> 39.65/4: Gu 16 Bulletin No. 16 M. M, LEIGHTON December 1, 1920, COMMONVEALTH OF PENNSYLVANIA DEPARTMENT OF INTERNAL APPAIRS James F. Woodward, Secretary BUREAU OF TOPOGRAPHIC ND GEOLOGICAL SURVEY George H. Ashley, State Geologist aes GEOLOGY OF OIL AND GAS IN RELATION TO COAL. 4g George H. .shley There has long existed an idea that oil and gas are Somehow re- ted to coal if, indeed, not derived from coal. The occurrence of il, gaS, and coal.in the same areas in many parts of the world, 20upled with the fact that gas is given off from coal in mines and that both oil and gag can be distilled from cosl, is largely resvonsi- ble for this idea. Granting thet this geographic relationship is ourely fortuitous; the more serious question arises: Just whet are the relations of coal, oil and gas in their origin, character and occur- rence* all are hydrocarbons, that is, consist of carbon and hydrogen — with some oxygen and nitrogen and possibly other substances, If coil be heated in a retort, oil and gas are given off which have many of the properties of oil and gas as found in nature and. separable into much the same series of primary compounds. Furthermore, our common theories of the origin of ali three deseribe them as derived from the remains of orgenic material. Mr. Reinhardt Thiessen hes shown that coel is made up of remnants of land and water plants that may have accumulated originaliy as a peaty deposit, Similar studies on the "oil shales" of Colorado by C. A. Davis show thet those shales consist in the main of plankton mixed with mud. Plankton is the gelatinous material composed of the remains of water weeds and smll lske animals thet accumulates at the bottom of lakes. Chemical and microscopic studies of cannel coal indicate that it lies about half way between bituminous coal and oil Shale. It, too, 4~ 2 water deposit but apvears to differ from the shale in that while oo) Bothy eu ee ‘ By Tes aye 4 ° id & . x et, Se . i . IVAN ae eon aby a Tie ia) BOG Pa Bay in AN onto He ; i ) hh 4 i } r ‘ ’ « . Va hae 4 \ Hl vt iY y* 4 UP N ¢ : ‘ i ont fy iat FA) tis a Y cn : ies : } a 1 t ) \ i tut i \ 4 ‘ : % a Dey ee a Yad i) : re ‘ uy vt } | Ae sa 3 } " EOP bath beetiy om) ae Be, aa ee Ree ny Uprtd poets dea vt bed Be LOR pid} he aye p ead ela | 6 Pere ee Se tT ie an ‘ Pe Poi rhe 4h wv RN 9 th ‘ p Aleve HEHE Algir® | b Mi fin oe hit a nt ” WE +h HERPES pare na eine ‘fe raha we ; 7 : mh y , aria ; 4 \ Pe dee va Orit: . H Ea Ryall " ' rf ; Va OMa i ; 9 ¥ ahh, me A eld pales aa Aka Av , } 9 ‘sf st We atay ; AES PSP RW RTED la GAS) tea ei Fie 1 ee hg Af ‘ yy iy anes 19) wy hj ; oe ype » spy i the shale contains principally the remains of gelatinous water piants, cannel coal contnins mainly the srores and decomposition products of the spores of ferns and other plants such as made up the bituminous coals. It would seem, therefore, that bituminous é¢oc2l, cannel coal, and Oil Shale differ in that bituminous co2l1 is deriveé from the remains of land or water plants, with more or less woody parts, which grew where the coal is found; cannel coal is derived mainly from the spores of these sane land and water plants floated to the place where the cannel coal is now found, usually lagoons within the coal swamp; and Oil shale derived its bituminous materiel from water plants and small animals accumulated on the bottom in open bodies of water. ODL end eas ldsrter. trom /coalvin one .imrortant particular,’ Goal: SU yo mneros it was puts (OL) and eas as a rule,’ do notvor, i at least, 6 Suppose that they do not because they can move through the rocks aa we believe that they were not deposited originally in the sands nere they ere commonly found today, That water can travel long dis- tances through rocks, possibly hundreds of miles, is proved by our “nowledge of artesian waters. That gas can and does travel throu: the rocks at least a few miles, is' well established by a study of gas occurrences and rock pressures in the gas fields. That oil will travel short distances is very well established. That it will travel long distances seems'a safe inference from our knowledge of the move- ment of water in the rocks. Then comes the all important problem: How do oil and gas travel? Gas, we know, travels in two ways: by its own expansion, from high pressure to low pressure areas; and by being pushed ahead of Licuids advancing with superior pressure. Oil may be said to travel in four * ways: First, it mns down hill under the attraction of gravity. Second ,- it will move forward under the influence of a gas exerting an unbalanced pressure on one Side. Third, it will rise to the surface of a heavier liquid and ride on toy of such a