meander belt deposits -','_grading downward to“. '. ,_ '.. QOarSe Sand and grave] til-.3.- '..: '..‘~ :- '.. ‘..... .'-- '..: . ;. ‘.. ‘..” _ ~. . . . . _ Flood Natural stage Normal E river stage Crowleys Ridge »9 . artesian seepage area E g 3 Generally clay-rich 0_3 km I . 04,500 m _ g) 8 :- 2 Tertiary deposrts .2 .2 ‘5 D: a D: (B E l< 40—60 km > [A 50—80 km — V =Water level FIGURE 15. —Schematic east-west cross section showing geologic and ground-water setting of St. Francis Basin. CHARACTERISTICS OF QUATERNARY ALLUVIUM Cyclic Pleistocene glaciations directly and indirectly controlled the origin, character, and distribution of vir- tually all the Pleistocene deposits in the basin (Saucier, 1974). Although continental glaciers did not extend into the St. Francis Basin, they supplied large volumes of glacial meltwater and outwash to southward—flowing river systems. Up to 60 m of valley fill composed of very coarse grained, well-graded (engineering sense) glacial outwash (gravel and sand) were first deposited by aggrading braided streams. After maximum aggrada- tion, numerous braided-stream terraces were deposited. The ancestral Mississippi River changed from a braided to a meandering regimen in early Holocene time, and since that time, slow aggradation has taken place in most parts of the valley. Most meander-belt deposits are medium-grained, well-graded sand; locally, silts and clays have been laid down. Sikeston Ridge (fig. 13), the highest terrace of St. Francis Basin, is early Wisconsinan in age, while the other braided-stream terraces are late Wisconsinan. The earlier braided-stream deposits are topographically higher, have greater relief, and have sandier surfaces than younger deposits. The older braided-stream depos- its occur in several terrace sublevels separated by 2 to 6 m. These deposits generally are capped with 3 to 7 m of silty or clayey sediments (the topstratum) containing some thin sand strata. The topstratum abruptly overlies the clean, outwash sands and gravels (the substratum) over large areas except at the highest sublevels and interfluves. The topstratum was deposited either by relatively slack streams as individual braided-stream levels were successively abandoned or by overbank deposition during widespread flooding of the Mississippi River and local streams that now occupy the topographic lows. Substratum sands and gravels generally are found in intercalated strata and lenses ranging from a few centimeters to a meter thick and tend to become coarser with depth. The Mississippi River meander belts represent succes- sive courses formed by lateral migration of the river. Most of the meander belt consists of point-bar “accre— tion” topography of parallel arcuate ridges and swales, abandoned channels in various stages of filling, and natural levees. Point-bar deposits are generally clean, well-graded sands4 that are capped by the topstratum except locally at the highest elevations. Point-bar depos- its of the Mississippi River typically have 2 to 3 m of local relief. Many abandoned channels are filled with 30 m or more of soft clays and silts and are swampy and densely forested. Large backswamp areas are found along the margins of some Mississippi River meander belts (Saucier, 1974). Backswamp deposits were formed by seasonal flood- Waters depositing silts and clays in low areas of the flood plains during the Holocene. The deposits average 12 m in thickness but are as much as 18 m thick. The ground-water setting is generally simple, as shown in figure 15. Major rivers such as the Mississippi and St. Francis both supply and drain large volumes of water in the substratum. Locally, especially within 0.5 to 1 km adjacent to levees, artesian conditions occur many years during flooding. Beyond this area of flood—related springs near levees, the streams have cut through the topstratum, thus preventing artesian conditions. In addi- tion, throughout the St. Francis Basin many topograph- ically elevated areas make artesian conditions impossi- ble. Present ground-water conditions are shown in a fairly detailed manner in a ground-water report by 4In this paper, the clean sands beneath the fine-grained cap are referred to as the “substratum,” and the fine-grained cap as the “topstratum,” irrespective of origin as meander-belt or braided-stream deposits. 24 EARTHQUAKE-INDUCED LIQUEFACTION FEATURES IN SOUTH CAROLINA AND THE NEW MADRID SEISMIC ZONE I ll Surface projection of buried rift complex \( 11/0 \ + + ~ 4 + + 4 + 4 owercrust+ + o + + + FIGURE 16.—Configuration of the buried New Madrid Rift Complex (from Graile and others, 1984). The structurally controlled rivers, Paleozoic rocks in the cratonic sedimentary basins, and the Missis- sippi Embayment, all associated with the buried rift complex, are also shown. Dark areas indicate intrusions near the edge of the buried rift. Krinitzsky and Wire (1964); detailed geologic maps by Saucier (1964) and Smith and Saucier (1971) can be used to help determine present and Holocene ground-water conditions. No evidence indicates .that ground-water conditions (especially the piezometric surface) were sig— nificantly different during the past few thousand years in the St. Francis Basin, except locally near manmade levees during times of flooding. SEISMOTECTONIC SETTING The St. Francis Basin lies in the northern Mississippi Embayment, which is a broad, southward-plunging syn- cline (fig. 16). The northern embayment is underlain by a late Precambrian intraplate rift that has been active periodically since its formation (Braile and others, 1984). Within this rift lies the New Madrid seismic zone. This zone is the most seismically active area in the United States east of the Rocky Mountains. Continuing fault movement, in response to regional compressive and perhaps thermal stresses, is the most likely cause of modern seismicity (Braile and others, 1984). Since 1812, at least 20 earthquakes having estimated body-wave magnitudes between 3.8 and 6.2 have occurred in the region (Nuttli, 1982). Most estimates for the return period of great earthquakes are between 500 and 700 years (Hopper and others, 1983). Figure 17 shows locations of instrumentally recorded earthquakes and principal structural elements in the New Madrid seismic zone. The trend of modern epicen- ters extending from Marked Tree, Ark., to Ridgley, Tenn., coincides at least approximately with the epicen— ters interpreted by Nuttli (1979) of the three principal shocks of the 1811-12 earthquakes. Subsurface faults are inferred by seismic-reflection data to lie beneath the most seismically active areas (O’Connell and others, 1982; Crone and others, 1985). CHARACTERISTICS OF AND CRITERIA FOR EARTHQUAKE- INDUCED LIQUEFACTION FEATURES Reports of level—ground and near-level ground failure features made shortly after the 1811—12 earthquakes noted great multitudes of vented-sand volcanoes, linear fissures up to 6 m deep and hundreds of meters long, craters many meters in diameter, and lateral spreads hundreds of meters long (for example, see Penick (1976)). Fuller (1912) described vicinities where these features were especially abundant. Individual vented—sand volca- noes and some long linear fissures through which sand vented are the only features that are still readily visible on the ground surface. Intruded dikes and sills are common in walls of deep (>3 to 4 m) drainage ditches in the clay-rich topstratum. We have not found other types of level-ground failure features such as deep craters or lateral spreads having downdropped blocks at the head such as those described by Fuller (1912, p. 48), primarily because we have not searched extensively in areas where these features would have formed (that is, locations in sandy topstratum for craters and locations near streams or scarps for lateral spreads). Limited observations in the New Madrid seismic zone by Wesnousky and others (1987) and by us of the characteristics of sand blows formed in a sandy topstratum indicate that open, deep craters are atypical forms. Instead, intrusions that extensively shattered the ground near the surface locally erupted to form shallow craters (up to 2 m deep). The geologic criteria (previously discussed) for inter- preting an earthquake origin with regard to specific features are identical in both the South Carolina and New Madrid earthquake areas. VENTED-SAND VOLCANOES The vented-sand volcanoes in the New Madrid area are similar to, though much larger than, those discovered in South Carolina. (See fig. 7.) Individual vented-sand volcanoes induced by the 1811—12 earthquakes are dome- like accumulations of clean sand on the ground surface. Fuller (1912, p. 79) noted that “the normal blow is a patch of sand nearly circular in shape, from 8 to 15 feet across, and 3 to 6 inches high.” Such small sand blows as Fuller described can rarely be found at present. The sand blows that are now obvious range from about 0.3 to 1.3 m in height at the center and thin to a feather-edge at a diameter of 20 to 60 m. Most vented-sand volcanoes have a well—defined inter- nal stratigraphy. Along the base of the vented-sand NEW MADRID SEISMIC ZONE 25 92°00 91°00 00°00 39°00 00°00 I ( I I I (“I > \ ILLINOIS flp/ H \ \ l/ I“. 