' Kr VVEALE’S RUDIMENTARY, SCIENTIFIC, AND EDUCATIONAL SERIES. ixhi mj The following are the Works already published in CIVIL ENGINEERING, &c. (The Volumes are bound in limp cloth, except where otherwise W CIVIL ENGINEERING, the Rudiments of; for the Sijg 01 Use of Beginners, for Practical Engineers, and for the Army ’ • and Navy. By Henry Law, C.E. Including/ a Section on Hydraulic Engineering, by George K. Burnell, C.E. Illustrated with Plates and Diagrams. 5s. THE DRAINAGE OF DISTRICTS AND LANDS. U Bv , Capital. With Examples and Particulars of actual Embank- ments, and also Practical Remarks on the Repair of old Sea Walls. By John Wiggins, F.G.S. New Edition. 2s. ■31 SUBTERRANEOUS SURVEYING, an Elementary and Practical Treatise on. By Thomas Fenwick. Also the Method of Conducting Subterraneous Surveys without the use of the Magnetic Needle, and other modern Improvements. By Thomas Baker, C.E. Illustrated. 2s. 6d. m $ GAS-WORKS , and the Practice of Manufacturing and Distributing Coal Gas. By Samuel Hughes, C.E. New Edi- tion, revised by W. Richards, C.E. Illustrated. 3s. it Sr- Ykfcipji r ,, rNSt r x. r; v-ii r r r ^ rN^rtt r r.'NAA r v c.'yjvC 1 c s* ( LOCKWOOD & CO, 7, STATIONERS’ HALL COURT, E.C. A •$? y-A; G • fci ’ W ' O •Sr C A TREATISE ON GAS WORKS AND THE PRACTICE OF MANUFACTURING AND DISTRIBUTING COAL GAS By SAMUEL HUGHES, C.E. FOURTH EDITION , , WITH ILLUSTRATIONS REVISED BY W. RICHARDS, C.E. library I umeit LONDON LOCKWOOD & CO., 7, STATIONERS’ HALL COURT LUDGATE HILL 1871 Digitized by the Internet Archive in 2016 https://archive.org/details/constructionofgaOOhugh preface. The engagements of Mr. Hughes having prevented his making the necessary revisions for a new Edition of this book, I have been entrusted with the task, and m accepting it have endeavoured to make a really practical manual of the present condition of gas manu- facture. Ihe great change which has taken place in this branch of industry during the past few years, has demanded considerable alteration in the work; much new matter has been added, and several woodcuts illustrative of the various apparatus have been intro- duced; so that I trust the present Edition may be found equal to the requirements of those interested in the production and distribution of gas. WILLIAM RICHARDS. CONI CHAPTER I. EARLY HISTORY OF GAS-LIGHTING. Inflammable gas known from a very early period — Most inflammable gases composed of very simple elements — Gas produced by decom- position, 1. Discoveries with respect to gas and steam — Effect of modern applications of science — Veneration of the ancient world for burning flames, 2. Superstitions entertained on the subject — Mists cleared away by modern chemistry — Notices of perpetual fires in the works of Strabo and Plutarch — Greek fire-altars, 3. Writings of Herodotus, Ctesias, Vitruvius, and others — Bituminous strata in various parts of the world — Springs of bitumen described by Herodotus, 4. Plutarch’s description of the burning fountain of naphtha in Ecbatana — Use of natural gas in China arising from beds of bituminous coal — Modern examples of inflammable gas issuing from the earth, 5. Mr. Shirley’s paper in the “ Philosophical Transactions” for 1667 — Burning spring near Wigan in Lancashire — Dr. Hales’s experiment on the distillation of coal — Sir James Lowther’s account of the in- flammable gas from a coal mine at Whitehaven, 6. Experiments made with this gas — Proposal by Mr. Spedding to apply this gas for lighting the town of Whitehaven, 7. Dr. Clayton’s paper and experiments on the distillation of coal, 8. Discoveries of Dr. Watson, Bishop of Llandaff — Mr. Murdoch’s application of coal gas for illumination, 9. Dr. Henry’s statement of Mr. Murdoch’s application of gas, 10. M. Lebon obtained a patent in France for producing gas — First public exhibition of gas-lighting, 11. First application of gas in France — Mr. Winsor first acquainted with gas-lighting — Mr. Winsor’ s first exhibition of gas-lighting — Mr. Murdoch erected the first gas-works, 12. Mr. Murdoch’s experiments described in the “Philosophical Transactions” for 18u8 ; also details of the mode of producing and burning gas, 13. Mr. Clegg, Mr. Northern of Leeds, Mr. Pemberton of Birmingham, and Mr. Accum, engage in experiments on gas-lighting, 14. First works constructed by Mr. Clegg — Mr. Murdoch received Count APPLICATION OF COAL GAS TO USEFUL PURPOSES. VI CONTENTS. Romford’s medal — Mr. Winsor obtains a patent in conjunction with gas-lighting, 15. Mr. Winsor’s exertions to establish the first gas company — Difficulties he encountered, 16. Pall Mall first lighted by gas, 17. Efforts to establish the “ National Light and Heat Company,” and failure, 18. Establishment of the “ Gas Light and Coke Company” — First operations of the company, 19. Engage- ment of Mr. Clegg as the engineer, 20. Westminster Bridge first lighted by gas — Ornamental illumination — Formation of other metropolitan and provincial gas companies, 21. Proposals to make gas from oils, fat, and resin, 22. Mr. Lowe’s successful opposition to oil gas, 23. The application of portable and com- pressed gas — Failure of the first gas companies, 23. Decent im- provements in the production of gas, 25. CHAPTER II. ON THE CHEMISTRY OP GAS LIGHTING. Description of the production of gas during the burning of ordinary lamps and candles, 26. Chemistry, organic and inorganic bodies, 27. The elements — compounds, 28. Analysis — decomposition, 29 Gases, 30. Tests, 31. Oxygen, its characteristics, 32. Method of obtaining oxygen — Hydrogen, its nature, 33. Produces water wherever flame exists — How to produce hydrogen gas — Nitrogen a constituent of the atmosphere, 34. Experiment demonstrating the existence of oxygen in the air, and separating the nitrogen there- from — Carbon abundant in nature — its properties, 35. Carbon does not exist alone as gas — Sulphur exists in various forms in nature, 36. Combination of the elements — Affinity — Chemical symbols, 37. Combining proportions — Equivalents — Formula, 38. Composition of coal gas — Marsh gas, 39. Olefiant gas, 40. Hydro-carbons — Experiments of Dr. Fyfe, Mr. Lewis Thompson, Messrs. Faraday and Coombe, 41. Carbonic oxide, 42. Impurities of coal gas — Sulphuretted hydrogen, 43. Carbonic acid, 44. Ammonia, 46. Bisulphide of carbon, 47. Cyanogen, 49. CHAPTER III. COAL USED IN GAS MAKING. Coal generally employed for the purpose of producing gas — The origin of coal, 49. The first coal mines opened in Newcastle-on-Tyne, 50. The earliest patent in conjunction with coal — Various descrip- tions of coal — Lignite, 51. Caking coal — Splint coal — Cherry coal — Cannel coal, 52. Anthracite — Analysis of coal — Fixed and volatile carbon, 53. Amount of volatile matter in various coals, 54. Average yield of gas and coke from a ton of Newcastle coal — Re- markable deterioration of caking coal, 55. Curious phenomena when coal is stored for a considerable time — Boghead cannel coal, 56. Table of experiments on the quantity of gas derived from coal, together with its weight and specific gravity, 57. Utility of the table, 61. CONTENTS. VU CHAPTER IY. ON THE CARBONISATION OE COAL. The process of carbonisation, 62. Engraving of section of hydraulic main, &c., 63. Cause of pressure of the gas — Temperature of furnaces — Wedgwood’s pyrometer, 64. Daniel’s pyrometer — Table of the degrees of temperature corresponding with the various colours, 65. Effects of various temperatures in carbonising — Method of decomposing coal, and converting its volatile constituents into liquid — The most suitable temperature for iron retorts, 66. The injurious effect of low temperature in distilling coal — Superiority of clay retorts — The charge for furnaces, 67. Coals for distillation should always be dry — Fuel used in heating furnaces — Average quantity of coke used as fuel — The red-hot coke from furnaces used by Mr. Croll for supplying the fires, 68. Tar used as fuel for the furnaces — On the mode of working retorts, 69. Double retorts, 70. The formation of carbon on the interior of retorts, 72. How produced and avoided — The methods of clearing off the carbon — The cause of obstructions in ascension pipes, 73. CHAPTER Y. SITES MOST APPROPRIATE FOR GAS-W ORKS. Choice of site for gas-works — Railway communication very advanta- geous — Great Central Company’s works at Bow, 74. Canal com- munication — Position of works relative to the district to be sup- plied, 75. Pressure of gas, 76. Plan of works — Knowledge of the nature of ground essential previously to deciding the mode of constructing works — Rules to be observed in planning works, 77. Engravings of plan and section of works by Mr. Penny, 78, 79. Magnitude of works described — Capital required for gas-works, estimated according to population — Average consumption of gas per head, 81. CHAPTER VI. ON THE RETORT-HOUSE AND BUILDINGS. Retort-houses, how constructed — The coke- vault, 82. Settings of re- torts — Single settings — Double settings, 83. Importance of the dimen- sions of retort-house being sufficiently ample — Cost of retort-house, 84. Precautions necessary in the construction of retort settings — Ventilating shaft, 86. Coal and coke store — Purifying house — Engine, boiler, and exhauster house, 87. Station meter and governor house — Chimney or stack — The cause of draught or current, 88. Chimney at Edinburgh Gas Company, 89. Prices of chimney stacks, 90. Vlil CONTENTS. CHAPTER VII. ON THE RETORTS USED IN GAS-MAKING. The earliest experiments of Mr. Murdock — Progressive alterations made in the settings of retorts, 91. Mr. Brunton’splan of setting, 92. Mr. Lowe’s reciprocating retorts — Mr. Clegg’s web retort — The retorts generally employed in the manufacture of gas, 93. The mouthpiece, 94. Engravings of section, side and front elevation of mouthpiece — Engravings of plan and side view of mouthpiece attached to retort, 94 — 96. Engravings of mode of attaching door to mouthpiece, 97. Wrought- iron lids preferable to cast iron — Iron retorts — Their disadvantages, 98. Their durability increased when in separate ovens, 99. Clay retorts — Mr. Winsor’s patent — Mr. Grafton’s patents — The first clay retorts constructed by Mr. Grafton, 100. Engraving of section of Mr. Grafton’s brick retort — Clay retorts used in Scotland previously to being employed in England — Clay retorts first employed in London on a large scale by Mr. Croll — Patent obtained bj r Mr. Cowen for the construction of clay re- torts, 101. Gradual improvement in the manufacture of clay retorts — The advantages of clay retorts — Arguments formerly used against clay retorts, 102. Necessity of having an exhauster wher- ever clay retorts are used, 103. The form of retort used generally in Scotland — Those used in England and the Continent — Retorts used at the Imperial Company’s Works, 104. Engraving of end elevation of clay retort, 105. Engraving of side view of mouthpiece attached to retort — Retorts sometimes cracked by the workmen, 106. Small leakages in clay retorts stopped by the gas — Method of attaching the mouthpieces to retorts, 107. Recipes for making iron cement for joints of pipes, 108. CHAPTER VIII. ON RETORT SETTINGS. Retort- setting explained — Precautions necessary in setting retorts, 109. Form of furnace — Mr. Croll’s furnace, 110. On setting clay retorts, 111. Engravings of section and longitudinal section of settings at Imperial Company’s Works, 112, 113. Diversity of opinion as to the best mode of setting — Price of settings, 114. Section of setting of seven retorts at the Commercial Company’s Works, 115. Cost of repairs — Iron retort settings — Various forms adopted in the mode of construction — Only useful in very small works, 116. En- graving of section of a setting of three iron retorts, 117. Engraving of longitudinal section of same, 118. Best description of bricks for retort furnaces — How to prevent the radiation of heat, 119. CHAPTER IX. METHOD OF COMBINING CLAY AND IRON RETORTS. The combination of clay and iron retorts first patented by Messrs. Kirkham and Lowe, 119. The system perfected and carried practi- CONTENTS. IX cally into operation by Mr. Croll, 120. Observations on the system of combining clay and iron retorts, 121. Engravings representing the application of the principle on the smallest scale, 120. Engravings representing other modifications, 122, 123 — Engravings represent- ing settings for large works, as practised by Mr. Croll, 124 — 127. Advantages of combination setting — The application of tar as fuel, 129. CHAPTER X. THE HYDRAULIC MAIN. Serves the purpose of hydraulic valve for each retort — Mode of con- struction described, 129. Engravings of section, end elevation, and part of hydraulic main in plan, as constructed of wr ought-iron, 130, 131. Cast-iron mains used — The action of hydraulic mains explained, 132. Mode of attaching the gas main to hydraulic — Valves, 134. Hydraulic and slide or surface valve — The action of the hydraulic valve explained — Engravings of hydraulic valves, 135. Slide valves described, 137. Engravings of sections of slide valves — Mr. Lowe’s bladder valve, 138. Furnace door, ash-pan, sight-boxes, and buck- staves, 139. ' CHAPTER XI. ON THE PURIFICATION OF GAS. On purification generally — Gas formerly used without purification — Observations on the various means of purifying gas, 141. The condenser, horizontal and vertical, 142. Engravings of vertical condenser, 143. Annular pipe condenser — Comparison between con- densation occurring by radiation and by contact with water, 144. Table illustrative of the variation — Excess of condensation causes the deposit of naphthaline in the mains, 14.5. Evidence and estimate of Mr. Croll relating to the cost price of condensers for the Great Central Company’s works — Mr. Barlow’s estimate of the cost of condensers — Area necessary for condensers, 146. On the tar and ammoniacal liquor tank — Its object — The mode of construction generally adopted — Seal pipe described, 147. Often in use in several parts of a gas-works — Capacity of tar- tank, 148. Selling prico of tar — Wash vessel described — Engravings of the apparatus, 149. Gas injured by washing — Washer seldom employed at the present time — The scrubber, or coke-condenser, described, 152. Sometimes employed without water — Ammoniacal liquor very generally em- ployed in the scrubber — Purification by wet lime — Method of pre- paring the lime for the purpose, 153. The purifier described, 154. Engraving of the apparatus, 155. Wet lime superior to other pro- cesses of purification — Advantages of dry lime purification, 156. The purifiers described, 157. The central hydraulic valve invented by Mr. John Malam, 158. Engravings of plan and elevation of puri- fiers, 160, 161. Modification of the hydraulic valve as a slide-valve, 162. On the quality of lime for purifying gas, 163. Mr. Croll’s and Mr. Barlow’s estimates of the expense of purifying gas, 166. X CONTENTS. Oxide of iron purification patented by Mr. Croll — The system of spontaneous revivification patented by Mr. Laming in France, and afterwards patented by Mr. Hills, 167. Method of working the oxide of iron, 168. Air has been proposed to be exhausted through the purifiers, 169. CHAPTER XII. VARIOUS MODES OE PURIFYING GAS. The earliest methods attempted to purify gas — Ammonia formerly obtained from Egypt, 169. Mr. Croll’ s process of separating am- monia from gas, 170. Description of purifier, with engravings, 171. Method of applying the system, 172. Mr. Croll’ s method of puri- fying by means of neutral salts, 174. Mr. Laming’s process of purification, 175. The Rev. Mr. Bowditch’s system of purifica- tion, 177. CHAPTER XIII. THE GASHOLDER. The gasholder described, 178. Cast-iron tanks, 180. Specification of cast-iron tanks, 181. A method of constructing tanks adopted by Mr. G. W. Stevenson, 182. Annular or ring tanks, 183. Brick tanks, where applicable — Dimensions of tanks, 184. Puddle employed in construction — Tanks often made of stone, 185. Specification and estimated cost of brick tank, 186. Specification of Imperial Com- pany’s tank at Pancras Station, 188. The holder, how constructed, 191. Engraving of holder, 192. Means of calculating weight or pressure, 194. Prices of various holders, 195. Specification of a single-lift gasholder, 196. Specification of apparatus for gas-works, 198. Specification of holder at Pancras Station, 200. Telescopic gasholders, how constructed, 203. Essential where space is limited, 204. Evils arising from telescopic gasholders — Imperial large holder at Hackney — Specification of tank and gasholder, 205. Gasholders as formerly constructed, 210. CHAPTER XIV. ON THE EXHAUSTER. Composition of gas — Carbon from gas may be obtained in solid state, 212. Mr. John Grafton’s experiments — The earliest machine for exhausting gas, 213. Various kinds of exhausters, Beal’s, Jones’s, Methvin’s, Anderson’s, 214. The loss of light by admixture of air or carbonic acid with gas — Meter formerly used as a motive power — Gas engine, 215. CHAPTER XV. ON GAS-METERS. First meter made by Mr. Clegg — Improved meter by Mr. Malam, 216. Sir William Congreve’s hour meter — The kinds of meters in use. CONTENTS. X] 217- The wet meter illustrated, 219. Section of meter, 220. Side view of meter, 222. Front view of meter, 223. Contingencies in the measurement — The attention of parliament called, 224. Com- pensating meter — Sanders and Donovan’s meter, 225. Station meter, 227. Dry meter^ 229. First record of dry meter — Defries’ meter — Croll and Richards’ meter, 230. Compared to steam engine, 232. CHAPTER XYI. ON LAYING MAINS AND SERVICES. Mains and services described — First mains laid by New River Com- pany — Brick conduits, earthenware and glass pipes, proposed for the transmission of gas — Chameroy pipes, 233. The action of exosmose and endosmose described, and signification of terms, 234. Mains should be tested by hydraulic pressure — Method of making joints of pipes, 235. Mr. Clegg’s and Mr. Wicksted’s methods, 236. Pipes having their ends turned and so fitted — Large mains of New River Company, how laid — To determine size of mains, 237. Table of the discharge of gas per hour, through various size mains, at various pressures, 238. Manner of applying table — Map of dis- trict indispensable, 241. M^ains laid generally in centre of street — Syphons, their object, and how constructed, 243. Condensation of gas — Leakage in gas mains — Method of preserving cast-iron pipes, 244. Pressure necessary under various circumstances for the proper supply of a district — How to discover the point where a main is obstructed, 245. Table of the weight and cost of cast-iron main per yard — Average price for laying, mains, 247. Services described — In England are generally of gun -barrel — On the Continent services are usually of lead pipe — Obstructions of services cleared by Hulett’s apparatus, 248. Galvanised gun-barrel often very advantageous for services — Leakage of mains — Various estimates of amount of loss by leakage — Mr. Croll’ s evidence 249. Quantity of atmospheric air discovered by Professor Graham to be intermixed with gas — Necessity for changing mains when too small for district, 250. Various incidental losses, often considered to arise from leakage, 251. CHAPTER XVII. ON APPARATUS FOR INDICATING AND RECORDING PRESSURE. Pressure gauge, how constructed — Necessity of instrument to indicate pressure, 252. Causes of excessive pressure — Mercury pressure gauge, 253. The pressure indicator, how constructed — Its action described, 254. Registering pressure gauge — Engraving of instru- ment, 255. Registering papers to be preserved as records, 256. Exhauster indicator, 257. CHAPTER XVIII. THE GOVERNOR AND REGULATOR. Governor described, 257. Engraving of instrument, 258. Wright’s governor — Governor absolutely necessary in every works — Gover- XI] CONTENTS. nors sometimes placed on mains to regulate the pressure of gas, 259. Dry governor used by Mr. Stevenson of Halifax — Regulator — Used for private houses and street lamps — Hulett’s mercurial regu- lator, 260. CHAPTER XIX. EXPERIMENTS ON COAL GAS. Gas affected by various causes — Effects of temperature on gas, 261. Effects illustrated by experiment — Barometric pressure — Barometer described, 262. The variations of increase or decrease of baro- metric pressure — Examples of the necessity of corrections — Moisture in gas — Specific gravity of gas, 263. On weighing gas — Various methods of conducting the operation, 264. Wright’s balloon for ascertaining the specific gravity — Wright’s directions, 265. Table for corrections of temperature and pressure of gas, 267. Cor- rections for moisture in gas — Table of aqueous vapour existing in gas under various temperatures, 270. Methods of drying gas, 272. On the bromine and chlorine tests, 273. Mode of operating, 274. Process under some conditions not satisfactory — On the com- parison of gases by means of the photometer, 275. The first form of photometer — Bunsen’s photometer, 276. Manufacturers of photometers, 277. Engravings of photometers, 278, 279. Table of the distances for scale of instrument — To ascertain the weights of gas produced from coal, 281. Comparison of the specific gravity of gas with number of candles — Tests for ascertaining the purity of gas, 282. Tests for sulphuretted hydrogen, ammonia, and carbonic acid — Instrument for detecting the presence of the sulphuret of carbon in gas, 283. Dr. Letheby’s instrument for determining the amount of sulphur in gas, 285. CHAPTER XX. ON THE MODE OF BURNING GAS. Theory of the combustion of gas — Various effects of excess or defi- ciency of air and pressure considered — Under certain conditions gas gives no light, 286. Loss of light by admixture of air with gas, according to Dr. Letheby — Effects of excess of pressure on the light given from gas, 287. Table of light yielded by various descriptions of gas — Cause of the variation, 288. Best results obtained when gas issues from burner at low pressure — For poor gas the holes of burners are required to be large — For rich gas holes of burners should be small, according to the quality of gas— Variation of light obtained by argand and other burners under different circumstances, 289. All burners require to be made expressly, according to the quality of gas they are destined to consume— The mode of determining the illuminating power of gas according to the Act of Parliament prejudicial to gases of superior quality — Suggestions for adopting a standard of illuminating power — For poor gases the argand considered the most suitable — For rich gas the fishtail is preferable, 290. Carburisation of gas— First CONTENTS. Xlll patented by Mr. Lowe — The system lately revived — Difficulties in the carburisation of coal gas — Experiments on the evaporation of liquid hydrocarbons — Mixing atmospheric air with vapours so as to give light, 292. Firms established for carburising gas — The process tried in the lamps of the City of London, and renounced, 293. CHAPTER XXI. RESIDUAL PRODUCTS FROM COAL. The coke, fuel for household and other purposes — Breeze used in brick-making ; also, when mixed with tar, producing an artificial coal, 294. Tar, the various attempts to distil this for producing gas — The products from tar, 295 — Pitch, a substitute for asphalte, and good coke, produced from tar — Ammonia, how formed into sulphate — Used as a purifying agent — Volatile alkali, and other compounds of ammonia, produced from the residue of gas- works — Waste lime from purifiers, 296. CHAPTER XXII. EXPLOSIONS OF GAS. First fears of explosions — Gas unmixed with air not explosive, 297. . Safety of gas-lighting — Mixture to be explosive, 298. Accidents which have occurred, and cause of them — Explosion of station meters, 299. Sheet-iron valve — Explosive compounds of gas not explosive when under pressure — Some experiments on explosions, 300. Precautions necessary where escapes of gas exist — Meters sometimes mysteriously destroyed by explosion — Causes of many explosions which have taken place — Mains break in an unaccoun- table manner, 302. Danger of placing mains in subways — Common error, that gasholders, when charged, are explosive, 303. Valves on the exterior of large buildings always of utility, 304. CHAPTER XXIII ON WATER GAS, OR THE HYDROCARBON PROCESS OF GAS-MAKING. On water gas — Hydrogen produced from water capable of heating apparatus, 304. Hydrogen intermixed with the vapours of volatile hydrocarbonaceous liquids capable of producing light — Patents obtained for the process — Sanguine expectations of its success, 305. Trials on extensive scale made at the Manchester and other gas companies’ works — Causes of failure, 306. Hydrogen gas employed by M. Gillard to heat platinum wire, and so produce light, 308. CHAPTER XXIV. ON THE RATING OF GAS-WORKS IN PAROCHIAL ASSESSMENTS. Great difference of opinion on the subject of rating — General principle of rating now established— Objections of public companies to the XIV CONTENTS. present mode of rating, 308. General views applicable to the rating of joint-stock companies — Rateable value of the London and Bir- mingham Railway — Comparison with rateable value of buildings representing the same amount of capital, 309. First determinations to be made with respect to rating — Consideration of the law laid down in the Parochial Assessment Act — Quotation from the Act — Determination of rent for which gas-works would let from year to year — Basis of groundwork for ascertaining this, 310. Conside- ration of the argument that joint-stock companies are rated on their profits — Amount of profit must be known before rent can be determined in cases where the owner holds the property in his own hands, 311. Mode of arriving at the profits of large joint-stock companies — Arbitrary allowances for time, superintendence, interest of capital, &c., 312. Principle of estimating these — Method usually pursued on the part of gas companies — Summary of arbitrary allowances claimed — Method pursued by advocates for the parishes — Disputed allowances for salaries, interest, &c. — Statutable allow- ances, 313. Repair and restoration of buildings, insurances, &c. — Claims on the part of gas companies — Opposite views contended for on the part of parishes — Reproduction of the rolling stock and permanent way on railways — Depreciation fund set aside by some railway companies, 314. Decisions at quarter sessions in rating cases — Arbitrary allowances for reproduction — Proposed mode of estimating costs of reproduction — Example of proposed method of calculation — Estimate of allowance for reproduction of an object whose duration is assumed at thirty years — Allowance where the duration is assumed at various other terms of years, 315. Mr. Lee’s estimate of rateable value made in the appeal case against the rate in the parish of Greenwich — Detailed estimate of arbitrary deduc- tions and statutable deductions — Estimate for reproducing trade fixtures, mains, &c., 316. Method of estimating pursued by the valuers for the parish, 317. Mr. Penfold’ s estimate of net rateable value of the Phoenix Company’s works — Comparison of Mr. Pen- fold’s and Mr. Lee’s rateable value — Case of the British Gas Company and the parish of Ratcliff — Mr. Lee’s valuation in detail, 318. Valuation by the author on the part of the parish — Pro- duction account — Residual products — Cost of distribution — Statu- table allowances, &c., 320. Detailed estimate of gross revenue — Detailed estimate of the labour of manufacturing — Detailed estimate of wear and tear of etorts, 321. Detailed estimate of residual pro- ducts — Detailed estimate of expenses of distribution, 322. Detailed estimate of statutable allowances — Detailed estimate of capital re- quired by tenant, 323. DIVISION OF TILE NET RATEABLE VALUE BETWEEN THE SEVERAL PARISHES. Great variety of opinion existing on this subject — Judgments of the Court of Queen’s Bench — Principle of dividing rateable value in proportion to receipts — Principle of dividing in proportion to mileage of line — Injustice of this division — Principle of divid- ing rateable value according to the quantity of apparatus in each parish, 324. Lord Denman’s judgment in the case of the Queen v. CONTENTS. XV the Cambridge Gas-Light Company — Consideration of this mode of division in the case of railways — Application of the principle to the rating of gas-works, 325. Mode of dividing the rateable value between the works and the mains — Cases in which gas-works have more than one manufacturing station — Division of rateable value amongst the mains — Principle of dividing according to the square yards of ground occupied by the mains in each parish — Injus- tice of this mode of division, 326. Principle of dividing according to the cubic yards of main in each parish — Unfairness of this mode of division — Proposed mode of dividing the rateable value amongst the mains — Proportion to be used for ascertaining value in each separate parish, 327. Proposed annual assessment of railways, canals, gas-works, &c., by a public officer to be appointed for the purpose, 328. MANUFACTURE AND DISTRIBUTION OF COAL GAS. CHAPTER I. EARLY HISTORY OF GAS-LIGHTING. The discovery and earliest observation of elastic aeriform fluids, capable of being inflamed and of imparting light and heat, must undoubtedly have been of great antiquity ; inas- much as many ancient writings contain notices of inflammable vapours springing from fissures and cavities in the earth. It is evident, therefore, that gas being a natural production, no such human individual as its discoverer or inventor ever existed. Modern chemistry demonstrates that inflammable gases, whether arising naturally from springs, or produced artificially by destructive distillation or otherwise, are com- posed of very simple elements, and present a remarkable analogy to the common carburetted hydrogen, which is the gas chiefly burnt in our street lamps and houses at the present day. Inflammable gas may be truly said to be as old as the creation of organic matter, for wherever animal or vegetable substances have existed, by the immutable laws of nature they have been subject to decomposition ; and wherever de- composition has taken place, a variety of gases have been produced, some of them inflammable, and others not so. Whether the decomposition be that caused by the slow B 2 EARLY HISTORY OF combustion of decay, or the more rapid process caused by the application of sensible heat, the effect is the same — the gases are equally produced in the two cases. Gas may with truth be called a more natural production than steam, although the latter has existed from the first creation of water, and in its palpable state, as proceeding from boiling water, must have been observed in all ages, although without any views of its present application having been conceived. The discoveries of man with respect to gas and steam ought rather to be called applications ; they are conquests over the elements, and the subjugation of great powers in nature to his use and convenience. So it is with nearly all great inventions, in which we find one power of nature after another chained, confined, bound down, stored, and then let loose when required, and made to work machines, to propel ships across the ocean, to supply the place of human labour itself in a thousand variety of ways, — nay, to pass far beyond the bounds of human labour, and effect that, by a single effort, which the manual strength of a world coula scarcely accomplish. If such astonishing applications of steam and gas had been made in the days of ancient Greece, what magnificent, all-expressive, world - astounding names would have been found to convey their meaning: instead of such contemptible little monosyllables as gas and steam , one might have heard of the soul of coal and the spirit of water, with some superlative adjective to stamp the vast importance of each. In such an age these wonderful conquests would have thrown all meaner efforts into the shade ; for them, perhaps, would poetry have strung its harp, and the grandest epic pro- ductions of genius might have commemorated the victory of man over the inanimate matter of nature, instead of dedicating her loftiest songs to the art of war. The avidity with which the early nations seized on all natural phenomena, and all exhibitions of great natural powers, is evident from the veneration paid to the burning flames which issued forth from fissures and cavities in the earth where probably lakes of petroleum existed, or in GAS-LIGHTING. 3 the neighbourhood of coal or bituminous schists. Some of the earliest nations have considered fire as a type of divinity ; and we can scarcely wonder at the feelings of veneration and superstition occasioned by mysterious out- bursts of flame, whose origin appeared utterly incompre- hensible. Hence Superstition erected her altars over such flames, and claimed the interference of the Gods to sustain the perpetual miracle. But all that had been observed with reference to inflammable vapours in ancient times was very far indeed from approaching to anything like a useful pur- pose. Far from leading to any attempt to collect and use these vapours, their very nature and composition were un- known, and the most mistaken ideas prevailed as to their real elements. It was not till modern chemistry had exploded volumes of ancient dogmas, — had traced the so-called elements to far simpler forms, — aqd had divulged the laws according to which elements are combined in order to constitute all forms of matter, — it was not till then that it began to be seen that the inflammable vapour of coal, wood, oils, and other fatty substances, was analogous with the marsh gas which arises in bubbles from the decomposition of vegetables under water ; that it was of a similar nature to the fatal dancing “ Will-o’- the-Wisp,” which on the wild moor or bog has lighted many a traveller to destruction ; finally, that it resembled the gas which arises from the decomposition of water, however pro- duced ; and, in fact, that water, the greatest antagonist and extinguisher of flame, was itself composed of the most in- flammable substance in nature, namely, hydrogen gas ; while oxygen, the other element of water, is the greatest known supporter of combustion. Many opinions have been hazarded to account for the almost perpetual fires which were kept burning on the ancient altars. Strabo and Plutarch mention these fires, which they describe as constantly burning, to which they add, that they are lighted by invisible means. This seems to involve a contradiction ; for if they were always burning they could not require lighting. The altar in the Temple of iEgina may be taken as an example of most of the ancient Greek fire -altars as exhibited B 2 4 EARLY HISTORY 0* in t lie temples. Hero a round hole, about 13 inches in diameter, is observed in a block of stone. This round orifice opens into a square hole, which passes down through solid stone to a depth of several feet. The lower end of the square hole communicates with a cavity in which Mr. Dod- well supposes a fire to have been constantly kept burning, so that the flame did not appear above the surface of the circular opening. He says nothing more would be necessary than to pour oil into the opening, when the flames would immediately burst forth, and appear to have a miraculous origin. The writings of Herodotus, Otesias, and Vitruvius, men- tion the bituminous wells of Zakunthus, the modern island of Zante. HClian notices springs near Apollonia ; and Plutarch, in his Life of Alexander, mentions the fountain of naphtha with fire issuing from the earth in the territory of Ecbatana in Media (the modern Hamadan).* The Babylonian bitumen, used for cementing masonry, was obtained from the district which now forms the pashalic of Bagdad. Bituminous strata also exist in Switzerland, Germany, France, in the papal territory, in Great Britain, Ireland, Cuba, and other parts of the world. The springs described by Herodotus are not now worked ; but their place is defined by the remains of a circular wall about 70 feet in diameter, within which the space is nearly filled up with earth. The opening from which the bitumen was extracted in his day is described as communicating with the sea, which, in calm weather, is tinged with the iridescent colours of the bitumen as it rises up to the surface of the water. The bitumen is now drawn from small wells about 5 feet diameter and 3 or 4 feet deep. This mineral was much used by the ancients, as not only suitable for mortar, but also for cementing reeds together, and forming floors and ceilings. The superstitions of eastern countries have always identi- fied fire with the loftiest attributes of Divinity, and even with Divinity itself — while traces of fire-worship are said to exist * Dodwell’s “ Classical and Topographical Tour through Greece.’* London, 1819. GAS-LIGHTING. 5 even at the present day. In Plutarch’s Life of Aristides there is a passage marking the superstitious reverence which the fire of their celebrated altars enjoyed, where the conquer- ing Greeks under Pausanias are directed by the oracle of Delphi to build an altar to Jupiter the Deliverer, but not to offer, any sacrifice on it till they had extinguished all the fires in the country, because it had been polluted by the barbarians (the Persians), and supplied themselves with pure fire from the altar at Delphi. In consequence of this the Grecian generals went all over the country and caused all the fires to be put out.* The Chinese are said to use to this day, for economical purposes, the gas which escapes spontaneously from beds of bituminous coal. Within 30 miles of Pekin is a coal-field having beds of salt associated with the coal, and streams of gas rising naturally from the coal are conveyed to the salt- works by means of bamboo tubes, and there used for the boiling and evaporation of the salt. Other pipes convey the gas intended for lighting the streets and houses.f There are many other instances at the present day where inflammable gases issue from the surface of the earth : this is the case at several places in the Apennines, particularly near Pietra Mala, on the road from Bologna to Florence. A similar case occurs in a mountain of Lycia, near the shore of the Gulf of Adalia in Asia Minor. Most of these phe- nomena no doubt arise from coal or other bituminous sub- * Extract from Plutarch, relative to the fountain of naphtha in Ecbatana, or Hamadan. Alexander “ traversed all the province of Babylon, which immediately made its submission ; and in the district of Ecbatana he was particularly struck with a gulf of fire, which streamed continually, as from an inexhaustible force. He admired also a flood of naphtha not far from the gulf, which flowed in such abundance that it formed a lake. The naphtha in many respects resembles the bitumen, but it is much more inflammable. Before any fire touches it, it catches light from a flame at some distance, and often kindles all the intermediate air. The barbarians, to show the king its force and the subtilty of its nature, scattered some drops of it in the street which led to his lodgings ; and standing at one end, they applied their torches to some of the first drops ; for it was night. The flame communicated itself swifter than thought, and the street was instantaneously all on fire.” — “ Life of Alexander,” book v. p. 152, Langhorne’s translation. 1832. t R. C. Taylor, on the Coal-fields of China, in the Journal of the Franklin Institute. A similar instance occurs in the village of Fredonia, N.Y., where the inflammable gas issues from a small stream, called Canada Way, over which a gasometer is erected for collecting it. — Brewster’s Journal, 1830. 6 APPLICATION OF COAL GAS stances, which by earthquake or like means have been buried at such a depth as to be distilled by the heat from the interior of our globe, so that the gas is expelled, and escapes through the fissures of the earth. APPLICATION OF COAL GAS TO USEFUL PURPOSES. We find among the “ Philosophical Transactions ” of 1667, a paper by Mr. Shirley, describing a spring arising in the coal district of Wigan in Lancashire, and which was supposed at the time to be a burning spring, because the vapour on the surface of it could be inflamed. Mr. Shirley pointed out that it was not the water which burnt, but the gas by which it was accompanied ; and he traced its origin to the beds of coal which abound in that part of the country where the spring broke out. Although these observations of Mr. Shirley referred the origin of the burning spring to the right cause, and clearly pointed to the possibility of procuring the same kind of gas by the combustion of coal, the subject appears to have re- ceived no particular attention at the time, and it was not till many years had elapsed that we find another observer prompted by this very same spring to institute experiments of a prac- tical nature on the distillation of coal. Probably the first authentic record of an experiment on the distillation of coal, appears in Dr. Hales’ work on “ Vege- table Statics,’’ published in 1726, where he states that from the distillation of 158 grains of Newcastle coal he obtained 180 cubic inches of air (or gas), which weighed 51 grains, being nearly one-third of the whole. This result, which is rather more than 8,500 cubic feet per ton, agrees very nearly with the production of gas actually realised from Newcastle coal at the present day. A few years afterwards, namely, in 1733, we find in the “ Transactions of the Royal Society ” a communication from Sir James Lowther, on the inflammable air issuing from the shaft of a coal mine near Whitehaven. The workmen were surprised on sinking to the depth of 42 fathoms to find a rush of air taking place, which caught fire from the flame of a TO USEFUL PURPOSES. 7 candle and burnt with great intensity, making a blaze about 3 feet diameter and 6 feet high. Several experiments were made on this flame by the steward and others, who successively caused it to be extinguished by beating it down and smother- ing it with the colliers’ hats and again lighting it. At length the heat communicated by the flame was found to be very inconvenient, as it warmed the pit to a high degree, and it was necessary to have recourse to water in order to extinguish it. After this the gas was not again allowed to be lighted till the sinking had proceeded down to a depth of several feet below the bed of coal through which the gas first made its appearance. The part of the pit at which the gas escaped was then securely walled off, and a tube about 2 inches square extended up the shaft to a height of 12 feet above the surface of the ground. Through this tube the gas was allowed to escape into the open air, which it continued to do in un- diminished quantity for several years. Many observations and experiments were made on the gas which was thus dis- charged from the extremity of the tube. It was collected in bladders, tied up and preserved for many days. When a small pipe was fixed in the mouth of the bladder, and the gas gently pressed out against the flame of a candle by squeezing it, the gas was observed to take fire, and to burn so long as the bladder was gently squeezed and the gas expelled. This experiment on gas which had been so confined nearly a month was made in the presence of the Royal Society. It was stated that the gas when it first issued from the top of the tube was as cold as frosty air, and that it would not take fire from a spark, but required a flame to ignite it. Some thirty years after the attention of the scientific world was thus called to the nature and properties of inflammable air or gas, — namely, about the year 1765, — we find a pro- position made to the magistrates of Whitehaven by the then agent of Lord Lonsdale, to convey this same gas through pipes to light the streets of the town. The magistrates, it appears, refused to entertain the subject, although the proposer, Mr. Spedding, proved its perfect praticability by conveying the gas into his own office and using it for the purpose of lighting. In the “ Transactions of the Royal Society ” for the year 8 APPLICATION OF COAL GAS 1789 is a paper by Dr. Clayton on the subject of distilling pit coal. This paper is an extract from a letter written by the author to the Honourable Bobert Boyle, who died in 1691. The letter, therefore, was probably written some time before this, and although not published till 1739, it appears clearly to confer on Dr. Clayton the merit of an earlier experiment on the mode of procuring gas from the distillation of coal than that described by Dr. Hales in 1726. I shall not quote in detail the experiments concerning the spirit of coal contained in Dr. Clayton’s letter to Boyle, as this letter appears in nearly every work on gas which has since been published in this country, and must therefore be familiar to most English readers. Those w T ho may wish to see the complete extract from Dr. Clayton’s letter will, how- ever, find it in page 59 of the “ Philosophical Transactions” for the year 1789. The author first gives an account of the ditch near Wigan in Lancashire, described by Mr. Shirley, in which the water was said to burn. He proved; however, the fallacy of this supposition, by causing a dam to be made and having the water below the dam scooped out of the ditch. At first the vapour would not take fire, but on digging down about 18 inches the vapour which arose from a shaly kind of coal took fire from a candle, and continued burning. Suspecting from the proximity of coal the true origin of this inflammable vapour, the Doctor proceeds to say, that he procured some coal and distilled it in a retort over an open fire. He de- scribes the products of his distillation as a phlegm which first came over (naphtha), afterwards a black oil (tar), and then likewise a “ spirit arose which I could noways condense, but it forced my lute or broke my glasses.” He discovered accidentally that this spirit (the gas) was inflammable. He then proceeded to collect it in bladders, and preserved it in these for the amusement of his friends, before whom he was in the habit of pricking holes in the bladder with a pin, and gently compressing it till the small stream of gas took fire at the flame of a candle, when it would continue burning till all the gas was pressed out. It is curious that the process of exosmose (hereafter explained) was observed at this early stage of experiments on coal gas, for the Doctor says when TO USEFUL PURPOSES. 9 he filled calves’ bladders with the gas, it would lose its inflam- mability in twenty -four hours ; he therefore recommends good thick bladders like those of an ox. The publication of Dr. Clayton’s experiments, although they clearly pointed to the practicability of procuring and storing up an inflammable gas derived by distilling coal, appears to have attracted no further notice at the time. No progress whatever appears to have been made in discovery for many years afterwards. To the celebrated Dr. Watson, afterwards Bishop of Llandaff, we are indebted for the first notice of the important fact that coal gas retains its inflammability after passing through water into which it was allowed to ascend through curved tubes. This is noticed amongst other results of Dr. Watson’s experiments ip the second volume of his “ Chemical Essays,” published in 1767. To this property is due much of the facility with which the manipulations of a gas-making establishment are carried on, particularly those connected with the hydraulic main, and the purification by means of wet lime. With the exception of Bishop Watson’s experiments, the whole subject of procuring from coal a valuable product in the shape of inflammable gas appears to have slumbered for more than half a century, till about 1790 we find an indivi- dual, who was afterwards connected with one of the first engineering workshops in the world, turning his attention to the subject in a truly practical form. This individual was Mr. William Murdoch, then resident at Truro, in Cornwall, and afterwards connected for many years with Messrs. Boulton and Watt’s establishment at Soho. There can be no doubt as to the exclusive merit of this gentleman, whose claim is unquestionable to the first practical application of artificially manufactured gas to the purposes of lighting. From his own narrations, written with all the earnest sim- plicity which commonly attends the development of great ideas, it even appears doubtful whether he was acquainted with the papers of Dr. Clayton already alluded to. It is also satisfactory to find that the pre-eminent claim of Mr. Mur- doch is most clearly and distinctly confirmed by the celebrated B 3 10 APPLICATION OF COAL GAS I)r. Henry, that brilliant philosopher; whose researches into the nature of aeriform fluids have gained for him the admi- ration of all Europe. It appears from Dr. Henry’s statement, that, in 1792, Mr. Murdoch actually lighted his own house and office at Redruth with gas. He distilled the coal in iron retorts, and conveyed the gas through tinned iron and copper tubes to a distance of 70 feet. He used portable gas, carrying it about with him in a bladder, or in bags of leather or varnished silk, and also in vessels of tinned iron fitted with a small metal tube and stop-cock, through which the gas, issuing from a minute orifice, was ignited, and made to serve as a lantern in travel- ling backwards and forwards between the mines and his ow^u house. He is said to have excited the unbounded astonishment of the country people, and to have confirmed them in the belief that he was a real wizard, by travelling in a steam carriage lighted up at night with gas contained in bladders. Mr. Murdoch also at this early period made many experiments on various kinds of coal, as the Swansea, Haver- fordwest, Newcastle, Shropshire, Staffordshire, and some kinds of Scotch coal. He also tried numerous forms of burners, varying in many ways the shape and disposition of the orifices for the emission of the gas. Thus, in some burners, the gas was allowed to issue from many very minute openings, form- ing a rose like the head of a watering-can, while in others it was thrown out in long thin sheets, and again from circular openings, on the principle of the argand burner. His atten- tion was also directed to the necessity for purifying the gas, and he certainly adopted the expedient of passing it through water, but does not appear to have made use of lime, the first application of which, to the purpose of purifying, appears due to Dr. Henry and Mr. Clegg. Mr. Murdoch pursued his experiments on the gas from coal, peat, wood, and other inflammable substances, at such intervals of leisure as his numerous other avocations would permit, principally with the intention of avoiding the disagreeable odour peculiar to it. About 1796, Mr. Murdoch communicated to Mr. James Watt, jun., son of the celebrated James Watt, the engineer, his views of employing gas as a substitute for lamps and TO USEFUL PURPOSES. 11 candles, and suggested that a patent should be obtained for that object. This proposal was not, however, entertained by Mr. Watt, on account of the heavy expenses his father had incurred a short time previously in defending some patents in connection with the steam-engine.* In 1798 Mr. Murdoch lighted part of the Soho foundry with gas, and exhibited his experiments to a few friends, who, in after years, when his claims to priority for the adap tion of gas were disputed, gave their testimony, and proved the entire justice of his pretensions. In 1799 a French engineer, of the name of Lebon, ob- tained a patent in France for procuring gas from wood, peat, cfec., and applying it to the purpose of illumination. This circumstance has caused French authors (who ignore the claims of Mr. Murdoch) to invariably award the merit of priority of application to their compatriot. In 1801, the brother of Mr. James Watt being in Paris, wrote, saying, “ that if anything were to be done with Mr. Murdoch’s gas, it must be done at once, as there was a Frenchman in Paris who had similar ideas, and proposed to illuminate that city by these means.” However, from some unaccountable cause, the patent was never applied for ; and it may be assumed that neither Mr. Watt nor Mr. Murdoch had the slightest conception of the gigantic industry they were on the threshold of establishing. The year 1802 is very remarkable in conjunction with gas lighting, for in that year, on the occasion of the procla- mation of peace, a public exhibition of gas-lighting was made at the Soho foundry ; and Mr. Matthews, an eye-witness, states, “ the illumination of the Soho works on this occasion was of the most extraordinary splendour ; the whole of the front of that extensive building was ornamented with a great variety of devices that admirably displayed many of the varied forms of which gas-light is susceptible. This lumi- nous spectacle was as novel as astonishing, and Birmingham poured forth its numerous population to gaze at and admire the wonderful display of the combined effects of science and * Evidence of Mr. James Watt before Committee of House of Commons, 1809. 12 APPLICATION OF COAL GAS art.”* Mr. Murdoch, however, had many difficulties to over- come before he attained the perfection which he exhibited on this occasion, but he united sound scientific knowledge, with great practical skill, and his perseverance enabled him to triumph. In this year M. Lcbon, before mentioned, had his house in Paris illuminated by gas, and numbers of people of all classes witnessed it with wonder and amazement. Also at the same period, Mr. Winsor, who afterwards did so much for the advancement of gas-lighting, being at Brunswick, saw an account of the “ rapport ” or communication of M. Lebon on gas for illuminating purposes, which had been read before the French Institute ; and, to use his own words, employed five years after, “ the thought struck him like an electric shock.” He translated the communication of M. Lebon into German and English, which he published as a pamphlet. He also carried out a series of experiments in connection with gas-lighting by distilling wood, &c., before the duke regent, Charles William Ferdinand, and his court.*)' And the same year he came to England (undoubtedly en- tirely ignorant of what had been achieved by Mr. Murdoch), with the intention of carrying the new enterprise into operation. In 1803 Mr. Winsor first publicly exhibited, at the Lyceum Theatre, in London, the system of illumination by gas. Here he delivered lectures on the subject, which he illustrated by a variety of interesting experiments ; amongst them he showed the means of conveying gas from one part of a build- ing to another, and by the employment of different burners was enabled to display the various forms which might be given to its flame. He also proved, in a very elaborate manner, the various advantages of gas-lighting, and its supe- riority over all other artificial light, all of which time and experience have fully confirmed. In 1802 and 1803, Mr. Murdoch erected works for the supply of gas to the premises of Messrs. Boulton and Watt; and in 1804, Mr. George Lee, of the firm of Messrs. Phillips * Matthews’ “ Historical Sketch of Gas Lighting.” t French translation of Accum on Gas, by F. A. Winsor. TO USEFUL PURPOSES. 13 and Lee, of Manchester, had liia dwelling lighted by gas, in order to test its salubrity, previously to its adoption in the cotton mills of the above-mentioned firm, and the following year the mills alluded to were so lighted ; and Mr. Lee's evidence afterwards contributed considerably towards over- coming the prejudice which existed against gas-lighting, and to demonstrate its advantages and economy. The quan- tity of light supplied to these mills was equal to that yielded by 2,000 mould candles of six to the pound, or about 2,500 cubic feet per day on the average of the whole year. To produce this quantity he used 7 cwt. of Wigan cannel coal, yielding at the rate of 7,143 cubic feet of gas per ton of coal, considerably less than the quantity made at the present day from the same coal. In his paper of 1805, vwhich was published in the “ Philo- sophical Transactions ” for 1808, Mr. Murdoch does not particularly describe the process which he followed in making the gas, but merely states that the coal is distilled in large iron retorts, and that the gas, as it issues from them, is conveyed by iron pipes into large reservoirs, or gasometers, where it is washed and purified previous to its being con- veyed through other pipes or mains to the mills. He describes the burners with some minuteness : these were of two kinds, one on the principle of the argand lamp, and resembling it in appearance ; the other a cockspur burner, consisting of a small curved tube with a conical end, having three circular apertures or perforations about one-thirtieth of an inch in diameter, one at the point of the cone, and two lateral ones The gas issuing through these apertures forms three diver- gent jets of flame, somewhat like a fleur-de-lis. The whole of the burners erected in the cotton-mills amounted to 271 argands, each of which gave a light equal to four mould candles of six to the pound, and 633 cockspurs, each of which gave a light equal to two and a quarter of the same candles. The quantity of tallow consumed by each candle was at the rate of four-tenths of an ounce, or 175 grains of tallow per hour. In his details of the comparative cost of lighting this establishment with gas, as compared with candles, Mr. Mur- 14 APPLICATION OF COAL GAS dock’s comparison is very much in favour of the former. Taking an average of two hours per day throughout the year, the expense of candles would be £2,000 per annum, while the cost of gas, including every expense of wear and tear and interest on capital, did not exceed £600 a year. On an average of three hours per day, the comparison is still more in favour of gas, the expense of candles in this case being £3,000 a year, while that of gas, estimated as before, would only amount to £650. Daring his experiments, and in erecting his earlier appa- ratus, Mr. Murdoch tried various forms of retorts, which will be more particularly noticed in the chapter on this subject, so that it may be sufficient to observe that the earliest forms were upright, with various contrivances for extracting the coke which remained after the expulsion of the gas. Many inconveniences attended this form, as well as an interme- diate form, in which the retorts were placed in a diagonal or inclined position. In time all the other contrivances gave place to the horizontal retort, which is the mode of setting universally adopted at the present day. The success of Mr. Murdoch’s new mode of lighting the cotton -mills of Lancashire appears to have enlisted a host of ingenious and speculative persons, who entered eagerly upon the course now open before them. About the years 1804 and 1805 w T e find the subject taken up by eminent chemists, such as Dr. Henry of Manchester, who ably illustrated the mode }f making gas in his lectures, and showed how readily and economically it might be used as a substitute for oil and candles. At this time also we find Mr. Clegg, an able mechanician, also engaged in the same establishment as Mr. Murdoch, where he entered as a pupil of Messrs. Boulton and Watt, devoting all his energies to the mechanical appliances connected with the successful application of gas. Mr. Northern of Leeds, Mr. Pemberton of Birmingham, and Mr. Accum were actively engaged at this time in experi- ments on coal gas, the means of procuring it and applying it to lighting purposes. Many of the contrivances and sugges- tions of these gentlemen were highly ingenious, and they each exhibited before the public gas-lights produced from appa- TO USEFUL PURPOSES. 15 ratas of tlioir own erection. The apparatus was of course on a very limited scale, and it does not appear that any inter- mediate process was practised between the retort and the burner, except that of washing the gas by passing it through water so as to condense and cool it before entering the gas- holder. Mr. Clegg appears to have struck off in the same direction as Mr. Murdoch, and to have embarked about the same time in the erection of private gas-works for cotton-mills and other establishments. Thus he was engaged in lighting the cotton- mill of Mr. Henry Lodge at Sowerby Bridge, near Halifax, at the same time that Mr. Murdoch was erecting his works at Messrs. Phillips and Lee’s mill. Indeed, Mr. Clegg, jun., states, on the authority of his father’s journal, that the mill at Sowerby Bridge was lighted a fortnight earlier than the one under Mr. Murdoch’s direction. In the following years, 1807 and 1808, Mr. Clegg pro- ceeded to erect gas-works at various other mills, and at the Catholic College at Stonyhurst, in Lancashire, where he first introduced the system of purifying the gas from carbonic acid and sulphuretted hydrogen by passing it through lime in a separate vessel. Previous to this use of a separate purifier, Mr. Clegg had used lime in the tank of the gas-holder, and applied an agitator to keep it in motion, but the difficulty of removing the saturated lime eventually led to its abandon- ment, and the adoption of a separate vessel. In this year Mr. Murdoch communicated to theBoyal Society a very interesting account of the successful application of coal- gas to lighting the extensive cotton-mills of Messrs. Phillips and Lee, of Manchester ; for this communication, Count Bumford’s gold medal was presented to him. The following year Mr. Clegg communicated to the Society of Arts his plan of an apparatus for lighting manufactories with gas, for which he received a silver medal. About the same period he erected a gas-apparatus for the manufactory of Mr. Harris, at Coventry. In 1801 Mr. Winsor obtained a patent for “ an im- proved oven, stove, or apparatus, for the purpose of extract- ing inflammable air, oil, pitch, tar, and acids, from, and re- 16 APPLICATION OF COAL GAS during into coke and charcoal, all kinds of fuel, which is also applicable to various other useful purposes.” “ A metal, brick, or earthen stove, oven, retort, or vessel, is so constructed to reduce by means of fire and heat all raw fuel of any kind into coke and charcoal, without any, or little, consumption of the fuel, by which operation the smoke being extracted from all raw fuel, is thus conducted through cold air or water into a condenser, where, after being suffi- ciently cooled and purified, it undergoes a natural chemical resolution into tar, pitch, oil acid, ammonia, and inflammable gas or air. “ The inflammable gas or air may be led in a cold state through tubes of silk, paper, earth, wood, or metal, to any distance, in houses, rooms, gardens, places, parks, and streets (and other places), to produce light and heat, or for any other purpose, such as for increasing and multiplying force and power.” This was the first patent obtained in connection with gas- lighting. Having this patent, Mr. Winsor described himself as the discoverer, inventor, and patentee of gas-lighting, and agi- tated the necessity of forming a company for its full develop- ment, so that the streets, shops, and private dwellings should enjoy its advantages; but gas-lighting, like every other great innovation, was looked upon by the public with excessive distrust. In the event of its success, several branches of in- dustry and commerce were doomed to suffer ; many interests were, or supposed to be, at stake ; some of the chemical pro- perties of gas were unknown ; great doubt existed as to its safety, and fears as to its salubrity ; indeed, the danger of explosion was magnified to the extent that it was asserted, and believed, that a town could be destroyed by the explo- sion of the main pipes in the streets ; and interested parties, in order to prevent the establishment of gas-lighting, did not scruple to appeal to the naval glory of the nation, and this shortly after Nelson had achieved his great victories. “ If,” said the opponents of the new light — “ if this become suc- cessful, then our naval supremacy is gone, for at present we obtain principally our artificial light from the whale fisheries : TO USEFUL PURPOSES. 17 these are the nurseries of our best sailors ; so if we destroy the one, the other must be affected; if the fisheries no longer exist, our navy must degenerate.’’ These objections and arguments were put forth frequently by the journals ; and Mr. Winsor, who by this time had become intimately associated with gas-lighting, and in a manner constituted himself its champion, met them with that extraordinary courage, perseverance, and zeal which so strongly characterised him ; but it is to be regretted that although a gentleman of superior intelligence — with the great qualities already awarded him — he lacked the scientific knowledge so' essential for the fulfilment of his undertaking, and unfortunately he was not aware of this deficiency. He boldly combatted all possible objections with unexampled ardour, but often committed the most egregious errors, at one time asserting that our atmosphere in its pure state was too powerful a medicine, and that a mixture of coal-gas rendered it more salubrious; again, that gas w T ould not explode when intermixed with air, and that its adoption would purify the atmosphere ; whilst the prospectus issued by him con- tained most extraordinary, exaggerated, and fabulous accounts of the enormous profits to be derived from gas-lighting. All this combined to retard his progress, and had he been of a less sanguine nature, his task would have been comparatively easy. These errors often brought down upon him the greatest ridi- cule, in which some of the leading scientific journals took prominent part ; but, undaunted, he still persevered. At length, after having struggled, during four years, single-handed, and, as it were, against the opinion of the world — having by his letters, pamphlets, lectures, &c., proved the advantages of gas — Mr. Winsor succeeded, in 1807, in obtaining a capital of £20,000 by means of subscribers, preliminary to the formation of a company ; which sum was intended to demonstrate the practicability of manufacturing and supplying gas on a large scale ; also for the purpose of forming the company, and obtaining a royal charter. Mr. Winsor then occupied extensive premises in Pall Mall, on the site of the present Carlton Club. On the basement he had gas manufacturing and other apparatus to 18 APPLICATION OF COAL GAS illustrate his lectures, demonstrating the practical utility of gas for lighting, heating, and cooking, also its safety and salubrity ; the public, on certain days, having free access to take cognisance of the process. From these premises a pipe was laid in Pall Mall to the corner of St. James’s Street westward, and to the Haymarket eastward, with lamp-ptfsts at short intervals, including several in front of Carlton House, the residence of the Prince Pegent ; and thus Pall Mall was the first street ever lighted by gas, and continued so during the sessions of parliament of 1809 and 1810, whilst endeavouring to obtain an Act of incorporation and charter. The intention of Mr. Winsor, and his subscribers or shareholders, in 1808, was to establish a company, and obtain a royal charter or exclusive privilege for lighting all the British possessions by gas ; and for this purpose they proposed a capital of one million sterling.