SlIRVr; • " JOHN A. HARRISON STATE OF ILLINOIS DEPARTMENT OF REGISTRATION AND EDUCATION Chemical and Physical Character of the Pennsylvanian Sandstones in Central Illinois James C. Bradbury Meredith E. Ostrom J. E. Lamar ILLINOIS STATE GEOLOGICAL SURVEY John C. Frye, Chief URBANA CIRCULAR 331 1962 Digitized by the Internet Archive in 2012 with funding from University of Illinois Urbana-Champaign http://archive.org/details/chemicalphysical310brad CHEMICAL AND PHYSICAL CHARACTER OF THE PENNSYLVANIAN SANDSTONES IN CENTRAL ILLINOIS James C. Bradbury, Meredith E. Ostrom, and J. E. Lamar CONTENTS Page Abstract 3 Introduction 3 Geologic Identity of Sandstones Sampled 4 Geologic Occurrence of Sandstones 4 Results of Earlier Studies 8 Samples 10 Character of Unweathered Sandstones 11 Preparation of Sandstones for Testing 11 Results of Sieve Tests 11 Grain Shape 16 Heavy Mineral Content 17 Light Mineral Content 18 Clay Mineral Content 18 Character of Clay Minerals in Sandstones 19 Chemical Composition IS Fusion Tests 25 Uses for Sandstones 28 Appendix - Description of Deposits Sampled 31 TABLES Page 1 . Geologic Column and Number of Samples Studied 5 2. Summary of Modal Analysis Data 6 3. Average Percentage of Carbonates, Clays, and Feldspar 9 4. Results of Sieve Tests 12 5. Heavy Mineral Content in Sandstones 16 6. Clay Minerals 20 7. Chemical Analyses of Sandstones 22 8. Summary of Chemical Analyses 25 9 . Results of Fusion Tests 26 10. Results of Fusion Tests by Geologic Group 28 11. Sample Numbers with County and Formation Identification 30 FIGURES 1. Index Map Showing Sample Locations and Pennsylvanian Boundary 2. Data on Amount of Sand Retained on 48-, 100-, and 200-mesh sieves 3. Clay Content of Samples by Formations 4. Clay Minerals in Samples by Formations 5. Relation of Fusion Temperatures to Amount and Kind of Clay and Ignition Loss Page CHEMICAL AND PHYSICAL CHARACTER OF THE PENNSYLVANIAN SANDSTONES IN CENTRAL ILLINOIS James C. Bradbury, Meredith E. Ostrom, and J. E. Lamar ABSTRACT Basic data for more than 90 samples of sandstones of Pennsylvanian age that crop out in the central part of Illinois are presented in this report. Chemical composition, refractori- ness, size of the grains composing the sandstones, and other properties that might affect the commercial usefulness of the sandstones either now or in the future are included. INTRODUCTION This report deals with the sandstones of Pennsylvanian age that crop out within the coal basin of Illinois (fig. 1), except those sandstones in extreme south- ern Illinois that have been discussed in an earlier report (Biggs and Lamar, 19 55) , The sandstones dealt with here are undeveloped and constitute a mineral resource of potential future usefulness, either in their natural state or disaggregated. A number of papers have dealt with the distribution of certain Pennsylvan- ian sandstones, their mineral composition, and to a lesser extent their grain shape and particle size (Andresen, 19 61; Ekblaw, 1931; Glass et al, , 1956; Hopkins, 1958; Potter and Glass, 1958; Rusnak, 1957; Siever, 1949, 1957; Siever and Potter, 1956). To determine the possible usefulness of the sandstones, however, additiona data are needed, including chemical analyses, detailed sieve tests, and fusion point data. These data, along with information on mineral composition, percentage of heavy minerals present, and grain shape, are given in this report for samples representing considerably greater thicknesses of sandstone than were studied for earlier reports. These data will enable the mineral industry to evaluate the present uses of the sandstones and their potential value for new uses of mineral raw mater- ials , [ 3 ] ILLINOIS STATE GEOLOGICAL SURVEY CIRCULAR 331 Acknowledgments Several staff members of the Il- linois State Geological Survey assisted in this investigation. L. D. McVicker made chemical analyses. Jack A. Simon checked Pennsylvanian stratigraphy, William F. Bradley provided x-ray data on the amount of clay in samples and the identity of clay minerals, David A. Schaefer and John D. Sims did field sampling and laboratory preparation and testing of samples, James W. Baxter and Richard D. Harvey did field sam- pling, and J. S. Machin supervised fusion tests . GEOLOGIC IDENTITY OF SANDSTONES SAMPLED Table 1 is a geologic column that shows the formations and named sandstones from which samples were taken and the number of samples ob- tained from each. The sampled units are separated by rocks such as shale and limestone and are not in contact ] with each other. Some of the Pennsylvanian sand- stones in Illinois have been given spe- cific names, such as Pleasantview Sandstone. In some cases different names have been given