J BBK NOTES ON THE TREATMENT OF MERCURY IN NORTH CALIFORNIA. BY T. EGLESTON, Ph. D., COLUMBIA SCHOOL OF MINES, NEW YORK CITY. [FROM VOL. Ill TRANSACTIONS OF THE AMERICAN INSTITUTE OF MINING ENGINEERS.] PHILADELPHIA: SHEKMAN & CO, PRINTERS. 1 8 7 6 . Digitized by the Internet Archive in 2016 https://archive.org/details/notesontreatmentOOegle NOTES ON THE TREATMENT OF MERCURY IN NORTH CALIFORNIA. The ores of mercury of North California are composed of metallic mercury and cinnabar. They are found in serpentine, and are very often associated with chalcedony, in masses more or less irregular, often concentrated enough, however, to furnish ores yielding from three to ten per cent., and sometimes richer. This deposit makes its appearance in Vallejo where it has been worked. North of here the mines are more developed. Most of the quicksilver mines, how- ever, are situated in Sonoma and Napa Counties. On its outcrop the serpentine rocks have become decomposed, and have often been washed away to a considerable depth, so that in many cases in their neighborhood, what is apparently nothing but ordinary dirt, will frequently contain from two to three per cent, of metallic mercury, with but a trace of cinnabar, in which case, as at the Sonoma mine, it is made up into adobes and distilled. Such material does not require to be mixed with dirt to be made into adobes. Very often, also, the outcrop of the rock, where it is not decomposed, is filled with metallic mercury, so that by striking a pick into it, as at the Rattle- snake mine, a pound or more of mercury at a time will sometimes spurt out. Such rock as this is found in several localities in every stage of impregnation, and usually makes very rich ore. There is generally, however, very little of it, and it is found only in the first workings ; the ore in depth is always cinnabar. At the Rattlesnake mine near Pine Flat, where large quantities of metallic mercury are found, the rock contains so much petroleum that it has been necessary to make special arrangements to burn the carbides of hydrogen, since the dis- tillation of the petroleum causes an extra quantity of poor soot to be formed in the condensation-chambers. At the Geysers the ore is associated with large quantities of sulphur and gypsum, so that in a hand specimen there is often more sulphur than cinnabar, which, is 2 4 NOTES ON THE TREATMENT a serious impediment to working, especially for the modern style of furnace with iron condensers, and causes so much soot to be formed that it has been known to penetrate as far as the blower, and to so completely clog it as to prevent its revolution. The ore coming from the mine is more or less hand-picked. In one or two cases attempts have been made to treat the poorest, and especially the very fine ores, mechanically as at the California works. The apparatus used for the purpose is very rude, and the treatment does not seem to be very successful, as there is visibly a considerable loss in the tailings. 7 Usually the fine ore is not concentrated ; it is taken as it comes from the mine, mixed with dirt and made up into adobes, which have no regular size or weight, and treated in the furnace. The processes by which the ore is treated are, first, the process by precipitation ; second, by roasting. The precipitation is done in retorts with lime, and consists of oxidizing the sulphur by means of an excess of air, and so producing sulphate of lime and free mercury. The roasting is done either in retorts, or in other furnaces which are not continuous, and in several styles of continuous furnaces. The reaction consists in volatilizing the sulphur and oxidizing it so as to produce free mercury and sulphuric acid, which, with the moisture of the fuel and ore is condensed and allowed to run to waste. The furnaces which are not continuous are a modification of the old Idria furnace, which is used at Knoxville and at New Almaden in South California. Those which are continuous are the Luckhart, which is used at Sonoma, and which was being built at the Rattlesnake mine and elsewhere ; and the Knox furnace, which is in very successful operation at the Redington, Manhattan, and the California mines, and elsewhere. There are a number of other varieties of furnaces, none of which, however, I saw. To these processes should be added the process of distillation, if the metallic mercury of the outcrops were found in sufficient quantities to warrant the ore being treated alone. This, however, has never been the case, and the small quantities that are found are charged in the furnace with the other ores, either as rock ore or as adobes. Very little effort is made to sort the ore, and this generally consists in a rough attempt at hand-picking. No as- says of any kind are made. The furnace manager, or miner, judges by the eye that the ore contains one, two, three, ten, or twenty-five per cent., as the case may be, and hence there is little faith to be placed in the statement of many of the advocates of different kinds of furnaces, that their furnace yields such and such a percentage of the assay value. OF MERCURY IN NORTH CALIFORNIA. 