* A memorial was accordingly presented to the king, setting forth the advantages which would result from gas -lighting, and the production and general employment of coke, praying for the concession ; but after the question had been duly considered in Privy Council, it was decided that his Majesty could not grant the charter of incorporation until a Bill had been obtained from parliament authorising the company. The following year Mr. Winsor and his shareholders again applied, with more moderate pretensions, to be esta- blished as the “National Light and Heat Company,” but were strongly opposed by Mr. Murdoch ; and on this occasion many scientific witnesses were examined before a committee of the House of Commons, who proved incon- testably that gentleman’s claim to priority of adopting gas for illumination. The evidence given is of the greatest interest ; but the errors of a leading witness for the com- pany, and the merits of Mr. Murdoch, caused the application to be refused. Amongst Mr. Winsor’s subscribers were some eminent men of the day, and, like himself, of the greatest perseve- rance and zeal. They had already been too familiar with difficulties to be discouraged by defeat ; and again, in 1810, * French translation of Accum on Gas, by F. A. Winsor. TO USEFUL PURPOSES. 19 they applied to parliament, and succeeded in obtaining an Act of incorporation as the “ Gas-light and Coke Company,” with a capital of £200,000. But the enterprise was looked upon as so visionary, that it was asserted this Act was granted in order to make a great experiment of a plan of such extra- ordinary novelty. The royal charter was granted to the company in 1812 ; but the privileges accorded by that charter were neither liberal nor encouraging ; for by it the company had no exclusive right, so as to prevent any other persons or com- pany from entering into competition with them. The power and ‘ authority granted were very moderate ; and whilst the company were under severe restrictions, they were confined to the metropolis, and were liable to have the charter annulled if they failed to fulfil their obligation. The very prominent part taken by Mr. Winsor in esta- blishing gas lighting has often been passed over, whilst his errors, the result of a very sanguine mind, have been displayed with all vigour ; and whilst the sacrifices he made have been forgotten, he has been represented as being actuated entirely by selfish motives ; but the evidence given before parliament on the subject of gas-lighting in 1809 and 1810 proves beyond doubt the important services he rendered to that art, and that through his instrumentality was the first gas company established. The injustice of the charge of selfish interestedness may be met by the fact that in 1815 and 1816, instead of remaining in England, and profiting by the position his labour and energy had created him, he went to France, there to fight again the battles he had so often fought in favour of gas-ligjiting ; and Mr. Peckstone only does justice w r hen, speaking of Mr. Winsor, he says, “ San- guine in his expectations, indefatigable in his exertions, and zealous in his cause, he directed all the talents and energy he possessed to the one great object, and thus achieved much for the public good ; but with all his ardour, his skill, and his exertions, he, like many others, achieved but little towards promoting his own comfort, or the comfort of his family.” The Gas-light Company being thus legally established, they commenced their operations at a wharf and premises 20 APPLICATION* OF COAL GAS in Canon Row, Westminster ; and there the new industry was left in the hands of chemists, who, however competent they might have been in their legitimate profession, were void of that mechanical knowledge and skill so essential to their task : in consequence, numerous experiments were made, at- the expense of a large portion of the capital invested ; and the shareholders, who had hitherto shown such extraordinary patience so long as the enterprise was only in project, now began to lose heart, when they saw so much money sacrificed, and so little done towards com- mercially realising their hopes and expectations. At this period, when the practical application of gas ap- peared doubtful, the company had the good fortune to engage Mr. Clegg, before-mentioned, as their engineer. This gentle- man had already acquired considerable experience in erecting gas-works. His genius rendered him capable of surmounting the greatest difficulties he encountered ; and he may with justice be said to have established the manufacture of gas. The main features in the present system of gas-lighting which are due to Mr. Clegg are, the system of wet-lime puri- fication ; the hydraulic main, with its contrivance of dip-pipes for isolating the retorts ; the mode of attaching the mouth- pieces to the retorts ; the governor or regulator for adjusting the delivery of gas into the mains; to which must be added the gas-meter in its earliest and most novel form, which was afterwards perfected by Mr. John Malam, aided by Mr. Samuel Crosley, and which will claim particular attention at a future page. These are the principal parts of the mechanism of gas apparatus introduced by Mr. Clegg, and which have become essential parts of the gas manufacture, while there are many other contrivances of perhaps equal ingenuity and merit which have not been successful. Among these are the rota- ting or web retort, of which a notice will be found further on ; the inferential dry gas-meter, the collapsing gas-holder, and an apparatus for the decomposition of oil, tar, &c. A review of these various inventions undoubtedly places the name of Mr. Clegg in the very foremost rank of those who have advanced the practice and science of gas-lighting. TO USEFUL PURPOSES. 21 In December, 181 3, Westminster Bridge was first lighted by gas ; and in the following year the old oil lamps were removed from the streets of St. Margaret’s parish, West- minster, and gas-lights put in their place ; this being the first parish w'hich applied for a contract to have the streets lighted with gas. / In the year 1814, when the allied sovereigns visited this country, and a general illumination took place in commemo- ration of the peace of Europe, the new light was brought into requisition, and exhibited to thousands of admiring spectators, in illuminating a magnificent pagoda erected in St. James’s Park. This building was instantaneously lighted up by a simple contrivance ; and in a single instant of time 10,000 lights burst forth, and formed an immense and brilliant fountain of fire. In the following year Guildhall was lighted up with gasj and on this occasion the public papers teemed with extravagant praises of the new light. Its mild splendour was described as “ shedding a brightness clear as summer’s noon, but undazzling and soft as moonlight, altogether forming a magnificent combination worthy the inauguration of the presiding citizen of the great city.” After the founders of the gas company had striven against and overcome the errors of public opinion — had become established — had expended considerable sums in experiments, and incurred great losses in carrying the new science to a successful issue — this done, and the trade being open to all, then arose rival companies in the metropolis, these being the City of London, the South London or Phoenix, and the Imperial. Other companies were also established, in Glasgow’, Edinburgh, Manchester, Bristol, Bath, Leeds, Chester, Chel- tenham, Macclesfield, Exeter, Birmingham, Rochester ; and such was the rapid progress of gas-lighting from 1814, that all the works in these, as in many other towns, were in operation in the year 1819. From about the year 1815 the names connected with gas- works become so numerous, inventions of all sorts and descrip- tions multiply so fast, and the records of the Patent Office exhibit such a spirit of invention, that it would be impossible to follow them in anything like detail. I must therefoie bo 22 APPLICATION OF COAL GAS satisfied with briefly noticing a few of the successive steps by which the practice and science of gas-lighting advanced until it entirely superseded all other modes of public lighting in the metropolis and other large towns, and even came to be exten- sively used for domestic illumination in place of candles and lamps. In 1815 Mr. John Taylor patented the means of obtaining gas from oils, fat, resin, and other oleaginous substances. The superiority of the gas thus obtained is unquestionable. It contains a much larger quantity of olefiant gas than that from common coal, and it had long been known that olefiant gas, containing as it does double as much carbon as ordinary carburetted hydrogen, was by far the most valuable ingre- dient for illumination in any inflammable gas. The gas from oil would also be free from sulphuretted hydrogen, and other impurities which cause considerable expense in the purifica- tion of coal gas. In addition to this, the advocates of oil gas contended that the expenses of production and management would be much less than in a coal-gas establishment, and that the large supply of oil required would afford employment to thousands of fishermen, who would be engaged in the capture of fish suitable for yielding oil in sufficient quantity. Of course all considerations of this nature require to be tested by actual practical experience, and when this was applied to the case of lighting by means of oil gas, the results were widely different from those w 7 hich had been anticipated in theory. It was found impossible to work the establishments with any- thing like the same economy as those for producing coal gas, and all the companies, without exception, found it w T as hope- less to expect any dividend for their outlay. Under these circumstances the oil-gas works w^ere abandoned one by one, and apparatus for distilling coal substituted in their place. But for some years oil gas w T as considered to be a for- midable rival to coal gas ; its vast superiority w 7 as supported by some of the first chemists of the day ; amongst them were Mr. Brande, Professor of Chemistry at the Royal Insti- tute, Mr. Michael Farraday (who has since acquired a world- wide reputation), then assistant to Mr., afterwards Sir, Humphry Davy, and Sir William Congreve, the govern- TO USEFUL PURPOSES. 23 ment inspector of gas works for the metropolis. According to these gentlemen, the light obtained from oil gas, compared with that from coal gas, was in the prop^j±feli^Qf three and a half to one. They also asserted that^as from oipfcas supe- rior on many accounts to that from dml. Sir W^^t^Con- greve stated, “ the most important/feature^aT the oil gas was its safety; as from the v^lry^ narrow Jiipits^^\^e explosive mixture that can be forme® qf this gfc&^it is.sctp^ely possible that an accident can occur. V'" ^ S Mr. George Lowe, who for mai^X^ears, so l^nouyabljf filled the post of consulting engineei\tf(0the Cliar£ered*l3a£ Company, being at that time at Derhw'^as thenrst al most conspicuous person who entered the^ld to oppose/jpe advocates of oil gas ; and his extensive lurrie d g the subject fully qualified him for engaging in the contest His communications to the various scientific journals on the sub- ject, while carrying conviction with them, were always cha- racterised by the peculiar wit and good-humour that those who have had the pleasure of his acquaintance can readily understand. The evidence given by Mr. Lowe before a committee of the House of Commons in 1823 on oil gas, was the severest blow it had received ; for he then convinced the committee of inquiry, by actual experiment, that oil gas was as explosive as that produced from coal ; that the light of oil gas was barely double that of the other ; and that very similar impu- rities existed both in oil and coal gas. His testimony on those occasions was so clear and positive, as to carry convic- tion with it, and sufficient to shake the opinions of those who hitherto had held oil gas in the highest estimation. In 1819 we find Mr. David Gordon obtaining a patent for compressing gas into suitable vessels fitted with proper valves, and capable of being carried about, so as to render the gas portable. This contrivance, which can scarcely be called an invention, as it had been practised by Mr. Murdoch many years before, led to the formation of the “ London Portable Gas Company.’* However, after carrying on business some * This was somewhat erroneous, as the force of explosion frrm a given quantity of gas is in proportion to the carbon combined therewith. 24 APPLICATION OF COAL GAS time, it was found tliat tlie scheme would not answer, and the company was ultimately broken up. About the same time Professor Daniel], F.R.S., was engaged in an unsuc- cessful attempt to make gas from resin. It is said that his apparatus was highly ingenious, but the project on trial was soon abandoned, from inability to compete with coal-gas works. The Act for lighting Bristol with oil gas was obtained as late as 1823, in spite of the warnings of several eminent gas engineers that the project would prove unsuccessful. The truth of these warnings was amply confirmed in the course of a few years. Paris was first lighted by gas in 1820, and although pre- viously strong prejudices existed against the project, yet, when carried out, it produced a corresponding enthusiasm ; and, to give an instance, a French author of the period, writing to a friend, describing the new light, said, “ where gas-light exists there is no night ; where gas-light is, there is continuous day.” He also mentioned, in the most glowing terms, the transcendent beauty of the ladies, as seen thereby. Here, it must be observed, that all the bright prospects, all the enormous profits calculated to be derived from gas enterprises, were far from being realised ; for, at the com- mencement, and for years after, commercially, they failed — few, if any, were successful. The causes of this loss were various ; in some instances the main pipes were either so bad, or laid in such a defective manner, that a large portion of the gas escaped. The extravagance of many consumers in burning, which no personal surveillance could control or counteract, was another serious source of evil. If we add the want of experience in the manufacture and distribution of gas, and the amount of misplaced and abused confidence, then we can understand how gas companies were unprofit- able. And to such an extent was this kind of property depreciated, that a London company was disposed to sell its plant, &c., to a rival establishment for about one-twentieth part of its cost ; a difference of a comparatively insignificant sum prevented the sale being effected. Such is a brief sketch of the leading historical facts which mark the progress of gas-lighting till within the last thirty TO USEFUL PURPOSES. 25 years. The chapters which follow will explain the modern system of constructing and working establishments for manu- facturing gas from coal. I can only hope, however, to present a fair selection of the various practices and contri- vances, which vary very much at different works. A gra- dual spirit of improvement has characterised the progress of all gas establishments, and improvements made almost imper- ceptibly, year after year, have brought their efficiency up to a high standard. This is evidenced in a most practical manner both by the increased produce of gas, and by the diminution of price to the consumer. In the metropolis few of the companies now charge more than 4$. per 1,000 feet for gas, yet the price a few years ago ranged from 8s. to 10s. While molt of the general arrangements have remained the same, more especially those for which we are indebted to Mr. Clegg, a constant succession of improvements in the sub- ordinate parts has vastly improved the value and efficiency of gas-lighting, thus alike benefiting the companies and the public. Amongst the most important of these improvements are, the very general adoption of clay retorts instead of iron, the more perfect system of main laying, by which the loss of gas is reduced almost to a minimum, the use of the scrubber, the improvements in purification — in short, a systematic change has taken place, ensuring alike economy in the manufacture and distribution of gas. Again, as connected with the dis- tribution of gas, the modern system of fittings deserves espe- cial commendation when contrasted with the very imperfect mode in which this kind of work was originally executed. The business of the gasfitter — one of considerable skill and nicety — has been, in fact, like many others, created since the general introduction of gas-lighting. When we consider the difficulty of confining in metallic pipes a subtle aeriform fluid of only half the specific gravity of common air, convey- ing it into all kinds of corners, and all parts of buildings, in addition to the use of innumerable cocks and burners, the delicacy and nicety required in every part of the gasfitter’s manipulation are entitled to considerable admiration ; while the advantage he has derived from the beautiful invention of O 26 ON THE CHEMISTRY OF GAS-LIGHTING. welded iron tubes and pewter-drawn tubes, contrasted with every other form of metallic tubing originally in use, adds considerably to his facilities. Gas may now be burnt in private houses without the slightest effluvia or escape from any of the pipes, joints, or fittings, and if properly purified, may be burnt in any kind of room, however highly orna- mented by gilding and otherwise, without being in any way prejudicial CHAPTER II. ON THE CHEMISTRY OF GAS-LIGHTING. In all the contrivances which have been used for producing light from oleaginous or fatty matters, either in lamps or in the form of candles, the various component parts of gas, as the carbon and hydrogen, are always vaporised and put into the form of gas before their combustion takes place. In this point of view every wick burning in any kind of lamp or candle is, in fact, a small laboratory for the production of gas, which is burnt or consumed at the instant of its pro- duction. It was reserved for the chemistry of our own day to point out this analogy, as it was reserved for the practical skill of our engineers and machinists to bring to perfection the means of producing this gas on a large scale, of storing it for an indefinite period, and then sending it forth whenever required, into our streets and houses, to communicate light, and enable mankind to pursue their useful and laborious avo- cations alike when darkness shrouds the earth, as well as in the light of day. A beautiful action takes place in the combustion of an ordinary lamp or candle, in which the wick surrounded by flame represents a series of capillary tubes to convey the melted matter in the form of gas into flame. This action ON THE CHEMISTRY OF GAS-LIGHTING. 27 will be very apparent to any one who will watch the process of combustion in an ordinary wax or tallow candle. First, he will perceive a cup of melted matter around the wick, in which a great number of small globules are seen constantly in progress towards the wick. Many of these globules are also seen standing on the wick, studding it all over like little sparkling diamonds. Let us consider what these globules contain. They are filled with the inflammable gas produced by the heat applied to the melted w^ax or tallow, but fortu- nately for the success of this method of burning, these globules do not break and set free the gas until they come into close contact with the flame, when the heat becomes so great that the expansion of the gas causes each little globule to bleak and add its contents to the already burning flame. How beautiful is this provision ! How exquisitely constituted are the properties of matter to cause this beautiful result ! In every common candle we behold an apparatus of wonder- fully refined ingenuity, in which gas is being enclosed in little microscopic pellicles, which are floated to the base of the wick. There hundreds of these little tiny globules are seen ascending the wick, while hundreds of others are every instant exploding and discharging their contents into the flame, which is thus made up by the instant combustion of gaseous matter at the moment when it leaves the liquid form, through the medium of this intermediate stage, in which it assumes the form of an infinitely small translucent glo- bule. It is obvious if the gas were to be actually formed at the surface of the small cup of melted fluid already spoken of, the surface being usually half an inch below the nearest part of the flame, that the gas would immediately diffuse itself through the air, and combustion could not proceed. It is only through the property which the gas possesses of taking an intermediate form and not finally assuming its gaseous condition till it reaches the flame, that the effect of continued combustion is preserved. The daily operations of the gas manufacturer, or manager, are so intimately associated w 7 ith chemistry, as to render a partial knowledge of that science (at least so far as regards c 2 28 ON THE CHEMISTRY OF GAS-LIGHTING. the gases he has to treat with) of the first necessity; it is therefore intended to give a brief outline of the subject. Chemistry is the science which teaches us the composition of bodies, and the laws regulating the combination of the elements of which they are composed. For the purposes of study, it is usually divided into two branches, viz., organic and inorganic chemistry. The first branch relates to every living object, from the largest being to the smallest animalcule ; likewise all vegetable life, from the most stupendous tree, to the minutest trace of vegetation. These, having organs of vitality, are with much propriety called organic bodies. The other class, which con- sists of inanimate objects, which neither live nor die, having no such organs of vitality, are called inorganic bodies. All organic and inorganic bodies, constituting everything accessible to man, consist of, or are composed of, about sixty- four simple substances called elements , which are so named because they cannot, by any known means, be decomposed ; that is, resolved into simpler kinds of matter. These ele- ments combine with each other in certain relative propor- tions, and form substances called compounds. Of the elements, about fifty belong to the class of metals, as iron, gold, copper, lead, &c.; but those which immediately interest the gas manufacturer are few in number, being only five, viz. oxygen, hydrogen, nitrogen, carbon, and sulphur, which are of the greatest importance, on account of their vast abundance, because one or more of these exist in almost every substance or compound in nature, and they all influence the manufacture or distribution of coal gas. To render the combination of the elements and the forma- tion of the compounds intelligible, we may compare the chemistry of our globe to a language having about sixty-four letters, each of which letters represents an element; these .etters, in unison, form the words, or compounds, and the compounds comprise the earth and all that is on its surface. A letter in a language resembles an element in chemistry, inasmuch as neither can be reduced or decomposed into any- thing less than itself. ON THE CHEMISTRY OF GAS-LIGHTING. 20 Letters combine in various manners and ways to form words ; so the elements combine in a similar manner to form compounds. The nature of the word is dependent on the letters com- posing it, and on their disposition ; so in chemistry, the nature of the compound depends on the composition, and disposition of its elements. And to continue the comparison, the five elements named may be compared to the vowels, without which no word can be formed ; so few compounds exist without the presence of one or more of the elements named. The elements which comprise a substance or compound are discovered by employing means to separate them from each other, which process is called decomposition, and is the basis of what is termed analysis. This decomposition is very frequently effected by N the application of heat — thus, the black oxide of manganese (a natural compound, an union of two elements, the one a metal called manganese, and the other oxygen), when submitted to a red heat in a retort, is decomposed, part of the oxygen being separated and expelled as gas, and a lower oxide of manganese is left in the retort. Here it is obvious that the oxygen now existing as gas must have formed part of the solid previously to the compound being exposed to the heat, and if the solid be weighed before and after the process, the loss of weight by the separation of part of the oxygen will be found to be considerable. Again, with limestone, a compound of three elements, carbon, oxygen, and calcium, or lime, some descriptions of which have almost a flinty appearance, when exposed to a great heat, as when destined for building purposes, loses about from 35 to 40 per cent, of its weight, which is driven off as a compound gas, consisting of carbon and oxygen, forming carbonic acid. The residue, deprived of these, is entirely altered in its nature, being no longer the hard rock, but lime, which crumbles to dust on exposure to the atmosphere. Hence, the elements of these gases must pre- viously have existed as a solid, composing part of the lime- stone. The decomposition of coal, by heat, as in the manufacture 30 ON THE CHEMISTRY OF GAS-LIGHTING. of coal gas, is entirely a chemical operation. Coal contains all the five elements named, and the result of the decomposition is, that the greatest portion of the hydrogen and the volatile carbon are expelled as gas ; a portion of the oxygen and hydrogen form water ; the nitrogen, with a portion of hydro- gen, constitutes ammonia; a portion of the sulphur and hydrogen comprise the impurity, sulphuretted hydrogen. Another portion of sulphur unites with carbon, and produces the troublesome impurity called bisulphide of carbon. The tar is a compound of several of these elements ; and the coke left in the retort is fixed carbon, intermixed with earthy substances and a minute portion of sulphur. Water is composed, by weight , of one of hydrogen and eight of oxygen ; by means of voltaic electricity, it may be decomposed into its two component gases, the one being liberated at what is called the positive pole, and the other at the negative pole of the battery. These gases, when collected, are found to be in the exact proportion, by volume , of two of hydrogen to one of oxygen. If we, therefore, take into consideration their respective weight and volume, oxygen is found to be sixteen times heavier than hydrogen. Now, if the gases produced from the decomposition of water are placed in a strong vessel, say a soda-water bottle, so as to fill it, and in the same proportions that they were liberated, on a lighted match being applied to the mouth of the bottle an explosion with a loud report takes place ; the two gases ignite, and at the same moment re-unite, forming water, which bedews the side of the bottle. By the first experiment water is resolved into the two gases of which it is composed ; and by the second, these, again, are converted into the liquid form — striking illustrations of the truth of chemistry. This is but one of the many instances, where a substance can be decomposed and afterwards again caused to assume its former state. From the foregoing illustrations it is manifest that oxygen enters into the composition of solids, as when it comprises part of the oxide of manganese, limestone, &c.; that it exists in liquids such as water ; and that when separated from its compounds it exists only as gas. Most elements can exist ON THE CHEMISTRY OF GAS-LIGHTING. 31 in three different states of aggregation — the solid, the liquid, and the gaseous. The form of solids and liquids is well known, but that of gases, for the general reader, requires some explanation. Gases are permanently elastic fluids — vapour or steam convey to us the idea of the bulk of gas. But this, by a diminution of temperature, condenses and becomes liquid ; whereas gases, under all ordinary circumstances, are perma- nent in their state. Smoke issuing from a chimney or else- where, is a mixture of several gases, combined with vapour and small solid particles of carbon, called soot. Gases are of various kinds, and very dissimilar in their properties ; and, although frequently invisible, the chemist’s art teaches him to distinguish the one from the other with the greatest certainty, so as to render them as palpable to the mind, if not to the ^ye, as the different solids which sur- round him. Each description of gas has some distinguishing characteristic, such as weight, odour, colour, power of ex- tinguishing fire or of supporting its combustion, or the man- ner it acts on particular substances, called tests, signifying testimony. These tests are substances which are known to change in their appearance and nature, in a peculiar and characteristic manner, when exposed to the action of certain gases or liquids. Thus, an impurity in coal gas is called sulphuretted hydro- gen (which, in ordinary language, may be rendered sulphured hydrogen), being a compound of sulphur and hydrogen ; and when this is allowed to act upon a piece of paper, saturated with the acetate, or sugar of lead, the paper immediately becomes blackened, and ultimately assumes a metallic appear- ance, occasioned by the sulphur of the sulphuretted hydrogen entering into combination with the lead which was previously in union with the acetic acid. Thus, the acetate of lead is one of the substances acted upon by the impurity in a perfectly understood manner, and is, therefore, selected as a test for sulphuretted hydrogen. There are, however, several kinds of tests ; amongst them is the method of ascertaining the presence of certain gases by 32 ON THE CHEMISTRY OF GAS-LIGHTING. means of certain absorbents which cause them to become fixed, and to assume a liquid or solid state. A very general test for discovering the presence of acids or alkalies, is litmus paper, which in its natural state is blue, but when treated with the least quantity of a weak vegetable acid, such as vinegar, becomes red ; and this when acted upon by an alkali resumes its former colour. The test generally used to detect the presence of ammonia is turmeric paper, which is of a peculiar yellow colour, but becomes brown when submitted to the action of that compound. With this introduction, we will consider the properties of the five elements named, and afterwards their combination in forming coal gas and its impurities. Oxygen . — This is by far the most abundant element in nature, and in its gaseous state forms more than one-fifth part of the atmosphere by which our earth is surrounded. As a liquid, in union with hydrogen, it constitutes by weight eight-ninths of all water ; as a solid, it is a portion of innumerable organic and inorganic bodies ; and is estimated to form about one -third of the mineral crust of our globe. Oxygen, when free, that is, when uncombined with any other element, exists only as a gas (all attempts to reduce it to a fluid having failed) ; and this occurs either when it is emitted by the leaves of plants, &c., or when by the agency of man it is separated from other elements with which nature has caused it to combine, and form certain compounds or substances. This element is the support of all animal life and combustion, and possesses very peculiar properties ; for instance, a body which burns in air, when it is immersed in oxygen gas burns with vastly increased splendour ; and the wick of a recently extinguished candle, having the least part red-hot, when inserted into a jar of this gas is immediately re-lighted; and a piece of charcoal with the smallest point ignited, when so treated burns with great brilliancy. Oxygen gas is inodorous, colourless, and rather heavier than air ; and it may be termed the aerial food of animal • life, for at each respiration a portion of it, intermixed with nitrogen, is received into the lungs, acts on the blood, and is afterwards ejected as a poisonous compound, carbonic acid gas. ON THE CHEMISTRY OF GAS-LIGHTING. 33 Oxygen, or any other natural element, can only be obtained from a compound which possesses it, and by adopting means to separate the required element from the compound. Thus, chlorate of potash, red oxide of mercury, and black oxide of manganese, in common with many other substances, contain a large quantity of oxygen, which is easily separated as a gas by means of heat. For example, red oxide of mercury is a mixture of oxy- gen and quicksilver, in the form of a red powder ; and if a few grains of this be placed in a test-tube and held over the flame of a lamp or gas-burner, the heat expels the oxygen as a colourless gas, leaving the quicksilver in its fluid state. This is decomposition, and was the means first employed to obtain oxygen by its discoverer. But a more economical manner of obtaining this gas is by taking a quantity of black oxide of manganese (of which one pound will evolve about 1,400 cubic inches of oxygen), placing it in a cast-iron retort, and distilling similarly to the distillation of coal for the production of gas ; the oxygen gas can be collected in a gas-holder, or other vessel, for use when required.* One ounce of chlorate of potash, by careful application of heat, will afford about two gallons of oxygen. Hydrogen . — This element is also very abundant, and does not exist free or uncombined in nature. It is a constituent of all animal and vegetable substances, forming, by weight, one-ninth part of water, and is a portion of most com- bustible bodies. Hydrogen gas is colourless and tasteless, and when quite pure is without odour ; it is inflammable when issuing from an orifice and intermixing with the atmosphere : burning with a faint violet colour, giving great heat, but very little light. This gas is the lightest substance in nature, being a little more than one-fifteenth part of the weight of air. It is an invariable component of coal gas, both in a free state and in combination with carbon, constituting certain hydro-carbons, such as light carburetted hydrogen (or marsh gas), olefiant gas, &c. * As these experiments are attended with danger, the reader should not attempt them without having some instruction on the subject. o 3 34 ON THE CHEMISTRY OF GAS-LIGHTING. Hydrogen, for perfect combustion, requires eight times its weight or half its volume of oxygen, as already demonstrated by experiment, the result of the combustion being water ; and in every case wherever artificial light is obtained by burning oil, tallow, gas, &c., this production of water is con- tinually taking place, arising from the hydrogen intermixed with the material being consumed uniting with the oxygen of the atmosphere. The water is distributed as vapour in the atmosphere wherever produced, unless means be employed to condense and collect it. Whenever gas-lights are burned in a shop-window without proper ventilation, the vapours are condensed by the cold glass, an inconvenience which is familiar to all ; or a bottle of cold water brought into a room where lights are burning is speedily covered with a dew, caused by the condensation of the vapours by the cold water. A simple way to obtain this gas is by passing a slow current of steam through a small iron tube (f or 1-in. gun barrel) loosely filled with iron borings ; the' tube is placed across a suitable furnace, or blacksmith’s forge, and heated to bright redness ; the steam on passing is decomposed into the two elements of water, viz., oxygen and hydrogen — the oxygen combining with the iron, forming the oxide of iron ; while the hydrogen gas being set free, can be collected in a holder. Another convenient method is, by putting a few pieces of zinc into a glass vessel, and pouring on them a mixture of one part of sulphuric acid, and four or five parts of water ; the gas then rises in bubbles. In this experiment the zinc unites with the oxygen of the water, and subsequently with the sulphuric acid, and the hydrogen is liberated. Thus, hydrogen exists in solids forming part of animal and vegetable substances ; in liquids, i.e. as a component of water, and can be obtained in its gaseous state by decom- posing one of its compounds, such as water, &c. Nitrogen . — This element is so called from its being the basis of nitric acid, and nitre, and is sometimes named azote, from its incapability of supporting life. Nitrogen constitutes nearly four-fifths of the air we breathe, and serves to temper the effects of the oxygen, ON THE CHEMISTRY OF GAS-LIGHTING. 35 which, if alone, or even when in moderate excess of the proportion stated, would be too energetic. It is also a com- ponent of all animal tissues, muscles, &c. Nitrogen gas is slightly lighter than air : it has neither colour, taste, nor smell ; it supports neither combustion nor respiration ; and is characterised by its negative properties, rather than by possessing any inherent poisonous qualities, such as are peculiar to carbonic oxide, or carbonic acid. Nitro- gen is of interest to the gas manufacturer on account of its influence on the combustion of gas ; also because it is one of the components of the alkali ammonia which is always generated, during the distillation of coal, in making coal gas. In order to demonstrate the composition of atmospheric air, let us take a cup containing a small piece of phosphorus, which is placed in a dish of water; the phosphorus is then ignited, and the cup covered by a bell-glass, or a glass shade, the mouth of which is immersed in the water. The phos- phorus, in burning, combines with the oxygen of the air enclosed in the glass, producing phosphoric acid, and when all the oxygen is removed by the phosphorus, or has entered into the fresh combination, the phosphorus ceases to burn in the absence of oxygen ; the water in the mean time, by the removal of the volume of the oxygen, ascends in the glass. The gas underneath the bell, after the operation, is nearly pure nitrogen, and the bulk will be found to be diminished about one-fifth ; this decrease of volume being due to the absence of the oxygen which formerly existed, which has entered into the composition of the flakes of phosphoric acid, and become absorbed by the water. Carbon . — This is, likewise, one of the most abundant elements, and is extensively distributed in nature as a consti- tuent of all animal and vegetable bodies. It exists in the mineral kingdom in various forms — very largely in the state of coal. It also enters into the composition of some earthy bodies; for, united with lime, it forms marble, chalk, and limestone. The diamond, although unlike any of the sub- stances named, is pure carbon, and is about three and a half times heavier than water. The carbonaceous incrustation in retorts, the soot produced 36 ON TI1E CHEMISTRY OF GAS-LIGHTING. by the imperfect combustion of oil or gas, lampblack, and charcoal, are all carbon, more or less impure. Under ordinary temperatures, carbon has no affinity for oxygen, nor is carbon affected by heat, unless oxygen, nitro- gen, and a few other substances be present. Thus, the diamond remains unaltered in the hottest furnace if these bodies are excluded ; but if oxygen is present, it will combine with it to form carbonic acid at a comparatively low temperature. The combustion of carbon in air or oxygen, produces light, more or less brilliant, according to the degree of heat to which it is raised. Carbon alone is never found in the gaseous state, but Several gases have the power of combining with it, and con- ferring on it that property ; but as soon as the combinations are destroyed by the abstraction of the other gaseous body, the carbon again becomes solid : a most important property, which requires especial attention in connection with the combustion of gas. Sulphur , — This exists in large quantities in nature, form- ing part of the ores of copper, lead, mercury, silver, and other metals. It also issues from volcanoes, in the form of gases, in great abundance, and in its solid state is well known under the name of brimstone. It exists in coal in the bright metallic laminae which intersect it, these being chiefly a com- pound of sulphur and iron. Coke, even after having been submitted to a very protracted and high heat, still contains a portion of sulphur, giving rise to the noxious odour occasioned by burning it in confined places. A highly volatile com- pound of sulphur and carbon is produced in the distillation of coal by the combination of a certain amount of sulphur, with carbon, viz. the bisulphide of carbon. The peculiar, disagreeable odours of many of the com- pounds of sulphur are familiar to all, and are the most troublesome of all the impurities of coal gas, the economical removal of which has for several years defied the chemist’s skill. COMBINATION OF THE ELEMENTS. 37 COMBINATION OF THE ELEMENTS. Having briefly given a description of the various elements in chemistry which immediately interest the gas manufac- turer, I will now enter on their combinations to form coal gas, its impurities, and the results of its combustion. By a law of nature all elements have, in their most minute particles or atoms, an innate attraction for certain others, with which they combine and form compounds. This by chemists is called affinity, and by this law of affinity oxygen and hydrogen combine and form water — these gases in like manner, by the intervention of the electric spark or fire, unite to compose the same liquid. By affinity, carbon combines with oxygen, producing carbonic oxide and carbonic acid. Sulphur combines with hydrogen, and the result is sul- phuretted hydrogen. Nitrogen combines with hydrogen, and ammonia is produced. And by this affinity all the various compounds or substances in nature are held together. For the sake of brevity and general elucidation, chemists have devised a very simple means of describing compounds, and at the same time to express their constituent and quan- titive parts. For this purpose instead of writing or naming the elements in full, abbreviations are employed, which are frequently the capital initial letter of the element to be expressed ; or when there are two or more with the same initial, then a second small letter is added to make the requi- site distinction. In those under notice the initial only is employed, thus — oxygen is expressed, 0 ; hydrogen, H ; nitrogen, N ; carbon, 0 ; sulphur, S ; and these are called the symbols of their respective elements. Of course all the others have their corresponding symbols. Whenever elements combine with each other it is only in a particular and definite manner, which is called their combining quantities or proportions, and this occurs by weight and by volume, which bear a direct relation to each other. 38 COMBINATION OF THE ELEMENTS! The elements named combine by weight only in the following proportions, or their multiples : — These numbers are called the equivalents of their respec- tive elements. When gases combine it is always by measures, which bear a simple relation to each other in the following propor- tions : — thus, hydrogen combines with oxygen in the pro- portion of two volumes or bulks of the former with one volume or bulk of the latter gas ; hydrogen and sulphur in like proportions ; nitrogen and hydrogen in the proportion of one to three ; &c. The chemical expression, or, as termed, formula, of the composition of water is H 2 0, signifying two atoms or equiva- lents of H (hydrogen), combined with an atom of 0 (oxygen). As already stated, hydrogen constitutes by weight one-ninth part of w T ater, and by volume two -thirds ; whilst oxygen by weight constitutes eight-ninths, and by volume one-third ; giving a simple illustration of the combining proportions by weight and volume. In order to give examples of the combination of the elements to form compounds, and the formula employed : — One equivalent or atom of carbon, combined with an atom of oxygen, form carbonic oxide, expressed by the for- mula 0 0. One atom of carbon with two of oxygen, expressed 0 0 2 , constitutes carbonic acid. One equivalent or atom of nitrogen with three atoms of hydrogen, formula N H 3 , produces ammonia. By these means the various com- pounds of gases are formed and expressed. The means of ascertaining the specific gravity or weight of gas is ascertained in the simplest manner with the balloon made by Mr. WTight, which is treated on in the chapter devoted to experiments on coal gas. Hydrogen Oxygen Carbon Sulphur Nitrogen 1 16 12 32 14 COMPOSITION OF COAL GAS. 39 COMPOSITION OF COAL GAS. Coal gas when purified is composed chiefly of carbon and hydrogen, and consists principally of a definite compound called light carburetted hydrogen, or marsh gas, combined with a variable mixture of vapours or gases consisting of carbon and hydrogen, called heavy hydrocarbons, the most important of which is known as olefiant gas ; carbonic oxide is also one of its constituents. The impurities are sulphu- retted hydrogen, ammonia, nitrogen, carbonic acid, and bisul- phide of carbon. Light carburetted hydrogen , or marsh gas, is a compound of carbon and hydrogen, in the proportion of one atom of the former to four atoms, of the latter, its chemical formula being 0 H 4 . It is this compound which constitutes the inflammable fire-damp of coal mines, where it is generated spontaneously ; it proceeds abundantly from the decompo- sition of vegetable substances, and is one of the products of the distillation of coal. This gas is colourless, nearly inodorous, and does not affect vegetable colours, and, like hydrogen, is permanently gaseous under intense cold or pressure. It is highly com- bustible in oxygen or air, and explosive to a violent degree if mixed with either of these in the due proportion necessary to convert all the hydrogen into water, and the carbon into carbonic acid. In proportion as the oxygen exceeds or falls short of that quantity, so is the explosive power decreased. By weight marsh gas contains 12 parts of carbon and 4 parts of hydrogen, or, 100 parts contain — Carbon . .75 Hydrogen . . 25 Its density is '559 (air being 1000), the weight of 100 cubic inches being 17*41 grains. To obtain this gas, a mixture of 40 parts of crystallised acetate of soda, 40 parts of solid hydrate of potash, and 60 parts of quicklime in powder, is transferred to a flask or retort, and strongly heated, when the gas is disengaged in great abundance. 40 COMPOSITION OF COAL GAS. When marsh gas is burned in the air, if allowed to issue as a large, thick flame, considerable light is obtained ; it is possible, however, to burn it without any appreciable light, by causing it to issue, under great pressure, from very minute orifices ; but this peculiarity of burning, with or without the emission of light, according to the circumstances attending the combustion, exists with all the gaseous com- pounds of carbon and hydrogen. Pure carburetted hydrogen gas may be respired with safety. The unpleasant smell of common coal gas is due to impurities. In its natural forms of marsh gas and fire-damp, it is generally contaminated with nitrogen, and with a small proportion of carbonic acid gas. Grains. A cubic foot of this gas weighs . ... 300 And requires for its combustion 2 cubic feet of oxygen . 1200 1500 The products are 1 cubic foot of carbonic acid, weighing 817 Water . . . 683 1500 Olefiant gas , or oil-making gas, is so named from its forming an oil when combined with chlorine or bromine. It consists of two atoms of carbon united to four atoms of hydrogen, its formula being C 2 H 4 ; hence by weight 100 of olefiant gas contain 85*7 carbon and 14*3 hydrogen. Its density is *981, and the weight of 100 cubic inches 30*57 grains. Olefiant gas containing double as much carbon as the light carburetted hydrogen, burns with much greater bril- liancy, and gives out a very superior light. This gas may be obtained from alcohol, by mixing with it five or six times its weight of sulphuric acid, placing this in a glass retort, and by the gentle application of heat, the gas distils over, which may be afterwards purified from carbonic acid by agitation with solution of caustic potash. Olefiant gas is combustible and explosive under similar circum- stances to light carburetted hydrogen, requiring, however, two volumes more oxygen. COMPOSITION OF COAL GAS. 41 There are other heavy hydrocarbons which enter into the composition of coal gas, having the same nature as olefiant gas, known as propylene, butylene, &c. ; these, with the general constituents of coal gas and its impurities, have been very ably treated on in a lecture delivered by Dr. Letheby, and recently published in the Journal of Gas Lighting , to which the attention of the reader is especially directed. Ole- fiant gas is decomposed by passing it through a tube heated to bright redness ; a deposit of carbon takes place, and the gas becomes converted into light carburetted hydrogen. If the operation be performed with increased heat, the whole of the carbon is deposited, leaving the hydrogen free. This illustrates very forcibly the deterioration of coal gas by the deposit of carbon in the retorts. Hydrocarbons . — Coal gas, according to the description of coal from wdiich it is produced, and the mode of distillation, contains from 3 to 30 per cent., by volume, of vapour or gaseous matter (carbon and hydrogen), to which the general name of hydrocarbons is applied ; and the illuminating power of gas is in direct proportion to the quantity of hydro- carbon in combination therewith. If chlorine, bromine, or dry sulphuric acid, be added to a sample of coal gas, or if the gas be subjected to excessive pressure or extreme cold, the heavy hydrocarbons are depo- sited in the form of oil, the volume of the gas being sensibly diminished in proportion to the quantity condensed. Dr. Fyfe has for a long period devoted his talents in order to arrive at a positive law, so as to be enabled to estimate the illuminating power of gas by the quantity condensed by chlorine ; and more recently Mr. Lewis Thompson has employed bromine for the same purpose. But by these means the volume only of the heavy hydrocarbons is ascer- tained ; and as a knowledge of their density is essential, and is not obtained by this process, therefore this mode of testing can only give comparative, but not absolute, results. Messrs. Faraday and Coombe have also attempted to define the illuminating power of gas by condensing the hydro- carbon under great pressure, the density of which being ascertained, the value of the gas was estimated accordingly ; 42 COMPOSITION OF COAL GAS but the delicate manipulation would prevent the general application of this operation. Formerly much importance was attached to the specific gravity of gas as an indication of its value ; and it is still the opinion of some eminent chemists, that when gas is free from impurities, this mode of ascertaining its quality or illuminating power is worthy of the greatest reliance. Dr. Henry was the first to indicate the evaluation of gas for illumination, by estimating the quantity of carbon con- tained in the condensable portions thereof. Carbonic oxide , or the protoxide of carbon, consists of one atom of carbon and one of oxygen, its atomic weight being, carbon 12 + oxygen 16 = 28, its formula being 0 O. Hence it contains by weight of 43 per cent, of carbon, and 57 per cent, of oxygen. Carbonic oxide is prepared in the labora- tory by passing carbonic acid over red-hot charcoal or metallic iron, by which half its oxygen is removed, and becomes converted into carbonic oxide. This change also explains the mode of its formation in the process of distilling coal for gas-making purposes. Carbonic oxide contains half its volume of oxygen, is a combustible gas, and burns with a beautiful blue flame, the product of combustion being car- bonic acid. This gas is extremely poisonous, even worse than carbonic acid, is colourless, and possesses very little odour. Its specific gravity is *968, the weight of 100 cubic inches being 30 grains. This compound exists more or less in coal gas, but seldom exceeding 10 per cent, by volume, and generally much less. It requires one volume of oxygen for combustion, being then converted into carbonic acid. Carbonic oxide contributes to the heat of the flame, but only indirectly to the light. It is not considered an impurity in coal gas ; although the fact of it giving off less heat than hydrogen, whilst it absorbs the same quantity of oxygen, and produces one volume of carbonic acid (a substance always very objectionable), undoubtedly renders it an impurity. Coal gas often contains a trace of free nitrogen and oxygen ; but these, by the best analysis, are generally in about the proportion required for atmospheric air. This is therefore IMPURITIES OF COAL GAS. 43 probably due to the admission of air either when changing the purifiers or by undue exhaustion. IMPURITIES OF COAL GAS. Sulphuretted hydrogen (hydro-sulphuric acid). — This com- pound consists by weignt of one part of hydrogen gas and sixteen parts of sulphur vapour, its atomic weight being H 2 + S 32 = 34, and expressed by the chemical formula H 2 S. By measure it contains two volumes of hydrogen, combined with one volume of the vapour of sulphur, the two being condensed into two volumes. The specific gravity of this impurity is greater than common air, being 1T78. The weight of 100 cubic inches is 36*51 grains. Sulphuretted hydrogen may be produced for experiments by putting some iron pyrites (a compound of sulphur and iron) and dilute sulphuric acid into a glass retort ; heat ■being applied, gas is disengaged, which is caused to pass through water, when pure sulphuretted hydrogen is obtained. This is a colourless gas, possessing acid properties, reddening litmus paper, and has a most offensive odour, similar to putrid eggs, which indeed contain it ; it is very poisonous, and if breathed into the lungs is injurious to life, occasioning suffocating vapours like those arising from the burning of brimstone ; it tarnishes metals, changes the colour of most kinds of paint and furniture hangings ; and when coal gas possessing this impurity is burned, the sulphur combines with the oxygen of the atmosphere, forming sulphurous acid. Therefore, with all the various evils enumerated, it is of the utmost importance that gas should be entirely free from it, and any establishment neglecting this does a serious injury to its business, as well as to the comforts of gas con- sumers. Sulphuretted hydrogen is removed from coal gas by means of lime in solution, the “ milk ” or “ cream ” of lime, as in the wet-lime purifiers ; or by means of the hydrate of lime (lime slackened and moistened), as in the dry -lime purifiers; or by the oxide of iron, muriate of manganese, &c. The incon- 44 IMPURITIES OF COAL GAS. venience occasioned by the lime purification, in consequence of the odour emanating therefrom, also the difficulty of disposing of the waste material, has of late years caused the use of oxide of iron to become very general ; and per- haps the economy attending it may have been an induce- ment. When dry lime is used it is necessary to have the lime greatly in excess, as it ceases to absorb sulphuretted hydrogen long before it becomes saturated. The absorbing action of the lime is said to be much increased by adding hydrous sulphate of soda : this has been proposed by Professor Graham ( Phil . Mag., June, 1841), who states that on the addition of the sulphate of soda the action Continues till two equivalents of sulphuretted hydrogen have been absorbed by one equivalent of lime. The lime is entirely converted into gypsum, or sulphate of lime, and the whole of the soda becomes bi-hydro-sulphuret of soda, which might easily be washed out of the lime : this bi-hydro-sulphuret may be readily again converted into soda by roasting it, and thus might be used over and over again to mix with the lime in the purifiers. Nearly all coal contains more or less sulphur — usually in combination with iron, and sometimes with lime in the form of sulphuret of iron (iron pyrites) — or the sulphuret of lime. During the process of distillation these sulphurets are decomposed, part of the sulphur being driven off in vapour or gas, and combining with hydrogen, the product being sulphuretted hydrogen. Previously to purification about 8 feet of sulphuretted hydrogen exist in every 1,000 feet of gas obtained from Newcastle coal. The presence of sulphuretted hydrogen in gas is ascer- tained by moistening a piece of unsized white paper with a solution of the acetate of lead, and allowing a stream of gas to impinge upon it, when, if present, the paper is immediately darkened, or blackened, in proportion to the quantity of impurity in the gas. Carbonic acid is another well-known oxide of carbon, con- taining two equivalents of oxygen to one of carbon. Its chemical composition is denoted by the formula 0 0 2 ; its atomic weight being C 12 + 0 2 32 = 44, and proportions IMPURITIES OE COAL GAS. 45 being 72*73 per cent, of oxygen, and 27*27 per cent, of carbon. This gas is readily procured by decomposing any of the earthy carbonates, as chalk or limestone, with a stronger acid, which, forming a new 7 combination with the earthy base, sets free the carbonic acid of the carbonate. Carbonic acid gas is without colour, and though possessing an agreeable pungent taste and odour, cannot be breathed for a moment with impunity, as it rapidly produces the effect of suffocation, insensibility, and death. This gas is familiar to us as the fatal choke-damp of mines, as the fixed air in champagne, . bottled beer, soda water, &c., and as the heavy gas which floats over the large vats in breweries w 7 hile the beer is undergoing the process of fermentation. It is also produced wdierever there is combustion, and should always be carried off by proper ventilation. The specific gravity of this gas is 1*524, the w 7 eight of 100 cubic inches being 47*26 grains. Not only is this gas entirely uninflammable, but it instantly extinguishes flame even wdien diluted with three times its volume of air. The carbonic acid gas, owing to its great affinity for lime, is readily separated either by being exposed to the absorption of hydrate of lime, or that of lime diffused through water, as in the w'et-lime purifiers. It is extremely injurious in gas intended for illu- minating purposes, as it tends directly to destroy combustion. At the same time the great density of carbonic acid gas would give to any compound containing it a false appearance of value by exhibiting a high specific gravity, and hence its presence may reasonably be expected in gas with feeble illu- minating pow 7 er and considerable density. Grains. According to Dr. Henry, a cubic foot of carbonic oxide weighs 520 And requires for its combustion half a cubic foot of oxygen, weighing . 300 The product being carbonic acid 820 The presence of this impurity in coal gas is detected by a solution of lime in w 7 ater, which must be filtered till quite clear ; a portion of which is put into a large test-tube, or wine-glass, and by means of a flexible tube the gas under examination is allowed to bubble through it for about one oi 46 IMPURITIES OF COAL GAS. two minutes ; if the water becomes cloudy or milky, it is a proof of the presence of carbonic acid. The rationale of this test is that lime is soluble in water, but the carbonate of lime or chalk produced by the action of the carbonic acid and lime is insoluble, and the cloudy appear- ance indicates the production of the carbonate of lime. Ammonia is produced during the distillation of coal by the union of hydrogen with the azote or nitrogen which is con- tained in coal, as in all other organic substances. In forming ammonia, one atom of nitrogen unites with three atoms of hydrogen, the chemical formula being NH 3 = 17*06, and the proportions by weight being 82*41 per cent, of nitrogen, and 17*59 per cent, of hydrogen. The density of ammonia is *589, the weight of 100 cubic inches being 18*26 grains. Two volumes of ammonia contain by measure three volumes of hydrogen and one of nitrogen, the whole being condensed to the extent of one-half. Ammonia is produced abundantly in nature from the decomposition of animal and vegetable substances : the gas is colourless and very pungent, acting strongly on the mucous membrane of the nose, eyes, and throat. A great part of the ammonia is separated from gas by the condensing apparatus, combined with water, and called ammoniacal liquor. The ammoniacal liquor is the principal source from which ammonia is procured ; and numerous patents have been taken out for improvements in the mode of treating this liquor, in order to effect the production of carbonates, muriates, and other salts of ammonia. The value of ammoniacal liquor as a manure for top-dressing grass lands, and in other applications, has been much insisted on of late years, When diluted with four times its bulk of water and applied by means of cylinder carts or other contrivances for distributing liquid manure, the effect is said to be highly beneficial. Although the ammoniacal liquor is at present the only source of ammonia in ordinary gas-works, there are other parts of the purifying process in which it may be separated, but not in sufficient quantities to be worth working. Where the breeze condenser is used, certain volatile oils together with ammonia are arrested ; also where dry lime is used for IMPURITIES OF COAL GAS. 47 purification, some volatile salts of ammonia are absorbed, and certain carbonates and sulphates of ammonia are decomposed, and the ammonia is set free. Ammonia has strong alkaline properties, and its presence is detected by moistened turmeric paper, which, when exposed to the action of this gas, changes from its yellow colour to a deep red or brown. It is also detected by reddened litmus paper, which changes to blue. But the most minute quantity that may be present is ascertained by filling a glass flask with the gas to be examined, and inserting into it a glass rod previously dipped into muriatic acid, when, if present, a white cloud is formed in the flask — this being the muriate of ammonia. Formerly the ammoniacal liquor of gas-works possessed but little value on account of the large quantity of water intermixed with it, and in some cases where pure water was used for the scrubbers, the greater portion of ammonia was entirely lost ; but at the present day the ammoniacal liquor from the condensation is made the medium of purification by being pumped continuously through the scrubbers, until, by the absorption of ammonia, it attains the desired specific gravity, so to render it a valuable commercial commodity Sometimes acidulated water is employed in the scrubbers to remove the ammonia. Ammonia in small quantities is not injurious to health, but it acts on some of the metals, as brass and copper of the fittings and meters, and is so far an impurity. Against this, it converts any sulphuric acid formed during combustion into sulphate of ammonia ; therefore in this respect it is beneficial, and must be considered so until means are devised of freeing gas from all its sulphur compounds. A very small quantity intermixed with the gas is also considered essential, to prevent the deposition of naphthaline in the pipes. Ammonia is a gaseous body, and that which is usually called so in the liquid state is ammoniacal gas intermixed with water, which takes up or absorbs about 700 times its own volume of that gas. Bisulphide of carbon . — This impurity in coal gas until recently attracted very little attention, but it is now found to 48 IMPURITIES OF COAL GAS be most objectionable on account of its very disagreeable odour, its injurious effects, and the difficulty in removing it. This gas is a compound of one equivalent of carbon and two equivalents of sulphur, or by weight carbon 6, sulphur 32 = 38 ; its formula is C S 2 . It forms whenever sulphur comes into contact with red-hot charcoal or coke. No practical method has yet been generally adopted for avoiding this obnoxious compound in coal gas ; the sub- stances which have hitherto been employed for the purpose, have at the same time deprived the gas of a portion of its heavy hydrocarbons, and in consequence its illuminating power has been much deteriorated. But there is reason to believe that Mr. Leigh, chemist of the Manchester Gas Com- pany, after some years’ labour, has succeeded in attaining the desired object. A means of preventing to a great extent the formation of this substance is by distilling coal at a moderate heat, and not allowing the charge to be quite exhausted. A few words of explanation will make this palpable. Whenever coke is burned in a confined place, the odour of sulphur is very manifest, and is one of the great objections against the more general usage of this fuel for domestic purposes; proving that after the more volatile gases are disengaged, sulphur must be in combination with the coke or carbon in the retort, and the formation of the bisulphide of carbon is only a natural result. The means of detecting the presence of this impurity is by passing the gas through a solution of potash and alcohol — when, if present, the liquid, after standing in a cool situation, deposes yellow needle-shaped crystals. The most delicate test known to chemists at present consists in an ethereal solution of Triethylphosphine, discovered some years ago by Dr. Hofmann, which precipitates the merest trace of C S 2 in the form of beautiful red needles. Apparatus hereafter explained is also very generally employed in gas-works for the purpose of indicating the presence of the compounds of sulphur. Bisulphide of carbon may be produced by heating to red- ness, in a close porcelain vessel, some iron pyrites, with one- fifth of its weight of well-burned and dry charcoal. It may COAL USED IN GAS MAKING. 