to the same sandstone in different areas of the state before the sand- stones were known to be equivalent. Many of the sandstones, however, have not been given specific names, but the name of the formation in which they occur is named. Such a sandstone might be referred to, for example, as "a sandstone in the Mattoon Formation. " All samples described as coming from a " sandstone" of a particular formation do not necessarily come from the same sandstone stratum because most formations contain more than one sandstone. We believe that this report includes samples from most or all of the major Pennsylvanian sandstones of Illinois, excluding those of extreme southern Illinois discussed by Biggs and Lamar (1955) . More samples were tested from the forma- tions of the McLeansboro Group, especially from the Mattoon Formation, than from other formations because this group contains many sandstone strata that are exposed at many places in south-central and southeastern Illinois. ■ Sample locations, group names, and limits of areas underlain by Pennsylvanian rocks. GEOLOGIC OCCURRENCE OF SANDSTONES The Pennsylvanian sandstones exhibit a wide variety of types of occurrence, ranging from thick, massive sandstones of considerable geographic extent, through PENNSYLVANIAN SANDSTONES IN CENTRAL ILLINOIS 5 massive sandstones of limited geographic extent, to thin-bedded, shaly sandstones of variable extent. The thick, massive, widespread sandstones are found in the Caseyville and Abbott Formations of the McCormick Group, the oldest of the three groups in the Pennsylvanian System of Illinois. Sandstones of the McCormick Group crop out around the edge of the Illinois Basin from southern and southwestern Illinois to Rock Island County in northwestern Illinois. Outcrops become less prominent in western and northwestern Illinois, however, as the thickness of the McCormick Group decreases from about 700 feet in southern Illinois to 100 feet or less in western Illinois (Kosanke et al., 1960). The Caseyville Formation, the lower of the two formations of the McCormick Group, generally is restricted to the southern part of the outcrop belt. Sandstones of the McCormick Group are exposed best in extreme southern Illinois where they form prominent cliffs along the southern edge of the Illinois Basin. As most of this outcrop belt was included in the report by Biggs and Lamar (19 55), the McCormick Group was not sampled extensively for our study. Only one sample from the Caseyville Formation is included. The 11 sandstone samples TABLE 1 -GEOLOGIC COLUMN AND NUMBER OF SAMPLES STUDIED Number of samples taken for Sieve Chemical Geologic column tests analyses McLeansboro Group Mattoon Formation 31 16 Bond Formation (undifferentiated) 9 6 McWain Sandstone Member* 1 1 Mt. Carmel Sandstone Member* 1 1 Modesto Formation (undifferentiated) 10 5 Trivoli Sandstone Member 2 2 Kewanee Group Carbondale Formation Copperas Creek Sandstone Member!]^ 2 2 Anvil Rock Sandstone Member* 1 1 Vermilionville Sandstone Member 9 9 Pleasantview Sandstone Member 8 8 Spoon Formation (undifferentiated) 2 2 Isabel Sandstone Membert 4 4 Palzo Sandstone Membert 2 . 2 Granger Sandstone Member 1 1 McCormick Group Abbott Formation (undifferentiated) 4 4 Bernadotte Sandstone Member+ 1 1 Murray Bluff Sandstone Member* 1 1 Finnie Sandstone Member 2 1 Babylon Sandstone Member 3 3 Caseyville Formation 1 1 * !f t + Each pair of symbols indicates rock units that probably are equivalent but crop out in different parts of the state. i 1 1 1 1 1 g § 1 g c 6 1 o § iis H 1 c 0) 1 1 o § •p >ig = 1^-S 8 ILLINOIS STATE GEOLOGICAL SURVEY CIRCULAR 331 from the Abbott Formation were taken from 4 outcrops in western and northwestern Illinois, a drill core in Jackson County in southwestern Illinois, and 4 outcrops in southern and southwestern Illinois. Sandstones of the Kewanee and McLeansboro Groups are not as well de- veloped as those of the McCormick Group. Their massive sandstones typically are found as fillings of channels in the underlying beds, and in the inter-channel areas the corresponding sandstone units commonly are thin bedded and silty or shaly. The distribution of the thick, massive sandstones, as deduced from out- crop and drilling data, indicates that the channels have configurations similar to present-day stream valleys and probably represent stream-cut valleys on ancient land surfaces . Depths and widths of the ancient valleys are variable, as would be expec- ted, but some are of considerable size. For example, the main channel of the Anvil Rock Sandstone, one of the more prominent channel sandstones, is 2 to 3 miles wide and, not uncommonly, contains thicknesses of sandstone in excess of 100 feet (Potter and