5 The mercury produced is put up in iron flasks, which contain 76J lbs. each, with an iron screw for a cork, and shipped. Irregu- lar flasks, as they are called, contain less or more. METHOD OF DISTILLATION. AMERICAN MINE. At the American Mine, near Pine Flat, all the ore is crushed fine in an ordinary California stamp-mill, with a battery of ten stamps, which is run at a high velocity. It is then mixed with lime, and treated in retorts. The average yield of the ore is said to be two per cent. There are twelve retorts 9 feet long, 2 feet wide, and 18 inches high in the middle. They are made of cast iron, and are D-shaped like the ordinary gas retort, and are arranged in benches of three, the centre one being the highest, so that there are four fireplaces to the twelve retorts. The charge consists of 150 lbs. of crushed ore, to which ten per cent, of quicklime is added. This charge is intro- duced into the muffle in an iron spoon 6 feet long, 9 inches wide, and 6 inches deep. This is carried by three men, one taking the end, which has an iron handle 2 feet long, with a crossbar of wood of the same length. The middle is supported on an iron bar, curved in the middle to fit the shape of the spoon, with handles projecting 18 inches from the sides, and is carried by two men. This spoon is introduced into the muffle and shoved to its end. It is drawn out by short jerks, so as to leave the charge in the retort. The doors of the retort are then fastened by means of thumb-screws, and luted with wood ashes, and fired during four hours, when the charge is withdrawn. Not over 500 lbs. per retort is treated in twelve hours. The condensation pipes are in the back of the retort. A pipe, about 18 inches long, connects each retort with a vertical pipe about 5 feet long, which connects with a horizontal pipe 6 inches in diameter, placed in a water-tank at a lower level than the front of the furnace, and which receives the pipes of all the retorts. Every six retorts are so arranged that they discharge their condensed mer- cury through a siphon pipe. The soot is treated with lime as is usual. These works are new and carefully built. It is surprising to see works upon which no expense seems to have been spared, apparently put up to treat such very small quantities at a time of very lean ore by such a system ; not even the possible economy of the retort sys- tem seems to have been taken into account. There did not seem to be sufficient care taken with the condensation apparatus, for the air 6 NOTES ON THE TREATMENT for some distance from the works was filled with mercurial vapors ; and though the workmen wore wet sponges over their mouths and noses, most of them were more or less salivated. I did not visit the mines; but any mine which would justify such carefully erected works with stamp-mills, would certainly justify the erection of other and less wasteful furnaces. METHOD OF ROASTING. The method by roasting is the one which is the most extensively used, and all the different varieties, of furnaces are adapted to it. Those most in use are retorts, and the modified Idria furnace of the non-continuous varieties, the Luckhart and the Knox furnace of the continuous ones. NON-CONTINUOUS FURNACES. Missouri Mine. At the Missouri mine, near Pine Flat, the average yield of the ore is from one-half to 2 per cent, of mercury. The cinnabar is irregu- larly scattered through a chalcedony found in very irregular masses in serpentine ; the large pieces are crushed in a Blake’s crusher to about 1 cubic inch in size. There are two benches of retorts, one con- taining two retorts and holding 250 pounds of charge at a time, and the other containing three retorts and holding 350 pounds, so that the small retorts treat 1000 and the large ones 2100 pounds in twenty-four hours. The large retorts have been in use but a short time, and have consequently produced but little. The retorts are D-shaped, and are here 9 feet long, 12 inches high, and 18 inches wide on the bottom ; they are charged every twelve hours by means of a shovel. At the Lost Ledge mine the same company have three retorts which are only five feet in length, and have a capacity of 500 pounds, or 160 pounds each ; they are charged every four hours, and consequently treat 