49 be condensed as a colourless liquid, having an acid taste and very offensive odour, which vaporises with great facility, is a remarkable solvent for india-rubber, and boils at 116° Falir. Cyanogen . — The property of nitrogen to unite with carbon and form cyanogen has been much studied. Cyanogen is an inflammable gas, burning with a beautiful purple or peach- blossom coloured flame, generating carbonic acid, and setting nitrogen free. It contains one equivalent of carbon and one of nitrogen, its atomic weight being 26, ' and the formula C N. Cyanogen exists in considerable quantities in the ammo- niacal liquor ; and the separation of the cyanides for the purpose of forming cyanide of potassium, prussiate of potash, Prussian blue, and other compounds, engaged at one period the serious attention of scientific men, but did not realise their expectations. This s compound is not generally classed amongst the impurities of coal gas, but as some chemists of ability have decided it to be an impurity, for that reason it is mentioned here. CHAPTER III. COAL USED IN GAS MAKING. Although there are many substances, such as wood, tallow, oil, resin, &c., from which gas for illumination can be obtained, but as these, on account of their increased cost, are very rarely used, it will answer all the purposes of the present treatise by confining myself simply to coal as the means of obtaining gas. The origin of this mineral is involved in some doubt, but the theory generally admitted by geologists is, that its forma- tion was caused by the deposit of vegetable matter, which in the course of ages became converted into coal. Some eminent geologists suppose coal beds to have been originally a kind of peat bog, or immense accumulations of masses of D 50 COAL USED IN GAS MAKING. vegetable remains, and that subsequently the tracts of country where they existed, by some extensive convulsions of the earth, subsided below their former level, and were covered by various deposits. Others suppose that the trees of pri- meval forests were carried away by floods and rivers, and deposited in immense lakes, where afterwards they were covered by mud, sand, argile, and such like substances, so constituting the covering strata. It is further conjectured that the vegetable remains, whether of 'trees, peat, moss, &c., being thus buried, became after many ages converted into coal, and the deposits were converted into rock, shale, schist, marl, &c., which now intersect and cover the various strata of coal. This assumption is formed from the fact that in all coal there are traces of vegetation, as ferns, and even the trunks of trees ; these are so positive in their form and appearance, often with the bark attached, as to leave no doubt of their origin. This is particularly the case with the Boghead Cannel, wherein the trunks and branches of trees are often found, the wood having the nature of that coal, and the bark resembling the caking coal. There are various other theories which have their sup- porters, and perhaps one of the most feasible is the supposi- tion that coal was formerly a deposit of carbonaceous liquid similar to petroleum, and that by crystallisation this liquid became coal, such as we find it. Those of this opinion argue that the presence of trees and vegetation might have been accidental, or probably by the design of Providence, in order to assist in the crystallisation of the mass. The use of coal is comparatively of modern date, for the first colliery was opened in the high grounds in the neigh- bourhood of ISfewcastle-on-Tyne in the year 1238. About 1306 coal was employed in London by brewers, dyers, and other branches of industry which required large fires ; but the smoke produced from it became so offensive to the resi- dent nobility and gentry, that they remonstrated against its use, and, in consequence, a Royal proclamation was issued, forbidding in London the use of coal as fuel. Some fow years afterwards, wood fuel becoming scarce, the nopu- COAL USED IN GAS MAKING. 51 lation and trade of the city increasing, prejudice gave way to utility, and the force of the proclamation diminished. The use of coal became afterwards very general, but the extortion and abuse of the dealers therein was so excessive, that by Act of Common Council of the City of London, in 1665, each of the city trades’ companies w T as ordered to lay up large stores of coal in summer, which in winter was to be vended to the poor at as low a price as possible, so as not to sustain loss. The first patent in conjunction with coal was granted in 1589, for the purpose of smelting iron therewith. Patents were subsequently obtained at various periods, for obtaining oil, pitch, tar, and making charcoal (coke) from coal. In 1781 a patent was granted to the Earl of Dundonald, for “ a method of extracting or making tar, pitch, essential oils, volatile alkali, mineral acids, salts, and cinders from pit coals.” By this it will be observed, that although the patentee was well acquainted with most of the residues, or results of the residues of the distillation of coal, yet the most valuable constituent, the gas, was entirely lost sight of. A few years after this (1791) a patent was obtained for using an ex- plosive mixture of inflammable air (gas) combined with atmospheric air, to produce motive power — an invention only at the present day being carried practically into operation. Dr. Thomson divides pit coal into three species : brown coal, black coal, and glance coal. The brown coal is a kind of lignite or imperfect coal found at Bovey Tracy in Devon- shire, also in several parts of Ireland, France, Germany, Iceland, &c. It contains a large quantity of bitumen, pro- ducing volatile carburets when distilled : the texture is fibrous, with evident marks of vegetable origin : it burns with a bright flame, yielding a peculiar bituminous odour, but does not occur in sufficient quantity to render it of much importance in the manufacture of gas. There are other classes of lignite which exist in many parts of the world, called bituminous wood, earthy lignite, and common lignite. Common lignite is of interest to the gas manufacturer, on account of its strong resemblance to coal, for which, by an inexperienced eye, it might readily D 2 COAL USED IN GAS MAKING. 53 be mistaken ; when distilled it gives off an abundance of water, with a small yield of gas of low illuminating power, possessing a most offensive sulphurous odour, which lime purification does not remove. This material contains very little tar, and the residue left in the retorts is simply breeze in cubes. It is therefore useless for the manufacture of gas, and only serviceable for burning lime, bricks, and other out-door purposes. The varieties of black coal are for the most part valu- able for the purposes of the manufacture of gas. They are divided by Dr. Thomson into four sub-species, — namely, caking coal, splint coal, cherry coal, and cannel or parrot coal. Caking coal, to which variety belong most of the North- umberland and Durham coals, is so named from its melting, by reason of which the separate particles become united to- gether into one pasty mass or cake, which, when used in a common fire-place, requires to be frequently broken up to allow currents of air to penetrate and promote its combustion. This coal is soft and easily broken, is very inflammable, and burns with a lively flame, giving out more heat in an open fire-place than most of the other kinds. Splint coal, so called from its splintery fracture, is broken with more difficulty than the caking coal, and requires a higher temperature to light it. This is the best description for making coke, and when used in furnaces gives out the greatest amount of heat. To this variety belongs the greater part of the coal used in South Wales for smelting the ores of iron and copper. It is probably the best coal in England for making coke for locomotive engines, and from the experi- ments of Sir Henry de la Beche and Dr. Lyon Playfair, is the coal which appears to be the best adapted for steam boilers in the Navy. Cherry coal is about the same hardness as- caking coal, and is easily broken ; it is also easily lighted, and burns with a bright flame. It burns out quickly, not caking at all, but leaving fully 10 per cent, of ash, while the best Newcastle caking coal leaves only per cent. Cannel coal is harder and more compact than any of the other varieties, and is frequently cut into ornaments, which COAL USED IN GAS MAKING. 53 are not inferior in lustre to jet : it is very easily kindled, burns with a bright flame, and does not soil the bars of a grate. Cannel coal is extensively obtained in Scotland, and is also procured from Lancashire, from whence it is brought to the London market, both for use in gas-works, and some- times, though rarely, for domestic consumption, its cleanliness and cheerful crackling mode of burning being its chief recom- mendation. Cannel coal is largely exported for the purpose of manufacturing gas ; the greatly increased light obtained therefrom renders it a very desirable commodity, particularly when the expenses of transport are great. Glance coal or anthracite consists almost entirely of carbon, and contains only a very small proportion of volatile con- stituents. Although extremely valuable as a heat-giving coal, it is almost worthless in the manufacture of gas. It exists in great abundance in the western part of the South Wales coal field, in Kilkenny, in Pennsylvania, and other parts of the world. All coals are composed nearly of the same ingredients, which, however, vary considerably in their respective quan- tities, to illustrate which a table of the analysis of a few classes is subjoined : — Locality, or Name of Coal. Specific Gravity. Car- bon. Hyd- rogen. Nitro- gen. Sul- phur. Oxy- gen. Ash. Coke. ( Thomas’s Merthyr . 1*30 90-12 4-33 1-00 •85 2- 02 1-68 | 86-53 o i Nixon's Merthyr . . 1*31 90-27 4-12 0-63 1-20 2-53 1-25 79 11 ^ Hill’sPlymouth works 1-35 88-49 4-00 0-46 0-84 3-82 2-39 | 82-25 0 /'Newcastle Hartley . 1-29 81-81 5-50 1-28 1-69 ' 2-58 7-14 64-61 | § i West Hartley Main . tO 1-26 81-85 5-29 1-69 1-13 7-53 2 51 59-20 ^ V Hasting’s Hartley . 1-25 82-24 5-42 1-61 1*35 6-44 2-94 ! 35-60 The carbon in the composition of coal may either be fixed or volatile ; by fixed carbon is understood that which does not volatise when undergoing ordinary distillation, but re- mains in the retort as coke. The volatile carbon is that which passes off as gas, hydrocarbons, tar, &c. The foregoing table demonstrates this difference very 54 COAL USED IN GAS MAKING. forcibly, for in the Welsh coal upwards of 90 per cent, remain fixed as coke, and as a consequence, this class, although admirably adapted for steam purposes, is useless for the manufacture of gas. According to the same table, the Hasting’s Hartley yields about 57 per cent, of volatile carbon, which renders it a good gas-producing agent. But it must be observed that the last mentioned material would, on account of its volatility, be ill adapted for steam purposes, as without the greatest care a large portion of it would pass off as smoke. The following table, by Mr. Lewis Thompson, and extracted from the “ Journal of Gas Lighting,” gives the per-centage of volatile matter in various coals : — Per-centage of volatile matter. Boghead 684 Old Wemyss 52*5 Lesmahago 49'6 Arniston 45*5 Wigan 37-0 Newcastle Cannel 36 8 Caking Coals. Heathern (Staffordshire) 429 Stavely (Derbyshire) 40'9 Silkstone (South Yorkshire) 343 Newcastle Gas Coals 27*8 to 31 '25 Coals are obtained very extensively in Belgium, France, and other parts of the Continent, likewise in America and Australia, and probably they exist in nearly every country in the world, and even in many places beneath the depths of the ocean. For the combined purposes of producing good gas and coke of excellent quality, possibly no mineral exists equal to the caking coals of Newcastle-on-Tyne ; there is, however, considerable variation in their respective natures ; some classes having the superiority for the production of gas, either in quantity or quality, while others give superior coke, and gas of diminished value. During the process of distillation this coal melts, forming itself into a doughy consistency, and expanding considerably ; but gradually, as the gas is expelled, it assumes a brittle COAL USED IN GAS MAKING. 55 homogeneous nature, and lias to be broken in order to extract it from the retort. The average yield of gas from a ton of Newcastle coal is 9,200 cubic feet, of a quality equal to about twelve candles, that is, an argand burner with fifteen holes, consuming five feet per hour, gives with this gas, a light equal to twelve sperm candles, each consuming 120 grains per hour ; or, five feet of gas is equal to 1,440 grains of sperm. With the production stated the quality is seldom superior to this, but is often much inferior. When retorts are heated to a moderate degree, the volume of gas produced is less than that mentioned, but its quality is improved. A ton of caking coal yields, on the average, 13 J- cwts. of coke. When the coal is distilled at a high temperature, the coke is hard and brittle ; when distilled at a low temperature, it is soft and friable. If caking coal be exposed to the direct action of the atmo- sphere, alike to sun and rain, its value as a gas and coke producing agent is diminished in a most remarkable manner, and the results of many observations justify the writer in asserting that coal, when extracted from the mine, and so exposed for three months, becomes deteriorated in value to the extent of about 10 per cent. Of course the subsequent deterioration is in a very reduced proportion ; but under the most favourable circumstances this class of coal diminishes in value by prolonged storage. Caking coal is generally very small, and when wetted, by accident or otherwise, and stored away in that state, has a great tendency to ignite spontaneously, which circumstance has frequently occurred. Another inconvenience with wet coal is, that when the retorts are charged, the water inter- mixed therewith is rapidly converted into steam, and carries off a large portion of the heat from the retorts, so facilitating the production of an excess of tar and a diminished quantity of gas ; and, on the authority of a late engineer of eminence, the distillation of small wet coals invariably produces naptha- line. These are sufficient reasons to cause every precaution to be employed to guard against such contingency. A very curious phenomenon occurs when coals are piled 56 COAL USED IN GAS MAKING. away and subjected to the action of the weather. In the course of time the iron pyrites become decomposed, and the sulphur distributes itself throughout the heap in regular strata at some distance from each other, the inclination or “dip” being about 30° to the horizon, and the strata running parallel. When the pile is seen in section it presents a very remarkable appearance. The cause of this spontaneous stratification must be left to our philosophers and geologists to define. For the purpose of producing very superior, or, as techni- cally termed, “ rich ” gas, the cannel coal obtained in Scotland and the North of England surpasses all other. There is, how- ever, considerable variation between the numerous classes ; but that called “Boghead” is the most extraordinary, a ton of this coal produces 15,000 feet of gas of a quality equal to thirty-six candles, it possesses no ammonia, and very little sulphur ; but the coke resulting from it is useless, except, perhaps, as a deodorising agent, for which purpose Mr. Lewis Thompson recommended it. The gas from Boghead is never commercially used alone, but it is often intermixed, like that from the other cannels hereafter mentioned, with “poor” gases from caking coal, in order to bring their illuminating power to the required standard. For this object the Boghead must be distilled in separate retorts, otherwise its residue would deteriorate the value of the coke produced from the other coal. The coke from nearly every description of cannel retains the form and size of the coal previously to distillation. In its nature it is compact, and resembles charcoal, for which it is often substituted abroad. This coke is sometimes used as fuel for the furnaces ; but very often an inferior description of coal is employed for the purpose, and the coke is sold. There is a description of Wigan cannel, also Bamsay’s cannel, which gives a coke very similar to the caking coal, enabling it to be used as fuel for the furnaces, and it is generally a more market- able commodity than the coke from other cannels. The gas derived from most cannel coal is suitable for en- riching the “ poorer” gases, and for the purpose, as a rule, the best quality is generally the cheapest. Boghead, in consequence of its extensive usage for extracting petroleum oil, has attained COAL USED IN GAS MAKING. 57 a very liigli price, and at present cannot be employed in many places with advantage ; but wherever freights are high it can be recommended. The other classes of cannel, as Leshmahago, to produce the same result, require a larger per-centage than Boghead. For instance, if we suppose the standard of illuminating power of gas required to be increased from twelve candle to fourteen candle gas, the additional illuminating power would be obtained from an admixture of about If per cent, of Boghead coal, whereas it would require nearly 3 per cent, of Lesmahago, and, of course, a consider- ably greater increase of the other inferior cannels. The following tables on experiments of the quantities of gas derived from various coals, together with their specific gravity and the weight of gas in pounds, must be interesting to all connected with gas-lighting : — Experiments on the Quantities of Gas derived from Coal. Description of coal. Cubic feet of gas per ton of coal. Specific gravity of the gas. Weight of gas in lbs. avoir- dupois per ton of coal. Authority. NEWCASTLE COALS. English Caking Coal . 8,000 •420 257 Dr. Fyfe. Newcastle Coal . 11,648 *475 423 Mr. Joseph Hedley. Pelaw, Newcastle . . 11,424 *444 389 Ditto. Pelton, ditto . . . 11,424 •437 382 Ditto. Blenkinsopp, Carlisle . 11,200 *521 447 Ditto. Newcastle .... 8,500 •412 268 London, 1837. f Quantity made in Wall’s End, Newcastle 12,000 •490 450 | the revolving web retort ; authority. l Mr. Clegg. Pelton 11,000 •430 363 > Leverson 10,800 •425 353 Washington . , . . 10,000 *430 330 Pelaw 11,000 •420 355 Mr. Lewis Thomp- New Pelton .... 10,500 •415 335 son, author of the Dean’s Primrose 10,500 •430 347 ► “ Chemistry of Garesfield .... 10,500 *398 321 Gas-Lighting,” in Gosforth 10,000 •402 308 the “ Journal of West Hartley . . . 10,500 •420 339 Gas-lighting.” Hasting’s Hartley . . 10,300 •421 333 ' Blenkinsopp .... 9,700 •450 335 ) D 3 58 COAL USED IN GAS MAKING. On the Quantities of Gas derived from Coal — continued. 1 Weight Cubic feet of Specific of gas in lbs. Description of coal. gas per gravity of avoir- Authority. ton of the gas. dupois ' coal. per ton of coal. NEWCASTLE COALS — continued . Berwick & Craister’s ) Wall’s End . . . j 12,507 •470 449 Mr. Clegg. Pelaw Main .... 12,400 •420 399 Ditto. Russell’s Wall’s End . 12,000 *418 384 Ditto. Ellison’s Main . . . 11,200 •416 357 Ditto. Felling Main . . . Pearith’s Wall’s End . 11,200 *410 351 Ditto. 11,147 *410 350 Ditto. Dean’s Primrose . . 11,120 *410 349 Ditto. Benton Main . . . 10,987 •400 337 Ditto. Eden Main . . . . 1 0,400 •400 318 Ditto. Heaton Main . . . 10,400 •410 326 Ditto. Pelton 11,000 •430 Mr. F. J. Evans. Leverson 10,800 •425 Ditto. Pelaw 11,000 *420 Ditto. Garesfield .... 10,500 *398 Ditto. Gosforth 10,000 •402 Ditto. Dean’s Primrose . . 10,500 •430 Ditto. PARROT OR CANNEL COALS. ( Mr. J. Evans, at Boghead Cannel . . 15,000 752 866 I Westminster Sta- | tion of Chartered 1 Gas Company.* Lesmahago, No. 1 . . 13,500 •642 666 Ditto. Ditto No. 2 . . 13,200 *618 627 Ditto. Capeldrae Cannel . . 14,400 •577 638 Ditto. Arniston ditto . . 12,600 •626 606 Ditto. Ramsay Cannel . . . 10,300 •548 433 Ditto. Wemyss ditto . . . 14,300 •580 637 Ditto. Kirkness ditto . . . 12,800 •562 552 Ditto. Knightswood ditto . . 13,200 •550 558 Ditto. Wigan (Ince Hall) ditto 11,400 •528 461 Ditto. Wemyss Cannel . . 10,976 •670 563 Mr. Wright. Ditto ditto . . . 10,192 •691 538 Ditto. Wigan Cannel . . . Knightswood Cannel . Lesmahago Cannel ) 9,408 9,720 11,681 •478 *590 •540 344 439 483 Ditto. Ditto. Ditto. 1st experiment . ( Ditto 2nd experiment 9,878 •650 492 Ditto. * Each of the results given by Mr. Evans is the mean of three experiments. COAL USED IN GAS MAKING 59 On the Quantities of Gas derived from Coal — continued . Description of coal. Cubic feet of Specific Weight of gas in lbs. gas per f. ravity of avoir- ton of the gas. dupois coal. per ton of coai. Authority. PARROT OR CANNEL coals — continued. Ramsay’s Newcastle ) Cannel . . . . j Lesmahago Cannel . . Welsh Cannel . . . Wigan Cannel . . . 9,016 11,812 11,424 11,200 •604 •737 *737 *606 Ditto ditto 9,500 •580 Lochgelly Parrot 9,123 •567 Ramsay’s Cannel 9,333 •598 Ditto ditto . . Wigan Cannel . . Scottish Parrot . . Ramsay’s Newcastle Cannel . . . . Yorkshire Parrot Wigan Cannel . . Ditto ditto . . Scotch ditto . . Ditto ditto . . . 9,667 . 9,500 . 9,500 | 9,746 . 11,500 . 14,453 . 14,267 . 14,000 . 13,813 •731 f -460 \ to [•520 •640 f -654 \ to [ *580 •640 *610 •580 •500 417 638 645 520 422 396 427 541 357 Mr. Wright. Mr. Joseph Hedley. Ditto. Ditto. { Liverpool New Gas and Coke Com- pany. Dr. Fyfe. { J. Z. Kay, Manager of Dundee Gas- Works. f Dr. Lessen, Dr. •j Miller, and Mr. [ G. H. Palmer. Dr. Fyfe. 466 Ditto. 423 Ditto. 708 664 622 529 Dr. Fyfe. Mr. Clegg. Ditto. Ditto. Ditto. DERBYSHIRE, WELSH, STAFFORDSHIRE, AND OTHER KINDS OF COAL. Derbyshire Deep Main Brymbo 2-yard Coal Powell Coal, 2 cwt. charges every 5 hours Powell Coal, cwt. charges every 5 hours 9,400 8,880 10,165 8,250 •424 •463 •459 •470 308 Mr. Wright. 315 Ditto. 357 Ditto. 296 Ditto. 60 COAL USED IN GAS MAKING. On the Quantities of Gas derived from Coal — continued . Weight 1 Cubic feet of Specific of gas in lbs. Description of coal. gas per ton of gravity of the gas. avoir- dupois Authority. coal. per ton of coal. DERBYSHIRE, WELSH, STAFFORDS HIRE, AND OTHER KINDS OF coal — continued . Bickerstaff, Liverpool 11,424 •475 415 Mr. Hedley. Neath, South Wales . 11,200 •468 401 Ditto. Birmingham Gas 1 f Birmingham Gas Company : Lump Coal from West Bromwich . . . 6,500 *453 226 -j Company. Parlia- [ mentary return. •455 227 f Birmingham and West Bromwich . 6,500 [ Staffordshire. Do. Macclesfield . . . 6,720 Stockport . . . Oldham Watergate 7,800 •539 322 Parliamentary return and Wigan Cannel mixed . . . . ^ 1 9,500 •534 388 Manchester. Do. Ormskirk or Wigan ) Slack \ 8,200 •462 290 f Liverpool, OldCom- | pany. Do. Low Moor mixed with j two kinds of Slack j i 8,000 •420 257 Bradford. Do. •530 f Leeds Company. Leeds Coal . . . • 6,500 263 \ Parliamentary re- l turn. Cannel .and common ' Coal mixed . . . , 1 8,000 •466 285 f Sheffield Company, j Parliamentary re- 1 turn. Derbyshire Soft Coal . 7,500 •528 303 Leicester. Do. Ditto ditto 7,000 *448 240 Derby. Do. Ditto ditto 7,000 •424 227 Nottingham. Do. Staffordshire . South’s .... 10,933 •398 333 Mr. Clegg. Second variety . . . 10,667 •395 322 Ditto. Third variety . . 10,667 •390 318 Ditto. Fourth variety . . 9,600 •320 235 Ditto. Forest of Dean . . 10,133 •350 271 Ditto. Second variety . . 10,133 *360 279 Ditto. Welsh Coal. First variety . . . 10,000 •385 295 Ditto. Second variety . . • 10,133 •380 295 Ditto. COAL USED IN GAS MAKING. Cl In examining the foregoing tables, at first sight one is struck with the apparent discrepancies, in trials on the same coal, existing between the various experimentalists, and if a reason could not be assigned for these, probably our faith in their general accuracy might be shaken ; but taking into con- sideration the imperfect apparatus employed thirty years back, when many of these experiments were made, and other causes, there is much to admire and little to object to. Some few years ago the influence of the various degrees of temperature of the retorts, in the production of gas, was not so well understood as at present — low temperatures, small retorts, and eight-hour charges were very common, and as a consequence a comparatively small volume of gas was obtained, with an increase of tar. Therefore it is to be assumed that the variations existing in the quantities produced from the same kind of coal, must l^ave arisen from the temperature of the retort during the operation. Thus, if we refer to the two trials of Lesmahago, by the late Mr. Wright, who was a most careful experimentalist, we find a great difference in the volume of gas produced, which, however, is compensated as near as possible by the specific gravity of the gas. The greater yield no doubt was derived from the increased tem- perature of the retort. The low production of’ gas obtained by some of the authorities very probably arose from the retort's not being sufficiently heated, so that a portion of the hydro- carbons were converted into tar. The variation in the specific gravity recorded is by no means remarkable, on account of the imperfect instrument formerly used for ascertaining it. The table serves as a guide of considerable importance to the gas manufacturer ; it enables him to estimate the quantity and quality of gas, and gives, by inference, the weight of coke derived from each description of coal. It also enables him to estimate the value of gases obtained from cannel coals, and to determine the quantity from each class of cannel that may be requisite to increase the illuminating quality of gas from one standard to another. 62 CARBONISATION OR DISTILLATION OF COAL. CHAPTER IV. MODE OF CARBONISING. — TEMPERATURE OF FURNACES. EFFECTS OF VARIOUS TEMPERATURES ON THE PRODUCTION OF GAS AND TAR. THE PROPER TEMPERATURE FOR RE- TORTS. THE CHARGES OF RETORTS. FUEL IN HEATING FURNACES. TAR AS FUEL. ON THE MODE OF WORKING RETORTS. INCRUSTATION OF CARBON IN THE RETORTS. MODE OF CLEANSING. CARBONISATION OR DISTILLATION OF COAL. The first process in gas manufacture consists in submitting the coal to the action of a high heat, whereby its destructive distillation, or as generally termed carbonisation, is effected. In practice, this is don'e by placing the coal into retorts of fire-clay or iron, which are previously heated considerably above its point of ignition. The retort being charged with coal, is then hermetically closed with a door and luting, leaving no means of escape for the gas, except through the ascension pipe. By these means the coal is decomposed and the gas evolved, and when effectually done the residue left in the retort is simply coke — a substance chiefly consisting of carbon, containing neither bitum.en, tar, nor other volatile matter capable of yielding a useful gas for the purpose of lighting. The gas expelled from the coal passes from the retort a (Fig. 1), up the vertical pipe, called ascension pipe, c ; then traverses the bridge, or H-pipe d, down the dip pipe e, into the hydraulic main l — which is a large tube placed horizon- tally, and extending along the length of the furnaces, b is the mouth-piece attached to the retort; h is the lid or door of mouth-piece ; j, the screw for securing the same ; f, the furnace ; k, the furnace door ; and g the ash or evaporating pan. The hydraulic main is about half filled with water or tar, into which the ends of each and all the dip pipes are im- mersed, and the gas, as generated, forces its passage through the liquid into the space above, but cannot again return into CARBONISATION OR DISTILLATION OF COAL. G3 Fig- 1. 64 TEMPERATURE OF FURNACES. the retorts; so that when once arrived in the hydraulic main, it is fairly secured, and ready for the operation of purifica- tion. The reason of this is very simple — for the heat, in expel- ling the gas from the coal, by the vastly increased volume, creates a pressure or force similar to that of steam when generated from water, the two processes being identical. This pressure being superior to the obstacles which oppose the passage of the gas, such as the dips of the hydraulic main, scrubbers, purifiers, gasholder, and atmospheric pressure, the gas in consequence passes freely as generated ; and the column of liquid in the hydraulic main and dip pipe being consider- ably greater than the pressure of the gas when in the holder, it is thus prevented from returning to the retort. In the manufacture of gas, the proper means of carbonising coal is of the first importance ; ignorance on this point has often entailed considerable and serious loss, when, by a little intelligence, proportionate profits would have resulted. To ensure the necessary degree of heat for the retort is of the utmost consequence. TEMPERATURE OF FURNACES. With reference to the heat which it is proper to employ in the distillation of coal for gas-making, it is unfortunate that science has not yet furnished the practical man with any convenient method of estimating high temperatures. Wedg- wood’s pyrometer, though extremely ingenious, gives all its indications on so small a base line as to require an accuracy and homogeneity in the composition of the clay cylinders employed which is physically impossible. The range of temperature indicated by the Wedgwood pyrometer being more than ten times greater than the range from the freezing to the boiling point of water, has to be expressed within the limits of only -Jths of an inch, this being the extent to which a cylinder of clay contracts between a faint red heat at about 950° Fahr. and the melting point of cast iron at 2800° Fahr. It is true this very small range of Iths of an inch, divided as it is into 240 parts, is made appreciable by Wedgwood’s TEMPERATURE OF FURNACES. 65 contrivance of reading off on a base or ruler about 2 feet long, but the delicacy of observing and manipulating with such an instrument is too great to render it available for practical purposes, besides which the cones or cylinders of clay can never be procured sufficiently uniform in structure. Daniell’s pyrometer is, perhaps, superior to any other that has been tried. Its indications are caused by the expansion or contraction of a bar of platinum connected with a lever which acts as an index. The dial on which the index revolves affords room for a greatly increased space to read off the results, but this instrument for practical use is liable to some of the objections against Wedgwood’s pyrometer. The recent methods pointed out by Mr. Prinsey for determining high temperatures by means of fusing the metals and their alloys, is far too troublesome and complicated for practical use. The beautiful experiment of obtaining the temperature of a furnace by means of thermo-electric currents is also far too delicate for ordinary use, and until some contrivance more capable of being reduced to daily practice shall be introduced into gas-making, we must be content to be guided in a great measure by the colours presented by the interior of the furnace. Constant observation will, indeed, greatly improve the faculty of estimating high heats by the shades of colour which they present, and at all events enable the observer to compare and adjust the working of his furnaces. The following table of high temperatures, expressed in the colours commonly used, with their corresponding tempera- tures reduced to Fahrenheit’s scale, has been principally compiled from M. Becquerel’s “ Traiffi de Physique : ” — Faint red 960° Fahr. Dull red 1290 „ Brilliant red (colour of red oxide of lead) 1470 „ Cherry red • 1650 ,, Bright cherry red 1830 „ Dull orange 2010 „ Bright orange 2190 „ White heat 2370 „ Bright white 2550 „ Brilliant white 2730 „ Melting point of cast iron 2786 „ Greatest heat of iron blast furnace . . 3300 66 EFFECTS OF VARIOUS TEMPERATURES. There are, however, difficulties in appreciating the various degrees of heat by colour ; for instance, when heated retorts are exposed to the direct action of daylight, the colour or temperature appears lower than it really is ; or when they are enclosed in a dark locality, on the contrary, the tempera- ture seems to be higher than reality. The means of judging the various degrees of temperature by sight is only acquired by continued practice. The technical name applied to the temperature of retorts is “heat ” or “ heats ; ” thus it is expressed “ a good heat,” “a low heat,” or “the heats were down,” “the heats were up,” &c., terms sufficiently significant to require no explanation. EFFECTS OF VARIOUS TEMPERATURES IN CARBONISING. Coal when submitted to a temperature approaching to 600° Fahr. — that is, a very dull red heat as seen in the dark, a degree of heat which slowly chars paper, but does not inflame it — its volatile matter is resolved into tar and oil, and little or no gas is evolved. Mr. Young, of Bathgate, turned the knowledge of this simple fact to very great advantage, by decomposing Bog- head cannel coal at that degree of temperature whereby oil and tar only are obtained, which are afterwards purified, and universally known as paraffin oil. When the operation is properly conducted, the quantity of gas evolved is very small, in some cases perhaps not exceeding 50 feet or 100 feet per ton, the rest of the volatile constituents being condensed into liquid. In the carbonisation of coal, in proportion as the heat of the retorts increases, so is the quantity of gas augmented, and the tar diminished. The best temperature for iron retorts compatible with their durability and good yield of gas, ranges from 1650° to 1800° Fahr., being cherry -red and bright cherry-red ; but with clay retorts, a temperature between dull and bright orange, or 2100° Fahr., is the most suitable, giving vastly superior results in the production of gas than can ever be attained by the use of iron retorts. Iron retorts, when worked at a low temperature, are of EFFECTS OF VARIOUS TEMPERATURES. G7 very considerable durability ; in this state no deposit or incrustation takes place in them ; but these supposed advan- tages are often very dearly purchased. The attention of the writer was once called by a gas manager to the great durability of his iron retorts, which had been in use upwards of fifteen months, had never required clearing of carbon- aceous deposit, and were almost in as good condition as when first fixed. This was all substantially correct; but on referring to the accounts, the yield of gas was ascertained not to have exceeded 6,500 feet per ton ; whereas by an alteration of furnaces, so that the proper temperature for the retorts could be attained, the yield was afterwards 9,200 feet per ton. By the low temperature a large portion of the coal was converted into tar, and this in the locality being nearly valueless, the enormous loss can be readily understood. As stated, the most advantageous degree of heat for car- bonising coal is about 2100° Fahr. ; but when iron retorts are heated above 1800°, they are speedily destroyed, or “ burnt out/’ Clay retorts on this account have an immense superiority; they can be heated to the proper temperature without the risk of injury ; they are of extraordinary dura- bility (their average duration in some works being four years); the quantity of coal carbonised by them is considerably greater, and labour less than when iron retorts are used. These combined circumstances have caused clay retorts to entirely supersede those of iron. The time the coal remains in the retort is called the charge ; thus, if subjected to four hours* distillation or carbonisation, it is termed a four hours’ charge ; if for six hours, a six hours’ charge. The word charge also applies to the quantity, as when a retort is supplied with a certain weight of coal, say 140 lbs. or 2 cwt., as the case may be ; they are respectively called a charge of 140 lbs. or a charge of 2 cwt. The nature of the coal must regulate the quantity and duration of the charge. Some descriptions, as cannels, yield the gas very rapidly ; so in Scotland, where this is very generally used, it is found necessary to have small charges of about 1| cwt. per retort, or less, which is drawn every three hours. With Newcastle coal, which does not yield its gas 08 FUEL USED IN HEATING FURNACES. so readily, 2 \ cwt. are very common charges, which is worked off sometimes in five hours, but more generally in six hours. The coals destined for carbonisation should always be in a dry state ; and when by accident they are otherwise, if possible they should be placed along the retort-house and opposite the beds in use, some hours before required, in order to dry them. In addition to the evils of wet coals already enumerated, according to the opinion of Mr. Lewis Thompson the steam is converted into hydrogen, thus impoverishing the gas ; but however correct this may appear in theory, from my own observation it does not occur ip practice, the heat to which the steam is exposed being insufficient for its decomposition. FUEL USED IN HEATING FURNACES. The fuel commonly used for heating the furnace is the coke produced in the retorts after the gas is expelled ; the quantity of course varying according to the quality of coal and coke, the construction of the furnaces, and the magnitude of the operation. When Newcastle coal is used, the carbon- isation is seldom effected, except in very extensive establish- ments, with less than 25 per cent., or one quarter of the coke obtained ; that is to say, to carbonise a ton of coal, about 3j cwt. of coke will be required as fuel for the furnaces. Coal is usually spoken of by weight, and coke by measure. Newcastle coal generally yields about 1 chaldron of 36 bushels, or from 13 to 14 cwt. of coke for every ton of coals. In well-conducted medium size works about one-fourth of the coke made is used as fuel in the furnaces, the surplus three - fourths remaining for sale, as more particularly described in the section devoted to residual products. In small estab- lishments this per-centage of fuel is exceeded ; and in very large works the fuel employed is often not more than 18 per cent, of the coke produced. Some years ago Mr. Croll introduced the system of charging the furnaces with the red-hot coke, as drawn from ON THE MODE OF WORKING RETORTS. 69 the retorts ; there appears to be considerable saving effected by this, which has induced many engineers and companies to adopt it. When tar is not a marketable commodity it can be used as fuel with advantage ; for this purpose the ash-pit and door are bricked up, but leaving two orifices of about 2 \ inches square, the one above the other ; the upper being on a level with the line of top of door, the other about 8 inches below this. The furnace being filled with breeze to the level of the bottom of lower opening, a gutter of angle iron, or a gutter in the brickwork itself, inclines in the upper orifice to the interior of furnace, and through this flows a small stream of tar of about -^th of an inch in diameter. When first used, a few pieces of wood are lighted in the furnace, and the stream of tar flowing in, ignites as a flame at the upper opening, whilst a portion of the tar is deposited in front of the lower opening in the form of coke ; so that the air entering the orifices becomes highly heated by the flame above, and the combustion of the coke below. Fur- naces by this means are kept at an excellent degree of temperature. One great difficulty with tar as fuel is that it acts as a flux on the brickwork, but this is remedied by constructing the furnace expressly for this purpose. The combustion of tar as fuel is facilitated by allowing a very small quantity of water to drop continuously and inter- mix with it in the channel; this avoids the smoke which would otherwise pass off by the chimney, and the water itself becoming combustible aids as fuel. By adopting this system no smoke arises, no coke is employed, and the economy in some cases is remarkably important. A cwt. of tar is equal to 1^ cwt. of coke, requiring about a quart of water to be intermixed with it during combustion. ON THE MODE OF WORKING RETORTS. The magnitude of the works must always decide the mode of operation. In large establishments, where double retorts are used, being open at both ends, a double set of men is 70 ON THE MODE OF WORKING RETORTS. required to work them so as to be enabled to charge the two ends simultaneously. The economy of this, over the old method of setting the retorts back to back in different ovens, is very considerable. Where double retorts are used, each end is worked with at least three stokers and an extra man for preparing the lids of the mouth -pieces. Others are required for extinguishing the coke, wheeling the coal into the retort-house, clinkering furnaces, and attending to fires. Three stokers, assisted by a man to extinguish the coke, will perform all the work of taking off the lids, raking out the coke, extinguishing and wheeling it away from a bench of seven retotts, in twelve or thirteen minutes ; they will then put the proper charge for each retort in the scoop, deliver its contents, and be ready for charging another bench in a further space of seven minutes, while a fourth workman will in the meantime have put on the lids, so that the whole work of discharging and charging the seven retorts will occupy barely twenty minutes. This extreme dexterity is of course only acquired by long practice, and it must be admitted the labour is very severe ; but this is moderated by the time the men have for repose between the charges. The first process, in discharging or drawing, is for one or two of the men to relieve the screws of the mouth-pieces of the retorts about to be discharged, by giving three or four rapid turns; another man instantly gives a knock to each of the cross bars to disengage them from the ears of the lid, and at the same time strikes the lid a blow w'ith a piece of iron or hammer, in order to break the luting, and a light is immediately applied to prevent explosion, which would be likely to crack the retort if of clay. For want of this pre- caution, many lamentable accidents have happened through the gas exploding when combined with atmospheric air. The men then lift oft the cross bar and screw of each retort, placing them on the ground, and then each seizes hold of a lid in both hands, lifting by the projecting ears, and placing it aside to cool, ready for luting for another charge. Three of the stokers then take up their iron rakes, which are simply rods of f-inch iron, about 12 feet long, having a ON THE MODE OF WORKING RETORTS. 71 handle at one end; the other end being turned at right angles is flat, about 6 inches long, 2 inches wide, and ^-inch thick. These are inserted in the retort, and the red-hot coke drawn to the mouth, whence it drops into the .coke vault, where there is a man ready to extinguish by throwing water on it ; or when there is no vault the coke drops into iron barrows placed ready to receive it, and wheeled rapidly away when the charge is withdrawn. If the coke were not imme- diately extinguished it would smoulder, and the surface become covered with earthy ash, which detracts from its appearance and value. Formerly, in charging retorts, the operation being compa- ratively very protracted, there was a considerable loss of gas, in addition to the time and extra fatigue to the men. In order to remedy these inconveniences, a method has been contrived for depositing the whole charge in the retort at once ; for this purpose an iron scoop is used, this being a semi-cylinder of sheet iron from 8 to 10 feet long and 10 or 12 inches diameter, with a cross handle at the end to assist in lifting and turning it round to empty the coals in the retort. The charge of coal is placed in the scoop while it rests on the ground, having a bent rod underneath for the purpose of lifting it : one man takes hold of the cross handle, and two others lift the other end by the bent rod and introduce it into the mouth of the retort. The scoop with its contents is then pushed forward to the further end, turned completely over, and immediately withdrawn, leaving the coal in the retort, which is raked into a layer of uniform thickness, when the lid, previously luted and ready, is placed in its position and screwed up as quickly as possible. The operation of charging a retort with the scoop does not occupy more than thirty or forty seconds, so that very little escape of gas can take place. Hence the scoop has come generally into use wherever the works are large enough to supply three men for the purpose of working it. The composition for luting the retorts is made generally of the spent lime from the purifiers, mixed with a little fire-clay or loam, and well worked up with water like mortar. In large works it is prepared outside the retort 72 ON THE MODE OF WORKING RETORTS. bouse and brought in by wheelbarrows as required. In dressing the retort-lid with the luting, the workman uses a trowel, and works a little of it up on a board, and applies it all round the rim, taking care previously to clear off the old lilting. In small works, which do not permit of the necessary men being employed to work double retorts, single retorts, gene- rally about 8 feet long, are used. These are charged by means of the shovel, and the process is necessarily more tedious than the scoop, and the expenses of labour for car- bonisation increased. The beds or ovens of single retorts in very small works are placed side by side, and extend the length of the retort- house. In works of larger magnitude they are placed back to back. The number of men required to carbonise a given quan- tity of coal depends on the size of the works. At extensive establishments each man carbonises from five to six tons of coal per day, whilst in small works, where iron retorts are used, often 25 cwt. is not attained. In Scotland formerly, and perhaps at present, it was sometimes the custom for the stokers to be engaged by piece-work. A very essential point in the carbonisation of coal is to keep the interior of the retorts free from incrustation, and, indeed, as far as possible, to prevent it taking place. This incrustation, as already referred to, is a solidification of the richest parts (the heavy hydro-carbons) of the gas, and when gas is subjected to a high pressure and great heat, these are deposited in great abundance. It also entails several other disadvantages, — it increases the fuel and labour : by its obstruction renders more retorts necessary, so increasing the capital invested ; and wherever it abounds the coke is always of inferior quality. In iron retorts, where the heats are not so high as in those of clay, supposing both to be subject to the same pressure, this deposit does not take place so speedily ; but it is always in excess in the hottest part of the retort, which is generally the closed end, and diminishes towards the mouth in proportion to the diminished temperature. It has often been considered that COAL USED IN MAKING GAS. 73 the exhauster was unnecessary wherever iron retorts were used ; but wherever the incrustation of carbon occurs, either in iron or clay retorts, it may be taken as a direct proof of the necessity of that instrument. When clay retorts are at the most advantageous tempera- ture, and the gas in them is under a pressure of 18 or 21 inches (which is not uncommon when no exhauster is used), two or three weeks are sufficient for a very inconvenient accu- mulation of carbon in the retorts : but when the pressure is diminished by the exhauster to about 1 inch, the same quan- tity of accumulation would require from three to four months. The mode sometimes adopted to clear out this carbon (the furnace being heated as usual), is to project from a tube a small jet of steam on to the crust attached to the roof of the retort. The oxygen of the steam combines with the carbon which gradually diminishes, and when sufficiently thin can be easily detached by means of a chisel bar, it being removed from the roof, like an arch without the key ; the deposit of the sides breaks away in large lumps. Others prefer a periodical cleansing by leaving the retorts exposed to the action of the atmosphere, the heats being kept up as usual ; for this purpose the door is placed in its position, leaving about an inch space between it and the mouth-piece. The air enters and gradually cleanses the retort. It is always advisable to clear out this deposit before it becomes too thick; if neglected, its accumulation is very rapid. In all coal, combined with the ash, there are particles of iron, lime, and other substances, which fuse and become slag, or clinker, which deposits itself between the furnace bars and stops the current of air. To effectually remove this the bars should be loose, as hereafter stated ; and the clinker is readily detached by means of a suitable bar. When the ascension pipes are placed too close to the fur- naces, or when the wall of the furnace is not sufficiently thick, the pipes are heated to such a degree that the tar in its pas- sage is deposited thereon, as pitch, thereby causing a speedy obstruction. 74 CHOICE OF SITE FOR GAS-WORKS. CHAPTER V. SITE MOST APPROPRIATE FOR GAS-WORKS. — CONSIDERATIONS IN CHOOSING SITE. OBSERVATIONS ON THE LOWEST LEVELS FOR SITES. LEAKAGE OF MAINS. OBSERVATIONS ON PLAN OF WORKS. — ESTIMATE OF CAPITAL OF WORKS. CHOICE OF SITE FOR GAS-WORKS. In the largest class of towns or cities, the site generally chosen for gas-works has been the side of a canal or river, so as to profit by the convenience of water carriage for the supply of coal, purifying materials, pipes, bricks, retorts, and apparatus, also for the economical transport of the residues, as coke, tar, ammoniacal liquor, breeze, waste lime, &c. Since the establishment of railways, a site contiguous to a line is found, so far as economy of transport is concerned, equally advantageous ; whilst it is superior on some accounts, not being, like the canal and river, liable to the contingencies of frost. There is the further advantage in the railway, that the coal is delivered daily and direct into the retort-house ready for use, so avoiding the expenses of unloading the barges, loading the trucks, and wheeling. The Great Central Company’s Works, at Bow, afford an excellent instance of this arrangement. A branch line is laid down connecting the works with the railway which serves for the supply of coal, and the rails are laid actually into the retort-house, the rails being raised a sufficient height above the level of the charging floor to enable the waggons to tilt with perfect ease, and deposit the coal beneath, directly opposite the furnaces where required. Nothing can surpass this arrangement for economy and convenience. The most eligible situation for erecting gas-works close to a railway station is where the railway is on an embankment 12 or 14 feet high. A siding should here be constructed, on which the coal-waggons turn out of the main line and discharge their contents through shoots or other well-known contrivances. The retort-house should be erected as close CHOICE OF SITE FOE GAS-WORKS. 75 to the siding as convenient, so that the coal as delivered from the waggons will be quite ready for charging the retorts, and all expense both of carting and -wheeling the coal will be avoided. In the north of England this juxtaposition of gas-works and railways is by no means uncommon, and many small towns are reaping the advantage of lighting by gas which might otherwise have long been without so great an acquisition. In some establishments which adjoin a canal or river, the coal is delivered from the barge into iron waggons contain- ing about a ton each ; these are raised by hoists, and deposited on a line of rail, by which they are conveyed, either into the retort-house for immediate use, or to be stored. There are few things connected with gas-lighting which demand greater care than the choice of site for the intended works. In making the selection due consideration must be given to the probable objections that might be raised on sanitary grounds, and if there is an improving or superior part of the town, this should be avoided. Two London companies, whose w T orks are situated in improving and superior neighbourhoods, were for some years put to great expense, in consequence of the complaints of evils that w T ere said to occur to the neighbourhood from the proximity of their works. For convenience of communication, and economy in the cost of mains, it is essential that the works should not be too distant from the locality to be supplied. There are other circumstances depending on the relative value of property, the means of acquiring it, the nature of the ground, whether suitable for the economical construction of the edifices, or if liable to be submerged by heavy floods. These are points which demand serious attention. It has frequently been laid down as an imperative law, that gas-works should always be established at the very lowest level of the district to be supplied, and often in follow* ing this impression, an unsuitable site has been chosen, the land has been procured at a fabulous price, and perhaps afterwards the works, from their position, have been the E 2 76 CHOICE OF SITE FOR GAS-WORKS. source of continued complaints ; whereas by the exercise of proper judgment a more advantageous and suitable site might have been procured at considerably less cost. The motive assigned for the necessity of so placing gas- works, is that the lower districts are by these means better supplied ; and there might be some reason in this, if gas derived its force or pressure from its own ascensive power, but this is not the case, as the pressure is dependent on the holder which expels the gas. Too much importance has generally been attached to this law, and I will give a case in order to prove how one might err in following it. Gas by its lightness has an ascensive power ; and when enclosed in the mains, at the period that there is no draught or supply therefrom, the ascensive power is equal to about 1 inch pressure for every 100 feet rise of elevation. So in a town where the difference between the highest and lowest level is 200 feet, the pressure in the lowest level being -f^ths of an inch, that in the highest parts would be ffths. The loss of gas by leakage from the mains is always in direct proportion to the square root of the pressure of the gas, so if from a certain main the loss be 500 feet per hour, the gas being at ffths pressure, it would be 400 feet at io^ths, and only 800 feet per hour with a pressure of i%ths. Therefore, in choosing a site, it becomes a serious consideration to avoid as much as possible the high pressure, which existing during the whole of the day, when there is no lighting, would entail a great loss. Now if in the town already referred to, the works were to be constructed midway between the two levels, with two distinct mains to supply the upper and lower districts, then a maximum pressure of -bjths would be sufficient ; and if the general lighting were in the upper part of the town, all other circumstances being equally favourable, great advantage would be gained by placing the works midway. As a rule, it is generally better to place the works in the lower part of the district, but the difference of a few feet in the level will never be of material consequence. When there is the full supply from the mains, the pressure is not always in relation to the level ; but being according to PLAN OF WORKS. 77 the size of the mains, the highest part of a town, that might have extraordinary pressure when there is little draught, as during the day, might through the insufficiency of the mains, or through an obstruction of naphthaline or water, be almost in darkness at night. PLAN OF WORKS. Previously to the arrangement of the plan of works, the nature of the ground chosen for the site should be ascer- tained. This is readily done by sinking a well to the desired depth of the foundations of intended gas-holders. A guide is then obtained as to the mode of constructing and the cost. Should water be abundant within a short distance of the surface, then cast-iron tanks for the gas-holders must be decided on. Should the substratum be of clay, ordinary earth, or gravel ; a brick or stone tank for the gas-holder can be constructed with facility and economy. Should it be “ made ground,” that is ground which had formerly been transported from elsewhere, then extraordinary precautions in the founda- tions are necessary ; and should rock be encountered the question then arises whether it would be more advantageous to excavate and construct the tank in masonry, or avoid the excavation by erecting an iron tank. The price of building materials and their nature must also influence the arrangement of a plan of works. In some parts bricks and puddle are abundant and cheap ; in other places neither are to be had, unless at an enormous cost for trans- port, which renders their employment entirely out of the question. In designing a new works there are a few rules to follow. To construct in such a manner, that at a future period, when required, the works may be increased without much demolition. The retort-house may be so arranged as to be doubled hereafter ; the ground so disposed as to admit of extra gas-holders, and sufficient space left for increase of purifiers. The entrance of the works ought to be placed, when practicable, at that part of the site nearest the locality to be supplied. 78 PLAN OF WORKS. i i o lb PLAN 80 PLAJST OF WORKS. In the disposition of the various buildings, the manager’s or foreman’s dwelling should be at the entrance, so that all may be under the immediate notice of the residing respon- sible person. The offices, store-rooms, and weighbridge — for the purpose of weighing the coal as it enters, and the coke, when sold by weight, as it leaves — should immediately adjoin the dwelling. A plurality of entrances to a works ought to be avoided. In order to avoid the expense of unnecessary transport the coal-stores, coke spreading floor, and shed for coke, should adjoin the retort-house. Sometimes a part of the coal-store is paved with bricks on edge serving for spreading- floor, and for extinguishing the coke. The purifying house, tar tank, lime, and purifying mate- rial store, are generally separated from the rest of the works, and placed where they may be considered the least offensive. When there is plenty of room the gas-holders are separated from the other buildings ; but provision should always be made for future extensions. Old works, which have been altered frequently from time to time, to suit the demands on them, do not afford the same facilities for excellence of design as those of more modern construction. One of the most perfect plans of gas-works of magnitude, is that of the Liverpool United Gas Company at Wavertree ; it is a combination of every advantage, alike for the company and their men, and reflects the highest credit on the engineer, Mr. King. The plan of the new works of the London Gas Company, as also that of the Great Central Company, are both very excellent and worthy of imitation. The accompanying figure (Fig. 2) represents the ground plan of a small works designed and erected by Mr. Penny, of London, for St. Mary Cray, Kent. Fig. 3 is an elevation of the same. It is a favourable specimen of modern works, and appears to be laid out with care and judgment. These works, in their present form, are capable of manufacturing and supplying about 60,000 cubic feet per diem ; with another gas-holder, and an increase in some of the apparatus, double that quantity could be produced. The cost of these, but not including the main pipes, was about £3,200. PLAN OF WORKS. 81 The magnitude of gas-works and plant is generally esti- mated by their annual production ; thus a works is described as ‘‘ten million,” signifying that number of feet per annum, the maximum production in the depth of winter being about 44,000 feet, the minimum, at midsummer, being about 18,000 feet per day. In a works of 50 million per annum, the maximum production is about 220,000 feet per day, and the minimum 90,000, and so on in proportion for the larger establishments. But there are works of such extraordinary magnitude that the production is estimated by the maximum per diem. The maximum produce of each of the Imperial Company’s works is about 5,000,000 feet, making with their three stations a daily production, in the depth of winter, of about 15,000,000 cubic feet of gas. The capital required for gas-works is variable : for modern works from <£600 to £800 per million feet per annum is about sufficient ; or if the capital be estimated according to the population, from 15s. to 25s. per head may be calculated. The capital of old-established works usually surpasses these estimates, and in some instances the excess is very material, arising from the high price formerly paid for the mains, appa- ratus, and the necessary contingencies attending the first establishment of gas-works. The general improvement in the modern construction of the various apparatus, contributes also to the diminished price. When gas-lighting is properly developed, which mainly depends on the company supplying according to the quality and price of the gas, and the facilities afforded for its adop- tion, the average consumption per head is from 2,000 to 2,500 feet per annum. Whenever the consumption of a town is proportionably small, as a rule, it arises from mismanage- ment on the part of the company. 82 ON THE RETORT-IIOUSE AND BUILDINGS. CHAPTER VI. ON THE RETORT-HOUSE AND BUILDINGS. The Retort-house, as its name implies, contains the ovens, or, as more generally termed, “ settings” or “ benches ” of retorts, in which the operation of distillation or carbonisation of coal is conducted. With very few exceptions this is a rec- tangular building, covered usually with iron principals, and slates or tiles. When economy is a consideration, the roof is of sheet iron, the durability of which is, however, very limited. The width of this edifice in large establishments is from 52 to 70 feet, and from 30 to 32 feet high ; the length, of course, depending on the size of works. A few of the largest establishments have the retort-house very differently arranged to those of the great majority. In the centre, and extending from end to end, are a series of arches built on suitable piers. On these are constructed the ovens or benches, the piers of which correspond with those below. On a level with the furnaces of the retorts there is a stage or firing floor, where the stokers work when charging or drawing the retorts. This is about 8 feet from the ground, and is commonly formed by cast-iron columns and plates, and extends on each side throughout the length of the retort- house, leaving a space of about 2 feet wide immediately in front of the furnaces, through which the coke drops when drawn from the retort, into the space below, which is called the coke -hole, or coke -vault. The coke -vault possesses some advantages, for where it exists the stokers are not exposed to the continuous heat of the coke when drawn ; since it falls immediately below, where it is extinguished by other men. The furnaces are also clin- kered from below, which saves the trouble of raking out the fire, thus avoiding the cooling effect of a current of air passing through the oven, an evil which always happens where the furnaces are clinkered from the door ; and the convenience of loading the coke direct into the carts from the coke-vault is also a recommendation. The objections to the coke -vault are the expense in construction ; the coke in falling breaks, ON THE RETORT-HOUSE AND BUILDINGS. 83 and it is further injured on account of the very limited space for spreading, extinguishing, and storage. There are few works which have coke -vaults attached to the retort-house. Generally the ovens are built on suitable foundations, ensuring solidity to the structure, and preventing as much as possible radiation of heat from beneath. In these the furnaces are nearly on a level with the ground, and the coke when drawn falls into iron barrows, and is wheeled away to a separate place for the purpose of extinguishing. In retort-houses having no coke -vault, the tops of the ash or evaporating pans are a few inches below the level of the ground, which is usually paved with fire-bricks on edge. Sometimes cast-iron plates have been tried as a substitute for brick paving, but the metal conducts the heat to the feet of the men with such facility as to render it objectionable. The benches of the retorts were formerly placed back to back, so that a building containing say sixty single benches, each about 8 feet 6 inches long, thirty of these had their open ends or mouthpieces towards one side of the retort-house, the other thirty having their mouthpieces towards the other side, and a 9 -inch or 14-inch wall separated the benches. These are called single settings. Of late years this method has been superseded by dispensing with the partition wall, and so the two single beds form one continuous oven, each retort being about 18 or 20 feet long, open throughout, and having a mouthpiece at each end. These are called double beds or double retorts, and the economy derived from this plan is very considerable, but they can only be employed in large establishments, where there are at least six stokers to charge both ends of the retorts simultaneously. In small works the retort-house is constructed only for a single row of ovens, which are placed side by side, often extending the entire length of the building. In this case the retort-house is from 24 to 28 feet wide, and from 15 to 18 feet high. The beds are placed at one side, leaving a space of from 13 to 16 feet wide for charging and drawing, also as a deposit of coal for immediate use. In works of the smallest descriptions the retort-house and coal-store frequently form one and the same building; this, however, is objectionable. 