38°00' — \ \ .. ,’,, T 37°00 — 36°00' _ 35°00 - ’ I ,3, ,: :, 3;... I L 1‘ :1; L | EXPLANATION N Plutons Faults 0 Earthquake epicenters Rift boundaries FIGURE 17. —Northern Mississippi Embayment (shaded area) showing earthquake epicenters, plutons, rift boundaries, and faults (from Zoback and others, 1980). volcano deposits, Where the vented sand spread over the ground surface, many irregular 1- to 3—cm-long clasts of topstratum clay (generally a blue-gray, highly plastic clay) are scattered throughout the sand. The clasts are largest and most plentiful closest to the vent, which is beneath the central part of the dome. The basal part of the sand-blow deposit contains numerous pieces (1—3 cm in diameter) of rounded charcoal fragments and other very low density materials vented to the surface from the substratum. This basal part contains and is overlain by a very clean, generally medium- to coarse—grained sand. This sand grades upward to a much finer sand, which is capped by a clayey, organic silt stratum, 0.5 to 4 cm thick (fig. 18); this cap may also contain multiple very thin (l—mm-thick) clay-rich layers (Saucier 1989). The organic matter in the silt is made up of small pieces of coal, lignite, and wood. The fining-upward sequence, from the basal clay clast-bearing sand to the organic silt stratum, represents the transition from the initially rapid, turbu— lent eruption to the final ebbing flow out of the vent. 26 EARTHQUAKE-INDUCED LIQUEFACTION FEATURES IN SOUTH CAROLINA AND THE NEW MADRID SEISMIC ZONE FIGURE 18.—Stratigraphy of vented-sand volcano showing organic- rich silt between two fining-upward sequences of sand. Presence of two fining-upward sequences is inferred to represent two separate liquefaction events or reactivation during a single earthquake. Height of shovel is 40 cm. Locally, near the vent, the beds may dip steeply toward the vent if flowage has been sufficiently slow. (Dipping beds in an excavation through vented-sand volcano deposits are shown in fig. 5 in an article by Newmann- Mahlkau (1976)). If a violent eruption has taken place, the lower and central portion of the vented—sand volcano may be sheared and disrupted. Figure 19 shows earthquake-induced “eruptive vent” in sand-blow depos- its of the 1811—12 earthquakes. A basal bed, several centimeters thick, of pea-sized clean gravel is the coarsest basal material that we have found in the sand blows. Within a sand matrix, isolated gravels up to 3 cm in diameter have been vented; these coarsest materials were vented only near the earthquake epicenters. Sand blows far from the epicenters, near the boundary of sand-blow occurrences (fig. 14), are rather small and are made up of finer grained material. Here the basal sands are often fine-grained and fine upward to a silty sand. At least two fining-upward sequences characteristi— cally occur in vented-sand volcanoes near epicentral regions; each sequence represents a separate occurrence of venting induced by the 1811—12 earthquake.5 How— ever, generally only one sequence occurs near the regional boundary of sand blows, which is shown in figure 13. Not only are the largest sand blows near the epicentral regions, but in some places the vented sand coalesces into continuous sheets. The sheets are up to 2 m thick 5Interpretation of 1811—12 earthquakes is based on the absence of a soil profile in any of the fining-upward sequences. and at several places blanket tens of square kilometers (for example, just south of the Missouri-Arkansas bound- ary and near the December 16, 1811, epicenter shown on fig. 14). Vented-sand—blow deposits are obvious on aerial pho- tographs at many places. Figure 20 shows some exam- ples. The light-colored spots show vented sand blows, and the light-colored linear features show fissures through which sand has vented. (Some of the linear features near streams probably mark edges of lateral spreads, but we have not confirmed this suspicion in our study, and therefore in this paper such features are simply called fissures). Figures 20A and 208 illustrate how sand blows typically occur at irregular, almost erratically spaced intervals, and the crazing pattern of vented sand suggests that the ground is fractured. Figure 200 illustrates that where less sand is vented to the surface, the venting is more erratic and is restricted to localized areas and that relatively small differences in site characteristics become important controls on vent locations. Comparison of figures 20A and 203 illustrates that sand-blow deposits may be more apparent in the older photographs than the more recent photographs. Some surficial features unrelated to earthquakes have a similar appearance to earthquake-related features shown in figure 200. An earthquake origin was attrib- uted to questionable features only if the features had a concentration of irregular, large (2—3 cm) clay clasts at the base (implying a strong hydraulic force); had a fining-upward clean sand (implying diminishing flow within a short time period); were irregularly spaced (suggesting ground fracturing); and (4) were located where spring flow from uplands or from beneath levees could not have occurred. (Sand boils formed by flow beneath levees are discussed later.) Only limited data have been collected to characterize vent shapes and sorting and flow structures in the vent filling. The vents are frequently steeply to vertically oriented and are fissure shaped. Vents generally appear to be filled with a structureless mixture of silt, sand, and clay clasts ranging from sand sized to having a length of up to 20 cm. The clasts have been transported up the vent and are derived from sidewalls and beds at depth. FISSURES Earthquake-induced fissures presently appear on the ground surface as lines of continuously or discontinuously vented sand. The fissures are common on level ground far from any (erosional) scarps but are especially com- monplace on those parts of terraces immediately above scarps and on river banks. Vented sand locally forms small ridges, but the ridges are generally not as high as nearby vented-sand-volcano deposits and sometimes are NEW MADRID SEISMIC ZONE barely discernible. Widths of fissure openings tend to range between 0.3 m to a feather edge, most being small; Plow zone : Quartzose sand . Eruptive 000005300 \ : wo \ Charcoal Buried B horizon 25 INCHES | l 50 CENTIMETERS 27 the wider openings almost certainly indicate association with lateral spreads. Fissure patterns can be highly sensitive to the local geologic setting. Fissures have a strong tendency to follow the crests of point-bar deposits; on braided-stream deposits having essentially a uniformly thick topstratum, the fissures are commonly oriented randomly (Ober— meier, 1989). Topstratum thickness appears to be an important control on development of fissures; more fis- sures develop at locations having a thin topstratum. Long irregular fissures through which sand has vented, such as those shown in figures 20A and ZOB, have not been observed to have originated by springs in the alluvial lowlands of the St. Francis Basin. Slumps and lateral spreads along rivers (generally caused by rapid hydraulic drawdown after floods) can generate fissures, but we have not observed sand flowing to the surface through the fissures except for small amounts associated with water oozing through the slide mass. In addition, aseismic lateral spreads and slumps that we have observed do not extend back from banks along large rivers more than 50 m. Thus we believe that fissures associated with vented sand that is located more than 50 m from present or former banks of rivers can generally be attributed to seismically induced slope instability. Confidence in this interpretation increases with increas- ing width of the sand-filled fissure and with increasing distance from the banks. In order to confidently attribute an earthquake mechanism to a specific vented-sand fis- sure, however, the location of the river at the time of fissure formation must be established, an undertaking that may be quite difficult. Fissures formed on terraces far from streams can be attributed to earthquakes more confidently. In inter- preting an origin for any feature, it is still necessary to assess ground—water conditions at the site and ascertain that the fissures could not have originated by some process related to syndepositional deformations. INTRUDED FEATURES Intruded features are sand-filled cracks that do not reach the surface, and therefore the features are visible 4 FIGURE 19. —“Eruptive vent” that cut stratified vented deposits of a vented-sand volcano (from Haller and Crone, 1986). A, Number 102 is above a severely disrupted zone. Distances between vertical edges of photograph is approximately 1 m. B, Number 61 is at contact between vented sediments and the original ground surface. Distance between vertical edges of photograph is approximately 1 m. C, Line drawing of “eruptive vent” in B. Heavy lines are stratigraphic contacts; fine lines show laminations within the “eruptive vent,” dashed where discontinuous. Open circles are aligned clay fragments. 28 EARTHQUAKE—INDUCED LIQUEFACTION FEATURES IN SOUTH CAROLINA AND THE NEW MADRID SEISMIC ZONE 0 I l 0 FIGURE 20. ——Aerial photographs showing vented sand, interpreted as the product of liquefaction and flowage during the 1811—12 earth- quakes. Note pattern of crazing in figures 20A and B, which is especially indicative of ground breakage caused by earthquake— induced liquefaction. A, Taken in 1941, showing more than 25 percent of ground surface covered by vented sand (small white I 1 KILOMETER spots and thin linear zones) near Marked Tree, Ark. B, Taken in 1959, showing more than 25 percent of ground surface covered by vented sand (small white spots and thin linear zones) near Portageville, Mo. C, Taken in 1940, showing localized venting of sand near Reelfoot Lake, Tenn. Regions with vented sand are outlined. NEW MADRID SEISMIC ZONE 29 is J. 1 O——O FIGURE 20. — only in exposures cut into the subsurface. A simple, very common type of intrusion having an earthquake origin is a near—vertical, wedge-shaped, sand-filled dike. At many places in the region of vented sand, the clay—rich topstra- tum is cut by vertical dikes that are spaced tens to hundreds of meters apart. The dikes extend upward from 1 Kl LOMETER Continued. the substratum. Dike widths are several centimeters near the substratum; widths commonly narrow upward to an apex near the ground surface. The sand in the dike is generally structureless and can contain clasts of top- stratum carried upward; the larger clasts are often oriented vertically. 