licuid if moving. Fourth, it will move through minute spaces by capillary attraction, as when oil rises in the wick of a lamp. Apparently ell four of these conditions exist in nature. To get more clearly in mind the conditions uncer which oil and gas accumulate in the rocks - for it is this accumulation which has wractical interest - let us recall: Tirst, tmt the beds of reeks aiffer in porosity and thet the same bed differs greatly in porosity Within itself. Second, that practically no rock lies exactly flat »vut all are tilted or folded in various degrees. The terme "monoclins", Wad oa Gul amore nel ui emer Rod ete Mn oe dome My ards eter ase Arevtamiilarw Third,» that aALimay' be doubted iif’ oll wilk. commonly ron DUiOL, Sx rock exceny Under Preasure Ol elthom gas) air) or artetian water. This is clearly shown where supposecly exhausted oil fields are revived by admitting gas, air or water under pressure. Experiments indicate thet the producing oil sands have & porovr:: of one-tenth to one-fourth of the volume of the rock, with an averare. of around one-fifth. Therefore, a little cifference in the pore sp2c may determine if a.rock is, productive or dry. In many fields the por: nay ate hans ee . 4 t : ; BAN is - ) \ . ‘ f ter 4 p , i) t i j 4 ‘ ‘er 7 2 ss , r ; | Ne ‘ nr an aK i be Y ; ‘ "4 ~~, VF Aas feild se a taaaiee ula x “ ‘ony eee’ ve ty y 4 ARK ro eo ny, ; ot eg ABA a +4 ciee n Se gS isi Ww ‘ ue iv J bs 1 “ - . Vv F swan ’ % thon ave eli a 0 ‘ ta ’ vA, \$ x , oh. . ‘ - rn 6 ¥ ws , i . yw ’ fi , re > ‘ _ \ 3 7 ae ~ e ‘ + x ‘ Py ‘ Pay Poa’, f ' ' ; a ek veh » . ‘ 7 as ae ; le 1“) ‘ . “Ts ae L)Y, s ‘ i Avr't os ’ a , ya + > cat : Le 2 i) , if { 4 1 x . } ' * . ! t #4 . & ' yay 5 * ¥ ‘ , * e , ’ ‘ ¥ j F y } io \ ' it ‘tf * ‘7 u \ ‘ «a \ ‘ - x LN ‘ i gl 2 d \ [ { id ‘ 4 al . i ' ‘ ri i , . my e ’ A { r. 4 , - ‘ \ n t t \ 7 . : 4 " R vs) ’ R , ‘ Aix iy \ \ t ¥ 8 ‘ : ‘ , — 4 ¥ | ‘ ar " +) 1 \ 4 A . \)! 5 i i “ r ‘s * ’ ; . * . i Z * Wi ' f be a : : ht is ; ; eu wien . \ (. } eo eit Pe Ree ee ae Week emai “sy « Fine 4 ’ © 6ree - ss A Me pe? i ae | 7 } a [ir es, Ay) Rens : nae of \ . ov . 5 ’ 1 j * J . ¥ T i a) Y ARES ve , ’ / . : ’ ' ‘ ¢ - A 2 ‘ / , - "l p : \ , - > . : " . ‘ , f \ | ‘ ne 4 ‘ £ « ‘ 3 ’ 7 ‘ ee 4 x ‘ j f Leek Do | a4 ‘ ' 4 ‘ ie , t Sire uae ‘ f ‘Nt J ' - i ¢ vy : ' ’ I , oe ” ; 4 ’ ‘ yt 1% AT. A . ‘ fe . ore riAdee Space seems to be the principal or only factor in determinine where O11 and gas will be found, In others, it is only one of the factors. Oil moty occur in association with water or in a “dry" or “water «ree"™ sand. It is probably always associated with some gas, though 625 is not always accompanied by recoverable oil. ‘here water, oil, and gas occur in the same stratum in inter- communicating space, they arrange themselves in the rock in the order citec, from the bottom up. Thus the gas is found in the highest part of the rock reservoir or only on the enticlines. The oi1 is found ox the flanks of the enticlines md the water in the synclines. This Simple theoretical arrangement, however, seldom holds sood, as will be evident to any one who studies the structural relations of the oil and gas pools of southwestern Permsylvania. Inthe first place, beyond 3,000 feet below the surface, there is an increasing tendency of the Bandstones to be water free. The Sone sandstone that contnrins water in easter Greene County, Pennsylvania, mav be dry in western Greene County where it is several hundred feet deever. gain, few or none of the anticlines are flat crested but rather "camel backed", not only rising irregularly into domes and saddles mut heaving a general rise alon= their axes toward one end. Thus, practically all of the anti- clines and synclines. of westem Penmnsvivania have « gener2l rise from the southwest toward the northeast, so that the tov of an anticline at one point may be much lower than the bottom of the syncline either Side at points a few miles to the northeast. Under these conditions, if a bed of sandstone is partly fillec with weter and the top of this water forms a level, as it will if free to move, it is obvious thet water level will be on top of the anticline -t cne noint ond in the nov som of the adjoining synclines a few miles northeast. It follows woo At Chere TS oll vine on the; water, this.oid will Lie on) the anticline in one area, {with g2zs, if present, fcrther up the same anticline) and in the syncline farther northeast where the synclines have risen above the water level. These statements give e Slight idea of the difficvity of pre- digting the presence of oil and gas in any aren witnout a very wide ane commorehensive study of all of the conditions (not includcinz the nore svace of the xwocks, which cannot even be esuessed at from the guritece). | Por example, inia given stratum or "sand" in eastern) Crean County, oi11 i185 found above water. How may we predicate the vresenc Or ‘either Oil or (gas farthéy. to the west. where the Sand is deopor one contains no water? We do find both oil and gas in the water-free Sands where deever farther to tho west. How did they get below the water? Has the water been driven pest them out of the deeper rock or is: the water working its way down, from the surface? In places water and oil are »pumped together from the wells as though in those »loces the water were passing the oil either up or down as the case might be, ané had not yet reached the naturel order of arrangement with rererence to weight. These sre a few of the problems that the new Geological Survey has set itself to try to work out for Permsylvania and it is hoping to reach some definite, helpful conclusions before the oil and gas fields of the State heve become only a memory. The hopeful element ane Ae ag te ra ivy Na eA mye i (he ane Naa 7 en ai ay bali eh ie y oat | ae sf. vas ae Vv S mt SIE RIE N ab NR, ; “tid ae ; ig li a sty edd fa we, 4 ‘ t ee ‘4 ' > cop AR a! , : vinta eh) sey : Ar ¥ aa} = # } 7 + ‘ ‘ ‘ + . i * i , p= Fab é : Pl : Nias i a af " be " f rhs 5 Reg 2 . *'. : ) * ah Fi { S PET ‘ . : bo eo i >? t i oat “ t ule wie SMe ae aie iS ay PORES ieee Ser in the problem is our belief that the oil fields are yet a long way from exhaustion if a method can be found to get from the sands all the oil not yet pumped out. For example, 2 sand with a pore space of 1/5 (20%) has a capacity of about 1,550 barrels of oil per acre foot. The Bradford field in MeKean County is estimated to contain 85,000 acres and the sand is estimated to Mave an average productive thick- ness of 45 feet. Assuming 1,000 barrels to the acre foot (for the Sand is closer grained at Bradford than most sands) gives 2 total capacity of 3,825,000,000 barrels, The estimated total production to date is 260,000,000 barrels or about 1/16 of the total. ‘Je do not, of course, know the exact porosity of the Bradford sand nor that the juve Space in that sand is full of oil. The figures, I .wever, show brat even if the pore space is over estimeted and the thickness of 1¢@ productive sand also over estimated, there still is room for the oroduction of many times as much oil as Ims yet been obtained from uhat field. Whether the same condition is true in other fields where the sand is more open grained, is not yet certain, but the evidence at hand points to the fact that the supposed exhaustion of most of the oil fields is really the exhaustion of the gas or water pressure thut previously forced the oil into the wells. The problem is to get out the oil remaining. Lest anyone think that because of these difficulties the possidle presence of oil or gas cannot be predicted, let me hasten to state that, given time for investigation, the geologist can be of very . great service to the oil and gas industry. He can never reach 100% efficiency, but consitering the cost of oil and gas wells, if he can reduce the failures from one in three ‘to one in’five, his services certainly are worth while. As evidence of this, Mr. F. G. Clapp has estimated that in nine townships of northern Oklahoma success in driiiing twerveased from 60% before geologic advice was sought to 87% following geologic advice. Dorsey Hager has show thet of the new pools opened in Oklahome between 1913 mad 1917, 70% were found on geologic advice. Under scientific direction one wild cat well out of three found oil as against one out of one hundred and fifty drilled in the usual haphazard way. Hager also finds that out of seventy five most important oil pools in Oklshome and Kansas dis-~ covered during those years, all but four were on well defined structures such as domes, anticlines and terrseces, Unfortunately, it is ‘not possible to rench the same success i. gost fields. For exemple, in parts of Texas and Louisiana, the surface geology bears little rclation to the underground geology ane. the geologist can be of little help except es he interprets drilling as it progresses and on that basis guides new drilling, In the Appalachian oil and gas field, which at least is nearer home, it may be noted: first, that much of the area lies within the Appalachian coal field and tmt within the cool field oil is confined to those areas where the coal is fairly high in volatile matter, having a fuel ratio of 2,orsless. 