84 ON THE RETORT-HOUSE AND BUILDINGS. In deciding on the dimensions of the retort-house, every consideration must be made, not only of the present require- ments of the locality to be supplied, but also that of the future ; for gas, even at the present day, is very far from attaining its full development, and it is impossible to antici- pate the various future uses to which it jnay be applied ; but the experience of the past demonstrates the necessity of making every reasonable provision for extension. It is also important to have a good margin, and not to estimate the power of carbonisation too highly ; for by unforeseen circum- stances, the supply of the ordinary coal may be temporarily discontinued, when resource must be had to that of inferior quality, which yields less gas and in consequence requires more retorts. No definite rule can be laid down for the dimensions of the retort-house ; this must entirely depend on the mode of setting. With one kind of setting considerably more coal is carbonised than with another ; it depends whether they are single or double, whether the retorts are of clay or iron, the kind of coal employed, and other circumstances. Mr. Clegg gives for the thickness of the walls in retort- houses built by him, 18 inches from the ground-line to the firing-floor, and 14 inches from the firing-floor to the top : he states, however, that where funds are available, he would prefer increasing each of these dimensions by half a brick, at all events to the height of the coal-store, which reaches to within 6 feet of the wall plate or top of the walls of the retort-house. There is nothing peculiar in the construction of the walls of the retort-house, more than other buildings of the same height ; of course precautions should be taken to secure a good foundation, to extend the base by footings, and where necessary to use pileing or concrete according to the nature of the foundation. On these points no general directions can be given, as the treatment must vary with the special circumstances of the case ; the general rule, however, applicable to ordinary foundations will apply here. The cost of erecting retort-houses will of course vary with the price of labour and building materials in the district. ON THE RETORT-HOUSE AND BUILDINGS. 85 Brickwork varies, in different parts of England, from ,£9 to £15 per rod, therefore it is useless to give the prices of any particular district as a standard ; but the following examples may be taken as an average : — A retort-house 32 ft. long, 25 ft. wide, and 16 ft. high, with iron roof, the firing -floor paved with bricks on edge, and square chimney 30 ft. high, cost £280. In Mr. Clegg’s “ Treatise on Coal Gas,” it is stated, a retort-liouse 50 ft. long, 24 ft. wide, and 18 ft. high, the roof of wrought iron and common tiles, and with a chimney 70 ft. above the ground, is estimated at £550. The next example given, is a retort-house and a coke- shed built on one side of it, on lower ground, so that the ground-line on one side was the firing-floor for the retorts, and the falling nature of the ground gave facilities for the coke to slide down the inclined plane into the shed. This building, which was 70 feet long, including a chimney- 90 feet high, but exclusive of foundations, cost . . £1200 Wrought-iron roof, slated J 90 Ventilator of wood, slated 43 £1433 Mr. Clegg’s next example is on a much larger scale, namely, a retort-house 200 ft. long and 54 ft. wide, with coke-vaults on the ground floor. His estimate for this build- ing is as follows : — Brickwork in outside walls, iron girders, flagged firing- floor, and centre portion for supporting retort benches £3950 Wrought-iron roof, slated 700 Chimney, 120 feet high 180 £4830 Mr. Barlow gives the size of a retort-house of 640 ft. iu length by 52 ft. in breadth and 24 ft. high. He estimates the building, including an iron roof covered with slates, at £16,640 Coal-sheds, to contain 10,000 tons of coal .... 9,000 Chimney, 120 feet high, with flues lined with fire-brick 450 800 retorts, namely, 400 clay and 400 iron, set complete, with hydraulic main, mouth-pieces, ascension-pipes, dip and bridge pipes, complete, at £17 15,?. each . 14,200 £40.290 86 ON THE RETORT-HOUSE AND BUILDINGS. The following is Mr. Croll’s estimate for a retort-house capable of containing 504 retorts, including the chimney, the purifying-house, the coal-stores, and a boundary wall to sur- round the works. £ s . d. 436 rods 33 feet standard brickwork, at £11 per rod 4797 10 0 793| yards of concrete, at 6$ 237 14 0 Roofing, as per tender 6615 0 0 Iron floor for purifying-house, 26 tons, at £10 per ton 260 0 0 12 tons of beams to support flooring, at £10 . . 120 0 0 504 retorts, as per former estimate, less £899 13s. 4^. for brick-work and concrete included in the above 6576 9 0 £18,606 13 0 Particular precaution is necessary in the erection of ovens, either in small or large works ; so that sufficient space be left for the expansion of the masonry, if not, there is every probability of the walls being forced out by the expansion or elongation of the brickwork. This precaution is particularly requisite for chimney-stacks, which should always be de- tached, and any flue into them should enter like a tube, with a slight space around it ; by this means, when the brick- work expands, the flue will not press against the chimney. Through want of attention on this point, many excellent stacks have been thrown so far off the perpendicular as to require rebuilding. In modern large retort-houses, they are built in blocks of about 100 ft. long, having free communication with each other ; there is often a ventilating shaft, constructed of wrought iron, with a valve or door, so by this the heated atmosphere of the building is considerably moderated, contri- buting much to the comfort of the men. And to the honour of many engineers, it must be said, that the comforts of the men employed in their respective companies have had their greatest consideration. In some gas-works libraries are established, in others baths and mutual benefit societies ; and there are gas-works that can boast of having a musical band, composed of the stokers and men of the establishment — cir- cumstances alike praiseworthy to the employers and employed. THE COAL-STORE. 87 THE COAL-STORE. This is generally attached to the retort-house, with every facility of communication for the purpose of transporting the coals. The dimensions of this building must be defined by circumstances. If the railway is the means of transport, then small stores may be sufficient, but should the ordinary means of obtaining the supply of coal be by river or canal, in order to provide against the probability of frost — the store should be ample for a supply of at least two months ; and whenever there are increased difficulties in obtaining the supply, it should be augmented in proportion. It is always advisable to have the coal-store sufficiently large, so that in summer, when not required for coal (and coke is abundant), it can be converted into a store for that residue. When employed as a spreading-floor, it should by all means be paved with fire-bricks, as stone is liable to crack with the heat. When not used for that object, ordinary common paving will answer the purpose. PURIFYING-HOUSE. The purifying house has, where practicable, the sides open, to permit a good current of air to pass through, and carry off any noxious gases. There should also be a ventilator in the roof, so that in the event of the lutes “ blowing,” the gas may escape readily at the top. The roof of the purifying -house is usually of wooden principals and tiles. Iron would be very speedily destroyed by the action of the sulphur emanating from the waste purifying material. In some works the purifiers are uncovered, this has the inconvenience of unnecessarily exposing the men at times to the inclemency of the weather, and ought to be avoided by a suitable roofing. ENGINE, BOILER, AND EXHAUSTER HOUSE. In the most moderate sized gas-works at the present day the steam-engine is an important auxiliary ; formerly the only use for an engine in a works was for pumping water, or for keeping in motion the wet lime purifiers, and in many 88 STATION METER-HOUSE. works of considerable capacity, where neither of these were requisite, a steam-engine did not exist. The use of clay retorts has caused motive power for work- ing the exhauster, to be introduced into gas-works of all denominations. The engine, boilers, and exhauster being attended by the same man, are usually in the same building, and more care is usually displayed in this than any other part of a gas-works. The edifice is often constructed with taste, and is no doubt an inducement to the men who have charge of the machinery to keep it cleanly, and in order with the building itself. STATION METER AND GOVERNOR HOUSE. These, like the engine-house, should only be accessible to the foreman, &c., and the man in charge. When there are several gas-holders together, it is not uncommon for the station-meter to be placed close to them, and the valves of the various gas-holders placed in the meter- house. Or on other occasions there is a distinct house for the valves ; but more commonly valves are attached to their respective holders. The most compact manner is the former, either when collected in the meter-house or a distinct valve-house. It is true there is some expense attached to this system, but it is much more convenient and secure. The governor is frequently placed in the same building as the station meter, but more generally a detached building is constructed expressly for it ; in large works there are several lines of mains issuing from the works, each of w'hich has its corresponding governor, with the various pressure gauges and pressure registers. CHIMNEY OR STACK. The chimney of a gas-w T orks, resembling all others, serves to separate the issuing hot air of the fire from the atmo- sphere around. Air when heated, becoming considerably lighter, has an ascensive power dependent on the degree of temperature it possesses ; and when highly heated — as when passing from CHIMNEY OR STACK. 89 the furnaces — is capable of ascending with great force and rapidity. The column of heated air thus ascending exerts itself, and draws through the furnace bars a quantity of cold air, which intermixes with the fuel, and produces combus- tion. The cold air is heated, and ascends, producing what is generally termed draught or current. The force of this draught or current is equal to the difference between the weight of the column of air in the shaft, and the weight of a like column of air of the atmosphere outside the stack. High stacks are constructed principally for the purpose of carrying off smoke or offensive products to a great height, where they are diffused over a large space, and a nuisance which otherwise would exist is prevented. In some chemical manufactories, the stacks are made of great dimensions, — one near Glasgow is 100 feet high. By means of this all noxious gases that may be generated are carried to and issue from the top, without the least prejudice to the neighbourhood. The largest chimney for a gas-works is that of the Edin- burgh Company, and is a fine piece of building, being 329 feet above the level of the ground, perfectly plomb, and without the slightest crack or fissure throughout the height. The current therein, when in ordinary working order, is equal to an exhaust of 2^ inches of water — a strong current in an ordinary chimney seldom exceeding half an inch exhaust. The cost of this stack, with the lateral flues, was upwards of £4,000. Some engineers attach little importance to high shafts ; and in neighbourhoods where the issuing smoke is not preju- dicial, small chimneys are employed. At the Great Central Company’s works, instead of a main stack for the furnaces, there are a series of small chimneys, each of an internal area of about 3 feet, and sufficient for six benches of retorts. They are built on the benches, each being about 20 feet high, and placed at intermediate distances throughout the length of the retort-house, and give every satisfaction. An advan- tage with them is, that in the event of an insufficiency of draught, a new chimney is erected in a few days, so supplying the deficiency. This plan is also adopted at other large establishments. 90 CHIMNEY OR STACK. Chimney stacks for gas-works are constructed in various manners, the simplest and cheapest being the square form ; but these are unsightly, and, offering greater resistance to the wind, require to be built strong accordingly. Some stacks are made circular, and others octagonal; the latter, when surmounted on a square pedestal, with a neat capital on the summit, have a remarkably good appearance, and the cost does not exceed that of the circular form. The ordinary chimneys of gas-works vary in height from 35 feet to 150 feet above the level of the ground ; their cost for a given height depends mainly on their internal area and the nature of the foundation. The ground being favourable, the price of a square chimney, 35 ft. high, with an internal area of 4 ft., will not exceed ,£30. An octagonal or circular stack of 8 ft. internal area, and 60 ft. high, under the same conditions as the former, will cost about £85. A similar stack of 10 ft. area, and 100 ft. high, would be £180 to £200. Chimney stacks, unless when placed in 'the centre of the beds, should never be built in the retort-house, as they occupy the space unnecessarily. Wherever constructed, they should always be detached, and, on account of their great weight and height, extraordinary precautions are necessary in their foundations. The area of these must be determined according to the degree of solidity of the ground where erected; the softer the soil, of course the greater will be the footings required. The pedestal for the base is usually one- tenth of the height square. Stacks for gas-works are always lined with fire-brick either for a portion or the whole of the height. Sometimes the lining is detached from the chimney, leaving a space for a current of air to pass between the former and the latter, which pre- vents the stack cracking. Small chimneys are usually con- structed entirely of fire-bricks. A mistaken notion often prevails, that by materially con- tracting the stack at the top, the draught is increased ; this, however, can only occur when of too great capacity. The stack, although tapering on the exterior, is internally nearly of one uniform area throughout, there being offsets at certain distances, according to the height and form. In ON THE RETORTS USED IN GAS MAKING. 91 erecting, every eight or ten courses should be built with hoop iron ; when this is not done, the stack frequently cracks, afterwards demanding the use of hooping on the exterior, which is unsightly. CHAPTER VII. ON THE RETORTS USED IN GAS MAKING. The earthenware or iron vessels in which coal is distilled for the purpose of separating the gas from the solid carbon are called retorts — a name borrowed from the language of che- mistry, in which a retort signifies a vessel either of glass, earthenware, or metal, in which distillation or decomposition is effected by the application of heat. The French, in their word cornue , have obviously adopted the name of a chemical vessel in the same manner to designate the retorts used in the distillation of coal gas. The earliest experiments on the form of retorts appear to have been made by Mr. Murdoch, when he erected the gas apparatus at the works of Messrs. Boulton and Watt, at Soho. The retort used there was a circular tube, the diameter ot which was equal to a third of its length. This was placed vertically over the fire-grate, and a horizontal pipe from the upper end conveyed away the gas, the open end of the vessel being of course uppermost. The form of these vertical retorts was afterwards varied, as it was found very inconvenient to extract the coke from them, when opened only at the top. The next form of retort was somewhat in the shape of a wine decanter; that is, of larger diameter at the base than at the top. The fire acted on the bottom and sides of this. In the side, close to the bottom, was an opening for extracting the coke, and a vertical pipe went off near the top for carry- ing away the gas. This form did not answer, owing to the mass of coal lying too much in a heap, and not presenting sufficient surface, so that an outer coat of coke was formed, which prevented the heat from penetrating quickly to the interior. 92 ON THE RETORTS USED IN GAS MAKING. The next contrivance was that of a cylindrical retort placed diagonally in the furnace. From this the coke could be readily extracted at the lower end, but the heat did not act so effectually as in the next form, which was that of a cylin- drical retort placed horizontally. The shape of this last was varied, being sometimes cylindrical in section, sometimes oval or ear-shaped, but the horizontal position and mode of setting were retained. During a series of years various systems were adopted before an economical mode of retort-oven or setting could be obtained. At first, retorts were set in sjngle ovens, each being heated by a distinct furnace ; afterwards, five were heated by three furnaces ; subsequently, one fire was sufficient for five retorts ; and such is the progress made in this, that at the present day very commonly a setting of nine or ten large clay retorts is heated by a single furnace. Amongst the various attempts to improve the settings of retorts may be mentioned that of Mr. Brunton, the web retort of Mr. Clegg, and the reciprocating retort of Mr. Lowe. The novelty in Mr. Brunton’s plan w T as the employment of a short retort, diminishing in size, so as to be considerably narrower at one end than the other. At the narrow end was a lid with a stuffing-box, through which passed a rod attached to a kind of piston inside the retort. Over this was a hopper, capable of containing about 28 lbs. of coal, which w T as admitted into the retort by drawing a slide or valve placed immediately under the hopper. The retort being charged with coal, the slide was shut, to prevent the escape of gas. At the wide end of the retort was a shoot dipping into a cistern of water, to prevent the gas escaping at that point. The coal being carbonised, the coke was forced forward by means of the piston, and dropped through the shoot into the cistern of water, from whence it was removed either by rake, shovel, or endless chain of buckets. The piston w r as again withdrawn to the narrow end of the retort, ready for another charge. Mr. Brunton claimed great superiority for this description of retort, and about 1840 it excited considerable attention, was tried in several places, but was not a success. ON THE RETORTS USED IN GAS MAKING. 93 Mr. George Lowe about the same period introduced his reciprocating retorts. In this system the retorts were con- nected together in pairs, w T ith suitable valves. The object of this was, that “ the products alternately of one of two retorts should be caused to pass into and mix with the pro- ducts of the other retort ; by which means, whichever of the two retorts w 7 as last charged, the products thereof, during the early part of the working, should pass into the other retort,” which, being in a highly heated state, would decom- pose any tar that might pass, and convert it into gas. This system, after being tried for some time at the Pancras station of the Imperial Gas Company, was abandoned. Mr. Clegg introduced a system of retort which w T as remark- able for its ingenuity. This consisted of a kind of endless chain of fire-bars, caused to travel by means of two re- volving cylinders set in motion by steam power, in principle very similar to Jukes’s self-consuming smoke apparatus or furnace ; the whole of this was enclosed, and the upper part of the chain exposed to the action of a high heat. The coal entered by a hopper, and fell on the web or chain, and by the motion of this, was carried to the point of distillation ; which done, the coke by the same motion was caused to drop into the receptacle destined for it. Mr. Clegg’s statement of the process with reference to the specific gravity and quantity of the gas was rather extra- ordinary ; but his assertion that the plates absorbed carbon, and were so converted into steel, was decidedly erroneous. There are two kinds of retorts employed in the gas manu- factory, viz. those of fire-clay, and those of cast iron, and in rare cases they are constructed of fire-bricks, built in the manner of an oven. Ketorts are single or double : the single retort is closed at one end, and generally from 7 ft. to 9 ft. long; the double retort is open throughout, and is charged simultaneously at both ends. They are very variable in their shape, being cylindrical, elliptical, in the form of the letter I), &c., depending on the judgment of the engineer. Formerly cast-iron retorts were universally employed in gas-works ; at present they are almost entirely superseded by 94 THE MOUTH-PIECE. those of fire-clay. Iron retorts exist now only in very small works, or when combined with settings of clay, hereafter mentioned. The iron retort, when now used, is the D shape, and single, being about 7 feet G inches long, 15 inches wide, and 13 inches high, interior measure, of the uniform thickness of If inch throughout, and weighing about 16 cwt. There is a flange on its end, corresponding to the flange of the mouth- piece, to which it is attached by bolts and nuts, and the joint made perfectly secure with cement. THE MOUTH-PIECE. The mouth-piece may be considered a continuation of the retort; but not being embedded in the brickwork, is not exposed to the same degree of heat as that, nor is it instru- mental in the distillation of the coal. The mouth-piece is usually about 10 or 12 inches long, having the same form as, but being considerably thinner than, the retort to which it is attached. There is a socket or flange cast thereon, to receive the end of the ascension pipe, THE MOUTII-PIECE. 95 which conveys the gas to the hydraulic main. There are also two pieces called ear -boxes, to which are fixed the ears for supporting the door, or as sometimes called, the lid of the mouth-piece. The cross-piece or screw-key is sup- ported by the ears, and when the retort is charged the lid has a layer of luting around it, and by means of the screw the joint is made hermetically tight. Figs. 4 to 8, drawn to a scale of -r 2 -th, or one inch to a foot, show details of a flanged mouth-piece for a D retort. Fig. 4 is a longitudinal section of mouth-piece, showing the socket cast on it to receive the ascension-pipe, and the lid affixed to the mouth. Fig. 5 is a corresponding elevation, showing the ear-box a, cast on each side of the retort to receive the ears, which are usually 14 inches long. Fig. 6 is a front elevation, showing the mouth -piece attached to the retort, but without the lid of the mouth-piece. Fig. 7 is a side elevation, and Fig. 8 is a plan of the mouth-piece attached to the retort, showing also the lid and the mode of securing it to the mouth-piece, b b are the ears passing through the ear- boxes a a , and secured by cotters, c c. d is the cross-bar through which passes the screw e, which presses on the lid and firmly secures it to the mouth -piece. The ears b b are 90 THE MOUTH-PIECE. fixed, and the mode of removing the door of the retort is by unscrewing the key, when the cross-bar d can be taken away and the door lifted off. The luting usually employed for the edges of the mouth-pieces is a composition of lime- mortar and fire-clay or loam, which, on being compressed by the screw, makes a perfectly gas-tight joint. There are various modifications of the parts connected with the lid, which may be briefly noticed. Sometimes the ear -boxes are so cast as to have no top, in which case they THE MOUTH-PIECE. 97 form a simple rectangular notch cast on each side of the moutli-piece. The ears, again, are not always perforated with the holes to receive the ends of the cross-bar, but have sometimes a simple notch in which the ear-bar rests. There is another method of fastening the lid, in which Fig. 10. the screw is altogether dispensed with, as shown in Figs 9 and 10. Here the ears form supports for an axis, a, which carries a lever formed at one extremity into a sort of eccentric or 98 IRON RETORTS. cam, and carrying at the other end a globe of solid cast iron about 4 inches in diameter. When the globular end of this lever is depressed, the cam presses with considerable force upon the back of the lid, and holds it as effectually in its place as the screw : in addition to which, if required, it is easy to increase the pressure by hanging on to the globular end of the lever an iron ring or other weight. Fig. 11 represents a door of a mouth-piece, which is supported in its position, and lifted, by the lugs at the sides. These were formerly of cast iron, but are now of wrought iron plate, about ^ inch thick, and slightly hol- lowed, to strengthen them. This simple alteration is of great importance, as it relieves the workman from lifting a cumbrous weighty mass, which was one of the most difficult parts of his duty. IRON RETORTS. For many years iron retorts were exclusively used, and their general abandonment by gas-works has only occurred within the last twelve or thirteen years. The evils arising from' iron retorts are numerous : they are costly in them- selves, which is increased by the expense in setting ; the price of fire-clay materials, as tiles, shields, bricks for arches, and labour, renders a bench of them expensive. Their dura- bility is also very limited, averaging about seven or eight months, and producing each about 600,000 or 700,000 cubic feet of gas. The average production from clay retorts being nearly four times that quantity. After having been in operation some time, iron retorts become bad conductors of heat, in consequence of the forma- tion cf a coat of peroxide of iron on their exterior ncces* XR ON RETORTS. 99 sitating continued cleansing, which, however, can only be effected in some parts of the retort, leaving the other parts covered ; and it sometimes happens that the retort is em- bedded in this non-conducting material, so that the heat cannot penetrate to it. Another evil is, that the iron becomes changed in its molecular nature, losing considerably its powers of conducting heat, and great care is requisite to protect them with fire- tiles ; stout arches are built to prevent the direct action of the heat on them. All this is a cause of a loss of fuel ; and with these precautions, care must be employed to prevent them attaining that degree of temperature which would be destruc- tive to them : and this sometimes produces a contrary effect, so that the temperature becomes too low, and a small yield of gas, with excess of tar, is the consequence. Iron retorts are only useful in small works, where the holders are heavy, or where wet lime purifiers, plunge- washers, and other circumstances exist which produce great pressure, and where an exhauster is not used ; or when the retort is continuously heated and cooled, as in experimental apparatus, and auxiliary settings. Iron retorts expand considerably, and after being worked some time and cooled down, a 7 ft. 6 in. retort will be found to have elongated about 3 inches. If this be put into operation it will again expand, but not in so great a proportion ; how- ever, it is not uncommon for a retort, as mentioned, which has been repeatedly heated and cooled, to expand 5 inches in length. Therefore, when used, the ovens of these should be considerably longer than the retort, otherwise the pro< liability is that the front wall of the oven will be bulged out. When iron retorts are required for future use, previously to being allowed to cool down the carbonaceous incrustation in the interior should be removed ; should this be allowed to remain, the retort sometimes breaks in tw r o halves, caused by the iron contracting in a much greater degree than the carbon. When in separate beds from the furnace, as in the com- pound settings of iron or clay, their durability is greatly increased, being on the average from eighteen to twenty 100 CLAY RETORTS. months ; nor do they form the peroxide of iron with the same facility, and this can be diminished to a minimum by a very thin coating of fire-clay on the exterior of the retort. CLAY RETORTS. The adoption of clay retorts has undoubtedly been one of the greatest improvements introduced into the manufacture of gas. As already stated, Mr. Winsor, in 1804, patented a “brick, or earthenware retort or oven,” but it does not appear that any application of this was made until 1818, when Mr. John Grafton patented improvements “ in employing retorts lined or cased with fire-clay.” In 1820 the same gentleman obtained a patent for improvements in clay retorts; in this specification he says, “ the Stourbridge clay heretofore used for clay retorts had generally failed in consequence of these retorts being made in one entire piece, which caused them to break in pieces very shortly after the fire was applied ; ” it continues, “ I caused the retort to be made in several pieces,” which, indeed, seems to have been the object of Mr. Grafton’s invention, and the substance of the specifica- tion leads us to believe that clay retorts were being tried previously to this; but if it were so, it must have been on a very limited scale, for neither the works of Accum nor Peckstone, published in 1819, mention anything about them. It is not very material whether Mr. Grafton was the first or not to introduce clay retorts ; it is, however, certain that he has been the direct means of bringing them into general use, for during several years, at great risk and loss, he tried various systems in order to ensure success. Amongst these was the mode of constructing the retort entirely of fire- bricks, built together with fire-clay ; these were in the shape of Fig. 12, about 5 feet 6 inches wide and 7 feet long, and capable of distilling from 7 to 9 cwt. of coal at each charge. This description of retort was in operation for many years in several parts of the Continent, where they had been CLAY RETORTS. 101 erected by Mr. Grafton. The advantages they possessed were a diminution of labour in charging and discharging, and the coke from them was of a good heavy quality, suitable for foundries, &c. ; but on the other hand they were very costly in their construction, and required a large quantity of fuel for carbonisation. The fire-brick retorts of Messrs. Spinney and Clift, described in the former edition of this treatise, were very similar to those just mentioned. Mr. Grafton afterwards had these retorts made in four or five pieces, similar to the plan now very generally adopted, going back to his original idea according to the specification quoted. Clay retorts were worked in Scotland for some years previously to their employment in England ; they were first applied in consequence of the high heats and short charges necessary in the distillation of cannel coal, which destroyed the iron retorts very rapidly, unless they were well pro- tected with fire-clay materials, so making the settings very costly. The first great trial of clay retorts in London was made by Mr. Croll, at the Brick-Lane Station of the Char- tered Company, in 1843. The retorts did not, however, answer the expectations ; they cracked, allowing the gas to escape, and this was considered by many at the period as being a fatal objection to their use. In 1844 Mr. Joseph Cowen, of Newcaetle-on-Tyne, ob- tained a patent for making clay retorts by a new and novel method, and for combining with the clay destined for the retort various substances, such as pounded coke, charcoal, 102 CLAY RETORTS. sawdust, &c., which project, beyond doubt, led the way to the present perfection in this branch of manufacture. Pro- bably the idea of Mr. Cowen was that the substances above- named would continue in combination with the retort, when in operation ; but the reverse of this took place, for in the course of time the carbonaceous matter so incorporated burned away, leaving the vessel porous ; but retorts made in this manner did not crack or break by the heat. The knowledge of this fact led to trials with other sub- stances intermixed with the clay, and finally to the present system, which is as follows : — In manufacturing clay retorts a portion of fire-clay is burned and reduced to a granulated state; this is then intermixed with just sufficient clay to hold the mass together ; the retort is then made by hand — allowed to dry very gradually — and then burned. The retorts so made, although much inferior in appearance to those of clay alone, are all that can be desired. From some peculiarity in the Scotch fire-clay this manipulation was not at first followed; the retorts made therefrom answered the object tolerably w r ell ; but those from Newcastle clay, without the granulated burnt clay, will not withstand the heat, for with all the care imaginable in firing they crack and break into numerous pieces. The advantages of clay retorts are — firstly, their great durability ; secondly, the degree of heat to which they may be submitted, which would be destructive to iron, is more suitable for carbonising the coal, producing the greatest quantity of gas, with little tar, and coke of good quality ; lastly, they require less labour. These important points have contributed much to the present economy in the pro- duction of gas, and the success of gas enterprises. For some years, however, great prejudice existed against the use of clay retorts ; an animated correspondence took place in the columns of the Journal of Gas-Lighting between two gentlemen of eminence, the one in favour, the other against them. The arguments unfavourable were, that clay being a bad conductor of heat, would require more fuel for the carbonisation of a given quantity of coal ; that the mate- rial being porous, the gas would escape to the atmosphere CLAY RETORTS. 103 instead of going to the holder ; and that by the high heat of clay retorts, the rich hydrocarbons would be deposited therein as incrustation. However, in working, experience has refuted all these objections, and the vast superiority of clay retorts is now universally demonstrated and admitted, not only in this country, but on the Continent and in America. But clay retorts cannot in most cases be worked advan- tageously without an exhauster to withdraw the gas the instant it is produced, to prevent it remaining under pres- sure, exposed to the red-hot surface. Should the exhauster not be employed, and the pressure in the retort be con- siderable, the heavy hydrocarbons are deposited in great abundance, deteriorating the value of the gas, generating a non-conducting material, which obstructs the interior of the retort, and demanding more fuel for carbonising. The objection that the clay of retorts is so porous as to permit the gas to pass through, is erroneous, which any one may be convinced of by breaking one of them which has .been in use for any length of time, when it will be found that the carbon has perhaps penetrated to the depth of one half or three-quarters of an inch, but shows no signs of having traversed the material. There are, however, some slight fissures or fire cracks which exist in the manufacture, which are speedily stopped after the first two or three charges ; but generally clay retorts of good construction, when the exhauster is applied, are not more porous than the best of iron. As regards the objection that clay is a worse conductor of heat than iron, no one will dispute this ; but the opponents of clay retorts did not take into account the vast quantity of this non-conducting material which was employed for the purpose of protecting the iron retorts, nor did they consider the quantity of non-conducting material continually being formed on their exterior. If this had been duly weighed, clay retorts would have had considerably less opposition. Although the manufacture of clay retorts would appear a very simple process, there is a peculiarity of manipulation in preparing and tempering the clay, and in constructing the retort, which, if not strictly adhered to, results in failure. In first-class fire-brick works a surprising amount of care is 104 CLAY RETORTS. taken with the clay, which when extracted from the mine is not considered suitable for the purpose until it has been exposed for many months, and sometimes years, to the action of the atmosphere, which acts chemically on it, and renders it suitable for the object intended. Thus, at the extensive works of Messrs. J. Cowen & Co. of Newcastle-on-Tyne, and probably at many others, there are mounds of some thousands of tons of clay undergoing this process, and to this circum- stance may very likely be due the excellence of the goods for which that house is celebrated. Clay retorts are as variable in their form as the iron ones were. Scotch engineers generally prefer them circular ; on the Continent the elliptical are almost universal ; whilst in England no definite conclusion on this point has been formed, their size and shape depending on the views of the respective engineers, and not on any positive grounds. In London the retorts usually employed are the D-shaped, with the corners rounded, otherwise, if square, the increased and uneven thickness would cause them to crack at that part. The form and size universally employed on the Continent is the oval, about 1 foot 8 inches wide, 1 foot 1 inch high, from 7 to 9 feet long, and invariably made in one piece. The D shape may be slightly preferable on account of the layer of coal when placed therein being of one uniform thickness ; against this, probably the circular and oval, being of greater regularity in their thickness, are not so liable to break. At most large gas-works double clay retorts are used. These are from 18 to 20 feet long, composed usually of four or six distinct pieces, jointed together with fire-clay, having a mouth -piece at each end, and are combined in sets of six, seven, eight, or ten. At the Imperial Company’s works there is considerable economy of space in the retort-house, by placing ten retorts in an oven, in two vertical rows. The upper retorts are charged and discharged by means of a travelling stage. Each of these double beds is capable of carbonising from 7 ^ to 8 tons of coals, producing from 70,000 to 75,000 cubic feet of gas per day. In the same space, with iron retorts CLAY RETORTS. 105 and old settings, of five retorts in a bench, little more than one-third of this result would be obtained. Clay retorts, like those of iron, are of uniform thickness throughout, averaging about 2J to 2| inches. Their mode of setting is remarkably simple, requiring no guard or shield tiles, and in some cases have no arches, which formerly were great obstacles to the distribution of the heat. The mouth- pieces of clay retorts are precisely similar to those of iron, but the sockets and the ascension-pipes are required larger ; the latter for clay retorts should never be less than 5 inches internal diameter. Fig. 13 shows the open end of a clay retort, and Fig. 14 shows the mode of attaching the mouth-piece by means of bolts with T-heads let into the body of the retort. Fig. 13 is a front elevation of the retort, showing the thickness of the part to which the mouth-piece is bolted, also the bolt-holes, 1^- inch in diameter. Fig. 14 is an elevation showing the mouth-piece attached, with a socket-pipe bolted on, but without the lid, and is similar in its details to that shown for iron retorts. Fig. 15 is an end elevation of one of the pieces of which F 3 106 OLAY RETORTS. the retort is composed, showing the triangular groove of a corresponding ring, for the reception of the fire-clay when making the joint ; and Fig. 16 is a section showing the junction between two pieces of the retort. In making the joints of clay retorts, or attaching the mouth-pieces to them, the part of the retort should be well wetted, so as to combine with the clay. For connecting together the ends of clay retorts, fire-clay alone is used, formed into the state of mortar. For the joints of mouth- pieces, a small portion of iron cement is often intermixed with the fire-clay. It is essential that these retorts should be allowed to remain a few days after being set, before being fired, to expel any moisture, which would be likely to cause them to crack. The breakage of clay retorts is occa- sioned sometimes by the stoker failing to apply a light, when in the act of discharging, as soon as the lid is loosened ; the CLAY RETORTS. 107 consequence is, the gas in the retort becoming combined with air, an explosion is produced, which shatters the retort. In first-class manufactured clay retorts, when an exhauster is employed, leaving only a pressure of about an inch on them, there is no leakage whatever. In others, of inferior make, the leakage will sometimes be considerable ; but this, in the course of a short time, is stopped by the carbon of the gas itself, which is deposited in the cracks and fissures ; these arising from fire-cracks, and not from the porosity of the material. In England clay retorts for the sake of strength are gene- rally supported in their ovens at intervals throughout, by walls, as seen in Fig. 19. On the Continent these are always dispensed with — the retorts, usually made in one piece of 8 or 9 feet long, only being supported by the pillars on which they are placed. In attaching the mouth-pieces to iron retorts, or the ascen- sion pipe to the mouth-pieces, &c., the ordinary iron cement should be employed ; this is driven in by means of a caulking- iron, and when properly done makes a good sound joint, but is never suitable when exposed to even a very low degree of red heat, for under these circumstances the cement is decom- posed, and becomes useless. 108 CLAY RETORTS. The recipes for making iron cement vary considerably Mr. Peckstone says 1 lb. of iron borings or turnings are to b pounded in a mortar into a state of fine dust or powder ; these are to be mixed with 2 oz. of sal ammoniac in powder and 1 oz. of flour of sulphur ; the whole to be thoroughly incorporated by being pounded in a mortar. When required for use, take one part by measure of the above compound, and mix it with twenty parts of pounded iron borings, adding water to bring the mixture to the consistence of ordinary mortar. This cement may be applied in making all sorts of flange joints, as in securing the mouth-pieces to the retorts, the dip-pipes to the hydraulic main, &c. Mr. Clegg’s recipe is somewhat different : he uses Iron borings or turnings 32 oz. Sal ammoniac 1 „ Hour of sulphur 1 „ To be well mixed together, and kept dry for use. When required, water to be added to bring the mixture to a proper consistency. The French employ for the same purpose a cement called the Mastic d’Aquin, which is thus prepared : — 98 parts of clean iron turnings, pounded and passed through a sieve. 1 part of flour of sulphur. 1 part of sal ammoniac, dissolved in sufficient boiling water to bring the whole mass to the consistency of ordinary mortar. This cement is not prepared till required for use, and should be employed as soon as possible. The iron borings should be sifted, and perfectly free from grease or oil, otherwise if too granulated or greasy a good joint cannot be made. ON RETORT SETTINGS. 109 CHAPTER VIII. ON RETORT BETTINGS. The disposition of the retorts in the ovens, or the manner they are placed or set, is called the “setting,” and the judicious arrangement of this part of the apparatus in gas manufacture is of the utmost importance ; for on this mainly depends alike the economical production of gas, and the use of the minimum quantity of coke as fuel. Setting retorts comprises the construction of the ovens and furnaces ; properly placing, supporting, and protecting the retorts ; arranging the passages between them so as to equalise the heat throughout; and making the communication with the main flue. To approach perfection in this, there are several points to be considered. The foundations of the retort ovens should be solid and sufficiently massive to prevent the loss of heat at that part. Sometimes a series of air-cells or small spaces in the brick- work of the foundations are formed in order to prevent loss of heat by radiation. All superfluous brickwork in the inte- rior of ovens should be avoided, leaving only that necessary for the proper support of the retorts, and, when iron retorts are used, the proper protection to guard them- from the injurious action of the heat. Other means to prevent the radiation of heat should, so far as practicable, be adopted ; for all heat lost unnecessarily by radiation is so much coke lost without a purpose. The openings or nostrils for distri- buting the heat from the furnace should always be amply wide. Many instances have occurred where the furnace has been at an intense degree of temperature, yet the retorts above could not attain an ordinary heat on account of the passages or nostrils being contracted. An essential point also is to have complete control over the damper leading to the flue ; for if this be too much open, and the draft strong, a great increase of fuel is necessary without any good result. Lastly, whilst due consideration should be had for the com- forts of the stokers employed, all useless loss of heat in the 110 ON RETORT SETTINGS. retort-house should be prevented, so that the buildings should not have too many openings, as windows, &c. ; and when air- shafts or ventilators are constructed, these should be provided with valves, to shut or close according to the weather, or the season of the year. Formerly in the construction of furnaces for gas-works the steam-boiler furnace was copied, this being of large area, and the fuel placed in a thin layer ; but the conditions of the two are widely different. A large area and thin stratum is well adapted for burning coal and generating steam ; but the reverse of this is requisite for burning coke and obtaining that high degree of temperature essential for retorts. It is now generally acknowledged that when the furnace is con- structed so as to heat comparatively a small quantity of air to great intensity, which afterwards diffuses itself, the best results are obtained. Fig. 17 shows a section of a furnace of this kind, which was first employed by Mr. Croll twenty years ago, and has since become very general. They are of small area, being at the bottom from 20 to 30 inches long, from 6 to 9 inches wide, and from 10 to 18 inches deep, depending on the size of the ovens to which they are attached, the smallest dimen- sions stated being sufficient for a bed of five retorts. ON SETTING CLAY RETORTS. Ill There are two bearers of wrought iron built into the brickwork, a short distance from the ends, and on these repose the fire bar or bars. In small furnaces one bar only is used, in large furnaces two are generally employed. These are simply bars of wrought iron of 1| to 2 inches square, placed loosely on the bearers. By this system the air passes through a thick stratum of fuel, and attains an intense heat ; whereas by the old furnace often a large portion of air passed through the uncovered bars without contributing to the heat, but, on the contrary, carrying with it a portion of that from the retorts. Great facilities for “ clinkering” are offered by this manner of placing the bars, so that they can easily be shifted, the clinker removed, and afterwards, when replaced, a few lumps of coke are thrown in to prevent the smaller pieces of coke from falling through the openings between the bars, which done, no more breeze passes through than with the old- fashioned method. These furnaces are now very generally employed, and are undoubtedly superior to others. ON SETTING CLAY RETORTS. In setting clay retorts there is not that degree of difficulty which exists with those of iron ; the complication of fire-tiles, shields, and protecting arch, are avoided. The retorts being placed on proper pillars or supports, the fire from the furnaces acts directly upon them. There is great diversity of opinion as to the best mode of setting, some engineers preferring six, others seven, eight, nine, and even ten retorts in a bed. Nor does this diversity of opinion confine itself to the number, but applies also to the mode of conducting the heated air. In some cases this passes direct into the main flue above, in other instances the heated air passes over the retorts above, and then descends into the main flue below ; but as the two methods are practised in our metropolitan w 7 orks, it may be inferred that there cannot be much difference in their results. Fig. 18 represents a section of a bed of ten clay retorts, as used at the Imperial Company’s works. In this setting there are ten double retorts, each 18 feet long, and charged at both 112 ON SETTING CLAY RETORTS. ON SETTING CLAY RETORTS. 113 114 ON SETTING CLAY IlETOItTS. ends simultaneously. The upper retorts are charged, and drawn by means of a travelling stage, which is wheeled from one end to the other of the retort-house, wherever required. a is the furnace, having one bar only ; r r the retorts ; b is the flue conducting to the main flue, there being various openings throughout the whole length for the heat to pass freely. The ordinary charge for this setting is 1 ton 16 cwt., which is sometimes carbonised in five hours, but more generally in six hours. Fig. 19 is a section of half a double setting of these retorts through the vertical line a b, the front wall and mouth-piece, for want of space, not being shown. It, will be observed that the brickwork is merely for supporting the retorts, and that the fire acts direct, without any interruption, ascending to the main flue above. These beds are fired with the red-hot coke as drawn from the retorts, producing a considerable economy. The general opinion is in favour of settings of seven clay retorts in a bed ; and where economy of space in the retort- house is not so necessary as at the Imperial Company’s works, the settings of seven may be preferable, on account of the whole of the retorts being worked from the ordinary firing floor, and not requiring the travelling stage. Fig. 20 represents a front section of a set of seven clay retorts as adopted at the Commercial Company’s works in London. In this the heated air diffuses amongst the upper retorts, and afterwards descends into the main flue below. The variation in the two systems of upward and downward current cannot be important, otherwise the results would speedily settle the division of opinion as to their respective merits. The price of a setting of single retorts, including founda- tions, oven, furnace, door, frame, ash-pan, fire-bars, buck- staves, sight boxes, retort, mouth-piece, two lids, ascension, bridge, dip-pipes, and hydraulic main — in short, the bed complete, with all its accessories — is generally estimated at £17 10s. per retort, so that a bed of seven single retorts, each 8 feet 6 inches long, will cost about £122 10s. The average durability of good clay retorts may be considered ON SETTING CLAY RETORTS. 115 about two and a half years, during which time the expense for fire-bars, repairs to furnace, &c,, will not exceed 20s. per retort. The duration of retorts in some of the London works is often four and even five years. The arch of ovens once properly built will last sever. 1 years. Taking down retorts, and replacing them with new Fig. 20. ones, including labour, materials, &c., averages £7 10s. per retort ; so that replacing a setting of seven clay retorts would cost about £52 10s. When double retorts are used, the same estimates per mouth-piece are applicable. 116 IRON RETORT SETTINGS. The cost of wear and tear of clay retorts in a medium size works may be estimated at 1 d. per thousand feet of gas pro- duced. In large establishments it will be considerably less than this. IRON RETORT SETTINGS. Among the various attempts to improve the working of ordinary iron retorts has been the system of subdividing them into two distinct longitudinal compartments, with the view that any tar that might be formed during carbonisation in the lower part would, in passing through the upper chamber, be converted into gas. This, however, would have the same inconveniences which accompany the production of gas from tar in the ordinary manner, and described elsewhere, with the inconvenience that the hydrocarbons of the gas would be deposited by their prolonged contact with the red-hot retort. It has also been proposed to construct iron retorts with projecting ribs in the interior, for the purpose of increasing the surface ; but this, instead of being beneficial, has tended to encourage the incrustation of carbon. Another method was to glaze iron retorts both internally and externally, which process possessed the advantages that the non-conducting material was not so rapidly formed on the exterior, and the incrustation of carbon was removed with great facility from the interior. These and many other systems have been patented from time to time ; but as clay retorts became gradually introduced, so was their great superiority under- stood, and iron retorts abandoned. Iron retorts are only useful in very small works, where there is no exhauster, and the pressure is too heavy for clay ; or when the settings, as auxiliaries, are subject to being in operation for a short period, and afterwards cooled down, which would cause clay retorts to crack and be useless ; or for experimental purposes, — in these cases they may be used with advantage. When circumstances oblige the use of iron retorts, imme- diately over the furnace there is an arch or fire slab, forming a kind of table or “ bench ” to receive the retorts. At each side of this there are openings for the heated air to pass and IRON RETORT SETTINGS. 117 iii r ■ i ^ „ I : I i IPP ' £ . 1 j__ i ._ _. . .. J .-- v i - i I I i diffuse itself throughout the bed, also fire-tile shields to pro- tect the retorts from the direct action of the fire. The accompanying Fig. 21 is a section of a bed of three iron retorts, f is the furnace, c the interior of oven, R r r the retorts, b b the fire slabs forming the table or bench, a a 118 IRON RETORT SETTINGS, the shields for protecting retorts from direct action of fire, d the supporting pillars, e small flue, fff the nostrils for the passage of the fire, g the damper, this being a kind of valve formed of fire-bricks and a fire- slab. Fig. 22. METHOD OP COMBINING CLAY AND IRON RETORTS. 119 Fig. 22 is a longitudinal section of the same, with the cor- responding letters of reference ; the front wall for want of space is not shown ; c is the back wall, which divides the two fur- naces when they work back to back. When in single beds this wall requires to be of good thickness, to prevent loss of heat. It is almost unnecessary to say that all parts in immediate contact with the fire should always be of good fire-bricks, for at least a thickness of 9 inches, built with fire-clay, and as thin joints as possible, the bricks being previously moistened. The furnaces should be constructed of the best bricks that can be procured for the purpose. Some descriptions of Stour- bridge bricks, others of Wales, called “ Dinas” bricks, are reputed to be good for the purpose. The radiation of heat from the tops of the arches may be greatly prevented by having a good thickness of brickwork, or a layer of sand, ashes, or similar non-conducting material, which is covered by a course of bricks. The front walls of ovens should never be less than 14 inches thick ; and when beds in use adjoin those out of action, the latter should be closed in all their parts ; the mouths of the retorts, the furnace door, and ash-pit bricked up, and the sight holes and damper securely luted with clay. The end bench of a setting has generally a massive wall as a buttress, which likewise prevents radiation at that point. The beds are also securely tied together by tie-rods and buckstaves. The following chapter will assist the reader to understand more fully the practice of setting retorts. CHAPTER IX. METHOD OP COMBINING CLAY AND IRON RETORTS. 1 The first conception of combining clay and iron retorts, so that the surplus heat from the former should afterwards be made available for the latter, is due to Messrs. Kirkham and Lowe ; but they appear not to have been cognisant of the import- ance of the system, and it was neglected, if not forgotten. 120 METHOD OF COMBINING CLAY AND IRON RETORTS. A short period afterwards Mr. Croll, unacquainted with what had been conceived by these gentlemen, patented a similar system, and with the means of properly carrying it to a successful issue. METHOD OF COMBINING CLAY AND IRON RETORTS. 121 In applying clay retorts to the carbonisation of coal, they are submitted to a much higher degree of heat than those of iron : the average temperature of the former being about 2100° Fahr., or an orange red ; whilst those of iron work most effectively at cherry red, or about 1700° Fahr. There- fore, it is obvious that the waste heat of clay retorts would be available for iron retorts. When clay retorts alone are employed, the surplus heat passes into the atmosphere and is lost ; but when combined with iron, as hereafter explained, this heat is made available, and is ample to maintain iron retorts at the proper degree of temperature alike for the economical production of gas and coke, thus effecting a very considerable economy in the fuel for carbonisation. This principle of combining clay and iron retorts has for a period of years engaged the attention of Mr. Croll, and under his management has been very success- fully applied ; but, like many other great innovations, has not met with the general approbation it merits, and, if we reflect on the time required to develop the superiority of clay retorts, this will occasion no surprise. Figs. 23 and 24: demonstrate the system of this improve- ment in the simplest form as in operation in small works. c is the furnace, the fire of which communicates directly with the three circular clay retorts above (r r r) ; and, after acting on these, passes over to heat the two O iron retorts (r' r'), and so to the flue i. Fig. 24: is a longitudinal section of the same setting, with corresponding letters to indicate the various parts. Another modification, varying slightly from the former, is shown in the Figs. 2 5 and 26. In this the clay retorts are immediately over the furnace, and the iron retorts at the sides. Figs. 27 and 28 represent a setting of this class for works of larger capacity. In this bench there are five clay retorts, each 7 feet 6 inches long, marked r, r, and four iron retorts of the same length, besides one O retort, 5 feet long, 20 inches wide, and 20 inches high, marked r' in Fig. 28. Through the courtesy of the editor of the Artisan , who has kindly permitted me to copy the admirable plates published in that journal, I am enabled to give, in Figs. 29 to 32, an Q r ■” 122 METHOD OF COMBINING CLAY AND IRON RETORTS. elevation, cross section, and longitudinal sections of one of Mr. Croll’s ovens, showing the mode of combining iron and Fig. 25. Kg- 26. METHOD OF COMBINING CLAY AND IRON RETORTS. 123 Fig. 27. Fig. 28. 124 METHOD OF COMBINING CLAY AND IRON RETORTS. clay retorts, as prac tised by him on a very large scale. These figures are all on a S3ale of 1 inch to 4 feet, a a a, &c., aro Fig. 29. the clay retorts, of which the upper two are elliptical, 18 METHOD OF COMBINING CLAY AND IRON RETORTS. 125 inches by 15 inches, and the other four circular, 15 inches in diameter inside. Each clay retort is made in four pieces, whicli Fig. 30. are jointed together with fire-clay, as described elsewhere, b b are the furnaces at each end of the retorts, which are ranged 126 METHOD OF COMBINING CLAY AND IKON RETORTS. METHOD OF COMBINING CLAY AND IRON RETORTS. 127 Fig. 32. 128 METHOD OF COMBINING CLAY AND IRON RETORTS. bo as to receive an equal share of the heat which diffuses it3elf in the upper oven, c c c c, > ft 40 40 8944 ft ft 50 53 13437 In examining this table we find a vast difference in the quantity of heat absorbed by water, especially as the excess of temperature rises ; and hence it follows that if the system of condensation by simple radiation into the air be adopted, the extent of surface exposed must be much greater than when water is used ; but although this would show a supe- riority of water as a cooling or condensing medium, yet it is generally believed that there is a certain mechanical effect produced in the gas passing through the series of pipes, which assists materially in the purification. This may be the reason why the air-condenser is so generally used almost to the exclusion of the other. Formerly water-condensers were much employed, now they are seldom seen, practice having proved theory to be incorrect. The gas in passing the condenser is acted on mechanically, by its various particles coming into contact with the surface of the pipes, and by this friction a large portion of the tar is deposited. The same effect will be observed with the purifi- cation ; when the exhauster is used the friction assists in the deposit of the tar. But gas may be condensed to an excess ; when this occurs naphthaline is deposited in the mains and services, causing continual annoyance, which is particularly the case in winter, when the condensation should be limited. Where the system of cooling by radiation in air is adopted, it is very advisable in dry and warm weather to assist the n 146 THE CONDENSER. cooling by allowing small streams of water to trickle down on the outside of the condensing pipes : this is effected by having a cistern of water fixed over them. The cooling effect of this water evaporating on the outside of the pipes is greater than if the latter were placed in w r ater, owing to the great quantity of caloric which passes from a sensible to a latent state during the formation of vapour. The more rapidly the vapour is formed, the greater will be the cooling effect, from which it follows that the effect will be greatest when the sun shines most powerfully, and that the con- denser should always be exposed as much as possible to the direct rays of the sun. The evidence taken in 1849 and 1850 before the Parlia- mentary Committees which sat on the Great Central Gas Con- sumers’ Bill, affords some valuable information on the subject of prices and the general construction of large works. The project brought forward by Mr. Croll, the engineer of the Company, contemplated an annual production of 368,000,000 cubic feet of gas, and the estimate for condensers in a gas- work of this magnitude was £1,237, exclusive of a concrete foundation, which would cost £5 or £6 more. Mr. Barlow, in his Report to the Directors of the City of London Gas Company, made no objection to this amount, and adopted it in his own calculation. This estimate is equal to *807 1*0 ,, 500 750 1000 i 1250 1054 859 942 744 815 942 666 739 845 942 Diameter of Pipe 4 inches. Length in yards /with 0-6 inch pressure » ga i*o \ „ i*5 750 1000 1250 j 1500 1932 1672 1 1932 1 1496 1728 1932 1366 1576 1761 2160 LAYING MAINS AND SERVICES, 239 Diameter or Pipe 5 inches. Length in yards j 750 1000 1250 1500 / with 0*6 inch pressure ■fj © ) yy „ Is „ i-o (Sr S \ „ 15 „ 2888 2508 3174 2236 2828 3174 1934 2596 2877 3540 Diameter or Pipe 6 inches. Length in yards 750 1000 1250 1500 .^'g / with 0*5 inch pressure *■£ © \ yy 0*8 „ f£ „ i-o ■ <§-3 l „ 1-5 4860 4210 5320 3770 4740 5320 3430 4340 4860 5970 Diameter of Pipe 8 inches. Length in yards £/g / with 0-6 inch pressure ■g © yy 9*8 ,, is I. 1 -® <§.§ l ,, 1-5 1000 1250 1500 1750 9450 10940 8480 9780 10940 7760 8940 9900 12200 7150 6260 9237 11300 Diameter of Pipe 10 inches. Length in yards £*"g / with 0*6 inch pressure *~£ © ) » 9*8 „ is) » 1000 1250 1500 1750 16500 19120 14800 17050 19120 13500 15600 17400 21300 12500 14400 16150 19600 Diameter of Pipe 12 inches. Length in yards 1000 1250 1500 1750 / with 0*6 inch pressure *"§ | ) yy 9*8 „ is j „ i-o Org V „ PS 26100 30200 23300 26900 30200 21400 24600 27500 33600 19800 22700 25450 31250 240 LAYING MAINS AND SERVICES. Diameter of Pipe 15 inches. Length in yards 1250 1500 1750 2000 £?% / with 0- 8 inch pressure 47000 42800 39800 37200 *"£ QJ ) >> 10 ,, 52600 48000 44400 41600 M if 1*5 58700 54300 50800 <§•3 ’ » 2-0 62800 58700 Diameter of Pipe 18 inches. Length in yards . . . . . 1500 2000 2500 3000 #8 1 f with 0*8 inch pressure 67600 58800 52300 33800 t £ 1 „ i*o 75700 65600 58800 53500 | „ 15 jf 80000 71800 65600 a-3 1 v „ 2-0 a 82800 75700 Diameter of Pipe 20 inches. Length in yards 1500 2000 2500 3000 / with 0*8 inch pressure "5 p j a 1‘0 ,, §£ ) „ 1-5 \ a 2-0 88000 98800 76500 85300 102300 68400 76500 93500 108000 62400 69800 85300 98800 Diameter of Pipe 24 inches. Length in yards ^ / with 0*8 inch pressure g ? a §5 „ 15 <§3 \ n 2*0 1500 2000 2500 3000 137200 155000 119000 135600 163000 106000 119000 145500 168000 ! 97000 108600 135600 155000 Diameter of Pipe 28 inches. Length in yards ( with 0 -5 inch pressure *■§ ® ) » 1,0 » <5-3 \ » 2-0 1500 2000 2500 3000 161000 229000 280000 140000 198000 241000 280000 125000 177000 216000 250000 114500 161000 198000 229000 LAYING MAINS AND SERVICES. 