Simon, 1961). However, where such great thicknesses are encountered, it is probable that more than one sandstone unit is represented. The Kewanee Group, represented by 29 samples mostly from western and northern Illinois, is well developed throughout the Illinois Basin. Its outcrop belt lies just inside that of the McCormick Group and forms a rude ring around the out- crop area of the younger McLeansboro Group. The McLeansboro Group, the youngest of the three Pennsylvanian groups, forms the surface of the bedrock throughout most of the Illinois Basin and is, there- fore, represented by the greatest number of samples— 54. However, the McLeans- boro Group is present only locally in northern Illinois, and no sandstone outcrops of this group deemed worth sampling were found farther north than Vermilion County. RESULTS OF EARLIER STUDIES Considerable data regarding the petrology of the Pennsylvanian sandstones have been published (references cited in Introduction), most of which are based on the examination of thin sections from hand-specimen sized samples. In this study channel samples were used, each representing a much greater thickness of sand- stone than does a hand specimen. The testing methods employed also were differ- ent, except in the case of the heavy minerals tests. Siever (19 57) presented the largest body of data regarding a variety of Penn- sylvanian sandstones. The major features of his data on heavy minerals are similar to those of the data in this report. Grain shape data, in so far as they can be compared, also are roughly similar. More feldspar, however, was found during the present study than in the earlier studies involving thin sections. The amount of clay mineral material found in the samples of the present study generally is less than that found in the earlier studies, although the amount of clay in some samples is about the same in both investigations. The results of the earlier studies are summarized in tables 2 and 3. The carbonate data are not exactly comparable because some of them include only cal- cite, others calcite and siderite or iron carbonate, and still other data presumably cover all carbonates. However, the data suggest considerable variation in carbon- ate content within geologic groups and between different specimens from the same PENNSYLVANIAN SANDSTONES IN CENTRAL ILLINOIS TABLE 3 -AVERAGE PERCENTAGE OF CARBONATES, CLAYS, AND FELDSPAR SHOWN BY PREVIOUS MODAL ANALYSES samples OUTCROP SAMPLES Carbonates-**- Clay Feldspar No. of (%) (%) (%) samples WELL CORE SAMPLES Carbonates Clay (%) (%) McLEANSBORO GROUP (Siever, 1957; Potter & Glass, 1958) Feldspar (%) Trivoli Sandstone Member (Andresen, 1961) KEWANEE GROUP (Siever, 1957; Potter & Glass, 1958) Pleasantview Sandstone Membert (Rusnak, 1957) Anvil Rock Sandstone Membert (Hopkins, 1958) Spoon Formation Sandstones in Western and Northern Illinoist* (Siever and Potter, 1956) McCORMICK GROUP (Siever, 1957) Babylon Sandstone Member in Western Illinoist# (Siever and Potter, 1956) 13 Caseyville Formation Sandstones in Southern Illinoist (Siever and Potter, 1956) 6 0.2 9 11 7 * Includes all carbonates except where specified otherwise. t Calcite and iron carbonate. t These data not included in those for the group. * These samples were called Tradewater by Siever and Potter but are now recognized as Spoon Formation. * Includes some samples that probably are in the Kewanee Group. o Calcite. 10 ILLINOIS STATE GEOLOGICAL SURVEY CIRCULAR 331 sandstone unit. With the exception of the Pleasantview Sandstone which is high in carbonate content, the sandstones of the McLeansboro Group seem to be more calcareous than those of the Kewanee Group, whereas the McCormick Group sand- stones, excepting the Caseyville sandstone which was noncalcareous in all out- crop samples examined, more often are of intermediate carbonate content. The average carbonate content of the well core samples is higher than that of the outcrop samples (table 3) . The difference in the averages is a matter of a few percent, except for the samples of Caseyville sandstone for which it is much greater. All of the Caseyville samples, most of the McLeansboro and Kewanee samples, and some of the McCormick samples contain carbonate. Generally, the average amount of clay in the outcrop samples from the McLeansboro and Kewanee Groups was about the same, but some of the Trivoli Sandstone samples contained less than the average. The McCormick Group samples also had a lower clay average. The core samples show essentially the same re- lationship, although the Kewanee samples have an average intermediate to those of the other two groups . Outcrop samples of the McCormick Group have the lowest average feldspar content (l