3000 pounds of ore in twenty-four hours. It takes three-quarters of an hour at the Missouri mine to discharge and charge the large retorts, and half an hour for the small ones, so that, as there is not much difference in the wear and tear, the large size retorts are the most advantageous. They are never filled full, as there would be danger that the pressure of the discharging vapors might force an exit through the luted joints. When the furnace is ready to be discharged the men cover their mouths and noses with wet sponges, tied on with bandages, and then remove the cover of the retorts. When they are about to be re- moved a little fan placed on the condensing pipes is set in motion to cause ah aspiration through the retorts, so that no mercurial fumes OF MERCURY IN NORTH CALIFORNIA. 7 escape. When the fumes cease to be dense the charge is drawn out of the retort with long hoes on to the floor in front of the furnace. The discharged ore is at a cherry -red heat, and, as it is not entirely free from mercury, a considerable quantity of fumes are given off so that the precaution of using the bandage over the mouth and nose is indispensable. After the ore has all been raked out, it is carried as quickly as possible a short distance from the furnace and extin- guished with water, a new charge being put in in the meantime. This is an exceedingly bad system, as the workmen are constantly exposed to fumes, more especially when water is scarce, since small quantities at a time thrown on the very hot ore seems to increase the quantity of fumes. The men, however, seem to know this, and take the necessary precautions, as none of them were salivated. The product of the small retorts varies from 3f to 70 pounds of mercury in twenty-four hours. The large ones yield from 10 to 100 pounds. As the two benches of retorts are at some distance, each bench requires one man per shift of twelve hours, who is paid $3.75 a day. They burn 3J cords of wood in twenty-four hours. Wood costs $6 per cord, and labor $64 per month with board. Each retort is connected by a short joint, with a horizontal pipe leading to the condenser, which must be large enough to insure of its not being clogged by the soot. This pipe is of cast iron, and is 30 feet long and 6 inches in diameter. The pipes leading from the retorts, in the latest and best construction, come from the back, where there is plenty of* room and they are not in the way, so that they can be large. Formerly they were made to come from the front, where they were in the way of the workmen, and were constantly in danger of being damaged by the charge lying against them as it was drawn from the furnace. The condensing apparatus consists of two cast-iron boxes 3 feet by 2, and 2 feet high, turned down into cast-iron tanks, with inclined bot- toms, which are covered with water. From the bottom of these tanks a wrought-iron pipe, curved in the shape of an S, is placed, with the arms sufficiently long to counterbalance the pressure of the water, so that the mercury flows from it continuously. The mercury commences to flow two and one-half hours after the charge is put in. Between the two cast-iron boxes, which are connected with each other, and on the main pipe, a small fan-blower is placed, and is made to suck out the vapors from the retorts, or when the condenser is to be cleaned into an exterior pipe. The fan is inclosed in a box 18 inches square, into which there is an opening 1 foot in diameter, closed with a hy- draulic packing. The pipesand condensers are cleaned once a week. 8 NOTES ON THE TREATMENT In the small furnace 140 pounds of soot and mercury together are collected ; this is put into a sheet-iron pan, 8 feet long, 3 feet wide, 6 inches deep, inclined about 25°, which is not fixed, but is moved from place to place as convenience may require. The soot is placed at its upper end, and is worked with a hoe for a quarter of an hour, to separate the free mercury. Three to five pounds of unslacked lime without water are then stirred into it. As the soot is already damp, the lime soon commences to slack ; it is left until it slacks en- tirely. No one goes near it for one-half or three-quarters of an hour, on account of the vapors arising frdpi it. It is then worked with a hoe for three hours. About one barrel of lime, which costs $3 the barrel, is used per week for treating the soot. The mercury as it is collected runs into the lower part of the pan, and is taken out with a ladle and put into fiasks. The residue, which has twice the bulk which the soot originally had, is added to the next charge of the retorts, in addition to the charge of ore. Such a charge will produce about 10 pounds more of