241 Diameter of Pipe 30 inc&ies. Length in yards 1000 2000 3000 4000 Quantity- delivered f with 0.5 inch pressure ► „ i*o 1 1*5 » v ,, 2*0 234000 332000 166000 234000 287000 135000 192000 234000 270000 117000 166000 203000 234000 Diameter of Pipe 36 inches. Length in yards 1000 2000 3000 4000 / with 1*0 inch pressure o 1 ) » 1-6 » §£ » 2 -°. „ 2*5 „ 530000 372000 456000 303000 372000 428000 265000 322000 372000 416000 To apply this table, let us suppose the maximum con- sumption per hour in a town to be 10,000 feet, the length of main from works to general divergence 1,500 yards, and the maximum pressure 1 inch, then on reference we find a close approximation to the quantity, and that an 8-inch leading main would be necessary. The principal leading main having been decided on, in a similar manner approximations must be made of the various quantities likely to be required per hour in each distinct locality, and providing the mains accordingly, taking into due consideration the probabilities of improvement or increase in the various districts. It is of the utmost importance to have the main pipes suf- ficiently large ; many companies have lost considerably by the escapes of gas caused by the high pressure necessary with small mains ; afterwards, when they were increased in size, the loss by escapes was reduced materially, and the company’s profits increased in like proportion. The first leading mains that were laid to supply London with gas were 3 inches in diameter, now there are several works which have them 36 inches diameter. It is very important to have a good map, not only of the site of the works, but of the whole district to be supplied 242 LAYING MAINS AND SERVICES. with gas ; on this map the course of all mains should be laid down, and the position of all syphons or water receivers should be marked. In addition to a mere surface plan, a network of levels should be taken over the whole district, and the grades or inclina- tions of all the mains marked on. The relative elevations of the whole district with reference to some fixed point near the gasholder would be best shown by contour lines of equal heights drawn throughout the district. When the town is nearly all on the same level, contour lines may be laid down at intervals of 2 or 3 feet vertical height, but where the streets are very steep, intervals of 6 or 8 feet would be suf- ficient. The best rule for laying on the contours is, that they ought to be so frequent as to show by a mere inspection of the map the level of every part of the surface with refer- ence to the fixed datum line. The admirable surveys of towns made under the directions of the officers of the corps of Royal Engineers, and plotted on a scale of 5 feet to 1 inch, are exceedingly well adapted for the delineation of gas and water pipes. The further information relative to the levels of the streets, the inclination of the mains, &c., will be readily added by a competent per- son, and will constitute the map a very valuable instrument in the hands of the gas company. There are as abundant examples of the mistakes made by gas and water companies as by commissioners of sewers, for want of proper maps delineating their under-ground works. Much economy and efficacy may be expected where the circumstances of each district as to levels and pressure can be at once ascertained, while on the other hand great losses are frequently occasioned by an ignorance of such particulars. It has been asserted by a writer on this subject that in a street of half a mile in length not less than twelve syphons have been discovered on taking up the main, while one, or at most two, would have been sufficient to drain the main. Blunders of this kind are evidently occasioned by the want of maps to refer to, show- ing the works already executed, and which would have ren- dered unnecessary the repeated reconstruction of the same works. LAYING MAINS AND SERVICES. 243 Mr. Clegg recommends, wherever practicable, that the main pipes should be connected to each other by cross pipes, which produce the effect of equalising the pressure of the gas at every point. Where this is not practicable, and where the irregularities of the district to be lighted are considerable, he recommends the use of a governor to reduce the pressure in the higher districts. It is generally considered that a governor is necessary when a difference of level equal to 60 feet exists, so that there are many towns which would require several governors in order to make the pressure more uni- form in the mains. Generally the mains are laid in or near the centre of the road, but when the streets are very wide they are often laid on each side near to the houses, the latter plan being adopted to avoid the expense of long services. Gas in its passage from the works carries with it a quantity of vapour of water ; this depending on the degree of condensation to which it has been submitted in the manufacture, or on the tempera- ture of the water in the tanks of the gasholder, which in- fluence the amount of vapour intermixed with the gas. The vapour existing from either of these causes, in its passage through the pipes underground is condensed, and if no pro- vision were made the water would eventually obstruct the pipes and stop the passage of the gas ; therefore water receivers (or syphons , as generally, although improperly, called) are placed at certain intervals to collect the liquor caused by condensation. Of necessity the mains must always incline into these syphons, to enable the water to drain into them, which is afterwards pumped out when desirable. These syphons are cylindrical vessels of cast iron, closed at top and bottom, having a socket on one side and spigot on the other, cast therewith, so that they may be connected to the main, of which they form a continuation. In the centre of the upper plate, or cover, is a f-inch pipe, which descends to nearly the bottom of the syphon, and a similar pipe, screwed on to this, and having a cap thereon, con- tinues to nearly the level of the ground, where it is sur- mounted by a box, or trap, generally of cast iron. On open- ing this trap, the cap of the syphon pipe can be unscrewed M 2 244 LAYING MAINS AND SERVICES. and a pump attached, so that any water in the vessels is easily removed. These vessels vary in size according to the main to which they are attached. Having the principal levels of a town, the position of the various syphons is easily decided, unless some unforeseen obstacle presents itself, such as sew 7 er, water-pipes, &c., 'which may render a slight alter- ation necessary. The syphons should be as few as possible consistent with the perfect drainage of the mains, thus avoid- ing unnecessary expense in placing them, unnecessary labour in trying them, and the probability of some of them being neglected. Much is often said of the large quantity of gas condensed in its transit; this is decidedly erroneous, for if the vast con- densation existed, which many pretend, it would be made apparent by the liquid deposited in the syphons. That this liquid arises from the condensation of vapours carried off with the gas is made manifest by the fact, that in summer, when the production of gas is at the minimum, the condensa- tion in the syphons is at the maximum, arising from the heat of the holder and the gas therein, which causes a large quantity of vapour to pass off into the mains. Another proof that this does not arise from the condensation of the gas is the nature of the liquid itself, which is neither more nor less than ammoniacal liquor. Therefore, with every confi- dence, we may say that the loss from condensation in mains, in the ordinary way of manufacturing gas, is not equal to one- thousandth part of the whole ; but when gases are so produced that the hydrogen does not chemically combine with the carbon, or when subjected to severe cold, then the deposit of the latter by condensation is often very considerable. Leakage in mains is a continuous and serious source of loss to a company ; therefore, gas mains should never be laid with undue haste ; the operation requires the utmost care, for on this greatly depends the success of the enterprise. An excellent plan to preserve pipes and to prevent leakage to some extent is to immerse them when hot into a vessel containing thin pitch, afterwards placing them erect to allow 7 the surplus to drain off, taking care previously to paint over the part of the spigot that enters the socket, as w T ell as LAYING MAINS AND SERVICES. 245 the interior of the socket, with loam intermixed with water to form a paste, allowing this to dry previously to immersion. The loam breaks off when the pipe is cold, leaving that part for making the joint entirely uncovered; if this were not done the pitch might prevent the joint being sound. The position of the works in relation to the locality to be supplied, together with the size of the leading mains, must determine the pressure at which the gas should be delivered ; thus, a town and works being on the same level, if the mains are ample, the gas having a pressure of 1 inch to 1| inch at the outlet of works should be sufficient for the supply of the whole district. Some extraordinary instances have occurred where, either by error or necessity, the works have been situated at the highest part of the district ; when this happens the pressure must be increased very considerably, in order to supply the lower districts. When the works are situated very low, sometimes, for the sake of economy, the gas may issue *at an exhaust of -j^ths or ! 5 0 ths of an inch, this being dependent on the position of the nearest light to be supplied. When mains are obstructed either by the deposit of naphthaline, or by water accumulated in consequence of not having drainage, a portion, or perhaps the whole, of the district is often without a proper supply of gas, occasioning the manager much annoyance and trouble. The way to discover the point of the main so obstructed is of the greatest simplicity. To detect where a stoppage exists in a main, recourse must be had to the pressure-gauge ; with this the pressure should be taken on the line of main when in full light- ing , at various intervals of say 100 or 200 yards, commencing from the works. This may be done on the public lamps or on the premises of a consumer ; but it is imperative that no light be burned on the same service during the trial, as this would cause a variation from the true pressure on the main, caused by the friction of the meter, or the gas passing through the pipes. Following the line of main, and noting the pressure at each point where tried, if the decrease of pressure be gra- 246 LAYING MAINS AND SERVICES. dual, this will be due to the friction of the gas in passing; and should it gradually decrease until insufficient for sup- plying the lights, then the main is too small for the quantity of gas delivered. But should the decrease of pressure be- tween one point and another, say in a distance of 100 yards, be sudden and excessive, then it may be concluded that an obstruction exists between these two places. This ascer- tained, perhaps it may be necessary to fix air-pipes, these being simply -|-inch or |-inch short pieces, screwed into the main, closed by a plug or cap, which are placed at various parts where tlie stoppage is suspected, with a block over them, and during full lighting the pressure is again tested on these air-pipes, when the stoppage may often be detected within a few yards. The remedy then is to cut the main, and remove the naphthaline, if that should be the cause ; or should the stoppage arise from an accumulation of water, the main must either be relaid or a syphon placed. The porosity of cast iron has long been a well-ascertained fact, and numerous experiments have been quoted to show that under high pressure even water may be forced through its pores and made to appear as a damp film on the outside of pipes. It is also certain that ordinary cast-iron pipes are permeable by gas, as the soil in contact with gas-pipes is almost invariably found to be saturated with gas, nor is the saturation confined to the joints, but continuous throughout the length of the pipes. These facts render it evident that great attention should be paid to the quality of the cast iron of which the pipes are composed, and that the pipes them- selves should be tested by a pressure of water, as in the case of water-pipes. Much greater attention is also now paid to the joints, which are made in a very superior manner to those formerly in use, as the success of an establishment is prin- cipally dependent on the soundness of the mains. Subjoined is a table of the average weight of pipes, and their price per yard at various rates per ton ; also an average price when laid in ballast at an ordinary depth. The price for paving must vary with the locality : often in London the ground opened has to be repaved in part or entirely a second time, which of course increases the expense. Table of Weight and Cost Price of Cast Iron Main Pipes. LAYING MAINS AND SERVICES. 247 ^ O CM CO 05 o CM CO 268 . CM CO WS CO GO 05 rH r— I r ” 1 i-H 1—1 rH co CO *53 CO 00 00 00 05 o o rH r “ l r "' CM . o CM CO rH ws CO «o H rH rH *“ l rH rH CM CM wo TH CO CM 05 CM c£ 05 o p-H CM CO tH tH rH 1-1 r “ l r— I rH 05 o 00 O © © ' r “‘ 1-1 00 00 05 o CM 1—1 rH *"“ l o O WO O CO o CO 00 CM r “ l «o ‘O * 0 > CO 00 00 m|n . coW CO, o -*H 00 CO 80 rH Co CO CO ^H Wi wo W 5 >o H|cq o CO o WS 68 rH - 1 oo CO CO CO CO TH ^H tH . Hcq *55 CO CO 05 o CM ws rH lO so CM ‘ (M CM CO CO CO CO ri|oq H|CQ oo O o r-H CO ws CO hH CO r-H CO I— 1 rH (M CM (M CM . rH(> ** ** ** o ^ 05 co*^ 00 *5§ CO oo*^ CO ^ 00 oo 1—1 ws *5$ ^H 00 r-H tH *53* rH Co ^ CO 00 O Hitt CM *« 05 60 O CM i 00 oo* ® Diameter of pipe in inches . 248 SERVICES. SERVICES. Services are the pipes which convey the gas from the company’s main to the consumers’ premises. Those in Eng- land are universally of iron tube, called gun-barrel, which in some description of soil is of great durability, therefore cannot be superseded by anything better; but there are other localities, such as towns which are on the sea-shore, having a sandy soil, where it is speedily destroyed. Whenever gun-barrel is used, it should always previously be heated, and ‘have a good coat of tar to prevent it oxydis- ing ; the workman when using it should only screw it by the socket, otherwise he will scrape off the pitch, exposing that part of the pipe to the destructive influence of the damp, &c. On the Continent, generally, lead pipe is used for services; its durability is very remarkable, but it requires more care in laying, in order to keep it even ; for that purpose it is usual to place a lath of about ^ an inch thick and 3 inches wide underneath it, which serves as a bed for the pipe, and prevents the uneven places, which would otherwise form and retain the water. The holes in gas mains should always be drilled : the clumsy and shapeless manner in which some men gouge them out is often the cause of great loss to the company. Services should always be laid with a declivity towards the main, so that water cannot lodge in them; if this hap- pened, it would cause at first oscillations of the lights, and afterwards a complete stoppage in the supply. Sometimes services are stopped by naphthaline, water, rust of iron, &c., wdiich is effectually removed by the service-cleaner of Messrs. Hulett and Co. This instrument is a kind of force- pump, and when applied to the obstructed pipe it is imme- diately cleared. The oscillation or jumping of lights is due to a portion of water deposited in the pipe through which the gas passes ; the pressure of the gas at one moment forcing a passage for itself through the water, and at another moment being ob- structed by the water. When services cannot be laid with an incline into the main, a syphon should always be placed ON THE LEAKAGE OF MAINS. 249 to collect the condensation ; this is formed with a tee-piece, with a short piece of pipe, and bends in a very simple manner ; syphons are also made expressly for the object. On the Continent, generally, there is a main -tap on the exterior of premises attached to the service supplying, for the purpose of shutting off in the event of fire. These taps were also formerly used for turning on and off the supply daily to contract consumers : at sunset a workman of the company turned on to each house, and again went his rounds at the various hours, according to the respective contracts, to shut off the gas. By these means such serious loss as was incurred at one time by gas companies in England, where the supply was kept on continuously, was prevented. Galvanised gun -barrel resists very effectually the action of rust. The increase of price is an obstacle to its use ; but in certain soils it is invaluable on account of its durability, and preventing loss of gas by decay of the services. ON THE LEAKAGE OF MAINS. This is a subject of great importance, and one which varies so much under different circumstances as to produce great influence on the returns of gas companies. Where every degree of foresight and economy has been exercised in the actual manufacture of the gas, it may afterwards be so much diminished by leakage between the gasholder and the meters of the consumers as to reduce the profits of the company to an alarming extent; indeed, in some instances has been ruinous. The amount of leakage is variously esti- mated at from 10 to 25 per cent. Many gas managers insist, with every reason, that when the mains and services are properly laid, and other necessary precautions taken, the loss by leakage should not exceed 10 per cent. Mr. Croll, in his parliamentary evidence, estimated that one-sixth of the whole gas sent out would be absorbed by leakage and stealage ; but in this must also be included the loss of gas occasioned by laying new mains, services, and alterations, which loss at times is very great, and demands the serious attention of engineers to prevent it. Mains are now laid in a very superior manner; and the M 3 250 ON THE LEAKAGE OF MAINS. oldest gas-works are those in which the most extensive leak- age prevails. There is also reason to suppose that the pipes are now cast in a superior manner, the metal being closer and more solid in texture, so as not to admit of so much leakage as that which prevails in porous and imperfect castings. It has been remarked that Professor Graham once found 25 per cent, of atmospheric air intermixed with the gas in its passage, which has been assumed to arise from the action of endosmose and exosmose before described ; but it is difficult to imagine this to have been the cause. More pro- bably the main was opened in a very low part of the district, where there was no pressure, and the air entering there was intermixed with the gas under examination. Gas often enters water-mains under similar conditions, there being a leakage in the water-main at the highest part of the district, also in the gas-main adjoining ; the gas is drawn into the water-pipe by a partial vacuum being formed therein, occa- sioned by the water escaping through a valve, or otherwise, at a part in the lower district. The effect of excessive pressure on the gas when de- livered into the mains tends considerably to increase the leakage ; and when the proper supply cannot be maintained without this, the more promptly the mains are replaced by those of larger and proper magnitude the greater will be the profits to the company. Sometimes the expense deters many from carrying the improvement into operation ; but sooner or later it must be done, and often by deferring it is post- poned until too late. For after consumers have complained repeatedly of insufficiency of supply, without redress, an opposition company makes its appearance ; and in some instances, after strong contention, the opposing has bought up the original company. A gradual stoppage in a leading main will have a similar effect as if the main were insufficient in size. The losses by leakage will be diminished materially by following the instructions in the article on “ Laying Mains” — by proving the pipes previously to being laid — by stopping their pores with bitumen — by coating the joints of the pipes afterwards with a flexible, impermeable composition — by PRESSURE GAUGE. 251 drilling, instead of gouging, the holes for the services — lastly, by making the service and main layers fully under- stand the valuable article they have at their control, and to adopt every means to prevent its loss. Sometimes the burners of the public lights deliver con- siderably more than their stipulated quantity, and give, through the excess of pressure, diminished light ; or, as it occurred in a London company’s district a few years ago, the meters had been so terribly neglected and decayed, that many of them did not register, whilst others only indicated a portion of the gas which passed. These and similar losses are generally put to the account of leakage. Cases like these are by no means uncommon CHAPTER XVII. ON APPARATUS FOR INDICATING AND RECORDING PRESSURE I PRESSURE GAUGE. PRESSURE INDICATOR, AND REGISTERING PRESSURE GAUGE. PRESSURE GAUGE. As already stated, when coal is distilled the heat decomposes it, and the gas is expelled in a manner analogous to the production of steam from water; the gas, when confined under ordinary pressure in a holder, assuming a bulk about 250 times greater than that of the coal from which it ema- nated, and if not retained by this means, dividing or diffus- ing itself to an indefinite extent. When gas is so confined the gasholder may be so counterbalanced as to prevent it issuing ; therefore, there being no weight, there would be no pressure, and by further counterbalance air would enter and intermix with the gas. The pressure of gas depends on a number of circumstances, such as the weight and area of holders, the size of pipes through which it passes, the means of purification, the seal or dip of hydraulic mains, and other obstacles which may be presented to its free passage ; and it is essential to the strict 252 TOESSUKE GAUGE. economy of a gas establishment that the pressure existing in all the parts of the manufactory, as well as in the mains for distribution, should be known. For this purpose a simple instrument called the “ pressure gauge” is employed, which consists in its simplest form of a glass tube about -§ inch internal diameter, and 6 or 8 inches long, bent in the form of the letter U, with the two legs approached as near as possible to each other. Between the two tubes is a scale, the centre being marked zero, and the space above and below is sub- divided into inches and tenths of inches. The gauge is filled with water to the line marked zero on the scale, and when not influenced by the pressure of the gas, the water, of course, stands at the same level in both tubes. When required for use, one end of the gauge is attached to the pipe through w T hich the gas is passing, when the pres- sure of the gas causes the water in one of the tubes to be depressed, and to be elevated in the other, the difference between the two water levels, as read on the scale, being the pressure of the gas. For example, if the water be depressed half an inch below the point marked zero, and elevated the same distance above, the pressure will be y§ths ; the scale may be dispensed with, and the difference of levels taken with an ordinary measure, and the pressure so ascertained. These gauges are often made with two straight tubes con- nected at top and bottom by a small chamber. The advan- tages of this system are, that the tubes are easily taken apart, and can be readily cleaned ; they can also be made much stronger. The bent tubes are very liable to break. In many establishments the maximum pressure in the town does not exceed 1 inch to 1^ inch, a minimum pressure of -fjyths being obtained in the lowest parts of the district, which is sufficient and ample. In others, however, perhaps from the position of their work? the size of mains, or the elevation of the locality supplied, much greater pressure is required. For ordinary purposes, as when ascertaining the pressure in the mains of the town, a gauge 5 or 6 inches long is sufficient. i The pressure in the streets may be ascertained by attaching the gauge by means of a flexible tube to the lamp burners, PRESSURE GAUGE. 253 or, if more convenient, on the premises of a consumer, but taking care that there is no supply from the same service. This operation is only done occasionally in the event of stoppages, or the mains being too small, in order to ascertain the defect. In gas-works, where the pressure is often equal to from 18 to 30 inches of water, caused by the weight of holders, the dip of washers, the smallness of mains, or perhaps from obstructions in the pipes, then gauges are made to suit the circumstances, and as the greatly increased length would prevent them being placed in many situations, mercury gauges are often employed ; these are constructed precisely similar to the water gauge, but the tubes are much narrower, being only about £ inch in diameter, and contain mercury instead of water. Mercury, at ordinary temperatures, is a fluid about thirteen and a half times heavier than water ; it consequently requires a proportionate amount of force or pressure to raise a column a given height. Or a given variation in the two levels of a mercury gauge indicates thirteen and a half times that pressure in water ; so that instead of requiring a water gauge 40 inches long, a mercurial gauge of 3 inches will be sufficient. There are other means of indicating pressure, by closed vessels being divided into two distinct compartments, and water being able to pass freely from the one to the other. In one of these compartments is placed a float, with a rod attached to it, passing through the cover of vessel, which is provided with a scale. The gas enters one compartment, and depresses the water therein, consequently elevating it in, the others, by which means the float is raised and the pressure shown on the scale by a pointer on the end of rod attached to float. This principle is applied in various ways, sometimes with a dial in the centre, or with a pointer and semicircular scale, and instruments of this class are often made very ornamental. The gauges above described only indicate the pressure acting on them at a particular moment, and leave no record; but there are other instruments employed which not only 254 PRESSURE REGISTER. indicate bat record rigidly throughout the day and night the pressure which has acted on them. Of these there are two kinds — the one called the Pressure Register or Indicator the other the Registering Pressure Gauge. THE PRESSURE REGISTER OR INDICATOR. This instrument in France is called the spy, “ le mouchard ,” signifying its duty to keep watch over and record the manner the workmen attend to their duty in the delivery of gas to the districts. Its action is automatic and continuous, requiring the application of a clock to indicate the various periods of time, whilst means are adopted to record the pressure. This instrument consists of a tank of cast-iron or tinned plate, of about 3 feet deep and 16 inches diameter, in the centre of which rises to about midway a vertical pipe in connection with the main. The top of the tank has a domed cover, on which is a receptacle for a vertical revolving cylinder of about 16 inches long and 5 inches diameter, the whole being surmounted by a clock, attached to the cylinder in such a manner as to cause it to revolve once in the 24 hours. In the tank there is a gasholder of about 14 inches diameter and 16 inches high, having a float throughout its length to give it the required degree of buoyancy when immersed, but which gives increased weight on rising. The holder has proper rollers and guides to enable it to rise and descend with every freedom. Attached to the top of the holder there is a rod which passes through the centre of cover of tank, and on the top of this rod is a spring pencil for the purpose of recording. Around the vertical cylinder is coiled a sheet of paper, which is marked into twenty -four vertical divisions, to indicate the hours of day and night, corresponding with the clock above. There are also a series of horizontal lines correspond- ing with the pressure, commonly being forty or fifty tenths, which are numbered, commencing from the bottom marked zero. The tank being supplied with water to the desired height, if there be no pressure the pencil will remain at zero ; but if the gas be admitted, say at a pressure equal to 2 inches, the holder rises, and with it the pencil, which REGISTERING PRESSURE GAUGE. 255 records on the horizontal lines of the coil of paper, and the vertical lines indicate the period that such pressure existed. By these means the slightest irregularity, if only existing for a minute, is recorded on the paper. THE REGISTERING PRESSURE GAUGE. The registering pressure gauge, represented by Fig. 62, is a much smaller and cheaper instrument than the former, and was invented by the late Mr. A. Wright. Its size renders it very portable, its moderate price permits its being adopted by works of all descriptions, and it is largely used by gas companies to record the pressure existing in different parts of their districts. This instrument consists of two concentric cylinders, the outer one, or case, a a } being about 16 inches diameter, and 256 REGISTERING PRESSURE GAUGE. 10 inches deep, closed at its base, also at the top over the annular space between it and the inner cylinder, c. These cylinders communicate with each other only through a small space left between the lower edge of the inner, and the bottom of the outer cylinder. The case is surmounted by a clock enclosed in a glass shade. The clock, instead of having an ordinary face, is provided with a metal disc which carries a circular sheet of paper divided by twenty -four radiating lines corresponding with the hours of day and night ; also having a series of concentric rings according with the various pressures. A float carrying a rod, d, and pencil similar to that of the Pressure Register, is placed in the inner cylinder, which is open at top. When required for use, water is poured into the vessel c until about half full. Gas being then admitted to the upper part of outer cylinder by pipe b f depresses the water in the annular space, and elevates that in the inner cylinder, precisely as in the gauges described, thereby lifting the float, causing the pencil to make a mark, high or low, in agreement with the pressure acting. Fresh sheets or discs are required daily, which should all be dated, and as they may become very important records, should be carefully preserved. These instruments are very essential — they serve to correct irregularities, to prevent blame being imputed in improper quarters, and point out when any complaint arising from irregularity of pressure has been made, not only at what station, but at what precise hour, and under whose management this has occurred. These records serve in the most delicate manner to check the pressure, and enable the superintendent to adjust it to the requirements of the district during the successive stages of the twenty-four hours, in which a remarkable variation takes place in the quantity of pressure required. For instance, there are some works which throughout the day scarcely require a greater pressure than three-tenths of an inch, though towards the time of lighting up the streets, shops, and private houses, the pressure requires to be in- creased to 3 or even 4 inches, and this continues till the hour when many of the shop lights and private house lights are ex- tinguished. Another diminution occurs about twelve o’clock, when most of the public-house lights are put out, and few THE GOVERNOR. 257 lights continue burning except the street lamps. The night pressure is further diminished to its minimum about the hour when the street lamps are extinguished, and continues at its minimum low state throughout the day. There is a modification of this instrument for the use of gas-works, which records the action of the exhauster, being very useful to prevent undue exhaustion, to which cause must undoubtedly be attributed the great variation existing from day to day in the quality of gas supplied by companies, as recorded by the chemical inspectors. CHAPTER XVIII. THE GOVERNOR AND REGULATOR. The governor is one of those ingenious self-acting machines which are equally admirable for their efficiency and simplicity. It is placed between the gasholder and the main pipe in order to regulate the pressure of gas admitted into the latter, and acts quite independently of any irregularity due to the unequal action of the gasholders or to other causes. The governor is also important in another point of view, viz., where a town has great variation of elevations, and where, without some contrivance to prevent it, the pressure of gas in the higher levels would be very excessive and alike pre- judicial to the company and consumer. This instrument is a single-lift gasholder and tank, having a peculiar valve in connection therewith, so that the pres- sure is always regulated according to the weight placed on its holder. The tank is made of cast-iron, its dimensions being dependent on the size of the mains for which it is destined, and the manner in which the apparatus is made. Fig. 63 is a view of a governor, the tank and a part of the holder being in section, in order to show the inte- rior ; a a is a cylindrical tank, having the columns b b to support the bridge e e, in the centre of which is a guide lor the flat rod d. The holder g is made of tinned iron, has . a conical plug suspended in it, and works very freely in the tank, being guided by rollers at its lower edge and the flat 258 THE GOVERNOR. rod d above. The inlet pipe is exactly in the centie, and has a conical-seated flange at top ; the outlet pipe being concentric to it, rises considerably above the level of water. The holder is provided with an annular float, o o, of such buoyancy, that when the tank is charged with the proper Fig. 63. quantity of water, it rises, carrying with it the suspended conical plug h, the base of which is turned and fitted to the flange on top of inlet, so as to be hermetically tight. The action of the instrument is very simple, for being supplied THE GOVERNOR. 259 with water to the proper height, and supposing the weights n n to be taken off, the holder ascends, lifting with it the conical plug, which, when at the top, stops the supply of gas. Under these circumstances the governor is destined to give no pressure. Now, if a pressure of xS-ths be requisite on placing weights on the holder equivalent to that pressure — no matter whatever variations may take place in the pres- sure in the works, or the quantity of gas being consumed in the town — the same pressure is strictly maintained by the governor ; if the quantity supplied be great, the holder descends with the plug, and so increases the size of orifice ; and should the quantity passing be small, the holder rises, and the plug closes the aperture, so that this simple machine delivers at all times any quantity of gas at the pressure desired, according to the weights on the holder. Another modification, called Wright’s governor, is to sub- stitute the float by a pillar lever-beam and counterbalance weights, the variation of pressure being obtained by adding or subtracting weights ; in other respects this instrument is precisely like the other. No gas works should be without a governor ; in some instances, where the whole pressure of works is left on the mains continually, it would repay its purchase-money in a month by the saving effected in gas from diminished leakages, tii many works the foreman, or stoker, has continually to regulate the pressure during the hours of lighting by means of a valve, giving much trouble, and the work is done very imperfectly. When there are great variations of levels in towns, governors are sometimes placed on the mains ; but for this purpose they are fixed on the principal main only ; and the branch mains from one governor should be disconnected from those of another. Thus, if the highest level of a town be 200 feet — by placing a governor at an elevation of 50 feet, and another, say 100 feet, and the third at 150 feet — the pipes sup- plied from the governor at each level should be quite detached from the others, otherwise the instrument would be useless. Another mode of governing the pressure of gas, is by means of a loose diaphragm of leather affixed to the top of 260 THE REGULATOR. a cylindrical vessel — having the conical plug and flange pipe similar to that before described — the pressure being varied by weights as before. Mr. Stevenson, of Halifax, has placed several of these on mains, and he speaks very highly of their efficiency. THE REGULATOR. This instrument is precisely the same in its construction and action as the governor ; but is considerably smaller, being sometimes made only to supply one light, as for the street lamps, or for establishments of any magnitude, as private dwellings, shops, manufactories, &c. There is considerable economy in private establishments by employing the regulator, inasmuch as it diminishes the pressure to the degree where the greatest amount of light is obtained from a given quantity of gas ; it likewise equalises any irregularities that may exist in the pressure from the company’s mains, and prevents loss of gas and smoke. The regulator is also very important for street lamps : it prevents waste, and the burners being suitable, the maximum amount of light is obtained from the gas. A metropolitan compan}^, which uses these instruments generally to its public lights, has set an excellent example ; and perhaps there is no place anywhere better lighted than their district. The street lamp regulators are indispensable wherever there is a heavy pressure on the mains. The instruments are sometimes made with a leather diaphragm, on the prin- ciple already mentioned. They were first made by Mr. Ford, of London ; Messrs. Wright, Sugg, and others, are also manufacturers. Their cost is about 3s. 6d. each. Another kind of regulator for street lamps and private consumers is the “ Mercurial,” manufactured by Messrs. Hulett and Co., London. This, in principle, is the same as the water-governor, the difference being that mercury is used to replace the water. These are, undoubtedly, more durable than leather regulators, many of them having been in operation thirteen years, without requiring the least attention or repair, and are now, apparently, in as good condition as when they were first fixed. EXPERIMENTS ON COAL GAS. 261 CHAPTER XIX. EXPERIMENTS ON COAL GAS. ON THE INFLUENCE OF TEMPERATURE AND BAROMETRIC PRESSURE ON GAS." — MODES OF EXAMINING AND COMPARING GAS. TESTS FOR IMPURITIES IN GAS. For the perfect analysis of gases a high degree of chemical knowledge is essential, and this subject forms in itself a very important branch of chemical investigation. Into this we do not propose to enter, but shall merely notice a few of those simple operations which the manager of every estab- lishment for the manufacture of gas should readily be able to perform, in order to satisfy himself and others of the value and purity of his gas, and to afford the means of rectifying errors. For this object it is proposed in this chapter to explain the means of examining gas, by its weight or specific gravity, by means of the photometer, and by the condensation of the hydrocarbons ; and although there may be some repetition, it is intended to give the various tests for ascertaining the purity of gas. Gas is materially affected by three causes, namely, the temperature, and barometric pressure to which it is subjected, which influence its volume ; and the amount of humidity combined therewith, which influences its weight. Gas is exceedingly elastic, and expands or contracts very sensibly with every variation of temperature, this expansion or con- traction being at the rate of -rid part for every degree of Fahr., or at the rate of nearly 2 per cent, for 10°, or nearly 20 per cent, for 100° difference of temperature to which it may be subjected. Thus 100 feet of gas at 40°, when its temperature is increased to 140°, expands and becomes nearly 120 feet; and the temperature again being reduced to 40°, the gas assumes its former volume. This variation of volume is illustrated by partially filling a common bladder w T itli gas or air (for they are alike in volume, and possess the same properties of contracting and expanding, according to temperature), the neck of the bladder being well secured so that gas cannot escape, when, if it be 262 EXPERIMENTS ON COAL GAS. held before a fire, the heat expands the gas enclosed therein, until the bladder becomes full and distended. If it be after- wards allowed to cool, on the gas attaining its previous temperature and volume, the bladder assumes its former collapsed state. Therefore it is usual in strictly defining the volume of gas to take a standard degree of temperature, viz., 60° Fahr., to which the proper corrections are made. Gas also contracts and expands by variations of the baro- metric pressure, concerning which a few words may be said. The air which surrounds our globe constituting our atmo- sphere is as tangible as the water on its surface, and is esti- mated to be from 40 to 45 miles high or thick. It is therefore obvious that, like all matter having what is termed weight, the air in the lowest parts, as at the surface of the earth, or at the level of the sea, has to bear the weight of the whole of the superincumbent mass above, so that at the lowest point it is necessarily compressed and reduced proportion- ably in bulk ; whilst on the top of high mountains, or when ascending with a balloon, the thickness or weight of air being diminished, the atmosphere in those places is subject to dimi- nished compression, when it is expanded in proportion to the elevation. Gas, following the same law T , is compressed or expanded according to the elevation where it exists : thus, at about five miles high, a given quantity expands to about twice the volume it would possess at the level of the sea. Or, a balloon containing 200 feet of gas at that elevation, when reaching the earth would by reason of the superincumbent pressure of the atmosphere be compressed into ' a space of 100 feet only. There is also another influence, according to the ever- varying state of the weather, whereby gas, in any given locality, is rendered more or less compressed or compact. These influences of the atmosphere are ascertained by means of the barometer, which is illustrated in its simplest form by taking a glass tube of about 33 inches long, having a bore of or \ inch diameter ; this being closed at one end, it is entirely filled with mercury. A cup containing a por- tion of mercury being at hand, the open end of the tube is firmly closed by the finger, when the tube is inverted and ON WEIGHING GAS. 263 held perfectly vertical, and the end immersed in the mercury contained in the cup, when, on the finger being removed, the column of mercury falls to a point according to the weather or the elevation of the locality where the operation is conducted. Under ordinary circumstances, the distance between the level of the mercury in the cup, and the top of column, is 30 inches, which is the standard of comparison for gas, which column is supported entirely by the pressure of the atmosphere. If we suppose the tube and the cup to be fixed, with a scale of inches and tenths of inches attached to indicate the height of the mercury, then we realise the construction of the barometer. By these means the degree of compression that gas is subjected to is known, and the proper corrections made to arrive at the given standard. The increase or decrease of volume is about -o^woth parts every variation of one-tenth of an inch of mercury. As examples of the necessity of these corrections, a volume of gas, when the mercury in the barometer is 31 inches, occupying 1,000 cubic feet, the barometer being 28 inches, would expand to 1,100 feet, or a difference of 10 per cent. The city of Madrid is about 2,000 feet above the level of the sea, and owing to the diminished pressure of the atmosphere, the yield of gas from a given quantity of coal averages there about 8 per cent, more in volume than would be obtained under precisely similar circumstances in a works nearly on a level with the sea. The moisture in gas can be readily understood by our every-day experience of its presence in the air, and it is almost needless to state that this moisture increases very considerably the weight of gas. With these preliminary observations we will proceed to describe the means of ascertaining the specific gravity or weight of gas, which is always defined by comparison with a like quantity of air ; this being assumed equal to 1,000, the weight of a like quantity of gas under examination being known, its specific gravity is determined ; thus, if a given quantity of air weighs 1,000 grains, and the same quantity of gas weighs only 470 grains, then the specific gravity of the gas under examination will be 470 2CA ON WEIGHING GAS. ON WEIGHING GAS. A method of weighing gas is to exhaust a globe of known capacity, such as are sold by philosophical instrument makers, fitted with a cap and stop-cock for the purpose. By means of an air-pump the globe is exhausted of all the air it contains, when it is very accurately weighed ; this done, it is filled with the gas under examination, and re-weighed, when the difference between the weight of the globe when empty and when filled with gas will of course be the weight of the gas. In defining the value of gas, or ascertaining its specific gravity, it is always compared with a certain quantity of atmospheric air, as stated of a mean temperature of 60° Fahr. and barometric pressure of 30 inches ; under these conditions 100 cubic inches of air weigh 31*017 grains. Whatever be the capacity of the globe, the weight of 100 cubic inches of the gas can be readily calculated when the weight of its con- tents are known. Then as 100 cubic inches of air of mean temperature and pressure weigh 31*017 grains, say as 31*017 i3 to the weight of 100 cubic inches of the gas, so is unity, or the specific gravity of air, to the specific gravity of the gas. Or another method may be adopted, which is indepen- dent of the capacity of the globe, and does not require that capacity to be determined at all. Weigh the globe when filled with gas, also when filled with air, and when exhausted ; from these three separate weights, that of the air contained in the globe may be ascertained as well as that of the gas which it contains. Then the weight of the gas divided by that of the air is equal to the specific gravity. In performing the opera- tion of weighing gases, however, many precautions are neces- sary, and many niceties of manipulation must be practised ; for instance, the gas must be reduced to mean pressure and temperature, and corrections must also be made for moisture both in the gas and the air, unless the gas has been pre- viously dried, which is now the practice of the best chemists. The accompanying table, by the late Mr. Wright, gives the corrections for the bulk, or volume, of gas under various degrees of pressure and temperature, the standard adopted being barometric pressure of 30 inches, and temperature of 60°, which on reference is 1,000. First, referring to the pressure, we find by this table that 933 feet of gas at 30 ON WEIGHING GAS. 265 inches would expand and become 1,000 feet when the baro- meter is at 28 inches, or 1,033 feet of gas at standard would be compressed into 1,000 feet when the pressure of the barometer was 31 inches. Then as regards temperature, it would require 1,058 feet of gas of standard temperature to occupy the space of 1,000 feet when the thermometer is at 32°. Or 944 feet of gas at 60° would become expanded to 1,000 feet when the temperature becomes 90°. Therefore the table is of the greatest import- ance in determining the precise value of gas under all the ordinary variations of pressure and temperature. Mr. Wright also contrived an ingenious apparatus for taking the specific gravity of gas by means of a balloon capable of containing when full 1,000 cubic inches of gas. This is sometimes gauged by a ring, so to limit the size of the balloon, but a more accurate way is to measure the gas through a good dry meter (the wet meter being objectionable on account of the moisture therefrom intermixing with the gas), when the specific gravity can be ascertained with remarkable accuracy. There is great prejudice against the use of dry meters for experimental purposes, arising from the supposition that they are not capable of measuring very small particles ; this, how- ever, is erroneous, as a well-constructed dry meter should measure the most minute quantity with the greatest accuracy. The following are Mr. Wright’s directions for performing the experiment, with the table which he has compiled for correcting the temperature and pressure of the gas accord- ing to the standard generally made use of, as already stated. Expel the air from the balloon by folding in the form in which it is first received, ascertain the weight of the balloon and car, fill the balloon with gas, insert the stopper, and put as many grains * in the car as will balance it in the air ; adc the number of grains which it carries to the weight of the balloon, and deduct the amount from the tabular number corresponding to the degree of temperature indicated by the thermometer, and the pressure indicated by the baro- * The weights used are not troy grains, 100 of them being equal to 30*5 grains troy. They are each equal to a cubic foot of air, when the barometer is at 30 inches, and thermometer at 60°. 266 ON WEIGHING GAS. meter; divide the result by the tabular number due to the temperature and pressure of the gas, to ascertain which allow the gas to blow upon the bulb of the thermometer until the mercury is stationary, and the three first figures are the specific gravity. Example 1. £ss£? °' ““ Si’s: j T > bni " »«»>■« «• Temperature of gas . 56° \ Barometer always the > Tabular number 958. same as air . . 28 ’5 in. ) Weight of balloon and grains in car, 560. 932 Tabular number for the air. 560 Weight of balloon, &c. Tabular number for the gas 958)3720(388 Specific gravity. 2874 8460 7664 7960 7664 296 Example 2. 2335 ? ? lh * Temperature of gas . 62° J Barometer always the > Tabular number 1013. same as air . . 30 5 in. ) Weight of balloon and grains in car, 560. 1058 Tabular number for the air. 560 Weight of balloon, &c. Tabular number for the gas 1013)4980(491 Specific gravity. 4052 9280 9117 1630 1013 617 Note. — This table will also be found convenient for correcting the quantity of gas made, as indicated by the station meter ; the quantity, being divided by the tabular number due to the temperature and pressure, will give the amount as if the gas bad been at 60° Fahrenheit and 30 inches barometer. ON WEIGHING GAS. 2G7 TABLE POIl CORRECTIONS OP TEMPERATURE AND PRESSURE OF GAS. BAR. THER. 32 ° o CO 36 ° 38 ° o O to o 44 ° 46 ° 00 o o O to 28-0 98 8 984 980 976 971 968 964 960 956 952 28-1 991 987 983 979 975 971 967 963 959 955 28-2 995 991 987 983 979 975 971 967 963 959 28*3 998 994 990 986 982 978 974 970 966 962 28*4 1002 998 993 990 985 981 977 973 970 966 28*5 1005 1001 997 993 989 985 981 977 973 969 28-6 1009 1005 1000 996 992 988 984 980 976 972 28*7 1012 1008 1004 1000 996 992 988 984 980 976 28-8 1016 1012 1008 1003 999 995 991 987 983 979 28-9 1020 1015 1011 1007 ' 1003 999 995 991 987 983 29-0 1023 1019 1015 1010 1006 1002 998 994 990 986 29*1 1027 1022 1018 1014 1010 1006 1002 998 993 989 29-2 1030 1026 1022 1017 1013 1009 1005 1001 997 993 29-3 1034 1029 1025 1021 1017 1012 1008 1004 1000 996 29-4 1037 1033 1029 1024 1020 1016 1012 1008 1004 1000 29-5 1041 1036 1032 1028 1024 1019 1015 1011 1007 1003 29-6 1044 1040 1036 1031 1027 1023 1019 1015 1010 1006 29-7 1048 1043 1039 1035 1031 1026 1022 1018 1014 1010 29*8 1051 1047 1043 1038 1034 1030 1026 1022 1017 1013 29'9 1055 1050 1046 1042 1038 1033 1029 1025 1021 1017 30-0 1058 1054 1050 1045 1041 1037 1033 1028 1024 1020 30-1 1062 1057 1053 1049 1044 1040 1036 1032 1028 1023 30*2 1065 1061 1057 1052 1048 1044 1039 1035 1031 1027 30*3 1069 1064 1060 1056 ]051 1047 1043 1039 1034 1030 30-4 1072 1068 r 064 1059 1055 1051 1046 1042 1038 1034 30-5 1076 1071 1067 1063 1058 1054 1050 1045 1041 1037 30-6 1079 1075 1071 1066 1062 1057 1053 1049 1045 1040 30*7 1083 1079 1074 1070 1065 1061 1057 1052 1048 1044 30-8 1087 1082 1078 1073 1069 1064 1060 1056 1051 1047 30-9 1090 1086 1081 1077 1072 1068 1063 1059 1055 1051 31-0 1094 1089 1085 1080 1076 1071 1067 1063 1058 1054 N 2 268 ON WEIGHING GAS, TABLE FOR CORRECTIONS OF TEMPERATURE AND PRESSURE OF GAS ( continued ). RAR. THER. 52° 54° 56° or oo 60° 62° 64° 66° 68° 70° 28-0 948 944 941 . 937 933 930 926 922 919 915 28T 952 948 944 940 937 933 929 926 922 919 28:2 955 951 947 944 940 936 933 929 925 922 28-3 958 955 951 947 943 940 936 932 929 925 28*4 962 958 954 950 947 943 939 936 932 928 28-5 965 961 958 954 950 946 943 939 935 932 28*6 969 965 961 957 953 950 946 942 939 935 28-7 972 968 964 960 957 953 949 945 942 938 28*8 975 971 968 964 960 956 952 949 945 941 28-9 979 975 971 967 963 960 956 952 948 944 29*0 982 978 974 970 967 963 959 955 952 948 29*1 985 982 978 974 970 966 962 959 955 951 29-2 989 985 981 977 973 969 966 962 958 954 29-3 992 988 984 981 977 973 969 965 961 957 29-4 996 992 988 984 980 976 972 969 965 961 29-5 999 995 991 987 983 979 976 972 968 964 29-6 1002 998 994 991 987 983 979 975 971 968 29*7 1006 1002 998 994 990 986 982 978 975 971 29-8 1009 1005 1001 997 993 989 986 982 978 974 29-9 1013 1009 1005 1001 997 993 989 985 981 978 30-0 1016 1012 1008 1004 1000 996 992 988 984 981 30-1 1019 1015 1011 1007 1003 999 995 992 988 984 30-2 1023 1019 1015 1011 1007 1003 999 995 991 987 30*3 1026 1022 1018 1014 1010 1006 100£ 998 994 990 30-4 1029 1025 1021 1017 1013 1009 1005 1002 998 994 30-5 1033 1029 1025 1021 1017 1013 1009 1005 1001 997 30-6 1036 1032 1028 1024 1020 1016 1012 1008 1004 1000 30-7 1040 1036 1031 1027 1023. 1019 1015 1011 1007 1004 30-8 1043 1039 1035 1031 1027 1023 1019 1015 1011 1007 30-9 1046 1043 1038 1034 1030 1026 1022 1018 1014 1010 31*0 1050 1046 1042 1037 1033 1029 1025 1021 1017 1013 ON WEIGHING GAS. 269 TABLE FOR CORRECTIONS OF TEMPERATURE AND PRESSURE OF GAS [continued). BAR. THER. 72° 740 76° 78° 0 0 CO 82° 84° 86° 0 00 CO 1 90° 28*0 912 908 905 901 898 895 891 888 885 881 28T 915 912 908 905 901 898 894 891 888 884 28*2 918 915 911 908 904 901 898 894 891 888 28-3 922 918 914 911 908 904 901 897 894 891 28*4 925 921 918 914 911 907 904 900 897 894 28*5 928 925 921 917 914 910 907 904 900 897 28-6 931 928 924 921 917 914 910 907 903 900 287 935 931 927 924 920 917 913 910 907 903 28*8 938 934 931 927 924 920 917 913 910 906 28-9 941 937 934 930 927 923 920 916 913 910 29*0 944 941 937 934 930 926 923 919 916 913 29T 948 944 940 937 933 930 926 923 919 916 29*2 951 947 944 940 936 933 929 926 922 919 29-3 954 950 947 943 940 936 933 929 926 922 29*4 957 954 950 946 943 939 936 932 929 925 29-5 961 957 950 946 942 939 935 932 928 29*6 964 960 957 953 949 946 942 939 935 932 29*7 967 963 960 956 952 949 945 942 938 935 29-8 970 967 963 959 956 952 948 945 941 938 29*9 974 970 966 963 959 955 952 948 944 941 30-0 977 973 969 966 962 958 955 951 948 944 30-1 980 976 973 969 965 962 958 954 951 947 30-2 983 980 976 972 969 965 961 958 954 950 30*3 987 983 979 975 972 968 964 961 957 954 30-4 990 986 982 979 975 971 968 964 960 957 30-5 993 989 986 982 978 974 971 967 963 960 30-6 996 993 989 985 981 978 974 970 967 963 30-7 1000 996 992 988 985 981 977 973 970 966 30-8 1003 999 995 991 988 984 980 977 973 970 30*9 1006 1002 998 995 991 987 984 980 976 973 31*0 1009 1006 1002 998 994 990 987 983 979 976 270 CORRECTIONS FOR MOISTURE IN GAS. The preceding table contains no correction for moisture, nor is this commonly considered necessary in practice if the experiments are made in a dry room at some distance from the gasholder, or vessel in which the gas has been standing over water ; nevertheless a few words will be said on the subject, so that if desirable the proper corrections may be made. CORRECTIONS FOR MOISTURE IN GAS. It has been ascertained by careful experiments that 100 cubic inches of permanent aqueous vapour, corrected for a temperature of 60° and a mean pressure of 30 inches, weigh 19*29 grains. If we then know the proportion of aqueous vapour absorbed by gas at different temperatures when in direct contact with water, we shall have the means of deter- mining, from the known volume and weight of the moist gas, the volume and weight of the dry gas. Professor Faraday, in his “ Chemical Manipulations/’ gives the follow- ing table, which is founded on the experiments of Dr. Dalton and Dr. Ure, and which ranges through most of the tempe- ratures at which gas is likely to be weighed : — Table showing the Proportion by Volume op Aqueous Vapour EXISTING IN ANY GrAS STANDING OYER OR IN CONTACT WITH "Water at the corresponding Temperatures, and at a mean Barometric Pressure of 30 inches. Temp. Proportion of vapour in 1 volume of gas. Temp. Proportion of vapour in 1 volume of gas. i . Temp. Proportion cf vapour in I volume of gas. deg. 40 •00933 deg. 54 •01533 deg. 68 .02406 41 •00973 55 *01586 69 •02483 42 •01013 56 •01640 70 •02566 43 •01053 57 •01693 71 •02653 44 •01093 58 •01753 72 •02740 45 •01133 59 •01810 73 •02830 46 •01173 60 •01866 74 •02923 47 •01213 61 •01923 75 •03020 48 •01253 62 •01980 76 •03120 49 •01293 63 •02000 77 •03220 50 •01333 64 •02120 78 •03323 51 •01380 65 •02190 79 •03423 52 •01426 66 •02260 80 •03533 53 •01480 67 •02330 CORRECTIONS FOR MOISTURE IN GAS. 271 It is easy from this table to determine the quantity or aqueous vapour present in gas of any given temperature which is standing over water, or which has been in contact with water ; for it is only necessary to multiply the volume of the moist gas by the number corresponding to the tem- perature, in order to find the volume of aqueous vapour which is present. Suppose 120 cubic inches of moist gas at a temperature of 70° weighing 22 grains under mean barometric pressure, then the volume of vapour present is equal to 120 X *02566 = 3*079 cubic inches. This volume corrected to a temperature of 60° will have to be deducted from the whole volume of gas corrected to the same temperature. Now 120 cubic inches at 70° are equal to 120 x 460 + 60 460 + 70 117*74' cubic inches at a temperature of 60°. Hence 117*74 — 3*079 = 114*66 cubic inches, the volume of dry gas at mean temperature. Then to find the weight of this volume of dry gas w^e must de-duct from the whole weight of 22 grains the weight of 3*079 cubic inches of aqueous vapour, which is equal to 3*079 X *1929 = *5939 grains. Hence we have 22* — *5939 = 21*4061 grains as the weight of 114*66 cubic inches of dry gas. From this it follows by simple proportion that 100 cubic inches of the dry gas corrected for temperature and moisture will weigh 21-4061 X 100 114*66 18*67 grains. Then as 100 cubic inches of air at mean temperature and pressure weigh 31 grains, the specific gravity of the gas will be 18*67 31 = *602. There are some advantages in operating on the moist gas, because the volume can be measured before passing it into the globe in which it is weighed ; and in this case no error will be made even if the globe be not perfectly exhausted,. 272 CORRECTIONS FOR MOISTURE IN GAS. or if the globe be not quite filled with gas, the only thing necessary being the increase of weight due to the gas actually admitted as measured by a graduated jar before transferring it to the globe. This measurement cannot so perfectly be made when the gas is dried beforehand, in which case the globe must be perfectly exhausted and perfectly filled with gas, when, its capacity being known, the specific gravity can be arrived at as before. The simplest method of drying gas is to pass it through a tube filled with some substance having a powerful attraction for water. The tubes used are about half an inch in diameter, and from 12 to 20 inches long. Chloride of lime will answer well as a desiccating material for gas which does not contain much ammonia. The chloride of lime should be heated and fused in an earthenware crucible, a temperature below that of visible redness being quite sufficient for the purpose; then poured upon a clean metallic or stone surface, and, as soon as it has solidified, broken up and put into stopped bottles. This chloride being divided into a mixture of large and small fragments is to be introduced rapidly into the tube, until the latter is nearly full ; the apparatus is then ready for use. The tube may be connected with the jar, gasholder, or other vessel containing or evolving the gas, or in any con- venient way ; and so much gas should be passed through as effectually to expel all the common air before the globe or vessel to be filled with the dry gas be attached. That being lone, the gas should be allowed to pass slowly, 100 cubical inches having from 10 to 20 minutes allowed for pass- ing through such a tube as that described, though if tho period be lengthened no injury is occasioned. If the tube be of smaller diameter, more time should be proportionably allowed. Chloride of lime will not answer for ammonia, or for sul- phurous and some other acid gases. Potash, or carbonate of potash, answers perfectly well for ammonia, but not for acid gases. Sulphuric acid is a very excellent desiccant for many gases, and may be used in a tube by first curving the tube, then filling it with fragments of glass or rock ON THE BROMINE TEST. 273 crystal, and afterwards pouring in so much concentrated oil of vitriol as shall moisten the fragments but not cause obstruction to the passage of the gas. By moving the tube a little from time to time the acid is made to pass from place to place ; it becomes mixed, and it remoistens the fragments, which from the previous quiescent state of the apparatus may have drained considerably. This substance is effectual with almost all ordinary gases except ammonia.* ON THE BROMINE TEST. There are substances which possess the property of reducing certain gases to a liquid state, — thus a solution of potash absorbs carbonic acid ; the solution of the acetate of lead absorbs sulphuretted hydrogen ; and chlorine and bromine condense the hydrocarbons existing in gas. Therefore, if a suitable graduated tube be employed, the volume of gas absorbed or condensed is known by the diminished volume of the mass. On this principle the means of ascertaining the quantity of olefiant gas, or hydrocarbons existing in gas, are determined, and its quality as an illuminating agent, under some circumstances, may be defined. The method of ascertaining the amount of condensation produced in coal gas by the addition of a single drop of bromine, is now much preferred to the use of chlorine, which presented some difficulties in estimating the volumes to be mixed. The chlorine test, however, in the hands of a skilful ope- rator, is a very beautiful experiment. It requires one mea- sure of chlorine gas to be passed into a jar inverted over water, and containing two measures of coal gas. This mix- ture will cause a diminution of volume in the gas, and an oily liquid will be formed by the hydrocarbons or olefiant gas uniting with the chlorine. The chlorine ought to be in excess ; and the remaining portion having been removed by the addition of a few drops of a strong solution of potash, the diminution of volume which the coal gas has sustained will * Faraday’s “ Chemical Manipulations,” p. 390. N 3 274 ON THE BROMINE TEST. be a measure of its value, by indicating the proportion of olefiant gas contained in it. For the purpose of testing gas with bromine a glass tube is used about 3 feet long and half an inch diameter inside. This is closed at one end and bent at the other into a small semicircle, so that the straight part of the tube is about 33 inches long, the remaining 3 inches being occupied by the bend. The straight part of the tube is graduated into hundredths towards the closed end as far as twenty-five divisions, or one-fourth of the length; this graduation serving to show the diminution in the volume of gas effected by the bromine. The tube is to be filled with water, and the curved or open end placed over an orifice from which the gas is allowed to flow. After passing up through the water the gas begins to displace the latter, and must be allowed to do so till the gas exactly fills the tube from the zero division or the beginning of the graduation to the top of the tube. The curved end of the tube remains filled with water, which acts as a seal and prevents the escape of gas. It is then necessary to add a few drops of a solution of potash to remove any carbonic acid which may be in the gas. A portion of bromine about the size of a small pea is dropped into the open end of the tube, and the thumb being placed firmly on this open end, the tube is to be shaken several times in order to bring the bromine into perfect contact with the gas. After this the thumb may be withdrawn under water, and a few drops of a solution of potash added, in order to remove from the tube the vapour of bromine contained in it. To effect this removal the thumb is to be again pressed on the open end of the tube, and its contents agitated by again inverting the tube once or twice. The open end of the tube is then to be placed in water, which will now rise considerably above zero, and after remaining at rest for some time, the height of the water may be read off on the graduated part of the tube. The division so read off will of course represent the conden- sation of the gas in parts of 100. Some of the inferior gases are not condensed by bromine to the extent of more than 3 or 4 per cent, while some of ON THE COMPARISON OF GASES. 