30 EARTHQUAKE-INDUCED LIQUEFACTION FEATURES IN SOUTH CAROLINA AND THE NEW MADRID SEISMIC ZONE 1 KILOMETER FIGURE 20. —Continued. Combinations of dikes and sills are also common in the only slightly deformed clay beds, but locally thin clay topstratum. The sills generally follow bedding planes or beds can be strongly warped. Figure 21A shows a typical other horizontal planes of weakness in the topstratum. relationship of near-vertical dikes connected to a later- Sills tended to form in thin beds of silt or sand beneath ally extensive sill. (The sill extends beyond the photo- NEW MADRID SEISMIC ZONE 31 graph and is at least 25 m long.) The internal layering of this sill is also typical of many of those we have studied. Individual laminae are composed of small pieces of char- coal or of much finer grained sand and silt. (See figs. 213 and 210.) A single laminae of silt or very fine sand can have a length as long as 10 cm. Lamina made up of pieces of charcoal can be much longer, and lengths of 300 cm are not unusual. In some places, the sills are structureless, having no traces of bedding, and contain many clay clasts in a sand matrix; in other places, sills have graded bedding with clay clasts concentrated along the base. The absence of bedding or the presence of graded bedding seems quite understandable; however, the pres- ence of planar strata of fine sand and silt within a much coarser sand cannot be explained by us with any degree of confidence. (Possibly the planar stratification develops by repeated intrusions of fluidized sand into an open crack.) Most certainly, however, sills having stratified bedding are common earthquake-related features that resulted from intrusion of liquefied substratum sands. (Sills that have stratified and graded bedding originating from earthquake-induced liquefaction of much deeper source beds have also been observed in the South Caro- lina study at sites HW and BLUF on fig. 1.) The clay clasts in the sills are generally angular, suggesting a brittle or shattering mode of breakage of the clay stratum from which the clasts were derived. This brittle mode of breakage also suggests that when the stratum was “shattered” the clay stratum was de- watered significantly from the initial depositional condi- tion. Such shattering indicates forceful intrusion and thus is not equivalent to the process causing formation of syndepositional soft-sediment deformation features (dis— cussed later). We have observed that the shattered clay strata can have a consistency that is so soft that a person can force his thumb a few inches into a stratum. Sills in the topstratum at depths of about a meter or less below the ground surface may be very wavy in vertical section and can thin and thicken dramatically within a meter, producing bulges at the surface. Sills can be as much as 0.5 m thick near the surface. Such large thicknesses seem less common at greater depths. Earthquake-induced sand dikes that cut the upper substratum sands and the lower topstratum are shown in figure 22A, which is a schematic depiction of a vertical ditch bank exposed about 15 km northwest of Marked Tree. The exposure also illustrates many of the other common forms of intrusions in the topstratum. In the FIGURE 21. — Sand dikes and sills, interpreted as having originated b by liquefaction and flowage during the 1811—12 earthquakes. A, Overview and line drawing of typical dikes and sills. Rectangle shows area of figure 213. B, View showing detailed layering in sill. 0, Very close View showing detailed layering in sill. O———D Injected sand 0 50 INCHES H—~—H 0 100 CENTIMETERS 2 INCHES l | 5 CENTIMETERS 32 EARTHQUAKE-INDUCED LIQUEFACTION FEATURES IN SOUTH CAROLINA AND THE NEW MADRID SEISMIC ZONE GROUND SURFACE BED ——‘/‘ —\’/' i_.gl —_l. y d— __4_ \ ——+ l t Clay, medium gray, blocky; altered by 44> + a i -—l + soil processes 'l'l'l'l'l'l'l ’5-_clay clastslx'f '- Sand, fine- to medium- grained, clean, orangish- brown, massive Clay, pale-blue, blocky, _ —1——_ _ f —‘;_ — T —L'_ G micro-fractured, well 1 I laminated at base Sand, medium- to coarse-grained, clean, prominent foreset beds E Sand, fine-grained, medium brown, silty, contains planar crossbeds ————-————————TOPSTRATUM ———_————————————————————-» Clay, highly plastic, grading up to sand, fine-grained, silty, bluish-gray, massive ( Clay, sandy, coarsening upward to sand, fine-grained, bluish-gray, weakly laminated Unconformity Sand, very fine grained, silty, bluish-gray, well laminated at base with carbonaceous partings composed of charcoal grains <-———-—-SUBSTRATUM-————+f——-—_———-———- Médifirfiééfid. Sand, medium-grained, clean buff-brown with yellow stains, crossbedded, contains wood (dated at 12,000 years before present) 0 3 FEET F—#1 0 l METER N0 VERTICAL EXAGGERATION FIGURE 22.—Section showing Holocene sediments (topstratum) and underlying Wisconsinan braided-stream sands (substratum) in ditch about 15 km northwest of Marked Tree, Ark. Earthquake-induced intrusions cut section at many places. A, Schematic diagram of stratigraphic relationships and earthquake—induced liquefaction fea- tures (numbered 1 through 5). Feature 1—Dike of medium sand that cut: substratum and topstratum. Features 2 and 3—Intruded dikes and sills o massive, clean, medium sand. Feature 4 —Dike of medium sand and largi clasts from bed G. Feature 5—Dikes of medium sand, truncated b: unconformity. Feature 6—Pseudonodules collapsed into bed D. NEW MADRID SEISMIC ZONE 33 Bed C intruded sand (feature 3) W“; my 9% vents (feature 1) small dike (feature 5) FIGURE 22.—Continued. B, Photo graph of beds A—D, showing sand oriented vertically in figure 22B. Knife is 12 cm long. E, Photograph of intrusion (feature 3). Knife is 12 cm long. C, Photograph of vents part of feature 4, showing clay clasts in sand matrix intruded into bed H. (feature 1) cutting substratum sand (bed A) and bed B. Knife is 12 cm Knife is 12 cm long. F, Photograph of dike of unknown origin (feature 5), long. D, Photograph of plan view of bed B, showing intrusion cutting through bed C and truncated by bed D. Coin diameter is about structures caused by feature 1; the plan view is in the area of the knife 1 cm. 34 EARTHQUAKE-INDUCED LIQUEFACTION FEATURES IN SOUTH CAROLINA AND THE NEW MADRID SEISMIC ZONE upper part of the substratum (bed A, fig. 22A), small dikes branch out from a large dike (feature 1), cut through the basal topstratum bed (bed B) at horizontal intervals of 0.5 to 1 m, and extend upward about 0.5 to 1 m. However, a few dikes and sills have intruded at much higher levels (features 2, 3, and 4). At places nearby (not shown) dikes extend to the surface, and sand has been vented to produce sand blows. The dikes and sills shown on figure 22A as features 1 through 4 contain clean, structureless, medium-grained sand. The edges of the intrusions are very sharp in clay-rich beds (such as beds C, D, and G). Edges are generally less distinct in beds of clean permeable sand. Dikes commonly terminate in a permeable sand bed (bed H); near the terminus there are often numerous clasts of clay-rich material from the subjacent bed. Features labeled 1 through 4 in figure 22 are probably earthquake—induced because (1) they are widely distrib- uted (common for tens of kilometers), (2) they contain evidence of intrusion by large volumes of water- saturated sediment (dikes and sills are commonly up to 15 cm wide), (3) there is evidence of forceful intrusion (clean, medium-sized sand containing large clay clasts), and (4) they are found in sites where artesian conditions are unlikely. Because of the lack of weathering of sand in the intrusions near the ground surface, we believe that features 1 through 4 probably formed during the 1811—12 earthquake. The dike shown as feature 5 has an uncertain origin. Three small dikes that are truncated at the contact of beds C and D were exposed in a 25—m section exposed along the ditch but were not found in other nearby exposures of beds C and D nor in the lowermost portion of the topstratum at exposures further away (where beds C and D cannot be traced). The dikes contain a large amount of silty fine sand and cannot be traced far down into substratum sands. From this information, we inter- pret that the dikes quite possibly originated due to springs formed near the base of a streambank or, less likely, as slump-related features. Feature 6 (pseudonodules) is discussed in the next section of the paper. FEATURES OF UNKNOWN OR NONEARTHQUAKE ORIGIN The principal features in this category include sand boils, mima mounds, load structures, sand dunes, “deer licks,” and sand ridges on point-bar deposits. Some of these features can be distinguished from sand blows on aerial photographs. Others may remain uncertain in their origin even after field studies. SAND BOILS During floods that occur every few years, sand boils originate due to artesian flowage beneath levees. Sand boils are common in