/j /. 1 . 7 ' r J Issued Decembei I U. S. DEPARTMENT OF AGRICULTURE, BURI \r OF PLANT INDUSTRY— Circular No. 43. 1'.. 1 GALLON AY, Chief of Bureau. THE DETERIORATION OF CORN IN STORAGE. J. W. T. DUVEL, Assistant i\ Charge of Laboratory Methods, I }r \i\ Standardization. SHINGIOH : OOVIHNUtNV PHlNTlNG ( ■ DC^M^^T" DEPOSITORY BUREAU OF PLANT INDUSTRY. Chit/ of Bureau, Beverly T. Galloway. Assistant Chief of Bureau, Albert F.Woods. Editor, J. E. Rockwell. CLnf Clerk, James E. Jones. [Cir. 43] 2 B. P. I. -521. THE DETERIORATION OF CORN IX STORAGE/ INTRODUCTION. In February, L909, special investigations were begun at Baltimore, M\ thermometer .1, was 56° F., which was within one- half degree of the highest temperature recorded at that depth during the cut ire test . On April 26, samples were again taken through the holes in the side of the bin at 1 I), '_'.">, and 10 feet from t he holt mn, together with a number of samples represent ing t he 1 ,000 bushels at t he top of the bin. At this time the com at the top of the bin was hot, musty, and sour, but no odor could be detected on the samples taken through the hole in feel from the bottom of the bin. However, the samples taken through the holes 25 and 10 feel from the bottom of the bin showed that the corn near the bin walls at those points was slightly sour. This condition was shown more clearly when the bin was emptied the Following day. the corn having a tendency to adhere to the sides. In emptying the bin the corn from the sides became unevenly mixed with the better corn from the interior, so that an odor was percep- tible on a considerable portion of the entire hulk. The fermentation in the upper 500 bushels of com was \er\ active at this i me and the temperature was increasing rapidly. On April 25 thermometer No. 7. in the center about 5 feel beneath the surface of the com, registered s 7" V. At 8 o'clock the following morning [t'e 8 THE DETERIORATION OF CORN IN STORAGE. this same thermometer registered 102°; at 11.45 a. m., 105°; at 3.10 p. m., 107°. and at 9 o'clock the morning of the 27th, 115°, an increase of 28 degrees F. in 48 hours. The highest temperature registered on April 27 was 133° F., in corner No. 4, 8 inches below the surface of the corn. In corner No. 1, 14 inches below the surface, the tem- perature was 110°; in corner No. 2, 112°; in corner No. 3, 125°: and in corner No. 4, 132+°. Thermometer B, in corner No. 2, the same depth below the surface as thermometer No. 7, registered 71.5° F. 1909. FEBRUARY MARCH. APRIL. 1909. Ill ■!■■ I WEATHER RECORD. IB -fi^/N OR SNOW, .01 fNCH OR MORE. \ \ = RAIN OR SNOW, TRACE. I 1= NO RAIN OR SNOW. Fig. 2. — Diagram showing the temperature of the corn in various parts of the bin. the daily maximum and minimum air temperature, and the precipitation from February 17 to April 27, 1909. A clearer understanding of these conditions will be had by consult- ing figure 2, which shows the temperature of the corn in various parts of the bin, together with the daily maximum and minimum air tem- perature, and the general character of the precipitation during the GO days covered by the experiment. CONDITION OF THE CORN AT THE END OF THE EXPERIMENT. As shown in figure 2, the only marked increase in temperature was in the G or 7 feet of corn at the top of the bin. The maximum tem- perature registered by thermometers No. 6 and A, approximately 12 [Cir.43] Ill I . DETERIORATION OF CORN IN STORAGE. \) feel below the surface, was 51 and ">f>\ !•'.. respectively. The tem- perature of the corn in the lower pari of the bin varied from 39-J° to 4H° V., as compared with a variation of from 36° to 40° F. at the beginning of the experiment. The moisture content of the corn immediately at the surface was 14.95 per cent, <>r .'>..!"> per cent less than on February 17. The moisture content of the 1,000 bushels at the top of the bin, exclusive of the corn on the surface, was slightly higher than when the corn was placed in the bin, showing that the deterioration of the corn was resulting in the formation of more water than was being given off by evaporat ion. The weight per bushel of the surface corn was 5 I pounds, while the weighl of the remainder of the upper 1,000 bushels had decreased from 53 to 51 pounds. The germination of the poorest corn from the top of the bin varied from to 17 per cent, with an average of 10.3 per cent, as compared with an average of 7_\ 4 per cent on February 17. This corn was damaged so that many of the germs were badly discolored. The average germination of the 1,070 bushels taken from the top of the bin for further experiment, which included not only the hot corn hut all that had a temperature over 50° F., was 42.6 per cent after being handled, dried, and loaded into car No. ti7(): J >1. The corn in the lower 1") feet of the bin, except !»