275 the rich and highly illuminating cannel coal gases are con- densed as much as 30 per cent. This process cannot, however, be regarded as satisfactory under all conditions, inasmuch as it only gives the volume of the hydrocarbons, without their density; and it follows that if the one be considered without the other, the experiment can have no value. With caking-coal gas, each per centage of condensation or diminished volume is considered equal to three candles, so that 4 per cent, condensation would indicate twelve candles ; but an admixture of cannel gas renders the experiment en- tirely worthless. Cannel gas, when examined by the process, gives no positive result, without the specific gravity of the condensed matter be ascertained, when, the volume and weight being known, the value of the gas is determined. Therefore, under some circum- stances, the bromine test cannot be relied on ; and, although exceedingly beautiful in operation, it must give place to other and more definite means of estimating the illuminating power of gas. ON THE COMPARISON OF GASES BY MEANS OF THE PHOTOMETER. The method of estimating the illuminating power of gases in measures of which the unit is a single wax candle con- suming a known weight of wax per hour, is a test of great beauty and simplicity. By many of the most experienced gas engineers this test of the value of a gas is preferred to all other methods of comparison. It has been justly said that the specific gravity of a gas is not a correct test of value, because this may be due to the presence of carbonic acid ; but when the actual lighting power is tried by the photo- meter, if the standard should fall short of that which might 1 e expected from the specific gravity of the gas, then the presence of carbonic acid may be fairly suspected. The earliest method of comparing the lighting power of gas with that of candles, or any other standard, was that pro- posed by Count Rumford, and commonly known as the method of shadows. For this purpose a simple apparatus was 276 ON THE COMPARISON OF GASES. designed, and named after its inventor, the Rumford pho- tometer. This consists simply of a black box opened at each end, which ends were presented to the two lights under ex- amination. In this box a white space is painted to receive the shadows made by intercepting the light from a gas-burner and a candle, placed at such distances as to give shadows of precisely the same intensity. When the distances are so adjusted that the shadows are precisely similar in colour or intensity, then the lighting powers of the two flames are proportionate to the squares of their distances from the sub- stance intercepting the light and throwing the shadow. Thus, if the gas-burner be 9 feet and the candle 3 feet from the centre of the photometer, the squares being 81 and 9, their light will be in the proportion of these numbers to each other, the gas giving the light of nine candles. Or if the gas give a shadow equal to that of a candle placed at one-fourth of the distance, it is equal to sixteen candles, and so on. In general terms, let d be the distance from the candle to the intercepting body of photometer, and x the distance from the gas-burner to the same photometer, then when the shadows are alike, the illuminating power of the gas is equal to the square of x divided by the square of d , that of the candle being unity. When the distance of the candle is fixed at 10 inches, it will only be necessary to cut off two figures from the square of the gas-burner’s distance to find the number of candles to which the ,gas is equal. Hence the distance of the gas-burner being 24 inches, while that of the candle is 10 inches, then the square of 24 is equal to 576, and the light given by the gas is 5*76 candles. Although the method of comparison by shadows is still highly spoken of by some who have practised it for many years, and have acquired a habit of great accuracy in dis- criminating the depth of shadows, it is not in general use at the present time, the Rumford photometer having been super- seded by an instrument invented by Professor Bunsen, of Marburg, and first introduced in this country by Dr. Lyon Playfair, who described it to Mr. King, of Liverpool. The comparison made by the Bunsen photometer is not one of shadows, but is a comparison of transmitted light passing ON THE COMPARISON OF GASES. 277 through a transparent surface, with reflected light striking on an opaque surface. This comparison is made by interposing between two lights a disc of paper with an annular space made transparent, and surrounding a small part in the centre which is opaque. Now, if any light whatever be placed behind a disc of this kind, the transparent ring will be illu- minated, while a dark circle will appear in the centre. If another light be now placed in front of the paper at such a distance as to cause the reflection from the opaque circle to be greater than that transmitted through the transparent ring, the centre space will be more illuminated than the ring. Again, if the light in front be placed at such a distance that the reflection is less than the transmitted light, then the central spot will appear darker than the ring, and be dis- tinctly visible. When, however, the light is so placed that the light reflected and that transmitted are exactly equal, then the centre spot is invisible, as the whole surface of the paper appears alike, and no difference is observed between the central spot and the annular space which surrounds it. When this condition is obtained the lights are to each other as before, in the ratio of the squares of their distance from the disc. Photometers made on this principle of comparing lights by means of a disc of this kind placed between them are now made by Mr. Wright and Mr. Sugg, both of West- minster, and by Messrs. Hulett and Company, who manu- facture the photometers known as Church and Mann’s. The composition at first used for making the paper trans- parent was melted spermaceti, but Dr. Fyfe recommends spermaceti dissolved in oil of naphtha till it acquires a con- sistence which is solid at natural temperatures, but is liquefied by the application of a very gentle heat, such as by holding the vessel for a few minutes in the warm hand. He applies the mixture when fluid, leaving in the centre a circle un- covered about the size of half-a-crown. After this the paper is held horizontally over a lamp, and very cautiously heated, so as to make all the inequalities disappear. Dr. Fyfe prefers the fine cream-coloured letter-paper for the purpose of the disc. 278 ON THE COMPARISON OF GASES. Fig. 66. ON TIIE COMPARISON OF GASES, 279 280 ON THE COMPARISON OF GASES. Figs. 64 to 67 show the Bunsen photometer as constructed by Mr. Wright. Fig. 64, drawn on a scale of -roth of the full size, is an elevation of the photometer : a a is a straight bar of wood carrying at one end a support for a candle, and at the other a support for the gas-burner, which can be screwed on when required. These supports are so placed that the lights are exactly 100 inches apart from centre to centre. Sometimes a meter is fixed at one end in place of the pillar e, and the burner is screwed on to a short pipe which passes up from the meter ; in other cases a flexible tube b is used for conveying the gas to the burner after passing through an experimental meter so made, that by an observation of a minute the gas consumed in an hour is indicated : c is the movable carrier supporting the disc, which can thus be placed in any position on the bar : d is the centre of the bar from which the divisions commence, the first division in the centre being marked 1 for one candle. The bar is divided into a scale towards the end where the candle is placed, which scale indicates candles and tenths of a candle, as far as nine candles. From 9 to 20 the spaces indicate half-candles, and from 20 to 36 they indicate only whole candles. Fig. 65, on a scale of ±th the full size, is an elevation of a blackened shade, which is placed over the disc in order to exclude any radiated light, and render the determina- tions on the disc more delicate. It consists of two short wide tubes made slightly conical, and united at top by a hinge, which allows them to be separated at the base. The shade is open entirely through, in the direction of its axis, and when placed over the disc, the surface of the latter is seen by the observer through the small spaces a a in the side of the shade. Figs. 66 and 67, on a sc.ale of ^th the full size, are an eleva- tion and side view of the disc and carrier. The disc is merely a circle about 4 inches diameter, inserted between two flat metal rings which are kept close by a small screw. The opaque space in the centre b is an inch and a half in diameter, and c is the transparent part surrounding it. In these figures d is the carrier, e is the divided bar, and f the pointer marking the division over which the disc stands. WEIGHT OF GAS FRODUCED FROM COAL. 281 The following table shows the distance on the scale of the whole candles up to 30 candles ; the fractional parts may be tolerably well ascertained by dividing the intermediate dis- tance. Distance of division Distance of division No. of candles. from centre of candle. Inches. No. of candles. from centre of candle. Inches. 2 . . 41*42 17 . . 19-52 3 . . . 36-61 18 . . 19-08 4 . . . 33-34 19 . . 18-67 5 . . . 30-90 20 . . 18-26 6 . . . 28-99 21 . . 17-96 7 . . , 27-43 22 . . 17-57 8 . . , 26-12 23 . . 17-25 9 . . , 25-00 24 . . 16-95 10 . . . 24-14 25 . . 16-67 11 . . . 23-16 26 . . 16-40 12 . . . 22-40 27 . . 16-14 13 . . . 21-71 28 . . 15-90 14 . . , 21.09 29 . . 15-64 15 . . 16 . . , 20-52 . 20-00 30 . . 15-41 The photometer made by Messrs. Hulett and Co., of London, has the disc always fixed at a distance of 10 inches from the candle ; this has the advantage that the beam being shorter it is more portable and occupies less space in the apartment where placed. THE WEIGHT OF GAS PRODUCED FROM COAL. In considering the quantity of gas produced from a ton of coal, the real value is determined by its volume and its specific gravity, so that the most convenient mode of ex- pressing the quantity is to give the weight of the gas pro- duced, this being a compound of the quantity and the specific gravity. The latter being known, the following rule will give the weight of any quantity. Kule. — Multiply the quantity in feet by the specific gravit}', and strike off the three right-hand figures, then multiply the remainder by the decimal *0753, then strike off the proper decimals, and the remainder is the weight in pounds. Thus, if 100 lbs of coal give 400 cubic feet of 282 TESTS FOR ASCERTAINING PURITY OF GAS. gas, of specific gravity 420 — then 420 X 400 X *0753 = 12*G5 lbs. of gas. The following comparison of the specific gravity of gas, with the illuminating power as shown by candles, is an average deduced from the results of the best experimenters : — No. of candles. Specific gravity. No. of candles. Specific gravity. 12 equal to •400 26 equal to •600 14 •425 28 ft •640 16 >> •450 30 tt •670 18 >> •475 32 ff •700 20 j) •500 34 tf •730 22 it •530 36 a *770 24 tf •560 For further details on the experiments on coal gas and the mode of analysing, the reader is referred to the ‘‘Analysis of Gas,” for practical men, by A. Wright. ON TESTS FOR ASCERTAINING THE PURITY OF GAS. The managers of many works unfortunately attach but little importance to the purification of the gas they supply ; and it is a lamentable fact that, notwithstanding the progress which the science of gas-lighting has made of late years, and the amount of practical chemical skill which has been ap- plied to the subject, there are yet many towns in England where the gas is so bad and so imperfectly purified as to be quite unfit for consumption in private houses, and where people are afraid to introduce it, well knowing its injurious effect on many articles of value exposed to its influence. This is an evil which must act seriously against the interest of any gas company, for it prevents the proper development of their business, causing continuous complaints and dissatis- faction ; and when we consider the small expense incurred in purifying, it becomes a matter of astonishment how it can possibly be neglected. By the adoption of the following tests, every manager has the means of assuring himself of the purity of the gas manufactured ; and every care should be adopted to make it of such a quality as to withstand such tests. Tests for Sulphuretted Hydrogen . — Test papers for detect- TESTS FOR ASCERTAINING PURITY OF GAS. 283 in g sulphuretted hydrogen are prepared by moistening common writing-paper with a solution of acetate of lead or nitrate of silver, the latter being the most delicate test. The gas under examination is caused to impinge on the moistened test-paper for about a minute, and should this become dark- ened in colour, it is a proof of the presence of this impurity. It may also be detected by passing the gas through solutions of either of these. Another method, sometimes practised, is to pass the gas into pure distilled water, then to add a single drop either of the acetate of lead, the nitrate of silver, or the chloride of bismuth : if any sulphuretted hy- drogen be present, it will immediately show itself by black- ening the water. Test for Ammonia . — This being an alkali, the test papers to be used must be either yellow turmeric paper, or litmus paper first reddened by solution of vinegar or any other weak acid. If the original blue colour of the litmus paper be re- stored by the gas, or the yellow colour of the turmeric be turned to brown, it indicates the presence of ammonia. Test for Carbonic Acid Gas . — Paper steeped in the blue tincture of litmus is rendered red both by carbonic acid gas and by sulphuretted hydrogen. In order to distinguish accurately which of these impurities is present, a solution may be maGe of pure barytes in the tincture of litmus. If the gas be passed into this solution and only sulphuretted hydrogen be present, no change will be produced, but should carbonic acid gas be present, a precipitate of the carbonate of barytes will immediately fall down. Carbonic acid may also be detected by causing the gas to blow or bubble through lime-water, and if this become cloudy or milky, the presence of this impurity is established. Test papers of turmeric, litmus, or acetate of lead, are to be purchased at many operative chemists in the form of small books, about 3 inches long and § inch wide, each book containing about 24 leaves. They are exceedingly conve- nient, and no works should be without them. A very useful little instrument is made by Mr. Wright, for the purpose of detecting sulphuret of carbon in gas. The presence of this compound of sulphur had long been 284 TESTS FOR ASCERTAINING PURITY OF GAS. suspected, and, as it cannot be detected by the ordinary test papers which are used, has often escaped observation. Every combination of sulphuric acid, however, being highly inju- rious in coal gas, it is important that every possible pains should be taken to remove this impurity. This apparatus is equally useful for detecting sulphuretted hydrogen or any other compound of sulphuric acid. The arrangement consists of a simple apparatus for con- densing the products of combustion from an ordinary gas flame, and of applying to the liquid so condensed a salt of barytes, which immediately precipitates the sulphur, when present in ever so small a quantity. In fig. 68, a is a small jet flame over which is a chimney, gradually contracted into a small tube, b b, half an inch in diameter, which tube is bent and carried through a metal cylinder c, about 18 inches long and 2 inches diameter. This cylinder is kept full of cold water, which is retained TESTS FOR ASCERTAINING PURITY OF GAS. 285 by means of screwed caps, g g , at each end, being pro- vided with small India-rubber washers, which make a perfect joint at each end of the tube, d is a funnel for filling the tube with water, and / is a siphon by which it overflows when the tube is full. The vapours which escape from the combustion of the gas at a pass through the tube b , in which they are condensed, and drop in the state of fluid into a glass placed to receive them, while the carbonic acid escapes at the same open end of the tube. The water which drops from the tube is generally colourless, nearly tasteless, but with a peculiar and not unpleasant odour. When a drop of the nitrate of baryta is added to the water thus condensed from the combustion of ordinary gas, a flocculent white powder immediately discolours the water, being the sulphate of baryta. This is considered by com- petent authorities the very severest test to which gas can be subjected. To obtain the whole of the sulphur present some ammonia should be placed around the jets of gas, in a vessel for the purpose. The vapour of ammonia will pass up the tube, and combining with the sulphurous acid, the whole of the sulphur compound will be condensed in the water in the form of sulphate of ammonia. Dr. Letheby employs a similar method, but has introduced an air condenser ; this is a glass vessel capable of holding about one gallon ; into this the products of combustion are conveyed, and there condensed, to be afterwards analysed. The difference between the two apparatus being, that in the former the condensation is caused by contact with water ; in the latter, by radiation or contact with the atmosphere. 286 ON THE MODE OF BURNING GAS. CHAPTER XX. ON THE MODE OF BURNING GAS. — EFFECTS OF PRESSURE, ETC. ADMIXTURE OF AIR ON GAS. — LIGHT OBTAINED. CARBURISATION OF GAS. When coal gas is ignited as it issues from a burner or orifice, its hydrogen is consumed at the lower part, produc- ing the blue flame characteristic of it, and the carbon being sufficiently heated is liberated in a solid state at the upper part of the flame, if properly consumed, where it combines with the oxygen of the atmosphere, again therewith resum- ing the state of gas as carbonic acid : and according to the degree of heat attained by the innumerable particles of carbon, so will be the amount of light emitted by the gas. Whenever the flame of gas is unduly cooled, or when the gas is intermixed with a portion of atmospheric air, or when it issues from the burners under great pressure, the light obtained from a given quantity is very materially re- duced, and when either of these contingencies is carried to an extreme, no material light is obtained from gas. To illustrate the first affirmation, I have only to call the reader’s attention to a large flame issuing from a stand pipe, frequently seen in London and other places where public works are being carried on at night. In this a volume of gas issues, giving at one moment, when the weather is calm, the light of thirty or forty candles ; but at the next instant, when a strong gust of wind blows upon it, a small blue flame only is perceptible, the gas giving no appreciable light. It may be supposed that the supply of gas is interrupted by the wind, and the loss of light due to this cause. This, however, is not the case, for experiment will prove it to be about uniform alike in the calm and under the influence of the wind ; therefore, when a flame is extremely cooled, gas gives no available light. The second affirmation, that when gas is intermixed with atmospheric air the light is diminished, is witnessed daily in igniting gas, when often an intense blue flame issues, but giving no light : this being occasioned by the admixture oN THE MODE OF BURNING GAS, 287 of air therewith. According to Dr. Letheby, the following are the proportions of light given by different quantities of air being intermixed with gas, supposing the light from gas unmixed with air to be 100 : — 2 per cent, of air in gas . Light, . . . 90 5 » )> ... 70 7 a a . . . 52 10 ... 34 20 ,, ,, ... 12 40 ... 1 50 „ „ ... 0 These results do not correspond entirely with the experi- ments of Messrs. Audouin and B6rard, already referred to, which may arise from the especial manner the gas was consumed, or perhaps from its quality. However, the per- nicious effect of an admixture of air with gas is fully demonstrated, and requires the utmost attention to avoid it either in the production, transmission, or consumption of gas. The affirmation, that the light given from gas is influenced according to the pressure with which it is emitted from the burners, requires to be illustrated by experiment ; and for the purpose let us take an argand burner, having fifteen holes of such dimensions as to permit 5 feet per hour to issue with a pressure of about *roth inch, when with ordinary gas from Newcastle coal we would obtain a light equal to about twelve candles. Now, if we reserve the same form and size of burner in every respect, but diminish the size of the holes so that a pressure of i^rths is necessary to expel the 5 feet of gas per hour, then the light will only be equal to five and a half candles ; and if we further diminish the size of the holes, so that Toths pressure will be required to expel the 5 feet, then that quantity of gas produces a blue flame, but no material light. With a fishtail burner, consuming at a low pressure 4 feet per hour, the light of seven candles may be given , but by increasing the pressure to expel 8 feet per hour from the same burner, the light is then diminished, and with 15 feet per hour there is very little light. All descriptions of burners are liable to this variation ; and it is a most important consideration to all connected with gas 288 ON THE MODE OF BURNING GAS. lighting, but more particularly to the manufacturers of burners. There is another important consideration in the consump- tion of gas, namely, its power of giving light. Gases are very variable in this respect, as the following table demonstrates. Table of Light yielded by various descriptions of Gas, when BURNED UNDER FAVOURABLE CIRCUMSTANCES, AND AT THE RATE OF 5 FEET PER HOUR. Anthracite, and some lignites, equal to from 3 to 10 Newcastle average 12 Knights wood Cannel 18 Ramsay’s „ 20 Wigan „ .20 Amiston „ 22 Lesmahago ,, 24 Boghead ,, 36 candles. a a a a a a This variation in the luminosity of different kinds of gas is due to the quantity of carbon they relatively contain, which carbon separates at the moment of ignition from the hydrogen in very minute, solid particles, and, by intermixing with the oxygen of the atmosphere, assumes a state of incandescence ; and, according to the number of these solid particles of carbon in gas, so is the amount of light to be derived from it. But it is essential for the carbon to attain the necessary degree of heat to combine with its equivalent of oxygen. In the event of the supply of this being deficient, the carbon then passes off in the solid state, distributing itself on the ceilings of apartments, the atmosphere, &c., as smoke. There- fore, for the perfect combustion of gas, the proper supply of atmospheric air requires the greatest attention. There is, however, another action takes place when the particles of carbon are cooled below the point necessary for their incandescence. In this case the carbon does not assume the solid form, but unites with the oxygen the same instant it leaves the hydrogen ; thus, as Mr. Wright observed, pass- ing from an union with one solvent (if the expression may be used), to unite with another solvent, and is completely consumed before it has been submitted to the high tempera- ture essential for the separation of the carbon. Thus for the economical consumption of gas there are ON THE MODE OF BURNING GAS. 289 various points for consideration, which, however, are resolved into two simple questions; the one, to avoid an excess of atmo- spheric air with the flame, the other, to ensure a sufficiency of this to combine with the carbon of the gas. Having attempted the explanation of the contingencies in the combustion of gas, it now becomes a question to consider the mode of obtaining the maximum of light from a given quantity. For this purpose, as a rule, the best results are obtained when the gas issues from the orifices of argand burners at about -roth inch pressure ; but fishtails and batswings, to burn advantageously, require a pressure of i%ths or -i- 0 ths. The holes of burners destined for poor gas should be large, so that the minute particles of the carbon in the gas when issuing become heated to the necessary extent to produce light. The holes of burners destined for rich gas should be small in proportion to the richness of the gas, in order that the par- ticles of carbon t may unite with their equivalents of oxygen from the atmosphere, and give light instead of passing off in the solid state as smoke. The orifices of the interior and the exterior of argand burners should be adjusted according to their relative sizes and quality of gas. Burners, whether argand, batswing, fishtail, or jet, give the maximum of light only with one particular consumption ; and this depends on the quality of the gas, — for example, the maximum of light from 12-candle gas, with an argand, is when it has 30 holes, and consuming about 7^ feet per hour. The richer kinds of gas are consumed in smaller quantities. An argand burner, with 15 holes, varies in the following extraordinary manner : — When consuming 5 feet per hour, the light is equal to 12 candles. „ diminished to 3J „ „ „ 45 „ 9i 1 *9 a a *2 a if a A ^ a 1 i. 0*9 a a x 2 a a a u “ a a a f a a a 0 ^2 a The other burners follow the same law ; for instance — A fishtail consuming 5 feet per hour, the light is equal to 10 candles. The same reduced to 3J „ „ „ 5'5 „ 290 ON THE MODE OF BURNING GAS. All burners require to be made especially for the quality of gas they are destined to consume ; therefore, a particular standard burner, or fixed rate of consumption for all classes of gas, is erroneous ; for an argand burner, which may be well adapted for burning 12-candle gas at 5 feet per hour, would be ill adapted for burning the same quantity of M or 16-candle gas, and still worse for the richer qualities. There- fore, it would appear that the Act of Parliament which defines the mode of testing the illuminating power of gas by restricting the holes of an argand to 15, and the consumption to 5 feet per hour, is prejudicial to gases of higher illuminat- ing power ; for, in the event of gas, say of a quality equal to 16 candles, being so consumed, either a large portion of it would pass off as smoke, or the holes would have to be so con- tracted in size as to prevent the quantity issuing except under an increase of pressure, both circumstances being unfavourable to the richer gas. As gas is generally employed either in places where the standard of quality is 12 candles, or in Scotland, where it is 2 4c candles, the average light yielded from each burner is about 12 candles. Perhaps, therefore, in estimating the value of gas, the correct manner would be for the richer gases to be brought to the standard of the poorer, by defining the quantity necessary to give the light of say 12 candles, which might be taken as a standard. According to this method, and adopting the table already mentioned as correct, 5 feet of Newcastle gas 31 „ Knightswood „ 2j „ Lesmahago „ 1J „ Boghead „ Of course the intermediate quantities could be readily defined according to the required standard of gas. It is generally believed that for poorer gases the argand burner is superior to the others, and for richer gases that the fishtail is the most suitable. The latter has the great dis- advantage that, under excess of pressure, gas passes off imper- ceptibly without giving light. Notice of this is given with the argand and batswing by the smoke engendered, when the evil may be corrected. ' would be ‘equal to the standard, or 12 candles. CARBURISATION OF GAS. 291 No general rule can be laid down for tlie sizes of the holes of the various burners, — this must be obtained by experi- ment, by regulating the holes so as to cause the required quantity to issue at the low pressures already referred to. The external and internal supply of air to the argand, as also the length of the glass chimneys, require great care in defining them. The slits of batswing burners should be always at least as deep as the diameter of the nib, so to form a good deep flame. The angles of the holes of fishtails require particular attention in drilling ; in experimenting, the results of these are very variable. CARBURISATION OF GAS. There is a method of enriching gas by causing it to pass, just previously to its combustion, through the vapours of car- bonaceous liquids, as naphtha 7 , spirit of petroleum, &c., whereby additional particles of carbon are communicated to it, and held mechanically in suspension for a brief period until ignited. This process is called carburisation. This system was first patented by Mr. Lowe in 1831, when he proposed to produce carbonic oxide, and enrich it with “ the vapour of essential oil (liquid hydrocarbons) or other illuminating material,” and the following year the same gentleman patented the means of “ increasing the illuminating powers of coal gas, by impregnating it with the vapours of naphtha, commonly called spirit of coal tar, or with any other hydrocarbonaceous liquid, by any convenient method.” Since that period various patents have been obtained from time to time for analogous processes — these being for com- bining the volatile hydrocarbons with atmospheric air, hydrogen, and other gases ; but the only manner of applying the system economically is, as proposed by Mr. Lowe, by intermixing these vapours with gas. Some years ago this was tried on an extensive scale, under the directions of the patentee ; and although gas was at that period twice its present price, it did not succeed. Within the last three or four years the same principle has been revived with all pretensions to originality, and it must be admitted that great efforts have been made to render it o 2 292 CARBURISATION OF GAS. successful ; for the hydrocarbon liquid is prepared expressly for the purpose, the apparatus employed are probably much superior to those formerly in use for the object, and there is, moreover, greater confidence in the issue ; but there still remains a strong doubt as to its ultimate success. The main difficulty existing against the carburisation of gas is the irregular evaporation of the liquid ; a portion of which, when first placed in the carburating vessel, is remarkably volatile, and passes off in abundance, requiring burners with small holes to prevent the formation of smoke. By degrees, when the most volatile vapours have evaporated, the gas in consequence not being enriched, a difficulty arises from the smallness of the burners, which, as already explained, give, for the quantity of gas consumed, a very diminished light. I subjoin an account of two experiments made in order to ascertain the rate of evaporation of liquid hydrocarbon. The material chosen was the spirit of petroleum, as light as it could be procured, being about 700 specific gravity. A portion was placed so as to fill a test-tube 4 inches long and half an inch wide, having a scale of the same length- attached to it, and divided into fractional parts of inches, for the pur- pose of appreciating the amount of evaporation. The first hour the evaporation was |th of an inch, or -^nd part of the whole; the second hour it was about y^th of andnch; and at the end of twenty -four hours was fths of an inch. The second day the evaporation was less than an inch, and at ihe end of fourteen days it amounted to inches, and in a month had increased to nearly 3 inches. Continuing the experiment, at the end of four months, there still remained J an inch, or ^-th of the whole of the liquid, which was highly carbonaceous, but not volatile. The temperature of the apartment in the meantime had varied from 45° to 75° Fahr. The other experiment was with 3 lbs. of the same material placed in a suitable vessel in such a manner as to expose a large surface for evaporation ; and on passing atmospheric air therethrough by means of a motive-power meter, a very large and rich flame, giving off abundance of smoke, was the result. This at the commencement, when adjusted to 5 feet per hour, gave a light equal to sixteen candles, but speedily CARBURISATION OF GAS. 293 the flame became perceptibly less ; in a short time it was diminished to a remarkable extent ; after twenty -six hours merely a bine light was obtained, and at the end of forty- eight hours no flame whatever existed, as all the volatile constituents at the temperature of the atmosphere had evapo- rated ; on reweighing the residue, barely one-half of the total quantity had been available. This clearly demonstrated how easily people may be deceived by a carefully prepared experi- ment ; for, at the commencement, the air was so highly charged with carbon as to occasion the greatest surprise, but as this was of such short duration, on account of the very small quantity of the highly volatile material, the experiment was very de- ceptive, and the process of carbonising the air utterly useless. These experiments are highly instructive as regards the carburisation of gas ; they show the great irregularity in the evaporation, also that a portjon of the liquid will not evapo- rate with sufficient rapidity under ordinary temperatures, and they show that a portion does not evaporate. If, on the contrary, the liquid evaporated regularly, even although it might require a comparatively high temperature for the purpose, then the carburisation of gas would be a very valuable adjunct to gas-lighting, as it would give to ordinary gas all the advantages of cannel, producing less heat for a given quantity of light, securing better ventilation, and the agreeable glow produced by the light of rich gas, which is an advantage much to be desired. There are, however, several firms established in London and elsewhere for carburating gas; they supply the appa- ratus and liquid; they undertake the exchange of the non- volatile for the volatile liquid ; and, indeed, attend to the entire process, taking all trouble and responsibility from the gas consumer who adopts the system. The process of carburisation was tried for one or two years on the public lamps in the City of London ; and, according to the estimates of the projectors, a considerable economy was to be effected, together with a great increase of light. To obtain these advantages, it was necessary to change the ordinary burners, consuming o feet per hour, and replace them by others consuming only 3 feet, which ol 294 RESIDUAL PRODUCTS FROM course diminished very materially the account of the gas company ; but, as the sequel will clearly prove, was not an economy. The carburising apparatus being placed in the lanthorns, were unsightly, besides throwing great shadows. The gas at one period, when supplied with fresh naphtha, issued with a smoky flame, rendering in a single night the glasses dirty and obscure ; but in the course of a short time the naphtha was useless, when, on account of the very small burners, the gas was consumed under a great disadvantage, and the light given was diminished to a serious extent. After a long trial it was renounced, on account of the difficulties it possessed and the absence of the economy anticipated. CHAPTER XXI. THE RESIDUAL PRODUCTS FROM THE DISTILLATION OF COAL,. COKE. The most important commercial commodity of these is the coke, which is an excellent fuel for household purposes, and much used in the arts and manufactures. The breeze or small of this is generally sold for the purpose of brick- making, but where fuel is dear it is often intermixed with a small portion of tar, and subjected to great pressure in suitable moulds, and so formed into blocks or bricks. These are after- wards placed in ovens and submitted to a moderate degree of temperature, in order to expel the volatile matter, as water and naphtha, when a very good artificial coal is produced. The coke obtained from caking coal is much superior to that from canned coal ; although the latter is very compact in its nature, it is very small, and comparatively possesses little value. The coke from cannel coal is sometimes reduced to powder, and intermixed with tar, compressed, and evaporated, and makes a very good substitute for charcoal, and is called by the French u charbon de Paris ,” Paris charcoal. The coke from Boghead cannel is useless as fuel, but is sometimes employed as a deodorising agent. DISTILLATION OF COAL. 295 TAR. Although not the most valuable, this is the most interesting of the residual products from coal. As already demonstrated, when the retorts are at a low heat this is produced in abun- dance, and probably with very careful manipulation coal could be carbonised without any material quantity of tar being produced. Among the first attempts to profit by this residue, was one to distil and convert it into gas, and the experiments connected therewith were sufficiently satisfactory to induce a large ex- penditure to carry it into practical operation ; but this, when- ever attempted, has always terminated in failure. The diffi- culties attending the operation are various : the tar cannot practically be decomposed with the required regularity ; it speedily obstructs the ascension pipes from the retorts with a solid mass of pitch ; the gas when produced from it has a great tendency to form itself into naphthaline, which stops the mains ; and it is also believed that it does not chemically combine with gas produced in the ordinary manner, and in consequence is deposed in its passage through the pipes. With these difficulties, the distillation of tar for the produc- tion of gas has for some years been abandoned. The products from coal tar are very numerous ; by careful distillation it yields naphtha suitable for burning in lamps, or for dissolving India-rubber, making varnish, &c. ; benzole is also obtained from it ; this is useful for extracting oils and grease from woollens, and a later residue of the distillation of tar is the dead or heavy oil much used for preserving railway sleepers and other timber exposed to the action of the soil and atmosphere. Amongst the other volatile results is paraffin oil, used very extensively in lamps, also an excel- lent oil for lubricating machinery. Paraffin tor candles, ex- celling for whiteness and beauty the best wax, is also extracted from tar. The various dyes known as magenta, aniline, and rosoline, are all obtained from gas tar, and according to the opinion of many chemists much of the worth of this important material remains to be discovered. The volatile parts of tar being expelled, pitch, used as a 296 RESIDUAL PRODUCTS FROM DISTILLATION OF COAL. substitute for asphalte, is obtained, which is employed for paving, or rendering walls or floorings impermeable to mois- ture. The pitch upon being distilled in suitable retorts gives off the best dead oil for preserving timber, and a very excellent coke for foundry purposes is produced, this being exceedingly compact and hard, and does not possess the least sulphur, the presence of which is always injurious to iron when smelted. AMMONIA. This is also an important residue in the distillation of coal. It is sometimes obtained in the manner already described in Mr. CrolFs process, at other times taken direct from the con- denser to be manufactured ; but more generally the liquid of condensation is concentrated by being pumped repeatedly over and over again into the scrubbers, where it absorbs the ammonia from the gas, and when sufficiently saturated is withdrawn and manufactured, so by this means serves as a purifying agent, and at the same time becomes more valuable. The simplest mode of manufacturing the ammoniacal liquor is to put slacked lime into a boiler, which is after- wards charged with the liquor, and when heat is applied the vapours of ammonia are caused to pass over into a vessel containing sulphuric acid, and this when neutralised is eva- porated and produces sulphate of ammonia, of which there is a very large demand for agricultural and other purposes. This process is adopted by many works at the present time. Volatile alkalies, the carbonate of ammonia, muriate of ammonia, or sal-ammoniac, as well as all the other compounds, are produced from the gas-works’ residues. Trials have been made to prepare Prussian blue and madder dye therefrom ; the first has been carried into operation, but does not produce the same brilliancy of colour as that ordinarily found in com- merce. WASTE LTME FROM PURIFIERS. The residue obtained from the wet lime purifiers has such a disagreeable odour that even its transport through the streets is the source of serious annoyance. It has been pro- posed to extract the sulphur from this, as well as the dry EXPLOSIONS OF GAS. 297 lime, by roasting it in ovens; but all who have adopted it agree that the system is not profitable. The wet lime residue is disposed of generally by mixing it with loam for luting the retort doors, for which purpose it is suitable. The dry lime sometimes finds a ready sale, being in some descriptions of ground very valuable as a fertilising agent. The residue from the oxide of iron purification is generally repurchased by the firms supplying the material, who, it is stated, derive considerable advantage from it. CHAPTER XXII. EXPLOSIONS OF GAS. When lighting by means of gas was first proposed, the fears of explosions were the strongest arguments against its adop- tion, and several scientific men of the period attempted to reduce these casualties to a positive law, by asserting that a gasholder containing 15,000 feet of gas would in exploding be as destructive as ten barrels of gunpowder. As a further proof of the slight knowledge of the nature of gas at the time, Sir William Congreve, with other learned gentlemen, when acting as a royal commission of inquiry on the subject of gas explosions, recommended that gasholders should be exceed- ingly limited in their dimensions (not to surpass 6,000 cubic feet each), and, further, that they should be surrounded by strong walls, to confine the disastrous effects of explosion should it occur. We can look with satisfaction to the advancement science has made in connection with this subject, for now we know, instead of gas being so terribly destructive, that when un- mixed with atmospheric air or oxygen, it is as harmless as regards explosion as the water in the tank beneath it ; and if it were possible to insert a lighted torch, or taper, into a holder containing gas, instead of the gas exploding, the flame would be extinguished. In other words, gas unmixed with oxygen suffocates flame, and in this state cannot ignite or explode. o 3 298 EXPLOSIONS OF GAS. That explosions by gas have occurred, and do sometimes even now happen, is well known, but these have been, and are, so remarkably few in number, that the extraordinary safety of gas lighting is as fully established as the safety of railway travelling under the most careful supervision ; how- ever, by treating on these accidents, and describing their causes, is to adopt the proper step to prevent them. Explosion is an instantaneous ignition of a mass, and that mass may be solid or gaseous ; thus, a mixture of charcoal, sulphur, and nitre in certain proportions, and prepared in a particular manner, form gunpowder, which ignites instanta- neously, and the increased volume, occasioned by the solid assuming the gaseous state, is the cause of the force or power attending the combustion. There are numerous other solid compounds even more explosive than gunpowder, but the simple mention of this will be sufficient as example. Certain gases, like the solids, when intermixed in due proportion, are likewise capable of instantaneous combustion ; for instance, hydrogen when intermixed with oxygen, as before stated, in the proportion, by volume, of two of the former and one of the latter, ignites, producing explosion ; and coal gas when combined with air in certain proportions is also explosive, this being due to the hydrogen and carbon composing it entering into combination with the oxygen of the atmosphere, producing water and carbonic acid gas ; and the nearer they approach to the proper proportions for the perfect formation of these compounds, the greater is the force of explosion. A mixture of seven parts of air and one of gas is considered to be the most explosive compound, but this must depend on the quality of the gas. Mixtures of less than three of air to one of gas, or more than eleven of air and one of gas, do not explode. Explosions from gas are exceedingly rare. By a Divine ordinance, the odour arising from gas is generally so repul- sive as to awaken in the minds of the most callous a desire to avoid the inconvenience, and in so doing the danger is averted. However, there are circumstances where this notice by odour is not manifested, as where from the light- ness of the compound it ascends in the atmosphere above ; EXPLOSIONS OF GAS. 299 but when in dwellings or other buildings the slightest odour of gas is noticed, it should always be attended to. At one period or other, in some of the largest cities of the United Kingdom, as well as those of the Continent, gas- works have been the scenes of explosions. This has often arisen from a new gasholder, when nearly terminated and ready for use, having, from a very simple oversight, been communicated with the manufacturing apparatus; and it has afterwards happened that through a leaky valve allowing the gas to pass, or perhaps by some careless person thoughtlessly opening the valve, the gas has entered, intermixed with the air in the holder, and the accidental production of a light has caused the disaster. Therefore, when new holders are con- structed they should either not be communicated, with the manufacturing apparatus until quite terminated, or the pipes should be “ logged,” or sealed with water, so that no gas can possibly enter until quite ready for use. But explosions of this nature have occurred when the holder was being first filled with gas ; one of the most remarkable took place a few years ago, by which the engineer was killed. This arose from a defect in the construction, and want of ordinary caution on the part of the unfortunate suf- ferer. The facts are simple, for the holder on being charged with gas at the commencement of the operations contained a considerable quantity of air, the two forming an explosive compound, and by a singular fatality it happened that the holder was so far bound, or set, as not to give any pressure. The engineer, desirous of judging the quality of gas, very imprudently tried it at an open orifice of about £ inch dia- meter; the consequence was, the flame entering, the explo- sive compound in the holder ignited, and produced the disaster. Had the gas been tried by an argand or fishtail burner the accident would not have occurred, the holes in these being too small to permit the flame to enter. Explosions have taken place in station meters when newly erected, just previously to their use, this arising from causes already mentioned — by leaky valve, or by unnecessary meddling on the part of the workpeople. On one occasion which came under the writer’s notice, a calamity of this kind 300 EXPLOSIONS OF GAS. occurred from the mixture taking fire through the meu making the joint with overheated lead. And this suggests the varied opinions as to the possibility of a spark igniting gas. The general opinion is that gas cannot be ignited by that means ; and, indeed, it is difficult to be done, but by chance a spark may be produced of sufficient heat to inflame gas. Accidents have frequently occurred when laying mains ; often occasioned by a bladder-valve, which has permitted a small portion of gas to pass into the main beyond it, where the explosive compound was formed, and by the merest hazard a neighbouring light has produced the calamity ; therefore, in laying mains, when practicable it is always better to have a sheet-iron temporary valve, which is done by having the spigots of two pipes together where the stoppage is desired, and a thin sheet of iron between them, which may be clayed or cemented round to prevent the leak- age of gas. The plate can be removed when requisite, and a temporary or permanent joint made with a running socket. An erroneous impression exists that if a gasholder were to be rent by accident, and the gas ignited, whenever the holder touched the ground, and there being no pressure, that the contents would explode. This is incorrect, for, no matter the size of the opening, when the pressure ceased the gas would be extinguished ; but from this moment danger would com- mence, for a portion of the gas remaining in the crown would gradually issue, and air take its place, so by degrees an explosive compound would be formed. An explosive compound of gas when under pressure only ignites at the exterior of the pipe ; but if the pressure be taken off, the flame enters, and it explodes. In illustration of these assertions, I will relate a few expe- riments entered into by myself in order to be convinced of some of the circumstances under which explosions take place. The most suitable and available vessels for the purpose were old tin-plate meter cases of the larger sizes. These were entirely closed except at the outlet and the bottom, or emptying plug. In the first, a 50-light, the gas was allowed to flow through for a considerable time, when the bottom plug was replaced and a light applied to the outlet. The gas then burned with a EXPLOSIONS OE GAS. 301 flame the diameter of the pipe, and about 18 inches high, but this quickly diminished until it died out or was extin- guished. This was tried several times with the same result, thus proving that when gas is enclosed in a vessel, the moment the pressure ceases the flame is extinguished. But by allow- ing the vessel to remain some time, and afterwards applying a light, it was shattered to pieces ; which arose from a part of the gas having gradually escaped, in the meantime air entering and combining with the remainder, so forming an explosive compound. Another similar vessel was again charged as before, but in this instance the bottom plug was left open, and on apply- ing the light the flame was considerably higher and more vivid than in the former experiments, caused by the gas ascending by its lightness, air entering by the lower orifice to fill the place of the gap ascending. Gradually the flame became dimmer and dimmer, and at last changed to a deep blue, when it suddenly entered like an inverted cone, and explosion took place, shattering the meter case, and throwing its ends a distance of several yards. On another occasion, on making a trial with a very small holder containing 2 feet of explosive compound, with a pres- sure of T^ths, the gas issuing from a £-inch orifice, it ignited with a very intense blue flame ; but on taking the pressure off the holder and applying the light, explosion occurred, lifting the holder from its place, and throwing the water of the tank in every direction. I need hardly say that these experiments require great care. Thin tinned iron vessels are sufficiently strong ; and as the debris is thrown a considerable distance, too much caution cannot be exercised. When a cylindrical vessel is subjected to explosion the ends generally give way, whilst the sides remain intact. The explosion of gas w’as formerly considered to be due to the hydrogen in combination therewith, which assertion was maintained by Sir William Congreve. However, it is now established that the richest gases are the most destructive when exploding. An explosive mixture always possesses a very powerful 302 EXPLOSIONS OF GAS. odour of gas ; this is sufficient to indicate to any one that a light should not be approached ; and under these circum- stances, when in dwellings, ordinary precautions only are requisite ; above all to have no lights near, and to open the doors and windows, the upper part of the latter especially, as gas by its lightness ascends, and will readily escape thence. The main tap should be turned off, and a careful inspection made, when perhaps a burner will be found turned on, or an hydraulic joint without water, or some other defect which can easily be remedied. No one should ever apply a light where there is an odour of gas in the upper part of an apartment ; many little mishaps have occurred through neglecting this precaution. Should there be any escape which can only be detected by flame, the gas ought to be turned off for two or three hours, and the other precautions being adopted, the light may be applied the moment the main tap is turned on; but it is always better and safer to detect escapes in dwellings without the employment of a flame, it requiring only a little more patience. Meters are sometimes mysteriously destroyed by explosion, even when fixed in their places. The syphon plug when not sealed by water, and the tap of a burner being left open, are sufficient to permit air to enter and form the explosive com- pound, and a light being applied to an orifice without a burner, the flame enters, but does no injury beyond rendering the meter useless. Of the few explosions that have occurred in gas-works, the majority have arisen from having the pipes in vaults and tunnels, or perhaps from open spaces existing under some of the apparatus, generally with the view of seeing to the per- fect condition of the pipes, &c. From this originated the first two accidents of the kind, which befell Mr. Clegg, form- ing a very powerful argument against the use of subways, pro- posed some time ago, for containing gas mains; and if these were unfortunately to be carried into operation, all the extravagant fears of danger which existed at the introduc- tion of gas would certainly be realised. It is well known that mains as now placed, even in isolated places where there is little traffic, are sometimes unaccount- EXPLOSIONS OF GAS. 303 ably broken, and this when entirely protected from the effects of severe cold or frost by the depth they are laid. It is also well known that cast iron, and even wrought iron, have a tendency to. become brittle when exposed to the action of frosty weather ; therefore we may reasonably suppose that, if mains break as now placed, accidents of this nature would be considerably more frequent if they were placed in these subways and subjected to the action of frost. In the event of a pipe breaking as mains are at present laid, the gas may percolate through the earth and be lighted on the surface, or even a portion may find its way into the sewer, in both cases giving timely notice for reparation ; but if such an event occurred with a pipe when enclosed in the subway it is difficult to imagine the consequences ; an ex- plosion under these circumstances would cause houses to totter to their foundations — probably shatter the subway con- taining them ; and in the midst of all this, the only possible means of remedying the evil would be to shut the valves which communicate with the broken pipe, and so put the district in total darkness, thus increasing the terror of the inhabitants, and offering facilities for committing depredation with impunity. There are minor objections against the use of subways, such as their excessive cost, and the difficulty of attaching services, which could only be done with safety by shutting off the supply in the neighbourhood, and this, to use the mildest term, would be a very serious inconvenience. These and many other reasons are sufficient to prevent subways for gas ever being successfully employed ; they may be tried, and may be used under certain circumstances, but can never be carried into operation successfully in the streets of a city. On the occasion of a fire occurring near a gas-works, the public journals generally fall into error by assuming the con- tents of the gasholders to be explosive, and conjecture the amount of damage that would arise from this event occurring, the excitement being much increased by this mis-statement. Gasholders when in use, that is, containing ordinary gas, cannot by any means explode, even although the plates forming them were to be made red-hot by the flames : all that 304 ON WATER GAS. could occur is that the gas, expanded by the heat, would issue in detached flames, but no explosion could take place. Another common error, when an edifice, as a theatre, takes fire, is to turn off the gas to prevent explosion, and this is done sometimes at the risk of putting the audience in darkness to find their way out in the best manner they can. Nothing is more absurd ; for supposing, at the worst, the fire to melt the pipes in the building, and the gas to issue, the same flame which melted the pipe would ignite the gas, so that explo- sion is not possible under these conditions. A good system is to have a valve or valves on the exterior of all public buildings of resort, which, in the event of a fire unfortunately occurring, can be shut off after all the people have left the building, so preventing the destructive effects of the flame should the gas ignite, and the loss of gas. CHAPTER XXIII. ON WATER GAS, OR THE HYDROCARBON PROCESS OF GAS- MAKING. If, as already stated, the steam or vapour of water be passed through a red-hot iron tube, it is decomposed, and hydrogen gas given off in considerable quantities : 10 lbs. or 1 gallon of water will yield 210 cubic feet of hydrogen gas, which, although possessed of considerable heating power, is quite worthless for illuminating purposes. Hydrogen gas, however, has been successfully applied for heating stoves, and when the jets of this are made to burn in a stove filled up with loose fragments of platinum -foil, a very cheerful-looking fire is produced, well known to the public from its frequent exhibition at the Polytechnic Insti- tution of London by Professor Bachhoffner, under the name of Bachhoffner’s polytechnic fire. No systematic manufacture of hydrogen gas has been attempted on the large scale for the purpose of heating, although it has been proposed on various occasions. Several patents have been taken out for producing hydrogen gas ON WATER GAS. 305 from water, and bringing it into combination with the rich gases derived from oil, resin, tar, naphtha, cannel coal, and other materials which yield highly illuminating gases. Among those who have obtained patents of this kind are Messrs. Donovan, Lowe, Manby,Val Marino, Hadley, White, Oroll, Webster, Barlow, and Gore. Although the processes indicated by all these patents differ very slightly from each other, if indeed they are not in some cases perfectly identical, the only one which was carried out in a really practical manner was that of Mr. Stephen White. Under the patents of this gentleman the towns of Ruthin, Southport, Warminster, Dunkeld, together with many mills and factories in Lancashire, were lighted with hydrogen produced from water and combined with the gas from resin or cannel coal, and called the hydrocarbon process. About twelve years ago, when this treatise was first pre- sented to the public, the hydrocarbon process was in great favour, and very sanguine expectations existed of its success. Amongst its ablest supporters were Dr. Frankland and the late Samuel Clegg, both of whom were entitled to the utmost confidence — the former on account of his profound chemical knowledge and the general accuracy of his opinions — the latter for his great ability and having been so intimately and honourably associated with gas-lighting from its earliest date. At the period mentioned, some sanguine minds gave the most extraordinary accounts of the process in question. Mr. Clegg’s statement of the process was undoubtedly of a very extravagant nature, for he assigned 75,000 feet of 12-candle gas as the produce of one ton of Boghead coal when so treated, and it is inconceivable how he could have fallen into this error, inasmuch as this production is literally impossible, for the weight of that quantity and quality of gas would be about 1 ton 1 cwt., whereas the whole of the volatile portion of a ton of Boghead coal, together with the weight of the hydrogen intermixed with it to form 75,000 feet of gas, would be under 15 cwt. ; therefore if the quantity stated were obtained, it could not be of the quality indicated. However, the process was so well supported as to induce 306 ON WATER GAS. many companies to make trials on an extensive scale; amongst these were the Manchester and South Metropolitan, and during several months, the engineers of these establish- ments did their utmost to ensure success; but experience and time proved the fallacy of the system, and the results of these extensive experiments only made evident the imprac- ticability of the hydrocarbon process. Whilst the towns before mentioned which were supplied by these means, instead of yielding profit, as was afterwards the case when coal gas was adopted, suffered one continuous loss. The causes of this signal failure were various. Firstly : The production of hydrogen by the decomposition of water is very costly ; under the most favourable circumstances much more fuel being required to produce a given quantity of gas from water than from coal. Secondly : Hydrogen when so produced and intermixed with rich hydrocarbons, forms merely a mechanical mixture — no chemical affinity existing between them — and, in consequence, the hydro- carbons were deposited in the pipes before the gas reached the consumers’ burners, whereby it was so much impoverished and deteriorated as often to be next to worthless as an illuminating agent. Thirdly : It was impossible to regulate the supply of steam in proportion to the heat of the retort where it was destined to be decomposed ; so that when there was an excess of steam, nearly the whole passed off merely superheated without being decomposed, to be afterwards condensed into water ; so, under these circumstances, the rich gases were delivered without the proper quantity of hydrogen, and of course a beautiful light was the result. On other occasions, when the water was successfully decomposed, the hydrogen being in excess, the gas would be exceedingly poor, possessing little illuminating power. Thus, one night the light would be of great brilliancy, and the next of the worst description. This irregularity was very fatal to the method. But one of the greatest objections was the cost of wear and tear. Clay retorts, although most suitable on account of being capable of sustaining that degree of heat essential for the decomposition of water, could not be employed ON WATER GAS. 307 because of the leakage, the hydrogen being much more pene- trating than coal gas. Therefore iron retorts only could be used ; and these, by the combined action of the heat and the oxygen absorbed by them from the water, were speedily converted into a kind of plumbago ; they also thickened to a great extent, thus presenting a large mass of non-conducting material, which not only increased the fuel to an enormous degree, but the retorts were of very short duration, so that the wear and tear and fuel account added considerably to the many other disadvantages. One of the great arguments of Dr. Frankland in favour of the hydrocarbon process was, that the hydrogen swept out the whole of the carbon, and instead of this being deposited in the retorts, it was carried to the burners for consumption. This might probably be a consideration at that period, but the improvements in carbonising coal, by the employment of the exhauster, have reduced this deposit to an unimportant amount. It may be stated that the zeal, energy, and perseverance displayed in endeavouring to carry this process to a successful issue, merited a better result ; but the system was erroneous, and a striking instance of the highly successful experiment of the laboratory being commercially worthless when carried into practice. Hydrogen gas was employed by M. Gillard in another manner. In this instance the gas issued from an argand burner surmounted by a platinum wire cage which reached a little above the dull hydrogen flame ; the wire cage became incandescent, and a cylinder of intense light was formed around it over the whole surface, the light being obtained simply by the incandescence of the platinum wire. Narbonne, and two or three other small towns in France were lighted for some time by these means, but the great expense of hydrogen caused it to be renounced. The light hy this process, although intense, w T as neither agreeable nor useful. With the view of obtaining hydrogen more economi- cally, M. Gillard erected a cupola similar to those in iron founderies ; this was filled with coke or charcoal, ignited, and the fuel brought to a state of incandescence by a fan or 308 ON THE RATING OF GAS-WORKS blower ; after which (all passage to or from the atmosphere being closed) steam was admitted at the lower part, and pas- sing through the volume of fuel was decomposed, when the hydrogen and carbonic acid with which it was impregnated were withdrawn by an exhauster from the upper part of the cupola. From time to time the supply of steam ceased, and air was furnished by the blower as before, to bring the fuel to the proper degree of temperature for the decomposition. This plan, although much more economical than the retort system, did not succeed ; the expense of manufacture was still very excessive. Therefore it may be concluded that the production of hydrogen gas by the decomposition of water is neither advantageous nor economical, and whether applied to be intermixed with rich gases, heating platinum wire, or being intermixed with oxygen to produce the hydro-oxygen or lime light, cannot at the present time compete with coal gas. CHAPTER XXIV. ON THE RATING OF GAS-WORKS IN PAROCHIAL ASSESS- MENTS. After many years of strife and contention, during which extravagant statements have undoubtedly been put forth on both sides of the question, a more rational and sober series of conditions appears to have been agreed upon. The principle is at least firmly established that every property, however great, and however extensive may be its ramifications, is to be rated on the rental which a tenant would give for it as a whole from year to year, deducting therefrom such expenses as will necessarily be incurred by the owner in order to com- mand such a rental. In the following discussion I wish to guard myself from any imputation of advocacy on either side of the question. All my inclinations lead me to lean to the side of public companies associated together for purposes of enterprise, and who at the same time are frequently entitled to rank as public benefactors. I cannot, however, conceal from myself the fact, IN PAROCHIAL ASSESSMENTS. 