lowlands near levees along the large rivers, particularly the Mississippi River (Kolb, 1976), and are generally restricted to the areas within 0.5 to 1 km of the levees. (See fig. 15.) The sedimentary structures and morphologies of sand boils are very similar to and may not be distinguishable from those of (earthquake—induced) sand blows. For example, both processes vent sand to the surface from source beds at depth. The stratigraphic position of the bed that provided the sand can be used to indicate origin at some places. In a sand boil, the sand on the surface commonly can be traced to a sand bed that immediately underlies the cohesive (and thus relatively impermeable) topstratum. In contrast, the source bed for a sand blow may be much deeper. By itself, this criterion is of limited value and generally is best used in a context that includes tests to determine the earthquake-induced liquefaction susceptibility of the various beds (discussed later). The shape of the vent in plan view may help distin— guish between sand boils and sand blows. Both sand boils and sand blows can have circular vents; however, many sand blows have linear vents that follow large fissures. Where large sand-filled fissures widen downward and extend for tens to hundreds of meters laterally, they are probably vents associable with earthquake-induced liq- uefaction (providing the possibility of nonseismic slump- ing can be eliminated as the source of the fissures). Sand boils have vents whose diameters range from 3 cm to greater than 1 m. Numerous small sand-filled fissures or tubes can be connected to the main vent of a sand boil; clay clasts up to 7 cm in diameter, derived from sidewalls, have been observed within the vent. The upper parts of the vents (as deep as 1 m or more below the original ground surface) of sand boils may contain stratified deposits of sand layered with other materials that fell into an open hole. A nonearthquake origin can be proven at some places because of the age of the materials in the vents. For example, the presence of agricultural produce such as rice or soybeans far down in the vent virtually eliminates an association with historic earth- quake origin in the New Madrid region, especially if the vent is within 1 km of a levee. (Soybeans and rice have been cultivated only within the past 50 years or so, much postdating the last liquefaction-producing earthquake, the 1895 Charleston, Mo., earthquake.) MIMA MOUNDS Mima mounds (sometimes called prairie mounds) are domes of sand—rich material, usually less than 30 m in diameter and 1 m high, that were not formed by venting; NEW MADRID SEISMIC ZONE 35 in exceptional cases the domes are as much as 1.7 m high but have diameters of only 10 to 12 m. Mirna mounds are present in alluvial lowlands (especially in the northern parts of the St. Francis and Western Lowlands Basins, north of the town of New Madrid) and are also in upland areas west of the Western Lowlands (fig. 13). The origins of mima mounds are not understood. In many upland areas, the mima mounds are formed on nonliquefiable deposits and therefore are of nonearthquake origin. Mirna mounds on alluvial lowlands can be identified as not resulting from earthquakes if excavation shows an absence of vents to connect the mounds to source beds below (Fuller, 1912, p. 80). On aerial photographs, mima mounds can often be distinguished from sand blows by criteria illustrated in figure 23, which is an aerial photograph of mima mounds taken in the northern part of the St. Francis Basin. These criteria are regularity of spacing, alignment, and size. In contrast, sand blows are typically irregularly spaced, have widely differing sizes (heights and diame- ters) at locations nearby, and are not aligned along such precisely defined curves. Comparison of sand blows formed on point-bar deposits (fig. 20C) with figure 23 illustrates the contrast. Locally it can be difficult to distinguish between sand blows and mima mounds on aerial photographs, and excavation is required to examine for feeder vents or other evidence of origin. Mima mounds in the vicinity of the St. Francis Basin characteristically have well- developed soil horizons that obviously predate the 1811—12 earthquakes and in addition are slightly cemented, making them difficult to auger using hand tools. LOAD STRUCTURES Many Holocene fluvial deposits in the Central United States have abundant syndepositional, soft-sediment deformation features known as “load-flow” or simply “load” structures. Load structures are bulbous down- ward intrusions of sandy or silty material into underlying weaker, finer grained muddy sediment. Two common types of load structures occur in the topstratum of the St. Francis Basin—pseudonodules and load-casted ripples. Pseudonodules occur when overlying sandy or silty sed- iments become detached and sink to become isolated subspheroidal bodies in the underlying clayey bed. Pseudonodules are usually found laterally adjacent to other undetached load structures (Allen, 1984, p. 359—360). Pseudonodules were experimentally produced in the laboratory by Kuenen (1958) by hammering a container in which sand overlies water-saturated, very soft clay. (See fig. 24.) Sims (1975) correlated subspheroidal pseudonodules found in modern lake sediments, similar to those pro- duced by Kuenen (and some possibly morphologically the same as those produced by Kuenen), with known earth- quake events. Sims argued that structures such as those produced by Kuenen could be interpreted as earthquake- induced if (1) they occur in a seismically active region, (2) they are restricted to specific stratigraphic horizons, (3) they are correlative over large areas within a sedimen- tary basin, and (4) there is no detectable influence of slope movement or failure. However, pseudonodules similar to Kuenen’s can form without shaking by the gravity-induced instability of denser sediment overlying less dense sediment (Allen, 1984, p. 363). The degree of soft-sediment deformation is controlled by the difference in densities between the two adjacent layers and the strength of the underlying layer. Sand deposited rapidly over water-saturated, muddy or extremely soft clay is ideal for deformation. In the case of load-casted ripples, sandy or silty intrusions form because of the unequal loading of migrat- ing ripples of sand on a clayey mud substratum. Load- casted ripples show progressively deformed radial inter- nal lamination caused by the rotation of the ripple cross-laminations as the ripples sink (Dzulynski and Walton, 1965, p. 146—149). The asymmetry reflects cur- rent direction, as illustrated in figure 25. The develop- ment of load-casted ripples requires local deformation synchronous with deposition of overlying sand, and therefore load-casted ripples cannot likely be related to earthquake events. The distinction between possible earthquake-induced load structures and those produced by rapid sedimenta- tion is illustrated in a ditch exposure near Marked Tree, Ark. The section in plate 1A is composed of bluish clays interbedded with layers of sand, apparently related to intermittent crevasse delta sand deposition in a water- filled swale as illustrated in plate 13. Small, deltalike sand bodies formed convex-upward sand lenses contain- ing climbing ripple cross-laminations. The lenses are coarser upward, fine toward the edges, and are laterally adjacent to layers of pseudonodules (25—50 cm long and 5—25 cm Wide) made up of similar grain sizes. The base of each sand lens has load structures, including load-casted ripples (pl. 13 ). The load structures make up a greater percentage of each sand lens as it thins toward the edge (see north-south View of pl. 18); downstream, each sand lens apparently grades into the pseudonodules. (See east-west view of pl. 1A.) The cross-lamination in the sand lenses has a gradational contact to the deformed ripple cross-laminae in the underlying load structures, whereas ripple cross-laminae above and laterally adja- cent to the load structures are undeformed. (See north- south View of pl. 13.) The pseudonodules are internally ripple cross—laminated, and some have load-casted ripples at the base. Isolated pseudonodules with the 36 EARTHQUAKE-INDUCED LIQUEFACTION FEATURES IN SOUTH CAROLINA AND THE NEW MADRID SEISMIC ZONE 0 1 MILE I I, 0 1 KILOMETER FIGURE 23. —Aerial photograph of mima mounds in northern part of St. Francis Basin. Mima mounds often appear as trails of light dots and are commonly formed on slightly elevated ridges of point-bar deposits. internal fabric of load-casted ripples have an asymmetry the sand lenses. The clay surrounding the pseudonodules reflecting a current direction about the same as that for has streaks of highly contorted silt, indicating flowage NEW MADRID SEISMIC ZONE 37 Water or an 0 5 INCHES a 0 10 CENTIMETERS FIGURE 24.—Pseudonodules formed by shaking, from Keunen (1958). A layer of sand (unit 1) overlies very soft clay (unit 2) in A. With shaking, pseudonodules developed (B and C) and became completely enclosed in clay (D and E). Note the destruction of layering from C to D. This deformation is due to sinking of the entire sand layer into the very soft clay and also to localized sinking caused by uneven loading. around the pseudonodules. The lower portion of the sequence of sediments in the trench is brecciated and faulted; the breccia, including pseudonodules, is sur- FIGURE 25.