4 possible cause for this is dis- covered when we remember thet all the coal was originally high in volatile matter ond that the low volatile coals have had port of the volatile matter driven off by the forces thot foldcd the rocks; and if we note also thrt the biack shmles of the same region, when distillcd ~ 4 = Lv “Ai ; ; ty ; yh A Te ately Biase oa aren 2h abe i sa ae ie : ue ft } be ve 4 Lak 0 i 4 ” * : r a aR Cel 1 “al ‘ ° 4 | ‘ i UN eT "0 rr ad ie M4 * a oR a” } ‘a } CP Any f ¥ . id ’ So cae re ‘ s 4 ~ : ' » he 4 » ‘ a en: oa i And +k toes 4 : i PALLY MS ia at, tat “ ke Ns rE pig y ‘ vi Te} i Oe : ; ‘ ey, Cy ie far es Me ae iti Be NE EO oes Wet aN AAR 28 MONE Hh soy Ae 1b ae BY? pai for oil, yield no-oil in the areca of the anthracite coal, little oil in the resion of the high carbon coals and much oil in the regions cf the high volatile coals. Evidently the lack of oil in the areas of high carbon coals is because the oil has been driven off or distilled into gas, If we recall that coal, when distilled, will yield oil if heater to a moderate temperature, Say less than 7509F., and gas, if heated to a high temperature, say 1200°P. , we might expect t0 find gas in areas of moderately high carbon coals and so we do. Thus if pros- pecting within the cel field, we might anticipate finding gas but not oil where the coal has a fuel ratio between 2 and 3.5, oil and gas if the fuel ratio is below 2, and neither oil nor gas if the fuel ratio is much above 3.5. Im the second place, oi] and gas are found so commonly in asso- ciation with folds in the rocks it even has been suggested thot the oil or gas is distilled only in the rocks where found and by the folding in those places. It is more likely that the folds have served as places of accunu- “lation because they interrupt the movement of oil on water.: Obvious- ly oil working its way down 2 slope which meets no obstacle, will ultimately land in fhe adjoinine (eyneline. Or, af being carriod up a& slope under the pressure of accumulating watcr, it will ultimtely ed) On tOp, OF : the Sere net, ig, however, in moving down,a lons 2ope a flat place or BLiphtiy reversed din .is encountered, some, oc oil is apt to lodge there; or, if water accompanies the oil, the ter may lodge on the fint or bench and :form a Seal that holds the IL 2 SB beeeHs TSO Phat ne ad Moyo oe found not on the bench but -t the foot of the slope above the. bench, --Ageain,.if is found that in plinccs on. long even monoc lines there aro folda. mirage to bhe dio makine what on 2 hillside we would call noses and ravines. Experience has Shown that many such structural "noses" or "ravines" are the site of zood oil pools. Such facts suggest that the most likely explanation Of ACCU. tes tons of ol] and gas in structures on the fisnks of enticlines or on monoclines, is that: the folding at these points haesslightly chaneed BNe \MiNULE SvIactire of the woek. A careful study ‘ot bent slabs of rock in grave yards or in buildings reveals a certain smount of almost microscopic fracturing where the rock has stretched, even though the peut is so slight ss to be hardly noticeable.’ ,It would seom quite Ossible. therefore’. that such Lloeni folding as I have mentioned faeht open up the rock in one area, and tend to seal it in another ates Many LUpinie \oil travels bys onpiliarity, such’ a change in’ the character of the rock would tend to retain the oil and create 2 pool at the fold, Discussion is omitted of the one hundreec and one finer »oints of the subject. such as the fnct that in Ponnsylvanio. the structure of the oil md gas sands does not quite agree with the surfrce structure, due principally to on unconformity at the base of the Pottsville; the cffect of unsymmetrical folding of the snticlines; “nc SO Ons RO foe ose tat c a ea et Baa Waal an “ fo o lent l \ rg al ee ws. ad oy mS : k vent ‘ ‘ At a me UD se, In conclusion, if asked to examine .ny nrea for oil and gas, the following srocedure ie suseested: 2. Study the fuel ratio o or tie oil content of black sh-les if they ore present. 2. Prepcrie J accurate a structure cantour map of a surface key rock as con- ‘itions will permit (if in a region of gently dipping monocline, ten root contours should be obtained, using a plane table).: 3. Preocxre structure contour map of each oil-or gas-bearing sand, using “con- vergence sheets", that is, sSheots Showing the varying intervals from that Sand to the surince key rock, 4. Study carefully locel pecu- 112 ‘rities - water pre aats porosity or grain of "sand"; Tlow cui Hy @) oO I~ Cai of oil welis, rock pressure of gas, variations a rock vressure in different wells as Rae ting “lay” of the pool ea at various times Ae SNeOVexrting The Lite or the pool. With these data on hand, you are ready to "go to it". inn 077640826