309 that a great deal of misplaced indignation lias been displayed of late years by public companies and their organs on the subject of rating. They seem to have been especially irritated at seeing their property assessed on the same principles as other descriptions of property, and have sought to introduce exceptions and modes of dealing with their particular case which do not appear warranted by the law as it now stands. I shall not discuss the justice of the present law of rating, but simply endeavour to give, as clearly as I am able, my view of the manner in which it should be carried out, and the way in which gas property should be rated in proportion to other property in the same parish. If powerful joint-stock com- panies possessing a large interest in the soil, such as railway, canal, gas, and water-works companies, would consider for a moment the number of separate individuals which their gigantic concern displaces^ and reflect how large an amount a parish would derive from the separate rating of so many individuals, they would see less reason than at present to complain of the injustice of parochial rating. From a parlia- mentary document which appeared a few years ago, it appears that the London and Birmingham railway proper, 112 miles in length, was rated to the relief of the poor on a net rate- able value of £131,159. Now, this rateable value applies to an expenditure of at least four millions sterling in works, buildings, and other stationary property which is clearly rateable, so that the value on which the railway is rated would be about 3*3 per cent, on the fee-simple of the property But conceive the same amount of four millions sterling in- vested in buildings of any description, and it will be admitted by most persons who have attended to the subject that such a rating is far below that which would be applied to buildings ; and that, in fact, a rateable value equal to 6 or 7 per cent, of the value is by no means unusual. While, on the one hand, it is highly unjust for public companies to be rated for a mere local purpose at a higher proportionate rate than other properties, it is also manifestly unfair that they should escape local taxation to a greater extent than any other kind of property. In proceeding to rate any description of property extending 310 ON THE RATING OF GAS-WORKS into many different parishes, such as a gas-work, a railway, a canal, or a water-work, it is necessary first to determine the net rateable value of the whole, and then to apportion this net rateable value amongst all the parishes in which the works are situate. I shall first consider the mode of ascer- taining the rateable value of the property as a whole, and then proceed to the method of subdividing or apportioning this amongst the parishes. Now, in order to arrive at the rateable value of the whole, we are clearly to be guided by the words of the Act 6th and 7th William IV. chap. 96, which enacts that property is to be assessed first at that rent which it might reasonably be expected to let for from year to year, and then that the net rateable value is to be found by deducting from this annual rent such expenses for insurance, repairs, &c., as will enable the property to command such rent. The exact words of the Act, which is commonly called the Parochial Assessment Act, are as follows : — “ That no rate for the relief of the poor in England and Wales shall be allowed by any justices, or be of any force, which shall not be made upon an estimate of the net annual value of the several hereditaments rated thereunto ; that is to say, of the rent at which the same might reasonably be expected to let, from year to year, free from all usual rates and taxes, tithe commutation rent charge, if any, and deducting therefrom the probable average annual cost of repairs, insurance, and other, expenses, if any, necessary to maintain them in a state to command such rent.” The first thing therefore in rating a gas-work is to deter- mine the rent at which it may be expected to let for from year to year, and here immediately and directly arises the necessity for a reference to the company’s balance sheet, in order to find out the profit which the company is making. It has happened in the absence of such a document, when access to the company’s books has been refused from some cause or other, that valuers have been required to form an estimate of the annual value from independent calculations of their own, in which the cost of manufacturing the gas is deduced from certain data real or imaginary, and a profit assumed as the amount realised by the company. I shall not IN PAROCHIAL ASSESSMENTS. 311 stop to inquire into the mode of so estimating the profits of a gas-work, although when the amount of coal carbonised is known, the selling price of gas being given, the locality and other circumstances taken into consideration, a tolerably fair approximation may be made. I am only desirous at present to establish, as a foundation to proceed upon, that the profit realised by the company in any one year is the basis or ground-work from which the rateable value must be derived. This point should be clearly settled at the outset, because it has been contended more or less ever since 1836, when the Parochial Assessment Act passed, that such a mode of assess- ment was unfair with respect to railways and similar works. It has been said that in seeking to ascertain the profits of a railway company you are seeking to rate them on profits , which is expressly forbidden by a short Act which is passed every session for the purpose of exempting stock in trade from liability to be rated. But on the other hand it is to be observed, that the inquiry into profits is rendered necessary in order to ascertain what the property would let for, and this is precisely that which is directed to be ascertained by the Parochial Assessment Act. The necessity for inquiring into profits is supported by every example that can be brought to bear on the subject. In the case of rating ordinary houses the gross annual value is a very simple affair, because the house has generally a tenant who does exactly pay a rent for it, and even if in the landlord’s occupation, the value to let is easily inferred from comparison with similar houses ; but when we come even to the most simple case of premises deriving a peculiar value from situation, manufacturing power, or any other circumstances, we require to know immediately the amount of profit which annually arises from such circumstances. Thus we may know perfectly well, without any inquiry into profits, what all the houses in any particular street will let for ; but suppose one house to be fitted with a billiard-table from which the tenant derives a profit, we shall require to know the amount of this profit before we can estimate the additional value which is conferred by the billiard-table. 312 ON THE RATING OF GAS-WORKS The same remark applies to peculiar situation and to manufacturing power, as where machinery exists on the premises. In all these cases, where the landlord holds or occupies the property himself, we ought to know the profit which he derives before we can possibly estimate the value of the property to let from year to year. Admitting then that the profit must be inquired into, there are two ways of arriving at this — either by taking it from the company’s books of account, or making an independent esti- mate of what the profit ought to be. In the case of railway companies, the business carried on is so extensive and com- plicated that as a matter of necessity the parochial officers and persons acting for them are compelled to take the profit from the accounts of the company, usually from the accounts published for their half-yearly meetings. In the case of gas companies, however, some of which are not under the most efficient management, it is not unusual for valuers to make their own estimate of the profits on certain known data , which are perhaps admitted on the part of the gas company. I shall not at present enter into the mode of estimating the productive power', and consequently the profit of a gas com- pany, but suppose that this has been ascertained by one or other of the means pointed out, and that the profit is found to consist of a certain sum which remains after deducting the total expenditure of the year from the gross receipts during the same period. We have now arrived at the profit made by the company whilst the works are in their own occupation, but this is not the sum which a tenant will give for them, because he must not only have a certain sum left for himself as a remuneration for his time and superintendence, but must have interest for the capital employed to carry on the works. The amount and nature of these arbitrary allowances for the tenant have given rise to great disputes, and the utmost variety of opinion is entertained on the subject. It appears to be an admitted principle on all sides that the tenant is to be allowed a certain amount of capital to carry on the works, that is, to pay for coal, lime, wages, &c., until his returns are received for gas and coke sold; and also that he is to be IN PAROCHIAL ASSESSMENTS. 313 allowed for capital corresponding in amount with the present value of such machinery as comes under the denomination of stock in trade, and which cannot be rated as forming a part of the premises, or an hereditament attached to the soil. On the part of the gas company the whole yearly expen- diture is first deducted from the gross receipts, including such items as wear and tear of retorts, loss by meters, rates and taxes, directors’ and auditors’ salaries, bad debts, &c. The balance which remains is then subject to what are termed arbitrary allowances for tenant, in which his capital is made to consist of the following items : — 1. Capital required to enable him to carry on the works, usually estimated by valuers for the companies at about half the gross expenses for one year. 2. The present value of the meters, retorts, and other stock in trade. On the capital so arrived at, it is assumed that the tenant would require 5 per cent, for interest and 12J per cent, for profit, which amount is therefore deducted from the gross value as an arbitrary allowance to the tenant. On the other hand, the parties usually employed to value for the parishes, contending that directors’ and auditors’ salaries being already allowed for in the expenses, make this a set-off against the remuneration of the tenant. Consider- ing further the perfect security for payment which the Act of Parliament gives to most gas companies, the means which they have of enforcing payment, and the small amount of risk incurred in carrying on their business, they contend that such an allowance of 17^- per. cent, for capital is excessive, and ought not to be more than 10 or at most 15 per cent. Then as to the amount of capital, they seem to have gene- rally allowed the retorts to be stock in trade, but not the meters, which they consider fixtures to the mains, and there- fore subject to be rated. An example of estimates formed on these varying prin- ciples will be shortly given, from which it will be seen how widely these arbitrary deductions vary according to the views adopted by the valuers. I now come to the class of deductions comprised under tho P 314 ON THE RATING OF GAS-WORKS head of statutable allowances, comprehending all those (such as rates, taxes, insurances, and repairs) which are necessary to enable the premises to command the rent assumed. Here the valuers for gas companies have sought to bring in charges for repairs, or rather for restorations, which are said to be necessary, in addition to those which appear in the annual current accounts. For instance, they claim an annual allow- ance for the repair of buildings, although the accounts include every farthing which has been expended in such repairs. They also claim an allowance for insurance of buildings beyond any amount which is actually paid for such a pur- pose. Besides which they claim an allowance of 2 per cent, on the value of all their trade fixtures and utensils, and of 1J or 2 per cent, on the value of all the mains, for the reproduc- tion of these when worn out. The valuers for parishes, ou the other hand, entirely dispute these allowances, and con- tend that the current expenses provide for such reproduction by having everything renewed as fast as it is worn out and requires to be replaced. Some years ago, in the rating of railways, very extrava- gant allowances were claimed, on the same principle, to cover the reproduction of the rolling stock and of the permanent way. It was, however, frequently suggested that if any provision were necessary for such a purpose, the railway company should itself set aside a sum annually, by way of sinking fund, to cover such an expense when found necessary. In certain cases where no such fund was set aside by the railway company, the allowance for reproduction was refused on the rate being appealed against. There is still, however, a difference amongst railway engineers as to the necessity for a depreciation fund. The London and Brighton Railway Company, acting probably under the advice of their able chairman, Mr. Lang, who possesses a vast amount of practical experience and valuable statistical knowledge, has been in the habit for some years of setting aside a sum out of its receipts to form a depreciation fund. On the other hand, such a fund has been declared altogether unnecessary by one of the most eminent and accomplished railway engineers of the day, who has devoted himself to every question of rail- IN PAROCHIAL ASSESSMENTS. 315 way politics with an energy and industry peculiarly his own. I need scarcely say that I allude to the originator of the broad gauge, who has publicly declared that the current accounts of the Great Western Railway include such ex- penses as are necessary, from time to time, for keeping in perfect order both the rolling stock and the permanent way, and that no annual reserve in the shape of a depreciation fund is necessary for their maintenance. I am aware that there are many rating cases which are tried on appeal at quarter sessions, where an intimation i3 given by the bench that some allowance for depreciation should be made to the company beyond that which appears in their accounts. In addition to this, in the valuing of houses, manufactories, and many other descriptions of pro- perty, where no accounts of repairs have been kept, or where it appears clear that a charge for restoration would accrue suddenly at some future time, and cannot be provided for by annual repairs and restoration, it may be necessary to calcu- late on sound principles what the allowance should be for such a purpose. It will not be sufficient in such a case to assume any mere arbitrary allowance on the cost, such as \\ f 2, or 5 per cent., all of which sums have been claimed for reproduction, but it must actually be ascertained what sum under the given conditions of the question will be an equi- table allowance for the purpose. There are two elements which must be assumed in any case of this kind ; first, the value of the object to be restored, and the period or distance of time at which the restoration is to be made. The value must not be the original value of the object when first erected, but its value at the time of making the rate; and when once the sum to be set aside annually is determined, it will be the same year after year, because, although the value of the object will diminish yearly, so also, in the same propor- tion, will diminish the number of years during which the annual sum is to be set aside. The principle I am now con- tending for is this, that the annual sum to be set aside is that sum which at compound interest will amount in the assumed number of years to the whole sum required at the end of that period to effect the restoration. For instance, p 2 310 ON THE RATING OF GAS-WORKS suppose a building or any other object whose present value is £1,000 should be assumed to last thirty years, when an amount of £1,000 must be employed to restore it; then, I say, the annual sum to be put aside is that which, at com- pound interest, at 3 per cent., will amount in thirty years to £1,000. Now, it appears from the tables of compound inte- rest that£l per annum invested at compound interest during thirty years will amount at the end of that time to £47. Hence it follows, if we divide 1,000 by 47. we shall have the sum which, being invested annually at compound interest, will at the end of that time produce £1,000. Then — = £21 5s. 8d., the sum to be invested annually. This w r ould amount to rather more than 2 per cent., which is the proper allowance when the duration is estimated at thirty years. When a period of tw r enty years is taken for the duration of an object, an allowance of nearly 4 per cent, must be made. When the period is 30 years, 2 per cent. „ 40 ‘ „ 1*3 „ 50 „ *88 „ The following estimate, made by Mr. Lee, of the net rate- able value of the Phoenix Gas Company, forms a good example of the mode usually adopted by the valuers of gas companies for assessing the rateable value. This valuation was made in 1849 on the occasion of an appeal by the Phoenix Gas Company against the rate in the parish of Greenwich. £ s. d. Net balance for 12 months, taken from the company’s books 21,964 12 0 Arbitrary deductions to arrive at the gross estimated rental. Floating capital employed by tenant, £ s. d. assumed equal to six months’ ex- penses 33,210 0 0 Present value of meters, the cost being £25,000 15,000 0 0 Present value of retorts 7,525 0 0 Total amount of tenant’s capital . £55,735 0 0 IN PAROCHIAL ASSESSMENTS. 317 £ s. d. £ s. d. Brought forward .... 21,964 12 0 5 per cent, for interest on £55,735 is . 2,786 0 0 J2£ per cent, for tenant’s profit on £55,735 6,966 0 0 Amount of interest and tenant’s profit for one year . 9,752 0 0 Gross estimated rental 12,21212 0 Statutable deductions. Bates and taxes previously deducted in arriving at not balance ; annual repairs of buildings previously de- ducted. Insurance on buildings, value £65,054, £ s. d . at 5s 162 0 0 2 per cent, for reproducing the follow- ing:— £ s. d. Trade fixtures, value 39,672 0 0 Utensils .... 12,94/5 0 0 Mains in the stations 6,271 0 0 Street mains . . . 105,760 0 0 £164,648 0 0 2 per cent, on £164,648 3,292 0 0 Total deduction for renewal and insurance . . . 3,454 0 0 Net rateable value of the whole property, the value being £278,998 £8,758 12 0 It appears that the valuers for the parish during this appeal did not treat the production of the Phoenix Gas-works as a whole, but confined their estimates to the production of the Greenwich Station alone, whereas the company has also manufacturing stations at Vauxhall and at Bankside. In consequence of this, no comparison can be made between the net rateable values arrived at by the two parties, treating the works as a whole. Mr. Penfold, however, in his work on Eating, has published a statement of net rateable value for the whole works, founded on the basis of the company's own rental, and on arbitrary allowances, according to Mr. Barlow’s statement of expenses for manufacturing gas. This statement is taken from an able Eeport made by Mr. Barlow in 1849 to the Directors of the City of London Gas Company. In his Report, Mr. Barlow analyses with 318 ON THE RATING OF GAS-WORKS great minuteness the prospects of the Great Central Gas Consumers’ Company. He investigates the cost of every item of gas manufacture under two distinct heads, 'production and distribution , making the total cost of production amount to 20 # 64cZ. per 1,000 feet of gas made, and the expense of distribution equal to 13*51c?. per 1,000. Mr. Penfold, con- sidering Mr. Barlow as the especial advocate of the then existing companies, and interested in proving the cost of gas- making to be as high as possible, considers such statements fair evidence as against any gas company on the question under discussion. Using the data before explained, Mr, Penfold makes the net rateable value of the whole of the Phoenix Company’s gas-works £18,312 And substituting Mr. Croll’s cost of manufacturing gas, as given in evidence before the Central Gas Committee, he makes the net rateable valuable of the whole 28,455 Mr. Lee’s valuation of the rateable value being . . 8,758 We shall present one other case in which the author was himself engaged, and Mr. Lee valued for the gas company. This was the case of the British Gas Company and the parish of Ratcliff. Mr. Lee’s valuation in this case was nearly on the same basis as in the Greenwich case, except that the esti- mates claimed only 1\ instead of 2 per cent, for the reproduc- tion of the mains. The following is Mr. Lee’s valuation : — Or. £ s. d. £ s. d. Total rental for gas-light . . . . ; 21,188 0 0 Cash for coke and ammonia .... 4,514 0 0 Total receipts for 12 months Dr. £ s. d . Coals, 12,322J tons used (at 145. 10 \d.) . . . 9,153 0 0 Lime used for purifying 267 0 0 Working process wages 5,092 0 0 Wear and tear of retorts, &c 2,020 0 0 Meter repairs and fixing .... £882 Meter rent received 400 Loss 482 0 0 25,732 0 ft Carried forward 17,014 0 0 25,732 0 0 IN PAROCHIAL ASSESSMENTS. 319 £ 5 . Brought forward 17,014 0 Bates and taxes (last year, 1848) .... 650 0 (Bates in 1849 are larger.) Office expenses and clerks’ salaries 742 0 Directors’ salaries. . . 500 0 Ordinary law expenses . 70 0 Interest on borrowed capital . . . £1,395 Bad debts and over- charges . . . . 400 0 d. 0 0 0 0 0 0 £ s. d. 25,732 0 0 19,376 0 0 Net balance for 12 months . . . 6,356 0 0 Deductions to arrive at the gross estimated value 5 per cent, on the capital* necessarily employed by a tenant 11,500 C 0 Ditto on the present value of meters (the cost being £5,640) . . 3,640 0 0 Ditto on the present value of retorts (cost £4,680) 2,420 0 0 Amount of tenant’s capital .... 17,560 0 0 5 per cent on the above is .... Amount of tenant’s profit, being 12J- per cent, on the above £17,560 capital £ s. d. 878 0 0 2,195 0 0 Amount of interest and tenant’s profit for 12 months .... Gross estimated rental of the whole property ...... Statutable deductions. The rates and taxes are before deducted. Annual average repairs of buildings . Insurance on buildings For renewal or reproducing trade fix- tures and utensils, their value being £16,847 (meters not included), at 2 per cent 3,073 0 0 3,283 0 0 390 0 0 106 0 0 336 0 0 Carried forward 832 0 0 3,383 0 0 * The capital here assumed is considerably more than six months’ expenses, and is nearly equal to six months’ gross receipts. 320 ON THE RATING OF GAS-WORKS Bi ought forward .... For renewal or reproducing the mains on the stations, and the street mains, their value being £24,453, at l£ per cent £ s. d. £ s. d. 832 0 0 3,383 0 0 367 0 0 Total of repairs, insurance, and renewal 1,199 0 0 Net rateable value of the whole property . . . £2,184 0 0 It being considered that this rateable value was too small, having regard to the magnitude and capacity of the works, the author was called in by the parish at the suggestion of Mr. Penfold, who was one of the arbitrators, and after going through the works and minutely considering the Company’s evidence to see what parts could be adopted as reasonable and fair, the result of his investigation was the following estimate : — Net rateable Value of all the Works and Mains. £ s. d. Gross revenue, as per statement A 24,172 17 3 Production account . £ s. d. £ s. d. Coal, as per evidence . . 9,153 0 0 Labour of distilling 12,322 tons of coal, as per state- ment B 2,261 5 0 Wear and tear of retorts, as per statement C . . 1,333 13 0 Expense of lime for puri- fying, 12,323 bushels, at 4 d 205 8 0 12,953 6 0 Less residual products, as per statement D . 4,601 13 4 Cost of distribution, as per statement E Statutable allowances, as per .state- ment E Arbitrary deduction for interest and tenant’s profit, £10,000, at 15 per cent., as per statement G . . . . 8,351 12 8 3,276 7 3 1,219 18 0 1,500 0 0 Deduct rates and taxes, as per company’s statement 14,347 17 11 9,824 19 4 650 0 0 Net rateable value of the whole property . . . £9,174 19 4 IN PAROCHIAL ASSESSMENTS. 321 A. — Estimate of Gross Revenue. 12,322^ tons of coal carbonised per annum, each ton assumed to yield 9,200 cubic feet of gas. Then 12,322J X 9,200 = 113,367,000 Less one-fourth for leakage 28,341,750 Total quantity to be sold .... 85,025,250 From this deduct consumption of 1,264 public lights, each at 50 feet per night, making 1,264 X 50 X 365 = . . 23,068,000 Deduct also quantity used in works, as per evidence . . 1,000,000 24,068,000 w — —————— £ s i Private consumption 60,957,250 j jg 237 2 0 at 6s. j * Receipts for public lights, as per company’s evidence . 5,885 15 3 , £24,172 17 3 B. — Estimate of Expense for the Larottr of manufacturing Gas FROM 12,323 TONS OF COAL. Salary of superintendent £200 0 0 Foreman, at 3 6s. per week 93 12 0 Two foremen of stokers, at 30s. per week each .... 156 0 0 Twenty ordinary stokers, at 24s. each 1,248 0 0 Wheeling coal, 12,323 tons, at 3 d. 154 1 0 Two purifying men, at 24s. each 124 16 0 Valve man, at 28s 72160 Storekeeper . 8000 Coke clerk 8000 Gatekeeper 5200 £2,261 5 0 O. — Wear and Tear of Retorts. In this estimate it is assumed that each retort will be worn out, and require to be taken down and reset, after producing 700,000 cube feet of gas. Hence the number of retorts required per annum will be 113,367,000 700,000 162 retorts, which are assumed to be of cast iron, weighing 16 cwt. each. £ s. d. Hence 162 retorts, at £5 .... 810 0 0 Taking down 162 old retorts, breaking the connections, and renewing old materials, 162 at 4s 32 8 0 p 3 Carried forward 842 8 0 322 ON THE RATING OF GAS-WORKS £ 8. d. Brought forward 842 8 0 Bricklayers’ w’ages for re-setting retorts, 162 at 12 s. 6d. 101 5 0 Fire-clay and fire-bricks used in re-setting retorts, and in repairing furnaces, 162 at 20s 16200 Making good connections to hydraulic main .... 26 0 0 Bolts and cement for new connections, wear and tear of ash-pit pans, furnace-doors and bars, ears and cross- bars, barrows, scoops, shovels, brooms, &c., 162 at 10s. 81 0 0 1,212 13 0 Allowance for contingencies, defective retorts, &c., 10 per cent 121 0 0 £1,333 13 0 No deduction is here made for the sale of the old retorts. D. — Residual Products. Total coal used 12,322 tons. Making 12,322 chaldrons of coke. Used for carbonising, one-third 4,107 Remaining for sale . . . . 8,215 chaldrons. £ s. d. 8,215 chaldrons, at 10s 4,107 10 0 100 tons of coal will yield 8 chaldrons of breeze, to be sold for brick-making, at 3s. per chaldron. 12 322 X 8 Hence — H[oo ~ 985, at 3s . . 147 15 0 Each ton of coal will yield 10 gallons of gas tar. Hence 123,220 gallons, at 1 d 513 8 4 4,768 13 4 Deductions . £ s. d. Filling 9,200 chaldrons of coke and breeze, at 3 d, 115 0 0 Labourers delivering tar and ammoniacal liquor 5200 167 0 0 £4,601 13 4 E.— Expenses op Distribution. £ s. d. Lighting and repairing 1,264 public lamps, at 20s. . . 1,264 0 0 Collection and bad debts, at 3 per cent, on rental of £24,000 720 0 0 Law expenses, stationery, and incidental expenses, 113,367 at \d. 472 7 3 Engineer, secretary, clerks, and inspectors 820 0 0 £3,276 7 3 IN PAROCHIAL ASSESSMENTS. 323 Engineer £200 Secretary ...... 200 Two clerks 150 Three inspectors . . . . 270 £820 .—Statutable Allowances. £ 5 . d. Insurance of buildings, and annual repairs of buildings and apparatus 50000 Renewal or reproduction of trade fixtures, valued at £17,644, at 2 per cent.* 352 18 0 Renewal of mains, valued at £24,453, at 1J per cent.* 367 0 0 £1,219 18 0 G. — Estimate of Capital required by a Tenant. Coal in stock, 2,000 tons, at 15s 1,500 0 0 £ s. d. One year’s consumption of coal . . . .9,153 0 0 One year’s wages for manufacturing, as per statement B 2,261 5 0 One year’s wear and tear of retorts, as per statement C 1,333 13 0 One year’s expenses of distribution, as per statement E 3,276 7 3 One year’s maintenance of works, repairs, insurance, &c 500 0 0 16,524 5 3 Deduct one year’s receipts for sale of coke 4,601 13 4 £11,922 11 11 The tenant would have to provide for half-a-j-oar’s payment, or L — 5,961 10 0 Assumed value of retort, as per evidence 2,420 0 0 £9,881 10 0 DIVISION OF THE NET RATEABLE VALUE BETWEEN THE SEVERAL PARISHES. We now come to the second branch of inquiry: namely the mode of apportioning the net rateable value, as deter- * These allowances were made because in former cases they had been decided at quarter sessions. The amounts being small, it was not thought advisable to complicate the case by contending for the principle of a sinking fund, which, as already explained, is the proper way to estimate costs of reproduction. 324 DIVISION OF THE NET RATEABLE VALUE mined for the whole gas-works, amongst the several parishes through which the mains extend. Here again we find quite as great a variety of opinion as on the other subject. Even the judgments delivered by the Court of Queen’s Bench, the highest court of appeal to which rating cases have been carried, seem to have undergone some change year after year since the passing of the Parochial Assessment Act. It appears to be clearly decided, in the case of the Queen v Cambridge Gas Lighting Company, that the rateable value is not to be divided in proportion to the receipts for gas in each parish ; and Lord Denman, in his judgment in this case, quoted a parish through which the New River passed, and in which no profits accrued to the Company, yet the New River works in this parish were rated, and properly so, at <£300, because the apparatus in the parish contributed to the whole value to let, although no receipts within the parish itself were derived from the apparatus lying within it. So it will often happen in the case of gas-works that mains may pass through a parish without any service-pipes being affixed to them, without supplying any gas in the parish, and con- sequently not yielding any receipts. But the works are nevertheless to be rated in this parish because they carry gas which passes through them for the supplying of other parishes where the company receives payment for its gas. Some of the judgments even seem to have inclined to the opinion, especially in the case of railways, that the total rateable value should be divided in proportion to the mileage or length of line passing through each parish. This division however, would usually be very unjust alike for railways, gas-works, and all similar undertakings. In each case the most remote and thinly inhabited parishes would reap far more than their share, while metropolitan parishes, and chiefly those nearest to the principal termini or principal sites of manufacture, would be injured in a proportionate degree. Other decisions, however, and those of a more recent date, have supported an opposite principle, — namely, that of dividing the net rateable value of the whole in pro- portion to the quantity of apparatus in each parish. Lord Denman, in his judgment in the case of the Queen v. the BETWEEN THE SEVERAL PARISHES. 325 Cambridge Gas-Light Company, speaking of the division amongst the parishes, says, “ We are aware of no rule which can be laid down as to the amount, except that it must be in proportion to the quantity of apparatus situate in each parish.” In the next case of importance, namely, that of the Queen v. the South-Western Kailway Company, a somewhat clearer principle was expressed ; and in the case of railways it was decided that the division should be in proportion to the earnings in each parish, having first deducted from the net rateable value of the whole the rateable value of the stations, which are separately rated in the parishes in which they are situated. Now in the case of a railway this mode of division is quite practicable, and no parish would be excluded from its just proportion of the whole assessment, even though no receipts are actually takep in it. Suppose a parish situate between two stations A and B, then the whole of the traffic passing from A to B and vice versa will pass through the parish. The parish accordingly will be entitled to its pro- portion of the receipts taken for traffic between A and B in proportion to its length, so that the case is amply provided for in which a parish has no station, and in which conse- quently no receipts are taken by the Company. The case is equally simple when the parish contains a station ; the net rateable value here being a proportion according to the mileage of the receipts between the station in the parish and that on each side of it, with the addition of a sum for the station itself. It would lead us too far out cf our way and be altogether inapplieable in this work to go further into the mode of dealing with the railway stations, and separating their rateable value from that of the railway proper ; and we must therefore confine our attention more immediately to the case of gas-works. Here, however, the same general principle prevails for separating the works, — that is, all the rateable apparatus at the head-quarters or manufacturing establishment from the pipes or mains extend- ing through the streets.. No satisfactory or even practicable mode of doing this has ever been suggested, except that arising from the cost or value of the works as compared with 326 DIVISION OF THE NET R VTEABLE VALUE tli at of the whole property, worhs and mains together. We shall suppose the net rateable value of the whole to have been arrived at, and, in order to find the separate part of this chargeable to the works and to the mains, we must have an estimate of the present value of the works and of the mains separately. Then we have this proportion ! — As the present value of the works and mains together is to the net rateable value of the whole, so is the present value of the works to the net rateable value of the works. In the same way the net rateable value of the mains is found by substituting the present value of the mains for that of the works in the third and fourth terms of this proportion. The principal station or manufacturing site of a gas esta- blishment is commonly at least equal in value to that of the mains, so that in this simple mode we get rid of half the rateable value by apportioning it to that parish in which the manufacturing station is situate. If there be more than one station the division is equally simple, each station being debited with its proportionate rateable value according to its present worth, as compared with the worth of the whole property. We have yet a further sum, however, to divide amongst the mains, and perhaps this division has given rise to more contention than any other question connected with the rating of gas-works. In the case of the Phoenix Company and the Parish of Greenwich, the Court of Quarter Sessions decided that the division was to be made in proportion to the square yards of ground occupied by the mains in each parish. Now, with great submission to the learned Bench of Magistrates, this decision was simply absurd, because the square yards of ground occupied are neither a measure of the quantity of apparatus, nor a measure of the earnings, nor a measure of the capacity of the mains. This mode of distributing the rateable value has the effect of giving an enormous advantage to the remote parishes, and in a pro- portionate degree injuring those which are nearest to the fountain-head, and which first distribute the gas before it can be taken out of the mains. Another principle of division which has been adopted is BETWEEN THE SEVERAL PARISHES. 327 also fallacious, but not to the same extent — namely, that of dividing the rateable value according to the cubic yards of main in each parish. This principle makes a perfectly cor- rect division according to the quantity of apparatus, but not according to earnings, which by the latest decision is clearly intended to be the basis of the subdivision. The error is of the same nature as the one allowed by the Quarter Sessions in the Phoenix case — namely, one of excess for the remote parishes, at the expense of those near the centre of distribu- tion. The principle, in fact, of dividing according to cubical capacity of the mains is only correct on the supposition that a main of a given area will deliver the same quantity of gas at all distances from the gasholder, which we know is very far from being the fact. Every one knows that a 12-inch main within 100 yards of the gasholder will pass a great deal more gas than the same main at the distance of a mile. The principle in question would also require this theoretical condition — namely, that the mains at the extremities of the company’s district should be attenuated to such dimensions as just to deliver the gas required for present consumption with the requisite pressure ; but this is notoriously not so, for with a view to extensions the mains are purposely not so much contracted as they otherwise might be. The effect of all this is, that this mode of subdivision does not give to the mains their proportionate value as parts of the apparatus in the arterial parishes, and gives too much value to those at a distance. It divides the rateable value in proportion to quantity of apparatus, not with reference to earnings, nor with reference to capacity for earning, or contributing to the whole earnings of the concern. I am now bound to explain the mode in which I propose to subdivide the rateable value amongst the mains, for which purpose I must have the cubical contents of all the mains, the cubical contents in the particular parish, the quantity of gas supplied in that parish, and the annual receipts for that gas. Then I should calculate the size of main which would be required simply for the delivery of the quantity of gas consumed in the parish, and consider the extra size of the main entitled to a further allowance for contributing to the 328 DIVISION OF THE NET RATEABLE VALUE earnings of the parishes lying beyond. Thus, I would say — As the whole receipts are to the rateable value of the whole, so are the receipts in the parish to the rateable value of the mains in respect of receipts within the parish. Then, to find the additional rating for the part contributed by the mains towards the receipts in other parishes, I would say— As the cubical contents of all the mains is to the extra cubical contents of main in the parish beyond what would be necessary for the supply of the parish, so is the rateable value of all the mains to the extra rateable value of mains in the parish. The fourth terms in each of these proportions being added together would give, as I conceive, the whole rateable value of the mains in any parish. I am afraid of extending this subject of rating to too great a length, as it might be wearisome to many of my readers. At the same time, the subject possesses much interest for gas companies, who would in many cases fare better if they did not attempt to shroud this affair in such impenetrable mys- tery. This air of mystery is often apt to occasion a sus- picion of far greater profit than that really derived. In all such cases fair play to the parishes is to be insisted on ; let each have its proper share, and let each have such means of information as will enable its officers to make assessments on a sound basis. It has not occurred to me now for the first time, consider- ing the many complicated interests which have to be assessed in these days of progressive improvement, that it would be desirable if some public officer were appointed to make an assessment every year of the property in gas-works, canals, railways, &c., rateable to the relief of the poor. Such an assessment would require to be varied every year, but the principle of division once settled would be permanent. A vast amount of litigation would be thus saved, and in the end all parties would find it much more satisfactory than the present blindfold system. INDEX. Accum and others engage in ex- periments on gas-lighting, 14. Air, mixture of, with gas dimin- ishes the light, 215. Air condenser, 143. Ammonia, its composition and origin, 46 ; Mr. Cr oil’s process for separating, 170 ; salts of, manufactured from ammoniacal liquor, 174; sulphate of, yielded by the liquor drawn from the purifiers in Croll’s process, 174; fertilising power of, 174. Ammoniacal liquor, its value for agricultural purposes, 46 ; puri- fication by means of, 153 ; Prus- sian blue made from, 296; price of, 149. Analysis and affinity described, 37. Annual assessment of railways, canals, gas-works, &c., proposed, 329. Apparatus, iron, complete for gas- works, specification of, 198. Arbitrary allowances in rating gas-works, 312. Arbitrary allowances for repro- duction, 316. Ar bitrary allowances made by Mr. Lee in rating cases, 317. Author, valuation by him in a rating case, 321. Bachhoffner’s polytechnic fire, 304. Barlow’s Report to the City of London Gas Company, 146 ; estimate for the erection of retorts, 85 ; dimensions and estimate for a large retort- house, 85 ; estimate for con- densers, 146 ; estimates of cost of purification, 166 ; his table of the discharge of gas from pipes of various dimensions and at different pressures, 238. Bitumen, springs of, described by Herodotus, 4. Bituminous strata, 4. Bituminous coal, gas arising from beds of, in China, 5. Black coal, 51. Boghead cannel, 56. Boghead cannel, per-centage of volatile matter in, 54; quality of gas produced from, 288. Breeze, the use of, 294. Brick retorts, Grafton’s, 100 ; Clift’s, 101 ; Spinney’s, 101 ; Winsor’s patent, 100. Brick tanks for gas-holders, 183 ; description of, 184 ; specifica- tions of, 186, 188. British Gas Company and the parish of Ratcliff, 318. Bromine test, on the, 373. Bromine, mode of operating with, and amount of condensation, 274. Br unton’s retort, description of, 92. Buildings in gas-works; retort- house, 82 ; coke vault, 82 ; coal store, 87 ; purifying house, 87 ; engine house, 88 ; station meter house, 88 ; chimney, 89. Bunsen photometer, 276; engrav- 330 I7.1DEX. ings of the, 278, 279; method of preparing the disc in the, 277. Burning spring near Wigan, 6. Caking coal, 52. Candles, production of gas during the burning of, 26. Cannel coal, superiority of, for producing gas, 53. Capital requisite for works, 81. Carbon, fixed and volatile, 53. Carbonisation, process of, 62. Carbonic acid, chemical com- position of, and Dr. Henry’s experiments on, 45. Carbonic oxide, description and mode of preparing, 42. Carburetted hydrogen, its chemi- cal equivalent and composition, 39. Cement used for clay retorts, 106; for iron pipes, &c., 108. Charge, method of drawing the, 70 ; method, in small works, of drawing and renewing the, 72. Charges for retorts, 71. Charging retorts, mode of, 70 ; method of, in small works ; use of the scoop — general descrip- tion of the process, 71. Chemistry of gas-lighting, 26. Cherry coal, cannel coal, 52. Chimneys of retort-houses, price of building, 90. Chlorine, condensation of gas by, 273. Church and Mann’s photometer, 277. Clay retorts first proposed by Mr. Grafton, 100. Clay retorts, advantages of, 98 ; first used in Scotland, 101 ; first used in London extensively, 102 ; forms of, very variable, 104; cost of settings of, 114; duration of, 115; engraving of mouth-piece of, 106; engraving showing how separate lengths of them are put together, 107 ; their alleged p< r osity, 101; where used, exhausted neces- sary, 103. Clay and iron retorts combined, 119; compared, 103. Clayton, Dr., experiments of, on distillation of coal, 8. Clegg, Mr., subject of gas-lighting taken up by, 14; his various important inventions, 20 ; de- scription of the revolving web retort by, 93 ; invented the first gas meter, 216; examples and estimates of retort-houses by, 85 ; his examples and estimates of cost for gas-holders, 195; his recommendation relative to lay- ing mains, 236 ; his estimate for retort-house, 85 ; his experi- ments on hydrocarbon gas, 305. Coals, used in gas-making, 49 ; supposed origin of, 50 ; first mines opened in Newcastle, 50; first patent obtained in con- junction with, 51 ; Dr. Thom- son’s classification of, 51 ; cak- ing, splint, cherry, cannel, anthracite, 52 ; constituents of, 53 ; percentage of volatile matter in certain classes, 54 ; quantity of gas produced from, 55 ; yield of coke from, 55 ; experiments of the quantity of gas derived from, 57 ; residual products from the .distillation, 294. Coke drawn from the retorts, dis- posal of the, 71. Coke, use of red-hot, for charging furnaces, 68. Coke vault, 82. Composition of gas, 39. Condensation, injurious effects of excess of, 145. Condenser, various kinds in use; Malam’ s condenser, 142; the ver- tical, 143; description of engrav- ings showing a vertical, 143 ; longitudinal section and cross section of, 1 44; description of con- denser at Imperial Gas-Works, 144 ; engraving and descrip- tions of tanks used to receive condensed products from the, 147 ; Messrs. Croll and Bar- low’s estimates for, 146. INDEX. 3131 Cotton-mills and factories in Lan- cashire lighted by Mr. Clegg, 15. Counterbalance, method of deter- mining the weight of, for gas- holder, 194. Cowley & Co., the wrought-iron main made by them for the Phoenix Company, 129. ^Jroll, Mr., his patent process of purification, 129; his fire-bars, and construction of furnace, 110 ; clay retorts used by him, 101 ; his mode of setting clay and iron retorts, 124; his esti- mate for a retort-house, 86 ; his estimate for condensers, 146; his process for separating am- monia, 170 ; his process of purifying, advantages in, 170; his process — plans, section, and description of the apparatus used in, 171, 172; his remarks on the fertilising value of re- fuse lime, 173 ; his estimates of the cost of purification by lime, 166 ; his estimate of leakage in mains, 249 ; his process of purification with neutral salts, 174. Croll & Richards’ dry meter, 231. Ctesias, writings of, 4. Cyanogen, 49. Daniell, Professor, attempts by him to make gas from resin, 24. Decomposition, gas produced by, 1. Defines’ dry meter, 230. Denman (Lord), judgment in the case of the Queen v. Cambridge Gas-Light Company, 325. Dip-pipe, description of, 62. Distillation of coal, Dr* Clayton’s experiments on, 8 ; Dr. Hales’s experiments on, 6, 62. Division of rateable value amongst the parishes in rating cases, 327. Drying gas, mode of, 272. Dry-lime purifiers, 157 ; engrav- ings of, 158, 159. Ecbatana, fountain of naphtha in, 5. Engine, gas, 215. Estimated quantities of brick- work and stone in tank of gas- holder, 187. Estimates for erecting and re- newing retorts, 114; by Mr. Cleggfor erecting retort-houses, 85 ; by Mr. Barlow for largo retort-house, 85 ; by Mr. Croll for a retort-house, 86 ; of cost for gasholders, by Mr. Clegg, 195. Exhauster, employment of an, 212 ; Mr. Grafton’s experi- ments on, 213; Beale’s, 214; Jones’s, 214; Methvin’s, 214; Anderson’s, 214. Experiments on explosions of gas, 300 ; on evaporation of hydrocarbon liquds, 292 ; Mr. Grafton’s, on exhauster, 213. Faraday’s “ Chemical Manipula- tion,” table extracted from, 270. Fire-bars and grate, dimensions of, 111. Fitter, gas, business of the, 25. Flames, burning, venerated by the ancient world, 2. Flow of gas through pipes, table from the “ Journal of Gas- lighting,” 238. Fuel required for carbonising coal, 68. Furnace, woodcut and descrip- tion of, 110. Gas, the constituents of, 39 ; effects of temperature and pressure on, 261 ; moisture in, 263 ; mode of burning, 286 ; explosions of, 297 ; air intermixed with, loss of light by, 215, 286 ; weighing, 264 ; vapours inter- mixed with, 270 ; consumption of average per head of popula- tion, 81; engine, 215; conden- sation of, 244. Gas company, first established 19. Gasholder described, 179; trus- 332 INDEX. sing for, 191; examples of price of, 195; specifications of, 196, 198 ; specifications of Pancras Station, 200 ; mode of ascer- taining its pressure and deter- mining the counterbalancing weight, 194; at Imperial Com- pany’s station, Hackney, 205 ; early forms of, 211 ; engraving of single-lift, 192; telescopic, 203; tanks of, 180; description of iron tanks for, 180 ; descrip- tion of brick tanks for, 183. Gillard’s water and platinum gas, 307. Glance coal, or anthracite, 53. Gordon, David, his patent for compressing gas, 23. Governor, its advantages, 257 ; description of the various parts of the, 257 ; engraving of, 258 ; necessity of, in gas-works, 259 ; used on street mains, 259. Governor or regulator used in street lamps, 260. Grafton, Mr., clay retorts pro- posed by, 100; experiments by, on the subject of pressure, 213. Greek fire-altars, 3. Hales* experiments on the distil- lation of coal, 6. Henry, Dr., subject of gas-light- ing taken up by, 10; his de- cription of Mr. Murdoch’s first trials, 10. Hydraulic main, use of, described, 129; section and elevation of, 130, 131 ; cost of, usual forms of, 130; fluid contained in, re- marks on, 132. Hydraulic valve, description of the, 135 ; engravings of two kinds of, 135. Hydrocarbon gas, mode of manu- facturing the, 304 ; produced from cannel coal and water, 304 ; causes of failure of, 306. Hydrocarbon process, Mr. Clegg’s observations on, 305. Hydrogen gas, method of making ; description and specific gravity of, 33 ; produced by the de- composition of water ; patents for combining hydrogen gas with carburotted gases, 305. Imperial gas - works, condenser used at the, 144 ; magnitude of operations of, 81 ; gasholders at, 188, 200, 205. India-rubber rings for joints of gas-pipes, 236. Indicator pressure, 254 ; record- ing, various contrivances for, 253. Inflammable gas known at a very early period, 1. Inflammable gas issuing from the earth, modern examples of, 6. Inflammable gas from a coal- mine, Sir James Lowther’s account of, 7. Iron retorts, useful only in small works, 99 ; average production from, 98; mode of setting, 117; comparison of clay and, 98. Iron-cement, recipes for making, 108. Ironwork in gas-works, specifica- tion of, 198. Laming, his process of purifica- tion, 175. Lamps and candles, production of gas during the burning of, 26. Leakage of mains, 249; Mr. Croll’s estimate of, 249. Lee, Mr., estimate of rateable value for Phoenix gas-works by, 318. Lime, quantity of, used for puri- fication ; lime best adapted for purification; varieties of lime, 164. Limestones, classification of, 164. Lowe, Mr., his successful opposi- tion to oil gas, 23 ; his inven- tion of carburising gases, 291; his combination of clay and iron retorts, 119; his reciprocating retort, 93 ; his bladder valve, 139. Lowther, Sir James, account by him of inflammable gas from a coal mine near Whitehaven, 6. ind ex. 333 Luting the retort-lids, composition for, 96. Mains described, 233 ; delivery of gas from, table of, 238 ; endos- mose and exosmose action on, 234 ; first laid by New River Company, 233 ; mode of detect- ing obstructions in, 245; method of preserving, 244; method of proving, and method of making joints of, 235 ; method of making the joints used in Liverpool and Manchester, 237 ; necessity for changing when too small, 250; on laying gas, 232 ; prices of, table of, 247 ; use of “ Chame- roy,” 233 ; use of vulcanised india-rubber rings for the joints of, 237. Malam, Mr., invention of gas- meter, 216 ; his improvements in purifiers, 158. Map of gas-works and district to be supplied very essential ; should contain the levels, 241. Mastic d’Aquin or iron cement used by the French, 108. Meter, early history of the, 216 ; Clegg’s, 216 ; Malam’ s, 216 ; Sir W. Congreve’s, 217; descrip- tion of wet, 220 ; engravings of wet, 220, 221, 222, 225 ; engrav- ings of Wright’s station, 228 ; description of dry, 230 ; Defries’ dry meter, 230 ; Croll and Richards’ ditto, 230 ; contin- gencies in measurement of, 224 ; compensating, 226; Sanders and Donovan’s, 227 ; formerly used as a motive power, 215. Metropolis, progress of gas-light- ing in the, 21. Moisture, correction for, 270 ; examples of correction for, 270. Mouth-pieces for retorts, engrav- ings of, 94, 95, &c. Mouth-pieces of clay retorts, 106. Mouth-pieces and mode of attach- ment, engraving of, 96. Murdoch’s experiments and appli- cation of coal gas to useful purposes, 10 ; his experiments described in the et Philosophical Transactions,” 13 ; his compari- son of the comparative cost of lighting by gas and by candles, 13; experiments on the best form of retort, 91. Nitrogen, 34. Neutral salts, purification by, 174. Oil, proposals to make gas from it and other materials, 22; com- parison of coal gas with that made from, 23. Olefiant gas, 40. Ornamental illumination, first, 11. Ovens, arrangement of retorts in, 109; retorts set in, 109. Oxide of iron purification, 167 ; spontaneous revivification, 167 ; method of working, 168. Oxygen, 32. Pall Mall the first street lighted by gas, 18. Parochial Assessment Act, 319. Phoenix gas-works, hydraulic main at, 129. Photometer test, value of the, 275. Photometer, by Professor Bunsen, 276 ; engravings of the Bunsen, 277, 278; Romford’s, 276; Church and Mann’s, 277. Plan and elevation of works, 78, 79. ^ Planning works, 77. Plutarch’s notices of perpetual fires, 3 ; description of the burn- ing fountain in Ecbatana, 5. Portable gas and gas-tubes first used by Mr. Murdoch, 10. Portable vessels, Gordon’s patent for compressing gas into, 23. Pressure of the gas-holder, how adjusted, 195 ; barometric in- fluence on gas, 262. Pressure of gas-holders, method of calculating, 194. Pressure, remarks on regulation of, 259 ; variations of, during different hours of day and night, 256; corrections for barometric, 334 INDEX. 263 ; corrections for pressure and temperature easily calcu- lated by Mr. Wright’s table, 264 ; necessary for district, 245 ; results of excessive, 245. Pressure-gauge, apparatus for re- cording pressure, 252. Pressure-indicators, 254. Prices at present charged for gas, 24. Profits, argument as to rating on, 312. Profits of large joint-stock com- panies, mode of arriving at, 313. Purification by means of lime in separate purifiers first adopted, 15. Purification, earliest modes of, 169 ; Mr. Croll’s process of separating ammonia, 170 ; plan, section, and description of the vessels used for, in Mr. Croll’s process, 171, 172; Mr. Oroll’s process by means of neutral salts, 174; Mr. Laming’ s process, 175. The Rev. Mr. Bowditch’s process, 177 ; gradual improve- ments in, 141 ; division of pro- cess, 141 ; notice of the ap- paratus used for, 141 ; by means of the washer, 149 ; by means of the scrubber, 152 ; by means of oxide of iron, 167 ; expense of, by Mr. Croll and Mr. Barlow, 166 ; by wet lime, 153. Purifiers, Mr. Croll’s opinion as to dry lime, 173; wet lime, 155; dry lime, construction of, &c., 157. Plan and section of dry lime, showing hydraulic valve, inlet and outlet pipes, 160, 161 ; mode of working the, 162; method of working, and charg- ing them with lime, 163 ; method of determining the size required, 158. Wet lime, 153 ; mode of working, and quantity of lime required, 166. Purifying process, order in which the various part3 succeed each other, 140. Pyrometer, objections to Wedg- wood’s ; Darnell’ s, 64. Radiation of heat from surfaces in air and in water, table show- ing quantity of heat lost by, 145. Rateable value, Mr. Lee’s esti- mate, 318; estimate by Mr. Penfold, 317 ; estimate by the Author, 322. Rating of gas-works, general principles, 309; objections to present mode, 310 ; law of, as laid down in the Parochial Assessment Act, 311. Receivers or syphons in gas mains, 243. Repairs and restorations, allow- ance for, in rating cases, 315. Resin and other materials, pro- posals to make gas from, 22. Resin, Professor Daniell’ s attempts to make gas from, 24. Retort-house, usual form of, 82-, thickness of walls in ; allowance for retorts undergoing repair, 84; cost of erecting, examples and estimates by Mr. Clegg, 85 ; estimates for, by Mr. Croll and Mr. Barlow, 85. Retorts, Murdoch’s experiments on the form of, 14, 91; used in gas-making, 91 ; Brunton’s de- scription of, 92 ; Lowe’s reci- procating, 93 ; Clegg’s revolving web, 93 ; mode of setting iron, 116 ; mode of setting clay, 111 ; made of fire-clay, proposed by Mr. Grafton, 100 ; of clay at Im- perial Company’s works, 111; of clay in Scotland, 101 ; of clay first used in London on an ex- tensive scale by Mr. Croll, 101 ; cement used for jointing clay, 106 ; consumption of fuel for heating, 68 ; comparison of clay andiron, 104; alleged porosity of clay, 103 ; comparative wear and tear of, 98 ; encrustation of carbon in, 73 ; method of clean- ing, 73; Clift’s brick, 101; of clay and iron combination, elevation of those erected by Mr. Croll, 126, 127, &c. ; of clay and iron require different in- INDEX. 335 tensities of heat, 121 ; method of charging them in small works ; general description of the pro- cess of charging, 70 ; number of men required for work- ing, 70 ; method of drawing the charge from, 70 ; method of drawing and renewing the charges in small works, 72; temperatures most advisable for working iron and clay, 67 ; necessity for reducing the pres- sure of gas in the, 73; settings of, diversity of opinion, 114; price of settings, 114; of iron, only useful in small works, 116. Scoop for charging, use of the, 71. Scotch gas-works, clay retorts, 104. Scrubber or coke condenser, 1527 Shadows, comparison of gases by means of, 27 5. Shirley, his Paper in the “ Philo- sophical Transactions,” 8. Site for gas-works, choice of a, 74 ; near a railway, canal, or navi- gable river, very favourable, 75. South Metropolitan works, trials made of the hydrocarbon pro- cess, 306. Specific gravity of gas, mode of ascertaining, 265; Mr. Wright’s apparatus for taking, 265. Specification of gas-holder, single lift, 196; of gas-holder and iron tank, 205 ; of gas-holder of Imperial Company, 200 ; of iron work for gas-works, 198 ; of brick tanks, 186, 188 ; of iron tank, 180. Spedding’s proposal to apply natural gas for lighting White- haven, 7. Splint coal, 52. Station, division of rateable value where gas-works have more than one manufacturing, 329. Station meter, description and engraving of, 227. Statutable allowances in rating gas-works, 315. Sulphuret of carbon, difficulty of separating it from coal gas, 48. Sulphuretted hydrogen, descrip- tion and tests for discovering, 43, 282. Sulphate of ammonia, how made, 296. Tank for receiving products of condensation ; description of, 147 ; connection between the hydraulic main and the, 147 ; method of removing liquids from the, 147. Tanks of gas-holders described, 178; cast-iron, 180; specifica- tion of, 181, 205 ; annular, 183 ; brick and masonry, 183; speci- fication of, 186, 188. Tar, price of, 149. Tar used as fuel, 69. Telescopic gas-holders, 203 ; de- scription of, and engraving showing water-seal, 204 ; at Imperial Company’s station, Hackney, 205. Temperature and long-continued distillation, effects of, 48. Temperature of furnaces corre- sponding with colours, 65. Temperature of gas, correction for, 261. Temperature, injurious effects of low, 67 ; formula for correcting the volume of the gas according to, 267.. Testing with bromine and chlorin e, mode of, 273. Tests for the various impurities contained in coal gas, 282. Thomson, Dr., his divisions of coal, 51. Yalve, the hydraulic, 135 : en- gravings and description of two kinds of, 135 ; slide, de- scription and engravings of, i38. Veneration of the ancient world for burning flames, 2, Vitruvius and others, writings of, 4. 336 INDEX. Wash-vessel, position in which it is placed, 149; plan of a, 149; side elevation and description of, 150 ; front elevation of, 151. Water gas, 304. Watson, Dr., discoveries of, 9. Wedgwood’s pyrometer, 64. Weighing gas, 281. Wet and dry lime purifiers, 153. Wickstead’s India-rubber rings for joints of pipes, 236. Winsor, Mr., his first exhibition and lectures on ga3-lighting, 12; patent obtained by, 15; assumed the title of inventor of gas, 16 ; his energetic efforts to establish a Company, 17; occupied premises in Pall Mall, 1 8 ; the subscribers applied to Parliament, 18 ; succeeded in getting incorporated the “ Gas- Light and Coke Company/' 19. Works, gas, magnitude described, 81 ; plan of, 78. Wright, Mr., his apparatus for detecting sulphuret of carbon in coal gas, 283 ; his apparatus for taking the specific gravity of gas, 282 ; his table for as- certaining specific gravity, 265, THE END, VIRTUE AXD CO., PRINTERS, CITY ROAD, LONBOJf. 3 : WORKS PUBLISHED BY LOCKWOOD & CO. “ No Englishman ought to be without this book!' EVERY MAN’S OWN LAWYER; a Handy- Book of the Prin- ciples of Law and Equity. By A Barrister. 8th Edition, carefully revised, including a Summary of the New Bankruptcy Laws, the Fraudulent Debtors Act, the Reported Cases of the Courts of Law and Equity, &c. With Notes and References to the Authorities. i2mo, price 6s. Sd. (saved at every consultation), strongly bound. Comprising the Rights and Wz'ongs of Individuals , Mercantile and Com- mercial % Law , Criminal Law , Parish Law , County . Court Lazo, Game and Fishery Laws, Poor Metis Lawsuits . I THE : Bankruptcy. Bills of Exchange. Contracts and Agreements. 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I. — Landlord and Tenant : their Position and Connections. Chap. II. — Lease of Land, Conditions and Restrictions; Choice of Tenant, and Assignation of the Deed. Chap. III. — Cultivation of Land, and Rotation of Crops. Chap. IV. — Buildings necessary on Cultivated Lands : Dwelling-houses, Farmeries, and Cottages for Labourers. Chap. V. — Laying out Farms, Roads, Fences, and Gates. Chap. VI. — Plantations, Young and Old Timber. Chap. VII. — Meadows and Embankments, Beds of Rivers, Water Courses, and Flooded Grounds. Chap. VIII. — Land Draining, Opened and Covered : Plan, Execution, and Arrangement between Landlord and Tenant. Chap. IX. — Minerals, Working, and Value. Chap. X. — Expenses of an Estate. Chap. XI. — Valuation of Landed Property ; of the Soil, of Houses, of Woods, of Minerals, of Manorial Rights, of Royalties, and of Fee Farm Rents. Chap. XII. — Land Steward and Farm Bailiff : Qualifications and Duties. Chap. XIII. — Manor Bailiff, Woodreeve, Gardener, and Gamekeeper; their Position and Duties. Chap. XIV. — Fixed Days of Audit : Half-yearly Payments of Rents, Form of Notices, Receipts, and of Cash Books, General Map of Es- tates, &c. PEIZE MEDAL, INTERNATIONAL EXHIBITION. 1862 was awarded to the Publishers of WE ALE’S RUDIMENTARY, SCIENTIFIC, EDUCATIONAL, AND CLASSICAL SERIES, OF WORKS SUITABLE FOR Engineers , Architects , Builders , Artisans , and Students generally , as well as to those interested in Workmen's Libraries , Free Libraries , Literary and Scientific Insti- tutions, Colleges, Schools, Science Classes, dc., dc. *** THE ENTIRE SERIES IS FREELY ILLUSTRATED WHERE REQUISITE. (The Volumes contained in this List are hound in limp cloth , except where otherwise stated . ) AGRICULTURE, 66. CLAY LANDS AND LOAMY SOILS, by J. Donaldson. Is. 140. SOILS, MANURES, AND CROPS, by R. Scott Burn. 25. 141. FARMING, AND FARMING ECONOMY, Historical and Practical, by R. Scott Burn. 35. 142. 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NATURAL PHILOSOPHY, by Charles Tomlinson. Is. 3. GEOLOGY, by Major-Gen. Portlock. New Edition. Is. 6 d. 4. MINERALOGY, by A. Ramsay, Jun. 3s. 7. ELECTRICITY, by Sir W. S. Harris. Is. 6d. 7*. GALVANISM, ANIMAL AND VOLTAIC ELECTRICITY, by Sir W. S. Harris. Is. 6r. cloth. Contents . — Introductory Remarks ; Beams Loaded at Centre ; Beams Loaded at unequal distances between supports ; Beams uniformly Loaded ; Girders with triangu- lar bracing Loaded at centre ; Ditto, Loaded at unequal distances between supports ; Ditto, uniformly Loaded ; Calculation of the Strains on Girders with triangular Basings ; Cantilevers; Continuous Girders; Lattice Girders; Girders with Vertical Struts and Diagonal Ties ; Calculation of the Strains on Ditto ; Bqw and String Girders ; Girders of a form not belonging to any regular figure ; Plate Girders ; Ap- portionments of Material to Strain ; Comparison of different Girders ; Proportion of Length to Depth of Girders ; Character of the Work ; Iron Roofs. Construction of Iron Beams, Pillars, &c. IRON AND HEAT, Exhibiting the Principles concerned in the Construction of Iron Beams, Pillars, and Bridge Girders, and the Action of Heat in the Smelting Furnace. By James Armour, C.E. Woodcuts, i2mo, cloth boards, 3 s. 6 d. ; cloth limp, 2 s. 6 d. [Just published. Power in Motion. POWER IN MOTION : Horse Power, Motion, Toothed Wheel Gearing, Long and Short Driving Bands, Angular Forces, &c. By James Armour, C.E. With 73 Diagrams. i2mo, cloth boards, 3 s. 6 d. [ This day. Trigonometrical Surveying. AN OUTLINE OF TPIE METHOD OF CONDUCTING A TRIGONOMETRICAL SURVEY, for the Formation of Geo- graphical and Topographical Maps and Plans, Military Recon- naissance, Levelling, &c., with the most useful Problems in Geodesy and Practical Astronomy, and Formulae and Tables for Facilitating their Calculation. By Major-General Frome, R.E., Inspector- General of Fortifications, &c. Third Edition, revised and improved. With 10 Plates and 113 Woodcuts. Royal 8vo, 12s. cloth. 8 WORKS PUBLISHED BY LOCKWOOD & CO. Hydraulics. HYDRAULIC TABLES, CO-EFFICIENTS, and FORMULAE for finding the Discharge of Water from Orifices, Notches, Weirs, Pipes, and Rivers. By John Neville, Civil Engineer, M.R.I.A. Second Edition, with extensive Additions, New Formulae, Tables, and General Information on Rain-fall, Catchment-Basins, Drainage, Sewerage, Water Supply for Towns and Mill Power. With nume- rous Woodcuts, 8vo, i6j\ cloth. * ** This work contains a vast number of different hydraulic formulae, and the most extensive and accurate tables yet published for finding the mean velocity of discharge from triangular, quadri- lateral, and circular orifices, pipes, and rivers ; with experimental results and co-efficients ; effects of friction ; of the velocity of approach ; and of curves, bends, contractions, and expansions ; the best form of channel ; the drainage effects of long and short weirs, and weir-basins ; extent of back-water from weirs ; contracted channels ; catchment-basins ; hydrostatic and hydraulic pressure ; water-power, &c. &c. Levelling. A TREATISE on the PRINCIPLES and PRACTICE of LEVELLING ; showing its Application to Purposes of Railway and Civil Engineering, in the Construction of Roads ; with Mr. Telford’s Rules for the same. By Frederick W. Simms, F.G.S., M. Inst. C.E. Fifth Edition, very carefully revised, with the addition of Mr. Law’s Practical Examples for Setting out Railway Curves, and Mr. Traut wine’s Field Practice of Laying out Circular Curves. With 7 Plates and numerous Woodcuts. 8vo, 8s. 6d. cloth. *** Trautwine on Curves, separate, price 5.5-. “One of the most important text-books for the general surveyor, and there is scarcely a question connected with levelling for which a solution would be sought but that would be satisfactorily answered by consulting the volume.” — Mining Journal. “ The text-book on levelling in most of our engineering schools and colleges.” — Engineer. “The publishers have rendered a substantial service to the profession, especially to the younger members, by bringing out the present edition of Mr. Simms’s useful work.” — E ngineering. Tunnelling. PRACTICAL TUNNELLING ; explaining in Detail the Setting out of the Works ; Shaft Sinking and Heading Driving ; Ranging the Lines and Levelling Under-Ground ; Sub-Excavating, Timber- ing, and the construction of the Brickwork of Tunnels ; with the Amount of Labour required for, and the Cost of the various Por- tions of the Work. By Fredk. W. Simms, F. R. A. S., F. G.S., M. Inst. C.E., Author of “A Treatise on the Principles and Practice of Levelling,” &c. &c. Second Edition, revised by W. Davis Haskoll, Civil Engineer, Author of “The Engineer’s Field-Book,” &c. &c. With 16 large folding Plates and numerous Woodcuts. Imperial 8vo, 1 l. is. cloth. WORKS PUBLISHED BY LOCKWOOD & CO. 9 Strength of Cast Iron , &c. A PRACTICAL ESSAY on the STRENGTH of CAST IRON and OTHER METALS ; intended for the Assistance of Engineers, Iron-Masters, Millwrights, Architects, Founders, Smiths, and others engaged in the Construction of Machines, Buildings, &c. ; containing Practical Rules, Tables, and Examples, founded on a series of New Experiments ; with an Extensive Table of the Pro- perties of Materials. By the late Thomas Tredgold, Mem. Inst. C.E., Author of “ Elementary Principles of Carpentry,” “ History of the Steam-Engine,” &c. Fifth Edition, much improved. Edited by Eaton Hodgkinson, F.R.S. ; to which are added EXPERIMENTAL RESEARCHES on the STRENGTH and OTHER PROPERTIES of CAST IRON ; with the Develop- ment of New Principles, Calculations Deduced from them, and Inquiries Applicable to Rigid and Tenacious Bodies generally. By the Editor. The whole Illustrated with 9 Engravings and nume- rous Woodcuts. 