percent), whereas the outcrop samples from the other groups average about 4 percent feldspar. Core sample data for all the groups show variations in average feldspar content of between 2 and 5 percent. SAMPLES An index list of sample numbers, the counties from which the samples came, and their geologic formation appear in table 11. Descriptions of the outcrops sam- pled are given in the appendix and are arranged by counties. Most of the samples were taken from sandstones more than 10 feet thick, but some thinner beds were sampled either because they were the thickest available in the area or because it was thought they might have uncommon mineralogical or chemical composition. All but three of the outcrop samples were obtained by taking blocks of stone at regular vertical intervals (generally not more than one foot) from the bottom to the top of the outcrops. If an outcrop contained more than one major kind of sand- stone in strata of considerable thickness, each kind was sampled separately. The exterior weathered material was removed from each block of sandstone, but all of the samples were more or less weathered, as indicated by the oxidized condition of their iron content. In some of the sandstones sampled, varying amounts of calcium carbonate were distributed between the sand grains as a cementing material. Other predomi- nantly noncalcareous sandstones contained lenses or beds of sandstone so cemen- ted. Still other sandstones were completely noncalcareous. If the sandstones contained only a few thin bands or lenses of firmly cemented calcareous sandstone, the calcareous parts usually were not included in the sample. However, some highly calcareous sandstone outcrops were sampled in their entirety. A few of the samples proved upon testing to contain so much clay or carbon- ate that strict lithologic usage might require some term other than sandstone for them, but because they had the gross appearance of sandstone in the outcrops, they are so described. PENNSYLVANIAN SANDSTONES IN CENTRAL ILLINOIS 11 CHARACTER OF UNWEATHERED SANDSTONES Only rarely has it been possible to compare the character of the weathered sandstone in an outcrop with that of the unweathered sandstone in the same deposit several hundred feet back from the outcrop and thus determine lateral variation. It is thought, however, that the sandstones that are calcareous in outcrop are likely to be calcareous away from the outcrop. Some noncalcareous sandstone outcrops may be more or less calcareous where freshly exposed and unweathered; others, however, are believed to be noncalcareous when fresh. Test drilling is advisable to determine the character of the sandstone away from the outcrop if the carbonate content of a sandstone deposit is critical to its use. Aside from the carbonate content, the chief differences between the fresh and weathered sandstone are believed to be as follows: (l) The fresh sandstones are more likely to be gray, or possibly nearly white, because the iron compounds present are not oxidized; (2) the actual amount of analytically determined Fe203 in the fresh samples probably is about the same as it is in the weathered samples, but the iron is present as hydrated oxides in the weathered rock, whereas in the fresh rock it is present as pyrite or marcasite (both iron sulfides) or as other iron minerals; (3) the clay mineral material in the fresh rock may be less degraded than that in the weathered stone; and (4) the unweathered sandstone may be harder than the weathered sandstone. PREPARATION OF SANDSTONES FOR TESTING Field samples were crushed to about one-fourth of an inch in a laboratory jaw crusher. Two fractions of about 200 grams each were split out mechanically. One was ground to 200 mesh in a ball mill and analyzed chemically. The second was used for particle size determinations and other tests. A reasonable state of disaggregation was achieved by means of a glass rolling pin and gentle rubbing in a mortar and pestle. Grain breakage or damage is believed to have been minor. Samples of firmly cemented calcareous sandstone were treated with hydrochloric acid to remove carbonates before sieving. RESULTS OF SIEVE TESTS Sieve tests of all samples were made with Tyler sieves. The sieving period was 10 minutes. The results of sieve tests are given in table 4. The sandstones are generally medium to fine grained but many are silty and clayey. Only 4 of the 95 samples reported in table 4 contain more than 10 percent of sand retained on a 35-mesh sieve Twenty-one samples have more than 10 percent sand coarser than a 48-mesh sieve. The combined pan and clay fractions of 51 samples are greater than 20 percent. 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