—Development of load-casted ripples, caused by ripple crests sinking into soft mud. Note the progressive tilt of the internal cross-lamination, which causes the downflow portion to be more steeply inclined than the upflow portion (modified from Dzulynski and Kotlarczyk, 1962). Load—casted ripples can also have an opposite sense of rotation (upflow more steeply inclined than downflow), as evidenced in field observations in the St. Francis Basin. rounded by a coarse-grained sand that has been injected from beneath. These larger scale deformation features are truncated by the uppermost sand lens (sand unit X), which is also laterally equivalent to pseudonodules. The load structures in plate 1A are interpreted as synsedimentary in origin and not as earthquake-induced on the basis of the following criteria: (1) The pseudonod- ules are gradational into the sand lenses, including load-casted ripples, with the same sense of flow direc- tion, (2) there are several layers of pseudonodules later- ally equivalent to largely undeformed sand lenses, and (3) the recurring conditions of sedimentation (rapid pro- gradational deposition of sand over soft clay) were con- 38 EARTHQUAKE-INDUCED LIQUEFACTION FEATURES IN SOUTH CAROLINA AND THE NEW MADRID SEISMIC ZONE ducive to this type of soft-sediment deformation. Although load structures such as these may be formed by earthquakes, their repeated occurrence in this sequence (as also shown by Allen, 1984, figs. 9, 10; or in Coleman and Prior, 1980, figs. 15, 21, 22, and 32) and their apparent localized occurrence argue for a depositional origin. (The injection features, brecciation of clay, and faulting in this exposure that crosscut the syndeposi- tional features are probably of earthquake origin.) Pseudonodules formed by earthquake shaking would be similar in shape to those formed by depositional processes, because the mechanism of sinking is similar. The environmental conditions conducive to pseudonodule development are also ideal for the formation of convo- luted bedding, fluidization dikes, and slumping. Any depositional environment in which coarse-grained sedi- ment is introduced rapidly in otherwise quiet, standing- water conditions, such as fluvial overbanks, lacustrine or marine deltas, and submarine fans, may include these features as part of its regular sedimentary record. We suggest that the difference between syndepositional deformation and earthquake-induced deformation would be in the relationship of the pseudonodules to the sur- rounding sediments. Intense earthquake shaking might cause collapse of an entire sand layer into clay, rather than only the thin edge, and a small portion of the base of a sand lens; in addition, the structures should be wide- spread in deposits having the same age. A widespread distribution of load structures formed at the same time is difficult to prove in most fluvial depositional environ- ments. OTHER FEATURES Field examination is often required to distinguish between sand blows and small aeolian sand dunes, par- ticularly on high terraces having very sandy surface soils. Another feature requiring field examination is a “deer lick,” which is a very light—colored area, up to 15 m in diameter, caused by a high sodium concentration in poorly drained silty soil on level ground (Brown and others, 1973). They are relatively common in western Tennessee. Aerial photographs often show arcuate ridges of sand on modern and Holocene point-bar deposits, as illus- trated in figure 200. These sand ridges form where the fine-grained topstratum is especially thin, and thus more quickly eroded, or was never present over the point-bar deposits. Field excavations are often required to deter- mine if the sands have been vented versus exposed by erosion. LOCAL GEOLOGIC CONTROLS ON PRODUCTION OF VENTED SAND Some of the geologic controls on production of vented sand during the 1811-12 earthquakes were first noted by Saucier (1977) and were later described in much more detail by Obermeier (1988, 1989). Principal controls are topstratum thickness and lithology, substratum sand grain size (and, indirectly, permeability), susceptibility to liquefaction of source sand (as related to age of the sediment and measured by the Standard Penetration Test (SPT)), and earthquake accelerations. The influence of these parameters was determined by hundreds of test borings, which were used to formulate a general notion of the geologic setting where sand was vented and to back-calculate 1811—12 earthquake accelerations. Along the border where sand blows developed (fig. 14), the Simplified Procedure of Seed and Idriss (1982) was used to estimate peak earthquake accelerations. Accelerations along the border probably did not exceed 0.25 g (Ober- meier, 1988, 1989). Substratum sands in the St. Francis Basin are typi- cally at least moderately dense (engineering sense). N1 values (SPT blow counts adjusted to an overburden stress of 1 ton/ftz) in the depth range most likely to liquefy (5—15 m) are rarely less than 10, and median values are generally about 25. Other basic data that should be kept in mind during this discussion of geologic controls for liquefaction fea- tures of the 1811—12 earthquakes are that the substratum sands generally have a narrow range of thickness (between 25 to 40 m); the epicenters of the three major shocks in 1811—12 were almost certainly somewhere within the areas where large volumes of sand were vented; and the MS values of the three major shocks were probably about 8.5 to 8.7. TOPSTRATUM THICKNESS In general, where nonliquefiable topstratum thickness exceeded a critical threshold, there was increasing resistance to development of sand blows and venting of large volumes of sand (Obermeier, 1989). A topstratum thicker than 10 m presented a major barrier to more than scattered venting, even in close proximity to the epicen- ter. No sand blows formed where the topstratum was thicker than about 15 m. Within 20 to 25 km of the epicentral regions, a 5- to 6-m-thick topstratum was insufficient to prevent severe, extensive venting. At more distant localities, near the border of sand blows, a 3- to 4-m thickness of topstratum noticeably reduced sand-blow development. Where a thick topstratum restricted venting to the surface, intrusions within the lower part of the topstratum were still plentiful. TOPSTRATUM LITHOLOGY Even though the great majority of our field observa- tions were at sites where the topstratum was dominantly clay, we observed enough areas where the surficial OVERVIEW OF STUDIES 39 deposits were sand rich to make some general observa- tions about the formation of craters and vented-sand volcanoes. The largest craters occurred Where the top- stratum was most sand rich at the ground surface. The stratigraphy in the craters is generally not well defined in comparison to craters in South Carolina. The largest clay clasts are at the base, and clast size decreases upward in a structureless sand matrix. The transition from graded zone to the overlying laminated bedding is difficult to find in some craters; the laminated bedding is generally defined only by thin, wispy layers of slightly different sizes of sand and silt. There is no evidence of organic material accumulating in an open hole, as in South Carolina. We did not observe V— or U-shaped fractures in regions of craters, as in South Carolina. Partly for that reason, and partly because of the difficulty of making moderately dense, well—graded sand flow extensively after being liquefied, we suspect that the mechanism for formation of craters in the New Madrid region differs from the mechanism in South Carolina, where the erup— tive craterlets were abundant. In the New Madrid region, the craters may have formed primarily because of abrasion and widening of the sidewalls as fluidized sand and water vented for a prolonged time. Similarly, large craters did not tend to form extensively in the clay-rich topstratum in the New Madrid region because of the difficulty of abrading the sidewalls. SUBSTRATUM GRAIN SIZE Medium-grained and coarse-grained, clean, well- graded sands greatly predominate in the substratum, in the depth ranges that were liquefied in 1811—12. Other factors being equal, the most extensive development of sand blows corresponded to areas underlain by medium- grained sand. Much smaller and more scattered sand blows developed over coarse-grained substratum sands than over medium-grained sands. Coarse-grained sub- stratum sands have much higher permeabilities than the medium-grained sands; possibly the higher permeability permitted pore pressures of the liquefied sands t0 dissi- pate rapidly enough to curtail sand—blow development. RESISTANCE OF SOURCE SAND TO LIQUEFACTION Only small regional variations in the relative density of the late Quaternary substratum sands are found in the St. Francis Basin; these sands are typically at least moderately dense and thus moderately difficult to liq- uefy. However, historical accounts (Street and Nuttli, 1984) and data by Fuller (1912) show that 1811—12 sand blows were common on modern flood plains far from the St. Francis Basin. The modern flood plains are underlain by younger and generally looser and more liquefiable sand beds than those in the St. Francis Basin (Obermeier and Wingard, 1985), thus explaining the development of sand blows much further from the epicenters. Liquefaction features in the New Madrid seismic zone have not been observed to be induced by numerous historic earthquakes having mb of 5.3 to 5.5, or by a single earthquake having mb of 6.0; in 1895, many sand blows (generally small) were produced by an mb 6.2 earthquake Whose epicenter was near Charleston, Mo. (Obermeier, 1988). These sand blows developed in allu- vium that is slightly less susceptible to liquefaction than that at most other places in the New Madrid seismic zone, excluding the modern (<500 yr) point—bar and sand-bar deposits of the rivers in the region. Thus a reasonable earthquake threshold is approximately mb 6.0 for small liquefaction features in braided stream and meander belt deposits, excluding very young alluvial deposits. OVERVIEW OF STUDIES Geologic criteria have been developed and geologic controls have been evaluated for earthquake-induced, level-ground liquefaction features in alluvium of coastal South Carolina and the New Madrid seismic zone. Many different types of earthquake features occur in these areas, in addition to features of unknown or nonseismic origin that might be interpreted as having an earthquake-induced origin. GEOLOGIC CRITERIA Assigning an earthquake origin to possible sand blows generally requires that four criteria be satisfied: 1. The features must have sedimentary characteristics that are consistent with earthquake-induced liquefaction origin; that is, there is evidence of an upward-directed, strong hydraulic force that was suddenly applied and was of short duration. 