8vo, 1 2s. cloth. *** Hodgkinson’s Experimental Researches on the Strength and Other Properties of Cast Iron may be had separately. With Engravings and Woodcuts. 8vo, price 6s. cloth. The Iligh-Pressu re Steam Engine. THE HIGH-PRESSURE STEAM ENGINE ; an Exposition of its Comparative Merits, and an Essay towards an Improved System of Construction, adapted especially to secure Safety and Economy. By Dr. Ernst Alban, Practical Machine Maker, Plau, Mecklenberg. Translated from the German, with Notes, by Dr. Pole, F.R.S., M. Inst. C.E., &c. &c. With 28 fine Plates, 8vo, 1 6s. 6d. cloth. “ A work like this, which goes thoroughly into the examination of the high-pressure engine, the. boiler, and its appendages, &c., is exceedingly useful, and deserves a place in every scientific library.” — Steam Shipping Chronicle. Tables of Curves. TABLES OF TANGENTIAL ANGLES and MULTIPLES for setting out Curves from 5 to 200 Radius. By Alexander Beazeley, M. Inst. C.E. Printed on 48 Cards, and sold in a cloth box, waistcoat-pocket size, price 3s. 6d. “ Each table is printed on a small cafd, which, being placed on the theodolite, leaves the hands free to manipulate the instrument — no small advantage as regards the rapidity of work. They are clearly printed, and compactly fitted into a small case for the pocket — an arrangement that will recommend them to all practical men.” — Engineer. “ Very handy : a man may know that all his day’s work must fall on two of these cards, which he puts into his own card-case, and leaves the rest behind.” — Athenceum. Laying Out Curves . THE FIELD PRACTICE of LAYING OUT CIRCULAR CURVES for RAILROADS. By John C. Trautwine, C.E., of the United States (extracted from Simms’s Work on Levelling). 8vo, $s. sewed. IO WORKS PUBLISHED BV LOCKWOOD & CO. Estimate and Pyice Book. THE CIVIL ENGINEER’S AND CONTRACTOR’S ESTI- MATE AND PRICE BOOK for Plome or Foreign Service : in reference to Roads, Railways, Tramways, Docks, Harbours, Forts, Fortifications, Bridges, Aqueducts, Tunnels, Sewers, Water- works, Gasworks, Stations, Barracks, Warehouses, &c. &c. &c. With Specifications for Permanent Way, Telegraph Materials, Plant, Maintenance, and Working of a Railway ; and a Priced List of Machinery, Plant, Tools, &c., required in the execution of Public Works. By W. Davis Haskoll, C.E. Plates and numerous Woodcuts. Published annually. Demy 8vo, cloth, 6s. As furnishing a variety of data on every conceivable want to civil engineers and contractors, this book has ever stood perhaps unrivalled .’’—Architect, Jan. 21, 1871. “ The care with which the particulars are arranged reflects credit upon the author, each subject being divided into tables under their own special heads, so that no difficulty arises in finding the exact thing one wants. The value of the work to the student and the experienced contractor is inestimable.” — Mechanic's Mag. , Feb. 3. “ Mr. Haskoll has bestowed very great care upon the preparation of his estimates and prices, and the work is one which appears to us to be in every way deserving of confidence.”' — Builder's Weekly Reporter , Jan. 27, 1871. Surveying ( Land and Marine). LAND AND MARINE SURVEYING, in Reference to the Preparation of Plans for Roads and Railways, Canals, Rivers, Towns’ Water Supplies, Docks and Harbours ; with Description and Use of Surveying Instruments. By W. Davis Haskoll, C.E., Author of “The Engineer’s Field Book,” “ Examples of Bridge and Viaduct Construction,” &c. Demy 8vo, price 12s. 6d. cloth, with 14 folding Plates, and numerous Woodcuts. “ * Land and Marine Surveying' is a most useful and well arranged book for the aid of a student We can strongly recommend it as a carefully- written and valuable text-book.” — Builder , July 14, 1868. “ He only who is master of his subject can present it in such a way as to make it intelligible to the meanest capacity. It is in this that Mr. Haskoll excels. He has knowledge and experience, and can so give expression to it as to make any matter on which he writes, clear to the youngest pupil in a surveyor’s office The work will be found a useful one to men of experience, for there are few such who will not get some good ideas from it ; but it is indispensable to the young practitioner.” — Colliery Guardian , May 9, 1868. “ A volume which cannot fail to prove of the utmost practical utility It is one which may be safely recommended to all students who aspire to become clean and expert surveyors ; and from the exhaustive manner in which Mr. Haskoll has placed his long experience at the disposal of his readers, there will henceforth be no excuse for the complaint that young practitioners are at a disadvantage, through the neglect of their seniors to point out the importance of minute details, since they can readily supply the deficiency by the study of the volume now under consideration.”— Mining Journal , May 5, 1868. Engineering Fieldwork. THE PRACTICE OF ENGINEERING FIELDWORK, applied to Land and Hydraulic, Hydrographic, and Submarine Surveying and Levelling. Second Edition, revised, with consider- able additions, and a Supplementary Volume on WATER- WORKS, SEWERS, SEWAGE, and IRRIGATION. By W. Davis Haskoll, C.E. Numerous folding Plates. Demy 8vo, 2 vols. in one, cloth boards, 1 /. IJ*. (published at 2/. 4J.) WORKS PUBLISHED BY LOCKWOOD & CO. ii Fire Engineering, FIRES, FIRE-ENGINES, AND FIRE BRIGADES. With a History of Manual and Steam Fire-Engines, their Construc- tion, Use, and Management ; Remarks on Fire-Proof Build- ings, and the Preservation of Life from Fire ; Statistics of the Fire Appliances in English Towns ; Foreign Fire Systems ; Hints for the formation of, and Rules for, Fire Brigades ; and an Account of American Steam Fire-Engines. By Charles F. T. Young, C.E., Author of “ The Economy of Steam Power on Common Roads, ” &c. With numerous Illustrations, Diagrams, &c., handsomely printed, 544 pp., demy 8vo, price I /. 4 s, cloth. “ A large well-filled and useful book upon a subject which possesses a wide and increasing public interest To such of our readers as are interested in the subject of fires and fire apparatus we can most heartily commend this book It is really the only English work we now have upon the subject.” — Engineeruig. “ Mr. Young has proved by his present work that he is a good engineer, and pos- sessed of sufficient literary energy to produce a very readable and interesting volume.” — Engineer. “A volume which must be regarded as the text-book of its subject, and which in point of interest and intrinsic value is second to no contribution to a special depart- ment of history with which we are acquainted. ‘ Fires, Fire-Engines, and Fire Brigades’ is the production of an earnest and diligent writer who comes to the task he has undertaken with a thorough love of it, and a firm determination to do it justice. . . . . The style of the work is admirable It has the surpassing merit of being thoroughly reliable.” — Eistirance Record. “Great credit is unquestionably due to Mr. Young for having brought before the public the results of his exploration in this hitherto untrodden field. We strongly recommend the book to the notice of all who are in any way interested in fires, fire- engines, or fire-brigades.” — Mechanics’ Magazine. Manual of Mining Tools. MINING TOOLS. For the use of Mine Managers, Agents, Mining Students, &c. By William Morgans, Lecturer on Prac- tical Mining at the Bristol School of Mines. i2mo. With an Atlas of Plates, containing 200 Illustrations. 4to. [ Just ready. Earthwork , Measurement and Calculation of. A MANUAL on EARTHWORK. By Alex. J. S. Graham, C.E., Resident Engineer, Forest of Dean Central Railway. With numerous Diagrams. i8mo, 2 s. 6 d. cloth. “We can cordially recommend the work to the notice of our readers.” — Building News. “As a really handy book for reference, we know of no work equal to it ; and the railway engineers and others employed in the measurement and calculation of earth- work will find a great amount of practical information very admirably arranged, and available for general or rough estimates, as well as for the more exact calculations required in the engineers’ contractor’s offices.” — Artizan. “ The object of this little book is an investigation of all the principles requisite for the measurement and calculation of earthworks, and a consideration of the data neces- sary for such operations. The author has evidently bestowed much care in effecting this object, and points out with much clearness the results of his own observations, derived from practical experience. The subjects treated of are accompanied by well- executed diagrams and instructive examples.” — Army and Navy Gazette. 12 WORKS PUBLISHED BY LOCKWOOD & CO. Field-Book for Engineers. THE ENGINEER’S, MINING SURVEYOR’S, * and CON- TRACTOR’S FIELD-BOOK. By W. Davis Haskoll, Civil Engineer. Second Edition, much enlarged, consisting of a Series of Tables, with Rules, Explanations of Systems, and Use of Theo- dolite for Traverse Surveying and Plotting the Work with minute accuracy by means of Straight Edge and Set Square only ; Levelling with the Theodolite, Casting out and Reducing Levels to Datum, and Plotting Sections in the ordinary manner; Setting out Curves with the Theodolite by Tangential Angles and Multiples with Right and Left-hand Readings of the Instrument ; Setting out Curves without Theodolite on the System of Tangential Angles by Sets of Tangents and Offsets; and Earthwork Tables to 80 feet deep cal- culated for every 6 inches in depth. With numerous wood-cuts, i2mo, price 12 s. cloth. “ A very useful work for the practical engineer and surveyor. Every person engaged in engineering field operations will estimate the importance of such a work and the amount of valuable time which will be saved by reference to a set of reliable tables prepared with the accuracy and fulness of those given in this volume.” — Rail- way Nezus. “The book is very handy, and the author might have added that the separate tables of sines and tangents to every minute will make it useful for many other purposes, the genuine traverse tables existing all the same.” — Atkenceum. “ The work forms a handsome pocket volume, and cannot fail, from its portability and utility, to be extensively patronised by the engineering profession.” — Mining Journal. “We know of no better field-book of reference or collection of tables than that Mr. Haskoll has given.” — Artizan. “ A series of tables likely to be very useful to many civil engineers.” — Building Nezvs. “A very useful book of tables for expediting field-work operations. . . . The present edition has been much enlarged. ” — Mechanics' Magazine. “We strongly recommend this second edition of Mr. Haskoll’s ‘ Field Book* to all classes of surveyors.” — Colliery Guardian. Railway Engineering. THE PRACTICAL RAILWAY ENGINEER. A concise Description of the Engineering and Mechanical Operations and Structures which are combined in the Formation of Railways for Public Traffic ; embracing an Account of the Principal Works exe- cuted in the Construction of Railways ; with Facts, Figures, and Data, intended to assist the Civil Engineer in designing and executing the important details required. By G. Drysdale Dempsey, C.E. Fourth Edition, revised and greatly extended. With 71 double quarto Plates, 72 Woodcuts, and Portrait of George Stephenson. One large vol. 4to, 2/. I2J-. 6 d. cloth. Harbours. THE DESIGN and CONSTRUCTION of HARBOURS. By Thomas Stevenson, F.R.S.E., M.I.C.E. Reprinted and en- larged from the Article “Harbours,” in the Eighth Edition of “ The Encyclopaedia Britannica.” With 10 Plates and numerous Cuts. 8vo, ioj*. 6 d. cloth. WORKS PUBLISHED BV LOCKWOOD & CO. 13 Bridge Construction in Masonry , Timber, and Iron. EXAMPLES OF BRIDGE AND VIADUCT CONSTRUC- TION OF MASONRY, TIMBER, AND IRON ; consisting of 46 Plates from the Contract Drawings or Admeasurement of select Works. By W. Davis Haskoll, C.E. Second Edition, with the addition of 554 Estimates, and the Practice of Setting out Works, illustrated with 6 pages of Diagrams. Imp. 4to, price 2/. I2J-. 6d. lialf-morocco. “ One of the very few works extant descending to the level of ordinary routipe, and treating on the common every-day practice of the railway engineer. ... A work of the present nature by a man of Mr. Haskoll’s experience, must prove invaluable to hundreds. The tables of estimates appended to this edition will considerably enhance its value.” — Engineering. “ We must express our cordial approbation of the work just issued by Mr. Haskoll. .... Besides examples of the best and most economical forms of bridge construction, the author has compiled a series of estimates which cannot fail to be of service to the practical man. . . . The examples Of bridges are selected from those of the most notable construction on the different lines of the kingdom, and their details may consequently be safely followed.” — Railway News. “ A very valuable volume, and may be added usefully to the library of every young engineer. ” — Builder. “ An excellent selection of examples, very carefully drawn to useful scales of pro- portion. ” — A rtizan. Mathematical and Drawing Instruments. A TREATISE ON THE PRINCIPAL MATHEMATICAL AND DRAWING INSTRUMENTS employed by the Engineer, Architect, and Surveyor. By Frederick W. Simms, F.G.S., M. Inst. C.E., Author of “Practical Tunnelling,” &c. &c. Third Edition, with a Description of the Theodolite, together with Instruc- tions in Field Work, compiled for the use of Students on commenc- ing practice. With numerous Cuts. i2mo, price 3s. 6d. cloth. Oblique Arches. A PRACTICAL TREATISE ON THE CONSTRUCTION of OBLIQUE ARCHES. By John Hart. Third Edition, with Plates. Imperial 8vo, price 8s. cloth. %* The small remaining stock of this work , which has been un- obtainable for some time , has just been purchased by Lockwood St Co. Oblique Bridges. A PRACTICAL and THEORETICAL ESSAY on OBLIQUE BRIDGES, with 13 large folding Plates. By Geo. Watson Buck, M. Inst. C.E. Second Edition, corrected by W. PI. Barlow, M. Inst. C.E. Imperial 8vo, 12 s. cloth. “The standard text-book for all engineers regarding skew arches, is Mr. Buck’s treatise, and it would be impossible to consult a better.” — Engitieer. “A very complete treatise on the subject, re-edited by Mr. Barlow, who has added to it a method of making the requisite calculations without the use of trigonometrical fo rmulae. ’ ' — Builder. 14 WORKS PUBLISHED BY LOCKWOOD & CO. IVeale’s Series of Rudimentary Works. These highly popular and cheap Series of Books, now comprising upwards of Two Hundred and Fifty distinct Works in almost every department of Science, Art, and Education, are recommended to the notice of Engineers, Architects, Builders, Artizans, and Students gene- rally, as well as to those interested in Workmen’s Libraries, Free Libraries, Literary and Scientific Institutions, Colleges, Schools, Science Classes, &c., &c. Lists of the several Series may be had on application to LOCKWOOD & CO. The following is a Selection of the Works on Civil Engineering : — STEAM ENGINE. By Dr. Lardneb. ij. TUBULAR AND IRON GIRDER BRIDGES, including the Britannia and Conway Bridges. By G. D. Dempsey, is. 6d. STEAM BOILERS, their Construction and Management. By R. Armstrong. With Additions, is. 6 d. RAILWAY CONSTRUCTION. By Sir M. Stephenson. New Edition, 2 *. 6 d. STEAM ENGINE, Mathematical Theory of. By T. Baker, is. ENGINEER’S GUIDE TO THE ROYAL AND MERCANTILE NAVIES. By a Practical Engineer. Revised by D. F. McCarthy. 3.?. LIGHTHOUSES, their Construction and Illumination. By Alan Stevenson. 3 s. CRANES AND MACHINERY FOR RAISING HEAVY BODIES, the Art of Constructing. By J. Glynn, ij. CIVIL ENGINEERING. By H. Law and G. R. Burnell. New Edition, 3 s . DRAINING DISTRICTS AND LANDS. By G. D. Dempsey, is Ad. ) The DRAINING AND SEWAGE OF TOWNS AND BUILDINGS. By f2v0ls.ini, G. D. Dempsey. 2 s. J SE- WELL-SINKING, BORING, AND PUMP WORK. By J. G. Swindell ; Revised by G. R. Burnell, is. ROAD-MAKING AND MAINTENANCE OF MACADAMISED ROADS. By Gen. Sir J. Burgoyne. is. 6d. AGRICULTURAL ENGINEERING, BUILDINGS, MOTIVE POWERS, FIELD MACHINES, MACHINERY AND IMPLEMENTS. By G. H. Andrews, C.E. 3 s. ECONOMY OF FUEL. By T. S. Prideaux. ir. 6 d. EMBANKING LANDS FROM THE SEA. By J. Wiggins. 2j. WATER POWER, as applied to Mills, &c. By J. Glynn. 2 s. GAS WORKS, AND THE PRACTICE OF MANUFACTURING AND DISTRIBUTING COAL GAS. By S. Hughes, C.E. 3 s . WATERWORKS FOR THE SUPPLY OF CITIES AND TOWNS. By S. Hughes, C.E. 3 j. SUBTERRANEOUS SURVEYING, AND THE MAGNETIC VARIATION OF THE NEEDLE. By T. Fenwick, with Additions by T. Baker. 2 s. 6 d. CIVIL ENGINEERING OF NORTH AMERICA. By D. Stevenson. 3 j. HYDRAULIC ENGINEERING. By G. R. Burnell. 3s . RIVERS AND TORRENTS, with the Method of Regulating their Course and Channels, Navigable Canals, &c., from the Italian of Paul Frisi. 2 s. 6 d. COMBUSTION OF COAL AND THE PREVENTION OF SMOKE. By C. Wye Williams, M.I. C.E. 3 s. WATER POWER, as applied to Mills, &c. By J. Glynn. 2 s. MARINE ENGINES and STEAM VESSELS and the SCREW. By Robert Murray, C.E. Fifth Edition. 3 s. ENGINEER’S GUIDE TO THE ROYAL AND MERCANTILE NAVIES. By a Practical Engineer. Revised by D. F. McCarthy. WORKS PUBLISHED BY LOCKWOOD & CO. 15 ARCHITECTURE, &c. Construction. THE SCIENCE of BUILDING : an Elementary Treatise on the Principles of Construction. Especially adapted to the Re- quirements of Architectural Students. By E. Wyndham Tarn, M.A., Architect. Illustrated with 47 Wood Engravings. Demy 8vo, price 8s. 6d. cloth. [Recently published. “ A very valuable book, which we strongly recommend to all students.” — Builder. “ A modest and valuable book of reference for the student. . . . The formulae will be found perfectly intelligible and available by the class for whom they are intended.” — A thenceum. “While Mr. Tarn’s valuable little volume is quite sufficiently scientific to answer the purposes intended, it is written in a style that will deservedly make it popular. The diagrams are numerous and exceedingly well executed, and the treatise does credit alike to the author and the publisher.” — Engmeer , Feb. 17, 1871. “No architectural student should be without this hand-book of constructional knowledge.” — A rchitect. “The book is very far from being a mere compilation ; it is an able digest of information which is only to be found scattered through various works, and contains more really original writing than many putting forth far stronger claims to originality. .... Mr. Tarn has done his work exceedingly well, and he has produced a book which ought to earn him the thanks of all architectural students.” — E 7 igineering. Beatoiis P ocket Estimator . THE POCKET ESTIMATOR FOR THE BUILDING TRADES, being an easy method of estimating the various parts of a Building collectively, more especially applied to Carpenters* and Joiners’ work, priced according to the present value of material and labour. By A. C. Beaton, Author of ‘ Quantities and Measurements.’ Numerous Woodcuts. \_In the Press. Villa Architecture. A HANDY BOOK of VILLA ARCHITECTURE ; being a Series of Designs for Villa Residences in various Styles. With Detailed Specifications and Estimates. By C. Wickes, Architect, Author of “ The Spires and Towers of the Mediaeval Churches of England,” &c. First Series, consisting of 30 Plates ; Second Series, 31 Plates. Complete in 1 vol., 4to, price 2/. ioa half morocco. Either Series separate, price 1 l. *js. each, half morocco. “ The whole of the designs bear evidence of their being the work of an artistic architect, and they will prove very valuable and suggestive to architects, students, and amateurs.” — Building News. The Architect' s Guide. THE ARCHITECT’S GUIDE ; or, Office and Pocket Com- panion for Engineers, Architects, Land and Building Surveyors, Contractors, Builders, Clerks of Works, &c. By W. Davis Haskoll, C.E., R. W. Billings, Architect, F. Rogers, and P. Thompson. With numerous Experiments by G. Rennie, C.E., &c. Woodcuts, i2mo, cloth, price 3s. 6d. Vitruvius' A rchitecture. THE ARCHITECTURE OF MARCUS VITRUVIUS POLLIO. Translated by Joseph Gwilt, F.S.A., F.R.A.S. Numerous Plates. i2mo, cloth limp, price $s. 16 WORKS PUBLISHED BY LOCKWOOD & CO. The Young Architect' s Book. HINTS TO YOUNG ARCHITECTS ; comprising Advice to those who, while yet at school, are destined to the Profession ; to such as, having passed their pupilage, are about to travel ; and to those who, having completed their education, are about to practise. By George Wightwick, Architect, Author of “The Palace of Architecture,” &c. &c. Second Edition. With numerous Wood- cuts. 8 vo, 7 x., extra cloth. Drawing for Builders and Students . PRACTICAL RULES ON DRAWING for the OPERATIVE BUILDER and YOUNG STUDENT in ARCHITECTURE. By George Pyne, Author of a “ Rudimentary Treatise on Per- spective for Beginners.” With 14 Plates, 4to, Js. 6d ., boards. Contents.— I. Practical Rules on Drawing — Outlines. II. Ditto — the Grecian and Roman Orders. III. Practical Rules on Drawing — Perspective. IV. Practical Rules on Light and Shade. V. Practical Rules on Colour, &c. &c. Drawing for Engineers, Cfc. THE WORKMAN’S MANUAL OF ENGINEERING DRAWING. By John Maxton, Instructor in Engineering Drawing, South Kensington. With upwards of 300 Plates and Diagrams. i2mo, cloth, strongly bound, 4 s. 6d. [This day. Cottages , Villas, and Country Houses. DESIGNS and EXAMPLES of COTTAGES, VILLAS, and COUNTRY HOUSES ; being the Studies of several eminent Architects and Builders ; consisting of Plans, Elevations, and Per- spective Views ; with approximate Estimates of the Cost of each. In 4to, with 67 plates, price 1 /. u., cloth. Weale's Builder s and Contractor s Price Book. THE BUILDER’S AND CONTRACTOR’S PRICE BOOK (Lockwood & Co.’s, formerly Weale’s). Published Annually. Containing Prices for Work in all branches of the Building Trade, with Items numbered for easy reference, and an Appendix of Tables, Notes, and Memoranda, arranged to afford detailed infor- mation, commonly required in preparing Estimates, &c. Originally Edited by the late Geo. R. Burnell, C.E., &c. i2mo, 4s., cloth. “A multitudinous varietv of useful information for builders and contractors With its aid the prices for all work connected with the building trade may be esti- mated. Building News. “ Carefully revised, admirably arranged, and clearly printed, it offers at a glance a ready method of preparing an estimate or specification upon a basis that is unquestion- able. A reliable book of reference in the event of a dispute between employer and employed. ” — Engineer. “ Well done and reliable. It is the duty of a just critic to point out where any improvement can be made in any work, but Mr. Burnell has anticipated all objections in his clearly-printed book. We therefore recommend it to all branches of the pro- fession. ” — English Mechanic. “Mr. Burnell has omitted nothing from this work that could tend to render it valuable to the builder or contractor.” — Mechanic's Magazine. WORKS PUBLISHED BY LOCKWOOD & CO. 17 Handbook of Specifications. THE HANDBOOK OF SPECIFICATIONS ; or, Practical Guide to the Architect, Engineer, Surveyor, and Builder, in drawing up Specifications and Contracts for Works and Constructions. Illustrated by Precedents of Buildings actually executed by eminent Architects and Engineers. Preceded by a Preliminary Essay, and Skeletons of Specifications and Contracts, &c., &c., and explained by numerous Lithograph Plates and Woodcuts. By Professor Thomas L. Donaldson, President of the Royal Institute of British Architects, Professor of Architecture and Construction, University College, London, M.I. B.A., Member of the various European Academies of the Fine Arts. With A Review of the Law of Contracts, and of the Responsibilities of Architects, Engineers, and Builders. By W. Cunningham Glen, Barrister-at-Law, of the Middle Temple. 2 vols., 8vo, with upwards of 1100 pp. of text, and 33 Lithographic Plates, cloth, 2/. 2 s. (Published at 4 /. ) “ In these two volumes of 1,100 pages (together), forty-four specifications of executed works are given, including the specifications for parts of the new Houses of Parliament, hy Sir Charles Barry, and for the "new Royal Exchange, by Mr. Tite, M.P. The latter, in particular, is a very complete and remarkable document. It embodies, to a great extent, as Mr. Donaldson mentions, ‘ the bill of quantities, with the description of the works,’ and occupies more than 100 printed pages. “Amongst the other known buildings, the specifications of which are given, are the Wiltshire Lunatic Asylum (Wyatt and Brandon) ; Tothill Fields Prison (R. Abra- ham) ; the City Prison, Holloway (Bunning) ; the High School, Edinburgh (Hamilton) ; Clothworkers’ Hall, London (Angel) ; Wellington College, Sandhurst (J. Shaw) ; Houses in Grosvenor Square, and elsewhere ; St. George’s Church, Doncaster (Scott) ; several works of smaller size by the Author, including Messrs. Shaw’s Ware- house in Fetter Lane, a very successful elevation ; the Newcastle-upon-Tyne Railway Station (J. Dobson) ; new Westminster Bridge (Page) ; the High Level Bridge, New- castle (R. Stephenson) ; various works on the Great Northern Railway (Brydone) ; and one French specification for Houses in the Rue de Rivoli, Paris (MM. Armand, Hittorff, Pellechet, and Rohault de Fleury, architects). The last is a very elaborate composition, occupying seventy 'pages. The majority of the specifications have illus- trations in the shape of elevations and plans. “ We are most glad to have the present work. It is valuable as a record, and more valuable still as a book of precedents. “ About 140 pages of the second volume are appropriated to an exposition of the law in relation to the legal liabilities of engineers, architects, contractors, and builders, by Mr. W. Cunningham Glen, Barrister-at-law ; intended rather for those persons than for the legal practitioner. Suffice it, in conclusion, to say in words what our readers will have gathered for themselves from the particulars we have given, that Donaldson’s Handbook of Specifications must be bought by all architects.” — Builder . Mechanical Engineering. A PRACTICAL TREATISE ON MECHANICAL ENGI- NEERING: comprising Metallurgy, Moulding, Casting, Forging, Tools, Workshop Machinery, Mechanical Manipulation, Manufac- ture of the Steam Engine, &c. &c. With an Appendix on the Analysis of Iron and Iron Ore, and Glossary of Terms. By Francis Campin, C.E. Illustrated with 91 Woodcuts and 28 Plates of Slotting, Shaping, Drilling, Punching, Shearing, and Riveting Machines — Blast, Refining, and Reverberatory Furnaces — Steam Engines, Governors, Boilers, Locomotives, &c. Demy 8vo, cloth, price 12 s. i8 WORKS PUBLISHED BY LOCKWOOD & CO. Grantham s Iron Ship- Building , enlarged. ON IRON SHIP-BUILDING ; with Practical Examples and Details. Fifth Edition. Imp. 4to, boards, enlarged from 24 to 40 Plates (21 quite new), including the latest Examples. Together with separate Text, i2mo, cloth limp, also considerably enlarged, By John Grantham, M. Inst. C.E., &c. Price 2/. 2 s. complete. Description of Plates . 1. Hollow and Bar Keels, Stem and Stern Posts. [Pieces. 2. Side Frames, Floorings, and Bilge 3. Floorings continued- — Keelsons, Deck Beams, Gunwales, and Stringers. 4. Gunwales continued — Lower Decks, and Orlop Beams. 4 a. Gunwales and Deck Beam Iron. 5. Angle-Iron, T Iron, Z Iron, Bulb Iron, as Rolled for Building. 6. Rivets, shown in section, natural size ; Flush and Lapped Joints, with Single and Double Riveting. 7. Plating, three plans ; Bulkheads and Modes of Securing them. 8. Iron Masts, with Longitudinal and Transverse Sections. 9. Sliding Keel, Water Ballast, Moulding the Frames in Iron Ship Building, Levelling Plates. 10. Longitudinal Section, and Half- breadth Deck Plan of Large Vessels on a reduced Scale. 11. Midship Sections of Three Vessels. 12. Large Vessel , showing Details — Fore End in Section, and End View, with Stern Post, Crutches, &c. 13. Large Vessel, showing Details — A fter End in Section, with End View, Stern Frame for Screw, and Rudder. 14. L arge Vessel, showing De tails — Mid- ship Section, half breadth. 15. Machines for Punching and Shearing Plates and Angle-Iron, and for Bending Plates ; Rivet Hearth. 15#. Beam-Bending Machine, Indepen- dent Shearing, Punching and Angle- Iron Machine. 15& Double Lever Punching and Shearing Machine, arranged for cutting Angle and T Iron, with Dividing Table and Engine. 16. Machines. — Garforth’s Riveting Ma- chine, Drilling and Counter-Sinking Machine. 1 6 a. Plate Planing Machine. 1 7. Air Furnace for Heating Plates and Angle-Iron : Various Tools used in Riveting and Plating. 18. Gunwale ; Keel and Flooring ; Plan for Sheathing with Copper. 18 a. Grantham’s Improved Plan of Sheath- ing Iron Ships with Copper. 19. Illustrations of the Magnetic Condi- tion of various Iron Ships. 20. Gray’s Floating Compass and Bin- nacle, with Adjusting Magnets, &c. 21. Corroded Iron Bolt in Frame of Wooden Ship ; Jointing Plates. 22-4. Great Eastern — Longitudinal Sec- tions and Half-breadth Plans — Mid- ship Section, with Details — Section in Engine Room, and Paddle Boxes. 25-6. Paddle Steam Vessel of Steel. 27. Scarbrough — Paddle Vessel of Steel. 28-9. Proposed Passenger Steamer. 30. Persian — Iron Screw Steamer. 31. Midship Section of H.M. Steam Frigate, Warrior. 32. Midship Section of H.M. Steam Frigate, Hercules. 33. Stem, Stern, and Rudder of H.M. Steam Frigate, Belleropho?i. 34. Midship Section of H. M. Troop Ship, Serapis. 35. Iron Floating Dock. “An enlarged edition of an elaborately illustrated work.” — Builder , July 11, 1868. “ This edition of Mr. Grantham’s work has been enlarged and improved, both with respect to the text and the engravings being brought down to the present period . . The practical operations required in producing a ship are described and illustrated with care and precision.” — Mechanics' Magazine , July 17, 1868. “ A thoroughly practical work, and every question of the many in relation to iron shipping which admit of diversity of opinion, or have various and conflicting personal interests attached to them, is treated with sober and impartial wisdom and good sense. . . . . As good a volume for the instruction of the pupil or student of iron naval architecture as can be found in any language.” — Practical Mechanic's Journal, August, 1868. “ A very elaborate work. . . . It forms a most valuable addition to the history of iron shipbuilding, while its having been prepared by one who has made the subject his study for many years, and whose qualifications have been repeatedly recognised, will recommend it as one of practical utility to all interested in shipbuilding.” — Army and Navy Gazette , July 11, 1868. WORKS PUBLISHED BY LOCKWOOD & CO. 19 CARPENTRY, TIMBER, &c. ♦ Tredgold' s Carpentry , new & enlarged Edition. THE ELEMENTARY PRINCIPLES OF CARPENTRY : a Treatise on the Pressure and Equilibrium of Timber Framing, the Resistance of Timber, and the Construction of Floors, Arches, Bridges, Roofs, Uniting Iron and Stone with Timber, &c. To which is added an Essay on the Nature and Properties of Timber, & c., with Descriptions of the Kinds of Wood used in Building ; also numerous Tables of the Scantlings of Timber for different purposes, the Specific Gravities of Materials, &c. By Thomas Tredgold, C.E. Edited by Peter Barlow, F.R.S. Fifth Edition, cor- rected and enlarged. With 64 Plates (1 i of which now first appear in this edition), Portrait of the Author, and several Woodcuts. In 1 vol., 4to, published at il. 2s., reduced to 1 /. 5 a, cloth. “‘Tredgold’s Carpentry’ ought to be in every architect’s and every builder’s library, and those who do not already possess it ought to avail themselves of the new issue.” — Builder , April 9, 1870. A work whose monumental excellence must commend it wherever skilful car- pentry is concerned. The Author’s principles are rather confirmed than impaired by time, and, as now presented, combine the surest base with the most interesting display of progressive science. The additional plates are of great intrinsic value.” — Building News, Feb. 25, 1870. “‘Tredgold’s Carpentry’ has ever held a high position, and the issue of the fifth edition, in a still more improved and enlarged form, will give satisfaction to a very large number of artisans who desire to raise themselves in their business, and who seek to do so by displaying a greater amount of knowledge and intelligence than their fellow-workmen. It is as complete a work as need be desired. To the superior workman the volume will prove invaluable ; it contains treatises written in language which he will readily comprehend.” — Mining Journal , Feb. 12, 1870. Grandy s Timber Tables . THE TIMBER IMPORTER’S, TIMBER MERCHANT’S, and BUILDER’S STANDARD GUIDE. By Richard E. Grandy. Comprising : — An Analysis of Deal Standards, Home and Foreign, with comparative Values and Tabular Arrangements for Fixing Nett Landed Cost on Baltic and North American Deals, including all intermediate Expenses, Freight, Insurance, Duty, &c., & c. ; together with Copious Information for the Retailer and Builder. i2mo, price 7 s. 6d. cloth. “ Everything it pretends to be : built up gradually, it leads one from a forest to a trenail, and throws in, as a makeweight, a host of material concerning bricks, columns, cisterns, &c. — all that the class to whom it appeals requires.” — English Mechanic. “ The only difficulty we have is as to what is not in its pages. What we have tested of the contents, taken at random, is invariably correct.” — Illustrated Builders Journal. Tables for Packing-Case Makers. PACKING-CASE TABLES ; showing the number of Superficial Feet in Boxes or Packing-Cases, from six inches square and upwards. Compiled by William Richardson, Accountant. Oblong 4to, cloth, price 3 s. 6d. “Will save much labour and calculation to packing-case makers and those who use packing-cases.” — Grocer. “ Invaluable labour-saving tables.” — Ironmonger. 20 WORKS PUBLISHED BY LOCKWOOD & CO. Nicholson s Carpenter s Guide. THE CARPENTER’S NEW GUIDE ; or, BOOK of LINES for CARPENTERS : comprising all the Elementary Principles essential for acquiring a knowledge of Carpentry. Founded on the late Peter Nicholson’s standard work. A new Edition, revised by Arthur Ashpitel, F.S.A., together with Practical Rules on Drawing, by George Pyne. With 74 Plates, 4to, 1 /. is. cloth. Dowsing' s Timber Merchant' s Companion. THE TIMBER MERCHANT’S AND BUILDER’S COM- PANION ; containing New and Copious Tables of the Reduced Weight and Measurement of Deals and Battens, of all sizes, from One to a Thousand Pieces, and the relative Price that each size bears per Lineal Foot to any given Price per Petersburgh Standard Hundred ; the Price per Cube Foot of Square Timber to any given Price per Load of 50 Feet; the proportionate Value of Deals and Battens by the Standard, to Square Timber by the Load of 50 Feet ; the readiest mode of ascertaining the Price of Scantling per Lineal Foot of any size, to any given Figure per Cube Foot. Also a variety of other valuable information. By William Dowsing, Timber Merchant. Second Edition. Crown 8vo, 3.5*. cloth. “ Everything is as concise and clear as it can possibly be made. There can be no doubt that every timber merchant and builder ought to possess it, because such possession would, with use, unquestionably save a very great deal of time, and, moreover, ensure perfect accuracy in calculations. There is also another class besides these who ought to possess it ; we mean all persons engaged in carrying wood, where it is requisite to ascertain its weight. Mr. Dowsing’s tables provide an easy means of doing this. Indeed every person who has to do with wood ought to have it .” — Hull Advertiser. Mechanic s Workshop Companion. THE OPERATIVE MECHANIC’S WORKSHOP COM- PANION, and THE SCIENTIFIC GENTLEMAN’S PRAC- TICAL ASSISTANT ; comprising a great variety of the most useful Rules in Mechanical Science ; with numerous Tables of Prac- tical Data and Calculated Results. By W. Templeton, Author of “The Engineer’s, Millwright’s, and Machinist’s Practical As- sistant.” Tenth Edition, with Mechanical Tables for Operative Smiths, Millwrights, Engineers, &c. ; together with several Useful and Practical Rules in Hydraulics and Hydrodynamics, a variety of Experimental Results, and an Extensive Table of Powers and Roots. 11 Plates. i2mo, 5 s. bound. [Just published. “ As a text-book of reference, in which mechanical and commercial demands are judiciously met, Templeton’s Companion stands unrivalled.” — Mechanics' Magazine. “ Admirably adapted to the wants of a very large class. It has met with great success in the engineering workshop, as we can testify ; and there are a great many men who, in a great measure, owe their rise in life to this little work .” — Building News. MECHANICS, >■ WORKS PUBLISHED BY LOCKWOOD & CO. 21 Engineer s Assistant. THE ENGINEER’S, MILLWRIGHT’S, and MACHINIST’S PRACTICAL ASSISTANT ; comprising a Collection of Useful Tables, Rules, and Data. Compiled and Arranged, with Original Matter, by W. Templeton. 4th Edition. i8mo, 2 s. 6 d. cloth. ** So much varied information compressed into so small a space, and published at a price which places it within the reach of the humblest mechanic, cannot fail to com- mand the sale which it deserves. With the utmost confidence we commend this book to the attention of our readers.” — Mecha?iics' Magazine . “ Every mechanic should become the possessor of the volume, and a more suitable present to an apprentice to any of the mechanical trades could not possibly be made.” — Building News. Designing , Measuring , and Valuing. THE STUDENT’S GUIDE to the PRACTICE of ME A- SURING, and VALUING ARTIFICERS’ WORKS ; containing Directions for taking Dimensions, Abstracting the same, and bringing the Quantities into Bill, with Tables of Constants, and copious Memoranda for the Valuation of Labour and Materials in the res- pective Trades of Bricklayer and Slater, Carpenter and Joiner, Painter and Glazier, Paperhanger, &c. With 43 Plates and Wood- cuts. Originally edited by Edward Dobson, Architect. New Edition, re-written, with Additions on Mensuration and Construc- tion, and several useful Tables for facilitating Calculations and Measurements. By E. Wyndham Tarn, M.A., Architect. 8vo, ioj'. 6 d. cloth. {Just published. “ This useful book should be in every architect’s and builder’s office. It contains a vast amount of information absolutely necessary to be known.” — Fhe Irish Biulder. “ The book is well worthy the attention of the student in architecture and surveying, as by the careful study of it his progress in his profession will be much facilitated.” — Mining Journal , Feb. n, 1871. “ We have failed to discover anything connected with the building trade, from ex- cavating foundations to bell-hanging, that is not fully treated upon in this valuable work.” — The Artizan, March, 1871. “ Mr. Tarn has well performed the task imposed upon him, and has made many further and valuable additions, embodying a large amount of information relating to the technicalities and modes of construction employed in the several branches of the building trade From the extent of the information which the volume embodies, and the care taken to secure accuracy in every detail, it cannot fail to prove of the highest value to students, whether training in the offices of provincial surveyors, or in those of London practitioners.” — Colliery Guardian , February 10th, 1871. “ Altogether the book is one which well fulfils the promise of its title-page, and we can thoroughly recommend it to the class for whose use it has been compiled. Mr. Tarn’s additions and revisions have much increased the usefulness of the work, and have especially augmented its value to students. Finally, it is only just to the pub- lishers to add that the book has been got up in excellent style, the typography being bold and clear, and the plates very well executed.” — Enguieering, March 24, 1871. Superficial Measurement. THE TRADESMAN’S GUIDE TO SUPERFICIAL MEA- SU REM ENT. Tables calculated from 1 to 200 inches in length, by 1 to 108 inches in breadth. For the use of Architects, Surveyors, Engineers, Timber Merchants, Builders, &c. By James Haw- kings. Fcp. 3J-. 6 d. cloth. 22 WORKS PUBLISHED BY LOCKWOOD & CO. MATHEMATICS, &c. Gregory s Practical Mathematics. MATHEMATICS for PRACTICAL MEN ; being a Common- place Book of Pure and Mixed Mathematics. Designed chiefly for the Use of Civil Engineers, Architects, and Surveyors. Part I. Pure Mathematics— comprising Arithmetic, Algebra, Geometry, Mensuration, Trigonometry, Conic Sections, Properties of Curves. Part II. Mixed Mathematics — comprising Mechanics in general, Statics, Dynamics, Hydrostatics, Hydrodynamics, Pneumatics, Mechanical Agents, Strength of Materials. With an Appendix of copious Logarithmic and other Tables. By Olinthus Gregory, LL.D., F.R. A.S. Enlarged by Henry Law, C.E. 4th Edition, carefully revised and corrected by J. R. Young, formerly Profes- sor of Mathematics, Belfast College; Author of “A Course of Mathematics,” &c. With 13 Plates. Medium 8vo, 1 /. Is. cloth. “ As a standard work on mathematics it has not been excelled.” — Artizan. “ The engineer or architect will here find ready to his hand, rules for solving nearly every mathematical difficulty that may arise in his practice. As a moderate acquaint- ance with arithmetic, algebra, and elementary geometry is absolutely necessary to the proper understanding of the most useful portions of this book, the author very wisely has devoted the first three chapters to those subjects, so that the most ignorant may be enabled to master the whole of the book, without aid from any other. The rules are in all cases explained by means of examples, in which every step of the process is clearly worked out.” — Builder. “ One of the most serviceable books to the practical mechanics of the country. . The edition of 1847 was fortunately entrusted to the able hands of Mr. Law, who revised it thoroughly, re-wrote many chapters, and added several sections to those which had been rendered imperfect by advanced knowledge. On examining the various and many improvements which he introduced into the work, they seem almost like a new structure on an old plan, or rather like the restoration of an old ruin, not only to its former substance, but to an extent which meets the larger requirements of modern times In the edition just brought out, the work has again been revised by Professor Young. He has modernised the notation throughout, introduced a few paragraphs here and there, and corrected the numerous typographical errors which have escaped the eyes of the former Editor. The book is now as complete as it is possible to make it We have carried our notice of this book to a greater length than the space allowed us justified, but the experiments it contains are so interesting, and the method of describing them so clear, that we may be excused for overstepping our limit. It is an instructive book for the student, and a Text- book for him who having once mastered the subjects it treats of, needs occasionally to refresh his memory upon them.” — Building News. The Metric System. A SERIES OF METRIC TABLES, in which the British Standard Measures and Weights are compared with those of the Metric System at present in use on the Continent. By C. H. Dowling, C. E. 8vo, ioj. 6d. strongly bound. “ Mr. Dowling’s Tables, which are well put together, come just in time as a ready reckoner for the conversion of one system into the other.” — Atheneeuni. “ Their accuracy has been certified by Professor Airy, the Astronomer Royal.” — Builder. “ Resolution 8. — That advantage will be derived from the recent publication of Metric Tables, by C. H. Dowling, C.E.” — Report of Section F, British Association , Bath. WORKS PUBLISHED BY LOCKWOOD & CO. 23 Inwood's Tables , greatly enlarged and improved. TABLES FOR THE PURCHASING of ESTATES, Freehold, Copyhold, or Leasehold ; Annuities, Advowsons, &c. , and for the Renewing of Leases held under Cathedral Churches, Colleges, or other corporate bodies ; for Terms of Years certain, and for Lives ; also for Valuing Reversionary Estates, Deferred Annuities, Next Presentations, &c., together with Smart’s Five Tables of Compound Interest, and an Extension of the same to lowfcr and Intermediate Rates. By William Inwood, Architect. The 18th edition, with considerable additions, and new and valuable Tables of Logarithms for the more Difficult Computations of the Interest of Money, Dis- count, Annuities, &c., by M. Fedor Thoman, of the Societe Credit Mobilier of Paris. i2mo, 8 s. cloth. This edition ( the 1 8th) differs in many important particulars from former ones. The changes consist , first, in a more convenient and systematic arrangement of the original Tables, and in the removal of certain numerical errors which a very careful revision of the whole has enabled the present editor to discover ; and secondly, in the extension of practical utility conferred on the work by the introduction of Tables now inserted for the first time. This new and important matter is all so much actually added to Inwood’s Tables ; nothing has been abstracted from the original collection : so that those who have been long in the habit of consulting Inwood for any special profes- sional purpose will, as heretofore , find the information sought still in its pages. “ Those interested in the purchase and sale of estates, and in the adjustment of compensation cases, as well as in transactions in annuities, life insurances, &c., will find the present edition of eminent service.” — Engineeri?ig. Geometry for the A rchitect, Engineer , &c. PRACTICAL GEOMETRY, for the Architect, Engineer, and Mechanic ; giving Rules for the Delineation and Application of various Geometrical Lines, Figures and Curves. By E. W. Tarn, M.A., Architect, Author of “The Science of Building,” &c. With Illustrations. Demy 8vo. [/;z the press. Compound Interest and A nnuities. THEORY of COMPOUND INTEREST and ANNUITIES ; with Tables of Logarithms for the more Difficult Computations of Interest, Discount, Annuities, &c., in all their Applications and Uses for Mercantile and State Purposes. With an elaborate Intro- duction. By Fedor Thoman, of the Societe Credit Mobilier, Paris. i2mo, cloth, 5^. “A very powerful work, and the Author has a very remarkable command of his subject.” — Professor A. de Morgan. “No banker, merchant, tradesman, or man of business, ought to be without Mr. Thoman’ s truly ‘handy-book.’ ” — Review. “ The author of this ‘ handy-book ’ deserves our thanks.” — Insurance Gazette. “We recommend it to the notice of actuaries and accountants.” — Athenceum. 24 WORKS PUBLISHED BY LOCKWOOD & CO. SCIENCE AND ART. The Military Sciences. AIDE-MEMOIRE to the MILITARY SCIENCES. Framed from Contributions of Officers and others connected with the dif- ferent Services. Originally edited by a Committee of the Corps of Royal Engineers. Second Edition, most carefully revised by an Officer of the Corps, with many additions ; containing nearly 350 Engravings and many hundred Woodcuts. 3 vols. royal 8vo, extra cloth boards, and lettered, price 4/. ioj*. “A compendious encyclopaedia of military knowledge, to which we are greatly in- debted.” — Edinburgh Review. “ The most comprehensive work of reference to the military and collateral sciences. Among the list of contributors, some seventy-seven in number, will be found names of the highest distinction in the services. . . . The work claims and possesses the great merit that by far the larger portion of its subjects have been treated originally by the practical men who have been its contributors.” — Volunteer Service Gazette. Field Fortification. A TREATISE on FIELD FORTIFICATION, the ATTACK of FORTRESSES, MILITARY, MINING, and RECON- NOITRING. By Colonel I. S. Macaulay, late Professor of Fortification in the Royal Military Academy, Woolwich. Sixth Edition, crown 8vo, cloth, with separate Atlas of 12 Plates, sewed, price 12 s. complete. Dye- Wares and Colours. THE MANUAL of COLOURS and DYE- W ARES : their Properties, Applications, Valuation, Impurities, and Sophistications. For the Use of Dyers, Printers, Dry Salters, Brokers, &c. By J. W. Slater. Post 8vo, cloth, price 7 s. 6 d. [Recently published. “ Essentially a manual for practical men, and precisely such a book as practical men will appreciate.” — Scientific Review. “ A complete encyclopaedia of the materia tinctoria. The information given respecting each article is full and precise, and the methods of determining the value of articles such as these, so liable to sophistication, are given with clearness, and are practical as well as valuable.” — Chemist and Druggist. Electricity. A MANUAL of ELECTRICITY ; including Galvanism, Mag- netism, Diamagnetism, Electro-Dynamics, Magno-Electricity, and the Electric Telegraph. By Henry M. Noad, Ph. D., F. C.S., Lecturer on Chemistry at St. George’s Hospital. P'ourth Edition, entirely rewritten. Illustrated by 500 Woodcuts. 8vo, I /. 4 s. cloth. “ This publication fully bears out its title of ‘ Manual.’ It discusses in a satisfactory manner electricity, frictional and voltaic, thermo-electricity, and electro-physiology.” — A theticeum. “ The commendations already bestowed in the pages of the Lancet on the former editions of this work are more than ever merited by the present. The accounts given of electricity and galvanism are not only complete in a scientific sense, but, which is a rarer thing, are popular and interesting.” — Lancet. WORKS PUBLISHED BY LOCKWOOD & CO. 2 Text-Book of Electricity. THE STUDENT’S TEXT-BOOK OF ELECTRICITY: in- eluding Magnetism, 'Voltaic Electricity, Electro-Magnetism, Dia- magnetism, Magneto-Electricity, Thermo-Electricity, and Electric Telegraphy. Being a Condensed Resume of the Theory and Ap- plication of Electrical Science, including its latest Practical Deve- lopments, particularly as relating to Aerial and Submarine Tele- graphy. By Henry M. No ad, Ph.D., Lecturer on Chemistry at St. George’s Hospital. Post 8vo, 400 Illustrations, 12 s. 6d. cloth. “We can recommend Dr. Noad’s book for clear style, great range of subject, a good index, and a plethora of woodcuts. Such collections as the present are indispensable." — A thenceum. “ A most elaborate compilation of the facts of electricity and magnetism, and of the theories which have been advanced concerning them." — Popular Science Reviezu. “ Clear, compendious, compact, well illustrated, and well printed, this is an excel- lent manual." — Lancet. “ We can strongly recommend the work, as an admirable text-book, to every student — beginner or advanced — of electricity.” — Ezigineermg. “ The most complete manual on the subject of electricity to be metwith." — Observer. “ Nothing of value has been passed "over, and nothing given but what will lead to a correct, and even an exact, knowledge of the present state of electrical science." — Mechanics' Magazine. “We know of no book on electricity containing so much information on experi- mental facts as this does, for the size of it, and no bo ok of any size that contains so complete a range of facts." — English Mechanic. Rudimentary Magnetism. RUDIMENTARY MAGNETISM : being a concise exposition of the general principles of Magnetical Science, and the purposes to which it has been applied. By Sir W. Snow Harris, F.R.S. New and enlarged Edition, with considerable additions by Dr. Noad, Ph.D. Numerous Woodcuts. i2mo. [_In the press. Chemical A nalysis. THE COMMERCIAL HANDBOOK of CHEMICAL ANA- LY SIS ; or Practical Instructions for the determination of the In- trinsic or Commercial Value of Substances used in Manufactures, in Trades, and in the Arts. By A. Normandy, Author of “ Prac- tical Introduction to Rose’s Chemistry,” and Editor of Rose’s “Treatise of Chemical Analysis.” Illustrated with Woodcuts. Second and cheaper Edition, post 8vo, 9^. cloth. “We -recommend this book to the careful perusal of every one ; it may be truly affirmed to be of universal interest, and we strongly recommend it to our readers as a guide, alike indispensable to the housewife as to the pharmaceutical practitioner." — Medical Times. “The very best work on the subject the English press has yet produced." — Me- chanics' Magazine. Practical Philosophy. A SYNOPSIS of PRACTICAL PHILOSOPHY. By the Rev. John Carr, M.A., late Fellow of Trin. Coll., Cambridge. Second Edition. i8mo, 5^. cloth. 26 WORKS PUBLISHED BY LOCKWOOD & CO. Science and A rt. THE YEAR-BOOK of FACTS in SCIENCE and ART ; ex- hibiting the most important Improvements and Discoveries of the Past Year in Mechanics and the Useful Arts, Natural Philosophy, Electricity, Chemistry, Zoology and Botany, Geology and Mine- ralogy, Meteorology and Astronomy. By John Timbs, F.S.A., Author of “Curiosities of Science,” “Things not Generally Known,” &c. With Steel Portrait and Vignette. Fcap. 5^. cloth. *** This work , published annually , records the proceedings of the principal scientific societies, and is indispensable to all who wish to possess a faithful record of the latest novelties in science and the arts. The back Volumes, from 1861 to 1870, each containing a Steel Portrait, and an extra Volume for 1862, with Photograph, may still be had, price $s. each. “ Persons who wish for a concise annual summary of important scientific events will find their desire in the ‘Year Book of Facts.’ ” — Aiherueunt. “ The standard work of its class. Mr. Timbs’s ‘ Year Book ’ is always full of sugges- tive and interesting matter, and is an excellent resume of the year’s progress in the sciences and the arts.” — Builder. “ A correct exponent of scientific progress .... a record of abiding interest. If anyone wishes to know what progress science has made, or what has been done in any branch of art during the past year, he has only to turn to Mr. Timbs’s pages, and is sure to obtain the required information.” — Mechanics' Magazine. “ An invaluable compendium of scientific progress for which the public are indebted to the untiring energy of Mr. Timbs.” — Atlas. “ There is not a more useful or more interesting compilation than the ‘ Year Book of Facts.’ . . . The discrimination with which Mr. Timbs selects his facts, and the admi- rable manner in which he condenses into a comparatively short space all the salient features of the matters which he places on record, are deserving of great praise. ” — Railway News. Science and Scripture. SCIENCE ELUCIDATIVE OF SCRIPTURE, AND NOT ANTAGONISTIC TO IT ; being a Series of Essays on— I. Alleged Discrepancies ; 2. The Theory of the Geologists and Figure of the Earth ; 3. The Mosaic Cosmogony ; 4. Miracles in general — Views of Hume and Powell ; 5. The Miracle of Joshua — Views of Dr. Colenso : The Supernaturally Impossible ; 6. The Age of the Fixed Stars — their Distances and Masses. By Professor J. R. Young, Author of “ A Course of Elementary Mathematics,” &c. &c. Fcap. 8vo, price $s. cloth lettered. “ Professor Young’s examination of the early verses of Genesis, in connection with modern scientific hypotheses, is excellent.” — English Churchman. “ Distinguished by the true spirit of scientific inquiry, by great knowledge, by keen logical ability, and by a style peculiarly clear, easy, and energetic.” — Nonconformist. “No one can rise from its perusal without being impressed with a sense of the sin- gular weakness of modern scepticism.”— Baptist Magazine. “The author has displayed considerable learning and critical acumen in combating the objections alluded to The volume is one of considerable value, inas- much as it contains much sound thought, and is calculated to assist the reader to dis- criminate truth from error, at least so f^r as a finite mind is able to separate them. The work, therefore, must be considered to be a valuable contribution to controversial theological literature.” — City Press. WORKS PUBLISHED BY LOCKWOOD & CO. 27 Geology and Genesis Harmonised. THE TWIN RECORDS of CREATION; or, Geology and Genesis, their Perfect Harmony and Wonderful Concord. By George W. Victor Le Vaux. With numerous Illustrations. Fcap. 8vo, price $s. cloth. “We can recommend Mr. Le Vaux as an able and interesting guide to a popular appreciation of geological science. ” — Spectator. “The author combines an unbounded admiration of science with an unbounded admiration of the Written Record. The two impulses are balanced to a nicety ; and the consequence is, that difficulties, which to minds less evenly poised, would be serious, find immediate solutions of the happiest kinds.” — Lotidon Review. “ A most instructive and readable book. We welcome this volume as aiding in a most important discussion, and commend it to those interested in the subject.” — Evangelical Magazine. “Vigorously written, reverent in spirit, stored with instructive geological facts, and designed to show that there is no discrepancy or inconsistency between the Word and the works of the Creator. The future of Nature, in connexion with the glorious destiny of man, is vividly conceived.” — Watchman- “ No real difficulty is shirked, and no sophistry is left unexposed.” — The Rock. Geology , Physical. PHYSICAL GEOLOGY-. (Partly based on Major-General Portlock’s Rudiments of Geology.) By Ralph Tate, A.L.S., F.G.S. Numerous Woodcuts. i2mo. [Just ready. Geology , Historical. HISTORICAL GEOLOGY. (Partly based on Major-General Portlock’s Rudiments of Geology.) By Ralph Tate, A.L.S., F.G.S. Numerous Woodcuts. i2mo. [Just ready. Wood- Carving. INSTRUCTIONS in WOOD-CARVING, for Amateurs; with Hints on Design. By A Lady. In emblematic wrapper, hand- somely printed, with Ten large Plates, price 2 s. 6d. “ The handicraft of the wood-carver, so well as a book can impart it, may be learnt from ‘A Lady’s’ publication.” — Athenceum. “ A real practical guide. It is very complete.” — Literary Chtirchman. “ The directions given are plain and easily understood, and it forms a very good introduction to the practical part of the carver’s art.” — English Mecha7iic. Popular Work on Painting. PAINTING POPULARLY EXPLAINED; with Historical Sketches of the Progress of the Art. By Thomas John Gullick, Painter, and John Timbs, F. S.A. Second Edition, revised and enlarged. With Frontispiece and Vignette. In small 8vo, 6s. cloth. *** This Work has been adopted as a Prize-book in the Schools of Art at South Kensington. ** A work that may be advantageously consulted. Much may be learned, even by those who fancy they do not require to be taught, from the careful perusal of this unpretending but comprehensive treatise.” — Art Journal. “A valuable book, which supplies a want. It contains a large amount of original matter, agreeably conveyed, and will be found of value, as well by the young artist seeking information as by the general reader. We give a cordial welcome to the book, and augur for it an increasing reputation.” — Builder. “This volume us one that we can heartily recommend to all who are desirous of understanding what they admire in a good painting.” — Daily News. 28 WORKS PUBLISHED BY LOCKWOOD & CO. Delamotte' s Works on Illumination & A Iphabets. A PRIMER OF THE ART OF ILLUMINATION ; for the use of Beginners : with a Rudimentary Treatise on the Art, Prac- tical Directions for its Exercise, and numerous Examples taken from Illuminated MSS., printed in Gold and Colours. By F. Dela- motte. Small 4to, price gs. Elegantly bound, cloth antique. “ A handy book, beautifully illustrated ; the text of which is well written, and cal- culated to be useful. . . . The examples of ancient MSS. recommended to the student, which, with much good sense, the author chooses from collections accessible to all, are selected with judgment and knowledge, as well as taste.” — Athenceum. ORNAMENTAL ALPHABETS, ANCIENT and MEDIAEVAL ; from the Eighth Century, with Numerals ; including Gothic, Church-Text, large and small, German, Italian, Arabesque, Initials for Illumination, Monograms, Crosses, &c. &c., for the use of Architectural and Engineering Draughtsmen, Missal Painters, Masons, Decorative Painters, Lithographers, Engravers, Carvers, &c. &c. &c. Collected and engraved by F. Delamotte, and printed in Colours. Royal 8vo, oblong, price 4 s. cloth. “A well-known engraver and draughtsman has enrolled in this useful book the result of many years’ study and research. For those who insert enamelled sentences round gilded chalices, who blazon shop legends over shop-doors, who letter church walls with pithy sentences from the Decalogue, this book will be useful.” — Athenceum. EXAMPLES OF MODERN ALPHABETS, PLAIN and ORNA- MENTAL ; including German, Old English, Saxon, Italic, Per- spective, Greek, Hebrew, Court Hand, Engrossing, Tuscan, Riband, Gothic, Rustic, and Arabesque ; with several Original Designs, and an Analysis of the Roman and Old English Alpha- bets, large and small, and Numerals, for the use of Draughtsmen, Surveyors, Masons, Decorative Painters, Lithographers, Engravers, Carvers, &c. Collected and engraved by F. Delamotte, and printed in Colours. Royal 8vo, oblong, price 4s. cloth. “ To artists of all classes, but more especially to architects and engravers, this very handsome book will be invaluable. There is comprised in it every possible shape into which the letters of the alphabet and numerals can be formed, and the talent which has been expended in the conception of the various plain and ornamental letters is wonderful. ” — Standard. MEDIAEVAL ALPHABETS AND INITIALS FOR ILLUMI- NATORS. By F. Delamotte, Illuminator, Designer, and Engraver on Wood. Containing 21 Plates, and Illuminated Title, printed in Gold and Colours. With an Introduction by J. Willis Brooks. Small 4to, 6j\ cloth gilt. “A volume in which the letters of the alphabet come forth glorified in gilding and all the colours of the prism interwoven and intertwined and intermingled, sometimes with a sort of rainbow arabesque. A poem emblazoned in these characters would be only comparable to one of those delicious love letters symbolized in a bunch of flowers well selected and cleverly arranged.” — Sun. THE EMBROIDERER’S BOOK OF DESIGN ; containing Initials, Emblems, Cyphers, Monograms, Ornamental Borders, Ecclesias- tical Devices, Mediaeval and Modem Alphabets, and National Emblems. Collected and engraved by F. Delamotte, and printed in Colours. Oblong royal 8vo, 2 s. 6d. in ornamental boards. WORKS PUBLISHED BY LOCKWOOD & CO. 29 AGRICULTURE, &c. Youatt and Burris Complete Grazier. THE COMPLETE GRAZIER, and FARMER’S and CATTLE- BREEDER’S ASSISTANT. A Compendium of Husbandry. By William Youatt, Esq., V.S. nth Edition, enlarged by Robert Scott Burn, Author of “The Lessons of My Farm,” &c . One large 8vo volume, 784 pp. with 215 Illustrations. 1 /. is. half-bd. On the Breeding , Rearing , Fatte7iing, and General Management of Neat Cattle. — Introductory View of the different Breeds of Neat Cattle in Great Britain. — Com- parative View of the different Breeds of Neat Cattle. — General Observations on Buying and Stocking a Farm with Cattle. — The Bull.— The Cow. — Treatment and Rearing of Calves. — Feeding of Calvesfor Veal. — Steers and Draught Oxen. — Graz- ing Cattle. — Summer Soiling Cattle. — Winter Box and Stall-feeding Cattle. — Artificial Food for Cattle. — Preparation of Food. — Sale of Cattle. On the Eco7iomy and Management of the Dairy . — Milch Kine. — Pasture and other Food best calculated for Cows, as it regards their Milk. — Situation and Buildings proper for a Dairy, and the proper Dairy Utensils. — Management of Milk and Cream, and the Making and Preservation of Butter. — Making and Pre- servation of Cheese. — Produce of a Dairy. On the Breeding , Rearing, and Ma- nagement of Farm-horses. — Introductory and Comparative View of the different Breeds of Farm-horses. — Breeding Horses, Cart Stallions and Mares. — Rearing and Training of Colts. — Age, Qualifications, and Sale of Horses. — Maintenance and Labour of Farm-horses. — Comparative Merits of Draught Oxen and Horses. — Asses and Mules. On the Breeding, Rearing, and Fat- tening of Sheep. — Introductory and Com- parativ e View of the different Breeds. — Merino, or Spanish Sheep. — Breeding and Management of Sheep. — Treatment and Rearing of House-lambs, Feeding of Sheep, Folding Sheep, Shearing of Sheep, &c. On the Breeding, Rearing, and Fat- tening of Swine. — Introductory and Com- parative View of the different Breeds of Swine. — Breeding and Rearing of Pigs. — Feeding and Fattening of Swine. — Curing Pork and Bacon. On the Diseases of Cattle. — Diseases Incident to Cattle. — Diseases of Calves. — Diseases of Horses. — Diseases of Sheep. — Diseases of Lambs. — Diseases Incident to Swine. — Breeding and Rearing of Do- mestic Fowls, Pigeons, &c. — Palmipedes, or Web-footed kinds. — Diseases of Fowls. On Farm Offices and Implements of Husbandry. — The Farm-house, the Farm- yard, and its Offices. — Construction of Ponds. — Farm Cottages. — Farm Imple- ments. — Steam Cultivation. — Sowing Ma- chines, and Manure Distributors. — Steam Engines, Thrashing Machine's, Corn- dressing Machines, Mills, Bruising Ma- chines. On the Culture and Management oj Grass Land. — Size and Shape of Fields, — Fences. — Pasture Land. — Meadow Land. — Culture of Grass Land. — Hay- making. — Stacking Hay. — Impediments to the Scythe and the Eradication of Weeds. — Paring and Burning. — Draining. Irrigation. — Warping. On the Cultivation and ApplicatioJi of Grasses, Pulse, and Roots. — Natural Grasses usually cultivated. — Artificial Grasses or Green Crops. — Grain and Pulse commonly cultivated for their Seeds, for their Straw, or for Green Forage. — Vegetables best calculated for Animal Food. — Qualities and Compara- tive Value of some Grasses and Roots as Food for Cattle. On Manures in General, and their Application to Grass Land. — Vegetable Manures. — Animal Manures. — Fossil and Mineral Manures.— Liquid or Fluid Ma- nures. — Composts. — Preservation of Ma- nures. — Application of Manures. — Flemish System of Manuring. — Farm Accounts, and Tables for Calculating Labour by the Acre, Rood, &c., and by the Day, Week, Month, &c. — Monthly Calendar of Work to be done throughout the Year. — Obser- vations on the Weather. — Index. “ The standard, and text-book, with the farmer and grazier.” — Farmer's Magazine. “ A valuable repertory of intelligence for all who make agriculture a pursuit, and especially for those who aim at keeping pace with the improvements of the age.” — Bell's Messenger. “ A treatise which will remain a standard work on the subject as long as British agriculture endures .” — Mark LaTte Express. 30 WORKS PUBLISHED BY LOCKWOOD & CO. Scott Burn s Introduction to Farming. 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