()() bushels of the best quality which was loaded into car No. 7.">1!)7 for further test, after being handled over three elevators and dried to 1 L87 per cent of moisture, was given a grade <>f "Mixed corn." The germination of this corn was SO.S per cent at the beginning of the experiment, 71.4 per cent when drawn from the bin, and 81.4 per cent after being handled and dried. The total loss in weight, as shown by the certificates furnished by the weighman of t he ( Jhamber of Commerce, resulting from filling and emptying the bin and the evaporation during the (>'.» days in storage, amounted to 310 pounds, or slightly less than one-tenth of l per cent. DRIED DAMAGED CORN FROM TOP OF BIN STORED IN CAR. The 1.1)7(1 bushels of corn drawn from the top of the bin was weighed, handled over three elevators, and reweighed, after which it was artificially dried in a grain drier at a temperature varying from 151 to 163 I-'. The average moisture content of this corn as taken from the bin was 18.64 per cent. The average moisture content when emptied into the drier was 18.30 per cent, of ; , reduction of i).:; i of 1 per cent a- a result of the handling, which i^ equivalent to a loss in weight of u. i ,,|' i per .-cut. In drying, the moisture con- Bureau "i' I'l.mi Industry . U. S. Dept. of Agriculture, entitled "Mois- ture Contenl and Shrinkage in Grain," explains why this dil cists and how it is calculated. [CIr. i:i] 10 THE DETERIORATION OF CORN IN STORAGE. tent was reduced from 18.3 per cent to 14.57 per cent, a reduction of 3.73 per cent, which is equivalent to a loss in weight of 4.44 percent. After this corn was dried and thoroughly cooled, 900 bushels, having an average moisture content of 14.57 per cent, were loaded into car No. 67031 as if intended for shipment. The car was run out into the yard and left standing on the track fully exposed to all atmospheric changes. The temperature of this corn immediately after it was loaded into the car, after drying and cooling, on April 27, varied from 57° to 58° F. Frequent temperature readings were made up to and including May 25, when the highest temperature at any point in the corn was 66° F., an increase of only 8 or 9 degrees, although the temperature of the air in the car had varied from 56° to 82° F. and the temperature of the air outside of the car from 41 ° to 90° F. On May 25, after being in the car 28 days without any noticeable change in condition, the corn was unloaded, elevated, and weighed, and then returned to the car and left an additional 9 days on the track. The air temperature at this time was 73 ° F. , resulting in a very slight increase in the temperature of the corn by the time it was returned to the car. On June 3 the temperature of the corn was 67° F., an increase of only 10 degrees during the entire 37 days that this corn was in the car. The condition of the corn was fully as good if not better than when it was placed in the car on April 27, although the odor resulting from the fermentation of the corn while in the bin had not entirely disappeared. On June 3 the moisture content of the corn on the surface was 13.1 per cent, with 14.48 per cent for the remainder of the corn in the car, a difference of 1.38 per cent in the moisture content, which is equiva- lent to a shrinkage in weight in the surface corn of 1.59 per cent in 9 days from May 25 to June 3. UNDBIED CORN FROM BIN STORED IN CAR. In order to secure data for comparison, 900 bushels of the best cool corn from the bin, principally the Illinois corn from the eighth and ninth drafts, were loaded into car No. 75197 and placed on the track alongside of the car containing the 900 bushels of dried damaged corn from the top of the bin. The temperature of this coin while still in the bin varied from 40° to 42° F., but in "running" from the bin, elevating to the scale, and loading into the car, the temperature was increased so that the temperature of the corn after being loaded was 48° F. The air temperature at this time was 51 ° F. and the rela- tive humidity of the atmosphere 70 per cent. The average moisture content of this car of coin was 17.5 per cent, and the weight per bushel was 55.3 pounds. | CIr. 131 I II I |i| II RIOB \ I [OK OF CI >i:X IN STOB \.GI . 