2. The features must have sedimentary characteristics that are consistent With historically documented obser- vations of earthquake-induced liquefaction processes. 3. The features must occur in ground-water settings where suddenly applied, strong hydraulic forces of short duration could not be reasonably expected except from earthquake-induced liquefaction. In particular, such set— tings are extremely unlikely sites for artesian springs. 4. Similar features must occur at multiple locations, preferably at least within a few kilometers of one another, having similar geologic and ground-water set- tings. Where evidence of age is present, it should sup- port the interpretation that the features formed in one or more discrete, short episodes that individually affected a 40 EARTHQUAKE-INDUCED LIQUEFACTION FEATURES IN SOUTH CAROLINA AND THE NEW MADRID SEISMIC ZONE large area and that the episodes were separated by long time periods during which no such features formed. As fewer of these elements are satisfied, confidence in interpretation of an earthquake origin generally dimin- ishes. Considerable reliance has been placed on the second element for interpreting an earthquake origin in coastal South Carolina and the New Madrid seismic zone. If, however, all the other criteria are unequivocally satisfied outside these geographic areas, an earthquake origin can still be ascertained in areas that have not had historic earthquakes. Criteria based on engineering analysis may be useful for diagnosis of the origin of features. To illustrate, if the source sand bed can be identified at a site of possible liquefaction, and the sand bed proves to be nonliquefiable on the basis of an engineering analysis, then an earthquake—induced origin can be eliminated. As another example, if mineralogical analysis associates vented sed— iment with a deep stratum of loose sand rather than with a shallower sand bed of much higher compactness, and an engineering analysis of nonearthquake-related ground- water flow forces shows that the shallower, more dense sand should have been transported up in preference to the deeper, loose sand, then an earthquake origin may be ascertained. TYPES OF EARTHQUAKE FEATURES In both coastal South Carolina and the New Madrid seismic zone, earthquake-induced liquefaction features originated in sand deposits that are relatively thick (3—50 m) and contain no or few intercalated silt- or clay-rich strata. At the ground surface there is a cap that is much less permeable than either the subjacent or deeper source sand beds. Properties of the cap have a major effect on the surface expression of the sand blows. In coastal South Carolina, Where the cap is generally a l-m-thick soil that is weakly cemented with humate, the sand blows are expressed as craters surrounded by thin sand sheets; in the New Madrid seismic zone, the cap is generally a clay—rich deposit about 2 to 10 m thick, and sand blows are expressed as sand volcanoes. Both vented and intruded features can be related to earthquake-induced liquefaction. Features characterized by sand vented to the surface include more or less circular, individual sand blows and also long, irregular sand-filled fissures, hundreds of meters long. Where a clay-rich cap exceeds a critical thickness, sand is not vented to the surface; instead, earthquake-induced liq— uefaction is represented only by sand intrusions. Intruded dikes usually have a massive internal structure, whereas sills can contain both graded and laminar bed- ding in coastal South Carolina and the New Madrid seismic zone. Lateral spreads produced by the 1811—12 earthquakes were common. (See Fuller, 1912, p. 48, for a schematic drawing.) We made no effort to locate lateral spreads in the New Madrid seismic zone, but evidence of lateral spreads is described in coastal South Carolina. GEOLOGIC CONTROLS The thickness of clay—bearing or impermeable surficial deposits can be an important control on development of surface venting. In the St. Francis Basin, our data show relations between the distance from the epicenter, thick- ness of topstratum, and development of surface venting produced by the 1811—12 New Madrid earthquakes; near the epicenters, a topstratum thickness more than about 12 m prevented venting, whereas near the farthest limits of sand-blow development, a topstratum more than 4 to 5 m thick greatly restricted development. In coastal South Carolina, a cap exceeding 3 to 5 m thick generally prevented development of sand blows for both 1886 and pre-1886 earthquakes. These differences in critical thick— nesses between coastal South Carolina and the New Madrid seismic zone most likely reflect the influence of factors such as thickness of source sand bed, susceptibil- ity of source sand bed to liquefaction, and earthquake magnitude. Similar relations between critical thickness of surficial cap and development of surface manifesta- tions of liquefaction have been noted by Ishihara (1985). The rate of expulsion of water to the surface while the sand blow was forming possibly controls whether sand blows formed as craters or as sand mounds, but this speculation has not been tested. Certainly, in coastal South Carolina, the sands are generally much looser than sands in the New Madrid seismic zone, and this looser state may have helped create a very thick, water-rich zone during shaking, which was probably the primary source zone during initial, very rapid explusion. Sands in the New Madrid seismic zone characteristically are much more permeable than the marine sands in coastal South Carolina, yet craters are not common features in the New Madrid seismic zone. Thus, the craters cannot be necessarily associated with higher permeability alone of source sands. Vertical cracks formed by desiccation or other pro- cesses may predispose clay-rich sediments to form vented-sand volcanoes rather than craters. Vertical cracks are common in both coastal South Carolina and the New Madrid seismic zone. Source beds for sand blows in the New Madrid seismic zone are predominantly medium- and coarse—grained sands; in the 1811—12 earthquakes, the coarse-grained and thus highly permeable source sands produced fewer and smaller sand blows than medium- to fine—grained source sands. Insufficient data are available to form SUGGESTIONS FOR FUTURE RESEARCH 41 conclusions about influence of grain size on sand-blow size in coastal South Carolina, because almost all sands are fine grained. Geologic age is an important control on liquefaction susceptibility in both the New Madrid seismic zone and coastal South Carolina. Youngest sediments are gener— ally most susceptible to liquefaction, for a given mode of deposition. SUGGESTIONS FOR FUTURE RESEARCH In recent years it has become increasingly clear that detection of liquefaction features is valuable as a tool for understanding earthquake activity. Liquefaction fea- tures can be used to identify strong earthquake shaking and to date the strong shaking events. We have described our interpretations of earthquake- and nonearthquake-related features from field studies in the New Madrid seismic zone and in coastal South Carolina. Still, more work is needed to better identify potential earthquake hazards in these geographic areas. In the study of New Madrid 1811—12 liquefaction features, much was learned that is relevant to any search for paleoseismic liquefaction in moderately thick fluvial sediments of the Central United States. Aerial photo- graphs are useful in a search for features formed in 1811—12, and earthquake deposits predating 1811—12 laid down on terraces having clay-rich surface soils may also be visible on such photographs. However, deposits laid down on terraces having sandy surficial soils have prob— ably been so intensely reworked by wind that the depos- its would be difficult, if not impossible, to identify. Aerial photographs should range from the earliest possible date (generally the late 1930’s and early 1940’s) to about the mid-1950’s. The earlier photographs may show many features destroyed by modern farming, whereas more modern photographs generally have better overall clar- ity. Field checking is generally required to determine the origin of features that on aerial photographs are sus- pected to have an earthquake origin. In particular, in point-bar deposits, field checking is often required to verify the origin of sand that appears to have been vented along slightly