mercury than usual. From 140 pounds of soot, 120 pounds of mercury are obtained directly, and about 10 pounds more from soot charged in the furnace. The large furnaces were run 10 days; 200 pounds were taken from the first condensers and pipes, and from 12 to 14 out of the second condenser. When there is only a small amount of soot to be treated, a small cast-iron sink 3 feet by 18 inches is used, the drain-hole being placed over an enamelled iron vessel 1 foot in diameter, and 6 inches deep. This vessel is used because ordinary kitchen utensils answer perfectly well, and can be had much cheaper than special apparatus, which would work no better. The expenses are for twenty-four hours : 2 men at the retorts, $6.50 3|- cords of wood, at $6, 21 00 Lime for soot, ......... 50 Crushing the ore two days, at $1.25, 2.50 There does not seem to be any real economy in using this retort system. The yield is not greater, nor is the cost of repairs and run- ning less, while the risk of salivation is greater. There is certainly an economy of first installation, and this seems to be the only reason why such furnaces are used. With the high prices of quicksilver w’hich have ruled during 1873 and most of 1874, every place where ores could be found has been worked, and as all the deposits are irregular and uncertain, the owners of such mines have not felt themselves justified in going to any greater expense. I saw no well- developed property, nor any property which appeared to have any OF MERCURY IN NORTH CALIFORNIA. 9 future, which was worked with retorts, except in a few instances, where the retorts were put up to have a yield while other furnaces were being erected on the property developed, or where the mines were evidently being worked w 7 ith too small a capital. MODIFIED IDRIA FURNACE. Redington Works. As an example of non-continuous working with shaft furnaces, I have selected the practice of the Redington mine, with the old Idria furnace, which is by far the largest mercury works in North California. But as everything relating to this variety of furnace, which is destined in a few years to disappear altogether, is of interest, I have added some details relating to the New Almaden furnace of the same type, which I visited shortly after, although they are south of San Fran- cisco. Great attention is being paid to the question of condensation, which is, perhaps, even more important than that of the furnace. The two questions are, however, intimately connected, and are en- gaging the most serious study of all persons interested in the metal- lurgy of mercury. At Knoxville, the Redington Quicksilver Company treat the ores from the Redington mine, which they own, in both the modified Idria furnaces, of which they have two, and also in the Knox fur- naces, of which there are two working, and two in the course of construction ; besides these, two others are to be built. The furnaces are situated at the mines and within a few feet of the ore shaft. The mine produces 700 to 800 tons of cinnabar per week. The ore occurs in a sand-rock, in serpentine. Much pure cinnabar is found, and a considerable quantity of high grade ore, but the average yield of the whole mine is about 3 per cent. Metacinnabarite is found in con- siderable quantities in these mines. Epsomite, resulting from the decomposition of the serpentine, also occurs here in very large quan- tities, in acicular crystals over a foot long. The ore is largely asso- ciated with pyrites. About one-tenth of the ore comes from the open cut made in the side of the hill. From the mine the ore is thrown upon screens placed one over the other ; the upper screen is made of round iron bars 1 \ inches in diameter, placed 2 inches apart at the top, and 2J- at the bottom. The screen itself is 5 feet wide at the top, 5 feet 6 inches at the bottom, and is 8 feet long. Whatever passes over this screen only, is hand-picked. What passes through falls upon strong iron-wire screen of J-inch mesh. What goes over the second screen goes directly to the furnace, and is charged with the hand-picked ore ; what passes through is treated as fine ore ; all 10 NOTES ON THE TREATMENT the large pieces are broken by hand. Before the Knox furnace was introduced, the ore was dressed by hand up to 5 per cent. All the fine ore is mixed with dirt and made into adobes, which are sun-dried and stored, for use in the modified Idria furnaces ex- clusively. There is no generally adopted size for the adobes. They are made in roughly constructed wooden frames, made by the work- men, which wear out rapidly. The usual sizes are 9x4x4 inches. When dry such adobes weigh 12 pounds. They are sometimes made 12 x 5 X 5 inches, which is