11 On M;i\ 20, after standing on the track 23 daj s, the corn in this car began to show unmistakable signs of deterioration. At that time the maximum temperature of the corn was 75 !•'.. and it had a distinctly Mini- an. I musty odor. Five days later the maximum temperature was L22 I' - . in the brake end of the car, approximately 6 inches below the -hi face of the corn. Tin' a\ erage weight per bushel had decreased from •">■">.•'! pounds to 52.6 pounds. The moisture content varied from 13.6 per cent in the corn at the surface to 17..") per cent where the tempera! lire was 1 '_''_' F., as compared with a varial ion of from 17 per cent tu 17. 7 per cent at the time the corn was loaded into the car. Z8 o*rs *tAX/M VM *Otf? rCA*P£RJiTVf?£ A? 2f ?S nun ~\/VO KA//V. Diagram showing the temperature of the undried corn in car No. 75197 and of ilio dried damaged corn in car No. G7031; the daily maximum air temperature; and the weather recor I from April 27 to June :s. 1909, whlli " elevator yards. ( )n Mas _'"i 1 hi- corn was unloaded, weighed, handled over five eleva- tor-, reweighed, screened, weighed a third time, and returned t<> the car for further obsen ation. When the emu was returned to the car the second time (May 25 • the temperature was 7'l 1''.. approximately the same a- the temperature of the air at the time the corn was handled. On .lime :;. 9 days later, the corn in thi- car was again hot. the maximum temperature being L12 1''.. showing that hoi corn i- iiut made safe for shipment when cooled -imply by handling. Figure •"> shows the changes in temperature in both the car of undried corn and the car of dried damaged corn while on the track [Cil ^^^^_ < (D Q O ^^^flj — gn Li. LL o h- (fl ^^^^ M ^^ X = -- - - T— z 3 ^^^^= ^^^^_ 12 THE DETERIORATION OF CORN IN STORAGE. from April 27 to May 25 and from May 25 to June 3, together with the daily maximum air temperature and the weather record for the same period. The diagram also shows that only the corn near the surface was influenced by the temperature of the outside air. LOSS EN MOISTURE AND SHRINKAGE. When the undried corn from the bin was first loaded into car No. 75197, on April 27, the average moisture content was 17.47 per cent. On May 25, when the maximum temperature of the corn was 122° F., the average moisture content of the surface corn was 13.55 per cent. Samples taken from 5 inches below the surface showed a moisture content of 17 per cent. The highest moisture content found was 17.5 percent, in samples taken at the point where the temperature was 122° F. The shrinkage in weight in the layer of corn at the surface, based on the reduction in moisture of 3.92 per cent, was 4.53 per cent. On May 25 this corn was unloaded and reweighed by the weighman of the Chamber of Commerce on the scales regularly used at the ele- vator. The loss in weight in the loading and unloading and through evaporation while in the car from April 27 to May 25 was 367 pounds, or 0.728 of 1 per cent. This corn was then handled over five elevators, screened, weighed, and reloaded. In this handling and reloading the moisture content was reduced to 16.55 per cent, or 0.92 of 1 per cent less than when the corn was first loaded into the car on April 27, which is equivalent to a loss in weight of 1.1 per cent due to the evaporation of moisture while in the car and in the handling of the hot corn in the elevator. On June 3, this car of corn, cooled by handling, was again hot, the temperature having increased from 73° F. to 112° F. from May 25 to June 3. The average moisture content of the surface corn was only 13.95 per cent, as compared with 16.55 per cent when reloaded, a reduction in moisture of 2.6 percent in 9 days. The low moisture content of the surface corn showed that water was being lost by evaporation and that this evaporation is quite rapid when the temperature of the corn is relatively high. It must be remembered, however, that this car was opened frequently and the com on the surface more or less disturbed in the securing of sam- ples, in reading temperatures, etc., so that the same results might not apply in the same degree to corn in transit where the cars are unopened from point of shipment to destination. Approved: James Wilson, Secretary of Agriculture. Washington, I). C, November 5, 1009. | Cir. 43] o