elevated, arcuate ridges. On ter- races having sandy surface soils, sand blows are often indistinguishable from sand dunes, and distinctive signs of previous earthquakes may be restricted to long fis- sures that formed near and parallel to scarps along terrace sublevels. Searches in drainage ditches and sand pits are proba— bly the only means for identifying liquefaction features that much predate the 1811—12 earthquakes. The best areas to search can be predicted by evaluating the influence of geologic controls such as sediment age, topstratum thickness, grain size of source beds, and proximity to suspected epicenters. Any search for paleoseismic features in coastal South Carolina and in the Coastal Plain of the Eastern United States should also make extensive use of exposures in ditches; aerial photographs, for example, are useless for locating 1886 and pre-1886 sand blows in South Carolina. Determination of an earthquake or nonearthquake origin for disrupted ground features in the Coastal Plain gen- erally requires a team of people having many skills. In addition to having an understanding of sedimentation processes, soil science, and engineering mechanics, there may also be a need for geochemistry studies because weathering in these humid environments produces bizarre features not previously described in the litera- ture. We have described some weathered and disrupted ground features that could cause confusion, but our catalog is far from complete. Research is also needed to provide criteria for distin- guishing between features having an earthquake- induced liquefaction origin and features having a short— term spring origin. Locations where springs can be easily eliminated as a cause, such as along the crests of beach ridges of coastal South Carolina, are relatively sparse in the Eastern United States. Fluvial terraces in lowlands contain the only potentially liquefiable deposits in most places of interest to paleoseismicity. Possible indicators of origin include the ground failure mode; the nature of the filling in vents, dikes, and sills; geologic characteris- tics of the source beds; and engineering characteristics of the source beds. The relevance of each indicator is discussed below. Ground failure mode.—Ground failure mode includes features such as lateral spreads, single long fractures, and shattered ground at the ground surface. All of these features generally indicate an earthquake origin. Earthquake-induced liquefaction does not always pro- duce these types of features, however, and in many cases they are not easy to recognize in ditch exposures even where they are known to have been relatively common, such as the meizoseismal region of the 1886 Charleston earthquake. Use of techniques that can rapidly develop a three-dimensional View, such as ground-penetrating radar, may prove to be of great value. Nature of filling—Vents associated with an earthquake-induced liquefaction origin generally appear to be filled with a structureless mixture of sand and silt grains and clasts derived from sidewalls and beds at depth. This structureless mixture apparently represents transport through the vent as a slurry. In some places, particularly near the top of the vent, the finer grained material has been winnowed out, thus indicating trans- port on a grain-by-grain basis. For either the slurry or 42 EARTHQUAKE-INDUCED LIQUEFACTION FEATURES IN SOUTH CAROLINA AND THE NEW MADRID SEISMIC ZONE the grain-by-grain mode of transport, it should be possi- ble to place limits on the hydraulic forces that caused the transport and, by means of a flow-potential diagram, calculate whether nonearthquake flow forces could pos- sibly have been the driving mechanism. Numerous observations in the New Madrid seismic zone show a wide variation in the nature of sill fillings caused by earthquake-induced liquefaction. The fillings range from layered bedding to graded bedding to a structureless mixture of sand, silt, and clay clasts; for paleoseismicity interpretations, we suspect that the structureless mixture is associated only with the very forceful injection caused by earthquake—induced liquefac- tion, whereas layered and graded bedding may be asso— ciated with either a spring or earthquake-induced lique- faction origin. In the New Madrid seismic zone, some of the larger sills within 2 m of the ground surface have domed the overlying beds as much as 0.3 m vertically over a horizontal distance of 5 m; such large doming may be unique to earthquake-induced liquefaction. The nature of the fillings in dikes may also be related to an earthquake- induced liquefaction or spring origin. Relevance of the fillings in vents, dikes, and sills can be verified only by research in the field. Geologic characteristics of source beds—Intuition suggests that earthquake-induced liquefaction should be much more effective than springs as a means to destroy original bedding over a large area. This suggestion has not been examined, however, and may be difficult to evaluate in practice. Earthquake-induced liquefaction would also probably produce many more widespread sills and dikes than springs. Engineering characteristics of source beds—The source beds containing the material vented by springs should be located selectively with respect to the ground- water setting and flow forces. For springs, the source beds must be connected to the source of flowage in such a manner that flowage goes toward the vent, and the flowage forces must be large enough to carry material from the source bed. This source bed would be, in general, the uppermost stratum of wide lateral extent with respect to hydraulic connection and would also be the uppermost fine-grained, noncohesive sand stratum. The source bed with regard to earthquake-induced liq- uefaction commonly lies much below (several meters) the uppermost sands of wide lateral hydraulic connection, according to limited observations in deep ditches in the New Madrid seismic zone. Thus, permeability relations may be quite useful for determining the causative mech- anism responsible for venting materials. Standard Penetration Test data that show relative ability to liquefy during earthquake shaking should also prove useful for determining origin at some places. Geologic investigation may also be required to determine origin in areas where Standard Penetration Test data indicate possible source beds that are thin (<1 m) and lie immediately beneath an impermeable cap, because (injected) sills beneath impermeable caps have been observed by us to approach a meter in thickness. RELEVANCE OF LIQUEFACTION FEATURES Recognition of the various features described in this paper, and identification of the most probable origin for each, provides a set of important tools for understanding the paleoseismicity in areas where faults are not obvious at the surface and where historic seismic activity is infrequent. Even where faults are available for study and offsets can be documented, there may be doubt that the offsets were associated with earthquakes; the presence of liquefaction-induced features is a means of verifying strong shaking. The criteria we describe in this paper can be applied to many worldwide geologic settings. We caution, however, that verification of paleoseismic events becomes gener- ally more difficult with increasing age of the event. The distinction between earthquake and nonearthquake liq- uefaction features is often impossible without knowledge of ground-water conditions. 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B p b o O 8 o STOCKTON FAULT 310 Stanislaus River HOHV NOJ.)I30J.S Tuolumne River __SE_CTLOE Merced River BEND IN SECTION San Joaquin River 310 San Joaquin River San Joaquin River BEND IN SECTION 510 BEND IN SECTION SECTION B , 8‘ Kings River peg 9x91 BJB|n_L SECTION c 7 C‘ HOHV CITEIIdSHENVG BEND IN SECTION WHITE WOLF FAULT PLEITO FAULT BEND lN SECTION .1 < ,aq SAN ANDREAS FAULT .8 .5 § § TEAS") VEIS 'IEIAEIT VHS — SHELBW .920 , ox. \\ .- grammar I? ’70’ 50b. o o S” INTERIOR—GEOLOGICAL sunvev, HESTON,VA~1991 35" 3° Base from US. Geological Survey SCALE 1 150° 00° Geology compiled by J.A. Bartow, 1986-87, from - - 10 State base map, compiled 1968, revrsed 1981 1,°_, ,_, H ,_, ,_. 4 2° 3° 4,0 M' LES L05 Angeles 09113111119111 ofWater 811d Poyver (1975. Lambert Conformal Conic ro'ection based fig. 25. MM), Harding (1976, fig. 3a), Jennlngs (1977), p I 1 o 1 o 20 30 4o 50 Dibblee (1979a), Herd (1979a), Webb (1981, fig. 3), and on standard parallels 33° and 45° l—Il—ll—Il—ll—l CONTOUR INTERVAL 500 FEET NATIONAL GEODETIC VERTICAL DATUM OF 1929 60 KILOMETERS j Bartow(1984, 1985) FEET SEA LEVEL CU WALTHAM CANYON FAULT OTs TJ 9V FEET SEA LEVEL 10,000 20,000 COALINGA ANTICLINE Tng (7) 21> ORTIGALITA FAULT f : a We we, ’ 9% ‘18 \ mu mar... sassmwmaa Rx_.“_r"~___7 1:71. . 11 m l FAULT ZONE SAN JOAQUIN CORRELATION OF MAP UNllS QUATERNARY N eogene CENOZOIC TERTIARY Paleogene CRETACEOUS AND MESOZOIC JURASSIC MESOZOIC AND PAIEOZOIC DESCRIPl ION OF MAP UNI l S Alluvial and lacustrine sediments (Quaternary) Alluvial deposits, sedimentary rocks, and minor volcanic rocks, undivided (Quaternary and Tertiary)—Used on cross sections only and consists of units Os and Ts. Dashed line shows approximate boundary between Paleogene and Neogene Volcanic rocks (Tertiary) Sedimentary rocks (T ertiary)—Marine and nonmarine rocks. Dashed line shows approximate boundary between Paleogene and Neogene Great Valley sequence (Tertiary to Jurassic)—Melanges of sedi- mentary rocks Franciscan Complex (Tertiary to Jurassic)—Melanges of sedi— mentary rocks, serpentinite, and blueschist in a sheared matrix and coherent sedimentary rocks Ultramafic rocks (Cretaceous and Jurassic) Crystalline rocks of the basement complex (Mesozoic and Paleozoic) Approximate area of structural arch Contact—Queried where uncertain in cross sections only Fault—Dashed where approximately located; dotted where concealed; queried where uncertain. Bar and ball on downthrown side; R on upthrown side of reverse fault; arrows indicate direction of relative movement. Relative lateral movement on cross sections only: A, away from observer; T, toward observer Thrust fault—Dotted where concealed, Sawteeth on upper plate Fold—Dotted where concealed. Showing approximate trace of axial plane; arrows indicate direction 04f plunge Anticline Syncline Boundary of structural region (see text)—Dashed where approxi— mately located Location of stratigraphic column—Number refers to column number on plate 2 SAN JOAQUIN VALLEV SYNCLINE San Joaquin River PROFESSIONAL PAPER 1501 PLATE 1 491% #5 PC, scar; No. 1601 I ( e) F313 2 I) 1992 can 7» a 5 ~LI.) 3 §§ 5% , s; A n:< m ELL be 2 bC FEET METERS ’ SEA LEVEL SEA LEVEL SAN JOAQUIN VALLEY SYNCLINE TURK ANTICLINE VERTIICAL EXAGGERATION X2 OTs l | I I I | l l I I | | | I | I I l 10,000 5,000 20.000 3! OT bC FEET METERS s _ ’ SEA LEVEL —— SEA LEVEL 10,000 — — — 5.000 — 20,000 _ ; 30,000 _ : -10,000 — 40,000 _ — 50000 ‘15-000 0 SAN ANDREAS FEET SEA LEVEL 10,000 20,000 FAU LT RECRUIT PASS FAULT GENERALIZED GEOLOGIC MAP AND CROSS SECTIONS OF THE SAN JOAQUIN VALLEY AREA, CALIFORNIA VERTICAL EXAGGERATION X 2 GRE E LEY FAULT SYSTEM POSO CREEK FAULT VERTICAL EXAGGERATION X 2 SOURCES OF lNFORMATlON A—A' Wentworth and others (1984, fig. 4), Bartow (1985), Wentworth (written commun., 1986) B— ' Hoots and others (1954, pl. 6), Wentworth (1985) C—C’ Church and Krammes (1957), Vedder (1970). Bartow (1984) D— ' Church and Krammes (1958), Davis (1986) METERS SEA LEVEL 5,000 DEPARTMENT OF THE INTERIOR U.S. GEOLOGICAL SURVEY PROFESSIONAL PAPER 1503 PLATE 1 82° 83° 84° 85° 86° 87° 89° SCALE 1:1000 000 50 MILES 25 F’——r 25 ERS 50 KILOMET 25 25 a? M if” _- v’? W ," s *4va “1% 8% &v% ml s l 85" 84" 83° 82° 86° 87° l‘Genlogic quadrangle name is HAMMACKSVILLE, 3Geologic quadrangle name is MODEL. 88° 2Genlogic quadrangle name is HAZEL. 89° lGenlogic quadrangle name is NEW MADRID SET 39° — _ o 7 3 38° — MAP OF KENTUCKY SHOWING 71/2’ QUADRANGLES DEPARTMENT OF THE INTERIOR U. S. GEOLOGICAL SURVEY ORESTIMBA CREEK SERIES AND AREA SUBSERIES1 PALEO— BATHYMETRY 3 DM SM NM SW STRATIGRAPHY SW NE SYSTEM AND SUBSYSTEM uvium HOLOCENE PLEISTOCENE O C ]> _4 ulare ormation u are F PLIOCENE "Del- mon- tian“ \ \ Fanglomerate Oro Loma Formation (Carbona unit of Raymond, 1969) Mehrten Formation Mohnian NEOGENE Luisian MIOCENE Relizifi . Saucesian Valley Springs Formation OLlGOCENE Zemorrian TERTIARY Poverty Flat Sandstone Kreyenhagen Kreyenhagen PALEOGENE Narizian EOCENE Domengine Sandstone Domengine Sandstone "Penutian" Ulatisian : Tesla Laguna Seca Formation BUI't'an Formation PALEOCENE Cheneyan w 1 Series and subseries boundaries from Berggren and others (1985). 2 Stage boundaries as follows: top of "Delmontian," Obradovitch and Naeser (1981); "Delmontian"—Mohnian, MohnianvLuisian, and Luisianr Relizian, Barron (1986); Relizian-Saucesian, Miller (1987); Saucesian-Zemorrian, Turner (1970), adjusted for new constants according to Dalrymple (1979), and Poore and others (1981); Zemorrian—Refugian and Refugian-Narizian, Poore (1980); Narizian-Ulatisian, Ulatisian— Penutian, Penutian—Bulitian, and Bulitian—Ynezian, Almgren and others (1988); Ynezian—Cheneyan, Poore (1980). 3 DM, deep marine (below shelf depth); SM, shallow marine (shelf depth); NM, nonmarine. Short dashes (- — —), water depth inferred; queried where uncertain " Based on data from Atwater (1970), Atwater and Molnar (1973), Dickinson and Snyder (1979), Page and Engebretson (1984), and Engebretson and others (1985). 5 From Huber (1981). 6 Based on data from Evemden and others (1964), Turner (1970), Prowell (1974), Stewart and Carlson (1976), Dickinson and Snyder (1979), Moore and Dodge (1980), Huber (1981), and Drinkwater (1983). 7 Modified from Haq and others (1987), adjusted to chronology of Berggren and others (1985). TA1 through T133 represent supercycles in the sequence chronostratigraphy of Haq and others (1987). 3 Informal name of local usage. 9 Of Miller and Bloom (1937). LOS BANOS- ORO LOMA AREA STRATIGRAPHY NORTHEAST VALLEY MARGIN PALEO— BATHYMETRY DM SM N BATEQLMEST'RY 3 STRATIGRAPHY NE DM SM NM SW NE Mehrten Table Mountai Latite Formation prlngs Fm. Valley Springs Formation Formation Tes|a(?) Formation Moreno Formation VALLECITOS SYNCLINE STRATIGRAPHY Nonmarine rocks Temblor L 1 Formation Tumey Formation Shale member Kreyenhagen o Arroyo Hondo hale Member Cantua Sandstone Member Cerros Shale Member Moreno Formation Sandstone member w. 5”. Lodo Formation KETTLEMAN HILLS NORTH DOME PALEO— BATHYMETRY 3 DM BATmLhEST—Rys STRATIGRAPHY DM SM NM NW SE Tulare Formation San Joaquin Etchegoin Formation Santa Margarita ormation Ridge. McLure Shale Member of Monterey Formation Upper variegated unit 8 Temblor Formation (upper part) ower variegated unit 8 Burbank sand 8 Whepley shale8 Formation part) "Vaqueros" sand 8 "Salt Creek" shale 8 "Leda" sand 8 Tumey Shale Kreyenhagen Lodo Formation Moreno Formation SM NM SW HAN FOR D-TU LARE EAST-SIDE AREA PALEO- BATHYMETRY 3 DM SM NM STRATIGRAPHY STRATIGRAPHY NE Tulare Formation L San Joaquin Kern River Etchegoin Formation Formation McLure Shale Member of Monterey Formation McLure Shale Member Devilwater Sh. and Gould Sh. Mbrs., Monterey Shale Olcese Sand deposits, undivided - Buttonbed Sandstone Member Media Shale Freeman Silt Member Santos e Member (upper part) undivided Agua 85. Bed Santos Shale Member (lower part) Temblor Formation Vedder(?) SS. Mbr'. Cymric Shale Member Wagonwheel Formation Welcome Shale Kre enha en y g Member ale Point of Rocks Sandstone Member Gredal Shale Kreyenhage Member Avenal amoso sand8 Sandstone Lodo Formation Moreno Formation EXPLANATION [ED] Hiatus maps (figs. 5-13) . $2325: Subduction llllllll Wrench faulting Rhyolite """IHIIIIII Andesite or rocks of mixed composition _ Basalt LOST HILLS- DEVILS DEN AREA PALEO— BATHYMETRY 3 DM Approximate time represented by paleogeographic ——-—?—Contact—Dashed where indefinite; queried where un- certain r\/\/\?I\ Unconformity—Queried where uncertain SM NM SW ELK HILLS AREA STRATIGRAPHY NE m Tulare Formation Etchegoin Formation Stevens sandstone 8 Sh. M McDonald Sh. Mbr.8 Devilwater Sh. and Gould Sh. Mbrs., Monterey Shale Media Shale Member 83. M #Sandstone Santos Shale Member Temblor Formation Wygal Sandstone Member Cymric Shale Member Wagonwheel Formation Kreyenhagen Tejon(?) Fm PALEO- BATHYMETRY 3 DM BAKERSFIELD ARCH 10 AREA BATWJST'W STRATIGRAPHY DM SM NM N 3 LI STRATIGRAPHY SM M SW NE Tulare Formation Kern River Formation Etchegoin Fm. and nonmarine deposits, Etchegoin undivided Formation Margarita" Fm. ' 9 Fruitvale Shale 9 Fruttvale Shale Round Round Mountain Silt . Mountain Monterey Shale Olcese Sand Freeman Tecuya Formation Volcanic rocks Silt Temblor Jewett Sand Formation Formation Vedder Tecuya Pleito Formation ? San 2 Z, Emigdio ' Walker Formation Formation KreYenhagen Shale Famoso _- a 1’ . Formation r a ’a a ,L_____ z ”a SAN EMlGDlO MOUNTAINS AREA PALEO— BATHYMETRY 3 DM SM NM TANGENTIAL MOVEMENT Pacific plate: North American plate NORMAL CONVERGENCE Farallon plate: North American plate OBLIQUE CONVERGENCE Farallon or Kula plate: North American plate PLATE TECTONIC EVENTS4 Mendocino triple junction Slight convergence in Pacific and North American migrating northwestward III IIIIIIIIIIIIIIIIIIIIlllllIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIII IIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIII7 Proto-San Andreas fault past San Joaquin basin e motio fl'i‘l San Andreas _| transform Wrench faulting concurrent OCOCDNO) thN—I PROFESSIONAL PAPER 1501 PLATE 2 SIERRA NEVADA UPLIFT RATE 5 mm /yr 0.4 .3 .2 .1 AGE (Ma) 'N EUSTATIC SEA LEVEL ADJACENT AREAS 6 250 200 150 100 50 O METERS Slip concen— trated on San Andreas fault TBS 1) Carson Pass-Sonora Pass 0.) U) C (U I 2 .0 .9 Q Opening of Gulf of California Deadman Pass on San Andreas fault TBZ First movement(?) m w m Western Nevada / eastern California lllllllllllll<—San Emigdio Mountains/ northern Gabilan Range rn II|IIIIIIIIIIIIlIIIllllllllllllllllllllllIlllllllllllllllllIIIIlIllIlIIIIIIl Central and northern lIIIIIII|llll|IIIlIIIIIIIIIIIIIIIIIIIIIIII Central / southern Sierra Nevada — - - -_ {Southe Sierra Nevada Santa Cruz Mountains - Neenach / Pinnacles areas’nn Wm WWW With oblique subduction orocllnal bending of southern Sierra Nevada SOURCES OF STRATIGRAPHIC INFORMATION [Number refers to column number on plate 2 and corresponding area on plate 1] Bartow (1985) Briggs (1953), Lettis (1982), Bartow (1985) Bartow (1985) Phillips and others (1974), Dibblee (1979b), Nilsen (1979), Berggren and Aubert (1983) Rentschler (1985) Woodring and others (1940), Church and Krammes (1959), Sullivan (1966), Graham and others (1982), Kuespert (1983), Bartow (1990) Dunwoody (1969), Bartow (1990) Dibblee (1973b), Graham and others (1982) Berggren and Aubert (1983), Bartow (1990) Church and Krammes (1957), Dibblee (1973b), Maher and others (1975) Bartow and McDougaIl (1984) Hluza (1960), Nilsen and others (1973), Davis (1983, 1986), DeCelIes (1986), Lagoe (1986) CORRELATION OF CENOZOIC STRATIGRAPHIC UNITS OF THE SAN JOAQUIN BASIN WITH TECTONIC, VOLCANIC, AND SEA-LEVEL EVENTS ?5 [7(9 595121777 6:: N U! (I 901 2. g; ) (or! L